A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（1 ) 1 1 本 發 明 係 有 關 一 種 金 屬 赍 及 金 屬 膜 的 製 法 Ο 更 詳 -5— 之 1 1 t 本 發 明 係 有 關 一 種 以 低 溫 燒 成 形 成 金 屬 膜 時 所 使 用 的 1 I 金 屬 赍 9 Κ 及 使 用 該 金 屬 赍 之 金 屬 膜 的 製 法 0 本 發 明 金 -V. 請 I 屬 脅 做 為 電 子 材 料 電 子 m 器 % m 械 材 料 等 之 表 面 處 理 先 閲 1 1 1 塗 覆 防 磁 及 裝 飾 或 觸 媒 及 殺 菌 所 使 用 的 金 屬 膜 原 背 之 1 料 極 為 有 用 t 另 外 > 做 為 利 用 於 醫 藥 、 農 藥 等 範 圍 之 金 注 意 1 屬 膜 的 原 钭 亦 極 為 有 用 〇 事 項 1 再 而 且 即 使 是 現 行 中 直 接 使 用 金 屬 本 身 亦 可 Μ 簡 單 Ί - 裝 本 地 製 作 所 企 求 的 金 靥 膜 就 金 屬 膜 之 利 用 而 易 於 處 理 頁 '·—^ 1 | 且 經 濟 Λ 惟 由 於 為 形 成 金 屬 膜 必 須 在 髙 溫 下 爐 A?u 成 故 基 1 1 板 僅 限 於 使 用 高 熔 點 材 料 此 處 若是形成金屬之燒成温g 1 | 愈 低 則 可 廣 泛 地 使 用 — 般 低 價 的 具 低 軟 化 點 之 基 板 1 訂 1 ( 玻 璃 塑 膠 等 ) Ο 本 發 明 係 有 關 可廣泛地利用於上述 範 圍 之 低 溫 燒 成 用 金 屬 赍 〇 1 I 金 屬 係 各 具 有 個 別 有 用 的 性 質 〇 各 種 金 屬 可 藉 由 各 種 1 1 的 方 法 單 獨 或 Μ 合 金 方 式 在 陶 瓷 等 之 基 板 上 形 成 膜 t 〜1 利 用 各 特 徵 之 性 質 ( 導 電 性 抵 抗 性 半 導 電 性 透 明 |-Η；'—' HI I 性 、 離 子 性 耐 腐 蝕 性 摩 擦 性 遮 光 性 著 色 性 及 / 1 1 或 金 屬 光 澤 性 ) 可 使 用 於 電 子 材 料 或 電 子 機 器 、 機 械 1 1 材 料 等 之 表 面 處 理 、 塗 覆 防 磁 裝 飾 觸 媒 及 殺 菌 * 1 I 更 可 利 用 於 醫 藥 農 藥 等 範 圍 Ο 1 1 製 作 金 屬 膜 之 習 知 技 術 9 如 下 所 述 0 1 1 ① 必 須 使 濺 射 法 等 之 髙 真 空 方 法 0 1 ② 塗 覆 厚 膜 眘 法 等 之 金 屬 墨 $ 並 予 Μ 燒 成 的 方 法 等 0 1 -3 1 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公* ) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（2 ) ①之濺射法必須使用高價的高真空之大型裝置，且Μ批 次式之量產性不佳、製造成本高。故使用設備費用低、 生產性高的②眘狀化法。該方法係在基板上塗覆各種金 屬菊=、並予Μ燒成，Μ簡單的方法與裝置連續地低價製 造金屬膜。 該厚膜赍法所使用的赍狀物，係為使各種金屬微粒子 化，僅分散於溶劑之不均勻黏性液體β將其塗覆並予Μ燒 成後，形成僅有金屬粒子接觸的金屬膜，無法形成均匀 膜。因此，為電子業界中最常使用的銀、鈀合金時，例 如即使Μ厚膜齋法形成，仍需升溫至約950¾予Μ燒成， 且使金屬微粒子物理性熔融成均勻的薄膜。所以，形成 金屬膜之基板，必須使用陶瓷基板或金屬板等之高熔點 基板。而且，由於在高溫下燒成，必須有耐高熱之大型 燒成爐與周邊設施、為使高溫燒成之能量等。 因此，能夠儘量降低赍狀物之燒成溫度，則可使設備 費用變得較便宜，亦可Μ節約能量、降低成本。而且， 為企求能夠於一般低價的具低軟化點之基板（玻璃、塑 膠等）上形成金屬膜，故企求更進一步降低形成金屬膜 之燒成溫度。 為了克服該缺點，提議將無機金屬粒子變換為有機金 屬化合物，均勻地溶解於溶劑後，藉由塗覆、燒成製得 薄的均勻金屬膜之方法（有機金屬（Μ0)法）。例如，為 金時使用含硫之有機金化合物的啻狀物法，與使金的微 粒子混練的厚膜裔狀物法相比，以約金量之1/7的微量 -4- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先鬩讀背面之注意事項再填寫本頁) -------------—c":裝------訂---- }! 經濟部中央標準局員工消費合作社印製 A7 __B7_ 五、發明説明（5 ) ，可形成發揮相等性質之均勻金膜。因此，在使用金之 範園，Μ M0法來取代習知的厚膜裔狀物法。 上述有機金屬化合物之製法，係使有機物直接鍵结於 金屬形成有機金屬化合物之合成法為一般的方法。該合 成法為使無機金屬變成有機金屬化合物，必須有特殊的 製法。而且，企求波時之100¾收率極為困難，與使用金 屬與溶劑之方法比較，為高價格的方法。因此，如金本 身為高價時雖可實用化，惟若為其他金屬時採用該方法 ，與金屬本身之價格相比，變換成有機金屬化合物之工 程所需的成本就變得高價了。因此，產業界係企求低價 格且容易製造金屬膜之金屬膏。 發明揭示 有鑑於上述顆題，本發明人等發現不使用特殊的高價 有機金屬化合物，而改用一般低價的固體有機或無機金 屬化合物，配合一般低價的睽基化合物，意外地可予Μ 液化或泥化，且製得可塗覆的黏性金屬菊1 *遂而完成本 發明。 在該固體有撵或無機金屬化合物中加入胺基化合物， 藉由攪拌之簡單操作可使直接做為有機金屬（Μ0)用墨之 有機或無機金屬化合物赍狀化之製造方法，係為文獻上 不為知的方法。 因此，本發明係提供一種由於常溫下為固體之周期表 中第3族〜第15族金屬的有機或無機金屬化合物，與做 為介質之胺基化合物所成，且具塗覆黏性之金屬爱。 -5- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -------@If 裝------訂---- (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（4 ) 一般而言，有機金屬化合物不安定，惟藉由在上述金 屬脅中添加有機酸或有機醇可使化合物安定化，並可提 高溶解性或印刷性，此傜本發明提供之金屬音的待歡。 另外，本發明另提供一種金屬膜之製法，其特徵為使 上述金屬膏塗覆於基板上，且藉由在9(TC〜550 °C之低 溫下燒成以形成金屬膜。 [圔面之簡單說明] 第1圖偽表示X線折射圖，第1圖（b)為第1圔（a)之 波峰數據、第1圖（c)為銀及耙之單獨波峰數據。 [發明之實施形態] 於本發明中，在常溫下為固定之周期表第3族〜第15 族的金屬化合物，偽含有金屬與羧基化合物之複合體、 有機酸金屬鹽等之有機金屬化合物，還有氡化金屬、硝 酸金屬鹽等之無機金屬化合物。 周期表第3族〜第15族之金屬，具體而言包含耙、 白金、鍩、金、銀、鈷、鉛、銅、銥、錫、銻、釕、 鋪、銘、祕、鉻、猛、鐵、鎳、鮮、鉬等。 硝酸金屬鹽之具體例，如硝酸钯、硝酸鍩、硝酸銀、 硝酸鈾、硝酸鉛、硝酸銅、硝酸絪、硝酸錫、硝酸釕、 硝酸鋪、硝酸鉈、硝酸鉍、硝酸鉻、硝酸錳、硝酸鐵、 硝酸鎳、硝酸鋅等。 氫化金屬之具體例，如氡化耙、氡化白金、氣化鍩、 氡化金、氡化銀、氰化鈾、氡化鉛、m化銅、氡化鉈、 ~ 6 ~ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) -CL裝------""訂----一 ^· A7 B7 五、發明説明（jT ) 氡化鐵、氡化鎳、氡化鈴等。 羰基化合物傜包含可與金屬形成複合體者。例如，與 乙醯丙酮、乙醯醋酸酯、乙醯丙酸酯之複合物。金屬與 羰基化合物之複合物具體例，有乙醯丙酮白金、乙醯丙 酮鍩、乙醯丙酮銀、乙醯丙酮鈷、乙醯丙酮鉛、乙醯丙 酮銅、乙醯丙酮銦、乙醯丙酮鎘、乙醯丙酮鉈、乙醯丙 酮鉻、乙醯丙酮錳、乙醯丙酮鐵、乙醯丙酮鎳、乙醯丙 酮鋅、乙醯丙酮鉬等金屬與乙醯丙酮化合物之複合物； 乙醯醋酸乙酯鋅等金屬與丙烯醋酸酯化合物之複合物； 乙醯丙酸乙酯鋅等金屬與乙醯丙酸酯化合物之複合物； 羰基鍩、羰基钌等金屬與羰基化合物之複合物等。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 此外，有機酸金屬鹽例如有甲酸金屬鹽、乙酸金屬鹽 、草酸金屬鹽、環己烷丙酸金屬鹽等。有機酸金屬鹽之 具體例，如甲酸耙、甲酸絪、甲酸錫、甲酸銻、甲酸銀 、甲酸釕等甲酸金屬鹽；乙酸耙、乙酸鍩、乙酸銀、乙 酸鈷、乙酸鉛、乙酸銅、乙酸絪、乙酸錫、乙酸銻、乙 酸釕、乙酸鋪、乙酸鉈、乙酸鉍、乙酸鉻、乙酸錳、乙 酸鐵、乙酸鎳、乙酸鋅、乙酸鉬等乙酸金屬鹽；草酸把 、草酸铑、草酸銀、草酸鈷、草酸鉛、草酸銅、草酸絪 、草酸錫、草酸銻、草酸釕、草酸鎘、草酸鉈、草酸铋 、草酸鉻、草酸錳、草酸鐵、草酸鎳、草酸鋅、草酸錨 等草酸金屬鹽；璟己烷丙酸釕、苯甲酸耙、苯甲酸銀等。 上述有機或無機金屬化合物，可以一種或複種組合使 用。而且，上述之有機或無機金屬化合物亦可以為水合 -7 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 經濟部中央標準局員工消費合作社印製 A7 __B7__ 五、發明説明（6 ) 物0 另外，於有機或無機金靥化合物中* Μ乙醯丙酸酯铑 、氰化金、乙酸鈀、乙酸鉈、乙酸銀、乙酸鉍、乙酸錫 乙酸鈷、乙酸絪、乙酸銅、乙酸銻、甲酸銀、甲酸鈀、 甲酸絪、甲酸錫、甲酸銅、環己烷丙酸釕、草酸錫較佳。 本發明所使用的胺基化合物，係含使有機或無機金屬 化合物圼現塗覆黏性之膏狀物。而且，本發明中可使用 通常為液體之胺基化合物，惟若最終為脔狀時亦可為固 體。更詳言之，本發明之胺基化合物，係指可與有機或 無機金屬化合物配位，且其生成物圼琨資狀性質之化合 物。該反應結果係為有機或無機金屬化合物與胺基化合 物，圼琨相溶狀態，且藉此形成適當黏性的裔狀物。因 此，胺基化合物亦可使用在常溫下為固體者。 較佳的胺基化合物，係為選自一般式[Α]與[Β]所示者： R 1 -ΝΗ-(Z-NH-R 2 )η ----[A] R 3 -HH-Y-O-R 4 ----[Β] (其中，R1，R2 ,R3及R4係表示氫原子或碳數1〜8之 線狀或碳數3〜8之環狀烴類（亦可Μ低碳伸烷基取代） ;Ζ及¥係表示碳數1〜12之線狀或碳數3〜12之環狀烴 類（可Μ低碳伸烷基取代）；η僑表示0〜4)。 另外，具體而言一般式[Α]所包含的化合物，例如有 1,3-二胺基丙烷、Ν-甲基-1,3-二胺基丙烷、2,2-二甲 基1,3-二胺基丙烷、1,4-二胺基丁垸、1,5-二胺基戊烷 、：1,6-二胺基己烷、1,2-二胺基環己烷、1,3-二胺基環 本紙伕尺度適用中國國家標準（CNS ) Α4規格（21〇Χ：297公釐） (請先閲讀背面之注意事項再填寫本頁) —¢/ 裝------訂----丫 . 經濟部中央標準局員工消費合作社印製 A7 __B7_: 五、發明説明（^ ) 己烷、1,4-二胺基環己烷、1,7-二胺基庚烷、1,2-二胺 基十二烷、2 -甲基-1,5 -二胺基庚烷、1,2 -伸苯基二胺 、1,3 -伸苯基二胺、1,4 -伸苯基二胺等二胺化合物、N-甲基腈、1-苯基乙胺等單胺基化合物；而一般式[B]所 包含的化合物，例如有2-甲氣基乙胺、3-甲氧基丙胺、 2 -乙氧基乙胺、3 -乙氧基丙胺、3 -丙氧基丙胺、2 -胺基 -卜丙醇、2 -胺基-2-甲基-卜丙醇、卜胺基-2-丙醇等單 胺基化合物。 另外，除此等胺基化合物外，亦可使用嗎福啉等。 上述之胺基化合物，可單獨或數種組合使用。 此處，一般而言單胺基化合物與二胺基化合物相比， 所生成的金屬膏之安定性不佳。然而，即使為單胺時， NH 2 - (CH 2 )η -OH 或 NH.2 - (CH 2 ) „ -OR 與其衍生物， (其中，R偽表示碳數1〜8之線狀或磺數3〜8之環狀烴 類（亦可以低碳伸烷基取代）；η傺表示1〜1 2 ) 不會比二安化合物差，易溶解各種有機或無機金屬化合 物，且安定性極佳。 例如，將氣化金溶解於乙二胺，做成金膏後保存於室 溫下，約1日卽産生分解。然而，在相同的條件下，使 用軟1,3 -二胺基丙烷為大的胺類時，可保持數週〜數 月。若η=2與η¥3時，視構造不同其安定性亦不同。總 之，金屬膏之安定性，視金屬的種類與胺的種類不同， 有很大的不同。另外，於Ν Η 2 - ( C H 2 ) n - N Η 2之二胺化 合物中，η為3以上之胺類具優異的溶解性與顯箸的安 -9 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) ~^)裝------訂---- 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（8 ) 定性，且可提供低溫下燒成的金羼赍，係為所企求。 本發明之金屬菊=,由上述有機或無機金屬化合物及胺 基化合物之混合物所成，該混合物具塗覆黏性。本發明 係藉由變化有機或無機金屬化合物與胺基化合物之混合 量，來調整企求的黏性。此處，胺基化合物對有機或無 機金屬化合物而言含有0.2巽耳以上、較佳者為0.6〜 17.51莫耳，更佳者為1.0〜3莫耳。而且，若小於0.2 莫耳時，一般而言不易得到塗覆黏性，造成印刷性不佳 ，且不易使有機或無機化合物溶解，係不為所企求。 金屬蕾中所含的有機基之分子量愈大時，於燒成金屬 膜時需使用高溫。因此，為了降低燒成溫度，有機基之 分子量愈小愈佳。然而，過小時會減少流動性，致使一 般的印刷性與成膜狀態不佳。此處，於金屬脅中添加有 機酸或/及醇類等加成於金屬上時，可抑制燒成溫度且 可提高印刷性與成膜性。 特別是即使本發明添加的有機酸為不安定的有機或無 機金屬化合物時*藉由添加可提高金屬膏之安定性與溶 解性，更可使燒成膜均句化，且成膜性佳。而且*視各 種目的與用途而定，藉由變化有機酸之種類，調整燒成 溫度且形成各種性質的金屬膜。 此處，使用下述一般式[C]所示之脂肪族或芳香放單 或二羧酸較佳。 R 5 -(C00R 6 )η ----[C] (其中，1?5及！？6係表示氫原子，可Μ伸烷基取代的碳 -10- 本紙張尺度適用中國S家標準（CNS ) A4規格（210X297公釐） (請先聞讀背面之注意事項再填寫本頁) -------------裝 I------訂---- 經濟部中央標準局負工消費合作社印製 A7 B7 五、發明説明（9 ) 數1〜20之線狀或碳數3〜20之環狀烴類；η係表示1〜3 (惟其中，R5為氫原子時，η = 1) 具體的脂肪族或芳香族單或二羧酸，例如有甲酸、乙二 酸、醋酸、丙酸、丁酸、戊酸、己酸、庚酸、辛酸、2-乙基己酸、環己酸、環己基丙酸、環己烷醋酸、壬酸、 蘋果酸、谷氨酸、閃白酸、羥基三甲基乙酸、三甲酸乙 酸、戊二酸、己二酸、環己烷二羧酸、庚二酸、辛二酸 、乙基丁酸、苯甲酸、苯基醋酸、苯基丙酸、羥基笨甲 酸等。 脂肪族或芳香族單或二羧酸之添加比例，視其種類而 不同，惟對1莫耳有機或無機金屬化合物而言Μ添加〇 〜5莫耳較佳。 另外，視添加的脂肪族或芳香族單或多元醇而定，即 使為不安定的有機或無機金屬化合物時，可提高金屬膏 之安定性與溶解性成印刷性。 此處，Μ使用下述一般式[D]所示之脂肪族或芳香族 單或多元醇較佳。 R 6 - (0Η) η ----[D] (其中，Re係表示可以伸烷基取代的碳數}〜20線狀或 碳數3〜20之環狀烴基；η係表示1〜4) 另外，脂肪族或芳香族單或多元醇亦可Μ為具取代基之 下述一般式[Ε]所示之Μ氰基取代的脂肪族或芳香族單 或多元醇較佳。 (NC)m -R7 - (0Η)η ----[Ε] -11- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） (請先閱讀背面之注意事項再填寫本頁) Θ. bi裝 "訂 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（1〇 ) (其中，R7係表示碳數1〜7之線狀或碳數3〜8之環狀 烴基；η係表示1〜3; m係表示1或2 (惟R7為碳數 1時n + m = l〜4,碳數2 Μ上時n + m = l〜6))。 一般式[D]之脂肪族或芳香族單或多元醇例如有橙花 醇、香茅醇、羥基橙花醇、羥基香茅醇、乙醇、丙醇、 丁醇、己醇、乙基己醇、癸醇、苄醇、羥基苄醇、苯基 乙醇、苯基丙醇、羥基苯、環己醇、乙基環己醇、丁基 環己醇、甲氧基苄醇、胡椒醇、乙二醇、丙二醇、1,2-丁二醇、2,2-二甲基-1,3-丙二醇等。 另外，亦使用一般式[D]之脂肪族或芳香族單或多元 醇與有機酸之酯類。具體而言例如笨甲酸甲酯、羥基苯 甲酸乙酯、2 -乙基己酸乙酯、醋酸乙酯、羥基醋酸乙_ 、亞麻油酸甲酯等。 此外，亦可使用一般式[D]之脂肪族或芳香族單或多 元醇之酯化合物。具體而言例如乙二醇單甲醚、二乙二 醇單***、三乙二醇單丙醚、丙二醇單甲醚、丙二醇單 ***、三丙二醇單丙醚、二乙二醇、二丙二醇、乙二醇 單丁醚、1-丁氧基-2-丙醇等。 一般式[E]之脂肪族或芳香族單或多元醇，例如有乳 腈、羥基、乙腈、乙烯氰基茚滿、丙齲氰基茚滿等。 上述脂肪族或芳香族單或多元醇內，尤Μ添加具一般 式[Ε]之氰基的醇類較佳。藉由添加該醇類，可使不安 定的有機或無機金屬化合物極為安定化，且安定地維持 透明的眘狀狀態。此處。使用1價金化合物的#狀物， -12- (請先閲讀背面之注意事項再填寫本頁) ,ο. "裝. 訂 本紙張尺度適用中國國家標準（CNS ) A4*t格（210Χ297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（11 ) 若添加具上述一般式[E]之氰基的醇類，可在室溫下保 存約4年Μ上。 脂肪族或芳香族單或多元醇之添加比例，視其種類而 不同，惟對1莫耳有機或無機金屬化合物而言，Μ添加 〇〜5莫耳較佳。 而且，將脂肪族或芳香族單或二羧酸及脂肪族或芳香 族單或多元醇兩種皆添加於金屬齋中亦可。 此處，一般的有機金屬化合物，若藉由印刷法塗覆時 ，其印刷性不佳係為已知。然而，本發明係藉由於上述 金屬脔中添加有機酮或有機醚，Μ平滑性改變成富有伸 展性之齎狀物。藉由此法可提高印刷性，更可提高保存 安定性，故可形成薄的均勻金屬膜。 上述有機酮可使用脂肪族或芳香族酮類。更具體而言 如丙麵、乙基甲酮、2-戊酮、3-戊酮、3-甲基-2-丁酮 、2-己酮、3-己酮、甲基丁酮、3-甲基-2-戊嗣、2-庚酮 、3-庚酮、4-庚酮、戊基甲酮、乙基丁酮、2,4-二甲基 -3-戊酮、2-辛酮、3-辛_、4-辛酮、2,5-二甲基-3-己 酮、環己酮、甲基環己酮、乙醯基丙_、2,3 -丁二_、 2,3-戊二酮、3,4-己二酮、2, 5-己二嗣、環己二酮等脂 肪族酮類，乙醯苯酮等芳香族酮類。 上述有機醚類可使用脂肪族或芳香族醚類。更具體而 言例如4 -甲氧基-2-丁酮、4-乙氧基-2-丁酮、4-甲氧基 -2-酮、2-甲氧基-2-甲基-4-戊_、乙二醇二甲醚、乙 二醇二***、乙二醇二丙醚、丙二醇二***、丙二醇二 一 1 3 — 本紙張尺度適用中國國家標準（CNS )八4規格（210Χ297公釐〉 -------©—^Q-裝------訂-----. (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（12 ) ***、二乙二醇二甲醚、二乙二醇二***、二丙二醇二 甲醚、二丙二醇二***、丙二醇二丙醚、乙縮醛、丙酮 二乙基乙縮醛、2, 2-二甲氧基丙烷等脂肪族醚類、茴香 醚、二甲氧基苯等芳香族醚類。 脂肪族或芳香族酮類或醚類之添加比例，視種類而不 同，惟對1莫耳有機或無機金屬化合物而言Μ添加0〜4 莫耳較佳。 而且，亦可Μ組合脂肪族或芳番族嗣類或醚類添加於 金鼷#中。 於本發明中製得安定金屬膏之理由，係為藉由下述之 作用。換言之，在常溫下為固體的有機或無機金屬化合 物中加入胺基化合物並予Μ攪拌，有機或無機金屬化合 物係與成為液體的胺基化合物配位而莆狀化。 而且，藉由有機或無機金屬化合物與胺基化合物組合 ，若為藉由混合而結晶化時，此時若為混合不同種類的 胺基化合物則可赍狀化。而且，有機或無機金鼷的胺基 化合物本身大多不安定，故於其中添加有機酸，則整體 成為陽性與陰性结合構造之組成物，故可使被夾住的活 性金鷓安定化。 本發明金屬膜之製法係將金屬脅塗覆於所企求的基板 上，藉由燒成來製造金屬膜。此時之燒成，首先在低溫 區分離结合力弱的醇類，再使酸分離，然後分解胺之配 位，再予Κ升溫切斷直接鍵结於金屬的有機基Κ形成金 屬的膜。此時小的有機基，由於比大的有機基在較低溫 -1 4 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公簸） (請先閲讀背面之注意事項再填寫本頁) •裝. 訂 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（15 ) 下分解，故κ低溫燒成可製造金屬膜。此係使在常溫下 為固體的有機或無機金屬化合物予K裔狀化，且在低溫 下分解Μ形成金屬膜之作用機構。 另外，金鼷係使用各種範圍中已使用者做為重要材料 。換言之，在電子材料、機械材料、光學材料、衛生材 料、生活材料、農業材料、醫藥材料等範圍內，重用上 述之金屬。在此等範圍内利用金屬特有的各性質，可利 用習知的金屬，使用本發明之裔狀物做為導電材料、柢 抗材料、傳熱材料、保溫材料、光及電磁波之反射及吸 收材料、耐蝕材料、機械強度材料、磨損吸收用材料、 觸媒用材料、金屬光澤用材料、著色用材料、裝飾用材 料或微生物繁殖抑制材料等。 燒成溫度為90t：〜5501C，較佳者為110〜35〇υ。該 溫度與在習知金屬的熔點Μ上溫度加熱、處理之習知方 法比較，熱處理溫度顯著降低。因此，可塗覆金屬菊=之 基板，不僅可使用習知附高熱的高熔點基板（陶瓷、金 屬）外，其他尚有一般的玻璃，樹脂（熱硬性樹脂、熱 塑性樹脂）、紙等基板亦適用於本發明金屬膜之製法。 所Κ，可提供具金屬特有性質之金屬被覆基板。而且， 本發明之基板亦包含薄膜狀、片板狀低熔點基板。 實施例 於下述中詳细地說明本發明之實施例。 實施例1 在1.00g(4.34毫奠耳）硝酸鈀（Pd(N〇3 )2 )中加入 -15- 本紙佚尺度適用中國國家標準（CNS ) 格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) -------------〇—^------'-IT----:--ί 經濟部中央標準局負工消費合作社印製 A7 B7 _ 五、發明説明（14 ) 0.70g(9.45毫莫耳）1,3-二胺基丙烷 (NH2 CH2 CH2 CH2 NH2 )、0.70g(7.94毫箕耳）N-甲基一 1,3-二胺基丙烷（CH3 NHCH2 CH2 CH2 NH2 ) 、 〇.4〇g (4.49毫莫耳）3-甲氧基丙胺（(：113〇〇112(：!12(^2^112) 並予M撹拌，形成膏狀物。加入1.20g(13.62毫莫耳）異 丁酸（（CH3) 2CHCOOH)且予以混練，形成暗茶色透明 的膏狀物。將其塗覆於玻璃等基板上，升溫至320 T：， 燒成5分鐘後，製得鈀之薄膜。而且，該實施例中對1 莫耳金屬而言使用5.04倍的胺基化合物。 實胞例2 在1.00g(6.31毫莫耳）氰基化鈀（Pd(CN2 )>中加入 0.60g(8.10毫莫耳）1,3-二胺基丙烷、0.20g(2.27毫莫 耳）N-甲基-1,3-二胺基丙烷、1.50g(19,97毫莫耳）2-甲 氧基乙胺（CH3 OCH2CH2 NH2 )、 0.40g(5.63毫莫耳）乳 腈（CH2CH(0H)CN)並予Μ攪拌，形成透明的脅狀物。將 其塗覆於玻璃等之基板上，升溫至300C,且燒成10分 鐘，製得鈀之均勻薄膜。而且，該實施例中對1莫耳金 屬而言使用4.81倍的胺基化合物。 實施例3 在1.00g(4.45毫萁耳）醋酸鈀（Pd(00(CH3 )2中加入 0.60g(6.80毫莫耳）H-甲基-1,3-二胺基丙烷、0.4〇g (5.33毫莫耳）2-甲氧基乙胺並予W攪拌，製得透明的賫 狀物。將其塗覆於玻璃等之基板上，升溫至250t：予W 燒成10分鐘後，製得鈀之均匀膜。而且，該實施例對1莫 -16- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） I.-----裝------訂----_-- (請先閲讀背面之注意事項再填寫本瓦y 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（15 ) 耳金屬而言使用2.73倍的胺基化合物。 實施例4 在1.00g(4.45毫莫耳）醋酸鈀中加人0.60g(5.60毫莫 耳）N -甲基苯胺（C6 Hs NHCH3 )、0.30g(3.41毫莫耳）異 丁酸並予Μ溶解後，得茶色的透明齎狀物。視其所需加 入苯基乙醇並予Μ混練，可得印刷性經提高的暗赤茶色 膏狀物。將其塗覆於玻璃等之基板上，升溫至250Ό並 予Μ燒成10分鐘，可得鏡面的鈀膜。而且，於該實施例 中對1莫耳金屬而言使用1.26倍胺基化合物。 實施例5 在1.00g(4.45毫莫耳）醋酸鈀（Pd(00(CH3 )2 )中加入 0.20g(1.05毫莫耳）N,H-二乙基三醯胺、3.00g(17.2毫 莫耳）羥基香茅醇並予以攪拌，可得半透明膏狀物。將 其塗覆於玻璃等之基板上，升溫至2501C並予K燒成10 分鐘，製得鈀的均匀膜。而且，於該實胞例中對1莫 耳金屬而言使用0.24倍的胺基化合物。 實施例6 在1.00g(4.45毫莫耳）醋酸鈀中加人0.20g(2.32毫莫 耳）甲基丙烯酸、0.35g(4.66毫莫耳）2-甲氧基乙胺並予 Μ搅拌，可得暗色的脔狀物。將其塗覆於玻璃等之基板 上升溫至230¾並予Μ燒成10分鐘，製得鈀的均匀膜。 而且，於該實施例中對1莫耳金屬而言使用1.05倍胺基 化合物。 實施例7 -17- 本紙張尺度適用中圉國家標率（CNS ) A4規格（210X297公釐） (請先閲讀肾面之注意事項再填寫本頁) _____________91) ^______Τ____/.!. ..„、.^. A 7 B7 五、發明説明（16 ) 在1.00g(4.45毫莫耳）醋酸鈀中加人0.40g(3.73毫莫 耳）卜苯基乙胺、0.40s(3.92毫萁耳）戊酸並予Μ攪拌， 混練至成黑茶色的眘狀物。將其塗覆於玻璃等之基板上 升溫至25〇υ並予Μ燒成10分鐘，可得鈀的均勻膜。而 且，於該實施例中對1莫耳金屬而言使用0.84倍的胺基 化合物。 _ 實施例8 在1.00g(3.02毫莫耳 > 硝酸白金二胺基丙烷配位化合 物（NH2 CH2 CH2 CH2 NH2 , Pt(N〇3 )2 )中加入 l.OOg (8.76毫莫耳）2 -二胺基環己烷並予M混練，製得約為透 明的淡茶色膏狀物。不論如何，將其塗覆於玻璃等之基 板上升溫至350C並予Μ燒成5分鐘，可得白金膜。此 時若使用庚酸等高碳酸時，可提高其密接性。而且，於 該實施例中對1莫耳金屬而言使用3.90倍的胺基化合物。 實施例9 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 在1.00g(3.75毫莫耳）硝酸鉈（Τ1Ν〇3 )中加人0.60g (5.25毫莫耳）1,2-二胺基環己烷、0.3(^(4.05毫莫耳） 1,3 -二胺基丙烷並予Μ攪拌，可得無色透明的#狀物。 將其塗覆於玻璃等之基板上升溫至170〜ΐδ〇υ,在還原 氣氛中燒成，可得鉈膜。而且，於該實施例中對1莫耳 金屬而言使用2.48倍胺基化合物。 實施例10 在1.00g(2.50毫莫耳）乙醯基醋酮酸铑 (RH(CH3 C0CHC0CH3 )2 中加入0.80g(9.07毫奠耳）N-甲 本纸張尺度適用中國國家標準（CNS ) A4規格（210X29?公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（17) 基-1,3-二胺基丙烷，可得資狀物。再加入〇.60g(6.81 毫莫耳）異丁酸予以混練而成暗茶色透明的均匀眘狀物 。將其塗覆於玻璃等基板上，升溫至390t：並予Μ燒成 5分鐘，製得鍩之薄膜。而且，於該實施例中對1莫耳 金鼷而言使用3.63倍的胺基化合物。 實施例11 在1.00g(5.63毫莫耳）十六羧基六鍺（Rhe (C0)16)中加入 0.60g(8.10毫莫耳）1,3-二胺基丙烷、0.40g(5.33毫莫 耳）2 -肢基-1-丙醇（HH2 CH(CH3 )CH2〇H)並予Μ混練而 成均勻的膏狀物。將其塗覆於玻璃等之基板上，升溫至 290TC且予Κ燒成5分鐘，製得铑膜。而且，於該實施 例中對1莫耳金屬而言使用2. 39倍之胺基化合物。 實施例12 在1.00g(4.48毫莫耳}氟化金（AuCN)中加人0.40g(4.54 毫莫耳）fj-甲基-1,3-二胺基丙烷、0.10g(0.77毫莫耳> 1,7-二胺基庚烷（HH2 (CH2 )7 NH2 )、〇.l〇s(1.12毫莫 耳）3-丙氧基丙胺並予Μ攪拌。再加人0.70g(5.46毫奠 耳 >環己酸（CeHii COOH)與0.80g(5,55毫萁耳）2-乙基己 酸（CH3 CH2 CH < CH3 CH2 >COOH)並予Μ混練而成赤紫 色透明的菊1狀物。將其塗覆於玻璃等之基板上並予Κ燒 成5 0 0〜5 5 0 C，製得金鏡薄膜。而且，於該實施例中對 1莫耳金屬而言使用1.44倍之胺基化合物。 貿施例13 在1.00g(4.48毫莫耳）氟化金中加人〇.8〇g(11.25毫莫 -19- 本紙張尺度適用中國國家標準（CNS > A4規格（2丨Ο X 297公釐） -------裝-- (請先閲讀背面之注意事項再填窝本頁) -訂------ A7 B7 ' --------—---—------- 五、發明説明（I8 ) 耳）乳腈、〇.60g(5.87毫萁耳）2,2-二甲基-1，3-二胺基 丙烷（NH2 CH2 C(CH3 )2 CHz NH2 )、〇.l〇s(〇.77毫奠 耳）1.7-二胺基庚烷、0.30g(3.37毫奠耳）3 -甲氧基丙胺 並予Μ攪拌而成淡橘色透明的裔狀物。將其塗覆於玻璃 等之基板上並在500〜5501C下予Κ燒成，製得金膜。此 時再加入乳腈，可知有機金屬化合物變得非常安定，可 在室溫下保存4年皆不會分解，仍為淡橘色透明的齋狀 物。而且，於該實施例中對1莫耳金屬而言使用2.23倍 的胺基化合物。 實施例1 4 在1.00g(5.99毫莫耳）醋酸銀（CH3 COOAg)中加人0.70g (4.42毫莫耳）壬酸（C8 H 17C00H)並予以混練。再於其 中加入0.60g(8.10毫莫耳）1,3 -二胺基丙烷並予K攪拌 而成白灰色膏狀物。另再予K混練而成茶色半透明的蕾 狀物。加入0.40g(0.37毫莫耳）1,4 -伸苯基二胺 (‘C 6 Η 4 (Ν Η 2 ) 2 )混練至赤色半透明。再於其中加入 〇.50g(6.75毫莫耳）、丙酸（CHa CH2 C00H)混練至赤茶 色透明的裔狀物。將其塗覆於玻璃等之基板上，升溫至 35 Ot：並予Μ燒成5分鐘，製得銀鏡之銀膜。而且，於 該實胞例中對1莫耳金屬而言使用1.41倍之胺基化合物° 實胞例15 在l.〇〇g(5.99毫莫耳）醋酸銀中加人〇*8〇s(8.98毫莫 耳）3-甲氧基丙胺、〇.〇5g(0.25毫莫耳）1,12-二胺基十 二烷（HH2 (CH2 )i2NH2 )並予Μ攪拌。再於其中加入 -2 0 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） m ϋ— -an 1^1 In · (請先閲讀背面之注意事項再填寫本頁) —ο. l裝------訂---- 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（l9 ) 1.〇〇8(7.68毫莫耳）庚酸（(：61113(：001〇、〇.15^(1.12毫 冥耳）蘋果酸（HOOCCH2 CH(OH)COOH)並予Μ搜拌。再加 入0.60g(8.10毫莫耳）1，3 -二胺基丙烷混練至淡煉瓦色 而成透明的齋狀物。將其塗覆於玻璃等之基板上，升 溫至3〇ου且予κ燒成ίο分鐘，製得銀色膜。而且，於 該實施例中對1莫耳金屬而言使用2.89倍之胺基化合物。 實施例1 6 在1.00g(5.99毫莫耳）醋酸銀中加人〇.5〇g(6.75毫莫 耳）1,3-二胺基丙烷、〇,60g(6.73毫莫耳甲氧基丙胺 、O.OSg (0.24毫莫耳）1,12-二胺基十二烷並予以攪拌。 再於其中加人0.80g(6.14毫莫耳）庚酸、〇.4〇s(2.56毫 莫耳）環己基丙酸（Cs Hu (CH2 )2 C00H)、〇」5g(1.12 毫萁耳）蘋果酸、〇.2g(1.75毫莫耳）1，2-二胺基環己烧 混練至昱紅橘色為止，形成透明的齋狀物。將其塗覆於 玻璃等之基板上，升溫至2 3 0 t：並予K燒成1 0分鐘，製 得銀鏡膜，或升溫至290 ¾並予K燒成〗〇分鐘，$胃m 色之膜。而且，於該實施例中對1莫耳金靥而言使用 1.46倍的胺基化合物。 實施例17 在1.00g(5.99毫莫耳）醋酸銀中加0.50g(6.75毫莫耳） 1,3-二胺基丙烷與0.40g(2.53毫奠耳）壬酸並予以混練 而成赤橙色透明的蕾狀物。再加入〇.l〇s(〇.88毫莫耳） 1,2-二胺基環己烷並予K混練。隔天形成紫色菊：狀物° 將其塗覆於玻璃等之基板上，升溫至300 ¾並予Μ燒$ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閲讀背面之注ί項再填寫本頁) 訂！ II-Ϊ 經濟部中央標準局員工消費合作社印製 A7A7 B7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (1) 1 1 This invention relates to a method for manufacturing a metal gadolinium and a metal film 0 More details-5-1 1 t This invention relates to a 1 I metal 赍 9 Κ used for firing to form a metal film and a method for producing the metal film using the metal 0 0 The present invention is gold-V. Please refer to the surface of electronic materials, electronic devices, electronic devices, mechanical materials, etc. Handling first 1 1 1 It is very useful to apply anti-magnetic and decorative or catalyst and sterilization to the metal film. It is extremely useful. T > As a gold used in medicine, pesticides, etc. Note 1 belongs to the original film It is also very useful. ○ Matter 1 and even if the current metal is used directly, it can be simple.-Installed by a local production company. The metal film is easy to handle because of the use of the metal film .'— ^ 1 | and economical Λ However, because the metal film must be heated at a high temperature of A? U, the base 1 1 board is limited to the use of high melting point materials. If the firing temperature for forming metal g 1 | is lower, it can be widely used-generally low-priced substrates with low softening point 1 order 1 (glass plastic, etc.) 〇 The present invention is related to the wide range of use in the above range Metals for low-temperature firing. 〇1 I metal systems each have individual useful properties. ○ Various metals can be formed on substrates such as ceramics by various 1 1 methods or M alloy methods. Conductive resistance Semi-conductive transparent | -Η; '—' HI I, Ionic corrosion resistance Friction light shading and / 1 1 or metal gloss) Can be used in electronic materials or electronic equipment, 1 1 Surface treatment of materials, coating of anti-magnetic decorative catalysts and sterilization * 1 I Can be used in a wide range of pharmaceuticals and pesticides, etc. 0 1 1 Known techniques for making metal films 9 As described below 0 1 1 ① Must be sputtered The method of vacuum method 0 1 ② The method of coating metal inks such as thick film method and sintering method 0 1 -3 1 1 1 1 This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 public *) Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (2) ① The sputtering method must use large equipment with high price and high vacuum, and the mass production of M batch type is not good. High manufacturing cost. Therefore, ② cautious method with low equipment cost and high productivity is used. In this method, various metal chrysanthemums are coated on a substrate, and fired at M. The simple method and device of M continuously produce metal films at low cost. The thick object used in the thick-film thickening method is to form various metals into fine particles, and it is coated with an uneven viscous liquid β which is dispersed only in a solvent, and is coated and fired to form a metal in which only the metal particles are in contact. Film, unable to form a uniform film. Therefore, for silver and palladium alloys most commonly used in the electronics industry, for example, even if the M-thick film is formed, it is necessary to raise the temperature to about 950 ° C and sinter, and physically melt the metal particles into a uniform thin film. Therefore, to form a metal film, a high melting point substrate such as a ceramic substrate or a metal plate must be used. Furthermore, since firing at a high temperature requires a large-scale firing furnace and surrounding facilities that are resistant to high heat, and energy for high-temperature firing. Therefore, by reducing the firing temperature of the maggots as much as possible, the equipment cost can be made cheaper, and energy can be saved and costs reduced. In addition, in order to form a metal film on a substrate (glass, plastic, etc.) with a low softening point, which is generally inexpensive, it is required to further reduce the firing temperature for forming a metal film. In order to overcome this disadvantage, a method (organic metal (MO) method) is proposed in which inorganic metal particles are converted into organic metal compounds, uniformly dissolved in a solvent, and then a thin, uniform metal film is formed by coating and firing. For example, in the case of gold, the method of using a sulphur-containing organic gold compound, compared with the thick film method of mixing fine particles of gold, is used in a trace amount of about 1/7 of the amount of gold. China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) -------------— c ": 装 ----- -Order ----}! A7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs __B7_ V. Description of the invention (5) can form a uniform gold film with equal properties. Therefore, in the use of the Golden Garden, M M0 method instead of the conventional thick film method. The above-mentioned method for producing an organometallic compound is a general method in which an organic substance is directly bonded to a metal to form an organometallic compound. This synthesis method requires a special production method to change the inorganic metal into an organometallic compound. In addition, it is extremely difficult to obtain a 100 ¾ yield at the time of the wave. Compared with the method using a metal and a solvent, it is a high-priced method. Therefore, although gold itself is practical when it is expensive, if it is used for other metals, the cost of the process of converting to an organometallic compound becomes higher than the price of the metal itself. Therefore, the industry is seeking metal pastes that are inexpensive and easy to produce metal films. Disclosure of the Invention In view of the above problems, the inventors discovered that instead of using special high-priced organometallic compounds, instead of using generally low-priced solid organic or inorganic metal compounds, in combination with generally low-priced fluorenyl compounds, unexpectedly could be The present invention is completed by liquefying or sliming and preparing a coatable viscous metal chrysanthemum 1 *. A method for producing an organic or inorganic metal compound directly used as an ink for an organic metal (MO) by adding an amine compound to the solid fluorene or inorganic metal compound through simple operation of stirring is a document Unknown method. Therefore, the present invention provides an organic or inorganic metal compound of a Group 3 to Group 15 metal in the periodic table which is solid at normal temperature, and an amine-based compound as a medium, which has a coating viscosity. Love. -5- This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) ------- @ If 装 -------- Order ---- (Please read the note on the back first Please fill in this page again) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (4) Generally speaking, the organometallic compounds are unstable, but by adding organic acids or organic alcohols to the above mentioned metals It stabilizes the compound and can improve the solubility or printability. This is the metal tone of the present invention. In addition, the present invention provides a method for manufacturing a metal film, which is characterized in that the above-mentioned metal paste is coated on a substrate, and a metal film is formed by firing at a low temperature of 9 ° C to 550 ° C. [圔 面 之 的Brief description] Figure 1 pseudo-represents the X-ray refraction chart, Figure 1 (b) is the peak data of 1 圔 (a), and Figure 1 (c) is the single peak data of silver and rake. [Implementation Mode of the Invention ] In the present invention, metal compounds of Groups 3 to 15 of the periodic table are fixed at ordinary temperature, pseudo-organic metal compounds containing a complex of a metal and a carboxyl compound, organic acid metal salts, and the like, and tritiated metals And inorganic metal compounds such as metal nitrate salts. Metals from Groups 3 to 15 of the Periodic Table, specifically including harrow, platinum, osmium, gold, silver, cobalt, lead, copper, iridium, tin, antimony, ruthenium, Shop, Ming, Secret, Chromium, Iron, Nickel, Fresh, Molybdenum, etc. Specific examples of nitrate metal salts, such as palladium nitrate, thorium nitrate, silver nitrate, uranium nitrate, lead nitrate, copper nitrate, thallium nitrate, tin nitrate, Ruthenium nitrate, nitrate, osmium nitrate, bismuth nitrate, chromium nitrate, manganese nitrate, Ferric acid, nickel nitrate, zinc nitrate, etc. Specific examples of hydrogenated metals, such as tritium rake, tritium platinum, gaseous thorium, tritium gold, silver tritide, uranium cyanide, lead tritide, copper tritide, tritium铊, ~ 6 ~ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling out this page) -CL Pack ------ " " Order ---- A ^ · A7 B7 V. Description of the invention (jT) Iron halide, nickel halide, halide boron, etc. Carbonyl compounds 傜 include those which can form complexes with metals. For example, with acetone, acetone, acetone Compounds of acetate and acetamyl propionate. Specific examples of composites of metals and carbonyl compounds include acetoacetone platinum, acetamidine acetonium, silver acetoacetone, cobalt acetamyl acetonate, lead acetamate, acetamidine Copper acetone, indium acetoacetone, cadmium acetoacetate, acetone acetoacetate, chromium acetoacetate, manganese acetoacetate, iron acetoacetate, nickel acetoacetate, zinc acetoacetate zinc, acetoacetate molybdenum and other metals and Complex of acetoacetone compounds; compound of metals such as ethylacetate zinc acetate and propylene acetate compounds ; Complexes of metals such as ethyl zinc propionate and acetic acid propionate compounds; Complexes of metals such as rhenium carbonyl and ruthenium carbonyl with carbonyl compounds etc. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read first Note on the back, please fill in this page again) In addition, the organic acid metal salt includes, for example, metal formate, metal acetate, metal oxalate, metal cyclohexanepropionate, etc. Specific examples of organic acid metal salts, such as formic acid, Samarium formate, tin formate, antimony formate, silver formate, ruthenium formate and other formate metal salts; acetate acetate, samarium acetate, silver acetate, cobalt acetate, lead acetate, copper acetate, scandium acetate, tin acetate, antimony acetate, ruthenium acetate, acetic acid Acetic acid, acetic acid, bismuth acetate, bismuth acetate, chromium acetate, manganese acetate, iron acetate, nickel acetate, zinc acetate, molybdenum acetate, etc .; oxalic acid handle, rhodium oxalate, silver oxalate, cobalt oxalate, lead oxalate, copper oxalate, oxalate , Tin oxalate, antimony oxalate, ruthenium oxalate, cadmium oxalate, rhenium oxalate, bismuth oxalate, chromium oxalate, manganese oxalate, iron oxalate, nickel oxalate, zinc oxalate, oxalate anchor and other metal oxalate metal salts; 璟Ruthenium hexanepropionate, benzoate rake, silver benzoate, etc. These organic or inorganic metal compounds may be used singly or in combination. In addition, the above organic or inorganic metal compounds can also be hydrated -7-This paper size applies Chinese National Standard (CNS) A4 specifications (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 __B7__ V. Description of the invention (6) 物 0 In addition, in organic or inorganic gold rhenium compounds * M ethyl acetate propionate rhodium, gold cyanide, palladium acetate, europium acetate, silver acetate, bismuth acetate, tin acetate cobalt acetate, europium acetate, copper acetate , Antimony acetate, silver formate, palladium formate, osmium formate, tin formate, copper formate, ruthenium cyclohexanepropionate, and tin oxalate are preferred. The amine-based compound used in the present invention contains a paste that makes an organic or inorganic metal compound appear viscous. Further, in the present invention, an amine compound which is usually a liquid can be used, but it may be a solid if it is finally crumbly. More specifically, the amine-based compound of the present invention refers to a compound which can coordinate with an organic or inorganic metal compound and has a product-like property. The result of this reaction is that the organic or inorganic metal compound and the amine compound are in a miscible state, and thereby form an appropriately viscous precursor. Therefore, the amine compound can also be used as a solid at normal temperature. A preferred amine-based compound is selected from the group consisting of the general formulae [A] and [B]: R 1 -ΝΗ- (Z-NH-R 2) η ---- [A] R 3 -HH- YOR 4 ---- [Β] (wherein R1, R2, R3 and R4 represent hydrogen atoms or linear hydrocarbons with 1 to 8 carbons or cyclic hydrocarbons with 3 to 8 carbons (also low carbon extension) Alkyl substitution); Z and ¥ represent linear hydrocarbons having 1 to 12 carbon atoms or cyclic hydrocarbons having 3 to 12 carbon atoms (may be substituted by low-carbon alkyl groups); η overseas Chinese represents 0 to 4). In addition, specifically, the compounds included in the general formula [A] include, for example, 1,3-diaminopropane, N-methyl-1,3-diaminopropane, and 2,2-dimethyl 1,3 -Diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane ,: 1,6-diaminohexane, 1,2-diaminocyclohexane, 1, 3-Diamine-based paper size is applicable to China National Standard (CNS) A4 specification (21〇 ×: 297 mm) (Please read the precautions on the back before filling this page) — ¢ / Packing ------ Order ---- Y. Printed by A7 __B7_ of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs: 5. Description of the Invention (^) Hexane, 1,4-diaminocyclohexane, 1,7-diaminoheptane , 1,2-diaminododecane, 2-methyl-1,5-diaminoheptane, 1,2-phenylenediamine, 1,3-phenylenediamine, 1,4 -Diamine compounds such as phenylenediamine, monoamine compounds such as N-methyl nitrile, and 1-phenylethylamine; and compounds included in general formula [B], for example, 2-methylaminoethylamine, 3-methoxypropylamine, 2-ethoxyethylamine, 3-ethoxypropylamine, 3-propoxypropylamine, 2-amino-propanol, 2-amino-2-methyl-bupropion Alcohol, propylamino-2-propanol And other monoamine compounds. In addition to these amine compounds, morpholine and the like can also be used. The aforementioned amine-based compounds may be used singly or in combination. Here, in general, the stability of the metal paste produced is poorer than that of the diamine-based compound. However, even in the case of monoamines, NH 2-(CH 2) η -OH or NH. 2-(CH 2) -OR and its derivatives, (where R is pseudo-linear or sulfonic with 1 to 8 carbon atoms. 3 to 8 cyclic hydrocarbons (also can be substituted with low-carbon alkylene); η 傺 means 1 to 1 2) It is not worse than dian compounds, easily dissolves various organic or inorganic metal compounds, and has excellent stability For example, when gasified gold is dissolved in ethylenediamine and stored at room temperature as a gold paste, it will decompose about one day later. However, under the same conditions, soft 1,3-diaminopropane is used as For large amines, it can be maintained for weeks to months. If η = 2 and η ¥ 3, the stability depends on the structure. In short, the stability of metal paste depends on the type of metal and amine. There is a big difference. In addition, among the diamine compounds of N Η 2-(CH 2) n-N η 2, amines with η 3 or more have excellent solubility and significant -9-9 Paper size applies to China National Standard (CNS) Α4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) ~ ^) Packing -------- Order ---- Central Standard of the Ministry of Economic Affairs Printed by A7 B7 in the Consumer Cooperatives of the Bureau of Standards. 5. Description of the invention (8) Qualitative, and can provide gold tincture fired at low temperature, is what we want. The metal chrysanthemum of the present invention is composed of the above organic or inorganic metal compounds and A mixture of amine compounds, the mixture has coating viscosity. The present invention is to adjust the desired viscosity by changing the mixing amount of organic or inorganic metal compounds and amine compounds. Here, amine compounds are organic Or the inorganic metal compound contains 0.2 mors or more, preferably 0.6 to 17.51 moles, more preferably 1.0 to 3 moles. In addition, if it is less than 0.2 moles, it is generally difficult to obtain coating viscosity. It causes poor printability, and it is not easy to dissolve organic or inorganic compounds, which is not desirable. The larger the molecular weight of the organic group contained in the metal bud, the higher the temperature when firing the metal film. Therefore, in order to reduce the The smaller the molecular weight of the organic group, the better the firing temperature. However, if it is too small, the fluidity will be reduced, resulting in poor general printability and film formation state. Here, an organic acid or / and / When added to a metal, it can suppress the firing temperature and improve printability and film formation. Especially when the organic acid added in the present invention is a unstable organic or inorganic metal compound *, the metal can be improved by addition. The stability and solubility of the paste can even make the firing film uniform, and the film formation is good. And * depending on various purposes and applications, by changing the type of organic acid, adjusting the firing temperature and forming various properties Here, it is preferable to use an aliphatic or aromatic mono- or dicarboxylic acid represented by the following general formula [C]. R 5-(C00R 6) η ---- [C] (wherein 1 ? 5 and! ? Series 6 represents a hydrogen atom, which can be substituted by an alkylene group. This paper size applies to Chinese Standards (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page)- ------------ Installation I ------ Order ---- Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives A7 B7 V. Description of Invention (9) Number 1 ~ 20 Linear or cyclic hydrocarbons with 3 to 20 carbons; η represents 1 to 3 (but where R5 is a hydrogen atom, η = 1) Specific aliphatic or aromatic mono- or dicarboxylic acids, such as formic acid , Oxalic acid, acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid, heptanoic acid, caprylic acid, 2-ethylhexanoic acid, cyclohexanoic acid, cyclohexylpropionic acid, cyclohexaneacetic acid, nonanoic acid, malic acid , Glutamic acid, hyaluronic acid, hydroxytrimethylacetic acid, tricarboxylic acid, glutaric acid, adipic acid, cyclohexanedicarboxylic acid, pimelic acid, suberic acid, ethylbutyric acid, benzoic acid, benzene Acetic acid, phenylpropionic acid, hydroxy stearic acid, etc. The proportion of the aliphatic or aromatic mono- or dicarboxylic acid to be added varies depending on the type, but for 1 mol organic or inorganic metal compound, it is preferable to add 0 to 5 mol. In addition, depending on the added aliphatic or aromatic mono- or polyhydric alcohol, even when it is an unstable organic or inorganic metal compound, the stability and solubility of the metal paste can be improved and the printability can be improved. Here, M is preferably an aliphatic or aromatic mono- or polyhydric alcohol represented by the following general formula [D]. R 6-(0Η) η ---- [D] (where Re is a cyclic hydrocarbon group having a linear number of carbons which can be substituted by alkyl groups) to 20 or 3 to 20 carbons; η means 1 to 4 ) In addition, the aliphatic or aromatic mono- or polyhydric alcohol may also be a cyano-substituted aliphatic or aromatic mono- or polyhydric alcohol represented by the following general formula [E] having a substituent. (NC) m -R7-(0Η) η ---- [Ε] -11- This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) (Please read the precautions on the back before filling in this Page) Θ. Bi equipment " Order printed by A7 B7, Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1〇) (where R7 is a linear shape with carbon number 1 to 7 or a carbon number of 3 to 8 A cyclic hydrocarbon group; η represents 1 to 3; m represents 1 or 2 (but R7 is n + m = 1 to 4 when the number of carbons is 1 and n + m = 1 to 6 when the number of carbons is 2 M). Aliphatic or aromatic mono- or polyhydric alcohols of the general formula [D] are, for example, nerol, citronellol, hydroxynerol, hydroxycitronellol, ethanol, propanol, butanol, hexanol, ethylhexanol , Decanol, benzyl alcohol, hydroxybenzyl alcohol, phenylethanol, phenylpropanol, hydroxybenzene, cyclohexanol, ethylcyclohexanol, butylcyclohexanol, methoxybenzyl alcohol, piperonyl alcohol, ethylene glycol Alcohols, propylene glycol, 1,2-butanediol, 2,2-dimethyl-1,3-propanediol, and the like. In addition, esters of aliphatic or aromatic mono- or polyhydric alcohols and organic acids of the general formula [D] are also used. Specific examples include methyl benzoate, ethyl hydroxybenzoate, ethyl 2-ethylhexanoate, ethyl acetate, ethyl glycolate, and methyl linoleate. Alternatively, an ester compound of an aliphatic or aromatic mono- or polyhydric alcohol of the general formula [D] may be used. Specifically, for example, ethylene glycol monomethyl ether, diethylene glycol monoethyl ether, triethylene glycol monopropyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, tripropylene glycol monopropyl ether, diethylene glycol, dipropylene glycol, ethylene glycol Glycol monobutyl ether, 1-butoxy-2-propanol, and the like. Aliphatic or aromatic mono- or polyhydric alcohols of the general formula [E] include, for example, lactonitrile, hydroxy, acetonitrile, vinyl cyanoindan, acyl cyanoindan, and the like. Among the above-mentioned aliphatic or aromatic mono- or polyhydric alcohols, it is particularly preferable to add an alcohol having a cyano group of the general formula [E]. By adding this alcohol, unstable organic or inorganic metal compounds can be extremely stabilized, and a transparent and cautious state can be stably maintained. Here. Use # -shaped, 1-valent gold compound, -12- (Please read the precautions on the back before filling in this page), ο. &Quot; 装. The size of the paper is applicable to the Chinese National Standard (CNS) A4 * t grid (210 × 297 (Mm) A7 B7 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (11) If a cyano alcohol having the general formula [E] is added, it can be stored at room temperature for about 4 years. The addition ratio of aliphatic or aromatic mono- or polyhydric alcohols varies depending on the type, but for organic or inorganic metal compounds of 1 mole, it is better to add M to 0-5 moles. Moreover, both aliphatic or aromatic mono- or dicarboxylic acids and aliphatic or aromatic mono- or polyhydric alcohols may be added to the metal fasting. Here, it is known that the general organometallic compound has poor printability when applied by a printing method. However, in the present invention, by adding an organic ketone or an organic ether to the above-mentioned metal rhenium, the smoothness of M is changed into an extensible rhenium. By this method, printability can be improved, and storage stability can be improved. Therefore, a thin uniform metal film can be formed. As the organic ketone, aliphatic or aromatic ketones can be used. More specifically, such as propyl noodles, ethyl ketone, 2-pentanone, 3-pentanone, 3-methyl-2-butanone, 2-hexanone, 3-hexanone, methylbutanone, 3- Methyl-2-pentanone, 2-heptanone, 3-heptanone, 4-heptanone, amyl ketone, ethyl butanone, 2,4-dimethyl-3-pentanone, 2-octanone , 3-octyl_, 4-octanone, 2,5-dimethyl-3-hexanone, cyclohexanone, methylcyclohexanone, acetamylpropane, 2,3-butanedione, 2, Fatty ketones such as 3-pentanedione, 3,4-hexanedione, 2,5-hexanedione, and cyclohexanedione; aromatic ketones such as acetophenone. As the organic ethers, aliphatic or aromatic ethers can be used. More specifically, for example, 4-methoxy-2-butanone, 4-ethoxy-2-butanone, 4-methoxy-2-one, 2-methoxy-2-methyl-4- Ethylene glycol, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dipropyl ether, propylene glycol diethyl ether, propylene glycol 213 — This paper size applies to the Chinese National Standard (CNS) 8.4 (210 × 297 mm) 〉 ------- © — ^ Q-pack ------ order -----. (Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of the invention (12) Ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, propylene glycol dipropyl ether, acetal, acetone diethyl Aliphatic ethers such as acetal, 2, 2-dimethoxypropane, aromatic ethers such as anisole, dimethoxybenzene, etc. The addition ratio of aliphatic or aromatic ketones or ethers depends on the type It is different, but for 1 mole organic or inorganic metal compounds, it is better to add 0 to 4 moles. Moreover, it is also possible to add aliphatic or aromatic fluorenes or ethers to Jinyin #. Invented The reason why the metal paste is fixed is to use the following effects. In other words, an amine compound is added to an organic or inorganic metal compound that is solid at ordinary temperature and stirred, and the organic or inorganic metal compound is mixed with a liquid amine group. The compound is coordinated to form a maggot. In addition, when the organic or inorganic metal compound is combined with the amine compound, if it is crystallized by mixing, the amine compound may be morphed if different types of amine compounds are mixed at this time. In addition, most of the amine compounds of organic or inorganic gold tinctures themselves are unstable. Therefore, when an organic acid is added thereto, the whole becomes a composition of a positive and negative binding structure, so the active gold tincture sandwiched can be stabilized. The manufacturing method of a metal film is to coat a metal substrate on a desired substrate, and manufacture the metal film by firing. At this time, first, alcohols with weak binding force are separated in a low temperature region, and then the acid is separated. Decompose the coordination of amine, and then preheat K to cut off the organic group K directly bonded to the metal to form a metal film. At this time, the smaller organic group is lower than the larger organic group -This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the notes on the back before filling this page) • Packing. Order printed by A7 B7, Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs It is explained that (15) decomposes, so κ low-temperature firing can produce a metal film. This is a mechanism that forms organic or inorganic metal compounds that are solid at normal temperature to form K, and decomposes M at low temperature to form a metal film. In addition, the gold alloy uses users already in various areas as important materials. In other words, in the areas of electronic materials, mechanical materials, optical materials, sanitary materials, living materials, agricultural materials, medical materials, etc., the above metals are reused. Within these ranges, the unique properties of metals can be used. Conventional metals can be used as conductive materials, anti-refractory materials, heat transfer materials, thermal insulation materials, light and electromagnetic wave reflection and absorption materials, Corrosion-resistant materials, mechanical strength materials, materials for abrasion absorption, materials for catalysts, materials for metallic gloss, materials for coloring, materials for decoration Or microbial growth inhibition materials. The firing temperature is 90t: ~ 5501C, preferably 110 ~ 35〇υ. Compared with the conventional method of heating and processing at the melting point M of the conventional metal, this temperature significantly reduces the heat treatment temperature. Therefore, it is possible to coat the substrate of metal chrysanthemum. Not only the conventional high melting point substrate (ceramic, metal) with high heat can be used, but also other general glass, resin (thermosetting resin, thermoplastic resin), paper and other substrates. It is suitable for the manufacturing method of the metal film of the present invention. Therefore, a metal-coated substrate with metal-specific properties can be provided. In addition, the substrate of the present invention also includes a film-shaped or sheet-shaped low-melting-point substrate. Examples Examples of the present invention will be described in detail below. Example 1 Add -15 to 1.00g (4.34 millimoles) of palladium nitrate (Pd (N03) 2). The paper's dimensions apply to the Chinese National Standard (CNS) grid (210X297 mm) (please read the first (Please note this page and fill in this page again) ------------- 〇 — ^ ------'- IT ----:-ί Print Preparation of A7 B7 _ 5. Description of the invention (14) 0.70 g (9.45 mmol) 1,3-diaminopropane (NH2 CH2 CH2 CH2 NH2), 0.70 g (7.94 mmol) N-methyl-1, 3-diaminopropane (CH3 NHCH2 CH2 CH2 NH2), 0.40 g (4.49 mmol) 3-methoxypropylamine ((: 113〇112 (:! 12 (^ 2 ^ 112)) Mix with M to form a paste. Add 1.20g (13.62 mmol) of isobutyric acid ((CH3) 2CHCOOH) and knead to form a dark brown transparent paste. Apply this to a substrate such as glass and heat up Up to 320 T: After firing for 5 minutes, a thin film of palladium was obtained. In this example, an amine compound was used in an amount of 5.04 times for 1 mole of metal. Cell Example 2 was 1.00 g (6.31 mmol). ) Palladium cyanocyanate (Pd (CN2))> 0.60 g (8.10 mmol) 1,3-diaminopropane, 0.2 0g (2.27 mmol) N-methyl-1,3-diaminopropane, 1.50 g (19,97 mmol) 2-methoxyethylamine (CH3 OCH2CH2 NH2), 0.40 g (5.63 mmol) (Ear) lactonitrile (CH2CH (0H) CN) and agitated to form a transparent threat. It was coated on a substrate such as glass, heated to 300C, and fired for 10 minutes to obtain a uniform film of palladium. In this example, an amine compound is used at a ratio of 4.81 times for 1 mole of metal. Example 3 0.60 g (6.80) of 1.00 g (4.45 millitorles) of palladium acetate (Pd (00 (CH3) 2) is added. Millimoles) H-methyl-1,3-diaminopropane, 0.40g (5.33 millimoles) of 2-methoxyethylamine, and stirred at W to obtain a transparent mash. This was coated with Cover the substrate with glass, etc., and heat up to 250t: After firing at W for 10 minutes, a homogeneous film of palladium is obtained. In addition, this example applies to China's national standard (CNS) A4 specification for this paper size. (210X 297 mm) I .----------------- Order ----_-- (Please read the precautions on the back before filling in this tile. Manufacturing A7 B7 V. Description of the invention (15) For ear metal use 2.73 Amine compounds. Example 4 To 1.00 g (4.45 mmol) of palladium acetate was added 0.60 g (5.60 mmol) of N-methylaniline (C6 Hs NHCH3), 0.30 g (3.41 mmol) of isobutyric acid and M After dissolving, a brown transparent mash was obtained. If necessary, phenylethanol is added and mixed with M to obtain a dark reddish brown paste with improved printability. This was coated on a substrate such as glass, heated to 250 ° F, and baked for 10 minutes to obtain a mirror-like palladium film. Further, in this example, a 1.26-fold amino compound was used for 1 mole of metal. Example 5 To 1.00 g (4.45 mmol) of palladium acetate (Pd (00 (CH3) 2) was added 0.20 g (1.05 mmol) of N, H-diethyltriamine, 3.00 g (17.2 mmol) (Ear) hydroxycitronellol and stirring to obtain a translucent paste. It is coated on a substrate such as glass, heated to 2501C, and fired at K for 10 minutes to obtain a uniform film of palladium. In this case, 0.24 times the amine compound is used for 1 mole of metal. Example 6 To 1.00 g (4.45 mmol) of palladium acetate was added 0.20 g (2.32 mmol) of methacrylic acid and 0.35 g (4.66 mmol) of 2-methoxyethylamine and stirring at M to obtain a dark-colored maggot. It was coated on a substrate such as glass and heated to 230 ¾ and baked at M for 10 minutes to obtain A homogeneous film of palladium. In this example, 1.05 times the amino compound is used for 1 mole of metal. Examples 7-17- This paper size applies the standard of China National Standard (CNS) A4 (210X297 mm) ) (Please read the precautions for the kidney surface before filling out this page) _____________91) ^ ______ Τ ____ /.!. ........ 7 A7 B7 V. Description of the invention (16) at 1.00g (4.45 millimolar) To the palladium acetate, add 0.40 g (3.73 mmol) of phenylethylamine, 0.40s (3.92 mmol) of valeric acid, and stir with M, and knead until a black tea-colored cautious substance is applied. It is coated on glass On the substrate, the temperature was raised to 25 ° C and baked for 10 minutes to obtain a uniform film of palladium. In this example, an amine-based compound was used at a ratio of 0.84 times for 1 mole of metal. _ Example 8 To 1.00 g (3.02 mmol) of platinum diamine propane nitrate complex (NH2 CH2 CH2 CH2 NH2, Pt (N03) 2) was added 1,000 g (8.76 mmol) of 2-diamine Cyclohexane was mixed with M to obtain a transparent light brown paste. In any case, it was coated on a substrate such as glass and heated to 350C and baked for 5 minutes to obtain a platinum film. This If high carbonic acid such as heptanoic acid is used, the adhesion can be improved. In this example, an amine compound of 3.90 times is used for 1 mole of metal. Example 9 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System (please read the precautions on the back before filling this page) add 1.00g (3.75 mmol) thorium nitrate (Τ1Ν〇3) 0.60g (5. 25 millimoles) 1,2-diaminocyclohexane, 0.3 (^ (4.05 millimoles) 1,3-diaminopropane and stirring them to obtain a colorless and transparent # -like substance. Apply it The substrate covered with glass is heated to 170 ~ ΐδ〇υ and fired in a reducing atmosphere to obtain a rhenium film. Further, in this example, a 2.48-fold amine-based compound was used for 1 mole of metal. Example 10 To 1.00g (2.50 millimoles) of rhodium acetoacetonate (RH (CH3 C0CHC0CH3) 2) was added 0.80g (9.07 millimoles) of N-A. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X29? Mm) A7 B7 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (17) Based on 1, -1,3-diaminopropane, materials can be obtained. Then add 0.60 g ( 6.81 mmol) isobutyric acid is kneaded to form a dark brown transparent uniform cautious substance. It is coated on a substrate such as glass and heated to 390t: and baked for 5 minutes to obtain a thin film of tritium. And In this example, an amine compound of 3.63 times is used for 1 mole of gold tincture. Example 11 0.60 g is added to 1.00 g (5.63 mmol) of hexadecyl hexa germanium (Rhe (C0) 16). (8.10 mmol) 1,3-diaminopropane, 0.40 g (5.33 mmol) 2-limyl-1-propanol (HH2 CH (CH3) CH2OH) and kneaded to make a uniform 39 倍。 It is coated on a substrate such as glass, heated to 290TC and pre-K fired for 5 minutes to obtain a rhodium film. Moreover, in this example, 2.39 times is used for 1 mole metal. Amination Example 12 To 1.00 g (4.48 mmol) gold fluoride (AuCN) was added 0.40 g (4.54 mmol) fj-methyl-1,3-diaminopropane, 0.10 g (0.77 mmol) Mol> 1,7-diaminoheptane (HH2 (CH2) 7 NH2), 0.110s (1.12 mmol) 3-propoxypropylamine and stir. Add 0.70 g ( 5.46 millimoles > cyclohexanoic acid (CeHii COOH) and 0.80g (5,55 millole) 2-ethylhexanoic acid (CH3 CH2 CH < CH3 CH2 > COOH) and mixed with M to obtain a red purple transparent chrysanthemum. This was coated on a substrate such as glass and baked at 5000 to 5500 C to obtain a gold mirror film. Further, in this example, an amine compound of 1.44 times is used for 1 mole of metal. Example 13 Add 1.00g (4.48 mmol) of gold fluoride to 0.80 g (11.25 mmol-19- This paper size applies to Chinese national standards (CNS > A4 size (2 丨 〇 X 297 (Mm) -------- Pack-(Please read the precautions on the back before filling in this page)-Order ------ A7 B7 '------------- --------- V. Description of the invention (I8) Ear) Laconitrile, 0.60g (5.87 millirales) 2,2-dimethyl-1,3-diaminopropane (NH2 CH2 C ( CH3) 2 CHz NH2), 0.10s (0.777 millimoles) 1.7-diaminoheptane, 0.30g (3.37 millimoles) 3-methoxypropylamine, and stirring to make light orange The color is transparent. It is coated on a glass substrate and fired at 500 ~ 5501C to produce a gold film. At this time, lactonitrile is added again. It can be seen that the organometallic compound becomes very stable. It will not be decomposed after 4 years of storage at room temperature, and it is still a light orange transparent fasting object. In this example, an amino compound of 2.23 times is used for 1 mole of metal. Example 1 4 Add 1.00g (5.99 mmol) silver acetate (CH3 COOAg) to 0.70g (4.42 mmol) nonanoic acid (C8 H 17C00H) and mix . Then add 0.60g (8.10 mmol) of 1,3-diaminopropane and stir it with K to make a white-gray paste. Mix K again to make a brown translucent bud. Add 0.40 g (0.37 mmol) 1,4-phenylenediamine ('C 6 Η 4 (Ν Η 2) 2) kneaded until red translucent. Then add 0.50 g (6.75 mmol), C The acid (CHa CH2 C00H) is kneaded to a red-brown color, and it is coated on a substrate such as glass and heated to 35 Ot: and baked for 5 minutes to obtain a silver film of silver mirror. In this case, 1.41 times the amine compound was used for 1 mole of metal. Case 15 added 1.0 g (5.99 mmol) of silver acetate to 0.8 g (8.98 mmol) (Ear) 3-methoxypropylamine, 0.05 g (0.25 mmol), 1,12-diaminododecane (HH2 (CH2) i2NH2) and stirred. Then add -2 0-this Paper size applies Chinese National Standard (CNS) Α4 specification (210 × 297 mm) m ϋ— -an 1 ^ 1 In · (Please read the precautions on the back before filling in this page) —ο. Linstall ------ Order ---- Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed A7 B7 V. Description of the invention (19) 1. 〇8 (7.68 mmol) heptanoic acid ((: 61113 (: 001, 0.15 ^ (1.12 mmol) malic acid) HOOCCH2 CH (OH ) COOH) and let M search. Add 0.60g (8.10 millimolar) of 1,3-diaminopropane and knead until the tile color becomes light. This was coated on a substrate such as glass, and the temperature was raised to 30 ° and firing was performed for 1 minute to obtain a silver film. Further, in this example, an amine compound of 2.89 times is used for 1 mole of metal. Example 16 To 1.00 g (5.99 mmol) of silver acetate was added 0.50 g (6.75 mmol) of 1,3-diaminopropane and 0.60 g (6.73 mmol of methoxypropylamine). , O.OSg (0.24 millimolar) 1,12-diaminododecane and stir. Then add 0.80g (6.14 millimolar) heptanoic acid, 0.40s (2.56 millimolar) ) Cyclohexylpropanoic acid (Cs Hu (CH2) 2 C00H), 0.5 g (1.12 millole) malic acid, 0.2 g (1.75 millimolar) 1,2-diaminocyclohexane and knead until it is red Transparent orange is formed until it is orange. It is coated on a substrate such as glass and heated up to 230 t: and fired with K for 10 minutes to obtain a silver mirror film, or heated to 290 K firing [0 minutes], m color film of stomach. In this example, 1.46 times of amine compound is used for 1 mole of gold tincture. Example 17 1.00 g (5.99 mmol) of acetic acid Add 0.50g (6.75 millimolar) of 1,3-diaminopropane and 0.40g (2.53 millimolar) of nonanoic acid to silver and knead them to form a red-orange transparent bud. Then add 0.10s (〇.88mmol) Molecules of 1,2-diaminocyclohexane and K. Purple chrysanthemum was formed the following day: Material ° Coated on a glass substrate, etc., heated to 300 ¾ and burned. The paper size is applicable to China National Standard (CNS) A4 specification (210 × 297 mm) (Please read the note on the back before filling This page) Order! II-Ϊ Printed by the Consumer Standards Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs, A7
經濟部中央標準局員工消費合作社印製 五、發明説明（20 ) 5分鐘，製得銀鏡膜。而且，於該實施例中對1莫耳金 屬而言使用1.27倍之胺基化合物。 實施例18 在1.00g(6.54毫莫耳）甲酸銀（HCOOAg)中加人0.80g (7.01毫莫耳）1,2-二胺基環己烷並予K混練。再加入 0.5〇g(6.58毫莫耳）乙二醇單甲醚而成黑灰色透明的# 狀物。將其塗覆於薄膜等基板上，升溫至130t：並予以 燒成，製得稍黃色帶狀銀膜。而且，於該實施例中尉1 其耳金属而言使用1.07倍之胺基化合物。 實胞例19 在1.00g(6.54毫莫耳）甲酸銀中加人〇.8〇g(l〇.80毫萁 耳）1,3 -二胺基丙並予K混練。將其塗覆於玻璃等之基 板上，升溫至llOt：並燒成5分鐘，製得銀膜°再加入 0.60g(9.98毫莫耳）醋酸（CH3 C00H)並予Μ混練製得安 定的裔狀物。將其塗覆於玻璃等之基板上，升溫至1 2 〇 t： 且燒成5分鐘，製得灰色銀膜。而且，於該實施例中對 1莫耳金鼷而言使用1.65倍之胺基化合物。 實施例20 在0.80g(4.79毫莫耳）醋酸銀之结晶中加人〇.273g (1.22毫莫耳）醋酸鈀之粉末並予以混合，再加入0.30g (2.58毫莫耳2-甲基-1,5-二胺基庚烷 (NH2 (CH2 )3 CH(CH3 )CH2 NH2 )、 〇.30g(2.58毫莫耳） 1-苯基乙胺（C6 H5 CH(NH2 )CH3 )、0.30g(3.44 毫莫耳） 嗎福啉（0<(CH2 )4 >NH)並予M攪拌。再加入0.30g(2.30 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) .裝- -6 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（21 ) 毫莫耳）庚酸並予κ混練而成茶色透明的膏狀物。將其 塗覆於玻璃等之基板上，升溫至3 2 0 C並予K燒成1 0分 鐘，製得鏡面之銀鈀合金膜。而且，於該實施例中對1 莫耳金屬而言使用1.41倍之胺基化合物。 實施例21 在1.00g(2.59毫莫耳）醋酸鉍（Bi(OOCCH3 )3中加入 1.20g(0.51毫莫耳）1,2-二胺基環己烷、0,60g(6.73毫 莫耳）3 -甲氧基丙胺並予Μ攪拌而成淡色透明的裔狀物 。將其塗覆於玻璃等之基板上，升溫至250〜3501C，在 還原氣氛中燒成，製得鉍膜。而且，於該實施例中對1 莫耳金屬而言使用6.66倍之胺基化合物。 實施例22 在1.00g(2.64毫莫耳）醋酸鉛三水合物（Pb(00CCH3 )2 • 3H2 0)中加入1.10g(9.63毫莫耳）1,2-二胺基環己烷 並予Μ攪拌。另再加入0.20s (2.27毫莫耳）異丁酸並予 Μ攪拌而成淡色大致上透明的賫狀物。將其塗覆於玻璃 等之基板上，升溫至270〜300t：,在還原氣氛中燒成， 製得鉛膜。而且，於該實施例中對1莫耳金屬而言使用 3.65倍之胺基化合物。 實施例23 在1.00g(4.01毫莫耳）醋酸鈷四水合物（Co(00CCH3 )2 • 4H2 0)中加人0.80g(9.07毫莫耳）N -甲基-1,3 -二胺基 丙烷並予Μ攪拌而成暗紫色透明的赍狀物。將其塗覆於 玻璃等之基板上，升溫至270〜30〇υ,在遷原氣氛中燒 -23- 本紙張尺度適用中國國家標準（CNS ) A4» (210Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) .~0 裝------訂 I--- 經濟部中央標準局貝工消費合作社印製 A7 _ B7_ 五、發明説明（22 ) 成，製得鈷膜。而且，於該實施例中對1莫耳金靥而言 使用2.26倍之胺基化合物。 實施例24 在l.〇〇g(3.42毫莫耳）醋酸絪（In(00CCH3 )3 )中加入 0.90g(12.15毫莫耳）1,3-二胺基丙烷並予Μ攪拌而成稍 為乳白的無色透明菊1狀物。將其塗覆於玻璃等之基板上 ，升溫至220〜230 C,在還原氣氛中燒成，製得絪膜。 而且，於該實施例中對1莫耳金屬而言使用3.55倍之胺 基化合物。 實施例2 5 在l.〇〇g(5.51毫莫耳）醋酸錮（Cu(00CCH3 )2 )中加入 1.20g(16.19 毫莫耳）1,3-二胺基丙烷、1.40g(15,71 毫 莫耳）3 -甲氧基丙胺、1.20g(6.90毫莫耳）羥基香茅醇 (HOC (CH 3 )2 CH2 CH2 CH2 CH(CH3 )CH2 CH2 0H)並予 M攪拌而成藍色透明液。將其塗覆於玻璃等之基板上， 升溫至350〜36〇υ,在遛原氣氛中燒成製得銅膜。而且 ，於該實施例中對1莫耳金靥而言使用5. 79倍之胺基化 合物。 實胞例26 在l.〇〇g(3.35毫莫耳）醋酸銻（Sb(00CCH3 )3中加入 0.60g(6,80毫莫耳）N -甲基-1,3-二胺基丙烷、0.60g (6.73毫莫耳）3 -甲氧基丙胺並予以攪拌。另再加入 0.40g(3.92毫莫耳）三甲基乙酸（CH3 C(CH3 )C00H)並予 Μ混練而成乳白色半透明的蕾狀物。將其塗覆於玻璃等 一 2 4 - 本紙伕尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝. -訂---. 經濟部中央標準局員工消費合作社印製 、發明説明（25 ) 之基板上，升溫至36〇υ,在堪原氣氛中燒成，製得銻 膜。而且，於該實施例中對i其耳金屬而言使用4.〇4倍 之胺基化合物。 實施例2 7 在l.〇〇g(3.75毫莫耳）醋酸鎘二水合物（Cd(〇〇CCfl3 • 2H2 0)中加人I.0^g(14.56毫其耳）卜胺基卜丙醇 CHCH3 )CH2 0H)而成黃色透明的資狀物。在2〇〇〜 240¾下予以處理’塗覆於坡璃等之基板上升溫至 MOt：，在遷原氣氛中燒成，製得鎘膜。而且，於該實 施例中對1莫耳金羼而言使用3.91倍之胺基化合物。 實施例28 在1.0 0H3.7 5毫莫耳）環己基丙酸釕 (Ru(〇〇CCH2 CH2 C6 Hii)3 )中加入 2.〇〇g(17 51 毫其耳） 1，2 -二胺基環己烷並予以攪拌。將所得的眘狀物塗覆於 玻璃等之基板上，升溫至30 0勺，且在堪原氣氛中燒成， 製得釘膜。而且，於該實施例中對1莫耳金屬而言使用 9.95倍之胺基化合物。 實施例29 在1.00g(4.84毫莫耳）草酸錫（Sn(C00)2 )中加人2.00g (17.51毫萁耳）1,2-二胺基環己皖、〇.9(^(12.15毫莫耳） 1,3-二胺基丙烷並予以攒拌而成乳白色裔狀物。再於其 中加人1.00g(6.40毫莫耳）環己烷丙酸並予κ攪拌而成半 透明的裔狀物。將其塗覆於玻璃等之基板上，升溫至 360t),在堪原氣氛中燒成，製得錫膜。而且，於該實 -25- 本紙張尺度逋用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝·Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (20) 5 minutes, the silver mirror film was produced. Further, in this example, an amine compound of 1.27 times is used for 1 mol metal. Example 18 To 1.00 g (6.54 mmol) of silver formate (HCOOAg) was added 0.80 g (7.01 mmol) of 1,2-diaminocyclohexane and K was mixed. Add 0.50 g (6.58 mmol) of ethylene glycol monomethyl ether to form a black-gray transparent #. This was coated on a substrate such as a thin film, and the temperature was raised to 130t: and fired to obtain a slightly yellow band-shaped silver film. Moreover, in this example, Lieutenant 1 uses an amine compound of 1.07 times for its ear metal. Cell Example 19 To 1.00 g (6.54 mmol) of silver formate was added 0.80 g (10.80 mmol) of 1,3-diaminopropyl and K was mixed. It was coated on a substrate such as glass, and heated to 110 °: and fired for 5 minutes to obtain a silver film. Then 0.60 g (9.98 mmol) of acetic acid (CH3 C00H) was added and mixed with M to obtain a stable seed. Thing. This was applied to a substrate such as glass, and the temperature was raised to 120 ° C .: and firing was performed for 5 minutes to obtain a gray silver film. Further, in this example, an amine compound of 1.65 times was used for 1 mol tincture. Example 20 To 0.80 g (4.79 mmol) of silver acetate crystals was added 0.273 g (1.22 mmol) of palladium acetate powder and mixed, and 0.30 g (2.58 mmol of 2-methyl- 1,5-diaminoheptane (NH2 (CH2) 3 CH (CH3) CH2 NH2), 0.30 g (2.58 mmol) 1-phenylethylamine (C6 H5 CH (NH2) CH3), 0.30 g (3.44 millimoles) Morpholine (0 < (CH2) 4 > NH) and stir with M. Add 0.30g (2.30) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (please Read the notes on the back before filling this page). Packing--6 Printed A7 B7 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (21) mol) Heptanoic acid and kneaded with κ to make it brown and transparent The paste was coated on a substrate such as glass, heated to 3 2 0 C, and fired at K for 10 minutes to obtain a mirror-like silver-palladium alloy film. In addition, 1 mol was used in this example. For the metal, an amine compound of 1.41 times is used. Example 21 To 1.00 g (2.59 mmol) of bismuth acetate (Bi (OOCCH3) 3) was added 1.20 g (0.51 mmol) of 1,2-diaminocyclohexane. Alkane, 0,60g (6.73 mmol) 3-Methoxypropylamine was stirred and stirred to produce a light-colored transparent descent. It was coated on a substrate such as glass, heated to 250 ~ 3501C, and fired in a reducing atmosphere to obtain a bismuth film. In this example, 6.66 times the amount of amine compound is used for 1 mole of metal. Example 22 1.10 g is added to 1.00 g (2.64 mmol) of lead acetate trihydrate (Pb (00CCH3) 2 • 3H2 0). (9.63 millimoles) 1,2-diaminocyclohexane and stirred at M. Another 0.20s (2.27 millimoles) of isobutyric acid was added and stirred at M to form a lightly transparent, substantially transparent mash. It is coated on a substrate such as glass, and the temperature is raised to 270 to 300 t: it is fired in a reducing atmosphere to prepare a lead film. In this example, an amino group of 3.65 times is used for 1 mole of metal. Example 23 To 1.00 g (4.01 mmol) of cobalt acetate tetrahydrate (Co (00CCH3) 2 • 4H2 0) was added 0.80 g (9.07 mmol) of N-methyl-1,3 -di Aminopropane is stirred and mixed to form a dark purple transparent maggot. It is coated on a substrate such as glass, heated to 270 ~ 30〇υ, and burned in the original atmosphere. Applicable to China National Standard (CNS) A4 »(210 × 297 mm) (Please read the notes on the back before filling this page). ~ 0 Packing ------ Order I --- Central Standards Bureau, Ministry of Economic Affairs Consumption cooperative prints A7 _ B7_ 5. Description of invention (22), Cobalt film is produced. Further, in this example, an amine compound of 2.26 times was used for 1 mole of tincture. Example 24 0.90 g (12.15 mmol) of 1,3-diaminopropane was added to 1.0 g (3.42 mmol) of europium acetate (In (00CCH3) 3), and the mixture was stirred to make it slightly milky. 1 colorless transparent chrysanthemum. It is coated on a substrate such as glass, heated to 220 to 230 C, and fired in a reducing atmosphere to obtain a rhenium film. Further, in this example, an amine compound of 3.55 times is used for 1 mole of metal. Example 2 5 To 1.00 g (5.51 mmol) of europium acetate (Cu (00CCH3) 2) was added 1.20 g (16.19 mmol) of 1,3-diaminopropane, 1.40 g (15,71 Mol) 3-methoxypropylamine, 1.20g (6.90 mol) hydroxycitronellol (HOC (CH 3) 2 CH2 CH2 CH2 CH (CH3) CH2 CH2 0H)) and stir to make it blue and transparent liquid. It was coated on a substrate such as glass, and the temperature was raised to 350-360 ° C, and the copper film was obtained by firing in a Kashihara atmosphere. Moreover, in this example, an amine compound of 5.79 times was used for 1 mole of gold tincture. Cell Example 26 To 1.00 g (3.35 mmol) of antimony acetate (Sb (00CCH3) 3) was added 0.60 g (6,80 mmol) of N-methyl-1,3-diaminopropane, 0.60g (6.73 mmol) 3-methoxypropylamine and stir. Another 0.40 g (3.92 mmol) of trimethylacetic acid (CH3 C (CH3) C00H) was added and mixed with M to form a milky white translucent It is coated on glass, etc. 2-4-The size of this paper is applicable to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) ---. On the substrate printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs and the invention description (25), the temperature was raised to 36 ° and fired in a Kanbar atmosphere to produce an antimony film. Moreover, in this embodiment For its ear metal, 4.04 times the amine compound was used. Example 2 7 In 1.0 g (3.75 mmol) cadmium acetate dihydrate (Cd (〇CCfl3 • 2H2 0) Adding I.0 ^ g (14.56 milliliters) of propylaminopropanol (CHCH3) CH2 0H) into yellow transparent materials. The substrate is coated at a temperature of 200 to 240 ¾ and is heated to MOt on a substrate coated with slope glass or the like. The substrate is fired in the original atmosphere to prepare a cadmium film. Further, in this example, an amine-based compound of 3.91 times is used for 1 mole of tincture. Example 28 To 1.0 0H3.7 5 mmoles of ruthenium cyclohexylpropionate (Ru (〇〇CH2CH2 C6 Hii) 3) was added 2.00 g (17 51 milliliters) of 1,2-diamine Cyclohexane and stirred. The obtained pellet was coated on a substrate such as glass, heated to 300 scoops, and fired in a Kanbar atmosphere to obtain a nail film. Further, in this example, an amine compound was used at a rate of 9.95 times for 1 mole of metal. Example 29 To 1.00 g (4.84 mmol) of tin oxalate (Sn (C00) 2) was added 2.00 g (17.51 mmol) of 1,2-diaminocyclohexane, 0.9 (^ (12.15 Millimolar) 1,3-diaminopropane and mixed with milky descent. Then add 1.00g (6.40 millimolar) of cyclohexanepropionic acid and stir with κ to make it translucent. It is coated on a substrate such as glass and heated to 360t) and fired in a Kanbar atmosphere to prepare a tin film. Moreover, in this case -25- this paper size uses the Chinese National Standard (CNS) A4 specification (210 × 297 mm) (please read the precautions on the back before filling this page)
訂I 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（2〇 胞例中對1莫耳金屬而言使用6.13倍之胺基化合物。 實施例30 在0.80g(4.79毫莫耳）醋酸銀之结晶中加入0.273g (1.22毫莫耳）醋酸鈀之粉末並予Μ混合，再加入0.30g (2.58毫莫耳）2-甲基-1,5-二胺基庚烷、0.30έ(2.48毫 莫耳）1-·苯基乙胺、0.30g(3.44毫莫耳）嗎福啉並予以攪 拌。然後，加入0.30g(2.30毫莫耳）庚酸並予Μ混練而 成茶色透明的赍狀物。將其塗覆於玻璃等之基板上，升 溫至29〇υ並予Κ燒成15分鐘，製得鏡面之金屬膜。ΚΧ 線繞射測定，如第1圖（a)〜（c)可知，完全沒銀單獨時 之位置波峰及鈀單獨時之位置波峰。另在銀單獨及鈀單 獨時之波峰位置中間產生1個波峰。而且，第1圖（a) 係表示X線繞射画，第1圖（b)係為第1圖（a)之波峰 數據，第1圖（c)係表示銀及鈀單獨的波峰數據（圖表 數據）。藉此可知，較各金屬熔點低很多的溫度290 ¾時 可生成銀鈀之合金。而且，於該實施例中對1莫耳金屬 而言使用1.41倍之胺基化合物。 實施例31 在1.00g(4.02毫莫耳）醋酸鎳四水合物（Ni(0CCH3 )2 • 4H2 0)之結晶中加入0.70g(7.94毫莫耳）N -甲基-1,3-二胺基丙烷、〇.l〇g(1.33毫奠耳）1-胺基-2-丙醇 (NH2 CH2 CH(CH3 )0H)並予Μ攪拌而成藍色透明黏液。 再於其中加入0.40g甲基異丁酮與0.80g異丁酸並予Μ攪 拌而成透明的赍狀物。將其塗覆於玻璃等之基板上，在 -26- 本紙張尺度適用中《 Β家標準（CNS ) Α4規格（210Χ 297公釐） I------裝------訂----V (請先閲讀背面之注意事項再填寫本頁) A 7 B7 五、發明説明（25 ) 還原氣氛中升溫至300 ¾並予Μ燒成，製得鎳膜。而且， 於該實施例中對1莫耳金靥而言使用2.31倍之胺基化合 物0 實施例32 在 1.00g(2.34 毫莫耳）醋酸鉬二聚物（[(CH3COO)2 Μο]2 ) 之结晶中加人1.30g(14.74毫莫耳）Ν -甲基1,3 -二胺基丙 烷、0.55g(7.32毫莫耳）1-胺基-2-丙醇並予Μ攪拌而成 茶色透明液。再於其中加入0.30g異戊基甲酮與1.80g異 丁酸並予Μ攪拌而成透明的膏狀物。將其塗覆於玻璃等 之基板上，在還原氣氛中升溫至35〇υ並予Μ燒成，製 得鉬膜。而且，於該實施例中對1莫耳金屬而言使用 4.72倍之胺基化合物。 實施例33 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在1.00g(4.31毫莫耳）醋酸錳二水合物（Mn(OOCCH3 )3 0E2H2 0)之结晶中加入0.70g(7.94毫莫耳）N -甲基-1,3-二胺基丙烷、0.40g(5.33毫莫耳）1-胺基-2-丙醇並予Μ 攪拌，而成暗茶色透明黏液。再於其中加入0.30g2, 4-二甲基-4-庚醇與1.10g異丁酸並予Μ攪拌，而成透明的 赍狀物。將其塗覆於玻璃等之基板上，在還原氣氛中升 溫至370 ¾並予Μ燒成，製得耔膜。而且，於該實施例 中對1莫耳金屬而言使用3. 08倍之胺基化合物。 實施例34 在1.00g(4.56毫莫耳）醋酸鋅二水合物（Zn(00CCH3 )2 • 2H2 0)之結晶中加人0.50g(5.67毫莫耳）N -甲基-1,3- -27-本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7 五、發明説明（26 ) 二胺基丙烷、0.50g(6.66毫莫耳>1-胺基-2-丙醇並予Μ 搅拌而成無色透明黏液。再於其中加入〇.3〇g乙二醇二 甲與1.00g3 -環己基丙酸（C6 HiiCH2 CH2 COOH)並予Μ 搅拌，而成透明的資狀物。將其塗覆於玻璃等之基板上 ，在還原氣氛中升溫至300t!並予Κ燒成，製得鎳膜。 而且，於該實施例中對1莫耳金屬而言使用2 . 7 0倍之胺 基化合物。 實施例35 在 1.00g(1.66毫莫耳）醋酸鉻（（CH3 C00)7 Cr3 (0H)2 ) 之结晶中加人0.85g(9.64毫莫耳）N-甲基-1,3-二胺基丙 烷、0,50g(6.66毫莫耳）1-胺基-2-丙醇並予Μ攪拌而成 綠色透明液。使其透過白熱電燈圼紫色，而透過螢光燈 圼黑灰色。再於其中加人0.30g2-庚酮與1.30g異丁酸並 予Μ攪拌而成透明的裔狀物。將其塗覆於玻璃等之基板 上，在還原氣氛中升溫至340 t並予Μ燒成，製得以粉 之鉻膜。而且，於該實施例中對1莫耳金屬而言使用 3.27倍之胺基化合物。 實施例36 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 在1.00g(5.75毫莫耳 > 醋酸鐵無水物（Fe(00CCG3 )2 ) 之结晶中加人0.60g(6.80毫莫耳）N-甲基-1,3-二胺基丙 烷、0.50g(6.66毫莫耳）1-胺基-2-丙醇並予W攪拌成茶 色透明黏液。再於其中加入0.30g乙二醇二甲醚與1.10g 異丁酸並予Μ攪拌成透明的裔狀物。將其塗覆於玻璃等 之基板上，在遨原氣氛中升溫至350*0並予Μ燒成，製 一 2 8 _ 本紙張尺度適用中國國家標準（CNS ) Α4洗格（210Χ297公釐） A7 , B7 五、發明説明（27 ) 得鐵膜。而且，對1莫耳金屬而言使用2.34倍之胺基化 合物。 本發明之金屬赍狀物，其特徵為常溫下為固體，屬於 周期表第3族〜第15族金屬之有機或無機金屬化合物中 配合做為介質之胺基化合物，可圼現塗覆粘性之裔狀物。 因此，不需要使用特殊的化合物及合成法，只需在一 般的低價固體有機或無機金屬化合物中加入一般的低價 胺基化合物，藉由所謂攪拌之簡易方法，使有機或無機 金屬化合物直接容易地膏狀化。此外，本發明之金屬膏 狀物，可在低溫（例如90〜550¾之範圍）下予K燒成， 製得各種金屬膜。故即使在一般各種具低軟化點的低價 基板上，K工業上簡便的方法與裝置，連續且低價製造 各種金屬或合金之金屬膜。 另外，由於在低溫下燒成，金屬之表面比在高溫下燒 成時不易氧化，可得導電性髙的金屬膜。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 換言之，使用低成本的有機或無機金屬化合物，可在 低溫下燒成，故製造金屬膜之設備費用低，同時可在一 般低價的低熔點基板上形成金屬膜。例如，目前銀、鈀 之金靥膜係在950"C之高溫下形成，惟於本發明中約在 32〇υ下燒成，即可在玻璃基板上形成均匀的銀、鈀之 合金膜。 -29- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐）Order I Printed by A7 B7, Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (20 cases use 6.13 times of amine compound for 1 mole of metal. Example 30 is 0.80g (4.79 millimoles) ) Add 0.273 g (1.22 mmol) of palladium acetate powder to the crystal of silver acetate and mix with M, then add 0.30 g (2.58 mmol) of 2-methyl-1,5-diaminoheptane, 0.30 (2.48 mmol) 1-phenylethylamine, 0.30 g (3.44 mmol) morpholine and stir. Then, add 0.30 g (2.30 mmol) of heptanoic acid and knead it with M to obtain brown. Transparent magma. Apply it on a substrate such as glass, heat up to 29〇υ and bake it for 15 minutes to prepare a mirror-shaped metal film. KK line diffraction measurement, as shown in Figure 1 (a) ~ (C) It can be seen that the position peak of silver alone and the position peak of palladium alone are absent. In addition, one peak is generated between the peak positions of silver alone and palladium alone. Moreover, (a) of Fig. 1 shows X In the line diffraction picture, Fig. 1 (b) shows the peak data of Fig. 1 (a), and Fig. 1 (c) shows the peak data (graphic data) of silver and palladium alone. It can be seen that an alloy of silver and palladium can be formed at a temperature much lower than the melting point of each metal at 290 ¾. Moreover, in this example, an amine-based compound of 1.41 times is used for 1 mole of metal. Example 31 4.02 millimolar) nickel acetate tetrahydrate (Ni (0CCH3) 2 • 4H2 0) crystals were added 0.70g (7.94 millimolar) N-methyl-1,3-diaminopropane, 0.1 g (1.33 millimolar) 1-amino-2-propanol (NH2 CH2 CH (CH3) 0H) and stirred to make a blue transparent slime. Then add 0.40g methyl isobutyl ketone and 0.80g Isobutyric acid and agitated to make a transparent maggot. It is coated on a substrate such as glass. It is applicable to -26- this paper size, "B family standard (CNS) A4 specification (210 × 297 mm) I ------ install ------ order ---- V (Please read the precautions on the back before filling this page) A 7 B7 V. Description of the invention (25) The temperature in the reducing atmosphere is raised to 300 ¾ It was calcined by M to obtain a nickel film. In this example, an amine compound of 2.31 times was used for 1 mole of gold tincture. Example 32 Dimerization of molybdenum acetate at 1.00 g (2.34 mmol) Of the substance ([(CH3COO) 2 Μο] 2) 1.30g (14.74 millimoles) of N-methyl 1,3-diaminopropane and 0.55g (7.32 millimoles) of 1-amino-2-propanol added to Zhongjia people and stirred to make a brown transparent liquid Then, 0.30 g of isoamyl ketone and 1.80 g of isobutyric acid were added thereto, and the mixture was stirred to obtain a transparent paste. This was coated on a substrate such as glass, and the temperature was raised to 350 in a reducing atmosphere, followed by firing at M to obtain a molybdenum film. Further, in this example, an amine compound was used in an amount of 4.72 times for 1 mole of metal. Example 33 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) at 1.00g (4.31 mmol) of manganese acetate dihydrate (Mn (OOCCH3) 3 0E2H2 0) Add 0.70g (7.94 millimoles) of N-methyl-1,3-diaminopropane and 0.40g (5.33 millimoles) of 1-amino-2-propanol to the crystals and stir them to make them dark. Brown transparent mucus. Then, 0.30 g of 2,4-dimethyl-4-heptanol and 1.10 g of isobutyric acid were added thereto, and the mixture was stirred to obtain a transparent mash. This was coated on a substrate such as glass, and the temperature was raised to 370 ¾ in a reducing atmosphere, followed by firing at M to obtain a rubidium film. Furthermore, in this example, 3.08 times the amine-based compound was used for 1 mole of metal. Example 34 To a crystal of 1.00 g (4.56 mmol) of zinc acetate dihydrate (Zn (00CCH3) 2 • 2H2 0) was added 0.50 g (5.67 mmol) of N-methyl-1,3-- 27- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (26) Diaminopropane, 0.50g (6.66 mmoles) > 1-amino-2-propane The alcohol was stirred with M to form a colorless transparent mucus. Then 0.30 g of ethylene glycol dimethyl and 1.00 g of 3-cyclohexylpropionic acid (C6 HiiCH2 CH2 COOH) were added and stirred to make a transparent material. It was coated on a substrate such as glass, heated to 300t in a reducing atmosphere, and calcined to produce a nickel film. In this example, 2.7 was used for 1 mole of metal. 0 times of amine-based compound. Example 35 0.85 g (9.64 mmol) of N-methyl was added to the crystals of 1.00 g (1.66 mmol) of chromium acetate ((CH3 C00) 7 Cr3 (0H) 2). -1,3-diaminopropane, 0,50g (6.66 millimolar) of 1-amino-2-propanol, and agitated with M to form a green transparent liquid. It was made to pass through the white light bulb and purple, and transmitted through fluorescent light. The lamp is black and gray. Add 0.30g2- Heptanone and 1.30 g of isobutyric acid were stirred to make a transparent descent. It was coated on a substrate such as glass, heated to 340 t in a reducing atmosphere, and fired at M to produce powdered chromium. Moreover, in this example, an amine compound of 3.27 times is used for 1 mole of metal. Example 36 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) To a crystal of 1.00 g (5.75 mmol) of iron acetate anhydrous (Fe (00CCG3) 2) was added 0.60 g (6.80 mmol) of N-methyl-1,3-diaminopropane, 0.50 g (6.66 mmol) 1-amino-2-propanol and stir to make a brown transparent mucus. Then add 0.30 g of ethylene glycol dimethyl ether and 1.10 g of isobutyric acid and stir to make it transparent. It is coated on a substrate such as glass, heated to 350 * 0 in the EBARA atmosphere, and fired to produce a 2 8 _ This paper size applies Chinese National Standard (CNS) Α4 wash grid (210 × 297 (Mm) A7, B7 V. Description of the invention (27) The iron film is obtained. Moreover, for 1 mole of metal, 2.34 times the amine compound is used. Gold of the present invention Reeds, which are characterized by being solid at normal temperature, are organic or inorganic metal compounds belonging to metals of Groups 3 to 15 of the periodic table, which are compounded as an amine-based compound, and can be coated with sticky descent. Therefore, there is no need to use special compounds and synthetic methods, and only general low-cost amine compounds are added to general low-cost solid organic or inorganic metal compounds, and the organic or inorganic metal compounds are directly made by the so-called simple method of stirring. Easily paste. In addition, the metal paste of the present invention can be fired with K at a low temperature (for example, in a range of 90 to 550¾) to obtain various metal films. Therefore, even on a variety of low-cost substrates with a low softening point in general, K-industry's simple methods and devices can continuously and inexpensively produce metal films of various metals or alloys. In addition, since the surface of the metal is sintered at a low temperature, the surface of the metal is less likely to be oxidized than when sintered at a high temperature, and a conductive metal film can be obtained. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). In other words, the use of low-cost organic or inorganic metal compounds can be fired at low temperatures, so the cost of equipment for manufacturing metal films is low. At the same time, a metal film can be formed on a generally low-priced low-melting-point substrate. For example, the current silver and palladium gold rhenium films are formed at a high temperature of 950 " C, but in the present invention, firing at about 320 ° C can form a uniform silver and palladium alloy film on a glass substrate. -29- This paper size applies to China National Standard (CNS) Α4 specification (210X 297 mm)