TW202239906A - Adhesive agent layer-equipped film - Google Patents

Adhesive agent layer-equipped film Download PDF

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TW202239906A
TW202239906A TW111101233A TW111101233A TW202239906A TW 202239906 A TW202239906 A TW 202239906A TW 111101233 A TW111101233 A TW 111101233A TW 111101233 A TW111101233 A TW 111101233A TW 202239906 A TW202239906 A TW 202239906A
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weight
cation
adhesive layer
layer
polyol
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森本有
中田美恵
半田至
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日商日東電工股份有限公司
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

Provided is a separatorless adhesive agent layer-equipped film in which a polyethylene-based film is not used as a substrate layer, wherein separatorless winding and unwinding are possible, contamination of the surface of an adherend can be suppressed, adhesive deposits during processing do not readily occur, and printing adhesion is excellent. An adhesive agent layer-equipped film according to an embodiment of the present invention has a substrate layer and an adhesive agent layer, wherein there is no separator on the side of the adhesive agent layer that is reverse of the substrate layer, there is no release layer on the side of the substrate layer that is reverse of the adhesive agent layer, the substrate layer includes a polyester-based resin, the adhesive agent layer is a urethane-based adhesive agent layer configured from a urethane-based adhesive agent, and the thickness of the adhesive agent layer is 1.0-6.0 [mu]m.

Description

附黏著劑層之膜film with adhesive layer

本發明係關於一種附黏著劑層之膜。The invention relates to a film with an adhesive layer.

於光學構件或電子構件之製造步驟中，貼附有表面保護膜(SPV)，用以防止在加工、組裝、檢查、輸送等時構件表面產生損傷。In the manufacturing steps of optical components or electronic components, a surface protection film (SPV) is attached to prevent damage to the surface of the component during processing, assembly, inspection, transportation, etc.

作為表面保護膜，先前報告有許多代表性而言依次具有基材層、黏著劑層及隔離件之表面保護膜。例如，報告有一種附隔離件之表面保護膜，其不會污染被黏著體之表面，且，即便於總厚度變薄之情形時，亦不易因外力而變形(專利文獻1)。As a surface protection film, many surface protection films representatively having a substrate layer, an adhesive layer, and a spacer in this order have been reported previously. For example, it is reported that there is a surface protection film with a spacer that does not contaminate the surface of the adherend and is not easily deformed by external force even when the total thickness is thinned (Patent Document 1).

另一方面，作為光學構件或電子構件之製造步驟中所使用之表面保護膜，出於削減隔離件之成本等理由，最近，要求一種在黏著劑層表面側不具有隔離件之(無隔離件)表面保護膜。作為此種無隔離件表面保護膜，報告有一種積層有聚乙烯系膜及黏著劑層之表面保護膜(專利文獻2)。該表面保護膜可藉由擠出成型而製造，可藉由對聚乙烯系膜之背面實施壓紋加工而於無隔離件之狀態下進行捲取及捲出，可以捲繞體之形式提供。On the other hand, as a surface protection film used in the manufacturing process of optical components or electronic components, for the reasons of reducing the cost of the spacer, etc., recently, there is a demand for a film that does not have a spacer on the surface side of the adhesive layer (spacer-free film). ) surface protective film. As such a spacer-free surface protection film, a surface protection film in which a polyethylene film and an adhesive layer are laminated is reported (Patent Document 2). The surface protection film can be produced by extrusion molding, and can be rolled up and unwound without a separator by embossing the back side of the polyethylene film, and can be provided in the form of a roll.

然而，存在如下問題，即，聚乙烯系膜中容易包含樹脂未完全熔融之塊(魚眼)。又，存在如下問題，即，由於對聚乙烯系膜之背面實施壓紋加工，故而貼合時會於光學構件或電子構件產生凹痕等。However, there is a problem that the polyethylene-based film tends to include lumps (fish eyes) where the resin is not completely melted. In addition, there is a problem that, since the back surface of the polyethylene film is embossed, dents or the like are generated in the optical member or the electronic member at the time of bonding.

又，關於無隔離件之表面保護膜，為了於無隔離件之狀態下順利地進行捲取及捲出，先前，多數情況下於基材層之與黏著劑層相反一側之最外表面設置有離型層。因此，離型層中所含之各種成分會移行至黏著劑層，於將表面保護膜貼附於被黏著體之情形時，存在污染被黏著體之表面之問題。In addition, for the surface protection film without a spacer, in order to smoothly carry out winding and unwinding without a spacer, conventionally, in many cases, it is provided on the outermost surface of the base material layer opposite to the adhesive layer. There is a release layer. Therefore, various components contained in the release layer migrate to the adhesive layer, and when the surface protection film is attached to the adherend, there is a problem of contaminating the surface of the adherend.

進而，作為先前之表面保護膜所產生之問題，存在如下問題：加工時產生糊劑殘渣；或對表面保護膜之列印密接性較低。 先前技術文獻 專利文獻 Furthermore, as the problems caused by the conventional surface protection film, there are the following problems: generation of paste residue during processing, or low printing adhesion to the surface protection film. prior art literature patent documents

專利文獻1：日本專利特開2017-31278號公報 專利文獻2：日本專利特開平06-033022號公報 Patent Document 1: Japanese Patent Laid-Open No. 2017-31278 Patent Document 2: Japanese Patent Application Laid-Open No. 06-033022

[發明所欲解決之問題][Problem to be solved by the invention]

本發明之課題在於提供一種無隔離件之附黏著劑層之膜，其係不使用聚乙烯系膜作為基材層之附黏著劑層之膜，可於無隔離件之狀態下進行捲取及捲出，可抑制被黏著體之表面之污染，加工時不易產生糊劑殘渣，且列印密接性優異。 [解決問題之技術手段] The object of the present invention is to provide a film with an adhesive layer without a separator, which is a film with an adhesive layer that does not use a polyethylene film as a base layer, and can be wound up without a separator. Rolling out can suppress the contamination of the surface of the adherend, it is not easy to produce paste residue during processing, and it has excellent printing adhesion. [Technical means to solve the problem]

本發明之實施方式之附黏著劑層之膜， 其係具有基材層及黏著劑層者， 該黏著劑層之與該基材層相反一側不具有隔離件， 該基材層之與該黏著劑層相反一側不具有離型層， 該基材層包含聚酯系樹脂， 該黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層，且 該黏著劑層之厚度為1.0 μm～6.0 μm。 A film with an adhesive layer according to an embodiment of the present invention, It has a substrate layer and an adhesive layer, The side of the adhesive layer opposite to the substrate layer does not have a spacer, The opposite side of the substrate layer to the adhesive layer does not have a release layer, The substrate layer contains a polyester resin, The adhesive layer is a urethane-based adhesive layer comprising a urethane-based adhesive, and The thickness of the adhesive layer is 1.0 μm˜6.0 μm.

於一個實施方式中，於溫度23℃、濕度50%RH下，以剝離速度0.3 m/分鐘、剝離角度180度所測得的上述黏著劑層對基材層之與該黏著劑層相反一側之面之低速剝離力為0.01 N/25 mm以上。In one embodiment, at a temperature of 23°C and a humidity of 50%RH, the above-mentioned adhesive layer is measured at a peeling speed of 0.3 m/min and a peeling angle of 180 degrees on the side opposite to the adhesive layer. The low-speed peeling force of the surface is above 0.01 N/25 mm.

於一個實施方式中，於溫度23℃、濕度50%RH下，以剝離速度10 m/分鐘、剝離角度180度所測得的上述黏著劑層對基材層之與該黏著劑層相反一側之面之高速剝離力為0.10 N/25 mm以下。In one embodiment, at a temperature of 23°C and a humidity of 50%RH, the above-mentioned adhesive layer is measured at a peeling speed of 10 m/min and a peeling angle of 180 degrees on the side opposite to the adhesive layer. The high-speed peel force of the surface is below 0.10 N/25 mm.

於一個實施方式中，上述胺基甲酸酯系黏著劑由胺基甲酸酯系黏著劑組合物形成，且該胺基甲酸酯系黏著劑組合物含有多元醇(A1)及多官能異氰酸酯化合物(B)。In one embodiment, the above-mentioned urethane-based adhesive is formed from a urethane-based adhesive composition, and the urethane-based adhesive composition contains polyol (A1) and polyfunctional isocyanate Compound (B).

於一個實施方式中，上述多元醇(A1)包含數量平均分子量Mn為400～20000之多元醇。In one embodiment, the above polyol (A1) includes a polyol having a number average molecular weight Mn of 400 to 20,000.

於一個實施方式中，上述多官能異氰酸酯化合物(B)相對於上述多元醇(A1)之含有比率為5重量%～60重量%。 [發明之效果] In one embodiment, the content rate of the said polyfunctional isocyanate compound (B) with respect to the said polyol (A1) is 5 weight% - 60 weight%. [Effect of Invention]

根據本發明，可提供一種無隔離件之附黏著劑層之膜，其係不使用聚乙烯系膜作為基材層之附黏著劑層之膜，可於無隔離件之狀態下進行捲取及捲出，可抑制被黏著體之表面之污染，加工時不易產生糊劑殘渣，且列印密接性優異。According to the present invention, it is possible to provide a film with an adhesive layer without a separator, which is a film without a polyethylene film as a film with an adhesive layer on the base layer, and can be wound and rolled without a separator. Rolling out can suppress the contamination of the surface of the adherend, it is not easy to produce paste residue during processing, and it has excellent printing adhesion.

於本說明書中，於表現為「重量」之情形時，作為表示重量之SI系單位(International System of Units，國際單位製)，亦可改稱為慣用之「質量」。In this manual, when expressed as "weight", the SI unit (International System of Units, International System of Units) expressing weight may also be referred to as the customary "mass".

於本說明書中，於表現為「(甲基)丙烯酸」之情形時，意指「丙烯酸及/或甲基丙烯酸」，於表現為「(甲基)丙烯酸酯」之情形時，意指「丙烯酸酯及/或甲基丙烯酸酯」，於表現為「(甲基)烯丙基」之情形時，意指「烯丙基及/或甲基烯丙基」，於表現為「(甲基)丙烯醛」之情形時，意指「丙烯醛及/或甲基丙烯醛」。In this specification, when expressed as "(meth)acrylic acid", it means "acrylic acid and/or methacrylic acid", when expressed as "(meth)acrylate", it means "acrylic acid "ester and/or methacrylate", when expressed as "(meth)allyl", means "allyl and/or methallyl", when expressed as "(meth)allyl" In the case of "acrolein", it means "acrolein and/or methacrolein".

《《1.附黏著劑層之膜》》 本發明之實施方式之附黏著劑層之膜係具有基材層及黏著劑層者，該黏著劑層之與該基材層相反一側不具有隔離件，該基材層之與該黏著劑層相反一側不具有離型層。代表性而言，本發明之實施方式之附黏著劑層之膜係具有基材層及黏著劑層者，且該基材層及該黏著劑層分別為最外層。 "1. Film with Adhesive Layer" The film with the adhesive layer according to the embodiment of the present invention has a substrate layer and an adhesive layer, the side of the adhesive layer opposite to the substrate layer does not have a spacer, and the substrate layer and the adhesive The side opposite the layer does not have a release layer. Typically, the film with the adhesive layer according to the embodiment of the present invention has a base material layer and an adhesive layer, and the base material layer and the adhesive layer are respectively the outermost layers.

由於本發明之實施方式之附黏著劑層之膜在黏著劑層之與基材層相反一側不具有隔離件，故而可削減隔離件之成本，且可省略隔離件剝離步驟。Since the adhesive layer-attached film according to the embodiment of the present invention does not have a spacer on the side of the adhesive layer opposite to the substrate layer, the cost of the spacer can be reduced, and the spacer peeling step can be omitted.

由於本發明之實施方式之附黏著劑層之膜在基材層之與黏著劑層相反一側不具有離型層，故而可避免離型層中所含之各種成分向黏著劑層移行，於將表面保護膜貼附於被黏著體之情形時，可抑制污染被黏著體之表面之問題。Since the film with the adhesive layer of the embodiment of the present invention does not have a release layer on the opposite side of the base material layer from the adhesive layer, it can prevent the various components contained in the release layer from migrating to the adhesive layer. When the surface protective film is attached to an adherend, it is possible to suppress the problem of contamination of the surface of the adherend.

只要本發明之實施方式之附黏著劑層之膜為具有基材層及黏著劑層者，則亦可於不損害本發明之效果之範圍內具有任意適當之其他層。As long as the adhesive layer-attached film according to the embodiment of the present invention has a base material layer and an adhesive layer, it may have any other appropriate layer within the range that does not impair the effects of the present invention.

如圖1所示，本發明之附黏著劑層之膜100之一個實施方式係基材層10與黏著劑層20直接積層而成之膜。As shown in FIG. 1 , one embodiment of the adhesive layer-attached film 100 of the present invention is a film in which the substrate layer 10 and the adhesive layer 20 are directly laminated.

本發明之實施方式之附黏著劑層之膜可用於各種用途。代表性而言，可例舉：在光學構件或電子構件(例如液晶顯示器等所使用之玻璃、偏光板、波片、相位差板、光學補償膜、反射板、增亮膜、透明導電性膜等)之製造步驟中，保護表面以防止在加工、組裝、檢查、輸送等時構件表面產生損傷之表面保護膜或載片等。The adhesive layer-attached film according to the embodiment of the present invention can be used for various purposes. Typical examples include: glass used in optical components or electronic components (such as liquid crystal displays, etc.), polarizers, wave plates, retardation plates, optical compensation films, reflectors, brightness enhancement films, transparent conductive films etc.) to protect the surface to prevent damage to the component surface during processing, assembly, inspection, transportation, etc.)

作為本發明之實施方式之附黏著劑層之膜之形態，可於不損害本發明之效果之範圍內採用任意適當之形態。作為此種形態，例如可例舉：捲繞體(亦稱為卷體)、單片體等。As the form of the film to which the adhesive layer is attached according to the embodiment of the present invention, any appropriate form can be adopted within the range that does not impair the effects of the present invention. As such a form, a wound body (it is also called a roll body), a single sheet body, etc. are mentioned, for example.

於本發明之實施方式之附黏著劑層之膜中，基材層包含聚酯系樹脂。藉由基材層包含聚酯系樹脂，能夠更加表現本發明之效果，特別是可消除先前使用聚乙烯系膜作為基材層之情形時之問題點。In the film with an adhesive layer according to the embodiment of the present invention, the base material layer contains a polyester-based resin. When the base material layer contains the polyester resin, the effect of the present invention can be further exhibited, and in particular, problems in the conventional case of using a polyethylene film as the base material layer can be eliminated.

於本發明之實施方式之附黏著劑層之膜中，黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層。藉由黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層，能夠更加表現本發明之效果，特別是可抑制加工時產生糊劑殘渣之問題。In the film with an adhesive layer according to the embodiment of the present invention, the adhesive layer is a urethane-based adhesive layer containing a urethane-based adhesive. When the adhesive layer is a urethane-based adhesive layer containing a urethane-based adhesive, the effects of the present invention can be further exhibited, and in particular, the generation of paste residue during processing can be suppressed.

於本發明之實施方式之附黏著劑層之膜中，黏著劑層之厚度可調整至1.0 μm～6.0 μm之範圍內。黏著劑層之厚度較佳為1.0 μm～5.5 μm，更佳為1.0 μm～5.0 μm，進而較佳為1.0 μm～4.5 μm，尤佳為1.5 μm～4.0 μm，最佳為1.5 μm～3.5 μm。藉由將黏著劑層之厚度調整至上述範圍內，能夠更加表現本發明之效果。若黏著劑層之厚度超出上述範圍過大，則有低速剝離力或高速剝離力變得過高之虞，特別是由於高速剝離力變得過高，而有產生在實際使用中在非期望之部位發生剝離等問題之虞。In the film with the adhesive layer according to the embodiment of the present invention, the thickness of the adhesive layer can be adjusted within the range of 1.0 μm to 6.0 μm. The thickness of the adhesive layer is preferably 1.0 μm to 5.5 μm, more preferably 1.0 μm to 5.0 μm, further preferably 1.0 μm to 4.5 μm, especially preferably 1.5 μm to 4.0 μm, most preferably 1.5 μm to 3.5 μm . By adjusting the thickness of the adhesive layer within the above-mentioned range, the effects of the present invention can be further expressed. If the thickness of the adhesive layer is too large beyond the above range, there is a possibility that the low-speed peeling force or the high-speed peeling force will become too high, especially because the high-speed peeling force becomes too high, and there will be undesired parts in actual use. There is a risk of problems such as peeling.

本發明之實施方式之附黏著劑層之膜於溫度23℃、濕度50%RH下，以剝離速度0.3 m/分鐘、剝離角度180度所測得的該黏著劑層對基材層之與黏著劑層相反一側之面之低速剝離力較佳為0.01 N/25 mm以上，更佳為0.01 N/25 mm～0.15 N/25 mm，進而較佳為0.01 N/25 mm～0.10 N/25 mm，尤佳為0.01 N/25 mm～0.05 N/25 mm。於上述低速剝離力未達0.01 N/25 mm之情形時，例如有如下之虞：當為了製成捲繞體而進行捲取時或在進行捲取之捲繞體之狀態下，黏著劑層對基材層之密接性變低，無法順利地進行捲取；或無法維持捲繞體之形狀。若上述低速剝離力處於上述範圍內，則可成為在無隔離件之狀態下捲取性良好者。上述低速剝離力之測定方法之詳情如下所述。Adhesion of the film with the adhesive layer according to the embodiment of the present invention to the substrate layer measured at a peeling speed of 0.3 m/min and a peeling angle of 180 degrees at a temperature of 23°C and a humidity of 50%RH The low-speed peeling force of the side opposite to the agent layer is preferably at least 0.01 N/25 mm, more preferably 0.01 N/25 mm to 0.15 N/25 mm, and more preferably 0.01 N/25 mm to 0.10 N/25 mm, preferably 0.01 N/25 mm to 0.05 N/25 mm. In the case where the above-mentioned low-speed peeling force is less than 0.01 N/25 mm, for example, there is a risk that the adhesive layer will Adhesion to the base material layer becomes low, and winding cannot be performed smoothly; or the shape of the wound body cannot be maintained. When the said low-speed peeling force exists in the said range, it can become a thing with favorable winding property in the state without a separator. The details of the method for measuring the above-mentioned low-speed peeling force are as follows.

本發明之實施方式之附黏著劑層之膜於溫度23℃、濕度50%RH下，以剝離速度10 m/分鐘、剝離角度180度所測得的該黏著劑層對基材層之與黏著劑層相反一側之面之高速剝離力較佳為0.10 N/25 mm以下，更佳為0.01 N/25 mm～0.10 N/25 mm，進而較佳為0.02 N/25 mm～0.10 N/25 mm，尤佳為0.03 N/25 mm～0.10 N/25 mm。若上述高速剝離力超過0.10 N/25 mm，則例如於附黏著劑層之膜自捲繞體之狀態捲出之情形時，有成為重剝離，無法順利捲出之虞。若上述高速剝離力處於上述範圍內，則可成為在無隔離件之狀態下捲出性良好者。上述高速剝離力之測定方法之詳情如下所述。Adhesion of the adhesive layer to the substrate layer measured at a peeling speed of 10 m/min and a peeling angle of 180 degrees at a temperature of 23°C and a humidity of 50%RH for a film with an adhesive layer according to an embodiment of the present invention The high-speed peel force of the surface opposite to the agent layer is preferably 0.10 N/25 mm or less, more preferably 0.01 N/25 mm to 0.10 N/25 mm, and more preferably 0.02 N/25 mm to 0.10 N/25 mm, preferably 0.03 N/25 mm to 0.10 N/25 mm. If the above-mentioned high-speed peeling force exceeds 0.10 N/25 mm, for example, when the film with the adhesive layer is unwound from the state of the winding body, heavy peeling may occur and smooth unwinding may not be possible. When the said high-speed peeling force exists in the said range, it can become a thing with favorable unwinding property in the state without a separator. The details of the method for measuring the above-mentioned high-speed peel force are as follows.

關於本發明之實施方式之附黏著劑層之膜，上述低速剝離力與上述高速剝離力較佳為低速剝離力≦高速剝離力之關係。若為此種關係，則能夠表現在無隔離件之狀態下更加優異之捲取性及更加優異之捲出性。Regarding the film with an adhesive layer according to the embodiment of the present invention, the above-mentioned low-speed peeling force and the above-mentioned high-speed peeling force are preferably in the relationship of low-speed peeling force≦high-speed peeling force. If there is such a relationship, it is possible to express more excellent winding properties and further excellent unwinding properties in a state without a spacer.

本發明之實施方式之附黏著劑層之膜之總厚度較佳為20 μm～100 μm，更佳為25 μm～80 μm，進而較佳為30 μm～60 μm。若本發明之實施方式之附黏著劑層之膜之總厚度處於上述範圍內，則能夠更加表現本發明之效果。The total thickness of the film with the adhesive layer in the embodiment of the present invention is preferably from 20 μm to 100 μm, more preferably from 25 μm to 80 μm, and still more preferably from 30 μm to 60 μm. If the total thickness of the adhesive layer-attached film according to the embodiment of the present invention is within the above range, the effects of the present invention can be further expressed.

本發明之實施方式之附黏著劑層之膜之全光線透過率較佳為60%以上，更佳為70%～100%，進而較佳為80%～100%，尤佳為83%～100%，最佳為85%～100%。The total light transmittance of the film with the adhesive layer according to the embodiment of the present invention is preferably 60% or more, more preferably 70% to 100%, further preferably 80% to 100%, especially preferably 83% to 100% %, the best is 85% to 100%.

本發明之實施方式之附黏著劑層之膜之霧度較佳為15%以下，更佳為0%～10%，進而較佳為0%～8%，尤佳為0%～7%，最佳為0%～6%。The haze of the film with the adhesive layer according to the embodiment of the present invention is preferably 15% or less, more preferably 0% to 10%, still more preferably 0% to 8%, especially preferably 0% to 7%, The best is 0% to 6%.

《1-1.基材層》 就能夠表現本發明之效果之方面而言，基材層包含聚酯系樹脂。 《1-1. Substrate layer》 The base material layer contains a polyester resin at the point which can express the effect of this invention.

基材層中之聚酯系樹脂之含有比率較佳為超過50重量%且為100重量%以下，更佳為70重量%～100重量%，進而較佳為90重量%～100重量%，尤佳為95重量%～100重量%，最佳為98重量%～100重量%。若基材層中之聚酯系樹脂之含有比率處於上述範圍內，則能夠更加表現本發明之效果。The content ratio of the polyester resin in the substrate layer is preferably more than 50% by weight and not more than 100% by weight, more preferably 70% by weight to 100% by weight, further preferably 90% by weight to 100% by weight, especially Preferably, it is 95% by weight to 100% by weight, most preferably, it is 98% by weight to 100% by weight. If the content ratio of the polyester resin in a base material layer exists in the said range, the effect of this invention can be expressed more.

作為聚酯系樹脂，可於不損害本發明之效果之範圍內採用任意適當之聚酯系樹脂。作為此種聚酯系樹脂，就能夠更加表現本發明之效果之方面而言，較佳為選自由聚對苯二甲酸乙二酯(PET)、聚萘二甲酸乙二酯(PEN)、聚對苯二甲酸丁二酯(PBT)所組成之群中之至少1種，更佳為聚對苯二甲酸乙二酯(PET)。As the polyester-based resin, any appropriate polyester-based resin can be employed within the range not impairing the effect of the present invention. Such a polyester resin is preferably selected from polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyethylene At least one of the group consisting of butylene terephthalate (PBT), more preferably polyethylene terephthalate (PET).

作為基材層之厚度，就能夠更加表現本發明之效果之方面而言，較佳為1 μm～300 μm，更佳為5 μm～200 μm，進而較佳為10 μm～150 μm，尤佳為20 μm～100 μm，最佳為30 μm～80 μm。The thickness of the substrate layer is preferably 1 μm to 300 μm, more preferably 5 μm to 200 μm, further preferably 10 μm to 150 μm, and especially preferably 20 μm to 100 μm, most preferably 30 μm to 80 μm.

基材層可僅為1層，亦可為2層以上。The base material layer may be only one layer, or may be two or more layers.

基材層亦可經延伸。The substrate layer may also be extended.

基材層亦可實施表面處理。作為表面處理，例如可例舉：電暈處理、電漿處理、鉻酸處理、臭氧暴露、火焰暴露、高壓電擊暴露、離子化輻射處理、利用底塗劑所進行之塗佈處理等。The substrate layer may also be surface treated. Examples of surface treatment include corona treatment, plasma treatment, chromic acid treatment, ozone exposure, flame exposure, high-voltage electric shock exposure, ionizing radiation treatment, coating treatment with a primer, and the like.

亦可於基材層中，於不損害本發明之效果之範圍內包含任意適當之添加劑。作為此種添加劑，例如可例舉：抗靜電劑、著色劑、顏料等粉體、界面活性劑、塑化劑、黏著賦予劑、低分子量聚合物、表面潤滑劑、整平劑、抗氧化劑、抗腐蝕劑、光穩定劑、紫外線吸收劑、聚合抑制劑、矽烷偶合劑、無機填充劑、有機填充劑、金屬粉、有機粒子、無機粒子等。Arbitrary appropriate additives may also be contained in the base material layer within the range which does not impair the effect of this invention. Such additives include, for example, antistatic agents, powders such as colorants and pigments, surfactants, plasticizers, adhesion imparting agents, low molecular weight polymers, surface lubricants, leveling agents, antioxidants, Anticorrosion agent, light stabilizer, ultraviolet absorber, polymerization inhibitor, silane coupling agent, inorganic filler, organic filler, metal powder, organic particles, inorganic particles, etc.

《1-2.黏著劑層》 黏著劑層可僅為1層，亦可為2層以上。 《1-2. Adhesive layer》 The adhesive layer may be only one layer, or may be two or more layers.

關於黏著劑層之厚度，如上所述，黏著劑層之厚度可調整至1.0 μm～6.0 μm之範圍內。黏著劑層之厚度較佳為1.0 μm～5.5 μm，更佳為1.0 μm～5.0 μm，進而較佳為1.0 μm～4.5 μm，尤佳為1.5 μm～4.0 μm，最佳為1.5 μm～3.5 μm。藉由將黏著劑層之厚度調整至上述範圍內，能夠更加表現本發明之效果。如上所述，若黏著劑層之厚度超出上述範圍過大，則有低速剝離力或高速剝離力變得過高之虞，特別是由於高速剝離力變得過高，而有產生在實際使用中在非期望之部位發生剝離等問題之虞。Regarding the thickness of the adhesive layer, as described above, the thickness of the adhesive layer can be adjusted within the range of 1.0 μm to 6.0 μm. The thickness of the adhesive layer is preferably 1.0 μm to 5.5 μm, more preferably 1.0 μm to 5.0 μm, further preferably 1.0 μm to 4.5 μm, especially preferably 1.5 μm to 4.0 μm, most preferably 1.5 μm to 3.5 μm . By adjusting the thickness of the adhesive layer within the above-mentioned range, the effects of the present invention can be further expressed. As mentioned above, if the thickness of the adhesive layer is too large beyond the above range, there is a possibility that the low-speed peeling force or the high-speed peeling force will become too high, especially because the high-speed peeling force becomes too high. There is a risk of problems such as detachment of undesired parts.

如上所述，黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層。藉由黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層，能夠更加表現本發明之效果，特別是可抑制加工時產生糊劑殘渣之問題。As described above, the adhesive layer is a urethane-based adhesive layer containing a urethane-based adhesive. When the adhesive layer is a urethane-based adhesive layer containing a urethane-based adhesive, the effects of the present invention can be further exhibited, and in particular, the generation of paste residue during processing can be suppressed.

胺基甲酸酯系黏著劑由胺基甲酸酯系黏著劑組合物形成。即，藉由由胺基甲酸酯系黏著劑組合物形成之胺基甲酸酯系黏著劑構成層形狀而成為黏著劑層。The urethane-based adhesive is formed from a urethane-based adhesive composition. That is, the layer shape is formed by the urethane-based adhesive formed from the urethane-based adhesive composition to form an adhesive layer.

胺基甲酸酯系黏著劑可規定為：由胺基甲酸酯系黏著劑組合物形成者。由於胺基甲酸酯系黏著劑組合物藉由加熱或紫外線照射等引起交聯反應等而成為胺基甲酸酯系黏著劑，且由於無法藉由其結構而直接特定胺基甲酸酯系黏著劑，又，存在完全不實際之情況(「不可能、不實際之情況」)，故而藉由規定胺基甲酸酯系黏著劑為「由胺基甲酸酯系黏著劑組合物形成者」，而將胺基甲酸酯系黏著劑妥當地特定為「物」。The urethane-based adhesive can be defined as being formed from a urethane-based adhesive composition. Since the urethane-based adhesive composition becomes a urethane-based adhesive due to a cross-linking reaction caused by heating or ultraviolet radiation, and the urethane-based adhesive cannot be directly identified by its structure Adhesives, and there are completely unrealistic situations ("impossible, unrealistic situations"), so by specifying urethane-based adhesives as "formed from urethane-based adhesive compositions ", and the urethane-based adhesive is properly specified as a "thing".

胺基甲酸酯系黏著劑由胺基甲酸酯系黏著劑組合物形成。作為此種形成方法，可於不損害本發明之效果之範圍內採用任意適當之形成方法。作為此種形成方法，例如可採用先前通常已知之胺基甲酸酯系黏著劑之形成方法。作為此種形成方法，具體而言，例如可例舉如下方法：將胺基甲酸酯系黏著劑組合物直接賦予至任意適當之基材膜(例如本發明之實施方式之表面保護膜中之基材層)，使之乾燥或硬化(直接法)；將胺基甲酸酯系黏著劑組合物賦予至剝離襯墊之表面(剝離面)，使之乾燥或硬化，藉此將形成於該表面上之胺基甲酸酯系黏著劑層貼合於基材膜(例如本發明之實施方式之表面保護膜中之基材層)，轉印該胺基甲酸酯系黏著劑層(轉印法)。就黏著劑層之抓固性之觀點而言，代表性而言，可較佳採用直接法。關於該等形成方法中之各種條件，可採用先前通常已知之胺基甲酸酯系黏著劑之形成方法中之各種條件。The urethane-based adhesive is formed from a urethane-based adhesive composition. As such a forming method, any appropriate forming method can be adopted within the range not impairing the effect of the present invention. As such a forming method, for example, a conventionally known method of forming a urethane-based adhesive can be employed. As such a forming method, specifically, for example, a method in which a urethane-based adhesive composition is directly applied to any appropriate base film (such as that used in the surface protection film according to the embodiment of the present invention) may be mentioned. substrate layer) and let it dry or harden (direct method); apply the urethane-based adhesive composition to the surface (release surface) of the release liner and let it dry or harden, whereby the The urethane-based adhesive layer on the surface is bonded to the substrate film (such as the substrate layer in the surface protection film of the embodiment of the present invention), and the urethane-based adhesive layer is transferred (transfer printing method). From the viewpoint of the grip property of the adhesive layer, typically, the direct method can be preferably employed. Regarding the various conditions in these forming methods, various conditions in the forming methods of conventionally known urethane-based adhesives can be employed.

作為此種胺基甲酸酯系黏著劑層之賦予(代表性而言，塗佈)之方法，例如可適當地採用如下先前公知之各種方法：輥式塗佈法、凹版塗佈法、反向塗佈法、接觸塗佈法、浸漬輥塗佈法、棒式塗佈法、輥式刷塗法、噴塗法、刮塗法、氣刀塗佈法、噴塗法、缺角輪塗佈法、直接塗佈法、利用模嘴塗佈機之塗佈法等。As a method of imparting (typically, coating) such a urethane-based adhesive layer, for example, the following conventionally known methods can be suitably adopted: roll coating method, gravure coating method, reverse coating method, etc. Directional coating method, contact coating method, dip roll coating method, rod coating method, roller brush coating method, spray coating method, blade coating method, air knife coating method, spray coating method, chipping wheel coating method , direct coating method, coating method using die coating machine, etc.

胺基甲酸酯系黏著劑組合物之乾燥可視需要於加熱下(例如藉由加熱至60℃～150℃左右)進行。作為使胺基甲酸酯系黏著劑組合物硬化之方法，例如可適當地採用紫外線、雷射線、α射線、β射線、γ射線、X射線、電子束。Drying of the urethane-based adhesive composition may be performed under heating (for example, by heating to about 60° C. to 150° C.) if necessary. As a method of curing the urethane adhesive composition, for example, ultraviolet rays, laser rays, α rays, β rays, γ rays, X rays, and electron beams can be suitably used.

作為胺基甲酸酯系黏著劑之製造方法，存在如下2種製造方法：一步法，其於不使用胺基甲酸酯預聚物之情況下，使多元醇與多官能異氰酸酯化合物直接反應而製造胺基甲酸酯系黏著劑；預聚物法，其使胺基甲酸酯預聚物與多官能異氰酸酯化合物反應而製造胺基甲酸酯系黏著劑。此處，由於「胺基甲酸酯預聚物」可具有複數個羥基，故而為了與「多元醇」明確區別，於本發明之說明中之「多元醇(A1)」中不包含本發明之說明中之「胺基甲酸酯預聚物(A2)」。As the production method of urethane-based adhesives, there are two production methods as follows: one-step method, which directly reacts polyol and polyfunctional isocyanate compound without using urethane prepolymer. Manufacture of urethane-based adhesives; prepolymer method, which reacts urethane prepolymers with polyfunctional isocyanate compounds to produce urethane-based adhesives. Here, since "urethane prepolymer" may have a plurality of hydroxyl groups, in order to clearly distinguish it from "polyol", "polyol (A1)" in the description of the present invention does not include the "polyol (A1)" of the present invention. "Urethane prepolymer (A2)" in the description.

＜1-2-1.一步法所製造之胺基甲酸酯系黏著劑＞ 聚胺基甲酸酯系黏著劑之一個實施方式係使含有多元醇(A1)及多官能異氰酸酯化合物(B)之胺基甲酸酯系黏著劑組合物硬化所獲得之聚胺基甲酸酯系黏著劑。即，該形態中之胺基甲酸酯系黏著劑組合物含有多元醇(A1)及多官能異氰酸酯化合物(B)。 ＜1-2-1. Urethane-based adhesive manufactured by one-step method＞ One embodiment of the polyurethane-based adhesive is a polyurethane obtained by curing a urethane-based adhesive composition containing a polyol (A1) and a polyfunctional isocyanate compound (B). Department of adhesive. That is, the urethane adhesive composition in this aspect contains a polyol (A1) and a polyfunctional isocyanate compound (B).

該形態中之胺基甲酸酯系黏著劑組合物中之多元醇(A1)與多官能異氰酸酯化合物(B)之合計量之含有比率在去除溶劑後較佳為50重量%～100重量%，更佳為55重量%～95重量%，進而較佳為60重量%～90重量%，尤佳為65重量%～85重量%，最佳為70重量%～80重量%。The content ratio of the total amount of the polyol (A1) and the polyfunctional isocyanate compound (B) in the urethane-based adhesive composition in this form is preferably 50% by weight to 100% by weight after removing the solvent, It is more preferably 55% by weight to 95% by weight, further preferably 60% by weight to 90% by weight, particularly preferably 65% by weight to 85% by weight, most preferably 70% by weight to 80% by weight.

[1-2-1-a.多元醇(A1)] 多元醇(A1)可僅為1種，亦可為2種以上。 [1-2-1-a. Polyol (A1)] The polyol (A1) may be only 1 type, and may be 2 or more types.

作為多元醇(A1)，只要為具有2個以上之OH基之多元醇，可採用任意適當之多元醇。作為此種多元醇(A1)，例如可例舉：具有2個OH基之多元醇(二醇)、具有3個OH基之多元醇(三醇)、具有4個OH基之多元醇(四醇)、具有5個OH基之多元醇(五醇)、具有6個OH基之多元醇(六醇)。As the polyol (A1), any appropriate polyol can be adopted as long as it is a polyol having two or more OH groups. As such a polyol (A1), for example, a polyol (diol) having 2 OH groups, a polyol (triol) having 3 OH groups, a polyol (triol) having 4 OH groups (tetraol) Alcohols), polyols with 5 OH groups (pentols), polyols with 6 OH groups (hexaols).

於本發明中，作為多元醇(A1)，較佳採用具有3個OH基之多元醇(三醇)作為必須成分。作為多元醇(A1)，若採用具有3個OH基之多元醇(三醇)作為必須成分，則能夠更加表現本發明之效果。In the present invention, as the polyol (A1), a polyol (triol) having three OH groups is preferably used as an essential component. As the polyol (A1), if a polyol (triol) having three OH groups is used as an essential component, the effect of the present invention can be further expressed.

多元醇(A1)中之具有3個OH基之多元醇(三醇)之含有比率較佳為50重量%～100重量%，更佳為70重量%～100重量%，進而較佳為80重量%～100重量%，進而較佳為90重量%～100重量%，尤佳為95重量%～100重量%，最佳實質上為100重量%。The content ratio of the polyol (triol) having three OH groups in the polyol (A1) is preferably 50% by weight to 100% by weight, more preferably 70% by weight to 100% by weight, and still more preferably 80% by weight % to 100% by weight, more preferably 90% by weight to 100% by weight, particularly preferably 95% by weight to 100% by weight, most preferably substantially 100% by weight.

作為多元醇(A1)，較佳包含數量平均分子量Mn為400～20000之多元醇。多元醇(A1)中之數量平均分子量Mn為400～20000之多元醇之含有比率較佳為50重量%～100重量%，更佳為70重量%～100重量%，進而較佳為90重量%～100重量%，尤佳為95重量%～100重量%，最佳實質上為100重量%。藉由將多元醇(A1)中之數量平均分子量Mn為400～20000之多元醇之含有比率調整至上述範圍內，能夠更加表現本發明之效果。As polyol (A1), it is preferable to contain the polyol whose number average molecular weight Mn is 400-20000. The content ratio of the polyol (A1) having a number average molecular weight Mn of 400 to 20,000 is preferably 50% by weight to 100% by weight, more preferably 70% by weight to 100% by weight, further preferably 90% by weight ~100% by weight, especially preferably 95% by weight to 100% by weight, most preferably substantially 100% by weight. The effect of this invention can be expressed more by adjusting the content ratio of the polyol whose number average molecular weight Mn in a polyol (A1) is 400-20000 to the said range.

於本發明中，作為多元醇(A1)，於採用具有3個OH基之多元醇(三醇)作為必須成分之情形時，較佳併用數量平均分子量Mn為7000～20000之三醇、數量平均分子量Mn為2000～6000之三醇、及數量平均分子量Mn為400～1900之三醇，更佳併用數量平均分子量Mn為8000～15000之三醇、數量平均分子量Mn為2000～5000之三醇、及數量平均分子量Mn為500～1800之三醇，進而較佳併用數量平均分子量Mn為8000～12000之三醇、數量平均分子量Mn為2000～4000之三醇、及數量平均分子量Mn為500～1500之三醇。若併用該等3種三醇，則能夠更加表現本發明之效果。In the present invention, as the polyol (A1), when a polyol (triol) having three OH groups is used as an essential component, it is preferable to use a triol having a number average molecular weight Mn of 7,000 to 20,000 in combination. Triols with a molecular weight Mn of 2,000 to 6,000, and triols with a number average molecular weight Mn of 400 to 1,900, preferably in combination with triols with a number average molecular weight Mn of 8,000 to 15,000, triols with a number average molecular weight Mn of 2,000 to 5,000, and a triol with a number average molecular weight Mn of 500 to 1800, and preferably a triol with a number average molecular weight Mn of 8000 to 12000, a triol with a number average molecular weight Mn of 2000 to 4000, and a number average molecular weight Mn of 500 to 1500 Triol. When these three kinds of triols are used in combination, the effects of the present invention can be further expressed.

作為多元醇(A1)，例如可例舉：聚酯多元醇、聚醚多元醇、聚己內酯多元醇、聚碳酸酯多元醇、蓖麻油系多元醇。As polyol (A1), polyester polyol, polyether polyol, polycaprolactone polyol, polycarbonate polyol, castor oil type polyol are mentioned, for example.

作為聚酯多元醇，例如，可藉由多元醇成分與酸成分之酯化反應而獲得。As polyester polyol, it can obtain by esterification reaction of a polyol component and an acid component, for example.

作為多元醇成分，例如可例舉：乙二醇、二乙二醇、1,3-丁二醇、1,4-丁二醇、新戊二醇、3-甲基-1,5-戊二醇、2-丁基-2-乙基-1,3-丙二醇、2,4-二乙基-1,5-戊二醇、1,2-己二醇、1,6-己二醇、1,8-辛二醇、1,9-壬二醇、2-甲基-1,8-辛二醇、1,8-癸二醇、十八烷二醇、甘油、三羥甲基丙烷、季戊四醇、己三醇、聚丙二醇。Examples of polyhydric alcohol components include ethylene glycol, diethylene glycol, 1,3-butanediol, 1,4-butanediol, neopentyl glycol, and 3-methyl-1,5-pentane Diol, 2-butyl-2-ethyl-1,3-propanediol, 2,4-diethyl-1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol , 1,8-octanediol, 1,9-nonanediol, 2-methyl-1,8-octanediol, 1,8-decanediol, octadecanediol, glycerin, trimethylol Propane, pentaerythritol, hexanetriol, polypropylene glycol.

作為酸成分，例如可例舉：琥珀酸、甲基琥珀酸、己二酸、庚二酸、壬二酸、癸二酸、1,12-十二烷二酸、1,14-十四烷二酸、二聚酸、2-甲基-1,4-環己烷二羧酸、2-乙基-1,4-環己烷二羧酸、對苯二甲酸、間苯二甲酸、鄰苯二甲酸、間苯二甲酸、對苯二甲酸、1,4-萘二甲酸、4,4'-聯苯二羧酸、該等之酸酐。As the acid component, for example, succinic acid, methylsuccinic acid, adipic acid, pimelic acid, azelaic acid, sebacic acid, 1,12-dodecanedioic acid, 1,14-tetradecane Diacid, dimer acid, 2-methyl-1,4-cyclohexanedicarboxylic acid, 2-ethyl-1,4-cyclohexanedicarboxylic acid, terephthalic acid, isophthalic acid, ortho Phthalic acid, isophthalic acid, terephthalic acid, 1,4-naphthalene dicarboxylic acid, 4,4'-biphenyl dicarboxylic acid, and their anhydrides.

作為聚醚多元醇，例如可例舉：將水、低分子多元醇(丙二醇、乙二醇、甘油、三羥甲基丙烷、季戊四醇等)、雙酚類(雙酚A等)、二羥基苯(鄰苯二酚、兒茶酚、對苯二酚等)等作為起始劑並藉由使環氧乙烷、環氧丙烷、環氧丁烷等環氧烷加成聚合所獲得之聚醚多元醇。作為聚醚多元醇，具體而言，例如可例舉：聚乙二醇、聚丙二醇、聚四亞甲基二醇。Examples of polyether polyols include water, low-molecular-weight polyols (propylene glycol, ethylene glycol, glycerin, trimethylolpropane, pentaerythritol, etc.), bisphenols (bisphenol A, etc.), dihydroxybenzene (Catechol, catechol, hydroquinone, etc.) as an initiator and polyether obtained by addition polymerization of alkylene oxides such as ethylene oxide, propylene oxide, and butylene oxide Polyol. Specifically, as polyether polyol, polyethylene glycol, polypropylene glycol, polytetramethylene glycol may be mentioned, for example.

作為聚己內酯多元醇，例如可例舉：藉由ε-己內酯、σ-戊內酯等環狀酯單體之開環聚合所獲得之己內酯系聚酯二醇。Examples of the polycaprolactone polyol include caprolactone-based polyester diol obtained by ring-opening polymerization of cyclic ester monomers such as ε-caprolactone and σ-valerolactone.

作為聚碳酸酯多元醇，例如可例舉：使上述多元醇成分與光氣進行縮聚反應所獲得之聚碳酸酯多元醇；使上述多元醇成分與碳酸二甲酯、碳酸二乙酯、碳酸二丙酯、碳酸二異丙酯、碳酸二丁酯、碳酸乙基丁酯碳酸、碳酸乙二酯、碳酸丙二酯、碳酸二苯酯、碳酸二苄酯等碳酸二酯類進行酯交換縮合所獲得之聚碳酸酯多元醇；併用2種以上之上述多元醇成分所獲得之共聚合聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與含羧基之化合物進行酯化反應所獲得之聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與含羥基之化合物進行醚化反應所獲得之聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與酯化合物進行酯交換反應所獲得之聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與含羥基之化合物進行酯交換反應所獲得之聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與二羧氧化合物進行縮聚反應所獲得之聚酯系聚碳酸酯多元醇；使上述各種聚碳酸酯多元醇與環氧烷共聚合所獲得之共聚合聚醚系聚碳酸酯多元醇。Examples of polycarbonate polyols include: polycarbonate polyols obtained by polycondensing the above-mentioned polyol components with phosgene; mixing the above-mentioned polyol components with dimethyl carbonate, diethyl carbonate, Propyl, diisopropyl carbonate, dibutyl carbonate, ethyl butyl carbonate, ethylene carbonate, propylene carbonate, diphenyl carbonate, dibenzyl carbonate and other carbonate diesters for transesterification condensation Polycarbonate polyols obtained; copolymerized polycarbonate polyols obtained by using two or more of the above polyol components; polycarbonate polycarbonates obtained by esterifying the above polycarbonate polyols with carboxyl-containing compounds Ester polyols; polycarbonate polyols obtained by etherifying the above-mentioned polycarbonate polyols with hydroxyl-containing compounds; polycarbonate polyols obtained by transesterifying the above-mentioned polycarbonate polyols with ester compounds Ester polyols; polycarbonate polyols obtained by transesterifying the above-mentioned polycarbonate polyols with hydroxyl-containing compounds; Ester-based polycarbonate polyol; a copolymerized polyether-based polycarbonate polyol obtained by copolymerizing the above-mentioned various polycarbonate polyols with alkylene oxide.

作為蓖麻油系多元醇，例如可例舉：使蓖麻油脂肪酸與上述多元醇成分反應所獲得之蓖麻油系多元醇。作為蓖麻油系多元醇，具體而言，例如可例舉：使蓖麻油脂肪酸與聚丙二醇反應所獲得之蓖麻油系多元醇。As a castor oil type polyol, the castor oil type polyol obtained by making castor oil fatty acid and the said polyol component react, for example is mentioned. As a castor oil type polyol, the castor oil type polyol obtained by making castor oil fatty acid and polypropylene glycol react specifically, for example is mentioned.

[1-2-1-b.一步法中所使用之多官能異氰酸酯化合物(B)] 一步法中所使用之多官能異氰酸酯化合物(B)可僅為1種，亦可為2種以上。 [1-2-1-b. Polyfunctional isocyanate compound (B) used in one-step method] The polyfunctional isocyanate compound (B) used in a one-step method may be only 1 type, and may be 2 or more types.

作為多官能異氰酸酯化合物(B)，可採用胺基甲酸酯化反應中可使用之任意適當之多官能異氰酸酯化合物。作為此種多官能異氰酸酯化合物(B)，例如可例舉：多官能脂肪族系異氰酸酯化合物、多官能脂環族系異氰酸酯、多官能芳香族系異氰酸酯化合物。As the polyfunctional isocyanate compound (B), any appropriate polyfunctional isocyanate compound that can be used in the urethanization reaction can be used. As such a polyfunctional isocyanate compound (B), a polyfunctional aliphatic isocyanate compound, a polyfunctional alicyclic isocyanate, and a polyfunctional aromatic isocyanate compound are mentioned, for example.

作為多官能脂肪族系異氰酸酯化合物，例如可例舉：三亞甲基二異氰酸酯、四亞甲基二異氰酸酯、六亞甲基二異氰酸酯、五亞甲基二異氰酸酯、1,2-伸丙基二異氰酸酯、1,3-伸丁基二異氰酸酯、十二亞甲基二異氰酸酯、2,4,4-三甲基六亞甲基二異氰酸酯。Examples of polyfunctional aliphatic isocyanate compounds include trimethylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, pentamethylene diisocyanate, and 1,2-propylene diisocyanate. , 1,3-butylene diisocyanate, dodecamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate.

作為多官能脂環族系異氰酸酯化合物，例如可例舉：1,3-環戊烷二異氰酸酯、1,3-環己烷二異氰酸酯、1,4-環己烷二異氰酸酯、異佛爾酮二異氰酸酯、氫化二苯基甲烷二異氰酸酯、氫化苯二甲基二異氰酸酯、氫化甲苯二異氰酸酯、氫化四甲基苯二甲基二異氰酸酯。Examples of polyfunctional alicyclic isocyanate compounds include: 1,3-cyclopentane diisocyanate, 1,3-cyclohexane diisocyanate, 1,4-cyclohexane diisocyanate, isophorone diisocyanate, Isocyanate, hydrogenated diphenylmethane diisocyanate, hydrogenated xylylene diisocyanate, hydrogenated toluene diisocyanate, hydrogenated tetramethyl xylylene diisocyanate.

作為多官能芳香族系二異氰酸酯化合物，例如可例舉：苯二異氰酸酯、2,4-甲苯二異氰酸酯、2,6-甲苯二異氰酸酯、2,2'-二苯基甲烷二異氰酸酯、4,4'-二苯基甲烷二異氰酸酯、4,4'-甲苯胺二異氰酸酯、4,4'-二苯醚二異氰酸酯、4,4'-二苯基二異氰酸酯、1,5-萘二異氰酸酯、苯二甲基二異氰酸酯。Examples of polyfunctional aromatic diisocyanate compounds include: phenylene diisocyanate, 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,2'-diphenylmethane diisocyanate, 4,4 '-Diphenylmethane diisocyanate, 4,4'-toluidine diisocyanate, 4,4'-diphenyl ether diisocyanate, 4,4'-diphenyl diisocyanate, 1,5-naphthalene diisocyanate, benzene Dimethyl diisocyanate.

作為多官能異氰酸酯化合物(B)，亦可例舉：如上所述之各種多官能異氰酸酯化合物之三羥甲基丙烷加成物、與水反應之滴定管(buret)體、具有異氰尿酸酯環之三聚物。又，亦可併用該等。Examples of the polyfunctional isocyanate compound (B) include trimethylolpropane adducts of various polyfunctional isocyanate compounds as described above, burets that react with water, and polyfunctional isocyanurate ring-containing The terpolymer. Also, these may be used in combination.

關於多官能異氰酸酯化合物(B)之含有比率，相對於多元醇(A1)，多官能異氰酸酯化合物(B)較佳為5重量%～60重量%，更佳為8重量%～60重量%，進而較佳為10重量%～60重量%。藉由將多官能異氰酸酯化合物(B)之含有比率調整至上述範圍內，能夠更加表現本發明之效果。Regarding the content ratio of the polyfunctional isocyanate compound (B), the polyfunctional isocyanate compound (B) is preferably 5% by weight to 60% by weight, more preferably 8% by weight to 60% by weight, based on the polyol (A1), and further Preferably it is 10% by weight to 60% by weight. By adjusting the content ratio of a polyfunctional isocyanate compound (B) in the said range, the effect of this invention can be expressed more.

關於多元醇(A1)與多官能異氰酸酯化合物(B)中之NCO基與OH基之當量比，就能夠更加表現本發明之效果之方面而言，NCO基/OH基超過1.0且為5.0以下，較佳為1.1～5.0，更佳為1.2～4.0，進而較佳為1.5～3.5，尤佳為1.8～3.0。Regarding the equivalent ratio of the NCO group and the OH group in the polyol (A1) and the polyfunctional isocyanate compound (B), in terms of the effect of the present invention can be more expressed, the NCO group/OH group exceeds 1.0 and is 5.0 or less, Preferably it is 1.1-5.0, More preferably, it is 1.2-4.0, More preferably, it is 1.5-3.5, Most preferably, it is 1.8-3.0.

[1-2-1-c.其他成分] 胺基甲酸酯系黏著劑組合物可於不損害本發明之效果之範圍內包含任意適當之其他成分。作為此種其他成分，例如可例舉：其他樹脂成分、除多官能異氰酸酯化合物(B)以外之交聯劑、交聯延遲劑、離子性化合物、氟系添加劑、矽酮系添加劑、脂肪酸酯、黏著賦予劑、無機填充劑、有機填充劑、金屬粉、顏料、箔狀物、軟化劑、抗老化劑、導電劑、紫外線吸收劑、抗氧化劑、光穩定劑、表面潤滑劑、整平劑、抗腐蝕劑、耐熱穩定劑、聚合抑制劑、潤滑劑、溶劑、觸媒。 [1-2-1-c. Other ingredients] The urethane-based adhesive composition may contain any appropriate other components within the range that does not impair the effects of the present invention. Such other components include, for example, other resin components, crosslinking agents other than the polyfunctional isocyanate compound (B), crosslinking retarders, ionic compounds, fluorine-based additives, silicone-based additives, fatty acid esters , adhesion imparting agent, inorganic filler, organic filler, metal powder, pigment, foil, softener, anti-aging agent, conductive agent, ultraviolet absorber, antioxidant, light stabilizer, surface lubricant, leveling agent , Anti-corrosion agent, heat-resistant stabilizer, polymerization inhibitor, lubricant, solvent, catalyst.

(離子性化合物) 若包含離子性化合物作為其他成分，則可提高本發明之實施方式之附黏著劑層之膜之抗靜電性能。 (ionic compounds) If the ionic compound is included as another component, the antistatic performance of the film with the adhesive layer according to the embodiment of the present invention can be improved.

作為離子性化合物之含有比率，可於不損害本發明之效果之範圍內採用任意適當之含有比率。就能夠更加提高本發明之實施方式的附黏著劑層之膜之抗靜電性能之方面而言，離子性化合物相對於多元醇(A1)總量之含有比率較佳為0.05重量%以上，更佳為0.10重量%～50重量%，進而較佳為0.20重量%～30重量%，尤佳為0.30重量%～10重量%，最佳為0.50重量%～1重量%。As the content ratio of the ionic compound, any appropriate content ratio can be adopted within the range that does not impair the effect of the present invention. From the point of view that the antistatic performance of the film with the adhesive layer according to the embodiment of the present invention can be further improved, the content ratio of the ionic compound to the total amount of the polyol (A1) is preferably 0.05% by weight or more, more preferably It is 0.10% by weight to 50% by weight, more preferably 0.20% by weight to 30% by weight, particularly preferably 0.30% by weight to 10% by weight, most preferably 0.50% by weight to 1% by weight.

作為離子性化合物，可於不損害本發明之效果之範圍內採用任意適當之離子性化合物。離子性化合物可僅為1種，亦可為2種以上。As the ionic compound, any appropriate ionic compound can be employed within the range not impairing the effect of the present invention. Only 1 type may be sufficient as an ionic compound, and 2 or more types may be sufficient as it.

作為離子性化合物，就能夠更加表現本發明之效果之方面而言，較佳為包含選自鎓陽離子及金屬陽離子之至少1種以及氟有機陰離子之離子性化合物、含離子性基之矽酮低聚物，就能夠使黏著劑層之外觀變得更加優異之方面而言，離子性化合物更佳為包含選自鎓陽離子及金屬陽離子之至少1種以及氟有機陰離子之離子性化合物。As the ionic compound, an ionic compound containing at least one selected from an onium cation and a metal cation and a fluorine organic anion, or an ionic group-containing silicone with a low As the polymer, the ionic compound is more preferably an ionic compound containing at least one selected from onium cations and metal cations and fluoroorganic anions in terms of being able to further improve the appearance of the adhesive layer.

離子性化合物亦可為離子性液體。離子性液體意指在25℃下呈液狀之熔鹽(離子性化合物)。The ionic compound may also be an ionic liquid. The ionic liquid means a molten salt (ionic compound) that is liquid at 25°C.

作為含離子性基之矽酮低聚物，可於不損害本發明之效果之範圍內採用任意適當之含離子性基之矽酮低聚物。作為含離子性基之矽酮低聚物，例如可例舉：信越化學工業公司製造之商品名「X-40-2450」。As the ionic group-containing silicone oligomer, any appropriate ionic group-containing silicone oligomer can be employed within the range that does not impair the effect of the present invention. As an ionic group-containing silicone oligomer, for example, the product name "X-40-2450" by Shin-Etsu Chemical Co., Ltd. is mentioned.

作為鎓陽離子，可於不損害本發明之效果之範圍內採用任意適當之鎓陽離子。就能夠更加表現本發明之效果之方面而言，此種鎓陽離子較佳為選自銨陽離子(含氮之鎓陽離子)、鋶陽離子(含硫之鎓陽離子)、含磷之鎓陽離子(鏻陽離子)之至少1種，更佳為銨陽離子。Any appropriate onium cation can be used as the onium cation within the range that does not impair the effect of the present invention. In terms of the aspect that can more exhibit the effect of the present invention, such onium cations are preferably selected from ammonium cations (nitrogen-containing onium cations), calcite cations (sulfur-containing onium cations), phosphorus-containing onium cations (phosphonium cations) ), more preferably ammonium cation.

作為金屬陽離子，可於不損害本發明之效果之範圍內採用任意適當之金屬陽離子。就能夠更加表現本發明之效果之方面而言，此種金屬陽離子較佳為Li陽離子、Na陽離子、K陽離子等鹼金屬陽離子。As the metal cation, any appropriate metal cation can be used within the range that does not impair the effect of the present invention. Such metal cations are preferably alkali metal cations such as Li cations, Na cations, and K cations in terms of being able to further express the effects of the present invention.

作為氟有機陰離子，可於不損害本發明之效果之範圍內採用任意適當之氟有機陰離子。氟有機陰離子可完全氟化(全氟化)，亦可部分氟化。As the fluoroorganic anion, any appropriate fluoroorganic anion can be used within the range that does not impair the effects of the present invention. Fluoroorganic anions can be fully fluorinated (perfluorinated) or partially fluorinated.

作為此種氟有機陰離子，例如可例舉：氟化之芳基磺酸鹽、全氟烷磺酸鹽、雙(氟磺醯基)醯亞胺、雙(全氟烷磺醯基)醯亞胺、氰基全氟烷磺醯胺、雙(氰基)全氟烷磺醯甲基化物、氰基-雙-(全氟烷磺醯基)甲基化物、三(全氟烷磺醯基)甲基化物、三氟乙酸酯、全氟烷化物、三(全氟烷磺醯基)甲基化物、(全氟烷磺醯基)三氟乙醯胺。Such fluorine organic anions include, for example, fluorinated arylsulfonates, perfluoroalkanesulfonates, bis(fluorosulfonyl)imides, bis(perfluoroalkanesulfonyl)imides, Amine, cyanoperfluoroalkanesulfonamide, bis(cyano)perfluoroalkanesulfonyl methide, cyano-bis-(perfluoroalkanesulfonyl)methylate, tris(perfluoroalkanesulfonyl) ) methide, trifluoroacetate, perfluoroalkylate, tris(perfluoroalkanesulfonyl)methide, (perfluoroalkanesulfonyl)trifluoroacetamide.

該等氟有機陰離子之中，就能夠更加表現本發明之效果之方面而言，較佳為全氟烷磺酸鹽、雙(氟磺醯基)醯亞胺、雙(全氟烷磺醯基)醯亞胺，更具體而言，例如為三氟甲磺酸鹽、五氟乙磺酸鹽、七氟丙磺酸鹽、九氟丁磺酸鹽、雙(氟磺醯基)醯亞胺、雙(三氟甲磺醯基)醯亞胺，較佳為雙(氟磺醯基)醯亞胺、雙(三氟甲磺醯基)醯亞胺。Among these fluoroorganic anions, perfluoroalkanesulfonate, bis(fluorosulfonyl)imide, bis(perfluoroalkanesulfonyl)imide, and ) imides, more specifically triflate, pentafluoroethanesulfonate, heptafluoropropanesulfonate, nonafluorobutanesulfonate, bis(fluorosulfonyl)imide . Bis(trifluoromethanesulfonyl)imide, preferably bis(fluorosulfonyl)imide and bis(trifluoromethanesulfonyl)imide.

作為離子性化合物，就能夠更加表現本發明之效果之方面而言，更佳為包含鎓陽離子及氟有機陰離子之離子性化合物。As the ionic compound, an ionic compound containing an onium cation and a fluoroorganic anion is more preferable at the point that the effects of the present invention can be more exhibited.

鎓陽離子較佳為具有選自通式(1)～(4)所表示之結構之至少1種。 [化1]

Figure 02_image001
The onium cation preferably has at least one structure selected from the structures represented by the general formulas (1) to (4). [chemical 1]
Figure 02_image001

於通式(1)中，Ra表示碳數4至20之烴基，亦可包含雜原子，Rb及Rc相同或不同地表示氫或碳數1至16之烴基，亦可包含雜原子。其中，於氮原子包含雙鍵之情形時，不存在Rc。In the general formula (1), Ra represents a hydrocarbon group having 4 to 20 carbons and may contain heteroatoms, and Rb and Rc may represent hydrogen or a hydrocarbon group having 1 to 16 carbons identically or differently and may contain heteroatoms. However, when the nitrogen atom contains a double bond, Rc does not exist.

於通式(2)中，Rd表示碳數2至20之烴基，亦可包含雜原子，Re、Rf及Rg相同或不同地表示氫或碳數1至16之烴基，亦可包含雜原子。In the general formula (2), Rd represents a hydrocarbon group with 2 to 20 carbons and may also contain heteroatoms, and Re, Rf and Rg may represent hydrogen or a hydrocarbon group with 1 to 16 carbons identically or differently and may contain heteroatoms.

於通式(3)中，Rh表示碳數2至20之烴基，亦可包含雜原子，Ri、Rj及Rk相同或不同地表示氫或碳數1至16之烴基，亦可包含雜原子。In the general formula (3), Rh represents a hydrocarbon group with 2 to 20 carbons, and may also contain heteroatoms, and Ri, Rj and Rk may represent hydrogen or a hydrocarbon group with 1 to 16 carbons, which may be identical or different, and may contain heteroatoms.

於通式(4)中，Z表示氮原子、硫原子或磷原子，Rl、Rm、Rn及Ro相同或不同地表示碳數1至20之烴基，亦可包含雜原子。其中，於Z為硫原子之情形時，不存在Ro。In the general formula (4), Z represents a nitrogen atom, a sulfur atom or a phosphorus atom, and R1, Rm, Rn and Ro identically or differently represent a hydrocarbon group having 1 to 20 carbon atoms, and may also contain heteroatoms. However, when Z is a sulfur atom, Ro does not exist.

作為通式(1)所表示之陽離子結構，例如可例舉：吡啶鎓陽離子結構、吡咯啶鎓陽離子結構、哌啶鎓陽離子結構、具有吡咯啉骨架之陽離子結構、具有吡咯骨架之陽離子結構。Examples of the cationic structure represented by the general formula (1) include a pyridinium cationic structure, a pyrrolidinium cationic structure, a piperidinium cationic structure, a cationic structure having a pyrroline skeleton, and a cationic structure having a pyrrole skeleton.

作為通式(1)所表示之陽離子之具體例，例如可例舉：1-乙基吡啶鎓陽離子、1-丁基吡啶鎓陽離子、1-己基吡啶鎓陽離子、1-乙基-3-甲基吡啶鎓陽離子、1-丁基-3-甲基吡啶鎓陽離子、1-己基-3-甲基吡啶鎓陽離子、1-丁基-4-甲基吡啶鎓陽離子、1-辛基-4-甲基吡啶鎓陽離子、1-丁基-3,4-二甲基吡啶鎓陽離子、1,1-二甲基吡咯啶鎓陽離子等吡啶鎓陽離子；1-乙基-1-甲基吡咯啶鎓陽離子、1-甲基-1-丙基吡咯啶鎓陽離子、1-甲基-1-丁基吡咯啶鎓陽離子、1-甲基-1-戊基吡咯啶鎓陽離子、1-甲基-1-己基吡咯啶鎓陽離子、1-甲基-1-庚基吡咯啶鎓陽離子、1-乙基-1-丙基吡咯啶鎓陽離子、1-乙基-1-丁基吡咯啶鎓陽離子、1-乙基-1-戊基吡咯啶鎓陽離子、1-乙基-1-己基吡咯啶鎓陽離子、1-乙基-1-庚基吡咯啶鎓陽離子、1,1-二丙基吡咯啶鎓陽離子、1-丙基-1-丁基吡咯啶鎓陽離子、1,1-二丁基吡咯啶鎓陽離子等吡咯啶鎓陽離子；1-丙基哌啶鎓陽離子、1-戊基哌啶鎓陽離子、1-甲基-1-乙基哌啶鎓陽離子、1-甲基-1-丙基哌啶鎓陽離子、1-甲基-1-丁基哌啶鎓陽離子、1-甲基-1-戊基哌啶鎓陽離子、1-甲基-1-己基哌啶鎓陽離子、1-甲基-1-庚基哌啶鎓陽離子、1-乙基-1-丙基哌啶鎓陽離子、1-乙基-1-丁基哌啶鎓陽離子、1-乙基-1-戊基哌啶鎓陽離子、1-乙基-1-己基哌啶鎓陽離子、1-乙基-1-庚基哌啶鎓陽離子、1-丙基-1-丁基哌啶鎓陽離子、1,1-二甲基哌啶鎓陽離子、1,1-二丙基哌啶鎓陽離子、1,1-二丁基哌啶鎓陽離子等哌啶鎓陽離子；2-甲基-1-吡咯啉陽離子；1-乙基-2-苯基吲哚陽離子；1,2-二甲基吲哚陽離子；1-乙基咔唑陽離子；該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Specific examples of the cation represented by the general formula (1) include: 1-ethylpyridinium cation, 1-butylpyridinium cation, 1-hexylpyridinium cation, 1-ethyl-3-methano Basepyridinium cation, 1-butyl-3-methylpyridinium cation, 1-hexyl-3-methylpyridinium cation, 1-butyl-4-methylpyridinium cation, 1-octyl-4- Pyridinium cation, 1-butyl-3,4-dimethylpyridinium cation, 1,1-dimethylpyrrolidinium cation and other pyridinium cations; 1-ethyl-1-methylpyrrolidinium Cation, 1-methyl-1-propylpyrrolidinium cation, 1-methyl-1-butylpyrrolidinium cation, 1-methyl-1-pentylpyrrolidinium cation, 1-methyl-1 -hexylpyrrolidinium cation, 1-methyl-1-heptylpyrrolidinium cation, 1-ethyl-1-propylpyrrolidinium cation, 1-ethyl-1-butylpyrrolidinium cation, 1 -Ethyl-1-pentylpyrrolidinium cation, 1-ethyl-1-hexylpyrrolidinium cation, 1-ethyl-1-heptylpyrrolidinium cation, 1,1-dipropylpyrrolidinium Pyrrolidinium cations such as cations, 1-propyl-1-butylpyrrolidinium cations, 1,1-dibutylpyrrolidinium cations; 1-propylpiperidinium cations, 1-pentylpiperidinium cations , 1-methyl-1-ethylpiperidinium cation, 1-methyl-1-propylpiperidinium cation, 1-methyl-1-butylpiperidinium cation, 1-methyl-1- Pentylpiperidinium cation, 1-methyl-1-hexylpiperidinium cation, 1-methyl-1-heptylpiperidinium cation, 1-ethyl-1-propylpiperidinium cation, 1- Ethyl-1-butylpiperidinium cation, 1-ethyl-1-pentylpiperidinium cation, 1-ethyl-1-hexylpiperidinium cation, 1-ethyl-1-heptylpiperidinium Onium cation, 1-propyl-1-butylpiperidinium cation, 1,1-dimethylpiperidinium cation, 1,1-dipropylpiperidinium cation, 1,1-dibutylpiperidinium Onium cations such as piperidinium cations; 2-methyl-1-pyrroline cations; 1-ethyl-2-phenylindole cations; 1,2-dimethylindole cations; 1-ethylcarbazole cations ; These cations further have at least one cation selected from the group consisting of vinyl (CH 2 =CH- group) and allyl group (CH 2 =CH-CH 2 - group).

該等之中，就能夠更加表現本發明之效果之方面而言，較佳為：1-乙基吡啶鎓陽離子、1-丁基吡啶鎓陽離子、1-己基吡啶鎓陽離子、1-乙基-3-甲基吡啶鎓陽離子、1-丁基-3-甲基吡啶鎓陽離子、1-己基-3-甲基吡啶鎓陽離子、1-丁基-4-甲基吡啶鎓陽離子、1-辛基-4-甲基吡啶鎓陽離子等吡啶鎓陽離子；1-乙基-1-甲基吡咯啶鎓陽離子、1-甲基-1-丙基吡咯啶鎓陽離子、1-甲基-1-丁基吡咯啶鎓陽離子、1-甲基-1-戊基吡咯啶鎓陽離子、1-甲基-1-己基吡咯啶鎓陽離子、1-甲基-1-庚基吡咯啶鎓陽離子、1-乙基-1-丙基吡咯啶鎓陽離子、1-乙基-1-丁基吡咯啶鎓陽離子、1-乙基-1-戊基吡咯啶鎓陽離子、1-乙基-1-己基吡咯啶鎓陽離子、1-乙基-1-庚基吡咯啶鎓陽離子等吡咯啶鎓陽離子；1-甲基-1-乙基哌啶鎓陽離子、1-甲基-1-丙基哌啶鎓陽離子、1-甲基-1-丁基哌啶鎓陽離子、1-甲基-1-戊基哌啶鎓陽離子、1-甲基-1-己基哌啶鎓陽離子、1-甲基-1-庚基哌啶鎓陽離子、1-乙基-1-丙基哌啶鎓陽離子、1-乙基-1-丁基哌啶鎓陽離子、1-乙基-1-戊基哌啶鎓陽離子、1-乙基-1-己基哌啶鎓陽離子、1-乙基-1-庚基哌啶鎓陽離子、1-丙基-1-丁基哌啶鎓陽離子等哌啶鎓陽離子；該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子；更佳為1-己基吡啶鎓陽離子、1-乙基-3-甲基吡啶鎓陽離子、1-丁基-3-甲基吡啶鎓陽離子、1-辛基-4-甲基吡啶鎓陽離子、1-甲基-1-丙基吡咯啶鎓陽離子、1-甲基-1-丙基哌啶鎓陽離子、該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Among these, 1-ethylpyridinium cation, 1-butylpyridinium cation, 1-hexylpyridinium cation, 1-ethyl- 3-methylpyridinium cation, 1-butyl-3-methylpyridinium cation, 1-hexyl-3-methylpyridinium cation, 1-butyl-4-methylpyridinium cation, 1-octyl -Pyridinium cations such as 4-methylpyridinium cation; 1-ethyl-1-methylpyrrolidinium cation, 1-methyl-1-propylpyrrolidinium cation, 1-methyl-1-butyl Pyrrolidinium cation, 1-methyl-1-pentylpyrrolidinium cation, 1-methyl-1-hexylpyrrolidinium cation, 1-methyl-1-heptylpyrrolidinium cation, 1-ethyl -1-propylpyrrolidinium cation, 1-ethyl-1-butylpyrrolidinium cation, 1-ethyl-1-pentylpyrrolidinium cation, 1-ethyl-1-hexylpyrrolidinium cation , 1-ethyl-1-heptylpyrrolidinium cation and other pyrrolidinium cations; 1-methyl-1-ethylpiperidinium cation, 1-methyl-1-propylpiperidinium cation, 1- Methyl-1-butylpiperidinium cation, 1-methyl-1-pentylpiperidinium cation, 1-methyl-1-hexylpiperidinium cation, 1-methyl-1-heptylpiperidinium Onium cation, 1-ethyl-1-propylpiperidinium cation, 1-ethyl-1-butylpiperidinium cation, 1-ethyl-1-pentylpiperidinium cation, 1-ethyl- Piperidinium cations such as 1-hexylpiperidinium cation, 1-ethyl-1-heptylpiperidinium cation, 1-propyl-1-butylpiperidinium cation, etc.; A cation of at least one of (CH 2 ═CH- group) and allyl group (CH 2 ═CH-CH 2 - group); more preferably 1-hexylpyridinium cation, 1-ethyl-3-picoline Onium cation, 1-butyl-3-methylpyridinium cation, 1-octyl-4-methylpyridinium cation, 1-methyl-1-propylpyrrolidinium cation, 1-methyl-1- The propylpiperidinium cation and these cations further have at least one cation selected from vinyl (CH 2 =CH- group) and allyl (CH 2 =CH-CH 2 - group).

作為通式(2)所表示之陽離子結構，例如可例舉：咪唑鎓陽離子結構、四氫嘧啶鎓陽離子結構、二氫嘧啶鎓陽離子結構。Examples of the cation structure represented by the general formula (2) include an imidazolium cation structure, a tetrahydropyrimidinium cation structure, and a dihydropyrimidinium cation structure.

作為通式(2)所表示之陽離子之具體例，例如可例舉：1,3-二甲基咪唑鎓陽離子、1,3-二乙基咪唑鎓陽離子、1-乙基-3-甲基咪唑鎓陽離子、1-丁基-3-甲基咪唑鎓陽離子、1-己基-3-甲基咪唑鎓陽離子、1-辛基-3-甲基咪唑鎓陽離子、1-癸基-3-甲基咪唑鎓陽離子、1-十二烷基-3-甲基咪唑鎓陽離子、1-十四烷基-3-甲基咪唑鎓陽離子、1,2-二甲基-3-丙基咪唑鎓陽離子、1-乙基-2,3-二甲基咪唑鎓陽離子、1-丁基-2,3-二甲基咪唑鎓陽離子、1-己基-2,3-二甲基咪唑鎓陽離子等咪唑鎓陽離子；1,3-二甲基-1,4,5,6-四氫嘧啶鎓陽離子、1,2,3-三甲基-1,4,5,6-四氫嘧啶鎓陽離子、1,2,3,4-四甲基-1,4,5,6-四氫嘧啶鎓陽離子、1,2,3,5-四甲基-1,4,5,6-四氫嘧啶鎓陽離子等四氫嘧啶鎓陽離子；1,3-二甲基-1,4-二氫嘧啶鎓陽離子、1,3-二甲基-1,6-二氫嘧啶鎓陽離子、1,2,3-三甲基-1,4-二氫嘧啶鎓陽離子、1,2,3-三甲基-1,6-二氫嘧啶鎓陽離子、1,2,3,4-四甲基-1,4-二氫嘧啶鎓陽離子、1,2,3,4-四甲基-1,6-二氫嘧啶鎓陽離子等二氫嘧啶鎓陽離子；該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Specific examples of the cation represented by the general formula (2) include, for example, 1,3-dimethylimidazolium cation, 1,3-diethylimidazolium cation, 1-ethyl-3-methyl Imidazolium cation, 1-butyl-3-methylimidazolium cation, 1-hexyl-3-methylimidazolium cation, 1-octyl-3-methylimidazolium cation, 1-decyl-3-methyl 1-dodecyl-3-methylimidazolium cation, 1-dodecyl-3-methylimidazolium cation, 1-tetradecyl-3-methylimidazolium cation, 1,2-dimethyl-3-propylimidazolium cation , 1-ethyl-2,3-dimethylimidazolium cation, 1-butyl-2,3-dimethylimidazolium cation, 1-hexyl-2,3-dimethylimidazolium cation and other imidazolium Cation; 1,3-dimethyl-1,4,5,6-tetrahydropyrimidinium cation, 1,2,3-trimethyl-1,4,5,6-tetrahydropyrimidinium cation, 1, 2,3,4-tetramethyl-1,4,5,6-tetrahydropyrimidinium cation, 1,2,3,5-tetramethyl-1,4,5,6-tetrahydropyrimidinium cation, etc. Tetrahydropyrimidinium cation; 1,3-dimethyl-1,4-dihydropyrimidinium cation, 1,3-dimethyl-1,6-dihydropyrimidinium cation, 1,2,3-trimethyl Base-1,4-dihydropyrimidinium cation, 1,2,3-trimethyl-1,6-dihydropyrimidinium cation, 1,2,3,4-tetramethyl-1,4-dihydro Dihydropyrimidinium cations such as pyrimidinium cations, 1,2,3,4 - tetramethyl-1,6-dihydropyrimidinium cations; these cations in turn have A cation of at least one type of allyl group (CH 2 =CH-CH 2 -group).

該等之中，就能夠更加表現本發明之效果之方面而言，較佳為1,3-二甲基咪唑鎓陽離子、1,3-二乙基咪唑鎓陽離子、1-乙基-3-甲基咪唑鎓陽離子、1-丁基-3-甲基咪唑鎓陽離子、1-己基-3-甲基咪唑鎓陽離子、1-辛基-3-甲基咪唑鎓陽離子、1-癸基-3-甲基咪唑鎓陽離子、1-十二烷基-3-甲基咪唑鎓陽離子、1-十四烷基-3-甲基咪唑鎓陽離子、該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子等咪唑鎓陽離子；更佳為1-乙基-3-甲基咪唑鎓陽離子、1-己基-3-甲基咪唑鎓陽離子、該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Among these, 1,3-dimethylimidazolium cation, 1,3-diethylimidazolium cation, 1-ethyl-3- Methylimidazolium cation, 1-butyl-3-methylimidazolium cation, 1-hexyl-3-methylimidazolium cation, 1-octyl-3-methylimidazolium cation, 1-decyl-3 -methylimidazolium cation, 1 -dodecyl-3-methylimidazolium cation, 1-tetradecyl-3-methylimidazolium cation, these cations further have CH-yl) and allyl (CH 2 =CH-CH 2 -yl) cations such as at least one imidazolium cation; more preferably 1-ethyl-3-methylimidazolium cation, 1-hexyl- The 3-methylimidazolium cation and these cations further have at least one cation selected from the group consisting of vinyl (CH 2 =CH- group) and allyl group (CH 2 =CH-CH 2 - group).

作為通式(3)所表示之陽離子結構，例如可例舉：吡唑鎓陽離子結構、吡唑啉鎓陽離子結構。As a cation structure represented by General formula (3), a pyrazolium cation structure and a pyrazolinium cation structure are mentioned, for example.

作為通式(3)所表示之陽離子之具體例，例如可例舉：1-甲基吡唑鎓陽離子、3-甲基吡唑鎓陽離子、1-乙基-2-甲基吡唑啉鎓陽離子、1-乙基-2,3,5-三甲基吡唑鎓陽離子、1-丙基-2,3,5-三甲基吡唑鎓陽離子、1-丁基-2,3,5-三甲基吡唑鎓陽離子等吡唑鎓陽離子；1-乙基-2,3,5-三甲基吡唑啉鎓陽離子、1-丙基-2,3,5-三甲基吡唑啉鎓陽離子、1-丁基-2,3,5-三甲基吡唑啉鎓陽離子等吡唑啉鎓陽離子；該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Specific examples of the cation represented by the general formula (3) include: 1-methylpyrazolium cation, 3-methylpyrazolium cation, 1-ethyl-2-methylpyrazolinium Cation, 1-ethyl-2,3,5-trimethylpyrazolium cation, 1-propyl-2,3,5-trimethylpyrazolium cation, 1-butyl-2,3,5 -Pyrazolium cations such as trimethylpyrazolium cation; 1-ethyl-2,3,5-trimethylpyrazolinium cation, 1-propyl-2,3,5-trimethylpyrazole Pyrazolinium cations such as olinium cations, 1 -butyl-2,3,5-trimethylpyrazolinium cations; these cations further have A cation of at least one kind of group (CH 2 =CH-CH 2 -group).

作為通式(4)所表示之陽離子結構，例如可例舉：四烷基銨陽離子結構、三烷基鋶陽離子結構、四烷基鏻陽離子結構、或上述烷基之一部分被烯基或烷氧基或環氧基取代而成者。As the cation structure represented by the general formula (4), for example, a tetraalkylammonium cation structure, a trialkylconium cation structure, a tetraalkylphosphonium cation structure, or a part of the above-mentioned alkyl groups replaced by alkenyl or alkoxy Substituted by group or epoxy group.

作為通式(4)所表示之陽離子之具體例，例如可例舉：四甲基銨陽離子、四乙基銨陽離子、四丁基銨陽離子、四戊基銨陽離子、四己基銨陽離子、四庚基銨陽離子、三乙基甲基銨陽離子、三丁基乙基銨陽離子、三甲基丙基銨陽離子、三甲基癸基銨陽離子、N,N-二乙基-N-甲基-N-(2-甲氧基乙基)銨陽離子、縮水甘油基三甲基銨陽離子、二烯丙基二甲基銨陽離子、N,N-二甲基-N-乙基-N-丙基銨陽離子、N,N-二甲基-N-乙基-N-丁基銨陽離子、N,N-二甲基-N-乙基-N-戊基銨陽離子、N,N-二甲基-N-乙基-N-己基銨陽離子、N,N-二甲基-N-乙基-N-庚基銨陽離子、N,N-二甲基-N-乙基-N-壬基銨陽離子、N,N-二甲基-N,N-二丙基銨陽離子、N,N-二乙基-N-丙基-N-丁基銨陽離子、N,N-二甲基-N-丙基-N-戊基銨陽離子、N,N-二甲基-N-丙基-N-己基銨陽離子、N,N-二甲基-N-丙基-N-庚基銨陽離子、N,N-二甲基-N-丁基-N-己基銨陽離子、N,N-二乙基-N-丁基-N-庚基銨陽離子、N,N-二甲基-N-戊基-N-己基銨陽離子、N,N-二甲基-N,N-二己基銨陽離子、三甲基庚基銨陽離子、N,N-二乙基-N-甲基-N-丙基銨陽離子、N,N-二乙基-N-甲基-N-戊基銨陽離子、N,N-二乙基-N-甲基-N-庚基銨陽離子、N,N-二乙基-N-丙基-N-戊基銨陽離子、三乙基丙基銨陽離子、三乙基戊基銨陽離子、三乙基庚基銨陽離子、N,N-二丙基-N-甲基-N-乙基銨陽離子、N,N-二丙基-N-甲基-N-戊基銨陽離子、N,N-二丙基-N-丁基-N-己基銨陽離子、N,N-二丙基-N,N-二己基銨陽離子、N,N-二丁基-N-甲基-N-戊基銨陽離子、N,N-二丁基-N-甲基-N-己基銨陽離子、三辛基甲基銨陽離子、N-甲基-N-乙基-N-丙基-N-戊基銨陽離子等四烷基銨陽離子；三甲基鋶陽離子、三乙基鋶陽離子、三丁基鋶陽離子、三己基鋶陽離子、二乙基甲基鋶陽離子、二丁基乙基鋶陽離子、二甲基癸基鋶陽離子等三烷基鋶陽離子；四甲基鏻陽離子、四乙基鏻陽離子、四丁基鏻陽離子、四己基鏻陽離子、四辛基鏻陽離子、三乙基甲基鏻陽離子、三丁基乙基鏻陽離子、三甲基癸基鏻陽離子等四烷基鏻陽離子；該等陽離子進而具有選自乙烯基(CH 2＝CH-基)及烯丙基(CH 2＝CH-CH 2-基)之至少1種之陽離子。 Specific examples of the cation represented by the general formula (4) include, for example, tetramethylammonium cation, tetraethylammonium cation, tetrabutylammonium cation, tetrapentylammonium cation, tetrahexylammonium cation, tetraheptylammonium cation, Trimethylammonium cation, triethylmethylammonium cation, tributylethylammonium cation, trimethylpropylammonium cation, trimethyldecylammonium cation, N,N-diethyl-N-methyl-N -(2-methoxyethyl)ammonium cation, glycidyltrimethylammonium cation, diallyldimethylammonium cation, N,N-dimethyl-N-ethyl-N-propylammonium Cation, N,N-Dimethyl-N-ethyl-N-butylammonium cation, N,N-Dimethyl-N-ethyl-N-pentylammonium cation, N,N-Dimethyl- N-ethyl-N-hexylammonium cation, N,N-dimethyl-N-ethyl-N-heptylammonium cation, N,N-dimethyl-N-ethyl-N-nonylammonium cation , N,N-dimethyl-N,N-dipropylammonium cation, N,N-diethyl-N-propyl-N-butylammonium cation, N,N-dimethyl-N-propane -N-pentylammonium cation, N,N-dimethyl-N-propyl-N-hexylammonium cation, N,N-dimethyl-N-propyl-N-heptylammonium cation, N, N-Dimethyl-N-butyl-N-hexylammonium cation, N,N-diethyl-N-butyl-N-heptyl ammonium cation, N,N-dimethyl-N-pentyl- N-hexylammonium cation, N,N-dimethyl-N,N-dihexylammonium cation, trimethylheptylammonium cation, N,N-diethyl-N-methyl-N-propylammonium cation , N,N-diethyl-N-methyl-N-pentyl ammonium cation, N,N-diethyl-N-methyl-N-heptyl ammonium cation, N,N-diethyl-N -Propyl-N-pentylammonium cation, triethylpropylammonium cation, triethylpentylammonium cation, triethylheptylammonium cation, N,N-dipropyl-N-methyl-N- Ethylammonium cation, N,N-dipropyl-N-methyl-N-pentylammonium cation, N,N-dipropyl-N-butyl-N-hexylammonium cation, N,N-dipropylammonium cation Base-N,N-dihexylammonium cation, N,N-dibutyl-N-methyl-N-pentylammonium cation, N,N-dibutyl-N-methyl-N-hexylammonium cation, Tetraalkylammonium cations such as trioctylmethylammonium cation, N-methyl-N-ethyl-N-propyl-N-pentylammonium cation; Trialkylconium cations such as base percited cations, trihexyl percited cations, diethylmethyl percited cations, dibutyl ethyl percited cations, dimethyldecyl percited cations, etc.; tetramethylphosphonium cations, tetraethylphosphonium cations , tetrabutylphosphonium cation, tetrahexylphosphonium cation, tetraoctylphosphonium cation, triethylmethylphosphonium cation, tributylethylphosphonium cation, trimethyldecylphosphonium cation and other tetraalkylphosphonium cations; The cation further has at least one cation selected from vinyl group (CH 2 =CH- group) and allyl group (CH 2 =CH-CH 2 - group).

離子性化合物較佳為包含選自上述鎓陽離子及上述金屬陽離子之至少1種以及上述氟有機陰離子之離子性化合物、含離子性基之矽酮低聚物，更佳為包含選自上述鎓陽離子及上述金屬陽離子之至少1種以及上述氟有機陰離子之離子性化合物，進而較佳為包含上述鎓陽離子及上述氟有機陰離子之離子性化合物。The ionic compound is preferably an ionic compound containing at least one selected from the above-mentioned onium cations and the above-mentioned metal cations, and the above-mentioned fluoroorganic anion, or an ionic group-containing silicone oligomer, and more preferably contains a silicone oligomer selected from the above-mentioned onium cations. and an ionic compound of at least one of the aforementioned metal cations and the aforementioned fluoroorganic anion, and more preferably an ionic compound comprising the aforementioned onium cation and the aforementioned fluoroorganic anion.

就能夠更加表現本發明之效果之方面而言，作為離子性化合物，具體而言，較佳為1-己基吡啶鎓雙(氟磺醯基)醯亞胺、1-乙基-3-甲基吡啶鎓三氟甲磺酸鹽、1-乙基-3-甲基吡啶鎓五氟乙磺酸鹽、1-乙基-3-甲基吡啶鎓七氟丙磺酸鹽、1-乙基-3-甲基吡啶鎓九氟丁磺酸鹽、1-丁基-3-甲基吡啶鎓三氟甲磺酸鹽、1-丁基-3-甲基吡啶鎓雙(三氟甲磺醯基)醯亞胺、1-辛基-4-甲基吡啶鎓雙(氟磺醯基)醯亞胺、1-甲基-1-丙基吡咯啶鎓雙(三氟甲磺醯基)醯亞胺、1-甲基-1-丙基吡咯啶鎓雙(氟磺醯基)醯亞胺、1-甲基-1-丙基哌啶鎓雙(三氟甲磺醯基)醯亞胺、1-甲基-1-丙基哌啶鎓雙(氟磺醯基)醯亞胺、1-乙基-3-甲基咪唑鎓三氟甲磺酸鹽、1-乙基-3-甲基咪唑鎓七氟丙磺酸鹽、1-乙基-3-甲基咪唑鎓雙(三氟甲磺醯基)醯亞胺、1-乙基-3-甲基咪唑鎓雙(氟磺醯基)醯亞胺、1-己基-3-甲基咪唑鎓雙(氟磺醯基)醯亞胺、1-烯丙基-3-甲基-咪唑鎓三氟甲磺酸鹽、1-烯丙基-3-甲基-咪唑鎓七氟丙磺酸鹽、1-烯丙基-3-甲基-咪唑鎓雙(三氟甲磺醯基)醯亞胺、1-烯丙基-3-甲基-咪唑鎓雙(氟磺醯基)醯亞胺、甲基三辛基銨雙(三氟甲磺醯基)醯亞胺、三甲基丙基銨雙(三氟甲磺醯基)醯亞胺、鋰雙(三氟甲磺醯基)醯亞胺、鋰雙(氟磺醯基)醯亞胺，更佳為、1-丁基-3-甲基吡啶鎓雙(三氟甲磺醯基)醯亞胺、1-乙基-3-甲基咪唑鎓雙(氟磺醯基)醯亞胺、1-烯丙基-3-甲基-咪唑鎓雙(三氟甲磺醯基)醯亞胺、甲基三辛基銨雙(三氟甲磺醯基)醯亞胺、三甲基丙基銨雙(三氟甲磺醯基)醯亞胺、鋰雙(三氟甲磺醯基)醯亞胺，進而較佳為1-丁基-3-甲基吡啶鎓雙(三氟甲磺醯基)醯亞胺、1-乙基-3-甲基咪唑鎓雙(氟磺醯基)醯亞胺、1-烯丙基-3-甲基-咪唑鎓雙(三氟甲磺醯基)醯亞胺、甲基三辛基銨雙(三氟甲磺醯基)醯亞胺、三甲基丙基銨雙(三氟甲磺醯基)醯亞胺。As the ionic compound, specifically, 1-hexylpyridinium bis(fluorosulfonyl)imide, 1-ethyl-3-methyl Pyridinium trifluoromethanesulfonate, 1-ethyl-3-methylpyridinium pentafluoroethanesulfonate, 1-ethyl-3-methylpyridinium heptafluoropropanesulfonate, 1-ethyl- 3-methylpyridinium nonafluorobutanesulfonate, 1-butyl-3-methylpyridinium trifluoromethanesulfonate, 1-butyl-3-methylpyridinium bis(trifluoromethanesulfonyl ) imide, 1-octyl-4-methylpyridinium bis(fluorosulfonyl)imide, 1-methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide Amine, 1-methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide, 1-methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide, 1-Methyl-1-propylpiperidinium bis(fluorosulfonyl)imide, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate, 1-ethyl-3-methyl Imidazolium heptafluoropropanesulfonate, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium bis(fluorosulfonyl) ) imide, 1-hexyl-3-methylimidazolium bis(fluorosulfonyl)imide, 1-allyl-3-methyl-imidazolium trifluoromethanesulfonate, 1-allyl -3-methyl-imidazolium heptafluoropropanesulfonate, 1-allyl-3-methyl-imidazolium bis(trifluoromethanesulfonyl)imide, 1-allyl-3- Methyl-imidazolium bis(fluorosulfonyl)imide, methyltrioctylammonium bis(trifluoromethanesulfonyl)imide, trimethylpropylammonium bis(trifluoromethanesulfonyl)imide Imide, lithium bis(trifluoromethanesulfonyl)imide, lithium bis(fluorosulfonyl)imide, more preferably, 1-butyl-3-methylpyridinium bis(trifluoroformyl) Sulfonyl)imide, 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide, 1-allyl-3-methyl-imidazolium bis(trifluoromethanesulfonyl) base) imide, methyltrioctylammonium bis(trifluoromethanesulfonyl)imide, trimethylpropylammonium bis(trifluoromethanesulfonyl)imide, lithium bis(trifluoromethanesulfonyl)imide Sulfonyl) imide, and further preferably 1-butyl-3-methylpyridinium bis(trifluoromethanesulfonyl)imide, 1-ethyl-3-methylimidazolium bis(fluoro Sulfonyl)imide, 1-allyl-3-methyl-imidazolium bis(trifluoromethanesulfonyl)imide, methyltrioctylammonium bis(trifluoromethanesulfonyl)imide imine, trimethylpropylammonium bis(trifluoromethanesulfonyl)imide.

離子性化合物可使用市售者，亦可使用藉由任意適當之方法所合成者。例如，離子液體可藉由如「離子性液體-開發之最前線及未來-」(CMC出版發行)所記載之鹵化物法、氫氧化物法、酸酯法、錯合法及中和法等而合成。As the ionic compound, commercially available ones may be used, or those synthesized by any appropriate method may be used. For example, ionic liquids can be produced by the halide method, hydroxide method, ester method, complex method, and neutralization method, etc. synthesis.

(氟系添加劑) 若包含氟系添加劑作為其他成分，則能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性或抗靜電性能。 (Fluorine additives) When a fluorine-based additive is included as another component, the winding-up and unwinding properties or antistatic performance of the film with the adhesive layer according to the embodiment of the present invention without a separator can be further improved.

作為氟系添加劑，可於不損害本發明之效果之範圍內採用任意適當之氟系添加劑。As the fluorine-based additive, any appropriate fluorine-based additive can be employed within the range that does not impair the effect of the present invention.

氟系添加劑可僅為1種，亦可為2種以上。The fluorine-based additive may be only one type, or may be two or more types.

作為氟系添加劑之含有比率，可於不損害本發明之效果之範圍內採用任意適當之含有比率。就能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性或抗靜電性能之方面而言，氟系添加劑相對於多元醇(A1)總量之含有比率較佳為0.01重量%以上，更佳為0.03重量%～30重量份，進而較佳為0.05重量份～10重量份，尤佳為0.05重量份～1重量份。As the content ratio of the fluorine-based additive, any appropriate content ratio can be adopted within the range that does not impair the effect of the present invention. The fluorine-based additive is more effective than the polyol (A1) at the point of being able to further improve the take-up and unwinding performance or antistatic performance of the film with the adhesive layer according to the embodiment of the present invention without a separator. The content ratio of the total amount is preferably at least 0.01% by weight, more preferably 0.03% by weight to 30 parts by weight, further preferably 0.05 to 10 parts by weight, particularly preferably 0.05 to 1 part by weight.

就能夠更加表現本發明之效果之方面而言，氟系添加劑及下述矽酮系添加劑之合計量相對於多元醇(A1)總量之含有比率較佳為0.01重量%以上，更佳為0.03重量%～30重量份，進而較佳為0.05重量份～10重量份，尤佳為0.05重量份～1重量份。From the viewpoint that the effect of the present invention can be more expressed, the content ratio of the total amount of the fluorine-based additive and the following silicone-based additive to the total amount of the polyol (A1) is preferably 0.01% by weight or more, more preferably 0.03% by weight % by weight to 30 parts by weight, more preferably 0.05 to 10 parts by weight, most preferably 0.05 to 1 part by weight.

作為氟系添加劑，例如可例舉：選自含氟之化合物、含羥基之氟系化合物、含交聯性官能基之氟系化合物之至少1種。As the fluorine-based additive, for example, at least one selected from the group consisting of fluorine-containing compounds, hydroxyl-containing fluorine-based compounds, and crosslinkable functional group-containing fluorine-based compounds may be mentioned.

作為含氟之化合物，例如可例舉：具有氟脂肪族烴骨架之化合物、使有機化合物及氟系化合物共聚合而成之含氟之有機化合物、包含有機化合物之含氟之化合物。作為氟脂肪族烴骨架，例如可例舉：氟甲烷、氟乙烷、氟丙烷、氟異丙烷、氟丁烷、氟異丁烷、氟第三丁烷、氟戊烷、氟己烷等氟C1～C10烷烴。此處，「C1～C10」之標記意指碳數1～10。Examples of the fluorine-containing compound include a compound having a fluoroaliphatic hydrocarbon skeleton, a fluorine-containing organic compound obtained by copolymerizing an organic compound and a fluorine-based compound, and a fluorine-containing compound including an organic compound. Examples of the fluoroaliphatic hydrocarbon skeleton include fluoromethane, fluoroethane, fluoropropane, fluoroisopropane, fluorobutane, fluoroisobutane, fluorobutane, fluoropentane, and fluorohexane. C1～C10 alkanes. Here, the notation of "C1-C10" means 1-10 carbon atoms.

含氟之化合物之較佳之實施方式係具有含氟基、及親水性基及/或親油性基之低聚物(「特定氟系化合物」)。藉由採用此種「特定氟系化合物」，能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性或抗靜電性能。作為含氟基，代表性而言，可例舉：含氟之烷基(例如CF 3-等)及/或含氟之伸烷基(例如-CF 2-CF 2-等)。親水性基係指具有親水性之基，親水性於英語中被譯為「hydrophilic」，為業者通常已知之意為「對水具有親和性」之特性(例如，參照McGraw-Hill Dictionary of Scientific and Technical Terms(修訂第3版，日刊工業新聞社)等)。親油性基係指具有親油性之基，親油性於英語中被譯為「lipophilic」，為業者通常已知之意為「對油具有親和性」之特性(例如，參照McGraw-Hill Dictionary of Scientific and Technical Terms(修訂第3版，日刊工業新聞社)等)。 A preferred embodiment of the fluorine-containing compound is an oligomer having a fluorine-containing group, and a hydrophilic group and/or an lipophilic group (“specific fluorine-based compound”). By employing such a "specific fluorine compound", the film with the adhesive layer according to the embodiment of the present invention can be further improved in winding and unwinding properties or antistatic performance in a state without a separator. Typical examples of the fluorine-containing group include fluorine-containing alkyl groups (eg, CF 3 -, etc.) and/or fluorine-containing alkylene groups (eg, -CF 2 -CF 2 -, etc.). Hydrophilic group refers to a group with hydrophilicity, and hydrophilicity is translated as "hydrophilic" in English, which is a characteristic commonly known by the industry as "having an affinity for water" (for example, referring to McGraw-Hill Dictionary of Scientific and Technical Terms (Revised 3rd Edition, Nikkan Kogyo Shimbun, etc.). Lipophilic group refers to a group with lipophilicity. Lipophilicity is translated as "lipophilic" in English, which is a characteristic generally known by the industry as "having an affinity for oil" (for example, referring to McGraw-Hill Dictionary of Scientific and Technical Terms (Revised 3rd Edition, Nikkan Kogyo Shimbun, etc.).

作為含氟之化合物，就能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性或抗靜電性能之方面而言，製成0.1%甲苯溶液之情形時之表面張力較佳為19.0 mN/m～26.0 mN/m(甲苯之表面張力為27.9 mN/m)。As a fluorine-containing compound, 0.1% is used to further improve the take-up and unwinding performance or antistatic performance of the film with the adhesive layer according to the embodiment of the present invention without a separator. In the case of a toluene solution, the surface tension is preferably 19.0 mN/m to 26.0 mN/m (the surface tension of toluene is 27.9 mN/m).

作為含氟之化合物，就能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性或抗靜電性能之方面而言，製成0.1%甲苯溶液之情形時之表面張力較佳為26.0 mN/m～28.0 mN/m(甲苯之表面張力為27.9 mN/m)。As a fluorine-containing compound, 0.1% is used to further improve the take-up and unwinding performance or antistatic performance of the film with the adhesive layer according to the embodiment of the present invention without a separator. In the case of a toluene solution, the surface tension is preferably 26.0 mN/m to 28.0 mN/m (the surface tension of toluene is 27.9 mN/m).

關於含氟之化合物，作為市售品，例如可例舉如下所述者。As a commercial item about a fluorine-containing compound, the following are mentioned, for example.

DIC股份有限公司製造之Megafac系列： 代表性而言，有「Megafac F-114」、「Megafac F-251」、「Megafac F-253」、「Megafac F-281」、「Megafac F-410」、「Megafac F-430」、「Megafac F-444」、「Megafac F-477」、「Megafac F-510」、「Megafac F-551-A」、「Megafac F-553」、「Megafac F-554」、「Megafac F-555-A」、「Megafac F-556」、「Megafac F-557」、「Megafac F-558」、「Megafac F-559」、「Megafac F-560」、「Megafac F-561」、「Megafac F-562」、「Megafac F-563」、「Megafac F-565」、「Megafac F-568」、「Megafac F-569」、「Megafac F-570」、「Megafac F-576」、「Megafac R-01」、「Megafac R-40」、「Megafac R-40-LM」、「Megafac R-41」、「Megafac R-41-LM」、「Megafac R-94」、「Megafac RS-56」、「Megafac RS-72-K」、「Megafac RS-75-A」、「Megafac RS-75-NS」、「Megafac RS-78」、「Megafac RS-90」等。 Megafac series manufactured by DIC Co., Ltd.: Representatively, there are "Megafac F-114", "Megafac F-251", "Megafac F-253", "Megafac F-281", "Megafac F-410", "Megafac F-430", "Megafac F-444", "Megafac F-477", "Megafac F-510", "Megafac F-551-A", "Megafac F-553", "Megafac F-554", "Megafac F-555-A" , "Megafac F-556", "Megafac F-557", "Megafac F-558", "Megafac F-559", "Megafac F-560", "Megafac F-561", "Megafac F-562", "Megafac F-563", "Megafac F-565", "Megafac F-568", "Megafac F-569", "Megafac F-570", "Megafac F-576", "Megafac R-01", " Megafac R-40", "Megafac R-40-LM", "Megafac R-41", "Megafac R-41-LM", "Megafac R-94", "Megafac RS-56", "Megafac RS-72 -K", "Megafac RS-75-A", "Megafac RS-75-NS", "Megafac RS-78", "Megafac RS-90", etc.

AGC Seimi Chemical股份有限公司製造之Surflon系列： 代表性而言，有「S-242」、「S-243」、「S-386」等。 Surflon series manufactured by AGC Seimi Chemical Co., Ltd.: Typically, there are "S-242", "S-243", and "S-386".

Sumitomo 3M股份有限公司製造之FC系列： 代表性而言，有「FC-4430」、「FC-4432」等。 FC series manufactured by Sumitomo 3M Co., Ltd.: Representatively, there are "FC-4430", "FC-4432" and the like.

Neos股份有限公司製造之Ftergent系列： 代表性而言，有「Ftergent 100」、「Ftergent 100C」、「Ftergent 110」、「Ftergent 150」、「Ftergent 150CH」、「Ftergent 250」、「Ftergent 400SW」等。 Ftergent series manufactured by Neos Co., Ltd.: Typically, there are "Ftergent 100", "Ftergent 100C", "Ftergent 110", "Ftergent 150", "Ftergent 150CH", "Ftergent 250", "Ftergent 400SW" and the like.

北村化學產業股份有限公司製造之PF系列： 代表性而言，有「PF-136A」、「PF-156A」、「PF-151N」、「PF-636」、「PF-6320」、「PF-656」、「PF-6520」、「PF-651」、「PF-652」、「PF-3320」等。 PF series manufactured by Kitamura Chemical Industry Co., Ltd.: Representatively, there are "PF-136A", "PF-156A", "PF-151N", "PF-636", "PF-6320", "PF-656", "PF-6520", "PF -651", "PF-652", "PF-3320", etc.

作為含羥基之氟系化合物，例如可使用先前公知之樹脂，例如可例舉：國際公開第94/06870號說明書、日本專利特開平8-12921號公報、日本專利特開平10-72569號公報、日本專利特開平4-275379號公報、國際公開第97/11130號說明書、國際公開第96/26254號說明書等所記載之含羥基之氟樹脂。作為其他含羥基之氟樹脂，例如可例舉：日本專利特開平8-231919號公報、日本專利特開平10-265731號公報、日本專利特開平10-204374號公報、日本專利特開平8-12922號公報等所記載之氟烯烴共聚物等。此外，可例舉：含羥基之化合物中具有經氟化之烷基的化合物之共聚物、使含羥基之化合物與含氟之化合物共聚合而成的含氟之有機化合物、含有含羥基之有機化合物之含氟之化合物。關於此種含羥基之氟系化合物，作為市售品，例如可例舉：商品名「Lumiflon」(旭硝子股份有限公司製造)、商品名「Cefral coat」(Central Glass股份有限公司製造)、商品名「Zaflon」(東亞合成股份有限公司製造)、商品名「Zeffle」(大金工業股份有限公司製造)。As the hydroxyl group-containing fluorine-based compound, for example, previously known resins can be used, for example: International Publication No. 94/06870 Specification, Japanese Patent Laid-Open No. 8-12921, Japanese Patent Laid-Open No. 10-72569, Hydroxyl-containing fluororesins described in Japanese Patent Laid-Open No. 4-275379, International Publication No. 97/11130, International Publication No. 96/26254, etc. Other hydroxyl-containing fluororesins include, for example, Japanese Patent Laid-Open No. 8-231919, Japanese Patent Laid-Open No. 10-265731, Japanese Patent Laid-Open No. 10-204374, and Japanese Patent Laid-Open No. 8-12922. Fluoroolefin copolymers and the like described in Publication No. In addition, examples include: copolymers of compounds having a fluorinated alkyl group among hydroxyl-containing compounds, fluorine-containing organic compounds obtained by copolymerizing a hydroxyl-containing compound and a fluorine-containing compound, organic compounds containing hydroxyl groups Compounds are fluorine-containing compounds. Commercially available examples of such hydroxyl-containing fluorine-based compounds include: trade name "Lumiflon" (manufactured by Asahi Glass Co., Ltd.), trade name "Cefral coat" (manufactured by Central Glass Co., Ltd.), trade name "Zaflon" (manufactured by Toa Gosei Co., Ltd.), brand name "Zeffle" (manufactured by Daikin Industries Co., Ltd.).

作為含交聯性官能基之氟系化合物，例如可例舉：全氟辛酸等之類之具有經氟化之烷基之羧氧化合物、含交聯性官能基之化合物中具有經氟化之烷基的化合物之共聚物、使含交聯性官能基之化合物與含氟之化合物共聚合而成的含氟之有機化合物、含有含交聯性官能基之化合物之含氟之化合物。作為此種含交聯性官能基之氟系化合物，作為市售品，例如可例舉：商品名「Megafac F-570」、「Megafac RS-55」、「Megafac RS-56」、「Megafac RS-72-K」、「Megafac RS-75」、「Megafac RS-76-E」、「Megafac RS-76-NS」、「Megafac RS-78」、「Megafac RS-90」(DIC股份有限公司製造)。Examples of the crosslinkable functional group-containing fluorine-based compound include carboxylate compounds having a fluorinated alkyl group such as perfluorooctanoic acid, and crosslinkable functional group-containing compounds having a fluorinated alkyl group. A copolymer of a compound containing a crosslinkable functional group, a fluorine-containing organic compound obtained by copolymerizing a crosslinkable functional group-containing compound and a fluorine-containing compound, or a fluorine-containing compound containing a crosslinkable functional group-containing compound. Such crosslinkable functional group-containing fluorine-based compounds are commercially available, for example: trade names "Megafac F-570", "Megafac RS-55", "Megafac RS-56", "Megafac RS -72-K", "Megafac RS-75", "Megafac RS-76-E", "Megafac RS-76-NS", "Megafac RS-78", "Megafac RS-90" (manufactured by DIC Co., Ltd. ).

可以市售品之形式而獲取之含氟之化合物之中，作為與上述「具有含氟基、及親水性基及/或親油性基之低聚物」相符者，代表性而言，可例舉：DIC股份有限公司製造之 「Megafac F-477」(含有含氟基、親水性基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝26.4 mN/m)、 「Megafac F-551-A」(含有含氟基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝25.6 mN/m)、 「Megafac F-553」(含有含氟基、親水性基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝26.4 mN/m)、 「Megafac F-554」(含有含氟基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝25.0 mN/m)、 「Megafac F-555-A」(含有含氟基、親水性基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝20.4 mN/m)、 「Megafac F-557」(含有含氟基、親水性基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝26.3 mN/m)、 「Megafac F-559」(含有含氟基、親水性基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝26.1 mN/m)、 「Megafac F-563」(含有含氟基、親油性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝20.2 mN/m)、 「Megafac F-569」(含有含氟基、親水性基之低聚物，設為0.1%甲苯溶液之情形時之表面張力＝19.7 mN/m)等。 Among the commercially available fluorine-containing compounds, those corresponding to the above-mentioned "oligomer having a fluorine-containing group and a hydrophilic group and/or lipophilic group" are representatively exemplified Example: Manufactured by DIC Co., Ltd. "Megafac F-477" (an oligomer containing fluorine-containing groups, hydrophilic groups, and lipophilic groups, surface tension = 26.4 mN/m in the case of a 0.1% toluene solution), "Megafac F-551-A" (Oligomer containing fluorine-containing and lipophilic groups, surface tension = 25.6 mN/m in the case of 0.1% toluene solution), "Megafac F-553" (an oligomer containing fluorine-containing groups, hydrophilic groups, and lipophilic groups, surface tension = 26.4 mN/m in the case of a 0.1% toluene solution), "Megafac F-554" (an oligomer containing fluorine-containing and lipophilic groups, surface tension = 25.0 mN/m in the case of a 0.1% toluene solution), "Megafac F-555-A" (an oligomer containing fluorine-containing groups, hydrophilic groups, and lipophilic groups, surface tension = 20.4 mN/m in the case of 0.1% toluene solution), "Megafac F-557" (an oligomer containing fluorine-containing groups, hydrophilic groups, and lipophilic groups, surface tension = 26.3 mN/m in the case of a 0.1% toluene solution), "Megafac F-559" (an oligomer containing fluorine-containing groups, hydrophilic groups, and lipophilic groups, surface tension = 26.1 mN/m in the case of a 0.1% toluene solution), "Megafac F-563" (an oligomer containing fluorine-containing groups and lipophilic groups, surface tension in the case of a 0.1% toluene solution = 20.2 mN/m), "Megafac F-569" (an oligomer containing a fluorine-containing group and a hydrophilic group, surface tension = 19.7 mN/m when used as a 0.1% toluene solution), etc.

(矽酮系添加劑) 若包含矽酮系添加劑作為其他成分，則能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性。 (Silicone-based additives) When a silicone-based additive is included as another component, the wind-up and unwinding properties of the film with the adhesive layer according to the embodiment of the present invention can be further improved in a state without a separator.

作為矽酮系添加劑，可於不損害本發明之效果之範圍內採用任意適當之矽酮系添加劑。As the silicone-based additive, any appropriate silicone-based additive can be employed within the range that does not impair the effects of the present invention.

矽酮系添加劑可僅為1種，亦可為2種以上。Only one type of silicone additive may be used, or two or more types may be used.

作為矽酮系添加劑之含有比率，可於不損害本發明之效果之範圍內採用任意適當之含有比率。就能夠更加提高本發明之實施方式的附黏著劑層之膜在無隔離件之狀態下之捲取性及捲出性之方面而言，矽酮系添加劑相對於多元醇(A1)總量之含有比率較佳為0.01重量%以上，更佳為0.015重量%～30重量份，進而較佳為0.02重量份～10重量份，尤佳為0.025重量份～1重量份。As the content ratio of the silicone-based additive, any appropriate content ratio can be adopted within the range that does not impair the effect of the present invention. In terms of improving the winding-up and unwinding properties of the adhesive layer-attached film according to the embodiment of the present invention without a separator, the amount of silicone-based additives relative to the total amount of polyol (A1) The content ratio is preferably at least 0.01% by weight, more preferably 0.015% by weight to 30 parts by weight, further preferably 0.02 to 10 parts by weight, and particularly preferably 0.025 to 1 part by weight.

就能夠更加表現本發明之效果之方面而言，上述氟系添加劑及矽酮系添加劑之合計量相對於多元醇(A1)總量之含有比率較佳為0.01重量%以上，更佳為0.03重量%～30重量份，進而較佳為0.05重量份～10重量份，尤佳為0.05重量份～1重量份。From the point where the effects of the present invention can be more expressed, the content ratio of the total amount of the above-mentioned fluorine-based additives and silicone-based additives to the total amount of the polyol (A1) is preferably 0.01% by weight or more, more preferably 0.03% by weight % to 30 parts by weight, more preferably 0.05 to 10 parts by weight, especially preferably 0.05 to 1 part by weight.

矽酮系添加劑可於不損害本發明之效果之範圍內採用任意適當之矽酮系添加劑。作為此種矽酮系添加劑，例如可例舉：反應性矽酮油、非反應性矽酮油。Silicone-based additive Any appropriate silicone-based additive can be used within the range that does not impair the effect of the present invention. Examples of such silicone-based additives include reactive silicone oil and non-reactive silicone oil.

作為反應性矽酮油，例如可例舉：側鏈型反應性矽酮油，其中有機基作為側鏈鍵結於用於矽氧烷鍵之Si原子；兩末端型反應性矽酮油，其中有機基鍵結於位於結構之兩末端之Si原子；單末端型反應性矽酮油，其中有機基僅鍵結於位於結構之兩末端之Si原子之一者；側鏈兩末端型反應性矽酮油，其中有機基作為側鏈鍵結於用於矽氧烷鍵之Si原子，且有機基鍵結於位於結構之兩末端之Si原子。As the reactive silicone oil, for example, a side chain type reactive silicone oil in which an organic group is bonded as a side chain to the Si atom for a siloxane bond; a double-terminal type reactive silicone oil in which The organic group is bonded to the Si atoms located at both ends of the structure; the single-terminal reactive silicone oil, in which the organic group is only bonded to one of the Si atoms located at the two ends of the structure; the side chain two-terminal reactive silicon oil Ketone oil in which organic groups are bonded to Si atoms for siloxane bonds as side chains, and organic groups are bonded to Si atoms located at both ends of the structure.

作為側鏈型反應性矽酮油，例如可例舉：胺基改性類型之側鏈型反應性矽酮油、環氧改性類型之側鏈型反應性矽酮油、甲醇改性類型之側鏈型反應性矽酮油、巰基改性類型之側鏈型反應性矽酮油、羧基改性類型之側鏈型反應性矽酮油、甲基氫矽酮油類型之側鏈型反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之側鏈型反應性矽酮油所市售之各種矽酮油。Examples of side chain reactive silicone oils include: amino-modified type side chain type reactive silicone oil, epoxy modified type side chain type reactive silicone oil, methanol modified type Side-chain reactive silicone oil, mercapto-modified side-chain reactive silicone oil, carboxyl-modified side-chain reactive silicone oil, methylhydrogen silicone oil-based side-chain reactive Silicone oil. As such commercially available products, for example, various silicone oils marketed as side chain type reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd. may be mentioned.

作為兩末端型反應性矽酮油，例如可例舉：胺基改性類型之兩末端型反應性矽酮油、環氧改性類型之兩末端型反應性矽酮油、甲醇改性類型之兩末端型反應性矽酮油、甲基丙烯酸改性類型之兩末端型反應性矽酮油、聚醚改性類型之兩末端型反應性矽酮油、巰基改性類型之兩末端型反應性矽酮油、羧基改性類型之兩末端型反應性矽酮油、酚改性類型之兩末端型反應性矽酮油、矽烷醇末端類型之兩末端型反應性矽酮油、丙烯酸改性類型之兩末端型反應性矽酮油、羧酸酐改性類型之兩末端型反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之兩末端型反應性矽酮油所市售之各種矽酮油。特別是可較佳採用信越化學工業公司製造之「KF-6000」、「KF-6001」、「KF-6002」、「KF-6003」、「KF-6028」等甲醇改性類型之兩末端型反應性矽酮油。Examples of double-terminal reactive silicone oils include: amino-modified double-terminal reactive silicone oil, epoxy-modified double-terminal reactive silicone oil, and methanol-modified silicone oil. Both-terminal reactive silicone oil, methacrylic acid-modified double-terminal reactive silicone oil, polyether-modified double-terminal reactive silicone oil, mercapto-modified double-terminal reactive silicone oil Silicone oil, carboxyl-modified double-terminal reactive silicone oil, phenol-modified double-terminal reactive silicone oil, silanol-terminated double-terminal reactive silicone oil, acrylic modified type Two-terminal reactive silicone oil, carboxylic acid anhydride modified two-terminal reactive silicone oil. Examples of such commercially available products include various silicone oils marketed as both-terminal-reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd. In particular, the two-terminal type of methanol modified type such as "KF-6000", "KF-6001", "KF-6002", "KF-6003", and "KF-6028" manufactured by Shin-Etsu Chemical Co., Ltd. can be preferably used Reactive silicone oil.

作為單末端型反應性矽酮油，例如可例舉：單末端反應性改性類型之單末端型反應性矽酮油、平均單末端羧基改性類型之單末端型反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之單末端型反應性矽酮油所市售之各種矽酮油。特別是可較佳採用信越化學工業公司製造之「X-22-170BX」、「X-22-170DX」、「X-22-4015」等甲醇改性類型之單末端型反應性矽酮油。Examples of the single-end reactive silicone oil include single-end reactive silicone oil of a single-end reactive modification type, and single-end reactive silicone oil of an average single-end carboxyl group-modified type. Examples of such commercially available products include various silicone oils marketed as single-end reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd., for example. In particular, methanol-modified single-end reactive silicone oils such as "X-22-170BX", "X-22-170DX", and "X-22-4015" manufactured by Shin-Etsu Chemical Co., Ltd. can be preferably used.

作為側鏈兩末端型反應性矽酮油，例如可例舉：側鏈胺基-兩末端甲氧基改性類型之側鏈兩末端型反應性矽酮油、環氧改性類型之側鏈兩末端型反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之側鏈兩末端型反應性矽酮油所市售之各種矽酮油。Examples of side chain two-terminal reactive silicone oils include side chain amino-two-terminal methoxy modified side chain two-terminal reactive silicone oils, and epoxy-modified side chains. Two-terminal reactive silicone oil. Examples of such commercially available products include various silicone oils marketed as side chain double-terminal-type reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd., for example.

作為非反應性矽酮油，例如可例舉：側鏈型非反應性矽酮油，其中有機基作為側鏈鍵結於用於矽氧烷鍵之Si原子；兩末端型非反應性矽酮油，其中有機基鍵結於位於結構之兩末端之Si原子。As the non-reactive silicone oil, for example, a side-chain type non-reactive silicone oil in which an organic group is bonded as a side chain to a Si atom for a siloxane bond; a double-terminal type non-reactive silicone oil Oil in which organic groups are bonded to Si atoms located at both ends of the structure.

作為側鏈型非反應性矽酮油，例如可例舉：聚醚改性類型之側鏈型非反應性矽酮油、芳烷基改性類型之側鏈型非反應性矽酮油、氟烷基改性類型之側鏈型非反應性矽酮油、長鏈烷基改性類型之側鏈型非反應性矽酮油、高級脂肪酸酯改性類型之側鏈型非反應性矽酮油、高級脂肪酸含有類型之側鏈型非反應性矽酮油、苯基改性類型之側鏈型非反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之側鏈型非反應性矽酮油所市售之各種矽酮油。特別是可較佳採用信越化學工業公司製造之「KF-351A」、「KF-352A」、「KF-353」、「KF-354L」、「KF-355A」、「KF-615A」、「KF-945」、「KF-640」、「KF-642」、「KF-643」、「KF-644」、「KF-6020」、「KF-6204」、「X-22-4515」等聚醚改性類型之側鏈型非反應性矽酮油。Examples of side-chain non-reactive silicone oils include polyether-modified side-chain non-reactive silicone oils, aralkyl-modified side-chain non-reactive silicone oils, fluorine Alkyl-modified side-chain non-reactive silicone oil, long-chain alkyl-modified side-chain non-reactive silicone oil, advanced fatty acid ester-modified side-chain non-reactive silicone Oil, higher fatty acid containing side chain type non-reactive silicone oil, phenyl modified type side chain type non-reactive silicone oil. Examples of such commercially available products include various silicone oils marketed as side-chain type non-reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd., for example. In particular, "KF-351A", "KF-352A", "KF-353", "KF-354L", "KF-355A", "KF-615A", "KF -945", "KF-640", "KF-642", "KF-643", "KF-644", "KF-6020", "KF-6204", "X-22-4515" and other polyethers Modified side chain type non-reactive silicone oil.

該等聚醚改性類型之側鏈型非反應性矽酮油之中，能夠更加降低糊劑殘留性之方面而言，較佳為HLB(Hydrophile Lipophile Balance，親水親油平衡)值較佳為8以上、更佳為9以上、進而較佳為10以上之聚醚改性類型之側鏈型非反應性矽酮油。作為此種聚醚改性類型之側鏈型非反應性矽酮油，例如可例舉：「KF-351A」(HLB＝12)、「KF-353」(HLB＝10)、「KF-354L」(HLB＝16)、「KF-355A」(HLB＝12)、「KF-615A」(HLB＝10)、「KF-640」(HLB＝14)、「KF-642」(HLB＝12)、「KF-643」(HLB＝14)、「KF-644」(HLB＝11)、「KF-6204」(HLB＝10)。Among these polyether-modified side-chain non-reactive silicone oils, the HLB (Hydrophile Lipophile Balance) value is preferably 8 or more, more preferably 9 or more, and more preferably 10 or more, polyether-modified side-chain non-reactive silicone oil. Examples of such polyether-modified side-chain non-reactive silicone oils include: "KF-351A" (HLB=12), "KF-353" (HLB=10), "KF-354L "(HLB=16), "KF-355A"(HLB=12), "KF-615A"(HLB=10), "KF-640"(HLB=14), "KF-642"(HLB=12) , "KF-643" (HLB=14), "KF-644" (HLB=11), "KF-6204" (HLB=10).

作為兩末端型非反應性矽酮油，例如可例舉：聚醚改性類型之兩末端型非反應性矽酮油。作為該等市售品，例如可例舉：作為信越化學工業公司製造之兩末端型非反應性矽酮油所市售之各種矽酮油。特別是可較佳採用信越化學工業公司製造之「KF-6004」等聚醚改性類型之兩末端型非反應性矽酮油。Examples of the double-end type non-reactive silicone oil include polyether-modified double-end type non-reactive silicone oil. As such commercially available products, for example, various silicone oils marketed as both-end type non-reactive silicone oils manufactured by Shin-Etsu Chemical Co., Ltd. may be mentioned. In particular, polyether-modified double-terminal non-reactive silicone oils such as "KF-6004" manufactured by Shin-Etsu Chemical Co., Ltd. can be preferably used.

作為矽酮系添加劑，可採用除上述以外先前公知之任意適當之矽酮系添加劑。作為此種矽酮系添加劑，例如可例舉：除上述以外之含矽氧烷鍵之聚合物、除上述以外之含羥基之矽酮系化合物、除上述以外之含交聯性官能基之矽酮系化合物。As the silicone-based additive, any appropriate conventionally known silicone-based additive other than the above can be used. Examples of such silicone-based additives include siloxane bond-containing polymers other than the above, hydroxyl-containing silicone compounds other than the above, and crosslinkable functional group-containing silicon compounds other than the above. Ketones.

作為除上述以外之含矽氧烷鍵之聚合物之市售品，例如可例舉：商品名「LE-302」(共榮社化學股份有限公司製造)、BYK-Chemie Japan股份有限公司製造之BYK系列之整平劑(「BYK-300」、「BYK-301/302」、「BYK-306」、「BYK-307」、「BYK-310」、「BYK-315」、「BYK-313」、「BYK-320」、「BYK-322」、「BYK-323」、「BYK-325」、「BYK-330」、「BYK-331」、「BYK-333」、「BYK-337」、「BYK-341」、「BYK-344」、「BYK-345/346」、「BYK-347」、「BYK-348」、「BYK-349」、「BYK-370」、「BYK-375」、「BYK-377」、「BYK-378」、「BYK-UV3500」、「BYK-UV3510」、「BYK-UV3570」、「BYK-3550」、「BYK-SILCLEAN3700」、「BYK-SILCLEAN3720」等)、Algin Chemie公司製造之AC系列之整平劑(「AC FS180」、「AC FS360」、「AC S20」等)、共榮社化學股份有限公司製造之Polyflow系列之整平劑(「Polyflow KL-400X」、「Polyflow KL-400HF」、「Polyflow KL-401」、「Polyflow KL-402」、「Polyflow KL-403」、「Polyflow KL-404」等)、信越化學工業股份有限公司製造之KP系列之整平劑(「KP-323」、「KP-326」、「KP-341」、「KP-104」、「KP-110」、「KP-112」等)、東麗道康寧股份有限公司製造之整平劑(「LP-7001」、「LP-7002」、「8032ADDITIVE」、「57ADDITIVE」、「L-7604」、「FZ-2110」、「FZ-2105」、「67ADDITIVE」、「8618ADDITIVE」、「3ADDITIVE」、「56ADDITIVE」等)。As commercial products of siloxane bond-containing polymers other than the above, for example: trade name "LE-302" (manufactured by Kyoeisha Chemical Co., Ltd.), manufactured by BYK-Chemie Japan Co., Ltd. Leveling agent of BYK series ("BYK-300", "BYK-301/302", "BYK-306", "BYK-307", "BYK-310", "BYK-315", "BYK-313" , "BYK-320", "BYK-322", "BYK-323", "BYK-325", "BYK-330", "BYK-331", "BYK-333", "BYK-337", " BYK-341", "BYK-344", "BYK-345/346", "BYK-347", "BYK-348", "BYK-349", "BYK-370", "BYK-375", " BYK-377", "BYK-378", "BYK-UV3500", "BYK-UV3510", "BYK-UV3570", "BYK-3550", "BYK-SILCLEAN3700", "BYK-SILCLEAN3720", etc.), Algin AC series leveling agents manufactured by Chemie ("AC FS180", "AC FS360", "AC S20", etc.), Polyflow series leveling agents manufactured by Kyoeisha Chemical Co., Ltd. ("Polyflow KL-400X" , "Polyflow KL-400HF", "Polyflow KL-401", "Polyflow KL-402", "Polyflow KL-403", "Polyflow KL-404", etc.), Shin-Etsu Chemical Co., Ltd. manufactured the KP series Leveling agents ("KP-323", "KP-326", "KP-341", "KP-104", "KP-110", "KP-112", etc.), manufactured by Toray Dow Corning Co., Ltd. Leveling agents ("LP-7001", "LP-7002", "8032ADDITIVE", "57ADDITIVE", "L-7604", "FZ-2110", "FZ-2105", "67ADDITIVE", "8618ADDITIVE", " 3ADDITIVE", "56ADDITIVE", etc.).

作為除上述以外之含羥基之矽酮之市售品，例如可例舉：BYK-Chemie Japan股份有限公司製造之「BYK-370」、「BYK-SILCLEAN3700」、「BYK-SILCLEAN3720」。As a commercial item of the hydroxyl-containing silicone other than the above, "BYK-370", "BYK-SILCLEAN3700", and "BYK-SILCLEAN3720" by BYK-Chemie Japan Co., Ltd. are mentioned, for example.

作為除上述以外之含交聯性官能基之矽酮系化合物之市售品，例如可例舉：東麗道康寧股份有限公司製造之「BY16-855」、「SF8413」、「BY16-839」、「SF8421」、「BY16-750」、「BY16-880」、「BY16-152C」。Examples of commercially available crosslinkable functional group-containing silicone compounds other than those mentioned above include "BY16-855", "SF8413", "BY16-839" manufactured by Toray Dow Corning Co., Ltd., "SF8421", "BY16-750", "BY16-880", "BY16-152C".

(抗劣化劑) 關於胺基甲酸酯系黏著劑組合物，就抑制胺基甲酸酯系黏著劑之劣化等方面而言，胺基甲酸酯系黏著劑組合物亦可包含抗劣化劑作為其他成分。抗劣化劑可僅為1種，亦可為2種以上。 (anti-deterioration agent) Regarding the urethane-based adhesive composition, the urethane-based adhesive composition may contain an anti-deterioration agent as another component from the viewpoint of suppressing deterioration of the urethane-based adhesive. The anti-deterioration agent may be only 1 type, and may be 2 or more types.

作為抗劣化劑，例如可例舉：抗氧化劑、紫外線吸收劑、光穩定劑。As an anti-deterioration agent, an antioxidant, a ultraviolet absorber, and a light stabilizer are mentioned, for example.

抗氧化劑可僅為1種，亦可為2種以上。Antioxidant may be only 1 type, and may be 2 or more types.

胺基甲酸酯系黏著劑組合物中之抗氧化劑之含有比率可於不損害本發明之效果之範圍內採用任意適當之含有比率。關於此種含有比率，抗氧化劑相對於多元醇(A1)總量之含有比率較佳為0.01重量%～10重量%以上，更佳為0.05重量%～5重量%，進而較佳為0.1重量%～3重量%，尤佳為0.2重量%～1重量%。The content rate of the antioxidant in a urethane type adhesive composition can employ|adopt arbitrary appropriate content rate in the range which does not impair the effect of this invention. Regarding such a content ratio, the content ratio of the antioxidant to the total amount of the polyol (A1) is preferably 0.01% by weight to 10% by weight or more, more preferably 0.05% by weight to 5% by weight, and still more preferably 0.1% by weight ~3% by weight, especially preferably 0.2% by weight to 1% by weight.

作為抗氧化劑，例如可例舉：自由基鏈抑制劑、過氧化物分解劑。As an antioxidant, a radical chain inhibitor and a peroxide decomposer are mentioned, for example.

作為自由基鏈抑制劑，例如可例舉：酚系抗氧化劑、胺系抗氧化劑。As a radical chain inhibitor, a phenolic antioxidant and an amine antioxidant are mentioned, for example.

作為過氧化物分解劑，例如可例舉：硫系抗氧化劑、磷系抗氧化劑。As a peroxide decomposing agent, a sulfur type antioxidant and a phosphorus type antioxidant are mentioned, for example.

作為酚系抗氧化劑，例如可例舉：單酚系抗氧化劑、雙酚系抗氧化劑、高分子型酚系抗氧化劑。As a phenolic antioxidant, a monophenolic antioxidant, a bisphenolic antioxidant, a polymer type phenolic antioxidant is mentioned, for example.

作為單酚系抗氧化劑，例如可例舉：2,6-二第三丁基-對甲酚、丁基化羥基甲氧苯、2,6-二第三丁基-4-乙基苯酚、硬脂-β-(3,5-二第三丁基-4-羥基苯基)丙酸酯。Examples of monophenolic antioxidants include 2,6-di-tert-butyl-p-cresol, butylated hydroxymethoxybenzene, 2,6-di-tert-butyl-4-ethylphenol, Stearyl-β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate.

作為雙酚系抗氧化劑，例如可例舉：2,2'-亞甲基雙(4-甲基-6-第三丁基苯酚)、2,2'-亞甲基雙(4-乙基-6-第三丁基苯酚)、4,4'-硫代雙(3-甲基-6-第三丁基苯酚)、4,4'-亞丁基雙(3-甲基-6-第三丁基苯酚)、3,9-雙[1,1-二甲基-2-[β-(3-第三丁基-4-羥基-5-甲基苯基)丙醯氧基]乙基]2,4,8,10-四氧雜螺[5,5]十一烷。Examples of bisphenol-based antioxidants include 2,2'-methylenebis(4-methyl-6-tert-butylphenol), 2,2'-methylenebis(4-ethyl -6-tert-butylphenol), 4,4'-thiobis(3-methyl-6-tert-butylphenol), 4,4'-butylenebis(3-methyl-6-th Tributylphenol), 3,9-bis[1,1-dimethyl-2-[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl base] 2,4,8,10-tetraoxaspiro[5,5]undecane.

作為高分子型酚系抗氧化劑，例如可例舉：1,1,3-三(2-甲基-4-羥基-5-第三丁基苯基)丁烷、1,3,5-三甲基-2,4,6-三(3,5-二第三丁基-4-羥基苄基)苯、四-[亞甲基-3-(3',5'-二第三丁基-4'-羥基苯基)丙酸酯]甲烷、雙[3,3'-雙-(4'-羥基-3'-第三丁基苯基)酪酸]二醇酯、1,3,5-三(3',5'-二第三丁基-4'-羥基苄基)-S-三𠯤-2,4,6-(1H、3H、5H)三酮、生育酚。Examples of polymeric phenolic antioxidants include 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane, 1,3,5-tris Methyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene, tetrakis-[methylene-3-(3',5'-di-tert-butyl -4'-hydroxyphenyl)propionate]methane, bis[3,3'-bis-(4'-hydroxy-3'-tert-butylphenyl)butyrate]diol, 1,3,5 - Tris(3',5'-di-tert-butyl-4'-hydroxybenzyl)-S-tris-2,4,6-(1H,3H,5H)trione, tocopherol.

作為硫系抗氧化劑，例如可例舉：3,3'-硫代二丙酸二月桂酯、3,3'-硫代二丙酸二肉豆蔻酯、3,3'-硫代二丙酸二硬脂酯。Examples of sulfur-based antioxidants include dilauryl 3,3'-thiodipropionate, dimyristyl 3,3'-thiodipropionate, and 3,3'-thiodipropionate Distearyl.

作為磷系抗氧化劑，例如可例舉：亞磷酸三苯酯、亞磷酸二苯基異癸酯、亞磷酸苯基二異癸酯。As a phosphorus antioxidant, triphenyl phosphite, diphenylisodecyl phosphite, and phenyl diisodecyl phosphite are mentioned, for example.

紫外線吸收劑可僅為1種，亦可為2種以上。The ultraviolet absorber may be only 1 type, and may be 2 or more types.

胺基甲酸酯系黏著劑組合物中之紫外線吸收劑之含有比率可於不損害本發明之效果之範圍內採用任意適當之含有比率。關於此種含有比率，紫外線吸收劑相對於多元醇(A1)總量之含有比率較佳為0.01重量%～10重量%以上，更佳為0.05重量%～5重量%，進而較佳為0.1重量%～3重量%，尤佳為0.2重量%～1重量%。The content rate of the ultraviolet absorber in a urethane type adhesive composition can employ|adopt arbitrary appropriate content rate in the range which does not impair the effect of this invention. Regarding such a content ratio, the content ratio of the ultraviolet absorber to the total amount of the polyol (A1) is preferably 0.01% by weight to 10% by weight or more, more preferably 0.05% by weight to 5% by weight, and still more preferably 0.1% by weight. % to 3% by weight, particularly preferably 0.2% to 1% by weight.

作為紫外線吸收劑，例如可例舉：二苯甲酮系紫外線吸收劑、苯并***系紫外線吸收劑、水楊酸系紫外線吸收劑、草酸苯胺系紫外線吸收劑、丙烯酸氰酯系紫外線吸收劑、三𠯤系紫外線吸收劑。Examples of the ultraviolet absorber include: benzophenone-based ultraviolet absorbers, benzotriazole-based ultraviolet absorbers, salicylic acid-based ultraviolet absorbers, oxalic acid aniline-based ultraviolet absorbers, cyanoacrylate-based ultraviolet absorbers , Three 𠯤 UV absorbers.

作為二苯甲酮系紫外線吸收劑，例如可例舉：2,4-二羥基二苯甲酮、2-羥基-4-甲氧基二苯甲酮、2-羥基-4-辛氧基二苯甲酮、2-羥基-4-十二烷氧基二苯甲酮、2,2'-二羥基-4-二甲氧基二苯甲酮、2,2'-二羥基-4,4'-二甲氧基二苯甲酮、2-羥基-4-甲氧基-5-磺基二苯甲酮、雙(2-甲氧基-4-羥基-5-苯甲醯基苯基)甲烷。Examples of benzophenone-based ultraviolet absorbers include 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octyloxydiphenone, Benzophenone, 2-hydroxy-4-dodecyloxybenzophenone, 2,2'-dihydroxy-4-dimethoxybenzophenone, 2,2'-dihydroxy-4,4 '-Dimethoxybenzophenone, 2-hydroxy-4-methoxy-5-sulfobenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl ) methane.

作為苯并***系紫外線吸收劑，例如可例舉：2-(2'-羥基-5'-甲基苯基)苯并***、2-(2'-羥基-5'-第三丁基苯基)苯并***、2-(2'-羥基-3',5'-二第三丁基苯基)苯并***、2-(2'-羥基-3'-第三丁基-5'-甲基苯基)-5-氯苯并***、2-(2'-羥基-3',5'-二第三丁基苯基)5-氯苯并***、2-(2'-羥基-3',5'-二第三戊基苯基)苯并***、2-(2'-羥基-4'-辛氧基苯基)苯并***、2-[2'-羥基-3'-(3'',4'',5'',6'',-四氫鄰苯二甲醯亞胺甲基)-5'-甲基苯基]苯并***、2,2'-亞甲基雙[4-(1,1,3,3-四甲基丁基)-6-(2H-苯并***-2-基)苯酚]、[2(2'-羥基-5'-甲基丙烯醯氧基苯基)-2H-苯并***。Examples of benzotriazole-based ultraviolet absorbers include 2-(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-5'-tert-butyl phenyl)benzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-3'-tert-butyl Base-5'-methylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)5-chlorobenzotriazole, 2 -(2'-Hydroxy-3',5'-di-tert-pentylphenyl)benzotriazole, 2-(2'-hydroxy-4'-octyloxyphenyl)benzotriazole, 2- [2'-Hydroxy-3'-(3'',4'',5'',6'',-tetrahydrophthalimidomethyl)-5'-methylphenyl]benzo Triazole, 2,2'-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol-2-yl)phenol], [2 (2'-Hydroxy-5'-methacryloxyphenyl)-2H-benzotriazole.

作為水楊酸系紫外線吸收劑，例如可例舉：水楊酸苯酯、水楊酸對第三丁基苯酯、水楊酸對辛基苯酯。Examples of the salicylic acid-based ultraviolet absorber include phenyl salicylate, p-tert-butylphenyl salicylate, and p-octylphenyl salicylate.

作為丙烯酸氰酯系紫外線吸收劑，例如可例舉：丙烯酸2-乙基己基-2-氰基-3,3'-二苯酯、丙烯酸乙基-2-氰基-3,3'-二苯酯。Examples of cyanoacrylate-based ultraviolet absorbers include: 2-ethylhexyl-2-cyano-3,3'-diphenyl acrylate, ethyl-2-cyano-3,3'-diphenyl acrylate, phenyl esters.

光穩定劑可僅為1種，亦可為2種以上。The light stabilizer may be only 1 type, and may be 2 or more types.

胺基甲酸酯系黏著劑組合物中之光穩定劑之含有比率可於不損害本發明之效果之範圍內採用任意適當之含有比率。關於此種含有比率，光穩定劑相對於多元醇(A1)總量之含有比率較佳為0.01重量%～10重量%以上，更佳為0.05重量%～5重量%，進而較佳為0.1重量%～3重量%，尤佳為0.2重量%～1重量%。As for the content rate of the light stabilizer in a urethane adhesive composition, arbitrary appropriate content rate can be employ|adopted in the range which does not impair the effect of this invention. Regarding such a content ratio, the content ratio of the light stabilizer to the total amount of the polyol (A1) is preferably 0.01% by weight to 10% by weight or more, more preferably 0.05% by weight to 5% by weight, and still more preferably 0.1% by weight % to 3% by weight, particularly preferably 0.2% to 1% by weight.

作為光穩定劑，例如可例舉：受阻胺系光穩定劑、紫外線穩定劑。As a light stabilizer, a hindered amine light stabilizer and an ultraviolet-ray stabilizer are mentioned, for example.

作為受阻胺系光穩定劑，例如可例舉：癸二酸[雙(2,2,6,6-四甲基-4-哌啶基)酯]、癸二酸雙(1,2,2,6,6-五甲基-4-哌啶基)酯、癸二酸甲基1,2,2,6,6-五甲基-4-哌啶酯。As hindered amine light stabilizers, for example, sebacic acid [bis(2,2,6,6-tetramethyl-4-piperidinyl) ester], sebacic acid bis(1,2,2 , 6,6-pentamethyl-4-piperidinyl) ester, methyl 1,2,2,6,6-pentamethyl-4-piperidinyl sebacate.

作為紫外線穩定劑，例如可例舉：鎳雙(辛基苯基)硫化物、[2,2'-硫代雙(4-第三辛基酚基)]-正丁基胺鎳、鎳錯合物-3,5-二第三丁基-4-羥基苄基-磷酸單乙醇鹽、鎳-二丁基二硫代胺基甲酸鹽、苯甲酸酯類型之抑止劑、鎳-二丁基二硫代胺基甲酸鹽。As the ultraviolet stabilizer, for example, nickel bis(octylphenyl)sulfide, [2,2'-thiobis(4-tertiary octylphenol)]-nickel n-butylamine, nickel aluminum Compound-3,5-di-tert-butyl-4-hydroxybenzyl-phosphate monoethanolate, nickel-dibutyldithiocarbamate, benzoate-type inhibitors, nickel-di Butyl dithiocarbamate.

抗劣化劑較佳為具有受阻酚結構之抗劣化劑。於包含具有受阻酚結構之抗劣化劑作為抗劣化劑之情形時，具有受阻酚結構之抗劣化劑之含有比率相對於多元醇(A)較佳為0.01重量%～10重量%，更佳為0.05重量%～10重量%，進而較佳為0.1重量%～10重量%。藉由將具有受阻酚結構之抗劣化劑之含有比率調整至上述範圍內，能夠更加表現本發明之效果。The anti-deterioration agent is preferably an anti-deterioration agent having a hindered phenol structure. When an anti-deterioration agent having a hindered phenol structure is included as the anti-deterioration agent, the content ratio of the anti-deterioration agent having a hindered phenol structure is preferably 0.01% by weight to 10% by weight relative to the polyol (A), more preferably 0.05% by weight to 10% by weight, more preferably 0.1% by weight to 10% by weight. By adjusting the content rate of the anti-deterioration agent which has a hindered phenol structure in the said range, the effect of this invention can be expressed more.

作為具有受阻酚結構之抗劣化劑，例如可例舉具有如下受阻酚結構之抗劣化劑，即，第三丁基等位阻較大之基與鍵結有苯酚之OH基之芳香族環上碳原子之鄰接碳原子之至少一者鍵結而成之受阻酚結構。As an anti-deterioration agent having a hindered phenol structure, for example, an anti-deterioration agent having a hindered phenol structure, that is, a sterically hindered group such as a tertiary butyl group and an aromatic ring bonded to an OH group of a phenol A hindered phenolic structure in which at least one of the adjacent carbon atoms of a carbon atom is bonded.

作為具有受阻酚結構之抗劣化劑，具體而言，例如可例舉：二丁基羥基甲苯(BHT)；商品名「IRGANOX1010」(BASF製造)、商品名「IRGANOX1010FF」(BASF製造)、商品名「IRGANOX1035」(BASF製造)、商品名「IRGANOX1035FF」(BASF製造)、商品名「IRGANOX1076」(BASF製造)、商品名「IRGANOX1076FD」(BASF製造)、商品名「IRGANOX1076DWJ」(BASF製造)、商品名「IRGANOX1098」(BASF製造)、商品名「IRGANOX1135」(BASF製造)、商品名「IRGANOX1330」(BASF製造)、商品名「IRGANOX1726」(BASF製造)、商品名「IRGANOX1425WL」(BASF製造)、商品名「IRGANOX1520L」(BASF製造)、商品名「IRGANOX245」(BASF製造)、商品名「IRGANOX245FF」(BASF製造)、商品名「IRGANOX259」(BASF製造)、商品名「IRGANOX3114」(BASF製造)、商品名「IRGANOX565」(BASF製造)、商品名「IRGANOX295」(BASF製造)等受阻酚系抗氧化劑；商品名「TINUVIN P」(BASF製造)、商品名「TINUVIN P FL」(BASF製造)、商品名「TINUVIN234」(BASF製造)、商品名「TINUVIN326」(BASF製造)、商品名「TINUVIN326FL」(BASF製造)、商品名「TINUVIN328」(BASF製造)、商品名「TINUVIN329」(BASF製造)、商品名「TINUVIN329FL」(BASF製造)等苯并***系紫外線吸收劑；商品名「TINUVIN213」(BASF製造)、商品名「TINUVIN571」(BASF製造)等液狀紫外線吸收劑；商品名「TINUVIN1577ED」(BASF製造)等三𠯤系紫外線吸收劑；商品名「TINUVIN120」(BASF製造)等苯甲酸酯系紫外線吸收劑；商品名「TINUVIN144」(BASF製造)等受阻胺系光穩定劑。Specific examples of the anti-deterioration agent having a hindered phenol structure include: dibutylhydroxytoluene (BHT); trade name "IRGANOX 1010" (manufactured by BASF), trade name "IRGANOX 1010FF" (manufactured by BASF), trade name "IRGANOX1035" (manufactured by BASF), product name "IRGANOX1035FF" (manufactured by BASF), product name "IRGANOX1076" (manufactured by BASF), product name "IRGANOX1076FD" (manufactured by BASF), product name "IRGANOX1076DWJ" (manufactured by BASF), product name "IRGANOX1098" (manufactured by BASF), product name "IRGANOX1135" (manufactured by BASF), product name "IRGANOX1330" (manufactured by BASF), product name "IRGANOX1726" (manufactured by BASF), product name "IRGANOX1425WL" (manufactured by BASF), product name "IRGANOX1520L" (manufactured by BASF), product name "IRGANOX245" (manufactured by BASF), product name "IRGANOX245FF" (manufactured by BASF), product name "IRGANOX259" (manufactured by BASF), product name "IRGANOX3114" (manufactured by BASF), product name Hindered phenolic antioxidants such as "IRGANOX565" (manufactured by BASF), trade name "IRGANOX295" (manufactured by BASF); TINUVIN234" (manufactured by BASF), product name "TINUVIN326" (manufactured by BASF), product name "TINUVIN326FL" (manufactured by BASF), product name "TINUVIN328" (manufactured by BASF), product name "TINUVIN329" (manufactured by BASF), product name " Benzotriazole-based ultraviolet absorbers such as TINUVIN329FL” (manufactured by BASF); liquid ultraviolet absorbers such as “TINUVIN213” (manufactured by BASF) and “TINUVIN571” (manufactured by BASF); ) and other tertiary UV absorbers; benzoate-based UV absorbers such as “TINUVIN120” (manufactured by BASF); and hindered amine light stabilizers such as “TINUVIN144” (manufactured by BASF).

(脂肪酸酯) 關於胺基甲酸酯系黏著劑組合物，就提高胺基甲酸酯系黏著劑之潤濕性等方面而言，胺基甲酸酯系黏著劑組合物亦可包含脂肪酸酯作為其他成分。脂肪酸酯可僅為1種，亦可為2種以上。 (fatty acid ester) Regarding the urethane adhesive composition, in terms of improving the wettability of the urethane adhesive, etc., the urethane adhesive composition may also contain fatty acid esters as other components . Only 1 type may be sufficient as fatty acid ester, and 2 or more types may be sufficient as it.

胺基甲酸酯系黏著劑組合物中之脂肪酸酯之含有比率可於不損害本發明之效果之範圍內採用任意適當之含有比率。此種含有比率相對於多元醇(A)總量較佳為1重量%～60重量%，更佳為5重量%～55重量%，進而較佳為10重量%～50重量%，尤佳為15重量%～45重量%，最佳為20重量%～40重量%。The content rate of the fatty acid ester in a urethane type adhesive composition can employ|adopt arbitrary appropriate content rate in the range which does not impair the effect of this invention. Such a content ratio is preferably 1% by weight to 60% by weight, more preferably 5% by weight to 55% by weight, further preferably 10% by weight to 50% by weight, and most preferably 15% by weight to 45% by weight, most preferably 20% by weight to 40% by weight.

脂肪酸酯之數量平均分子量Mn較佳為200～400，更佳為210～395，進而較佳為230～380，尤佳為240～360，最佳為250～350。藉由將脂肪酸酯之數量平均分子量Mn調整至上述範圍內，能夠更加提高潤濕速度。若脂肪酸酯之數量平均分子量Mn過小，則有即便添加份數較多，潤濕速度亦不會變快之虞。若脂肪酸酯之數量平均分子量Mn過大，則有乾燥時黏著劑之硬化性變差，且不僅對潤濕特性亦對其他黏著特性帶來不良影響之虞。The number average molecular weight Mn of the fatty acid ester is preferably 200-400, more preferably 210-395, further preferably 230-380, especially preferably 240-360, most preferably 250-350. Wetting speed can be further improved by adjusting the number average molecular weight Mn of a fatty acid ester in the said range. If the number average molecular weight Mn of the fatty acid ester is too small, there is a possibility that the wetting speed may not be increased even if the number of additions is large. If the number average molecular weight Mn of the fatty acid ester is too large, the hardening property of the adhesive during drying may deteriorate, and may adversely affect not only the wettability but also other adhesive properties.

作為脂肪酸酯，可於不損害本發明之效果之範圍內採用任意適當之脂肪酸酯。作為此種脂肪酸酯，例如可例舉：聚氧乙烯雙酚A月桂酸酯、硬脂酸丁酯、棕櫚酸2-乙基己酯、硬脂酸2-乙基己酯、山萮酸單縮水甘油酯、2-乙基己酸鯨蠟酯、肉豆蔻酸異丙酯、棕櫚酸異丙酯、膽固醇異硬脂酸酯、甲基丙烯酸月桂酯、椰子油脂肪酸甲酯、月桂酸甲酯、油酸甲酯、硬脂酸甲酯、肉豆蔻酸肉豆蔻酯、肉豆蔻酸辛基十二烷基酯、季戊四醇單油酸酯、季戊四醇單硬脂酸酯、季戊四醇四棕櫚酸酯、硬脂酸硬脂酯、硬脂酸異十三烷基酯、2-乙基己酸三酸甘油酯、月桂酸丁酯、油酸辛酯。As the fatty acid ester, any appropriate fatty acid ester can be employed within the range not impairing the effect of the present invention. Examples of such fatty acid esters include: polyoxyethylene bisphenol A laurate, butyl stearate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, behenic acid Monoglycidyl Ester, Cetyl 2-Ethylhexanoate, Isopropyl Myristate, Isopropyl Palmitate, Cholesterol Isostearate, Lauryl Methacrylate, Coco Fatty Acid Methyl Ester, Methyl Laurate ester, methyl oleate, methyl stearate, myristyl myristate, octyldodecyl myristate, pentaerythritol monooleate, pentaerythritol monostearate, pentaerythritol tetrapalmitate, hard Stearyl stearate, isotridecyl stearate, 2-ethylhexanoic triglyceride, butyl laurate, octyl oleate.

(觸媒) 其他成分亦可包含觸媒。作為觸媒，例如可例舉：有機金屬系化合物、三級胺化合物等。觸媒可僅為1種，亦可為2種以上。 (catalyst) Other ingredients may also include catalysts. As a catalyst, an organometallic compound, a tertiary amine compound, etc. are mentioned, for example. A catalyst may be only 1 type, and may be 2 or more types.

作為有機金屬系化合物，例如可例舉：鐵系化合物、錫系化合物、鈦系化合物、鋯系化合物、鉛系化合物、鈷系化合物、鋅系化合物。該等之中，就反應速度及黏著劑層之適用期之方面而言，較佳為鐵系化合物、錫系化合物。Examples of the organometallic compounds include iron-based compounds, tin-based compounds, titanium-based compounds, zirconium-based compounds, lead-based compounds, cobalt-based compounds, and zinc-based compounds. Among these, iron-based compounds and tin-based compounds are preferable in terms of reaction speed and pot life of the adhesive layer.

作為鐵系化合物，例如可例舉：乙醯丙酮酸鐵、2-乙基己酸鐵。As the iron-based compound, for example, iron acetylpyruvate and iron 2-ethylhexanoate may be mentioned.

作為錫系化合物，例如可例舉：二氯化二丁基錫、氧化二丁基錫、二溴化二丁基錫、馬來酸二丁基錫、二月桂酸二丁基錫、二乙酸二丁基錫、硫化二丁基錫、三丁基甲醇錫、乙酸三丁基錫、三乙基乙醇錫、三丁基乙醇錫、氧化二辛基錫、二月桂酸二辛基錫、氯化三丁基錫、三氯乙酸三丁基錫、2-乙基己酸錫。Examples of tin-based compounds include: dibutyltin dichloride, dibutyltin oxide, dibutyltin dibromide, dibutyltin maleate, dibutyltin dilaurate, dibutyltin diacetate, dibutyltin sulfide, tributyltin Tin methoxide, tributyltin acetate, triethyltin ethoxide, tributyltin ethoxide, dioctyltin oxide, dioctyltin dilaurate, tributyltin chloride, tributyltin trichloroacetate, 2-ethylhexanoic acid tin.

作為鈦系化合物，例如可例舉：二氯化二丁基鈦、鈦酸四丁酯、三氯化丁氧基鈦。Examples of the titanium-based compound include dibutyltitanium dichloride, tetrabutyl titanate, and butoxytitanium trichloride.

作為鋯系化合物，例如可例舉：環烷酸鋯、乙醯丙酮酸鋯。Examples of the zirconium-based compound include zirconium naphthenate and zirconium acetylacetonate.

作為鉛系化合物，例如可例舉：油酸鉛、2-乙基己酸鉛、苯甲酸鉛、環烷酸鉛。Examples of the lead-based compound include lead oleate, lead 2-ethylhexanoate, lead benzoate, and lead naphthenate.

作為鈷系化合物，例如可例舉：2-乙基己酸鈷、苯甲酸鈷。Examples of the cobalt-based compound include cobalt 2-ethylhexanoate and cobalt benzoate.

作為鋅系化合物，例如可例舉：環烷酸鋅、2-乙基己酸鋅。As a zinc compound, zinc naphthenate and zinc 2-ethylhexanoate may be mentioned, for example.

作為三級胺化合物，例如可例舉：三乙胺、三伸乙基二胺、1,8-二氮雜雙環-(5,4,0)-十一烯-7。As the tertiary amine compound, for example, triethylamine, triethylenediamine, and 1,8-diazabicyclo-(5,4,0)-undecene-7 may be mentioned.

觸媒之量相對於多元醇(A)較佳為0.02重量%～0.50重量%，更佳為0.05重量%～0.40重量%，進而較佳為0.07重量%～0.30重量%，尤佳為0.10重量%～0.20重量%。The amount of the catalyst is preferably 0.02% by weight to 0.50% by weight relative to the polyol (A), more preferably 0.05% by weight to 0.40% by weight, further preferably 0.07% by weight to 0.30% by weight, especially preferably 0.10% by weight % to 0.20% by weight.

(交聯延遲劑) 作為交聯延遲劑，代表性而言，可例舉：產生酮-烯醇互變異構之化合物。若採用產生酮-烯醇互變異構之化合物作為交聯延遲劑，則例如可抑制胺基甲酸酯系黏著劑組合物之黏度過度上升或過度凝膠化，且能夠表現出延長胺基甲酸酯系黏著劑組合物之適用期之效果。該技術較佳為可較佳用於如下情形，即，胺基甲酸酯系黏著劑組合物為有機溶劑溶液或無溶劑之形態。 (crosslinking retarder) Typical examples of the crosslinking retarder include compounds that cause keto-enol tautomerization. If a compound that produces keto-enol tautomerism is used as a crosslinking retarder, for example, it can inhibit the excessive increase in viscosity or excessive gelation of the urethane adhesive composition, and can exhibit extended urethane The effect of the pot life of the ester-based adhesive composition. This technique is preferably applicable when the urethane-based adhesive composition is in the form of an organic solvent solution or a solvent-free form.

作為產生酮-烯醇互變異構之化合物，例如可使用各種β-二羰基化合物。作為具體例，例如可例舉：乙醯丙酮、2,4-己烷二酮、3,5-庚烷二酮、2-甲基己烷-3,5-二酮、6-甲基庚烷-2,4-二酮、2,6-二甲基庚烷-3,5-二酮等β-二酮類；乙醯乙酸甲酯、乙醯乙酸乙酯、乙醯乙酸異丙酯、乙醯乙酸第三丁酯等乙醯乙酸酯類；丙醯乙酸乙酯、丙醯乙酸乙酯、丙醯乙酸異丙酯、丙醯乙酸第三丁酯等丙醯乙酸酯類；異丁醯乙酸乙酯、異丁醯乙酸乙酯、異丁醯乙酸異丙酯、異丁醯乙酸第三丁酯等異丁醯乙酸酯類；丙二酸甲酯、丙二酸乙酯等丙二酸酯類；等。該等之中，較佳為選自乙醯丙酮、乙醯乙酸酯之至少1種。As the compound causing keto-enol tautomerism, for example, various β-dicarbonyl compounds can be used. Specific examples include: acetylacetone, 2,4-hexanedione, 3,5-heptanedione, 2-methylhexane-3,5-dione, 6-methylheptane β-diketones such as alkane-2,4-dione and 2,6-dimethylheptane-3,5-dione; methyl acetylacetate, ethyl acetylacetate, isopropyl acetylacetate Acetyl acetates such as tert-butyl acetyl acetate; ethyl acyl acetate, ethyl acyl acetate, isopropyl acyl acetate, t-butyl acyl acetate and other acyl acetates; isobutyl Ethyl isobutyryl acetate, ethyl isobutyryl acetate, isopropyl isobutyryl acetate, tertiary butyl isobutyryl acetate and other isobutyryl acetates; methyl malonate, ethyl malonate and other malonyl esters; etc. Among them, at least one selected from acetylacetone and acetyl acetate is preferable.

產生酮-烯醇互變異構之化合物可僅為1種，亦可為2種以上。The compound that causes keto-enol tautomerization may be only one kind, or two or more kinds.

產生酮-烯醇互變異構之化合物之含量相對於基礎聚合物(例如丙烯酸系聚合物、多元醇、胺基甲酸酯預聚物、矽酮系聚合物)100重量份較佳為0.1重量份～20重量份，更佳為0.5重量份～15重量份，進而較佳為1重量份～10重量份。若產生酮-烯醇互變異構之化合物之含量過少，則有不易發揮充分之使用效果之虞。若使用超過所需之產生酮-烯醇互變異構之化合物，則有殘留於黏著劑層，使凝集力降低之虞。The content of the compound that produces keto-enol tautomerism is preferably 0.1 parts by weight relative to 100 parts by weight of the base polymer (such as acrylic polymer, polyol, urethane prepolymer, silicone polymer) parts by weight to 20 parts by weight, more preferably 0.5 parts by weight to 15 parts by weight, and still more preferably 1 parts by weight to 10 parts by weight. If the content of the compound causing keto-enol tautomerization is too small, it may be difficult to exert a sufficient use effect. If the compound that produces keto-enol tautomerization is used more than necessary, it may remain in the adhesive layer and reduce the cohesive force.

(界面活性劑) 關於成為黏著劑層之材料之胺基甲酸酯系黏著劑組合物，就提高再剝離性或提高黏著劑組合物對被黏著體之潤濕性之觀點而言，成為黏著劑層之材料之胺基甲酸酯系黏著劑組合物可含有界面活性劑。 (surfactant) Regarding the urethane-based adhesive composition used as the material of the adhesive layer, from the viewpoint of improving the re-peelability or improving the wettability of the adhesive composition to the adherend, it is one of the materials used as the adhesive layer. The urethane-based adhesive composition may contain a surfactant.

作為界面活性劑，可例舉：公知之陰離子性界面活性劑、公知之非離子性界面活性劑、公知之陽離子性界面活性劑、公知之兩性界面活性劑等。As a surfactant, a well-known anionic surfactant, a well-known nonionic surfactant, a well-known cationic surfactant, a well-known amphoteric surfactant, etc. are mentioned.

界面活性劑可僅為1種，亦可為2種以上。Surfactant may be only 1 type, and may be 2 or more types.

界面活性劑之含量相對於基礎聚合物(例如丙烯酸系聚合物、多元醇、胺基甲酸酯預聚物、矽酮系聚合物)100重量份較佳為0.01重量份～10重量份，更佳為0.1重量份～1重量份。The content of the surfactant is preferably 0.01 to 10 parts by weight relative to 100 parts by weight of the base polymer (such as acrylic polymers, polyols, urethane prepolymers, silicone polymers), and more preferably Preferably, it is 0.1 weight part - 1 weight part.

＜1-2-2.預聚物法所製造之胺基甲酸酯系黏著劑＞ 聚胺基甲酸酯系黏著劑之一個實施方式係使含有胺基甲酸酯預聚物(A2)及多官能異氰酸酯化合物(B)之胺基甲酸酯系黏著劑組合物硬化所獲得之聚胺基甲酸酯系黏著劑。即，該形態中之胺基甲酸酯系黏著劑組合物含有胺基甲酸酯預聚物(A2)及多官能異氰酸酯化合物(B)。 ＜1-2-2. Urethane-based adhesive produced by prepolymer method＞ One embodiment of the polyurethane-based adhesive is obtained by curing a urethane-based adhesive composition containing a urethane prepolymer (A2) and a polyfunctional isocyanate compound (B). Polyurethane-based adhesive. That is, the urethane adhesive composition in this form contains a urethane prepolymer (A2) and a polyfunctional isocyanate compound (B).

該形態中之胺基甲酸酯系黏著劑組合物中之胺基甲酸酯預聚物(A2)與多官能異氰酸酯化合物(B)之合計量之含有比率在去除溶劑後較佳為50重量%～100重量%，更佳為55重量%～95重量%，進而較佳為60重量%～90重量%，尤佳為65重量%～85重量%，最佳為70重量%～80重量%。The content ratio of the total amount of the urethane prepolymer (A2) and the polyfunctional isocyanate compound (B) in the urethane-based adhesive composition in this form is preferably 50% by weight after removing the solvent. % to 100% by weight, more preferably 55% to 95% by weight, more preferably 60% to 90% by weight, especially preferably 65% to 85% by weight, most preferably 70% to 80% by weight .

[1-2-2-a.胺基甲酸酯預聚物(A2)] 胺基甲酸酯預聚物(A2)可僅為1種，亦可為2種以上。 [1-2-2-a. Urethane prepolymer (A2)] The urethane prepolymer (A2) may be only 1 type, or may be 2 or more types.

胺基甲酸酯預聚物(A2)之數量平均分子量Mn較佳為3000～1000000。The number average molecular weight Mn of the urethane prepolymer (A2) is preferably from 3,000 to 1,000,000.

胺基甲酸酯預聚物(A2)較佳為聚胺基甲酸酯多元醇，更佳為使聚酯多元醇(a21)或聚醚多元醇(a22)分別單獨於存在觸媒之情況下或無觸媒之情況下與有機聚異氰酸酯化合物(a23)反應而成者、或使聚酯多元醇(a21)或聚醚多元醇(a22)以(a21)與(a22)之混合物之形式於存在觸媒之情況下或無觸媒之情況下與有機聚異氰酸酯化合物(a23)反應而成者。The urethane prepolymer (A2) is preferably polyurethane polyol, more preferably polyester polyol (a21) or polyether polyol (a22) separately in the presence of catalyst The reaction of organic polyisocyanate compound (a23) with or without catalyst, or the mixture of polyester polyol (a21) or polyether polyol (a22) in the form of (a21) and (a22) It is formed by reacting with an organic polyisocyanate compound (a23) in the presence or absence of a catalyst.

作為聚酯多元醇(a21)，可使用任意適當之聚酯多元醇。作為此種聚酯多元醇(a21)，例如可例舉：使酸成分與二醇成分反應所獲得之聚酯多元醇。作為酸成分，例如可例舉：對苯二甲酸、己二酸、壬二酸、癸二酸、鄰苯二甲酸酐、間苯二甲酸、偏苯三甲酸。作為二醇成分，例如可例舉：乙二醇、丙二醇、二乙二醇、丁二醇、1,6-己二醇、3-甲基-1,5-戊二醇、3,3'-二羥甲基庚烷、聚氧乙二醇、聚氧丙二醇、1,4-丁二醇、新戊二醇、丁基乙基戊二醇，作為多元醇成分，可例舉：甘油、三羥甲基丙烷、季戊四醇。作為聚酯多元醇(a21)，除上述以外，亦可例舉：使聚己內酯、聚(β-甲基-γ-戊內酯)、聚戊內酯等內酯類開環聚合所獲得之聚酯多元醇等。Any appropriate polyester polyol can be used as the polyester polyol (a21). As such a polyester polyol (a21), the polyester polyol obtained by making an acid component and a diol component react may be mentioned, for example. As the acid component, for example, terephthalic acid, adipic acid, azelaic acid, sebacic acid, phthalic anhydride, isophthalic acid, and trimellitic acid may, for example, be mentioned. Examples of diol components include ethylene glycol, propylene glycol, diethylene glycol, butylene glycol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, 3,3' - Dimethylol heptane, polyoxyethylene glycol, polyoxypropylene glycol, 1,4-butanediol, neopentyl glycol, butyl ethylpentanediol, as polyhydric alcohol components, for example: glycerin, Trimethylolpropane, Pentaerythritol. Examples of the polyester polyol (a21) include, in addition to the above, compounds obtained by ring-opening polymerization of lactones such as polycaprolactone, poly(β-methyl-γ-valerolactone), and polyvalerolactone. Obtained polyester polyol, etc.

作為聚酯多元醇(a21)之分子量，自低分子量至高分子量均可使用。作為聚酯多元醇(a21)之分子量，數量平均分子量Mn較佳為100～100000。若數量平均分子量Mn未達100，則有反應性變高，容易凝膠化之虞。若數量平均分子量Mn超過100000，則有反應性變低，進而聚胺基甲酸酯多元醇自身之凝集力變小之虞。聚酯多元醇(a21)之使用量於構成聚胺基甲酸酯多元醇之多元醇中較佳為0莫耳%～90莫耳%。The molecular weight of the polyester polyol (a21) can be used from low molecular weight to high molecular weight. As the molecular weight of the polyester polyol (a21), the number average molecular weight Mn is preferably from 100 to 100,000. If the number average molecular weight Mn is less than 100, the reactivity may become high and gelation may be likely to occur. When the number average molecular weight Mn exceeds 100,000, the reactivity may decrease, and furthermore, the cohesive force of the polyurethane polyol itself may decrease. The amount of the polyester polyol (a21) used is preferably 0 mol % to 90 mol % in the polyols constituting the polyurethane polyol.

作為聚醚多元醇(a22)，可使用任意適當之聚醚多元醇。作為此種聚醚多元醇(a22)，例如可例舉：使用水、丙二醇、乙二醇、甘油、三羥甲基丙烷等低分子量多元醇作為起始劑並藉由使環氧乙烷、環氧丙烷、環氧丁烷、四氫呋喃等環氧乙烷化合物聚合所獲得之聚醚多元醇。作為此種聚醚多元醇(a22)，具體而言，例如可例舉：聚丙二醇、聚乙二醇、聚四亞甲基二醇等官能基數為2以上之聚醚多元醇。Any appropriate polyether polyol can be used as the polyether polyol (a22). Examples of such polyether polyols (a22) include, for example, water, propylene glycol, ethylene glycol, glycerin, trimethylolpropane, and other low-molecular-weight polyols used as starters and mixed with ethylene oxide, Polyether polyols obtained by polymerizing ethylene oxide compounds such as propylene oxide, butylene oxide, and tetrahydrofuran. Specific examples of such polyether polyol (a22) include polyether polyols having two or more functional groups such as polypropylene glycol, polyethylene glycol, and polytetramethylene glycol.

作為聚醚多元醇(a22)之分子量，自低分子量至高分子量均可使用。作為聚醚多元醇(a22)之分子量，數量平均分子量Mn較佳為100～100000。若數量平均分子量Mn未達100，則有反應性變高，容易凝膠化之虞。若數量平均分子量Mn超過100000，則有反應性變低，進而聚胺基甲酸酯多元醇自身之凝集力變小之虞。聚醚多元醇(a22)之使用量於構成聚胺基甲酸酯多元醇之多元醇中較佳為0莫耳%～90莫耳%。The molecular weight of the polyether polyol (a22) can be used from low molecular weight to high molecular weight. As the molecular weight of the polyether polyol (a22), the number average molecular weight Mn is preferably from 100 to 100,000. If the number average molecular weight Mn is less than 100, the reactivity may become high and gelation may be likely to occur. When the number average molecular weight Mn exceeds 100,000, the reactivity may decrease, and furthermore, the cohesive force of the polyurethane polyol itself may decrease. The amount of polyether polyol (a22) used is preferably 0 mol % to 90 mol % in the polyols constituting the polyurethane polyol.

聚醚多元醇(a22)可視需要將其一部分取代為乙二醇、1,4-丁二醇、新戊二醇、丁基乙基戊二醇、甘油、三羥甲基丙烷、季戊四醇等二醇類、或乙二胺、N-胺基乙基乙醇胺、異佛爾酮二胺、苯二甲胺等多價胺類等而併用。Polyether polyol (a22) may be partially substituted with diethylene glycol, 1,4-butanediol, neopentyl glycol, butyl ethylpentanediol, glycerin, trimethylolpropane, pentaerythritol, etc. Alcohols, or polyvalent amines such as ethylenediamine, N-aminoethylethanolamine, isophoronediamine, xylylenediamine, etc. are used in combination.

作為聚醚多元醇(a22)，可僅使用2官能性之聚醚多元醇，亦可部分使用或全部使用數量平均分子量Mn為100～100000且1分子中具有至少3個以上之羥基的聚醚多元醇。若部分使用或全部使用數量平均分子量Mn為100～100000且1分子中具有至少3個以上之羥基的聚醚多元醇作為聚醚多元醇(a22)，則可使黏著力與再剝離性之平衡良好。於此種聚醚多元醇中，若數量平均分子量Mn未達100，則有反應性變高，容易凝膠化之虞。又，於此種聚醚多元醇中，若數量平均分子量Mn超過100000，則有反應性變低，進而聚胺基甲酸酯多元醇自身之凝集力變小之虞。此種聚醚多元醇之數量平均分子量Mn更佳為100～10000。As the polyether polyol (a22), only a bifunctional polyether polyol may be used, or a polyether having a number average molecular weight Mn of 100 to 100,000 and having at least 3 or more hydroxyl groups in one molecule may be used partially or entirely. Polyol. If a polyether polyol (a22) with a number-average molecular weight Mn of 100 to 100,000 and at least 3 or more hydroxyl groups in one molecule is used partially or entirely as the polyether polyol (a22), the balance between adhesive force and re-peelability can be achieved good. In such a polyether polyol, when the number average molecular weight Mn is less than 100, the reactivity may become high, and gelation may become easy. Moreover, in such a polyether polyol, when the number average molecular weight Mn exceeds 100,000, the reactivity may decrease, and furthermore, the cohesive force of the polyurethane polyol itself may decrease. The number average molecular weight Mn of such polyether polyol is more preferably 100-10000.

作為有機聚異氰酸酯化合物(a23)，可使用任意適當之有機聚異氰酸酯化合物。作為此種有機聚異氰酸酯化合物(a23)，例如可例舉：芳香族聚異氰酸酯、脂肪族聚異氰酸酯、芳香脂肪族聚異氰酸酯、脂環族聚異氰酸酯等。Any appropriate organic polyisocyanate compound can be used as the organic polyisocyanate compound (a23). As such an organic polyisocyanate compound (a23), aromatic polyisocyanate, aliphatic polyisocyanate, araliphatic polyisocyanate, alicyclic polyisocyanate etc. are mentioned, for example.

作為芳香族聚異氰酸酯，例如可例舉：1,3-苯二異氰酸酯、4,4'-二苯基二異氰酸酯、1,4-苯二異氰酸酯、4,4'-二苯基甲烷二異氰酸酯、2,4-甲苯二異氰酸酯、2,6-甲苯二異氰酸酯、4,4'-甲苯胺二異氰酸酯、2,4,6-甲苯三異氰酸酯、1,3,5-苯三異氰酸酯、聯大茴香胺二異氰酸酯、4,4'-二苯醚二異氰酸酯、4,4',4''-三苯甲烷三異氰酸酯。As the aromatic polyisocyanate, for example, 1,3-phenylene diisocyanate, 4,4'-diphenyl diisocyanate, 1,4-benzene diisocyanate, 4,4'-diphenylmethane diisocyanate, 2,4-Toluene Diisocyanate, 2,6-Toluene Diisocyanate, 4,4'-Toluene Diisocyanate, 2,4,6-Toluene Triisocyanate, 1,3,5-Benzene Triisocyanate, Anisidine Diisocyanate, 4,4'-diphenyl ether diisocyanate, 4,4',4''-triphenylmethane triisocyanate.

作為脂肪族聚異氰酸酯，例如可例舉：三亞甲基二異氰酸酯、四亞甲基二異氰酸酯、六亞甲基二異氰酸酯、五亞甲基二異氰酸酯、1,2-伸丙基二異氰酸酯、2,3-伸丁基二異氰酸酯、1,3-伸丁基二異氰酸酯、十二亞甲基二異氰酸酯、2,4,4-三甲基六亞甲基二異氰酸酯。As the aliphatic polyisocyanate, for example, trimethylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, pentamethylene diisocyanate, 1,2-propylidene diisocyanate, 2, 3-butylene diisocyanate, 1,3-butylene diisocyanate, dodecamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate.

作為芳香脂肪族聚異氰酸酯，例如可例舉：ω,ω'-二異氰酸酯-1,3-二甲基苯、ω,ω'-二異氰酸酯-1,4-二甲基苯、ω,ω'-二異氰酸酯-1,4-二乙基苯、1,4-四甲基苯二甲基二異氰酸酯、1,3-四甲基苯二甲基二異氰酸酯。Examples of araliphatic polyisocyanates include ω,ω'-diisocyanate-1,3-dimethylbenzene, ω,ω'-diisocyanate-1,4-dimethylbenzene, ω,ω' - Diisocyanate - 1,4-diethylbenzene, 1,4-tetramethylxylylene diisocyanate, 1,3-tetramethylxylylene diisocyanate.

作為脂環族聚異氰酸酯，例如可例舉：3-異氰酸基甲基-3,5,5-三甲基環己基異氰酸酯、1,3-環戊烷二異氰酸酯、1,3-環己烷二異氰酸酯、1,4-環己烷二異氰酸酯、甲基-2,4-環己烷二異氰酸酯、甲基-2,6-環己烷二異氰酸酯、4,4'-亞甲基雙(環己基異氰酸酯)、1,4-雙(異氰酸基甲基)環己烷、1,4-雙(異氰酸基甲基)環己烷。Examples of alicyclic polyisocyanate include: 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, 1,3-cyclopentane diisocyanate, 1,3-cyclohexyl Alkane diisocyanate, 1,4-cyclohexane diisocyanate, methyl-2,4-cyclohexane diisocyanate, methyl-2,6-cyclohexane diisocyanate, 4,4'-methylene bis( cyclohexyl isocyanate), 1,4-bis(isocyanatomethyl)cyclohexane, 1,4-bis(isocyanatomethyl)cyclohexane.

作為有機聚異氰酸酯化合物(a23)，可併用：三羥甲基丙烷加成物、與水反應之滴定物、具有異氰尿酸酯環之三聚物等。As the organic polyisocyanate compound (a23), a trimethylolpropane adduct, a titrated product reacted with water, a trimer having an isocyanurate ring, and the like can be used in combination.

作為獲得聚胺基甲酸酯多元醇時可使用之觸媒，可使用任意適當之觸媒。作為此種觸媒，例如可例舉：三級胺系化合物、有機金屬系化合物。Any appropriate catalyst can be used as a catalyst that can be used when obtaining polyurethane polyol. As such a catalyst, a tertiary amine compound and an organometallic compound are mentioned, for example.

作為三級胺系化合物，例如可例舉：三乙胺、三伸乙基二胺、1,8-二氮雜雙環(5,4,0)-十一烯-7(DBU)。As the tertiary amine compound, triethylamine, triethylenediamine, and 1,8-diazabicyclo(5,4,0)-undecene-7 (DBU) may be mentioned, for example.

作為有機金屬系化合物，例如可例舉：錫系化合物、非錫系化合物。As an organometallic compound, a tin-based compound and a non-tin-based compound are mentioned, for example.

作為錫系化合物，例如可例舉：二氯化二丁基錫、氧化二丁基錫、二溴化二丁基錫、二馬來酸二丁基錫、二月桂酸二丁基錫(DBTDL)、二乙酸二丁基錫、硫化二丁基錫、硫化三丁基錫、氧化三丁基錫、乙酸三丁基錫、三乙基乙醇錫、三丁基乙醇錫、氧化二辛基錫、氯化三丁基錫、三氯乙酸三丁基錫、2-乙基己酸錫。Examples of tin-based compounds include dibutyltin dichloride, dibutyltin oxide, dibutyltin dibromide, dibutyltin dimalate, dibutyltin dilaurate (DBTDL), dibutyltin diacetate, and dibutyltin sulfide. , Tributyltin Sulfide, Tributyltin Oxide, Tributyltin Acetate, Triethyltin Ethoxide, Tributyltin Ethoxide, Dioctyltin Oxide, Tributyltin Chloride, Tributyltin Trichloroacetate, Tin 2-Ethylhexanoate.

作為非錫系化合物，例如可例舉：二氯化二丁基鈦、鈦酸四丁酯、三氯化丁氧基鈦等鈦系化合物；油酸鉛、2-乙基己酸鉛、苯甲酸鉛、環烷酸鉛等鉛系化合物；2-乙基己酸鐵、乙醯丙酮酸鐵等鐵系化合物；苯甲酸鈷、2-乙基己酸鈷等鈷系化合物；環烷酸鋅、2-乙基己酸鋅等鋅系化合物；環烷酸鋯等鋯系化合物。Examples of non-tin-based compounds include: titanium-based compounds such as dibutyltitanium dichloride, tetrabutyl titanate, butoxytitanium trichloride; lead oleate, lead 2-ethylhexanoate, benzene Lead compounds such as lead formate and lead naphthenate; iron compounds such as iron 2-ethylhexanoate and iron acetylpyruvate; cobalt compounds such as cobalt benzoate and cobalt 2-ethylhexanoate; zinc naphthenate , Zinc compounds such as zinc 2-ethylhexanoate; zirconium compounds such as zirconium naphthenate.

於在獲得聚胺基甲酸酯多元醇時使用觸媒之情形時，關於存在聚酯多元醇(a21)與聚醚多元醇(a22)之2種多元醇之體系，由於其等之反應性不同，故若為單獨之觸媒體系，則容易產生凝膠化或反應溶液渾濁之問題。因此，藉由在獲得聚胺基甲酸酯多元醇時使用2種觸媒，而容易控制反應速度、觸媒之選擇性等，從而可解決該等問題。作為該等2種觸媒之組合，例如可例舉：三級胺/有機金屬系、錫系/非錫系、錫系/錫系，較佳為錫系/錫系，更佳為二月桂酸二丁基錫與2-乙基己酸錫之組合。關於其調配比，以重量比計，2-乙基己酸錫/二月桂酸二丁基錫較佳為未達1，更佳為0.2～0.6。若調配比為1以上，則有由於觸媒活性之平衡而容易凝膠化之虞。In the case of using a catalyst for obtaining polyurethane polyol, regarding the system of two types of polyols including polyester polyol (a21) and polyether polyol (a22), due to their reactivity Different, so if it is a separate catalyst system, it is easy to cause problems of gelation or turbidity of the reaction solution. Therefore, by using two kinds of catalysts when obtaining a polyurethane polyol, it is easy to control the reaction rate, the selectivity of a catalyst, etc., and these problems can be solved. As the combination of these two catalysts, for example, tertiary amine/organometallic, tin-based/non-tin-based, tin-based/tin-based, preferably tin-based/tin-based, more preferably dilaurel A combination of dibutyltin nitrate and tin 2-ethylhexanoate. Regarding the compounding ratio thereof, tin 2-ethylhexanoate/dibutyltin dilaurate is preferably less than 1, more preferably 0.2 to 0.6 in terms of weight ratio. When the compounding ratio is 1 or more, there is a possibility that gelation is likely to occur due to the balance of catalytic activity.

於在獲得聚胺基甲酸酯多元醇時使用觸媒之情形時，觸媒之使用量相對於聚酯多元醇(a21)、聚醚多元醇(a22)及有機聚異氰酸酯化合物(a23)之總量較佳為0.01重量%～1.0重量%。In the case of using a catalyst when obtaining polyurethane polyol, the amount of catalyst used is relative to the amount of polyester polyol (a21), polyether polyol (a22) and organic polyisocyanate compound (a23) The total amount is preferably from 0.01% by weight to 1.0% by weight.

於在獲得聚胺基甲酸酯多元醇時使用觸媒之情形時，反應溫度較佳為未達100℃，更佳為85℃～95℃。若為100℃以上，則有不易控制反應速度、交聯結構之虞，且有不易獲得具有特定之分子量之聚胺基甲酸酯多元醇之虞。When a catalyst is used for obtaining polyurethane polyol, the reaction temperature is preferably less than 100°C, more preferably 85°C to 95°C. When it is 100 degrees C or more, it may become difficult to control a reaction rate and a crosslinked structure, and it may become difficult to obtain the polyurethane polyol which has a specific molecular weight.

當獲得聚胺基甲酸酯多元醇時，亦可使用觸媒。於該情形時，反應溫度較佳為100℃以上，更佳為110℃以上。又，當於無觸媒之情況下獲得聚胺基甲酸酯多元醇時，較佳為反應3小時以上。A catalyst may also be used when obtaining polyurethane polyols. In this case, the reaction temperature is preferably at least 100°C, more preferably at least 110°C. Moreover, when obtaining a polyurethane polyol without a catalyst, it is preferable to react for 3 hours or more.

作為獲得聚胺基甲酸酯多元醇之方法，例如可例舉：1)將聚酯多元醇、聚醚多元醇、觸媒、有機聚異氰酸酯全部裝入至燒瓶之方法；2)將聚酯多元醇、聚醚多元醇、觸媒裝入至燒瓶且滴下有機聚異氰酸酯進行添加之方法。作為獲得聚胺基甲酸酯多元醇之方法，就控制反應之方面而言，較佳為2)之方法。Examples of methods for obtaining polyurethane polyols include: 1) a method of filling polyester polyol, polyether polyol, catalyst, and organic polyisocyanate into a flask; A method in which polyol, polyether polyol, and catalyst are charged into a flask, and organic polyisocyanate is added dropwise. As a method for obtaining a polyurethane polyol, the method of 2) is preferable at the point which controls a reaction.

當獲得聚胺基甲酸酯多元醇時，可使用任意適當之溶劑。作為此種溶劑，例如可例舉：甲基乙基酮、乙酸乙酯、甲苯、二甲苯、丙酮等。該等溶劑之中，較佳為甲苯。When obtaining the polyurethane polyol, any appropriate solvent may be used. As such a solvent, methyl ethyl ketone, ethyl acetate, toluene, xylene, acetone, etc. are mentioned, for example. Among these solvents, toluene is preferred.

[1-2-2-b.預聚物法中所使用之多官能異氰酸酯化合物(B)] 預聚物法中所使用之多官能異氰酸酯化合物(B)可僅為1種，亦可為2種以上。 [1-2-2-b. Polyfunctional isocyanate compound (B) used in prepolymer method] The polyfunctional isocyanate compound (B) used by the prepolymer method may be only 1 type, and may be 2 or more types.

作為預聚物法中所使用之多官能異氰酸酯化合物(B)，可援用上述一步法中所使用之多官能異氰酸酯化合物(B)。As the polyfunctional isocyanate compound (B) used in the prepolymer method, the polyfunctional isocyanate compound (B) used in the above-mentioned one-step method can be used.

關於胺基甲酸酯預聚物(A2)與多官能異氰酸酯化合物(B)中之NCO基與OH基之當量比，NCO基/OH基較佳為5.0以下，更佳為0.01～4.75，進而較佳為0.02～4.5，尤佳為0.03～4.25，最佳為0.05～4.0。若NCO基/OH基之當量比處於上述範圍內，則能夠更加表現本發明之效果。Regarding the equivalent ratio of NCO groups to OH groups in the urethane prepolymer (A2) and the polyfunctional isocyanate compound (B), the NCO group/OH group is preferably 5.0 or less, more preferably 0.01 to 4.75, and further Preferably it is 0.02-4.5, especially preferably 0.03-4.25, most preferably 0.05-4.0. When the equivalent ratio of NCO group/OH group exists in the said range, the effect of this invention can be exhibited more.

關於多官能異氰酸酯化合物(B)之含有比率，相對於胺基甲酸酯預聚物(A2)，多官能異氰酸酯化合物(B)較佳為0.01重量%～30重量%，更佳為0.05重量%～25重量%，進而較佳為0.1重量%～20重量%，尤佳為0.5重量%～17.5重量%，最佳為1重量%～15重量%。若多官能異氰酸酯化合物(B)之含有比率處於上述範圍內，則能夠更加表現本發明之效果。The content ratio of the polyfunctional isocyanate compound (B) is preferably 0.01% by weight to 30% by weight, more preferably 0.05% by weight, based on the urethane prepolymer (A2). ~25% by weight, more preferably 0.1% by weight to 20% by weight, especially preferably 0.5% by weight to 17.5% by weight, most preferably 1% by weight to 15% by weight. If the content rate of a polyfunctional isocyanate compound (B) exists in the said range, the effect of this invention can be expressed more.

作為由含有胺基甲酸酯預聚物(A2)及多官能異氰酸酯化合物(B)之胺基甲酸酯系黏著劑組合物形成胺基甲酸酯系黏著劑之方法，只要為使用所謂「胺基甲酸酯預聚物」作為原料來製作聚胺基甲酸酯系樹脂之方法，則可採用任意適當之製造方法。As a method of forming a urethane adhesive from a urethane adhesive composition containing a urethane prepolymer (A2) and a polyfunctional isocyanate compound (B), as long as the so-called " "Urethane prepolymer" is used as a method of producing a polyurethane-based resin as a raw material, and any appropriate production method can be adopted.

《1-3.抗靜電層》 本發明之實施方式之附黏著劑層之膜亦可於基材層與黏著劑層之間具有抗靜電層。 《1-3. Antistatic layer》 The adhesive layer-attached film according to the embodiment of the present invention may have an antistatic layer between the substrate layer and the adhesive layer.

作為抗靜電層之厚度，可於不損害本發明之效果之範圍內採用任意適當之厚度。此種厚度較佳為1 nm～1000 nm，更佳為5 nm～900 nm，進而較佳為7.5 nm～800 nm，尤佳為10 nm～700 nm。As the thickness of the antistatic layer, any appropriate thickness can be adopted within the range that does not impair the effect of the present invention. Such a thickness is preferably 1 nm to 1000 nm, more preferably 5 nm to 900 nm, further preferably 7.5 nm to 800 nm, especially preferably 10 nm to 700 nm.

抗靜電層可僅為1層，亦可為2層以上。The antistatic layer may be only one layer, or may be two or more layers.

作為抗靜電層，只要為能夠發揮抗靜電效果之層，則可於不損害本發明之效果之範圍內採用任意適當之抗靜電層。此種抗靜電層較佳為將包含導電性聚合物之導電塗佈液塗佈於任意適當之基材層上所形成之抗靜電層。具體而言，例如為將包含導電性聚合物之導電塗佈液塗佈於基材(例如基材層)上所形成之抗靜電層。作為具體之塗佈之方法，可例舉：輥式塗佈法、凹版塗佈法、反向塗佈法、輥式刷塗法、噴塗法、氣刀塗佈法、利用模嘴塗佈機等之擠出塗佈法等。As the antistatic layer, any appropriate antistatic layer can be used as long as it exhibits an antistatic effect within a range that does not impair the effect of the present invention. Such an antistatic layer is preferably an antistatic layer formed by coating a conductive coating liquid containing a conductive polymer on any suitable substrate layer. Specifically, for example, it is an antistatic layer formed by coating a conductive coating solution containing a conductive polymer on a substrate (such as a substrate layer). Specific coating methods include roll coating, gravure coating, reverse coating, roll brush coating, spray coating, air knife coating, and using a die coater. etc. Extrusion coating method etc.

作為包含導電性聚合物之導電塗佈液，可於不損害本發明之效果之範圍內採用任意適當之導電塗佈液。此種導電塗佈液較佳為包含導電性聚合物、黏合劑、交聯劑及溶劑。由於該溶劑於形成抗靜電層之過程中藉由加熱等而藉由揮發或蒸發等實質上消失，故而抗靜電層較佳包含導電性聚合物、黏合劑及交聯劑。As the conductive coating liquid containing a conductive polymer, any appropriate conductive coating liquid can be employed within the range not impairing the effect of the present invention. Such a conductive coating solution preferably includes a conductive polymer, a binder, a crosslinking agent and a solvent. Since the solvent substantially disappears by volatilization or evaporation by heating or the like during the process of forming the antistatic layer, the antistatic layer preferably includes a conductive polymer, a binder, and a crosslinking agent.

作為導電性聚合物，可於不損害本發明之效果之範圍內採用任意適當之導電性聚合物。作為此種導電性聚合物，例如可例舉：π共軛系導電性聚合物中摻雜有聚陰離子所得之導電性聚合物等。作為π共軛系導電性聚合物，可例舉：聚噻吩、聚吡咯、聚苯胺、聚乙炔等鏈狀導電性聚合物。作為聚陰離子，可例舉：聚苯乙烯磺酸、聚異戊二烯磺酸、聚乙烯基磺酸、聚烯丙基磺酸、聚丙烯酸乙基磺酸、聚甲基丙烯酸羧酸等。導電性聚合物可僅為1種，亦可為2種以上。As the conductive polymer, any appropriate conductive polymer can be employed within a range that does not impair the effects of the present invention. As such an electroconductive polymer, the electroconductive polymer obtained by doping a polyanion in the π-conjugated electroconductive polymer, etc. are mentioned, for example. Examples of the π-conjugated conductive polymer include chain conductive polymers such as polythiophene, polypyrrole, polyaniline, and polyacetylene. The polyanion may, for example, be polystyrenesulfonic acid, polyisoprenesulfonic acid, polyvinylsulfonic acid, polyallylsulfonic acid, polyacrylic acid ethylsulfonic acid or polymethacrylic acid carboxylic acid. Only 1 type may be sufficient as a conductive polymer, and 2 or more types may be sufficient as it.

抗靜電層中之導電性聚合物之含有比率較佳為3重量%～80重量%，更佳為5重量%～60重量%。The content rate of the conductive polymer in the antistatic layer is preferably from 3% by weight to 80% by weight, more preferably from 5% by weight to 60% by weight.

作為溶劑，例如可例舉：有機溶劑、水、或該等之混合溶劑。作為有機溶劑，例如可例舉：乙酸乙酯等酯類；甲基乙基酮、丙酮、環己酮等酮類；四氫呋喃(THF)、二㗁烷等環狀醚類；正己烷、環己烷等脂肪族或脂環族烴類；甲苯、二甲苯等芳香族烴類；甲醇、乙醇、正丙醇、異丙醇、環己醇等脂肪族或脂環族醇類；伸烷基二醇單烷基醚(例如乙二醇單甲醚、乙二醇單***)、二伸烷基二醇單烷基醚等二醇醚類；等。作為溶劑，較佳為水或將水作為主成分之混合溶劑(例如水與乙醇之混合溶劑)。As a solvent, an organic solvent, water, or these mixed solvents are mentioned, for example. Examples of organic solvents include: esters such as ethyl acetate; ketones such as methyl ethyl ketone, acetone, and cyclohexanone; cyclic ethers such as tetrahydrofuran (THF) and dioxane; n-hexane, cyclohexane, etc. Aliphatic or alicyclic hydrocarbons such as alkanes; Aromatic hydrocarbons such as toluene and xylene; Aliphatic or alicyclic alcohols such as methanol, ethanol, n-propanol, isopropanol and cyclohexanol; Alcohol monoalkyl ethers (such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether), glycol ethers such as dialkylene glycol monoalkyl ethers; etc. The solvent is preferably water or a mixed solvent containing water as a main component (for example, a mixed solvent of water and ethanol).

抗靜電層中之黏合劑之含有比率較佳為50重量%～95重量%，更佳為60重量%～90重量%。The content of the binder in the antistatic layer is preferably from 50% by weight to 95% by weight, more preferably from 60% by weight to 90% by weight.

作為導電塗佈液中可包含之黏合劑，可於不損害本發明之效果之範圍內採用任意適當之黏合劑。黏合劑可僅為1種，亦可為2種以上。此種黏合劑較佳為樹脂，更佳為聚酯樹脂。黏合劑中所占之聚酯樹脂之比率較佳為90重量%～100重量%，更佳為98重量%～100重量%。As the binder that can be contained in the conductive coating liquid, any appropriate binder can be employed within the range that does not impair the effect of the present invention. Only one type of binder may be used, or two or more types may be used. Such binder is preferably resin, more preferably polyester resin. The ratio of the polyester resin in the binder is preferably from 90% by weight to 100% by weight, more preferably from 98% by weight to 100% by weight.

聚酯樹脂較佳包含聚酯作為主成分(占較佳為超過50重量%、更佳為75重量%以上、進而較佳為90重量%以上、尤佳為實質上100重量%之成分)。The polyester resin preferably contains polyester as a main component (preferably more than 50% by weight, more preferably at least 75% by weight, further preferably at least 90% by weight, especially preferably substantially 100% by weight).

作為聚酯，可於不損害本發明之效果之範圍內採用任意適當之聚酯。作為此種聚酯，較佳為具有如下結構，即，選自1分子中具有2個以上之羧基之多元羧酸(例如二羧氧化合物)及其衍生物(例如多元羧酸之酸酐、酯化物、鹵化物等)之1種或2種以上之化合物(多元羧酸成分)與選自1分子中具有2個以上之羥基之多元醇(例如二醇)之1種或2種以上之化合物(多元醇成分)縮合而成之結構。As the polyester, any appropriate polyester can be employed within the range not impairing the effects of the present invention. Such a polyester preferably has a structure selected from polycarboxylic acids (such as dicarboxylates) and derivatives thereof (such as anhydrides and esters of polycarboxylic acids) having two or more carboxyl groups in one molecule. Compounds, halides, etc.) of one or more compounds (polycarboxylic acid components) and one or more compounds selected from polyols (such as diols) having two or more hydroxyl groups in one molecule (Polyol component) condensation structure.

作為多元羧酸成分，可於不損害本發明之效果之範圍內採用任意適當之多元羧酸。作為此種多元羧酸成分，例如可例舉：草酸、丙二酸、二氟丙二酸、烷基丙二酸、琥珀酸、四氟琥珀酸、烷基琥珀酸、(±)-蘋果酸、內消旋酒石酸、伊康酸、馬來酸、甲基馬來酸、富馬酸、甲基富馬酸、乙炔二羧酸、戊二酸、六氟戊二酸、甲基戊二酸、戊烯二酸、己二酸、二硫代己二酸、甲基己二酸、二甲基己二酸、四甲基己二酸、亞甲基己二酸、黏康酸、半乳糖二酸、庚二酸、軟木酸、全氟軟木酸、3,3,6,6-四甲基軟木酸、壬二酸、癸二酸、全氟癸二酸、十三烷二酸、十二烷基二羧酸、十三烷基二羧酸、十四烷基二羧酸等脂肪族二羧酸類；環烷基二羧酸(例如1,4-環己烷二羧酸、1,2-環己烷二羧酸)、1,4-(2-降𦯉烯)二羧酸、5-降𦯉烯-2,3-二羧酸(雙環庚烯二甲酸)、金剛烷二羧酸、螺庚烷二羧酸等脂環式二羧酸類；鄰苯二甲酸、間苯二甲酸、二硫代間苯二甲酸、甲基間苯二甲酸、二甲基間苯二甲酸、氯間苯二甲酸、二氯間苯二甲酸、對苯二甲酸、甲基對苯二甲酸、二甲基對苯二甲酸、氯對苯二甲酸、溴代對苯二甲酸、萘二甲酸、氧茀二羧酸、蒽二羧酸、聯苯二羧酸、聯伸苯二羧酸、二甲基聯伸苯二羧酸、4,4''-對聯三伸苯二羧酸、4,4''-對聯四苯二羧酸、聯苄二羧酸、偶氮苯二羧酸、高鄰苯二甲酸、伸苯基二乙酸、伸苯基二丙酸、萘二甲酸、萘二丙酸、聯苯二乙酸、聯苯二丙酸、3,3'-[4,4'-(亞甲基二對聯伸苯)]二丙酸、4,4'-聯苄二乙酸、3,3'(4,4'-聯苄)二丙酸、氧二對伸苯基二乙酸等芳香族二羧酸類；上述任一種多元羧酸之酸酐；上述任一種多元羧酸之酯(例如，烷基酯。單酯、二酯等)；與上述任一種多元羧酸對應之醯鹵化物(例如二羧酸醯氯)；等。As the polyvalent carboxylic acid component, any appropriate polyvalent carboxylic acid can be employed within the range not impairing the effects of the present invention. Examples of such polyvalent carboxylic acid components include oxalic acid, malonic acid, difluoromalonic acid, alkylmalonic acid, succinic acid, tetrafluorosuccinic acid, alkylsuccinic acid, (±)-malic acid , meso-tartaric acid, itaconic acid, maleic acid, methyl maleic acid, fumaric acid, methyl fumaric acid, acetylene dicarboxylic acid, glutaric acid, hexafluoroglutaric acid, methyl glutaric acid , glutaconic acid, adipic acid, dithioadipic acid, methyl adipate, dimethyl adipate, tetramethyl adipate, methylene adipate, muconic acid, galactose Diacid, pimelic acid, corkic acid, perfluorocorkic acid, 3,3,6,6-tetramethylcorkic acid, azelaic acid, sebacic acid, perfluorosebacic acid, tridecanedioic acid, Aliphatic dicarboxylic acids such as dialkyl dicarboxylic acid, tridecyl dicarboxylic acid, and tetradecyl dicarboxylic acid; cycloalkyl dicarboxylic acids (such as 1,4-cyclohexanedicarboxylic acid, 1, 2-cyclohexane dicarboxylic acid), 1,4-(2-nor-dicarboxylic acid), 5-nor-dicarboxylic acid, 2,3-dicarboxylic acid (bicycloheptene dicarboxylic acid), adamantane dicarboxylic acid alicyclic dicarboxylic acids such as spiroheptane dicarboxylic acid; phthalic acid, isophthalic acid, dithioisophthalic acid, methyl isophthalic acid, dimethyl isophthalic acid, chlorine Isophthalic acid, dichloroisophthalic acid, terephthalic acid, methyl terephthalic acid, dimethyl terephthalic acid, chloroterephthalic acid, bromoterephthalic acid, naphthalene dicarboxylic acid, oxygen Diphenylene dicarboxylic acid, anthracene dicarboxylic acid, biphenyl dicarboxylic acid, biphenyl dicarboxylic acid, dimethyl biphenyl dicarboxylic acid, 4,4''-p-triphenylene dicarboxylic acid, 4,4 ''-Petraphenylene dicarboxylic acid, bibenzyl dicarboxylic acid, azobenzene dicarboxylic acid, homophthalic acid, phenylenediacetic acid, phenylenedipropionic acid, naphthalene dicarboxylic acid, naphthalene dipropionic acid , biphenyl diacetic acid, biphenyl dipropionic acid, 3,3'-[4,4'-(methylene biphenylene)] dipropionic acid, 4,4'-biphenyl diacetic acid, 3,3 Aromatic dicarboxylic acids such as '(4,4'-bibenzyl)dipropionic acid and oxydiphenylene diacetic acid; anhydrides of any of the above-mentioned polycarboxylic acids; esters of any of the above-mentioned polycarboxylic acids (for example, alkane base esters, monoesters, diesters, etc.); acyl halides corresponding to any of the above-mentioned polycarboxylic acids (such as dicarboxylic acid acyl chloride); etc.

作為多元羧酸成分，可較佳例舉：對苯二甲酸、間苯二甲酸、萘二甲酸等芳香族二羧酸類及其酸酐；己二酸、癸二酸、壬二酸、琥珀酸、富馬酸、馬來酸、雙環庚烯二甲酸、1,4-環己烷二羧酸等脂肪族二羧酸類及其酸酐；該等二羧酸類之低級烷基酯(例如與碳原子數1～3之單醇之酯)；等。As the polycarboxylic acid component, preferably, aromatic dicarboxylic acids such as terephthalic acid, isophthalic acid, and naphthalene dicarboxylic acid and their anhydrides; adipic acid, sebacic acid, azelaic acid, succinic acid, Fumaric acid, maleic acid, bicycloheptenedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid and other aliphatic dicarboxylic acids and their anhydrides; lower alkyl esters of these dicarboxylic acids (for example, with the number of carbon atoms 1 to 3 monoalcohol esters); etc.

作為多元醇成分，可於不損害本發明之效果之範圍內採用任意適當之多元醇。作為此種多元醇成分，例如可例舉：乙二醇、丙二醇、1,2-丙二醇、1,3-丙二醇、1,3-丁二醇、1,4-丁二醇、新戊二醇、1,5-戊二醇、1,6-己二醇、3-甲基戊二醇、二乙二醇、1,4-環己烷二甲醇、3-甲基-1,5-戊二醇、2-甲基-1,3-丙二醇、2,2-二乙基-1,3-丙二醇、2-丁基-2-乙基-1,3-丙二醇、苯二甲醇、氫化雙酚A、雙酚A等二醇類；該等二醇類之環氧烷加成物(例如環氧乙烷加成物、環氧丙烷加成物等)；等。As the polyol component, any appropriate polyol can be employed within the range not impairing the effect of the present invention. Examples of such polyhydric alcohol components include ethylene glycol, propylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, and neopentyl glycol. , 1,5-pentanediol, 1,6-hexanediol, 3-methylpentanediol, diethylene glycol, 1,4-cyclohexanedimethanol, 3-methyl-1,5-pentane Diol, 2-methyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, 2-butyl-2-ethyl-1,3-propanediol, benzenedimethanol, hydrogenated bis Diols such as phenol A and bisphenol A; alkylene oxide adducts of these diols (such as ethylene oxide adducts, propylene oxide adducts, etc.); etc.

關於聚酯樹脂之分子量，藉由凝膠滲透層析法(GPC)所測得之標準聚苯乙烯換算之重量平均分子量(Mw)較佳為5×10 3～1.5×10 5，更佳為1×10 4～6×10 4。 Regarding the molecular weight of the polyester resin, the standard polystyrene-equivalent weight average molecular weight (Mw) measured by gel permeation chromatography (GPC) is preferably 5×10 3 to 1.5×10 5 , more preferably 1×10 4 to 6×10 4 .

聚酯樹脂之玻璃轉移溫度(Tg)較佳為0℃～120℃，更佳為10℃～80℃。The glass transition temperature (Tg) of the polyester resin is preferably from 0°C to 120°C, more preferably from 10°C to 80°C.

作為聚酯樹脂，例如可使用市售之Toyobo公司製造之商品名「VYLONAL」等。As a polyester resin, the commercially available Toyobo company make, a brand name "VYLONAL", etc. can be used, for example.

導電塗佈液可於不損害本發明之效果之範圍內進而含有除聚酯樹脂以外之樹脂(例如，選自丙烯酸樹脂、丙烯酸胺基甲酸酯樹脂、丙烯酸苯乙烯樹脂、丙烯酸矽酮樹脂、矽酮樹脂、聚矽氮烷樹脂、聚胺基甲酸酯樹脂、氟樹脂、聚烯烴樹脂之至少1種樹脂)作為黏合劑。The conductive coating solution may further contain resins other than polyester resins (for example, selected from acrylic resins, acrylic urethane resins, acrylic styrene resins, acrylic silicone resins, At least one resin selected from silicone resin, polysilazane resin, polyurethane resin, fluororesin, and polyolefin resin) as a binder.

作為導電塗佈液中可包含之交聯劑，可於不損害本發明之效果之範圍內採用任意適當之交聯劑。交聯劑可僅為1種，亦可為2種以上。作為此種交聯劑，可較佳例舉：異氰酸酯系交聯劑、環氧系交聯劑、三聚氰胺系交聯劑、過氧化物系交聯劑、及脲系交聯劑、金屬烷氧化物系交聯劑、金屬螯合物系交聯劑、金屬鹽系交聯劑、碳二醯亞胺系交聯劑、㗁唑啉系交聯劑、氮丙啶系交聯劑、胺系交聯劑等。其中較佳為三聚氰胺系交聯劑。As the crosslinking agent that may be contained in the conductive coating liquid, any appropriate crosslinking agent can be employed within the range that does not impair the effect of the present invention. The crosslinking agent may be only 1 type, and may be 2 or more types. As such a crosslinking agent, preferably, an isocyanate-based crosslinking agent, an epoxy-based crosslinking agent, a melamine-based crosslinking agent, a peroxide-based crosslinking agent, a urea-based crosslinking agent, a metal alkoxide Material-based cross-linking agent, metal chelate-based cross-linking agent, metal salt-based cross-linking agent, carbodiimide-based cross-linking agent, oxazoline-based cross-linking agent, aziridine-based cross-linking agent, amine-based crosslinking agent, etc. Among them, a melamine-based crosslinking agent is preferred.

抗靜電層中之交聯劑之含有比率較佳為1重量%～30重量%，更佳為2重量%～20重量%。The content ratio of the crosslinking agent in the antistatic layer is preferably 1% by weight to 30% by weight, more preferably 2% by weight to 20% by weight.

抗靜電層中亦可於不損害本發明之效果之範圍內包含任意適當之其他成分。Any other appropriate components may be contained in the antistatic layer within the range that does not impair the effect of the present invention.

《1-4.導電層》 本發明之實施方式之附黏著劑層之膜亦可於基材層與黏著劑層之間具有導電層。 《1-4. Conductive layer》 The adhesive layer-attached film according to the embodiment of the present invention may have a conductive layer between the base material layer and the adhesive layer.

導電層可僅為1層，亦可為2層以上。The conductive layer may be only one layer, or may be two or more layers.

導電層可藉由形成於任意適當之基材上(例如基材層)而設置。The conductive layer can be provided by being formed on any suitable substrate, such as a substrate layer.

關於導電層，例如藉由真空蒸鍍法、濺鍍法、離子鍍覆法、噴霧熱分解法、化學鍍覆法、電氣鍍覆法、或該等之組合法等任意適當之薄膜形成法而於任意適當之基材(例如基材層)上形成導電膜。該等薄膜形成法之中，就導電膜之形成速度或大面積膜之形成性、生產性等方面而言，較佳為真空蒸鍍法或濺鍍法。The conductive layer can be formed by any appropriate thin film forming method such as vacuum evaporation, sputtering, ion plating, spray pyrolysis, electroless plating, electroplating, or a combination thereof. A conductive film is formed on any suitable substrate (eg, a substrate layer). Among these thin film forming methods, the vacuum evaporation method or the sputtering method is preferable in terms of the formation speed of a conductive film, the formability of a large-area film, and productivity.

作為用於形成導電膜之材料，例如可使用：包含金、銀、鉑、鈀、銅、鋁、鎳、鉻、鈦、鐵、鈷、錫、該等之合金等之金屬系材料；包含氧化銦、氧化錫、氧化鈦、氧化鎘、該等之混合物等之金屬氧化物系材料；包含碘化銅等之其他金屬化合物；等。As the material used to form the conductive film, for example, metal-based materials including gold, silver, platinum, palladium, copper, aluminum, nickel, chromium, titanium, iron, cobalt, tin, alloys thereof, etc.; Metal oxide-based materials such as indium, tin oxide, titanium oxide, cadmium oxide, and mixtures thereof; other metal compounds including copper iodide, etc.; etc.

作為導電層之厚度，可於不損害本發明之效果之範圍內根據目的而採用任意適當之厚度。作為此種厚度，例如，於由金屬系材料形成之情形時，較佳為30 Å～600 Å，於由金屬氧化物系材料形成之情形時，較佳為80 Å～5000 Å。As the thickness of the conductive layer, any appropriate thickness can be adopted according to the purpose within the range that does not impair the effect of the present invention. Such a thickness is, for example, preferably 30 Å to 600 Å when formed of a metal-based material, and preferably 80 Å to 5000 Å when formed of a metal oxide-based material.

導電層之表面電阻值較佳為1.0×10 10Ω/□以下，更佳為1.0×10 9Ω/□以下，進而較佳為1.0×10 8Ω/□以下，尤佳為1.0×10 7Ω/□以下。 The surface resistance of the conductive layer is preferably 1.0×10 10 Ω/□ or less, more preferably 1.0×10 9 Ω/□ or less, still more preferably 1.0×10 8 Ω/□ or less, and most preferably 1.0×10 7 Ω/□ Ω/□ or less.

當於任意適當之基材(例如基材層)上形成導電膜時，亦可對該基材(例如基材層)之表面實施電暈放電處理、紫外線照射處理、電漿處理、濺鍍蝕刻處理、底漆塗佈處理等任意適當之預處理而提高導電膜與該基材(例如基材層)之密接性。When forming a conductive film on any suitable substrate (such as a substrate layer), the surface of the substrate (such as a substrate layer) can also be subjected to corona discharge treatment, ultraviolet irradiation treatment, plasma treatment, sputter etching Any appropriate pretreatment such as treatment and primer coating treatment can improve the adhesion between the conductive film and the substrate (such as the substrate layer).

《《2.附黏著劑層之膜之製造方法》》 本發明之實施方式之附黏著劑層之膜可於不損害本發明之效果之範圍內藉由任意適當之方法而製造。 "2. Manufacturing method of film with adhesive layer" The film with the adhesive layer according to the embodiment of the present invention can be produced by any appropriate method within the range that does not impair the effect of the present invention.

作為附黏著劑層之膜之製造方法之代表例，如圖1所示，對附黏著劑層之膜100為基材層10與黏著劑層20直接積層而成之膜之形態的情形進行說明。As a representative example of the production method of the adhesive layer-attached film, as shown in FIG. 1 , the case where the adhesive layer-attached film 100 is in the form of a film in which the base material layer 10 and the adhesive layer 20 are directly laminated will be described. .

於附黏著劑層之膜為基材層與黏著劑層直接積層而成之膜之情形時，作為代表性製造方法，可例舉如下述(1)、(2)之方法。 (1)製備用於形成黏著劑層之黏著劑組合物。 (2)將黏著劑組合物塗佈於基材層之表面，視需要進行加熱及乾燥，視需要進行硬化，於基材層上形成黏著劑層。 [實施例] When the film with the adhesive layer is a film in which the base material layer and the adhesive layer are directly laminated, the following (1) and (2) methods can be exemplified as typical production methods. (1) Prepare an adhesive composition for forming an adhesive layer. (2) Apply the adhesive composition on the surface of the substrate layer, heat and dry if necessary, and harden if necessary to form an adhesive layer on the substrate layer. [Example]

以下，藉由實施例具體地說明本發明，但本發明並不受該等實施例任何限定。再者，實施例等中之試驗及評價方法如下所示。再者，於記載為「份」之情形時，只要沒有特別記載事項，則意指「重量份」，於記載為「%」之情形時，只要沒有特別記載事項，則意指「重量%」。Hereinafter, the present invention will be specifically described by way of examples, but the present invention is not limited by these examples. In addition, the test and evaluation method in an Example etc. are as follows. In addition, when described as "part", unless otherwise specified, it means "weight part", and when described as "%", unless otherwise specified, it means "weight%" .

＜厚度之測定＞ 實施例及比較例之黏著劑層之厚度係使用干涉膜厚計(大塚電子公司製造，製品名「MCPD-3700」實施測定。 ＜Measurement of thickness＞ The thickness of the adhesive layer in Examples and Comparative Examples was measured using an interference film thickness meter (manufactured by Otsuka Electronics Co., Ltd., product name "MCPD-3700").

＜Tg之測定＞ 關於玻璃轉移溫度(Tg)(℃)，將各單體之均聚物之玻璃轉移溫度設為Tgn(℃)，使用下述文獻值，藉由下述式而求出。 式：1/(Tg＋273)＝Σ[Wn/(Tgn＋273)] (式中，Tg(℃)表示共聚物之玻璃轉移溫度，Wn表示各單體之重量分率，Tgn(℃)表示各單體之均聚物之玻璃轉移溫度，n表示各單體之種類) 丙烯酸2-乙基己酯(2EHA)之均聚物之玻璃轉移溫度：-70℃ 丙烯酸羥基乙酯(HEA)之均聚物之玻璃轉移溫度：-15℃ 丙烯酸4-羥基丁酯(HBA)之均聚物之玻璃轉移溫度：-32℃ 丙烯酸(AA)之均聚物之玻璃轉移溫度：106℃ 再者，參照「丙烯酸樹脂之合成、設計及新用途開發」(中央經營開發中心出版部發行)作為文獻值。 ＜Determination of Tg＞ Regarding the glass transition temperature (Tg) (° C.), the glass transition temperature of the homopolymer of each monomer was defined as Tgn (° C.), and it was obtained by the following formula using the following literature value. Formula: 1/(Tg+273)=Σ[Wn/(Tgn+273)] (In the formula, Tg (°C) represents the glass transition temperature of the copolymer, Wn represents the weight fraction of each monomer, Tgn (°C) represents the glass transition temperature of the homopolymer of each monomer, n represents the type of each monomer ) Glass transition temperature of homopolymer of 2-ethylhexyl acrylate (2EHA): -70℃ Glass transition temperature of homopolymer of hydroxyethyl acrylate (HEA): -15℃ Glass transition temperature of homopolymer of 4-hydroxybutyl acrylate (HBA): -32℃ Glass transition temperature of homopolymer of acrylic acid (AA): 106°C Furthermore, refer to "Synthesis, Design and New Application Development of Acrylic Resin" (published by the Publishing Department of the Central Management and Development Center) as the literature value.

＜重量平均分子量之測定＞ 重量平均分子量係藉由凝膠滲透層析法(GPC)法進行測定。具體而言，使用商品名「HLC-8120GPC」(東曹股份有限公司製造)作為GPC測定裝置，藉由下述條件進行測定，藉由標準聚苯乙烯換算值進行計算。 (分子量測定條件) ・樣品濃度：0.2重量%(四氫呋喃溶液) ・樣品注入量：10 μL ・管柱：商品名「TSKguardcolumn SuperHZ-H(1根＋TSKgel SuperHZM-H(2根)」(東曹股份有限公司製造) ・參考管柱：商品名「TSKgel SuperH-RC(1根)」(東曹股份有限公司製造) ・溶離液：四氫呋喃(THF) ・流量：0.6 mL/min ・檢測器：示差折射計(RI) ・管柱溫度(測定溫度)：40℃ ＜Determination of weight average molecular weight＞ The weight average molecular weight is measured by gel permeation chromatography (GPC) method. Specifically, using a trade name "HLC-8120GPC" (manufactured by Tosoh Corporation) as a GPC measuring device, measurement was performed under the following conditions, and calculation was performed using standard polystyrene conversion values. (Molecular weight measurement conditions) ・Sample concentration: 0.2% by weight (tetrahydrofuran solution) ・Sample injection volume: 10 μL ・Column: Product name "TSKguardcolumn SuperHZ-H (1 piece + TSKgel SuperHZM-H (2 pieces)" (manufactured by Tosoh Co., Ltd.) ・Reference string: Trade name "TSKgel SuperH-RC (1 piece)" (manufactured by Tosoh Co., Ltd.) ・Eluent: Tetrahydrofuran (THF) ・Flow rate: 0.6 mL/min ・Detector: Differential refractometer (RI) ・Column temperature (measuring temperature): 40°C

＜以剝離速度0.3 m/分鐘、剝離角度180度所測得之低速剝離力之測定＞ 對於所製造之附黏著劑層之膜，藉由手壓輥將黏著劑層壓接於基材層，其後，於0.25 MPa、0.3 m/min之壓接條件下進行層壓貼合，於23℃、濕度50%RH之環境下放置20分鐘。其後，將膜裁剪成25 mm之寬度，將黏著劑層之與基材層相反一側貼合於SUS(Steel Use Stainless，不鏽鋼)板(SUS304BA)進行固定。當使用萬能拉伸試驗機(Minebea股份有限公司製造，製品名：TCM-1kNB)，以剝離速度0.3 m/分鐘、剝離角度180度將黏著劑層自基材層剝離時，將所測得之剝離力設為低速剝離力。 <Measurement of low-speed peeling force measured at a peeling speed of 0.3 m/min and a peeling angle of 180 degrees> For the manufactured film with the adhesive layer, the adhesive layer was bonded to the substrate layer by hand roller, and then laminated under the pressure bonding conditions of 0.25 MPa and 0.3 m/min. Place it in an environment of 23°C and 50%RH for 20 minutes. Thereafter, the film was cut to a width of 25 mm, and the side of the adhesive layer opposite to the substrate layer was bonded to a SUS (Steel Use Stainless, stainless steel) plate (SUS304BA) and fixed. When the adhesive layer is peeled from the substrate layer at a peeling speed of 0.3 m/min and a peeling angle of 180 degrees using a universal tensile testing machine (manufactured by Minebea Co., Ltd., product name: TCM-1kNB), the measured The peel force was set as a low-speed peel force.

＜以剝離速度10 m/分鐘、剝離角度180度所測得之高速剝離力之測定＞ 對於所製造之附黏著劑層之膜，藉由手壓輥將黏著劑層壓接於基材層，其後，於0.25 MPa、0.3 m/min之壓接條件下進行層壓貼合，於23℃、相對濕度50%RH之環境下放置20分鐘。其後，將膜裁剪成25 mm之寬度，將黏著劑層之與基材層相反一側貼合於SUS板(SUS304BA)進行固定。當使用萬能拉伸試驗機(Minebea股份有限公司製造，製品名：TCM-1kNB)，以剝離速度10 m/分鐘、剝離角度180度將黏著劑層自基材層剝離時，將所測得之剝離力作為高速剝離力。 <Measurement of high-speed peeling force measured at a peeling speed of 10 m/min and a peeling angle of 180 degrees> For the manufactured film with the adhesive layer, the adhesive layer was bonded to the substrate layer by hand roller, and then laminated under the pressure bonding conditions of 0.25 MPa and 0.3 m/min. Place in an environment of 23°C and relative humidity of 50%RH for 20 minutes. Thereafter, the film was cut to a width of 25 mm, and the side of the adhesive layer opposite to the base layer was bonded to a SUS plate (SUS304BA) and fixed. When the adhesive layer is peeled from the substrate layer at a peeling speed of 10 m/min and a peeling angle of 180 degrees using a universal tensile testing machine (manufactured by Minebea Co., Ltd., product name: TCM-1kNB), the measured The peel force is taken as a high speed peel force.

＜異物去除率＞ 對於所製造之附黏著劑層之膜，於溫度23℃、濕度50%RH下，於非清潔環境下(具體而言，與如藉由ISO146441-1：2015中之定義對潔淨度進行區分以設置管理基準之無塵室不同的空間)，將黏著劑層與光學膜(具體而言，日本專利特開2017-26939號公報之實施例所記載之「透明保護膜1A」)以10 cm 2×10 cm 2之尺寸進行貼合，對貼合時咬入之異物進行標記，藉由光學顯微鏡對異物之尺寸進行確認。對100 μm以上之異物進行計數，剝離附黏著劑層之膜後，對殘留於光學膜之異物進行計數，確認異物去除率。 <Foreign matter removal rate> For the film with the adhesive layer produced, at a temperature of 23°C and a humidity of 50%RH, in a non-clean environment (specifically, as defined by ISO146441-1:2015) Cleanliness is differentiated to set management standards in different spaces of the clean room), the adhesive layer and the optical film (specifically, the "transparent protective film 1A" described in the embodiment of Japanese Patent Laid-Open No. 2017-26939 ) with a size of 10 cm 2 ×10 cm 2 , mark the foreign matter bitten during lamination, and confirm the size of the foreign matter with an optical microscope. Count the foreign objects larger than 100 μm, and after peeling off the film with the adhesive layer, count the foreign objects remaining on the optical film to confirm the foreign object removal rate.

＜列印密接性＞ 於23℃×50%RH之測定環境下，使用旗牌(Shachihata)公司製造之X壓模，於附黏著劑層之膜之背面(即，基材層)上實施列印，其後，自該列印之上貼附米其邦(Nichiban)公司製造之Sellotape(註冊商標)，其次，於剝離速度30 m/分鐘、剝離角度180度之條件下進行剝離。其後，目測觀察剝離後之基材層表面，將列印面積剝離50%以上之情形評價為×(列印性不良)，將列印面積殘留50%以上而未剝離之情形評價為○(列印性良好)。 ＜Print Adhesiveness＞ Under the measurement environment of 23°C×50%RH, the X stamper manufactured by Shachihata Co., Ltd. was used to print on the back side of the film with the adhesive layer (ie, the substrate layer), and then, from Sellotape (registered trademark) manufactured by Nichiban Co., Ltd. was attached to the print, and then peeled off at a peeling speed of 30 m/min and a peeling angle of 180 degrees. Thereafter, the surface of the substrate layer after peeling was visually observed, and the case where 50% or more of the printed area was peeled off was evaluated as × (poor printability), and the case where 50% or more of the printed area remained without peeling was evaluated as ○ ( good printability).

＜糊劑殘渣評價＞ 用筆尖摩擦黏著劑層之表面，目視判斷黏著劑層是否被破壞。 於螢光燈下進行目視。若黏著劑層未破壞，則不會產生糊劑殘渣，若黏著劑層被破壞，則會產生糊劑殘渣。評價係藉由下述基準進行。 ○：完全未觀察到糊劑殘渣產生。 ×：觀察到糊劑殘渣產生。 ＜Evaluation of Paste Residue＞ Rub the surface of the adhesive layer with a pen tip, and visually judge whether the adhesive layer is damaged. Visual inspection was performed under fluorescent light. If the adhesive layer is not damaged, no paste residue will be generated, and if the adhesive layer is damaged, paste residue will be generated. The evaluation was performed by the following criteria. ◯: Generation of paste residue was not observed at all. X: Paste residue generation was observed.

[製造例1] 使用具有3個OH基之多元醇Preminol S3011(旭硝子股份有限公司製造，Mn＝10000)85重量份、具有3個OH基之多元醇Sannix GP-3000(三洋化成股份有限公司製造，Mn＝3000)13重量份、具有3個OH基之多元醇Sannix GP-1000(三洋化成股份有限公司製造，Mn＝1000)2重量份作為多元醇(A1)，調配作為多官能異氰酸酯化合物(B)之多官能脂環族系異氰酸酯化合物Coronate HX(Nippon Polyurethane Industry股份有限公司)18重量份、觸媒(日本化學產業股份有限公司製造，商品名：三乙醯丙酮鐵)0.15重量份、作為抗劣化劑之Irganox1010(BASF製造)0.50重量份、脂肪酸酯(棕櫚酸異丙酯，花王製造，商品名：EXCEPARL IPP，Mn＝299)30重量份、作為稀釋溶劑之乙酸乙酯241重量份，藉由分散機進行攪拌，獲得胺基甲酸酯系黏著劑組合物(1)。 [manufacturing example 1] Use 85 parts by weight of polyol Preminol S3011 (manufactured by Asahi Glass Co., Ltd., Mn=10000) with 3 OH groups, and Sannix GP-3000 (manufactured by Sanyo Chemical Industry Co., Ltd., Mn=3000) with 3 OH groups 13 parts by weight, polyol Sannix GP-1000 (manufactured by Sanyo Chemical Industry Co., Ltd., Mn=1000) having 3 OH groups, 2 parts by weight as polyol (A1), and blending as polyfunctional isocyanate compound (B) Alicyclic isocyanate compound Coronate HX (Nippon Polyurethane Industry Co., Ltd.) 18 parts by weight, catalyst (manufactured by Nippon Chemical Industry Co., Ltd., trade name: iron triacetylacetonate) 0.15 parts by weight, Irganox 1010 as an anti-deterioration agent (manufactured by BASF) 0.50 parts by weight, fatty acid ester (isopropyl palmitate, manufactured by Kao, trade name: EXCEPARL IPP, Mn=299) 30 parts by weight, 241 parts by weight of ethyl acetate as a diluting solvent, by a disperser Stirring was performed to obtain a urethane-based adhesive composition (1).

[製造例2] 於具備攪拌葉片、溫度計、氮氣導入管、冷卻器之四口燒瓶中裝入丙烯酸2-乙基己酯(2EHA)100重量份、丙烯酸4-羥基丁酯(4HBA)10重量份、丙烯酸(AA)0.02重量份、作為聚合起始劑之2,2'-偶氮二異丁腈(AIBN)(和光純藥製造)0.2重量份、乙酸乙酯157重量份，一面緩慢地進行攪拌，一面導入氮氣，將燒瓶內之液溫保持在65℃左右進行約6小時之聚合反應，製備丙烯酸系聚合物(1)之溶液(固形物成分濃度＝40重量%)。所獲得之丙烯酸系聚合物(1)之重量平均分子量(Mw)為54萬，Tg為-67℃。藉由乙酸乙酯將所獲得之丙烯酸系聚合物(1)之溶液(固形物成分濃度＝40重量%)稀釋至5重量%，相對於該溶液中之丙烯酸系聚合物(1)100重量份(固形物成分)，加入六亞甲基二異氰酸酯之異氰尿酸酯體(Nippon Polyurethane Industry公司製造，Coronate HX)6重量份、作為錫系觸媒之二月桂酸二辛基錫(Tokyo Fine Chemical製造，Embilizer OL-1)0.03重量份、作為交聯延遲劑之乙醯丙酮10重量份，保持在25℃左右進行約1分鐘之混合攪拌，製備丙烯酸系黏著劑組合物(1)。 [Manufacturing example 2] 100 parts by weight of 2-ethylhexyl acrylate (2EHA), 10 parts by weight of 4-hydroxybutyl acrylate (4HBA), acrylic acid (AA ) 0.02 parts by weight, 0.2 parts by weight of 2,2'-azobisisobutyronitrile (AIBN) (manufactured by Wako Pure Chemical Industries, Ltd.) as a polymerization initiator, and 157 parts by weight of ethyl acetate, while stirring slowly, introduce Nitrogen gas was used to keep the liquid temperature in the flask at about 65° C. and perform a polymerization reaction for about 6 hours to prepare a solution of the acrylic polymer (1) (solid content concentration = 40% by weight). The weight average molecular weight (Mw) of the obtained acrylic polymer (1) was 540,000, and Tg was -67 degreeC. The obtained solution of the acrylic polymer (1) (solid content concentration = 40% by weight) was diluted to 5% by weight with ethyl acetate, relative to 100 parts by weight of the acrylic polymer (1) in the solution (Solid content), add 6 parts by weight of isocyanurate body of hexamethylene diisocyanate (manufactured by Nippon Polyurethane Industry, Coronate HX), dioctyltin dilaurate (Tokyo Fine Made by Chemical, 0.03 parts by weight of Embilizer OL-1) and 10 parts by weight of acetylacetone as a crosslinking retarder were kept at about 25°C for about 1 minute and mixed to prepare an acrylic adhesive composition (1).

[製造例3]：離型層形成材料(1)之製備 使乾燥丁醛樹脂(積水化學工業製造，S-LEC KW-10)所獲得之樹脂100重量份溶解於二甲苯(太陽化學製造，xylol)900重量份中，繼而，加入十八烷基異氰酸酯(Ohara Paragium Chemical股份有限公司製造，R-NCO)480重量份。進而，將該溶液藉由甲苯(出光石油化學製造)進行稀釋使得固形物成分成為0.2重量%，製作離型層形成材料(1)。 [Manufacturing example 3]: Preparation of release layer forming material (1) 100 parts by weight of resin obtained by drying butyral resin (manufactured by Sekisui Chemical Industry, S-LEC KW-10) was dissolved in 900 parts by weight of xylene (manufactured by Taiyo Chemical Industry, xylol), and then octadecyl isocyanate ( Ohara Paragium Chemical Co., Ltd. product, R-NCO) 480 parts by weight. Furthermore, this solution was diluted with toluene (manufactured by Idemitsu Petrochemical Co., Ltd.) so that the solid content would become 0.2% by weight, and a release layer forming material (1) was produced.

[實施例1] 將製造例1所獲得之胺基甲酸酯系黏著劑組合物(1)塗佈於作為基材層之厚度38 μm之PET膜(Mitsubishi Chemical製造，Diafoil T100C38)，於130℃下乾燥30秒，形成厚度1.0 μm之胺基甲酸酯系黏著劑層，製成基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度1.0 μm)之構成的無隔離件之附黏著劑層之膜(1)。將結果示於表1。 [Example 1] The urethane-based adhesive composition (1) obtained in Production Example 1 was applied to a PET film (manufactured by Mitsubishi Chemical, Diafoil T100C38) with a thickness of 38 μm as a substrate layer, and dried at 130° C. for 30 seconds , forming a urethane-based adhesive layer with a thickness of 1.0 μm to form a substrate layer (thickness 38 μm) / urethane-based adhesive layer (thickness 1.0 μm) without a spacer. The film of agent layer (1). The results are shown in Table 1.

[實施例2] 除將黏著劑層之厚度設為2.0 μm以外，以與實施例1相同之方式進行，製成基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度2.0 μm)之構成的無隔離件之附黏著劑層之膜(2)。將結果示於表1。 [Example 2] Except that the thickness of the adhesive layer was set to 2.0 μm, it was carried out in the same manner as in Example 1, and the composition of the substrate layer (thickness 38 μm)/urethane-based adhesive layer (thickness 2.0 μm) was prepared. Adhesive layer-attached film (2) without separator. The results are shown in Table 1.

[實施例3] 除將黏著劑層之厚度設為3.0 μm以外，以與實施例1相同之方式進行，製造基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度3.0 μm)之構成的無隔離件之附黏著劑層之膜(3)。將結果示於表1。 [Example 3] Except that the thickness of the adhesive layer was set to 3.0 μm, it was carried out in the same manner as in Example 1, and a substrate layer (thickness: 38 μm)/urethane-based adhesive layer (thickness: 3.0 μm) was produced. Adhesive layer-attached film (3) without spacer. The results are shown in Table 1.

[實施例4] 除將黏著劑層之厚度設為6.0 μm以外，以與實施例1相同之方式進行，製造基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度6.0 μm)之構成的無隔離件之附黏著劑層之膜(4)。將結果示於表1。 [Example 4] Except that the thickness of the adhesive layer was set to 6.0 μm, it was carried out in the same manner as in Example 1, and a composition consisting of a substrate layer (thickness 38 μm)/urethane-based adhesive layer (thickness 6.0 μm) was produced. Adhesive layer-attached film (4) without spacer. The results are shown in Table 1.

[比較例1] 將製造例3所獲得之離型層形成材料(1)塗佈於作為基材層之厚度38 μm之PET膜(Mitsubishi Chemical製造，Diafoil T100C38)，於130℃下乾燥60秒，製作離型層與基材層之積層體。離型層之乾燥後之厚度為20 nm。進而，將製造例2所獲得之丙烯酸系黏著劑組合物(1)塗佈於上述積層體之基材層之與離型層相反一側，於130℃下加熱60秒，形成厚度1.5 μm之丙烯酸系黏著劑層，製造離型層(厚度20 nm)/基材層(厚度38 μm)/丙烯酸系黏著劑層(厚度1.5 μm)之構成的無隔離件之附黏著劑層之膜(C1)。將結果示於表1。 [Comparative example 1] The release layer forming material (1) obtained in Production Example 3 was applied to a PET film (manufactured by Mitsubishi Chemical, Diafoil T100C38) with a thickness of 38 μm as a substrate layer, and dried at 130° C. for 60 seconds to prepare a release layer A laminate with a substrate layer. The thickness of the release layer after drying is 20 nm. Furthermore, the acrylic adhesive composition (1) obtained in Production Example 2 was coated on the side opposite to the release layer of the substrate layer of the above-mentioned laminate, and heated at 130°C for 60 seconds to form a 1.5 μm-thick adhesive. Acrylic adhesive layer, for the production of release layer (thickness 20 nm) / substrate layer (thickness 38 μm) / acrylic adhesive layer (thickness 1.5 μm) without separator adhesive layer film (C1 ). The results are shown in Table 1.

[比較例2] 將製造例2所獲得之丙烯酸系黏著劑組合物(1)塗佈於作為基材層之厚度38 μm之PET膜(Mitsubishi Chemical製造，Diafoil T100C38)，於130℃下乾燥60秒，形成厚度1.0 μm之丙烯酸系黏著劑層，製造基材層(厚度38 μm)/丙烯酸系黏著劑層(厚度1.0 μm)之構成的無隔離件之附黏著劑層之膜(C2)。將結果示於表1。 [Comparative example 2] The acrylic adhesive composition (1) obtained in Production Example 2 was applied to a PET film (manufactured by Mitsubishi Chemical, Diafoil T100C38) with a thickness of 38 μm as a substrate layer, and dried at 130° C. for 60 seconds to form a thickness of 1.0 μm. The acrylic adhesive layer of μm was used to manufacture a film (C2) with an adhesive layer without a spacer consisting of a substrate layer (thickness 38 μm)/acrylic adhesive layer (thickness 1.0 μm). The results are shown in Table 1.

[比較例3] 除將黏著劑層之厚度設為0.5 μm以外，以與實施例1相同之方式進行，製造基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度0.5 μm)之構成的無隔離件之附黏著劑層之膜(C3)。將結果示於表1。 [Comparative example 3] Except that the thickness of the adhesive layer was set to 0.5 μm, it was carried out in the same manner as in Example 1, and a substrate layer (thickness: 38 μm)/urethane-based adhesive layer (thickness: 0.5 μm) was produced. Film with adhesive layer without separator (C3). The results are shown in Table 1.

[比較例4] 除將黏著劑層之厚度設為9.0 μm以外，以與實施例1相同之方式進行，製造基材層(厚度38 μm)/胺基甲酸酯系黏著劑層(厚度9.0 μm)之構成的無隔離件之附黏著劑層之膜(C4)。將結果示於表1。 [Comparative example 4] Except that the thickness of the adhesive layer was set to 9.0 μm, it was carried out in the same manner as in Example 1, and a substrate layer (thickness: 38 μm)/urethane-based adhesive layer (thickness: 9.0 μm) was produced. Film with adhesive layer without separator (C4). The results are shown in Table 1.

[表1]       基材層 黏著劑層 離型層 自背面剝離力 異物去除率 列印密接性 糊劑殘渣評價 用於形成之黏著劑組合物 厚度 (μm) 低速剝離力 (N/25 mm) 高速剝離力 (N/25 mm) 實施例 1 PET 胺基甲酸酯系黏著劑組合物(1) 1 無 0.010 0.07 83% ○ ○ 2 PET 胺基甲酸酯系黏著劑組合物(1) 2 無 0.013 0.08 85% ○ ○ 3 PET 胺基甲酸酯系黏著劑組合物(1) 3 無 0.014 0.09 88% ○ ○ 4 PET 胺基甲酸酯系黏著劑組合物(1) 6 無 0.016 0.10 90% ○ ○ 比較例 1 PET 丙烯酸系黏著劑組合物(1) 1.5 有 0.022 0.05 83% × × 2 PET 丙烯酸系黏著劑組合物(1) 1 無 0.123 0.35 80% ○ × 3 PET 胺基甲酸酯系黏著劑組合物(1) 0.5 無 0.008 0.06 78% ○ ○ 4 PET 胺基甲酸酯系黏著劑組合物(1) 9 無 0.022 0.12 90% ○ ○ [產業上之可利用性] [Table 1] Substrate layer adhesive layer Release layer Peel force from the back Foreign matter removal rate print tightness Paste Residue Evaluation Adhesive composition for forming Thickness (μm) Low speed peeling force (N/25 mm) High-speed peel force (N/25 mm) Example 1 PET Urethane Adhesive Composition (1) 1 none 0.010 0.07 83% ○ ○ 2 PET Urethane Adhesive Composition (1) 2 none 0.013 0.08 85% ○ ○ 3 PET Urethane Adhesive Composition (1) 3 none 0.014 0.09 88% ○ ○ 4 PET Urethane Adhesive Composition (1) 6 none 0.016 0.10 90% ○ ○ comparative example 1 PET Acrylic adhesive composition (1) 1.5 have 0.022 0.05 83% x x 2 PET Acrylic adhesive composition (1) 1 none 0.123 0.35 80% ○ x 3 PET Urethane Adhesive Composition (1) 0.5 none 0.008 0.06 78% ○ ○ 4 PET Urethane Adhesive Composition (1) 9 none 0.022 0.12 90% ○ ○ [Industrial availability]

本發明之附黏著劑層之膜可較佳地用於光學構件或電子構件之製造步驟等。The film with an adhesive layer of the present invention can be preferably used in manufacturing steps of optical members or electronic members, and the like.

10:基材層 20:黏著劑層 100:附黏著劑層之膜 10: Substrate layer 20: Adhesive layer 100: film with adhesive layer

圖1係本發明之附黏著劑層之膜之一個實施方式之概略剖視圖。Fig. 1 is a schematic cross-sectional view of one embodiment of the film with an adhesive layer of the present invention.

10:基材層 10: Substrate layer

20:黏著劑層 20: Adhesive layer

100:附黏著劑層之膜 100: film with adhesive layer

Claims (6)

一種附黏著劑層之膜，其係具有基材層及黏著劑層者， 該黏著劑層之與該基材層相反一側不具有隔離件， 該基材層之與該黏著劑層相反一側不具有離型層， 該基材層包含聚酯系樹脂， 該黏著劑層為包含胺基甲酸酯系黏著劑之胺基甲酸酯系黏著劑層，且 該黏著劑層之厚度為1.0 μm～6.0 μm。 A film with an adhesive layer comprising a substrate layer and an adhesive layer, The side of the adhesive layer opposite to the substrate layer does not have a spacer, The opposite side of the substrate layer to the adhesive layer does not have a release layer, The substrate layer contains a polyester resin, The adhesive layer is a urethane-based adhesive layer comprising a urethane-based adhesive, and The thickness of the adhesive layer is 1.0 μm˜6.0 μm. 如請求項1之附黏著劑層之膜，其中於溫度23℃、濕度50%RH下，以剝離速度0.3 m/分鐘、剝離角度180度所測得的上述黏著劑層對上述基材層之與該黏著劑層相反一側之面之低速剝離力為0.01 N/25 mm以上。A film with an adhesive layer as claimed in claim 1, wherein the adhesive layer to the substrate layer is measured at a peeling speed of 0.3 m/min and a peeling angle of 180 degrees at a temperature of 23°C and a humidity of 50%RH. The low-speed peeling force of the side opposite to the adhesive layer is 0.01 N/25 mm or more. 如請求項1或2之附黏著劑層之膜，其中於溫度23℃、濕度50%RH下，以剝離速度10 m/分鐘、剝離角度180度所測得的上述黏著劑層對上述基材層之與該黏著劑層相反一側之面之高速剝離力為0.10 N/25 mm以下。A film with an adhesive layer according to claim 1 or 2, wherein the adhesive layer is measured against the substrate at a temperature of 23°C and a humidity of 50%RH at a peeling speed of 10 m/min and a peeling angle of 180 degrees. The high-speed peeling force of the side of the layer opposite to the adhesive layer is 0.10 N/25 mm or less. 如請求項1至3中任一項之附黏著劑層之膜，其中上述胺基甲酸酯系黏著劑由胺基甲酸酯系黏著劑組合物形成，且該胺基甲酸酯系黏著劑組合物含有多元醇(A1)及多官能異氰酸酯化合物(B)。The film with an adhesive layer according to any one of claims 1 to 3, wherein the urethane-based adhesive is formed from a urethane-based adhesive composition, and the urethane-based adhesive is The agent composition contains a polyol (A1) and a polyfunctional isocyanate compound (B). 如請求項4之附黏著劑層之膜，其中上述多元醇(A1)包含數量平均分子量Mn為400～20000之多元醇。The film with an adhesive layer according to claim 4, wherein the polyol (A1) includes a polyol having a number average molecular weight Mn of 400 to 20,000. 如請求項4或5之附黏著劑層之膜，其中上述多官能異氰酸酯化合物(B)相對於上述多元醇(A1)之含有比率為5重量%～60重量%。The film with an adhesive layer according to claim 4 or 5, wherein the content ratio of the polyfunctional isocyanate compound (B) to the polyol (A1) is 5% by weight to 60% by weight.
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