TW202023383A - Clothes insect pest repellent composition, and clothes deodorizing method and clothes insect pest repelling and deodorizing method using said composition - Google Patents

Clothes insect pest repellent composition, and clothes deodorizing method and clothes insect pest repelling and deodorizing method using said composition Download PDF

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TW202023383A
TW202023383A TW108139870A TW108139870A TW202023383A TW 202023383 A TW202023383 A TW 202023383A TW 108139870 A TW108139870 A TW 108139870A TW 108139870 A TW108139870 A TW 108139870A TW 202023383 A TW202023383 A TW 202023383A
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clothing
pest repellent
fragrance
repellent composition
component
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TW108139870A
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Chinese (zh)
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田丸友裕
鹿島誠一
中山幸治
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日商大日本除蟲菊股份有限公司
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Textile Engineering (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Toxicology (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Provided is a fabric pest repelling composition achieving a pest proofing function while being capable of removing unpleasant odors attached to clothes in a sustained manner. In this fabric pest repelling composition containing a pest repelling component and an aroma component, the aroma component has a deodorization function of removing unpleasant odors that have attached to clothes, and the pest repelling component has a sustaining function that causes the deodorization function of the aroma component to be sustained. The pest repelling component is at least one component selected from the group consisting of 3-(N-butylacetamide)ethyl propionate, icaridin, and N,N-diethyltoluamide, and the aroma component is a compound having carbon atoms, hydrogen atoms, and oxygen atoms, having no sulfur atoms, no nitrogen atoms, and no halogen atoms, whereof the molecular weight is 98 to 270 and the number of carbons is 6 to 18, and having no electron conjugated moieties other than the electron conjugated moieties derived from a benzene ring, a benzoate ester structure, or a salicylate ester structure.

Description

衣料害蟲忌避組成物、以及使用該組成物之衣料除臭方法及衣料害蟲忌避除臭方法Clothing pest repellent composition, and clothing deodorizing method using the composition and clothing pest repellent deodorizing method

本發明係有關於一種含有害蟲忌避成分與香料成分的衣料害蟲忌避組成物及使用該組成物之衣料除臭方法。再者，本發明係有關於一種對衣料同時進行害蟲忌避處理與除臭處理的衣料害蟲忌避除臭方法。The present invention relates to a clothing pest repellent composition containing pest repellent components and fragrance components and a clothing deodorizing method using the composition. Furthermore, the present invention relates to a method for preventing and deodorizing clothing from pests in which pest repelling treatment and deodorizing treatment are simultaneously performed on clothing.

為了保護纖維製品免於衣料害蟲，已開發出各種衣料害蟲防除製品，且既已實用化。例如，已知有以香料成分作為有效成分來替代具有常溫揮發性之擬除蟲菊酯系防蟲成分的衣料害蟲防除製品(例如參照專利文獻1)。In order to protect fiber products from clothing pests, various clothing pest control products have been developed and have been put into practical use. For example, there is known a clothing pest control product that uses a fragrance component as an active ingredient instead of a pyrethroid-based pest control component having room temperature volatility (for example, refer to Patent Document 1).

專利文獻1之衣料害蟲防除製品係使乙酸酯化合物、烯丙酯化合物等香料成分保持於吸水性聚合物而成，透過長期維持有效成分的揮發性，可殺死衣櫃、抽屜、壁櫥、衣料收納箱等收納空間中的衣料害蟲的幼蟲，而發揮優良的攝食抑制效果。 [先前技術文獻] [專利文獻]The clothing pest control product of Patent Document 1 is made by holding perfume ingredients such as acetate compounds and allyl ester compounds in a water-absorbing polymer. By maintaining the volatility of the active ingredients for a long time, it can kill wardrobes, drawers, closets, and clothing. The larvae of the clothing pests in the storage space such as the storage box exerts an excellent feeding suppression effect. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本特開2015-117231號公報[Patent Document 1] JP 2015-117231 A

[發明所欲解決之課題][The problem to be solved by the invention]

衣類於穿著時常會附著汗臭、老人味、菸臭味等的日常生活臭味。因此，就衣類的管理，除衣料害蟲的防除外，較理想的是去除附著於衣類之惡臭。此外，由於外衣等係經常連日使用，而有前一天附著於衣類的日常生活臭味，在隔天穿著時帶來不適感之虞，因此較理想的是可於外出時持續地去除惡臭。Clothing often has daily odors such as sweat, old people, and cigarette odors when worn. Therefore, in terms of clothing management, except for the prevention of clothing pests, it is desirable to remove the bad odor attached to clothing. In addition, since outerwear is often used day-to-day, and there is a daily odor attached to clothing the day before, which may cause discomfort when worn the next day, it is desirable to continuously remove the odor when going out.

專利文獻1之衣料害蟲防除製品係以香料成分作為有效成分而可望發揮除臭機能，惟其係著眼於對衣料害蟲之防蟲機能來選擇作為香料成分的化合物，關於對衣類特有的惡臭之除臭機能尚有探討的空間。The clothing pest control product of Patent Document 1 is expected to exhibit deodorizing function by using fragrance components as effective ingredients, but it focuses on the pest control function against clothing pests and selecting compounds as fragrance components. Regarding the removal of odors specific to clothing There is still room for discussion on odor function.

本發明係有鑑於上述問題而完成者，茲以提供一種可發揮防蟲機能且可持續去除附著於衣類之惡臭的衣料害蟲忌避組成物及使用該組成物之衣料除臭方法為目的。再者，本發明係以提供一種僅以一次之處理即可對衣料同時賦予害蟲忌避效果與持續的除臭效果的衣料害蟲忌避除臭方法為目的。 [解決課題之手段]The present invention has been completed in view of the above-mentioned problems, and aims to provide a clothing pest repellent composition that can exert its anti-insect function and can continuously remove odors attached to clothing, and a clothing deodorizing method using the composition. Furthermore, the present invention aims to provide a clothing pest repellent and deodorizing method that can simultaneously impart a pest repellent effect and a sustained deodorizing effect to clothing. [Means to solve the problem]

供解決上述課題的本發明之衣料害蟲忌避組成物之特徵構成在於， 一種衣料害蟲忌避組成物，其含有害蟲忌避成分與香料成分，其中， 前述香料成分係具有去除附著於衣料之惡臭的除臭機能， 前述害蟲忌避成分係具有持續維持前述香料成分之除臭機能的持續機能。The characteristic structure of the clothing pest repellent composition of the present invention for solving the above-mentioned problems is: A clothing pest repellent composition, which contains pest repellent components and fragrance components, wherein, The aforementioned fragrance ingredients have a deodorizing function to remove bad odors attached to clothing, The aforementioned pest repellent component has a continuous function of continuously maintaining the deodorizing function of the aforementioned fragrance component.

本構成之衣料害蟲忌避組成物係本案發明人等在調製各種的衣料害蟲忌避組成物並重複種種試驗之下，新發現出特定的害蟲忌避成分具有持續維持香料成分之除臭機能的持續機能而臻至完成者。根據本構成之衣料害蟲忌避組成物，透過香料成分具有去除附著於衣料之惡臭的除臭機能，害蟲忌避成分具有持續維持香料成分之除臭機能的持續機能，可發揮害蟲忌避成分對衣料害蟲之防蟲機能，並可在長期持續維持香料成分所產生的除臭機能之下持續去除附著於衣類之惡臭。因此，藉由在外出前預先將本發明之衣料害蟲忌避組成物對衣類進行處理，可於外出中持續維持香料成分所產生的除臭機能，而能夠防止附著衣類之惡臭產生不適感。The clothing pest repellent composition of this composition is based on the inventors of this case. After preparing various clothing pest repellent compositions and repeating various tests, they have newly discovered that a specific pest repellent component has the continuous function of maintaining the deodorizing function of the fragrance ingredient. A person who has reached completion. According to the clothing pest repellent composition of this structure, the fragrance component has a deodorizing function to remove the offensive odor attached to the clothing material, and the pest repellent component has the continuous function of maintaining the deodorizing function of the fragrance component, and can exert the effect of the pest repellent component on the clothing pests. It has anti-insect function and can continuously remove bad odors attached to clothing while maintaining the deodorizing function produced by fragrance ingredients for a long time. Therefore, by pre-treating the clothing pest repellent composition of the present invention on clothing before going out, the deodorizing function generated by the fragrance component can be continuously maintained while going out, and it is possible to prevent uncomfortable odors from adhering to clothing.

本發明之衣料害蟲忌避組成物中，較佳的是 前述害蟲忌避成分係選自由3-(N-丁基乙醯胺)丙酸乙酯、埃卡瑞丁及N,N-二乙基苯甲醯胺所成群組的至少一種， 前述香料成分係不具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部，碳數為6～18，分子量為98～270，具有碳原子、氫原子及氧原子，且不具有硫原子、氮原子及鹵素原子的化合物。In the clothing pest repellent composition of the present invention, preferably The aforementioned pest repellent ingredient is at least one selected from the group consisting of 3-(N-butylacetamide) ethyl propionate, Icaridin and N,N-diethylbenzamide, The aforementioned fragrance ingredients do not have electronic conjugated parts other than those derived from benzene ring, benzoate structure or salicylate structure, carbon number is 6-18, molecular weight is 98-270, and it has carbon atoms , Hydrogen atom and oxygen atom, without sulfur atom, nitrogen atom and halogen atom compound.

根據本構成之衣料害蟲忌避組成物，透過組合上述特定的害蟲忌避成分與香料成分，可藉由害蟲忌避成分與香料成分的相乘效果而長期持續維持香料成分所產生的除臭機能。According to the clothing pest repellent composition of this structure, by combining the above-mentioned specific pest repellent component and the fragrance component, the deodorizing function of the fragrance component can be continuously maintained for a long time due to the synergistic effect of the pest repellent component and the fragrance component.

本發明之衣料害蟲忌避組成物中， 前述香料成分較佳為選自由順-3-己烯醇、二氫香葉烯醇、乙基沉香醇、沉香醇、香葉醇、四氫香葉醇、萜品醇、苯乙醇、新洋茉莉醛、鈴蘭醛、苯甲酸苄酯、水楊酸苄酯、順-3-己烯基水楊酸酯、二氫茉莉酸甲酯、沉香基乙酸酯、覆盆子酮、佳樂麝香、十三碳二酸乙二醇酯及十五碳內酯所成群組的至少一種。In the clothing pest repellent composition of the present invention, The aforementioned fragrance ingredients are preferably selected from the group consisting of cis-3-hexenol, dihydrogeranyl alcohol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenethyl alcohol, Xinyang Jasmaldehyde, lily of the valley, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate, methyl dihydrojasmonate, agarinyl acetate, raspberry ketone, carol musk, At least one of the group consisting of ethylene glycol tridecanedioate and pentadecanolide.

根據本構成之衣料害蟲忌避組成物，透過含有上述香料成分，可增大害蟲忌避成分與香料成分的相乘效果，而提升除臭機能的持續性。According to the clothing pest repellent composition of the present structure, by containing the above-mentioned fragrance components, the synergistic effect of the pest repellent components and fragrance components can be increased, and the continuity of the deodorizing function can be improved.

本發明之衣料害蟲忌避組成物中， 前述香料成分的含量較佳為0.1～1.0w/v%。In the clothing pest repellent composition of the present invention, The content of the aforementioned fragrance ingredient is preferably 0.1 to 1.0 w/v%.

根據本構成之衣料害蟲忌避組成物，由於香料成分的含量係處於適確的範圍，可藉由芳香掩蔽附著於衣類之惡臭而獲得充分的除臭性。According to the clothing pest repellent composition of this constitution, since the content of the fragrance component is in an appropriate range, the smell attached to the clothing can be masked by the fragrance to obtain sufficient deodorization.

本發明之衣料害蟲忌避組成物中， 前述香料成分(a)與前述害蟲忌避成分(b)的摻混比(a/b)，以重量比計較佳為0.1～1.5。In the clothing pest repellent composition of the present invention, The blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is preferably 0.1 to 1.5 in terms of weight ratio.

根據本構成之衣料害蟲忌避組成物，由於摻混比係處於適確的範圍，可充分發揮害蟲忌避成分所產生之對衣料害蟲的防蟲機能，且可充分發揮害蟲忌避成分與香料成分的相乘效果，而能夠長期持續維持香料成分所產生的除臭機能。According to the clothing pest repellent composition of this constitution, since the blending ratio is in an appropriate range, the pest repellent component can give full play to the pest repellent function of clothing pests, and can give full play to the relationship between the pest repellent component and the fragrance component. By taking advantage of the effect, it can maintain the deodorizing function of fragrance ingredients for a long time.

供解決上述課題的本發明之衣料除臭方法之特徵構成在於， 其係使用前述任一項之衣料害蟲忌避組成物的衣料除臭方法，其中， 對衣料噴灑前述衣料害蟲忌避組成物而進行處理。The characteristic structure of the clothing deodorizing method of the present invention for solving the above-mentioned problems is: It is a clothing deodorization method using any one of the foregoing clothing pest repellent compositions, wherein: The clothing material is treated by spraying the aforementioned clothing material pest repellent composition.

根據本構成之衣料除臭方法，藉由對衣料噴灑前述任一項之衣料害蟲忌避組成物而進行處理，可獲得害蟲忌避成分所產生的防蟲機能，且可藉由害蟲忌避成分與香料成分的相乘效果而長期持續維持香料成分所產生的除臭機能。因此，藉由在外出前實施本發明之衣料除臭方法，於外出中可持續維持香料成分所產生的除臭機能，而防止附著於衣類之惡臭產生不適感。According to the clothing deodorization method of this structure, by spraying the clothing pest repellent composition of any one of the foregoing on the clothing, the pest repellent function can be obtained by the pest repellent component and the fragrance component The synergistic effect of this product keeps the deodorizing function produced by the fragrance ingredients for a long time. Therefore, by implementing the clothing deodorizing method of the present invention before going out, the deodorizing function generated by the fragrance ingredients can be continuously maintained during going out, and the malodor attached to the clothes can be prevented from causing discomfort.

供解決上述課題的本發明之衣料害蟲忌避除臭方法之特徵構成在於， 其係對衣料同時進行害蟲忌避處理與除臭處理的衣料害蟲忌避除臭方法，其包含： 噴灑步驟，係對處理對象之衣料噴灑含有害蟲忌避成分與香料成分的衣料害蟲忌避組成物；及 變更步驟，係變更對前述衣料噴灑前述衣料害蟲忌避組成物的位置，以使前述衣料持續維持充分的害蟲忌避效果及除臭效果。The characteristic structure of the clothing pest repellent and deodorant method of the present invention for solving the above-mentioned problems is: It is a clothing pest repellent and deodorant method that simultaneously performs pest repellent treatment and deodorant treatment on clothing, which includes: The spraying step is to spray the clothing pest repellent composition containing pest repellent ingredients and perfume ingredients on the clothing of the treatment object; and The modification step is to change the position where the clothing pest repellent composition is sprayed on the clothing material, so that the clothing material continues to maintain a sufficient pest repellent effect and deodorant effect.

根據本構成之衣料害蟲忌避除臭方法，藉由對處理對象之衣料噴灑含有害蟲忌避成分與香料成分的衣料害蟲忌避組成物，並進一步變更對該衣料噴灑衣料害蟲忌避組成物的位置，以使衣料持續維持充分的害蟲忌避效果及除臭效果，可僅以一次之處理對衣料同時賦予害蟲忌避效果與持續的除臭效果。而且，藉由本發明之衣料害蟲忌避除臭方法進行處理之衣料，藉由害蟲忌避成分與香料成分的相乘效果，由於可長期持續維持香料成分所產生的除臭機能，例如，即使一整天外出時，惱人的害蟲也不會靠近，且可不在意臭味地長時間舒適地活動。According to the clothing pest repellent deodorization method of this composition, the clothing pest repellent composition containing pest repellent components and fragrance ingredients is sprayed on the clothing material of the treatment object, and the position of the clothing pest repellent composition sprayed on the clothing is further changed to make The clothing continues to maintain sufficient pest repellent and deodorant effects, and the clothing can be treated at the same time with a pest repellent effect and a continuous deodorizing effect. Moreover, the clothing material treated by the method for preventing and deodorizing clothing pests of the present invention has the synergistic effect of the pest repellent ingredient and the fragrance ingredient, since the deodorizing function of the fragrance ingredient can be maintained for a long time, for example, even all day long. When going out, annoying pests will not come close, and you can move comfortably for a long time without caring about the smell.

[實施發明之形態][The form of implementing the invention]

以下就本發明之衣料害蟲忌避組成物及衣料除臭方法加以說明。惟，本發明非意圖限定於以下說明之實施形態所記載的構成。The clothing pest repellent composition and the clothing deodorizing method of the present invention will be described below. However, the present invention is not intended to be limited to the configuration described in the embodiment described below.

＜衣料害蟲忌避組成物＞ 本發明之衣料害蟲忌避組成物係含有：香料成分，係具有去除附著於衣料之惡臭的除臭機能；及害蟲忌避成分，除害蟲忌避效果外尚具有持續維持香料成分之除臭機能的持續機能。＜Clothing pest repellent composition＞ The clothing pest repellent composition of the present invention contains: a fragrance component, which has a deodorizing function to remove the odor attached to the clothing; and a pest repellent component, which has the continuous function of maintaining the deodorizing function of the fragrance component in addition to the pest repellent effect .

屬本發明之衣料害蟲忌避組成物的主成分之一的害蟲忌避成分，係使用3-(N-丁基乙醯胺)丙酸乙酯(以下表記為「IR3535」)、埃卡瑞丁及N,N-二乙基苯甲醯胺(以下表記為「避蚊胺」)。此等可單獨使用，亦能以二種以上之混合物的形態使用。IR3535、埃卡瑞丁及避蚊胺係具有揮發性，且對衣料害蟲，尤為衣蛾或袋衣蛾的成蟲具有高忌避效果。如此，IR3535、埃卡瑞丁及避蚊胺向來係作為害蟲忌避劑使用；而本案發明人等在使用IR3535、埃卡瑞丁及避蚊胺而調製各種的衣料害蟲忌避組成物之下新發現，IR3535、埃卡瑞丁及避蚊胺係具有持續維持後述特定的香料成分之除臭機能的持續機能。本發明之衣料害蟲忌避組成物，藉由噴霧處理等而使其附著於衣類，可使害蟲忌避成分由使用中的衣類揮發而防止衣料害蟲靠近或接觸，而預防穿著時衣料害蟲的產卵，同時可長期持續去除附著於使用中之衣類的惡臭。此處所稱「使用中」，係指由收納空間取出衣類後，至再次收納於收納空間為止的狀態，不僅包含穿著中之狀態，亦包含在穿著前後靜置於收納空間外的狀態。就穿著中的衣類，由於可藉由使用者的體溫而促進害蟲忌避成分的揮發，而能夠更有效地防止衣料害蟲的靠近或接觸。又，也有時會在野外等為了調節溫度而脫去衣類；由於IR3535、埃卡瑞丁及避蚊胺具有揮發性，就於使用中脫去而靜置於野外等的衣類，亦可充分防止衣料害蟲的靠近或接觸。此外，IR3535及埃卡瑞丁對於纖維製品不易產生斑點或變色等影響，而且幾乎無臭，對人體的安全性較高。因此，本發明之衣料害蟲忌避組成物可無需在意對衣類的危害或害蟲忌避成分的臭味地在穿著時使用。衣料害蟲忌避組成物中之害蟲忌避成分的含量較佳為0.4～10.0w/v%。若為此種範圍，藉由噴灑衣料害蟲忌避組成物而進行處理等而使其附著於衣類，可發揮對衣料害蟲的忌避效果，且可發揮與後述特定的香料成分的相乘效果，而提升除臭機能的持續性。當害蟲忌避成分的含量未達0.4w/v%時，則有對衣料害蟲之忌避效果、或與香料成分之相乘效果所產生的除臭機能的持續性不充分之虞。害蟲忌避成分的含量超過10.0w/v%時，則超過實用上所需之可獲得忌避效果的量地摻混害蟲忌避成分，經濟上較為不利。The pest repellent component, which is one of the main components of the clothing pest repellent composition of the present invention, uses 3-(N-butylacetamide) ethyl propionate (hereinafter referred to as "IR3535"), Icaridin and N,N-Diethylbenzamide (denoted as "DEET" in the following table). These can be used alone or in the form of a mixture of two or more kinds. IR3535, Icaridin and DEET are volatile, and have a high repellent effect on clothing pests, especially the adults of clothing moths or bag clothing moths. In this way, IR3535, Icaridin and DEET have always been used as pest repellents; and the inventors of this case have newly discovered by using IR3535, Icaridin and DEET to prepare various clothing pest repellent compositions , IR3535, Icaridin and DEET have the continuous function of maintaining the deodorizing function of the specific fragrance ingredients mentioned later. The clothing pest repellent composition of the present invention is attached to clothing by spray treatment or the like, so that the pest repellent component can be volatilized from the clothing in use to prevent clothing pests from approaching or contacting, and preventing clothing pests from laying eggs during wearing. At the same time, it can continuously remove the malodor attached to the clothes in use for a long time. The term "in use" here refers to the state after the clothing is taken out from the storage space until it is stored in the storage space again, and includes not only the state of being worn, but also the state of being placed outside the storage space before and after wearing. With regard to clothing being worn, since the user's body temperature can promote the volatilization of pest repellent components, the approach or contact of clothing pests can be more effectively prevented. In addition, clothing is sometimes taken off to adjust the temperature in the field. Because IR3535, Icaridin and DEET are volatile, they can be taken off during use and left in the wild. It can also be fully prevented The approach or contact of clothing pests. In addition, IR3535 and Icaridin are less likely to cause spots or discoloration on fiber products, and are almost odorless, which is safe for the human body. Therefore, the clothing pest repellent composition of the present invention can be used during wearing without caring about the damage to clothing or the smell of pest repellent components. The content of the pest repellent component in the clothing pest repellent composition is preferably 0.4-10.0 w/v%. If it is in this range, by spraying the clothing pest repellent composition and treating it to adhere to the clothing, the clothing pest repellent effect can be exerted, and the synergistic effect with the specific fragrance ingredients mentioned later can be exerted, thereby enhancing Sustainability of deodorizing function. When the content of the pest repellent component is less than 0.4w/v%, the repellent effect on clothing pests or the deodorizing function produced by the synergistic effect of the fragrance component may not be sufficient. When the content of the pest repellent component exceeds 10.0 w/v%, the pest repellent component is blended in an amount that is practically necessary to obtain the repellent effect, which is economically disadvantageous.

屬本發明之衣料害蟲忌避組成物的主成分之一的香料成分，係使用不具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部，碳數為6～18，分子量為98～270，具有碳原子、氫原子及氧原子，且不具有硫原子、氮原子及鹵素原子的化合物。此種化合物係具有可藉由芳香掩蔽附著於衣類之惡臭(汗臭、中年男性體臭、老人味、菸臭味及調理臭味)之優良的除臭機能，同時藉由與在本發明中作為害蟲忌避成分使用之IR3535、埃卡瑞丁及避蚊胺的相乘效果，可長時間持續維持其除臭機能。作為此類化合物，可舉出下述式(1)：The fragrance ingredient, which is one of the main components of the clothing pest repellent composition of the present invention, uses electronic conjugated parts other than those derived from benzene ring, benzoate structure or salicylate structure, A compound having a carbon number of 6 to 18, a molecular weight of 98 to 270, a carbon atom, a hydrogen atom, and an oxygen atom, and no sulfur atom, nitrogen atom, or halogen atom. This compound has an excellent deodorizing function that can mask the odor attached to clothing (sweat odor, middle-aged male body odor, elderly odor, smoke odor, and conditioning odor) by fragrance, and at the same time, it is combined with the present invention The synergistic effects of IR3535, Icaridin and DEET used as pest repellent ingredients can maintain its deodorizing function for a long time. As such compounds, the following formula (1) can be mentioned:

Figure 02_image001
所示之順-3-己烯醇(下稱「化合物A」)、下述式(2)：
Figure 02_image001
The shown cis-3-hexenol (hereinafter referred to as "Compound A"), the following formula (2):

Figure 02_image003
所示之二氫香葉烯醇(下稱「化合物B」)、下述式(3)：
Figure 02_image003
The dihydrogeraniol (hereinafter referred to as "compound B") shown in the following formula (3):

Figure 02_image005
所示之乙基沉香醇(下稱「化合物C」)、下述式(4)：
Figure 02_image005
The shown ethyl linalool (hereinafter referred to as "compound C"), the following formula (4):

Figure 02_image007
所示之沉香醇(下稱「化合物D」)、下述式(5)：
Figure 02_image007
The shown linalool (hereinafter referred to as "compound D"), the following formula (5):

Figure 02_image009
所示之香葉醇(下稱「化合物E」)、下述式(6)：
Figure 02_image009
The geraniol shown (hereinafter referred to as "compound E"), the following formula (6):

Figure 02_image011
所示之四氫香葉醇(下稱「化合物F」)、下述式(7)：
Figure 02_image011
The shown tetrahydrogeraniol (hereinafter referred to as "compound F"), the following formula (7):

Figure 02_image013
所示之萜品醇(下稱「化合物G」)、下述式(8)：
Figure 02_image013
The terpineol shown (hereinafter referred to as "compound G"), the following formula (8):

Figure 02_image015
所示之苯乙醇(下稱「化合物H」)、下述式(9)：
Figure 02_image015
The phenethyl alcohol (hereinafter referred to as "compound H") shown in the following formula (9):

Figure 02_image017
所示之新洋茉莉醛(下稱「化合物I」)、下述式(10)：
Figure 02_image017
Shown as Xinyang Jasminaldehyde (hereinafter referred to as "Compound I"), the following formula (10):

Figure 02_image019
所示之鈴蘭醛(下稱「化合物J」)、下述式(11)：
Figure 02_image019
The shown lily of the valley (hereinafter referred to as "compound J"), the following formula (11):

Figure 02_image021
所示之苯甲酸苄酯(下稱「化合物K」)、下述式(12)：
Figure 02_image021
The shown benzyl benzoate (hereinafter referred to as "compound K"), the following formula (12):

Figure 02_image023
所示之水楊酸苄酯(下稱「化合物L」)、下述式(13)：
Figure 02_image023
The shown benzyl salicylate (hereinafter referred to as "compound L"), the following formula (13):

Figure 02_image025
所示之順-3-己烯基水楊酸酯(下稱「化合物M」)、下述式(14)：
Figure 02_image025
The shown cis-3-hexenyl salicylate (hereinafter referred to as "compound M"), the following formula (14):

Figure 02_image027
所示之二氫茉莉酸甲酯(下稱「化合物N」)、下述式(15)：
Figure 02_image027
The shown methyl dihydrojasmonate (hereinafter referred to as "compound N"), the following formula (15):

Figure 02_image029
所示之沉香基乙酸酯(下稱「化合物O」)、下述式(16)：
Figure 02_image029
The shown agarinyl acetate (hereinafter referred to as "compound O"), the following formula (16):

Figure 02_image031
所示之覆盆子酮(下稱「化合物P」)、下述式(17)：
Figure 02_image031
The shown raspberry ketone (hereinafter referred to as "compound P"), the following formula (17):

Figure 02_image033
所示之佳樂麝香(下稱「化合物Q」)、下述式(18)：
Figure 02_image033
The Jiale Musk (hereinafter referred to as "Compound Q") shown in the following formula (18):

Figure 02_image035
所示之十三碳二酸乙二醇酯(下稱「化合物R」)、下述式(19)：
Figure 02_image035
The shown glycol ester of tridecanedioic acid (hereinafter referred to as "compound R"), the following formula (19):

Figure 02_image037
所示之十五碳內酯(下稱「化合物S」)等。
Figure 02_image037
The 15-carbon lactone shown (hereinafter referred to as "compound S"), etc.

上述化合物A～S可單獨使用，亦可組合多種使用。香料成分的含量較佳為0.1～1.0w/v%。香料成分的含量若為此種範圍，可掩蔽附著於衣類之惡臭而獲得充分的除臭性。香料成分的含量未達0.1w/v%時，有除臭性不足之虞。香料成分的含量超過1.0w/v%時，香料成分的芳香過強，而有讓不喜歡強烈芳香的消費者感到不適之虞，而且超過實用上所需之可獲得除臭性的量地摻混香料成分，經濟上亦為不利。The above-mentioned compounds A to S may be used alone or in combination of multiple types. The content of the fragrance ingredient is preferably 0.1 to 1.0 w/v%. If the content of the fragrance component is in this range, the bad odor adhering to clothing can be masked to obtain sufficient deodorizing properties. If the content of the fragrance component is less than 0.1w/v%, the deodorizing property may be insufficient. When the content of the fragrance component exceeds 1.0w/v%, the fragrance of the fragrance component is too strong, which may make consumers who do not like strong fragrance feel uncomfortable, and it may be blended in an amount exceeding practically necessary to obtain deodorizing properties. Mixed spice ingredients are also economically disadvantageous.

本發明之衣料害蟲忌避組成物中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計較佳調整成0.1～1.5。摻混比(a/b)若為此種範圍，可增大害蟲忌避成分與香料成分的相乘效果，而長期持續維持香料成分所產生的除臭機能。摻混比(a/b)未達0.1時及摻混比(a/b)超過1.5時，則有無法充分發揮害蟲忌避成分與香料成分的相乘效果之虞。In the clothing pest repellent composition of the present invention, the blending ratio (a/b) of the perfume component (a) and the pest repellent component (b) is preferably adjusted to 0.1-1.5 by weight. If the blending ratio (a/b) is in this range, the synergistic effect of the pest repellent component and the fragrance component can be increased, and the deodorizing function of the fragrance component can be maintained for a long time. When the blending ratio (a/b) is less than 0.1 and when the blending ratio (a/b) exceeds 1.5, the synergistic effect of the pest repellent component and the fragrance component may not be fully exhibited.

本發明之衣料害蟲忌避組成物，除上述成分外，亦可適宜摻混害蟲忌避成分之安定劑、以黴類或菌類等為對象之防黴劑、抗菌劑、殺菌劑、抗靜電劑、消泡劑等。例如使用IR3535作為害蟲忌避成分時，安定劑可使用三乙醇胺。透過含有三乙醇胺作為安定劑，可提升在酸性條件下容易分解之IR3535的穩定性，在長期間保存衣料害蟲忌避組成物時仍可防止IR3535的含量過度減少。衣料害蟲忌避組成物中之三乙醇胺的含量較佳為0.05～0.2w/v%。若為此種範圍，由於可充分提升IR3535的穩定性，衣料害蟲忌避組成物其長期保存性優良而能夠便於使用。三乙醇胺的含量未達0.05w/v%時及三乙醇胺的含量超過0.2w/v%時，有無法充分提升IR3535的穩定性之虞。作為安定劑，較佳除三乙醇胺外亦併用薄荷醇。衣料害蟲忌避組成物中之薄荷醇的含量較佳為0.2～1.5w/v%。若為此種範圍，可藉由三乙醇胺與薄荷醇的相乘效果而進一步提升IR3535的穩定性。薄荷醇的含量未達0.2w/v%時及薄荷醇的含量超過1.5w/v%時，有無法充分發揮與三乙醇胺的相乘效果之虞。此外，薄荷醇向來係作為香料使用；而本案發明人等調製各種的衣料害蟲忌避組成物，結果當薄荷醇的含量為上述範圍時，薄荷醇未顯示去除附著於衣料之惡臭的除臭機能。又，以顯示除臭機能之程度使薄荷醇的含量大於上述範圍時，亦無法藉由IR3535、埃卡瑞丁及避蚊胺持續維持除臭機能。因此，作為本發明之香料成分，係不含薄荷醇。防黴劑、抗菌劑及殺菌劑可舉出檜木醇、2-巰基苯并噻唑、2-(4-噻唑基)苯并咪唑、5-氯-2-甲基-4-異噻唑啉-3-酮、賽福寧、3-甲基-4-異丙基酚、鄰苯基酚等。The clothing pest repellent composition of the present invention, in addition to the above-mentioned components, can also be suitably blended with stabilizers of pest repellent components, antifungal agents, antibacterial agents, fungicides, antistatic agents, and disinfectants for molds or fungi. Foaming agent, etc. For example, when IR3535 is used as a pest repellent, triethanolamine can be used as a stabilizer. By containing triethanolamine as a stabilizer, the stability of IR3535, which is easily decomposed under acidic conditions, can be improved, and the content of IR3535 can be prevented from excessive reduction when the clothing pest repellent composition is stored for a long time. The content of triethanolamine in the clothing pest repellent composition is preferably 0.05 to 0.2 w/v%. If it is in this range, since the stability of IR3535 can be sufficiently improved, the clothing pest repellent composition has excellent long-term storage properties and can be used conveniently. When the content of triethanolamine is less than 0.05w/v% and when the content of triethanolamine exceeds 0.2w/v%, the stability of IR3535 may not be sufficiently improved. As a stabilizer, it is preferable to use menthol in addition to triethanolamine. The content of menthol in the clothing pest repellent composition is preferably 0.2 to 1.5 w/v%. If it is in this range, the stability of IR3535 can be further improved by the synergistic effect of triethanolamine and menthol. When the content of menthol is less than 0.2w/v% and when the content of menthol exceeds 1.5w/v%, the synergistic effect with triethanolamine may not be fully exhibited. In addition, menthol has always been used as a fragrance; however, the inventors of the present invention prepared various clothing pest repellent compositions. As a result, when the content of menthol was within the above range, menthol did not exhibit a deodorizing function of removing bad odors attached to clothing. In addition, when the content of menthol is greater than the above range to show the degree of deodorization function, the deodorization function cannot be maintained continuously by IR3535, Icaridin and DEET. Therefore, as the fragrance ingredient of the present invention, menthol is not contained. Antifungal agents, antibacterial agents and bactericides include cypress alcohol, 2-mercaptobenzothiazole, 2-(4-thiazolyl)benzimidazole, 5-chloro-2-methyl-4-isothiazoline-3 -Ketone, Saifenin, 3-methyl-4-isopropylphenol, o-phenylphenol, etc.

本發明之衣料害蟲忌避組成物係以適當的重量比摻混上述各成分，並進一步添加水及醇類而將各成分的濃度調整為適當者。作為醇類，較佳為碳數為2～3之低級醇，特佳為乙醇。The clothing pest repellent composition of the present invention blends the above-mentioned components in an appropriate weight ratio, and further adds water and alcohol to adjust the concentration of each component to an appropriate one. As the alcohol, a lower alcohol having 2 to 3 carbon atoms is preferred, and ethanol is particularly preferred.

＜衣料害蟲防除用噴霧製品＞ 本發明之衣料害蟲忌避組成物的較佳製品形態為噴霧製品。例如藉由在噴霧容器中封入本發明之衣料害蟲忌避組成物與視需求而定的噴射劑，而構成衣料害蟲防除用噴霧製品。噴霧容器較佳為具備觸發式噴霧器者。藉此，噴灑時衣料害蟲忌避組成物會擴散，而使衣料害蟲忌避組成物在處理對象之衣類的附著量大致呈均勻。又，可依據噴霧次數而對處理對象之衣類賦予正確量的衣料害蟲忌避組成物。＜Spray products for controlling clothing pests＞ The preferred product form of the clothing pest repellent composition of the present invention is a spray product. For example, by enclosing the clothing pest repellent composition of the present invention and a propellant as required in a spray container, a spray product for controlling clothing pests is constructed. The spray container is preferably one equipped with a trigger sprayer. As a result, the clothing pest repellent composition spreads during spraying, and the adhesion amount of the clothing pest repellent composition to the clothes of the treatment object is approximately uniform. In addition, the clothing pest repellent composition can be given the correct amount of clothing pest repellent composition to the clothing to be treated according to the number of sprays.

＜衣料除臭方法＞ 本發明之衣料除臭方法係對衣料噴灑本發明之衣料害蟲忌避組成物而進行處理，例如可使用上述衣料害蟲防除用噴霧製品來實施。具體而言，係使用者握持衣料害蟲防除用噴霧製品的觸發器，向衣類或帽子噴灑衣料害蟲忌避組成物。藉此，衣類等的表面即附著有衣料害蟲忌避組成物。此時，衣類可為穿著狀態及未穿著狀態任一種。就本發明之衣料害蟲忌避組成物，由於係使用對人體安全性高的IR3535、埃卡瑞丁及避蚊胺作為害蟲忌避成分，而能夠在穿著狀態下對衣類實施噴霧處理。實施衣料害蟲忌避組成物的噴霧處理，則可對衣類賦予優良的防蟲機能及持續的除臭機能。其結果，能有效預防衣料害蟲在穿著中的衣類產卵，且可去除附著於衣類之惡臭。＜How to deodorize clothing＞ The clothing deodorizing method of the present invention is to spray the clothing pest repellent composition of the present invention on the clothing material for treatment. For example, it can be implemented using the above-mentioned spray product for clothing pest control. Specifically, the user holds the trigger of the spray product for controlling clothing pests and sprays the clothing pest repellent composition on clothing or hats. Thereby, the clothing pest repellent composition adheres to the surface of clothing and the like. At this time, the clothing may be in either a worn state or an unworn state. With regard to the clothing pest repellent composition of the present invention, since IR3535, Icaridin and DEET, which are highly safe to the human body, are used as pest repellent components, the clothing can be sprayed while being worn. The spray treatment of the clothing pest repellent composition can impart excellent insect repellent function and continuous deodorizing function to clothing. As a result, it is possible to effectively prevent clothing pests from laying eggs on clothing being worn, and it is possible to remove bad odors attached to clothing.

＜衣料害蟲忌避除臭方法＞ 本發明之衣料害蟲忌避除臭方法係執行：噴灑步驟，係對處理對象之衣料噴灑含有害蟲忌避成分與香料成分的衣料害蟲忌避組成物；及變更步驟，係變更對該衣料噴灑衣料害蟲忌避組成物的位置，以使衣料持續維持充分的害蟲忌避效果及除臭效果。本發明之衣料害蟲忌避除臭方法其基本的步驟(操作)係與上述之衣料除臭方法相同，而於變更步驟中，為了使衣料害蟲忌避組成物附著於衣料全體，使用者只要一面適當地移動衣料害蟲防除用噴霧製品一面噴灑即可。例如，藉由對衣料當中尤其在意臭味的部位(例如腋下、頸部四周、腳周邊部等)仔細地進行噴霧處理，可對衣料同時賦予有效的害蟲忌避效果與持續的除臭效果。如此，只要實施本發明之衣料害蟲忌避除臭方法，僅以一次之處理即可對衣料同時賦予害蟲忌避效果與持續的除臭效果。而且，藉由本發明之衣料害蟲忌避除臭方法進行處理之衣料，藉由後述之害蟲忌避成分與香料成分的相乘效果，由於可長期持續維持香料成分所產生的除臭機能，例如，即使一整天外出時，惱人的害蟲也不會靠近，且可不在意臭味地長時間舒適地活動。＜How to avoid and deodorize clothing pests＞ The clothing pest repellent and deodorant method of the present invention implements: a spraying step, spraying a clothing pest repellent composition containing pest repellent ingredients and perfume ingredients on the clothing material of the treatment object; and changing the step of changing the clothing pest repellent composition of spraying the clothing material The position of the object, so that the clothing will continue to maintain sufficient pest repellent effect and deodorant effect. The basic steps (operations) of the clothing pest repellent deodorization method of the present invention are the same as the above-mentioned clothing deodorization method. In the modification step, in order to make the clothing pest repellent composition adhere to the entire clothing, the user only needs to properly Spray the spray products for the prevention and control of mobile clothing pests on one side. For example, by carefully spraying the parts of the clothing that are particularly odorous (such as underarms, around the neck, and around the feet), the clothing can be simultaneously provided with an effective pest repellent effect and a continuous deodorizing effect. In this way, as long as the clothing pest repelling and deodorizing method of the present invention is implemented, only one treatment can give the clothing a pest repellent effect and a continuous deodorizing effect. Moreover, the clothing treated by the clothing pest repellent deodorization method of the present invention has the synergistic effect of the pest repellent component and the fragrance component described later, since the deodorizing function produced by the fragrance component can be maintained for a long time, for example, even if one When going out all day, annoying pests will not come close, and you can move comfortably for a long time without caring about the smell.

本發明之衣料害蟲忌避組成物，透過對害蟲忌避成分組合特定的香料成分，藉由害蟲忌避成分與香料成分的相乘效果，可長期持續維持香料成分所產生的除臭機能。除臭機能的持續期間係隨害蟲忌避成分與香料成分的組合、兩成分的摻混比例、衣料害蟲忌避組成物的使用條件等而異，可充分持續維持除臭機能達約半天至一天左右。因此，只要依循使用此衣料害蟲忌避組成物來執行的本發明之衣料除臭方法，於外出前實施噴霧處理，例如在12小時左右的外出期間可持續維持香料成分所產生的除臭機能，且可防止附著於衣類之惡臭產生不適感。 [實施例]The clothing pest repellent composition of the present invention combines specific fragrance components with the pest repellent components, and through the synergistic effect of the pest repellent components and the fragrance components, the deodorizing function produced by the fragrance components can be continuously maintained for a long time. The duration of the deodorizing function varies with the combination of the pest repellent component and the fragrance component, the blending ratio of the two components, and the use conditions of the clothing pest repellent composition, and the deodorizing function can be fully maintained for about half a day to about a day. Therefore, as long as the clothing deodorization method of the present invention implemented using this clothing pest repellent composition is implemented, spray treatment is applied before going out, for example, the deodorizing function generated by the fragrance ingredients can be maintained continuously during the outing period of about 12 hours, and It can prevent the bad smell attached to clothing from causing discomfort. [Example]

為了對本發明之衣料害蟲忌避組成物確認除臭機能的持續性，而準備具備本發明之特徵構成的衣料害蟲忌避組成物(實施例1～54)，實施除臭機能確認試驗。又，為了比較而準備未具備本發明之特徵構成的衣料害蟲忌避組成物(比較例1～56)，並實施同樣的除臭機能確認試驗。此外，於實施例1～54及比較例1～56中作為重量的單位係示出「g」，但能以任意倍率按比例放大。亦即，單位「g」可改稱為「重量份」。In order to confirm the sustainability of the deodorizing function of the clothing pest repellent composition of the present invention, the clothing pest repellent composition (Examples 1 to 54) having the characteristic structure of the present invention was prepared, and the deodorizing function confirmation test was carried out. In addition, for comparison, a clothing pest repellent composition (Comparative Examples 1 to 56) that did not have the characteristic structure of the present invention was prepared, and the same deodorizing function confirmation test was performed. In addition, in Examples 1 to 54 and Comparative Examples 1 to 56, "g" is shown as the unit of weight, but it can be scaled up at any magnification. That is, the unit "g" can be changed to "parts by weight".

＜實施例1～21＞ 根據使用IR3535作為害蟲忌避成分的下述配方1，來調製衣料害蟲忌避組成物(實施例1～21)。實施例1～19之衣料害蟲忌避組成物中，係使用化合物A～S作為香料成分。實施例20之衣料害蟲忌避組成物中，係使用化合物B、H、L、N及Q以等量混合而成的調合香料(下稱「調合香料1」)作為香料成分。實施例21之衣料害蟲忌避組成物中，係使用化合物L、N、Q、β-突厥酮及開司米木麝香(cashmeran)以等量混合而成的調合香料(下稱「調合香料2」)作為香料成分。<Examples 1-21> According to the following formula 1 using IR3535 as a pest repellent component, the clothing pest repellent composition (Examples 1 to 21) was prepared. In the clothing pest repellent composition of Examples 1 to 19, compounds A to S were used as fragrance components. In the clothing pest repellent composition of Example 20, a blended fragrance (hereinafter referred to as "blended fragrance 1") obtained by mixing compounds B, H, L, N, and Q in equal amounts was used as a fragrance component. In the clothing pest repellent composition of Example 21, a blended perfume (hereinafter referred to as "blended perfume 2") obtained by mixing the compounds L, N, Q, β-turkone and cashmeran in equal amounts was used as Spice ingredients.

配方1： 將香料成分0.5g(0.5w/v%)、IR3535 3.5g(3.5w/v%)、異丙基甲基酚(IPMP)0.1g(0.1w/v%)、薄荷醇1.0g(1.0w/ v%)、三乙醇胺(TEA)0.05g(0.05w/v%)、純水40g(40w/ v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方1中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為0.14。Recipe 1: Fragrance ingredients 0.5g (0.5w/v%), IR3535 3.5g (3.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w /v%), 0.05g (0.05w/v%) of triethanolamine (TEA), 40g (40w/v%) of pure water, and absolute ethanol of the remaining components (for balance) to prepare a total of 100mL. In Formulation 1, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is 0.14 by weight.

＜實施例22～27＞ 根據使用IR3535作為害蟲忌避成分的下述配方2，來調製衣料害蟲忌避組成物(實施例22～27)。實施例22～27之衣料害蟲忌避組成物中，係使用化合物B、H、L、N、Q及調合香料1作為香料成分。<Examples 22-27> According to the following formula 2 using IR3535 as a pest repellent component, a clothing pest repellent composition (Examples 22 to 27) was prepared. In the clothing pest repellent compositions of Examples 22-27, Compounds B, H, L, N, Q and the blended fragrance 1 were used as fragrance components.

配方2： 將香料成分0.5g(0.5w/v%)、IR3535 0.5g(0.5w/v%)、異丙基甲基酚(IPMP)0.1g(0.1w/v%)、薄荷醇1.0g(1.0w/v%)、三乙醇胺(TEA)0.05g(0.05w/v%)、純水40g(40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方2中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為1.00。Formulation 2: Fragrance ingredients 0.5g (0.5w/v%), IR3535 0.5g (0.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w /v%), 0.05g (0.05w/v%) of triethanolamine (TEA), 40g (40w/v%) of pure water, and absolute ethanol of the remaining components (for balance) to prepare a total amount of 100mL. In Formula 2, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is 1.00 in terms of weight ratio.

＜實施例28～48＞ 根據使用埃卡瑞丁作為害蟲忌避成分的下述配方3，來調製衣料害蟲忌避組成物(實施例28～48)。實施例28～48之衣料害蟲忌避組成物中，係使用化合物A～S、調合香料1及調合香料2作為香料成分。<Examples 28 to 48> The clothing pest repellent composition (Examples 28 to 48) was prepared according to the following formula 3 using Icaridin as the pest repellent component. In the clothing pest repellent composition of Examples 28 to 48, compounds A to S, blended fragrance 1 and blended fragrance 2 were used as fragrance components.

配方3： 將香料成分0.5g(0.5w/v%)、埃卡瑞丁3.5g(3.5w/ v%)、異丙基甲基酚(IPMP)0.1g(0.1w/v%)、薄荷醇1.0g(1.0w/v%)、三乙醇胺(TEA)0.05g(0.05w/v%)、純水40g(40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方3中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為0.14。Recipe 3: Flavor ingredients 0.5g (0.5w/v%), Icaridin 3.5g (3.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w/v%), 0.05g (0.05w/v%) of triethanolamine (TEA), 40g (40w/v%) of pure water, and absolute ethanol of the remaining ingredients (for balance) to prepare a total amount of 100mL . In formula 3, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) was 0.14 by weight.

＜實施例49～54＞ 根據使用埃卡瑞丁作為害蟲忌避成分的下述配方4，來調製衣料害蟲忌避組成物(實施例49～54)。實施例49～54之衣料害蟲忌避組成物中，係使用化合物B、H、L、N、Q及調合香料1作為香料成分。<Examples 49-54> The clothing pest repellent composition (Examples 49 to 54) was prepared according to the following formula 4 using Icaridin as the pest repellent component. In the clothing pest repellent composition of Examples 49-54, compounds B, H, L, N, Q and blended fragrance 1 were used as fragrance components.

配方4： 將香料成分0.5g(0.5w/v%)、埃卡瑞丁0.5g(0.5w/ v%)、異丙基甲基酚(IPMP)0.1g(0.1w/v%)、薄荷醇1.0g (1.0w/v%)、三乙醇胺(TEA)0.05g(0.05w/v%)、純水40g (40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方4中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為1.00。Recipe 4: Combine fragrance ingredients 0.5g (0.5w/v%), Icaridin 0.5g (0.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w/v%), 0.05g (0.05w/v%) of triethanolamine (TEA), 40g (40w/v%) of pure water, and absolute ethanol of the remaining ingredients (for balance) to prepare a total volume of 100mL . In formula 4, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is 1.00 in terms of weight ratio.

＜比較例1～21＞ 根據未摻混害蟲忌避成分的下述配方5，來調製衣料害蟲忌避組成物(比較例1～21)。比較例1～21之衣料害蟲忌避組成物中，係使用化合物A～S、調合香料1及調合香料2作為香料成分。<Comparative Examples 1-21> The clothing pest repellent composition (Comparative Examples 1 to 21) was prepared according to the following formula 5 in which no pest repellent component was blended. In the clothing pest repellent composition of Comparative Examples 1 to 21, the compounds A to S, the blended fragrance 1 and the blended fragrance 2 were used as fragrance components.

配方5： 將香料成分0.5g(0.5w/v%)、異丙基甲基酚(IPMP)0.1g(0.1w/v%)、薄荷醇1.0g(1.0w/v%)、三乙醇胺(TEA)0.05g(0.05w/v%)、純水40g(40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。Formula 5: Combine fragrance ingredients 0.5g (0.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w/v%), triethanolamine (TEA) 0.05 g (0.05w/v%), pure water 40g (40w/v%), and the remaining components (for balance) are mixed with absolute ethanol to prepare a total of 100 mL.

＜比較例22＞ 根據使用IR3535作為害蟲忌避成分的下述配方6，來調製衣料害蟲忌避組成物(比較例22)。比較例22之衣料害蟲忌避組成物中，係未摻混香料成分。<Comparative Example 22> According to the following formula 6 using IR3535 as a pest repellent component, a clothing pest repellent composition (Comparative Example 22) was prepared. In the clothing pest repellent composition of Comparative Example 22, fragrance ingredients were not blended.

配方6： 將IR3535 3.5g(3.5w/v%)、異丙基甲基酚(IPMP)0.1g (0.1w/v%)、薄荷醇1.0g(1.0w/v%)、三乙醇胺(TEA)0.05g (0.05w/v%)、純水40g(40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方6中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為0.00。Formulation 6: Combine IR3535 3.5g (3.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w/v%), triethanolamine (TEA) 0.05g (0.05w/v%), pure water 40g (40w/v%), and the remaining components (for balance) of absolute ethanol are mixed to prepare a total of 100 mL. In Formula 6, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is 0.00 in terms of weight ratio.

＜比較例23＞ 根據使用埃卡瑞丁作為害蟲忌避成分的下述配方7，來調製衣料害蟲忌避組成物(比較例23)。比較例23之衣料害蟲忌避組成物中，係未摻混香料成分。<Comparative Example 23> According to the following formula 7 using Icaridin as a pest repellent component, a clothing pest repellent composition (Comparative Example 23) was prepared. In the clothing pest repellent composition of Comparative Example 23, fragrance ingredients were not blended.

配方7： 將埃卡瑞丁3.5g(3.5w/v%)、異丙基甲基酚(IPMP)0.1g (0.1w/v%)、薄荷醇1.0g(1.0w/v%)、三乙醇胺(TEA)0.05g (0.05w/v%)、純水40g(40w/v%)、以及其餘成分(平衡用)的無水乙醇混合，調製成總量100mL。配方7中，香料成分(a)與害蟲忌避成分(b)的摻混比(a/b)，以重量比計為0.00。Formulation 7: Icaridin 3.5g (3.5w/v%), isopropyl methylphenol (IPMP) 0.1g (0.1w/v%), menthol 1.0g (1.0w/v%), triethanolamine (TEA ) 0.05g (0.05w/v%), pure water 40g (40w/v%), and the remaining components (for balance) are mixed with absolute ethanol to prepare a total of 100 mL. In Formula 7, the blending ratio (a/b) of the fragrance component (a) and the pest repellent component (b) is 0.00 by weight.

＜比較例24～34＞ 根據使用IR3535作為害蟲忌避成分的配方1，來調製衣料害蟲忌避組成物(比較例24～34)。比較例24～34之衣料害蟲忌避組成物中，係使用具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部的化合物作為香料成分。具體而言，比較例24之衣料害蟲忌避組成物中，係使用下述式(20)：<Comparative Examples 24 to 34> According to formula 1 using IR3535 as a pest repellent component, a clothing pest repellent composition (Comparative Examples 24 to 34) was prepared. In the clothing pest repellent composition of Comparative Examples 24 to 34, a compound having an electronic conjugated part derived from a benzene ring, a benzoate structure or a salicylate structure was used as a fragrance component. Specifically, in the clothing pest repellent composition of Comparative Example 24, the following formula (20) was used:

Figure 02_image039
所示之香豆素(下稱「化合物C1」)作為香料成分。
Figure 02_image039
The indicated coumarin (hereinafter referred to as "compound C1") is used as a fragrance ingredient.

比較例25之衣料害蟲忌避組成物中，係使用下述式(21)：In the clothing pest repellent composition of Comparative Example 25, the following formula (21) was used:

Figure 02_image041
所示之β-紫羅蘭酮(下稱「化合物C2」)作為香料成分。
Figure 02_image041
The shown β-ionone (hereinafter referred to as "compound C2") is used as a fragrance ingredient.

比較例26之衣料害蟲忌避組成物中，係使用下述式(22)：In the clothing pest repellent composition of Comparative Example 26, the following formula (22) was used:

Figure 02_image043
所示之β-突厥酮(下稱「化合物C3」)作為香料成分。
Figure 02_image043
The indicated β-turketone (hereinafter referred to as "compound C3") is used as a fragrance ingredient.

比較例27之衣料害蟲忌避組成物中，係使用下述式(23)：In the clothing pest repellent composition of Comparative Example 27, the following formula (23) was used:

Figure 02_image045
所示之大馬仙酮(下稱「化合物C4」)作為香料成分。
Figure 02_image045
The indicated damascenone (hereinafter referred to as "compound C4") is used as a fragrance ingredient.

比較例28之衣料害蟲忌避組成物中，係使用下述式(24)：In the clothing pest repellent composition of Comparative Example 28, the following formula (24) was used:

Figure 02_image047
所示之檸檬醛(下稱「化合物C5」)作為香料成分。
Figure 02_image047
Citral (hereinafter referred to as "compound C5") shown as a fragrance ingredient.

比較例29之衣料害蟲忌避組成物中，係使用下述式(25)：In the clothing pest repellent composition of Comparative Example 29, the following formula (25) was used:

Figure 02_image049
所示之肉桂醛(下稱「化合物C6」)作為香料成分。
Figure 02_image049
The cinnamaldehyde shown (hereinafter referred to as "compound C6") is used as a fragrance ingredient.

比較例30之衣料害蟲忌避組成物中，係使用下述式(26)：In the clothing pest repellent composition of Comparative Example 30, the following formula (26) was used:

Figure 02_image051
所示之乙基-2-甲基-6-戊基-4-氧基-2-環己烯羧酸酯(Calixole)(下稱「化合物C7」)作為香料成分。
Figure 02_image051
The indicated ethyl-2-methyl-6-pentyl-4-oxy-2-cyclohexene carboxylate (Calixole) (hereinafter referred to as "compound C7") is used as a fragrance ingredient.

比較例31之衣料害蟲忌避組成物中，係使用下述式(27)：In the clothing pest repellent composition of Comparative Example 31, the following formula (27) was used:

Figure 02_image053
所示之開司米木麝香(下稱「化合物C8」)作為香料成分。
Figure 02_image053
The cashmere musk (hereinafter referred to as "compound C8") shown as a fragrance ingredient.

比較例32之衣料害蟲忌避組成物中，係使用下述式(28)：In the clothing pest repellent composition of Comparative Example 32, the following formula (28) was used:

Figure 02_image055
所示之麥芽酚(下稱「化合物C9」)作為香料成分。
Figure 02_image055
The indicated maltol (hereinafter referred to as "compound C9") is used as a fragrance ingredient.

比較例33之衣料害蟲忌避組成物中，係使用下述式(29)：In the clothing pest repellent composition of Comparative Example 33, the following formula (29) was used:

Figure 02_image057
所示之香芹酮(下稱「化合物C10」)作為香料成分。
Figure 02_image057
The indicated carvone (hereinafter referred to as "compound C10") is used as a fragrance ingredient.

比較例34之衣料害蟲忌避組成物中，係使用下述式(30)：In the clothing pest repellent composition of Comparative Example 34, the following formula (30) was used:

Figure 02_image059
所示之法呢烯(下稱「化合物C11」)作為香料成分。
Figure 02_image059
The farnesene shown (hereinafter referred to as "compound C11") is used as a fragrance ingredient.

＜比較例35～45＞ 根據使用埃卡瑞丁作為害蟲忌避成分的配方3，來調製衣料害蟲忌避組成物(比較例35～45)。比較例35～45之衣料害蟲忌避組成物中，係使用具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部的化合物C1～C11作為香料成分。＜Comparative Examples 35～45＞ According to formula 3 using Icaridin as a pest repellent component, a clothing pest repellent composition (Comparative Examples 35 to 45) was prepared. In the clothing pest repellent composition of Comparative Examples 35 to 45, compounds C1 to C11 having electronic conjugate parts other than those derived from benzene ring, benzoate structure or salicylate structure were used as fragrances ingredient.

＜比較例46～56＞ 根據未摻混害蟲忌避成分的配方5，來調製衣料害蟲忌避組成物(比較例46～56)。比較例46～56之衣料害蟲忌避組成物中，係使用具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部的化合物C1～C11作為香料成分。＜Comparative Examples 46～56＞ According to formula 5 in which no pest repellent component was blended, a clothing pest repellent composition (Comparative Examples 46 to 56) was prepared. In the clothing pest repellent composition of Comparative Examples 46-56, compounds C1 to C11 having an electronic conjugate part derived from a benzene ring, a benzoate structure or a salicylate structure are used as a fragrance ingredient.

將實施例1～54及比較例1～56之衣料害蟲忌避組成物的配方及香料成分示於表1、2。The formulations and fragrance components of the clothing pest repellent compositions of Examples 1 to 54 and Comparative Examples 1 to 56 are shown in Tables 1 and 2.

Figure 02_image061
Figure 02_image061

Figure 02_image063
Figure 02_image063

[除臭機能確認試驗] 茲實施對汗臭、中年男性體臭、老人味、菸臭味及調理臭味之除臭機能確認試驗。對於汗臭，係將試驗棉布(5cmx5cm棉布(金巾3號))置於高周緣深皿(外徑75mm、高度60mm)中，以異丁酸(Nacalai Tesque股份有限公司製)的乙醇溶液作為測試惡臭並以噴霧玻璃瓶適量噴灑。對於中年男性體臭，係將試驗棉布置於高周緣深皿中，以聯乙醯(Nacalai Tesque股份有限公司製)的乙醇溶液作為測試惡臭並以噴霧玻璃瓶適量噴灑。對於老人味，係將試驗棉布置於高周緣深皿中，以2-壬烯醛(東京化成工業股份有限公司製)的乙醇溶液作為測試惡臭並以噴霧玻璃瓶適量噴灑。對於菸臭味，係在密閉小空間內使試驗棉布暴露於香菸的煙下而進行處理，其後，將試驗棉布置於高周緣深皿中。對於調理臭味，係在密閉小空間內燃燒牛油並使試驗棉布暴露於此煙下而進行處理，其後，將試驗棉布置於高周緣深皿中。[Deodorization function confirmation test] We are here to carry out tests to confirm the deodorizing function of sweat odor, middle-aged male body odor, elderly odor, cigarette odor, and conditioning odor. For sweat odor, a test cotton cloth (5cmx5cm cotton cloth (Golden Scarf No. 3)) was placed in a deep dish (outer diameter 75mm, height 60mm), and an ethanol solution of isobutyric acid (manufactured by Nacalai Tesque Co., Ltd.) was used as the test Malodorous and spray appropriate amount with spray glass bottle. For the body odor of middle-aged men, the test cotton is placed in a deep dish with a high periphery, and an ethanol solution of acetonitrile (manufactured by Nacalai Tesque Co., Ltd.) is used as the test odor and sprayed with a spray glass bottle. For the odor of the elderly, the test cotton was placed in a deep dish with a high periphery, and an ethanol solution of 2-nonenal (manufactured by Tokyo Chemical Industry Co., Ltd.) was used as the test malodor and sprayed with a spray glass bottle. Regarding the smell of smoke, the test cotton cloth was exposed to cigarette smoke in a small enclosed space for treatment, and then the test cotton was placed in a deep dish with a high periphery. Regarding the conditioning of odors, the tallow was burned in a confined small space and the test cotton cloth was exposed to the smoke for treatment. After that, the test cotton was placed in a deep dish with a high periphery.

對附加有惡臭的各試驗棉布，以噴霧玻璃瓶噴灑0.03mL的實施例1～54及比較例1～56之試驗溶液，於試驗溶液剛噴灑後、3小時後及12小時後評定高周緣深皿內的臭氣。臭氣的評定係依以下5等級臭氣強度表示法請5位試驗員來進行評定，求出平均分數。將平均分數0以上且未達2者評為○、2以上且未達3者評為△、3以上4以下者評為×。 0：未聞到香味 1：極薄弱地聞到 2：微弱地聞到 3：明顯聞到 4：強烈聞到To each test cotton cloth with bad odor, spray 0.03 mL of the test solution of Examples 1 to 54 and Comparative Examples 1 to 56 in a spray glass bottle, and evaluate the high peripheral depth immediately after spraying the test solution, 3 hours, and 12 hours. The stench in the dish. The evaluation of odor is based on the following five-level odor intensity representation method, and 5 testers are invited to evaluate and obtain the average score. Those with an average score of 0 or more and less than 2 are rated as ○, those with 2 or more and less than 3 are rated as △, and those with 3 or more and 4 or less are rated as x. 0: No fragrance 1: Smell very weakly 2: Smell faintly 3: Obviously smell 4: Strong smell

將對汗臭之除臭機能確認試驗的結果示於表3、4。Tables 3 and 4 show the results of the confirmation test for the deodorizing function of sweat.

Figure 02_image065
Figure 02_image065

Figure 02_image067
Figure 02_image067

將對中年男性體臭之除臭機能確認試驗的結果示於表5、6。Tables 5 and 6 show the results of the deodorizing function confirmation test on the body odor of middle-aged men.

Figure 02_image069
Figure 02_image069

Figure 02_image071
Figure 02_image071

將對老人味之除臭機能確認試驗的結果示於表7、8。Tables 7 and 8 show the results of the test to confirm the deodorizing function of the elderly odor.

Figure 02_image073
Figure 02_image073

Figure 02_image075
Figure 02_image075

將對菸臭味之除臭機能確認試驗的結果示於表9、10。Tables 9 and 10 show the results of the deodorizing function confirmation test for smoke odor.

Figure 02_image077
Figure 02_image077

Figure 02_image079
Figure 02_image079

將對調理臭味之除臭機能確認試驗的結果示於表11、12。Tables 11 and 12 show the results of the deodorizing function confirmation test for the conditioning odor.

Figure 02_image081
Figure 02_image081

Figure 02_image083
Figure 02_image083

除臭機能確認試驗的結果，具備本發明之特徵構成的衣料害蟲忌避組成物，含有IR3535作為害蟲忌避成分的實施例1～27及含有埃卡瑞丁作為害蟲忌避成分的實施例28～54，對於汗臭、中年男性體臭、老人味、菸臭味及調理臭味，在試驗溶液的噴霧處理至12小時後均顯示優良的除臭性。由此研判，藉由將具備本發明之特徵構成的衣料害蟲忌避組成物，於外出前預先對衣類噴灑而進行處理，12小時左右的外出期間可持續維持香料成分所產生的除臭機能，而能夠防止附著於衣類之惡臭產生不適感。As a result of the deodorant function confirmation test, the clothing pest repellent composition with the characteristic structure of the present invention, Examples 1-27 containing IR3535 as a pest repellent ingredient, and Examples 28 to 54 containing Icaridin as a pest repellent ingredient, For sweat odor, middle-aged male body odor, elderly odor, smoke odor, and conditioning odor, they all showed excellent deodorization after spraying the test solution for 12 hours. From this study, it was determined that by spraying the clothing pest repellent composition with the characteristics of the present invention on the clothing before going out, the deodorizing function of the fragrance ingredients can be maintained continuously during the outing period of about 12 hours, and It can prevent uncomfortable odors attached to clothing.

另一方面，未含有害蟲忌避成分的比較例1～21之衣料害蟲忌避組成物，雖與含有IR3535作為害蟲忌避成分的實施例1～27及含有埃卡瑞丁作為害蟲忌避成分的實施例28～54含有相同的香料成分，但對於汗臭、中年男性體臭、老人味、菸臭味及調理臭味，均僅顯示試驗溶液的噴霧處理至3小時後的除臭性，試驗溶液的噴霧處理至12小時後並未顯示充分的除臭性。On the other hand, the clothing pest repellent compositions of Comparative Examples 1 to 21 that did not contain pest repellent components were compared with Examples 1 to 27 containing IR3535 as a pest repellent component and Example 28 containing Icaridin as a pest repellent component ～54 contains the same fragrance ingredients, but for sweat odor, middle-aged male body odor, elderly odor, smoke odor and conditioning odor, all only show the deodorization of the test solution after spraying treatment to 3 hours. The spray treatment did not show sufficient deodorizing properties after 12 hours.

比較例22之衣料害蟲忌避組成物係與實施例1～27同樣地含有IR3535作為害蟲忌避成分，且比較例23之衣料害蟲忌避組成物係與實施例28～54同樣地含有埃卡瑞丁作為害蟲忌避成分，但比較例22及23均未含有香料成分。此種比較例22及23之衣料害蟲忌避組成物對於汗臭、中年男性體臭、老人味、菸臭味及調理臭味均未顯示除臭性。由此確認，單獨含有害蟲忌避成分之IR3535及埃卡瑞丁時並不具有除臭性。儘管單獨含有害蟲忌避成分之IR3535及埃卡瑞丁時不具有除臭性，但與比較例1～21之衣料害蟲忌避組成物相比，在僅對此等摻混害蟲忌避成分的實施例1～54之衣料害蟲忌避組成物中之所以能長時間持續維持除臭機能，研判是因為害蟲忌避成分會與本發明中所規定的特定香料成分發揮某些相乘效果之故。The clothing pest repellent composition system of Comparative Example 22 contains IR3535 as a pest repellent component as in Examples 1-27, and the clothing pest repellent composition system of Comparative Example 23 contains Icaridin as the same as Examples 28 to 54 Pest repellent components, but Comparative Examples 22 and 23 did not contain fragrance components. The clothing pest repellent compositions of Comparative Examples 22 and 23 showed no deodorizing properties against sweat odor, middle-aged male body odor, elderly odor, smoke odor, and conditioning odor. This confirms that IR3535 and Icaridin, which are pest repellent ingredients alone, do not have deodorizing properties. Although IR3535 and Icaridin, which contain pest repellent components alone, do not have deodorizing properties, compared with the clothing pest repellent composition of Comparative Examples 1-21, in Example 1 where only these pest repellent components are blended The reason why the clothing pest repellent composition of ~54 can maintain the deodorizing function for a long time is judged because the pest repellent component exerts some synergistic effects with the specific fragrance components specified in the present invention.

此外，使用具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部的化合物作為香料成分的比較例24～56，對於汗臭、中年男性體臭、老人味、菸臭味及調理臭味，均僅顯示試驗溶液的噴霧處理至3小時後的除臭性，試驗溶液的噴霧處理至12小時後並未顯示充分的除臭性。在含有IR3535作為害蟲忌避成分時(比較例24～34)及含有埃卡瑞丁作為害蟲忌避成分時(比較例35～45)，之所以無法長時間持續維持除臭機能，研判係因未使用本發明中所規定的特定香料成分，而無法獲得害蟲忌避成分與香料成分的相乘效果之故。In addition, Comparative Examples 24-56 using compounds having electronic conjugated parts other than those derived from a benzene ring, a benzoate structure or a salicylate structure as a fragrance ingredient, for sweaty, middle-aged men Body odor, elderly odor, smoke odor, and conditioning odor all showed only the deodorization performance after spray treatment of the test solution for 3 hours, and the spray treatment of the test solution did not show sufficient deodorization performance after 12 hours. When IR3535 was contained as a pest repellent ingredient (Comparative Examples 24 to 34) and Icaridin was contained as a pest repellent ingredient (Comparative Examples 35 to 45), the reason why the deodorant function could not be maintained for a long time was determined because it was not used The specific fragrance component specified in the present invention cannot achieve the synergistic effect of the pest repellent component and the fragrance component.

由以上的結果確認，具備本發明之特徵構成的衣料害蟲忌避組成物(實施例1～54)，藉由特定的害蟲忌避成分與特定的香料成分之組合，可獲得害蟲忌避成分與香料成分的相乘效果，且長時間持續維持可香料成分所產生的除臭機能。 [產業上可利用性]From the above results, it is confirmed that the clothing pest repellent composition (Examples 1 to 54) with the characteristics of the present invention can obtain a combination of pest repellent ingredients and perfume ingredients by combining specific pest repellent ingredients and specific fragrance ingredients. It has a synergistic effect and maintains the deodorizing function produced by the fragrance ingredients for a long time. [Industrial availability]

本發明之衣料害蟲忌避組成物及衣料除臭方法係用以去除附著於衣類之惡臭，可利用於纖維製品的除臭。再者，本發明之衣料害蟲忌避除臭方法可利用於對纖維製品的害蟲忌避及除臭。The clothing pest repellent composition and the clothing deodorizing method of the present invention are used to remove the malodor attached to clothing, and can be used for deodorizing fiber products. Furthermore, the method for preventing and deodorizing clothing pests of the present invention can be used for preventing and deodorizing fiber products from pests.

Claims (7)

一種衣料害蟲忌避組成物，其含有害蟲忌避成分與香料成分，其中， 前述香料成分係具有去除附著於衣料之惡臭的除臭機能， 前述害蟲忌避成分係具有持續維持前述香料成分之除臭機能的持續機能。A clothing pest repellent composition, which contains pest repellent components and fragrance components, wherein, The aforementioned fragrance ingredients have a deodorizing function to remove bad odors attached to clothing, The aforementioned pest repellent component has a continuous function of continuously maintaining the deodorizing function of the aforementioned fragrance component. 如請求項1之衣料害蟲忌避組成物，其中前述害蟲忌避成分係選自由3-(N-丁基乙醯胺)丙酸乙酯、埃卡瑞丁及N,N-二乙基苯甲醯胺所成群組的至少一種， 前述香料成分係不具有源自苯環、苯甲酸酯結構或水楊酸酯結構之電子共軛部以外的電子共軛部，碳數為6～18，分子量為98～270，具有碳原子、氫原子及氧原子，且不具有硫原子、氮原子及鹵素原子的化合物。Such as the clothing pest repellent composition of claim 1, wherein the aforementioned pest repellent ingredient is selected from the group consisting of 3-(N-butylacetamide) ethyl propionate, Icaridin and N,N-diethylbenzyl At least one of the group of amines, The aforementioned fragrance ingredients do not have electronic conjugated parts other than those derived from benzene ring, benzoate structure or salicylate structure, carbon number is 6-18, molecular weight is 98-270, and it has carbon atoms , Hydrogen atom and oxygen atom, without sulfur atom, nitrogen atom and halogen atom compound. 如請求項1或2之衣料害蟲忌避組成物，其中前述香料成分係選自由順-3-己烯醇、二氫香葉烯醇、乙基沉香醇、沉香醇、香葉醇、四氫香葉醇、萜品醇、苯乙醇、新洋茉莉醛、鈴蘭醛、苯甲酸苄酯、水楊酸苄酯、順-3-己烯基水楊酸酯、二氫茉莉酸甲酯、沉香基乙酸酯、覆盆子酮、佳樂麝香、十三碳二酸乙二醇酯及十五碳內酯所成群組的至少一種。Such as the clothing pest repellent composition of claim 1 or 2, wherein the aforementioned fragrance ingredients are selected from the group consisting of cis-3-hexenol, dihydrogeranyl alcohol, ethyl linalool, linalool, geraniol, and tetrahydrogen Leaf alcohol, terpineol, phenethyl alcohol, new jasmonal, lily of the valley, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate, methyl dihydrojasmonate, agarwood At least one of the group consisting of acetate, raspberry ketone, carol musk, ethylene tridecanedioate and pentalactone. 如請求項1或2之衣料害蟲忌避組成物，其中前述香料成分的含量為0.1～1.0w/v%。For example, the clothing pest repellent composition of claim 1 or 2, wherein the content of the aforementioned fragrance ingredient is 0.1 to 1.0 w/v%. 如請求項1或2之衣料害蟲忌避組成物，其中前述香料成分(a)與前述害蟲忌避成分(b)的摻混比(a/b)，以重量比計為0.1～1.5。The clothing pest repellent composition of claim 1 or 2, wherein the blending ratio (a/b) of the aforementioned fragrance component (a) and the aforementioned pest repellent component (b) is 0.1 to 1.5 by weight. 一種衣料除臭方法，其係使用如請求項1～5中任一項之衣料害蟲忌避組成物，其中， 對衣料噴灑前述衣料害蟲忌避組成物而進行處理。A method for deodorizing clothing, which uses the clothing pest repellent composition according to any one of claims 1 to 5, wherein: The clothing material is treated by spraying the aforementioned clothing material pest repellent composition. 一種衣料害蟲忌避除臭方法，其係對衣料同時進行害蟲忌避處理與除臭處理，其包含： 噴灑步驟，係對處理對象之衣料噴灑含有害蟲忌避成分與香料成分的衣料害蟲忌避組成物；及 變更步驟，係變更對前述衣料噴灑前述衣料害蟲忌避組成物的位置，以使前述衣料持續維持充分的害蟲忌避效果及除臭效果。A method for repelling and deodorizing clothing pests, which simultaneously performs pest repelling treatment and deodorizing treatment on clothing, including: The spraying step is to spray the clothing pest repellent composition containing pest repellent ingredients and perfume ingredients on the clothing of the treatment object; and The modification step is to change the position where the clothing pest repellent composition is sprayed on the clothing material, so that the clothing material continues to maintain a sufficient pest repellent effect and deodorant effect.
TW108139870A 2018-11-06 2019-11-04 Clothes insect pest repellent composition, and clothes deodorizing method and clothes insect pest repelling and deodorizing method using said composition TW202023383A (en)

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