TW201904559A - Hair conditioning composition - Google Patents
Hair conditioning compositionInfo
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- TW201904559A TW201904559A TW107122846A TW107122846A TW201904559A TW 201904559 A TW201904559 A TW 201904559A TW 107122846 A TW107122846 A TW 107122846A TW 107122846 A TW107122846 A TW 107122846A TW 201904559 A TW201904559 A TW 201904559A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Abstract
Description
本發明涉及毛髮調理組合物，更詳細地，涉及含有矽丙烯酸酯類成膜劑及具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇作為有效成分的毛髮調理組合物。The present invention relates to a hair conditioning composition, and more particularly, to a hair conditioning composition containing a silicon acrylate film-forming agent and polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mol as an active ingredient. combination.
通常賦予毛髮調理(改善毛髮狀態)感的產品可以分為需要清洗的沖洗(wash-off)產品和不需要清洗的免洗(leave-on)產品。Products that generally give a feeling of hair conditioning (improving the condition of the hair) can be divided into wash-off products that require cleaning and leave-on products that do not require cleaning.
需要清洗的沖洗(wash-off)產品有潤髮劑、焗油膏、護髮膜(hair pack)、髮膜(hair mask)、頭髮濃縮精華素等，主要藉由含有四級陽離子表面活性劑和矽油、合成油或天然油等成分的乳化劑型，對毛髮賦予潤澤度和光潤度。Wash-off products that need to be washed include hair conditioners, creams, hair packs, hair masks, hair concentrates, etc., mainly by containing four-level cationic surfactants and Emulsifiers containing silicone oil, synthetic oil or natural oil, give moisturization and gloss to hair.
不需要清洗的免洗(leave-on)產品有頭髮噴霧、亮髮素、護髮精華液、髮油等，藉由多種劑型賦予毛髮調理效果。Leave-on products that do not require cleaning include hair sprays, brighteners, hair serums, hair oils, etc., which impart hair conditioning effects through a variety of formulations.
就用於毛髮調理組合物中的矽油而言，根據其種類或分子量而具有多種功能，即使是具有相同化學結構的矽油也會根據其含量顯示出多種使用感特性。The silicone oil used in the hair conditioning composition has various functions according to its kind or molecular weight, and even the silicone oil having the same chemical structure exhibits various use-feel characteristics depending on its content.
根據分子量，矽油顯示出多種形態，從分子量最低的揮發性形態，根據分子量增大的順序顯示為液體、有黏性的液體、黏膠(Gum)、凝膠、彈性體及樹脂的形態。即，矽的分子量增加時也會增加黏性。According to molecular weight, silicone oil shows a variety of forms, from the lowest volatile form to the form of liquid, viscous liquid, Gum, gel, elastomer, and resin in the order of increasing molecular weight. That is, viscosity increases as the molecular weight of silicon increases.
為了延長保持功效的時間，通常習知的毛髮調理產品含有過量的矽油，在這種情況下，用在毛髮時可以立即賦予潤澤度和光潤度，但是存在因過量的矽油導致的使用上的黏膩感、引起毛髮的黏糊感的問題。In order to extend the retention time, the conventional hair conditioning products usually contain excess silicone oil. In this case, when used in the hair, it can immediately impart moisturization and gloss, but there is stickiness caused by excessive silicone oil. The problem of greasiness and stickiness of hair.
先前技術文獻 專利文獻 (專利文獻1) 韓國公開專利公報第10-1996-0704516號 (專利文獻2) 韓國公開專利公報第10-2014-0040683號Prior Art Literature Patent Literature (Patent Literature 1) Korean Laid-open Patent Publication No. 10-1996-0704516 (Patent Literature 2) Korean Laid-Open Patent Publication No. 10-2014-0040683
要解決的技術問題Technical problem to be solved
本發明的目的在於提供毛髮調理組合物，其為使用高黏度及高分子量的非揮發性矽油聚二甲基矽氧烷醇(Dimethiconol)，從而延長毛髮保持潤澤度及柔順度的時間，並在其中以特定的混合比一同使用矽丙烯酸酯成膜劑(Film former)來提高毛髮的彈性及捲曲持久力，從而能夠提高頭髮造型的保持力的毛髮調理組合物。The object of the present invention is to provide a hair conditioning composition, which is a non-volatile silicone oil polymethiconol (Dimethiconol) with high viscosity and high molecular weight, so as to prolong the time that hair stays moisturized and supple. Among them, a hair conditioning composition that uses a silicon former film former (Film former) at a specific mixing ratio to improve hair elasticity and curl durability, thereby improving the retention of hair styling.
技術方案Technical solutions
本發明為了實現如上所述的目的，其組成特徵在於，毛髮調理組合物含有矽丙烯酸酯類成膜劑(Film former)及具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇(Dimethiconol)作為有效成分。In order to achieve the above-mentioned object, the present invention is characterized in that the hair conditioning composition contains a silicone acrylate film former (Film former) and polydimethyl methoxide having an average molecular weight of 800,000 to 1.1 million g / mole. Dimethiconol is used as an active ingredient.
發明效果Invention effect
本發明的毛髮調理組合物以特定的混合比混合使用具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇(Dimethiconol)和矽丙烯酸酯類成膜劑(Film former)，從而長時間對毛髮賦予潤澤度及光潤度的同時提高彈性及捲曲持久力，因此能夠提高頭髮造型的保持力。The hair conditioning composition of the present invention is used in a specific mixing ratio by mixing a polydimethylsilanol (Dimethiconol) and a silicone former (Film former) having an average molecular weight of 800,000 to 1.1 million g / mole. ), So as to provide moisturization and gloss to the hair for a long time, while improving elasticity and curling endurance, it is possible to improve the retention of hair styling.
下面，對本發明的毛髮調理組合物進行具體說明。Hereinafter, the hair conditioning composition of this invention is demonstrated concretely.
若沒有特別提及，本說明書中所提及的化合物的名稱表示登載於美國化妝品協會(Cosmetic, Toiletry and Fragrance Association，CTFA)發行的國際化妝品原料詞典(International Cosmetic Ingredient Dictionary，ICID)中的國際化妝品原料命名(International Nomenclature Cosmetic Ingredient，INCI)的名所對應的化合物，若INCI名中沒有該名稱，則表示根據國際純粹與應用化學聯合會(International Union of Pure and Applied Chemistry，IUPAC)所制定的IUPAC命名法的化合物，若不存在根據IUPAC命名法的化合物，則表示對應於本發明技術領域中通用的化合物的名稱的化合物。Unless otherwise mentioned, the names of the compounds mentioned in this specification represent the international cosmetics listed in the International Cosmetic Ingredient Dictionary (ICID) issued by the Cosmetic, Toiletry and Fragrance Association (CTFA) The compound corresponding to the name of the International Nomenclature Cosmetic Ingredient (INCI). If the name is not included in the INCI name, it means that it is named according to the IUPAC established by the International Union of Pure and Applied Chemistry (IUPAC) If a compound according to the IUPAC nomenclature does not exist, it means a compound corresponding to the name of a compound commonly used in the technical field of the present invention.
本發明的毛髮調理組合物可以含有矽丙烯酸酯類成膜劑(Film former)及聚二甲基矽氧烷醇(Dimethiconol)作為有效成分，並可以實現為透明的劑型。The hair conditioning composition of the present invention may contain a silicone acrylate film former (Film former) and polymethiconol (Dimethiconol) as active ingredients, and may be realized as a transparent dosage form.
所述矽丙烯酸酯類成膜劑為矽丙烯酸酯共聚物類型的成膜劑，為了實現所期望的效果，相對於毛髮調理組合物的總重量，可以含有0.1~4重量%的所述矽丙烯酸酯類成膜劑，較佳可以含有0.1~2重量%的量。如果所述矽丙烯酸酯類成膜劑的含量小於上述含量的下限，則無法期待毛髮的捲曲持久力效果，如果所述矽丙烯酸酯類成膜劑的含量超過上述含量的上限，則會形成硬的膜而具有瞬時柔順度低且劑型的透明度降低的缺點。The silicone acrylate film former is a silicone acrylate copolymer film former. In order to achieve a desired effect, it may contain 0.1 to 4% by weight of the silicone acrylic acid relative to the total weight of the hair conditioning composition. The ester film-forming agent may preferably be contained in an amount of 0.1 to 2% by weight. If the content of the silicone acrylate film-forming agent is less than the lower limit of the above content, the curling endurance effect of hair cannot be expected, and if the content of the silicone acrylate film-forming agent exceeds the upper limit of the content, a hard The film has the disadvantages of low instantaneous compliance and reduced transparency of the dosage form.
本發明的一個實施方式中，聚二甲基矽氧烷醇為具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇，其黏度範圍可以為77,000~140,000cs(厘斯，centi-stock)。與使用具有60萬g/莫耳以下的分子量的聚二甲基矽氧烷醇時相比，使用上述分子量範圍的聚二甲基矽氧烷醇時，能夠提高潤澤度持久力及柔順度持久力。In one embodiment of the present invention, the polydimethylsilanol is a polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mole, and its viscosity range may be 77,000 to 140,000 cs ( Centi-stock). Compared with the use of polydimethylsilanol having a molecular weight of 600,000 g / mole or less, the use of polydimethylsilanol in the above molecular weight range can improve the moisturizing durability and softness lasting force.
此外，為了實現所期望的效果，相對於毛髮調理組合物的總重量，可以含有1~20重量%的所述聚二甲基矽氧烷醇，較佳可以含有5~15重量%。如果所述聚二甲基矽氧烷醇的含量小於上述含量的下限，則難以期待毛髮調理效果，如果所述聚二甲基矽氧烷醇的含量超過上述含量的上限，則會出現黏糊且黏膩的使用感，並且具有難以均勻地塗佈於毛髮上的問題。In addition, in order to achieve a desired effect, the polydimethylsiloxane may be contained in an amount of 1 to 20% by weight, and may preferably be contained in an amount of 5 to 15% by weight based on the total weight of the hair conditioning composition. If the content of the polydimethylsilanol is less than the lower limit of the above content, it is difficult to expect a hair conditioning effect. If the content of the polydimethylsilanol exceeds the upper limit of the content, a slime appears and It has a sticky feel and has a problem that it is difficult to apply it evenly to hair.
另外，為了實現所期望的效果，以重量為基準，所述聚二甲基矽氧烷醇與矽丙烯酸酯類成膜劑可以以10:1~100:1的比例進行配合。In addition, in order to achieve a desired effect, the polydimethylsilanol and the silicone acrylate-based film-forming agent may be blended at a ratio of 10: 1 to 100: 1 on a weight basis.
本發明的一個實施方式中，所述毛髮調理組合物可以含有本領域中通常使用的成分，較佳可以進一步包含選自揮發性矽油及烴類油中的一種以上，但並不限定於此。In one embodiment of the present invention, the hair conditioning composition may contain ingredients generally used in the art, and it may further include one or more selected from volatile silicone oil and hydrocarbon oil, but is not limited thereto.
所述揮發性矽油可以是黏度為0.5~5cs的直鏈型聚矽氧烷及環狀聚矽氧烷中的至少一種以上。The volatile silicone oil may be at least one of a linear polysiloxane and a cyclic polysiloxane having a viscosity of 0.5 to 5 cs.
其中，所述直鏈型聚矽氧烷可以是聚甲基矽氧烷或聚乙基矽氧烷，所述環狀聚矽氧烷可以是聚苯基矽氧烷、聚甲基苯基矽氧烷或甲基環聚矽氧烷，但並不限定於此。Wherein, the linear polysiloxane may be polymethylsiloxane or polyethylsiloxane, and the cyclic polysiloxane may be polyphenylsiloxane, polymethylphenylsiloxane Oxane or methylcyclopolysiloxane, but is not limited thereto.
較佳地，所述揮發性矽油可以是作為環狀聚矽氧烷的環聚二甲基矽氧烷和作為直鏈聚矽氧烷的聚二甲基矽氧烷的混合物。具體而言，所述揮發性矽油可以是黏度為3.5~4.5cs的環聚二甲基矽氧烷及黏度為0.5~1cs的聚二甲基矽氧烷的混合物。Preferably, the volatile silicone oil may be a mixture of a cyclic polydimethylsiloxane as a cyclic polysiloxane and a polydimethylsiloxane as a linear polysiloxane. Specifically, the volatile silicone oil may be a mixture of cyclic polydimethylsiloxane having a viscosity of 3.5 to 4.5 cs and polydimethylsiloxane having a viscosity of 0.5 to 1 cs.
為了實現所期望的效果，相對於毛髮調理組合物的總重量，可以含有50~99重量%的所述揮發性矽油，較佳可以含有70~99重量%。如果所述揮發性矽油的含量小於上述含量的下限，則難以獲得清爽的使用感，如果所述揮發性矽油的含量超過99重量%，則具有使賦予毛髮柔順度的效果及持久力降低的問題。In order to achieve a desired effect, the volatile silicone oil may be contained in an amount of 50 to 99% by weight, and preferably 70 to 99% by weight, relative to the total weight of the hair conditioning composition. If the content of the volatile silicone oil is less than the lower limit of the above content, it is difficult to obtain a refreshing feeling of use. If the content of the volatile silicone oil exceeds 99% by weight, there is a problem that the effect of imparting softness to the hair and reducing the durability are reduced .
本發明的一個實施方式中，為了實現使用時在手上的清爽的使用感，並發揮賦予毛髮潤澤度的效果，可以進一步包含烴類油，其為分子量低且延展性(spreadability)大的非揮發性油。In one embodiment of the present invention, in order to achieve a refreshing feeling on the hand during use and exert the effect of imparting moisturization to the hair, a hydrocarbon oil may be further included, which is a non-molecular, low molecular weight and high spreadability Volatile oil.
所述烴類油可以為選自碳原子數為10~20個的低分子量烴類油、礦物油、角鯊烷、α-烯烴低聚物、氫化聚癸烯及氫化聚異丁烯的一種以上，但並不限定於此。此外，所述碳原子數為10~20個的低分子量烴類油較佳可以為碳原子數為12~16個的低分子量烴類油。The hydrocarbon oil may be one or more selected from low molecular weight hydrocarbon oils having 10 to 20 carbon atoms, mineral oil, squalane, α-olefin oligomer, hydrogenated polydecene, and hydrogenated polyisobutylene. But it is not limited to this. In addition, the low molecular weight hydrocarbon oil having 10 to 20 carbon atoms may preferably be a low molecular weight hydrocarbon oil having 12 to 16 carbon atoms.
為了實現所期望的效果，相對於毛髮調理組合物的總重量，可以含有0.1~10重量%的所述烴類油，較佳可以含有1~5重量%。In order to achieve a desired effect, the hydrocarbon oil may be contained in an amount of 0.1 to 10% by weight, and preferably 1 to 5% by weight, with respect to the total weight of the hair conditioning composition.
此外，本發明提供在製備含有矽丙烯酸酯類成膜劑及具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇作為有效成分的毛髮調理組合物中的矽丙烯酸酯類成膜劑及具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇的用途。In addition, the present invention provides a silicone acrylic acid for preparing a hair conditioning composition containing a silicone acrylate film-forming agent and polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mol as an active ingredient. Use of an ester film-forming agent and polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mol.
如上述的說明，就本發明提出的毛髮調理組合物而言，藉由以特定的混合比混合使用具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇和矽丙烯酸酯類成膜劑，從而長時間對毛髮賦予潤澤度及光潤度的同時提高彈性及捲曲持久力，因此能夠期待提高頭髮造型的保持力的效果。As described above, in the hair conditioning composition provided by the present invention, polydimethylsilanol and silicone acrylic acid having an average molecular weight of 800,000 to 1.1 million g / mole are mixed and used at a specific mixing ratio. Ester-based film-forming agents increase the elasticity and curl durability of the hair while imparting moisturization and gloss to the hair for a long period of time. Therefore, the effect of improving the retention of hair styling can be expected.
下面，藉由實施例及試驗例對本發明的內容進行更加具體的說明。這些實施例及試驗例僅僅是為了理解本發明的內容而提出的，本發明的權利範圍並不受限於這些實施例及試驗例，可以實施本領域中通常習知的變形、取代及***等，並且其亦包含於本發明的範圍。Hereinafter, the content of the present invention will be described more specifically with reference to examples and test examples. These embodiments and test examples are merely provided for understanding the content of the present invention, and the scope of the right of the present invention is not limited to these embodiments and test examples, and can be modified, replaced and inserted, which are generally known in the art. And it is also included in the scope of the present invention.
[製備例] 毛髮調理組合物的製備[Preparation example] Preparation of hair conditioning composition
根據下述表1的組成添加下述含量的各成分，並用真空乳化機（Agi mixing）進行攪拌(250rpm)來製備，在每次添加原料時均進行攪拌（mixing）1分鐘以上，添加最終原料後，攪拌30分鐘，從而製備比較例1~6、實施例1及2。下述表1中的含量的單位是相對於組合物總重量的對應成分的重量%。According to the composition of Table 1 below, each component with the following content is added, and it is prepared by stirring (250 rpm) with a vacuum emulsifier (Agi mixing). Each time the raw materials are added, mixing is performed for more than 1 minute, and the final raw materials are added After that, the mixture was stirred for 30 minutes to prepare Comparative Examples 1 to 6, and Examples 1 and 2. The unit of content in the following Table 1 is the weight% of the corresponding component with respect to the total weight of the composition.
表1
[試驗例1] 賦予毛髮潤澤度的效果及潤澤度持久力評估試驗[Experimental Example 1] Evaluation of hair moisturizing effect and moisturizing endurance evaluation test
為了評估本發明提出的毛髮調理組合物的賦予潤澤度的效果及潤澤度持久力，在使用沒有調理功效的基礎洗髮水進行洗滌後進行沖洗並用吹風機進行乾燥而準備的用於實驗的人毛髮上，分別以120μl塗佈所述表1中的比較例1~4及實施例1的組合物，並在塗佈後即刻起以1小時為間隔，測量毛髮表面的潤澤度直至塗佈後的3小時為止。In order to evaluate the effect of imparting moisturization and moisturizing power to the hair conditioning composition provided by the present invention, human hair prepared for the experiment was prepared by washing with basic shampoo without conditioning effect, washing it with a hair dryer, and drying it. The compositions of Comparative Examples 1 to 4 and Example 1 in Table 1 were coated with 120 μl, and the moisturizing degree on the surface of the hair was measured at intervals of 1 hour immediately after coating. So far.
所述毛髮的表面潤澤度是藉由以下方法測量，即，利用SAMBA儀器(SAMBA毛髮系統(SAMBA Hair system)，波薩諾瓦科技公司(Bossa Nova Technologies))來測量基於光照射角度(-45°~+45°)的光的最大反射量，並將該測量值表示為毛髮潤澤度。其結果示於下述表2及第1圖中。表2中的潤澤度測量值的單位是%。The surface moisturization of the hair is measured by using a SAMBA instrument (SAMBA Hair system, Bossa Nova Technologies) to measure the light-based angle (-45 ° ~ + 45 °), and the measured value is expressed as hair moisturization. The results are shown in Table 2 and Figure 1 below. The unit of the moisturization measurement values in Table 2 is%.
表2
從上述表2及第1圖的結果可以確認，與包含具有60萬g/莫耳以下的平均分子量的聚二甲基矽氧烷醇的比較例1及2相比，就如同本發明提出的毛髮調理組合物包含具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇的實施例1、比較例3及4而言，自塗佈後即刻起至塗佈後1~3小時為止，持續保持優異的潤澤度。From the results of the above Table 2 and FIG. 1, it can be confirmed that, as compared with Comparative Examples 1 and 2 containing polydimethylsilanol having an average molecular weight of 600,000 g / mole or less, it is similar to that proposed by the present invention For the hair conditioning composition of Example 1, Comparative Examples 3 and 4 containing polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mole, from immediately after coating to after coating Maintains excellent moisturization until 1 to 3 hours.
此外，可以確認，與不包含碳原子數為12~16的烷烴的比較例1及3相比，在包含碳原子數為12~16的烷烴的實施例1、比較例2及4中分別測量到更加優異的潤澤度。In addition, it was confirmed that, compared with Comparative Examples 1 and 3 that did not include an alkane having 12 to 16 carbon atoms, it was measured in Example 1, Comparative Examples 2 and 4, respectively, containing an alkane having 12 to 16 carbon atoms. To more excellent moisturization.
尤其，可以確認，與比較例1~4相比，如同本發明提出的毛髮調理組合物，進一步包含矽丙烯酸酯類成膜劑的實施例1中測量到的潤澤度最為優異。In particular, compared with Comparative Examples 1 to 4, it was confirmed that, like the hair conditioning composition proposed by the present invention, the moisturizing degree measured in Example 1 further containing a silicone acrylate film-forming agent was the most excellent.
並且，觀察表2中塗佈後即刻與塗佈後經過3小時時的潤澤度測量值的差異及第1圖中曲線的傾斜度，可以確認與其餘的比較例1~4相比，如同本發明提出的毛髮調理組合物，混合使用具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑，並包含碳原子數為12~16的烷烴的實施例1的潤澤度的減少程度非常小，從而潤澤度持久力最為優異。In addition, by observing the difference in the measured values of moisturization immediately after coating and 3 hours after coating in Table 2 and the inclination of the curve in the first graph, it can be confirmed that the comparison with the other comparative examples 1 to 4 is the same as this. The hair conditioning composition provided by the invention is a mixture of polydimethylsilanol and a silicon acrylate film-forming agent having an average molecular weight of 800,000 to 1.1 million g / mole, and contains 12 to 16 carbon atoms. The degree of reduction in the degree of moisturization of Example 1 of Alkanes was very small, so that the moisturizing durability was the most excellent.
因此，可以確認，與使用具有60萬g/莫耳以下的平均分子量的聚二甲基矽氧烷醇時相比，使用具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇、使用矽丙烯酸酯類成膜劑及屬於烴類油的碳原子數為12~16的烷烴時，對毛髮賦予潤澤度的效果更加優異，並且潤澤度持久力也非常優異。Therefore, it was confirmed that polydimethylsiloxane having an average molecular weight of 800,000 to 1.1 million g / mol was used as compared with the case of using polydimethylsiloxane having an average molecular weight of 600,000 g / mol or less. When silanol, a silicone acrylate-based film-forming agent, and an alkane having 12 to 16 carbon atoms, which are hydrocarbon oils, are more effective in imparting moisturization to hair, and have excellent moisturizing and long-lasting power.
[試驗例2] 賦予毛髮柔順度的效果的評估試驗[Experimental Example 2] Evaluation test of effect of imparting hair flexibility
為了確認本發明提出的毛髮調理組合物的賦予毛髮柔順度的效果，在如上述試驗例1中準備的用於實驗的人毛髮上分別以120μl塗佈所述表1中的比較例1~6及實施例1的組合物，並在塗佈後立即測量了毛髮的柔順度。In order to confirm the effect of imparting hair suppleness to the hair conditioning composition provided by the present invention, the human hair prepared for the experiment as prepared in the above Test Example 1 was coated with 120 μl of Comparative Examples 1 to 6 in Table 1 respectively. And the composition of Example 1, and the softness of the hair was measured immediately after coating.
就所述毛髮的柔順度而言，利用毛髮特性測量儀MTT 175拉伸試驗儀器(Dia-Stron公司)，測量未經處理的對照組毛髮和用組合物進行處理的毛髮對梳理的阻力的gmf值。並以未經處理的對照組為基準，藉由下述數學式1將其轉換為百分數(%)。As for the compliance of the hair, the gmf of the resistance to combing of the hair of the untreated control hair and the hair treated with the composition was measured using a hair property measuring instrument MTT 175 tensile tester (Dia-Stron). value. Based on the untreated control group, it was converted into a percentage (%) by the following mathematical formula 1.
[數學式1] [Mathematical formula 1]
其結果示於下述表3(單位：%)及第2圖中。The results are shown in Table 3 (unit:%) and Figure 2 below.
[表3]
從上述表3及第2圖的結果可以確認，與包含具有60萬g/莫耳以下的平均分子量的聚二甲基矽氧烷醇的比較例1及2相比，包含具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇的比較例3~6及實施例1的的柔順度顯著優異。From the results in Tables 3 and 2 described above, it can be confirmed that compared to Comparative Examples 1 and 2 containing polydimethylsilanol having an average molecular weight of 600,000 g / mole or less, it contained 800,000 to 110 Comparative examples 3 to 6 and Example 1 of the polydimethylsilanol having an average molecular weight of 10,000 g / mole were remarkably excellent in compliance.
此外，可以確認，與分別以2:1及1:1的混合比包含所述聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑的比較例5及6相比，如同本發明提出的毛髮調理組合物，以10:1的混合比包含具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑的實施例1的柔順度顯著優異。In addition, it was confirmed that, as compared with Comparative Examples 5 and 6 including the polydimethylsiloxane and the silicone acrylate-based film-forming agent at a mixing ratio of 2: 1 and 1: 1, respectively, The hair conditioning composition of Example 10 in a mixing ratio of 10: 1 including the polydimethylsilanol and the silicone acrylate film-forming agent having an average molecular weight of 800,000 to 1.1 million g / mole. Degree is significantly excellent.
因此，可以確認，並不是無視具有特定的平均分子量範圍的聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑的混合比而單純混合使用，而是如同本發明的毛髮調理組合物，以特定的比例混合使用聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑時才能夠大幅提高賦予毛髮柔順度的效果。Therefore, it was confirmed that, instead of ignoring the mixing ratio of polydimethylsilanol and silicone acrylate film-forming agent having a specific average molecular weight range, they were simply mixed and used, but were like the hair conditioning composition of the present invention, The effect of imparting softness to hair can be greatly enhanced when polydimethylsilanol and a silicone acrylate-based film-forming agent are mixed in a specific ratio.
[試驗例3] 毛髮柔順度持久力評估試驗[Experimental Example 3] Evaluation of hair compliance and staying power
為了評估本發明提出的毛髮調理組合物的柔順度持久力，在如同上述試驗例1準備的用於實驗的人毛髮上分別以120μl塗佈所述表1的比較例1~4及實施例1的組合物，並在塗佈後即刻起至3小時為止，以1小時為間隔，測量毛髮的柔順度。In order to evaluate the softness and staying power of the hair conditioning composition provided by the present invention, Comparative Examples 1 to 4 and Example 1 of Table 1 were coated on human hair prepared for the experiment as in Test Example 1 above with 120 μl, respectively. The composition was measured immediately after application to 3 hours at 1-hour intervals to measure the compliance of the hair.
利用3D雷射掃描儀器(奧林巴斯公司)，對毛髮的表皮層進行雷射掃描而獲得圖像，並在該圖像中測量表面粗糙度的值(Sa)。以未經處理的對照組為基準，藉由下述數學式2將其轉換為百分數(%)，並表示為柔順度值。A 3D laser scanning device (Olympus) was used to perform laser scanning on the epidermal layer of hair to obtain an image, and the surface roughness value (Sa) was measured in the image. Based on the untreated control group, it was converted into a percentage (%) by the following mathematical formula 2 and expressed as a compliance value.
[數學式2] [Mathematical formula 2]
其結果示於下述表4(單位：%)及圖3中。The results are shown in the following Table 4 (unit:%) and FIG. 3.
[表4]
從上述表4及第3圖的結果可以確認，與包含具有60萬g/莫耳以下的平均分子量的聚二甲基矽氧烷醇的比較例1及2相比，如同本發明提出的毛髮調理組合物，包含具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇的實施例1、比較例3及4自塗佈後即刻起至塗佈後的1~3小時為止，持續保持優異的毛髮柔順度。From the results of the above Tables 4 and 3, it can be confirmed that, compared with Comparative Examples 1 and 2 containing polydimethylsilanol having an average molecular weight of 600,000 g / mole or less, it is similar to the hair proposed by the present invention. Conditioning composition, Example 1, Comparative Examples 3 and 4 containing polydimethylsilanol having an average molecular weight of 800,000 to 1.1 million g / mole, from immediately after coating to 1 to 1 after coating Up to 3 hours, it maintains excellent hair suppleness.
此外，與不包含碳原子數為12~16的烷烴的比較例1及3相比，包含碳原子數為12~16的烷烴的實施例1、比較例2及4中分別測量到顯著優異的柔順度值。In addition, as compared with Comparative Examples 1 and 3 which did not contain an alkane having 12 to 16 carbon atoms, significantly superior values were respectively measured in Example 1, Comparative Examples 2 and 4 containing an alkane having 12 to 16 carbon atoms. Compliance value.
尤其，可以確認，與比較例1~4相比，如同本發明提出的毛髮調理組合物，進一步包含矽丙烯酸酯類成膜劑的實施例1中測量到的柔順度值最為優異。In particular, compared with Comparative Examples 1 to 4, it was confirmed that the softness value measured in Example 1 further containing a silicone acrylate film-forming agent, like the hair conditioning composition proposed by the present invention, was the most excellent.
並且，觀察表4中塗佈後即刻與塗佈後經過3小時時的柔順度值的差異及第3圖中曲線的傾斜度，可以確認與其餘的比較例1~4相比，如同本發明提出的毛髮調理組合物，混合使用具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇及矽丙烯酸酯類成膜劑，並包含碳原子數為12~16的烷烴的實施例1的柔順度的減少程度非常小，並且柔順度持久力最為優異。In addition, by observing the difference in the compliance values immediately after coating and 3 hours after coating in Table 4 and the inclination of the curve in Figure 3, it can be confirmed that the comparison with the other Comparative Examples 1 to 4 is similar to the present invention. The proposed hair conditioning composition is a mixture of polydimethylsilanol and a silicon acrylate film-forming agent having an average molecular weight of 800,000 to 1.1 million g / mole, and contains 12 to 16 carbon atoms. The degree of decrease in the compliance of the alkane example 1 was very small, and the durability of the compliance was most excellent.
[試驗例4] 捲曲持久力評估試驗[Test Example 4] Evaluation of curl endurance
為了評估含有矽丙烯酸酯類成膜劑時的捲曲持久力，利用捲髮器，在如同所述試驗例1中準備的用於實驗的人毛髮上人為進行捲曲（curling），然後分別以120μl塗佈所述表1中的比較例1~6及實施例1的組合物，並在經過8小時後測量了捲髮（curl）的直徑。藉由下述數學式3將其轉換為相對於塗佈前的值的百分數來確認持久力。In order to evaluate the curl endurance when the silicone acrylate-based film-forming agent is contained, a curler is used to artificially curl the human hair prepared for the experiment as described in Test Example 1 and then coated with 120 μl each The compositions of Comparative Examples 1 to 6 and Example 1 in Table 1 were measured for the diameter of curls after 8 hours. The endurance was confirmed by converting it into the percentage with respect to the value before application by the following mathematical formula 3.
[數學式3]L：塗佈前的髮辮長度 L0：塗佈後即刻的髮辮長度 Lt：塗佈8小時後的髮辮長度[Mathematical formula 3] L: Tress length before coating L0: Tress length immediately after coating Lt: Tress length after 8 hours of coating
其結果示於下述表5(單位：%)及第4圖中。The results are shown in Table 5 (unit:%) and Figure 4 below.
[表5]
從上述表5及第4圖的結果可以確認，與不包含矽丙烯酸酯類成膜劑的比較例1~4相比，如同本發明提出的毛髮調理組合物，包含具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇和矽丙烯酸酯類成膜劑的比較例5、6及實施例1的捲曲持久力非常優異。From the results in Tables 5 and 4 above, it can be confirmed that, as compared with Comparative Examples 1 to 4 which do not contain a silicone acrylate film-forming agent, as in the hair conditioning composition proposed by the present invention, it contains 800,000 to 1.1 million g. The comparative examples 5 and 6 and Example 1 of the average molecular weight polydimethylsiloxane and silicon acrylate-based film-forming agents of Moore were excellent in curl durability.
此外，可以確認，與含有1重量%的矽丙烯酸酯類成膜劑的實施例1相比，分別包含5重量%及10重量%的矽丙烯酸酯類成膜劑的比較例5及6中，矽丙烯酸酯類成膜劑的含量越多，越增加捲曲持久力，但是根據前述的試驗例2可以確認，與實施例1相比，含有5%重量以上的矽丙烯酸酯類成膜劑的比較例5及6的柔順度顯著降低而大幅降低使用感。In addition, it can be confirmed that in Comparative Examples 5 and 6 containing 5% and 10% by weight of the silicone acrylate film-forming agent, respectively, as compared with Example 1 containing 1% by weight of the silicone acrylate film-forming agent, The larger the content of the silicone acrylate film-forming agent, the more the curling endurance is increased. However, according to the aforementioned Test Example 2, it can be confirmed that compared with Example 1, a silicone acrylate film-forming agent containing 5% by weight or more is compared. The flexibility of Examples 5 and 6 was significantly reduced, and the feeling of use was greatly reduced.
因此，可以確認，本發明的實施例1含有適量的矽丙烯酸酯類成膜劑，從而能夠顯示出高柔順度賦予效果的同時捲曲持久力也很優異。Therefore, it can be confirmed that Example 1 of the present invention contains a suitable amount of a silicone acrylate film-forming agent, can exhibit a high flexibility imparting effect, and is also excellent in curl durability.
[試驗例5] 官能評估試驗[Test Example 5] Functional evaluation test
為了評估本發明提出的毛髮調理組合物的效果，使11名專家小組對比較例6與本發明的實施例1及2的潤澤度、柔順度、捲曲保持力、手延展性(用手延展塗抹時的容易性)、毛髮塗抹性、毛髮吸收性及清爽度進行評估，其中，比較例6的柔順度低且劑型為不透明但在上述試驗例4中顯示出最高的捲曲持久力，上述評估是以滿分為10分且上述屬性越強則用越大的數值顯示，從而計算平均值。其結果示於下述表6及第5圖中。In order to evaluate the effect of the hair conditioning composition proposed by the present invention, a panel of 11 experts was asked to compare the moisturization, compliance, curl retention, and hand extensibility of Comparative Example 6 and Examples 1 and 2 of the present invention (hand spreading application) Ease of use), hair applicability, hair absorbency, and freshness were evaluated. Among them, Comparative Example 6 had low compliance and the formulation was opaque but showed the highest curl endurance in Test Example 4. The above evaluation is The maximum score is 10 points, and the stronger the attribute is, the larger the value is displayed, and the average value is calculated. The results are shown in Tables 6 and 5 below.
[表6]
從上述表6及第5圖的結果可以確認，與含有10重量%的矽丙烯酸酯類成膜劑的比較例6相比，如同本發明提出的毛髮調理組合物，以1重量%及0.1重量%的量含有矽丙烯酸酯類成膜劑且以10:1及100:1的配合比含有具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇和矽丙烯酸酯類成膜劑的實施例1及2中，只有捲曲保持力略有降低，其餘的潤澤度、柔順度、手延展性、毛髮塗抹性、毛髮吸收性及清爽度的項目上均非常優異。From the results in Tables 6 and 5 above, it can be confirmed that, compared with Comparative Example 6 containing 10% by weight of a silicone acrylate film-forming agent, the hair conditioning composition of the present invention is 1% by weight and 0.1% by weight. The amount of% contains a silicone acrylate film-forming agent and contains a polydimethylsilanol and a silicone acrylate having an average molecular weight of 800,000 to 1.1 million g / mol in a compounding ratio of 10: 1 and 100: 1. In Examples 1 and 2 of the film-forming agent, only the curl retention was slightly reduced, and the remaining items such as moisturization, suppleness, hand extensibility, hair applicability, hair absorption, and freshness were very excellent.
尤其，可以確認，與以1重量%的量含有矽丙烯酸酯類成膜劑的實施例1相比，以0.1重量%的量含有矽丙烯酸酯類成膜劑的實施例2的捲曲保持力高，從而可以確認矽丙烯酸酯類成膜劑的量越多時，並不一定會提高捲曲保持力，並且與實施例1相比，除捲曲保持力以外，包括清爽度在內的柔順度、毛髮塗抹性、毛髮吸收度也顯示出增加的趨勢，從而能夠確認以適當的混合比含有聚二甲基矽氧烷醇和矽丙烯酸酯類成膜劑很重要。In particular, it was confirmed that the curl retention of Example 2 containing the silicone acrylate-based film-forming agent in an amount of 0.1% by weight was higher than that in Example 1 containing the silicone acrylate-based film-forming agent in an amount of 1% by weight. Therefore, it can be confirmed that the larger the amount of the silicone acrylate-based film-forming agent, the curl retention is not necessarily improved. Compared with Example 1, in addition to the curl retention, the softness and the hair including the freshness are included. Applicability and hair absorbency also show an increase, and it can be confirmed that it is important to include polydimethylsilanol and a silicone acrylate film-forming agent in an appropriate mixing ratio.
因此，可以確認本發明的實施例1及2藉由以適當的混合比含有具有80萬~110萬g/莫耳的平均分子量的聚二甲基矽氧烷醇和矽丙烯酸酯類成膜劑，並且以適當的含量含有矽丙烯酸酯類成膜劑，從而潤澤度、柔順度、手延展性、毛髮塗抹性、毛髮吸收性、清爽度等優異，而在具有非常優異的使用感的同時捲曲保持力也優異。Therefore, it can be confirmed that in Examples 1 and 2 of the present invention, a polydimethylsiloxane and a silicone acrylate film-forming agent having an average molecular weight of 800,000 to 1.1 million g / mole are contained in an appropriate mixing ratio. In addition, it contains a silicone acrylate film-forming agent in an appropriate content, so that it has excellent moisturization, suppleness, hand extensibility, hair applicability, hair absorption, and freshness, and has a very good feeling of use while maintaining curl. Power is also excellent.
無no
第1圖為示出試驗例1的賦予毛髮潤澤度的效果及潤澤度持久力評估試驗結果的圖表。FIG. 1 is a graph showing the effect of imparting moisturization to hair and the results of a moisturizing endurance evaluation test in Test Example 1. FIG.
第2圖為示出試驗例2的賦予毛髮柔順度的效果評估試驗結果的圖表。FIG. 2 is a graph showing the results of an evaluation test of the effect of imparting hair compliance to Test Example 2. FIG.
第3圖為示出試驗例3的毛髮柔順度持久力評估試驗結果的圖表。FIG. 3 is a graph showing the results of a hair compliance endurance evaluation test of Test Example 3. FIG.
第4圖為示出試驗例4的捲曲持久力評估試驗結果的圖表。FIG. 4 is a graph showing a curl endurance evaluation test result of Test Example 4. FIG.
第5圖為示出試驗例5的官能評估結果的圖表。FIG. 5 is a graph showing the results of the functional evaluation of Test Example 5. FIG.
Claims (9)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020170083039A KR20190002835A (en) | 2017-06-30 | 2017-06-30 | Hair conditioning composition |
| KR10-2017-0083039 | 2017-06-30 | ||
| ??10-2017-0083039 | 2017-06-30 |
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| Publication Number | Publication Date |
|---|---|
| TW201904559A true TW201904559A (en) | 2019-02-01 |
| TWI759502B TWI759502B (en) | 2022-04-01 |
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| TW107122846A TWI759502B (en) | 2017-06-30 | 2018-07-02 | Hair conditioning composition |
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| KR (1) | KR20190002835A (en) |
| CN (1) | CN109199911B (en) |
| TW (1) | TWI759502B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2676923B1 (en) * | 1991-06-03 | 1995-04-21 | Oreal | COMPOSITION FOR TREATING KERATINIC MATERIALS BASED ON SILICONE AND LATEX. |
| AU2001214602A1 (en) * | 2000-05-30 | 2001-12-11 | The Procter And Gamble Company | Hair conditioning composition comprising silicones and frizz control agents |
| US7758848B2 (en) * | 2004-10-22 | 2010-07-20 | L'oreal | Cosmetic composition containing a polyorganosiloxane polymer |
| US20060269499A1 (en) * | 2005-05-25 | 2006-11-30 | Grant Industries, Inc. | Substantive anionic silicone oil emulsion compositions for hair and skin conditioning |
| FR2932985B1 (en) * | 2008-06-25 | 2011-03-18 | Chanel Parfums Beaute | COSMETIC COMPOSITION COMPRISING ACRYLATE SILICONE AND POLYESTER WAX. |
| BR112012008808B8 (en) * | 2009-11-06 | 2023-09-26 | Avon Prod Inc | Method to prevent or reduce the frizzy appearance of hair |
| US8592376B2 (en) * | 2011-12-06 | 2013-11-26 | Avon Products, Inc | Hair care compositions |
-
2017
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2018
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| CN109199911B (en) | 2022-11-04 |
| TWI759502B (en) | 2022-04-01 |
| KR20190002835A (en) | 2019-01-09 |
| CN109199911A (en) | 2019-01-15 |
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