TWI776023B

TWI776023B - Hair conditioning composition

Info

Publication number: TWI776023B
Application number: TW108106349A
Authority: TW
Inventors: 金旼珍; 李京美; 賓聖娥; 崔壯源
Original assignee: 南韓商愛茉莉太平洋股份有限公司
Priority date: 2018-02-28
Filing date: 2019-02-25
Publication date: 2022-09-01
Also published as: TW201936168A; KR20190103949A

Abstract

本發明涉及一種毛髮調理組合物，更詳細而言，涉及一種含有高分子聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物作為有效成分，並提高毛髮的光澤度、柔順度以及光滑度的持久力的毛髮調理組合物，較佳為涉及一種受損毛髮的調理組合物。The present invention relates to a hair conditioning composition, in more detail, to a composition containing high molecular polydimethylsiloxane and linear siloxane compounds as active ingredients, which can improve the gloss, softness and smoothness of hair. A hair conditioning composition for smoothness staying power, preferably a conditioning composition for damaged hair.

Description

毛髮調理組合物hair conditioning composition

通常，賦予毛髮調理感（改善毛髮狀態）的產品可以分為需要清洗類型的產品（沖洗類產品）和不需要清洗類型的產品（免洗類產品）。需要清洗的產品可以分為護髮素、焗油劑、護髮膜(hair pack)、髮膜(hair mask)、頭髮精華素等，主要藉由在乳化劑型中含有四級陽離子表面活性劑以及少量的矽油或者合成油、天然油類等調理成分，對毛髮賦予光澤度和光滑度。In general, products that impart a conditioning feel to the hair (improvement of hair condition) can be divided into products that require washing (rinse-in products) and products that do not require washing (leave-in products). Products that need to be cleaned can be divided into conditioners, oils, hair packs, hair masks, hair essences, etc., mainly by containing quaternary cationic surfactants and a small amount of cationic surfactants in the emulsion formulation. Conditioning ingredients such as silicone oil or synthetic oil, natural oil, etc., impart luster and smoothness to the hair.

免洗類產品可以分為頭髮噴霧、亮髮素、護髮精華液、髮油等，藉由多種劑型賦予毛髮調理效果。Leave-in products can be divided into hair spray, hair brightener, hair conditioner, hair oil, etc., which can impart hair conditioning effects through a variety of formulations.

對免洗類的毛髮調理組合物中使用的矽油而言，根據其種類或者分子量而具有多種功能，由此，即便具有相同化學結構的矽油，也會顯示出多種使用感特性。根據分子量以及黏度，矽顯示出多種形態，從分子量以及黏度最低的揮發性形態到分子量以及黏度增大的順序顯示為液體、有黏性的液體、黏膠(Gum)、凝膠、彈性體及樹脂的形態。即，矽的分子量增加時，黏性也會增加。Silicon oils used in leave-on hair conditioning compositions have various functions depending on their types or molecular weights, and therefore, silicone oils with the same chemical structure exhibit various properties of feeling in use. According to molecular weight and viscosity, silicon exhibits various forms, from the volatile form with the lowest molecular weight and viscosity to the liquid, viscous liquid, glue (Gum), gel, elastomer and the order of increasing molecular weight and viscosity. form of resin. That is, as the molecular weight of silicon increases, the viscosity also increases.

在所述免洗類產品中，尤其護髮精華液是過量的矽油被分散的劑型，當用在毛髮上時，可以立即賦予光澤度和光滑度，但是存在因過量的矽油導致使用上的黏膩感、毛髮的黏糊感等缺點的問題。Among the leave-in products, especially the hair care essence is a formulation in which excess silicone oil is dispersed. When used on the hair, it can immediately impart gloss and smoothness, but there is stickiness caused by excess silicone oil. Problems such as greasy feeling and stickiness of hair.

另外，習知毛髮調理組合物（劑型）雖然可以立即賦予毛髮光澤度和光滑度，但是其持久力短且在手和毛髮上會感覺到油膩（Oily）的殘留感。習知技術為了完善所述問題，使用了過量的矽油以及揮發性矽油、清爽使用感的潤滑劑等，然而其效果不能持續很久，而且引起使用上的黏膩感以及毛髮的厚重下垂等問題（參考專利文獻1和2）。In addition, although conventional hair conditioning compositions (formulations) can impart gloss and smoothness to the hair immediately, they have short staying power and feel an oily residual feeling on hands and hair. In order to solve the above-mentioned problems, the conventional technology uses excessive amount of silicone oil, volatile silicone oil, lubricants with refreshing use feeling, etc., but the effect cannot last for a long time, and causes problems such as sticky feeling and heavy sagging of hair ( Refer to Patent Documents 1 and 2).

習知技術文獻專利文獻（專利文獻1）韓國公開專利第10-2013-0049305號（2013.05.14）（專利文獻2）韓國公開專利特2001-0024126（2001.03.26）Known technical literature Patent Literature (Patent Document 1) Korean Patent Publication No. 10-2013-0049305 (2013.05.14) (Patent Document 2) Korean Laid-Open Patent Publication No. 2001-0024126 (2001.03.26)

本發明的目的在於，提供一種顯著提高毛髮的光澤度、柔順度以及光滑度的持久力的毛髮調理組合物，較佳為提供一種受損毛髮的調理組合物。The purpose of the present invention is to provide a hair conditioning composition that significantly improves the gloss, softness and smoothness of hair, and preferably provides a conditioning composition for damaged hair.

本發明的其他目的在於，提供一種由所述組合物製造的化妝品。Another object of the present invention is to provide a cosmetic produced from the composition.

在上述技術背景之下，為了達成所述目的，本說明書的發明人為了開發提高毛髮調理功效（提高毛髮的光澤度、柔順度、光滑度等）的持久力的組合物而不懈努力的結果，確認到在毛髮調理組合物中，如果使用低含量的高分子聚二甲基矽氧烷醇和直鏈型矽氧烷類化合物（較佳為三矽氧烷）作為有效成分，則可以顯著提高毛髮的光澤度、柔順度以及光滑度的持久力，由此完成了本發明。Under the above technical background, in order to achieve the above object, the inventors of the present specification have made unremitting efforts to develop a composition that improves the lasting power of hair conditioning effects (improving hair gloss, softness, smoothness, etc.), It was confirmed that in the hair conditioning composition, if a low content of high molecular polydimethylsiloxane and linear siloxane compounds (preferably trisiloxane) are used as active ingredients, the hair can be significantly improved. The gloss, suppleness and smoothness of the staying power, thus completing the present invention.

為此，本發明提供毛髮調理組合物，其為含有聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物作為有效成分的毛髮調理組合物，其特徵在於：所述聚二甲基矽氧烷醇的平均分子量（莫耳質量（molar mass, M））為60萬~130萬g/mol，較佳為70萬~120萬g/mol，最佳為80萬~110萬g/mol。Therefore, the present invention provides a hair conditioning composition, which is a hair conditioning composition containing polydimethylsiloxane and a linear siloxane compound as active ingredients, characterized in that: the polydimethylsiloxane is characterized in that: The average molecular weight (molar mass, M) of the siloxanol is 600,000 to 1.3 million g/mol, preferably 700,000 to 1.2 million g/mol, and most preferably 800,000 to 1.1 million g/mol mol.

另外，本發明提供一種聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的混合物在毛髮調理化妝料組合物或者化妝品的製造中的應用，更加準確而言，作為毛髮調理增進劑的應用。所述聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。In addition, the present invention provides the application of a mixture of polydimethylsiloxane and linear siloxane compounds in the manufacture of hair conditioning cosmetic compositions or cosmetics, more precisely, as a hair conditioning enhancer Applications. The average molecular weight of the polydimethylsiloxane is 600,000-1,300,000 g/mol.

根據本發明的毛髮調理組合物向毛髮（尤其，受損毛髮）賦予光澤度和柔順度的同時，黏膩感少，具有清爽和塗抹光潤的特性，可以向使用者提供優秀的使用感。The hair conditioning composition according to the present invention imparts gloss and softness to the hair (especially, damaged hair), has low stickiness, has the characteristics of freshness and smooth application, and can provide the user with an excellent feeling of use.

未作其他定義時，本說明書中使用的所有技術以及科學術語具有與所屬技術領域具有通常知識者通常所理解的含義相同的含義。通常，本說明書中使用的命名法是在本技術領域中所熟知且通常使用的。Unless otherwise defined, all technical and scientific terms used in this specification have the same meanings as commonly understood by those of ordinary skill in the art. In general, the nomenclature used in this specification is well known and commonly used in the art.

以下，針對本發明進行更加詳細的說明。Hereinafter, the present invention will be described in more detail.

在本說明書中，在表示濃度、含量、長度、面積、體積、溫度、角度、時間（期間）等中使用的術語“約”是指在該數值或者數值範圍中最大存在10%的容許誤差。In this specification, the term "about" used in expressing concentration, content, length, area, volume, temperature, angle, time (period), etc., means that there is a maximum allowable error of 10% in the value or value range.

本發明的一思想在於，An idea of the present invention is that,

涉及一種毛髮調理組合物，較佳為涉及一種受損毛髮的調理組合物，其為含有聚二甲基矽氧烷醇（dimethiconol）以及直鏈型矽氧烷類化合物作為有效成分的毛髮調理組合物，其特徵在於，所述聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。It relates to a hair conditioning composition, preferably a conditioning composition for damaged hair, which is a hair conditioning composition containing polydimethylsiloxane (dimethiconol) and a linear silicone compound as active ingredients It is characterized in that the average molecular weight of the polydimethylsiloxane is 600,000 to 1,300,000 g/mol.

在本發明中，所述聚二甲基矽氧烷醇的平均分子量較佳為70萬~120萬g/mol，最佳為80萬~110萬g/mol。如果所述聚二甲基矽氧烷醇的平均分子量不足60萬g/mol，則具有毛髮塗層的持久力低下的問題，如果所述聚二甲基矽氧烷醇的平均分子量超過130萬g/mol，則在毛髮塗層的持久效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, the average molecular weight of the polydimethylsiloxane is preferably 700,000 to 1.2 million g/mol, and the best is 800,000 to 1.1 million g/mol. If the average molecular weight of the dimethiconol is less than 600,000 g/mol, there is a problem that the staying power of the hair coating is low, and if the average molecular weight of the dimethiconol exceeds 1.3 million g/mol, the long-lasting effect of the hair coating is not greatly increased, but the feeling of use is reduced. Therefore, it is preferable to use it appropriately within the above-mentioned range.

在本發明中，所述直鏈型矽氧烷類化合物可以選自由三矽氧烷（trisiloxane）、二矽氧烷（disiloxane）以及聚二甲基矽氧烷（dimethicone）而成的群中的一種以上，但是並不局限於此，較佳為三矽氧烷以及聚二甲基矽氧烷。In the present invention, the linear siloxane compound may be selected from the group consisting of trisiloxane, disiloxane and dimethicone. More than one, but not limited thereto, preferably trisiloxane and polydimethylsiloxane.

在本發明中，所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的混合比按照重量基準為5.1~34.9:1.0~27.5，較佳為12.0~32.0：5.0~25.0，最佳為16.0~24.0：6.0~10.0。In the present invention, the mixing ratio of the polydimethylsiloxane alcohol and the straight-chain siloxane compound is 5.1-34.9:1.0-27.5 on a weight basis, preferably 12.0-32.0:5.0-25.0, The best is 16.0~24.0: 6.0~10.0.

當超過所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物（例如，三矽氧烷）的混合比（重量比）範圍時，所述組合物其毛髮的光澤度、柔順度以及光滑度的持久力改善效果有可能會降低。When the mixing ratio (weight ratio) of the polydimethylsiloxane alcohol and the linear siloxane compound (eg, trisiloxane) exceeds the range of the composition, the hair gloss, softness and smoothness of the composition are improved. The effect of improving the staying power of smoothness and smoothness may be reduced.

在本發明中，在保持所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的重量比的狀態下，所述組合物中所含的聚二甲基矽氧烷醇的含量為5.1~34.9重量%，較佳為12.0~32.0重量%，最佳為16.0~24.0重量%。如果所述聚二甲基矽氧烷醇的含量不足5.1重量%，則具有毛髮調理效果低下的問題，如果所述聚二甲基矽氧烷醇的含量超過34.9重量%，則在毛髮調理效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, in a state where the weight ratio of the polydimethylsiloxanol and the linear siloxane compound is maintained, the content of the polydimethylsiloxane contained in the composition is The content is 5.1 to 34.9% by weight, preferably 12.0 to 32.0% by weight, and most preferably 16.0 to 24.0% by weight. If the content of the dimethiconol is less than 5.1 wt %, there is a problem that the hair conditioning effect is low, and if the content of the dimethiconol exceeds 34.9 wt %, the hair conditioning effect will be reduced. There is no large increase in the above, but the feeling of use is reduced, and therefore, it is preferable to use it appropriately within the above-mentioned range.

在本發明中，在保持所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的重量比的狀態下，所述組合物中所含的直鏈型矽氧烷類化合物的含量為1.0~27.5重量%，較佳為5.0~25.0重量%，最佳為6.0~10.0重量%。如果所述直鏈型矽氧烷類化合物的含量不足1.0重量%，則具有黏膩感改善效果低下的問題，如果所述直鏈型矽氧烷類化合物的含量超過27.5重量%，則在黏膩感改善效果上沒有大的增加，反而使用感降低，因此，較佳在所述範圍內適當使用。In the present invention, in a state where the weight ratio of the polydimethylsiloxane alcohol and the linear siloxane compound is maintained, the amount of the linear siloxane compound contained in the composition is The content is 1.0 to 27.5% by weight, preferably 5.0 to 25.0% by weight, and most preferably 6.0 to 10.0% by weight. If the content of the linear siloxane-based compound is less than 1.0 wt %, there is a problem that the effect of improving the stickiness is low, and if the content of the linear siloxane-based compound exceeds 27.5 wt %, the tackiness There is no significant increase in the effect of improving the greasy feeling, but the feeling of use is reduced, so it is preferable to use it appropriately within the above-mentioned range.

在本發明中，所述組合物可以進一步包括選自由2-辛基十二醇肉豆蔻酸酯（2-Octyldodecyl Myristate）、肉豆蔻酸異丙酯（Isopropyl Myristate）、C12-15烷基苯甲酸酯（C12-15 Alkyl Benzoate）、棕櫚酸異丙酯（Isopropyl Palmitate）、丁基辛醇水楊酸酯（Butyloctyl Salicylate）、鯨蠟醇乙基己酸酯（Cetyl Ethylhexanoate）、棕櫚酸乙基己酯（Ethylhexyl Palmitate）、碳酸二辛酯（Dicaprylyl Carbonate）以及椰油醇-辛酸酯/葵酸酯（Coco-Caprylate/Caprate）而成的群中的一種以上的酯類油（Ester Oil），但並不局限於此，優選為進一步包括碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物。In the present invention, the composition may further comprise selected from 2-Octyldodecyl Myristate, Isopropyl Myristate, C12-15 Alkyl Benzene C12-15 Alkyl Benzoate, Isopropyl Palmitate, Butyloctyl Salicylate, Cetyl Ethylhexanoate, Ethyl Palmitate Ester Oil (Ester Oil) of one or more of the group consisting of Ethylhexyl Palmitate, Dicaprylyl Carbonate and Coco-Caprylate/Caprate , but not limited thereto, preferably a mixture further comprising dioctyl carbonate and coco-octanoate/caprate.

在本發明中，所述組合物中所含的酯類油的含量為3.0~25.0重量%，較佳為4.0~22.0重量%，最佳為18.0~22.0重量%。如果所述酯類油的含量不足3.0重量%，則具有毛髮調理保持效果低下的問題，如果所述酯類油的含量超過25.0重量%，則在毛髮調理保持效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the ester oil contained in the composition is 3.0-25.0 wt %, preferably 4.0-22.0 wt %, and most preferably 18.0-22.0 wt %. If the content of the ester oil is less than 3.0 wt %, there is a problem that the hair conditioning and maintenance effect is low, and if the content of the ester oil exceeds 25.0 wt %, the hair conditioning and maintenance effect is not greatly increased. Since the feeling is reduced, it is preferable to use it appropriately within the above-mentioned range.

在本發明中，所述組合物可以進一步包括選自由荷荷巴油（Jojoba oil）、葵花籽油、蓖麻油、橄欖油、椰子油、深海兩節薺籽油（Crambe Abyssinica seed oil）以及豆油（例如，黑豆油）而成的群中的一種以上的植物油，但並不局限於此，較佳為荷荷巴油、椰子油、深海兩節薺籽油以及黑豆油，最佳為進一步含有荷荷巴油。In the present invention, the composition may further comprise selected from Jojoba oil, sunflower oil, castor oil, olive oil, coconut oil, Crambe Abyssinica seed oil and soybean oil (for example, black soybean oil) one or more vegetable oils in the group, but not limited to this, preferably jojoba oil, coconut oil, camelina seed oil and black soybean oil, and most preferably further contains Jojoba oil.

在本發明中，所述組合物中所含的植物油的含量為0.05~7.0重量%，較佳為0.1~6.5重量%，最佳為4.0~6.0重量%。如果所述植物油的含量不足0.05重量%，則具有毛髮調理保持效果低下的問題，如果所述植物油的含量超過7.0重量%，則在毛髮調理保持效果上沒有大的增加，反而增加劑型的不穩定性，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the vegetable oil contained in the composition is 0.05-7.0% by weight, preferably 0.1-6.5% by weight, and most preferably 4.0-6.0% by weight. If the content of the vegetable oil is less than 0.05 wt %, there is a problem that the hair conditioning and maintenance effect is low. If the content of the vegetable oil exceeds 7.0 wt %, the hair conditioning and maintenance effect is not greatly increased, but the instability of the formulation is increased. Therefore, it is preferable to use it appropriately within the above-mentioned range.

在本發明中，所述組合物可以進一步含有環狀矽氧烷類化合物，所述環狀矽氧烷類化合物可以是環聚二甲基矽氧烷（Cyclomethicone），優選為環三聚二甲基矽氧烷（Cyclotrisiloxane）、環四聚二甲基矽氧烷（Cyclotetrasiloxane）、環五聚二甲基矽氧烷（Cyclopentasiloxane）、環己矽氧烷（Cyclohexasiloxane）、環庚矽氧烷（Cycloheptasiloxane）或者其混合物，但並不局限於此，最佳為環五聚二甲基矽氧烷以及環己矽氧烷的混合物。In the present invention, the composition may further contain a cyclosiloxane compound, and the cyclosiloxane compound may be cyclomethicone, preferably cyclotrimethicone Cyclotrisiloxane, Cyclotetrasiloxane, Cyclopentasiloxane, Cyclohexasiloxane, Cycloheptasiloxane ) or a mixture thereof, but not limited thereto, the most preferred is a mixture of cyclopentasiloxane and cyclohexylsiloxane.

在本發明中，所述組合物中所含的環狀矽氧烷類化合物的含量為21.5~78.5重量%，較佳為22.0~38.0重量%，最佳為24.0~26.0重量%。如果所述環狀矽氧烷類化合物的含量不足21.5重量%，則具有清爽的使用感低下的問題，如果所述環狀矽氧烷類化合物的含量超過78.5重量%，則在效果上沒有大的增加，反而柔順使用感的持久力會降低，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the cyclic siloxane compound contained in the composition is 21.5-78.5 wt %, preferably 22.0-38.0 wt %, and most preferably 24.0-26.0 wt %. If the content of the cyclosiloxane-based compound is less than 21.5% by weight, there is a problem that the refreshing feeling in use is reduced, and when the content of the cyclosiloxane-based compound exceeds 78.5% by weight, the effect is not large. The increase of , on the contrary, the lasting power of the smooth feeling of use will decrease, so it is better to use it appropriately within the above range.

在本發明中，所述聚二甲基矽氧烷醇的黏度為6萬~16萬cs，較佳為6萬5千~15萬cs，最佳為7萬7千~14萬cs。如果所述聚二甲基矽氧烷醇的黏度不足6萬cs，則具有毛髮塗層的持久力低下的問題，如果所述聚二甲基矽氧烷醇的黏度超過16萬cs，則在效果上沒有大的增加，反而增加劑型的不穩定性，因此，較佳為在所述範圍內適當使用。In the present invention, the viscosity of the polydimethylsiloxane is 60,000-160,000 cs, preferably 65,000-150,000 cs, and most preferably 77,000-140,000 cs. If the viscosity of the dimethiconol is less than 60,000 cs, there is a problem that the staying power of the hair coating is lowered, and if the viscosity of the polydimethylsiloxanol exceeds 160,000 cs, the The effect is not greatly increased, but rather the instability of the dosage form is increased. Therefore, it is preferable to use it appropriately within the above-mentioned range.

在本發明中，所述直鏈型矽氧烷類化合物的黏度可以為0.5~2.5cs，較佳為0.65~2.0cs，最佳為1.0~1.5cs。所述直鏈型矽氧烷類化合物的黏度範圍為用於保持直鏈型矽氧烷類化合物的揮發性的黏度範圍，較佳為在所述範圍內適當使用。In the present invention, the viscosity of the straight-chain siloxane compound may be 0.5-2.5cs, preferably 0.65-2.0cs, and most preferably 1.0-1.5cs. The viscosity range of the linear siloxane-based compound is a viscosity range for maintaining the volatility of the linear-chain siloxane-based compound, and it is preferable to use it appropriately within the range.

在本發明中，所述環狀矽氧烷類化合物的黏度可以為3.0~5.0cs，較佳為3.2~4.8cs，最佳為3.5~4.5cs。所述環狀矽氧烷類化合物的黏度範圍為用於保持環狀矽氧烷類化合物的揮發性的黏度範圍，較佳為在所述範圍內適當使用。In the present invention, the viscosity of the cyclosiloxane compound may be 3.0-5.0cs, preferably 3.2-4.8cs, and most preferably 3.5-4.5cs. The viscosity range of the cyclosiloxane compound is a viscosity range for maintaining the volatility of the cyclosiloxane compound, and it is preferable to use it appropriately within the range.

所述聚二甲基矽氧烷醇、直鏈型矽氧烷類化合物（例如，三矽氧烷等）以及環狀矽氧烷類化合物（例如，環聚二甲基矽氧烷等）各自的黏度是基於如下結果的黏度，即用LVT模型黏度計（博勒飛工程實驗室：Brookfield Engineering Laboratories, Inc.）在30rpm的轉速下利用4號轉子杆（Spindle bar）在常溫下測定1分鐘的結果。The polydimethylsiloxanes, linear siloxanes (eg, trisiloxane, etc.), and cyclic siloxanes (eg, cyclodimethylsiloxane, etc.) are each The viscosities are those based on the results measured with an LVT model viscometer (Brookfield Engineering Laboratories, Inc.) at 30 rpm for 1 minute at room temperature with a No. 4 Spindle bar the result of.

所述聚二甲基矽氧烷醇、直鏈型矽氧烷類化合物（例如，三矽氧烷等）以及環狀矽氧烷類化合物（例如，環聚二甲基矽氧烷）各自的穩定度是基於如下評價結果的穩定度，即為了在惡劣環境下進行評價，在60℃的恆溫槽條件或者將溫度範圍以-15℃~45℃每12小時進行變更的溫度循環條件下，一周期間觀察乳化穩定度，確認穩定、稍微不穩定、水相部分/油相部分的分離與否，從而評價乳化穩定度（數據未圖示）。The respective polydimethylsiloxanes, linear siloxanes (eg, trisiloxane, etc.), and cyclic siloxanes (eg, cyclodimethylsiloxane) The stability is the stability based on the evaluation results of one week under a constant temperature bath condition of 60°C or a temperature cycle in which the temperature range is changed from -15°C to 45°C every 12 hours for evaluation in a harsh environment. During the period, the emulsion stability was observed, and the stability, slight instability, and separation of the water phase part and the oil phase part were confirmed to evaluate the emulsion stability (data not shown).

在本發明中，所述組合物考慮到化妝品安全有關規則中的使用限量，可以進一步包括保濕劑（多元醇等）、蠟、黏度調節劑、增黏劑、pH調節劑、脂肪、有機溶劑、溶解劑、濃縮劑、凝膠劑、軟化劑、抗氧化劑、懸浮劑、穩定劑、發泡劑（foaming agent）、芳香劑、表面活性劑、水、離子型乳化劑、非離子型乳化劑、填充劑、金屬離子封鎖劑、螯合劑、保存劑、維生素、潤濕劑、染料、顏料、親水性活性劑、親油性活性劑、脂囊泡或者與化妝品中通常使用的任意其他成分相同的化妝品學或者皮膚科學領域中通常使用的助劑。另外，本發明的組合物為了增加皮膚狀態改善效果，可以進一步包括皮膚吸收促進物質。In the present invention, the composition may further include moisturizing agents (polyols, etc.), waxes, viscosity modifiers, tackifiers, pH modifiers, fats, organic solvents, Dissolving agents, concentrates, gelling agents, softeners, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, surfactants, water, ionic emulsifiers, nonionic emulsifiers, Fillers, metal ion blockers, chelating agents, preservatives, vitamins, humectants, dyes, pigments, hydrophilic actives, lipophilic actives, lipid vesicles, or any other ingredient commonly used in cosmetic products Adjuvants commonly used in the field of dermatology or dermatology. In addition, the composition of the present invention may further include a skin absorption promoting substance in order to increase the skin condition improving effect.

在本發明中，所述組合物為了向皮膚以及/或者毛髮賦予有用的功能性，進一步包括適當含量的甘油等保濕成分、抗氧化劑等抗氧化/抗老化成分、酪氨酸酶抑制劑、角質再生促進劑等美白成分、紫外線遮擋劑等保護成分、透明質酸、膠原蛋白、彈性蛋白等傷口治療成分、消炎劑等含鹽成分等，從而能夠向皮膚以及/或者毛髮賦予保濕、抗老化、美白、保護、傷口治療等功效，但並不局限於此。In the present invention, the composition further includes a moisturizing ingredient such as glycerin, an antioxidant/antiaging ingredient such as an antioxidant, a tyrosinase inhibitor, a keratin, and a suitable content in order to impart useful functionality to the skin and/or hair. Whitening ingredients such as regeneration accelerators, protective ingredients such as ultraviolet shielding agents, wound healing ingredients such as hyaluronic acid, collagen, and elastin, and salt-containing ingredients such as anti-inflammatory agents, etc., can impart moisturizing, anti-aging, Whitening, protection, wound treatment and other effects, but not limited to this.

在本發明中，所述組合物的特徵在於，可以提高毛髮，較佳為提高受損毛髮的調理（毛髮的光澤度、柔順度以及光滑度的程度以及持續期間等）。In the present invention, the composition is characterized in that it improves the conditioning of the hair, preferably damaged hair (the degree of gloss, suppleness and smoothness of the hair and the duration, etc.).

在本發明中，所述毛髮可以是包括人類的哺乳類身體中任意的毛髮或者毛，例如頭髮、眉毛、睫毛、髭、須、胸毛、後背毛、胳膊毛、腿毛、生殖器毛、鼻毛或者耳毛，但並不局限於此。In the present invention, the hair may be any hair or hair in mammalian bodies including humans, such as hair, eyebrows, eyelashes, mustache, beard, chest hair, back hair, arm hair, leg hair, genital hair, nose hair, or ear hair Mao, but not limited to this.

在本發明中，所述受損毛髮可以是因選自由染色以及燙髮而成的群中的一種以上的化學處理、物理損傷、壓力或者缺乏營養導致的受損毛髮，但並不局限於此。In the present invention, the damaged hair may be damaged hair caused by one or more chemical treatments selected from the group consisting of dyeing and perming, physical damage, stress or lack of nutrition, but is not limited thereto.

在本發明中，所述組合物在劑型方面並未有特別限定，可以是具有軟膏、護髮水、護髮霜、護髮膜、頭髮營養液、護髮乳、焗油劑、頭皮護理劑、洗髮水、護髮素、髮蠟（pomade）等劑型的具有化妝品學用途的組合物。所述各個劑型的組合物根據所述各種劑型或者為了符合最終目的，可以包括在通常的化妝料組合物中調配的各種成分，所述成分的種類和劑量可以由所屬技術領域具有通常知識者容易選定。例如，作為在所述組合物中調配的成分，可以使用油脂成分、保濕劑、潤滑劑、表面活性劑、有機以及無機顏料、有機粉體、紫外線吸收劑、防腐劑、殺菌劑、防氧化劑、植物萃取物、pH調節劑、乙醇、色素、香料、血液循環促進劑、涼爽劑、止汗劑、淨化水等。In the present invention, the composition is not particularly limited in terms of dosage form, and can be ointment, hair care lotion, hair care cream, hair care film, hair nutrient solution, hair care milk, baking oil, scalp care agent, Compositions for cosmetic use in the form of shampoos, conditioners, pomades and the like. The composition of the respective dosage forms may include various ingredients formulated in ordinary cosmetic compositions according to the respective dosage forms or in order to meet the final purpose, and the kinds and doses of the ingredients can be easily determined by those with ordinary knowledge in the art. selected. For example, as components to be formulated in the composition, oil and fat components, humectants, lubricants, surfactants, organic and inorganic pigments, organic powders, ultraviolet absorbers, antiseptics, bactericides, antioxidants, Plant extracts, pH adjusters, ethanol, pigments, fragrances, blood circulation enhancers, cooling agents, antiperspirants, purified water, etc.

以下，藉由實施例更加詳細說明本發明。所述實施例僅用於示例本發明，所屬技術領域具有通常知識者應理解本發明的範圍並不由所述實施例而受限。Hereinafter, the present invention will be described in more detail by way of examples. The embodiments are only used to illustrate the present invention, and those skilled in the art should understand that the scope of the present invention is not limited by the embodiments.

參考例：毛髮調理組合物的製造Reference example: Manufacture of hair conditioning composition

製造出具有下表1以及表2的組成和含量的毛髮調理組合物。其中，高分子聚二甲基矽氧烷醇具有80萬~110萬g/mol的平均分子量，低分子聚二甲基矽氧烷醇具有45萬~59萬g/mol的平均分子量。Hair conditioning compositions having the composition and content of Table 1 below and Table 2 were produced. Among them, the high molecular polydimethylsiloxanol has an average molecular weight of 800,000 to 1.1 million g/mol, and the low molecular polydimethylsiloxane has an average molecular weight of 450,000 to 590,000 g/mol.

下列表1以及表2顯示毛髮調理組合物的組成（單位：重量%）。Table 1 and Table 2 below show the composition (unit: % by weight) of the hair conditioning composition.

表1

Table 1

表2

Table 2

實驗例1：毛髮的光澤度持久力評價Experimental Example 1: Evaluation of Hair Gloss Persistence

向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的光澤度持久力（塗層力）進行了評價。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above reference examples was applied to the hair, and then the gloss staying power (coating power) of the hair was measured and evaluated as follows.

＜毛髮的光澤度持久力測定方法＞<Measuring method of glossiness endurance of hair>

實驗對象：test subject:

（1）正常毛髮：標準毛髮，約10cm長度的正常黑毛（髮辮，BM-B10，Beaulax公司，日本）(1) Normal hair: standard hair, normal black hair about 10cm in length (braid, BM-B10, Beaulax, Japan)

（2）受損的乾燥毛髮：將所述正常毛髮用脫色劑進行脫色處理約30分鐘，然後用洗髮水進行處理後，在約30℃的溫度下用水沖洗3分鐘，進行乾燥準備的受損的乾燥毛髮。(2) Damaged dry hair: The normal hair is decolorized with a decolorizing agent for about 30 minutes, then treated with shampoo, rinsed with water at a temperature of about 30°C for 3 minutes, and the damaged hair is prepared for drying of dry hair.

實驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用SAMBA儀器（SAMBA毛髮系統（SAMBA Hair system），Bossa Nova Technologies公司），隨時間（塗抹後即刻，經過1、2、3小時之後）測定毛髮表面的光澤度程度。其中，毛髮的光澤度持久力是藉由隨時間測定毛髮基於光照射角度（-45°~+45°）的光的最大反射量而得出的。The tresses (normal hair or damaged dry hair) used in the experiment were washed with basic shampoo without conditioning effect, rinsed with water for about 1 minute, then dried for about 5 minutes, and then applied the composition (Example 1~ 6 and Comparative Examples 1 to 8), and then using a SAMBA instrument (SAMBA Hair system, Bossa Nova Technologies), the gloss of the hair surface was measured over time (immediately after application, after 1, 2, and 3 hours). degree. Among them, the gloss staying power of the hair is obtained by measuring the maximum reflection amount of the light based on the light irradiation angle (-45°~+45°) of the hair over time.

其結果，如下表3以及第1圖中所示，確認到：As a result, as shown in Table 3 and Figure 1 below, it was confirmed that:

①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的光澤度程度較高，①Compared with the composition containing low-molecular-weight polydimethylsiloxane as the main component (comparative example 1), the composition containing high-molecular-weight polydimethylsiloxane as the main component (comparative example 3) has Immediately after application, the hair has a high degree of gloss,

②比起作為主成分含有低分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例1），作為主成分含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有作為酯類油的碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和作為植物油的荷荷巴油的組合物（比較例2）其在塗抹後即刻，毛髮的光澤度程度較高，②Compared with the composition containing low molecular weight polydimethylsiloxane as the main component and not containing dioctyl carbonate, coco-octanoate/caprate mixture and jojoba oil (Comparative example 1), contains low molecular weight polydimethylsiloxane as the main component, and contains dioctyl carbonate as ester oil and mixture of coco-octanoate/caprate and vegetable oil The composition of jojoba oil (Comparative Example 2) immediately after application, the degree of glossiness of the hair is high,

③比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1、5以及6）其在塗抹後即刻，毛髮的光澤度程度長時間較高。③Compared to contain high molecular polydimethylsiloxane as the main component, and do not contain trisiloxane, dioctyl carbonate, mixture of coco-octanoate/caprate and jojoba oil A composition (Comparative Example 3) containing a high molecular weight polydimethylsiloxane as a main component, and containing trisiloxane, dioctyl carbonate, and coco-octanoate/caprate as constituent components The combination of the mixture and jojoba oil (Examples 1, 5 and 6) showed a higher level of gloss on the hair immediately after application.

一方面，確認到比起實施例1、5以及6的組合物，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油，而且不含有三矽氧烷的組合物（比較例4）其在塗抹後即刻，毛髮的光澤度程度較低（未提供數據）。On the other hand, compared with the compositions of Examples 1, 5, and 6, it was confirmed that polymer polydimethylsiloxane was contained as the main component, and dioctyl carbonate and coco-octanoate were contained as the composition components. The combination of /caprate and jojoba oil, and the composition without trisiloxane (Comparative Example 4), gave less gloss to the hair immediately after application (data not provided).

與此不同地，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例2、3以及4）與基於實施例1的組合物類似，在塗抹後即刻，毛髮的光澤度程度長時間顯示較高（未提供數據）。On the other hand, it contains high-molecular polydimethylsiloxane as the main component, and contains trisiloxane, dioctyl carbonate, a mixture of coco-octanoate/caprate and charge as components. The compositions of jojoba oil (Examples 2, 3 and 4) were similar to the compositions based on Example 1, and immediately after application, the level of gloss of the hair was shown to be higher over time (data not provided).

另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的光澤度持久力的結果，可以獲得如下表3以及與基於第1圖的實施例1的組合物的結果類似的結果（未提供數據）。In addition, the results of evaluating the gloss staying power of the hair when the compositions based on Examples 1, 2, 3, 4, 5 and 6 were applied to the damaged dry hair, the following Table 3 and Similar results were obtained for the composition of Example 1 of Figure 1 (data not provided).

綜合所述結果，確認到一同含有本發明中規定的含量作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮光澤度持久力。Based on the above results, it was confirmed that the polymer polydimethylsiloxane alcohol as the main component and trisiloxane, dioctyl carbonate, and coco-octanoate as the constituent components are contained together in the content specified in the present invention. A combination of caprate/caprate and jojoba oil, which showed the best hair gloss staying power.

以下表3是顯示在毛髮塗抹毛髮調理組合物前後，隨著時間測定正常毛髮的光澤度持久力的結果（單位：%）。Table 3 below shows the results (unit: %) of measuring the gloss staying power of normal hair over time before and after application of the hair conditioning composition to the hair.

表3

table 3

實驗例2：毛髮的柔順度評價Experimental Example 2: Evaluation of Softness of Hair

向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的柔順度（柔軟性）程度進行了評價。The hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above reference examples were applied to the hair, and the degree of softness (softness) of the hair was measured and evaluated as follows.

＜毛髮的柔順度程度測定方法＞<Method for measuring the degree of softness of hair>

實驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用MTT175儀器（小型拉伸試驗儀器（Miniature Tensile Tester）,Dia-Stron公司），測定毛髮的柔順度程度。其中，毛髮的柔順度程度是將相對於對照組試料的毛髮梳理時的阻力用gmf值進行數值化而得出的，毛髮的阻力值越小，代表毛髮沒有亂成一團而保持柔順狀態。The tresses used in the experiment (normal hair or damaged dry hair; refer to Experimental Example 1) were washed with a basic shampoo without conditioning effect, rinsed with water for about 1 minute, then dried for about 5 minutes, and then the composition was applied. (Examples 1 to 6 and Comparative Examples 1 to 8), the degree of softness of the hair was measured using an MTT175 instrument (Miniature Tensile Tester, Dia-Stron). Among them, the degree of softness of the hair is obtained by quantifying the resistance when combing the hair of the control sample with the gmf value.

其結果，如下表4以及第2圖所示，確認到：As a result, as shown in Table 4 and Fig. 2 below, it was confirmed that:

①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的柔順度程度較高，①Compared with the composition containing low-molecular-weight polydimethylsiloxane as the main component (comparative example 1), the composition containing high-molecular-weight polydimethylsiloxane as the main component (comparative example 3) has Immediately after application, the degree of softness of the hair is high,

②比起作為主成分含有低分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例1），作為主成分含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例2）其在塗抹後即刻，毛髮的柔順度程度較高，②Compared with the composition containing low molecular weight polydimethylsiloxane as the main component and not containing dioctyl carbonate, coco-octanoate/caprate mixture and jojoba oil (Comparative example 1), a composition containing low-molecular-weight polydimethylsiloxane as the main component, and dioctyl carbonate, a mixture of coco-caprylate/caprate and jojoba oil as a component ( Comparative Example 2) Immediately after application, the degree of softness of the hair is high,

③比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4）其在塗抹後即刻，毛髮的柔順度程度較高，③Compared with the composition containing polymer polydimethylsiloxane as the main component, and not containing dioctyl carbonate, coco-octanoate/caprate mixture and jojoba oil (comparative example) 3), as the main component containing high molecular polydimethylsiloxane alcohol, and as the composition component containing dioctyl carbonate and coco-caprylate/caprate mixture and jojoba oil composition ( Comparative Example 4) Immediately after application, the degree of softness of the hair is high,

④比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1以及2）其在塗抹後即刻，毛髮的柔順度程度較高，④Compared to containing high molecular polydimethylsiloxane as the main component, and not containing trisiloxane, dioctyl carbonate, mixture of coco-octanoate/caprate and jojoba oil A composition (Comparative Example 3) containing a high molecular weight polydimethylsiloxane as a main component, and containing trisiloxane, dioctyl carbonate, and coco-octanoate/caprate as constituent components The composition of the mixture and jojoba oil (Examples 1 and 2) has a higher degree of softness of the hair immediately after application,

⑤比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1）其在塗抹後即刻，毛髮的柔順度程度較高。⑤Compared with the composition containing polymer polydimethylsiloxane as the main component, and not containing dioctyl carbonate, coco-caprylate/caprate mixture and jojoba oil (comparative example) 4), contains high molecular polydimethylsiloxane as the main component, and contains trisiloxane, dioctyl carbonate and mixture of coco-octanoate/caprate and jojoba as components The composition of the oil (Example 1) has a higher degree of softness of the hair immediately after application.

一方面，確認到即便是作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，當組合物中高分子聚二甲基矽氧烷醇的含量顯著降低時（基於比較例8的組合物），毛髮的柔順度程度顯示為較低。On the one hand, it was confirmed that even if it contained a high molecular polydimethylsiloxane as a main component, it also contained a mixture of trisiloxane, dioctyl carbonate, and coco-octanoate/caprate as constituent components The composition with jojoba oil, when the content of high molecular polydimethylsiloxane in the composition is significantly reduced (based on the composition of Comparative Example 8), the degree of softness of the hair is shown to be lower.

與此不同地，確認到作為主成分含有高含量的高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例3、4、5以及6）與基於實施例1以及2的組合物類似，毛髮的柔順度程度顯示為較高。On the other hand, it was confirmed that a high content of high-molecular polydimethylsiloxane was contained as a main component, and trisiloxane, dioctyl carbonate, and coco-octanoate/capric acid were contained as components. The ester mixture and jojoba oil compositions (Examples 3, 4, 5 and 6) were similar to the compositions based on Examples 1 and 2, and the degree of softness of the hair was shown to be higher.

另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的柔順度程度的結果，可以獲得與基於如下表4的實施例1的組合物的結果類似的結果（未提供數據）。In addition, the results of evaluating the degree of softness of the hair when the compositions based on Examples 1, 2, 3, 4, 5 and 6 were applied to the damaged dry hair were obtained, and the results of the Examples based on the following Table 4 were obtained. Similar results were obtained for the composition of 1 (data not presented).

綜合所述結果，確認到一同含有本發明中規定的含量的作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮柔順度程度。Based on the results, it was confirmed that the polymer polydimethylsiloxane alcohol as the main component and trisiloxane, dioctyl carbonate, and coco-octanoic acid as the constituent components are contained together in the content specified in the present invention. Esters/caprate blends and jojoba oil compositions showing the best degree of hair softness.

以下表4是顯示藉由柔順度增加率（對比塗抹前）換算測定在毛髮塗抹毛髮調理組合物前後，正常毛髮的柔順度程度的結果（單位：%）。Table 4 below shows the results (unit: %) of the degree of softness of normal hair before and after application of the hair conditioning composition to the hair by conversion of the rate of increase in softness (compared to before application).

【表4】

【Table 4】

實驗例3：毛髮的光滑度持久力評價Experimental Example 3: Evaluation of smoothness and staying power of hair

向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的光滑度持久力（摩擦力）進行了評價。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above reference examples was applied to the hair, and then the smoothness staying power (frictional force) of the hair was measured and evaluated as follows.

＜毛髮的光滑度持久力測定方法＞<Method for measuring the smoothness and durability of hair>

試驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用MTT175儀器（小型拉伸試驗儀器（Miniature Tensile Tester）,Dia-Stron公司），隨著時間（塗抹後即刻、經過1、2、3小時後）測定了毛髮的光滑度程度。其中，毛髮的光滑度程度是將相對於對照組試料的毛髮的表面摩擦力用gmf值進行數值化而得出的光滑度，毛髮的摩擦力值越小，代表毛髮的表面保持光潤狀態。The tresses (normal hair or damaged dry hair; refer to Experimental Example 1) used in the test were washed with a basic shampoo with no conditioning effect, rinsed with water for about 1 minute, then dried for about 5 minutes, and then the composition was applied. (Examples 1 to 6 and Comparative Examples 1 to 8), and then using the MTT175 instrument (Miniature Tensile Tester, Dia-Stron), with time (immediately after application, after 1, 2, 3 hours) the degree of smoothness of the hair was measured. The degree of smoothness of the hair is obtained by digitizing the surface friction force of the hair relative to the control sample with the gmf value. The smaller the friction force value of the hair, the smoother the surface of the hair is.

其結果，如下表5以及第3圖所示，確認到：As a result, as shown in Table 5 and Fig. 3 below, it was confirmed that:

①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的光滑度程度較高，①Compared with the composition containing low-molecular-weight polydimethylsiloxane as the main component (comparative example 1), the composition containing high-molecular-weight polydimethylsiloxane as the main component (comparative example 3) has Immediately after application, the smoothness of the hair is high,

②比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1~6）其在塗抹後即刻，毛髮的光滑度程度長時間較高。②Compared to containing high molecular polydimethylsiloxane as the main component, and not containing trisiloxane, dioctyl carbonate, mixture of coco-octanoate/caprate and jojoba oil A composition (Comparative Example 3) containing a high molecular weight polydimethylsiloxane as a main component, and containing trisiloxane, dioctyl carbonate, and coco-octanoate/caprate as constituent components The composition of the mixture and jojoba oil (Examples 1 to 6) immediately after application, the degree of smoothness of the hair was high for a long time.

另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的光滑度持久力的結果，可以獲得與基於如下表5的實施例1的組合物的結果類似的結果（未提供數據）。In addition, the results of evaluating the smoothness staying power of the hair when the compositions based on Examples 1, 2, 3, 4, 5, and 6 were applied to the damaged dry hair as a subject were comparable to the results of the implementation based on the following Table 5. Similar results were obtained for the composition of Example 1 (data not provided).

綜合所述結果，確認到一同含有本發明中規定的含量的作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮光滑度持久力。Based on the results, it was confirmed that the polymer polydimethylsiloxane alcohol as the main component and trisiloxane, dioctyl carbonate, and coco-octanoic acid as the constituent components are contained together in the content specified in the present invention. A blend of esters/caprates and a combination of jojoba oil showing the best hair smoothness staying power.

以下表5是顯示藉由光滑度增加率（對比塗抹前）換算隨著時間測定在毛髮塗抹毛髮調理組合物前後，正常毛髮的光滑度持久力的結果（單位：%）。Table 5 below shows the results (unit: %) of the smoothness staying power of normal hair before and after application of the hair conditioning composition to the hair over time, converted by the rate of smoothness increase (compared to before application).

表5

table 5

試驗例4：使用感評價Test Example 4: Evaluation of Usability

以11名感官評價專家小組為對象，在毛髮以及皮膚上塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8）後，以15分標準，對使用感進行了如下所示的感官評價（15分標準的評價分數基準被確認為是，[1分]非常低-[5分]很一般-[10分]較高-[15]非常高）。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above reference examples was applied to the hair and skin of 11 sensory evaluation expert panels, and then the use was evaluated on a 15-point scale. The sensory evaluation was performed as shown below (the 15-point scale evaluation score benchmark was confirmed as yes, [1 point] very low - [5 point] very average - [10 point] high - [15] very high).

＜毛髮的使用感感官評價方法＞<Method for sensory evaluation of the usability of hair>

試驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後11名感官評價專家小組針對七種項目（手塗抹性（用手塗抹時的容易性）、手清爽度、柔順度、毛髮塗抹性、毛髮吸收性、毛髮擰團、毛髮光澤度）進行了評價。The tresses (normal hair or damaged dry hair; refer to Experimental Example 1) used in the test were washed with a basic shampoo with no conditioning effect, rinsed with water for about 1 minute, then dried for about 5 minutes, and then the composition was applied. (Examples 1 to 6 and Comparative Examples 1 to 8), and then a panel of 11 sensory evaluation experts evaluated seven items (hand spreadability (ease of spreading by hand), hand freshness, softness, hair spreadability, hair absorbency, hair curling, hair gloss) were evaluated.

其結果，如表6以及第4圖所示，根據由11名感官評價專家小組的評價分數的感官評價，基於實施例1以及實施例3~6的組合物相比基於比較例3以及比較例4的組合物，在七種項目（手塗抹性（用手塗抹時的容易性）、手清爽度、柔順度、毛髮塗抹性、毛髮吸收性、毛髮擰團、毛髮光澤度）的綜合評價上，其效果顯示優勢，從而被評價為有利於毛髮調理。As a result, as shown in Table 6 and FIG. 4 , the compositions based on Example 1 and Examples 3 to 6 were compared with those based on Comparative Example 3 and Comparative Example based on the sensory evaluation based on the evaluation scores of the 11 sensory evaluation expert panels. The composition of 4, on the comprehensive evaluation of seven items (hand spreadability (ease of application by hand), hand freshness, softness, hair spreadability, hair absorbability, hair curling, hair gloss) , its effect shows advantages and thus is evaluated as beneficial for hair conditioning.

具體地，相比作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3）或者作為主成分含有高分子聚二甲基矽氧烷醇，並且含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物中的實施例1、3、4、5、6的組合物的感官評價綜合分數（合計）顯示較高。Specifically, it contains high molecular polydimethylsiloxane as the main component, and does not contain trisiloxane, dioctyl carbonate, a mixture of coco-octanoate/caprate and jojoba The oil composition (Comparative Example 3) or as the main component contains high molecular polydimethylsiloxane, and contains dioctyl carbonate, a mixture of coco-caprylate/caprate, and jojoba oil The composition (Comparative Example 4) containing polymer polydimethylsiloxane as the main component, and trisiloxane, dioctyl carbonate and coco-octanoate/caprate as the component components The sensory evaluation composite score (total) of the compositions of Examples 1, 3, 4, 5, and 6 in the mixture of jojoba oil and the composition of jojoba oil showed higher.

另外，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例2）與基於實施例1的組合物類似，確認到毛髮的光滑度程度顯示較高（未提供數據）。In addition, it contains high molecular polydimethylsiloxane as the main component, and trisiloxane, dioctyl carbonate, a mixture of coco-octanoate/caprate and jojoba oil as components The composition of (Example 2) was similar to the composition based on Example 1, and it was confirmed that the degree of smoothness of the hair showed a higher level (data not provided).

另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的使用感的結果，可以獲得與基於如下表6的實施例1的組合物的結果類似的結果（未提供數據）。In addition, as a result of evaluating the feeling of use when applying the compositions based on Examples 1, 2, 3, 4, 5, and 6 on damaged dry hair, a combination with Example 1 based on the following Table 6 was obtained. Similar results were obtained for the analytes (data not provided).

一方面，含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物中，基於比較例5的組合物由於低含量的高分子聚二甲基矽氧烷醇，而顯示組合物的黏度非常低，且缺乏柔順度，含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例7）顯示毛髮黏膩感和油膩感（oily）強，而使用感低下（未提供數據）。In one aspect, it contains a high molecular weight polydimethylsiloxane alcohol, and as constituents contains a combination of trisiloxane, dioctyl carbonate, a mixture of coco-octanoate/caprate and jojoba oil Among them, the composition based on Comparative Example 5 shows that the viscosity of the composition is very low and lacks flexibility due to the low content of high-molecular polydimethylsiloxane, and the composition contains low-molecular polydimethylsiloxane. , and the composition (Comparative Example 7) containing trisiloxane, dioctyl carbonate and a mixture of coco-octanoate/caprate and jojoba oil as constituents (Comparative Example 7) showed a sticky and greasy hair (oily) strong, but poor usability (data not provided).

以下表6是顯示以11名感官評價專家小組為對象，在正常毛髮以及皮膚上塗抹根據本發明的毛髮調理組合物後，以15分標準，對使用感進行感官評價的結果。Table 6 below shows the results of sensory evaluation of the feeling of use on a 15-point scale after applying the hair conditioning composition according to the present invention to normal hair and skin by 11 panelists for sensory evaluation.

表6

Table 6

以上針對本發明內容的特定部分進行了詳細說明，然而所屬技術領域具有通常知識者應明確所述具體技術說明僅是較佳的實施形態，並不由此限定本發明的範圍。因此，本發明的實際範圍應由所附的申請專利範圍及其等價物而定。The specific part of the content of the present invention has been described in detail above, but those skilled in the art should clearly understand that the specific technical description is only a preferred embodiment, and does not limit the scope of the present invention. Accordingly, the actual scope of the present invention should be determined by the appended claims and their equivalents.

無none

第1圖是示出隨著時間測定在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的光澤度持久力的結果的圖表。Figure 1 is a graph showing the results of measuring the gloss staying power of hair over time before and after application of the hair conditioning composition according to the present invention to the hair.

第2圖是示出藉由柔順度增加率（對比塗抹前）換算在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的柔順度程度的結果的圖表。Figure 2 is a graph showing the results of the degree of softness of the hair before and after application of the hair conditioning composition according to the present invention, converted by the rate of increase in softness (compared to before application).

第3圖是示出藉由柔順度增加率（對比塗抹前）換算隨著時間測定在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的柔順度持久力的結果的圖表。Figure 3 is a graph showing the results of measuring the softness staying power of hair before and after application of the hair conditioning composition according to the present invention over time by conversion of softness increase rate (vs. before application).

第4圖是示出以11名感官評價專家小組為對象，在毛髮以及皮膚上塗抹根據本發明的毛髮調理組合物後，以15分標準，對使用感進行感官評價的結果的圖表。Fig. 4 is a graph showing the results of sensory evaluation of the feeling of use on a 15-point scale after applying the hair conditioning composition according to the present invention to hair and skin by a panel of 11 sensory evaluation experts.

Claims

一種毛髮調理組合物，其為含有聚二甲基矽氧烷醇及直鏈型矽氧烷類化合物作為有效成分的毛髮調理組合物，其特徵在於，該聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。A hair conditioning composition, which is a hair conditioning composition containing polydimethylsiloxane and a linear silicone compound as active ingredients, characterized in that: The polydimethylsiloxane has an average molecular weight of 600,000 to 1,300,000 g/mol.

如申請專利範圍第1項所述的毛髮調理組合物，其中該直鏈型矽氧烷類化合物選自由三矽氧烷、二矽氧烷以及聚二甲基矽氧烷而成的群組中的一種以上。The hair conditioning composition of claim 1, wherein the linear siloxane compound is selected from the group consisting of trisiloxane, disiloxane and polydimethylsiloxane of more than one.

如申請專利範圍第1項所述的毛髮調理組合物，其進一步包括選自由2-辛基十二醇肉豆蔻酸酯、肉豆蔻酸異丙酯、C12-15烷基苯甲酸酯、棕櫚酸異丙酯、丁基辛醇水楊酸酯、鯨蠟醇乙基己酸酯、碳酸二辛酯、棕櫚酸乙基己酯以及椰油醇-辛酸酯/葵酸酯而成的群組中的一種以上的酯類油。The hair conditioning composition of claim 1, further comprising a composition selected from the group consisting of 2-octyldodecyl myristate, isopropyl myristate, C12-15 alkyl benzoate, palm A group consisting of isopropyl acid, butyl octanol salicylate, cetyl ethyl hexanoate, dioctyl carbonate, ethyl hexyl palmitate, and coco-caprylate/caprate More than one ester oil from the group.

如申請專利範圍第1項所述的毛髮調理組合物，其進一步包括選自由荷荷巴油、葵花籽油、蓖麻油、橄欖油、椰子油、深海兩節薺籽油以及豆油而成的群組中的一種以上的植物油。The hair conditioning composition of claim 1, further comprising a group selected from the group consisting of jojoba oil, sunflower oil, castor oil, olive oil, coconut oil, camelina seed oil and soybean oil More than one vegetable oil from the group.

如申請專利範圍第1項所述的毛髮調理組合物，其進一步包括環狀矽氧烷類化合物。The hair conditioning composition according to claim 1, further comprising a cyclosiloxane compound.

如申請專利範圍第5項所述的毛髮調理組合物，其中該環狀矽氧烷類化合物為環聚二甲基矽氧烷。The hair conditioning composition as claimed in claim 5, wherein the cyclosiloxane compound is cyclopolydimethylsiloxane.

如申請專利範圍第6項所述的毛髮調理組合物，其中該環狀矽氧烷類化合物的黏度為3.0~5.0cs。The hair conditioning composition according to item 6 of the claimed scope, wherein the viscosity of the cyclic siloxane compound is 3.0-5.0 cs.

如申請專利範圍第1項所述的毛髮調理組合物，其中該聚二甲基矽氧烷醇的黏度為6萬~16萬cs。The hair conditioning composition as described in item 1 of the patent application scope, wherein the viscosity of the polydimethylsiloxane is 60,000-160,000 cs.

如申請專利範圍第1項所述的毛髮調理組合物，其中該直鏈型矽氧烷類化合物的黏度為0.5~2.5cs。The hair conditioning composition according to item 1 of the claimed scope, wherein the viscosity of the straight-chain siloxane compound is 0.5-2.5cs.

如申請專利範圍第1項所述的毛髮調理組合物，其中該聚二甲基矽氧烷醇及該直鏈型矽氧烷類化合物的混合比按照重量基準為5.1~34.9:1.0~27.5。The hair conditioning composition according to item 1 of the claimed scope, wherein the mixing ratio of the polydimethylsiloxane and the linear siloxane compound is 5.1-34.9:1.0-27.5 on a weight basis.

如申請專利範圍第1項所述的毛髮調理組合物，其中毛髮是因選自由染色以及燙髮而成的群中的一種以上的化學處理、物理損傷、壓力或者缺乏營養導致的受損毛髮。The hair conditioning composition of claim 1, wherein the hair is damaged hair caused by one or more chemical treatments selected from the group consisting of dyeing and perming, physical damage, stress or lack of nutrition.

如申請專利範圍第1項所述的毛髮調理組合物，其係選自由軟膏、護髮水、護髮霜、護髮膜、頭髮營養液、護髮乳、焗油劑、頭皮護理劑、洗髮水、護髮素以及髮蠟而成的群組中的一種以上劑型。The hair conditioning composition according to claim 1, which is selected from the group consisting of ointment, hair care lotion, hair care cream, hair care film, hair nourishing liquid, hair conditioner, baking oil, scalp care agent, shampoo One or more dosage forms in the group consisting of , hair conditioner and hair wax.

一種聚二甲基矽氧烷醇及直鏈型矽氧烷類化合物的混合物在毛髮的調理化妝料組合物或者化妝品的製造中的應用，其中該聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。The application of a mixture of polydimethylsiloxane and straight-chain siloxane compounds in the manufacture of hair conditioning cosmetic compositions or cosmetics, wherein the average molecular weight of the polydimethylsiloxane is 600,000 to 1.3 million g/mol.