TW201711673A - Lip cosmetic composition emulisified as water-in-oil type comprising a water-soluble polymer - Google Patents

Abstract

The present invention relates to a water-in-oil type lip cosmetic composition which uses a water-soluble polymer, and more particularly, to a lip cosmetic composition which stabilizes a water-soluble polymer in oil without using an emulsifier. The lip cosmetic composition provides a sufficient lip volume-enhancing effect via the water-soluble polymer while exhibiting excellent glossiness and having good adhesiveness to the lips without being sticky, and thus feels good when used.

Description

包含水溶性聚合物的油包水型唇部化妝品組合物Water-in-oil lip cosmetic composition comprising water-soluble polymer

本發明涉及一種利用水溶性聚合物的油包水型唇部化妝品組合物，更加詳細而言，涉及一種如下唇部化妝品組合物，所述唇部化妝品組合物中，水溶性聚合物在沒有乳化劑的情況下穩定於油相內，藉由水溶性聚合物提供充分的提高唇部豐盈的效果，同時表現出優異的光澤性，在唇部上的貼合感好，並且沒有黏糊感，使用感突出。The present invention relates to a water-in-oil type lip cosmetic composition using a water-soluble polymer, and more particularly to a lip cosmetic composition in which a water-soluble polymer is not emulsified In the case of the agent, it is stable in the oil phase, and the water-soluble polymer provides a sufficient effect of increasing the lip abundance, and at the same time exhibits excellent gloss, a good fit on the lips, and no stickiness. Outstanding.

本申請主張於2015年6月26日提交於韓國專利局的韓國專利申請第10-2015-0091009號的申請日的利益，其全部內容包含在本說明書中。The present application claims the benefit of the filing date of the Korean Patent Application No. 10-2015-0091009, which is filed on June 26, 2015, the entire contents of which is incorporated herein by reference.

近年來，女性對緩解皮膚皺紋的化妝品的關注度逐漸增加，特別是對能夠使在生理、物理及生物學特性上與皮膚不同的唇部顯示出具有豐盈感、飽滿、性感外形的產品的關注度逐漸增加。根據這些要求，也實行整形外科手術，但考慮到費用和皮肉之苦等，越來越多的人想藉由化妝品來實現上述要求。隨著想藉由化妝品來解決這種要求的消費者逐漸增多，正在積極開展研究增強唇部豐盈及唇部輪廓的產品，並且陸續生產出了相關產品。In recent years, women's attention to cosmetics that alleviate skin wrinkles has gradually increased, especially for products that can display a rich, full, and sexy appearance on lips that are physiologically, physically, and biologically different from the skin. Gradually increase. According to these requirements, plastic surgery is also carried out, but in view of the cost and the pain of the flesh and blood, more and more people want to achieve the above requirements by cosmetics. With the increasing number of consumers who want to solve this demand with cosmetics, products that enhance lip abundance and lip contours are being actively researched, and related products are being produced one after another.

一般具有豐唇效果（lip-plumping）或改善皺紋效果的唇部用化妝品是藉由在油性基材中混合蠟狀物質而制得，其組成成分可分為如下幾種。首先，第一種為包含如小燭樹蠟、地蠟(ceresin)、巴西棕櫚蠟、石蠟、木蠟、鯨蠟、蜜蠟、微晶蠟及聚乙烯等的藉由提高硬度來維持唇部用化妝品組合物的外形的蠟相成分，第二種為包含荷荷芭油、角鯊烷、羊毛脂油、羊毛脂衍生物、從動物中提取的油、合成酯類油以及矽油等液相油性成分，第三種為摻和有用於改善唇部狀態的功效成分、維生素類、高保濕成分及抗氧化成分，第四種為包含由有機色素和無機色素組成的色素成分，第五種為包含抗氧化劑、防腐劑、著香劑及營養成分，第六種為添加有珍珠顏料等其他成分。A lip cosmetic which generally has a lip-plumping effect or a wrinkle-improving effect is obtained by mixing a waxy substance in an oily base material, and its constituent components can be classified into the following types. First, the first one is to maintain the lip by increasing the hardness, such as candelilla wax, ceresin, carnauba wax, paraffin wax, wood wax, cetyl wax, beeswax, microcrystalline wax, and polyethylene. The wax phase component of the shape of the cosmetic composition, and the second is liquid phase oily oil including jojoba oil, squalane, lanolin oil, lanolin derivative, oil extracted from animals, synthetic ester oil, and eucalyptus oil. Ingredients, the third is a combination of functional ingredients, vitamins, high moisturizing ingredients and antioxidants for improving the state of the lips, the fourth is a pigment component consisting of organic and inorganic pigments, and the fifth is contained. Antioxidants, preservatives, flavoring agents and nutrients, and the sixth is the addition of other ingredients such as pearl pigments.

此外，提供豐盈效果的習知物質有提供溫感（warming）效果的增溫劑（warming agent）即多元醇、辣椒粉、辣椒香料、辣椒汁、辣椒素（capsaicin）、高辣椒鹼（Homocapsaicin）、高二氫辣椒鹼、壬醯香草胺(nonanoyl vanillyl amide)、壬酸香草醚、香草醇烷基醚衍生物（日本公開專利公報昭57-9729號）、異香草醇烷基醚（isovanillyl alcohol alkyl ether）、乙基香草醇烷基醚、藜蘆基醇衍生物、被取代的苄醇衍生物、被取代的苄基醇烷基醚、香蘭素丙二醇縮醛、乙基香蘭素丙二醇縮醛、薑汁、生薑油、薑辣素（gingerol）、薑（gingeron）、鹿蹄草、桂皮、生薑、迷迭香及煙酸成分等，除了增溫劑以外的物質有棕櫚醯寡肽（Palmitoyl Oligopeptide;Pal-GHK）及膠原蛋白（collagen）成分等。Further, a conventional substance which provides a bulking effect has a warming agent which provides a warming effect, that is, a polyhydric alcohol, a paprika powder, a chili flavor, a chili sauce, a capsaicin, a high capsaicin, and a homocapsaicin. , homodihydro vanillyl amide, nonanoyl vanillyl amide, vanillic acid vanillyl ether, vanillyl alcohol ether derivative (Japanese Laid-Open Patent Publication No. SHO 57-9729), isovanillyl alcohol alkyl Ether), ethyl vanillyl alcohol ether, succinyl alcohol derivative, substituted benzyl alcohol derivative, substituted benzyl alcohol alkyl ether, vanillin propylene glycol acetal, ethyl vanillin propylene glycol acetal, Ginger juice, ginger oil, gingerol, gingeron, wintergreen, cinnamon, ginger, rosemary and niacin, etc., other than the warming agent, palmitoyl oligopeptide ( Palmitoyl Oligopeptide; Pal-GHK) and collagen components.

然而，當使用這種具有豐唇效果的成分時，有對唇部產生刺激並且黏糊感強的問題。However, when such a lip-enhancing ingredient is used, there is a problem that the lip is irritated and the sticky feeling is strong.

此外，對於現有的唇部用化妝品組合物，為了顯示光澤效果，主要使用了油溶性聚合物。但是，當使用油溶性聚合物時，黏糊感強且有沉悶感。Further, in the conventional lip cosmetic composition, an oil-soluble polymer is mainly used in order to exhibit a gloss effect. However, when an oil-soluble polymer is used, the sticky feeling is strong and there is a dull feeling.

並且，當使用水溶性聚合物，且劑型為口紅時，會降低棒(stick)的硬度，且顯著降低口紅成分之間的相容性，導致油從口紅中分離出，使得棒的外觀變得雜亂，並且因為為了乳化水溶性成分而使用的各種乳化劑，對皮膚刺激危險性大（韓國申請公開專利第10-1999-0009865（1999年02月05日公開））。並且，雖然韓國授權專利第10-1221270號（2013年01月11日公告）中公開了適用包含水溶性聚合物的乳化基質的口紅，但所述口紅是由圓筒形狀核心部和圍繞所述核心部的殼部組成的雙重結構的口紅，其中沒有公開使用於單一劑型的內容。Moreover, when a water-soluble polymer is used and the dosage form is a lipstick, the hardness of the stick is lowered, and the compatibility between the lipstick components is remarkably lowered, resulting in separation of the oil from the lipstick, so that the appearance of the rod becomes In addition, various emulsifiers used for emulsifying a water-soluble component have a high risk of skin irritation (Korean Patent Application Laid-Open No. 10-1999-0009865 (published on Feb. 05, 1999)). Further, although a lipstick applying an emulsifying base containing a water-soluble polymer is disclosed in Korean Patent No. 10-1221270 (November 11, 2013), the lipstick is composed of a cylindrical core portion and surrounding The double-structured lipstick consisting of the shell of the core has no disclosure of content for a single dosage form.

欲解決的技術問題Technical problem to be solved

對此，本申請的發明人發現，使用水溶性聚合物可以解決現有的具有豐唇效果特性的組合物的問題點，同時能夠提高光澤效果並降低貼合感，從而完成了本發明。On the other hand, the inventors of the present application have found that the use of a water-soluble polymer can solve the problem of the conventional composition having lip-enhancing properties, and at the same time, can improve the gloss effect and reduce the feeling of fit, thereby completing the present invention.

因此，本發明提供一種唇部用化妝品組合物，所述唇部用化妝品組合物中，水溶性聚合物在沒有乳化劑的情況下穩定於油相內，從而提供唇部豐盈效果的同時，提高光澤並且提供沒有黏糊感的貼合感唇部。Accordingly, the present invention provides a cosmetic composition for a lip, wherein the water-soluble polymer is stabilized in the oil phase without an emulsifier, thereby providing a lip filling effect while improving Gloss and provide a snug lip with no sticky feel.

技術方案Technical solutions

為了實現上述目的，本發明涉及一種包含水溶性聚合物、蠟和漿料的油包水型唇部化妝品組合物。In order to achieve the above object, the present invention relates to a water-in-oil type lip cosmetic composition comprising a water-soluble polymer, a wax and a slurry.

有益效果Beneficial effect

唇部與現有的導致局部疼痛的豐唇用組合物不同，本發明的唇部用化妝品組合物顯示出優異的豐盈提高效果，同時不刺激唇部，塗抹後光澤度高且沒有黏糊感，並且提高了貼合感，從而使用感非常優異。The lip composition of the lip composition of the present invention exhibits an excellent effect of enriching the abundance, and does not irritate the lip, has high gloss after application, and has no sticky feeling, and the lip portion is different from the existing lip lip composition for causing local pain. The feeling of fit is improved, and the feeling of use is excellent.

本發明涉及一種在不適用使用乳化劑的乳化基質，且不使用乳化劑的情況下，將水溶性聚合物穩定於油相內的油包水型唇部用組合物。The present invention relates to a water-in-oil type lip composition which stabilizes a water-soluble polymer in an oil phase without using an emulsified base using an emulsifier and without using an emulsifier.

本發明中提及的化合物名稱在沒有特別說明的情況下，表示相當於美國化妝品協會（Cosmetic，Toiletry and Fragrance Association，CTFA）發行的國際化妝品原料集（International Cosmetic Ingredient Dictionary，ICID）中記載的國際化妝品原料命名（International Nomenclature Cosmetic Ingredient，INCI）的化合物，若該名稱不存在於國際化妝品原料命名中，則表示屬於國際純粹與應用化學聯合會（International Union of Pure and Applied Chemistry, IUPAC）指定的IUPAC命名法的化合物，若不存在基於IUPAC命名法的化合物，則表示對應於本發明的技術領域中通用的化合物名稱的化合物。The names of the compounds mentioned in the present invention are equivalent to those described in the International Cosmetic Ingredient Dictionary (ICID) issued by the Cosmetics and Fragrance Association (CTFA) unless otherwise specified. A compound of International Nomenclature Cosmetic Ingredient (INCI), if the name does not exist in the international cosmetic raw material nomenclature, means that it belongs to the IUPAC designated by the International Union of Pure and Applied Chemistry (IUPAC). The nomenclature compound, if no compound based on the IUPAC nomenclature, represents a compound corresponding to the compound name common in the technical field of the present invention.

本說明書中的油包水（Water in Oil，W/O）型表示連續相是油相，分散相是水相的乳液劑型。The water in oil (W/O) type in the present specification means an emulsion form in which the continuous phase is an oil phase and the dispersed phase is an aqueous phase.

本發明中乳液劑型是指包含一種以上液體相的分散相（dispersed phase）以液滴（droplet）形狀分散於包含一種以上的液體相的連續相中（continuous phase）的劑型。The emulsion dosage form of the present invention refers to a dosage form comprising a dispersed phase of more than one liquid phase dispersed in the form of a droplet in a continuous phase comprising more than one liquid phase.

習知在油相中使用水溶性聚合物的唇部用組合物的情況下，從確保劑型的穩定性方面考慮，必須使用乳化劑。然而，在本發明中的水溶性聚合物的穩定化中不涉及乳化劑的使用。In the case where a lip composition for a water-soluble polymer is used in an oil phase, it is necessary to use an emulsifier from the viewpoint of ensuring the stability of the dosage form. However, the use of an emulsifier is not involved in the stabilization of the water-soluble polymer in the present invention.

為了在不使用乳化劑的情況下穩定化劑型的油相內的水溶性聚合物，本發明中使最佳含量的蠟和漿料的結構與水溶性聚合物一起混合，由此，提高組合物的黏度，從而使組合物記憶體在的水穩定化。此外，製備組合物時，在適當的溫度下注入水溶性聚合物，較佳為在75~35℃的溫度下注入水溶性聚合物，更佳為在45℃的溫度下注入水溶性聚合物，劑型化在常溫下進行。In order to stabilize the water-soluble polymer in the oil phase of the dosage form without using an emulsifier, in the present invention, the structure of the optimum amount of the wax and the slurry is mixed with the water-soluble polymer, thereby improving the composition. The viscosity of the composition stabilizes the water in the composition. Further, in preparing the composition, the water-soluble polymer is injected at a suitable temperature, preferably a water-soluble polymer is injected at a temperature of 75 to 35 ° C, and more preferably a water-soluble polymer is injected at a temperature of 45 ° C. The dosage form is carried out at normal temperature.

為了在不使用乳化劑的情況下穩定化劑型的油相內的水溶性聚合物，本發明中為了高黏度劑型而使用了黏彈性高的蠟和漿料。In order to stabilize the water-soluble polymer in the oil phase of the dosage form without using an emulsifier, in the present invention, a wax and a slurry having high viscoelasticity are used for the high-viscosity dosage form.

本發明的組合物中所使用的水溶性組合物可以選自瓊脂、纖維素膠、卡波姆、羥乙基纖維素、羥甲基纖維素、羥丙基纖維素、膨潤土、聚乙烯醇、聚乙酸乙烯酯、聚乙烯吡咯烷酮、聚氨酯、果膠、澱粉及黃原膠，以組合物總重量計，使用0.5~40重量%的量。所述聚氨酯可由化學式1來表示。The water-soluble composition used in the composition of the present invention may be selected from the group consisting of agar, cellulose gum, carbomer, hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, bentonite, polyvinyl alcohol, Polyvinyl acetate, polyvinylpyrrolidone, polyurethane, pectin, starch and xanthan gum are used in an amount of from 0.5 to 40% by weight based on the total weight of the composition. The polyurethane can be represented by Chemical Formula 1.

[化學式1] [Chemical Formula 1]

所述化學式1的n較佳為1~68。所述化學式1中，R和R’為亞苯基。n of the Chemical Formula 1 is preferably from 1 to 68. In the chemical formula 1, R and R' are a phenylene group.

此外，如上所述，本發明的組合物為了水溶性組合物的穩定化而使用蠟和漿料。Further, as described above, the composition of the present invention uses a wax and a slurry for the stabilization of the water-soluble composition.

本發明的組合物中所使用的蠟較佳為固相蠟，可以使用選自微晶蠟、天然地蠟(ozokerite)、蜜蠟、小燭樹蠟、巴西棕櫚蠟、精鍊地蠟(ceresin)、石蠟、褐煤蠟、日本蠟、可可脂及合成蠟中的一種以上，但不限定於此。較佳為使用微晶蠟。這是因為在常溫上凝固時，黏性和彈性高使得黏著力高，從而有助於水溶性聚合物的穩定化。本發明的組合物中，以組合物總重量計，蠟的使用量為0.5~4重量%、較佳為1~2重量%。The wax used in the composition of the present invention is preferably a solid phase wax, and may be selected from the group consisting of microcrystalline wax, ozokerite, beeswax, candelilla wax, carnauba wax, ceresin. One or more of paraffin wax, montan wax, Japanese wax, cocoa butter, and synthetic wax, but is not limited thereto. It is preferred to use a microcrystalline wax. This is because when it is solidified at a normal temperature, the viscosity and elasticity are high to make the adhesion high, thereby contributing to the stabilization of the water-soluble polymer. In the composition of the present invention, the wax is used in an amount of 0.5 to 4% by weight, preferably 1 to 2% by weight based on the total weight of the composition.

根據產品特點，漿料可以使用氫化蓖麻油異硬脂酸酯、雙-二甘油多醯基己二酸酯-2、氫化聚苯乙烯*乙烯/丙烯/苯乙烯共聚物*丁稀/乙烯/苯乙烯共聚物、油酸/亞油酸/亞麻酸聚甘油酯、礦酯、礦物油*辛酸癸酸甘油三酯*氫化苯乙烯/異戊二烯共聚物、雙-羥基月桂基二甲聚矽氧烷/異佛爾酮二異氰酸酯（IPDI）共聚物、植物固醇/異硬脂醇/鯨蠟醇/硬脂醇/山崳醇二聚亞油酸酯等，但不限定於此。以化妝品組合物總重量計，這種漿料較佳為使用10~70重量%。According to the characteristics of the product, the slurry can be hydrogenated castor oil isostearate, bis-diglyceryl polydecyl adipate-2, hydrogenated polystyrene * ethylene / propylene / styrene copolymer * butyl / ethylene / Styrene copolymer, oleic acid/linoleic acid/linolenic acid polyglycerol ester, mineral ester, mineral oil* caprylic acid triglyceride* hydrogenated styrene/isoprene copolymer, bis-hydroxylauryl dimerization A butane/isophorone diisocyanate (IPDI) copolymer, phytosterol/isostearyl alcohol/cetyl alcohol/stearyl alcohol/behenyl dimerized linoleate, and the like, but is not limited thereto. The slurry is preferably used in an amount of 10 to 70% by weight based on the total weight of the cosmetic composition.

本發明的唇部化妝品組合物，除了所述有效成分以外，在不損壞本發明效果的範圍內，可以包含其他蠟、油、粉、顏料、營養成分、揮發性溶解劑、抗氧化劑、防腐劑及香等通常唇部化妝品組合物所包含的成分（以下稱為“其他成分”）。以組合物總重量計，所述其他成分可以包含1~90重量%。The lip cosmetic composition of the present invention may contain other waxes, oils, powders, pigments, nutrients, volatile solvents, antioxidants, preservatives, in addition to the active ingredients, within the range not impairing the effects of the present invention. A component (hereinafter referred to as "other component") contained in a general lip cosmetic composition such as a fragrance. The other ingredients may comprise from 1 to 90% by weight, based on the total weight of the composition.

油成分可以使用諸如液體石蠟的礦物性油，鯊魚烯及水角鯊烯(hydro squalene)等動物性油；棕櫚油、鱷梨油、荷荷芭油、香油、橄欖油及蓖麻油等植物性油；肉豆蔻酸丁酯、肉豆蔻酸異丙酯、鯨蠟醇豆蔻酸酯(cetyl myristate)、棕櫚酸異丙酯、硬脂酸丁酯、聚乙丁烯、聚異丁烯、氫化聚異丁烯、各種多元醇、三-2-乙己基甘油、甘油三酯油、乳酸肉豆蔻、辛基十二烷醇及二異硬脂醇蘋果酸酯等合成油，但不限定於此。The oil component may use mineral oil such as liquid paraffin, animal oil such as sharkene and hydro squalene; plant oil such as palm oil, avocado oil, jojoba oil, sesame oil, olive oil and castor oil. Oil; butyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, butyl stearate, polybutylene, polyisobutylene, hydrogenated polyisobutylene, A synthetic oil such as various polyols, tri-2-ethylhexylglycerol, triglyceride oil, lactic acid nutmeg, octyldodecanol or diisostearyl malate, but is not limited thereto.

粉成分可以使用通常適用於化妝品的粉，例如白雲母、合成雲母、絹雲母、二氧化鈦、氧化鈦塗層雲母、鋁粉、硫酸鐵、鐵黑、炭黑、硫酸鋇、二氧化矽及泡沸石等無機粉，及尼龍、聚甲基丙烯酸甲酯（PMMA，poly（methyl methacrylate））、聚苯乙烯粉、聚乙烯粉及纖維素粉等有機粉，但不限定於此。As the powder component, a powder generally suitable for use in cosmetics such as muscovite, synthetic mica, sericite, titanium dioxide, titanium oxide coated mica, aluminum powder, iron sulfate, iron black, carbon black, barium sulfate, cerium oxide and zeolite can be used. Ordinary powder, and organic powder such as nylon, polymethyl methacrylate (PMMA, poly(methyl methacrylate)), polystyrene powder, polyethylene powder, and cellulose powder, but is not limited thereto.

上述顏料可以使用黃色203號、黃色4號、黃色5號、黃色201號、黃色204號、紅色103號、紅色201號、紅色202號、紅色218號、紅色220號、紅色223號、紅色226號、紅色227號、藍色1號、藍色2號等的鋇或鋁色澱的有機顏料及珍珠顏料等，但不限定於此。The above pigments may be yellow 203, yellow 4, yellow 5, yellow 201, yellow 204, red 103, red 201, red 202, red 218, red 220, red 223, red 226 No., red No. 227, blue No. 1, blue No. 2, etc., or an organic pigment of pearl or aluminum pearl, and the like, but are not limited thereto.

本發明的唇部用化妝品組合物，除了劑型化為口紅之外，還可以劑型化為液相形狀，例如可以劑型化為口紅、潤唇膏、護唇膏、唇筆、唇蜜（Liquid rouge）或唇彩，但不限定與此。The lip cosmetic composition of the present invention may be formulated into a liquid phase shape in addition to being formulated into a lipstick, and may be, for example, formulated into a lipstick, a lip balm, a lip balm, a lip pencil, a liquid rouge or Lip gloss, but not limited to this.

此外，本發明提供一種將前述唇部用化妝品組合物成型而製備的口紅。所述成型是指將所述唇部用化妝品組合物固化為棒形狀。Further, the present invention provides a lipstick prepared by molding the aforementioned cosmetic composition for a lip. The molding means that the lip cosmetic composition is cured into a rod shape.

以下，藉由實施例和比較例對本發明進行更加詳細的說明，但本發明的範圍並不限定於這些例子。Hereinafter, the present invention will be described in more detail by way of examples and comparative examples, but the scope of the invention is not limited to these examples.

[參照例1]唇部用組合物的製備[Reference Example 1] Preparation of Lip Composition

按照下述表1所示的組成來製備了口紅形狀的唇部用組合物。實施例1是根據本發明所製備的口紅，其為以組合物總重量計，包含10重量%的水溶性聚合物而製備的口紅，比較例1是使用油溶性聚合物聚異丁烯來代替水溶性聚合物而製備的口紅，比較例2是不包含水溶性聚合物和油溶性聚合物（含量：根據組合物總重量的重量%）A lip-shaped lip composition was prepared according to the composition shown in Table 1 below. Example 1 is a lipstick prepared according to the present invention, which is a lipstick prepared by containing 10% by weight of a water-soluble polymer based on the total weight of the composition, and Comparative Example 1 uses an oil-soluble polymer polyisobutylene instead of water-soluble. Lipstick prepared from the polymer, Comparative Example 2 does not contain a water-soluble polymer and an oil-soluble polymer (content: wt% by weight based on the total weight of the composition)

表1 Table 1

根據所述表1的組成，分別製備實施例1至5及比較例1至3的口紅的具體製備過程如下。According to the composition of Table 1, the specific preparation processes of the lipsticks of Examples 1 to 5 and Comparative Examples 1 to 3, respectively, were as follows.

1.對所述原料（1）~（4）及（6）（比較例2的情況下，所述原料（1）~（6））進行稱量，並加熱到90℃以上而溶解後，用攪拌器攪拌，從而製備了混合物。1. The raw materials (1) to (4) and (6) (in the case of Comparative Example 2, the raw materials (1) to (6)) are weighed and heated to 90 ° C or higher to be dissolved. The mixture was prepared by stirring with a stirrer.

2.稱量所述原料（7）並放入所述1的混合物中，在45℃的溫度下進行分散。2. The raw material (7) was weighed and placed in the mixture of 1, and dispersed at a temperature of 45 °C.

3.用均勻器均勻地混合2的混合物，然後放入色素調色，並藉由脫氣、賦香及冷卻的過程而製備口紅。3. The mixture of 2 was uniformly mixed with a homogenizer, then the pigment was tinted, and a lipstick was prepared by a process of degassing, scenting, and cooling.

此外，按照如下述表2所示的組成來製備了唇彩形狀的唇部用組合物實施例6。Further, Example 6 of a lip gloss-shaped composition for a lip was prepared in accordance with the composition shown in Table 2 below.

表2 Table 2

根據表2的組成，製備實施例6的唇彩的具體製造過程如下。According to the composition of Table 2, the specific manufacturing process for preparing the lip gloss of Example 6 is as follows.

1.對所述原料（1）~（4）及（6）進行稱量，並加熱到90℃以上進行溶解後，用攪拌器攪拌，從而製備了混合物。1. The raw materials (1) to (4) and (6) were weighed and heated to 90 ° C or higher for dissolution, and then stirred with a stirrer to prepare a mixture.

2.稱量所述原料（7）並放入所述1的混合物中，在45℃的溫度下進行分散。2. The raw material (7) was weighed and placed in the mixture of 1, and dispersed at a temperature of 45 °C.

3.用攪拌器均勻混合所述2的混合物後，放入色素調色，並藉由脫氣、賦香及冷卻的過程製備了口紅。3. After uniformly mixing the mixture of 2 with a stirrer, coloring the dye, and preparing a lipstick by degassing, fragrant, and cooling.

[試驗例1] 使用感評價[Test Example 1] Evaluation of feeling of use

（1）光澤及唇部豐盈提高效果的評價(1) Evaluation of gloss and lip abundance improvement effect

將所述實施例1的口紅分別塗抹於化妝經驗至少為2年的24~35歲女性，且一周至少持續使用5次以上唇部產品的專家組20名的唇部上後，比較了剛塗抹後和經過15秒後的狀態。對於各個狀態進行了拍照記錄，並將其中1名的結果顯示在第1圖中。The lipstick of the first embodiment was applied to a female of 24 to 35 years old who had a cosmetic experience of at least 2 years, and a lip of 20 of the expert group who continued to use the lip product for at least 5 times a week was compared with the freshly applied smear. After and after 15 seconds. Photographs were taken for each state, and the results of one of them were displayed in Fig. 1.

根據第1圖可確認到，塗抹組合物後經過15秒時的光澤度高於剛塗抹後的光澤度，並且能看出提高了唇部豐盈度。According to Fig. 1, it was confirmed that the gloss after 15 seconds from the application of the composition was higher than that after the application, and it was found that the lip abundance was improved.

此外，將所述實施例1，2和比較例1至3的口紅分別塗抹於化妝經驗至少2年的24~35歲女性，且一周至少持續使用5次以上唇部產品的專家組20名的唇部上後，比較了塗抹15秒後的狀態。對各個狀態進行拍照記錄，並將其中1名的結果顯示於第2圖中。Further, the lipsticks of Examples 1 and 2 and Comparative Examples 1 to 3 were respectively applied to women aged 24 to 35 who had at least 2 years of makeup experience, and 20 of the expert groups who continued to use the lip products at least 5 times a week. After the lip, the state after 15 seconds of application was compared. Photographs were taken for each state, and the results of one of them were displayed in Fig. 2.

根據第2圖可確認到，實施例1、2的組合物的唇部豐盈效果高於比較例1至3。As can be seen from Fig. 2, the lip abundance effects of the compositions of Examples 1 and 2 were higher than those of Comparative Examples 1 to 3.

（2）光澤度評價(2) Gloss evaluation

利用光澤計（加德納公司）測定根據所述實施例1至5和比較例1至3的組成而製備的口紅的塗抹光澤。The application gloss of the lipstick prepared according to the compositions of Examples 1 to 5 and Comparative Examples 1 to 3 was measured using a gloss meter (Gardner Co.).

測定方法如下所述，即在光澤測定紙上以一定的力塗抹5次根據組成而製備的口紅後，利用光澤計測定在塗抹面以60度的反色角度照射光時的反射量來測定光澤度，並將光澤度顯示於表1中（測定3次後的平均值）。下述表3中的結果顯示的數值越高，表示其光澤度越優異。The measurement method is as follows. After applying the lipstick prepared according to the composition five times on the gloss measurement paper with a certain force, the glossiness is measured by measuring the amount of reflection when the application surface is irradiated with light at an inverse color angle of 60 degrees. The glossiness is shown in Table 1 (the average value after three measurements). The higher the numerical value shown by the results in Table 3 below, the more excellent the gloss is.

表3 table 3

（3）唇部紋遮蔽效果（面膜效果）(3) lip line shadowing effect (mask effect)

在人造革上以一定的力塗抹5次所製備的口紅後，對紋路填補的程度進行拍照和比較評價。After applying the lipstick prepared five times on the artificial leather with a certain force, the degree of texture filling was photographed and compared.

對此的測定結果顯示於表3中。The measurement results for this are shown in Table 3.

根據第3圖可知，塗抹比較例1至3的口紅時，紋路清晰，但塗抹實施例1、4和5的口紅時，特別是塗抹實施例1的口紅時，可確認到紋路基本填補上，塗抹在唇部時，唇部紋被遮蔽，可以得到與做面膜類似的效果。As can be seen from Fig. 3, when the lipsticks of Comparative Examples 1 to 3 were applied, the texture was clear, but when the lipsticks of Examples 1, 4 and 5 were applied, in particular, when the lipstick of Example 1 was applied, it was confirmed that the texture was substantially filled. When applied to the lips, the lip lines are masked and a similar effect to the mask can be obtained.

（4）光澤感、豐盈感、無黏糊感、貼合感及遮紋評價(4) Gloss, fullness, no sticky feeling, fit and shading evaluation

在24~35歲女性且化妝經驗至少2年以上，並且一周至少持續使用5次以上唇部產品的女性專家組20名的唇部使用實施例1至5和比較例1至3的口紅唇部後，以每個項目5分制（1分：非常差，3分：一般，5分：非常好）來進行了評價。The lip of the female expert group of 24 to 35 years old who has at least 2 years of cosmetic experience and at least 5 times of continuous use of the lip product in a week uses the lipstick lips of Examples 1 to 5 and Comparative Examples 1 to 3 After that, we evaluated each item with a 5-point scale (1 point: very bad, 3 points: average, 5 points: very good).

評價結果，以5分為滿分（1分：非常差，2分：差，3分：一般，4分：好，5分：非常好）進行評分，並求出了平均分數，且將結果顯示在下述表4中。The result of the evaluation is scored with a score of 5 (1 point: very bad, 2 points: bad, 3 points: general, 4 points: good, 5 points: very good), and the average score is obtained, and the result is displayed. In Table 4 below.

表4 Table 4

如上述表4所示，可知不含水溶性或油溶性聚合物的比較例2的情況下，塗抹於唇部後，雖然沒有黏糊感，但顯示光澤感和豐盈感的程度較弱，並且由於沒有貼合感，因此容易被擦除。As shown in the above Table 4, in the case of Comparative Example 2 which does not contain a water-soluble or oil-soluble polymer, although it is applied to the lip portion, although it has no sticky feeling, the degree of glossiness and fullness is weak, and since It has a sense of fit and is therefore easy to erase.

此外，含油溶性聚合物的比較例1顯示出的光澤感和豐盈感的程度較高，貼合感也優異，但黏糊感強，因此具有沉悶感。與此相反，使用水溶性聚合物的實施例1，在光澤感和唇部豐盈感方面顯示出滿足的結果，並且貼合感優異，同時無黏糊感，可以提供輕盈的使用感，從而可以減少使用時的唇部沉悶的感覺。Further, Comparative Example 1 containing an oil-soluble polymer showed a high degree of glossiness and a feeling of fullness, and was excellent in a feeling of fit, but had a strong feeling of stickiness and thus had a dull feeling. On the contrary, Example 1 using a water-soluble polymer showed satisfactory results in terms of glossiness and lip volume feeling, and was excellent in fit feeling, and had no sticky feeling, and provided a light feeling of use, thereby being able to reduce The feeling of dullness of the lips when used.

無no

第1圖是表示對剛塗抹實施例1後和塗抹15秒後的光澤及唇部豐盈提高效果進行測定的結果。Fig. 1 is a graph showing the results of measuring the effect of improving the gloss and lip augmentation after the application of Example 1 and after 15 seconds of application.

第2圖是表示塗抹實施例1、2和比較例1至3並經過15秒後對光澤及唇部豐盈提高效果進行測定的結果。Fig. 2 is a graph showing the results of measuring the effect of improving the gloss and lip abundance after 15 seconds of application of Examples 1 and 2 and Comparative Examples 1 to 3.

第3圖是表示將實施例1、4、5及比較例1至3塗抹於人造革上後的唇部紋的遮蔽效果。Fig. 3 is a view showing the shielding effect of the lip lines after applying Examples 1, 4, and 5 and Comparative Examples 1 to 3 to the artificial leather.

無no

Claims (9)

一種油包水型的唇部化妝品組合物，其包含一水溶性聚合物、一蠟及一漿料。A water-in-oil type lip cosmetic composition comprising a water-soluble polymer, a wax and a slurry. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，該水溶性聚合物是選自瓊脂、纖維素膠、卡波姆、羥乙基纖維素、羥甲基纖維素、羥丙基纖維素、膨潤土、聚乙烯醇、聚乙酸乙烯酯、聚乙烯吡咯烷酮、聚氨酯、果膠、澱粉及黃原膠中的一種以上。The cosmetic composition for a lip according to claim 1, wherein the water-soluble polymer is selected from the group consisting of agar, cellulose gum, carbomer, hydroxyethyl cellulose, hydroxymethyl cellulose, and hydroxy group. One or more of propyl cellulose, bentonite, polyvinyl alcohol, polyvinyl acetate, polyvinylpyrrolidone, polyurethane, pectin, starch, and xanthan gum. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，以組合物總重量計，包含0.5~40重量%的該水溶性聚合物。The cosmetic composition for a lip according to claim 1, wherein the water-soluble polymer is contained in an amount of 0.5 to 40% by weight based on the total weight of the composition. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，該蠟是選自微晶蠟、天然地蠟、蜜蠟、小燭樹蠟、巴西棕櫚蠟、精鍊地蠟、石蠟、褐煤蠟、日本蠟、可可脂及合成蠟中的一種以上。The cosmetic composition for a lip according to claim 1, wherein the wax is selected from the group consisting of microcrystalline wax, natural wax, beeswax, candelilla wax, carnauba wax, refined ceresin wax, and paraffin wax. One or more of montan wax, Japanese wax, cocoa butter, and synthetic wax. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，以組合物總重量計，包含0.5~4重量%的該蠟。The cosmetic composition for a lip according to claim 1, wherein the wax is contained in an amount of 0.5 to 4% by weight based on the total weight of the composition. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，該漿料是選自氫化蓖麻油異硬脂酸酯、雙-二甘油多醯基己二酸酯-2、氫化聚苯乙烯*乙烯/丙烯/苯乙烯共聚物*丁稀/乙烯/苯乙烯共聚物、油酸/亞油酸/亞麻酸聚甘油酯、礦酯、礦物油*辛酸癸酸甘油三酯*氫化苯乙烯/異戊二烯共聚物、雙-羥基月桂基二甲聚矽氧烷/異佛爾酮二異氰酸酯共聚物、植物固醇/異硬脂醇/鯨蠟醇/硬脂醇/山崳醇二聚亞油酸酯中的一種以上。The cosmetic composition for a lip according to claim 1, wherein the slurry is selected from the group consisting of hydrogenated castor oil isostearate, bis-diglyceryl polydecyl adipate-2, hydrogenated poly Styrene*ethylene/propylene/styrene copolymer*butylene/ethylene/styrene copolymer, oleic acid/linoleic acid/linolenic acid polyglycerol ester, mineral ester, mineral oil* caprylic acid triglyceride* hydrogenated benzene Ethylene/isoprene copolymer, bis-hydroxylauryl dimethylpolysiloxane/isophorone diisocyanate copolymer, phytosterol/isostearyl alcohol/cetyl alcohol/stearyl alcohol/behenyl alcohol More than one of dimerized linoleate. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，以組合物總重量計，包含5~40重量%的該漿料。The cosmetic composition for a lip according to claim 1, wherein the slurry is contained in an amount of 5 to 40% by weight based on the total weight of the composition. 如申請專利範圍第1項所述之唇部用化妝品組合物，其中，該組合物劑型化為口紅、潤唇膏、護唇膏、唇筆、唇蜜或唇彩的形狀。The cosmetic composition for a lip according to claim 1, wherein the composition is formulated into a shape of a lipstick, a lip balm, a lip balm, a lip pencil, a lip gloss or a lip gloss. 一種口紅，係為如申請專利範圍第1項至第7項中任一項所述之唇部化妝品組合物成型而製備的。A lipstick prepared by molding a lip cosmetic composition according to any one of claims 1 to 7.