KR102672796B1 - Solid cosmetic composition comprising silicone-urethane-based polymer - Google Patents
Solid cosmetic composition comprising silicone-urethane-based polymer Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 102
- 239000002537 cosmetic Substances 0.000 title claims abstract description 49
- 229920000642 polymer Polymers 0.000 title claims abstract description 29
- 239000007787 solid Substances 0.000 title claims abstract description 27
- 238000009472 formulation Methods 0.000 claims abstract description 23
- 229920002050 silicone resin Polymers 0.000 claims abstract description 13
- 229920001577 copolymer Polymers 0.000 claims abstract description 12
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 11
- -1 bis-hydroxyethoxy Chemical group 0.000 claims abstract description 8
- 229940008099 dimethicone Drugs 0.000 claims abstract description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 8
- 239000004615 ingredient Substances 0.000 claims description 7
- 210000004709 eyebrow Anatomy 0.000 claims description 4
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 claims description 2
- 229940088638 glycereth-7 Drugs 0.000 claims description 2
- 210000004209 hair Anatomy 0.000 claims description 2
- 229940072106 hydroxystearate Drugs 0.000 claims description 2
- 239000002210 silicon-based material Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 238000011161 development Methods 0.000 abstract description 19
- 230000002688 persistence Effects 0.000 abstract description 19
- 239000000843 powder Substances 0.000 abstract description 10
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 abstract description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 27
- 238000005259 measurement Methods 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 239000002649 leather substitute Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000020897 Formins Human genes 0.000 description 1
- 108091022623 Formins Proteins 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- ULGYAEQHFNJYML-UHFFFAOYSA-N [AlH3].[Ca] Chemical compound [AlH3].[Ca] ULGYAEQHFNJYML-UHFFFAOYSA-N 0.000 description 1
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229940087068 glyceryl caprylate Drugs 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 229940114937 microcrystalline wax Drugs 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- SMYKBXMWXCZOLU-UHFFFAOYSA-N tris-decyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCC)C(C(=O)OCCCCCCCCCC)=C1 SMYKBXMWXCZOLU-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
본 발명은 실리콘-우레탄 중합체를 적용시켜 포함한 고형상 화장료 조성물에 있어서, 보다 상세하게는 상기 고형상 화장료 조성물은 실리콘레진으로 트리메칠실록시실리케이트를 제외하고 실리콘-우레탄 중합체로 비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트를 사용하여 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 고형상 화장료 조성물에 관한 것이다.The present invention relates to a solid cosmetic composition comprising a silicone-urethane polymer. More specifically, the solid cosmetic composition is a silicone resin excluding trimethylsiloxysilicate and a silicone-urethane polymer containing bis-hydroxyethoxy. A solid cosmetic composition with excellent water resistance, color persistence, color development, and spreadability by using propyl dimethicone/IPDI copolymer ethyl carbamate to develop a formulation that does not significantly increase hardness and improves the phenomenon of the formulation falling like powder. It's about.
Description
본 발명은 실리콘 레진을 제외하고 우레탄계 폴리머를 포함하여 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상과 내수성, 색상 지속성, 발색력 및 발림성이 우수한 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition that contains a urethane-based polymer excluding silicone resin, does not significantly increase hardness, has a powder-like formulation, and is excellent in water resistance, color persistence, color development, and spreadability.
실리콘 레진을 적용한 고형상 화장품은 내수성, 색상 지속성을 나타내는 특성이 있으나 해당 성분이 많이 사용될수록 경도가 상승하여 딱딱한 사용감이 관찰되며, 메이크업 후 시간이 지남에 따라 제형이 가루와 같이 떨어지는 현상이 나타나는 등의 문제가 있었다. Solid cosmetics using silicone resin have the characteristics of water resistance and color persistence, but as more of the ingredient is used, the hardness increases and a hard feeling is observed. Over time after makeup, the formulation falls off like powder, etc. There was a problem.
이에, 본 발명자들은 종래기술의 문제점을 극복하기 위해 예의 연구노력한 결과, 본 발명에서 구현한 실리콘-우레탄 중합체를 적용시켜 포함하므로써, 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 현상을 가지는 것을 확인하고 본 발명을 완성하게 되었다.Accordingly, the present inventors have made diligent research efforts to overcome the problems of the prior art, and as a result, by applying and including the silicone-urethane polymer implemented in the present invention, the hardness does not increase significantly and the phenomenon of the formulation falling like powder has been improved. By devising a formulation, it was confirmed that it had excellent water resistance, color persistence, color development, and spreadability, and the present invention was completed.
따라서, 본 발명의 내수성, 색상 지속성, 발색력 및 발림성이 우수하도록 실리콘-우레탄계 폴리머 중합체를 적용시킨 고형상 화장료 조성물을 제공하는 데 있다.Therefore, the object of the present invention is to provide a solid cosmetic composition to which a silicone-urethane-based polymer is applied to have excellent water resistance, color persistence, color development, and spreadability.
상기 목적을 달성하기 위하여, 본 발명은 실리콘 레진을 제외하고 실리콘-우레탄계 폴리머를 포함하여 제조된 고형상 화장료 조성물에 있어서, 상기 고형상 화장료 조성물은 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a solid cosmetic composition manufactured including a silicone-urethane-based polymer excluding silicone resin, wherein the hardness of the solid cosmetic composition does not increase significantly and the formulation falls like powder. By designing a formulation that improves the phenomenon, we provide a cosmetic composition with excellent water resistance, color persistence, color development, and spreadability.
본 발명의 실시예에 따른 실리콘-우레탄 중합체를 적용시켜 포함한 고형상 화장료 조성물에 따르면, 상기 고형상 화장료 조성물은 실리콘레진으로 트리메칠실록시실리케이트를 제외하고 실리콘-우레탄 중합체로 비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트를 사용하여 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 화장 효과를 제공하는 것이다.According to a solid cosmetic composition comprising a silicone-urethane polymer according to an embodiment of the present invention, the solid cosmetic composition is a silicone resin, excluding trimethylsiloxysilicate, and a silicone-urethane polymer, including bis-hydroxyethoxy. By using propyl dimethicone/IPDI copolymer ethyl carbamate, we designed a formulation that does not significantly increase the hardness and improves the phenomenon of the formulation falling like powder, providing a cosmetic effect with excellent water resistance, color persistence, color development, and spreadability. It is done.
도 1은 본 발명에 따른 화장료 조성물의 Saturation(채도) 증감률에 대한 비교 그래프를 나타낸 사진이다.
도 2는 본 발명에 따른 화장료 조성물의 발색력을 나타낸 이미지이다.
도 3은 본 발명에 따른 화장료 조성물의 색상 지속력에 관한 그래프를 나타낸 것이다.
도 4는 본 발명에 따른 화장료 조성물의 색상 지속력에 관한 이미지를 나타낸 것이다.
도 5는 본 발명에 따른 화장료 조성물의 내수성 정도에 관한 그래프를 나타낸 것이다.
도 6은 본 발명에 따른 화장료 조성물의 내수성 정도에 관한 이미지를 나타낸 것이다.
도 7은 본 발명에 따른 화장료 조성물의 발림성 정도에 관한 이미지를 나타낸 것이다.
도 8은 본 발명에 따른 화장료 조성물의 경도에 관한 그래프를 나타낸 것이다.Figure 1 is a photograph showing a comparative graph of the increase/decrease rate of saturation of the cosmetic composition according to the present invention.
Figure 2 is an image showing the color development power of the cosmetic composition according to the present invention.
Figure 3 shows a graph regarding the color persistence of the cosmetic composition according to the present invention.
Figure 4 shows an image regarding the color sustainability of the cosmetic composition according to the present invention.
Figure 5 shows a graph regarding the degree of water resistance of the cosmetic composition according to the present invention.
Figure 6 shows an image regarding the degree of water resistance of the cosmetic composition according to the present invention.
Figure 7 shows an image of the spreadability of the cosmetic composition according to the present invention.
Figure 8 shows a graph regarding the hardness of the cosmetic composition according to the present invention.
아래에서는 첨부한 기술을 참조하여 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 본 발명을 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 하기에서 설명하는 실시예에 한정되지 않음은 당업자에게 자명할 것이다.Below, with reference to the attached technology, the present invention will be described in detail so that those skilled in the art can easily practice it. However, it will be apparent to those skilled in the art that the present invention can be implemented in various different forms and is not limited to the embodiments described below.
본 발명은 실리콘-우레탄계 폴리머 중합체를 적용하여 제조된 고형상 화장료 조성물에 있어서, 상기 고형상 화장료 조성물은 실리콘-우레탄 중합체를 적용시켜 포함하므로써, 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 화장 효과를 제공한다.The present invention relates to a solid cosmetic composition manufactured by applying a silicone-urethane polymer. As the solid cosmetic composition contains a silicone-urethane polymer, the hardness does not increase significantly and the formulation falls like powder. By designing an improved formulation, it provides cosmetic effects with excellent water resistance, color persistence, color development, and spreadability.
본 발명의 상기 실리콘-우레탄계 폴리머는 바람직하게는 비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트를 포함하는 것일 수 있으며, 상기 비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트 성분은 실리콘을 우레탄에 중합시켜 만든 성분으로서 우레탄의 탄성감을 가지면서도 건조되면서 피막을 형성하여 수분 증발을 방지하고 가벼운 마찰에 쉽게 닦이거나 지워지지 않는 특징이 있다. The silicone-urethane-based polymer of the present invention may preferably include bis-hydroxyethoxypropyl dimethicone/IPDI icopolymer ethyl carbamate, and the bis-hydroxyethoxypropyl dimethicone/I.P. PDI copolymer ethyl carbamate is a component made by polymerizing silicone into urethane. It has the elasticity of urethane, but forms a film as it dries to prevent moisture evaporation and is not easily wiped or erased by light friction.
이 때, 상기 실리콘-우레탄계 폴리머는 비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트, 비스-하이드록시라우릴다이메티콘/아이피디아이코폴리머(BisHydroxylaurylDimethicone/IPDI Copolymer) 및 글리세레스-7하이드록시스테아레이트/아이피디아이코폴리머(Glycereth-7 Hydroxystearate/IPDI Copolymer) 등이 있으나, 이에 한정되는 것만은 아니다. 또한 이들을 탄화수소계 오일, 에스테르계 오일, 휘발성 실리콘 오일 및 실리콘 오일 등에 혼합된 것을 사용하거나 우레탄계 폴리머 자체만으로도 사용할 수 있으며, 이들 중 1종 이상을 혼합하여 사용할 수도 있다.At this time, the silicone-urethane polymer is bis-hydroxyethoxypropyl dimethicone/IPDI copolymer ethyl carbamate, bis-hydroxylauryl dimethicone/IPDI copolymer (BisHydroxylaurylDimethicone/IPDI Copolymer), and glycerol. Glycereth-7 Hydroxystearate/IPDI Copolymer, etc., but are not limited thereto. In addition, they can be used mixed with hydrocarbon oil, ester oil, volatile silicone oil, silicone oil, etc., or can be used alone with urethane polymer. One or more of these can also be mixed.
또한, 상기 실리콘-우레탄계 폴리머는 조성물 총 중량을 기준으로 10내지 20 중량%을 포함하고, 예를 들어, 상기 실리콘-우레탄계 폴리머는 조성물 총 중량에 대하여 10 중량% 이상, 11 중량% 이상 또는 12 중량% 이상 포함될 수 있다. 또한, 상기 실리콘-우레탄계 폴리머는 조성물 총 중량에 대하여 20 중량% 이하, 19 중량% 이하 또는 18 중량% 이하 포함될 수 있다. 바람직하게는 조성물 총 중량에 대하여 3중량% 이상, 15 중량% 이하를 포함하는 것일 수 있다. 그 함량이 10 중량% 미만이면 내수성이 감소하고, 20 중량%을 초과하면 점도가 증가하는 문제점이 있다. In addition, the silicone-urethane-based polymer includes 10 to 20% by weight based on the total weight of the composition. For example, the silicone-urethane-based polymer contains 10% by weight or more, 11% by weight or more, or 12% by weight based on the total weight of the composition. It may contain more than %. Additionally, the silicone-urethane-based polymer may be included in an amount of 20% by weight or less, 19% by weight or less, or 18% by weight or less based on the total weight of the composition. Preferably, it may contain 3% by weight or more and 15% by weight or less based on the total weight of the composition. If the content is less than 10% by weight, water resistance decreases, and if it exceeds 20% by weight, viscosity increases.
본 발명에 있어서, 상기 고형상 화장료 조성물은 실리콘 레진 또는 실리콘 수지를 포함하지 않는 것으로 보다 구체적으로 상기 실리콘 레진은 트리메칠실록시실리케이트 및 폴리프로필세스퀴옥세인 중에서 선택되는 어느 1종 이상을 포함하는 것일 수 있으며 상기 성분이 많이 사용될수록 경도가 상승하여 딱딱한 사용감이 관찰되고 메이크업 후 시간이 지남에 따라 제형이 굳어 가루와 같이 떨어지는 현상을 미연에 방지하여 개선하는 것일 수 있다. In the present invention, the solid cosmetic composition does not contain a silicone resin or a silicone resin. More specifically, the silicone resin includes at least one selected from trimethylsiloxysilicate and polypropylsesquioxane. As more of the above ingredients are used, the hardness increases and a hard feeling is observed. This may be improved by preventing the formulation from hardening and falling like powder over time after makeup.
본 발명의 상기 조성물의 경도는 125 내지 155 g/cm2인 것일 수 있으며, 바람직하게는 135 내지 145 g/cm2일 수 있다. 125 g/cm2미만이면 피부에 도포 시 제형이 불균일하게 도포거나 고형상이 파괴되고, 155 g/cm2를 초과하면 발색이 감소하는 문제점이 있다. The hardness of the composition of the present invention may be 125 to 155 g/cm 2 , preferably 135 to 145 g/cm 2 . If the content is less than 125 g/cm 2 , the formulation may be applied unevenly or the solid form may be destroyed when applied to the skin, and if it exceeds 155 g/cm 2 , there is a problem in that color development is reduced.
본 발명의 화장료의 용도 및 제형 등에 대해서는 특별한 제한이 없고, 예를 들면, 각 스틱 제형의 아이섀도우, 아이브로우, 아이라이너, 아이프라이머 또는 립크레용, 립라이너, 립스틱, 선스틱, 하이라이터 스틱, 컨투어 스틱, 파운데이션 스틱, 헤어 픽서 스틱, 아이브로우 픽서 스틱 제품 등을 들 수 있다. There are no particular restrictions on the use and formulation of the cosmetic of the present invention, and for example, each stick formulation of eye shadow, eyebrow, eyeliner, eye primer or lip crayon, lip liner, lipstick, sun stick, highlighter stick, These products include contour sticks, foundation sticks, hair fixer sticks, and eyebrow fixer sticks.
본 발명의 화장료 조성물은, 이들 화장료의 제조방법에 특별히 제한은 없고, 공지의 방법으로 제조할 수 있다. 바람직하게는, 혼합 용기에 왁스와 오일을 평량하여 투입하고 완전히 투명하게 액상으로 용융될 때까지 가열한 뒤 무기안료, 유기안료 및 펄 안료를 투입하여 아지믹서로 균일하게 분산시킨다. 이후 휘발성 오일에 분산시킨 실리콘-우레탄계 폴리머를 천천히 첨가하고 아지믹서로 균일하게 분산시킨다. 분산을 마친 뒤 휘발되어 감소한 휘발성 오일의 중량을 후첨하여 상기 조성물을 제조하는 것일 수 있다. The cosmetic composition of the present invention is not particularly limited in the manufacturing method of these cosmetics, and can be manufactured by a known method. Preferably, the wax and oil are added by weight to a mixing container, heated until completely transparent and melted into a liquid state, and then the inorganic pigment, organic pigment, and pearl pigment are added and uniformly dispersed using an azimixer. Afterwards, the silicone-urethane polymer dispersed in volatile oil is slowly added and uniformly dispersed using an azimixer. The composition may be prepared by post-adding the weight of the volatile oil that has been volatilized and reduced after dispersion.
이하, 본 발명을 구체적으로 설명하기 위해 실시예 및 실험예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예 및 실험예는 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예 및 실험예에 한정되는 것으로 해석되어서는 안된다. 본 발명의 실시예 및 실험예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되는 것이다.Hereinafter, the present invention will be described in detail using examples and experimental examples to specifically explain the present invention. However, the examples and experimental examples according to the present invention may be modified into various other forms, and the scope of the present invention should not be construed as being limited to the examples and experimental examples described in detail below. Examples and experimental examples of the present invention are provided to more completely explain the present invention to those with average knowledge in the art.
[실시예] 화장료 조성물 제조[Example] Preparation of cosmetic composition
하기 표 1과 같은 성분 및 함량으로, 실시예 및 비교예에 해당하는 화장료 조성물을 제조하였다(본 명세서에서 다르게 언급되지 않는 한, 성분 함량은 중량%이다).Cosmetic compositions corresponding to Examples and Comparative Examples were prepared with the ingredients and contents shown in Table 1 below (unless otherwise stated herein, ingredient contents are in weight%).
하기 표 1의 각 성분 및 함량(중량%)에 따라 계량한 후, 혼합 용기에 왁스와 오일을 평량하여 투입하고 완전히 투명하게 액상으로 용융될 때까지 80℃에서 90℃ 내에서 가열한 뒤 무기안료, 유기안료 및 펄 안료를 투입하여 아지믹서로 균일하게 1,000 rpm, 10 min 동안 분산시킨다. 이후 휘발성 오일에 분산시킨 실리콘-우레탄계 폴리머를 천천히 첨가하고 아지믹서로 균일하게 1,000 rpm, 10 min 동안 분산시킨다. 분산을 마친 뒤 휘발되어 감소한 휘발성 오일의 중량을 후첨하여 상기 조성물을 제조한다. After weighing according to each ingredient and content (% by weight) in Table 1 below, Add the wax and oil by weight to the mixing container, heat at 80℃ to 90℃ until completely transparent and melted into a liquid, then add the inorganic pigment, organic pigment, and pearl pigment and mix evenly with an azimixer at 1,000 rpm for 10 minutes. Disperse for min. Afterwards, the silicone-urethane polymer dispersed in volatile oil is slowly added and dispersed uniformly using an azimixer at 1,000 rpm for 10 min. After dispersion is completed, the weight of the volatile oil that has been volatilized and reduced is added to prepare the composition.
(CI 77891)titanium dioxide
(CI 77891)
[실험예] 실시예 및 비교예로 제조된 조성물의 특성 확인 [Experimental Example] Confirmation of properties of compositions prepared in Examples and Comparative Examples
상기 실시예 및 비교예에서 제조한 실리콘-우레탄 중합체를 화장료 조성물에 적용하여 우수한 발색력, 색상 지속력, 내수성 및 발림성을 가지는 것에 대해 데이터를 측정하였으며, 그 결과를 하기 표 2에 나타내었다.The silicone-urethane polymer prepared in the above Examples and Comparative Examples was applied to a cosmetic composition and data were measured for excellent color development, color persistence, water resistance, and spreadability, and the results are shown in Table 2 below.
총 10명의 연구대상자로 시작하였으며, 모든 연구대상자가 시험 전 과정을 성실하게 참여하였다. 연구대상자들의 평균 연령은 26.6 ± 2.0세로 최고 연령은 29세, 최저 연령은 25세였다. The study started with a total of 10 subjects, and all subjects faithfully participated in the entire testing process. The average age of the study subjects was 26.6 ± 2.0 years, with the highest age being 29 years and the lowest age being 25 years.
(채도변화율)(Saturation change rate)
실험예 1: 발색력 측정Experimental Example 1: Measurement of color development
상기 표 1에 표기된 조성으로 제조한 화장료 조성물에 적용하여 발색력을 평가하고 상기 표 2, 도 1 및 도 2에 나타내었다. The coloring power was evaluated by applying it to the cosmetic composition prepared with the composition shown in Table 1 and shown in Table 2 and Figures 1 and 2.
본 발명의 발색력은 실시예 및 비교예의 조성물을 1회 도포했을 때와 3회 도포했을 때와의 사진을 촬영, Saturation(채도)의 변화율을 산출하여 확인하였다. 이 때 촬영 기기는 VISIA-CR(Canfield Scientific, Inc., U.S.A)을 사용하였으며. Saturation(채도) 값이 감소할수록 기존보다 색상이 퇴색됨을 나타내고, 제품 1회 도포 후와 3회 도포 후의 Saturation(채도) 변화율이 적을수록, 발색이 더 우수한 것으로 판단하였다(측정 기기: Image Pro Analyzer (Media Cybernetics, Inc., U.S.A). The color development power of the present invention was confirmed by taking pictures of the compositions of Examples and Comparative Examples when applied once and three times and calculating the rate of change in saturation. At this time, the imaging device used was VISIA-CR (Canfield Scientific, Inc., U.S.A.). As the saturation value decreases, the color fades compared to before, and the smaller the rate of change in saturation after applying the product once and three times, the better the color development was judged to be (Measurement device: Image Pro Analyzer ( Media Cybernetics, Inc., U.S.A).
본 발명의 도 1은 본 발명에서 구현한 고형상 화장료 조성물의 Saturation(채도) 증감률에 대한 비교 그래프를, 도 2는 본 발명에서 구현한 고형상 화장료 조성물의 발색력을 나타낸 이미지인 것으로, 상기 도 1에 나타낸 실리콘-우레탄계 폴리머를 포함하여 제조된 고형상 화장료 조성물은 도 2에 나타난 바와 같이 3회 도포 후 발색된 정도가 우수한 것으로 육안으로 비교가 가능하여 이에 대하여 확인을 하였으며, 실제로 비교예로 제조되었을 때보다 선명하게 색상이 발현이 되는 차이가 있음을 확인할 수 있었다. 또한, 도 1에 나타난 바와 같이 실시예 1과 비교예 1로 제조된 조성물을 각각 3회 도포 후 saturation(채도) 증감률은 saturation의 변화율이 적을수록 발색이 더 우수한 것으로 판단되는 것으로, 측정 기기로 제형 발색 사진의 영역을 지정하여 분석한 결과 각각 약 11.7%, 30.2%로 나타남에 따라, 실시예로 제조된 제품이 비교예로 제조된 제품에 비해 발색이 더 우수하게 나타나는 것을 확인할 수 있었다. Figure 1 of the present invention is a comparative graph of the saturation increase/decrease rate of the solid cosmetic composition implemented in the present invention, and Figure 2 is an image showing the color development power of the solid cosmetic composition implemented in the present invention. The solid cosmetic composition manufactured including the silicone-urethane polymer shown in 1 was confirmed to have excellent color development after three applications as shown in Figure 2, and it was possible to compare it with the naked eye. It was actually manufactured as a comparative example. It was confirmed that there was a difference in the color being expressed more clearly than before. In addition, as shown in Figure 1, the rate of change in saturation after applying the compositions prepared in Example 1 and Comparative Example 1 three times each shows that the smaller the rate of change in saturation, the better the color development, as measured by a measuring device. As a result of analyzing the area of the formulation color photo, it was found to be about 11.7% and 30.2%, respectively, confirming that the product manufactured in the example had better color development than the product manufactured in the comparative example.
실험예 2. 색상 지속력 측정Experimental Example 2. Measurement of color persistence
상기 표 1에 표기된 조성으로 제조한 화장료 조성물에 적용하여 색상 지속력을 평가하고 상기 표 2, 도 3 및 도 4에 나타내었다. Color persistence was evaluated by applying it to the cosmetic composition prepared with the composition shown in Table 1 and shown in Table 2, Figures 3 and 4.
본 발명의 색상 지속력은 실시예 및 비교예의 조성물을 각 시간 별 시험 부위의 L.value 값을 분석하여 지속력을 도출하여 측정하였다. 상기 L.value 값은 밝기를 나타내며 값이 증가할수록 기존보다 밝기가 밝아지는 것을 나타내는 것이다(측정 기기: Image Pro Analyzer (Media Cybernetics, Inc., U.S.A). The color persistence of the present invention was measured by analyzing the L.value of the compositions of Examples and Comparative Examples at the test site for each time to derive the persistence. The L.value value indicates brightness, and as the value increases, the brightness becomes brighter than before (Measurement device: Image Pro Analyzer (Media Cybernetics, Inc., U.S.A.).
하기 식을 통해 본 발명의 색상지속력(%)에 대해 확인하였다.The color persistence (%) of the present invention was confirmed through the following formula.
본 발명의 도 3 및 도 4는 본 발명에서 구현한 고형상 화장료 조성물의 색상 지속력에 관하여 나타낸 그래프 및 이미지인 것으로, 상기 도 3에 나타낸 실리콘-우레탄계 폴리머를 포함하여 제조된 고형상 화장료 조성물은 도 4에 나타난 바와 같이 색상 지속력이 8시간 후에도 흐트러짐 없이 우수하게 유지되는 것을 육안으로 확인하였으며, 실제로 비교예로 제조되었을 때보다 가루가 떨어지는 현상이 적게 나타나고 색상이 오래 지속되는 것을 확인할 수 있었다. 또한, 도 3에 나타난 바와 같이 실시예 1과 비교예 1로 제조된 조성물을 사용 8시간 후 색상지속력(%)은 각각 약 91.9%, 87.7%로 나타남에 따라 실시예로 제조된 제품이 비교예로 제조된 제품에 비해 색상지속력이 높은 것을 확인할 수 있었다. FIGS. 3 and 4 of the present invention are graphs and images showing the color sustainability of the solid cosmetic composition implemented in the present invention, and the solid cosmetic composition manufactured including the silicone-urethane-based polymer shown in FIG. 3 is shown in FIG. As shown in Figure 4, it was confirmed with the naked eye that the color persistence was maintained well without fading even after 8 hours. In fact, it was confirmed that less powder falling off occurred and the color lasted longer than when manufactured as a comparative example. In addition, as shown in Figure 3, the color persistence (%) after 8 hours of use of the compositions prepared in Example 1 and Comparative Example 1 was approximately 91.9% and 87.7%, respectively, so that the products manufactured in Example 1 were similar to those of Comparative Example 1. It was confirmed that the color persistence was higher than that of products manufactured with .
실험예 3. 내수성(water-resistance) 측정Experimental Example 3. Water-resistance measurement
상기 표 1에 표기된 조성으로 제조한 화장료 조성물에 적용하여 내수성을 평가하고 상기 표 2, 도 5 및 도 6에 나타내었다. Water resistance was evaluated by applying it to the cosmetic composition prepared with the composition shown in Table 1, and shown in Table 2, Figures 5, and 6.
본 발명의 내수성은 실시예 및 비교예의 조성물을 각 단계별 촬영된 인조가죽의 L.value를 분석하여 3조각 모두 water resistance decision value가 50% 이상일 때, water-resistance가 있다고 판단하였으며 이를 확인하였다. The water resistance of the present invention was determined by analyzing the L.value of the artificial leather photographed at each stage of the composition of Examples and Comparative Examples, and when the water resistance decision value of all three pieces was 50% or more, it was judged to have water-resistance and this was confirmed.
보다 상세하게는, 바람직한 내수성 범위는 최소 90.0(%) 이상이며, 이 때 측정값은 제형을 도포한 인조가죽을 침수시켜 수중 교반한 후에 제형이 가죽에서 벗겨진 정도를 측정하여 나타낸 판정값을 일컫는 것이다. 본 발명에서 확인한 실시예 및 비교예로 제조된 조성물에서는 모두 내수성이 있다고 보여지며 100% 이상으로 나타난 수치는 도포된 제형이 벗겨지지 않은 것을 의미하는 것일 수 있다.More specifically, the desirable water resistance range is at least 90.0 (%), and in this case, the measured value refers to the judgment value expressed by measuring the degree to which the formulation is peeled off the leather after submerging the artificial leather to which the formulation has been applied and stirring it underwater. . The compositions prepared in the Examples and Comparative Examples confirmed in the present invention all appear to have water resistance, and a value of 100% or more may mean that the applied formulation is not peeled off.
하기 식을 통해 본 발명의 내수성 판정값에 대해 확인하였다(측정 기기: Image Pro Analyzer (Media Cybernetics, Inc., U.S.A).The water resistance judgment value of the present invention was confirmed through the following equation (Measurement device: Image Pro Analyzer (Media Cybernetics, Inc., U.S.A.).
본 발명의 도 5 및 도 6은 본 발명에서 구현한 고형상 화장료 조성물의 내수성 정도에 관하여 나타낸 그래프 및 이미지인 것으로, 상기 도 5에 나타낸 실리콘-우레탄계 폴리머를 포함하여 제조된 고형상 화장료 조성물은 도 6에 나타난 바와 같이 인조가죽 3개 모두 water resistance decision value가 50% 이상으로 유지됨에 따라 실시예로 제조된 조성물은 water resistance 효과가 있는 것을 확인할 수 있었다. FIGS. 5 and 6 of the present invention are graphs and images showing the degree of water resistance of the solid cosmetic composition implemented in the present invention, and the solid cosmetic composition manufactured including the silicone-urethane-based polymer shown in FIG. 5 is shown in FIG. As shown in Figure 6, the water resistance decision value of all three artificial leathers was maintained above 50%, confirming that the composition prepared in the example had a water resistance effect.
실험예 4. 발림성 측정Experimental Example 4. Spreadability measurement
상기 표 1에 표기된 조성으로 제조한 화장료 조성물에 적용하여 발림성을 평가하고 상기 표 2 에 나타내었다. Applying it to the cosmetic composition prepared with the composition shown in Table 1 above, spreadability was evaluated and shown in Table 2 above.
본 발명의 발림성은 실시예 및 비교예의 조성물을 하박 부위에 각각 10회씩 발색한 후 실시예가 비교예에 비하여 진한 발색을 나타냄에 따라 실시예로 제조된 조성물이 비교예로 제조된 조성물에 비해 발림성(pay-off)가 다소 높은 것을 확인할 수 있었다(도 7 참조). The spreadability of the present invention was determined after applying the compositions of the examples and comparative examples to the lower arm area 10 times each, and the examples showed darker coloring than the comparative examples. As a result, the compositions prepared in the examples were more spreadable than the compositions prepared in the comparative examples. pay-off) was confirmed to be somewhat high (see Figure 7).
실험예 5. 경도 측정Experimental Example 5. Hardness measurement
상기 표 1에 표기된 조성으로 제조한 화장료 조성물에 적용하여 경도를 평가하고 상기 표 3 에 나타내었다(측정 기기: SUN RHEO METER CR-3000EX). The hardness was evaluated by applying it to the cosmetic composition prepared with the composition shown in Table 1 and shown in Table 3 (Measurement device: SUN RHEO METER CR-3000EX).
상기 표 3은 실시예와 비교예의 조성물을 성형한 후 25℃에 보관하여 24시간이 경과한 후 절단 강도를 측정한 결과, 실시예로 제조된 조성물이 비교예로 제조된 조성물에 비하여 낮은 절단 강도를 나타냄에 따라 경도가 낮은 것을 확인하였다.Table 3 shows that the compositions of Examples and Comparative Examples were molded and then stored at 25°C and the cutting strength was measured after 24 hours. As a result, the cutting strength of the compositions prepared in Examples was lower than that of the compositions prepared in Comparative Examples. It was confirmed that the hardness was low.
보다 상세하게는, 본 발명의 도 8에서 경도는 실시예 및 비교예의 조성물을 각각 동일한 온도, 환경 조건에 보관하여 7일이 경과하였을 때 단면 7.4mm 몰딩 샘플의 절단 강도 (g/cm2)를 산출하여 비교 평가하여 나타내었다. 이 때, 실시예 및 비교예의 절단 강도를 비교하여 절단 강도가 낮은 샘플이 발림성이 더 부드러운 것으로 판단하였다. 여기서, 인장 거리는 6.0 mm 이고, 보관 조건은 25℃, 7일 항온조 보관 후 측정하였으며 몰딩 샘플 형태는 7.4 파이 몰드이다. 이에, 실시예 및 비교예의 조성물의 절단 강도를 측정한 결과 각각 약 133.7 g/cm2, 165.1 g/cm2로 나타남에 따라, 실시예로 제조된 조성물이 비교예로 제조된 조성물에 비해 발림성이 부드러운 것으로 확인할 수 있었다. More specifically, in Figure 8 of the present invention, the hardness is the cutting strength (g/cm 2 ) of a molding sample with a cross-section of 7.4 mm when 7 days have passed by storing the compositions of Examples and Comparative Examples at the same temperature and environmental conditions, respectively. It was calculated, compared and evaluated. At this time, by comparing the cutting strengths of the examples and comparative examples, it was determined that the sample with lower cutting strength had a softer spreadability. Here, the tensile distance is 6.0 mm, the storage conditions were measured after storage in a thermostat for 7 days at 25°C, and the molding sample shape is a 7.4 pie mold. Accordingly, as a result of measuring the cutting strength of the compositions of Examples and Comparative Examples, it was found to be about 133.7 g/cm 2 and 165.1 g/cm 2 , respectively. As a result, the compositions prepared in Examples were more spreadable than the compositions prepared in Comparative Examples. It was confirmed to be soft.
이를 통해 실리콘 레진을 적용한 고형상 화장료 조성물의 경우 경도가 상승하여 딱딱한 사용감과 시간이 지남에 따라 제형이 가루와 같이 떨어지는 현상 등의 문제를 본 발명의 실시예에서는 실리콘 수지 또는 실리콘 레진을 전혀 포함하지 않고 이를 개선하기 위해, 실리콘-우레탄계 폴리머 중합체를 포함하여 제조된 고형상 화장료 조성물은 경도가 크게 상승하지 않고, 제형이 가루와 같이 떨어지는 현상을 개선한 제형을 고안하여 내수성, 색상 지속성, 발색력 및 발림성이 우수한 것을 확인하였다.Through this, in the case of solid cosmetic compositions using silicone resin, the hardness increases, causing problems such as a hard feeling of use and the phenomenon of the formulation falling like powder over time. In the embodiment of the present invention, the silicone resin or silicone resin is not included at all. In order to improve this problem, a solid cosmetic composition manufactured including a silicone-urethane polymer polymer was designed to improve the phenomenon of the formulation falling like powder without significantly increasing the hardness, thereby improving water resistance, color persistence, color development, and spreadability. This was confirmed to be excellent.
Claims (6)
상기 실리콘-우레탄계 폴리머를 제외한 실리콘계 물질을 포함하지 않으며,
수상 성분을 포함하지 않는 것을 특징으로 하고,
상기 실리콘-우레탄계 폴리머는 조성물 총 중량을 기준으로 10 내지 20 중량% 포함되며,
조성물의 경도는 125 내지 155 g/cm2인 것을 특징으로 하는, 고형상 화장료 조성물.Including silicone-urethane polymers,
Does not contain silicone-based materials other than the silicone-urethane polymers,
Characterized by not containing aqueous ingredients,
The silicone-urethane polymer is contained in an amount of 10 to 20% by weight based on the total weight of the composition,
A solid cosmetic composition, characterized in that the hardness of the composition is 125 to 155 g/cm 2 .
상기 실리콘-우레탄계 폴리머는,
비스-하이드록시에톡시프로필다이메티콘/아이피디아이코폴리머에틸카바메이트, 비스-하이드록시라우릴다이메티콘/아이피디아이코폴리머(BisHydroxylaurylDimethicone/IPDI Copolymer) 및 글리세레스-7하이드록시스테아레이트/아이피디아이코폴리머(Glycereth-7 Hydroxystearate/IPDI Copolymer)로 이루어진 군에서 선택된 1종 이상인 것을 포함하는 것을 특징으로 하는, 고형상 화장료 조성물.
According to paragraph 1,
The silicone-urethane polymer is,
Bis-Hydroxyethoxypropyl Dimethicone/IPDI Copolymer Ethyl Carbamate, Bis-HydroxylaurylDimethicone/IPDI Copolymer and Glycereth-7Hydroxystearate/I. A solid cosmetic composition comprising at least one selected from the group consisting of PDI copolymer (Glycereth-7 Hydroxystearate/IPDI Copolymer).
상기 조성물은,
실리콘 레진 또는 실리콘 수지를 포함하지 않는 것을 특징으로 하는, 고형상 화장료 조성물.
According to paragraph 1,
The composition is,
A solid cosmetic composition, characterized in that it does not contain silicone resin or silicone resin.
상기 조성물은 각 스틱 제형의 아이섀도우, 아이브로우, 아이라이너, 아이프라이머 또는 립크레용, 립라이너, 립스틱, 선스틱, 하이라이터 스틱, 컨투어 스틱, 파운데이션 스틱, 헤어 픽서 스틱, 아이브로우 픽서 스틱 제품인 것을 특징으로 하는, 고형상 화장료 조성물.According to clause 1,
The composition is an eyeshadow, eyebrow, eyeliner, eye primer or lip crayon, lip liner, lipstick, sun stick, highlighter stick, contour stick, foundation stick, hair fixer stick, and eyebrow fixer stick product of each stick formulation. Characterized by solid cosmetic composition.
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