TW201341494A - 用於太陽能電池背板之黏膠 - Google Patents
用於太陽能電池背板之黏膠 Download PDFInfo
- Publication number
- TW201341494A TW201341494A TW102107154A TW102107154A TW201341494A TW 201341494 A TW201341494 A TW 201341494A TW 102107154 A TW102107154 A TW 102107154A TW 102107154 A TW102107154 A TW 102107154A TW 201341494 A TW201341494 A TW 201341494A
- Authority
- TW
- Taiwan
- Prior art keywords
- adhesive
- solar cell
- polyol
- isocyanate
- cell backsheet
- Prior art date
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 112
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 112
- 229920005862 polyol Polymers 0.000 claims abstract description 98
- -1 isocyanate compound Chemical class 0.000 claims abstract description 88
- 150000003077 polyols Chemical class 0.000 claims abstract description 86
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 62
- 150000001875 compounds Chemical class 0.000 claims abstract description 57
- 239000012948 isocyanate Substances 0.000 claims abstract description 56
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 47
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 20
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 20
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 14
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 12
- 229920001897 terpolymer Polymers 0.000 claims description 9
- 239000003822 epoxy resin Substances 0.000 claims description 7
- 229920000647 polyepoxide Polymers 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 abstract description 24
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 24
- 230000032683 aging Effects 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 33
- 229920005906 polyester polyol Polymers 0.000 description 20
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 18
- 125000003118 aryl group Chemical group 0.000 description 15
- 239000010410 layer Substances 0.000 description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 13
- 239000000126 substance Substances 0.000 description 12
- 230000009477 glass transition Effects 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 229920000570 polyether Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 239000004721 Polyphenylene oxide Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 229920000297 Rayon Polymers 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 230000007774 longterm Effects 0.000 description 8
- 239000013638 trimer Substances 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000002985 plastic film Substances 0.000 description 7
- 229920006255 plastic film Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 5
- 239000005058 Isophorone diisocyanate Substances 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000002334 glycols Chemical class 0.000 description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 5
- 239000012188 paraffin wax Substances 0.000 description 5
- 238000006068 polycondensation reaction Methods 0.000 description 5
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000010030 laminating Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 235000019809 paraffin wax Nutrition 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 239000003566 sealing material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- AAMHBRRZYSORSH-UHFFFAOYSA-N 2-octyloxirane Chemical compound CCCCCCCCC1CO1 AAMHBRRZYSORSH-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 238000009820 dry lamination Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000007719 peel strength test Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- JWTGRKUQJXIWCV-UHFFFAOYSA-N 1,2,3-trihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(O)C(O)CO JWTGRKUQJXIWCV-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- LSZMEVZPFPOJIT-UHFFFAOYSA-N 2,2-dimethoxyethoxy(ethenyl)silane Chemical compound COC(CO[SiH2]C=C)OC LSZMEVZPFPOJIT-UHFFFAOYSA-N 0.000 description 1
- AGHXQOHLJDLUCU-UHFFFAOYSA-N 2,3,3,4-tetramethylhex-1-ene-1,1-diamine Chemical compound CCC(C)C(C)(C)C(C)=C(N)N AGHXQOHLJDLUCU-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- CWNOEVURTVLUNV-UHFFFAOYSA-N 2-(propoxymethyl)oxirane Chemical compound CCCOCC1CO1 CWNOEVURTVLUNV-UHFFFAOYSA-N 0.000 description 1
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 1
- SITYOOWCYAYOKL-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(3-dodecoxy-2-hydroxypropoxy)phenol Chemical compound OC1=CC(OCC(O)COCCCCCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 SITYOOWCYAYOKL-UHFFFAOYSA-N 0.000 description 1
- MFAWEYJGIGIYFH-UHFFFAOYSA-N 2-[4-(trimethoxymethyl)dodecoxymethyl]oxirane Chemical compound C(C1CO1)OCCCC(C(OC)(OC)OC)CCCCCCCC MFAWEYJGIGIYFH-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 description 1
- VAYMIYBJLRRIFR-UHFFFAOYSA-N 2-tolyl isocyanate Chemical compound CC1=CC=CC=C1N=C=O VAYMIYBJLRRIFR-UHFFFAOYSA-N 0.000 description 1
- ZKAPVLMBPUYKKP-UHFFFAOYSA-N 2-undecyloxirane Chemical compound CCCCCCCCCCCC1CO1 ZKAPVLMBPUYKKP-UHFFFAOYSA-N 0.000 description 1
- LBIHNTAFJVHBLJ-UHFFFAOYSA-N 3-(triethoxymethyl)undec-1-ene Chemical compound C(=C)C(C(OCC)(OCC)OCC)CCCCCCCC LBIHNTAFJVHBLJ-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- DFYGYTNMHPUJBY-UHFFFAOYSA-N 4-(trimethoxymethyl)dodecane-1-thiol Chemical compound SCCCC(C(OC)(OC)OC)CCCCCCCC DFYGYTNMHPUJBY-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- BAWKIVWMQSQMAX-UHFFFAOYSA-N C(=C)C(C(C)(C)OC)CCCCCCCC Chemical compound C(=C)C(C(C)(C)OC)CCCCCCCC BAWKIVWMQSQMAX-UHFFFAOYSA-N 0.000 description 1
- VXLHENRCUVMBIR-UHFFFAOYSA-N C(=C)C(C(OC)(OC)C)CCCCCCCC Chemical compound C(=C)C(C(OC)(OC)C)CCCCCCCC VXLHENRCUVMBIR-UHFFFAOYSA-N 0.000 description 1
- JZHKIUBMQMDQRG-UHFFFAOYSA-N C(=C)C(C(OC)(OC)OC)CCCCCCCC Chemical compound C(=C)C(C(OC)(OC)OC)CCCCCCCC JZHKIUBMQMDQRG-UHFFFAOYSA-N 0.000 description 1
- ZMVUAAWOARKYDT-UHFFFAOYSA-N C(=C)C(C(OCCOC)(OCCOC)CC)CCCCCCCC Chemical compound C(=C)C(C(OCCOC)(OCCOC)CC)CCCCCCCC ZMVUAAWOARKYDT-UHFFFAOYSA-N 0.000 description 1
- UCMUEHUSODZYBG-UHFFFAOYSA-N C(=C)C(C(OCCOC)(OCCOC)OCCOC)CCCCCCCC Chemical compound C(=C)C(C(OCCOC)(OCCOC)OCCOC)CCCCCCCC UCMUEHUSODZYBG-UHFFFAOYSA-N 0.000 description 1
- LRLBBIDLIMSRSR-UHFFFAOYSA-N C(=C)C(C(OCOCC)(OCOCC)OCOCC)CCCCCCCC Chemical compound C(=C)C(C(OCOCC)(OCOCC)OCOCC)CCCCCCCC LRLBBIDLIMSRSR-UHFFFAOYSA-N 0.000 description 1
- UFJAJMCJOSRTQN-UHFFFAOYSA-N C(C)C(CCCCCCCCC)(OCCOC)CC Chemical compound C(C)C(CCCCCCCCC)(OCCOC)CC UFJAJMCJOSRTQN-UHFFFAOYSA-N 0.000 description 1
- MTDLVDBRMBSPBJ-UHFFFAOYSA-N C(C1CO1)OCCCC(C(OCC)(OCC)OCC)CCCCCCCC Chemical compound C(C1CO1)OCCCC(C(OCC)(OCC)OCC)CCCCCCCC MTDLVDBRMBSPBJ-UHFFFAOYSA-N 0.000 description 1
- WNFLEJVXKSUIJP-UHFFFAOYSA-N C(C1CO1)OCCCC(CCCCCCCCC)(OCC)OCC Chemical compound C(C1CO1)OCCCC(CCCCCCCCC)(OCC)OCC WNFLEJVXKSUIJP-UHFFFAOYSA-N 0.000 description 1
- LKYCIZFMSSPSQN-UHFFFAOYSA-N C(CC)C(C(OC)(OC)C)CCCCCCCC Chemical compound C(CC)C(C(OC)(OC)C)CCCCCCCC LKYCIZFMSSPSQN-UHFFFAOYSA-N 0.000 description 1
- VPLKXGORNUYFBO-UHFFFAOYSA-N C1(CC2C(CC1)O2)CCC(C(OC)(OC)OC)CCCCCCCC Chemical compound C1(CC2C(CC1)O2)CCC(C(OC)(OC)OC)CCCCCCCC VPLKXGORNUYFBO-UHFFFAOYSA-N 0.000 description 1
- AKCJPWFKCRGCSD-ZETCQYMHSA-N CC(C)[C@@H](C(=O)OC(=O)C(C)(C)CO)NO Chemical compound CC(C)[C@@H](C(=O)OC(=O)C(C)(C)CO)NO AKCJPWFKCRGCSD-ZETCQYMHSA-N 0.000 description 1
- YNZWBRRDIHXALL-UHFFFAOYSA-N CCCCCCCC(CC(OC(=C)C)OC(=C)C)COCC1CO1 Chemical compound CCCCCCCC(CC(OC(=C)C)OC(=C)C)COCC1CO1 YNZWBRRDIHXALL-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- KRWKYUMVNGWTNM-UHFFFAOYSA-N SCCCC(C(OCC)(OCC)OCC)CCCCCCCC Chemical compound SCCCC(C(OCC)(OCC)OCC)CCCCCCCC KRWKYUMVNGWTNM-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004826 Synthetic adhesive Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- TUEIURIZJQRMQE-UHFFFAOYSA-N [2-(tert-butylsulfamoyl)phenyl]boronic acid Chemical compound CC(C)(C)NS(=O)(=O)C1=CC=CC=C1B(O)O TUEIURIZJQRMQE-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 125000005055 alkyl alkoxy group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- FLPKSBDJMLUTEX-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)(CCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FLPKSBDJMLUTEX-UHFFFAOYSA-N 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- WTNDADANUZETTI-UHFFFAOYSA-N cyclohexane-1,2,4-tricarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C(C(O)=O)C1 WTNDADANUZETTI-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical class CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- STWFZICHPLEOIC-UHFFFAOYSA-N decylcyclohexane Chemical compound CCCCCCCCCCC1CCCCC1 STWFZICHPLEOIC-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- ACYQDCZIQOLHRX-UHFFFAOYSA-M dodecanoate;trimethylstannanylium Chemical compound CCCCCCCCCCCC(=O)O[Sn](C)(C)C ACYQDCZIQOLHRX-UHFFFAOYSA-M 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- GWCHPNKHMFKKIQ-UHFFFAOYSA-N hexane-1,2,5-tricarboxylic acid Chemical compound OC(=O)C(C)CCC(C(O)=O)CC(O)=O GWCHPNKHMFKKIQ-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- HHACNQLZWJFHIC-UHFFFAOYSA-N isocyano cyanate Chemical compound [C-]#[N+]OC#N HHACNQLZWJFHIC-UHFFFAOYSA-N 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- LATKICLYWYUXCN-UHFFFAOYSA-N naphthalene-1,3,6-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 LATKICLYWYUXCN-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- MBAUOPQYSQVYJV-UHFFFAOYSA-N octyl 3-[4-hydroxy-3,5-di(propan-2-yl)phenyl]propanoate Chemical compound OC1=C(C=C(C=C1C(C)C)CCC(=O)OCCCCCCCC)C(C)C MBAUOPQYSQVYJV-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- UJJLJRQIPMGXEZ-UHFFFAOYSA-N tetrahydro-2-furoic acid Chemical compound OC(=O)C1CCCO1 UJJLJRQIPMGXEZ-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/58—Epoxy resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4045—Mixtures of compounds of group C08G18/58 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
- C08G18/4269—Lactones
- C08G18/4277—Caprolactone and/or substituted caprolactone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6283—Polymers of nitrogen containing compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6644—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
- C08G18/7642—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/049—Protective back sheets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesive Tapes (AREA)
- Photovoltaic Devices (AREA)
Abstract
本發明之一目的係提供一種用於太陽能電池背板之黏膠,其於固化後對薄膜具有極佳初始黏性,於高溫下具有高黏性,並且具有長期抗水解性以及亦具有良好整體平衝。另一目的係提供一種藉由利用該黏膠所獲得之太陽能電池背板和一太陽能電池模組。揭露一種藉由混合(A)末端具有異氰酸酯基之胺基甲酸酯預聚物與(B)多元醇所獲得用於太陽能電池背板之黏膠,其中藉由反應含羥基化合物與異氰酸酯化合物獲得該胺基甲酸酯預聚物(A),以及該含羥基化合物包含一聚己內酯多元醇。該用於太陽能電池背板之黏膠於固化後對薄膜具有極佳初始黏性,於高溫下具有高黏性,並且具有長期抗水解性以及亦具有良好整體平衝。
Description
本專利申請案在巴黎公約第4條之規定下聲稱擁有2012年3月19日於日本提出之日本專利申請案號2012-062229之優先權,藉由引述將其全部內容併入於此。
本發明係關於一種用於太陽能電池背板之黏膠。更明確而言,本發明係關於一種藉由利用該黏膠所獲得之太陽能電池背板,以及一種藉由利用該太陽能電池背板所獲得之太陽能電池模組。
實際使用太陽能電池作為有用能源已獲得長足進展。太陽能電池包括各種之類型,以及已知典型太陽能電池為矽基太陽能電池、無機化合物太陽能電池、有機太陽能電池等。
這些太陽能電池通常具有保護接受陽光照射表面之保護膜。背面保護膜(背板)亦具有用於保護太陽能電池之反側受光表面,並且該背板具有各種極佳物理性質諸如耐候性、防水、隔熱、阻潮性以及阻氣性以避免太陽能電池於長期使用後造成性能上的劣化。
通常藉由化學處理法(酸洗),其係基於金屬材料暴露於含單獨或相互混合一或多種無機礦酸(硫酸、氫氯酸、硝酸、氫氟酸)之酸浴於適當稀釋和溫度中作用,接著至少一次最終水中清洗以除去該表面氧化層。
為獲得具有各種物理性質之片材,使用各種薄膜以及其實例包括金屬箔、金屬板和金屬沈積鍍膜,例如鋁、銅和鋼板;塑膠薄膜例如聚丙烯、聚氯乙烯、聚酯、氟樹脂和丙烯酸樹脂薄膜等。
為進一步改善其性能,亦使用層合這些薄膜之膠合層作為太陽能電池之背板。
藉由層合薄膜獲得膠合層之一實例示於第1圖。一背板10係由複數個薄膜11和12所構成之膠合層,以及該薄膜11和12係由置於其中之黏膠13所層合。
薄膜之層合通常係藉由乾式層合法,並且其需要對薄膜11和12具有足夠黏著性之黏膠13。
該背板10與一密封材料20、一太陽能電池胞30和一玻璃板40構成太陽能電池模組1(請看第3圖)。
由於太陽能電池模組1係長期暴露於室外,因此必需具有能夠抵抗高溫、高濕和陽光之耐用性。尤其是當使用低性能黏膠13時,致使薄膜11和12剝落而因此造成層合背板10受損。因此,用於太陽能電池背板之黏膠13必需甚至在長期暴露之下仍不會導致薄膜11之剝落。
已知用於太陽能電池背板之黏膠之實例為聚胺基甲酸酯。專利文件1至3揭露一種藉由利用聚胺基甲酸酯所製造之太陽能電池背板,其係混合多元醇之固化劑例如異氰酸酯以改善各種性能諸如耐候性和黏著性。
專利文件1利用藉由混合丙烯酸聚合物與異氰酸酯固化劑獲得之黏膠(請看專利文件1之表1和2)作為用於太陽能背板之黏膠,其可改善太陽能電池模組之各種性能(請看專利文件1之表3和4)。
專利文件2和3揭露一種藉由己內酯型多元醇與異氰酸樹脂反應而固化之聚胺基甲酸酯樹脂。
專利文件2揭露上述已固化樹脂係形成於阻氣基材上作為耐候性塗層(請看專利文件2,申請專利範圍第1項和[0044]至[0051])。專利文件2([0103]至[0105])中亦揭露其可塗佈合成自聚酯多元醇之聚胺基甲酸酯作為黏膠。
專利文件3揭露獲得自己內酯改性聚酯多元醇和二異氰酸酯之胺基甲酸酯預聚物可被用作為太陽能電池背板之底層材料(請看專利文件3,申請專利範圍第1項和圖1)。相同文件段落0057中揭露一種聚胺基甲酸酯型黏膠。
專利文件1至3中所使用之胺基甲酸酯可改善太陽能電池模組之耐候性和抗水解性。然而,其仍不易完全滿足高要求消費者。此外,對用於太陽能電池背板之黏膠耐用性要求已逐年遞增,因此對用於背板之黏膠要求具有較高之黏著性。由於太陽能電池模組主要被用於室外,因此要求在高溫下具有較高黏著性。
因此,用於太陽能電池背板之黏膠不僅對膠膜基材具有較高黏著性(尤指於固化後之較高黏著性),以及甚至在高溫下亦具有足夠黏著性,並且長期暴露該黏膠於室外時仍能維持極高抗水解性。當利用專利文件1至3之黏膠製成該太陽能電池背板時,該由複層膜所構成之背板若置於嚴酷環境下可能會相互剝離。
專利文件1:JP 2009-246360 A
專利文件2:WO 2010/005029 A1
專利文件3:JP 2011-077397 A
本發明因而可解決上述問題以及其目標係提供一種用於太陽能電池背板之胺基甲酸酯黏著劑,其於製造太陽能電池背板時對薄膜具有極佳初始黏度(或黏著性),以及在高溫下具有高黏性,並且亦具有長期足夠之抗水解性和極良好總體平衡;一藉由利用該黏膠所獲得之太陽能電池背板;以及一藉由利用該太陽能電池背板所獲得之太陽能電池模組。
本發明已經廣泛地研究並且驚訝地發現當獲得該胺基甲酸酯預聚物(A)之含羥基化合物中含有特定多元醇例如聚己內酯多元醇時,藉由混合胺基甲酸酯預聚物(A)與多元醇(B)可獲得聚胺基甲酸酯型黏膠,以及因而完成本發明。
換句話說,在一態樣中,本發明藉由混合(A)具有異氰酸酯端基之胺基甲酸酯預聚物與(B)多元醇可獲得用於太陽能電池背板之黏膠,其中藉由含羥基化合物與異氰酸酯化合物之反應獲得該胺基甲酸酯預聚物(A),以及該含羥基化合物含有聚己內酯多元醇。
在一具體實施例中,本發明提供一種用於太陽能電池背板之黏膠,其中該胺基甲酸酯預聚物(A)進一步含有異氰酸酯化合物之三聚物。
該胺基甲酸酯預聚物(A)較佳為具有2.0至4.0之異氰酸酯指數。
在一較佳具體實施例中,本發明提供一種用於太陽能電池背板之黏
膠,其中該含羥基化合物進一步含有三甲醇丙烷。
在一更佳具體實施例中,本發明提供一種用於太陽能電池背板之黏膠,其中該多元醇(B)包括具有酯鍵之多元醇。
該具有酯鍵之多元醇較佳為包括聚酯多元醇。
在另一較佳具體實施例中,本發明提供一種用於太陽能電池背板之黏膠,其進一步含有環氧樹脂。
又另一較佳具體實施例中,本發明提供一種用於太陽能電池背板之黏膠,其中該多元醇(B)具有10℃或更低之玻璃轉變溫度。
另一態樣中,本發明提供一種藉由利用上述用於太陽能電池背板之黏膠所獲得之太陽能電池背板。
在一較佳態樣中,本發明提供一種藉由利用上述太陽能電池背板所獲得之太陽能電池模組。
在一更佳態樣中,本發明提供一種具有(A)異氰酸酯端基之胺基甲酸酯預聚物與(B)多元醇之組合物,以獲得上述用於太陽能電池背板之黏膠。
藉由混合(A)具有異氰酸酯端基之胺基甲酸酯預聚物與(B)多元醇獲得根據本發明用於太陽能電池背板之黏膠,以及藉由含羥基化合物與異氰酸酯化合物之反應獲得該胺基甲酸酯預聚物(A),以及該含羥基化合物含有聚己內酯多元醇。因此,其於固化後對薄膜具有極佳初始黏度(或黏著性)並且在高溫下具有高黏性,以及亦具有高抗水解性而因此即使經過一段長時間仍可維持極佳黏性和極良好總體平衡。
當該胺基甲酸酯預聚物(A)進一步含有異氰酸酯化合物之三聚物時,可改善其抗熱性以及於高溫度下具有極佳抗水解性。
當該胺基甲酸酯預聚物(A)具有2.0至4.0之異氰酸酯指數時,可進一步改善其抗水解性以及即使於一段長時間之後仍具有極佳黏度。
該根據本發明用於太陽能電池背板之黏膠於高溫下即使在一段長時間之後仍具有極佳抗水解性,以及當該含羥基化合物進一步含有三甲醇丙烷時於固化後亦具有極佳黏著性。
用於根據本發明太陽能電池背板之黏膠中,當該多元醇(B)包括具有酯鍵之多元醇時,可大為改善其於固化後對薄膜之黏性。
當該多元醇具有含聚酯多元醇之酯鍵時,可進一步改善其於固化後對薄膜之黏性。
當該根據本發明用於太陽能電池背板之黏膠進一步含有環氧樹脂時,可更加改善其抗水解性,並且即使於一段長時間之後仍具有極佳之黏性。
在根據本發明用於太陽能電池背板之黏膠中,當該多元醇(B)具有10℃或更低之玻璃轉變溫度時,可改善其於固化後對薄膜之黏性以及維持相當平衡狀態之抗水解性。
由於根據本發明之太陽能電池背板係獲得自上述用於太陽能電池背板之黏膠,因此其在長期暴露於室外之後可避免薄膜從黏膠和從初步層合階段中剝落。
由於根據本發明之太陽能電池模組係獲得自上述太陽能電池背板,因此其較不易造成外觀不良以及亦具有極佳之耐用性。
根據本發明用於太陽能電池背板之黏膠係獲得自混合(A)具有異氰酸酯端基之胺基甲酸酯預聚物(此處有時亦稱為「胺基甲酸酯預聚物(A)」)與(B)多元醇。該胺基甲酸酯預聚物(A)與多元醇(B)反應後固化,因而可作為黏膠。
該胺基甲酸酯預聚物(A)係獲得自含羥基化合物與異氰酸酯化合物之反應,並且該含羥基化合物含有聚己內酯多元醇。
於此,該含羥基化合物,祇要其含有聚己內酯多元醇及可獲得本發明之目標黏膠,則含有通常用於製造胺基甲酸酯預聚物之含羥基化合物。
已知化合物可被用作為該含羥基化合物,並且在本發明中可能與該多元醇(B)重疊。含羥基化合物之特定實例包括屬於下列(1)至(7)群之化合物:(1)多元醇例如乙二醇、丙二醇、1,3-丙二醇、1,4-丁二醇、1,3-丁二醇、1,5-戊二醇、新戊二醇、1,6-己二醇、1,4-二(羥甲基)環己烷、雙酚A、氫化雙酚A、羥基新戊酸羥基新戊酯(hydroxypivalyl hydroxypivalate)、三甲醇乙烷、三甲醇丙烷、2,2,4-三甲基-1,3-戊二醇、甘油和己三醇;(2)各種聚醚乙二醇例如聚氧乙烯乙二醇、聚氧丙烯乙二醇、聚氧乙烯聚氧四亞甲基二醇、聚氧丙烯聚氧四亞甲基二醇和聚氧乙烯聚氧丙烯聚氧四亞甲基二醇;(3)藉由上述各種多元醇或聚醚乙二醇與各種含(環狀)醚鍵化合物例如氧化乙烯、氧化丙烯、四氫呋喃、乙基縮水
甘油醚、丙基縮水甘油醚、丁基縮水甘油醚、苯基縮水甘油醚和烯丙基縮水甘油醚之開環聚合反應獲得改性聚醚多元醇;(4)藉由一或多種上述各種多元醇和聚醚乙二醇與聚羧酸之共縮合作用獲得聚酯多元醇,該聚羧酸特別代表琥珀酸、己二酸、癸二酸、壬二酸、苯二甲酸、間苯二甲酸、對苯二甲酸、四氫酞酸、六氫酞酸、馬來酸、富馬酸、檸康酸(citraconic acid)、伊康酸(itaconic acid)、戊烯二酸、1,2,5-己烷三甲酸、1,4-環己烷二甲酸、1,2,4-苯三甲酸、1,2,5-苯三甲酸、1,2,4-環己三甲酸和2,5,7-萘三甲酸;(5)藉由一或多種上述各種多元醇和聚醚乙二醇與各種內酯例如ε-己內酯、δ-戊內酯和3-甲基-δ-戊內酯之聚縮合反應獲得內酯系聚酯多元醇,或藉由上述各種多元醇或聚醚乙二醇與聚羧酸和各種內酯之聚縮合反應獲得內酯改性聚酯多元醇;(6)於聚酯多元醇合成時藉由利用結合一或多種各種環氧化合物例如雙酚A型環氧化合物、氫化雙酚A型環氧化合物、單及/或多元醇之縮水甘油醚,以及一元酸及/或多元酸之縮水甘油酯獲得環氧改性聚酯多元醇;以及(7)聚酯聚醯胺多元醇、聚碳酸酯多元醇、丙烯酸多元醇、聚丁二烯多元醇、聚戊二烯多元醇、蓖麻油、蓖麻油衍生物、氫化蓖麻油、氫化蓖麻油衍生物、含羥基丙烯酸基共聚物、含羥基含氟化合物,或含羥基矽氧樹脂。
其亦可使用舉例來說脂肪族多元醇諸如藉由氧化乙烯、氧化丙烯和氧化丁烯之開環聚合反應利用諸如乙二醇、二乙二醇、1,2-丙二
醇、二丙二醇、1,3-丁二醇、1,4-丁二醇、1,6-己二醇、新戊二醇、三甲醇丙烷、甘油、異戊四醇和聚四亞甲基醚二醇之多元醇作為引發劑所獲得之聚合物或共聚物;具有環己基之多元醇,諸如藉由氧化乙烯、氧化丙烯和氧化丁烯之開環聚合反應利用環己烷二甲醇、環己二醇、氫化雙酚A和其乙二醇作為引發劑所獲得之聚合物或共聚物;具有芳香基之多元醇,諸如藉由添加氧化乙烯、氧化丙烯和氧化丁烯利用雙酚A、氫醌雙(2-羥乙基醚)、對苯二甲醇、對苯甲酸雙(β-羥乙)酯和其乙二醇作為引發劑所獲得之聚合物或共聚物;以及具有各種官能基之多元醇,例如具有一羧基之乙二醇如二甲醇基丙酸和雙酚酸,以及包括三級胺如N-甲基二乙醇胺之乙二醇。
可單獨或組合使用這些含羥基化合物。
本發明中,該含有羥基化合物含有「聚己內酯多元醇」。在本發明中,該「聚己內酯多元醇」意指藉由己內酯之開環聚合反應所獲得多元醇。例如,其含有藉由一或多種上述各種多元醇和聚醚乙二醇與ε-己內酯之聚縮合反應所獲得之聚己內酯多元醇,其屬於上述第(5)類,以及亦含有藉由一或多種上述各種多元醇和聚醚乙二醇與聚羧酸和ε-己內酯之聚縮合反應所獲得之改性聚己內酯多元醇。
由於該含羥基化合物含有聚己內酯多元醇,因此本發明用於太陽能電池背板之黏膠於固化後對薄膜具有極佳初始黏性和抗水解性(高溫下之黏性和長時間後之黏性)。
可根據已知方法獲得此類聚己內酯多元醇,更明確而言,係於催化劑存在下利用下列多元醇作為引發劑,藉由ε-己內酯之開環聚合反應而獲得。
該屬於ε-己內酯聚合引發劑之多元醇包括,例如乙二醇、二乙二醇、1,2-丙二醇、二丙二醇、1,3-丁二醇、1,4-丁二醇、1,6-己二醇、新戊二醇、三甲醇丙烷、甘油、異戊四醇和聚四亞甲基醚二醇。
在本發明中,該含羥基化合物較佳為更含有三甲醇丙烷。當該含羥基化合物含有三甲醇丙烷時,本發明用於太陽能電池背板之黏膠即使長期在高溫下仍具有極佳抗水解性,以及於固化後仍具有極佳初始黏性。
異氰酸酯化合物之實例包括脂族異氰酸酯、脂環族異氰酸酯和芳香族異氰酸酯,以及祗要可獲得本發明用於太陽能電池背板之標的黏膠,對該異氰酸酯化合物並無特殊限制。
此處,「脂族異氰酸酯」指具有一鏈狀羥鍵,其異氰酸酯直接結合至該羥鏈之化合物,以及亦具有無環狀羥鏈。雖然「脂族異氰酸酯」可能具有一芳香環,但是該芳香環並未直接結合異氰酸酯基。
此處,該芳香環不包含於環狀烴鏈內。
該「脂環族異氰酸酯」係一種具有一環狀烴鏈以及可能具有一鏈狀烴鏈之化合物。該異氰酸酯基可直接結合環狀烴鏈,或直接結合可能存在之鏈狀烴鏈。雖然該「脂環族異氰酸酯」可能含有一芳香環,但是該芳香環並未直接結合至該異氰酸酯基。
該「芳族異氰酸酯」指一種具有一芳香環之化合物,其異氰酸酯基係直接結合該芳香環。因此,其異氰酸酯基未直接結合芳香環之化合物被歸類成脂族異氰酸酯,或甚至分子內含有芳香環之脂環族異氰酸酯。
由於該異氰酸酯基係直接結合至芳香環,因此例如4,4'-二苯基甲烷二異氰酸酯(OCN-C6H4-CH2-C6H4-NCO)相當於芳香族異氰酸酯。另一方面,由於該異氰酸酯基並未直接結合至芳香環,因此例如二異氰酸二甲苯(OCN-CH2-C6H4-CH2-NCO)相當於脂族異氰酸酯,並且當二異氰酸二甲苯含有芳香環時直接與亞甲基相結合。
該芳香環可能融合二或多個苯環。
脂族異氰酸酯之實例包括1,4-二異氰酸丁烷、1,5-二異氰酸戊烷、1,6-二異氰酸己烷(此後亦稱為二異氰酸六亞甲酯)、1,6-二異氰酸-2,2,4-三甲基己烷、2,6-二異氰酸己酸甲酯(離胺酸二異氰酸酯)和1,3-雙(異氰酸甲基)苯(二異氰酸二甲苯)。
脂環族異氰酸酯之實例包括5-異氰酸-1-異氰酸甲基-1,3,3-三甲基環己烷(異佛爾酮二異氰酸酯)、1,3-雙(異氰酸甲基)環己烷(氫化二甲苯二異氰酸酯)、雙(4-異氰酸環己基)甲烷(氫化二苯甲烷二異氰酸酯)和1,4-二異氰酸環己烷。
芳香族異氰酸酯之實例包括4,4'-二苯甲烷二異氰酸酯、對-亞苯基二異氰酸酯和間-亞苯基二異氰酸酯。
可單獨或組合使用這些異氰酸酯化合物。
本發明中,祇要可獲得本發明標的胺基甲酸酯黏著劑,所使用異氰酸酯化合物並無特殊限制。較佳為選擇自脂族和脂環族異氰酸酯。明確而言,較佳為二異氰酸六亞甲酯、異佛爾酮二異氰酸酯和二甲苯二異氰酸酯,以及最佳為二甲苯二異氰酸酯。
該異氰酸酯化合物可含有上述異氰酸酯化合物之三聚物。
該異氰酸酯化合物之三聚物較佳為含有至少一選自異佛爾酮二異氰酸酯之三聚物和二異氰酸六亞甲酯之三聚物。
較佳為藉由含羥基化合物與進一步含上述異氰酸酯化合物三聚物之異氰酸酯化合物之反應獲得上述胺基甲酸酯預聚物(A)。該異氰酸酯化合物之三聚物較佳為含有至少一選自異佛爾酮二異氰酸酯之三聚物和二異氰酸六亞甲酯之三聚物。
本發明中,該胺基甲酸酯預聚物(A)較佳為具有2.0至4.0之異氰酸酯指數。當異氰酸酯指數於上述範圍內時,更能改善該用於太陽能電池背板黏膠之抗水解性,並且即使於長時間之後仍具有極佳黏性。
如此處所述,該異氰酸酯指數具有通常用於聚胺基甲酸酯技術領域中之涵義,以及意指在製造胺基甲酸酯預聚物(A)過程中含於異氰酸酯化合物內異氰酸酯基(NCO)對含於羥基化合物內羥基(OH)之當量比(即NCO/OH)。當(NCO/OH)比值超過1.0時,意指製造聚胺基甲酸酯預聚物過程中該羥基已完全耗盡而因此於胺基甲酸酯預聚物(A)之末端出現NCO基。
本發明中,祇要可與胺基甲酸酯預聚物(A)反應以及可製備成用於本發明太陽能電池背板之標的黏膠,對該多元醇(B)並無特殊限制,並且該多元醇可能與先前所述含羥基化合物相重疊。
如本發明之較佳具體實施例,該多元醇(B)較佳為包括具有一酯鍵之多元醇,以及更佳為具有一酯鍵之多元醇。祇要可獲得用於本發明太陽能電池背板之黏膠,對該具有一酯鍵之多元醇並無特殊限制,以及該多元醇含有通常所稱之聚酯多元醇和丙烯酸多元醇。
本發明中,該「聚酯多元醇」指一種「主鏈型」聚酯並且
「主鏈」內具有酯鍵和羥基之化合物。此羥基通常位於該主鏈之末端,以及作為與異氰酸酯基反應之官能基。
通常可藉由低分子量多元醇與二羧酸及其酐之縮聚合反應獲得該聚酯多元醇。亦即,其相當於此處第(4)類中說明「含羥基化合物」之範例。在本發明中,聚酯多元醇最佳為合成自間苯二甲酸。
本發明中,該「丙烯酸多元醇」指一種藉由具有羥基以及「側鏈」中具有酯鍵之(甲基)丙烯酸酯之加成聚合反應所獲得之化合物。
該「丙烯酸多元醇」可為具有羥基之(甲基)丙烯酸酯之均聚物,或帶有「其他聚合單體」之共聚物。該丙烯酸多元醇之羥基係與異氰酸酯基產生反應。
該「具有羥基之(甲基)丙烯酸酯」包括,例如2-羥乙基(甲基)丙烯酸酯、2-羥丙基(甲基)丙烯酸酯、3-羥丙基(甲基)丙烯酸酯、甘油單(甲基)丙烯酸酯,和4-羥丁基丙烯酸酯。
該「其他聚合單體」指除了「具有羥基之(甲基)丙烯酸酯」外之「具有乙烯雙鍵之自由基可聚合單體」。其特定實例包括(甲基)丙烯酸、(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丁酯、(甲基)丙烯酸環己酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸雙環戊酯、(甲基)丙烯酸異[廾伯]基酯、苯乙烯和乙烯基甲苯。
祇要可獲得本發明用於太陽能電池背板之標的黏膠,該多元醇(B)可含有除了具有酯鍵多元醇外之多元醇。例如,其可含有聚醚多元醇。該聚醚多元醇包括,例如聚氧四亞甲基二醇(PTMG)、聚氧丙烯二醇(PPG),和聚氧乙烯二醇(PEG)。
本發明之多元醇(B)較佳為具有10℃或更低,較佳為5℃或更低,以及最佳為-30℃至5℃之玻璃轉變溫度。當玻璃轉變溫度在上述範圍內時,可改善固化後對薄膜之初始黏度,並且對用於太陽能電池背板黏膠之抗水解性(高溫下黏性以及經過長時間後之黏性)能保持良好平衡。
此處該「玻璃轉變溫度」指依照下列方法所測得之值。利用示差掃描量熱儀(SII奈米科技DSC6220,製造自SII奈米科技公司),以5℃/分之溫度上升速率測定而其樣本之DSC曲線為5至15 mg時,則該DSC曲線之曲折點溫度為其玻璃轉變溫度。
根據本發明用於太陽能電池背板之黏膠係一種藉由混合(A)胺基甲酸酯預聚物與(B)多元醇所獲得之胺基甲酸酯黏膠。僅混合該兩種成分即可使其產生反應。其混合方法可利用一般的混合法。
該用於本發明太陽能電池背板之黏膠可含有用於改善長期耐候性之紫外線吸收劑。可使用羥基苯基三[口井]系化合物和其他市售紫外線吸收劑作為紫外線吸收劑。該「羥基苯基三[口井]系化合物」係一種羥基苯基衍生物連接至三[口井]衍生物之碳原子的三[口井]衍生物,以及其實例包括供應自BASF公司之TINUVIN 400、TINUVIN 405、TINUVIN 479、TINUVIN 477和TINUVIN 460(全部為商品名稱)。
用於太陽能電池背板之黏膠進一步含有受阻酚系化合物。該「受阻酚系化合物」通常指受阻酚系之化合物,並且祇要能獲得用於本發明太陽能電池背板之標的黏膠並無特殊限制。
受阻酚系化合物可使用市售之產品。該受阻酚系化合物係,例如供應自BASF公司之市售產品。其實例包括IRGANOX1010、IRGANOX1035、
IRGANOX1076、IRGANOX1135、IRGANOX1330和IRGANOX1520(全部為商品名稱)。該受阻酚系化合物被添加至黏膠作為抗氧化劑並且可被用於,例如結合亞磷酸鹽系抗氧化劑、硫醚系抗氧化劑,和胺系抗氧化劑。
該用於本發明太陽能電池背板之黏膠可進一步含有受阻胺系化合物。
該「受阻胺系化合物」通常指受阻胺系之化合物,並且祇要能獲得用於本發明太陽能電池背板之標的黏膠並無特殊限制。
受阻胺系化合物可使用市售之產品。該受阻胺系化合物之實例包括供應自BASF公司之TINUVIN 765、TINUVIN 111FDL、TINUVIN 123、TINUVIN 144、TINUVIN 152、TINUVIN 292和TINUVIN 5100(全部為商品名稱)。該受阻胺系化合物被添加至黏膠作為光安定劑並且可被用於,例如結合苯并***系化合物、苯甲酸酯系化合物,和苯并***化合物。
用於根據本發明太陽能電池背板之黏膠可進一步含有矽烷化合物。
矽烷化合物可使用,例如(甲基)丙烯氧基烷基三烷氧基矽烷、(甲基)丙烯氧基烷基烷基烷氧基矽烷、乙烯基三烷氧基矽烷、乙烯基烷基烷氧基矽烷、環氧矽烷、巰基矽烷,和異三聚氰酸矽烷。然而,該矽烷化合物並非僅侷限這些矽烷化合物。
「(甲基)丙烯氧基烷基三烷氧基矽烷」之實例包括3-(甲基)丙烯氧基丙基三甲氧基矽烷、3-(甲基)丙烯氧基丙基三乙氧基矽烷,和4-(甲基)丙烯氧基乙基三甲氧基矽烷。
「(甲基)丙烯氧基烷基烷基烷氧基矽烷」之實例包括3-(甲基)丙烯氧基
丙基甲基二甲氧基矽烷、3-(甲基)丙烯氧基丙基甲基二乙氧基矽烷、3-(甲基)丙烯氧基丙基乙基二乙氧基矽烷,和3-(甲基)丙烯氧基乙基甲基二甲氧基矽烷。
「乙烯基三烷氧基矽烷」之實例包括乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基二甲氧基乙氧基矽烷、乙烯基三(甲氧乙氧基)矽烷,和乙烯基三(乙氧甲氧基)矽烷。
「乙烯基烷基烷氧基矽烷」之實例包括乙烯基甲基二甲氧基矽烷、乙烯基乙基二(甲氧乙氧基)矽烷、乙烯基二甲基甲氧基矽烷,和乙烯基二乙基(甲氧乙氧基)矽烷。
例如,該「環氧矽烷」可被分類成縮水甘油類矽烷和環氧環己基類矽烷。該「縮水甘油類矽烷」具有縮水甘油醚氧基,以及其特定實例包括3-縮水甘油醚氧基甲基二異丙烯氧基矽烷、3-縮水甘油醚氧基丙基三甲氧基矽烷、3-縮水甘油醚氧基丙基三乙氧基矽烷,和3-縮水甘油醚氧基丙基二乙氧基矽烷。
該「環氧環己基類矽烷」具有3,4-環氧環己基,以其特定實例包括2-(3,4-環氧環己基)乙基三甲氧基矽烷,和2-(3,4-環氧環已基)乙基三乙氧基矽烷。
該「巰基矽烷」之實例包括3-巰基丙基三甲氧基矽烷和3-巰基丙基三乙氧基矽烷。
該「異三聚氰酸矽烷」之實例包括三(3-(三甲氧基矽烷基)丙基)異氰酸酯。
用於根據本發明太陽能電池背板之黏膠祇要可獲得用於太陽能電池背板之標的黏膠可進一步含有其他成分。
祇要可獲得用於根據本發明太陽能電池背板之標的黏膠,用於太陽能電池背板之黏膠內加入「其他成分」之時間點並無特殊限制。
下列為加入該其他成分之時間點:(1)當合成胺基甲酸酯預聚物(A)時,與含羥基化合物和異氰酸酯化合物一起加入該其他成分;(2)當藉由胺基甲酸酯預聚物(A)與多元醇(B)之反應合成胺基甲酸酯黏著劑時,與成分(A)和(B)一起加入該其他成分;以及(3)在藉由胺基甲酸酯預聚物(A)與多元醇(B)之反應合成胺基甲酸酯黏著劑之後,加入該其他成分。
該「其他成分」之實例包括增黏樹脂、顏料、增塑劑、阻燃劑、催化劑,和石蠟。
該「增黏樹脂」之實例包括苯乙烯系樹脂、萜烯系樹脂、脂族石油樹脂、芳香族石油樹脂、松香脂、丙烯酸樹脂,和聚酯樹脂(聚酯多元醇除外)。
該「顏料」之實例包括氧化鈦和碳黑。
該「增塑劑」之實例包括酞酸二辛酯、酞酸二丁酯、二異壬基酞酸酯、酞酸二辛酯,和礦油精。
該「阻燃劑」之實例包括鹵素基阻燃劑、磷系阻燃劑、銻基相阻燃劑,和金屬氫氧化物阻燃劑。
該「催化劑」之實例包括金屬催化劑諸如錫催化劑(月桂酸三甲錫、氫氧化三甲錫、辛酸亞錫、二月桂酸二丁基錫、二醋酸二丁基錫、馬來酸二丁基錫等),鉛類催化劑(油酸鉛、環烷酸鉛、辛烯酸鉛等),以及其他金屬催化劑(環烷酸金屬鹽諸如環烷酸鈷)和胺系催化劑諸如三乙烯二
胺、四甲基乙烯二胺、四甲基己烯二胺、二氮雜雙環烯烴,和二烷胺基烷基胺。
該「石蠟」較佳為石蠟諸如固體石蠟和微晶石蠟。
藉由利用旋轉式黏度計(TOKIMEC公司製造之BM型)測定用於太陽能電池背板黏膠之黏度。當溶液黏度於40%固體含量為4,000 mPa.s或更高時,將劣化黏膠之塗佈性。若進一步加入溶劑以降低黏度,而於低固體成分濃度下進行塗佈時,將劣化該太陽能電池背板之產量。
藉由混合上述胺基甲酸酯樹脂與加入適量其他成分可製造本發明太陽能電池背板之黏膠。祇要可獲得用於根據本發明太陽能電池背板之標的黏膠,該混合方法並無特殊限制。這些成分之混合順序亦無特殊限制。製造用於根據本發明太陽能電池背板之黏膠並不需要特殊混合方法和特殊混合順序。所獲得用於太陽能電池背板之黏膠於固化後對薄膜具有足夠初始黏性。由於該黏膠維持高度之極佳抗水解性,其於高溫下和經過長時間之後亦具有極佳黏著性,並且維持極佳總體平衡。
需要一種用於製造太陽能電池模組具有高度黏著性和抗水解性之黏膠。該用於本發明太陽能電池背板之黏膠於固化對薄膜滿意之黏著性以及極佳抗水解性,而因此使其適合被用作為太陽能電池背板之黏膠。
於製造太陽能電池背板時,將本發明之黏膠塗佈至薄膜。執行本發明時可藉由各種方法諸如凹面塗佈、線棒塗佈、氣刀式塗佈、晶片塗佈、唇鏝塗佈(lip coating)和刮刀式塗佈法(comma coating methods)。相互層疊以用於本發明太陽能電池背板之胺基甲酸酯黏著劑所塗佈之複數層薄膜而獲得太陽能電池背板。
本發明提供一種上述胺基甲酸酯預聚物其末端具有異氰酸酯基(A)與上述多元醇(B)之組合,以獲得該用於太陽能電池背板之黏膠。本發明之黏膠係一種所謂之雙組分黏膠,其能藉由混合胺基甲酸酯預聚物(A)與多元醇(B)引發反應而因此產生固化。因此,該胺基甲酸酯預聚物(A)和多元醇(B)較佳在易於混合之狀態下組合以及儲存。此時,該「其他成分」可被含於(A)或(B)內,或分開放置而組合成為「其他成分」。祇要該「其他成分」不與(A)產生反應,該其他成分較佳為被含於(A)內。
本發明太陽能電池背板之具體實施例已示於第1至3圖,但是本發明非僅侷限於這些具體實施例。
第1圖係本發明太陽能電池背板之剖面圖。該太陽能電池背板10係由兩片薄膜所構成並且以用於太陽能電池背板之黏膠13夾置其間,以及兩片薄膜11和12藉由用於太陽能電池背板之黏膠13相互層合。該薄膜11和12可由相同或不同材料所製成。第1圖中,該兩片薄膜11和12係相互層合,或互相層合三或多片薄膜。
第2圖所示係根據本發明太陽能電池背板之另一具體實施例。第2圖中,薄膜11和用於太陽能電池背板之黏膠13間形成一薄膜11a。例如,該圖顯示一具體實施例,其於薄膜11表面上形成金屬薄膜11a,而該薄膜11係一塑膠薄膜。該金屬薄膜11a可藉由氣相沈積法形成於該塑膠薄膜11上,以及藉由層合其表面上形成金屬薄膜11a之薄膜11,並且與該薄膜12以用於太陽能電池背板之黏膠13夾置其間而獲得第2圖所示太陽能電池背板。
沈積於塑膠薄膜上金屬之實例包括鋁、鋼、銅等。該塑膠薄膜於進行薄膜之氣相沈積時可賦予阻隔性。可使用氧化矽或氧化鋁作為氣相沈積材
料。該用作為基材之塑膠薄膜11可為透明,或白色或黑色。
由聚氯化乙烯、聚酯、氟樹脂或丙烯酸樹脂所製成之塑膠薄膜可被用作為薄膜12。為了賦予抗熱性、耐候性、硬度和絕緣性,較佳為使用聚乙烯對酞酸酯或聚對酞酸酯薄膜。該薄膜11和12可為透明,或著色。利用根據本發明用於太陽能電池背板之黏膠13相互層合薄膜11之沈積薄膜11a和薄膜12,以及通常利用乾式層合法相互層合薄膜11和12。因此,用於太陽能電池背板之黏膠13必需在層合時對薄膜具有極佳之初始黏性以及於固化後對薄膜具有極佳黏性(或黏著性)。
第3圖為本發明太陽能電池模組一實例之剖面圖。第3圖中,藉由層疊一玻璃板40、密封材料20諸如乙烯醋酸乙酯樹脂(EVA)、複數個通常相互連接以產生所欲電壓之太陽能電池胞30和相互層合之背板10,然後利用隔片50固定這些元件10、20、30和40以獲得太陽能電池模組。
如上所述,由於背板10係複數個薄膜11和12之層壓板,該胺基甲酸酯黏著劑13即使背板10長期暴露於室外時必需不導致薄膜11和12之剝落,並且於高溫下具有極佳黏性,亦即具有極高度之抗水解性。
下列為本發明之主要具體實施例。
1.藉由混合(A)具有異氰酸酯端基之胺基甲酸酯預聚物與(B)多元醇獲得根據本發明用於太陽能電池背板之黏膠,其中藉由含羥基化合物與異氰酸酯化合物之反應獲得該胺基甲酸酯預聚物(A),以及該含羥基化合物含有聚己內酯多元醇。
2.根據上述第1項中用於太陽能電池背板之黏膠,其中該胺基甲酸酯預聚物(A)進一步含有異氰酸酯化合物之三聚物。
3.根據上述第1項或第2項中用於太陽能電池背板之黏膠,其中該胺基甲酸酯預聚物(A)具有2.0至4.0之異氰酸酯指數。
4.根據上述第1項至第3項中任一項用於太陽能電池背板之黏膠,其中該含羥基化合物進一步含有三甲醇丙烷。
5.根據上述第1項至第4項中任一項用於太陽能電池背板之黏膠,其中該多元醇(B)包括具有酯鍵之多元醇。
6.根據上述第5項中用於太陽能電池背板之黏膠,其中該具有酯鍵之多元醇包括聚酯多元醇。
7.根據上述第1項至第6項中任一項用於太陽能電池背板之黏膠,其進一步含有環氧樹脂。
8.根據上述第1項至第7項中任一項用於太陽能電池背板之黏膠,其中該多元醇(B)具有10℃或更低之玻璃轉變溫度。
9.藉由利用根據上述第1項至第8項中任一項用於太陽能電池背板之黏膠獲得一太陽能電池背板。
10.藉由利用根據上述第9項之太陽能電池背板獲得一太陽能電池模組。
11.一種(A)其末端具有異氰酸酯基之胺基甲酸酯預聚物與(B)多元醇之組合,以獲得根據上述第1項至第8項中任一項用於太陽能電池背板之黏膠。
下列為元件符號之說明:
1‧‧‧太陽能電池模組
10‧‧‧背板
11‧‧‧薄膜
11a‧‧‧沈積薄膜
12‧‧‧薄膜
13‧‧‧黏膠層
20‧‧‧密封材料(EVA)
30‧‧‧太陽能電池胞
40‧‧‧玻璃板
50‧‧‧隔片
第1圖係根據本發明太陽能電池背板一具體實施例之剖面圖。
第2圖係根據本發明太陽能電池背板另一具體實施例之剖面圖。
第3圖係根據本發明太陽能電池模組一具體實施例之剖面圖。
將藉由下列實例和比較實例說明本發明,以及這些實例僅供說明之用途並且非指本發明僅侷限於此。
於配備一攪拌葉、一溫度計、一氮進氣管和一回流冷凝管之四頸瓶內,充填入1.07重量份聚己內酯多元醇(Daicel公司製造)、0.47重量份三甲醇丙烷(Wako Pure化學工業製造),和3.82重量份乙酸乙酯(Wako Pure化學工業製造)而使其非揮發性成分之濃度成為60%重量比,接著加熱至60℃。確認三甲醇丙烷完全溶解之後,加入4.19重量份二甲苯二異氰酸酯(XDI)(Mitsui化學公司製造),以及混合物於約65℃反應4小時。確認完成反應之後,加入5.73重量份(9.55重量份之60%乙酸乙酯溶液產品)異佛爾酮二異氰酸酯三聚物(Evonik工業製造)以獲得含60%重量比胺基甲酸酯預聚物(A1)之非揮發性成分。
利用示於表1和表2各種含量(重量份)之成分合成胺基甲酸酯預聚物(A2)至胺基甲酸酯預聚物(A8)。使用與胺基甲酸酯預聚物(A1)之相同合成法。表1和表2內單位數值為重量份。
原料示於下列表1和表2。
聚己內酯多元醇1:聚己內酯三醇(PCL303(商品名),Daicel公司製造)
聚己內酯多元醇2:聚己內酯三醇(PCL305(商品名),Daicel公司製造)
三甲醇丙烷:Wako Pure化學工業有限公司製造
異氰酸酯化合物:二甲苯二異氰酸酯(XDI)(TAKENATE 500(商品名),Mitsui化學公司製造)
異氰酸酯三聚物1:異佛爾酮二異氰酸酯(IPDI)三聚物(VESTANAT T1890/100(商品名),Evonik工業製造)
異氰酸酯三聚物2:六亞甲基二異氰酸酯(HDI)三聚物(SUMIDULE
N3300(商品名),Sumika Bayer胺基甲酸酯股份有限公司製造)
使胺基甲酸酯預聚物(A)與多元醇(B)反應以產生用於太陽能電池背板之黏膠。
多元醇成分(B)詳述如下。
使用市售產品作為聚酯多元醇。
(B1)聚酯多元醇合成自間苯二甲酸(LA2692-21(商品名),漢高(Henkel)公司製造,玻璃轉變溫度(Tg)0℃)
(B2)聚酯多元醇合成自間苯二甲酸(UR2790-22(商品名),漢高公司製造,玻璃轉變溫度(Tg)-29℃)
(B3)丙烯酸多元醇係合成自用於製造黏膠之單體。下列為其合成方法。合成丙烯酸多元醇(B3)
於配備一攪拌葉、一溫度計和一回流冷凝管之四頸瓶內,充填入150 g乙酸乙酯(Wako Pure化學工業製造)然後回流於約80℃。於該燒瓶內,加入1 g之2,2-偶氮二異丁腈作為聚合引發劑,然後於1小時和30分鐘過程中持續加入示於表3各種數量單體之混合物。於另外加熱2小時之後,獲得含40.0%重量比非揮發成分(固體含量)丙烯酸多元醇之溶液。
丙烯酸多元醇(B3)之可聚合單體成分組成物示於表3。
表3
甲基丙烯酸甲酯(MMA):Wako Pure化學工業有限公司製造
丙烯酸丁酯(BA):Wako Pure化學工業有限公司製造
甲基丙烯酸縮水甘油酯(GMA):Wako Pure化學工業有限公司製造
丙烯腈(AN):Wako Pure化學工業有限公司製造
甲基丙烯酸2-羥乙酯(HEMA):Wako Pure化學工業有限公司製造
苯乙烯(St):Wako Pure化學工業有限公司製造
2,2-偶氮二異丁腈(AIBN):Otsuka化學有限公司製造
依照下列方法測定多元醇(B)之玻璃轉變溫度(Tg)。
利用示差掃描量熱儀(SII奈米科技DSC6220,SII奈米科技公司製造)以5℃/分之溫度上升速率測得其樣本之DSC曲線為10 mg,此時該DSC曲線之曲折點溫度被視為其玻璃轉變溫度。
稱取含11.5重量份固體含量之胺基甲酸酯預聚物(A1)以及含88.5重量份固體含量之聚酯多元醇(B1)(漢高公司製造)以及將其混合之後,將醋酸乙酯加入混合物以製備含30%重量比固體含量之溶液,使用該獲得之製備溶液作
為太陽能電池背板之黏膠。
首先,將實例1用於太陽能電池背板之黏膠塗佈至用於製造太陽能電池背板之透明聚對酞酸酯(PET)板上(OE300EW36(商品名),Mitsubishi聚酯薄膜公司製造)而使固體成分之重量成為10 g/m2,然後於80℃乾燥10分鐘。
接著,將經表面處理透明聚氟化亞乙烯(PVD)薄膜(Kyner膜302 PGM TR(商品名),Arkema公司製造)放置於PET板之黏膠-塗佈表面上而使經處理表面能接觸該黏膠-塗佈表面,然後利用一平面壓合機(ASF-5(商品名),SHINTO金屬工業製造)於1.0 MPa壓合壓力(或閉壓力)下在50℃壓合30分鐘。壓合時,將該二薄膜於50℃固化一週而獲得薄膜層1。
利用實例和比較實例用於太陽能電池背板之黏膠製造薄膜層,然後進行評估試驗。使用如薄膜層1之相同製造方法製造其他薄膜層。該評估試驗詳述如下。
1.評估薄膜固化後之黏性
將薄膜層1切割成15 mm寬小塊,接著利用拉伸長度測試機(TENSILON RTM-250(商品名),ORIENTEC公司製造)於100 mm/分拉伸測試速度之室溫環境下進行180°剝裂試驗。其評估標準如下:
A:剝離強度為9 N/15 mm或更高
B:剝離強度為7 N/15 mm或更高及低於9 N/15 mm
D:剝離強度為低於7 N/15 mm
2.抗水解性之評估
2-1高溫下之抗水解性(剝離強度試驗)
藉由加速評估法利用加壓蒸汽進行評估。將薄膜層1切割成15 mm寬小塊,利用高壓煮鍋(高壓釜SP300(商品名),Yamato科技公司製造)於0.1 MPa之121℃加壓環境下放置25小時,取出,然後在室溫環境下陳化一天。之後,如同經固化薄膜之剝離強度測量法進行測定。其評估標準如下:
A:剝離強度為9 N/15 mm或更高
B:剝離強度為7 N/15 mm或更高及低於9 N/15 mm
D:剝離強度為低於7 N/15 mm
2-2長時間後之抗水解性試驗(剝離試驗)
將薄膜層1切割成50 mm方塊,然後放置於鋁片上而使聚氟化亞乙烯一邊朝上,接著利用鋁帶密封四邊。利用高壓煮鍋於0.1 MPa之121℃加壓環境下將該經密封樣本放置100小時後取出,然後於取出後立刻進行剝離評估。其評估標準如下:
A:由於黏著力強而無法剝離薄膜
B:剝離時因需強剝離力而使薄膜破裂
C:剝離時雖然需強剝離力但薄膜仍未破裂
D:薄膜可輕易地被剝離
根據示於表4至6之組成物,製造用於太陽能電池背板之黏膠。使用如實例1相同方法製造該用於太陽能電池背板之黏膠。亦藉由如實例1相同方法製造薄膜層。
使用下列如表4和表5之環氧樹脂
環氧樹脂:jER828(商品名),Mitsubishi化學公司製造
如表4至5所示,這些用於太陽能電池背板之黏膠實例於固化後對薄膜具有極佳之初始黏度,以及在高溫下呈現高黏性,並且由於係藉由反應含有聚己內酯多元醇之含羥基化合物與異氰酸酯化合物獲得胺基甲酸酯預聚物(A1)至胺基甲酸酯預聚物(A6),因此亦具有極高抗水解性。
相較之下,如表6所示,由於胺基甲酸酯預聚物(A'7)對胺基甲酸酯預聚物(A'8)而言係獲得自反應不含聚己內酯多元醇之含羥基化合物與異氰酸酯化合物,因此用於太陽能電池背板之比較實例具有顯著較差黏膠抗水解性。與用於太陽能電池背板之黏膠實例比較,比較實例中用於太陽能電池背板之黏膠於固化後對薄膜的黏性較差。
這些結果證明當以含羥基化合物作為含有聚己內酯多元醇胺基甲酸酯預聚物(A)之原料時,可獲得適合用於太陽能電池背板之胺基甲酸酯黏膠。此外,當含聚酯多元醇或環氧樹脂之多元醇(B)被事後加入獲得之胺基甲酸酯黏膠內時,該胺基甲酸酯黏膠更適合被用作為用於太陽能電池背板之黏膠。
本發明提供一種用於太陽能電池背板之黏膠。根據本發明該用於太陽能電池背板之黏膠具有極高產量以及對背面膜片具有高黏著性和長期耐用性,並且極適合被用於太陽能電池背板和太陽能電池模組。
10‧‧‧背板
11‧‧‧薄膜
12‧‧‧薄膜
13‧‧‧黏膠層
Claims (8)
- 一種藉由混合(A)具有異氰酸酯端基之胺基甲酸酯預聚物與(B)多元醇獲得用於太陽能電池背板之黏膠,其中,該胺基甲酸酯預聚物(A)係獲得自含羥基化合物與異氰酸酯化合物之反應,以及該含羥基化合物含有聚己內酯多元醇。
- 根據申請專利範圍第1項所述用於太陽能電池背板之黏膠,其中,該胺基甲酸酯預聚物(A)進一步含有異氰酸酯化合物之三聚物。
- 根據申請專利範圍第1項至第3項中其一或多項之酸性水溶液,其中,該鐵離子數量為至少15 g/l。根據申請專利範圍第1或2項所述用於太陽能電池背板之黏膠,其中該胺基甲酸酯預聚物(A)具有2.0至4.0之異氰酸酯指數。
- 根據申請專利範圍第1項至第3項中任一項所述用於太陽能電池背板之黏膠,其中,該含羥基化合物進一步含有三甲醇丙烷。
- 根據申請專利範圍第1項至第4項中任一項所述用於太陽能電池背板之黏膠,其中,該多元醇(B)包括具有酯鍵之多元醇。
- 根據申請專利範圍第1項至第5項中任一項所述用於太陽能電池背板之黏膠,其中,該黏膠進一步含有環氧樹脂。
- 一種藉由利用根據申請專利範圍第1項至第6項中任一項所述用於太陽能電池背板之黏膠所獲得之太陽能電池背板。
- 一種藉由利用根據申請專利範圍第7項所述太陽能電池背板所獲得之太陽能電池模組。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012062229A JP2013194131A (ja) | 2012-03-19 | 2012-03-19 | 太陽電池バックシート用接着剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201341494A true TW201341494A (zh) | 2013-10-16 |
TWI586779B TWI586779B (zh) | 2017-06-11 |
Family
ID=48050883
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW102107154A TWI586779B (zh) | 2012-03-19 | 2013-03-01 | 用於太陽能電池背板之黏膠 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9401445B2 (zh) |
EP (1) | EP2828310A1 (zh) |
JP (1) | JP2013194131A (zh) |
KR (1) | KR20140138175A (zh) |
CN (1) | CN104204019B (zh) |
TW (1) | TWI586779B (zh) |
WO (1) | WO2013141329A1 (zh) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6349073B2 (ja) * | 2013-11-12 | 2018-06-27 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 封止材組成物およびそれを硬化させてなる太陽電池モジュール封止材ならびにそれを用いてなる太陽電池モジュールの製造方法 |
JP6391370B2 (ja) * | 2014-08-29 | 2018-09-19 | キヤノン株式会社 | 光ポンピング磁力計及び磁気センシング方法 |
WO2016080508A1 (ja) * | 2014-11-19 | 2016-05-26 | 横浜ゴム株式会社 | 2液ウレタン系接着剤組成物 |
JP6480174B2 (ja) * | 2014-12-17 | 2019-03-06 | ヘンケルジャパン株式会社 | 積層シート用接着剤 |
CN104877625B (zh) * | 2015-05-08 | 2016-01-06 | 浙江晶茂科技有限公司 | 一种胶粘剂及其制备方法 |
DE102015007236A1 (de) * | 2015-06-09 | 2016-12-15 | Duropan Gmbh | Thermo-Photovoltaik-System (TPV) als ein Thermischer Hybrid-Transmitter basierend auf einer fluiddurchströmten Trägerplatte |
JP6701670B2 (ja) * | 2015-10-29 | 2020-05-27 | 横浜ゴム株式会社 | 2液ウレタン系接着剤組成物 |
CN105907354B (zh) * | 2016-06-13 | 2019-06-14 | 中国乐凯集团有限公司 | 一种耐候性胶粘剂及其在太阳能电池背板上的应用 |
CN106590504A (zh) * | 2016-11-18 | 2017-04-26 | 浙江工业大学之江学院 | 一种耐水洗聚氨酯胶黏剂组合物及其制备方法 |
CN109321193B (zh) * | 2018-08-07 | 2021-04-27 | 中国乐凯集团有限公司 | 胶粘剂及其制备方法和应用 |
CN109207112B (zh) * | 2018-08-07 | 2021-05-04 | 中国乐凯集团有限公司 | 胶粘剂及其制备方法、太阳能电池背板和太阳能电池 |
CN110791247A (zh) * | 2019-11-28 | 2020-02-14 | 沈阳化工研究院有限公司 | 一种太阳能电池背板胶黏剂树脂及其制备方法 |
CN115232573B (zh) * | 2021-04-23 | 2024-03-26 | 大洲电子材料(株) | 高温可分离的导电性粘接剂及太阳能电池模块 |
CN113462341B (zh) * | 2021-07-01 | 2022-12-09 | 河南省科学院化学研究所有限公司 | 一种双组分无溶剂反应型聚氨酯热熔胶 |
CN113736412B (zh) * | 2021-09-15 | 2023-02-14 | 浙江多邦新材料有限公司 | 一种防泼水面料用聚氨酯热熔胶及其制备方法 |
CN114316877B (zh) * | 2021-12-30 | 2024-03-15 | 东莞澳中新材料科技股份有限公司 | 一种适用于太阳能电池背板材料的含氟聚氨酯胶粘剂及其应用 |
CN114716964B (zh) * | 2021-12-30 | 2023-11-28 | 无锡市万力粘合材料股份有限公司 | 一种太阳能背板材料粘结用uv固化胶水及其制备方法 |
KR102633854B1 (ko) * | 2022-02-14 | 2024-02-08 | (주)아이컴포넌트 | 유기태양전지용 접착필름 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2032276B2 (de) | 1970-06-23 | 1974-06-12 | Isar-Rakoll Chemie Gmbh, 8000 Muenchen | Verwendung von Lösungen von PoIyesterurethanen als Klebstoff zum Verkleben von Werkstoffen |
US4055534A (en) * | 1975-11-14 | 1977-10-25 | Horizons Incorporated, A Division Of Horizons Research Incorporated | Upgraded aromatic polyester material in powder form |
US4393186A (en) * | 1979-06-19 | 1983-07-12 | Lord Corporation | Thermoplastic polyurethanes prepared by reacting polyisocyanate, polyester polyol, cycloaliphatic diol and a monofunctional chain-terminating compound |
US4842938A (en) * | 1986-01-27 | 1989-06-27 | Essex Specialty Products, Inc. | Metal reinforcing patch and method for reinforcing metal |
DE102005019397A1 (de) * | 2005-04-25 | 2006-10-26 | Bayer Materialscience Ag | Polyurethan-Dispersionen mit verbesserten Verfilmungseigenschaften |
WO2007049722A1 (ja) * | 2005-10-27 | 2007-05-03 | Hitachi Chemical Co., Ltd. | 樹脂組成物及びそれを用いた光学部材 |
CN101274977B (zh) * | 2007-03-29 | 2011-05-25 | 周建明 | 一种固化剂1,6-己二异氰酸酯预聚物及其制备方法 |
WO2009113318A1 (ja) | 2008-03-13 | 2009-09-17 | 株式会社日本触媒 | 太陽電池モジュール用バックシート |
KR20110031375A (ko) * | 2008-07-11 | 2011-03-25 | 미쓰비시 쥬시 가부시끼가이샤 | 태양 전지용 백시트 |
CN101747488A (zh) * | 2008-12-06 | 2010-06-23 | 周建明 | 无溶剂固化剂二苯基甲烷二异氰酸酯预聚物及其制备方法和应用 |
CN101775120A (zh) * | 2009-01-08 | 2010-07-14 | 周建明 | 一种固化剂二异氰酸酯预聚物及其制备方法 |
JP5382336B2 (ja) | 2009-09-30 | 2014-01-08 | 大日本印刷株式会社 | 太陽電池モジュール用裏面保護シート、及び太陽電池モジュール |
US9617453B2 (en) * | 2009-12-14 | 2017-04-11 | Air Products And Chemicals, Inc. | Solvent free aqueous polyurethane dispersions and methods of making and using the same |
-
2012
- 2012-03-19 JP JP2012062229A patent/JP2013194131A/ja active Pending
-
2013
- 2013-03-01 TW TW102107154A patent/TWI586779B/zh not_active IP Right Cessation
- 2013-03-14 EP EP13715016.5A patent/EP2828310A1/en not_active Withdrawn
- 2013-03-14 CN CN201380014147.XA patent/CN104204019B/zh not_active Expired - Fee Related
- 2013-03-14 KR KR1020147026069A patent/KR20140138175A/ko not_active Application Discontinuation
- 2013-03-14 WO PCT/JP2013/058192 patent/WO2013141329A1/en active Application Filing
-
2014
- 2014-09-18 US US14/489,843 patent/US9401445B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN104204019A (zh) | 2014-12-10 |
US20150005450A1 (en) | 2015-01-01 |
EP2828310A1 (en) | 2015-01-28 |
TWI586779B (zh) | 2017-06-11 |
WO2013141329A1 (en) | 2013-09-26 |
CN104204019B (zh) | 2016-07-06 |
KR20140138175A (ko) | 2014-12-03 |
JP2013194131A (ja) | 2013-09-30 |
US9401445B2 (en) | 2016-07-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI586779B (zh) | 用於太陽能電池背板之黏膠 | |
JP6210307B2 (ja) | 樹脂組成物、2液型ラミネート用接着剤、積層フィルム及び太陽電池のバックシート | |
JP5889611B2 (ja) | 太陽電池バックシート用接着剤 | |
TWI421320B (zh) | 接著劑組成物及積層體 | |
TWI557148B (zh) | 樹脂組成物、二液型積層黏著劑、積層薄膜及太陽能電池之背板 | |
KR101429578B1 (ko) | 수지 조성물, 2액형 라미네이트용 접착제, 적층 필름 및 태양 전지의 백 시트 | |
JP5690583B2 (ja) | 太陽電池バックシート用接着剤 | |
KR101850876B1 (ko) | 적층 시트용 접착제 조성물 및 태양 전지용 이면 보호 시트 | |
JP2011111519A (ja) | 積層シート用接着剤組成物 | |
WO2012090857A1 (ja) | 屋外用ウレタン接着剤 | |
TW201410821A (zh) | 層壓板黏著劑 | |
TW201239057A (en) | Adhesive composition for laminating sheet and back protective sheet for solar cell | |
JPWO2016010132A1 (ja) | 太陽電池バックシート用接着剤、太陽電池バックシート接着剤用ポリオール組成物、太陽電池バックシート、及び太陽電池モジュール | |
WO2012073859A1 (ja) | 屋外用ウレタン接着剤 | |
CN108779226B (zh) | 用于层合片的粘合剂 | |
KR102419236B1 (ko) | 적층 시트용 우레탄 접착제 | |
JP5531866B2 (ja) | 積層シート用接着剤組成物 | |
TW201348372A (zh) | 層壓板黏著劑 | |
JP5546706B1 (ja) | 太陽電池バックシート用接着剤 | |
JP5406409B2 (ja) | 太陽電池バックシート用接着剤 | |
JP5406408B2 (ja) | 太陽電池バックシート用接着剤 | |
JP5546705B1 (ja) | 太陽電池バックシート用接着剤 | |
JP2015067669A (ja) | 樹脂組成物、2液型ラミネート接着剤、積層フィルム及び太陽電池のバックシート | |
JP2014015619A (ja) | 太陽電池バックシート用接着剤 | |
JP2013251530A (ja) | 太陽電池バックシート用接着剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |