TW201236846A - Insert molded body and method for producing insert molded body - Google Patents

Insert molded body and method for producing insert molded body Download PDF

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Publication number
TW201236846A
TW201236846A TW100141744A TW100141744A TW201236846A TW 201236846 A TW201236846 A TW 201236846A TW 100141744 A TW100141744 A TW 100141744A TW 100141744 A TW100141744 A TW 100141744A TW 201236846 A TW201236846 A TW 201236846A
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TW
Taiwan
Prior art keywords
insert
stress concentration
thermoplastic resin
rough surface
molded body
Prior art date
Application number
TW100141744A
Other languages
Chinese (zh)
Inventor
Junichiro Sugiura
Kazuki Ohi
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Polyplastics Co
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Publication of TW201236846A publication Critical patent/TW201236846A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14311Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

With respect to an insert molded body provided with an insert member and a thermoplastic resin member which covers at least a part of a surface of the insert member, a technology for increasing heat shock resistance of the thermoplastic resin member is provided. An insert molded body is provided with an insert member and a thermoplastic resin member which covers at least a part of a surface of the insert member, wherein when the thermoplastic resin member comprises at least one welded portion extending in a predetermined direction, a rough surface is formed on the surface of the insert member at an area right below the all welded portions and/or an area near the right-below area. More specifically, the rough surface is formed so that opposite ends of the rough surface are located at substantially the same positions or more external positions compared to the positions of the opposite ends of the welded portion.

Description

201236846 ' 六、發明說明: 【發明所屬之技術領域】 本發明係有關於***件成形體及***件成形體之製造 方法。 【先前技術】 ***件成形法係活用樹脂之特性與金屬、無機固體等 (以下有將金屬、無機固體等稱為***構件的情況)之材料 的特性,將***構件土里入樹脂的成料,所得之***件成 形體具有熱可塑性樹脂構件與***構件。利用***件成形 法所得之***件成形體用作汽車零件或電性、電子元件、7 0A機益零件等。依此方式,插人件成形體是在廣大之領域 所使用的有用材料。201236846 ' VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a method of manufacturing an insert molded body and an insert molded body. [Prior Art] The insert molding method is a property of a resin and a metal, an inorganic solid or the like (hereinafter, a metal, an inorganic solid or the like is referred to as an insert member), and a material of the insert member is poured into the resin. The resulting insert molded body has a thermoplastic resin member and an insert member. The insert molded body obtained by the insert molding method is used as an automobile part or an electric component, an electronic component, a 70A machine benefit part, or the like. In this way, the insert molded body is a useful material used in a wide range of fields.

可是,***件成形體具有剛成形後之熱可 二的制、使用中的溫度變化所造成之熱可塑性J Γ成為間題的情況。該問題是由於熱可塑性樹脂構件 的溫度變化所造成之膨脹率或收縮率、及插牛 變化所造成之膨膳至七你π * 專件的,皿度 4之膨料或收縮率相異利起。而且, 在熱可塑性樹脂構件具有焊接部的情況、二題 件且有尖銳Λwm部分'或***構 /、 A兄之角洛部的情況)易發生。因此 開,插二件成形體之用途或形狀等受到限制。 裂 “可疋冑近’在汽車領域’盛行將引擎周圍之全遥 件替代成樹脂零件的檢討。作為該檢討之-,進:::: 3 201236846 件成形體用於替代金屬零件的於叫_ 闻+件的檢&寸。具體而言,在點 關零件、分電盤零件、备綠武、日丨L 相 〜 種感測益零件、各種致動器零件、 節流零件、動力模組零件 令什ϋχυ零件及各種連接器零件 常檢討利用聚苯硫醚(以下銪 *·呢、以下簡稱為PPS)樹脂為代表的 芳硫系樹脂(以下有猶 有稱為PAS树脂的情況)、聚對笨二甲However, the insert molded body has a heat-resistant shape immediately after molding, and the thermoplasticity J Γ caused by temperature change during use becomes a problem. This problem is due to the expansion rate or shrinkage rate caused by the temperature change of the thermoplastic resin member, and the expansion caused by the change of the inserted cattle to the seven π * special pieces, the expansion or shrinkage rate of the degree 4 is different. Start. Further, in the case where the thermoplastic resin member has a welded portion, and the case where there are two sharp parts, the sharp portion wm portion 'or the insertion structure / the corner portion of the A brother's horn is likely to occur. Therefore, the use or shape of the two-piece molded body is limited. The crack "can be close to the 'in the automotive field' prevails in the review of the replacement of the entire remote parts of the engine into resin parts. As a review -, :::: 3 201236846 Parts used to replace metal parts _ 闻+件的检& inch, specifically, in point-off parts, distribution board parts, preparation green wu, 丨 L phase ~ kinds of sensing parts, various actuator parts, throttling parts, power For the parts and various connector parts, the arsenic-based resin represented by polyphenylene sulfide (hereinafter referred to as PPS) resin is often reviewed (the following is also known as PAS resin). )

酸丁 一醇酉旨樹脂(以下有避主PKT 有稱為PBT樹脂的情況)包住鋁、 銅、鐵、黃銅、各種合全望 等之金屬零件、金屬端子的插 件成形體。 可疋引擎周圍之零件係構造複雜,或樹脂部之厚度 變化大’或者曝露於溫度變化大的環境下(例如引擎室: 近)。結果,易發生如上述所示之熱可塑性樹脂構件之裂開 的問題。因此’要求即使配置於有大的溫度變化的環境下, 亦可防止熱可塑性樹脂構件之裂開的技術。即,要求改善 熱可塑性樹脂構件之耐熱衝擊性的技術。 /乍為在耐熱衝擊性優異的樹脂材料(原料),揭示在聚 芳爪醚系知&quot;曰調合了具有扁平截面形狀之纖維狀的填料 之樹脂組成物(參照專利讀1)。又,揭示在聚對苯二甲 酸丁二醇S旨樹脂調合了特定之耐衝擊性賦與劑、無機填料 及芳香族酯化合物的樹脂組成物(參照專利文獻2)。 在該專利文獻卜2所記載之樹脂組成物係作為使熱可 ,性樹脂構件之耐熱衝擊性《高的樹脂材料上優異。可 是,近年來,對熱可塑性樹脂構件之更薄型化的要求亦變 =,又,零件的形狀亦複雜化,而無法避免對熱可塑性樹 月曰構件之焊接部的形成,而要求更提高該耐熱衝擊性。 201236846 [專利文獻] [專利文獻]日本特開2005 — 161693號公報 [專利文獻]日本特開20 08 — 6829號公報 【發明内容】 【發明所欲解決之課題】 本發明係為了解決以上的課題而開發的,其目的在於 提供-種技術,該技術係用以在具有***構件、及被覆插 入構件之表面的至少一部分之熱可塑性樹脂構件,且該熱 可塑性樹脂構件具有焊接部及/或應力集中部的***件成 开v體使熱可塑性樹脂構件的耐熱衝擊性提高。 【解決課題之手段】 本發明者們為了解決該課題而再三地專心研究、结 :,發現在具有***構件、及被覆***構件之表面的至少 —部分之熱可塑性樹脂構件,且熱可塑性樹脂構件具有一 :以上之在既定方向所延伸之焊接部的情況,若在***構 的表面之全部的焊接部之正下的區域及/或正下的區域 =近形成粗面,可解決該課題,以至於完成本發明。更呈 體而言’本發明提供以下所示者。 八 ⑴:種***件成形體,具有***構件、及被覆該*** =®的至少一部分之熱可塑性樹脂構件,該熱可塑 ^生樹脂構件係具有一個 邱.产 有㈣以上之在既定方向所延伸的焊接 :之=入構件之表面的一部分,形成在與該焊接部相 向所延伸的粗面;該粗面係配置於在該***構件的 201236846 表面之全部的該焊接部之正下的區域及/或該正下的區域 附近;該粗面之兩端的位置係與該焊接部之兩端的位置大 致一致或更外側。 (2) —種***件成形體,具有***構件、及被覆該*** 構件之表面的至少一部分之熱可塑性樹脂構件,該熱可塑 性樹脂構件係具有一個以上之因該熱可塑性樹月旨構件之膨 脹收縮所產生之應力集中的應力集中部,該應力集中部係 在既定方向延伸;在該***構件之表面的一部&amp;,形成在 與該應力#中部相同之方向所延伸的粗面;神面係配置 於在該***構件的表®之全部❺該應力#中部之正下的區 域及/或該正下的區域附近;該粗面之兩端的位置係與該應 力集中部之兩端的位置大致一致或更外側。 (3) 如(1)項所記載之***件成形體,其中進而,該熱 可塑性樹脂構件係具有一個以上之因該熱可塑性樹脂構件 之膨脹收縮所產生之應力集中的應力集&quot;,該應力集中 部係在既定方向延#;在與該應力#中部相同之方向所延 伸的粗面係配置於在該***構件的表面之全部的該應力集 中。P之正下的區域及’或該正下的區域附近;該粗面之兩端 的位置係與該應力集中部之兩端的位置大致一致或更外 侧。 (4) 如(1)項所記載之***件成形體,其中進而,該熱 可塑性樹脂構件係具有一個以上之因該熱可塑性樹脂構件 之膨脹收縮所產生之應力集中的應力集中#,該應力集中 部係在既定方向延伸;該應力集中部的位置與該焊接部的 6 201236846 &quot; 位置大致一致。 (5) 如(1)至(4)項中任一項所記載之***件成形體,其 中至少一處之該粗面係被設置成夾住在該***構件的表面 之該焊接部及/或該應力集中部之正下的區域。 (6) 如(1)至(5)項中任一項所記載之***件成形體,其 中該粗面係利用雷射所形成的粗面。 、 ⑺如(1)至(6)項中任一項所記載之***件成形體,其 中該熱可塑性樹脂構件係由結晶性熱可塑性樹脂組成 構成。 ⑻如⑴至⑺項中任-項所記載之***件成形體,复 中該結晶性熱可塑性樹脂組成物係聚亞芳硫趟系樹脂組成 物或聚對苯二甲酸丁二醇醋系樹脂組成物。 ⑻—種插人件成形體的製造方法,製造具有***構 件、及被覆該***構件之表面 ^ . ^ ^ y 刀之熱可塑性樹 月曰構件之***件成形體,該熱可塑性樹脂構件係具有一個 在㈣㈣料伸料接料在^方向所延伸之 應力集中部的至少一方.且 . 方,具有.粗面形成製程,係 可塑性樹脂構件具有焊接 ° 令邱66 # W k Α 度兄在***構件的表面之 。一知接。Ρ之正下的區域及/或該正下 成在與該焊接部相同 區域附近形 樹脂構件不具有谭接部 纟該熱可塑性 吁伐冲的情況,在***構 的該應力集中部之正 5表面之王斗 下的區域及/咬續 成在與該應力集中部相同° @區域附近形 可塑性樹脂構件具有 *面,在疋該熱 亥^接部與該應力集中部的情況,且 7 201236846 焊接部之位置與應力集中部之位置不-致或不大致-致的 情況’在該***構件的表面之全部的焊接部之正下的區域 及/或正下的區域附近形成在與該焊接部相同之方向所延 伸的粗面、與在全部的該應力集中部之正下的區域及/或正 下的區域附近形成在與該應力集中部相同之方向所延伸的 粗面;及熱可塑性樹脂構件形成製程,係將該粗面形成製 程後的***構件配置於模具後,向該模具***出熔化的熱 可塑@以被覆該粗面之至少—部分的方式將熱可 塑性樹脂構件形成於該插人構件的表面;在該熱可塑性樹 脂構件具有焊接部的情況,該粗面之兩端的位置係與該焊 接°卩之兩端的位置大致一致或更外側;在該熱可塑性樹脂 構件不八有:tp接部的情況,該粗面之兩端的位置係與該應 力集中部之兩端的位置大致一致或更外側;在係該熱可塑 性樹脂構件具有該焊接部與該應力集中部的情況,且焊接 部的位置與應力集中部之位置不一致或不大致一致的情 况該粗面之兩端的位置係與在大致正上所形成之該焊接 部或應力集中部之兩端的位置大致一致或更外側。 (10) 如(9)項所記載之***件成形體的製造方法,其中 更具有龜裂發生位置確認製程,該製程係在該粗面形成製 程之前’利用熱使使用未形成粗面的***構件所製造之插 入件成形體的熱可塑性樹脂構件膨脹、收縮後,確認熱可 塑性樹脂構件之表面的龜裂發生位置。 (11) 如(ίο)項所記載之***件成形體的製造方法,其 中該粗面係形成於在該龜裂發生位置確認製程所確認之發 8 201236846 生龜裂的預測位置附近。 【發明效果】 右依據本發明,可使構成***件成形體之熱可塑性樹 脂構件的耐熱衝擊性提高。 【實施方式】 、下說月本發明的實施形態。此外,本發明未限定 為以下的實施形態。 本發明係在具有熱可塑性樹脂構件與***件的***件 成形體’在熱可塑性樹脂構件具有焊接部或應力集中部的 情況’使熱可塑性樹脂構件之耐熱衝擊性提高。在說明插 入件、熱彳塑性樹脂構件後’關於本發明以以 的情況為例,說明本發明。 接部 態)。 ⑴增可塑性樹脂構件具有焊接部 焊接部之位置盥廂七 、叫力集中部’且 按I之位置與應力集中部之位 施形態)致的情況(第2實 (i i i)熱可塑性樹脂構件不具有 集中部的情況(第3實施形態)。 。’而僅具有應力 ㈤本發明之***件成形體之 態)。 去(第4實施形 〈***構件〉 201236846 他八稱件可使用自U+ 性…件成形體所使用之-r 的。p,構成***構件的材料亦可是金 ^ 有機材料之任一種。且^ .、,、機材料、 紹、銅、金、銀、黃鋼等之金屈道鱗鐵、不鱗鋼' 寻之金屬、導熱性的陶 等。又,在表面形成金屬薄膜的金屬等亦可用作插材料 作為金屬的薄膜,例如可列舉利用電***構件, 牛〜用電鍍處理(濕式雷枯老 =式電鑛處理等)所形成的薄膜。此外,插:構件;: =屬:無機材料等之單體,亦有指具有複 :: 脂4之複合體的情況。 ® A树 t構成***構件之材料的決定係例如考慮用途、 月曰構件之樹脂材料的熱膨脹率 佳的㈣。 ^的物性後’適當地決定較 ***構件具有粗面。粗面的 曰益+ &amp; 凹扪形成方法無特別限定,但 疋藉雷射之粗面的开^成方法# 忒係簡便,而較佳。此外,關於 粗面的形成位置或粗面的面積、 ; 與後、f少為 粗面的粗糙度等,以根據 興後述之熱可塑性樹脂構件 ^ 0 , 件所具有之焊接部或應力集中部 的關係發揮本發明之效果的方 m 決定。此外,在利用雷射 形成粗面的情況,加工機輪出 戥古斤丄、 刀旱追逐寬度、雷射束光 ώ 雨出功率為20〜40W、追逐赏 又為〇.〇2〜〇.6ηπη、雷射束光點直 且仏約為130 # m是平常使 用之範圍。此外,第1圖係表 沾固主 表不追逐寬度之概念(第1圖中 的圓表示藉脈波之雷射的照射。* 掃描方向)。 二白前唬表不雷射的 ***構件的形狀無特別限定,亦可是四角柱形、圓柱 10 201236846 形專之單純的形狀,亦可是如堂彳生从 疋如零件的形狀之複雜的形狀。 粗面的形成方法無特別限 』限疋但是例如在金屬的情況,可 模鑄、射 利用以往周知之藉工具機之切削加工等的加工 出成形、沖壓等的模具鑄造等的方法製造。 〈熱可塑性樹脂構件〉 亦可是結 作為這些 構成熱可塑性樹脂構件的材料無特別限定 晶性樹脂組成物’亦可是非結晶性樹脂組成物 樹脂組成物所含的泛用熱可塑性樹脂,可列舉聚乙稀 (PE)'聚丙稀(PP)、聚4—甲基—戍稀、聚環稀煙等之 聚稀烴、聚苯乙稀(PS)、AS樹脂、ABS樹脂、聚氣化乙稀 (PVC)聚丙稀腈(pAN)、(甲基)丙稀酸樹脂、纖維素系樹 脂、彈性體等。作為卫程樹脂,可列舉如尼龍6、尼龍6, 6、 匕龍12尼龍6’12之各種脂肪族聚醯胺或芳香族聚醯胺 (PA)、如聚對苯二曱酸(pET)、聚對苯二甲酸丁二醇酯 (PBT)、聚萘二甲酸(PEN)之芳香族聚醋樹脂、聚碳酸醋 (PC)、聚醛(Ρ0Μ)、聚笨醚(PPE)、聚苯硫醚(pps)、聚砜 (PSu)、聚醯亞胺(PI)、液晶聚酯、液晶醯胺等。又,亦可 疋~το酸、脂肪族二醇、脂肪族氨基酸或來自其環 化^物的脂肪族聚酿,進而這些利用二異氰酸醋等增加分 子罝的脂肪族聚酯等之可生物降解樹脂等。此外,亦可使 用2種以上之上述的樹脂。又,在樹脂組成物包含僅含 微量的雜質等之實質上由結晶性熱可塑性樹脂所構成的情 況。 尤其,在熱可塑性樹脂構件由聚亞芳硫醚(PAS)樹脂組 11 201236846 成物、聚對苯二甲酸丁二醇酯(PBT)系樹脂組成物等之結晶 性樹脂組成物所構成的情況,因為熱可塑性樹脂構件因結 晶化而膨脹、收縮,所以熱可塑性樹脂構件易發生裂開的° 問題。可是,若依據本發明,即使是熱可塑性樹脂構件由 結晶性樹脂組成物所構成的情況,亦可抑制該熱可塑性樹 脂構件之裂開的問題。 在結晶性樹脂組成物中,尤其PAS樹脂组成物具有高 耐熱性、機械性物性、耐藥性、尺寸穩定性、難燃性等的 性質。又,PBT樹脂具有機械性物性、電性物性、耐藥性 等的性質。具有這種優異之性質的這些樹脂都應用於汽車 零件、電性、電子元件等。此外,作為可使用的PAS樹脂, 可列舉在㈣1 32935號公報所記狀奶樹脂。作 為可使用的PBT樹脂,可列舉在特開2〇〇6 — 1 1 1 693號公報 所記載之PBT樹脂。 又’ PAS樹脂亦一併具有缺乏勒性而脆弱的缺點。因 此,在使用PAS樹脂形成熱可塑性樹脂構件的情況,在溫 度變化大的環境下配置***件成形體時,熱可塑性樹脂;: 件特别易裂開。可是,若依據本發明,即使使用⑽樹脂, 亦可充分抑制熱可塑性樹脂構件之裂開的問題。 又,構成熱可塑性樹脂構件的樹脂組成㈣可在樹脂 組成物含有防止氧化劑、安定劑、可塑劑、顏料等之以往 周知的添加劑等。 本發明的熱可塑性樹脂構件具有焊接部與應力集中部 之至少一方。 201236846 焊接部係在形成熱可塑性 在模具的空腔内匯流’而在樹脂:彼二二種樹脂流 接部。是否形成禪接部、焊接部的個數、焊接:成的嬋 與熱可塑性樹脂構件的形狀、或用以形成埶叮置係 件之換具所具有之逢口的位置等相依。 &quot;曰構 應力集中部可列舉角落部、缺口部、 空心部及流痕部等。庙士在a * 貝牙孔、 應力集中部的位置或大小亦有可從敎 可塑性樹脂構件之形狀黧m + m』從熱 ……开4專特疋的情況,亦有無法特定的情 況在,、,、法特定的情況,可實際上製诰插 認熱可塑性樹脂構件…門的邱t 件成形體’確 此特定。構件之易裂開的部分’或進行模擬等,藉 熱可塑性樹脂構件的形狀無特別限定。使用具有所要 ,空腔的模具’將***構件配置於該模具,使溶化狀態的 树脂組成物向空腔内流入,使該樹脂組成物固化,藉此, 可在插人構件上形成所要之形狀的熱可塑性樹脂構件。 〈第1實施形態〉 以第2圖所示的***件成形體為例,說明第上實施形 態的***件成形體。第2圖係在模式上表示第i實施形態 之***件成形體的圖,(a)係立體圖’ (b)係⑷的平面圖: 第3圖係在模式上表示***構件的立體圖。第*圖係表示 形成焊接部之狀況的模式圖。 如第2圖所示,***件成形體丨具有***構件丨1、及 熱可塑性樹脂構件12(以下只稱為樹脂構件12),樹脂構件 12以覆蓋***構件u之一部分的方式所形成。在第丄實 201236846 施形態,以你 ***構件u貫穿長方體形之樹脂構件12之上 樹脂構件12形成於***構件11上。然後,因 :底面側具有洗口之模具所製造的***件成形 瓶 尸/Γ从如笛^ 罘2圖(a)所示,在形成樹脂構件12時,在4 處發生焊接部12〇。 ^如第2圖所示,因為***構件^具有4處角落部, 斤乂樹知構件12具有4處應力集中部,這些應力集中部的 位置與焊接部12。的位置一致。 在***構件11之比第3圖所示的二點鏈線更靠近底面 側的。卩分疋與樹脂構件丨2接觸的部分。粗面11〇形成於與 〜樹月曰構件1 2接觸的面。在本實施形態,如第3圖所示, 在***構件11的側面上形成複數個長方形(長邊、短邊 L2)的粗面11〇。 粗面110以與後述之焊接部12〇所延伸之方向大致平 行的方式形成於***構件丨丨的表面◊「大致平行」係除了 &amp;王平行以外,還包含大致平行。只要是具有本發明之效 果的範圍’焊接部1 20所延伸之方向與粗面u 〇所延伸之 方向之夾角的大小無特別限定,但是該夾角是2。以下較 佳。 在第1實施形態’如第3圖所示,粗面110以2個粗 面110平行地排列的方式形成於各側面的兩端附近。形成 粗面11 0的位置亦可是焊接部丨2 〇之正下的區域附近。例 如,距離焊接部12〇約2mm亦無問題。另一方面,從操作 性的觀點,最短是約〇.卜〇· 2mn^在本實施形態,因為焊 14 201236846 接部120的位置是位於***構件之側面的稜線上,該「附 近」疋從該稜線至粗面11 〇的距離,在第3圖中以L表示 此外,焊接部120與粗面110之間的該距離係指在焊^部 120與粗面110最接近的位置之兩者之間的距離。 又,在本實施形態,在焊接部12〇所延伸的方向之該 粗面110之兩端的位置與焊接部12〇之兩端的位置大致I 致(長邊L,&lt;從虛線至***構件u之底面的長度Lp)。「大 致-致」意指亦可是該粗面! 1〇之兩端的位置比在該既定 方向之焊接部12〇之兩端的位置更稍内側。「稍内側」係 只,是對本發明之效果無害之範圍,其長度無特別限定, =各端。部彼此之長度的差只要是長邊l之1。%以内即 ^ 5:内更佳。此外,在本發明,在既定方向之粗面 ΐΐϋ之兩端的位置传方令士&amp; 置外側較佳。 疋方向之焊接部120之兩端的位 “又,紐邊L2之長度係與***構件m L2平行的邊之 長度的1/3〜1/15較佳4 仃的邊之 大,需要形成而接 ' 更佳。樹脂之收縮愈 y 積愈寬的粗面,需要更長的短邊ί2。 該粗面m利用錯效果,提高樹脂構件 11的密接性。 兴描入構件 粗面⑴的形成方法無特別限定,可採 方法。例如,可列舉利用雷射處理形成粗 卜 蝕刻處理形成粗面的方法“心面的方法、利用 方法較佳。 方法。尤其利用雷射處理形成粗面的 如上述所不,樹脂構 牡4愿具有焊接部120。如 15 201236846 以下所示形成該谭接部120。 將形成該粗面110的***構件n設定於模具内,再向 該模具***出熔化狀態的熱可塑性樹脂,使其固化。在本 實施形態,因為從第4圖之箭號Q的方向射出溶化樹脂, 所以溶化樹脂的流動分成Q1與Q2。而且,在qi與以碰 撞的區域形成焊接部1 2 〇。 在本實施形態,焊接部12〇形成於以第4圖所示之一 點鏈線包圍的區域(在第4圖為了便於說明僅表示一 處)。焊接部120是長方形的區域。焊接部12()的長邊之一 位於與***構件U之側邊重疊的位置。焊接部η。的短邊 如第4圖所示’與將樹脂構件12的上面及底面二等份之線 的一部分重疊。 接著說明第1實施形態之***件成形體所具有的效 果。在第1實施形態之***件成形體i,粗面110形成於 ***構件11之表面的—八。 ' 〇P 77在形成粗面110的部分,插 =件U與樹脂構件12的密接力變強。結果,第i實施 A之***件成形體即使曝露於溫度變化大的環境下,亦 ::用密接力強的部分抑制樹脂構件12的膨脹及收縮,而 P制在樹脂構件12的表面發生龜裂。 更具體地說明該效果。第5圖係用以說明本發明的效 开果=件成形體的模式圖,(a)係本實施形態之***件成 垂直的二視圖,㈤係形成在與焊接部所延伸之既定方向 直的方向延伸之粗面 ⑷係在***件的表面二***件成形體的正視圖, 形成粗面的情況之***件成形體 201236846 的正視圖。 焊接Sot***件成形體1,在樹脂構件12的表面,與 藉!二Γ 發生龜裂的可能性高。在本實施形態, 發生*白=所示的粗面110形成於***構件,即使在 η:密:力收縮,樹脂構件12與插,^ 接力才強,因為阻礙收縮運動’所以可抑制收縮量。 藉由抑制收縮量,減和作用 减鬏作用於樹脂構件12的負擔,而難發 裂。此外,藉由粗面11G相對焊接部120所延伸之方 向千订地延伸’而可—面抑制必須形成之粗面110的面 積’一面高效率地抑制龜裂的發生。此外,如後述所示, 粗面U 0的面積大時,發生問題。 又,如第5圖⑷所示,藉由在插人構件u所形成的 粗面110夹住焊接部120 ’即使發生空白箭號方向之樹脂 =縮’亦可使焊接部12G之部分之樹脂的收縮量變小。 k疋由於利用在***構件i i之表面所形成的粗面m,插 入構件11與樹脂構件12堅固地密接,而抑制焊接部12〇 :近的樹脂收縮。結果,本發明的***件成形體i即使曝 路於概度變化大的環境下,亦因為焊接部i20附近之樹脂 構件12 #收縮、膨脹量變小,所以可減輕作用於焊接部 12 〇之收縮或膨脹的負擔,而可抑制龜裂的發生。 藉由在既定方向之粗面110之兩端的位置係與在既定 方向之焊接部120之兩端的位置大致一致或更外侧,而可 大為抑制龜裂的發生。 在如第5圖(b)所示之粗面11〇形成於***構件n的 17 201236846 情況,例如由於只能留住一小部分因收縮而易發生破壞之 處(在本實施形態為焊接部12Q),幾乎無法阻礙樹脂構件 12的收缩’而幾乎無提高耐熱衝擊性之效果。X,在與如 第5圖(b)所示之焊接部所延伸的方向垂直地延伸的粗 面,欲充分地抑制焊接部附近之樹脂的收縮時,粗面的面 積變成過大(即,需要***構件之與樹脂構件重疊之面的大 部分形成粗面°)°粗面的面積變成過大時’易導致導電性 等之物性的變化、創意性降低。又,在形成粗面後,對包 含粗面之***構件的表面施加電銀處理的情況,電鐘層形 成於粗面的凹凸上,而有樹脂構件與***構件之密接性不' 會變強的傾向。 如第5圖(c)所示,在***構件未形成粗面110的情 況,無法使樹脂構件之收縮、膨腺量變小,而無法抑制因 樹脂構件收縮、膨脹而作用於樹脂構件12的負擔。 在本實施形態,粗面係利用雷射加工形成於***構件 二1的表面。若是利用雷射處理形成粗面的方法,因為局部 處理亦容易’所以可易於將粗面形成於所要之範圍。 以上’說明了第i實施形態的***件成形體,但是如 第6圖(a)所示’亦可是焊接部與應力集中部—致的插人件 二=。第6圖⑷所示的***件成形體是利用圓筒形的樹 曰冓牛12覆柱形之插人構件u的側面之—部分的形 :姆在樹脂構件i2的側面,形成在圓筒所延伸之方向延伸 ,场。在第6圖(a)所示的***件成形 應力集中部。又,以””之底…槽#相當於 /口者該槽之底的方式形成焊接部120。 18 201236846 然後,在***構件丨丨的 ^ ® 11 π V- 面之該焊接部120之正下的區域 形成粗面110。在該焊接部 ΛΑ ,μ. ^ 女4 Λ U之正下的區域形成粗面110 的情况,亦抑制在焊接部 婁,盥μ、+.哲 20之樹月曰構件1 2之收縮的結 果,與上述第2圖至第4 M ϋ ^ 圖所不之第1實施形態的情況一 樣地抑制龜裂的發生。 又亦可疋如第β圖 ^ ^ 所不之焊接部與應力集中部 一致的***件成形體。第 ^ ^ ^ ! 〇 6圖(b)所示之***件成形體係 僅樹月日構件1 2所具有之摊 有之槽的形狀與第6圖(a)所示之*** 件成形體相異。在第6圖( ^ ^ 、;所不之***件成形體的情況, 槽之底的角落部分及厘;# 又薄的分相當於應力集中部。在 與槽之底的角落部分之一 方相同的位置形成焊接部120的 情況’在***構件的表面之該焊接部。。之正下的區域或 正:的區域附近形成粗自11〇即可。此外在第6圖⑻ 所丁之***件成形體,因為具有複數個應力集中部,所以 亦可在***構件的表面之應力集中部之正下的區域或正 下的區域附近形成粗面’ iU在應力集中部之正下的區域 或其附近形成粗面11 0時,可钿生丨 吟了抑制在應力集中部之龜裂的 發生。 又’亦可是如第6圖(C)所示之焊接部與應力集中部一 致的***件成形體。第6圖(〇所示之***件成形體係在樹 脂構件12具有槽部、及圓筒形之樹脂構件12的中心軸盥 圓柱形之插人構件u的中心m,與第6圖⑷所 示之***件成形體相異。樹脂構件12之厚度最薄的部分是 應力集中部。以與該應力集中部—致的方形形成焊接部A butyl acrylate-based resin (hereinafter referred to as a PBT resin) is a molded article of a metal part or a metal terminal which is wrapped with aluminum, copper, iron, brass, and various materials. The structure of the parts around the engine may be complicated, or the thickness of the resin portion may vary greatly or be exposed to an environment with a large temperature change (for example, an engine room: near). As a result, the problem of cracking of the thermoplastic resin member as described above is liable to occur. Therefore, it is required to prevent the cracking of the thermoplastic resin member even when it is disposed in an environment having a large temperature change. That is, there is a demand for a technique for improving the thermal shock resistance of a thermoplastic resin member. In the case of a resin material (raw material) having excellent thermal shock resistance, a resin composition in which a fibrous filler having a flat cross-sectional shape is blended is known (see Patent Reading 1). Further, a resin composition in which a specific impact resistance imparting agent, an inorganic filler, and an aromatic ester compound are blended in a resin of a polybutylene terephthalate S resin is disclosed (see Patent Document 2). The resin composition described in Patent Document 2 is excellent as a resin material having high thermal shock resistance to a heat-resistant resin member. However, in recent years, the demand for thinner thermoplastic resin members has also become smaller, and the shape of the parts has become complicated, and the formation of the welded portion of the thermoplastic tree member has not been avoided, and it is required to further improve the Thermal shock resistance. [Patent Document] [Patent Document] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. The purpose of the development is to provide a technique for using at least a portion of a thermoplastic resin member having an insert member and a surface of the cover insert member, and the thermoplastic resin member has a weld portion and/or a stress. The insert of the concentrated portion is opened to increase the thermal shock resistance of the thermoplastic resin member. [Means for Solving the Problem] In order to solve this problem, the inventors have repeatedly studied and concluded that at least a part of the thermoplastic resin member having the surface of the insertion member and the covering insertion member, and the thermoplastic resin member are found. In the case of a weld portion extending in a predetermined direction, the problem can be solved by forming a rough surface in a region immediately below the welded portion of all the surfaces of the insert structure and/or a region immediately below. The invention is thus completed. More specifically, the present invention provides the following. Eight (1): a molded article molded body having an insert member and a thermoplastic resin member covering at least a part of the insert =®, the thermoformable resin member having one (4) or more extending in a predetermined direction Welding: a part of the surface of the member is formed in a rough surface extending toward the welded portion; the rough surface is disposed in a region directly under the welded portion of the surface of the insert member 201236846 and / or near the area immediately below; the position of both ends of the rough surface is substantially the same as the position of both ends of the welded portion or the outer side. (2) An insert molded body having an insert member and a thermoplastic resin member covering at least a part of a surface of the insert member, wherein the thermoplastic resin member has one or more expansions due to the thermoplastic resin member a stress concentration portion that concentrates stress generated by shrinkage, the stress concentration portion extends in a predetermined direction; a portion on the surface of the insertion member forms a rough surface extending in the same direction as the middle portion of the stress #; The surface is disposed in a region directly under the middle of the stress # of the insert member and/or in the vicinity of the region immediately below; a position of both ends of the rough surface is at a position of both ends of the stress concentration portion Roughly consistent or outside. (3) The insert molded body according to the item (1), wherein the thermoplastic resin member has one or more stress sets due to stress concentration caused by expansion and contraction of the thermoplastic resin member, The stress concentration portion is extended in a predetermined direction; the rough surface extending in the same direction as the middle portion of the stress # is disposed on the entire stress concentration on the surface of the insertion member. The area immediately below P and the vicinity of the area immediately below; the positions of both ends of the rough surface are substantially the same as the positions of both ends of the stress concentration portion or the outer side. (4) The insert molded body according to the item (1), wherein the thermoplastic resin member further has one or more stress concentrations due to stress concentration caused by expansion and contraction of the thermoplastic resin member, the stress The concentrating portion extends in a predetermined direction; the position of the stress concentrating portion substantially coincides with the position of the welding portion 6 201236846 &quot;. (5) The insert molded body according to any one of (1) to (4) wherein at least one of the rough faces is provided to sandwich the welded portion of the surface of the insert member and/or Or the area directly under the stress concentration section. (6) The insert molded body according to any one of (1) to (5), wherein the rough surface is a rough surface formed by a laser. The insert molded body according to any one of the above aspects, wherein the thermoplastic resin member is composed of a crystalline thermoplastic resin. (8) The insert molded body according to any one of (1) to (7), wherein the crystalline thermoplastic resin composition is a polyarylene sulfide resin composition or a polybutylene terephthalate resin Composition. (8) A method for producing a molded article molded body, comprising: an insert member and an insert molded body having a thermoplastic resin tree member of a surface of the insert member; the thermoplastic resin member having a (4) (4) at least one of the stress concentration portions extending from the material in the direction of the material, and having a rough surface forming process, the plastic resin member having the welding degree 邱66 # W k Α degree in the insert member The surface of it. I know it. The region immediately below the crucible and/or the portion in the vicinity of the same region as the welded portion does not have a tandem portion, and the thermoplasticity is smashed, and the stress concentration portion of the interposed structure is positive 5 The region under the king's surface of the surface and/or the bite continue to be the same as the stress concentration portion. The plastic resin member has a * surface in the vicinity of the region, in the case of the heat and the stress concentration portion, and 7 201236846 The position of the welded portion and the position of the stress concentration portion are not uniform or not substantially formed in the vicinity of the portion of the welded portion of the surface of the insert member and/or the region immediately below and formed in the vicinity of the welded portion. a rough surface extending in the same direction, and a rough surface extending in the same direction as the stress concentration portion in the vicinity of the region immediately below the stress concentration portion and/or the region immediately below; and the thermoplasticity The resin member forming process is such that after the inserting member after the rough surface forming process is disposed in the mold, the molten thermoplastic resin is injected into the mold to coat the thermoplastic resin member in such a manner as to cover at least a portion of the rough surface. Formed on the surface of the insertion member; in the case where the thermoplastic resin member has a welded portion, the positions of both ends of the rough surface are substantially the same as or more than the positions of the ends of the welded portion; in the thermoplastic resin member In the case of the tp joint, the positions of the both ends of the rough surface are substantially the same as the positions of the both ends of the stress concentration portion or the outer side; the thermoplastic resin member has the welded portion and the stress concentration portion. In a case where the position of the welded portion does not coincide with or does not substantially coincide with the position of the stress concentration portion, the positions of both ends of the rough surface substantially coincide with the positions of both ends of the welded portion or the stress concentrated portion formed substantially at the front or More outside. (10) The method for producing an insert molded body according to the item (9), further comprising a crack occurrence position checking process, wherein the process is performed by using heat to insert an unformed insert before the rough surface forming process After the thermoplastic resin member of the insert molded body produced by the member was expanded and contracted, the crack occurrence position on the surface of the thermoplastic resin member was confirmed. (11) The method for producing an insert molded body according to the item (10), wherein the rough surface is formed in the vicinity of a predicted position of the crack which is confirmed by the crack occurrence position confirmation process. [Effect of the Invention] According to the present invention, the thermal shock resistance of the thermoplastic resin member constituting the insert molded body can be improved. [Embodiment] An embodiment of the present invention will be described below. Further, the present invention is not limited to the following embodiments. In the present invention, the insert molded body having the thermoplastic resin member and the insert has a welded portion or a stress concentration portion in the thermoplastic resin member, and the thermal shock resistance of the thermoplastic resin member is improved. The present invention will be described by taking the case of the present invention as an example after explaining the insert and the hot plastic resin member. Connected state). (1) The case where the plasticized resin member has the position of the welded portion of the welded portion, the seventh portion, and the position of the stress concentration portion (the position of the I and the stress concentration portion) (the second actual (iii) thermoplastic resin member is not In the case of having a concentrated portion (third embodiment), it has only stress (five) the state of the insert molded body of the present invention). (4th embodiment <insert member> 201236846 The octagonal member can be used from the U-type...former-r-.p. The material constituting the insert member can also be any of the gold/organic materials. .,,, machine materials, Shao, copper, gold, silver, yellow steel, etc., such as gold, stainless steel, stainless steel, stainless steel, metal, thermal conductive ceramics, etc. Examples of the film which can be used as the intercalation material as a metal include a film formed by electroplating, a plating treatment (wet type, old type, electric ore treatment, etc.). Further, a member is inserted: The monomer of the inorganic material or the like may also be referred to as a composite having a complex:: grease 4. The determination of the material of the insert member by the A tree t is, for example, a thermal expansion coefficient of the resin material of the meniscus member. (4) ^ After the physical property 'appropriately determined that the insert member has a rough surface. The rough surface is beneficial + &amp; The method of forming the concave ridge is not particularly limited, but the method of opening the rough surface of the laser is simple. And better. In addition, regarding the formation position of the rough surface The area of the rough surface, the roughness of the rough surface after the f and the rear, and the effect of the present invention are exhibited by the relationship between the welded portion or the stress concentration portion of the thermoplastic resin member 0, which will be described later. m. In addition, in the case of using a laser to form a rough surface, the processing machine turns out the 丄古斤丄, the knife and the chasing width, the laser beam ώ rain power is 20~40W, and the chasing reward is 〇.〇2 ~〇.6ηπη, the laser beam spot is straight and the 仏 is about 130 # m is the range that is usually used. In addition, the first picture is the concept that the main table does not chase the width (the circle in Fig. 1 represents the vein) Irradiation of the laser of the wave. * Scanning direction. The shape of the insert member that is not laser-exposed in the front of the white plate is not particularly limited, and may be a simple shape of a quadrangular prism or a cylinder 10 201236846, or may be a church. The shape of the part is complicated, such as the shape of the part. The method of forming the rough surface is not limited, but for example, in the case of metal, it can be molded and shot by a conventionally known machine tool. Die casting, etc. The thermoplastic resin component may be a non-crystalline resin composition as a material for forming the thermoplastic resin member, or may be a general-purpose thermoplastic resin contained in the resin composition of the amorphous resin composition. Examples thereof include polyethylene (PE) 'polypropylene (PP), poly-4-methyl-anthracene, polycyclic hydrocarbon such as polystyrene, polystyrene (PS), AS resin, ABS resin, and gas gathering. Ethylene (PVC) polyacrylonitrile (pAN), (meth) acryl resin, cellulose resin, elastomer, etc. As a process resin, for example, nylon 6, nylon 6, 6, Snapdragon 12 Nylon 6'12 of various aliphatic polyamines or aromatic polyamines (PA), such as polyterephthalic acid (pET), polybutylene terephthalate (PBT), polynaphthalene dicarboxylic acid ( PEN) Aromatic Polyacetate, Polycarbonate (PC), Polyaldehyde (P0), Polyether Ether (PPE), Polyphenylene Sulfide (pps), Polysulfone (PSu), Polyimine (PI) , liquid crystal polyester, liquid crystal guanamine and the like. Further, it is also possible to use τ~το acid, an aliphatic diol, an aliphatic amino acid or an aliphatic polymer derived from the cyclized product, and further, these aliphatic polyesters which increase molecular enthalpy by using diisocyanate or the like may be used. Biodegradable resin, etc. Further, two or more kinds of the above resins may be used. Further, the resin composition contains substantially a small amount of impurities and the like, and is substantially composed of a crystalline thermoplastic resin. In particular, the thermoplastic resin member is composed of a crystalline resin composition such as a polyarylene sulfide (PAS) resin group 11 201236846 or a polybutylene terephthalate (PBT) resin composition. Since the thermoplastic resin member expands and contracts due to crystallization, the thermoplastic resin member is liable to cause cracking. However, according to the present invention, even when the thermoplastic resin member is composed of a crystalline resin composition, the problem of cracking of the thermoplastic resin member can be suppressed. Among the crystalline resin compositions, in particular, the PAS resin composition has properties such as high heat resistance, mechanical properties, chemical resistance, dimensional stability, flame retardancy and the like. Further, the PBT resin has properties such as mechanical properties, electrical properties, and chemical resistance. These resins having such excellent properties are used in automotive parts, electrical, electronic components and the like. Further, as the PAS resin which can be used, a milk resin as described in the publication No. 1 32935 can be mentioned. As the PBT resin which can be used, the PBT resin described in JP-A-2-61 1 693 can be cited. Moreover, PAS resins also have the disadvantage of being lacking in character and being fragile. Therefore, in the case where the thermoplastic resin member is formed using the PAS resin, the thermoplastic resin is particularly likely to be cracked when the insert molded body is disposed in an environment where the temperature changes greatly. However, according to the present invention, even if the resin (10) is used, the problem of cracking of the thermoplastic resin member can be sufficiently suppressed. Further, the resin composition (4) constituting the thermoplastic resin member may contain a conventionally known additive such as an oxidizing agent, a stabilizer, a plasticizer, or a pigment in the resin composition. The thermoplastic resin member of the present invention has at least one of a welded portion and a stress concentrated portion. 201236846 The welded part is formed by forming a thermoplastic in the cavity of the mold and in the resin: the other two resin flow parts. Whether or not the number of the nip portions, the number of the welded portions, and the welding are formed depends on the shape of the thermoplastic resin member or the position of the replacement member for forming the mounting member. &quot;曰 The stress concentration portion includes a corner portion, a notch portion, a hollow portion, and a flow mark portion. The location or size of the a* bei hole and the stress concentration part of the temple can also be changed from the shape of the plastic resin member 黧m + m to the special feature of the heat. In the case where the method is specific to the law, it is possible to actually insert the thermoplastic resin member into the door. The shape of the member which is easily ruptured or the simulation or the like is not particularly limited. The insert member is placed in the mold using a mold having a desired cavity, and a resin composition in a molten state flows into the cavity to solidify the resin composition, whereby a desired shape can be formed on the insert member. Thermoplastic resin member. <First Embodiment> An insert molded body of the first embodiment will be described by taking an insert molded body shown in Fig. 2 as an example. Fig. 2 is a view schematically showing an insert molded body of the i-th embodiment, wherein (a) is a perspective view. (b) A plan view of (4): Fig. 3 is a perspective view schematically showing an insert member. The Fig.* is a schematic view showing the state in which the welded portion is formed. As shown in Fig. 2, the insert molding body 丨 has an insertion member 丨1 and a thermoplastic resin member 12 (hereinafter simply referred to as a resin member 12), and the resin member 12 is formed to cover one portion of the insertion member u. In the case of the first embodiment, the resin member 12 is formed on the insertion member 11 with the member member u inserted through the rectangular parallelepiped resin member 12. Then, the insert molding bottle manufactured by the mold having the mouth on the bottom side is shown in Fig. 2(a), and when the resin member 12 is formed, the welded portion 12 is generated at four places. As shown in Fig. 2, since the insertion member has four corner portions, the armature member 12 has four stress concentration portions, and the positions of the stress concentration portions and the welded portion 12. The position is the same. The insertion member 11 is closer to the bottom side than the two-dot chain line shown in Fig. 3. The portion where the bismuth is in contact with the resin member 丨2. The rough surface 11〇 is formed on the surface in contact with the sapling member 12. In the present embodiment, as shown in Fig. 3, a plurality of rough faces 11' having a rectangular shape (long side, short side L2) are formed on the side surface of the insertion member 11. The rough surface 110 is formed on the surface of the insertion member 大致 so as to be substantially parallel to the direction in which the welded portion 12A described later extends, and is substantially parallel to the "parallel parallel" of the &amp; king. The angle between the direction in which the welded portion 126 extends and the direction in which the rough surface u 延伸 extends is not particularly limited as long as it has the effect of the present invention, but the included angle is 2. The following is better. In the first embodiment, as shown in Fig. 3, the rough surface 110 is formed in the vicinity of both ends of each side surface so that the two rough surfaces 110 are arranged in parallel. The position at which the rough surface 11 0 is formed may be in the vicinity of the area immediately below the welded portion 丨2 〇. For example, there is no problem if the distance from the welded portion 12 is about 2 mm. On the other hand, from the viewpoint of operability, the shortest is about 〇. 〇· 2 mn ^ In this embodiment, since the position of the joint 14 of the welding 14 201236846 is on the ridge line on the side of the insertion member, the "nearby" 疋The distance from the ridge line to the rough surface 11 , is indicated by L in Fig. 3, and the distance between the welded portion 120 and the rough surface 110 refers to the position at which the welding portion 120 and the rough surface 110 are closest to each other. the distance between. Further, in the present embodiment, the positions of both ends of the rough surface 110 in the direction in which the welded portion 12A extends are substantially the same as the positions of both ends of the welded portion 12' (long side L, &lt; from the broken line to the insertion member u The length of the bottom surface is Lp). "Immediately-induced" means that it can also be the rough side! The positions of the ends of the one turn are slightly inside the positions of the both ends of the welded portion 12A in the predetermined direction. "Slightly inside" is only a range which is not harmful to the effects of the present invention, and the length thereof is not particularly limited, = each end. The difference between the lengths of the parts is as long as 1 of the long side. Within %, it is better within ^ 5:. Further, in the present invention, it is preferable to transmit the side of the square and the outer side of the rough surface of the predetermined direction. The position of both ends of the welded portion 120 in the 疋 direction is "the length of the new side L2 is larger than the side of the side parallel to the insertion member m L2 by 1/3 to 1/15, preferably 4 ,, and needs to be formed and connected. It is more preferable that the thicker surface of the resin is more y, and the longer the short side is required. The rough surface m uses the wrong effect to improve the adhesion of the resin member 11. The method of forming the rough surface of the member (1) There is no particular limitation, and a method can be used. For example, a method of forming a rough surface by a laser etching treatment to form a rough surface is preferred. method. In particular, the formation of the rough surface by the laser treatment is as described above, and the resin structure 4 is intended to have the welded portion 120. The tan junction 120 is formed as shown below in the following. The insert member n forming the rough surface 110 is set in the mold, and the molten thermoplastic resin is injected into the mold to be solidified. In the present embodiment, since the molten resin is emitted from the direction of the arrow Q in Fig. 4, the flow of the molten resin is divided into Q1 and Q2. Further, the welded portion 1 2 〇 is formed in the region where qi collides with the collision. In the present embodiment, the welded portion 12A is formed in a region surrounded by a dotted chain line as shown in Fig. 4 (only one of them is shown in Fig. 4 for convenience of explanation). The welded portion 120 is a rectangular region. One of the long sides of the welded portion 12 () is located at a position overlapping the side of the insertion member U. Weld η. The short side is overlapped with a part of the line connecting the upper surface and the bottom surface of the resin member 12 as shown in Fig. 4 . Next, the effect of the insert molded body of the first embodiment will be described. In the insert molded body i of the first embodiment, the rough surface 110 is formed on the surface of the insert member 11. In the portion where the rough surface 110 is formed, the adhesion of the insert member U to the resin member 12 becomes strong. As a result, even if the insert molded body of the first embodiment A is exposed to an environment having a large temperature change, the expansion and contraction of the resin member 12 are suppressed by the portion having a strong adhesion, and the turtle is formed on the surface of the resin member 12 by the P. crack. This effect is more specifically explained. Figure 5 is a schematic view for explaining the effect of the present invention, wherein the insert of the present embodiment is perpendicular to the two views, and (5) is formed in a direction perpendicular to the direction in which the welded portion extends. The rough surface (4) extending in the direction is a front view of the insert molding body on the surface of the insert, and a front view of the insert molding body 201236846 in the case of forming a rough surface. The sot insert molding body 1 is welded to the surface of the resin member 12, and borrowed! Second, there is a high probability of cracking. In the present embodiment, the rough surface 110 shown by *white= is formed in the insertion member, and even if the η:tight: force contraction, the resin member 12 and the insertion force are strong, because the contraction movement is hindered, so the contraction amount can be suppressed. . By suppressing the amount of shrinkage, the reduction effect reduces the burden on the resin member 12, and it is difficult to crack. Further, the occurrence of cracks is efficiently suppressed by the rough surface 11G extending in the direction in which the welded portion 120 extends, and the surface of the rough surface 110 which is required to be formed is suppressed. Further, as will be described later, when the area of the rough surface U 0 is large, a problem occurs. Further, as shown in Fig. 5 (4), the resin of the portion of the welded portion 12G can be made by sandwiching the welded portion 120' between the rough surface 110 formed by the insertion member u even if the resin in the direction of the blank arrow is reduced. The amount of shrinkage becomes smaller. Since the insertion surface 11 and the resin member 12 are firmly adhered to each other by the rough surface m formed on the surface of the insertion member i i , the welding portion 12 抑制 is prevented from contracting. As a result, even if the insert molded body i of the present invention is exposed to an environment having a large change in the degree of abundance, the shrinkage and expansion amount of the resin member 12 in the vicinity of the welded portion i20 are reduced, so that the shrinkage acting on the welded portion 12 can be reduced. Or the burden of swelling, and can inhibit the occurrence of cracks. The occurrence of cracks can be greatly suppressed by the position of both ends of the rough surface 110 in the predetermined direction being substantially equal to or more than the position of both ends of the welded portion 120 in the predetermined direction. In the case of the 201211846 in which the rough surface 11〇 shown in Fig. 5(b) is formed in the insertion member n, for example, since only a small portion is likely to be damaged due to shrinkage (in the present embodiment, the welded portion) 12Q), the shrinkage of the resin member 12 is hardly hindered, and the effect of improving the thermal shock resistance is hardly obtained. X, in the rough surface extending perpendicularly to the direction in which the welded portion shown in Fig. 5(b) extends, in order to sufficiently suppress the shrinkage of the resin in the vicinity of the welded portion, the area of the rough surface becomes excessive (i.e., it is required When most of the surface of the insert member that overlaps the resin member forms a rough surface, the area of the rough surface becomes too large, which tends to cause changes in physical properties such as conductivity, and the creativity is lowered. Further, after the rough surface is formed, when the surface of the insert member including the rough surface is subjected to the electro-silver treatment, the electric clock layer is formed on the uneven surface of the rough surface, and the adhesion between the resin member and the insert member is not strong. Propensity. As shown in Fig. 5(c), when the insert member is not formed with the rough surface 110, the shrinkage of the resin member and the amount of expansion of the resin member cannot be made small, and the burden of acting on the resin member 12 due to contraction and expansion of the resin member cannot be suppressed. . In the present embodiment, the rough surface is formed on the surface of the insertion member 2 by laser processing. If the method of forming a rough surface by laser treatment is used, since the local treatment is also easy, it is easy to form the rough surface in a desired range. In the above, the insert molded body of the i-th embodiment has been described. However, as shown in Fig. 6(a), the insert portion and the stress concentration portion may be the same. The insert molded body shown in Fig. 6 (4) is a portion of a side surface of a cylindrical member yak 12 which is covered with a cylindrical member inserting member u: a side surface of the resin member i2 is formed in the cylinder The direction of extension extends, field. The insert shown in Fig. 6(a) is formed into a stress concentration portion. Further, the welded portion 120 is formed so that the bottom of the groove is equivalent to the bottom of the groove. 18 201236846 Then, a rough surface 110 is formed in a region directly under the welded portion 120 of the ^11 π V-plane of the insert member 。. In the case where the rough surface 110 is formed in the region under the weld portion μ, μ. ^ female 4 Λ U, the shrinkage of the 曰μ, +. The occurrence of cracks is suppressed as in the case of the first embodiment which is not shown in the above Figs. 2 to 4M. Alternatively, for example, the insert molded body in which the welded portion and the stress concentrated portion are not included in the Fig. The insert forming system shown in Fig. 4(b) only has the shape of the groove of the tree member 12 which is different from the insert molded body shown in Fig. 6(a). . In Fig. 6 (^^, where the insert is not formed, the corner portion of the bottom of the groove and the PCT; #th thinner portion corresponds to the stress concentration portion. It is the same as the corner portion of the bottom of the groove. The position of the welded portion 120 is formed in the vicinity of the welded portion of the surface of the insert member. The area immediately below or the area of the positive: can be formed from 11 inches. In addition, the insert shown in Fig. 6 (8) Since the molded body has a plurality of stress concentration portions, a region in which the rough surface 'iU is directly under the stress concentration portion or a region directly under the stress concentration portion of the surface of the insertion member or the portion immediately below is formed When the rough surface 11 is formed in the vicinity, it is possible to suppress the occurrence of cracks in the stress concentration portion. Further, the insert portion may be formed in the welded portion and the stress concentration portion as shown in Fig. 6(C). Fig. 6 (the insert molding system shown in Fig. 在 has a groove portion of the resin member 12, and a center m of the cylindrical member of the cylindrical resin member 12, and a center m of the insertion member u, and Fig. 6 (4) The insert molded bodies shown are different. The resin member 12 The thinnest part of the thickness is the stress concentration portion, and the welded portion is formed in a square with the stress concentration portion.

S 19 201236846 120。然後,在***構件的表面之焊接部12〇之正下的區域 形成粗面110。 又,亦可疋如第7圖所示之焊接部與應力集中部一致 的***件成形體。帛7 ®所示之***件成形體的***構件 11是長方體。又’帛7圖所示之***件成形體的樹脂構件 12係以包圍長方體之***構件丨丨且***件成形體整體成 為長方體的方式所形成 '然後,在樹脂構件12,將6處空 心部形成於側面。以點圖案表示帛7圖所示之***件成形 體之樹脂構件12耗力集中部。又,以虛線表示焊接部 120。如第7圖所示’因為焊接部12〇的位置與應力集中部 的區域重疊’所以可說焊接冑120的位置與應力集中部的 位置一致。 〈第2實施形態〉 第8圖係在杈式上表示第2實施形態之***件成形體 的立體圖。如第8圖所#,以覆蓋四角柱形的***構件n 之側面之一部分的方式形成樹脂構件12。位於***構件H 之側面的4處角落部分相當於應力集中部。而i,藉由調 整澆口的位置’焊接部12〇以與應力集中部大致平行的方 式形成於應力集中部與應力集中部之間。在第2實施形 態,在***構件u的表面之焊接部12〇之正下的區域或正 下的區域附近、應力集中部之正下的區域或正下的區域附 近形成粗面粗® 110,使樹脂構件的耐熱衝擊性提高。此 外,第2實施形態之***構件u的形狀係與第^施形態 的***構件11 —樣,除了在插人構件11的表面之焊接部 20 201236846 120之正下的區域或正下的區域附近亦形成粗面HQ以 外,係與在第1實施形態所使用之***構件—樣。 又,亦可是如第9圖所示之焊接部120與應力集中部 不一致的***件成形體。雖然第9圖所示之***件成形體 的形狀係與苐7圖所示之***件成形體一樣,但是在焊接 部120(虛線)的位置與應力集中部(點部分)不重疊上,與 第7圖所示之***件成形體相異。在第9圖所示之***件 成形體的情況’在焊接部120之正下的區域或正下的區域 附近、應力集中部之正下的區域或正下的區域附近形成粗 面’使樹脂構件1 2的耐熱衝擊性提高。 〈第3實施形態〉 第10圖係表不第3實施形態之***件成形體的立體 圖。雖然第10圖所示之***件成形體的形狀係與第8圖所 示之***件成形體一樣,但是在樹脂構件12不具有焊接部 120上,與第8圖所示之***件成形體相異。藉由在*** 件成形體的底面側調整澆口的位置,而未形成焊接部丨2〇。 在第3實施形態的***件成形體,在***構件的表面之應 力集中部之正下的區域或正下的區域附近形成粗面11〇。 〈第4實施形態〉 第4實施形態是本發明之***件成形體的製造方法。 第4實施形態之***件成形體的製造方法具有:粗面形成 製程’係將粗面形成於***構件的表面;及熱可塑性樹脂 構件形成製程(在本專利說明書,有稱為樹脂構件形成製程 的情況)’係將熱可塑性樹脂構件形成於已形成粗面之*** 21 201236846 構件的表面之至少一部分。 在***構件之表面的粗面係在樹脂構件具有焊接部的 情況’形成於全部之焊接部之正下的區域及/或正下的區域 附近,而樹脂構件不具有焊接部的情況,形成於全部之應 力集中部之正下的區域及/或正下的區域附近,在是熱可塑 性树月曰構件具有焊接部與應力集中部的情況,且焊接部之 位置與應力集中部之位置不一致或不大致一致的情況,形 成在***構件的表面之全部的焊接部之正下的區域及/或 正下的區域附近、與全部的應力集中部之正下的區域及/ 或正下的區域附近。此外,關於粗面、***構件之具體的 内令’因為ir'如在第1實施形態〜第3實施形態的說明所 示’所以省略其說明。 關於焊接部、應力集中部等,因為係如在第(實施形 態〜第3實施形態的說明所示,所以省略其說明。如上述所 示,形成焊接部的位置或是否形成焊接部,係才艮據所使用 之逢口的位置決定。 右依據本實施形態之***件成形體的製造方法,即使 ***件成形體曝露於溫度變化大的環境下,亦可使樹脂之S 19 201236846 120. Then, a rough surface 110 is formed in a region directly under the welded portion 12 of the surface of the insertion member. Further, an insert molded body in which the welded portion and the stress concentrated portion are aligned as shown in Fig. 7 may be used. The insertion member 11 of the insert molded body shown by 帛7® is a rectangular parallelepiped. Further, the resin member 12 of the insert molded body shown in Fig. 7 is formed so as to surround the rectangular parallelepiped insert member and the entire insert molded body is a rectangular parallelepiped. Then, in the resin member 12, six hollow portions are formed. Formed on the side. The resin member 12 of the insert molded body shown in Fig. 7 is shown in a dot pattern as a power concentrating portion. Further, the welded portion 120 is indicated by a broken line. As shown in Fig. 7, the position of the welded portion 120 coincides with the position of the stress concentration portion because the position of the welded portion 12A overlaps with the region of the stress concentration portion. <Second Embodiment> Fig. 8 is a perspective view showing the insert molded body of the second embodiment. As shown in Fig. 8, the resin member 12 is formed so as to cover a portion of the side surface of the quadrangular prism-shaped insertion member n. The four corner portions on the side of the insertion member H correspond to the stress concentration portion. Further, i is formed between the stress concentration portion and the stress concentration portion by adjusting the position of the gate, the welded portion 12, substantially parallel to the stress concentration portion. In the second embodiment, the rough surface roughness is formed in the vicinity of the region immediately below the welded portion 12 of the surface of the insertion member u or in the vicinity of the region immediately below, or in the vicinity of the region immediately below the stress concentration portion, or in the vicinity of the region immediately below. The thermal shock resistance of the resin member is improved. Further, the shape of the insertion member u of the second embodiment is the same as that of the insertion member 11 of the second embodiment, except for the area immediately below or below the welded portion 20 201236846 120 on the surface of the insertion member 11. In addition to the rough surface HQ, it is the same as the insert member used in the first embodiment. Further, an insert molded body in which the welded portion 120 and the stress concentrated portion do not coincide with each other as shown in Fig. 9 may be used. Although the shape of the insert molded body shown in Fig. 9 is the same as that of the insert molded body shown in Fig. 7, the position of the welded portion 120 (dotted line) does not overlap with the stress concentrated portion (dot portion), and The insert molded bodies shown in Fig. 7 are different. In the case of the insert molded body shown in Fig. 9, 'the rough surface' is formed in the vicinity of the region immediately below the welded portion 120 or in the vicinity of the region immediately below, or in the vicinity of the region immediately below the stress concentration portion. The thermal shock resistance of the member 12 is improved. <Third Embodiment> Fig. 10 is a perspective view showing an insert molded body according to a third embodiment. Although the shape of the insert molded body shown in Fig. 10 is the same as that of the insert molded body shown in Fig. 8, the resin member 12 does not have the welded portion 120, and the insert molded body shown in Fig. 8 Different. The welded portion 未2〇 is not formed by adjusting the position of the gate on the bottom surface side of the insert molded body. In the insert molded body of the third embodiment, the rough surface 11〇 is formed in the region immediately below the stress concentration portion on the surface of the insert member or in the vicinity of the region immediately below. <Fourth Embodiment> A fourth embodiment is a method for producing an insert molded body of the present invention. The method for producing an insert molded body according to the fourth embodiment has a rough surface forming process of forming a rough surface on the surface of the insert member, and a thermoplastic resin member forming process (in this patent specification, there is a resin member forming process). The case where the thermoplastic resin member is formed on at least a part of the surface of the insert 21 201236846 member in which the rough surface has been formed. The rough surface of the surface of the insertion member is formed in a region where the resin member has a welded portion, and is formed in a region immediately below the entire welded portion and/or in a vicinity of a region immediately below, and the resin member does not have a welded portion, and is formed in the case where the resin member has a welded portion. In the vicinity of the region immediately below the stress concentration portion and/or in the vicinity of the region immediately below, the thermoplastic resin tree member has a welded portion and a stress concentration portion, and the position of the welded portion does not coincide with the position of the stress concentration portion. In the case where they do not substantially coincide with each other, the region immediately below the welded portion of the surface of the insert member and/or the region immediately below, and the portion immediately below the entire stress concentration portion and/or the region immediately below are formed. . In addition, the specific internal order of the rough surface and the insert member is ir' as described in the description of the first embodiment to the third embodiment, and the description thereof will be omitted. Since the welding portion, the stress concentration portion, and the like are as described in the first to third embodiments, the description thereof will be omitted. As described above, the position of the welded portion or the formation of the welded portion is formed. Depending on the position of the mouth to be used. According to the method of manufacturing the insert molded body of the present embodiment, even if the insert molded body is exposed to an environment having a large temperature change, the resin can be made.

收縮量、膨脹量變小。這是由於藉由存在提高***構件U 與樹脂構件12之間之密接力的部分,阻礙樹脂之收縮及膨 脹的運動。結果,改善樹脂構件的耐熱衝擊性,而可抑制 樹脂之收縮及膨脹所造成之龜裂的發生。 此外,在本發明的劁】告古、土 .. I把方法,在粗面形成製程之前具 有龜裂發生位置確認製程較佳 狂权住龜裂發生位置確認製程係 22 201236846 利用熱使使用A形成粗面的插人構件所製造之插人件成形 體的熱可塑性樹脂構件膨脹、收縮後確認熱可塑性樹脂 構件之表面的龜裂發生位置的製程。藉由具有本製程,^ 使是未預先知道易發生龜裂之位置(應力集中部之位置)的 情況,亦可從龜裂發生位置確認該位置。 因此,如上述所示確認應力集中部的位置後藉由將 粗面形成在***構件的表面之應力集中部之正下的區域或 正下的區域附,即使是未預先知道易發生龜裂之位置的情 況’亦可提高樹脂構件的耐熱衝擊性。 [實施例] 以下,利用實施例具體說明本發明,但是本發明未限 定為該實施例。 〈第1實施例〉 在熱可塑性樹脂構件的形成使用ppS樹脂,作為*** 構件’使用SUS(S52C)’利用以下所示的方法,製造了第2 圖所示的***件成形體。***構件的尺寸係縱14111[11&gt;&lt;橫 14mmx高度46mm。如第3圖所示,在該***構件的側面之 與樹脂構件接觸的面’藉由以雷射束光點直徑約13〇 # m施 加雷射加工,而形成Li = 22mm、L2 = 2mm的粗面。此外,距離 U設為2nun。粗面形成於4個側面的全部(共8處)。 將該樹脂成形體配置於模具,並使溶化狀態的PPS樹 脂向模具内流入’藉此’製造實施例的***件成形體。具 體而言,利用以下的方法製造。使用樹脂粒(含有彈性體之 熱衝擊等級上市品「FN1150T7」),以缸體溫度32〇t、模 23 201236846 具溫度150°C、射出時間〇. 84秒、冷卻時間40秒,在測 試片成形用模具(在縱22mm、橫22mm、高度28mm的角柱内 部***縱14mm、橫14mm、高度46mm之鐵芯的模具),以樹 月曰部之最薄厚度成為lmm的方式進行***射出成形,而製 造***件成形體。此外,為了後述之耐熱衝擊性的評估, 製造了共3個該***件成形體。 〈第1比較例〉 除了***構件的表面未形成粗面以外,利用與第1實 施例相同的方法製造第1比較例的***件成形體。此外, 為了後述之耐熱衝擊性的評估,製造了共3個一樣的*** 件成形體。 〈第2比較例&gt; 除了在與焊接部所延伸之方向垂直的方向延伸,而且 通過焊接部的中央部分,粗面之大小&amp; 2龍寬度X全周以 外,利用與第1實施例相同的方法製造第2比較例的*** 體此外’為了後述之耐熱衝擊性的評估,製造了 共3個-樣的插人件成形體。 〈評估〉The amount of shrinkage and the amount of expansion become small. This is because the portion where the adhesion between the insertion member U and the resin member 12 is increased is present, and the contraction and expansion of the resin are hindered. As a result, the thermal shock resistance of the resin member is improved, and the occurrence of cracks caused by shrinkage and expansion of the resin can be suppressed. In addition, in the present invention, the method of smashing the earth, the soil.. I method, the crack occurrence location confirmation process before the rough surface forming process is better, the madness of the crack occurrence location confirmation process system 22 201236846 using heat to use A The thermoplastic resin member of the insert molded body produced by forming the rough-faced insert member is expanded and contracted, and the crack occurrence position of the surface of the thermoplastic resin member is confirmed. By having this process, the position where the crack is likely to occur (the position of the stress concentration portion) is not known in advance, and the position can be confirmed from the crack occurrence position. Therefore, after confirming the position of the stress concentration portion as described above, the rough surface is formed in the region immediately below the stress concentration portion of the surface of the insertion member or the region immediately below, even if it is not known in advance that cracking is likely to occur. In the case of position, the thermal shock resistance of the resin member can also be improved. [Examples] Hereinafter, the present invention will be specifically described by way of examples, but the present invention is not limited to the examples. <First embodiment> The ppS resin was used for the formation of the thermoplastic resin member, and the insert molded body shown in Fig. 2 was produced by the following method using SUS (S52C) as the insert member. The size of the insert member is 14111 [11 &gt;&lt; horizontal 14 mm x height 46 mm. As shown in Fig. 3, the surface "in contact with the resin member on the side surface of the insertion member" is subjected to laser processing with a laser beam spot diameter of about 13 〇 # m to form Li = 22 mm and L2 = 2 mm. Rough surface. In addition, the distance U is set to 2nun. The rough surface was formed on all four sides (eight in total). The resin molded body was placed in a mold, and the PPS resin in a molten state was allowed to flow into the mold. The insert molded body of the example was produced. Specifically, it is produced by the following method. Resin pellets (thermal shock grade listed product "FN1150T7" containing elastomer) were used, with a cylinder temperature of 32 〇t, modulo 23 201236846 with a temperature of 150 ° C, an injection time of 84 84 seconds, and a cooling time of 40 seconds. The molding die (a mold in which a core of 14 mm in length, 14 mm in width, and 46 mm in height is inserted into a corner column having a length of 22 mm, a width of 22 mm, and a height of 28 mm) is inserted and injection molded so that the thinnest thickness of the sap portion is 1 mm. The insert molded body is manufactured. Further, a total of three insert molded bodies were produced for the evaluation of the thermal shock resistance to be described later. <First comparative example> An insert molded body of the first comparative example was produced by the same method as that of the first embodiment except that the surface of the insert member was not formed with a rough surface. Further, for the evaluation of the thermal shock resistance to be described later, a total of three identical insert molded bodies were produced. <Second Comparative Example> The same as in the first embodiment except that the center portion of the welded portion extends in the direction perpendicular to the direction in which the welded portion extends, and the size of the rough surface &amp; In the method of manufacturing the insert of the second comparative example, in addition to the evaluation of the thermal shock resistance to be described later, a total of three insert-shaped molded articles were produced. <assessment>

利用 LV 下的方法進行耐熱衝擊性的評估。使用冷孰衝 擊測試機,姐7 .,、、呵 +所仔之3個***件成形體,進行以在18〇t \小時後,降溫p4〇t, 180°C的過护* , 町便丹升/皿至 循環取J 環的耐熱衝擊測試…面每隔20個 數,而坪估了 ^ ’一面測量至在成形品發生龜裂的循環 耐熱衝擊性。在第1表表示評估結果。 201236846 [第1表]The thermal shock resistance was evaluated by the method of LV. Using the cold heading test machine, the sisters 7 , , , , and the three inserts of the molded body were carried out to cool the p4〇t, 180 °C after 18 〇t hours, and the town Dansheng/dish to cycle to take the J-ring's thermal shock test... every 20th surface, and ping estimated ^' side to measure the thermal shock resistance of the cycle in which the molded product is cracked. The evaluation results are shown in the first table. 201236846 [Table 1]

表,確認藉由在***構件的表面之焊接 下的區域或正下的區域附近形 伸的鈿Λ牡/、焊接部相同方向所延 申勺粗面’而耐熱衝擊性提高。 接部所延伸的方向番亩方6 χ心即使形成在與焊 會提言 ° D延伸的粗面,耐熱衝擊性亦不 〈第2實施例&gt; 在熱可塑性樹脂構件的形成使用m樹脂,作為*** 構件,使帛SUS(S52C),利用以下所示的方法,製造了第 1〇圖所示的***件成形體。***構件的尺寸係縱14贿橫 14随X高度46麗。如第3圖所示,在該***構件的側面之 與樹脂構件接觸的面,藉由以雷射束光點直徑約13〇/zm施 加雷射加工,而形成Ι^ = 22ιηιη ' L2 = 2mm的粗面。此外,距離 L3設為l〇〇#m。粗面形成於4個側面的全部(共8處)。 將該樹脂成形體配置於模具,並使熔化狀態的PBT樹 脂向模具内流入,藉此,製造實施例的***件成形體。具 體而言,利用以下的方法製造。使用樹脂粒(上市品 「DX733LD」),以缸體溫度25〇。〇、模具溫度8〇乞、射出 時間0. 8秒、冷卻時間1 〇秒,在測試片成形用模具(在縱 25 201236846 15. 4mm、橫15. 4mm、高度28mm的角柱内部***縱i4mm、 橫14ππη、高度46職之鐵芯的模具),以樹脂部之最薄厚度 成為0. 7mm的方式進行***射出成形,而製造***件成形 體。此外,為了後述之耐熱衝擊性的評估,製造了共5個 該***件成形體。 〈第3比較例〉 除了***構件的表面未形成粗面以外,利用與第2實 施例相同的方法製造第3比較例的插人件成形體。此外,、 為了後述之耐熱衝擊性的評估,製造了共5個—樣的*** 件成形體。 〈評估〉 利用以下的方法進行耐熱衝擊性的評估。使用冷熱子 擊測试機’對所得之5個插人件成形體,進行以在U(n 加熱h5小時後’降溫至-40°C,冷卻1.5小時後,再^ 至140 C的過程為—個循環的耐熱衝擊測試,一面每朽 環數’而評估耐熱衝擊性。在第2表表示評估結果。 [第2表]In the table, it was confirmed that the thermal shock resistance was improved by the fact that the surface of the insert member was welded or the vicinity of the region immediately below, and the weld portion was extended in the same direction. In the direction in which the joint portion is extended, even if it is formed on the rough surface which is extended by the weld, the thermal shock resistance is not changed. [Second embodiment] The m resin is used for the formation of the thermoplastic resin member. The insert member was produced by the 帛 SUS (S52C) by the method shown below, and the insert molded body shown in Fig. 1 was produced. The size of the insert member is 14 horizontally 14 with a height of 46. As shown in Fig. 3, a surface which is in contact with the resin member on the side surface of the insertion member is formed by laser processing with a laser beam spot diameter of about 13 Å/zm to form Ι^ = 22ιηιη ' L2 = 2 mm. The rough side. Further, the distance L3 is set to l〇〇#m. The rough surface was formed on all four sides (eight in total). The resin molded body was placed in a mold, and a PBT resin in a molten state was allowed to flow into the mold, whereby the insert molded body of the example was produced. Specifically, it is produced by the following method. Resin pellets (listed as "DX733LD") are used, and the cylinder temperature is 25 〇. 〇, mold temperature 8 〇乞, injection time 0.8 sec, cooling time 1 〇 second, in the test piece forming mold (in the vertical 25 201236846 15. 4mm, horizontal 15.4mm, height 28mm inside the corner column inserted vertical i4mm, In the mold of the iron core having a height of 14 ππη and a height of 46, the insert molded body was produced by insert-injection molding so that the thinnest thickness of the resin portion was 0.7 mm. Further, a total of five insert molded bodies were produced for the evaluation of the thermal shock resistance to be described later. <Third Comparative Example> The insert molded body of the third comparative example was produced by the same method as in the second embodiment except that the rough surface was not formed on the surface of the insert member. Further, in order to evaluate the thermal shock resistance described later, a total of five insert-like molded bodies were produced. <Evaluation> The following methods were used to evaluate the thermal shock resistance. Using the hot and cold sub-testing machine's 5 pieces of the formed inserts, the process was carried out in U (n heating after 5 hours, 'cooling to -40 ° C, cooling for 1.5 hours, then ^ to 140 C - The thermal shock resistance of one cycle is evaluated, and the thermal shock resistance is evaluated on the side of each ring. The evaluation results are shown in Table 2. [Table 2]

從第2表 確認藉由在***構件的表面之應力集甲部 20個搞ί哀取出並確認,—面測量至在成形品發生龜裂的名 26 201236846 之正下的區域或正下的區域附近形成在與應力集中部相同 方向所延伸的粗面,而耐熱衝擊性提高。 【圖式簡單說明】 第1圖係表示剖面線寬之概念的圖。 第2圖係在模式上表示***件成形體的圖,(幻係立體 圖,(b)係(a)的上視圖。 第3圖係在模式上表示***構件丨丨的立體圖。 第4圖係表示形成焊接部之狀況的模式圖。 第5圖係用以說明本發明的效果之***件成形體的模 式圖’⑷係本實施形態之***件成形體i的正視圖,⑻ 係與焊接部所延伸之既定方向垂直地形成粗面的情況之插 入件成形體的正視圖’ (c)係在***件的表面未形成粗面的 情況之***件成形體的正視圖。 第6圖(a)〜(c)係在模式上表示與第2圖所示的***件 成形體相異之焊接部與應力集中部一致的***件成形體之 具體例的平面圖。 第7圖係在模式上表示與第2、6圖所示的***件成形 體相異之焊接部與應力集中部—致的***件成形體之具體 例的立體圖。 第8圖係在模式上表示在熱可塑性樹脂構件具有焊接 部與應力集&quot;,且焊接部之位置與應力集中部之位置不 一致的情況之***件成形體之具體例的立體圖。 第9圖係在模式上表示在與第8圖所示的***件成形 2Ί 201236846 體相異之焊接部之位置與應力集中部之位置不一致的情況 之***件成形體之具體例的立體圖。 第1 〇圖係在模式上表示在熱可塑性樹脂構件不具有 焊接部,而僅具有應力集中部的情況之***件成形體的立 體圖。 【主要元件符號說明】 I ***件成形體 II ***構件 11 0粗面 12 樹脂構件 120焊接部 28From the second table, it is confirmed that 20 pieces of the stress-collecting part on the surface of the insert member are taken out and confirmed, and the surface is measured to the area directly under the name 26 201236846 where the molded product is cracked or the area immediately below. The rough surface extending in the same direction as the stress concentration portion is formed in the vicinity, and the thermal shock resistance is improved. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing the concept of a section line width. Fig. 2 is a view showing the insert molded body in a mode, (a perspective view, (b) is a top view of (a). Fig. 3 is a perspective view showing the insertion member 在 in a mode. Fig. 4 Fig. 5 is a schematic view showing an insert molded body for explaining the effects of the present invention. (4) is a front view of the insert molded body i of the present embodiment, and (8) is a welded portion. A front view of the insert molding body in the case where the rough direction is formed in a predetermined direction is extended (c) is a front view of the insert molding body in the case where the rough surface is not formed on the surface of the insert. Fig. 6 (a) (c) is a plan view showing a specific example of the insert molded body in which the welded portion and the stress concentration portion are different from the insert molded body shown in Fig. 2 in the mode. Fig. 7 is a schematic representation A perspective view of a specific example of an insert molded body in which a welded portion and a stress concentration portion are different from the insert molded body shown in Figs. 2 and 6 . Fig. 8 is a view schematically showing welding of a thermoplastic resin member in a mode. Department and stress set &quot;, and the welding department A perspective view showing a specific example of the insert molded body in a case where the position of the stress concentration portion does not match. Fig. 9 is a view schematically showing the position of the welded portion different from the insert molding 2 Ί 201236846 shown in Fig. 8. A perspective view of a specific example of the insert molded body in a case where the position of the stress concentration portion does not match. The first drawing schematically shows the insert in the case where the thermoplastic resin member does not have a welded portion and only has a stress concentration portion. A perspective view of a molded body. [Description of main component symbols] I Insert molded body II Inserting member 11 0 rough surface 12 Resin member 120 welded portion 28

Claims (1)

201236846 七、申請專利範圍: 1 · 一種***件成形體,具有***構 媸从 ± 及被覆該*** 構件之表面的至少一部分之熱可塑性樹脂構件, 其中該熱可塑性樹脂構件係具有一個以上之在既定方 向所延伸的焊接部; 在該***構件之表面的一部分, _ 刀 Φ成在與該焊接部相 同之方向所延伸的粗面; 該粗面係配置於在該***構件的砉 偁仟的表面之全部的該焊接 邠之正下的區域及/或該正下的區域附近; 該粗面之兩端的位置係與該焊接部之兩端的位置大致 一致或更外側。 2.-種***件成形體’具有***構件、及被覆該*** 構件之表面的至少一部分之熱可塑性樹脂構件, 其中該熱可塑性樹脂構件係具有一個以上之因該熱可 塑性樹脂構件之膨脹收縮所產 丨度生之應力集中的應力集中 部,該應力集中部係在既定方向延伸; 在該***構件之表面的-部分,形成在與該應力集中 部相同之方向所延伸的粗面; 該粗面係配置於在該***構件的表面之全部的該應力 集中部之正下的區域及/或該正下的區域附近; 該粗面之兩端的位置係與該應力集中部之兩端的位置 大致一致或更外側。 3.如申請專利範圍第1項之***件成形體,其中進 而’該熱可塑性樹脂構件係具有-個以上之因該熱可塑性 29 201236846 樹脂構件之膨脹收縮所產生之應力集中的應力集中部該 應力集中部係在既定方向延伸; 在與該應力集中部相同之方向所延伸的粗面係配置於 在該***構件的表面之全部的該應力集中部之正下的區域 及/或該正下的區域附近; 該粗面之兩端的位置係肖該應力#中部之兩端的位置 大致一致或更外側。 4. 如申請專利範圍第丨項之***件成形體,其中進 而該熱可塑性樹脂構件係具有一個以上之因該熱可塑性 樹脂構件之膨脹收縮所產生之應力t中的應力集中部,該 應力集中部係在既定方向延伸; 至少一處之該應力集中部的位置與該焊接部的位置大 致一致。 5. 如申請專利範圍帛1至4項中任一項之***件成形 體,其中至少一處之該粗面係被設置成夾住在該***構件 的表面之該烊接部及/或該應力集中部之正下的區域。 6. 如申凊專利範圍第1至4項中任一項之***件成形 體’其中該粗面係利用雷射所形成的粗面。 7. 如申請專利範圍第1至4項中任一項之***件成形 體其中該熱可塑性樹脂構件係由結晶性熱可塑性樹脂組 成物所構成。 8. 如申请專利範圍第1至4項中任一項之***件成形 體’其中該結晶性熱可塑性樹脂組成物係聚亞芳硫醚系樹 月旨組成物或聚對笨二甲酸丁二醇酯系樹脂組成物。 30 201236846 ’製造具有***構 部分之熱可塑性樹 9. 一種***件成形體的製造方法 件、及被覆該***構件之表面的至少一 脂構件之***件成形體, 其中該熱可塑性樹脂構件係 再仟係具有一個以上之在既定方 向所延伸的焊接部及應力集中部的至少—方; 具有: ’ 粗面形成製程’係在該熱可塑性樹脂構件具有焊接部 的情況,在***構件的表面之全部的該焊接部之正下的區 域及/或該正下的區域附近形成在與該焊接部相同之方向 所延伸的粗面;在該熱可塑性樹脂構件不具有焊接部的情 況,在***構件的表面之全部的該應力集中部之正下的區 域及/或該正下的區域附近形成在與該應力集中部相同之 方向所延伸的粗面.尤 部與該應力集二二ΠΓ性樹脂構件具有該焊接 P,清况,且知接部之位置與應力集中部 之位置不-致或不大致一致的情況,在該***構件的表面 2部料接部之正下的區域及/或正下的區域附近形成 隹該,接部相同之方向所延伸的粗面、與在全部的該應 '、申P之正下的區域及/或正下的區域附近形成在與該 應力集中部相同之方向所延伸的粗面;及 熱可塑性樹脂構件形成製程,係將該粗面形成製程後 的***構件配置於模具後,向該模具***出炼化的熱可塑 :樹月曰’而以被覆該粗面之至少一部分的方式將熱可塑性 祕月曰構件形成於該插人構件的表面; 在該熱可塑性樹脂構件具有焊接部的情況,該粗面之 31 201236846 兩端的位置大致一致或更外 兩端的位置係與該焊接部之兩 側; 不具有焊接部的情況,該粗面 中部之兩端的位置大致一致或 在該熱可塑性樹脂構件不具 之兩端的位置係與該應力集中部 更外側;201236846 VII. Patent application scope: 1 . An insert molded body having a thermoplastic resin member having an insertion structure from ± and covering at least a part of a surface of the insertion member, wherein the thermoplastic resin member has more than one a welded portion extending in a direction; a portion of the surface of the insert member, the _ knife Φ being a rough surface extending in the same direction as the welded portion; the rough surface being disposed on a surface of the cymbal of the insert member All of the areas immediately below the weld rim and/or the vicinity of the area immediately below; the positions of the ends of the rough surface are substantially the same as the positions of the ends of the welded portion or the outside. 2. An insert molded body' having an insert member and a thermoplastic resin member covering at least a portion of a surface of the insert member, wherein the thermoplastic resin member has more than one expansion and contraction of the thermoplastic resin member a stress concentration portion in which the stress concentration is concentrated, the stress concentration portion extending in a predetermined direction; a portion of the surface of the insertion member being formed in a rough surface extending in the same direction as the stress concentration portion; The surface is disposed in a region immediately below the stress concentration portion of the surface of the insertion member and/or in the vicinity of the region immediately below; a position of both ends of the rough surface is substantially at a position of both ends of the stress concentration portion Consistent or outside. 3. The insert molded body according to claim 1, wherein the thermoplastic resin member further has a stress concentration portion of - or more stress concentration due to expansion and contraction of the thermoplastic member 29 201236846 resin member. The stress concentration portion extends in a predetermined direction; the rough surface extending in the same direction as the stress concentration portion is disposed in a region directly under the stress concentration portion of the surface of the insertion member and/or directly below Near the area; the position of the ends of the rough surface is the same as the position of the two ends of the middle portion of the stress. 4. The insert molded body according to claim 2, wherein the thermoplastic resin member further has one or more stress concentration portions in a stress t due to expansion and contraction of the thermoplastic resin member, the stress concentration The portion extends in a predetermined direction; the position of the stress concentration portion at least one portion substantially coincides with the position of the welded portion. 5. The insert shaped body of any one of claims 1 to 4, wherein at least one of the rough faces is configured to be sandwiched by the splicing portion of the surface of the insert member and/or The area directly under the stress concentration section. 6. The insert formed body of any one of claims 1 to 4 wherein the rough surface is a rough surface formed by a laser. 7. The insert molded body according to any one of claims 1 to 4 wherein the thermoplastic resin member is composed of a crystalline thermoplastic resin composition. 8. The insert molded body of any one of claims 1 to 4, wherein the crystalline thermoplastic resin composition is a polyarylene sulfide-based tree composition or a poly(p-phenylene dicarboxylate) An alcohol ester resin composition. 30 201236846 'Production of a thermoplastic tree having an insert portion 9. A method of manufacturing an insert molded body, and an insert molded body of at least one grease member covering the surface of the insert member, wherein the thermoplastic resin member is further The lanthanum has at least one of a weld portion and a stress concentration portion extending in a predetermined direction; and has: 'a rough surface forming process' in the case where the thermoplastic resin member has a welded portion, on the surface of the insert member All of the areas immediately below the welded portion and/or the vicinity of the portion immediately below are formed in a rough surface extending in the same direction as the welded portion; in the case where the thermoplastic resin member does not have a welded portion, the insert member a portion of the surface directly under the stress concentration portion and/or the vicinity of the portion immediately below is formed in a rough surface extending in the same direction as the stress concentration portion. The portion and the stress collector diterpenoid resin The member has the welding P, the condition of the condition, and the position of the known joint portion and the position of the stress concentration portion are not uniform or not substantially identical, The area immediately below the surface of the two-part material of the insert member and/or the vicinity of the area immediately below are formed, and the rough surface extending in the same direction of the joint portion, and the entire portion of the joint, a rough surface extending in the same direction as the stress concentration portion in the vicinity of the region and/or the immediately below region; and a thermoplastic resin member forming process for disposing the insert member after the rough surface forming process in the mold Injecting the refining and heating thermoplastic into the mold: forming a thermoplastic thermoplastic mooncake member on the surface of the insertion member in such a manner as to cover at least a portion of the rough surface; and welding the thermoplastic resin member In the case of the portion, the positions of the rough faces 31 201236846 are substantially the same or the positions of the outer ends are opposite to the sides of the welded portion; in the case of not having the welded portion, the positions of the ends of the middle portion of the rough face are substantially the same or The position of the thermoplastic resin member not having both ends is outside the stress concentration portion; 所形成之該焊接部或應力集中部之兩端的位置大致一致或 更外側。 1 0.如申請專利範圍第9項之***件成形體的製造方 法,其中更具有龜裂發生位置確認製程,該製程係在該粗 面形成製程之則’利用熱使使用未形成粗面的***構件所 製造之***件成形體的熱可塑性樹脂構件膨脹、收縮後, 確認熱可塑性樹脂構件之表面的龜裂發生位置。 11.如申請專利範圍第1 〇項之***件成形體的製造方 法,其中該粗面係形成於在該龜裂發生位置確認製程所破 認之發生龜裂的預測位置附近。 32The positions of both ends of the welded portion or the stress concentration portion formed are substantially the same or more. 1 . The method for producing an insert molded body according to claim 9 , further comprising a crack occurrence position confirming process, wherein the process is formed by the heat forming process using the heat without using a rough surface. After the thermoplastic resin member of the insert molded body produced by the insert member was expanded and contracted, the crack occurrence position on the surface of the thermoplastic resin member was confirmed. 11. The method of producing an insert molded article according to the first aspect of the invention, wherein the rough surface is formed in the vicinity of a predicted position at which the crack is broken by the crack occurrence position confirmation process. 32
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US10322535B2 (en) 2013-03-26 2019-06-18 Daicel Polymer Ltd. Method of manufacturing composite molded body
US11267171B2 (en) 2013-03-26 2022-03-08 Daicel Polymer Ltd. Method of manufacturing composite molded body

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WO2012073694A1 (en) 2012-06-07

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