TW201224065A

TW201224065A - Coloring composition for color filter, color filter, display element, and pigment dispersion for color filter

Info

Publication number: TW201224065A
Application number: TW100139504A
Authority: TW
Inventors: Hidenori Naruse; Shou Matsumoto; Tomohiro Takami; Takaki Minowa
Original assignee: Jsr Corp
Priority date: 2010-11-08
Filing date: 2011-10-31
Publication date: 2012-06-16
Also published as: JP2012118505A; JP5919698B2; TWI510564B; KR101762449B1; KR20120049131A; CN102540711B; CN102540711A

Abstract

The present invention provides a coloring composition capable of producing a color filter with excellent chroma features, high contrast and good heat and solvent resistance. A coloring composition for a color filter is characterized by comprising the following components (A), (B) and (C): (A) a coloring agent including pigments; (B) a copolymer that comprises a repeating unit (1) represented by the following formula (1), a repeating unit (2) represented by the following formula (2) and a repeating unit (3) having a cross-linking functional group, wherein the copolymerization ratio of the repeating unit (2) is 90 % by mass of the total repeating unit excluding the repeating unit (1) and the repeating unit (3); and (C) a cross-linking agent. [In the formula (1), R1 represents a hydrogen atom or a methyl group, Z represents -N+R2R3R4Y- (wherein R2 to R4 each independently represent a hydrogen atom or an optionally substituted hydrocarbon group and Y- represents a counter anion), -NR5R6 (wherein R5 and R6 each independently represent a hydrogen atom or an optionally substituted hydrocarbon group) or an optionally substituted nitrogen-containing heterocyclic group, and X1 represents divalent connecting groups; and in the formula (2), R7 represents a hydrogen atom or a methyl group, and R8 represents a saturated aliphatic hydrocarbon group or a saturated alicyclic type hydrocarbon group].

Description

201224065 六、發明說明：【發明所屬之技術頜域】本七明係關於彩色濾光片用著色組成物、彩色濾光片、顯示元件及彩色濾光片用顏料分散液，更詳言之，係關於在穿透型或反射型之彩色液晶顯示^件^體攝 ::件、有機EL顯示元件、電子紙等使用之彩色滤光片為有用之著色層形成所用之著色組成物、具備使用該著色組成物形成之著色層的彩 ^ ^ .. 石匕,J矽巴/愿先片、及具備該彩色濾光片之顯示元件。【先前技術】使用著色感放射線性組成物製造彩色濾光片時，已知有以下方法:在基板上塗布顏料分散型之著色感放射線性組成物並乾燥之後’將乾燥塗膜以所望圖案形狀照射放射線⑼下稱為「曝光」。）並進行_，藉此獲得各色之畫素(專利文獻卜2)。又，亦已知有利用使碳黑分散而得之光聚合性組成物來形成黑色矩陣之方法（專利文獻3)。再者，也已知有使用顏料分散型之著色熱硬化性樹脂組成物利用噴墨方式彳彳# ‘ ' 土八U传各色晝素之方法（專利文獻4)。攝像元件使用之彩色濾光高對比度化之要求，使用。為了實現如此微粒化之已知使用分散劑係為有改善顏料的分散性，而使且顯影性等也提升的各種而於液晶顯示元件或固體片之領域中’伴隨高輝度化或之顏料有越來越微粒化的傾向顏料的安定且良好的分散性效。已有人提供使用該分散劑得對比度或分散安定性提升，方法（專利文獻5〜6)。 -5 - 201224065 先前技術文獻專利文獻專利文獻1 日本特· 專利文獻2 日本特專利文獻3 日本特專利文獻4 日本特專利文獻5 日本特專利文獻6 曰本特【發明内容】開平2-144502號公報開平3-53201號公報開平6-3 5 1 88號公報開2000-3 10706號公報開2009-258 1 3號公報開2010-13441 9號公報 [發明的概要] [發明欲解決之課題] 但是即便依照該等專利文獻5〜6記載之方法，仍難以達成近年對於彩色液晶顯示元件之高對比度化、高色純度化及尚輝度化的要求，且也難解決彩色濾光片量產中的耐熱性、耐溶劑性等各問題。所以，強烈需求開發著色組成物其能夠製造達成近年對於高對比度化、高色純度化及高輝度化之要求而且耐熱性、耐溶劑性等優異的彩色濾光片。因此，本發明之課題在於提供—種著色組成物，其能製造色度特性優異，對比度高且耐熱性、耐溶劑性良好的彩色濾光片。再者，本發明之課題在於提供—種^ 備由上述著色組成物形成之著色層而成的彩色濾、光片= 及具備該彩色遽光片的顯示元件。 -6- 201224065 [用以解決課題之方法】有‘於该實情’本案發明人等努力研究，结果發現 0曰由使用具有特定重複單位的共聚物能夠解決上述課通’並完成本發明。亦即’本發明提供一種彩色濾光片用著色組成物，八特徵為含有以下成分（A)、（Β)及（C): (A)含有顏料之著色劑； W共聚物(以下也稱為「⑻共聚物」），其含有以下 :式⑴表不之重複單位⑴、Μ下述式⑺表示之重複單 Γ (2)及具有父聯性官能基之重複單位（3),且前述重複 —位（2) Π合比例為不含前述重複單位⑴及前述重硬單位（3)之全部重複單位中的9Qf量％以上； (C)交聯劑； R1| 十 (1) X1201224065 VI. Description of the invention: [Technology of the jaw region of the invention] This is a coloring composition for a color filter, a color filter, a display element, and a pigment dispersion for a color filter, more specifically, The color filter used in the color-type liquid crystal display of the transmissive or reflective type: the color filter used for the material, the organic EL display element, the electronic paper, etc., is a colored composition for forming a useful color layer, and is used. The coloring layer formed by the coloring composition is a coloring layer, a stone, a J-bar, a chip, and a display element having the color filter. [Prior Art] When a color filter is produced using a coloring sensitizing radiation composition, a method is known in which a pigment-dispersed color-sensitive radiation composition is coated on a substrate and dried, and the dried coating film is in a desired pattern shape. The radiation (9) is called "exposure". And _, to obtain the pixels of each color (Patent Document 2). Further, a method of forming a black matrix by using a photopolymerizable composition obtained by dispersing carbon black is known (Patent Document 3). Further, a method of using a pigment-dispersion-type colored thermosetting resin composition by using an ink-jet method 彳彳# ‘ '土土U-transmitting color 昼素 is also known (Patent Document 4). The color filter used for the image sensor is required for high contrast and is used. In order to achieve such a micronization, it is known that a dispersant is used to improve the dispersibility of a pigment, and the developability and the like are also improved. In the field of a liquid crystal display element or a solid sheet, a pigment having a high luminance or a pigment is present. The more and more micronized pigments tend to be stable and have good dispersibility. A method for improving the contrast or dispersion stability using the dispersant has been proposed (Patent Documents 5 to 6). -5 - 201224065 PRIOR ART DOCUMENT Patent Document Patent Document 1 Japanese Patent Document 2 Japanese Patent Literature 3 Japanese Patent Literature 4 Japanese Patent Literature 5 Japanese Patent Literature 6 曰本特 [Abstract] Kaiping 2-144502公告 Kaikai No. 3-53201, Kaiping 6-3, 5 1 88, Kaikai, 2000-3, 10, 706, and the opening of the Japanese Patent Publication No. 2009-258 No. 3, Publication No. 2010-13441 No. 9 (Summary of the Invention) [Problems to be Solved by the Invention] However, according to the methods described in Patent Documents 5 to 6, it is difficult to achieve high contrast, high color purity, and high luminance in color liquid crystal display devices in recent years, and it is difficult to solve the problem of mass production of color filters. Various problems such as heat resistance and solvent resistance. Therefore, there is a strong demand for the development of a coloring composition which is capable of achieving high contrast, high color purity, and high luminance in recent years, and is excellent in heat resistance and solvent resistance. Accordingly, an object of the present invention is to provide a coloring composition which can produce a color filter which is excellent in chromaticity characteristics, has high contrast, and is excellent in heat resistance and solvent resistance. Further, an object of the present invention is to provide a color filter, a light sheet, and a display element including the colored light-emitting sheet, which are prepared from the coloring layer formed of the coloring composition. -6- 201224065 [Method for Solving the Problem] The inventors of the present invention conducted an effort to study the results of the present invention. As a result, it has been found that the use of a copolymer having a specific repeating unit can solve the above-mentioned teachings and complete the present invention. That is, the present invention provides a coloring composition for a color filter, which is characterized by containing the following components (A), (Β), and (C): (A) a pigment-containing coloring agent; W copolymer (hereinafter also referred to as The "(8) copolymer") contains the following repeating unit (1) represented by the formula (1), a repeating unit (2) represented by the following formula (7), and a repeating unit (3) having a parental functional group, and the foregoing The repeat-position (2) blending ratio is not more than 9Qf% of all repeating units of the above repeating unit (1) and the aforementioned heavy hard unit (3); (C) Crosslinking agent; R1| 十(1) X1

ZZ

[1 (1)中’ R1代表氫原子或甲I，z代表 :NRRRY.(其中」R2〜R4彼此獨立而代表氯原子、或也 :具1取代6基之烴基’ Y代表相對陰離子卜-nW(其中’R及R彼此獨立而代表氫原子、或也可具有取代基之煙基）、或也可具有取代基之含氮雜環基，Χι代表2 價之連結基。][1 (1) wherein 'R1 represents a hydrogen atom or a group I, z represents: NRRRY. (wherein "R2 to R4 are independent of each other and represent a chlorine atom, or also: a hydrocarbon group having a 1 substituted 6 group" Y represents a relative anion - nW (wherein 'R and R are each independently represent a hydrogen atom or a nicotyl group which may have a substituent), or a nitrogen-containing heterocyclic group which may have a substituent, and Χι represents a divalent linking group.]

201224065 一[式⑺中，R7代表氫原子或甲基，…代表飽和族煙基或飽和脂環式煙基。] 又，本發明提供具備使用該著色組成物而形成之著色層而成的彩色濾光片、及具備該彩色濾光片的顯示元件。再者，本發明提供一種彩色濾光片用顏料分散液，其特徵為含有：上述（A)含有顏料之著色劑、上述（B)共聚物及（F)溶劑。在此，「著色層」係指彩色濾光片使用之各色畫素、黑色矩陣、.黑色間隔物等。 [發明之效果] 若使用本發明之著色組成物，可獲得色度特性優異、對比度高，且具良好的耐熱性與耐溶劑性之各色畫素之彩色濾光片。因此’本發明之彩色濾光片用著色組成物，係極適於使用在以彩色液晶顯示元件用彩色濾光片、固體攝像凡件之色分解用彩色濾光片、有機EL顯示元件用彩色濾光片、電子紙用彩色濾光片為首之各種彩色濾光片的製作。【實施方式】 [用以實施發明之形態] 以下對於本發明詳細説明。彩色濾光片用著色组成物以下對於本發明之彩色濾光片用著色組成物（以下 I稱為「著色組成物」）之構成成分加以説明。 -8 · 201224065 -(A)著色劑- 本叙明之著色組成 ^ Kl| - 含有顏料當做（A)著色劑。顏枓不特別限疋，可為有 m 明中，顏料可單獨使用，或將2種以上混合使用。=發也可將有機顏料與無機顏料混合使用。 … 就上述有機顏料而言，例如於彩色指數（C l 了“ Society of Dyers and Colourists 公司發行）分類為顏料之化合物。具體而言，例如命名為如下述彩色指數（C I ) 者0 C.I.顏料黃12、C.I.顏料黃13、C.I.顏料黃14、Cl 顏料黃17、C.I.顏料黃20、C.I.顏料黃24、C.I·顏料黃 31、C_I·顏料黃55、C.I.顏料黃83、C.I.顏料黃93、Cl 顏料黃109、C.I.顏料黃11〇、C.I，顏料黃138、c.I.顏料買139、C.I.顏料黃150、C.I·顏料黃153、C.I.顏料黃154、 C.I.顏料黃155、C.I.顏料黃166、C.I.顏料黃168、CJ 顏料黃1 8 0、C · I.顏料黃211 ; C. I ·顏料橙5、C · I.顏料橙1 3、C. I.顏料橙14、C I 顏料橙24、C.I·顏料橙34、C.I·顏料橙36、C.I.顏料检 38、C.I.顏料橙40、C_I.顏料撥43、C.I.顏料橙46、Cl 顏料橙49、C.I.顏料橙61、C.I.顏料橙64、C.I·顏料检 68、C.I.顏料橙70、（:丄顏料橙71、C.I_顏料橙72、C I 顏料橙73、C.I.顏料橙74 ;201224065 [In the formula (7), R7 represents a hydrogen atom or a methyl group, ... represents a saturated group or a saturated alicyclic group. Further, the present invention provides a color filter including a coloring layer formed using the colored composition, and a display element including the color filter. Furthermore, the present invention provides a pigment dispersion liquid for a color filter, comprising: (A) a pigment-containing coloring agent, the (B) copolymer, and (F) a solvent. Here, the "colored layer" refers to each color pixel used in the color filter, a black matrix, a black spacer, and the like. [Effects of the Invention] When the coloring composition of the present invention is used, a color filter having excellent chromaticity characteristics, high contrast, and excellent heat resistance and solvent resistance can be obtained. Therefore, the coloring composition for a color filter of the present invention is extremely suitable for use in color filters for color liquid crystal display elements, color filters for color separation of solid-state imaging devices, and color for organic EL display elements. The production of various color filters, including filters and electronic paper color filters. [Embodiment] [Mode for Carrying Out the Invention] Hereinafter, the present invention will be described in detail. Coloring composition for color filter The constituent components of the coloring composition for color filters (hereinafter referred to as "coloring composition") of the present invention will be described below. -8 · 201224065 - (A) Colorant - The color composition of this description ^ Kl| - Contains pigment as (A) colorant. The pigment is not particularly limited, and the pigment may be used alone or in combination of two or more. = Hair can also be used in combination with inorganic pigments. In the case of the above organic pigments, for example, a color index (C l "The Society of Dyers and Colourists") is classified as a compound of a pigment. Specifically, for example, it is named as a color index (CI) as follows: 0 CI Pigment Yellow 12. CI Pigment Yellow 13, CI Pigment Yellow 14, Cl Pigment Yellow 17, CI Pigment Yellow 20, CI Pigment Yellow 24, CI·Pig Yellow 31, C_I·Pig Yellow 55, CI Pigment Yellow 83, CI Pigment Yellow 93, Cl Pigment Yellow 109, CI Pigment Yellow 11〇, CI, Pigment Yellow 138, cI Pigment Buy 139, CI Pigment Yellow 150, CI·Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment Yellow 166, CI Pigment Yellow 168, CJ Pigment Yellow 1 800, C · I. Pigment Yellow 211; C. I · Pigment Orange 5, C · I. Pigment Orange 1 3, CI Pigment Orange 14, CI Pigment Orange 24, CI·Pig Orange 34, CI·Pigment Orange 36, CI Pigment Check 38, CI Pigment Orange 40, C_I. Pigment Dial 43, CI Pigment Orange 46, Cl Pigment Orange 49, CI Pigment Orange 61, CI Pigment Orange 64, CI·Pigment Check 68, CI Pigment Orange 70, (: 丄 Pigment Orange 71, C.I_Pigment Orange 72, CI Pigment Orange 73, CI Pigment Orange 74;

C.I.顏料紅1、C.I.顏料紅2、C.I.顏料紅5、C.I.顏料紅17、C.I.顏料紅3卜C.I.顏料紅32、C.I.顏料紅41、 C.I.顏料紅122、C.I.顏料紅123、C.I.顏料紅144、CI -9- 201224065 顏料紅149、C.I.顏料紅166、C.I.顏料紅168、C.I.顏料紅1 7 0、C · I.顏料紅1 7 l、C. I.顏料紅1 7 5、C. I ·顏料紅1 7 6、 C.I.顏料紅 177、C.I·顏料紅 178、C.I.顏料紅 179、C.I. 顏料紅180、C.I.顏料紅185、C.I.顏料紅187、C.I.顏料紅202、C.I.顏料紅206、C.I.顏料紅207、C.I.顏料紅209、 C.I.顏料紅 214、C.I.顏料紅 220、C.I.顏料紅 221、C.I. 顏料紅224、C.I.顏料紅242、C.I.顏料紅243、C.I·顏料紅 254、（：.1.顏料紅 25 5、（：.1.顏料紅 262、（：.1.顏料紅 264、 C.I·顏料紅272 ; C.I.顏料紫1、C.I.顏料紫19、C.I.顏料紫23、C.I. 顏料紫29、C.I·顏料紫32、C.I·顏料紫36、C.I.顏料紫 38 ； C.I.顏料藍1、C.I.顏料藍15、C.I.顏料藍15:3、 C.I.顏料藍15 : 4、C.I.顏料藍15 : 6、C.I.顏料藍60、 C.I.顏料藍80 ; C.I.顏料綠7、C.I.顏料綠36、C.I.顏料綠58 ; C.I.顏料棕23、C.I.顏料棕25 ; C.I.顏料黑1、C.I.顏料黑7。又，無機顏料例如：氧化鈦、硫酸鋇、碳酸鈣、鋅華、硫酸鉛、黃色鉛、鋅黃、鐵丹（紅色氧化鐵（III))、鎘紅、群青、紺青、氧化鉻綠、鈷綠、赭土、鈦黑、合成鐵黑、碳黑等。本發明中，可將顏料利用再結晶法、再沉澱法、溶劑洗滌法、昇華法、真空加熱法或該等之組合精製並使用。又，顏料視所望可將其粒子表面以樹脂改質並使用。 -10- 201224065 將顏料之粒子表面改 2〇〇1-1〇8817號公報記之樹脂，例如，日本特開或市售的各種顏料分散:載/基樹脂（vehicle resin)、方法而言，例如可採用曰t脂。就碳黑表面之樹脂被覆本特開平9-95625號公郝本特開平9·7 1 733號公報、日等記載之方法。又，有^日本特開平9-124969號公報 ^ ^ ^ ^ ^ 機，1料較佳為利用所謂的鹽磨將 ==化後使用。就鹽磨之方法而言，例如可採用曰本特開平08-1791 1 1號公報揭示之方法。而’彩色濾光片用著色組成物中，藉由使用染料當做著色劑，可達到顏料單獨無法達成的高輝度化或高對比度化。但是，若使用染料當做著色劑，冑時著色層之耐熱性或耐溶劑性會顯著惡化（參照比較例6)。相對於此，本發明之著色組成物中，藉由使用（B)共聚物當做顏料分散劑’比起組合顏料與染料當做著色劑之情形，可獲得能形成耐熱性耐溶劑性良好之著色層的著色組成物 (參照實施例10及11)。染料例如命名為如下述彩色指數（C.I.)之化合物。 C.I.酸性黃11、c.l酸性橙7、C.I,酸性紅37、c.I. 酸性紅180、C.I.酸性藍29、C.I.直接紅μ、c.i.直接紅 83、C.I.直接黃12、C.I.直接镫26、C·〗直接綠28、c.I. 直接綠5 9、C. I ·反應黃2、c.1 ·反應紅1 7、c. I,反應紅12 0、 C.I.反應黑5、C.I.分散禮 5 C.I.刀散紅58、C.I·分散藍 165、C.I.鹼性藍 41、C.I·鹼性紅 18、C.I.媒染紅 7、C.I· 媒染黃5、C _ I.媒染黑7等之偶氮系染料； 201224065 C.I.還原藍4、C.I.睃性藍4〇、c.I.酸性綠25 ' C j 反應藍19、C.I.反應藍49、c.i.分散紅60、C.I.分散藍 5 6、C. I.分散藍6 0等之蒽g昆系染料； — C · I.還原藍5等之敝花青系染料； C.I.臉性藍3、C.I.驗性藍9等之.酿亞胺系染料·， C.I.溶劑黃33、C.I.酸性黃3、c.I.分散黃64等之喹啉系染料； C.I.酸性黃1、C.I.酸性橙3、c·〗·分散黃42等之硝基系染料； C.I·分散黃20卜CJ•溶劑黃179等之次甲基系染料。本發明中，使用染料當做著色劑時，染料可單獨使用，或混合2種以上使用。 (A)著色劑之含有比例，從形成輝度高、色純度優異之畫素、或遮光性優異之黑色矩陣的觀點，通常在著色組成物之固體成分中為5〜7〇質量％，較佳為5〜6〇質量 %。在此’固體成分’係指後述溶劑以外之成分。 -(B)共聚物- 本發明中，（B)共聚物，係具有重複單位（1)、重複單位（2)及重複單位（3)，且重複單位（2)之共聚合比例為不含重複單位（1)及重複單位（3)之全部重複單位中之9〇質量％以上之共聚物，.當做顏料分散劑之功能。 ®複單位（1)係以上述式（1)表示者。上述式（1)中，Ri在氫原子及甲基當中，以甲基較佳。又’ Z代表-n + r2r3r4y-、-NR5R6或也可具有取代基之含氣雜環基，R2〜R6彼此獨立而代表氫原子、或也可 -12- 201224065 具有取代基之烴基，但本發明中，「烴基」係 =基、脂環式煙基及芳香族煙基之概念，可為；=族分支狀及環狀任-形態，且可為飽和烴基也^不飽和烴基，也可在分子内及末端任一者具有不飽和鍵。就上述脂肪族烴基而言，以碳數1〜20(較佳為之烷基較佳。具體而言，例如：甲基、乙基、丙基、丁基等。又，就上述脂環式烴而言，以碳數3~20(較佳為3〜12) 之脂環式烴基較佳，碳數3〜20(較佳為3〜12)之環烷基更佳。具體而言，例如環丙基、環丁基、環戊基、環己基等。再者，就上述芳香族烴基而言，以碳數6〜2〇(較佳為 6〜1〇)之芳香族烴基較佳，碳數6〜2〇(較佳為6~1〇)之芳基、碳數7〜20(較佳為碳數7〜16)之芳烷基更佳。在此，本發明中’「芳基」係指單環〜3環芳香族烴基，例如，苯基、萘基、聯苯基' 蒽基等。就芳烷基之具體例而言，例如苄基、苯乙基、心甲基苄基、2_苯基丙烷_2_基等。其中，就R2〜R6中的烴基而言，以碳數1M2(又更佳為1〜6)之烷基、碳數7〜16(又更佳為7〜12)之芳烷基較佳，甲基、乙基、丙基、丁基、苄基尤佳。又，就R2〜R6中的取代基而言，例如，碳數卜6之烷基、画素原子、羥基、取代或非取代之胺基、硝基、氰基、致基、碳數1〜6之院氧基。就Y-而言，例如cr、Br-、Ϊ•等之齒素離子，cl〇4·、 BFV、CH3COO·、PF6-等之酸之相對陰離子。又，本發明巾，「含氮雜環基J係、指環之構成要素具有至少1個氮原子的雜環基，較佳為料環基、或該等 -13- 201224065 環基可為不飽和環也子以外之雜原子（例 2個縮合成的縮合雜環基。該等雜可為飽和環，也可於環内具有氮厚如，氧原子、硫原子）。 D比啶環、咪唑環、噻唑、四氫嘧啶環等。又，娘咬環、σ底听環等。言，例如，碳數卜6之喊基、羥基、胺基、醯就不飽和雜環而言，例如，環、噚唑環、***環、咪唑啉環就飽和雜環而言，例如，咪啉環又’就含氮雜環基中的取代基而烧基、鹵素原子、羧基、酯基、胺基、疏醇基、硫醚基等。上述雜單環基以5〜7員環較佳，具體而！，例如具乂下述式（1])或（1_2)表示之基本骨架的基團該等雜皁環基也可具有取代基。CI Pigment Red 1, CI Pigment Red 2, CI Pigment Red 5, CI Pigment Red 17, CI Pigment Red 3 Bu CI Pigment Red 32, CI Pigment Red 41, CI Pigment Red 122, CI Pigment Red 123, CI Pigment Red 144, CI -9- 201224065 Pigment Red 149, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 1.7, C · I. Pigment Red 1 7 l, CI Pigment Red 1 7 5, C. I · Pigment Red 1 7 6. CI Pigment Red 177, CI·Pigment Red 178, CI Pigment Red 179, CI Pigment Red 180, CI Pigment Red 185, CI Pigment Red 187, CI Pigment Red 202, CI Pigment Red 206, CI Pigment Red 207, CI Pigment Red 209, CI Pigment Red 214, CI Pigment Red 220, CI Pigment Red 221, CI Pigment Red 224, CI Pigment Red 242, CI Pigment Red 243, CI·Pigment Red 254, (:.1. Pigment Red 25 5, (:.1. Pigment Red 262, (:.1. Pigment Red 264, CI·Pigment Red 272; CI Pigment Violet 1, CI Pigment Violet 19, CI Pigment Violet 23, CI Pigment Violet 29, CI·Pigment Violet 32, CI·Pigment Violet 36, CI Pigment Violet 38; CI Pigment Blue 1, CI Pigment Blue 15, CI Pigment Blue 15:3, CI Pigment Blue 15: 4, CI Pigment Blue 15 : 6, CI Pigment Blue 60, CI Pigment Blue 80; CI Pigment Green 7, CI Pigment Green 36, CI Pigment Green 58; CI Pigment Brown 23, CI Pigment Brown 25; CI Pigment Black 1, CI Pigment Black 7. Inorganic pigments such as: titanium oxide, barium sulfate, calcium carbonate, zinc oxide, lead sulfate, yellow lead, zinc yellow, iron oxide (red iron oxide (III)), cadmium red, ultramarine blue, indigo, chrome oxide green, cobalt green , alumina, titanium black, synthetic iron black, carbon black, etc. In the present invention, the pigment may be purified and used by a recrystallization method, a reprecipitation method, a solvent washing method, a sublimation method, a vacuum heating method, or the like. Further, the pigment can be modified and used as a resin as desired. -10- 201224065 The surface of the pigment particle is changed to a resin described in Japanese Unexamined Patent Publication No. Hei No. Hei No. 8817, for example, Japanese Patent or Commercial Various pigment dispersions: for the vehicle resin, the method, for example, 曰t grease can be used. The resin coating on the surface of the carbon black is disclosed in Japanese Patent Publication No. 9-95625, and the public bulletin of Kaiping No. 9·7 1 733 , Japanese, etc., and there is a Japanese Gazette No. 9-124969. ^ ^ ^ ^ Machine, 1 material is preferably used after the use of the so-called salt mill ==. For the method of salt milling, for example, the method disclosed in Japanese Patent Publication No. 08-1791 1 1 can be used. On the other hand, in the coloring composition for a color filter, by using a dye as a coloring agent, high luminance or high contrast which cannot be achieved by the pigment alone can be achieved. However, when a dye is used as a coloring agent, the heat resistance or solvent resistance of the colored layer is remarkably deteriorated (refer to Comparative Example 6). On the other hand, in the coloring composition of the present invention, by using the (B) copolymer as a pigment dispersing agent, a coloring layer capable of forming a heat-resistant and solvent-resistant property can be obtained as compared with a case where a combination of a pigment and a dye is used as a coloring agent. The colored composition (see Examples 10 and 11). The dye is, for example, designated as a compound of the following color index (C.I.). CI Acid Yellow 11, Cl Acid Orange 7, CI, Acid Red 37, cI Acid Red 180, CI Acid Blue 29, CI Direct Red μ, Ci Direct Red 83, CI Direct Yellow 12, CI Direct 镫26, C·〗 Direct Green 28, cI direct green 5 9, C. I · reaction yellow 2, c.1 · reaction red 1 7, c. I, reaction red 12 0, CI reaction black 5, CI dispersion ceremony 5 CI knife loose red 58, CI·Disperse blue 165, CI alkaline blue 41, CI·basic red 18, CI mordant red 7, CI· mordant yellow 5, C _ I. azo dye 7 such as mordant black 7; 201224065 CI reduction blue 4 CI睃 blue 4〇, cI acid green 25 'C j reaction blue 19, CI reaction blue 49, ci disperse red 60, CI disperse blue 5 6 , CI disperse blue 6 0, etc. 昆 g Kun dye; — C · I. Reduction of cyanine dyes such as blue 5; CI face blue 3, CI blue test 9, etc. Brewing imine dyes, CI Solvent Yellow 33, CI Acid Yellow 3, cI Disperse Yellow 64, etc. Quinoline dyes; CI acid yellow 1, CI acid orange 3, c · · Disperse yellow 42 and other nitro dyes; CI · Disperse yellow 20 Bu CJ • Solvent yellow 179 and other minor methyl dyes. In the present invention, when a dye is used as the coloring agent, the dye may be used singly or in combination of two or more. (A) The content ratio of the coloring agent is usually from 5 to 7 % by mass, more preferably from 5 to 7 % by mass in the solid content of the coloring composition, from the viewpoint of forming a pixel having high luminance, excellent color purity, or a black matrix having excellent light blocking properties. It is 5 to 6 〇 mass%. Here, the 'solid content' means a component other than the solvent described later. - (B) Copolymer - In the present invention, the (B) copolymer has a repeating unit (1), a repeating unit (2), and a repeating unit (3), and the copolymerization ratio of the repeating unit (2) is not included. A copolymer of 9 〇 mass% or more of all the repeating units of the unit (1) and the repeating unit (3), which functions as a pigment dispersing agent. The compound unit (1) is represented by the above formula (1). In the above formula (1), Ri is preferably a methyl group among a hydrogen atom and a methyl group. Further, 'Z represents -n + r2r3r4y-, -NR5R6 or a gas-containing heterocyclic group which may have a substituent, and R2 to R6 are independently of each other and represent a hydrogen atom, or may be a hydrocarbon group having a substituent of -12-201224065, but In the invention, the concept of "hydrocarbon group" = base, alicyclic nicotyl and aromatic nicotyl can be; = group branch and cyclic any form, and may be a saturated hydrocarbon group or an unsaturated hydrocarbon group, or Any one of the intramolecular and the terminal has an unsaturated bond. The aliphatic hydrocarbon group is preferably a carbon number of 1 to 20 (preferably an alkyl group. Specifically, for example, a methyl group, an ethyl group, a propyl group, a butyl group, etc.) The hydrocarbon is preferably an alicyclic hydrocarbon group having 3 to 20 carbon atoms (preferably 3 to 12) and a cycloalkyl group having 3 to 20 carbon atoms (preferably 3 to 12 carbon atoms). For example, a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, etc. Further, in the above aromatic hydrocarbon group, an aromatic hydrocarbon group having a carbon number of 6 to 2 Å (preferably 6 to 1 Å) is preferred. The aryl group having 6 to 2 Å (preferably 6 to 1 Å) carbon number and the aralkyl group having 7 to 20 carbon atoms (preferably having 7 to 16 carbon atoms) are more preferable. Here, in the present invention, "Aryl" means a monocyclic to 3-ring aromatic hydrocarbon group, for example, a phenyl group, a naphthyl group, a biphenyl 'fluorenyl group, etc. Specific examples of the aralkyl group, such as a benzyl group, a phenethyl group, and a nail base a benzyl group, a 2-phenylpropan-2-yl group, etc., wherein, in the case of the hydrocarbon group in R2 to R6, an alkyl group having a carbon number of 1 M 2 (more preferably 1 to 6) and a carbon number of 7 to 16 ( Further preferably, the aralkyl group of 7 to 12) is preferably methyl, ethyl, propyl, butyl or benzyl. Further, R2~ The substituent in R6 is, for example, an alkyl group having a carbon number of 6, a pixel atom, a hydroxyl group, a substituted or unsubstituted amino group, a nitro group, a cyano group, a group, and a oxy group having 1 to 6 carbon atoms. In the case of Y-, for example, dentate ions such as cr, Br-, Ϊ, etc., relative anions of acids such as cl〇4·, BFV, CH3COO·, and PF6-. Further, the present invention has a nitrogen-containing heterocyclic ring. a heterocyclic group having at least one nitrogen atom in the constituents of the group J and the ring, preferably a ring group, or a hetero atom other than the unsaturated ring in the case of the-13-201224065 ring group (Example 2 a condensed heterocyclic group which may be a saturated ring or a nitrogen ring such as an oxygen atom or a sulfur atom in the ring. D is a pyridine ring, an imidazole ring, a thiazole, a tetrahydropyrimidine ring, etc. , a mother bite ring, a σ bottom ring, etc., for example, a carbon number, a hydroxyl group, an amine group, a hydrazine, an unsaturated heterocyclic ring, for example, a ring, a carbazole ring, a triazole ring, an imidazole The porphyrin ring is, for example, a saturated heterocyclic ring, for example, a morpholine ring and a substituent in the nitrogen-containing heterocyclic group, a halogen group, a halogen atom, a carboxyl group, an ester group, an amine group, and an alcohol group. a thioether group or the like. The above heteromonocyclic group is preferably a 5- to 7-membered ring, and specifically, for example, a group having a basic skeleton represented by the following formula (1) or (1_2); The group may also have a substituent.

RR

N+N+

(1-1) 式（1-1)中，R代表氫原子、或也可具有取代基之烴 &’「*」代表連接鍵’但R中的烴基例如與上述R2為同樣者。(1-1) In the formula (1-1), R represents a hydrogen atom or a hydrocarbon which may have a substituent. "*" represents a linkage bond', but the hydrocarbon group in R is, for example, the same as the above R2.

-14- 201224065 式（1-2)中’「*」代表連接鍵。又’就上述縮合雜環基而言，具體而言以下述式（1-3)〜（1-5)表示之基本骨架的基團雜環基也可具有取代基。-14- 201224065 In the formula (1-2), '*' stands for the connection key. Further, the above-mentioned condensed heterocyclic group, specifically, a group having a basic skeleton represented by the following formulas (1-3) to (1-5) may have a substituent.

例如具有該等縮合 (1-3) (1-4) (1-5) / 不」代衣運接鍵。上述式（1)中，就2價之連結基（Χ1)而言，例如，亞甲基、碳數2〜1〇(較佳為2〜6)之伸烷基、伸芳基、 ΟΝΗ-r _基、_c〇〇 Rl2•基等。在此，汉"及彼此立而為單鍵、亞甲基、碳數2〜1〇(較 2之 :、或碳數2〜10之醚基（伸烷基氧基伸烷基）。其中，χ1 X c〇0'R12-基較佳，r丨2以碳數2〜6之伸烷基較佳。重複單位（2)係以上述式（2)表示者。 -1 5- 201224065 上述式（2)中’就R7而言，在氫原子及曱基當中，以曱基較佳。 R中，就飽和脂肪族烴基而言，以碳數i〜丨5 (較佳為1〜12)之烷基較佳，以曱基、乙基、丙基、丁基、異丁基、第三丁基、2·乙基己基、異癸基、十二烷基尤佳。又，R中，就飽和脂環式烴基而言，例如環烷基、飽和縮合多環烴基、飽和橋接環烴基、飽和螺烴基、飽和環狀祐婦烴基等。其中，就r8而言，以碳數3〜2〇(較佳為4〜15)之飽和脂環式烴基較佳，以環己基、第三丁基環己基、十氫-2-萘基..參環[5 2.} 〇2,6]癸_8_基、金剛基、五環十五烷基、參環戊烯基、異莰基尤佳。重複单位（3)具有交聯性官能，但該交聯性官能基不特別限疋命j如’乙烯性不飽和基、環氧乙烷基、環氧丙烧基、四氫咬°“、四氫。比喃基、環硫基、（二硫)碳酸S日基專。該等交胸祕0 A炊士哥又聯性g旎基之中，從耐熱性、耐溶劑性婦性不飽和基、環氧Q基四風夫喃基較佳。又，從對比度之觀點四氫咬喃基較佳。衣乳丙说基就上述乙烯性不飽和之基、乙烯基氧基、（甲美)…Λ ’例如:稀丙等。又，就上述環y基）丙烯氧基、^基节基氧基衰氧乙烧基之具體例而基、2-甲基環氧内基、環氧丙氧基、3,4_^，^如：環氧丙 -甲基環氧丙烷丙烷-3-基甲氧就上述環氧丙烷基之具體例而言，例乳土 ;衣己基等， •3-基、3-乙基環氣丙烷·3_基、”基環患基、3-乙基核氧丙烷_3_基甲氧基等。又… ’就上述四氫吱 -16- 201224065 喃基之具體例而言，例如：四氫咬β南-2 -基、四氫吱喃-3 -基等。就重複單位（3)而言，例如以下述式（3)表示之重複單位。 R10For example, it has such condensation (1-3) (1-4) (1-5) / no" clothing transfer button. In the above formula (1), the divalent linking group (Χ1) is, for example, a methylene group, a carbon number of 2 to 1 Å (preferably 2 to 6) of an alkyl group, an aryl group, and an anthracene group. r _ base, _c〇〇Rl2• base, etc. Here, Han " and each other stand for a single bond, methylene, carbon number 2 to 1 〇 (more than 2:, or an ether number of 2 to 10 carbon atoms (alkylalkyloxyalkylene). Χ1 X c〇0'R12- group is preferred, and r丨2 is preferably an alkylene group having 2 to 6 carbon atoms. The repeating unit (2) is represented by the above formula (2). -1 5- 201224065 In the formula (2), in the case of R7, among the hydrogen atom and the fluorenyl group, a fluorenyl group is preferred. In the case of R, in the case of a saturated aliphatic hydrocarbon group, a carbon number i to 丨5 (preferably 1 to 12) The alkyl group is preferably a mercapto group, an ethyl group, a propyl group, a butyl group, an isobutyl group, a tert-butyl group, a 2-ethylhexyl group, an isodecyl group or a dodecyl group. In the case of a saturated alicyclic hydrocarbon group, for example, a cycloalkyl group, a saturated condensed polycyclic hydrocarbon group, a saturated bridged cyclic hydrocarbon group, a saturated spirohydrocarbyl group, a saturated cyclic hydrocarbon group, etc., wherein, in the case of r8, the carbon number is 3~ 2 〇 (preferably 4 to 15) of a saturated alicyclic hydrocarbon group is preferably a cyclohexyl group, a tert-butylcyclohexyl group, a decahydro-2-naphthyl group; a sulphide [5 2.} 〇 2,6癸_8_ group, adamantyl, pentacyclopentadecyl, cyclopentenyl, isodecyl is especially preferred. The repeating unit (3) has a crosslinkable function, but the crosslinkable functional group is not particularly limited to a life expectancy such as 'ethylenically unsaturated group, oxiranyl group, propylene oxide group, tetrahydrogen bite°, Tetrahydrogen. Compared with cyclyl, cyclothio, (dithio)carbonic acid, S. sylvestris. The same as the chestnut 0 A sergeant and the joint g thiol, from heat resistance, solvent resistance, not A saturated group or an epoxy group Q-based tetrafolyl group is preferred. Further, from the viewpoint of contrast, a tetrahydroanion group is preferred. The group of the above-mentioned ethylenically unsaturated group, vinyloxy group, (A) US)...Λ 'For example: dilute propyl, etc., in addition to the above ring y group) acryloxy, benzyl oxy oxyalkylene group, 2-methyl epoxide group, ring Oxypropoxy group, 3,4_^, ^ such as: propylene oxide-methyl propylene oxide propane-3-yl methoxy, in the specific example of the above propylene oxide group, for example, latex; hexyl group, etc. 3-Based, 3-ethylcyclopropane·3_yl, "base ring-affinity group, 3-ethyl nucleus oxypropane-3-yloxy group, etc. Further, 'specific examples of the tetrahydroanthracene-16-201224065 thiol group include a tetrahydronene β-n-2-yl group and a tetrahydrofuran-3-yl group. In the case of the repeating unit (3), for example, a repeating unit represented by the following formula (3). R10

A 式（3)中’ R10代表氫原子或曱基’ A代表交聯性官月&基’ X代表單鍵或2價之連結基。上述式（3)中’就R10而言’在氫原子及甲基當中以曱基較佳。 2價之連結基（X2)例如，-C0NH_R丨3_( * )基、 -COO-R14-( * )基、_c〇〇_Ri5_〇〇CNH Rl6_( * )基、 C6H4CH2-(* )基、_c,5H4CH2OR17-(* )基等。在此，R" 及R 彼此獨立而代表單鍵、亞曱基、也可具有羥基之碳數2〜10之烴基或碳數2〜1〇之醚基（伸烷基氧基伸烷基），R15及R16彼此獨立而代表亞甲基或碳數2〜1〇(較佳為2〜6)之伸烷基，R”代表也可具有羥基之碳數2〜丨〇之伸烷基，（* )代表與A鍵結之連接鍵。又，RU及rH 中’烴基例如與上述R2同樣者。其中，就X2而言，以-COO-Ri、基、 -co〇-r15-〇〇cnh-r16-基較佳。土 (B)共聚物也可具有上述以外之重複單位（以下稱為「重複單位（4)」）。就如此的重複單位（4)之例而言，例 201224065 如來自於苯乙烯、α-曱基苯乙烯等之苯乙烯系單體；（甲基）丙稀、馬來酸、馬來酸酐、琥ίό酸單[2-(甲基）丙稀醯氧乙自曰]、ω-羧基聚已内酯單（曱基）丙烯酸酯、具有對乙烯基苯曱酸、對羥基苯乙烯、對羥基-α-曱基苯乙烯等之酸性基之乙烯基系單體；（甲基）丙烯酸苯酯、（曱基）丙烯I苄®曰等之（甲基）丙烯酸芳基酯系單體；（曱基）丙烯醯氣等之（甲基）丙烯醯_化物系單體；（甲基）丙烯醯胺、 N-羥曱基丙烯醯胺等之（甲基）丙烯醯胺系單體；乙酸乙烯基；丙烯腈；N·甲基丙烯醯基咮啉等之單體之重複單位，以下述式（4)表示之重複單位。在此，本發明中，「（甲基）丙烯酸酯」係指「丙烯酸酯或甲基丙烯酸酯 R20In the formula (3), R10 represents a hydrogen atom or a fluorenyl group. A represents a crosslinkable sir. & base 'X represents a single bond or a divalent linking group. In the above formula (3), 'in terms of R10' is preferably a fluorenyl group among a hydrogen atom and a methyl group. The divalent linking group (X2) is, for example, -C0NH_R丨3_(*) group, -COO-R14-(*) group, _c〇〇_Ri5_〇〇CNH Rl6_(*) group, C6H4CH2-(*) group , _c, 5H4CH2OR17-(*), and the like. Here, R" and R are independent of each other and represent a single bond, an anthranylene group, a hydrocarbon group having a carbon number of 2 to 10 or a hydrocarbon group having 2 to 1 carbon atoms (alkylalkyloxyalkylene group). R15 and R16 are independently of each other and represent a methylene group or an alkylene group having a carbon number of 2 to 1 Torr (preferably 2 to 6), and R" represents an alkylene group having a carbon number of 2 to 羟基 having a hydroxyl group, ( *) represents a bond to the A bond. Further, the 'hydrocarbon group' in RU and rH is, for example, the same as R2 above. Among them, in the case of X2, -COO-Ri, base, -co〇-r15-〇〇cnh The -r16- group is preferred. The earth (B) copolymer may have a repeating unit other than the above (hereinafter referred to as "repeating unit (4)"). In the case of such a repeating unit (4), the example 201224065 is derived from a styrene monomer such as styrene or α-mercaptostyrene; (meth) acryl, maleic acid, maleic anhydride, Succinic acid mono [2-(methyl) propylene oxime oxime], ω-carboxypolycaprolactone mono(indenyl) acrylate, with p-vinylbenzoic acid, p-hydroxystyrene, p-hydroxyl a vinyl-based monomer having an acidic group such as α-mercaptostyrene; an aryl (meth)acrylate monomer such as phenyl (meth)acrylate or (indenyl) propylene Ibenzyl®; (meth)acryloyl hydrazine-based monomer such as (meth)acrylonitrile or the like; (meth)acrylamide-based monomer such as (meth)acrylamide or N-hydroxydecyl acrylamide; acetic acid A repeating unit of a monomer such as a vinyl group; acrylonitrile; N-methylpropenyl porphyrin, and the like, and a repeating unit represented by the following formula (4). Here, in the present invention, "(meth)acrylate" means "acrylate or methacrylate R20"

CH2--CCH2--C

(4) coo—(-R21〇i^-R22 式（4)中，R2〇代表氫原子或曱基，RZ1代表碳數2〜4 之伸烷基，R22代表碳數1〜6之烷基。 (B)共聚物中，重複單位（1)之共聚合比例，在全部重複單位中，較佳為5〜70質量％，更佳為1〇〜6〇質量％，又更佳為15〜40質量％。重複單位（2)之共聚合比例，為不含重複單位（1)及重複單位（3)的全部重複單位中的9〇質量％以上，較佳為95質量％以上，更佳為1〇〇質量0/〇。重複單位（3)之共聚合比例，在全部重複單位中，較佳為3〜80質量％，更佳為5〜7〇質量％，又更佳為1〇~6〇質里％。藉由使各重複單位以如此的比例共聚合，能使所望效果更高。 -18- 201224065 又，就（B)共聚物中的重複單位（丨）而言，當z含有 -n+r2r3r4y·重複單位且z含有_NR5R6重複單位兩者時，由能使對比度更高之觀點為較佳。於此情形，z為 -n+r2r3r4y·重複單位與z為_NR5R6重複單位之共聚合比（莫耳比），為20/80-99/1較佳，3〇/7〇〜98/2更佳， 40/60〜97/3 尤佳。 (B)共聚物只要是具有重複單位（1)、重複單位（2)及重複單位（3)即不特別限定，但從使分散性更高之觀點，為嵌段共聚物較佳，其包含：A嵌段，不具重複單位⑺ 及重複單位（3) ’具有重複單位⑴；及B嵌段，不具重複單位⑴，具重複單位(2)及重複單位(3)。該欲段共聚物為A-B嵌段共聚物或B_A_B嵌段共聚物較佳。於此情形， A嵌段/B嵌段之共聚合比（質量比）為5/95〜7〇/3〇較佳， 10/90〜60/40 更佳，15/85〜40/60 尤佳。、A嵌段中’重複單位⑴可在“固A嵌段中含有2種 :上’於此情形’各重複單位在該A嵌段中可以無規共 A合、嵌段共聚合任-態樣含有。本發明中，A嵌段較 2 3有z為_n+r2r3r4y^重複單位⑴與z為_nr5r6 之重複單位（1)兩者。另合任@ M Μ嵌段中，可以無規共聚合、喪段共聚 U二二二複單位（2)及重複單位（3)。⑻共聚物具有:Β心：Γ重二段共聚物’其 W嵌段，且有重^ „。（）且不具重複單位⑴;及複早位（3)且不具重複單位（2)。又，重早位（2)及重複單位（3)可在1個Β礙段中各含有2種以 -19- 201224065 上’於此情形’可A兮七讯丄 J在該Β嵌段中以無規共聚合、嵌段此聚合任一態樣含有各重複單位。 a B二段中也可含有重複單位及重複單位（3)以外之重複單位，就如此的重複單位而言，例如上述重複單位（4)。 (B)肷段共聚物之分子量，以凝膠滲透層析、洗提溶劑：DMF)測定之聚甲基丙烯酸甲醋換算之重量平均分子量（以下也稱為「Mw」），較佳為1，〇〇〇〜3〇,〇〇〇，尤佳為5,000〜15,〇〇〇。又，（B)嵌段共聚物之Mw與以 GPC(洗提溶劑：DMF)測定之聚甲基丙烯酸甲酯換算之數量平均分子量（以下稱為「Mn」）之比（Mw/Mn) ’較佳為 1.0〜1.8 ’更佳為m.7 ’又更佳為丨〇〜丨6，尤佳為 1.0〜1.5。藉由使（B)共聚物為如此的態樣，能獲得分散性及鹼顯影性優異的著色組成物。 (B)共聚物可利用習知之方法製造，但共聚物為嵌段共聚物時，例如可藉由將賦予上述各重複單位之單體進行活性聚合而製造。就活性聚合法而言，可採用日本特開平9-62002號公報；曰本特開2〇〇2_31713號公報；P. Lutz，P. Masson et al，Polym. Bull. 12，79 (1984); B. C. Anderson, G. D. Andrews et al, Macromolecules, 14, 1601(1981); K. Hatada, K. Ute, et al, Polym. J. 17, 977 (1 985); K. Hatada, K. Ute, et al, P〇lym. J. 18, 1037 (1986);右手浩一、畑田耕一，高分子加工、36,366(1987); 東村敏延、澤本光男’高分子論文集、46, 189(1989); Μ· Kuroki， T. Aida，J. Am. Chem. Soc，109, 4737(1987);相田卓三、井上祥平， -20- 201224065 有機合成化學，43,300(1 985); D. Y. Sogoh，W. R. Hertler et al, Macromolecules, 20, 1473(1 987); J. p〇lym. Sci. Part A Polym. Chem., 47, 3 7 7 3-3794(2009); J. P〇lym. Sci Part A Polym. Chem·, 47，3 544-3 5 5 7(2009)等記載之習知方法。為賦予重複單位（1)之單體且就式（1)中的z為 -N + R2R3R4Y_或-NR5R6之單體而言，例如’（甲基）丙烯醯胺基丙基三曱基氯化銨、（甲基）丙烯醯氧基乙基三曱基氯化銨、（曱基）丙烯醯氧基乙基三乙基氣化銨、（甲基）丙烯醯氧基乙基（4-苯曱醯基苄基）二甲基溴化銨、（曱基）丙烯醯氧基乙基节基二甲基氣化銨、（曱基）丙烯醯氧基乙基苄基二乙基氯化敍、（曱基）丙烯酸二曱胺基乙酯、（曱基）丙烯酸二乙胺基乙酯、（甲基）丙烯酸二甲胺基丙酯、 (甲基）丙烯酸二乙胺基丙酯等。又，Z為-N + R2R3R4Y_之重複單位（1)，例如，也可將Z為-NR5R6之單體（例如，（曱基）丙烯酸二甲胺基乙酯）共聚合後，使該共聚物與氯曱苯等之_素化烴化合物反應，將胺基4級化而獲得。又，為提供重複罝位（1)之單體且就式（1)中之Z為含氮雜環基之單體而言，例如，下述式之化合物群α(單體 1〜18) '以下述式（5)表示之化合物等。又，提供重複單位 (1)之單體，可單獨使用，也可將2種以上混合使用。 -2 1- 201224065 〔化合物群 Cllg—r CHf=CH i!>-(CH;： to 0 ccw^-jj^p(單體·1) · (單體.2)(4) coo—(-R21〇i^-R22 In the formula (4), R2〇 represents a hydrogen atom or a fluorenyl group, RZ1 represents an alkylene group having a carbon number of 2 to 4, and R22 represents an alkyl group having 1 to 6 carbon atoms. (B) The copolymerization ratio of the repeating unit (1) in the copolymer is preferably from 5 to 70% by mass, more preferably from 1 to 6 % by mass, still more preferably from 15 to 70% by mass in all the repeating units. 40% by mass. The copolymerization ratio of the repeating unit (2) is 9% by mass or more, preferably 95% by mass or more, more preferably 95% by mass or more, based on the total repeating unit (1) and the repeating unit (3). The mass ratio of the repeating unit (3) is preferably from 3 to 80% by mass, more preferably from 5 to 7% by mass, even more preferably 1%. ~6% in enamel. By allowing each repeating unit to be copolymerized in such a ratio, the desired effect can be made higher. -18- 201224065 Further, in the case of (B) the repeating unit (丨) in the copolymer, when When z contains -n+r2r3r4y· repeating unit and z contains both _NR5R6 repeating units, it is preferable to make the contrast higher. In this case, z is -n+r2r3r4y·the repeating unit and z are _NR5R The copolymerization ratio (molar ratio) of 6 repeating units is preferably 20/80-99/1, more preferably 3〇/7〇~98/2, and particularly preferably 40/60~97/3. (B) Copolymerization The material is not particularly limited as long as it has a repeating unit (1), a repeating unit (2), and a repeating unit (3), but is preferably a block copolymer from the viewpoint of higher dispersibility, and includes: A block. , without repeating unit (7) and repeating unit (3) 'having repeating unit (1); and B block, without repeating unit (1), having repeating unit (2) and repeating unit (3). The copolymer of the desired segment is AB block copolymerization The material or the B_A_B block copolymer is preferred. In this case, the copolymerization ratio (mass ratio) of the A block/B block is preferably 5/95 to 7 Å/3 Torr, and more preferably 10/90 to 60/40. Preferably, 15/85~40/60 is particularly good. In the A block, the 'repeating unit (1) can be contained in the "solid A block: two": in this case, each repeating unit can be absent in the A block. In the present invention, the A block has a ratio of _n+r2r3r4y^ repeating unit (1) and z is a repeating unit (1) of _nr5r6. In addition to the @ M Μ block, it can be randomly copolymerized, The segment copolymer U 2 22 complex unit (2) and the repeat unit (3). (8) The copolymer has: Β: Γ heavy two-stage copolymer 'its W block, and has a weight „. () and no repeating unit (1); and early morning position (3) and no repeat unit (2). Also, the early morning position (2) and the repeat unit (3) may contain 2 types in each of the obstacle sections to -19-201224065. In this case, 'A" can be randomly copolymerized in the hydrazine block, and each of the repeating units is contained in any of the blocks. The repeating unit and the repeating unit other than the repeating unit (3) may be included in the second section of a B. For such a repeating unit, for example, the above repeating unit (4). (B) The molecular weight of the oxime copolymer, which is a weight average molecular weight (hereinafter also referred to as "Mw"), preferably 1 in terms of polymethyl methacrylate, measured by gel permeation chromatography and elution solvent: DMF. , 〇〇〇~3〇, 〇〇〇, especially good for 5,000~15, 〇〇〇. Further, the ratio (Mw/Mn) of the number average molecular weight (hereinafter referred to as "Mn") of the Mw of the (B) block copolymer to the polymethyl methacrylate measured by GPC (eluent solvent: DMF) It is preferably 1.0 to 1.8 'better than m.7' and more preferably 丨〇~丨6, especially preferably 1.0 to 1.5. By setting the (B) copolymer in such a manner, a coloring composition excellent in dispersibility and alkali developability can be obtained. (B) The copolymer can be produced by a conventional method. However, when the copolymer is a block copolymer, it can be produced, for example, by living-polymerizing a monomer which is given to each of the above repeating units. In the case of the living polymerization method, Japanese Patent Laid-Open Publication No. Hei 9-62002; Japanese Patent Laid-Open Publication No. Hei 2 No. Hei 2_31713; P. Lutz, P. Masson et al, Polym. Bull. 12, 79 (1984); BC Anderson, GD Andrews et al, Macromolecules, 14, 1601 (1981); K. Hatada, K. Ute, et al, Polym. J. 17, 977 (1 985); K. Hatada, K. Ute, et al , P〇lym. J. 18, 1037 (1986); Right Hand Hao Yi, Putian Gengyi, Polymer Processing, 36, 366 (1987); Dong Cun Min Yan, Ze Benguang Men's Polymer Proceedings, 46, 189 (1989); Kuroki, T. Aida, J. Am. Chem. Soc, 109, 4737 (1987); Xiangtian Zhuo San, Inoue Xiangping, -20- 201224065 Organic Synthetic Chemistry, 43,300 (1 985); DY Sogoh, WR Hertler et al, Macromolecules , 20, 1473 (1 987); J. p〇lym. Sci. Part A Polym. Chem., 47, 3 7 7 3-3794 (2009); J. P〇lym. Sci Part A Polym. Chem·, 47,3 544-3 5 5 7 (2009) and other known methods. To give a monomer of the repeating unit (1) and for the monomer in the formula (1) wherein z is -N + R2R3R4Y_ or -NR5R6, for example, '(meth) acrylamidopropyltridecyl chloride Ammonium, (meth) propylene methoxyethyl triammonium chloride, (mercapto) propylene methoxyethyl triethylammonium hydride, (meth) propylene oxiranyl ethyl group (4- Phenylbenzyl benzyl) dimethyl ammonium bromide, (fluorenyl) propylene oxiranyl ethyl benzyl dimethyl ammonium hydride, (fluorenyl) propylene methoxyethyl benzyl diethyl chlorination曱, (fluorenyl) diamylaminoethyl acrylate, diethylaminoethyl (meth) acrylate, dimethylaminopropyl (meth) acrylate, diethylaminopropyl (meth) acrylate, etc. . Further, Z is a repeating unit (1) of -N + R2R3R4Y_. For example, a copolymer in which Z is -NR5R6 (for example, dimethylaminoethyl (meth) acrylate) may be copolymerized to copolymerize the copolymer. The product is obtained by reacting with a sulfonated hydrocarbon compound such as chlorinated benzene to form an amine group. Further, in order to provide a monomer which repeats the monomer of (1) and wherein Z in the formula (1) is a nitrogen-containing heterocyclic group, for example, a compound group α of the following formula (monomers 1 to 18) 'A compound represented by the following formula (5). Further, the monomer of the repeating unit (1) may be used alone or in combination of two or more. -2 1- 201224065 [Compound group Cllg-r CHf=CH i!>-(CH;: to 0 ccw^-jj^p (monomer·1) · (monomer.2)

CHg-CH C^O <C4e]a-j|' (單體.3)CHg-CH C^O <C4e]a-j|' (monomer.3)

'9Hj chf-c Π (單體-5) -O—tWaJy (單體-6)'9Hj chf-c Π (monomer-5) -O-tWaJy (monomer-6)

?HS CHs=?<J>0 O-ICH CHf=CH 0-0 O-iCH^a-(單體_S)?HS CHs=?<J>0 O-ICH CHf=CH 0-0 O-iCH^a-(monomer_S)

CHi=CH :〇 (單體-11) CHf-QH o~o HN {CH^Y^i 乂 yN(單體-9) CHg=ipH D-O (單體-12) (單體-7) CH, CH*=Cp=o (阜體-10) 0*0 O-tCHe), (單體-13)CHi=CH :〇(monomer-11) CHf-QH o~o HN {CH^Y^i 乂yN(monomer-9) CHg=ipH DO (monomer-12) (monomer-7) CH, CH*=Cp=o (阜-10) 0*0 O-tCHe), (Monomer-13)

Η (單體-15) (單體-16)Η (monomer-15) (monomer-16)

-22 201224065 又，就提供重複單位（2)之單體而言，例如，（甲基）丙稀酸甲酿、（甲基）丙稀酸乙醋、（甲基）丙稀酸丙醋、（甲基）t丙烯酸異丙酯、（甲基）丙烯酸丁酯、（曱基）丙烯酸異丁知、（甲基）丙烯酸第三丁酯、（曱基）丙烯酸2_乙基己曰（甲基）丙稀酸異癸酯、（甲基）丙烯酸十二酯、（曱基） 7烯酸環己酯、參環[5 2丨02,6]癸_8_基（曱基）丙烯酸曰（甲基）丙稀酸異莰酯、（甲基）丙稀酸金剛酯、（曱基）丙烯i文十氫-2-萘酯、（曱基）丙烯酸五環十五烷酯等◦該等可單獨使用，或混合2種以上使用。 ^提供重複單位（3)之單體’例如，（甲基）丙烯酸烯丙西曰（甲基）丙烯酸2-(2-乙烯氧基乙氧基）乙酯、（甲基）丙烯酸環氧丙酯、（甲基）丙烯酸2-甲基環氧丙酯、（甲基）丙烯馱4-環氧丙基氧基丁酯、（曱基）丙烯酸3，4-環氧基環己基曱酯、對乙烯基苄基環氧丙醚、3_(乙烯基氧基甲基）3乙基環氧丙烷、3_[(甲基）丙烯醯氧基曱基]環氧丙烷、3_[(曱基）丙烯醯氧基曱基]_3_乙基環氧丙烷、（曱基）丙稀ϊ夂四氫糠醋、（甲基）丙烯酸3_四氫糠酯、（甲基）丙稀 I 2 (四氫糠基氧基）乙酯等。該等可單獨使用，或將2 種以上混合使用。又乂也p性官能基為乙稀性不飽和鍵之重複單位 (3)除了將（甲基）丙稀酸稀丙酯、（曱基）丙稀酸2-(2-乙烯氧基乙氧基）乙酯等進行共聚合以外，也可利用各種方法導入。就該方法而言，例如將具有羧基之乙烯性不飽和單體（例如’（甲基）丙烯酸）共聚合後，使該共聚物與具有環氧乙烷基之乙烯性不飽和化合物（例如，（甲基）丙 -23- 201224065 烯酸環氡丙酯）反魔夕士 ’法、將具有環氣乙烷基之乙烯性不飽和皁體共聚合後，使該共聚物與具有羧基之乙烯性不飽和化合物反鹿$ ^ OD ，·力法、將具有羥基之乙烯性不飽和早體（例如，（甲基）丙植.缺、臂物呈右里"Λ 烯·文2'羥基乙酯）共聚合後，使該共 ▲- 鼠酉欠酉曰基之乙烯性不飽和化合物"列如，異氰 u(甲基)丙稀醢氧基乙龍)反應之方法等。又’^提供重複單位（4)之單體，例如，苯乙烯、心甲基本乙你、（曱基彳$ 0〇 ro _ ^ )丙炀馱、馬來酸、馬來酸酐、琥珀酸 :舻炉土 )丙烯醯氧乙基]、ω-羧基聚己内酯單(曱基)丙 ::曰、對乙烯基笨甲酸、對經基苯乙烯、對羥基-α_甲土本乙烯、（甲基）丙烯酸笨酯、（曱基）丙烯酸苄酯、（甲基)丙烯酉夂苯基乙酯、（甲基)丙烯醯胺、Ν-羥曱基丙烯醯胺（甲基)丙烯酸2-甲氧基乙酯、（曱基)丙烯酸甲氧基二 =一醇S曰、（甲基）丙烯酸甲氧基三乙二醇酯、（甲基）丙烯氧土丙—醇、（曱基）丙稀酸曱氧基二丙二醇酯等。4等可單獨使用，或將2種以上混合使用。 (B)共聚物可單獨使用或將2種以上混合使用。（B) 共聚物之含量，相對於顏料100質量份，通常為1〜100 質量份，較佳為5〜7〇質量份，又更佳為1〇〜5〇質量份。 (B)共聚物之含量若過多，有損及顯影性之虞。本發明中’為了提高分散性，可更含有習知之分散劑。習知之分散劑，例如，胺甲酸酯系分散劑、聚乙烯 f fe系分散劑、聚氧乙烯烷醚系分散劑、聚氧乙烯烷基苯醚系分散劑、聚乙二醇二酯系分散劑、山梨糖醇酐脂肪酸醋系分散劑、脂肪酸改f聚s旨系分散劑、丙稀酸系分散劑、顏料衍生物等。 ” -24- 201224065 就如此的分散齋丨& s g , , _ d的具體例而δ ，例如商品名為 EFKA(EFKA)公司製）、DiSperbyk(BYK 公司製）、-22 201224065 Further, in the case of a monomer providing a repeating unit (2), for example, (meth)acrylic acid brewing, (meth)acrylic acid ethyl acetate, (meth)acrylic acid propyl vinegar, (Methyl) isopropyl acrylate, butyl (meth) acrylate, isobutyl ketone (meth) acrylate, tert-butyl (meth) acrylate, 2-ethylhexyl acrylate (meth) Isodecyl acrylate, dodecyl (meth)acrylate, cyclohexyl (nonyl)enoate, sulfonium [5 2丨02,6]癸8-yl(fluorenyl) ruthenium acrylate (meth)isodecyl acrylate, adamantyl (meth) acrylate, (fluorenyl) propylene i-decahydro-2-naphthyl ester, pentacyclopentadecyl (decyl) acrylate, etc. They may be used singly or in combination of two or more. ^ Providing a monomer of repeating unit (3) 'for example, 2-(2-vinyloxyethoxy)ethyl (meth)acrylate (meth)acrylate, or propylene (meth)acrylate Ester, 2-methylglycidyl (meth)acrylate, (meth)acryloyl 4-epoxypropyloxybutyl, (meth)acrylic acid 3,4-epoxycyclohexyl decyl ester, P-vinylbenzyl epoxidized propyl ether, 3-(vinyloxymethyl) 3 ethyl propylene oxide, 3-[(meth) propylene decyl fluorenyl] propylene oxide, 3-[(indenyl) propylene醯曱 ]]]_3_ethyl propylene oxide, (fluorenyl) acrylonitrile tetrahydroanthracene vinegar, (meth)acrylic acid 3_tetrahydrofurfuryl ester, (meth) propylene I 2 (tetrahydrogen) Mercaptooxy)ethyl ester and the like. These may be used alone or in combination of two or more. Further, the p-functional group is a repeating unit of an ethylenically unsaturated bond (3) except that (meth) propyl acrylate, (mercapto) acryl 2-(2-vinyloxy ethoxy) In addition to the copolymerization of ethyl or the like, it may be introduced by various methods. In the method, for example, after copolymerizing an ethylenically unsaturated monomer having a carboxyl group (for example, '(meth)acrylic acid), the copolymer and an ethylenically unsaturated compound having an oxiranyl group (for example, (Methyl)-C--23-201224065 Cyclohexyl acrylate) Anti-Magic' method, copolymerization of an ethylenically unsaturated soap having a cyclohexane group, and copolymerization of the copolymer with a carboxyl group Sexually unsaturated compound anti-deer $ ^ OD, · force method, will have hydroxyl-containing ethylenically unsaturated early body (for example, (methyl) propyl plant. deficiency, arm is right-right" Λ · · 文 2' hydroxyl After the copolymerization of ethyl ester), the method of reacting the ethylenically unsaturated compound of the total ▲-murine oxime group, such as, for example, isocyanuric acid (oxypropyl). And '^ provide a repeating unit (4) of the monomer, for example, styrene, heart methyl, you, (曱基彳 $ 0〇ro _ ^) propylene, maleic acid, maleic anhydride, succinic acid: Furnace soil) propylene oxiranyl ethyl], ω-carboxypolycaprolactone mono(indenyl)propene:: fluorene, p-vinyl benzoic acid, p-vinyl styrene, p-hydroxy-α-carbene, Butyl (meth)acrylate, benzyl (meth)acrylate, (meth)acryloylphenylethyl, (meth)acrylamide, hydrazine-hydroxydecyl acrylamide (meth)acrylic acid 2 -methoxyethyl ester, (mercapto)acrylic acid methoxy bis-monohydric alcohol S 曰, (meth)acrylic acid methoxy triethylene glycol ester, (meth) propylene oxide propyl alcohol - ketone ) propylene dioxyethylene dipropylene glycol and the like. 4 or the like may be used alone or in combination of two or more. (B) The copolymer may be used singly or in combination of two or more. (B) The content of the copolymer is usually from 1 to 100 parts by mass, preferably from 5 to 7 parts by mass, more preferably from 1 to 5 parts by mass, per 100 parts by mass of the pigment. (B) If the content of the copolymer is too large, it may impair the developability. In the present invention, in order to improve the dispersibility, a conventional dispersant may be further contained. A conventional dispersant, for example, a urethane dispersant, a polyethylene f fe dispersant, a polyoxyethylene alkyl ether dispersant, a polyoxyethylene alkyl phenyl ether dispersant, a polyethylene glycol diester system A dispersing agent, a sorbitan fatty acid vinegar-based dispersing agent, a fatty acid-modified polydispersant, an acrylic acid-based dispersing agent, a pigment derivative, and the like. -24- 201224065 For the specific example of the dispersion of 丨丨 &; s g , , _ d , for example, the trade name is EFKA (EFKA), DiSperbyk (BYK company),

Disparlon(倘本化成（股）製）、s〇lsperse(Lubrizol 公司製）、KP(信越化學工業（股）製）、Polyflow (共榮社化學（股）製）、FTOP (Tohkem products公司製）、心糾叫大曰本油墨化學工業（股）製）、Flu〇rad(住友3M (股）製）、Disparlon (if it is a chemical system), s〇lsperse (made by Lubrizol), KP (Shin-Etsu Chemical Co., Ltd.), Polyflow (Kyoei Chemical Co., Ltd.), FTOP (made by Tohkem Products) , 心叫曰油墨油墨油墨 ink industry (stock) system, Flu 〇 rad (Sumitomo 3M (share) system),

Asahiguard、Surflon(以上，為旭确子（股）製）等。又，就顏料衍生物之具體例而言，例如：銅酞花青、二酮基吡咯并吼σ各、喧琳黃之續酸衍生物等。 -(c)交聯劑- 本發明中’（C)交聯劑係指具有2個以上可聚合之基團的化合物。就可聚合之基團而言，例如，乙烯性不飽和基、環氧乙烧基、環氧丙烧基、Ν -烧氧基曱胺基等。本發明中’就（C)交聯劑而言，較佳為具有2個以上（甲基）丙烯醯基之化合物、或具有2個以上Ν -烧氧基曱胺美之化合物。就具有上述2個以上（曱基）丙烯醯基之化合物之具體例而言，例如：脂肪族多羥基化合物與（曱基）丙稀酸反應獲得之多官能（曱基）丙稀酸醋、經己内醋改質之多官能（曱基）丙烯酸酯、經氧化烯烴改質之多官能（甲基）丙稀酸酯、具有羥基之（曱基）丙烯酸酯與多官能異氰酸g旨反應獲得之多官能胺曱酸酯（曱基）丙烯酸酯、具有羥基之 (曱基）丙烯酸酯與酸酐反應獲得之具羧基之多官能（曱基丙烯酸酯等。 -25- 201224065Asahiguard, Surflon (above, for Asahi (stock) system). Further, specific examples of the pigment derivative include, for example, copper phthalocyanine, diketopyrroloindole σ, and hydrazine yellow acid derivative. - (c) Crosslinking agent - In the present invention, the '(C) crosslinking agent means a compound having two or more polymerizable groups. As the polymerizable group, for example, an ethylenically unsaturated group, an epoxy group, a propylene group, an anthracene-oxoamine group or the like can be mentioned. In the present invention, the (C) crosslinking agent is preferably a compound having two or more (meth)acryl fluorenyl groups or a compound having two or more fluorenyloxyalkylamines. Specific examples of the compound having the above two or more (fluorenyl) acrylonitrile groups include, for example, a polyfunctional (mercapto) acrylic acid vinegar obtained by reacting an aliphatic polyhydroxy compound with (mercapto)acrylic acid. a polyfunctional (meth) acrylate modified with vinegar, a polyfunctional (meth) acrylate modified with an oxidized olefin, a (fluorenyl) acrylate having a hydroxyl group, and a polyfunctional isocyanate The polyfunctional amine phthalate ester obtained by the reaction, the polyfunctional group having a carboxyl group obtained by reacting a hydroxyl group (mercapto) acrylate with an acid anhydride, etc. -25- 201224065

如，亞甲苯二異氰酸酯、六亞甲基二異氰酸酯、二苯基亞曱基一異氰酸酯、異佛爾酮二異氰酸酯等。就酸酐而 5 ’例如’琥珀酸酐、馬來酸酐、戊二酸酐、衣康酸酐、鄰苯二甲酸酐、均四酸酐、聯聋的四元酸二酐。肝、六氫鄰苯二甲酸酐之類的二元酸酐、苯聯苯四竣酸二酐、二苯基酮四羧酸二酐之類又’就上述經己内酯改質之多官能（曱基）丙烯酸酯而言’例如.，日本特開1 1-44955號公報之段落 [0 0 1 5 ]〜[0 〇 1 8 ]記載之化合物。就上述經氧化烯烴改質之多B月b (甲基）丙稀酸醋而言，例如：雙紛a之氧乙烯及/ 或氧丙烯改質二（甲基）丙烯酸酯、異氰尿酸之氧乙烯及/ 或氧丙稀改質三（甲基）丙烯酸酯、三羥甲基丙烷之氧乙烯及/或氧丙烯改質三（曱基）丙烯酸酯、新戊四醇之氧乙烯及/或氧丙烯改質三（甲基）丙烯酸酯、新戊四醇之氧乙烯及/或氧丙烯改質四（曱基）丙烯酸酯、二新戊四醇之氧乙烯及/或氧丙烯改質五（甲基）丙烯酸酯、二新戊四醇之氧乙稀及/或氧丙烯改質六（甲基）丙烯酸酯等。 -26- 201224065 又，就上述具有2個以上之N_炫氧基曱胺基的化合物而σ命"α ’具有三聚氰胺構造、笨并胍胺 (benzoguanamine)構造、脲構造之化合物等。又，三聚氰胺構造、苯并胍胺構造，係指具有丨以上之三啩環或笨基取代三哜環為基本骨架之化學構造，也包含三聚氰胺、苯并胍胺或此等之縮合物的概念。就具冑2個以上之N-烷氧基曱胺基的化合物之具體例而言，例如：>^，^，>|’’，：^’’-.六（烷氧基甲基）三聚氰胺、 N，N，N’，N’-四（烷氧基甲基）苯并胍胺、N，N，N，，N，-四（烷氧基曱基）甘脲等。該等多官能性單體之中，使3價以上之脂肪族多羥基化合物與（甲基）丙烯酸反應得到之多官能（甲基）丙烯酸醋、經己内酯改質之多官能（曱基）丙稀酸酯、多官能聚胺醋（曱基）丙烯酸酯、具有羧基之多官能（曱基）丙烯酸醋、N，N，N’，N’，N’’，N，，-六（烷氧基甲基）三聚氰胺、 N，N，N，N -四（烧氧基甲基）苯并脈胺較佳。由著色層之強度高、著色層之表面平滑性優異，且未曝光部之基板上及遮光層上不容易發生印聚附著（scuniming)、殘膜等之觀點’尤佳為：使3價以上之脂肪族多羥基化合物與（甲基）丙烯酸反應所得到之多官能（曱基）丙烯酸酯之中的三丙烯酸三羥曱基丙烷酯、三丙烯酸新戊四醇酯、五丙烯酸二新戊四醇酯、六丙烯酸二新戊四醇酯、及在具有羧基之多官能（甲基）丙烯酸酯之中，使三丙烯酸新戊四醇酉曰與破轴酸針反應所獲得之化合物、使五丙細酸一新戍四醇酯與琥珀酸酐反應所獲得之化合物。 -27- 201224065 本發明中，（c)交聯劑可單合使用。门早獨使用’或將2種以上混本發明中，相對於(A)著色劑1〇〇質量劑之含量係以10~1，000質量份平乂1主尤佳為20〜50(1暂里份。於此情形，若多官能性 I工平遐^含量過少，右獲得充分硬化性之虞D另—太 ^ 有…法至Λ夕丄另方面，若多官能性單體之含罝過多，當對於本發明之著多 3 舍右妗齠县，w你, 成物賦予鹼顯影性時，會有鹼顯影性低、未曝弁邱 τ 不.Κ九。卩之基板上生印漿附著、殘膜等之傾向。 t尤層上合易發 -(D)黏結劑樹脂_ 月之著色組成物中，可含有⑼黏結劑樹 ^可使者色組成物㈣顯影性或對㈣向。就如此的黏結劑樹脂而古极之、，口者f生栓 V/Λ «· 不特別限定’較佳為且有羧基、本酚性羥基等酸性官 -八羧基之聚合物（以下也稱為「含八八有例如具有1個以上羧基之乙）車4 不飽和單_υ」(下稱為體（以下稱為「不飽和單體咖^之乙稀性不飽和單 H、+、（ 2)」）之共聚物。就上述不飽和單體（d〗）焉來酸、民七滅例如’（甲基）丙烯酸、馬孓駄馬來酸酐、琥珀酸單『24 φ #、 r'. '4^ M S% (甲基）丙烯酿氧乙酷1、 …叛基聚己内酿單（甲基）丙氣乙西曰] 作h ku 〇夂％對乙烯基苯甲酸等。使用。使用或將2種以上混合又，就上述不飽和單體（d 來醯亞胺、N_環己基馬來)：：，例如’N-苯基馬 ώ胺之類的N-位取代馬來醯 '28- 201224065 亞胺；苯乙烯、α-甲基苯乙烯、對羥基苯乙烯、對羥基_α_ 甲基苯乙烯、對乙烯基苄基環氧丙醚、苊烯之類的芳香族乙稀基化合物； (甲基）丙烯酸曱酯、（曱基）丙烯酸正丁酯、（甲基）丙烯酸2·乙基己酯、（曱基）丙烯酸2_羥基乙酯、（甲基）丙烯酸稀丙酯、（甲基）丙烯酸苄酯、聚乙二醇（η=2〜10)甲醚（曱基）丙烯酸酯、聚丙二醇〇)曱醚（曱基）丙烯酸酯、聚乙二醇（η =2〜10)單（甲基）丙烯酸酯、聚丙二醇 (η = 2〜1 0)單（甲基）丙烯酸酯、（曱基）丙烯酸環己酯、（甲基）丙烯酸異莰酯、參環[5.2.1.〇2,6]癸-8_基（曱基）丙烯酸醋、（甲基）丙烯酸二環戊烯酯、單（甲基）丙烯酸甘油酯、 (甲基）丙烯酸4-羥基苯酯、對異丙苯基苯酚之氧乙烯改質（甲基）丙烯酸酯、（曱基）丙烯酸環氧丙酯、（甲基）丙烯酸3，4-環氧基環己基曱酯、3·[(甲基）丙烯醯氧基甲基]環氧丙烷、3-[(甲基）丙烯醯氧基曱基]_3_乙基環氧丙烷之類的（曱基）丙烯酸酯；環己基乙烯醚、異莰基乙烯醚、參環[5.2· 1 .〇2,6]癸_8_ 基乙烯醚、五環十五烷基乙烯醚、3_(乙烯基氧基甲基）_3_ 乙基環氧丙烷之類的乙烯醚；聚苯乙烯、聚（甲基）丙烯酸甲酯、聚（曱基）丙稀酸正丁酯、聚矽氧烷之類的在聚合物分子鏈的末端具有單（甲基）丙烯醯基之巨單體等。該等不飽和單體（d2)可單獨使用或將2種以上混合使用。 -29- 201224065 不飽和單體（dl)與不飽和單體（d2)之共聚物中，該共聚物甲之不飽和單體（dl)之共聚合比例較佳為5〜5〇質量 %，更佳為10〜40質量％。藉由於如此的範圍使不飽和單體（dl)共聚合，可獲得鹼顯影性及保存安定性優異的著色組成物。就不飽和單體（dl)與不飽和單體（d2)之共聚物之具體例而言，例如，日本特開平7_14〇654號公報、日本特開平8-259876號公報、日本特開平1〇_313〇8號公報、曰本特開平10-300922號公報 '日本特開平u_174224 號公報、曰本特開平U_258415號公報、日本特開 2000-561 1 8號公報、日本特開2〇〇2_296778號公報、日本特開2 0 0 4 -1 〇 1 7 2 8公報等揭示之共聚物。又，本發明中，可例如，日本特開平5_丨9467號公報、日本特開平6-230212號公報、日本特開平7 2〇72ii 號公報、日本特開平09-325494號公報、日本特開平 i 1_14〇144號公報、日本特開2〇〇8_181〇95號公報等所揭示’將側鏈具有（曱基）丙烯醯基等聚合性不飽和鍵之含緩基之聚合物當做黏結劑樹脂使用β 本發明中’黏結劑樹脂以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量，通常為 1，000〜100,000，較佳為3,〇〇〇〜50,000。若重量平均分^ 量過小，獲得之被膜之殘膜率等會低落，或損害圖案形狀、耐熱性等，且有電特性惡化之虞；另一方面，若過大，則解像度會低落、或損及圖案形狀，且利用狹縫噴嘴方式塗布時有容易發生乾燥異物之虞。 -30- 201224065 又，本發明中，黏結劑樹脂之重量平均分子量與以 GPC(洗提溶劑··四氫呋喃）測定之聚苯乙烯換算之數量平均分子量之比’較佳為1.0〜5.0，更佳為〜3 〇。本發明令’黏結劑樹脂可依照習知方法製造，但也可藉由例如曰本特開2003-222717號公報、曰本特開 2006-259680號公報、國際公開第07/029871號小冊等所揭不之方法’控制其構造或Mw、Mw/Mn。本發明中’黏結劑樹脂可單獨使用或將2種以上混合使用。本發明中’相對於（A)著色劑1 〇〇質量份，黏結劑樹脂之含量通常為10〜1，〇〇〇質量份，較佳為2〇〜5〇〇質量份。黏結劑樹脂之含量若過少，則例如，鹼顯影性低落，或得到之著色組成物之保存安定性會有低落之虞；另一方面’若過多’則相對的著色劑濃度會降低，故對薄膜而言達成為目的之色濃度有變得困難之虞。 -(E)光聚合起始劑- 本發明之著色組成物中可含有（E)光聚合起始劑。藉此，可對於著色組成物賦予感.放射線性。本發明使用之 (E)光聚合起始劑，係可藉由可見光線、紫外線、遠紫外線、電子束、X射線等放射線之曝光而產生開始上述（c) 交聯劑之聚合的活性物質的化合物。就如此的光聚合起始劑而言，例如’噻噸酮系化合物、苯乙酮系化合物、聯咪唑系化合物、三畊系化合物、〇 -醯基肟系化合物、鏽鹽系化合物、笨偶因系化合物、二笨基酮系化合物、α -二酮系化合物、多核酿系化合物、重氮系化合物、醯亞胺確酸酯系化合物等。 -3 1- 201224065 本發明中，光聚合起始劑可單獨使用或將2種以上混合使用。就光聚合起始劑而言，較佳為選自於噻吨酮系化合物、苯乙酮系化合物、聯咪唑系化合物、三啩系化合物、0-醯基肟系化合物之群組當中至少1種。本發明中的較佳光聚合起始劑之中，就噻噸酮系化合物之具體例而言，例如：α塞°頓酮、2 -氯°塞4員酮、2 -曱基噻噸酮、2 -異丙基噻噸酮、4-異丙基噻噸酮、2，4 -二氣噻噸酮、2,4 -二曱基噻噸酮、2,4 -二乙基噻噸酮、2,4 -二異丙基噻噸酮等。又，就上述苯乙酮系化合物之具體例而言，例如：2-曱基-1-[4-(曱硫基）苯基]-2-咮啉丙烷-1-酮、2-苄基-2-二甲胺基-1-(4-味啉苯基）丁烷-1-酮、2-(4-曱基苄基）-2-(二曱胺基）-1-(4-味琳苯基）丁烧-1-嗣等。又，就上述聯咪唑系化合物之具體例而言，例如：2,2’-雙（2-氣苯基）-4,4’，5,5’ -四苯基-1,2’-聯咪唑、 2,2’-雙（2,4-二氯苯基）-4,4’，5,5’-四苯基-1，2’-聯咪唑、 2,2’-雙（2,4,6-三氣苯基）-4,4’，5,5’-四苯基-1,2’-聯咪唑等。又，光聚合起始劑使用聯咪唑系化合物時，以能改良感度之觀點，併用氫供給體為較佳。在此所指「氫供給體」，係指對於由於曝光從聯咪唑系化合物產生的自由基能提供氫原子之化合物。就氫供給體而言，例如，2-巯基苯并噻唑、2-巯基苯并嘮唑等之硫醇系氫供給體， 4,4’-雙（二曱胺基）二笨基酮、4,4’-雙（二乙胺基）二苯基酮等之胺系氫供給體。本發明中，氫供給體可單獨使用或 -32- 201224065 將2種以上混合使用，但組合1種以上之硫醇系氫供給體與1種以上之胺系氳供給體使用於更能改良感度之觀點為較佳。又，就上述三哜系化合物之具體例而言，例如：2,4,6-參（三氯甲基）-s-三啩、2-曱基-4,6-雙（三氯甲基）-s-三啩、 2-[2-(5-甲基呋喃-2-基）乙烯基]-4,6-雙（三氣曱基）-8-三 °井、2-[2-(°夫喃-2-基）乙稀基]-4,6-雙（二氯曱基）-s-二钟、 2-[2-(4-二乙胺基-2-甲基苯基）乙烯基]-4,6-雙（三氯曱基）-s-三啩、2-[2-(3,4-二甲氧基苯基）乙烯基]-4,6-雙（三氣曱基）-s-三啩、2-(4-甲氧基苯基）-4,6-雙（三氯曱基）-s-三啩、2-(4-乙氧基苯乙烯基）-4,6-雙（三氯甲基）-s-三啩、 2-(4-正丁氧基苯基）-4,6-雙（三氣甲基）-s-三啩等之具有鹵曱基之三啩系化合物。又，就0-醯基肟系化合物之具體例而言，例如1,2-辛二酮，1-.[4-(苯基硫）苯基]-，2-(0-苯曱醯基肟）、乙酮，1-[9 -乙基- 6-(2-甲基苯甲醯基）-9H-咔唑-3-基]-，l-(0-乙酿基月亏）、乙酉同，l-[9-乙基-6 - (2 -曱基-4 -四氮。夫°南基曱乳基苯甲醯基）-9H-咔唑-3-基]-，1-(0-乙醯基肟）、乙酮，1-[9-乙基-6- { 2-甲基-4-(2,2-二曱基-1，3-二氧戊烷基）曱氧基苯曱醯基} -9H-咔唑-3-基]-,1-(0-乙醯基肟）等。本發明中，使用苯乙酮系化合物等之聯咪唑系化合物以外之光聚合起始劑時，可併用增感劑。就如此的增感劑而言，例如，4,4雙（二曱胺基）二苯基酮、4,4’-雙（二乙胺基）二苯基酮、4-二乙胺基苯乙酮、4-二甲胺基苯丙酮、4-二甲胺基苯曱酸乙酯、4-二甲胺基苯甲酸2-乙基 -33- 201224065 己酯、2,5-雙（4-二乙胺基亞苄基）環己酮、7_二乙胺基 -3-(4-二乙胺基苯甲醯基）香豆素、4_(二乙胺基）查酮等。本發明中，相對於（C)交聯劑100質量份，光聚合起始劑之含量以0.01〜120質量份較佳，尤其丨〜丨⑽質^份較佳。於此情形，若光聚合起始劑之含量過少，藉由曝光所致硬化有變得不足之虞；另一方面，若過多，β形成之著色層會有容易在顯影時從基板脱落之傾向。 -(?)溶劑- 本發明之著色組成物，通常係藉由將含有顏料之著色劑於（F)溶劑中與（β)共聚物及視需要的其他分散劑或（D)黏結劑樹脂的—部分一起使用例如珠磨、輥磨等粉碎並混合·分散成為顏料分散液，接著，於該顏料分散液中添加（C)交聯劑及視需要的黏結劑樹脂、光聚合起始劑’再追加（F)溶劑等並混合之方法製備。就（F) 溶劑而言’只要能將構成著色組成物之成分（Α)〜（C)或其他成分分散或溶解’且不會與此等成分反應，且具有適度揮發性者即可’可適當選擇使用。惟，製備上述顏料分散液時’從分散性及安定性之觀點，併用（Π)具羥基之冷知丨（以下也稱為「溶劑（f 1)」。）與（f2)不具羥基之溶劑（以下也稱為「溶劑（f2)」）較佳。如此的溶劑之中，就溶劑（fl)而言，例如：乙一醇單甲醚、乙二醇單***、乙二醇單正丙醚、乙二醇單IP τ χ , 干止丁醚、二乙二醇單甲醚、二乙二醇單***、二乙二醇罝X π 平正丙醚、二乙二醇單正丁醚、三乙二醇單甲醚、三乙一辟 tm 一醇單***、丙二醇單甲醚、丙二醇單***、 34- 201224065 丙二醇單正丙醚、丙二醇單正丁醚、二丙二醇單曱醚、二丙二醇單***、二丙二醇單正丙醚、二丙二醇單正丁醚、三丙二醇單曱醚、三丙二醇單***等之（聚）烯烴基二醇單烷醚類；乳酸甲酯、乳酸乙酯等之乳酸烷酯類；甲醇、乙醇、丙醇、丁醇、異丙醇、異丁醇、第三丁醇、辛醇、2-乙基己醇、環己.醇等之（環）烷基醇類；二丙酮醇等之酮醇類等。該等溶劑（Π)之中，（聚）烯烴基二醇單烷醚類較佳，尤其丙二醇單曱醚、丙二醇單***較佳。溶劑（fl)可單獨使用或將2種以上混合使用。又，就溶劑（f2)而言，例如：乙二醇單曱醚乙酸酯、乙二醇單***乙酸酯、二乙二醇單曱醚乙酸酯、二乙二醇單***乙酸酯、丙二醇單曱醚乙酸酯、丙二醇單*** 乙酸酯、二丙二醇單曱醚乙酸酯、3 -曱氧基丁基乙酸酯、 3 -曱基-3 -曱氧基丁基乙酸酯等之（聚）烯烴基二醇單烷醚乙酸酯類；二乙二醇二甲喊、二乙二醇甲基***、二乙二醇二 ***、四氫呋喃等之其他醚類；曱乙酮、環己酮、2-庚酮、3-庚酮等之酮類；丙二醇二乙酸酯、1,3 -丁二醇二乙酸酯、1,6 -己二醇二乙酸酯等之二乙酸酯類； 3 -甲氧基丙酸甲酯、3 -甲氧基丙酸乙酯、3 -乙氧基丙酸曱酯、3 -乙氧基丙酸乙酯、乙氧基乙酸乙酯、3 -曱基-3 -甲氧基丁基丙酸酯等之烷氧基羧酸酯類； -35- 201224065 乙酸乙酯、乙酸正丙酯、乙酸異丙酯、乙酸正丁酯、乙酸異丁酯、曱酸正戊酯、乙酸異戊酯、丙酸正丁酯、丁酸乙酯、丁酸正丙酯、丁酸異丙酯、丁酸正丁酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸正丙酯、乙醯乙酸甲酯、乙醯乙酸乙酯、2 -側氧基丁酸乙酯等之其他酯類；曱苯、二甲苯等之芳香族烴類； N，N-二甲基甲醯胺、N，N-二曱基乙醯胺、N-曱基吡咯烷酮等醯胺或内醯胺類等。該等溶劑（f2)之中，（聚）烯烴基二醇單烷醚乙酸酯類、醚類、酮類、二乙酸酯類、烷氧基羧酸酯類較佳，尤其乙二醇單曱醚乙酸酯、丙二醇單甲醚乙酸酯、丙二醇單***乙酸酯、3 -曱氧基丁基乙酸酯、二丙二醇單曱醚乙酸酯、二乙二醇二曱醚、二乙二醇曱基***、環己酮、1,3 - 丁二醇二乙酸酯、1,6 -己二醇二乙酸酯、3 -曱氧基丙酸乙酯、3 -乙氧基丙酸曱酯、3 -乙氧基丙酸乙酯較佳。溶劑（f2)可單獨使用或將2種以上混合使用。本發明中，顏料分散液中，溶劑（fl)與溶劑（f2)之含有比率（質量比）較佳為1/99〜30/70，更佳為5/95〜25/75。溶劑之含量不特別限定，無論是顏料分散液還是著色組成物，其量為使該顏料散液或著色組成物之不含溶劑之各成分之合計濃度為 5〜50質量％較佳，尤佳為 1 0〜40質量％之較佳。藉由如此的態樣，可獲得分散性、安定性良好之著色劑分散液、及塗布性、安定性良好之著色組成物。 -36- 201224065 -添加劑- 本發明之著色組成物視需要也可含有 π々里添加劑。就添加劑而言，例如，玻璃、氧化鋁 <兄填劑；聚乙二醇、聚（氟烧基丙浠酸酯）類等之高分子化八氟系界面活性劑、矽系界面活性劑等之界面活性劑.，烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基參^ 甲氧基乙氧基）矽烷、N-(2-胺基乙基）_3_胺基丙基甲美t 甲氧基石夕烧、N-(2-胺基乙基）_3_胺基丙基三‘氧2石一烧、胺基丙基三乙氧基砂燒、3_環氧丙氧基丙基：：氧基石夕烧、3-環氧丙氧基丙基曱基二曱氧基石夕烧、* 環氧基環己基）乙基三甲氧基耗、3_氣丙基甲基二甲’ 基矽烷、3-氯丙基三曱氧基石夕烧、 y3甲基丙烯醯氧基丙基三甲氧基石夕&、3_硫基兩基三甲氧基石夕貌等之密八促進劑；2,2-硫雙（4_甲基_6_第三丁基苯紛）、26•二第:丁基苯齡等之抗氧化劑；2·(3·第三丁基-5_甲基_2_經基苯基)-5-氯苯并三嗤、烷氧基二苯基酮類等之紫外線吸收劑’聚丙稀酸料之抗凝集劑；丙m、衣康酸、摔康酸、富馬酸、中康酸、2-胺基乙醇、3_胺基-卜For example, toluene diisocyanate, hexamethylene diisocyanate, diphenyl sulfenyl monoisocyanate, isophorone diisocyanate, and the like. In the case of an acid anhydride, for example, succinic anhydride, maleic anhydride, glutaric anhydride, itaconic anhydride, phthalic anhydride, tetracarboxylic anhydride, and tetrabasic acid dianhydride. a dibasic acid anhydride such as liver or hexahydrophthalic anhydride, benzene biphenyl phthalic acid dianhydride, diphenyl ketone tetracarboxylic dianhydride, and the like, which are modified by the above-mentioned caprolactone ( For example, the compound described in the paragraph [0 0 1 5 ] to [0 〇 18] of Japanese Laid-Open Patent Publication No. Hei 1-14555. For the above-mentioned oxidized olefin-modified multi-B month b (meth) acrylate vinegar, for example, bis- oxy-ethylene and/or oxypropylene-modified di(meth) acrylate, isocyanuric acid Oxyethylene and/or oxypropylene modified tris(meth)acrylate, trimethylolpropane oxyethylene and/or oxypropylene modified tris(indenyl) acrylate, neopentyl alcohol oxyethylene and/or Or oxypropylene modified tris(meth)acrylate, neopentyl alcohol oxyethylene and/or oxypropylene modified tetrakis(yl) acrylate, dipentaerythritol oxyethylene and/or oxypropylene modification Penta(meth)acrylate, oxyethylene dipentaerythritol and/or oxypropylene modified hexa(meth)acrylate. -26-201224065 Further, in the above-mentioned compound having two or more N-leuco oxime amine groups, the σ life "α' has a melamine structure, a benzoguanamine structure, a urea structure, and the like. Further, the melamine structure and the benzoguanamine structure refer to a chemical structure having a triterpene ring or a stupid group substituted triterpene ring as a basic skeleton, and also includes a concept of melamine, benzoguanamine or the like. . For a specific example of a compound having two or more N-alkoxyguanamine groups, for example: >^,^,>|'',:^''-.hexa-alkoxymethyl Melamine, N,N,N',N'-tetrakis(alkoxymethyl)benzoguanamine, N,N,N,N,-tetrakis(alkoxymethyl) glycoluril, and the like. Among these polyfunctional monomers, a polyfunctional (meth)acrylic acid vinegar obtained by reacting an aliphatic polyhydroxy compound having a trivalent or higher value with (meth)acrylic acid, and a polyfunctional group modified by caprolactone (mercapto group) Acetate, polyfunctional polyamine acetate (mercapto) acrylate, polyfunctional (fluorenyl) acrylate with carboxyl group, N, N, N', N', N'', N,, - six ( Alkoxymethyl)melamine, N,N,N,N-tetrakis(oxooxymethyl)benzamide are preferred. The strength of the colored layer is high, and the surface smoothness of the colored layer is excellent, and the viewpoint of scuniming and residual film is less likely to occur on the substrate and the light-shielding layer of the unexposed portion. Among the polyfunctional (fluorenyl) acrylates obtained by reacting an aliphatic polyhydroxy compound with (meth)acrylic acid, trihydroxymercaptopropane triacrylate, neopentyl glycol triacrylate, dipentaerythritol pentaacrylate a compound obtained by reacting an alcohol ester, dipentaerythritol hexaacrylate, and a polyfunctional (meth) acrylate having a carboxyl group to react a barium neopentyl pentoxide with a sulfuric acid needle; A compound obtained by reacting a propofol monopropanol ester with succinic anhydride. -27- 201224065 In the present invention, (c) a crosslinking agent can be used singly. The door is used alone or in combination of two or more. In comparison with the (A) coloring agent, the content of the massing agent is 10 to 1,000 parts by mass, and the total amount is preferably 20 to 50 (1). In this case, if the content of the polyfunctional I work is too small, the right is fully hardened. D is too - too ^ There is a method to the other side, if the polyfunctional monomer is included If there are too many cockroaches, when it is given to the present invention, it will give alkali developability, and there will be low alkali developability, and it will not be exposed. The tendency of printing paste adhesion, residual film, etc. t 尤层上合发-(D) binder resin _ month color composition, may contain (9) binder tree ^ can be color composition (4) developability or pair (four) In this case, the adhesive resin is the same as the ancient one, and the mouth of the mouth is V/Λ «· is not particularly limited. It is preferably a polymer having a carboxyl group or a phenolic hydroxyl group and the like. Also known as "including eight or eight, for example, B with more than one carboxyl group", the car is not saturated with a single _ υ (hereinafter referred to as "unsaturated monomer coffee ^ B" a copolymer of a monounsaturated single H, +, (2)"). In the above unsaturated monomer (d), hydrazine, hexazone, such as '(meth)acrylic acid, mazanoic maleic anhydride, succinic acid Single "24 φ #, r'. '4^ MS% (methyl) propylene brewing oxygen B. 1, ... reneggler polyglycols (methyl) propane gas oxime] as h ku 〇夂% pair Vinyl benzoic acid, etc. Use. Use or mix two or more kinds of the above unsaturated monomers (d lysine, N_cyclohexylmaine)::, for example, 'N-phenyl mazamine The N-position of the class replaces the maleate '28- 201224065 imine; styrene, α-methylstyrene, p-hydroxystyrene, p-hydroxy-α-methylstyrene, p-vinylbenzyl epoxidized ether, Aromatic ethylene compound such as terpene; decyl (meth) acrylate, n-butyl (meth) acrylate, 2 · ethylhexyl (meth) acrylate, 2 hydroxy hydroxy (meth) acrylate Ester, propyl (meth) acrylate, benzyl (meth) acrylate, polyethylene glycol (η = 2~10) methyl ether (mercapto) acrylate, polypropylene glycol oxime oxime ether (fluorenyl) Ethyl ester, polyethylene glycol (η = 2~10) mono (meth) acrylate, polypropylene glycol (η = 2~1 0) mono (meth) acrylate, (decyl) cyclohexyl acrylate, Isodecyl (meth)acrylate, sulfonium [5.2.1.〇2,6]癸-8-yl(fluorenyl)acrylic acid vinegar, dicyclopentenyl (meth)acrylate, mono(meth)acrylic acid Glyceryl ester, 4-hydroxyphenyl (meth)acrylate, oxyethylene modified (meth) acrylate of p-cumylphenol, glycidyl (meth) acrylate, (meth) acrylate 3, 4 - Epoxycyclohexyl decyl ester, 3 · [(methyl) propylene methoxymethyl] propylene oxide, 3- [(methyl) propylene fluorenyl fluorenyl] _ 3 - ethyl propylene oxide (fluorenyl) acrylate; cyclohexyl vinyl ether, isodecyl vinyl ether, sulphide [5.2·1.〇2,6]癸_8_yl vinyl ether, pentacyclopentadecyl vinyl ether, 3_(ethylene Vinyl ethers such as methoxymethyl)_3_ethyl propylene oxide; polystyrene, poly(methyl) methacrylate, poly(decyl) n-butyl acrylate, polyoxathane, etc. At the end of the polymer molecular chain Giant monomer (meth) Bing Xixi the group. These unsaturated monomers (d2) may be used singly or in combination of two or more. -29- 201224065 In the copolymer of the unsaturated monomer (dl) and the unsaturated monomer (d2), the copolymerization ratio of the unsaturated monomer (dl) of the copolymer is preferably 5 to 5 % by mass. More preferably 10 to 40% by mass. By copolymerizing the unsaturated monomer (dl) in such a range, a coloring composition excellent in alkali developability and storage stability can be obtained. For a specific example of the copolymer of the unsaturated monomer (dl) and the unsaturated monomer (d2), for example, Japanese Laid-Open Patent Publication No. Hei 7-14〇654, Japanese Patent Application Laid-Open No. Hei 8-259876, and Japanese Patent Application No. Hei. _313〇号〇〇 10 10 10 10 10 10 10 10 10 10 10 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Copolymer disclosed in Japanese Unexamined Patent Publication No. Publication No. Publication No. Publication No. H. In the present invention, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A polymer containing a slow-radical group having a polymerizable unsaturated bond such as a (fluorenyl) acrylonitrile group in a side chain is disclosed as a binder resin, as disclosed in Japanese Unexamined Patent Publication No. Hei No. Hei. No. Hei. Use of β In the present invention, the weight average molecular weight of the binder resin measured by GPC (eluent solvent: tetrahydrofuran) is usually 1,000 to 100,000, preferably 3, 〇〇〇 to 50,000. When the weight average amount is too small, the residual film ratio of the obtained film may be lowered, or the pattern shape, heat resistance, and the like may be impaired, and electrical characteristics may deteriorate. On the other hand, if the film size is too large, the resolution may be lowered or damaged. And the shape of the pattern, and the application of the slit nozzle method is likely to cause drying of foreign matter. -30- 201224065 Further, in the present invention, the ratio of the weight average molecular weight of the binder resin to the number average molecular weight in terms of polystyrene measured by GPC (eluent solvent·tetrahydrofuran) is preferably 1.0 to 5.0, more preferably For ~3 〇. The present invention allows the 'adhesive resin to be produced according to a conventional method, but it can also be exemplified by, for example, 曰本特开2003-222717, 曰本特开2006-259680, International Publication No. 07/029871, and the like. The method disclosed is 'controlling its structure or Mw, Mw/Mn. In the present invention, the binder resin may be used singly or in combination of two or more. In the present invention, the content of the binder resin is usually 10 to 1 by mass based on 1 part by mass of the (A) colorant, preferably 2 parts by mass to 5 parts by mass. If the content of the binder resin is too small, for example, the alkali developability is lowered, or the storage stability of the obtained colored composition may be lowered; on the other hand, if too much, the relative colorant concentration is lowered, so It is difficult for the film to achieve a desired color density. - (E) Photopolymerization initiator - The coloring composition of the present invention may contain (E) a photopolymerization initiator. Thereby, it is possible to impart a feeling to the coloring composition and to emit radiation. The (E) photopolymerization initiator used in the present invention is an active material which starts the polymerization of the above (c) crosslinking agent by exposure to radiation such as visible light, ultraviolet light, far ultraviolet light, electron beam, or X-ray. Compound. Examples of such a photopolymerization initiator include a thioxanthone compound, an acetophenone compound, a biimidazole compound, a tri-tillage compound, a ruthenium-fluorenyl compound, a rust salt compound, and a stupid compound. A compound, a dipyridyl ketone compound, an α-diketone compound, a polynuclear brewing compound, a diazo compound, a quinone imide compound, or the like. -3 1-201224065 In the present invention, the photopolymerization initiator may be used singly or in combination of two or more. The photopolymerization initiator is preferably at least 1 selected from the group consisting of a thioxanthone compound, an acetophenone compound, a biimidazole compound, a triterpenoid compound, and a 0-fluorenyl compound. Kind. Among the preferred photopolymerization initiators in the present invention, specific examples of the thioxanthone-based compound are, for example, α-Septonone, 2-Chloro-4, and 2-Hydroxythione , 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-dithioxanthone, 2,4-dimercaptothioxanthone, 2,4-diethylthioxanthone 2,4-diisopropylthioxanthone and the like. Further, as a specific example of the above acetophenone-based compound, for example, 2-mercapto-1-[4-(indolylthio)phenyl]-2-indolyl propan-1-one, 2-benzyl group 2-dimethylamino-1-(4-morpholinylphenyl)butan-1-one, 2-(4-mercaptobenzyl)-2-(diguanylamino)-1-(4- Wei Lin phenyl) Ding Shao-1-嗣 and so on. Further, as a specific example of the above biimidazole-based compound, for example, 2,2'-bis(2-phenylphenyl)-4,4',5,5'-tetraphenyl-1,2'-linked Imidazole, 2,2'-bis(2,4-dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2'-bis (2, 4,6-trisylphenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole. Further, when the photopolymerization initiator is a biimidazole compound, it is preferred to use a hydrogen donor from the viewpoint of improving the sensitivity. The term "hydrogen donor" as used herein refers to a compound which supplies a hydrogen atom to a free radical energy generated from a biimidazole compound by exposure. In the case of a hydrogen donor, for example, a mercaptan-based hydrogen donor such as 2-mercaptobenzothiazole or 2-mercaptobenzoxazole, 4,4'-bis(diguanidino)diphenyl ketone, 4 An amine-based hydrogen donor such as 4'-bis(diethylamino)diphenyl ketone. In the present invention, the hydrogen donor may be used alone or in combination of two or more types of -32 to 201224065, but a combination of one or more kinds of thiol-based hydrogen donors and one or more kinds of amine-based ruthenium donors may be used to improve sensitivity. The viewpoint is preferred. Further, as a specific example of the above triterpenoid compound, for example, 2,4,6-parade(trichloromethyl)-s-triterpene, 2-mercapto-4,6-bis(trichloromethyl) )-s-triterpene, 2-[2-(5-methylfuran-2-yl)vinyl]-4,6-bis(triseodecyl)-8-three well, 2-[2- (°uf-2-yl)ethenyl]-4,6-bis(dichloroindenyl)-s-two, 2-[2-(4-diethylamino-2-methylphenyl) )vinyl]-4,6-bis(trichloroindenyl)-s-triterpene, 2-[2-(3,4-dimethoxyphenyl)vinyl]-4,6-bis (three) Gas-based)-s-triterpene, 2-(4-methoxyphenyl)-4,6-bis(trichloroindenyl)-s-triterpene, 2-(4-ethoxystyryl -4,6-bis(trichloromethyl)-s-triterpene, 2-(4-n-butoxyphenyl)-4,6-bis(trimethylmethyl)-s-triterpene A triterpenoid compound having a halogen group. Further, as a specific example of the 0-fluorenyl fluorene compound, for example, 1,2-octanedione, 1-.[4-(phenylthio)phenyl]-, 2-(0-benzoinyl)肟), ethyl ketone, 1-[9-ethyl-6-(2-methylbenzhydryl)-9H-indazol-3-yl]-, l-(0-ethyl aryl group) Acetyl, l-[9-ethyl-6 - (2-indolyl-4 -tetrazine, sulphate, sulphate, benzylidene)-9H-indazol-3-yl]-, 1- (0-ethylhydrazine), ethyl ketone, 1-[9-ethyl-6- { 2-methyl-4-(2,2-dimercapto-1,3-dioxolanyl) hydrazine Oxyphenyl fluorenyl} -9H-carbazol-3-yl]-, 1-(0-ethenyl fluorene) and the like. In the present invention, when a photopolymerization initiator other than the biimidazole compound such as an acetophenone-based compound is used, a sensitizer can be used in combination. In the case of such a sensitizer, for example, 4,4 bis(diguanyl)diphenyl ketone, 4,4'-bis(diethylamino)diphenyl ketone, 4-diethylamino benzene Ethyl ketone, 4-dimethylaminopropiophenone, ethyl 4-dimethylaminophenyl phthalate, 2-ethylaminobenzoic acid 2-ethyl-33- 201224065 hexyl ester, 2,5-bis (4 -diethylaminobenzylidene)cyclohexanone, 7-diethylamino-3-(4-diethylaminobenzimidyl)coumarin, 4-(diethylamino)chalcone, and the like. In the present invention, the content of the photopolymerization initiator is preferably 0.01 to 120 parts by mass, particularly preferably 丨~丨(10) by mass, based on 100 parts by mass of the (C) crosslinking agent. In this case, if the content of the photopolymerization initiator is too small, the curing due to exposure becomes insufficient. On the other hand, if the amount is too large, the coloring layer formed of β tends to be easily peeled off from the substrate during development. . - (?) Solvent - the coloring composition of the present invention, usually by using a pigment-containing coloring agent in (F) a solvent with (?) a copolymer and optionally other dispersing agents or (D) a binder resin - the parts are pulverized together by, for example, bead milling, roll milling, etc., mixed and dispersed to form a pigment dispersion liquid, and then (C) a crosslinking agent and optionally a binder resin, a photopolymerization initiator are added to the pigment dispersion liquid. Further, (F) a solvent or the like is added and mixed. As far as (F) solvent is concerned, 'as long as it can disperse or dissolve the components (Α)~(C) or other components constituting the colored composition, and does not react with these components, and has moderate volatility. Choose the right use. However, when preparing the above-mentioned pigment dispersion liquid, 'from the viewpoint of dispersibility and stability, a cold hydrazine having a hydroxyl group (hereinafter also referred to as "solvent (f 1)") and (f2) a solvent having no hydroxyl group are used in combination. (hereinafter also referred to as "solvent (f2)") is preferred. Among such solvents, in terms of the solvent (fl), for example: ethyl alcohol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene glycol single IP τ χ, dry butyl ether, two Ethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol 罝X π n-propyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monomethyl ether, triethyl epoxide monoethyl ether , propylene glycol monomethyl ether, propylene glycol monoethyl ether, 34-201224065 propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, dipropylene glycol monoterpene ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, a (poly)olefin-based diol monoalkyl ether such as tripropylene glycol monoterpene ether or tripropylene glycol monoethyl ether; an alkyl lactate such as methyl lactate or ethyl lactate; methanol, ethanol, propanol, butanol, and isopropyl a (cyclo)alkyl alcohol such as an alcohol, isobutanol, tert-butanol, octanol, 2-ethylhexanol or cyclohexanol; a ketone alcohol such as diacetone alcohol or the like. Among these solvents (poly), (poly)alkylene glycol monoalkyl ethers are preferred, and propylene glycol monoterpene ether and propylene glycol monoethyl ether are preferred. The solvent (fl) may be used singly or in combination of two or more. Further, as the solvent (f2), for example, ethylene glycol monoterpene ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monoterpene ether acetate, diethylene glycol monoethyl ether acetate Ester, propylene glycol monoterpene ether acetate, propylene glycol monoethyl ether acetate, dipropylene glycol monoterpene ether acetate, 3-methoxybutyl acetate, 3-mercapto-3-oxobutyl butyl (poly) olefinic diol monoether ether acetates such as acid esters; other ethers such as diethylene glycol dimethyl sulfonate, diethylene glycol methyl ether, diethylene glycol diethyl ether, tetrahydrofuran, etc.; Ketones such as ketone, cyclohexanone, 2-heptanone, 3-heptanone, etc.; propylene glycol diacetate, 1,3-butanediol diacetate, 1,6-hexanediol diacetate, etc. Diacetate; methyl 3-methoxypropionate, ethyl 3-methoxypropionate, decyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethoxyacetic acid Ethyloxy carboxylate such as ethyl ester or 3-mercapto-3-methoxybutylpropionate; -35- 201224065 ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate , isobutyl acetate, n-amyl decanoate, isoamyl acetate, N-butyl acrylate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate, methyl acetate, Other esters such as ethyl acetate, 2-ethyloxybutyrate, etc.; aromatic hydrocarbons such as toluene and xylene; N,N-dimethylformamide, N,N-difluorene A decylamine such as etidamine or N-mercaptopyrrolidone or an indoleamine. Among the solvents (f2), (poly)alkylene glycol monoalkyl ether acetates, ethers, ketones, diacetates, alkoxycarboxylates, and especially ethylene glycol monoterpenes. Ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, 3-methoxyoxybutyl acetate, dipropylene glycol monoterpene ether acetate, diethylene glycol dioxime ether, diethyl Glycol decyl ether, cyclohexanone, 1,3-butanediol diacetate, 1,6-hexanediol diacetate, ethyl 3-methoxyoxypropionate, 3-ethoxypropane The acid ester and ethyl 3-ethoxypropionate are preferred. The solvent (f2) may be used singly or in combination of two or more. In the present invention, in the pigment dispersion liquid, the ratio (mass ratio) of the solvent (fl) to the solvent (f2) is preferably from 1/99 to 30/70, more preferably from 5/95 to 25/75. The content of the solvent is not particularly limited, and it is preferably a pigment dispersion or a coloring composition in an amount such that the total concentration of the components of the pigment dispersion or the coloring composition containing no solvent is preferably 5 to 50% by mass. It is preferably from 10 to 40% by mass. According to such an aspect, a colorant dispersion having good dispersibility and stability and a coloring composition excellent in coatability and stability can be obtained. -36- 201224065 - Additive - The coloring composition of the present invention may also contain a π 々添加剂 additive as needed. In terms of additives, for example, glass, alumina < brother filler; polyethylene glycol, poly(fluoroalkylpropionate), etc., high molecular weight octafluoro surfactant, lanthanide surfactant Surfactant, etc., alkenyl trimethoxy decane, vinyl triethoxy decane, vinyl methoxy ethoxy decane, N-(2-aminoethyl) _ 3 - aminopropyl甲甲美 t methoxy 夕烧, N-(2-aminoethyl)_3_aminopropyl tris-oxygen 2 stone one burning, aminopropyl triethoxy sand burning, 3_epoxy Oxypropyl:: Oxygen oxylate, 3-glycidoxypropyl decyl ruthenium oxide, * Epoxycyclohexyl) ethyltrimethoxy, 3-propylmethyl Dimethyl' decane, 3-chloropropyltrimethoxy oxysulfide, y3 methacryloxypropyltrimethoxy zeoxime &, 3-thiol-based trimethoxy sulphate 2,2-sulfobis(4_methyl_6_t-butylbenzene), 26•di: antioxidants such as butyl benzene; 2·(3·t-butyl-5_ UV of methyl-2-phenyl-p-phenyl)-5-chlorobenzotriazine, alkoxydiphenyl ketone, etc. Absorbent "material of polyacrylic acid antiaggregation agent; propan m, itaconic acid, mesaconic acid fell, fumaric acid, mesaconic acid, 2-amino ethanol, amino 3_ - Bu

丙醇、5-胺基小戊醇、3,基-1，2-丙二醇、2-胺基·H 丙-醇、4·胺基]，2_ 丁二醇等之殘渣改善劑；琥拍酸單 [2_(甲基）丙㈣氧以旨]、鄰苯二甲酸單[2·(甲基）丙稀酿氧乙酿]、①-缓基聚己内酿單（甲基）丙婦酸醋等之顯影性改善劑等。 '37- 201224065 彩色渡光本發成物形成就製例。首先以區隔形散有紅色成物之後對於該塗膜之未曝晝素圖案其次物，與上塗布、預序形成綠將紅色、而成的彩序不限於又，金屬薄膜散有黑色形成時以就形砂、聚碳聚醯亞胺片及其製造方法明之彩色濾光片，係具備使用本發明之著色層者。造彩色遽光片之方法而言，先舉以 ’在基板表面上視需要形成遮光層（黑成畫素之部分。其次’在該基板上塗著色劑之本發明之感放射線性組成物 ’進行預烘烤使溶劑蒸發，並形成塗港膜隔著光罩曝光後，使用驗顯影液顯光部溶解除去。之後，藉由後烘烤，以既定排列配置成的晝素陣列。 ’使用綠色或藍色的各著色感放射述同樣進行，實施各著色感放射線性供烤、曝光、顯影及後烘烤，在同一色之畫素陣列及藍色的畫素陣列。藉綠色及藍色的三原色的畫素陣列配置色濾光片。惟，本發明中，形成各色上述者。黑色矩陣可藉由將由濺鍍或蒸鍍成膜以光微影法成為所望圖案而形成，也著色劑之著色感放射線性組成物，與同樣方式形成。成彩色濾光片時使用之基板而言，例酸8旨、聚_、芳香族聚醯胺、聚醯胺等。之著色組下方法為色矩陣），布例如分之液狀組 I。其次，影，將塗形成紅色線性組成組成物之基板上依此，獲得在基板上晝素之順之鉻等的可使用分上述畫素忙，玻璃、醯亞胺、 -38- 201224065 又，該等基板玎視所望先進行以矽烷偶合劑等之藥品處理、電漿處理、離子電鍍、濺鍍、氣相反應法、真空蒸鍍等適當的前處理。將著色感放射線性組成物塗布於基板時，可採用噴塗法、輥塗法、旋轉塗布法（spin coat法）、狹縫模塗布法、桿塗布法等適當的塗布法，尤其採用旋轉塗布法、狹縫模塗布法較佳。預供烤通常係組合減壓乾燥與加熱乾燥進行。減壓乾燥通常進行至到達50〜20〇Pp又，加熱乾燥之條件通常為於70〜U〇°c約1〜1〇分鐘。通常為0.6〜8.0 μ m，塗布厚度，就乾燥後膜厚而言車父佳為1.2〜5.0μπι。就形成畫素及/或黑色矩陣時使用之放射線之光源 =言，例如’氤燈、齒素燈、鶴燈、高壓水銀燈、超高金❹化物燈、中壓水銀燈、低壓水銀燈等 :燈=源，或氬離子雷射、YAG雷射、射、氮雷射等之雷射屯览狀干刀丁由笳111的你斛6雷射先源專，但以波長為190〜450nm之乾圍的放射線較佳。 :射曝光量’ -般為10〜Α。。。— 2較佳。鈉、氫氧化鉀述鹼顯影液而言，例如，碳酸鈉、氩氧化 U鄉、四甲其紅p 環-[5.4.〇]-7_十—土虱虱化銨、膽鹼、I8·二氮雜雙的水溶液為較佳/ 、丨，5-二氮雜雙環-[4·3.0]-5-壬烯等上述驗顯影液中水溶性有機溶巧布κ例如可適直添加曱醇、乙醇等之進行水洗。 5 ，面’舌性劑等。又，鹼顯影後通常會 -39- 201224065 就顯影處理法而言，可使用喷淋顯影法、嘴塗顯影法、dip (浸潰）顯影法、浸置（pa(jdle)顯影法等。顯影條件為常溫進行5〜3 0 0秒為較佳。後烘烤之條件，通常為於180〜280°C進行約1〇〜6〇分鐘。如此形成之畫素之膜厚，通常為0.5〜5.〇μιη，較佳為 1 · 0〜3.0μιη。又，製造彩色濾光片之第二方法，可採用如日本特開平7-318723號公報、日本特開2000-3 10706號公報等揭示之利用喷墨方式獲得各色畫素之方法。該方法中，首先在基板表面上形成兼具遮光功能之隔壁。其次，在形成之隔壁内從喷墨裝置吐出例如分散有紅色著色劑之本發明之著色組成物之液狀組成物，之後進行預洪烤使溶劑蒸發。其次，將該塗膜視需要曝光，之後進行後烘烤使硬化，形成紅色之晝素圖案。其次’使用綠色或藍色之各著色組成物，與上述同樣進行，在同/基板上依序形成綠色的畫素圖案及藍色的畫素圖案。藉此，獲得於基板上配置有紅色、綠色及色二原色之畫素圖案的彩色濾光片。惟，本發明中，形成各色晝素之順序不限於上述者。又，上述隔壁不僅有遮光功能，尚有使吐出到隔間内之各色著色組成物不致混色的功能，故比起上述^ ^ 方法使用之黑色矩陣，膜厚為厚。因此，隔壁通常使用黑色感放射線性組成物形成。 -40- 201224065 形成彩色據光片時使用之基板或放射線之光源，及預烘烤或後烘烤之方法或條件，與上述第一方法相同。以此方式’利用喷墨方式形成之晝素之膜厚，與隔壁之高度為同程度。在以此方式獲得之畫素圖案上視需要形成保護膜後，以濺鍍形成透明導電膜。也可形成透明導電膜後，再形成間隔物，以製成彩色濾光片。間隔物，通常使用感放射線性組成物形成，但也可為具遮光性之間隔物（黑色間隔物）。此時，可使用分散有黑色著色劑之著色感放射線性組成物，但是本發明之著色組成物也理想地可使用於黑色間隔物之形成。以如此方式獲得之本發明之彩色濾光片’由於輝度及色純度極高，故對於彩色液晶顯示元件、彩色攝像管元件、彩色感測器、有機EL顯示元件、電子紙等極有用。顯示元件本發明之顯示元件具備本發明之彩色濾光片。就顯示元件而言，例如··彩色液晶顯示元件、有機顯示元件、電子紙等。本發明之具備彩色濾光片之彩色液晶顯示元件可採適當構造。例如’將彩色遽光片形成在與配置有薄膜電晶體（TFT)之驅動用基柘或土板為不同的基板上，使驅動用基板與形成有彩色濾光片之美门 <巷板馮隔者液晶層而相對向之構造’再者，也可採取你古便在配置有溥膜電晶體（TFT)之驅動用基板之表面上形在、士 TTnr^M ^ .成有衫色濾光片之基板，與形成有 I TO(掺雜有錫之氧化鋼四）電極之基板，係隔著液晶層而相 -41- 201224065 對向之構造。後者之構造，可使開口率格外提高，具有能獲得明亮且高精細的液晶顯示元件的優點。本發明之彩色液晶顯示元件，除了冷陰極榮光管 (CCFL:Cold Cathode Fluorescent Lamp)以外，可具備以白色LED當做光源之背光單元。就白色LED而言，例如，組合紅色LED與綠色LED與藍色LED而混色獲得白色光之白色LED、組合藍色LED與紅色LED與綠色螢光體而混色獲得白色光之白色LED、組合藍色LED與紅色發光螢光體與綠色發光螢光體而混色獲得白色光之白色 LED、將藍色LED與YAG系螢光體混色獲得白色光之白色LED、組合藍色LED與橙色發光螢光體與綠色發光螢光體而混色獲得白色光之白色LED、組合紫外線LED與紅色發光螢光體與綠色發光螢光體與藍色發光螢光體而混色獲得白色光之白色LED等。本發明之彩色液晶顯示元件中’可應用TN(扭轉向列（Twisted Nematic))型、STN(超扭轉向列（super TwistedResidue improver of propanol, 5-aminol pentanol, 3,yl-1,2-propanediol, 2-amino·H-propanol, 4·amino], 2-butanediol, etc. Single [2_(methyl)propane (tetra)oxygen], phthalic acid mono[2·(methyl) propylene oxide ethoxylate], 1- slow-base poly-caprol (methyl)-propionic acid A developer improving agent such as vinegar. '37- 201224065 Color crossing light The formation of this product is a case. First, the red film is scattered in the shape of the partition, and the unexposed pattern of the coating film is not limited to the color of the unexposed pigment pattern of the coating film, and the green color is formed by the coating, and the green film is formed in black. In the case of a colored sand, a polycarbopolyimide sheet, and a method for producing the same, a color filter using the present invention is provided. For the method of producing a color light-emitting sheet, first, a light-shielding layer (a portion of a black pixel) is formed on the surface of the substrate as needed. Secondly, the radiation-sensitive linear composition of the present invention is coated with a coloring agent on the substrate. Pre-baking causes the solvent to evaporate, and forms a coating film which is exposed to the mask and then dissolved and removed by using the developer developing unit. After that, the matrix is arranged in a predetermined arrangement by post-baking. Or the blue coloring sensation is performed in the same manner, and each coloring sensation is linearly baked, exposed, developed, and post-baked, and the pixel array and the blue pixel array of the same color are used. The color array of the three primary color pixel arrays is disposed. However, in the present invention, the above-described color is formed. The black matrix can be formed by sputtering or vapor deposition into a film by photolithography, and is also a coloring agent. The coloring sensitizing radioactive composition is formed in the same manner. The substrate used for the color filter is exemplified by acid, poly-, aromatic polyamine, polyamine, etc. Moment ), The liquid distribution group I. divided e.g. Secondly, the shadow is applied to the substrate which is formed into a red linear composition. According to this, it is possible to obtain a chrome on the substrate, such as chrome, etc., which can be used in the above-mentioned pixels, glass, yttrium, and -38-201224065 These substrates are subjected to appropriate pretreatment such as drug treatment, plasma treatment, ion plating, sputtering, gas phase reaction, vacuum vapor deposition, etc., using a decane coupling agent or the like. When the colored radiation-sensitive composition is applied to a substrate, an appropriate coating method such as a spray coating method, a roll coating method, a spin coating method, a slit die coating method, or a rod coating method may be employed, and in particular, a spin coating method may be employed. The slit die coating method is preferred. Pre-bake roasting is usually carried out by combining dry-pressure drying and heat drying. The drying under reduced pressure is usually carried out until reaching 50 to 20 Torr Pp, and the conditions of heating and drying are usually about 70 to 10,000 ° C for about 1 to 1 Torr. Usually, it is 0.6 to 8.0 μm, and the coating thickness is 1.2 to 5.0 μm in terms of film thickness after drying. A source of radiation used to form a pixel and/or a black matrix = for example, 'Xenon lamp, tooth lamp, crane lamp, high pressure mercury lamp, ultra high gold bismuth lamp, medium pressure mercury lamp, low pressure mercury lamp, etc.: lamp = Source, or argon-ion laser, YAG laser, radiation, nitrogen laser, etc. The laser-shaped dry knife is used by the 笳111 laser, but with a wavelength of 190~450nm. The radiation is better. : The amount of exposure shots - generally 10 ~ Α. . . - 2 is preferred. For sodium and potassium hydroxide, the alkali developer is, for example, sodium carbonate, argon-oxidized U-home, tetramethyl-pyrene-p-cyclo-[5.4.〇]-7-deca-ammonium, choline, I8· The aqueous solution of diazapine is preferably a water-soluble organic solvent such as ketone, 5-diazabicyclo-[4.3.0]-5-decene, etc. , ethanol, etc. are washed with water. 5, face 'tongue agent, etc. Further, after alkali development, it is usually -39-201224065. For the development treatment method, a shower development method, a nozzle development method, a dip (dip) development method, a dipping (pa (jdle) development method, etc. may be used. The condition is preferably 5 to 300 seconds at room temperature. The conditions for post-baking are usually about 1 to 6 minutes at 180 to 280 ° C. The film thickness of the pixel thus formed is usually 0.5 to 0.5 5. 〇μιη, preferably 1 to 0 to 3.0 μm. Further, a second method for producing a color filter can be disclosed, for example, in Japanese Laid-Open Patent Publication No. Hei 7-318723, No. 2000-3 10706, and the like. A method of obtaining a color pixel by an inkjet method. First, a partition wall having a light-shielding function is formed on a surface of a substrate. Secondly, the present invention in which a red colorant is dispersed is ejected from an inkjet device in a formed partition wall. The liquid composition of the color composition is then pre-baked to evaporate the solvent. Secondly, the coating film is exposed as needed, and then post-baked to harden to form a red halogen pattern. Next, 'use green or blue Coloring composition, and Similarly, a green pixel pattern and a blue pixel pattern are sequentially formed on the same/substrate, thereby obtaining a color filter in which a pixel pattern of red, green, and color primary colors is placed on the substrate. However, in the present invention, the order of forming each color element is not limited to the above. Further, the partition wall not only has a light-shielding function, but also has a function of preventing the coloring composition of each color discharged into the compartment from being mixed, so that the above-mentioned ^^ The black matrix used in the method has a thick film thickness. Therefore, the partition wall is usually formed using a black radiation-sensitive linear composition. -40- 201224065 A substrate or a radiation source used for forming a color light film, and prebaking or postbaking The method or condition is the same as the first method described above. In this way, the film thickness of the element formed by the ink jet method is the same as the height of the partition wall. The pixel pattern obtained in this manner is required to be protected. After the film, a transparent conductive film is formed by sputtering. After the transparent conductive film is formed, a spacer is formed to form a color filter. The spacer is usually made of a radiation-sensitive composition. Formed, but may also be a light-shielding spacer (black spacer). In this case, a color-sensitive radiation composition in which a black colorant is dispersed may be used, but the coloring composition of the present invention is also desirably used in black. The formation of the spacer. The color filter of the present invention obtained in this manner has a high luminance and color purity, and thus is suitable for a color liquid crystal display element, a color image pickup device element, a color sensor, an organic EL display element, and an electronic paper. Display element The display element of the present invention includes the color filter of the present invention. For the display element, for example, a color liquid crystal display element, an organic display element, an electronic paper, etc. The color filter of the present invention is provided. The color liquid crystal display element can be suitably configured. For example, 'the color light-emitting sheet is formed on a substrate different from the driving substrate or the earth plate on which the thin film transistor (TFT) is disposed, so that the driving substrate and the color are formed. The beauty of the filter < the lining of the phoenix lining the liquid crystal layer and the relative structure of it. Again, you can also take the enamel transistor in the ancient The surface of the driving substrate of the TFT) is formed on the substrate of the TTnr^M^. The substrate having the shirt color filter, and the substrate on which the I TO (the tin-doped oxidized steel IV) electrode is formed is interposed. The liquid crystal layer is phase-41-201224065 opposite structure. The latter structure allows the aperture ratio to be particularly improved, and has the advantage of being able to obtain a bright and high-definition liquid crystal display element. The color liquid crystal display element of the present invention may be provided with a backlight unit using a white LED as a light source in addition to a Cold Cathode Fluorescent Lamp (CCFL). In the case of a white LED, for example, a combination of a red LED and a green LED and a blue LED to obtain a white light white LED, a combination of a blue LED and a red LED and a green phosphor to obtain a white light white LED, a combination blue Color LED and red illuminating phosphor and green illuminating phosphor are mixed to obtain white light white LED, blue LED and YAG fluorescent body are mixed to obtain white light white LED, combined blue LED and orange luminescent fluorescent The body and the green luminescent phosphor are mixed to obtain a white LED of white light, a combination of an ultraviolet LED and a red illuminating phosphor, and a green luminescent phosphor and a blue luminescent phosphor are mixed to obtain a white LED or the like. In the color liquid crystal display device of the present invention, TN (Twisted Nematic) type, STN (super twisted nematic (super Twisted) can be applied.

Nematic))型、IPS(面内切換（In-Planes Switching))型、 VA(垂直排列（Vertical Alignment))型、OCB(光學補償雙折射（Optically Compensated Birefringence))型等適當的液晶模式。又’具備本發明之彩色濾光片之有機EL顯示元件可採用適當構造’例如，日本特開平11 _307242號公報揭示的構造。又’具備本發明之彩色濾光片之電子紙，可採用適當構造，例如，曰本特開2007-41 169號公報揭示之構造。 -42- 201224065 [實施例] [實施例1] 以下舉實施例對於本發明之實施形態更具體說明。惟，本發明不限於下述實施例。以下使用之原料之簡稱如下。 THF ·_四氮β夫喃 ΕΕΜΑ :曱基丙烯酸1-乙氧基乙酯 ΜΑ :曱基丙烯酸 ηΒΜΑ :甲基丙烯酸正丁酯 ΜΜΑ :甲基丙烯酸甲酯 ΟΧΜΑ : 3-(曱基丙烯醯氧基甲基）-3-乙基環氧丙炫 ΑΜΑ :烯丙基甲基丙烯酸酯 THFMA ：四氫糠基曱基丙烯酸酯 ΑΙΒΝ : 2,2’-偶氮雙異丁腈 DAMA :二曱胺基乙基甲基丙烯酸酯Suitable liquid crystal modes such as Nematic), IPS (In-Planes Switching), VA (Vertical Alignment), and OCB (Optically Compensated Birefringence). Further, the organic EL display element having the color filter of the present invention can be suitably constructed. For example, the structure disclosed in Japanese Laid-Open Patent Publication No. Hei 11-307242. Further, the electronic paper having the color filter of the present invention can be suitably constructed, for example, the structure disclosed in Japanese Laid-Open Patent Publication No. 2007-41169. -42 - 201224065 [Embodiment] [Embodiment 1] Hereinafter, embodiments will be described in more detail with reference to embodiments of the present invention. However, the invention is not limited to the embodiments described below. The abbreviations of the materials used below are as follows. THF ·_tetrazine β-pentanose : 1-ethoxyethyl methacrylate ΜΑ : 曱丙烯酸 ΒΜΑ : n-butyl methacrylate ΜΜΑ : methyl methacrylate ΟΧΜΑ : 3-(mercapto propylene oxime Methyl)-3-ethylepoxypropanone : allyl methacrylate THFMA : tetrahydrofurfuryl decyl acrylate : 2,2'-azobisisobutyronitrile DAMA : decylamine Ethyl methacrylate

BzMA :苄基甲基丙烯酸酯 PME-200 :曱氧基聚乙二醇單甲基丙稀酸酯（曰油（股）公司製） PGMEA :丙二醇單曱醚乙酸醋 PGME :丙二醇單曱謎 BzCl :氯甲苯 <(B)共聚物之合成> 合成例1 於1000mL燒瓶添加THF518.26g、氣化鋰（4.05質量 %THF溶液）42.09g、二異丙胺2 〇6g，冷卻至_6〇。〇。之 -43- 201224065 後添加正丁基鋰8.50g( 15.36質量％己烷溶液），進行15 分鐘熟成。其次，滴加DAMA44.7 1 g ’滴加後繼續反應20分鐘。並且’測定氣相層析（以下簡稱GC)，並確認單體消失。其次，花費60分鐘滴加MMA28.05g、nBMA39.24g、 OXMA28.03g之混合液，滴加後繼續反應30分鐘。測定 GC，確認單體消失後，添加甲醇3.22g而使反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後’將溶劑餾去。將溶劑取代為PGMEA後’添加PGME，調整成為 PGMEA/PGME= 7/3(質量比）之35質量％溶液。添加相對於DAMA為0.8當量之BzCl，於7〇°C反應7小時，進行 4級銨化。如此，獲得嵌段共聚物溶液，其為包含以下而成：A嵌段，來自DAMA之重複單位之約80莫耳％經 4級銨化；及B嵌段，具有來自於nBMA、MMA及OXMA 之重複單位。獲得之嵌段共聚物稱為「共聚物（B-1 )」。合成例2 於1000mL燒瓶添加THF535.69g、氣化鋰（4.05質量 %THF溶液）44.41g、二異丙胺2.10g，冷卻至_60°C。之後，添加正丁基鋰8.53g(15.36質量％己烷溶液），進行 1 5分鐘熟成。其次，滴加DAMA45.57g ’滴加後繼續反應20分鐘。並且，測定GC確認單體消失。其次，花費60分鐘滴加MMA23.83g、nBMA39.32g、 Ο X M A 2 5 · 2 4 g、E E M A 1 2.7 4 g之混合液，滴加後繼續反應 30分鐘。測定GC，確認單體消失後，添加甲醇3.28g 將反應停止。 -44- 201224065 以乙酸乙醋稀釋反應液，進行三次水洗後，將溶劑餾去。將溶劑取代為PGMEA後，添加與聚合物為同量之水’於11 5 °C熟成7小時。其次，添加PGME，調整使成為pGMEA/pGME = 7/3(質量比）之35質量％溶液。添加對於DAMA為〇 8當量之BzCl，於7(TC反應7小時，進行4級銨化。如此獲得傲段共聚物溶液’其係包含以下而成：A欲段，來自 DAMA之重複單位之約80莫耳％經4級銨化；B嵌段，具有來自於nBMA、：VIMA、MA及οχμα之重複單位。獲得之嵌段共聚物稱為「共聚物合成例3 於1000mL燒瓶中添加THF521 71g、氣化鋰（4 〇5 質篁％THF浴液）46.79g、二異丙胺2.14g，冷卻至- 60°C。之後添加正丁基經8.20g(15.36質量。/〇己烷溶液），進行 1 5分鐘熟成。其次滴加DAMA44.82g，滴加後繼續反應2〇分鐘。並且，測定GC，確認單體消失。其次’花費60分鐘滴加MMA28.50g、nBMA39_60g、 AMA28.48g之混合液，滴加後繼續反應3〇分鐘。測定 GC ’確認單體消失後’添加曱醇3.3 8 g並將反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後，將溶劑餾去。將溶劑取代為PGMEA後，添加PGME，調整成為 PGMEA/PGME=7/3(質量比）之35質量。/。溶液。添加相對於DAMA為〇_8當量之BzC卜於70°C反應7小時，進行 4級銨化。如此’獲得嵌段共聚物溶液，其係包含以下 -45- 201224065 而成：A嵌段，來自DAMA之重複單位之約80莫耳％經 4級銨化；B嵌段，具有來自於nBMA、MMA及ΑΜΑ之重複單位。獲得之嵌段共聚物稱為「共聚物（Β-3)」。合成例4 於lOOOmL燒瓶添加THF519.56g、氯化鋰（4.05質量 %THF溶液）48.46g、二異丙胺2.1 lg，冷卻至_60。(3。之後添加正丁基鐘8.47g(15.36質量％己院溶液），進行15 分鐘熟成。其次滴加DAMA45.12g，滴加後繼續反應20分鐘。並且測定GC，確認單體消失。其次’花費60分鐘滴加MMA23.86g、nBMA39.95g、 AM A25.5 7 g、EEM A 1 2 _ 7 8 g之混合液，滴加後繼續反應 30分鐘。測定GC ’確認單體消失後，添加甲醇3.22g 將反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後，將溶劑館去。將溶劑取代為PGMEA後，添加與聚合物為同量之水，於11 5 °C熟成7小時。其次添加PGME，調整成PGMEA/PGME二7/3(質量比）之35質量％溶液。添加相對於DAMA為〇.8當量之 BzCl，於70°C使反應7小時，實施4級銨化。如此，獲得敌段共聚物溶液’其係包含以下而成：A嵌段，來自 DAMA之重複單位之約8〇莫耳％經4級銨化；及b嵌段，其具有來自於nBMA、MMA、MA及ΑΜΑ之重複單位。獲得之嵌段共聚物稱為「共聚物（Β_4)」。 -46- 201224065 合成例5 於1000mL燒瓶添加THF521 .〇3g、氯化鋰（3.59質量 %THF溶液）48.20g、二異丙胺2.11g，冷卻至- 60°C。之後添加正丁基鋰8.67g(l5.36質量％己烷溶液），進行15 分鐘熟成。其次滴加DAMA44.75g，滴加後繼續反應20分鐘。並且，確認測定GC、單體之消失。其次，花費60分鐘滴加MMA27.80g、nBMA39.31g、 THFMA28.1 5g之混合液，滴加後繼續反應30分鐘。測疋G C，確s忍早體消失後’添加曱醇3.2 9 g使反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後，將溶劑餾去。將溶劑取代為PGMEA後，添加PGME，調整成 PGMEA/PGME= 7/3(質量比）之35質量％溶液。添加相對於DAMA為0.8當量之BzC卜並於70°C反應7小時，以貫施4級敍化。如此獲得拔段共聚物溶液，其係包含以下而成：A嵌段，來自D ΑΜΑ之重複單位之約8〇莫耳％經4級敍化；及Β嵌段，具有來自於ηΒΜΑ、ΜΜΑ及 THFMA之重複單位。獲得之嵌段共聚物稱為「共聚物 (Β-5)」。合成例6 於具備攪拌子之燒瓶内’將nBMA7.8g、MMA5.6g、 OXMA.5.6g、AIBN228mg及0比唾-1-二硫代幾酸氰基（二曱基）甲6旨58 8mg溶於甲苯30mL並打入30分鐘氮氣使起泡。之後緩慢授拌’使反應溶液之溫度升高到6〇，於該溫度保持24小時，實施活性自由基聚合。 -47- 201224065 其次，對於上述反應溶液添加將 AIBN466mg與 DAMA9.0g溶於曱苯20mL並進行30分鐘氮氣取代的溶液，於60°C進行24小時活性自由基聚合。之後進行減壓濃縮，調整成為PGME之26.7質量％溶液。以如此方式，獲得嵌段共聚物溶液，其係包含具有來自DAMA之重複單位之A嵌段以及具有來自於nBMA、MMA及OXMA 之重複單位的B嵌段而成。其次，於獲得之嵌段共聚物溶液，添加相對於DAMA 為0.8當量之BzCl，之後緩慢攪拌，使嵌段共聚物溶液之溫度升高到8 0 °C，於該溫度保持1 5小時，實施4級銨化。以此方式，獲得嵌段共聚物溶液，其係包含以下而成：A嵌段，來自 DAMA之重複單位之約80莫耳％經4 級銨化；以及B嵌段，具有來自於nBMA、MMA及OXMA 之重複單位。獲得之嵌段共聚物稱為「共聚物（B-6)」。合成例7 於具備攪拌子之燒瓶内，將nBMA7.8g、MMA5.6g、 AMA5.6g、AIBN254mg及0比。坐-1-二硫代叛酸氰基（二曱基）曱酯656mg溶於f苯30mL並打入30分鐘氮氣使起泡。之後緩慢攪拌，使反應溶液之溫度升高到6 0 °C，於該溫度保持24小時，實施活性自由基聚合。BzMA: benzyl methacrylate PME-200: decyloxy polyethylene glycol monomethyl acrylate (made by oyster sauce) PGMEA: propylene glycol monoterpene acetate vinegar PGME: propylene glycol monoterpene BzCl Synthesis of chlorotoluene <(B) copolymer> Synthesis Example 1 In a 1000 mL flask, 518.26 g of THF, 42.09 g of lithium carbonate (4.05 mass% THF solution), and 6 g of diisopropylamine 2 were added, and the mixture was cooled to -6 Torr. . Hey. After -43-201224065, 8.50 g (15.36 mass% hexane solution) of n-butyllithium was added, and the mixture was aged for 15 minutes. Next, DAMA 44.7 1 g ' was added dropwise and the reaction was continued for 20 minutes. Further, gas chromatography (hereinafter referred to as GC) was measured, and it was confirmed that the monomer disappeared. Next, a mixture of MMA 28.05 g, nBMA 39.24 g, and OXMA 28.03 g was added dropwise over 60 minutes, and the reaction was continued for 30 minutes after the dropwise addition. After measuring the GC and confirming the disappearance of the monomer, 3.22 g of methanol was added to stop the reaction. The reaction solution was diluted with ethyl acetate, and washed with water three times, and then solvent was evaporated. After replacing the solvent with PGMEA, PGME was added, and a solution of 35% by mass of PGMEA/PGME = 7/3 (mass ratio) was adjusted. The addition of 0.8 equivalent of BzCl to DAMA was carried out at 7 ° C for 7 hours to carry out a 4-stage ammonium. Thus, a block copolymer solution is obtained which comprises the following: an A block, about 80 mole % of repeating units from DAMA, 4 grade ammonium; and a B block, having nBMA, MMA and OXMA Repeat unit. The obtained block copolymer is referred to as "copolymer (B-1)". Synthesis Example 2 In a 1000 mL flask, 535.69 g of THF, 44.41 g of lithium sulfate (4.05 mass % THF solution), and 2.10 g of diisopropylamine were added, and the mixture was cooled to _60 °C. Thereafter, 8.53 g (15.36 mass% of a hexane solution) of n-butyllithium was added, and the mixture was aged for 15 minutes. Next, dropwise addition of DAMA 45.57 g ' was added and the reaction was continued for 20 minutes. Further, the measurement of the GC confirmed that the monomer disappeared. Next, a mixture of MMA 23.83 g, nBMA 39.32 g, Ο X M A 2 · 2 4 g, and E E M A 1 2.7 4 g was added dropwise over 60 minutes, and the reaction was continued for 30 minutes after the dropwise addition. After measuring the GC and confirming the disappearance of the monomer, 3.28 g of methanol was added to stop the reaction. -44- 201224065 The reaction solution was diluted with ethyl acetate and washed with water three times, and then the solvent was evaporated. After replacing the solvent with PGMEA, the same amount of water as the polymer was added and cooked at 11 5 ° C for 7 hours. Next, PGME was added, and a 35 mass% solution which became pGMEA/pGME = 7/3 (mass ratio) was adjusted. Adding 8 equivalents of BzCl for DAMA, and performing 7-stage ammonium acylation at 7 (TC reaction for 7 hours. Thus obtaining a proud copolymer solution) is composed of the following: A segment, a repeating unit from DAMA 80 mol% is grade 4 ammonium; B block has repeat units derived from nBMA, VIMA, MA, and οχμα. The obtained block copolymer is referred to as "copolymer synthesis example 3. THF521 71g is added to a 1000 mL flask. , gasification of lithium (4 〇 5 篁% THF bath) 46.79g, diisopropylamine 2.14g, cooled to -60 ° C. After adding n-butyl via 8.20g (15.36 mass / hexane solution), The mixture was aged for 15 minutes. Next, DAMA 44.82 g was added dropwise, and the reaction was continued for 2 minutes after the dropwise addition. Further, the GC was measured to confirm the disappearance of the monomer. Next, it took 60 minutes to add a mixture of MMA 28.50 g, nBMA 39_60 g, and AMA 28.48 g. After the dropwise addition, the reaction was continued for 3 minutes. After the GC 'confirmation of the disappearance of the monomer, '3.38 g of sterol was added and the reaction was stopped. The reaction solution was diluted with ethyl acetate, washed with water three times, and then the solvent was distilled off. After the solvent is replaced by PGMEA, PGME is added and adjusted to PGMEA/PGME=7/ 3 (mass ratio) of 35 mass% of the solution. Adding BzC with a DAMA of 〇8 equivalents at 70 ° C for 7 hours, performing a 4-stage ammoniumation. Thus 'obtaining a block copolymer solution, the system Contains the following -45-201224065: A block, about 80 moles of repeating units from DAMA, grade 4 ammonium; B block, with repeating units from nBMA, MMA, and hydrazine. The copolymer was referred to as "copolymer (Β-3)". Synthesis Example 4 519.56 g of THF, 48.46 g of lithium chloride (4.05 mass% THF solution), 2.1 lg of diisopropylamine were added to a 1000 mL flask, and the mixture was cooled to _60. 3. After adding n-butyl clock 8.47 g (15.36 mass% of the house solution), it was aged for 15 minutes. Next, DAMA 45.12 g was added dropwise, and the reaction was continued for 20 minutes after the dropwise addition. The GC was measured to confirm the disappearance of the monomer. A mixture of MMA 23.86 g, nBMA 39.95 g, AM A25.5 7 g, and EEM A 1 2 _ 7 8 g was added dropwise over 60 minutes, and the reaction was continued for 30 minutes after the dropwise addition. After the GC was confirmed to confirm the disappearance of the monomer, the addition was carried out. The reaction was stopped by 3.22 g of methanol. The reaction mixture was diluted with ethyl acetate, washed with water three times, and the solvent was removed. The solvent of PGMEA substituted, added with the same amount of polymer is water at 11 5 ° C aging for 7 hours. Then of PGME was added, was adjusted to PGMEA / PGME two 7/3 (mass ratio) 35 mass% solution. The reaction was carried out at 70 ° C for 7 hours with the addition of BZCl of 8 equivalents to DAMA, and a 4-stage ammoniumation was carried out. Thus, a copolymerized copolymer solution is obtained which comprises the following: an A block, about 8 moles of repeating units from DAMA, 4 grade ammonium; and a b block, which has nBMA, MMA. , MA and ΑΜΑ repeat units. The obtained block copolymer is referred to as "copolymer (Β_4)". -46-201224065 Synthesis Example 5 THF521 was added to a 1000 mL flask, 〇3 g, lithium chloride (3.59 mass% THF solution) 48.20 g, and diisopropylamine 2.11 g, and cooled to -60 °C. Thereafter, 8.67 g (1.53 mass% hexane solution) of n-butyllithium was added, followed by aging for 15 minutes. Next, DAMA 44.75 g was added dropwise, and the reaction was continued for 20 minutes after the dropwise addition. Further, it was confirmed that the GC and the disappearance of the monomer were measured. Next, a mixture of MMA 27.80 g, nBMA 39.31 g, and THFMA 28.1 5 g was added dropwise over 60 minutes, and the reaction was continued for 30 minutes after the dropwise addition.疋G C was measured, and it was confirmed that s. The reaction liquid was diluted with ethyl acetate, washed with water three times, and then the solvent was evaporated. After replacing the solvent with PGMEA, PGME was added to adjust to a 35 mass% solution of PGMEA/PGME = 7/3 (mass ratio). A BzC of 0.8 equivalents relative to DAMA was added and reacted at 70 ° C for 7 hours to carry out a 4-stage normalization. The extraction copolymer solution thus obtained comprises the following steps: A block, about 8 〇 mol% of the repeating unit derived from D 经 is classified by 4 stages; and Β block having ηΒΜΑ, ΜΜΑ and Repeat unit of THFMA. The obtained block copolymer is referred to as "copolymer (Β-5)". Synthesis Example 6 In a flask equipped with a stirrer, 'nBMA 7.8 g, MMA 5.6 g, OXMA.5.6 g, AIBN 228 mg, and 0-pyral-1-dithiolacanoic acid cyanide (didecyl)methyl 6 58 8 mg Dissolve in 30 mL of toluene and blow in nitrogen for 30 minutes to foam. Thereafter, the mixture was slowly stirred to raise the temperature of the reaction solution to 6 Torr, and maintained at this temperature for 24 hours to carry out living radical polymerization. -47-201224065 Next, a solution in which AIBN 466 mg and DAMA 9.0 g were dissolved in 20 mL of toluene and nitrogen-substituted for 30 minutes was added to the above reaction solution, and living radical polymerization was carried out at 60 ° C for 24 hours. Thereafter, the mixture was concentrated under reduced pressure to adjust to a 26.7% by mass solution of PGME. In this manner, a block copolymer solution was obtained which contained an A block having a repeating unit derived from DAMA and a B block having repeating units derived from nBMA, MMA and OXMA. Next, in the obtained block copolymer solution, 0.8 equivalent of BzCl was added with respect to DAMA, followed by slow stirring to raise the temperature of the block copolymer solution to 80 ° C, and maintained at this temperature for 15 hours. Grade 4 ammonium. In this way, a block copolymer solution is obtained which comprises the following: an A block, about 80 mole % of repeating units from DAMA, 4 grade ammonium; and a B block, having nBMA, MMA And the repeat unit of OXMA. The obtained block copolymer is referred to as "copolymer (B-6)". Synthesis Example 7 In a flask equipped with a stirrer, nBMA 7.8 g, MMA 5.6 g, AMA 5.6 g, AIBN 254 mg, and 0 ratio were used. 656 mg of 1-cyanothionate cyano (didecyl) decyl ester was dissolved in 30 mL of fbenzene and bubbled with nitrogen for 30 minutes to cause foaming. Thereafter, the mixture was slowly stirred, and the temperature of the reaction solution was raised to 60 ° C, and maintained at this temperature for 24 hours to carry out living radical polymerization.

其次，於上述反應溶液添加將 AIBN466mg 與 DAMA9.0g溶於曱苯20mL並進行30分鐘氮氣取代的溶液，於60°C進行24小時活性自由基聚合。之後利用減壓濃縮，調整為PGME之26.7質量％溶液。如此獲得嵌段共聚物溶液，其係包含以下而成：A嵌段，具有來自DAMA -48- 201224065 之重複單位；及，B嵌段，具有來自於nBMA、MMA及 ΑΜΑ之重複單位。其次於獲得之嵌段共聚物溶液中，添加相對於 DAMΑ為0.4當量之BzCl，之後緩慢攪拌，使反應溶液之溫度升高到70°C，於該溫度保持24小時，進行4級銨化。以此方式獲得嵌段共聚物溶液，其係包含以下而成：A 嵌段，來自DΑΜΑ之重複單位之約40莫耳％經4級鍵化；及Β嵌段，具有來自於ηΒΜΑ、ΜΜΑ及ΑΜΑ之重複單位。獲得之嵌段共聚物稱為「共聚物（Β-7)」。合成例8 於具備攪拌子之燒瓶内，將nBMA7.8g、MMA5.6g、 THFMA5.6g、AIBN254mg及吡唑-1-二硫代羧酸氰基（二曱基）曱酯626mg溶於曱苯30mL並打入30分鐘氮氣使起泡。之後缓慢攪拌，並使反應溶液之溫度升高到60°C，於該溫度保持24小時，進行活性自由基聚合。其次，於上述反應溶液添加將 AIBN513mg 與 DAMA9.0g溶於甲苯：20mL並進行30分鐘氮氣取代的溶液，於60°C進行24小時活性自由基聚合。之後利用減壓濃縮，調整成PGME之26.7質量％溶液。如此獲得嵌段共聚物溶液，其係包含以下而成：A嵌段，具有來自DAMA 之重複單位；及 B嵌段，具有來自於ηΒΜΑ、MMA及 THFMA之重複單位。其次，於獲得之嵌段共聚物溶液中添加相對於 DAMΑ為0.8當量之BzCl，之後緩慢攪拌，並使反應溶液之溫度升高到90°C，於該溫度保持8小時，進行4級 -49- 201224065 銨化。如此’獲得嵌段共聚物溶液，其係包含以下而成：A 嵌段，來自DAMA之重複單位之約80莫耳％經4級銨化；及B嵌段，具有來自於nBMA、MMA及THFMA之重複單位。獲得之嵌段共聚物稱為「共聚物（Β_8)」。比較合成例1 於1000mL燒瓶添加THF617.82g、氣化鋰（3.63質量 %THF溶液）12.44g、二苯基乙烯3.39g，冷卻至。之後添加正丁基裡7.82g(15_36質量0/◦己烧溶液），進行 1 5分鐘熟成。其次’花費60分鐘滴加MMA40.24g、nBMA18.70g、 10.17g的PME-200、〇XMA27.3 0g之混合液，滴加後繼續反應2 0分鐘。並且，測定G C，確認單體消失。其次’滴加DAMA47.38g，滴加後繼續反應30分鐘。並且，測定GC，確認單體消失後，添加甲醇3.86g，將反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後，將溶劑餾去。將溶劑取代為PGMEA後，添加PGME，調整成 PGMEA/PGME= 7/3(質量比）之35質量。/〇溶液。添加相對於DAMA為0.8當量之BzCl ’於70°C反應7小時，實施 4級銨化。如此獲得嵌段共聚物溶液，其係包含以下而成：A嵌段，來自DAMA之重複單位之約80莫耳％經4 級銨化；及B嵌段，其具有來自於nBMA、MMA、PME-200 及OXMA之重複單位。獲得之欲段共聚物稱為「共聚物 (b-1)」。 -50- 201224065 比較合成例2 於100〇1111^燒瓶添加1'11?560.418、氯化裡（3.63質量 %THF溶液）11.32g、二苯基乙烯3.27g，冷卻至_60。(3。之後添加正丁基鋰7.28g(15.36質量％己烧溶液），進行 1 5分鐘熟成。其次，花費60分鐘滴加MMA33.69g、nBMAl 5.80g、 PME-200 8.66g、AMA23.15g之混合液，滴加後繼續反應20分鐘。並且，測定GC，確認單體消失。其次’滴加DAMA40.30g ’滴加後繼續反應30分鐘。並且，測定G C ’確認單體消失後’添加曱醇3 · 6 5 g，將反應停止。以乙酸乙醋稀釋反應液，進行三次水洗後，將溶劑餾去。將溶劑取代為PGMEA後，添加pgmE，調整成 PGMEA/PGME= 7/3(質量比）之35質量％溶液。添加相對於DAMA為0.8當量之BzC卜於70t反應7小時，實施 4級銨化。如此獲得嵌段共聚物溶液，其係包含以下而成.A嵌^又，來自D A Μ A之重複單位之約8 〇莫耳％經4 級知化，及B嵌·^又，具有來自於nBMA、MMA、PME-200 及ΑΜΑ之重複單位。獲得之嵌段共聚物稱為「共聚物 (b-2)」。比較合成例3 於1000mL燒瓶中添加thf626 56 3,3； ΓΓ， -60°C。之後添加正丁基鋰6.95g(1 5 36質量％己烷溶液），進行1 0分鐘熟成。 201224065 其次’花費30分鐘滴加MMA26.52g、nBMA62.13g 之混合液，滴加後繼續反應15分鐘。並測定，確認單體消失。其次滴加DAMA42.1 9份，滴加後繼續反應3〇分鐘。並且，測定GC，確認單體消失後，添加曱醇3 79份，將反應停止。以乙酸乙酯稀釋反應液，進行三次水洗後，將溶劑館去。溶劑取代為PGMEA後，添加PgMe，調整成 pgmEA/pgme=7/3(質量比）之35質量％溶液。添加相對於DAMA為0.8當量之BzC卜於70°C反應7小時，以實施4級銨化。如此獲得嵌段共聚物溶液，其係包含以下而成.A嵌段，來自DAMA之重複單位之約8〇莫耳％經4 級銨化；及B嵌段，具有來自於nBMA& MMA2重複單位。獲得之嵌段共聚物稱為「共聚物（b_3)」^ 上述合成例中，4級銨化前之共聚物之Mw、Mn及各單體之共聚合比例（質量％)，如表1。 <酸價之測定> ^上述各合成例獲得之（B)共聚物之酸價依下述方法測定。表1顯示測定結果。精稱嵌段共聚物溶液〇.5g，至達到lmg的單位，分 =到玻璃容器。以丙二醇單甲醚乙酸酯稀釋成5〇mL後，姊加紛Sii ’以0.1N乙醇性氫氧化鉀水溶液進行滴定，以 :色：粉紅色之點當做終點。以同樣方式進行空白試二伙（B)共聚物與空白試驗之〇1N乙醇性氫氧化鉀水冷液滴加量計算酸價（單位：mgKOH/g) 〇 -52- 201224065 <胺價之測定> 上述各合成例獲得之（B)共聚物之胺價依下述方法測定。表1顯示測定結果。精稱共聚物溶液〇. 5 g，至達到1 m g之單位，分裝到玻璃容器。添加乙酸酐/乙酸=9/1(體積比）20mL並溶解，於室溫放置3小時。之後再添加乙酸3OmL，之後使用電位差測定裝置 AT-510(京都電子工業（股）公司製），以0.1 mo 1/L過氯酸•乙酸溶液進行滴定。以同樣方式進行空白試驗。從（B)嵌段共聚物與空白試驗之0.1 mol/L 過氣酸.乙酸溶液滴加量，計算胺價（單位：mgKOH/g)。 -53- 201224065 I < 比較合成例 m CO Xi (N CO o ο 1.08 5770 o ro (N (N CN X) s m O\ 卜 cn m o i〇 00 1.10 9430 o cs X) 00 CN m On 卜 m ΓΛ o ν-ϊ oo 1.07 7640 o m (N 合成例 oo OO (N (N ΓΛ o o 1.64 8400 o (N 卜 B-7 OO <N s (N m o o V-H '1.71 8700 o OO v〇 B-6 OO (N S (N cn o o 1-H 00 VO 8300 o m rvi »r> B-5 OO <N (N m o o CN 9020 o (N 寸 B-4 «η 卜 00 (N oo CN m 100 g 1.50 6340 m m <N B-3 OO <N CN m o o r-H 11320 o m CM tN B-2 卜 00 (N OO cn o F-4 § 1.46 6510 CO m (N ώ oo fN CN m 100 o 1.17 9410 o fS 共聚物名 ΜΑ 1 MMA nBMA OXMA ! AiMA THFMA PME-200 DAMA 合計(質量％) 重複單位(2)之共聚合比例（質量％)*) Mw/Mn Mw 酸價(mgKOH/g) 胺價(mgKOH/g) —寸lr)_ 201224065 <顏料分散液之製備> 製備例1 使用當做著色劑之9質量份C · I.顏料紅丨7 7 量份C.I,顏料紅254、共聚物（B-1)溶液17.0質量及6質發成分=3 5質量％)、當做溶劑之丙二醇單 77 (非揮 60.0質量份及丙二醇單甲醚8質量份，以久酉旨備成顏料分散液（A-1)。 1々理’製製備例2〜14及比較製備例1〜6 將製備例1中，著色劑、（B)共聚物及溶劑之種類量改變為如表2所示，除此以外與製備例丨、及 J 1以Η樣方式進行’製備顏料分散液（Α-2)〜（Α-20)。 <著色劑分散液之評價> 使用Ε型黏度計（東京計器製）測定獲得之顏料分散液之黏度。又，將獲得之顏料分散液充填於遮光玻璃容器，於密閉狀態於23。<:靜置丨4曰後，使用Ε型黏度計（東京計器製）再度測定黏度。並且，計算相黏度，於保存14日後之黏度之增加率，增加率低於\% 時評為「Α」；5%以上低於10%時評為「Β」；ι〇%以上時 δ平為「C」。評價結果如表2。表2中，「R177」代表C.L顏料紅177，「R254」代丄顏料254’「⑽」代表CJ.顏料、綠.I 表C.I.顏料黃150，「Β15: 6」代表「τ令代表C.L顏料紫23，「Υ179」代表二料藍15:6’「V23」劑黃179，「PGMEA」代表丙二醇單甲有機染料之C.1.溶代表丙二醇單甲醚。甲_乙㈣，「PGME」 -55- 201224065 CN^ 比較製備例 A-20 12.6 寸 csi s 00 卜 r-^ o < A-19 Os VO s 00 t> 寸 < A-18 〇\ VO s 00 CN < A-17 cs § oo 卜〇\ < A-16 cs g 00 o CQ A-15 〇\ VO s 卜〇\ CQ 製備例 A-14 CS *—H 寸〇\ < A-13 σ\ VO s oo 卜〇\ C A-12 〇\ VO § 00 卜 00 < A-ll 12.6 寸 ri 00 o On < A-10 12.6 寸 <Ν· s oo OO c A-9 VO oo vo 卜 PQ A-8 m CN S 卜卜 < A-7 σ\ § oo r- v〇 < A-6 VO s cn «Ο < A-5 Cj 3 卜 < A-4 10.5 — 2 m 卜卜 < A-3 ro (N S 寸 OO < A-2 〇\ VO 63.5 oo 13.5 OS < ON s 00 卜卜 < R177 R254 B15:6 V23 G58 Y150 | 1 V170 I上… I PGMEA PGME ! CQ B-2 B-3 B-4 B-5 B — 6 B-7 00 1 CQ ji (N X) m X) 初期黏度（mPa · s) 保存安定性著色劑溶劑 (B)共聚物溶液 -9ln_ 201224065 <黏結劑樹脂之合成> 合成例9 於配備冷卻管與攪拌機之燒瓶中，將對乙烯基苄基環氧丙醚44_0g、N-笨基馬來醯亞胺4〇.〇g、BzMA16.〇g 溶於丙二醇單甲醚乙酸酯300g，再投入AIBN8.0g及α-曱基苯乙烯二聚物8. 〇g ’之後，進行15分鐘氮氣吹洗。氮氣吹洗後，將反應溶液一面攪拌及一面打入氮氣，加熱至8 0。(：並聚合5小時。其次，於該反應溶液中添加MA17.0g、對曱氧基苯酚0.5g及四丁基溴化銨4.4g，於120°C反應9小時。再者，添加琥珀酸酐18.5g，於i〇〇°c反應6小時後，保持液溫為85°C，進行2次水洗，並進行減壓濃縮，獲得含黏結劑樹脂（D-1) 33質量％之溶液。該黏結劑樹脂 (D-1)，以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量=7,800、以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量與數量平均分子量之比=2.8。合成例10 於配備冷卻管與攪拌機之燒瓶中，將BzMA30.0g、 nBMA20.0g、甲基丙烯酸羥基乙酯l5.0g、苯乙烯20.0g 及ΜΑ 15.0g溶於丙二醇單曱醚乙酸酯200g，再投入 AIBN3.0g及α-甲基苯乙烯二聚物5.〇g，之後進行15分鐘氮氣吹洗。氮氣吹洗後，將反應液一面攪拌及打入氮氣使起泡，一面加熱至8 0 X：，進行5小時聚合，藉此獲得含黏結劑樹脂（D-2)33質量％之溶液。該黏結劑樹脂 -57- 201224065 (D-2)，以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量=10,000，以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量與數量平均分子量之比= 2.5。合成例11 於配備冷卻管與攪拌機之燒瓶中，將〇XMA25.0g、 MA18.0g、琥珀酸單2 -丙烯醯氧基乙酯9.0g、N -苯基馬來醯亞胺l〇_〇g、BzMA24.0g、曱基丙烯酸羥基乙酯14.〇g 溶於丙二醇單曱醚乙酸酯3 00g，再投入AIBN6.0g及曱基苯乙晞二聚物6.0g，之後進行15分鐘氮氣吹洗。氮氣吹洗後，將反應液一面攪拌及氮氣吹洗’一面加熱到 80°C，進行5小時聚合，獲得前驅物共聚物溶液。於獲得之前驅物共聚物溶液200g中添加2-甲基丙烯醯氧基乙基異氰酸酯1 3.4g、當做聚合抑制劑之4-甲氧基苯酚〇.2g ’於90°C反應2小時。對於該反應液，以每1次7 5 g的離子交換水進行2次水洗，並進行減壓濃縮，獲得含黏結劑樹脂（D-3) 33質量％之溶液。黏結劑樹月旨（D-3)，以GpC(洗提溶劑：四氫呋喃）測定之聚苯乙稀換算之重量平均分子量=11，〇〇〇，以GPC(洗提溶劑：四氫呋喃）測定之聚苯乙烯換算之重量平均分子量與數量平均分子量之比==1 · 9。 <著色組成物之製備及評價> 著色組成物之製備實施例1 -58- 201224065 將顏料分散液（A-1 ) 1 00質量份、當做黏結劑樹脂之黏結劑樹脂（D - 2)溶液3 4.1質量份、當做交聯劑之東亞合成（股）公司製M-402(六丙烯酸二新戍四醇酯為主成分）11.3質量份、當做光聚合起始劑之2-(4-曱基苄基）-2-(二甲胺基）-丨彳心味啉苯基）丁烷·丨_酮（商品名Next, a solution in which AIBN 466 mg and DAMA 9.0 g were dissolved in 20 mL of toluene and nitrogen-substituted for 30 minutes was added to the above reaction solution, and living radical polymerization was carried out at 60 ° C for 24 hours. Thereafter, the mixture was concentrated under reduced pressure to adjust to a 26.7% by mass solution of PGME. The block copolymer solution thus obtained was obtained by the following steps: an A block having a repeating unit derived from DAMA-48-201224065; and a B block having repeating units derived from nBMA, MMA and hydrazine. Next, in the obtained block copolymer solution, 0.4 equivalent of BzCl with respect to DAMΑ was added, followed by slow stirring, and the temperature of the reaction solution was raised to 70 ° C, and maintained at this temperature for 24 hours to carry out 4-grade ammonium. In this way, a block copolymer solution is obtained which comprises the following: an A block, about 40 mol% of repeating units derived from DΑΜΑ, and a 4-stage bonding; and a hydrazine block having ηΒΜΑ, ΜΜΑ and Repeat unit. The obtained block copolymer is referred to as "copolymer (Β-7)". Synthesis Example 8 In a flask equipped with a stirrer, nBMA 7.8 g, MMA 5.6 g, THFMA 5.6 g, AIBN 254 mg, and pyrazole-1-dithiocarboxylic acid cyano (didecyl) decyl ester 626 mg were dissolved in benzene. 30 mL and nitrogen gas for 30 minutes to foam. Thereafter, the mixture was slowly stirred, and the temperature of the reaction solution was raised to 60 ° C, and maintained at this temperature for 24 hours to carry out living radical polymerization. Next, a solution in which 513 mg of AIBN and 9.0 g of DAMA were dissolved in toluene: 20 mL and nitrogen-substituted for 30 minutes was added to the above reaction solution, and living radical polymerization was carried out at 60 ° C for 24 hours. Thereafter, the mixture was concentrated under reduced pressure to adjust to a 26.7% by mass solution of PGME. The block copolymer solution thus obtained was obtained by the following steps: an A block having a repeating unit derived from DAMA; and a B block having repeating units derived from ηΒΜΑ, MMA and THFMA. Next, 0.8 eq of BzCl relative to DAM oxime was added to the obtained block copolymer solution, followed by slow stirring, and the temperature of the reaction solution was raised to 90 ° C, and maintained at this temperature for 8 hours, and 4 - 49 was carried out. - 201224065 Ammonium. Thus 'obtaining a block copolymer solution comprising the following: A block, about 80 mole % from DAMA repeating unit 4 grade ammonium; and B block having nBMA, MMA and THFMA Repeat unit. The obtained block copolymer is referred to as "copolymer (Β_8)". Comparative Synthesis Example 1 In a 1000 mL flask, 617.82 g of THF, 12.44 g of lithium carbonate (3.63 mass % THF solution), and 3.39 g of diphenylethylene were added, and the mixture was cooled. Then, 7.82 g of n-butyl hydride (15-36 mass 0 / hexane solution) was added and aging was carried out for 15 minutes. Next, a mixture of MMA 40.24 g, nBMA 18.70 g, 10.17 g of PME-200, and 〇XMA 27.3 0 g was added dropwise over 60 minutes, and the reaction was continued for 20 minutes after the dropwise addition. Further, G C was measured to confirm the disappearance of the monomer. Next, DAMA 47.38 g was added dropwise, and the reaction was continued for 30 minutes after the dropwise addition. Further, after measuring the GC and confirming the disappearance of the monomer, 3.86 g of methanol was added to stop the reaction. The reaction liquid was diluted with ethyl acetate, washed with water three times, and then the solvent was evaporated. After replacing the solvent with PGMEA, PGME was added and adjusted to 35 masses of PGMEA/PGME = 7/3 (mass ratio). /〇 solution. The addition of 0.8 equivalents of BzCl' to DAMA was carried out at 70 ° C for 7 hours to carry out a 4-stage ammonium. The block copolymer solution is thus obtained, which comprises the following steps: A block, about 80 mol% of repeating units from DAMA, 4 grade ammonium; and B block, which has nBMA, MMA, PME -200 and OXMA repeat units. The obtained copolymer is referred to as "copolymer (b-1)". -50-201224065 Comparative Synthesis Example 2 In a 100〇1111 flask, 1'11?560.418, chlorinated (3.63 mass% THF solution), 11.32 g, and diphenylethylene (3.27 g) were added, and the mixture was cooled to _60. (3) Then, 7.28 g of n-butyllithium (15.36 mass% hexane solution) was added, and aging was carried out for 15 minutes. Next, 33.69 g of MMA, 5.80 g of nBMAl, 8.66 g of PME-200, and 23.15 g of AMA were added dropwise over 60 minutes. After the dropwise addition, the reaction was continued for 20 minutes, and the GC was measured to confirm the disappearance of the monomer. Next, 'DAMA 40.30 g was added dropwise' and the reaction was continued for 30 minutes after the dropwise addition. The reaction was stopped with 3 6 5 5 g of decyl alcohol. The reaction solution was diluted with ethyl acetate, washed with water three times, and the solvent was distilled off. After replacing the solvent with PGMEA, pgmE was added and adjusted to PGMEA/PGME = 7/3 ( a mass ratio of 35% by mass of a solution. Adding 0.8 eq of BzC to DAMA at 70 t for 7 hours, performing a 4-stage ammonium crystallization. Thus obtaining a block copolymer solution, which comprises the following. , about 8 〇 mol % from the repeat unit of DA Μ A, 4 levels of knowledge, and B embedded · ^, with repeat units from nBMA, MMA, PME-200 and ΑΜΑ. Obtained block copolymer This is called "copolymer (b-2)". Comparative Synthesis Example 3 Adding thf626 to a 1000 mL flask 56 3,3; ΓΓ, -60 ° C. Then add 6.95 g of n-butyllithium (1 5 36 mass % hexane solution), and aging for 10 minutes. 201224065 Next, it took 30 minutes to add MMA 26.52g, nBMA62 After the dropwise addition, the reaction mixture was continued for 15 minutes, and the measurement was confirmed to confirm the disappearance of the monomer. Next, 9 parts of DAMA 42.1 was added dropwise, and the reaction was continued for 3 minutes after the dropwise addition. Further, the GC was measured to confirm that the monomer disappeared. Adding 79 parts of decyl alcohol to stop the reaction. The reaction mixture was diluted with ethyl acetate, washed three times, and then the solvent was removed. After the solvent was replaced by PGMEA, PgMe was added to adjust to pgmEA/pgme=7/3 (mass 35 mass % solution of the ratio. Adding 0.8 eq of BzC to DAMA at 70 ° C for 7 hours to carry out 4-stage ammonium crystallization. Thus obtained a block copolymer solution, which comprises the following. The segment, about 8 〇 mol % from the repeating unit of DAMA is quaternized by the 4th grade; and the B block has the repeating unit derived from nBMA & MMA 2. The obtained block copolymer is called "copolymer (b_3)" ^ In the above synthesis example, the copolymerization of Mw, Mn and each monomer of the copolymer before the 4-stage ammonium ionization Examples (% by mass) are shown in Table 1. <Measurement of Acid Value> ^ The acid value of the (B) copolymer obtained in each of the above Synthesis Examples was determined by the following method. Table 1 shows the measurement results. The solution is 〇5g, up to the unit of 1mg, and the fraction = to the glass container. After diluting to 5 〇mL with propylene glycol monomethyl ether acetate, the Sii' was titrated with a 0.1 N aqueous solution of potassium hydroxide, and the color: pink point was used as the end point. In the same manner, the blank test group (B) copolymer and the blank test were carried out. 1N ethanol potassium hydroxide water-cooled droplets were added to calculate the acid value (unit: mgKOH/g) 〇-52- 201224065 < Determination of amine price > The amine valence of the (B) copolymer obtained in each of the above Synthesis Examples was measured by the following method. Table 1 shows the results of the measurements. Finely weighed the copolymer solution 〇. 5 g, up to 1 m g, and dispensed into a glass container. Acetic anhydride/acetic acid = 9/1 (volume ratio) 20 mL was added and dissolved, and allowed to stand at room temperature for 3 hours. Thereafter, 3 mL of acetic acid was added, and then a potentiometric apparatus AT-510 (manufactured by Kyoto Electronics Co., Ltd.) was used, and titration was carried out with a 0.1 mol/L perchloric acid/acetic acid solution. A blank test was performed in the same manner. The amine valence (unit: mgKOH/g) was calculated from the amount of the (B) block copolymer and the 0.1 mol/L peroxyacid. acetic acid solution in the blank test. -53- 201224065 I < Comparative Synthesis Example m CO Xi (N CO o ο 1.08 5770 o ro (N (N CN X) sm O\ 卜 moi〇00 1.10 9430 o cs X) 00 CN m On 卜 m ΓΛ o ν-ϊ oo 1.07 7640 om (N Synthetic oo OO (N (N ΓΛ oo 1.64 8400 o (N 卜 B-7 OO < N s (N moo VH '1.71 8700 o OO v〇B-6 OO ( NS (N cn oo 1-H 00 VO 8300 om rvi »r> B-5 OO <N (N moo CN 9020 o (N inch B-4 «η 卜 00 (N oo CN m 100 g 1.50 6340 mm < N B-3 OO <N CN moo rH 11320 om CM tN B-2 00 (N OO cn o F-4 § 1.46 6510 CO m (N ώ oo fN CN m 100 o 1.17 9410 o fS copolymer name ΜΑ 1 MMA nBMA OXMA ! AiMA THFMA PME-200 DAMA Total (% by mass) Repeating unit (2) copolymerization ratio (% by mass)*) Mw/Mn Mw Acid value (mgKOH/g) Amine value (mgKOH/g) - inch lr)_201224065 <Preparation of pigment dispersion> Preparation Example 1 9 parts by mass of C·I. Pigment Red 丨 7 7 parts by weight, Pigment Red 254, Copolymer (B-1) Solution 17.0 mass and 6 hair growth components = 35 mass%), As a solvent, propylene glycol mono 77 (non-volatile 60.0 parts by mass and propylene glycol monomethyl ether 8 parts by mass, prepared as a pigment dispersion (A-1) for a long time. 1 Preparation 'Preparation Examples 2 to 14 and Comparative Preparation Example 1 ～6 In the preparation example 1, the amount of the colorant, the (B) copolymer, and the solvent were changed as shown in Table 2, and the preparation of the pigment dispersion was carried out in the same manner as in Preparation Example 及 and J 1 in the same manner. (Α-2)~(Α-20). <Evaluation of Colorant Dispersion> The viscosity of the obtained pigment dispersion liquid was measured using a Ε-type viscosity meter (manufactured by Tokyo Keiki Co., Ltd.). Further, the obtained pigment dispersion liquid was filled in a light-shielding glass container in a sealed state at 23. <: After standing at 4 Torr, the viscosity was measured again using a Ε-type viscometer (manufactured by Toyo Keiki Co., Ltd.). Also, calculate the viscosity, and increase the viscosity after 14 days of storage. When the increase rate is lower than \%, it is rated as “Α”; when it is less than 10%, it is rated as “Β”; when 〇% or more, it is “δ”. C". The evaluation results are shown in Table 2. In Table 2, "R177" stands for CL Pigment Red 177, "R254" for 丄 Pigment 254' "(10)" stands for CJ. Pigment, Green. I Table CI Pigment Yellow 150, "Β15: 6" stands for "τ Order represents CL pigment Violet 23, "Υ179" stands for two blue 15:6' "V23" agent yellow 179, "PGMEA" stands for propylene glycol monomethyl organic dye C.1. Soluble represents propylene glycol monomethyl ether. A_B (4), "PGME" -55- 201224065 CN^ Comparative Preparation Example A-20 12.6 inch csi s 00 卜r-^ o < A-19 Os VO s 00 t> inch < A-18 〇\ VO s 00 CN < A-17 cs § oo 〇〇 \ < A-16 cs g 00 o CQ A-15 〇\ VO s 〇〇 \ CQ Preparation Example A-14 CS *—H 〇〇 \ < A -13 σ\ VO s oo 〇〇 \ C A-12 〇 \ VO § 00 00 00 < A-ll 12.6 inch ri 00 o On < A-10 12.6 inch <Ν· s oo OO c A-9 VO oo vo 卜 PQ A-8 m CN S 卜卜< A-7 σ\ § oo r- v〇< A-6 VO s cn «Ο < A-5 Cj 3 卜< A-4 10.5 — 2 m Bub < A-3 ro (NS inch OO < A-2 〇 VO 63.5 oo 13.5 OS < ON s 00 Bub < R177 R254 B15:6 V23 G58 Y150 | 1 V170 I... IP GMEA PGME ! CQ B-2 B-3 B-4 B-5 B — 6 B-7 00 1 CQ ji (NX) m X) Initial viscosity (mPa · s) Preservative stability colorant solvent (B) copolymer Solution -9ln_201224065 <Synthesis of binder resin> Synthesis Example 9 In a flask equipped with a cooling tube and a stirrer, p-vinylbenzyl epoxidized ether 44_0g, N-stupyl maleimide 4 〇. 〇g, BzMA16.〇g was dissolved in 300 g of propylene glycol monomethyl ether acetate, and then charged with AIBN 8.0 g and α-mercaptostyrene dimer 8. 〇g ', followed by nitrogen purge for 15 minutes. After purging with nitrogen, the reaction solution was stirred while being purged with nitrogen gas and heated to 80. (: and polymerization for 5 hours. Next, MA17.0 g, p-methoxyphenol 0.5 g and tetrabutylammonium bromide 4.4 g were added to the reaction solution, and the mixture was reacted at 120 ° C for 9 hours. Further, succinic anhydride was added. 18.5 g, after reacting for 6 hours at i〇〇°c, maintaining the liquid temperature at 85 ° C, washing with water twice, and concentrating under reduced pressure to obtain a solution containing 33% by mass of the binder resin (D-1). The binder resin (D-1), the weight average molecular weight in terms of polystyrene measured by GPC (eluent solvent: tetrahydrofuran) = 7,800, and the weight average molecular weight in terms of polystyrene measured by GPC (eluent solvent: tetrahydrofuran) Ratio to number average molecular weight = 2.8. Synthesis Example 10 In a flask equipped with a cooling tube and a stirrer, BzMA 30.0 g, nBMA 20.0 g, hydroxyethyl methacrylate 15.0 g, styrene 20.0 g, and hydrazine 15.0 g were dissolved. 200 g of propylene glycol monoterpene ether acetate, and then added AIBN 3.0 g and α-methylstyrene dimer 5. 〇g, followed by nitrogen purge for 15 minutes. After nitrogen purge, the reaction solution was stirred and beaten. Blistening with nitrogen gas, heating to 80 X:, and polymerizing for 5 hours. a solution containing 33% by mass of a binder resin (D-2). The binder resin-57-201224065 (D-2), weight average molecular weight = 10,000 in terms of polystyrene measured by GPC (eluent solvent: tetrahydrofuran) The ratio of the weight average molecular weight to the number average molecular weight in terms of polystyrene measured by GPC (eluent solvent: tetrahydrofuran) = 2.5. Synthesis Example 11 In a flask equipped with a cooling tube and a stirrer, 〇XMA 25.0 g, MA18. 0 g, succinic acid mono-2-propenyloxyethyl ester 9.0 g, N-phenylmaleimine l〇_〇g, BzMA 24.0 g, hydroxyethyl methacrylate 14. 〇g dissolved in propylene glycol monoterpene 3 00 g of ether acetate, and then 6.0 g of AIBN and hydrazinophenidin dimer were added, followed by nitrogen purge for 15 minutes. After nitrogen purge, the reaction solution was heated while stirring and nitrogen purged. At 80 ° C, polymerization was carried out for 5 hours to obtain a precursor copolymer solution. To obtain 200 g of the precursor copolymer copolymer solution, 2-methylpropenyloxyethyl isocyanate 1 3.4 g was added as a polymerization inhibitor 4-A Oxyphenol oxime. 2g 'reacted at 90 ° C for 2 hours. For the reaction solution, Each time, 7 5 g of ion-exchanged water was washed twice with water, and concentrated under reduced pressure to obtain a solution containing 33% by mass of the binder resin (D-3). The binder was used (D-3) to GpC. (eluent solvent: tetrahydrofuran), the weight average molecular weight of polystyrene conversion = 11, 〇〇〇, the ratio of the weight average molecular weight to the number average molecular weight in terms of polystyrene measured by GPC (eluent solvent: tetrahydrofuran) ==1 · 9. <Preparation and Evaluation of Coloring Composition> Preparation Example of Coloring Composition Example 1 -58- 201224065 100 parts by mass of the pigment dispersion liquid (A-1), as a binder resin of a binder resin (D - 2) Solution 3 4.1 parts by mass, as a crosslinking agent, M-402 (manocyanol hexaacrylate as a main component) of 11.3 parts by mass, as a photopolymerization initiator 2-(4- Mercaptobenzyl)-2-(dimethylamino)-indole phenyl phenyl)butane oxime ketone (trade name)

Irgacure379、Ciba Speciality Chemicals 公司製）4.2 質量份、當做氟系界面活性劑之DIC(股）公司製Megafac F - 5 5 4 〇 · 〇 5質量份及當做溶劑之3 _乙氧基丙酸乙酯1 6 2 質量份混合’製備液狀之著色組成物。色度特性之評價將獲得之著色組成物使用旋塗機塗布在玻璃基板上後’以1 0 0 c的熱板進行2分鐘預烘烤，形成膜厚不同的 3片塗膜。其次，將該等基板冷卻至室溫後，對於基板上之塗膜’使用高壓水銀燈對於各塗膜不透過光罩地以 l，〇〇〇J/m的曝光量以含365nm、4〇5ηπι及436nm之各波長之放射線進行曝光。之後於220°C進行20分鐘後烘烤’在基板上形成硬化膜。針對得到的3片硬化膜，使用衫色分析儀（大塚電子（股）製MCPD2000)，於C光源、 2度視野，測定CIE表色系中的色度座標値（x，y)及刺激値（Y)彳足測疋結果求取色度座標値X = 0.640時之色度座仏値y及刺激値（Y)。評價結果如表3。對比度之評價針對上述「色度特性之評價」獲得之3片硬化膜，使用對比度計（壺坂電機製對比度測定器CT-1 )，測定對比度°從測定結果求取色度座標値X = 0.640時之對比度。评價結果如表3。 -59- 201224065 耐溶劑性之評價Irgacure 379, manufactured by Ciba Speciality Chemicals Co., Ltd., 4.2 parts by mass of Megaafac F-5 5 4 〇·〇, which is a fluorine-based surfactant, and 3 _ethoxypropionate as a solvent 1 6 2 parts by mass mixed 'prepared liquid colored composition. Evaluation of chromaticity characteristics The obtained coloring composition was applied onto a glass substrate using a spin coater, and then prebaked on a hot plate of 100 ° C for 2 minutes to form three coating films having different film thicknesses. Next, after the substrates are cooled to room temperature, a high-pressure mercury lamp is used for the coating film on the substrate, and the exposure amount of each coating film is not transmitted through the mask, and the exposure amount of 〇〇〇J/m is 365 nm, 4〇5ηπι. Exposure was performed by radiation of each wavelength of 436 nm. Thereafter, it was baked at 220 ° C for 20 minutes to form a cured film on the substrate. For the obtained three cured films, the color coordinates (x, y) and the stimuli in the CIE color system were measured using a shirt color analyzer (MCPD2000 manufactured by Otsuka Electronics Co., Ltd.) at a C light source and a 2 degree field of view. (Y) The results of the enthalpy test are obtained for the chromaticity coordinates 仏値 y and the stimuli Y (Y) when the chromaticity coordinate 値 X = 0.640. The evaluation results are shown in Table 3. Evaluation of Contrast For the three cured films obtained by the above "Evaluation of Chroma Characteristics", a contrast meter (Conduit Electromechanical Contrast Tester CT-1) was used to measure the contrast. From the measurement results, the chromaticity coordinates 値X = 0.640 were obtained. The contrast of time. The evaluation results are shown in Table 3. -59- 201224065 Evaluation of solvent resistance

將上述「色度特性之評價」中獲得的基板當中的^ 片浸泡於60 C的N-甲基吡咯烷酮中3〇分鐘。並且求取浸潰刖後之色變化。小於3時評為A 以上時評為C。上小於5時評為b 耐熱性之評價將上述「色度特性之評價」中獲得之基板當中的1 片’再於25〇<t追加加熱30分鐘。並且，以目鏡倍率1〇 ^物鏡彳°率10倍的光學顯微鏡觀察基板表面。於1個視野中確認的異物為3個以下時評為A ;於i個視野中嫁認的異物為4個以上9個以下時評為B ;力丄個視野中確認之異物為1〇個以上時評為c。實施例2〜14及比較例丨〜6 將實施例1中，改變顏料分散液、黏結劑樹脂、交聯劑、光聚合起始劑、及溶劑之種類及量為如表3所示，除此以外與實施例1同樣進行，實施著色組成物之製備及評價。評價結果如表3。又，關於綠色之著色組成物（實施例2貫施例1 0〜1 2及比較例4〜6 )，求取色度座標値 y= 0.5 90之色度座標値χ、刺激値（γ)及對比度。關於藍色的著色組成物（實施例4)，求取色度座標値y = 〇.〇9〇之色度座標値X、刺激値（Y)及對比度。評價結果如表3。 -60- 201224065 比較例 o o 寸 \〇 CN S q 0.590 0.299 14500 U < ΙΛι o 〇 Os <N cn 1-H m g 0.590 0.299 13600 m < 寸 o 00 <N m CN rn »n CN (N s 0.590 0.299 14000 PQ < o 〇 »-H On r<i CN (N 0.325 0.640 8900 o ο <N o 寸· 寸 ό 〇\ rn CN >Λ> 〇 (N 0.325 0.640 9100 PQ < o ι-Η CO CN <N Ό od 0.313 0.640 12400 m < 實施例寸〇寸 fn 00 卜 1-H (N 0.325 0.640 9200 < < o rn r-H (N <N Ό i-H m 〇6 ψ-η 0.313 0.640 13000 < < CN o 卜 od <N m cs »0 CN <n § 0.590 0.299 14500 < < o 寸 »τΐ v〇 VO CN s 〇〇 VO 0.590 0.299 14600 < < o o i-H ro CM <ri v〇 <N σί VO 〇\ o 0.299 14800 < < ON o f-H — m rn (N 寸 (N v〇 »«H od 0.313 0.640 12500 < < OO o m 寸 d r—i OS rn <N ^Ti (N (N 0.325 0.640 9300 < < 卜 o 汰 ΓΛ (N 寸 (N v〇 ΓΟ od 0.313 0.640 12800 < < o 窆 VO in ¥ »n CN OO 0.313 0.640 12900 < < i/Ί o (N »〇 cs <n <N Os ΓΟ Ό »〇 fN 0.325 | 0.640 9900 < < 寸 o «—H o r〇 m 〇\ H OO o o g o 0.152 7700 < < m 〇寸 OO Γ- γο (N (N 0.325 0.640 9600 < < <N Ο 卜 \〇 OO rn <N CS »-H § 0.590 0.299 14700 < < o r^i cn f-H CN ¥ <N v〇 «—H 寸 od 0.313 0.640 13200 < < < <N < m < < irj < < 卜 < 00 <i 〇\ < A-10 A-ll 1 A-12 cn 1 < 1 a-14 I [A-15 1 A-16 [A-17 1 [A-18 1 1 a-19 1 | A-20 | 1 Q <N Q m ά ό (N ύ w (N W EEP MBA Y値 X 對比度耐溶劑性耐熱性顏料分散液交聯劑光聚合起始劑溶劑 ί； 201224065 表3中的各成分如下。、^ .d:六丙烯酸二新戊四醇酯與五丙烯酸二新戊四醇酯之混合物（商品名M-402、東亞合成（股）公司製） C-2 :五丙烯酸二新戊四醇酯與琥拍酸之單醋化物、六丙烯酸二新戊四醇酯及五丙烯酸二新戊四醇醋之混*合物（商品名TO-1 3 82、東亞合成（股）公司製） E-1 :乙酮，1-[9 -乙基-6-(2-曱基苯曱醯基）-9H-咔唑 -3-基]-，l-(〇-乙醯基肟）（商品名 IRGACURE 0X02、Ciba Speciality Chemicals 公司製） E-2 : 2-(4 -曱基苄基）_2_(二甲胺基）_卜（4_味啉苯基）丁烧-1-酮（商品名 Irgacure379、Ciba Speciality Chemicals 公司製） EEP : 3-乙氧基丙醆乙酯腦：3-甲氧基丁基乙酸酯【圖式簡單說明】無。【主要元件符號說明】無0 -62-The sheet of the substrate obtained in the above "Evaluation of Chroma Characteristics" was immersed in 60 C of N-methylpyrrolidone for 3 minutes. And to find the color change after dipping. When it is less than 3, it is rated as C when it is rated as A or more. Evaluation of heat resistance of b when it was less than 5 The one piece of the substrate obtained in the above "evaluation of chromaticity characteristics" was further heated at 25 Å < t for 30 minutes. Further, the surface of the substrate was observed with an optical microscope having an eyepiece magnification of 1 〇 ^ objective lens 10 10 times. When the foreign matter confirmed in one field of view is three or less, it is rated as A; when the foreign matter that is married in one field of view is four or more and nine or less, it is rated as B; when the foreign matter confirmed in one field of view is more than one or more For c. Examples 2 to 14 and Comparative Examples 丨 to 6 In Example 1, the types and amounts of the pigment dispersion liquid, the binder resin, the crosslinking agent, the photopolymerization initiator, and the solvent were changed as shown in Table 3, except Other than the above, the preparation and evaluation of the colored composition were carried out in the same manner as in Example 1. The evaluation results are shown in Table 3. Further, regarding the green coloring composition (Example 1 Example 10 to 12 and Comparative Examples 4 to 6), the chromaticity coordinate 値 y= 0.5 90 chromaticity coordinate 値χ, stimulating 値 (γ) was obtained. And contrast. Regarding the blue coloring composition (Example 4), the chromaticity coordinates 値X, the stimuli Y (Y), and the contrast of the chromaticity coordinates 値y = 〇.〇9〇 were obtained. The evaluation results are shown in Table 3. -60- 201224065 Comparative example oo inch 〇CN S q 0.590 0.299 14500 U < ΙΛι o 〇Os <N cn 1-H mg 0.590 0.299 13600 m < inch o 00 <N m CN rn »n CN ( N s 0.590 0.299 14000 PQ < o 〇»-H On r<i CN (N 0.325 0.640 8900 o ο <N o inch·inchό 〇\ rn CN >Λ> 〇(N 0.325 0.640 9100 PQ < o ι-Η CO CN <N Ό od 0.313 0.640 12400 m <Example inch inch fn 00 卜 1-H (N 0.325 0.640 9200 << o rn rH (N <N Ό iH m 〇6 Ψ-η 0.313 0.640 13000 << CN o 卜 <N m cs »0 CN <n § 0.590 0.299 14500 < o 寸»τΐ v〇VO CN s 〇〇VO 0.590 0.299 14600 << oo iH ro CM <ri v〇<N σί VO 〇\ o 0.299 14800 << ON o fH — m rn (N 〇 (N v〇»«H od 0.313 0.640 12500 << OO om dr dr-i OS rn <N ^Ti (N (N 0.325 0.640 9300 << 卜o ΓΛ ( N inch (N v〇ΓΟ od 0.313 0.640 12800 < o 窆 VO in ¥ »n CN OO 0.313 0.640 12900 << i/Ί o (N »〇cs <n <N Os ΓΟ Ό » 〇fN 0.325 | 0.640 9900 << inch o «—H or〇m 〇\ H OO oogo 0.152 7700 << m 〇 inch OO Γ- γο (N (N 0.325 0.640 9600 <<<N Ο布\〇OO rn <N CS »-H § 0.590 0.299 14700 << or^i cn fH CN ¥ <N v〇«—H inch od 0.313 0.640 13200 <<<<N< m << irj <<< 00 <i 〇\ < A-10 A-ll 1 A-12 cn 1 < 1 a-14 I [A-15 1 A-16 [A-17 1 [A-18 1 1 a-19 1 | A-20 | 1 Q <NQ m ά ό (N E w (NW EEP MBA Y値X Contrast Solvent resistance Heat resistance Pigment dispersion Crosslinking agent Photopolymerization Starter Solvent ί; 201224065 The components in Table 3 are as follows. , ^ .d: a mixture of dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate (trade name M-402, manufactured by Toagosei Co., Ltd.) C-2: dine pentaerythritol pentaacrylate a mixture of an ester and a monoacetate of succinic acid, dipentaerythritol hexaacrylate and dipentaerythritol pentaacetate (trade name: TO-1 3 82, manufactured by Toagosei Co., Ltd.) E -1 : Ethylketone, 1-[9-ethyl-6-(2-mercaptophenyl)-9H-indazol-3-yl]-, 1-(anthracene-ethenyl) (product) IRGAGURE 0X02, manufactured by Ciba Speciality Chemicals Co., Ltd.) E-2 : 2-(4-mercaptobenzyl)_2-(dimethylamino)-b (4_glypholine phenyl) butyl-1-one (trade name) Irgacure 379, manufactured by Ciba Speciality Chemicals Co., Ltd.) EEP: 3-ethoxypropionate brain: 3-methoxybutyl acetate [simple description] None. [Main component symbol description] No 0 -62-

Claims

201224065 七、申請專利範圍： 1. 一種彩色濾光片用著色組成物，其特徵為包含以下分（A)、（B)及（C): (A) 含有顏料之著色劑； (B) 共聚物，其含有以下述式〇)表示之重複單位 (1)、以下述式（2)表示之重複單位（2)、及具交聯性官能基之重複單位（3) ’且該重複單位（2)之共聚合比例為^ 含該重複單位（1)及該重複單位（3)之全部重複單位中的9 0質量％以上； (C) 交聯劑；201224065 VII. Patent application scope: 1. A coloring composition for color filters, which is characterized by comprising the following sub-components (A), (B) and (C): (A) a pigment-containing coloring agent; (B) copolymerization And a repeating unit (1) represented by the following formula (2), a repeating unit (2) represented by the following formula (2), and a repeating unit (3) ' having a crosslinkable functional group and the repeating unit ( 2) The copolymerization ratio is more than 90% by mass of all the repeating units of the repeating unit (1) and the repeating unit (3); (C) a crosslinking agent;

[式（1)中， R1代表氫原子或曱基， Z代表-N + R2R3R4Y_(其中，R2〜R4彼此獨立而代表氫原子、或也可具有取代基之烴基，γ-代表相對陰離子）' -NR5R6(其中’ R5及R6彼此獨立而代表氫原子、或也可具有取代基之烴基）、或也可具有取代基之含氮雜環基， X1代表2價之連結基];[In the formula (1), R1 represents a hydrogen atom or a fluorenyl group, and Z represents -N + R2R3R4Y_ (wherein R2 to R4 are independently of each other and represent a hydrogen atom, or a hydrocarbon group which may have a substituent, and γ- represents a relative anion)' -NR5R6 (wherein R 5 and R 6 are each independently and represent a hydrogen atom, or a hydrocarbon group which may have a substituent), or a nitrogen-containing heterocyclic group which may have a substituent, and X 1 represents a divalent linking group];

-63- 201224065 [式（2)中， r7代表氫原子或甲基， r8代表飽和脂肪族烴基或飽和脂環式烴基]。 2. 如申請專利範圍第1項之彩色渡光片用著色組成物，其中該（B)共聚物之重量平均分子量Mw與數量平均分子量 Μη 之比（Mw/Mn)為 1·0~1·8。 3. 如申請專利範圍第1項之彩色濾光片用著色組成物，其中該（Β)共聚物係嵌段共聚物，其包含：具有該重複單位（1)之Α嵌段、與具有該重複單位（2)及該重複單位（3) 之B嵌段。 4·如申請專利範圍第丨項之彩色濾光片用著色組成物，其係進一步包含（D)黏結劑樹脂（其中，不含該（B)成分）。 5. 如申請專利範圍第1項之彩色濾光片用著色組成物，其中其係進一步含有染料當做著色劑。 6. 如申請專利範圍第1項之彩色濾光片用著色組成物，其係進一步包含（E)光聚合起始劑。 7. —種彩色濾光片，其係具備使用如申請專利範圍第i 至6項中任一項之彩色濾光片用著色組成物而形成之者色層而成。 8. —種顯示元件，其係具備如申請專利範圍第7項之彩色渡光片。 9. 一種衫色濾光片用顏料分散液，其特徵為包含以下成分（A)、（B)及（ρ): -64- 201224065 (A) 含有顏料之著色劑； (B) 共聚物，其包含以下述式（1)表示之重複單位 (1)、以下述式（2)表示之重複單位（？）、及具有交聯性官能基之重複單位（3) ’且該重複單位（2)之共聚合比例為不含該重複單位（1)及該重複單位（3)之重複單位中的 90質量％以上； (F)溶劑； R1 —^-CH2—C^— ⑴ X1 I z [式（1)中， R1代表氫原子或曱基， Z代表-N+R2R3R4Y-(其中，R2〜R4彼此獨立而代表虱原子、或也可具有取代基之煙基，γ_代’表相對陰離子）、-NR5R6(其中，R5及R6彼此獨立而代表氫原子、或也可具有取代基之烴基）、或也可具有取代基之含氮雜環基， X1代表 2價之連結基];-63- 201224065 [In the formula (2), r7 represents a hydrogen atom or a methyl group, and r8 represents a saturated aliphatic hydrocarbon group or a saturated alicyclic hydrocarbon group]. 2. The coloring composition for a color light-passing sheet according to the first aspect of the invention, wherein the ratio (Mw/Mn) of the weight average molecular weight Mw to the number average molecular weight Μη of the (B) copolymer is 1.0·1·1· 8. 3. The coloring composition for a color filter according to the first aspect of the invention, wherein the (Β) copolymer-based block copolymer comprises: a block having the repeating unit (1), and having the same Repeat the unit (2) and the B block of the repeating unit (3). 4. The coloring composition for a color filter according to the ninth aspect of the invention, further comprising (D) a binder resin (wherein the component (B) is not contained). 5. The coloring composition for a color filter according to claim 1, wherein the dyeing composition further comprises a dye as a coloring agent. 6. The coloring composition for a color filter according to claim 1, further comprising (E) a photopolymerization initiator. A color filter comprising a color layer formed by using the coloring composition for a color filter according to any one of claims 1 to 6 of the patent application. 8. A display element comprising a color light-emitting sheet as set forth in claim 7 of the patent application. A pigment dispersion for a shirt color filter comprising the following components (A), (B) and (ρ): -64- 201224065 (A) a pigment-containing coloring agent; (B) a copolymer, It comprises a repeating unit (1) represented by the following formula (1), a repeating unit (?) represented by the following formula (2), and a repeating unit (3) having a crosslinkable functional group and the repeating unit (2) The copolymerization ratio is 90% by mass or more of the repeating unit excluding the repeating unit (1) and the repeating unit (3); (F) solvent; R1 - ^-CH2 - C^ - (1) X1 I z [ In the formula (1), R1 represents a hydrogen atom or a fluorenyl group, and Z represents -N+R2R3R4Y- (wherein R2 to R4 are independent of each other and represent a ruthenium atom or a ketone group which may have a substituent, and the γ-generation' table is relative Anion), -NR5R6 (wherein R5 and R6 are independently of each other and represent a hydrogen atom, or a hydrocarbon group which may have a substituent), or a nitrogen-containing heterocyclic group which may have a substituent, and X1 represents a divalent linking group];

I4- 8 COO-R8I4- 8 COO-R8

[式（2)中， R7代表氫原子或曱基， R8代表飽和脂肪族烴基或飽和脂環式烴基]。 -65- 201224065 四、指定代表圖： (一) 本案指定代表圖為：無。 (二) 本代表圖之元件符號簡單說明：無0 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式：[In the formula (2), R7 represents a hydrogen atom or a fluorenyl group, and R8 represents a saturated aliphatic hydrocarbon group or a saturated alicyclic hydrocarbon group]. -65- 201224065 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: None 0. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: