201219294 六、發明說明 【發明所屬之技術領域】 [0001] [0002] Ο [0003] 〇 [0004] [0005] 099137721 本發明涉及-種奈米碳管膜承載結構及其使用方法。 [先前技術] 奈米碳管係-種由石墨稀片卷成的中空管狀物，其 優異的力學、熱學及電學性質。奈米碳管應用領^ 廣闊，例如’它可用於製作場效應電晶體、原子 鏡針尖、場發射電子搶、奈米模板等等。惟，目前我攻 上都係在微觀尺度下應用奈米碳管，操作較困難^本 ，將奈米碳管紐裝成宏觀尺度的結騎於奈米碳營Κ 觀應用具有重要意義。 、 、宏 ;.f 1爾+ J! |!是 , 先前的奈米碳管宏觀結構主要有奈米碳管膜，惟〜 破管膜等奈米碳管宏觀結構的比表面積很大卡 現出很強的黏性，一旦接觸到其他物體便會黏 表 難分開’所以給保存和轉移奈米碳管宏觀結構报 的困難，從而大大限制了奈米碳管膜等奈米碳營大 宏觀領域的進一步應用。 ^構在 【發明内容】 有鑒於此，冑供一種奈米碳管膜承載結構及其使用 實為必要。 '1之用方法 二：::結搆’該奈米❹联承載〜 二構，且該奈米破管媒狀結構與該 承栽、、。構接觸後可完整地從該承載結構脫離，其中，該奈載結構包括一本體，所述本體具有-表面 ’jt體的表面具有一奈米碳管膜承载區域，該奈米 第3頁/共27頁 表單編號A0101 0992065765-0 201219294 碳管膜承載區域具有複數個凹陷結構’所述複數個凹陷 結構的總凹陷面積大於等於所述奈米碜管膜承載區域面 積的80°/❶，從而使所述奈米碳管膜狀結構設置於所述奈米 碳管膜承載區域時，所述奈米碳管膜狀結構與所述本體 的有效接觸面積小於等於所述奈米碳管臈狀結構本身面 積的20%。 [0006] 一種奈米碳管膜承載結構的使用方法’包括以下步驟： 提供至少一奈米碳管膜承载、结構’所述奈米碳管膜承載 結構包括一本體，所述本髏臭有一表面，該表面具有一 奈米碳管膜承载區域，該奈米碳管膜承載區域具有複數 個凹陷結構，所述複數個四陷結構的總凹陷面積大於等 於所述奈米碳管膜承載區威的面積的8&% ;提供一奈米碳 管膜狀結構；以及將所述奈米破管膜狀結構直接設置於 所述奈米碳管膜承載結構的奈米碳管臈承載區域，所述 奈米碳管膜狀結構與所述奈米碳管膜承载結構的有效接 觸面積小於等於所述奈米後管膜狀緣構本身面積的20%。 [00〇7]相較先前技術，所述奈米碳管膜承載結構具有結構簡單 等特點，該奈米碳管膜承載結構通過在一本體的表面設 置複數個凹陷結構，使得將一奈米碳管膜狀結構設置於 所述奈米碳管膜承載結構表面時’該奈米礙管膜狀結構 的大部分結構通過所述凹陷結構懸空設置’從而大大地 減少了所述奈米碳管膜狀結構與所述奈米碳管骐承載結 構的有效接觸面積，進而降低了所述奈米碳管膜狀結構 與所述奈米碳管膜承載結構之間的凡得瓦力’最後實現 奈米碳管膜狀結構的保存和轉移。 099137721 表單編號A0101 第4頁/共27頁 0992065765-0 201219294 [0008] 所述奈米碳管膜承 管膜直接承载於一太二=方法，通過將-奈米碳 載區域，從而實現^ 構的奈米碳管膜承 方法簡單易行。㈣狀結構的保存和轉移，該 【實施方式】 [0009] 下面將結合_及具體實施例 細說明。 對本發明作進_步的詳 [0010]201219294 VI. Description of the Invention [Technical Field] [0001] [0003] [0003] The invention relates to a nanocarbon tube film carrying structure and a method of using the same. [Prior Art] The carbon nanotube system is a hollow tubular body rolled from a graphite flake, and has excellent mechanical, thermal and electrical properties. The application of carbon nanotubes is broad, such as 'it can be used to make field effect transistors, atomic mirror tips, field emission electrons, nano templates, and so on. However, at present, I am applying the carbon nanotubes at the microscopic scale, which is difficult to operate. It is of great significance to install the carbon nanotubes into a macroscopic scale. , macro, .f 1 er + J! |! Yes, the previous nano carbon tube macro structure mainly has a carbon nanotube film, but the specific surface area of the nano tube of the nano tube of the broken tube film is very large. It has a strong viscosity. Once it touches other objects, it will be difficult to separate. So it is difficult to save and transfer the macroscopic structure of the carbon nanotubes, which greatly limits the carbon nanotubes and other nano carbon camps. Further application of the field. [Structure] In view of this, it is necessary to provide a carbon nanotube film bearing structure and its use. The method of '1': 2::: structure' The nano-coupled bearing ~ two structures, and the nano-tube structure and the planting, and. The contact structure can be completely detached from the load-bearing structure, wherein the load-bearing structure comprises a body having a surface of the surface of the body having a carbon nanotube film bearing area, the third page of the nanometer / A total of 27 pages of the form number A0101 0992065765-0 201219294 carbon tube film bearing area has a plurality of recessed structures 'the total recessed area of the plurality of recessed structures is greater than or equal to 80 ° / 面积 of the area of the nanotube film bearing area, thereby When the carbon nanotube film structure is disposed on the carbon nanotube film bearing region, the effective contact area of the carbon nanotube film structure with the body is less than or equal to the carbon nanotube shape 20% of the area of the structure itself. [0006] A method for using a carbon nanotube film carrying structure includes the following steps: providing at least one carbon nanotube film bearing, structure, wherein the carbon nanotube film carrying structure comprises a body, and the body has a body a surface having a carbon nanotube film bearing region, the carbon nanotube film bearing region having a plurality of recessed structures, the total recessed area of the plurality of quadrangular structures being greater than or equal to the carbon nanotube film bearing region 8&% of the area of the wei; providing a carbon nanotube film-like structure; and directly placing the nano-tube-membrane structure on the carbon nanotube-bearing bearing region of the carbon nanotube film-bearing structure, The effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing structure is less than or equal to 20% of the area of the film structure of the nanotube. [00〇7] Compared with the prior art, the carbon nanotube film bearing structure has the characteristics of simple structure, etc., the carbon nanotube film bearing structure is provided with a plurality of concave structures on the surface of a body, so that one nanometer is made When the carbon nanotube film structure is disposed on the surface of the carbon nanotube film bearing structure, the majority structure of the film obstructing the film structure is suspended by the recess structure, thereby greatly reducing the carbon nanotube The effective contact area of the membrane-like structure with the carbon nanotube-bearing structure, thereby reducing the van der Waals between the carbon nanotube membrane structure and the carbon nanotube membrane bearing structure Preservation and transfer of the membrane structure of the carbon nanotubes. 099137721 Form No. A0101 Page 4 / Total 27 Page 0992065765-0 201219294 [0008] The carbon nanotube film bearing film is directly carried in a TWO = method, by the - nano carbon loading region, thereby achieving The carbon nanotube membrane bearing method is simple and easy. (4) Preservation and transfer of the structure, [Embodiment] [0009] The following will be described in conjunction with the specific embodiment. DETAILED DESCRIPTION OF THE INVENTION [0010]
请參閲圖卜本發明第一實施例提供一種奈米碳管膜承載 結構1〇0 ’該奈米碳管臈承載結構·用於承載或仵護-奈米碳管舰結構，且該奈料料__所絲米 碳管膜承載频__後可完整地賴轉米碳管膜承 載結構100剝離。該奈东碳管膜承載結構1,00包括：一本 體110其中所述本體11〇具有一表面112，該表面m 上設置有-奈米碳管膜承載區域114。該奈米碳管膜承載 區域114用於承栽-奈米碳管膜狀結構。該奈米碳管膜承 載區域114具有複數個凹陷結構116。該複數個凹陷結構 116的總凹陷面積大於等於所述奈米碳管膜承載區域114 的面積的80%，從而使得將一奈米碳管膜狀結構設置於所 述奈米碳管膜承載區域114時’該奈米碳管膜狀結構與所 述本體110的有效接觸面積小於所述奈米碳管膜狀結構本 身面積的20%，使該奈米碳管膜狀結構可以完整地從該本 體110的表面112剝離。優選的，該複數個凹陷結構116 的總凹陷面積大於等於所述奈米碳管膜承載區域114的面 積的90%，從而使得將一奈米碳管膜狀結構設置於所述奈 米碳管膜承載區域114時，該奈米碳管膜狀結構與所述本 099137721 表單編號A0101 第5買/共27頁 0992065765-0 201219294 體11 0的有效接觸面積小於所述奈米碳管膜狀結構本身面 積的1 0%。 [0011] 所述本體110為具有一定強度的薄片狀結構，其形狀、尺 寸可依據實際需求設計。該本體110的材料可選自硬性或 具有一定強度的柔性材料。具體地，該本體110的材料選 自金屬、金屬氧化物、陶瓷、樹脂等材料。所述本體110 的表面112可以為平面、曲面或其他不規則面等。 [0012] 所述奈米碳管膜承載區域114可以為本體110的整個表面 112或者部分表面112。所述奈米碳管膜承載區域114包 括複數個相互間隔設置的凹陷結構116。該凹陷結構116 可以通過化學方法或物理方法形成於所述本體110的表面 112。該複數個凹陷結構116可以為微孔、凹槽或微孔與 凹槽的組合等結構。所述微孔可以為通孔或盲孔，該微 孔的橫截面的形狀不限於圓型，亦可以為方形、矩形、 橢圓形等其他規則或不規則的幾何形狀。所述凹槽可為 長條形或其他形狀。優選地，所述本體110的表面112形 成有複數個均勻分佈且間隔設置的微孔，該微孔的直徑 可以為100微米〜1毫米，相鄰的微孔之間的間距為10微 米〜100微米，該微孔的深度為1微米〜1毫米。可以理解 ，所述微孔亦可以採用其他不同結構的組合。只需滿足 所述微孔的直徑和間距的比值大於等於5 : 1，且所述微 孔的間距小於等於100微米，使得所述複數個凹陷結構 116的總凹陷面積大於等於所述奈米碳管膜承載區域114 的面積的80%，從而使得將一奈米碳管膜狀結構設置於所 述奈米碳管膜承載區域114時，該奈米碳管膜狀結構與所 099137721 表單編號Α0101 第6頁/共27頁 0992065765-0 201219294 =总米厌s膜承栽區域114的有效接觸面積小於所述奈求 結構12Q本身面積的2G%。優選的，所述微孔的 於等V::值大_0:1，且所述微孔的間距小 z、使彳于所述複數個凹陷結構11 Θ的總凹陷 面積大於等於所述奈米碳管膜承«域114的面積的^ ’從而使得將-奈米碳管膜狀結構設置於所述奈米碳管 膜承载區域114時，該奈米碳管膜狀结構與所述奈米碳管 Ο [0013] 膜承載區域114的有效接觸面積小於所述奈米碳管膜狀結 構120本身面積的1〇p 本實施例中*所述本趙11〇為一邊長為1〇cm的方形陽極氧 化鋁薄片。該陽極氧化鋁薄片為:通過陽極氧化法製備得 到。該陽極氧化鋁薄片具有複數個均勻分佈的微孔，相 鄰的微孔之間的距離約為50微米。所述微孔的直徑約為 500微米。Please refer to the first embodiment of the present invention to provide a carbon nanotube membrane bearing structure 1 〇 0 'the carbon nanotube 臈 bearing structure · for carrying or tampering - carbon nanotube ship structure, and the The material __ silky carbon tube film carrying frequency __ can be completely peeled off the carbon nanotube film bearing structure 100. The NEA film carrying structure 1,00 comprises: a body 110 wherein the body 11 has a surface 112 on which a carbon nanotube film bearing region 114 is disposed. The carbon nanotube film bearing region 114 is used for a bearing-nanocarbon tube film structure. The carbon nanotube film bearing region 114 has a plurality of recessed structures 116. The total recessed area of the plurality of recessed structures 116 is greater than or equal to 80% of the area of the carbon nanotube film bearing region 114, so that a carbon nanotube film structure is disposed on the carbon nanotube film bearing region. At 114 o'clock, the effective contact area of the carbon nanotube film structure with the body 110 is less than 20% of the area of the carbon nanotube film structure itself, so that the carbon nanotube film structure can be completely intact from the The surface 112 of the body 110 is peeled off. Preferably, the total recessed area of the plurality of recessed structures 116 is greater than or equal to 90% of the area of the carbon nanotube film bearing area 114, so that a carbon nanotube film structure is disposed on the carbon nanotubes. When the film bearing region 114, the effective contact area of the carbon nanotube film structure with the body of the 099137721 Form No. A0101 5th buy/total 27 page 0992065765-0 201219294 body 11 is smaller than the film structure of the carbon nanotube film 10% of its area. [0011] The body 110 is a sheet-like structure having a certain strength, and its shape and size can be designed according to actual needs. The material of the body 110 can be selected from a flexible material having a strength or strength. Specifically, the material of the body 110 is selected from the group consisting of metals, metal oxides, ceramics, resins, and the like. The surface 112 of the body 110 may be a flat surface, a curved surface or other irregular surface or the like. [0012] The carbon nanotube film bearing region 114 may be the entire surface 112 or a portion of the surface 112 of the body 110. The carbon nanotube film bearing region 114 includes a plurality of recessed structures 116 that are spaced apart from each other. The recessed structure 116 can be formed on the surface 112 of the body 110 by chemical or physical means. The plurality of recessed structures 116 may be micropores, grooves or a combination of microvias and grooves. The micropores may be through holes or blind holes, and the shape of the cross section of the micro holes is not limited to a circular shape, and may be other regular or irregular geometric shapes such as a square, a rectangle, an ellipse or the like. The groove may be elongated or otherwise shaped. Preferably, the surface 112 of the body 110 is formed with a plurality of uniformly distributed and spaced micropores, the micropores may have a diameter of 100 micrometers to 1 millimeter, and the spacing between adjacent microholes is 10 micrometers to 100 millimeters. The micropores have a depth of 1 micrometer to 1 millimeter. It will be understood that the micropores may also be combined with other different structures. It suffices that the ratio of the diameter and the pitch of the micropores is greater than or equal to 5:1, and the pitch of the micropores is less than or equal to 100 micrometers, so that the total recessed area of the plurality of recessed structures 116 is greater than or equal to the nanocarbon. 80% of the area of the tubular membrane bearing region 114, such that when a carbon nanotube membrane structure is disposed in the carbon nanotube membrane bearing region 114, the carbon nanotube membrane structure and the 099137721 form number Α 0101 Page 6 of 27 0992065765-0 201219294 = The effective contact area of the total rice smear bearing area 114 is less than 2G% of the area of the native structure 12Q itself. Preferably, the micropore has a value of _0:1, and the pitch of the microholes is small, so that the total recessed area of the plurality of recessed structures 11 大于 is greater than or equal to the When the carbon nanotube film receives the area of the domain 114 such that the film-like structure of the carbon nanotube film is disposed in the carbon nanotube film bearing region 114, the carbon nanotube film structure and the nai The carbon nanotube Ο [0013] The effective contact area of the membrane-bearing region 114 is less than 1 〇p of the area of the carbon nanotube membrane-like structure 120. In this embodiment, the 〇11〇 is one side and the length is 1 〇cm. Square anodized aluminum flakes. The anodized aluminum flakes were obtained by anodizing. The anodized aluminum foil has a plurality of uniformly distributed micropores, and the distance between adjacent micropores is about 50 microns. The micropores have a diameter of about 500 microns.
[0014] G 請參閱圖2 ’本發明第二實施例提供一種奢来碳管膜承載 結構200，該奈米碳管膜承載結構200用於承載或保護一 奈米碳管膜狀結構，且該奈米碳;管膜狀結構與所述奈米 碳管膜承載結構200接觸後可完整地從該奈米碳管膜承載 結構200剝離。所述奈米碳管膜承載結構200包括：一本 體210 ’其中，所述本體21〇具有一表面212，該表面212 上設置有一奈米碳管膜承載區域214 °該奈米碳管膜承載 區域214用於承載一奈米碳管膜狀結構°該奈米碳管膜承 載區域214具有複數個凹陷結構216。該複數個凹陷結構 216的總凹陷面積大於等於所述奈米碳管膜承載區域214 的面積的80% ’從而使得將一奈米礙管膜狀結構設置於所 099137721 表單編號A0101 第7頁/共27頁 0992065765-0 201219294 述奈米碳官膜承載區域214時，該奈米碳管膜狀結構與所 述本體210的有效接觸面積小於所述奈米碳管膜狀結構本 身面積的20%，該奈米碳管膜狀結構可以完整地從該本體 210的表面212剝離。優選的，該複數個凹陷結構216的 總凹陷面積大於等於所述奈米碳管膜承載區域214的面積 的9 0 %，從而使得將一奈米礙管膜狀結構設置於所述奈米 碳管膜承載區域214時’該奈米碳管膜狀結構與所述本體 210的有效接觸面積小於所述奈米碳管膜狀結構本身面積 的 10%。 [0015] 本實施例中’所述本體210爲具有一定強度的陶瓷薄片。 所述奈米碳管膜承載區域214為所述陶竞薄.片的部分表面 。所述奈米碳管膜承載區域214包括複數個凹槽216。該 複數個凹槽216均勻分佈且相互平行間隔設置。該凹槽 21 6可以通過化學方法或物理方法形成於所述本體21〇的 表面212。該凹槽216的寬度可以為1〇〇微米〜1毫米，相 鄰的凹槽216之間的間距為1〇微米〜loo凌米。所述凹槽 216的深度為1微米〜1毫米。可以理解，形成在所述本體 210的表面212的複數個凹槽216亦可以採用其他不同結 構的組合。只需滿足所述凹槽216的寬度和間距的比值大 於等於5 : 1 ’且所述凹槽21 6的間距小於等於1 〇 〇微米， 使得所述複數個凹槽216的總凹陷面積大於等於所述奈米 碳管膜承載區域214的面積的80%，從而使得將一奈米碳 管膜狀結構設置於所述奈米碳管膜承載區域214時，該奈 米碳管膜狀結構與所述奈米碳管膜承載區域214的有效接 觸面積小於所述奈米碳管膜狀結構本身面積的20%。優選 099137721 表單編號A0101 第8頁/共27頁 0992065765-0 201219294 的，所述凹槽的寬度和間距的比值大於等於: 1，且所 述凹槽的間距小於等於1〇〇微米，使得所述複數個凹槽 116的總凹陷面積大於等於所述奈米碳管膜承載區域214 的面積的90%，從而使得將—奈米碳管膜狀結構設置於所 述奈求碳管膜承載區域214時，該奈采碳管膜狀結構與所 述奈米碳管膜承載區域214的有效接觸面積小於所述奈米 碳管膜狀結構本身面積的1〇%。 [0016] Ο[0014] Please refer to FIG. 2, a second embodiment of the present invention provides a luxury carbon nanotube film bearing structure 200 for carrying or protecting a carbon nanotube film structure, and The nanocarbon; the tubular film structure is completely peeled off from the carbon nanotube film bearing structure 200 after being in contact with the carbon nanotube film bearing structure 200. The carbon nanotube film bearing structure 200 includes: a body 210', wherein the body 21 has a surface 212, and the surface 212 is provided with a carbon nanotube film bearing region 214 °. The carbon nanotube film bearing The region 214 is for carrying a carbon nanotube film structure. The carbon nanotube film bearing region 214 has a plurality of recess structures 216. The total recessed area of the plurality of recessed structures 216 is greater than or equal to 80% of the area of the carbon nanotube film bearing region 214 such that a nano-membrane structure is disposed at 099137721, Form No. A0101, page 7 / 27 pages 0992065765-0 201219294 When the carbon carbon film bearing region 214 is described, the effective contact area of the carbon nanotube film structure with the body 210 is less than 20% of the area of the carbon nanotube film structure itself. The carbon nanotube film structure can be completely peeled off from the surface 212 of the body 210. Preferably, the total recessed area of the plurality of recessed structures 216 is greater than or equal to 90% of the area of the carbon nanotube film bearing region 214, so that a nano-membrane structure is disposed on the nanocarbon. When the film bearing region 214 is 'the effective contact area of the carbon nanotube film structure with the body 210 is less than 10% of the area of the carbon nanotube film structure itself. [0015] In the present embodiment, the body 210 is a ceramic sheet having a certain strength. The carbon nanotube film bearing region 214 is a part of the surface of the ceramic tile. The carbon nanotube film bearing region 214 includes a plurality of grooves 216. The plurality of grooves 216 are evenly distributed and spaced apart from each other. The recess 21 6 may be formed on the surface 212 of the body 21 by chemical or physical means. The width of the recess 216 may be 1 〇〇 micrometer to 1 mm, and the spacing between adjacent recesses 216 is 1 〇 micrometer to loo. The groove 216 has a depth of 1 μm to 1 mm. It will be understood that the plurality of grooves 216 formed in the surface 212 of the body 210 may also be a combination of other different configurations. It is only required that the ratio of the width and the pitch of the groove 216 is greater than or equal to 5: 1 ' and the pitch of the groove 21 6 is less than or equal to 1 〇〇 micrometer, so that the total concave area of the plurality of grooves 216 is greater than or equal to The carbon nanotube film bearing region 214 has an area of 80%, such that when a carbon nanotube film structure is disposed on the carbon nanotube film bearing region 214, the carbon nanotube film structure and The effective contact area of the carbon nanotube film bearing region 214 is less than 20% of the area of the carbon nanotube film structure itself. Preferably, the ratio of the width and the pitch of the groove is greater than or equal to: 1, and the pitch of the grooves is less than or equal to 1 〇〇 micrometer, so that the groove is less than or equal to 1 〇〇 micrometer, so that the groove is less than or equal to 1 μm. The total recessed area of the plurality of grooves 116 is greater than or equal to 90% of the area of the carbon nanotube film bearing region 214, so that the carbon nanotube film structure is disposed in the carbon nanotube film bearing region 214. The effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing region 214 is less than 1% of the area of the carbon nanotube film structure itself. [0016] Ο
GG
[0017] 明參閱圖3 ’本發明進一步提供—種所述奈米碳管膜承載 結構100的使用方法，該方法主要包括以下步驟：（S101 )提供至少一奈米碳營膜承載結構，所述奈米碳管膜承 載結構包括一本體，所述本艘具:有一表面，該表面具有 一奈米碳管膜承載區域，該奈米碳營1膜承載區域具有複 數個凹陷結構，所述複數個凹陷結構的總凹陷面積大於 等於所述奈米碳管膜承載區域面積的80%; (S102)提供 一奈米碳管膜狀結構；以及（S103)將所述奈米碳管膜 狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管 膜承載區域，所述奈来碳管膜散結構與所述奈米碳管膜 承栽結構的有效接觸面積小於所述奈米碳管膜狀結構本 身面積的20%。 步驟S101，提供至少一奈米碳管膜承載結構，所述奈米 碳管膜承載結構包括一本體，所述本體具有一表面，該 表面具有一奈米碳管膜承載區域，該奈米碳管膜承載區 域具有複數個凹陷結構，所述複數個凹陷結構的總凹陷 面積大於等於所述奈米破管膜承載區域的面積的8〇%。 [0018] 099137721 所述奈米碳管犋承載結構為本發明 表單编號A0101 第9頁/共27頁 第一實施例所提供的 0992065765- 201219294 奈来碳官膜承載結構1 G〇。可以理解，所述奈米碳管膜承 載結構亦可以為本發明第二實施例所提供的奈米碳管膜 承載結構200或其他結構。 [0019] [0020] [0021] [0022] 膜狀結構。 步驟S102，提供一奈米碳管 提供一奈米碳管膜狀結構12()，所述奈米碳管膜狀結構 120包括至少一個奈米碳管膜。該奈米碳管膜可以係奈米 碳m奈米碳管絮化膜或奈米碳管礙壓嫉等。 。月參見圖4 ’所述奈米碳管拉膜為從—奈米破管陣列中直 接拉取獲得的整體結構。該奈米碳管拉膜係由複數個奈 米石反管組成的自支撐結構。所述自支撐結構係指該奈米 炭s拉膜可無需基底支撑’自支撐存在。所述複數個奈 米碳管基本沿同-方向擇優取向延伸、所述擇優取向係 指在奈米碳管拉膜中大多數奈米碳管的整體延伸方向基 本朝同-方向。而且’所述大多數奈米碳管的整體延伸 方向基本平行於所述奈米轉拉麟L進一步地， 所述奈米碳管拉膜巾多數奈_管係驗凡得瓦力首 相連並且基本沿同-方向延伸^述奈米碳管拉膜及其 製備方法請參見圖年2月12日申請的，2㈣年了叫曰 公告的’公告號為tw I327m的台灣發明專利申請公開 說明書。 所述奈米碳管礙顏包括％分佈的奈求碳管，該夺米 碳管無序，沿同—方向或不同方向擇優取向排列。請參 見圖5 ’優選地’所述奈米碳管碾壓膜中的奈米碳管基本 沿同-方向延伸且平行於該奈米碳管礙壓膜的表面。所 099137721 表單編號Α0101 第10頁/共27頁 0992065765-0 201219294 述奈米碳管碾壓膜中的奈米碳管相互交疊。所述奈米碳 管碾壓膜中奈米碳管之間通過凡得瓦力相互吸引，緊密 結合，使得該奈米碳管碾壓膜具有很好的柔韌性，可以 彎曲折疊成任意形狀而不破裂。所述奈米碳管碾壓膜及 其製備方法請參見2009年1月1日公開的，公開號為 TW200900348的台灣發明專利申請公開說明書。 [0023] 請參見圖6，所述奈米碳管絮化膜包括相互纏繞的奈米碳 管。該奈米碳管之間通過凡得瓦力相互吸引、纏繞，形 成網路狀結構。所述奈米碳管絮化膜各向同性。所述奈 米碳管絮化膜中的奈米碳管為均勻分佈，無規則排列。 所述奈米碳管絮化膜及其製備方法請參見2008年11月16 日公開的，公開號為TW200844041的台灣發明專利申請 公開說明書。 [0024] 本實施例中，所述奈米碳管膜狀結構120包為一奈米碳管 拉膜，該奈米碳管拉膜為從一奈米碳管陣列中直接拉取 獲得，其製備方法具體包括以下步驟： [0025] 首先，提供一形成於一生長基底的奈米碳管陣列，該陣 列為超順排的奈米碳管陣列。 [0026] 所述超;啥排的奈米碳管陣列採用化學氣相沉積法製備， 該超順排奈米碳管陣列的製備方法可參見台灣專利公告 第TW 1303239號。該超順排的奈米碳管陣列為複數個彼 此平行且垂直於生長基底生長的奈米碳管形成的純奈米 碳管陣列。通過控制生長條件，該超順排的奈米碳管陣 列中基本不含有雜質，如無定型碳或殘留的催化劑金屬 099137721 表單編號A0101 第11頁/共27頁 0992065765-0 201219294 顆粒等，適於從中拉取奈米碳管膜。本發明實施例提供 的奈米碳管陣列為多壁奈米碳管陣列。所述奈米碳管的 直徑為0. 5〜50奈米，長度為50奈米〜5毫米。本實施例中 ，奈米碳管的長度優選為100微米~900微米。 [0027] 其次，採用一拉伸工具從所述奈米碳管陣列中拉取奈米 碳管獲得一奈米碳管膜，其具體包括以下步驟：（a)從 所述超順排奈米碳管陣列中選定一個或具有一定寬度的 複數個奈米碳管，本實施例優選為採用具有一定寬度的 膠帶接觸奈米碳管陣列以選定一個或具有一定寬度的複 數個奈米碳管；（b)以一定速度拉伸該選定的奈米碳管 ，從而形成首尾相連的複數個奈米碳管片段，進而形成 一連續的奈米碳管拉膜。該拉取方向沿基本垂直於奈米 碳管陣列的生長方向。 [0028] 在上述拉伸過程中，該複數個奈米碳管片段在拉力作用 下沿拉伸方向逐漸剝離生長基底的同時，由於該複數個 奈米碳管片段之間凡得瓦力的作用，該選定的複數個奈 米碳管片段分別與其他奈米碳管片段首尾相連地連續地 被拉出，從而形成一連續、均勻且具有一定寬度的奈米 碳管拉膜。所述奈米碳管拉膜中的奈米碳管包括單壁奈 米碳管、雙壁奈米碳管及多壁奈米碳管中的一種或多種 。該奈米碳管拉膜具有較大的比表面積，故該奈米碳管 拉膜宏觀上表現出較大的黏性。 [0029] 步驟S103，將所述奈米碳管膜狀結構直接設置於所述奈 米碳管膜承載結構的奈米碳管膜承載區域，所述奈米碳 管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積 099137721 表單編號A0101 第12頁/共27頁 0992065765-0 201219294 [0030] 】於所述奈米碳管膜狀結構本身面積的20% β ^ = 7 ’將所述奈米碳管膜狀結構⑵設置於所述奈 二反、承栽結構1GG的奈米碳管膜承栽區域114，該夺 X碳管膜狀結構12G在所述奈米碳管膜承載區域U4中的 複數個凹陷結構116處懸空設置。 [0031] Ο[0017] Referring to FIG. 3, the present invention further provides a method for using the carbon nanotube film bearing structure 100, which mainly includes the following steps: (S101) providing at least one nanocarbon film bearing structure, The carbon nanotube film carrying structure comprises a body, the ship has a surface having a carbon nanotube film bearing region, and the nanocarbon camping film bearing region has a plurality of recessed structures, The total recessed area of the plurality of recessed structures is greater than or equal to 80% of the area of the carbon nanotube film bearing area; (S102) providing a carbon nanotube film structure; and (S103) forming the carbon nanotube film The structure is directly disposed on the carbon nanotube film bearing region of the carbon nanotube film bearing structure, and the effective contact area between the carbon nanotube film bulk structure and the nano carbon tube film bearing structure is smaller than the nai The carbon nanotube film structure itself is 20% of the area. Step S101, providing at least one carbon nanotube film bearing structure, the carbon nanotube film supporting structure comprising a body, the body having a surface having a carbon nanotube film bearing region, the nano carbon The tubular film bearing region has a plurality of recessed structures, and the total recessed area of the plurality of recessed structures is greater than or equal to 8〇% of the area of the nanocapsule membrane bearing region. [0018] 099137721 The carbon nanotube load-bearing structure is the present invention Form No. A0101 Page 9 of 27 The first embodiment provides the 0992065765-201219294 Nilai carbon film bearing structure 1 G〇. It can be understood that the carbon nanotube film supporting structure can also be the carbon nanotube film bearing structure 200 or other structure provided by the second embodiment of the present invention. [0022] [0022] A film-like structure. Step S102, providing a carbon nanotube to provide a carbon nanotube film structure 12 (), the carbon nanotube film structure 120 comprising at least one carbon nanotube film. The carbon nanotube film can be a nano carbon carbon nanotube flocculation membrane or a carbon nanotube barrier. . Referring to Figure 4, the carbon nanotube film is a monolithic structure obtained by directly pulling from a nanotube array. The carbon nanotube film is a self-supporting structure composed of a plurality of nano-reverse tubes. The self-supporting structure means that the nano-carbon slab can be self-supported without substrate support. The plurality of carbon nanotubes extend substantially in the same direction in the same direction, and the preferred orientation means that the overall extension direction of most of the carbon nanotubes in the carbon nanotube film is substantially in the same direction. Moreover, the overall extension direction of the majority of the carbon nanotubes is substantially parallel to the nano-Tenlin L, and the majority of the carbon nanotube-coated membranes are connected to each other and Basically extending in the same direction and extending the carbon nanotube film and its preparation method, please refer to the Taiwan invention patent application publication specification of the announcement number tw I327m, which was filed on February 12 of the same year. The carbon nanotubes of the carbon nanotubes include a carbon nanotube having a % distribution, and the carbon nanotubes are disordered and arranged in the same direction or in different directions. Referring to Fig. 5', preferably, the carbon nanotubes in the carbon nanotube rolled film extend substantially in the same direction and parallel to the surface of the carbon nanotube film. 099137721 Form No. Α0101 Page 10 of 27 0992065765-0 201219294 The carbon nanotubes in the carbon nanotube rolled film overlap each other. The carbon nanotubes in the carbon nanotube film are attracted to each other by van der Waals force, and the carbon nanotubes have good flexibility and can be bent and folded into any shape. Does not break. The carbon nanotube rolled film and the preparation method thereof are described in the Taiwan Patent Application Publication No. TW200900348, which is published on Jan. 1, 2009. [0023] Referring to FIG. 6, the carbon nanotube flocculation membrane comprises intertwined carbon nanotubes. The carbon nanotubes are attracted and entangled by van der Waals forces to form a network structure. The carbon nanotube flocculation membrane is isotropic. The carbon nanotubes in the carbon nanotube flocculation membrane are uniformly distributed and arranged irregularly. The carbon nanotube flocculation film and the preparation method thereof are described in the Taiwan Patent Application Publication No. TW200844041, which is published on Nov. 16, 2008. [0024] In this embodiment, the carbon nanotube film structure 120 is a carbon nanotube film, and the carbon nanotube film is directly drawn from a carbon nanotube array. The preparation method specifically includes the following steps: [0025] First, an array of carbon nanotubes formed on a growth substrate, which is a super-aligned array of carbon nanotubes, is provided. [0026] The super-tantalum carbon nanotube array is prepared by chemical vapor deposition, and the preparation method of the super-sequential carbon nanotube array can be referred to Taiwan Patent Publication No. TW 1303239. The super-aligned carbon nanotube array is a plurality of pure carbon nanotube arrays formed of carbon nanotubes that are parallel to each other and grown perpendicular to the growth substrate. By controlling the growth conditions, the super-aligned carbon nanotube array contains substantially no impurities, such as amorphous carbon or residual catalyst metal. 099137721 Form No. A0101 Page 11 of 27 0992065765-0 201219294 Particles, etc., suitable for Pull the carbon nanotube film from it. The carbon nanotube array provided by the embodiment of the present invention is a multi-walled carbon nanotube array. The carbon nanotubes have a diameter of 0.5 to 50 nm and a length of 50 nm to 5 mm. In this embodiment, the length of the carbon nanotubes is preferably from 100 μm to 900 μm. [0027] Next, a carbon nanotube film is obtained by pulling a carbon nanotube from the carbon nanotube array by using a stretching tool, which specifically includes the following steps: (a) from the super-shunned nano tube Selecting one or a plurality of carbon nanotubes having a certain width in the carbon tube array, in this embodiment, preferably contacting the carbon nanotube array with a tape having a certain width to select one or a plurality of carbon nanotubes having a certain width; (b) stretching the selected carbon nanotubes at a rate to form a plurality of carbon nanotube segments connected end to end, thereby forming a continuous carbon nanotube film. The pull direction is substantially perpendicular to the growth direction of the carbon nanotube array. [0028] During the above stretching process, the plurality of carbon nanotube segments gradually peel off the growth substrate in the stretching direction under the action of tension, and the effect of the vanadium force between the plurality of carbon nanotube segments The selected plurality of carbon nanotube segments are continuously pulled out end to end with the other carbon nanotube segments, thereby forming a continuous, uniform and a certain width of the carbon nanotube film. The carbon nanotubes in the carbon nanotube film include one or more of a single-walled carbon nanotube, a double-walled carbon nanotube, and a multi-walled carbon nanotube. The carbon nanotube film has a large specific surface area, so that the carbon nanotube film exhibits a large viscosity on a macroscopic basis. [0029] Step S103, the film structure of the carbon nanotubes is directly disposed on a carbon nanotube film bearing region of the carbon nanotube film bearing structure, and the carbon nanotube film structure and the nai Effective contact area of the carbon nanotube film bearing structure 099137721 Form No. A0101 Page 12 of 27 0992065765-0 201219294 [0030] The area of the film structure of the carbon nanotubes itself is 20% β ^ = 7 ' The carbon nanotube film-like structure (2) is disposed on the carbon nanotube film bearing region 114 of the nano-reverse and bearing structure 1GG, and the carbon nanotube film-like structure 12G is on the carbon nanotube film A plurality of recessed structures 116 in the load-bearing area U4 are suspended. [0031] Ο
G :以理解’由於所述本體no的表面112具有複數個凹陷 =構116 ’且該凹陷結構116的總凹陷面積大於等於所述 奈^碳管媒承載區域114的面積物％，因此，將所述奈 米碳管膜狀結構12G設置在所述奈米碳管膜承載區域ιΐ4 時，該奈米碳管膜狀結構12p與所述本體11〇表面ιΐ2的 有效接觸面積小於所述奈祕管職結構120本身面積的 20%，從而降低該奈米碳管膜狀結構12〇與該本體〗^的 表面112之間的凡得瓦力’使該奈米碳管膜狀結構12〇與 该本體110的表面112之間的凡得瓦力小於所述奈米碳管 膜狀結構120令複數個奈米碳管之間凡得瓦力。因此，將 所述奈米碳管膜狀結構120設置於所述奈米碳管膜承載結 構100時，由於所述奈米碳管膜狀結構120與所述本體 110表面112之間的凡得瓦力小於所述奈米碳管膜狀結構 120中複數個奈米碳管之間的凡得瓦力，從而使該奈米碳 管膜狀結構120可以容易地從所述本體11〇的表面112剝 離’而不至於破壞該奈米碳管膜狀結構12()的形態和結構 ，從而實現了該奈米碳管膜狀結構丨2〇的保存和轉移。 本實施例中’將一奈米碳管拉膜設置於所述陽極氡化鋁 薄片的表面時，該奈米碳管拉膜的大部分結構懸空設置 於所述陽極氧化鋁薄片表面的複數個微孔處，從而使所 099137721 表單編號A0101 第13頁/共27頁 0992065765-0 [0032] 201219294 述不米兔管拉膜與所述陽拖氧化銘薄片的有效接觸面積 小於所述奈米碳管拉膜本身面積的1〇%，進而降低該奈米 石反管拉膜與該陽極氧化鋁薄片的表面之間的凡得瓦力， 使该奈米碳管拉膜與該陽極氧化鋁薄片的表面之間的凡 知瓦力小於所述奈米碳管杈膜中複數個奈米碳管之間凡 得瓦力。因此，將所述奈米碳管拉膜設置於所述陽極氧 化鋁薄片的表面時，由於所述奈米碳管拉膜與所述陽極 氧化鋁薄片的表面之間的凡得瓦力小於所述奈米碳管拉G: to understand 'because the surface 112 of the body no has a plurality of depressions = structure 116' and the total depression area of the recessed structure 116 is greater than or equal to the area % of the carbon nanotube-bearing region 114, therefore, When the carbon nanotube film structure 12G is disposed in the carbon nanotube film bearing region ιΐ4, the effective contact area of the carbon nanotube film structure 12p with the surface ΐ2 of the body 11 is smaller than the secret 20% of the area of the pipe structure 120 itself, thereby reducing the van der Waals between the carbon nanotube film structure 12 〇 and the surface 112 of the body 〖 to make the carbon nanotube film structure 12 〇 The van der Waals force between the surfaces 112 of the body 110 is less than the carbon nanotube film structure 120 to create a wattage between the plurality of carbon nanotubes. Therefore, when the carbon nanotube film structure 120 is disposed on the carbon nanotube film bearing structure 100, due to the difference between the carbon nanotube film structure 120 and the surface 112 of the body 110 The tile force is smaller than the van der Waals force between the plurality of carbon nanotubes in the carbon nanotube film structure 120, so that the carbon nanotube film structure 120 can be easily smashed from the surface of the body 11 112 peeling 'does not destroy the morphology and structure of the carbon nanotube film structure 12 (), thereby realizing the preservation and transfer of the carbon nanotube film structure 丨2〇. In the present embodiment, when a carbon nanotube film is placed on the surface of the anodized aluminum foil, most of the structure of the carbon nanotube film is suspended on the surface of the anodized aluminum foil. The micropores, so that the 099137721 Form No. A0101 Page 13 / Total 27 Page 0992065765-0 [0032] 201219294 The effective contact area of the non-male rabbit tube film and the Yangtuo oxidation sheet is smaller than the nano carbon The tube is pulled by 1% of the area of the membrane itself, thereby reducing the van der Waals force between the nanometer tube and the surface of the anodized aluminum sheet, so that the carbon nanotube film and the anodized aluminum sheet are The wattage between the surfaces of the carbon nanotubes is less than the van der Waals between the plurality of carbon nanotubes in the carbon nanotube film. Therefore, when the carbon nanotube film is disposed on the surface of the anodized aluminum foil, the van der Waals force between the carbon nanotube film and the surface of the anodized aluminum foil is smaller than Nano carbon tube pull
膜中複數個奈米碳管之間的凡得瓦力，從而使該奈米碳 管拉膜可以容易地從所述陽麵氧化铭薄片的表面剝離， 而不至於破壞該奈米碳管拉啤的形態和結構，從而實現 了該奈米碳管拉膜的保存和轉移。 [0033] [0034] 可以理解，當所述奈米破管膜狀結構包括複數個奈米碳 管膜時，該複數個奈米破管膜可以層疊設置或並排設置 於所述奈米碳管膜承載—。具體地，將所述奈米碳管 膜設置於所述奈米碳管嫉承載區_’可以進一步將另 -奈米碳管膜覆蓋至先前的奈米碳賴表面’如此反復 多次，在該奈米碳管膜承載區域上铺設複數個奈米碳管 膜。此外，倾述奈#㈣承載區域具有較大的面積 時’將所述奈米碳管膜^個方向設置於所述奈求碳管 膜承載區域後，還可以將另，奈㈣管膜並排設置於所 述奈米碳«承載《以鮮奈祕管膜的區域。可 以理解，該步驟為可選少驟。 此外，將所述奈㈣管神结搆直接設置於所述奈米石炭 管膜承載結構的奈«管媒承載區域後，可以進一步將a van der Waals force between the plurality of carbon nanotubes in the film, so that the carbon nanotube film can be easily peeled off from the surface of the oxidized sheet, without destroying the carbon nanotube The morphology and structure of the carbon nanotube film are preserved and transferred. [0034] It can be understood that when the nano-tube-shaped membrane structure comprises a plurality of carbon nanotube membranes, the plurality of nano-barrel membranes may be stacked or arranged side by side on the carbon nanotubes. Membrane bearing -. Specifically, the carbon nanotube film is disposed in the carbon nanotube support region _', and the other carbon nanotube film may be further covered to the previous nanocarbon surface. A plurality of carbon nanotube films are laid on the carbon nanotube film bearing area. In addition, when the dumping Nai (4) bearing area has a large area, 'the carbon nanotube film is disposed in the direction of the carbon nanotube film bearing area, and the other (four) tube film can be arranged side by side. It is disposed in the area where the nanocarbon «bears the membrane of the fresh navel. It can be understood that this step is optional. In addition, after the na[iota] tube structure is directly disposed on the nano-tube carrier bearing area of the nano-carboniferous membrane supporting structure, the
099137721 表單編號Α0101 第14真，共27頁 0992065765-0 201219294 Ο 另一奈米礙管膜承載結構覆蓋在所述奈来碳 的表面，並使所述另-奈米碳管料栽結構巾的奈^碳 管膜承載區域與所述奈米碳管膜狀結構相接觸，形成一 兩邊為奈米碳管膜承載結構，中間為奈米碳管膜的爽心 結構。在所述夾心結構中’所述奈以管膜I结構挾持 於兩個奈米碳管膜承載結構的中間，使奈米碳管膜狀結 構位於兩個奈米碳管膜承載結構具有凸起結構的表面之 間，並分別與兩個奈米碳管膜承載結構具有凸起結構的 表面接觸，使所述奈祕管膜狀結構可以更牢固地被固 定，從而使該奈米磷管膜狀結構可以更為容易的保存和 轉移。此外，該夹心結構還可㈣所迷奈老碳管膜狀結 構不受到破壞’以及具有防塵等作用。 [0035] 本發明實施例提供的奈米碳管膜承載結構具有結構簡單 、成本較低等特點。該奈米碳管膜承栽結構通過在一本 體的表面設置複數個凹陷結構，使得將一奈米破管膜狀 結構設置於所述奈米碳管膜承載結構表南時，該奈米碳 ：! ❹ 管膜狀結構的大部分結構通過所述凹陷結構懸空設置， 從而大大地滅少了所述奈米碳管膜狀結構與所述奈米碳 管膜承載結構的有效接觸面積，進而降低了所述奈米碳 管膜狀結構與所述奈米碳管膜承載結構之間的凡得瓦力 ，最後實現奈米礙官'膜狀結構的保存和轉移。 [0036] 本發明實施例所述奈米碳管膜承載結構的使用方法，通 過將一奈米碳管膜狀結構直接承載於一奈米碳管膜承載 結構的奈米碳管膜承裁區域，從而實現奈米碳管膜狀結 構的保存和轉移’該方法簡單易行。此外，將另一奈米 099137721 表單蹁號Α0Ι01 第15頁/共27頁 0992065765-0 201219294 [0037] [0038] [0039] 反&膜承載結構覆蓋在所述承载於— 構中的太不水碳®膜承載結 管膜構的表面’形成-兩側為奈米碳 太栽、、，。構中間為奈米碳管膜狀結構的夾心結構。所 中礙管膜狀結構挾持於兩個奈米碳管料载結構的 曰’使該奈米碳管膜狀結構更牢固地被固定。 結構還可以使所述奈米碳管膜狀結構不受到外界 作用力的破壞，還具有防塵等作用。 综上所述，本發料已符合發明專利之要件，遂依 出專利中請。^上⑽者麵本發歡較佳實施例 ’自不能以此限制本案之巾請專利範園^舉凡習知本案 技藝之人士援依本發明之精神所作之等效修飾或⑹卜、 皆應涵蓋於以下申請專利範圍内。 【圖式簡單說明】 圖1為本發明第-實施例所提供的奈米碳管膜承載結構 的示意圖。 圖2為本發明第二實施例所提供的麵碳管膜承栽結構 的示意圖。 [0040] @3為應用本發明實施例提供的奈米礙管膜承载結構承 載奈米碳管膜狀結構的流程圖。 [0041] 圖4為應#發明實施例提供的奈米碳管膜承载結構承 載的奈米碳管拉膜的SEM照片。 [0042] 圖5為_本發明實施例提供的奈以管膜承栽結構承 載的奈米碳管碾壓膜的SEM照片。 099137721 圖6為應用本發明實施提供的奈米唆營胺灰恭姓 表單煸號A0101 第16頁/共27頁 ％ 構承載 0992065765-0 [0043] 201219294 [0044] 的奈米碳管絮化膜的SEM照片。 圖7為應用本發明實施例提供的奈米碳管膜承載結構承 載一奈米碳管膜狀結構的示意圖。 [0045] 【主要元件符號說明】 奈米碳管膜承載結構：100 ; 200 [0046] 本體：110 ; 210 [0047] 表面：112 ; 212 ❹ [0048] 奈米碳管膜承載區域：114 ; 214 9 [0049] 凹陷結構：116 ; 216 [0050] 奈米碳管膜狀結構：120 099137721 表單編號A0101 第17頁/共27頁 0992065765-0099137721 Form No. 1010101 14th true, 27 pages 0992065765-0 201219294 另一 Another nano-membrane bearing structure covers the surface of the naf carbon and makes the other-nano carbon nanotube material The bearing region of the carbon nanotube film is in contact with the film structure of the carbon nanotube, and forms a carbon nanotube film bearing structure on both sides, and the center is a smooth structure of the carbon nanotube film. In the sandwich structure, the na[iota] structure is held in the middle of the two carbon nanotube film-bearing structures, so that the nano-carbon tube film-like structure has protrusions on the two carbon nanotube film-bearing structures. Between the surfaces of the structure, and respectively contact with the surface of the two carbon nanotube film bearing structures having a convex structure, so that the mesenteric membrane structure can be more firmly fixed, thereby making the nanophosphor film The structure can be more easily preserved and transferred. In addition, the sandwich structure can also be used to prevent the membrane structure of the carbon tube from being damaged and having dustproof effects. [0035] The carbon nanotube film bearing structure provided by the embodiment of the invention has the characteristics of simple structure, low cost and the like. The carbon nanotube film bearing structure is provided with a plurality of recessed structures on a surface of a body such that a nanometer tube-breaking membrane structure is disposed on the surface of the carbon nanotube membrane supporting structure, the nanocarbon :! Most of the structure of the tubular membrane structure is suspended by the recessed structure, thereby greatly eliminating the effective contact area of the carbon nanotube membrane structure and the carbon nanotube membrane supporting structure, thereby further The van der Waals force between the film structure of the carbon nanotubes and the carbon nanotube film bearing structure is reduced, and finally the preservation and transfer of the film structure of the nanometer is achieved. [0036] The method for using the carbon nanotube film bearing structure according to the embodiment of the present invention, by directly carrying a carbon nanotube film structure on a carbon nanotube film bearing area of a carbon nanotube film bearing structure In order to achieve the preservation and transfer of the membrane structure of the carbon nanotubes, the method is simple and easy. In addition, another nano 099137721 form nickname Ι0Ι01 page 15 / total 27 page 0992065765-0 201219294 [0037] [0039] The anti-film bearing structure covers the bearing in the structure too The water-carbon® membrane carries the surface of the junction membrane structure's formation - both sides are nano-carbon too planted, and. The sandwich structure in the middle of the membrane structure of the carbon nanotubes. The film structure of the two nanotubes is supported by the 曰' of the two carbon nanotubes, so that the film structure of the carbon nanotubes is more firmly fixed. The structure can also prevent the film structure of the carbon nanotube from being damaged by external forces and also have the function of dust prevention. In summary, the issue has met the requirements of the invention patent, and please refer to the patent. ^上(10)者本本发好实施实施例 'There is no way to limit the case of the case. Please use the patent paradigm. Anyone who knows the skill of the case can use the equivalent modification of the spirit of the invention or (6) It is covered by the following patent application. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a carbon nanotube film bearing structure provided by a first embodiment of the present invention. Fig. 2 is a schematic view showing a carbon nanotube film bearing structure according to a second embodiment of the present invention. [0040] @3 is a flow chart for loading a nanocarbon tube membrane-like structure using the nano tube film carrying structure provided by the embodiment of the present invention. 4 is a SEM photograph of a carbon nanotube film carried by a carbon nanotube film supporting structure provided by an embodiment of the invention. [0042] FIG. 5 is a SEM photograph of a carbon nanotube rolled film carried by a tubular film bearing structure according to an embodiment of the present invention. 099137721 FIG. 6 is a view of a nano carbon tube flocculation film provided by the application of the present invention, which is provided by the embodiment of the present invention. The nickname A0101, page 16 of 27%, the structure of the carrier, 0992065765-0 [0043] 201219294 [0044] SEM photo. Fig. 7 is a schematic view showing the application of a carbon nanotube film supporting structure according to an embodiment of the present invention to a film structure of a carbon nanotube. [Main element symbol description] Nano carbon tube film bearing structure: 100; 200 [0046] Body: 110; 210 [0047] Surface: 112; 212 ❹ [0048] Nano carbon tube film bearing area: 114; 214 9 [0049] Recessed structure: 116; 216 [0050] Carbon nanotube film structure: 120 099137721 Form No. A0101 Page 17 / Total 27 Page 0992065765-0