TW201136613A

TW201136613A - Powder-dispersing agent comprising silicone phosphoric acid trimester, surface-coated/treated powder, and cosmetic

Info

Publication number: TW201136613A
Application number: TW100106081A
Authority: TW
Inventors: Yuji Masubuchi; Kazuhiro Suzuki
Original assignee: Kose Corp
Priority date: 2010-02-25
Filing date: 2011-02-23
Publication date: 2011-11-01
Also published as: CN102781420B; CN102781420A; HK1175695A1; WO2011105076A1; KR20120120320A; TWI519318B; KR101450530B1

Abstract

Disclosed is a novel silicone phosphoric acid triester which is applicable to cosmetics and the like. The silicone phosphoric acid triester is a compound represented by formula (I) (wherein R1's independently represent a C1-4 alkyl group; R represents a bivalent C2-7 hydrocarbon group which may have at least one group selected from -O- and -CO-; and n represents an integer of 5 to 40). When the compound is used, a silicone phosphoric acid diester and/or a silicone phosphoric acid monoester may be added. The silicone phosphoric acid triester or a silicone phosphoric acid ester mixture containing the trimester can be used as a cosmetic without any modification. Alternatively, the trimester can be used as a surface-treating agent or a dispersing agent for powders, and the resulting surface-coated/treated powder or the resulting powder dispersion can be used in cosmetics or the like.

Description

201136613 六、發明說明：【發明所屬之技術領域】本發明係關於一種含有新穎聚矽氧磷酸三酯之粉體分散劑、表面被覆處理粉體及化妝料。更詳細而言係關於一種含有聚矽氧磷酸三酯之化妝料，利用新穎聚矽氧鱗酸三醋進行表面被覆處理之粉體及含有其之化妝料，以及含有聚矽氧磷酸三酯之粉體分散劑、粉體分散體及含有其之化妝料。【先前技術】先前’於化妝料中調配有經改質之有機（聚）矽氧烷。例如存在胺基改質、環氧改質、羧酸改質、磷酸酯改質等有機（聚）石夕氧烧。該等之中，關於磷酸酯改質有機（聚）矽氧烷，例如於專利文獻1中記載有機（聚）矽氧烷之至少丨個矽原子經下式 [化1] i〇R\ (OR4)* [式中’ R1表示碳數2~20之直鏈或支鏈伸烷基，R2表示可經經基取代之碳數1〜20之直鏈或支鏈伸烷基，R3及R4相同或不同’分別表示碳數1〜22之直鏈或支鏈烷基，p表示〇〜20中之數，a、b及c分別表示鍵結於磷原子上的括號内之基之數’ a+b+c=3，a為1或2，b及c為0或1 ;其中，p=〇時’ R2之碳數為9〜20]所示之磷酸三酯基修飾的磷酸三酯改質有機（聚）矽氧烷。 154116.doc 201136613 又，於專利文獻2中，記載有雖作為化妝料用粉體之表面處理劑而存在，但作為磷酸酯改質有機（聚）矽氧烷，有機（聚）矽氧烷之至少1個矽原子經下式 [化2] (〇Μ)β ICK〇rVi\ -^ch2ch,r»-(〇r')F〇^-|^· [R及R2表示C2〜20之伸坑基，r3表示可經_〇h取代之 C1〜20之伸烧基’ R4表示C1〜22之烧基，Μ表示Η或1價陽離子，Ρ及q表示0〜200中之數，a、b及c表示鍵結於磷原子上的括號内之基之數，a+b+c=3，a及c為1或2，b為0或1] 所示之填酸S旨基修飾的麟酸g旨改質有機（聚）石夕氧烧。又，於專利文獻3中記載有機（聚）矽氧烷之至少1個矽原子經下式 [{-CH2CH2-R2-(OR1)p-〇}3P=〇]1/3 [式中，於方括號内之3價基中，3p個R1相同或不同，表示碳數2〜20之直鏈或支鏈伸烷基，3個R2相同或不同，表示可經羥基取代之碳數7〜20之直鏈或支鏈伸烷基，3個p相同或不同，表示0〜20中之數；再者，3個末端碳原子全部鍵結於相同或者2或3個分子不同之有機（聚）矽氧烷分子的矽原子上]所示之基修飾的磷酸三酯改質有機（聚）矽氧烷。然而，於上述專利文獻1及2中未記載將本發明所使用之聚矽氧磷酸三酯即3個有機（聚）矽氧烷鍵結於磷酸上而成之三酯體調配於化妝料中，於上述專利文獻3中，雖記載有3 個有機（聚）矽氧烷鍵結於磷酸上而成之三酯體’但有機 154116.doc 201136613 (聚）石夕氧烧與填酸係經由-Cf^CHrR^ORhp-基而鍵結，該基為碳數9個以上之長鏈。又，於專利文獻3中，磷酸三酯改質有機（聚）矽氧烷係藉由使下式 {CH2=CH-R2-(OR1)p-0}3P=〇 [式中，3p個R1相同或不同，表示碳數2〜20之直鏈或支鏈伸院基’ 3個R2相同或不同，表示可經經基取代之碳數 7〜20之直鏈或支鏈伸烷基’ 3個p相同或不同，表示〇〜2〇中之數]所示之碗酸三酯與具有至少1個鍵結於石夕原子上之氫原子的有機聚矽氧烷進行反應而製造，但該方法於本發明之情形般之-cha^-rMor^-基較短之情形時，合成困難。因此，關於-CH2CH2_R -(OR1、·基較短之填酸三g旨改質有機（聚）矽氧烷（亦稱為聚矽氧磷酸三酯），其作為化妝料之基材是否有用完全不為人知。又’於化妝料中，以彩妝效果或調整觸感等為目的而調配有無機粉體、有機粉體、色素粉體等粉體。該等粉體包含無機化合物、有機化合物’由於其性質具有親水親油性，故而不僅易溶於水而且易溶於油。因此，調配此種粉體之化妝料受水及汗、皮脂等分泌物職而損害化妝料所具有的本來之色調’或者由於出汗或面部活動等而損害化妝膜之均勻性，引起所謂「脫妝」現象。 _ t刖以來’作為防止汗或皮脂所導致的脫妝之技術，對利用各種表面處理劑處理粉體表面或添加分散劑等 154116.doc 201136613 技術進行研究。為添加分散劑之技術，開發關於為於較多化妝料中調配聚矽氧油作為油分而使用改質聚矽氧的粉體分散劑之技術。例如可列舉：（A)有機聚矽氧烷單體與（B)具有含聚内酯之基、羥基或陰離子性基之單體的共聚物（專利文獻4)，聚 -質聚石夕氧（專利文獻5)，聚甘油改質聚石夕氧（專利文獻 6)兩末端聚矽氧化聚乙二醇（專利文獻7)，支鏈聚合物中具有聚氧伸烧基與醯胺烧基之矽氧烧化合物（專利文獻8) 等。作為利用各種表面處理劑對粉體表面進行被覆處理之技術，例如可列舉：二曱聚矽氧烷、氫曱基聚矽氧烷、全氟烷基二曱基曱氧基矽烷等矽烷偶合劑等聚矽氧類，全氟烷基磷酸二乙醇胺鹽、含有全氟烷基之磷酸酯等氟系化合物’硬脂酸鋅等脂肪酸金屬皂’醯基麵胺酸鋁等醯化胺基酸衍生物，卵磷脂或其金屬鹽，磷酸酯改質有機（聚）矽氧烷等（例如專利文獻2、9〜1 7等）。藉由該等之開發，可提供於品質方面、使用感等方面得到改善者，但由於並不充分滿意，故而期待更優異之聚石夕氧系粉體分散劑或聚矽氧系表面被覆處理劑之開發。 [先前技術文獻] [專利文獻] [專利文獻1]曰本專利特開平9-048855號公報 [專利文獻2]曰本專利特開平9· 13681 5號公報 154116.doc 201136613 [專利文獻3]曰本專利特開平9-157397號公報 [專利文獻4]曰本專利特開平u_263706號公報 [專利文獻5]曰本專利特開2〇〇 1-58926號公報 [專利文獻6]日本專利特開2004-169015號公報 [專利文獻7]日本專利特開2005_154736號公報 [專利文獻8]日本專利特開2007-269689號公報 [專利文獻9]日本專利特開平5_3395 18號公報 [專利文獻1〇]曰本專利特開2003-55 142號公報 [專利文獻Π]曰本專利特開2009-263213號公報 [專利文獻I2]曰本專利特開昭62-250074號公報 [專利文獻13]曰本專利特開平1 〇_丨6793丨號公報 [專利文獻14]日本專利特開平i〇_2〇3926號公報 [專利文獻15]曰本專利特開平u_335227號公報 [專利文獻16]曰本再公表專利2006-106728號公報 [專利文獻I7]日本專利特開2008-247834號公報【發明内容】 [發明所欲解決之問題] 本發明之課題在於：開發一種與專利文獻3所記載之聚矽氧磷酸三酯不同之-CHAHrR^OR1^基較短之聚矽氧磷酸三酯’並將其用作化妝料、及化妝用粉體等粉體之分散劑或表面處理劑。 [解決問題之技術手段] 本發明者等人為解決上述課題進行潛心研究，結果本發明者等人發現若將專利文獻3中無法合成的-CHAHz-R^OR1 )p- I54116.doc 201136613 基較短之聚矽氧磷酸三酯化合物用作化妝料之基材，則修護效果、柔滑之使用感或化妝持久效果優異，進而發現若將其用作粉體之表面處理劑，則以少量之處理量亦可表現出較高之斥水性、分散性，且粉體處理效率優異，又發現若於金屬氧化物等之粉體之油中分散系中使用，則顯示出高分散能力’進而於調配有該聚矽氧磷酸三酯化合物之化妝料中，化妝膜之均勻性或化妝持久效果優異，從而完成本發明。即，本發明係關於： (1)一種化妝料，其含有式（工） [化3]BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a powder dispersant containing a novel polyphosphoric acid triester, a surface-coated powder, and a cosmetic. More specifically, it relates to a cosmetic containing polyphosphoric acid triester, a powder coated with a novel polyoxonium triacetate for surface coating, a cosmetic containing the same, and a polyphosphonium phosphate triester. A powder dispersant, a powder dispersion, and a cosmetic containing the same. [Prior Art] A modified organic (poly) alkane was previously formulated in a cosmetic. For example, there are organic (poly) oxime oxygen burning such as amine-based modification, epoxy modification, carboxylic acid modification, and phosphate modification. Among these, as for the phosphate-modified organic (poly) alkane, for example, in Patent Document 1, at least one of the ruthenium atoms of the organic (poly) alkane is subjected to the following formula [I1] i〇R\ ( OR4)* [wherein R1 represents a linear or branched alkyl group having 2 to 20 carbon atoms, and R2 represents a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted by a radical, R3 and R4. The same or different 'representing a straight or branched alkyl group having a carbon number of 1 to 22, respectively, p is a number in 〇~20, and a, b, and c respectively represent the number of bases in parentheses bonded to a phosphorus atom' a+b+c=3, a is 1 or 2, b and c are 0 or 1; wherein, when p=〇, the phosphotriester-modified phosphotriester represented by the carbon number of R2 is 9-20 Modification of organic (poly) alkane. 154116.doc 201136613 Further, Patent Document 2 describes that it is a surface treatment agent for a cosmetic powder, but it is a phosphate-modified organic (poly) alkane or an organic (poly) alkane. At least one helium atom is subjected to the following formula [2] (〇Μ)β ICK〇rVi\ -^ch2ch,r»-(〇r')F〇^-|^· [R and R2 represent the extension of C2~20 Pit base, r3 represents C1~20 which can be substituted by _〇h, R4 represents a C1~22 alkyl group, Μ represents Η or a monovalent cation, Ρ and q represent the number in 0~200, a, b and c represent the number of bases in parentheses bonded to the phosphorus atom, a+b+c=3, a and c are 1 or 2, and b is 0 or 1] The linonic acid g is intended to modify the organic (poly) stone oxygen burning. Further, Patent Document 3 discloses that at least one ruthenium atom of an organic (poly) alkane is subjected to the following formula [{-CH2CH2-R2-(OR1)p-〇}3P=〇]1/3 [in the formula, Among the trivalent groups in the square brackets, 3p of R1 are the same or different, and represent a straight or branched alkyl group having 2 to 20 carbon atoms, and 3 R2s are the same or different, and represent a carbon number 7 to 20 which can be substituted by a hydroxyl group. Straight or branched alkyl, 3 p are the same or different, indicating the number in 0~20; in addition, all three terminal carbon atoms are bonded to the same or 2 or 3 molecules different organic (poly) The modified phosphotriester of the oxime atom of the siloxane molecule is modified with an organic (poly) siloxane. However, in the above-mentioned Patent Documents 1 and 2, it is not described that the triester body obtained by binding three poly(poly)oxyalkylene oxides, which are used in the present invention, to phosphoric acid, is formulated in a cosmetic. In the above-mentioned Patent Document 3, a triester body in which three organic (poly) alkane are bonded to phosphoric acid is described, but organic 154116.doc 201136613 (poly) Shixi oxygen burning and acid filling are via -Cf^CHrR^ORhp-based, which is a long chain having 9 or more carbon atoms. Further, in Patent Document 3, the phosphoric acid triester is modified by an organic (poly) alkoxyane by making the following formula {CH2=CH-R2-(OR1)p-0}3P=〇[wherein, 3p R1 The same or different, which means that the linear or branched chain of the carbon number 2 to 20 '3 R2 is the same or different, and represents a linear or branched alkyl group having a carbon number of 7 to 20 which may be substituted by a base group 3 Manufactured by reacting a bowl acid triester represented by the same or different p, which represents a number in 〇~2〇, with an organopolyoxane having at least one hydrogen atom bonded to a stellate atom, but The method is difficult in the case of the case where the -cha^-rMor^-base is short in the case of the present invention. Therefore, with regard to -CH2CH2_R - (OR1, a short acid-filled three g of modified organic (poly) alkane (also known as polyphosphoric acid triester), is it useful as a substrate for cosmetics? It is not known. In the cosmetics, powders such as inorganic powders, organic powders, and pigment powders are blended for the purpose of coloring or adjusting the touch. These powders contain inorganic compounds and organic compounds. Because of its hydrophilic and lipophilic nature, it is not only soluble in water but also soluble in oil. Therefore, the cosmetic formulated with this powder is damaged by water, sweat, sebum and other secretions, which impairs the original color of the cosmetic. 'Or the uniformity of the cosmetic film due to sweating or facial activity, causing the phenomenon of so-called "dressing off". Since _ t刖, as a technique to prevent makeup caused by sweat or sebum, it is treated with various surface treatment agents. The surface of the powder or the addition of dispersing agents, etc. 154116.doc 201136613 Technology was studied. In order to add a dispersing agent technology, the use of modified polyfluorene oxygen for the blending of polyoxylized oil as a component in more cosmetics was developed. The technique of the powder dispersing agent, for example, a copolymer of (A) an organic polyoxyalkylene monomer and (B) a monomer having a polylactone-containing group, a hydroxyl group or an anionic group (Patent Document 4), Poly-mass polysulfide (Patent Document 5), polyglycerol-modified polychlorite (Patent Document 6), two-end polyfluorene oxide polyethylene glycol (Patent Document 7), and a polyoxyl extension in a branched polymer An oxy-oxygenated compound of a ruthenium group and a mercaptoalkyl group (Patent Document 8), etc. As a technique of coating the surface of the powder with various surface treatment agents, for example, dioxonium polyoxyalkylene or hydroquinone-based polymerization can be mentioned. a polyfluorene compound such as a decane coupling agent such as a decane or a perfluoroalkyl decyl decyl decane, a perfluoroalkylphosphoric acid diethanolamine salt or a fluorochemical compound such as a perfluoroalkyl phosphate. a derivative of a fatty acid such as zinc, such as zinc sulfhydryl aluminum amide, a lecithin or a metal salt thereof, a phosphate ester modified organic (poly) alkane, etc. (for example, Patent Documents 2, 9 to 17) Etc.) With these developments, improvements in quality and use can be provided. However, since it is not sufficiently satisfactory, development of a more excellent polysulfide-based powder dispersant or a polyfluorene-based surface coating treatment agent is expected. [Prior Art] [Patent Document] [Patent Document 1] [Patent Document 2] Japanese Patent Laid-Open No. Hei 9-136681 No. Hei 9-157397 [Patent Document 4] 曰 Patent Publication No. 9-157397 [Patent Document 4] [Patent Document 5] Japanese Patent Laid-Open Publication No. 2004-169015 (Patent Document 7) Japanese Patent Laid-Open No. 2005-154736 [Patent Document 8] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 2003-55 No. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Publication No. Hei 2〇3926 [Patent Document 15] [Patent Document 16] Japanese Patent Laid-Open Publication No. Hei. No. 2008-106834 (Patent Document No. 2008-247834) SUMMARY OF INVENTION [Problems to be Solved by the Invention] The present invention The problem is to develop a poly-phosphonium phosphate triester which is different from the polyphosphonium phosphate triester described in Patent Document 3, and which is shorter in composition and used as a cosmetic and cosmetic powder. A dispersant or surface treatment agent for powders. [Means for Solving the Problems] The inventors of the present invention have conducted intensive studies to solve the above problems. As a result, the inventors of the present invention found that -CHAHz-R^OR1)p-I54116.doc 201136613, which cannot be synthesized in Patent Document 3, is found. The short polyoxophosphoric acid triester compound is used as a base material for a cosmetic, and the repair effect, the smooth feeling of use, or the long-lasting effect of the makeup are excellent, and it is found that if it is used as a surface treatment agent for a powder, a small amount is used. The treatment amount can also exhibit high water repellency and dispersibility, and the powder treatment efficiency is excellent, and it is found that if it is used in a dispersion of oil of a metal oxide or the like, it exhibits high dispersibility. In the cosmetic prepared with the polyphosphoric acid triester compound, the uniformity of the cosmetic film or the long-lasting effect of the makeup is excellent, and the present invention has been completed. That is, the present invention relates to: (1) a cosmetic containing a formula (chemical)

(式中，各R!分別獨立表示碳數卜4之烷基，R表示可具有選自及-Co-中之至少丨種的碳數2〜7之2價烴基，n表示 5 40中之任一整數）所示之聚矽氧磷酸三酯中之1種或2種以上； [化4](wherein R: each independently represents an alkyl group of carbon number 4, and R represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may have at least one selected from the group consisting of -Co-, and n represents 5-40 1 or more of the polyphosphoric acid triesters represented by any integer); [Chemical 4]

(2)如上述（1)之化妝料，其含有包含6〇〜1〇〇質量％之式⑴ (式中，各K 選自-0-及-CC 5〜4〇中之任一，η表示各Rl为別獨立表示碳數1〜4之烷基，R表示可具有及-CO-中之至少1種的碳數2〜7之2價烴基，打表示〜任一整數）所示之聚矽氧磷酸三酯中之1種或2種 154116.doc 201136613 以上，〇〜35質量％之式（II) [化5](2) The cosmetic of the above (1), which contains the formula (1) containing 6 〇 to 1% by mass (wherein each K is selected from any of -0- and -CC 5 to 4, η It is shown that each R1 is an alkyl group having a carbon number of 1 to 4 independently, and R is a divalent hydrocarbon group having 2 to 7 carbon atoms which may have at least one of -CO-, and is represented by any integer. One or two of polyphosphonium phosphates 154116.doc 201136613 or more, 〇~35 mass% of formula (II) [Chemical 5]

(式中，R,、R及η與上述式（I)中之定義相同）所示之聚矽氧填酸二酯中之1種或2種以上，及 0〜5質量％之式（III) [化6](in the formula, R, R and η are the same as defined in the above formula (I)), one or more of the polyoxo acid diesters, and 0 to 5 mass% of the formula (III) ) [Chem. 6]

(式中，R!、R及η與上述式（I)中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上的聚矽氧磷酸酯；以及 (3) 如上述（1)或（2)之化妝料，其更含有油劑。又，本發明係關於： (4) 一種粉體，其係藉由式 [化7](in the formula, R!, R and η are the same as defined in the above formula (I)), one or two or more kinds of polyphosphonium phosphates; and (3) The cosmetic of the above (1) or (2) further contains an oil agent. Further, the present invention relates to: (4) A powder by the formula [Chem. 7]

(式中，各R丨分別獨立表示碳數卜4之烷基，R表示可具有選自-〇-及-CO-中之至少旧的碳數2〜7之2價烴基，η表示中之任整數）所示之聚矽氧磷酸三酯中之丨種或2種以上進行表面被覆處理者； (5)如上述（4)之粉體，其係藉由包含⑼質量％質量。/〇之 154116.doc 201136613 式⑴ [化8](wherein each R丨 independently represents an alkyl group of carbon number 4, and R represents a divalent hydrocarbon group having at least an old carbon number of 2 to 7 selected from -〇- and -CO-, and η represents (5) The powder of the above-mentioned (4), which contains (9) mass% of the mass, of the above-mentioned (4). /〇之 154116.doc 201136613 Formula (1) [Chem. 8]

(式中，各R丨分別獨立表示碳數卜4之烷基，R表示可具有選自-Ο-及-CO-中之至少1種的碳數2〜7之2價烴基，n表示 5〜40中之任一整數）所示之聚矽氧磷酸三酯中之i種或2種以上， 0〜35質量％之式（II) [化9](wherein each R丨 independently represents an alkyl group of carbon number 4, and R represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may be selected from at least one selected from the group consisting of -Ο- and -CO-, and n represents 5 (i) of the polyphosphonium phosphate triesters represented by any of the integers of 40 to 2 or more, 0 to 35 mass% of the formula (II) [Chemical 9]

(式中，R,、R及η與上述式⑴中之定義相同）所示之聚矽氧磷酸二酯中之1種或2種以上，及〇〜5質量％之式（III) [化 10](in the formula, R, R and η are the same as defined in the above formula (1)), one or more of the polyphosphoric acid diesters, and 〇 to 5 mass% of the formula (III) 10]

(式中，R,、R及η與上述式⑴中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上的聚矽氧磷酸酯進行表面被覆處理； (6) 如上述（4)或（5)之表面被覆處理粉體，其不僅含有上述聚矽氧磷酸酯而且更含有作為表面處理劑之有機鈦酸酯； (7) 如上述（6)之粉體，其中聚矽氧磷酸酯及有機鈦酸酯之 154116.doc -10· 201136613 質量比為1:9〜9:1 ; (8) 如上述（6)或（7)之粉體，其中有機鈦酸酯為異丙基三異硬脂基鈦酸酯； (9) 如上述（4)至（8)中任一項之經表面被覆處理之粉體，其中粉體為選自由氧化鈦、氧化辞及氧化鐵所組成之群中之至少1種； (10) 如上述（4)至（9)中任一項之經表面被覆處理之粉體，其中聚石夕氧磷酸酯之被覆量為表面被覆處理粉體之〇.〇1〜5質量％ ;以及 (11) 一種化妝料’其含有如上述（4)至（1 〇)中任一項之經表面被覆處理之粉體。進而’本發明係關於： (12) —種粉體分散劑，其含有式⑴ [化 11](in the formula, R, R and η are the same as defined in the above formula (1)), one or two or more kinds of polyphosphonium phosphates are subjected to surface coating treatment; (6) The surface-coated powder according to the above (4) or (5), which contains not only the above-mentioned polyphosphonium phosphate but also an organic titanate as a surface treatment agent; (7) the powder of the above (6), The mass ratio of 154116.doc -10·201136613 of polyphosphonium phosphate and organic titanate is 1:9~9:1; (8) The powder of the above (6) or (7), wherein the organic titanic acid The powder is a surface-coated powder according to any one of the above (4) to (8), wherein the powder is selected from the group consisting of titanium oxide and oxidized And a surface-coated powder according to any one of the above (4) to (9), wherein the coating amount of the polyoxophosphoric acid ester is a surface (1) A cosmetic material which contains the surface-coated powder of any one of the above (4) to (1). Further, the present invention relates to: (12) a powder dispersant containing the formula (1) [Chem. 11]

(式中’各Rl分別獨立表示碳數1〜4之烷基，R表示可具有選自-〇-及-CO-中之至少^的碳數2〜7之2價烴基，η表示 5〜40中之任一整數）所示之聚矽氧磷酸三酯中之1種或2種以上； (13)如上述（12)之粉體分散劑，其含有包含60質量％〜1〇〇質量％之式（I) [化 12] 154116.doc • 11 - 201136613(wherein each R1 independently represents an alkyl group having 1 to 4 carbon atoms, and R represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may be selected from at least 〇- and -CO-, and η represents 5~ (1) The powder dispersant according to the above (12), which contains 60% by mass to 1% by mass of the above-mentioned (12) %(I) [12] 154116.doc • 11 - 201136613

(式宁，各R,分別獨立表示碳數丨〜4之烷基，R表示可具有選自-〇-及-C〇-中之至少1種的碳數2〜7之2價烴基，n表示 5〜40中之任一整數）所不之聚矽氧磷酸三酯中之丨種或2種以上， 0〜35質量％之式（Π) [化 13](Formula, each R, each independently represents an alkyl group having a carbon number of 44, and R represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may have at least one selected from the group consisting of -〇- and -C〇-, n丨或或或或 ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ]

(式中’ R〗、R及η與上述式⑴中之定義相同）所示之聚矽氧磷酸二酯中之1種或2種以上，及〇〜5質量％之式（III) [化 14](in the formula, R, η, R and η are the same as defined in the above formula (1)), one or more of the polyphosphoric acid diesters, and 〇 5% by mass of the formula (III) 14]

Of-Sh—CH-8I—R—0一P0(0H)a (nj) ni R> R, (式中’ Ri、R及n與上述式⑴中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上的聚矽氧磷酸酯； (14) 一種粉體分散體，其含有如上述（12)或（13)之粉體分散劑、粉體及油劑；以及 (15) —種化妝料，其含有如上述（14)之粉體分散體。【實施方式】以下對本發明之詳細情況進行說明。 1聚矽氧磷酸三酯本發明所使用之聚矽氧磷酸三酯係由式⑴ I54116.doc -12- 201136613 [化 15]Of-Sh-CH-8I-R-0-P0(0H)a(nj) ni R> R, (wherein Ri, R and n are the same as defined in the above formula (1)) (1) a powder dispersion containing a powder dispersant, a powder and an oil agent as described in (12) or (13) above; (15) A cosmetic comprising the powder dispersion of the above (14). [Embodiment] Hereinafter, the details of the present invention will be described. 1 polyphosphoric acid triester The polyphosphonium phosphate triester used in the present invention is of the formula (1) I54116.doc -12- 201136613 [Chem. 15]

?， TO (1)?, TO (1)

Ri J3 表示。式中，各h分別獨立表示碳數卜4之院基，r表示可具有 k自0及-C0-中之至少旧的碳數2〜7之2價煙基η表示 5〜40中之任一整數。 ” 作為R丨中之「碳數1〜4之烷基」，可列舉：甲基、乙基、正丙基、異丙基、正丁基、第二丁基、異丁基、第三丁基。作為Ri ’該等之中較佳為甲基。作為R中之「可具有選自_〇K〇_中之至少！種的碳數 2〜7之2彳貝烴基」之「碳數2〜7之2價烴基」，可列舉：伸乙基鏈、伸丙基鏈、甲基伸乙基鏈、伸丁基鏈、丨，2二曱基伸乙基鏈、伸戊基鏈、丨_甲基伸丁基鏈、2_甲基伸丁基鏈、伸己基鏈、伸庚基鏈等。作為「具有選自-0-及-CO-中之至少1種的碳數2〜7之2 4貝煙基」’可具有1或2個以上之-〇 -或_ c 〇 -，例如可列舉： -CH2-0-(CH2)2- ' -(CH2)2-〇-(CH2)2- ' -(CH2)3-0-(CH2)2-、 -(CH2)4-〇-(CH2)2-、-(CH2)2-〇(CH2)2-〇-(CH2)2-、-(CH2)2-〇-(CH2)4-、-(CH2)2-0-(CH2)5，、-(CH2)3-〇-CH2-、-CH2-CO-(CH2)2-、-(CH2)2-C〇-(CH2)2-、-(CH2)3-C〇-(CH2)2-、-(CH2)4-C〇-(CH2)2-' -(CH2)2-CO-(CH2)4- ' -(CH2)2-CO-(CH2)5- ' -(CH2)3-CO-CH2-等。作為「可具有選自-0-及-CO-中之至少1種的碳數2〜7之2 1541I6.doc -13- 201136613 價烴基」，該等之中較佳為_(CH2)3〇(CH2)2q 具體而言，作為聚矽氧磷酸三酯，例如可列舉以下者其中，η為5〜40中之任一整數。 [化 16]Said by Ri J3. Wherein each h represents independently a carbon number of 4, and r represents a divalent nicotine η which may have at least the old carbon number of 2 to 7 from 0 and -C0-, representing any of 5 to 40 An integer. "As the alkyl group having 1 to 4 carbon atoms" in R丨, a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, a second butyl group, an isobutyl group, and a third group are mentioned. base. Among these, Ri" is preferably a methyl group. The "two-valent hydrocarbon group having 2 to 7 carbon atoms" having "a carbon dioxide group having 2 to 7 carbon atoms which may be selected from at least a compound of 〇K〇_" in R may, for example, be an ethyl group having a carbon number of 2 to 7. Chain, propyl chain, methyl extended ethyl chain, butyl chain, hydrazine, 2 decyl extended ethyl chain, extended pentyl chain, 丨-methyl butyl chain, 2-methyl butyl chain, hexyl chain, Stretching the base chain and so on. As the "24 ketone group having a carbon number of 2 to 7 selected from at least one of -0- and -CO-", it may have 1 or more - 〇- or _c 〇-, for example, Listed: -CH2-0-(CH2)2- '-(CH2)2-〇-(CH2)2- '-(CH2)3-0-(CH2)2-, -(CH2)4-〇-( CH2)2-, -(CH2)2-〇(CH2)2-〇-(CH2)2-, -(CH2)2-〇-(CH2)4-, -(CH2)2-0-(CH2) 5,, -(CH2)3-〇-CH2-, -CH2-CO-(CH2)2-, -(CH2)2-C〇-(CH2)2-, -(CH2)3-C〇-( CH2)2-, -(CH2)4-C〇-(CH2)2-'-(CH2)2-CO-(CH2)4-'-(CH2)2-CO-(CH2)5- '-( CH2) 3-CO-CH2- and the like. As the "2 1541I6.doc -13-201136613 valent hydrocarbon group having a carbon number of 2 to 7 which may be selected from at least one of -0- and -CO-", among these, _(CH2)3〇 is preferable. (CH2) 2q Specifically, examples of the polyphosphoric acid triester include η of any of 5 to 40. [Chemistry 16]

該等可單獨使用1種，亦可使用2種以上之混合物。 2聚矽氧磷酸三酯之製造方法本發明之聚石夕氧镇酸三g旨例如可藉由以下反應式所示之方法而製造。 [化 17] 〇v) (V) (〇 (式中，Ri、R及η與式（I)中之定義相同）使式（IV)所示之單末端.曱醇改質聚矽氧與式（ν)所示之鱗醯氣於溶劑中，在鹼之存在下進行反應。作為進行上述反應時使用之溶劑，可使用四氫咳鳴、二曱基亞砜、Ν，Ν-二曱基曱醯胺、丙酮、二***、乙猜等極性溶劑等。作為鹼，可使用二乙胺、三乙胺等烷基胺類，哌唤、味。坐等雜環狀胺類，氣化苄基三乙基銨、氣化曱基三辛基敍 154116.doc 201136613 等四級銨鹽類，正丁基鋰、二異丙基醯胺鋰等有機金屬類等。反應溫度通常為25°C〜5(TC左右，反應時間亦根據聚矽氧鍵長而有所不同，但通常為2小時〜2〇小時左右。藉由上述反應，可獲得式⑴所示之聚矽氧磷酸三酯，但作為副產物而產生式（Π)所示之聚矽氧磷酸二酯、式（ΙΠ) 所不之聚矽氧磷酸單酯等。亦可於該等副產物存在之狀態下用作聚矽氧磷酸酯混合物，亦可藉由通常之方法將產物純化’從而實質上僅使用式⑴所示之聚矽氧磷酸三酯。 3含有聚發氧鱗酸三醋之化妝料本發明之化妝料含有上述式⑴所示之聚矽氧磷酸三酯中之1種或2種以上及視需要之式（π) [化 18]These may be used alone or in combination of two or more. Process for producing 2-polyoxyphosphoric acid triester The poly-glycolic acid tri-glycol of the present invention can be produced, for example, by the method shown by the following reaction formula.化v) (V) (〇(wherein, Ri, R and η are the same as defined in formula (I)) The single-end sterol modified by formula (IV) is modified with polyoxyl The xanthene gas of the formula (ν) is reacted in a solvent in the presence of a base. As the solvent used in the above reaction, tetrahydrogen cough, dimercaptosulfoxide, anthracene, fluorene-difluorene can be used. A polar solvent such as sulfhydrylamine, acetone, diethyl ether or ethyl bromide. As the base, an alkylamine such as diethylamine or triethylamine can be used, and a heterocyclic amine such as a heterocyclic amine can be used. a quaternary ammonium salt such as n-butyl ammonium or a gasified decyl trioctyl 154116.doc 201136613; an organic metal such as n-butyllithium or lithium diisopropylamide; etc. The reaction temperature is usually 25 ° C. ~5 (about TC, the reaction time also varies depending on the length of the polyoxyl bond, but it is usually about 2 hours to 2 hours. By the above reaction, the polyphosphonium phosphate triester represented by the formula (1) can be obtained. However, as a by-product, a polyphosphonium phosphate diester represented by the formula (Π), a polyphosphonium phosphate monoester which is not represented by the formula (ΙΠ), and the like may be produced. As a polyphosphonium phosphate mixture, the product can be purified by a usual method to substantially use only the polyphosphonium phosphate triester represented by the formula (1). 3 A cosmetic material containing polyoxygenated triacetate The cosmetic of the invention contains one or more of the polyphosphoric acid triesters represented by the above formula (1) and, if necessary, the formula (π).

(式中’ R!、R及η與上述式⑴中之定義相同）所示之聚矽氧碟酸二酯中之1種或2種以上，及/或式（III) [化 19](1) or 2 or more of the polyoxo acid diesters represented by the formula (R?, R and η are the same as defined in the above formula (1)), and/or the formula (III) [Chem. 19]

(式中’ R〗、R及η與上述式⑴中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上。式（I)所示之聚矽氧磷酸三酯、式（11)所示之聚矽氧磷酸二酯及式（III)所示之聚矽氧磷酸單酯的調配比例只要式〇) 154H6.doc -15- 201136613 所示之聚矽氧磷酸三酯發揮作為化妝料之基材的效果，則無特別限定，較佳為式⑴所示之聚矽氧磷酸三酯為6〇〜1〇〇質量°/。’式（π)所示之聚矽氧磷酸二酯為〇〜3 5質量％，及式 (HI)所示之聚矽氧磷酸單酯為〇〜5質量％。該等聚矽氧磷酸酯整體於化妝料中之調配比例為丨〜50質量％ ’較佳為5-3 0質量〇/〇 » 於化妝料中，可根據種類適當調配能夠調配之成分。例如可調配：油齊,j、界面活性劑、醇類、水、㈣劑、凝膠化劑及增黏劑、粉體、紫外線吸收劑、防腐劑、抗菌齊！抗氧化劑、美膚用成分（美白劑、細胞賦活劑、消炎劑、血液循環促進劑、皮膚收斂劑、抗脂溢劑等）、維生素類、胺基酸類、核酸、激素等。这等之中，較料與油劑-併㈣，只要為可溶解上述聚石夕氧鱗酸酷之油劑，則無特別限定。藉由調配聚石夕㈣酸醋而具有提高醋油等極性油與聚残油等非極性油之相溶性，可均勻地溶解油劑整體等效果。油劑之調配量並無特別限定，較佳為㈣質量更佳為5〜20質量％。作為油劑’可列舉：固體油、半固體油、液狀油等例示：天然動植物油及半合成油、烴油、酿油、甘油、聚石夕氧油、高級醇、高級脂肪酸、有機溶劑等。作為固體油，可列舉：巴西標摘織、堪地躐、蟲膠躐、硬化油等天然幾類，地壤、純輯、：微晶蟻等礦物线，聚乙稀織、費托壤、乙稀-丙稀 154116.doc •16· 201136613 物等合成蟻，山茶醇、録壤醇、硬脂醇、膽固醇'植固醇寻而級醇，硬脂酸、山蓊酸等高級脂肪酸等。於液狀油中’作為天然動植物油及半合成油，具體可列舉.路梨油、亞麻仁油、杏仁油、蟲蝶、蘇子油、撖欖油、香榧油、肝油、杏桃幻由、小麥胚芽油、芝麻油、大 . 《胚芽油、米糠油、山茶油、紅花子油、中國桐油、錫蘭肉桂油、海龜油、大豆油、茶杆油、捲油、月見草油、玉米油、菜籽油、日本桐油、糠蝶、胚芽油、桃仁油、掠搁油、棕摘仁油、、藍麻油、蔡花軒油、葡萄抒油、荷荷琶油、，洲胡桃油、棉籽油、椰子油、三挪子油脂肪酸甘油西旨、花生油、羊毛脂、液狀羊毛脂、還原羊毛脂、羊毛脂醇、乙酸羊毛脂、羊毛脂脂肪酸異丙酯、POE羊毛脂醇醚、POE羊毛脂醇乙酸酷、羊毛脂脂肪酸聚乙二醇醋、 POE氫化羊毛脂醇醚、蛋黃油等。作為火二'由’可列舉：角鯊烷、角鯊烯、流動石蠟、姥鮫烷、聚異丁烯等》作為g曰油，可列舉.己二酸二異丁酯、己二酸己基癸 • 酯、己二酸二庚基十—烷基酯、單異硬脂酸N-烷基乙二醇酯、異硬脂酸異鯨蠟酯、三異硬脂酸三羥甲基丙烷 ' 酯、2-乙基已酸鯨蠟酯、二-2-乙基已酸乙二醇酯、二_2_ 乙基已酸新戍二醇酯、三_2_乙基已酸三羥甲基丙烷酯、四-2-乙基已酸季戊四醇酯、辛酸鯨蠟酯、辛基十二烷基膠酯、油醇油酸酯、油酸辛基十二烷基酯、油酸癸酯、二癸酸新戊二醇酯、檸檬酸三乙酯、丁二酸2_乙基己酯、乙酸 154116.doc •17- 201136613 戊酉旨、乙酸乙3旨、乙酸丁醋、硬月旨酸異錄㈣、硬脂酸丁酯、癸二酸二異丙酯、癸二酸二·2_乙基己酯、乳酸鯨蠟酉曰、礼酸十四烷基酯、棕櫚酸異丙酯、棕橺酸2_乙基己醋、棕搁酸2-己基癸醋、掠摘酸2-庚基十一烧基醋、12_經基硬脂酸膽固㈣、二季戊四醇脂肪酸@旨、肉豆鐘酸異丙 ^ _肉且謹酸2-辛基十二院基醋、肉豆蔬酸2_己基癸醋、十四;^基@日 '二甲基辛酸己基癸醋、月桂酸乙 =、j桂酸己醋、N-月桂醯心麩胺酸_2_辛基十二烧基醋、蘋果酸二異硬脂酯等。作為甘油醋油，可列礙. t J舉.乙醯甘油酯、三異辛酸甘油酯、三異硬脂酸甘油酯、三異棕櫚酸甘油醋、三-2_乙基已 :甘油醋、單硬脂酸甘油酿一庚基十一酸甘油酿、三肉豆蔻酸甘油酯等。作為聚石夕氧油，可列盤. •二甲基聚矽氧烷、曱基苯基聚石夕氧烧、甲基氫聚矽氣軋烷、八曱基環四矽氧烷、十甲基環五矽氧烷、十二甲其卢丄、昤 ^ 土衣〇矽氧烷、四曱基四氫環四矽氧烧、燒基改質聚石夕氧等。作為高級醇，可列無. 醇、]舉.油醇、月桂醇、硬脂醇、異硬脂并t辛基十二烷醇等。作為高級脂肪酸， J歹】舉：油酸、棕櫚酸、肉豆蔻酸、更月曰S文、異硬脂酸等。作為有機溶劑，可列贫 _ 』歹1舉.正己烷、環己烷等烴，苯、甲、一甲苯等芳香族 ^ . 合物，乙酸乙酯、乙酸丁酯等非芸香私系化合物，氯伙_ 寸非方、一氣甲烷、二氯乙烷等氣系化合 154116.doc 201136613 物、二哼烷、四氫呋喃等醚系化合物，2_丙醇、苄醇、笨氧基乙醇、卡必醇類’賽珞蘇類，聚丁烯、旋子油等。作為界面活性劑，只要為通常用於化妝料者，則無特別限定，可使用任意者《界面活性劑可列舉：陰離子性界面活性劑、陽離子性界面活性劑、非離子性界面活性劑、兩性界面活性劑等，該等可視需要使用丨種或將2種以上組合使用。作為陰離子性界面活性劑，具體可列舉：硬脂酸鈉或棕櫚酸三乙醇胺等脂肪酸皂，烷基醚羧酸及其鹽、胺基酸與脂肪酸之縮合等之羧酸鹽，烷基磺酸、烯基磺酸鹽、脂肪酸酯之磺酸鹽、脂肪酸醯胺之磺酸鹽、烷基磺酸鹽與其甲酿縮合物之磺酸鹽，烷基硫酸酯鹽、二級高級醇硫酸酉旨鹽、院基及晞丙基醚硫酸酯鹽、脂肪酸酯硫酸酯鹽、脂肪酸烷基醇醯胺之硫酸酯鹽、聚氧乙烯烷基硫酸酯鹽、土耳其紅油等硫酸酯鹽類，烷基磷酸鹽、醚磷酸鹽、烷基烯丙基醚磷酸鹽、醯胺磷酸鹽，N-醯基胺基酸系活性劑等。作為陽離子性界面活性劑，以長鏈烷基三曱基銨鹽、二長鏈烧基二甲基銨鹽、長鏈烷基二甲基苄基銨鹽、二聚氧乙烯烷基甲基銨鹽、二聚氧乙烯烷基醚二甲基銨鹽、聚氧丙細曱基一乙基錄鹽專烧基四級敍鹽或芳香族四級敍鹽為代表，可列舉：烷基吡啶鏽鹽等吡啶鑌鹽、烷基二羥基乙基咪唑啉鹽等咪唑啉鹽、N_醯基驗性胺基酸低級烧基酯鹽，並且可列舉：院基胺鹽、聚胺、胺基醇脂肪酸衍生物等胺鹽等。 154116.doc •19· 201136613 作為非離子性界面活性劑’可列舉：去水山梨醇脂肪酸醋'甘油脂肪酸醋、聚甘油脂肪酸酿、丙二醇脂肪酸醋、聚乙二醇脂肪酸醋、薦糖脂肪酸醋、聚氧乙稀烧基鱗、聚氧丙烯烧基謎、聚氧乙稀燒基笨趟、聚氧乙埽脂肪酸醋、聚氧乙烯去水山梨醇脂肪酸醋、聚氧乙烯山梨醇脂肪酸醋、聚氧乙烯甘油脂肪酸醋、聚氧乙婦丙二醇脂肪酸醋、聚氧乙縣麻油、聚氧乙烯氫化魏油、聚氧乙烯嚴化菌麻油脂肪酸醋、聚氧乙烯植物留烷醇醚、聚氧乙烯植固醇驗、聚氧乙稀二氫膽固醇域、聚氧乙稀膽固醇驗、聚氧伸烧基改質有機聚石夕氧烧、聚氧伸烧基·烧基共改質有機聚石夕氧烧'院醇酿胺、糖喊、糖酿胺等。作為兩性界面活性劑，可列舉··院基二f基胺基乙酸甜菜驗、脂肪酸醯胺丙基二甲基胺基乙酸甜⑽、烧基二經基乙基胺基乙酸甜菜鹼等羰基甜菜鹼型兩性界面活性劑，烷基磺基甜菜鹼等磺基甜菜鹼型兩性界面活性劑，N•脂肪酸醯基-N-羧曱基_N-羥基乙基乙二胺鹽、N_脂肪酸醯基_ N-羧基甲氧基乙基_N_羧甲基乙二胺二鹽等醯胺胺型（咪唑啉型）兩性界面活性劑，Ν·[3_烷氧基_2_羥基丙基]精胺酸鹽等胺基酸型兩性界面活性劑，烷基亞胺基二羧酸鹽型兩性界面活性劑等。作為醇類，具體可列舉：乙醇、異丙醇等低級醇，甘油、二甘油、聚甘油、二乙二醇、聚乙二醇、丙二醇、二丙二醇、聚丙二醇、丨，3_丁二醇、赤蘚醇等多元醇，山梨醇、麥芽糖、木糖醇、麥芽糖醇等糖醇等。 154116.doc •20· 201136613 作為保濕劑，可列舉：尿素、玻尿酸、硫酸軟骨素、吡咯烷酮羧酸鹽等。作為水系增黏劑、凝膠化劑，存在：***膠、黃蓍膠、半乳聚糖、刺槐豆膠、古亞膠、刺梧桐樹膠、鹿角菜膠果膠、瓊脂、榲樟籽（Marmelo，榲樟）、澱粉（大米、玉米、馬鈴薯、小麥）、海藻膠、特蘭托膠、刺槐豆膠等勿系向刀子，二仙膠、葡聚糖、破玉白酿聚糖、支鏈澱粉等微生物系高分子，膠原蛋白、酪蛋白、白蛋白、明膠等動物系南分子，羧甲基澱粉、曱基羥基丙基澱粉等澱粉系问分子，曱基纖維素、乙基纖維素、羥基丙基甲基纖維素、羧甲基纖維素、羥基曱基纖維素、羥基丙基纖維素、硝化纖維素、纖維素硫酸鈉、羧曱基纖維素鈉、結晶纖維素、纖維素粉末等纖維素系高分子，海藻酸鈉、海藻酸丙二醇酯等海藻酸系高分子，聚乙烯曱醚、羧乙烯聚合物、烷基改質羧乙烯聚合物等乙烯系高分子、聚氧乙烯系高分子、聚氧乙烯聚氧丙烯共聚物系高分子，聚丙烯酸鈉、聚丙烯酸乙酯、聚丙烯醯胺等丙烯酸系高分子，膨潤土、矽酸鋁鎂、合成鋰皂石、鋰蒙脫石、無水矽酸等無機系增黏劑，聚乙烯亞胺，陽離子聚合物等。又，其中亦包括聚乙烯醇或聚乙烯吼咯烷酮等皮膜形成劑。作為油凝膠化劑，可列舉：硬脂酸鋁、硬脂酸鎂、肉豆蔻酸鋅等金屬皂，N-月桂醯_L·麩胺酸、〇^_二_正丁基胺等胺基酸衍生物，棕櫚酸糊精酯、硬脂酸糊精酯、孓乙其已酸棕橺酸糊精酯等脂肪酸糊精酯，棕櫚酸蔗糖酯、硬脂 I54H6.doc •21- 201136613 酸庶糖酯等脂肪酸蔗糖酯，單早亞苄基山梨醇、二亞苄基山梨醇等山梨醇之亞苄基衍 …… 土何生物’二甲基节基十二烷基銨微晶尚嶺石黏土、二甲某- ,4- '…u 一（十/烷基）銨微晶高嶺石黏土等有機改質黏土礦物。作為粉體，其形狀（球狀、 3丁狀扳狀專）、粒徑（煙霧狀、微粒、顏料級等）、粒于、、'°構（多孔質、無孔質等）不限，可使用任意者。例如可列舉. 〜率·無機粉體、有機粉體、界面活性劑金屬鹽粉體、有多 ^ 铜巳顔枓、珍珠顏料、金屬粉末顏料、天然色素等。作為具體例，可列舉以下者。無機粉體：氧化鈦、氧化錯、氧化鋅、氧化鈽、氧化鎮、硫酸鋇、硫酸妈、硫酸鎮、碳酸两、碳酸鎮、滑石、雲母、高嶺土、絹雲母、白雲母、合成雲母、金雲母、紅雲母、黑雲母、鐘雲母、妙酸、無水矽酸、碎酸铭、矽酸鎂、矽酸鋁鎂、矽酸鈣、石夕酸鋇、石夕酸锶、鎮酸金屬鹽、羥磷灰石、蛭石、氫氧化鋁（HIGIUTE)、膨潤土、蒙脫石、鋰蒙脫石、沸石、陶瓷粉末、磷酸氫二鈣、氧化鋁、乳氧化紹、氮化蝴等。有機粉體：聚醯胺粉末、聚酯粉末、聚乙烯粉末、聚丙烯粉末、聚苯乙烯粉末、聚胺基曱酸酯、苯并胍胺粉末、聚甲基笨并胍胺粉末、四氟乙烯粉末、聚甲基丙烯酸曱酯卷末、纖維素' 絲粉末、尼龍粉末、12尼龍、6尼龍、具有父聯有二曱基聚矽氧之結構的交聯型聚矽氧細粉末、交聯型聚秒氧·網狀聚矽氧嵌段共聚物、聚甲基倍半矽氧烷 154116. doc -22- 201136613 之細粉末、苯乙烯-丙烯酸共聚物、二乙稀苯-苯乙稀共聚物、乙稀樹脂、尿素樹脂、酌樹脂、氟樹脂、石夕樹脂、丙烯酸樹脂、三聚氰胺樹脂、環氧樹脂、聚碳酸酯樹脂、微晶纖維粉體、澱粉粉末、月桂醯離胺酸等。界面活性劑金屬鹽粉體（金屬皂）：硬脂酸鋅、硬脂酸銘、硬脂酸詞、硬脂酸鎮、肉豆蔻酸辞、肉豆謹酸鎂、錄蠟基磷酸辞、鯨蠟基磷酸鈣、鯨蠟基磷酸鋅鈉等。有色顏料.氧化鐵、氫氧化鐵、鈦酸鐵等無機紅色顏料；γ-氧化鐵等無機褐色系顏料，氧化鐵黃、黃土等無機黃色系顏料’氧化鐵黑、碳黑等無機黑色顏料；猛紫、鈷紫等無機紫色顏料；氫氧化鉻、氧化鉻、氧化鈷、鈦酸鈷等無機綠色顏料；鐵藍、群青等無機藍色系顏料；使焦油系色素色澱化而成者、使天然色素色澱化而成者、及使該等粉體複合化而成之合成樹脂粉體等。珍珠顏料：氧化鈦被覆雲母、氧化鈦被覆雲母、氧氣化鉍、氧化鈦被覆氧氣化鉍、氧化鈦被覆滑石、阿艮亭鹼、氧化鈦被覆玻璃粉末、氧化鈦被覆著色雲母等。金屬粉末顏料：鋁粉末、銅粉末、不鏽鋼粉末等。 …、油色素.紅色3號、紅色丨〇4號、紅色丨〇6號、紅色 7虎、紅色202號、紅色204號、紅色205號、紅色220號、紅色226號、紅色227號、紅色228號、紅色230號、紅色4〇1 號、紅色5G5號、黃色4號、黃色5號、黃色2()2號、黃色 2〇3號、汽色204號、黃色401號、藍色1號、藍色2號、藍色2〇1號、藍色404號、綠色3號、綠色201號、綠色2〇4 154116.doc •23· 201136613 號、綠色205號、橙色201號、橙色203號、橙色204號、橙色206號、橙色207號等》天然色素：胭脂色酸、蟲漆酸、紅花素、巴西蘇木素、藏花素等。該等粉體可直接使用，亦可使該等粉體複合化，或利用油劑、聚矽氧、氟化合物等進行表面處理而使用。上述粉體可視需要使用1種或將2種以上組合使用。作為紫外線吸收劑，可列舉：對胺基苯曱酸等苯甲酸系紫外線吸收劑、鄰胺苯曱酸甲酯等鄰胺苯甲酸系紫外線吸收劑、水楊酸曱酯等水楊酸系紫外線吸收劑、對曱氧基肉桂酸辛酯等肉桂酸系紫外線吸收劑、2,4-二羥基二苯甲酮等二苯甲酮系紫外線吸收劑、尿刊酸乙酯等尿刊酸系紫外線吸收劑等。作為防腐劑、抗菌劑，可列舉：對羥基苯甲酸酯、苯曱酸、苯曱酸鈉、山梨酸、山梨酸鉀、苯氧基乙醇、水楊酸、石碳酸、山梨酸、對氣間甲酚、六氣酚、氣化苯二曱烴錄、氣化雙氣苯雙胍己啶、三氯碳醯代雙胺苯、感光素、異丙基甲基苯酚等。作為抗氧化劑，可列舉：生育酚、丁基羥基苯甲醚、二丁基經基曱苯等’作為pH調整劑，可列舉：乳酸、乳酸鹽、擰檬酸、檸檬酸鹽、乙醇酸、丁二酸、酒石酸、蘋果酸、碳酸鉀、碳酸氫鈉、碳酸氫銨等，作為螯合劑，可列舉：丙胺酸、依地酸鈉鹽、聚磷酸鈉、偏磷酸鈉、磷酸鹽、羥基乙烷二膦酸等，作為清涼劑，可列舉：L-薄荷 154116.doc •24- 201136613 腦、樟腦、薄荷油、胡椒薄荷油（peppermint 〇il)、桉葉油等，作為消炎劑，可列舉：尿囊素、甘草次酸鹽、甘草次酸衍生物、傳明酸、甘菊藍等。作為美膚用成分，可列舉：熊果苷、麩胱苷肽、虎耳草萃取物等美白劑，蜂王漿、感光素、膽固醇衍生物、幼牛血液萃取液等細胞賦活劑，皮膚粗糙改善劑、壬酸香草基醯胺、菸鹼酸苄酯、菸鹼酸β_丁氧基乙酯、辣椒素、薑油酮、斑蝥酊、魚石脂、咖啡因、鞣酸、α_龍腦、煙鹼酸生育酚、六菸鹼酸肌醇、環扁桃酯、辛那伶（cinnarizine)、托拉佐林、乙醢膽驗、維拉帕米（Verapamil)、頭花千金藤鹼（cepharanthine)、γ-谷維素等血液循環促進劑，氧化辞、鞣酸等皮膚收斂劑，硫、二甲噻蒽等抗脂溢劑等。作為維生素類，可列舉：維生素Α油、視網醇、乙酸視網醇、棕橺酸視網醇等維生素A類，核黃素、丁酸黃素、黃素腺核苷酸等維生素B2類，吡哆醇鹽酸鹽、吡π多醇二辛酸酯等維生素Β6類，L-抗壞血酸、L_抗壞血酸二棕櫊酸酯、L-抗壞血酸-2-硫酸鈉、di_a_生育酚_L_抗壞血酸磷酸二醋二鉀等維生素C類’泛酸鈣、D-泛醇、泛醇乙謎 '乙醯泛醇***等泛酸類，麥角鈣化固醇、膽鈣化醇等維生素 D類，菸鹼酸、菸鹼酸苄酯、菸鹼醯胺等菸鹼酸類，dl_a_ 生月酌、乙酸dl-a-生育紛、於驗酸dl-a-生育紛、丁二酸 dl-a-生育紛等維生素e類，維生素p，生物素等。作為胺基酸類’可列舉：精胺酸、天冬醯胺酸、胱胺酸、半胱胺酸、曱硫胺酸、絲胺酸、白胺酸、異白胺酸、 154116.doc •25· 201136613 色胺酸、丙胺酸、甘胺酸.、脯胺酸等，作為核酸，可舉出脫氧核糖核酸等，作為激素，可列舉：***、乙炔雌二醇等。 — 於單獨使用本發明之聚矽氧磷酸三酯、或將含有其之聚矽氧磷酸酯混合物用作化妝料之情形時，可視需要併用其他成分，利用常規方法而製備，例如以液狀、乳液狀、乳霜狀、固體狀、凝膠狀、膏狀等各種形態實施。又，本發明之化妝料為油性系、油包水型乳化系、水包油型乳化系等，其劑形並無特別限定，具體可以乳液、乳霜、美容液、化妝油、唇膏、護手霜、洗面乳等護膚品、粉底、妝前乳、腮紅、眼影、睫毛膏、眼線液、眉筆、定妝劑 (Overcoat agent)、口紅、唇彩等彩妝品，養髮露、髮乳、洗髮精、调絲精、護髮素、整髮劑等頭皮或毛髮用化妝料等各種化妝料之形態實施。 4利用聚梦氧磷酸三酯進行表面被覆處理之粉體本發明之經表面被覆處理之粉體所使用之表面處理劑係含有上述式（I)所示之聚矽氧磷酸三酯中之1種或2種以上及視需要之式（II) [化 20](1) or 2 or more of the polyphosphoric acid phosphate monoesters of the formula (R), R and η, which are the same as defined in the above formula (1). The polyoxonium phosphate triester represented by the formula (I), the polyphosphonium phosphate diester represented by the formula (11) and the polyphosphazene phosphate monoester represented by the formula (III) are as long as the formula 〇 154H6. The effect of the polyoxyphosphoric acid triester shown in doc -15-201136613 as a base material of a cosmetic is not particularly limited, and it is preferred that the polyphosphoric acid triester represented by the formula (1) is 6 〇 to 1 〇〇. Quality ° /. The polyphosphonium phosphate diester represented by the formula (π) is 〇3 to 35 mass%, and the polyphosphonium phosphate monoester represented by the formula (HI) is 〇5 to 5% by mass. The proportion of the polyphosphonium phosphate as a whole in the cosmetic is 丨 50 50% by mass ‘preferably 5 to 3 0 〇/〇» In the cosmetic, the ingredients which can be formulated can be appropriately formulated according to the type. For example, it can be equipped with: oil Qi, j, surfactant, alcohol, water, (four) agent, gelling agent and tackifier, powder, UV absorber, preservative, antibacterial Qi! Antioxidants and skin-care ingredients (whitening agents, cell activators, anti-inflammatory agents, blood circulation promoters, skin astringents, anti-lipids, etc.), vitamins, amino acids, nucleic acids, hormones, and the like. Among these, the oil-based agent (4) is not particularly limited as long as it is a solvent capable of dissolving the above-mentioned polyoxosulfate. By blending Ju Shi Xi (4) vinegar, it has the effect of improving the compatibility of polar oil such as vinegar oil and non-polar oil such as poly-residual oil, so that the effect of the entire oil agent can be uniformly dissolved. The blending amount of the oil agent is not particularly limited, and it is preferably (4) the mass is more preferably 5 to 20% by mass. Examples of the oil agent include solid oils, semi-solid oils, and liquid oils: natural animal and vegetable oils and semi-synthetic oils, hydrocarbon oils, brewing oils, glycerin, polyoxime oil, higher alcohols, higher fatty acids, and organic solvents. Wait. As the solid oil, there may be mentioned natural types such as Brazilian standard woven, candid, shellac, and hardened oil, soil, pure series, microcrystalline ants and other mineral lines, polyethylene woven, Fischer-Tropsch, Ethylene-propylene 154116.doc •16· 201136613 Synthetic ants such as catechins, sorbitol, stearyl alcohol, cholesterol, phytosterols, tertiary alcohols, stearic acid, behenic acid and other high-grade fatty acids. As a natural animal and vegetable oil and semi-synthetic oil in liquid oil, specifically, road pear oil, linseed oil, almond oil, insect butterfly, sage oil, eucalyptus oil, citron oil, liver oil, apricot peach , wheat germ oil, sesame oil, large. "germ oil, rice bran oil, camellia oil, safflower oil, Chinese tung oil, ceylon cinnamon oil, sea turtle oil, soybean oil, tea oil, coiled oil, evening primrose oil, corn oil, Rapeseed oil, Japanese tung oil, nymphalid, germ oil, peach kernel oil, grazing oil, brown sesame oil, linseed oil, Caihuaxuan oil, grape glutinous rice oil, lotus root oil, pecan oil, cottonseed oil, coconut Oil, Sannuo oil fatty acid glycerin, peanut oil, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropyl ester, POE lanolin alcohol ether, POE lanolin alcohol Acetic acid cool, lanolin fatty acid polyethylene glycol vinegar, POE hydrogenated lanolin ether, egg butter and the like. As the fire two 'by', it can be mentioned: squalane, squalene, mobile paraffin, decane, polyisobutylene, etc. As the g-oil, a diisobutyl adipate or a hexyl adipate can be mentioned. Ester, diheptyl deca-adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate 2-ethylhexanoic acid cetyl ester, di-2-ethylhexanoic acid ethylene glycol ester, di-2-ethylhexanoic acid neodecyl glycol ester, tris-2-ethylhexanoic acid trimethylolpropane ester , pentaerythritol tetra-2-hexanoate, cetyl octanoate, octyl dodecyl phthalate, oleyl oleate, octyl lauryl oleate, decyl oleate, diterpenic acid Pentyl glycol ester, triethyl citrate, 2-ethylhexyl succinate, acetic acid 154116.doc • 17- 201136613 酉酉, acetic acid B 3, acetic acid butyl vinegar, hard acid acid (4), Butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactic acid, tetradecyl gluconate, isopropyl palmitate, palmitic acid 2 _Ethyl hexanoic acid, palmitic acid 2-hexyl vinegar, grazing acid 2-heptyl ten A calcined vinegar, 12_base stearic acid, bicarbonate (tetra), dipentaerythritol fatty acid @, 豆豆酸酸 _ meat and acid 2-octyl 12 yard vinegar, meat and vegetable acid 2_己基癸 vinegar, fourteen; ^基@日' dimethyl octanoic acid hexyl vinegar, lauric acid B =, j lauric acid vinegar, N-laurel glutamic acid _2 _ octyl decyl vinegar, Diisostearyl malate and the like. As a glycerin vinegar oil, it can be listed as a glycerin, glycerol triisocaprylate, glyceryl triisostearate, glycerol triisopalmitate, tris-2-ethylidene: glycerin, Monostearic acid glycerin is brewed with heptyl decanoic acid glycerin and trimyristyl glycerate. As a polysulfuric acid oil, it can be listed. • Dimethyl polyoxyalkylene, nonylphenyl polyoxan, methyl hydrogen polyfluorene gas, octadecyl cyclotetraoxane, ten Base ring pentaoxane, dodecyl quinone, 昤^ 〇矽〇矽〇矽、, tetradecyltetrahydrocyclotetrahydrogen, sulphur-based modified poly-stone oxygen. As the higher alcohol, it can be listed as an alcohol, an oil alcohol, lauryl alcohol, stearyl alcohol, isostearyl and t-octyldodecanol. As a higher fatty acid, J歹]: oleic acid, palmitic acid, myristic acid, sorghum, isostearic acid, and the like. As an organic solvent, it can be classified as a hydrocarbon such as n-hexane or cyclohexane, an aromatic compound such as benzene, methyl or monomethylbenzene, or a non-musk proprietary compound such as ethyl acetate or butyl acetate. Chlorine _ _ non-square, gas methane, dichloroethane and other gas system 154116.doc 201136613, ether compounds such as dioxane, tetrahydrofuran, 2-propanol, benzyl alcohol, stupid oxyethanol, carbitol Class '赛赛苏类, polybutene, spin oil, etc. The surfactant is not particularly limited as long as it is generally used for cosmetics, and any of the surfactants may be used: an anionic surfactant, a cationic surfactant, a nonionic surfactant, and both sexes. For the surfactant or the like, these may be used in combination or in combination of two or more. Specific examples of the anionic surfactant include a fatty acid soap such as sodium stearate or triethanolamine palmitate, a carboxylate of an alkyl ether carboxylic acid and a salt thereof, a condensation of an amino acid with a fatty acid, and an alkylsulfonic acid. , alkenyl sulfonate, sulfonate of fatty acid ester, sulfonate of fatty acid decylamine, sulfonate of alkyl sulfonate and its condensate, alkyl sulphate, secondary higher alcohol sulphate Sulfate salts such as salt, hospital base and propyl ether ether sulfate, fatty acid ester sulfate, fatty acid alkyl decyl sulfate, polyoxyethylene alkyl sulfate, and Turkish red oil, An alkyl phosphate, an ether phosphate, an alkyl allyl ether phosphate, a guanamine phosphate, an N-decylamino acid active agent, and the like. As a cationic surfactant, a long-chain alkyltrimethylammonium salt, a di-long-chain alkyldimethylammonium salt, a long-chain alkyldimethylbenzylammonium salt, or a di-oxyethylene alkylammonium salt Salt, dioxyethylene alkyl ether dimethyl ammonium salt, polyoxypropylene thiol-ethyl-ethyl salt salt-based four-stage salt or aromatic four-stage salt is representative, for example, alkyl pyridinium rust An imidazoline salt such as a pyridinium salt such as a salt or an alkyldihydroxyethyl imidazoline salt, or an N-fluorenyl-based amino acid lower alkyl ester salt, and examples thereof include a hospital amine salt, a polyamine, and an amino alcohol. An amine salt such as a fatty acid derivative. 154116.doc •19· 201136613 As a nonionic surfactant, it can be enumerated as: sorbitan fatty acid vinegar 'glycerin fatty acid vinegar, polyglycerin fatty acid brewing, propylene glycol fatty acid vinegar, polyethylene glycol fatty acid vinegar, and recommended fatty acid vinegar. Polyoxyethylene sulphate scale, polyoxypropylene sulphur mystery, polyoxyethylene sulphonic alum, polyoxyethyl hydrazine fatty acid vinegar, polyoxyethylene sorbitan fatty acid vinegar, polyoxyethylene sorbitol fatty acid vinegar, poly Oxyethylene glycerin fatty acid vinegar, polyoxyethylene propylene glycol propylene glycol fatty acid vinegar, polyoxyethylene sesame oil, polyoxyethylene hydrogenated Wei oil, polyoxyethylene strictified sesame oil fatty acid vinegar, polyoxyethylene plant alkanol ether, polyoxyethylene plant Sterol test, polyoxyethylene dihydrocholesterol domain, polyoxyethylene cholesterol test, polyoxygen extension base modified organic poly-stone oxygen burning, polyoxygen extension base, burn-based co-modified organic poly-stone Burning 'house alcohol amine, sugar shouting, sugar-brown amine and so on. Examples of the amphoteric surfactant include carbonyl beet such as a hospital-based di-f-aminoacetic acid beet test, a fatty acid guanamine propyl dimethylaminoacetate (10), and a thioglycolic acid ethylaminoacetate betaine. Alkaline amphoteric surfactant, sulfobetaine type amphoteric surfactant such as alkyl sulfobetaine, N•fatty acid thiol-N-carboxymethyl _N-hydroxyethylethylenediamine salt, N-fatty acid hydrazine Amidoxime type (imidazoline type) amphoteric surfactant such as N-carboxymethoxyethyl_N-carboxymethylethylenediamine di-salt, Ν·[3_alkoxy-2-hydroxypropyl An amino acid type amphoteric surfactant such as arginine, an alkyl iminodicarboxylate type amphoteric surfactant or the like. Specific examples of the alcohols include lower alcohols such as ethanol and isopropyl alcohol, glycerin, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, hydrazine, and 3-butanediol. Polyols such as erythritol, sugar alcohols such as sorbitol, maltose, xylitol, and maltitol. 154116.doc •20· 201136613 Examples of the humectant include urea, hyaluronic acid, chondroitin sulfate, and pyrrolidone carboxylate. As water-based tackifiers and gelling agents, there are: gum arabic, tragacanth, galactan, locust bean gum, guar gum, karaya gum, carrageenan pectin, agar, medlar seed (Marmelo) , 榲樟), starch (rice, corn, potato, wheat), seaweed gum, tranplast gum, locust bean gum, etc. Do not tie to the knife, Erxian gum, dextran, broken jade white sugar, branch Microbial polymers such as starch, collagen, casein, albumin, gelatin and other animal strains, starch molecules such as carboxymethyl starch and mercaptohydroxypropyl starch, sulfhydryl cellulose, ethyl cellulose, Hydroxypropylmethylcellulose, carboxymethylcellulose, hydroxydecylcellulose, hydroxypropylcellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, etc. Cellulose-based polymer, alginic acid-based polymer such as sodium alginate or propylene glycol alginate, vinyl polymer such as polyvinyl decyl ether, carboxyvinyl polymer, alkyl modified carboxyvinyl polymer, or polyoxyethylene Molecular, polyoxyethylene polymerization Acrylic copolymer-based polymer, acrylic polymer such as sodium polyacrylate, polyethyl acrylate or polyacrylamide, inorganic minerals such as bentonite, aluminum magnesium niobate, laponite, hectorite, and anhydrous citric acid Adhesives, polyethyleneimine, cationic polymers, etc. Further, it also includes a film forming agent such as polyvinyl alcohol or polyvinylpyrrolidone. Examples of the oil gelling agent include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristic acid, and amines such as N-lauroside _L·glutamic acid and 〇^_di-n-butylamine. Acid derivatives, palmitic acid dextrin esters, stearic acid dextrin esters, fatty acid dextrin esters such as succinic acid palmitate, sucrose palmitate, stearin I54H6.doc • 21- 201136613 acid Fatty acid sucrose esters such as sucrose esters, benzylidene derivatives of sorbitol such as benzylidene sorbitol, dibenzylidene sorbitol, etc. 何何生物' dimethyl benzyl dodecyl ammonium microcrystalline shale Organically modified clay minerals such as clay, dimethyl-, 4-'...u-(ten/alkyl)ammonium microcrystalline kaolinite clay. As the powder, the shape (spherical shape, 3-shaped shape), particle size (smoke, fine particles, pigment grade, etc.), grain, and '° structure (porous, non-porous, etc.) are not limited. Any one can be used. For example, the ratio of the inorganic powder, the organic powder, the surfactant metal salt powder, the amount of copper enamel, the pearl pigment, the metal powder pigment, and the natural pigment are mentioned. Specific examples include the following. Inorganic powder: titanium oxide, oxidation fault, zinc oxide, cerium oxide, oxidized town, barium sulfate, sulfuric acid mother, sulfuric acid town, carbonic acid, carbonated town, talc, mica, kaolin, sericite, muscovite, synthetic mica, gold Mica, red mica, biotite, clock mica, miracle acid, anhydrous citric acid, broken acid, magnesium citrate, magnesium aluminum citrate, calcium citrate, bismuth citrate, strontium strontium, acid metal salt, Hydroxyapatite, vermiculite, aluminum hydroxide (HIGIUTE), bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, milk oxide, nitriding butterfly, and the like. Organic powder: polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyamino phthalate, benzoguanamine powder, polymethyl cuminamide powder, tetrafluoro Ethylene powder, polymethyl methacrylate powder, cellulose 'silk powder, nylon powder, 12 nylon, 6 nylon, crosslinked polyoxynized powder with a structure of a diterpene-based polyfluorene, and Linked polysecond oxygen network reticulated polyoxyalkylene block copolymer, polymethylsesquioxanes 154116. doc -22- 201136613 fine powder, styrene-acrylic acid copolymer, diphenyl benzene-styrene Copolymer, ethylene resin, urea resin, discretionary resin, fluororesin, lithium resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, starch powder, lauric acid lysine, etc. . Surfactant metal salt powder (metal soap): zinc stearate, stearic acid, stearic acid, stearic acid, myristic acid, magnesium myristate, waxy phosphate, whale Calcium phosphate, sodium cetyl zinc phosphate, and the like. Colored pigments: inorganic red pigments such as iron oxide, iron hydroxide, and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as iron oxide yellow and loess, and inorganic black pigments such as iron oxide black and carbon black; Inorganic purple pigments such as violent purple and cobalt violet; inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide, and cobalt titanate; inorganic blue pigments such as iron blue and ultramarine; and pigmented tar pigments. A resin obtained by subjecting a natural pigment to a lake, and a synthetic resin powder obtained by combining the powders. Pearl pigment: titanium oxide coated mica, titanium oxide coated mica, oxygenated ruthenium, titanium oxide coated ruthenium oxide, titanium oxide coated talc, agmatine base, titanium oxide coated glass powder, titanium oxide coated colored mica, and the like. Metal powder pigment: aluminum powder, copper powder, stainless steel powder, and the like. ..., oil color. Red 3, red 丨〇 4, red 丨〇 6, red 7 tiger, red 202, red 204, red 205, red 220, red 226, red 227, red 228, red 230, red 4〇1, red 5G5, yellow 4, yellow 5, yellow 2 () 2, yellow 2〇3, steam color 204, yellow 401, blue 1 No., blue 2, blue 2〇1, blue 404, green 3, green 201, green 2〇4 154116.doc •23·201136613, green 205, orange 201, orange 203 No., orange 204, orange 206, orange 207, etc. Natural pigments: rouge acid, lacquer acid, safflower, Brazilian hematoxylin, crocin and so on. These powders may be used as they are, or may be used in combination with an oil agent, a polyfluorene oxide, a fluorine compound or the like. The powder may be used singly or in combination of two or more kinds as needed. Examples of the ultraviolet absorber include a benzoic acid-based ultraviolet absorber such as an aminobenzoic acid, an o-amine benzoic acid-based ultraviolet absorber such as methyl ortho-benzoic acid methyl ester, and a salicylic acid-based ultraviolet absorber such as an ylide salicylate. Ultraviolet absorption of urinary acid such as absorbing agent, cinnamic acid ultraviolet absorber such as octyl octyl octyl cinnamate, benzophenone ultraviolet absorbing agent such as 2,4-dihydroxybenzophenone, or urinary acid ethyl ester Agents, etc. Examples of the preservative and the antibacterial agent include p-hydroxybenzoic acid ester, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, salicylic acid, phenolic acid, sorbic acid, and gas. M-cresol, six-gas phenol, gasified benzodiazepine, gasified double gas benzodiazepine, trichlorocarbon bis-diphenylbenzene, photoreceptor, isopropylmethylphenol, and the like. Examples of the antioxidant include tocopherol, butyl hydroxyanisole, and dibutyl fluorenyl benzene. Examples of the pH adjuster include lactic acid, lactate, citric acid, citrate, and glycolic acid. Succinic acid, tartaric acid, malic acid, potassium carbonate, sodium hydrogencarbonate, ammonium hydrogencarbonate, etc., as a chelating agent, examples thereof include alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphate, and hydroxyethyl Examples of the cooling agent include L-menthol 154116.doc •24-201136613 Brain, camphor, peppermint oil, peppermint 〇il, eucalyptus oil, etc., as an anti-inflammatory agent, : allantoin, glycyrrhetinic acid salt, glycyrrhetinic acid derivative, tranexamic acid, chamomile blue, and the like. Examples of the skin-care ingredients include whitening agents such as arbutin, glutathione, and saxifrage extract, cellulite such as royal jelly, photoreceptor, cholesterol derivative, and blood extract of young cow, and skin roughness improving agent. , vanillyl citrate, benzyl nicotinic acid, β-butoxyethyl nicotinic acid, capsaicin, zingerone, canthax, fish fat, caffeine, citric acid, α_borneol, nicotine Tocopherol, nicotinic acid inositol, cyclomandelic acid, cinnarizine, torasolin, acetaminophen, verapamil, cepharanthine, gamma - blood circulation promoters such as oryzanol, skin astringents such as oxidized words and citric acid, anti-lipids such as sulfur and dimethyl thiazide. Examples of the vitamins include vitamin bismuth oil, retinol, retinyl alcohol, palmitic acid, and retinol, vitamin A, riboflavin, butyrate, flavin, and other vitamin B2. , pyridoxine hydrochloride, pyridoxine dicaprylate and other vitamins, 6 types, L-ascorbic acid, L_ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, di_a_tocopherol_L_ Vitamin C such as ascorbyl phosphate dipotassium diacetate, such as calcium pantothenate, D-panthenol, panthenol, and pantothenic acid such as acetaminophen ethyl ether, keratin calciferol, cholecalciferol and other vitamin D, nicotinic acid , nicotinic acid such as benzyl nicotinic acid, nicotinamide, dl_a_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Class e, vitamin p, biotin, etc. As the amino acid, 'exemplified by: arginine, aspartic acid, cystine, cysteine, methionine, serine, leucine, isoleucine, 154116.doc • 25 In the case of the nucleic acid, deoxyribonucleic acid or the like is mentioned, and examples of the hormone include estradiol and ethinyl estradiol. - when the polyphosphonium phosphate triester of the present invention is used alone or a mixture of polyphosphonium phosphate containing the same is used as a cosmetic, it may be prepared by a conventional method using other components as needed, for example, in a liquid form, Various forms such as an emulsion form, a cream form, a solid form, a gel form, and a paste form are used. Further, the cosmetic of the present invention is an oil-based, water-in-oil emulsion or oil-in-water emulsion, and the dosage form thereof is not particularly limited, and specific examples thereof include an emulsion, a cream, a cosmetic liquid, a cosmetic oil, a lipstick, and a care product. Hand cream, facial cleanser and other skin care products, foundation, makeup cream, blush, eye shadow, mascara, eyeliner, eyebrow pencil, overcoat agent, lipstick, lip gloss and other cosmetics, hair care, hair, It is applied in the form of various cosmetic materials such as shampoo, conditioner, conditioner, hair conditioner, and the like for scalp or hair. (4) The surface treatment agent used for the surface-coated powder of the present invention contains the polyphosphonium phosphate triester represented by the above formula (I). Species or more than two and as needed (II) [Chem. 20]

(式中，Ri、R及η與上述式⑴中之定義相同）所示之聚矽氧磷酸二酯中之1種或2種以上，及/或式（III) [化 21] 154116.doc -26 - 201136613(wherein, Ri, R and η are the same as defined in the above formula (1)), one or more of the polyphosphoric acid diesters, and/or the formula (III) [Chem. 21] 154116.doc -26 - 201136613

Ri—$1—Or-SI—oj-SIR·~*0—POfOHh (ID)Ri—$1—Or-SI—oj-SIR·~*0—POfOHh (ID)

Ri nt (式中，R!、R及n與上述式（I)中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上的聚矽氧碟酸醋。式（I)所示之聚矽氧磷酸三酯、式（H)所示之聚矽氧磷酸二酯及式（III)所示之聚矽氧磷酸單酯之調配比例只要式⑴ 所示之聚矽氧磷酸三酯發揮作為粉體之表面處理劑的效果，則無特別限定，較佳為式⑴所示之聚矽氧磷酸三酯為 60〜100質量％、式（11)所示之聚矽氧磷酸二酯為〇〜35質量。/〇、及式（III)所示之聚矽氧磷酸單酯為〇〜5質量％。作為單獨利用上述式⑴所示之聚矽氧磷酸三酯、或利用含有式（I)所不之聚矽氧磷酸三酯之聚矽氧磷酸酯混合物進行表面被覆處理之粉體，其形狀（球狀、針狀、板狀等）或粒徑（煙霧狀、微粒、顏料級等）、粒子結構（多孔質、無孔質等)不P艮，可使用任意者。例如可列舉：無機粉體、有機粉體、界面活性劑金屬鹽粉體、有色顏料、珍珠顏料、金屬粉末顏料、天然色素等。作為具體例，可列舉以下者。無機粉體：氧化鈦、氧化锆、氧化鋅、氧化鈽、氧化鎂、硫酸鋇、硫酸鈣、硫酸鎂、碳酸鈣、碳酸鎂、滑石、雲母、咼嶺土、絹雲母、白雲母、合成雲母、金雲母、紅雲母、黑雲母、鐘雲母、石夕酸、無水石夕酸、石夕酸叙、石夕酸鎮、石夕酸紹鎂、石夕酸！弓、石夕酸鎖、石夕酸錄、、鹤酸金屬踏、羥磷灰石、蛭石、氫氧化鋁、膨潤土、蒙脫石、 154116.doc •27· 201136613 沸石、陶瓷粉末、磷酸氫二轉、氧化鋁、氫氧化鋁、氮化硼等。有機粉體：聚醯胺粉末、聚酯粉末、聚乙烯粉末、聚丙烯粉末、聚苯乙烯粉末、聚胺基甲酸酯、苯并胍胺粉末、聚甲基苯并胍胺粉末、四氟乙烯粉末、聚曱基丙烯酸曱酯粉末、纖維素、絲粉末、尼龍粉末、12尼龍、6尼龍、具有交聯有二曱基聚矽氧之結構的交聯型聚矽氧細粉末、交聯孓聚石夕氧-網狀聚石夕氧嵌段共聚物、聚甲基倍半;ε夕氧烧之細粉末、苯乙烯-丙烯酸共聚物、二乙烯笨·苯乙烯共聚物、乙烯樹脂、尿素樹脂、酚樹脂、氟樹脂、矽樹脂、丙稀8九樹爿a、二聚氛胺樹脂、環氧樹脂、聚碳酸酯樹脂、微晶纖維粉體、澱粉粉末、月桂醯離胺酸等。界面活性劑金屬鹽粉體（金屬皂）：硬脂酸鋅、硬脂酸鋁、硬脂酸鈣、硬脂酸鎂、肉豆蔻酸鋅、肉豆蔻酸鎂、鯨蠟基磷酸鋅、鯨蠟基磷酸鈣、鯨蠟基磷酸鋅鈉等。有色顏料：氧化鐵、氫氧化鐵、鈦酸鐵等無機紅色顏料’ γ-氧化鐵等無機褐色系顏料、氧化鐵黃、黃土等無機黃色系顏料；氧化鐵黑、碳黑等無機黑色顏料；錳紫、鈷兔4無機紫色顏料；氮氧化鉻、氧化鉻、氧化始、鈦酸始 4無機綠色顏料；鐵藍、群青等無機藍色系顏料；使焦油系色素色澱化而成者、使天然色素色澱化而成者、及使該等粉體竣合化而成之合成樹脂粉體等。珍珠顏料：氧化鈦被覆雲母、氧化鈦被覆雲母、氧氯化叙、氧化鈦被覆氧氣化鉍、氧化鈦被覆滑石、阿艮亭鹼、 154116.doc •28· 201136613 氧化鈦被覆玻璃粉末、氧化鈦被覆著色雲母等β 金屬粉末顏料··鋁粉末、銅粉末、不鏽鋼粉末等。焦油色素··紅色3號、紅色104號、紅色1〇6號、紅色2〇1 號、紅色202號、紅色204號、紅色2〇5號、紅色22〇號、紅色226號、紅色227號、紅色228號、紅色23〇號、紅色4 = 號、紅色505號、黃色4號、黃色5號、黃色2〇2號' 黃色 2〇3號、黃色204號、黃色4〇1號、藍色㈣、藍色现、、藍色201號、藍色4〇4號 '綠色3號、綠色训號、綠色如號、綠色205號、橙色201號、橙色2〇3號、橙色2〇4號撥色206號、橙色2〇7號等。且天然色素：胭脂色酸、蟲漆酸、紅花素、巴西蘇木素、藏花素等。 ” 該等粉體可直接使肖，亦可使該等粉體複合化，或利用油劑、聚石夕氧、氣化合物等進行表面處理而使用。上述粉體可根據目的或用途適當選擇使用，其中，較佳為氧化鈦、氧化鋅、氧化鐵等金屬氧化物。於本發明中’作為對該等粉體進行表面被覆含有上述式 ⑴所不之聚碎㈣酸三g旨之聚石夕氧破酸g旨之處理之方法，並無特別限定，可使用通常公知之處理方法。具體可列舉：/接與粉體混合之方法（乾式處理法），使用乙醇、異丙醇、正己烷、苯、甲笨等溶劑之方法(濕式法），氣相法’機械化學法等。例如’可列舉於亨舍爾混合機等混合機中添加己烧等溶劑與含有上述式（I)所示之聚％氧賴三_之聚發氧構酸酷 154116.doc •29· 201136613 使其/合解後，添加粉體使其 J J刀敢。Μ而一面攪拌該浴液一面加熱至1〇crc左右，於減壓下餾去溶劑，冷卻至室溫後，利用粉碎機等粉碎處理機進行粉碎，從而獲得被覆表面之粉體的方法。其後，亦可於阶以上之溫度下進行煅燒處理》又，於本發明中，亦可同時對粉體進行被覆含有上述式 ⑴所示之聚錢«三自旨之㈣氧碟_旨並且料氧化合物、氣化合物、油劑、油脂、高級醇、蠟、高分子、樹脂等通常公知之表面處理劑之處理。可選擇該等其他表面處理劑中之！種或2種以上，尤其若同時進行被覆有機欽酸醋表面處理劑之處理，則表面被覆粉體對油劑之分散性提高，故而較佳。有機鈦酸酯可列舉具有烷氧基之例如長鏈羧酸型、焦磷酸型、亞_請、胺基酸型等烧基欽酸醋等。作為有機欽酸酯之烷氧基，就與粉體之反應性之觀點而言，較佳為具有碳數1〜4之烷基者，該等可為直鏈亦可分支，例如可列舉.甲氧基、乙氧基、丙氧基、丁氧基等。該等有機鈦酸酯中，若選擇具有碳數8〜22之烷基之長鏈羧酸型烧基鈦酸酯，則就分散性之觀點而言較佳，該等可例示下式（VI) (R2〇)-Ti-(OCOR3)3 (VI) (式中’ R2表示碳數1〜4之烷基，r3表示碳數8〜22之烷基，該專烧基可為直鍵亦可分支）所示之化合物。具體而言’可列舉：異丙基三異硬脂基鈦酸酯、異丙基 154I16.doc •30- 201136613 三異十四醯基鈦酸酯、異丙基三辛醯基鈦酸酯、甲基三異硬脂醯基鈦酸酯、甲基三異十四醯基鈦酸酯、乙基三異硬脂醯基鈦酸酯、乙基三異十四醯基鈦酸酯等，該等可使用 1種或2種以上。該等之中，若選擇異丙基三異硬脂基欽酸酯，則油劑中之表面被覆粉體之分散性成為良好，故而尤佳。又，於使複數種表面處理劑同時進行被覆處理之情形時，若選擇能夠使複數種表面處理劑一併均勻溶解之溶劑’並利用濕式法進行’則可對粉體表面進行均勾地被覆處理’故而較佳。本發明之表面處理粉體係粉體表面經含有上述式⑴所示之聚石夕氧《三S旨之聚♦氧錢酯被覆者，其被覆量並益特別限定，相對於粉體較佳為Q.G1〜5f量％。若在該範圍内’則可獲得耐水性及對皮膚之附著性尤其優異之表面被覆粉體。又於與有機鈦酸醋等複數種表面處理劑同時進行被覆。處理之情形時，表面處理劑之合計量較佳為001〜10質量。此時，含有上豸式⑴所示之聚石夕氧鱗酸三醋之聚石夕氧鱗酸酿與其他表面處理劑之質量比較佳為1:9〜9:1之範圍，進而’右為1:3〜3:1之範圍，則可獲得對油劑之分散性尤其優異之表面被覆粉體。从於將本發明之表面被覆處理粉體用作化妝料之情形時， =依據常規方法使上述表面被覆處理粉體中之！種或2種、^ A知之化妝料成分組合調配而製造。本發明之化妝 154116.doc • 31 - 201136613 料中之該表面被覆處理粉體之調配量並無特別限定，根據化妝料之劑型或對象（Item)而有所不同，為1〜90質量％，較佳為5〜40質量％。於化妝料中，可根據種類適當調配能夠調配之成分。例如可調配：油劑、界面活性劑、醇類、水、保濕劑、凝膠化劑及增黏劑、除上述經表面被覆處理以外之粉體、紫外線吸收劑、.防腐劑、抗菌劑、抗氧化劑、美膚用成分 (美白劑、細胞賦活劑、消炎劑、血液循環促進劑、皮膚收斂劑、抗脂溢劑等）、維生素類、胺基酸類、核酸、激素等。具體可列舉與「3含有聚矽氧磷酸三酯之化妝料」之項中所列舉者相同者。又，於將本發明之表面被覆處理粉體用作化妝料之情形時’可與「3含有聚矽氧磷酸三酯之化妝料」之項所記載者同樣地以各種形態、對象而實施。 5含有聚矽氧磷酸三酯之粉體分散劑本發明之粉體分散劑含有上述式⑴所示之聚石夕氧填酸三醋中之1種或2種以上及視需要之式（π) [化 22]One or two or more kinds of polyoxosilicate vinegar of Ri nt (wherein R!, R and n are the same as defined in the above formula (I)). The ratio of the polyphosphonium phosphate triester represented by the formula (I), the polyphosphonium phosphate diester represented by the formula (H) and the polyphosphazene phosphate monoester represented by the formula (III) is as shown in the formula (1). The polyphosphonium phosphate triester exhibits an effect of the surface treatment agent of the powder, and is not particularly limited, and is preferably a polyphosphonium phosphate triester represented by the formula (1) in an amount of 60 to 100% by mass, represented by the formula (11). The polyphosphonium phosphate diester is 〇~35 mass. The polyphosphonium phosphate monoester represented by the formula (III) is 〇 5% by mass. As a powder which is subjected to surface coating treatment by using the polyphosphonium phosphate triester represented by the above formula (1) or a polyphosphonium oxyphosphate mixture containing the polyphosphonium phosphate triester of the formula (I), the shape thereof ( Any of spherical material, needle shape, plate shape, or particle size (smoke, fine particles, pigment grade, etc.) or particle structure (porous, non-porous, etc.) may be used. For example, inorganic powders, organic powders, surfactant metal salt powders, colored pigments, pearl pigments, metal powder pigments, natural pigments, and the like can be mentioned. Specific examples include the following. Inorganic powder: titanium oxide, zirconium oxide, zinc oxide, antimony oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, muscovite, synthetic mica , phlogopite, red mica, biotite, clock mica, ashes acid, anhydrous stone acid, Shi Xi acid, Shi Xi acid town, Shi Xi acid Shao magnesium, Shi Xi acid! Bow, Shixi acid lock, Shixi acid record, tartaric acid metal, hydroxyapatite, vermiculite, aluminum hydroxide, bentonite, montmorillonite, 154116.doc •27· 201136613 zeolite, ceramic powder, hydrogen phosphate Two turns, alumina, aluminum hydroxide, boron nitride, and the like. Organic powder: polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoro Ethylene powder, polydecyl methacrylate powder, cellulose, silk powder, nylon powder, 12 nylon, 6 nylon, crosslinked polyoxynized fine powder having a structure of crosslinked dimercaptopolyoxyl, cross-linking孓石氧氧 - 网网网网网网网网网 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Urea resin, phenol resin, fluororesin, enamel resin, acryl 8 爿 a, dimeric amine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, starch powder, lauric acid lysine, etc. . Surfactant metal salt powder (metal soap): zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, cetyl zinc phosphate, cetyl wax Calcium phosphate, sodium cetyl zinc phosphate, and the like. Colored pigments: inorganic red pigments such as iron oxide, iron hydroxide, and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as iron oxide yellow and loess; inorganic black pigments such as iron oxide black and carbon black; Manganese violet, cobalt rabbit 4 inorganic purple pigment; chromium oxynitride, chromium oxide, oxidation start, titanic acid 4 inorganic green pigment; iron blue, ultramarine and other inorganic blue pigment; tar pigment pigmentation, A resin obtained by lake-forming a natural pigment, and a synthetic resin powder obtained by kneading the powders. Pearl pigment: titanium oxide coated mica, titanium oxide coated mica, oxychlorinated, titanium oxide coated oxygenated cerium, titanium oxide coated talc, aztec base, 154116.doc •28·201136613 titanium oxide coated glass powder, titanium oxide It is coated with β metal powder pigment such as colored mica, aluminum powder, copper powder, stainless steel powder, and the like. Tar color ··Red 3, red 104, red 1〇6, red 2〇1, red 202, red 204, red 2〇5, red 22〇, red 226, red 227 , red 228, red 23 、, red 4 =, red 505, yellow 4, yellow 5, yellow 2 〇 2 'Yellow 2〇3, yellow 204, yellow 4〇1, blue Color (four), blue present, blue 201, blue 4〇4 'green 3, green training number, green number, green 205, orange 201, orange 2〇3, orange 2〇4 No. 206, orange 2, 7 and so on. And natural pigments: blush acid, laccase acid, safflower, Brazilian hematoxylin, crocin and so on. These powders may be directly used for the purpose of compounding the powders, or may be used by surface treatment with an oil agent, a polysulfide, a gas compound, etc. The above powders may be appropriately selected depending on the purpose or use. In the present invention, a metal oxide such as titanium oxide, zinc oxide or iron oxide is preferred. In the present invention, the surface of the powder is coated with a polycrystalline stone containing the poly(tetra) acid of the above formula (1). The method for treating the oxygen-decomposing acid is not particularly limited, and a generally known treatment method can be used, and specific examples thereof include a method of mixing with a powder (dry treatment method), and using ethanol, isopropanol, and hexane. A method of a solvent such as an alkane, a benzene or a methyl group (wet method), a gas phase method, a mechanochemical method, etc. For example, a solvent such as hexane or the like may be added to a mixer such as a Henschel mixer and the above formula (I) ) The poly-oxygen lanthanum _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 1 〇 crc, distilling off the solvent under reduced pressure, cooling After the room temperature, the powder is pulverized by a pulverizer such as a pulverizer to obtain a powder covering the surface. Thereafter, the powder may be calcined at a temperature higher than the order. Further, in the present invention, it may be simultaneously The powder is coated with a generally known surface containing the above-mentioned formula (1), and the oxygen-containing compound, the gas compound, the oil agent, the oil, the oil, the higher alcohol, the wax, the polymer, the resin, and the like. Treatment of the treatment agent. It is possible to select one or more of these other surface treatment agents, and in particular, when the organic acid vinegar surface treatment agent is simultaneously treated, the dispersibility of the surface coating powder to the oil agent is improved. The organic titanate may, for example, be a long-chain carboxylic acid type, a pyrophosphoric acid type, a sub-acid, an amino acid type, or the like having an alkoxy group. The base is preferably an alkyl group having a carbon number of 1 to 4 from the viewpoint of reactivity with the powder, and these may be linear or branched, and examples thereof include a methoxy group and an ethoxy group. Propoxy, butoxy, etc. the organic titanic acid In the ester, when a long-chain carboxylic acid-type alkyl titanate having an alkyl group having 8 to 22 carbon atoms is selected, it is preferable from the viewpoint of dispersibility, and the following formula (VI) (R2〇) can be exemplified. -Ti-(OCOR3)3 (VI) (wherein R2 represents an alkyl group having 1 to 4 carbon atoms, and r3 represents an alkyl group having 8 to 22 carbon atoms, and the specific alkyl group may be a straight bond or a branch) Specific examples - exemplified by: isopropyl triisostearyl titanate, isopropyl 154I16.doc • 30-201136613 triisotetradecyl titanate, isopropyl trioctyl decyl titanate , methyl triisostearyl phthalocyanate, methyl triisotetradecyl titanate, ethyl triisostearyl phthalate, ethyl triisotetradecyl titanate, etc. One or two or more kinds of these may be used. Among them, when isopropyl triisostearyl phthalate is selected, the dispersibility of the surface-coated powder in the oil agent is particularly good, and therefore it is particularly preferable. Further, when a plurality of types of surface treatment agents are simultaneously subjected to coating treatment, if a solvent capable of uniformly dissolving a plurality of kinds of surface treatment agents is selected, and the wet method is used, the surface of the powder can be uniformly The coating process is therefore preferred. The surface of the powder of the surface-treated powder system of the present invention is preferably coated with a polyoxo-oxygen ester coating containing the polyoxo oxygen of the above formula (1), and the amount thereof is particularly limited, and is preferably defined with respect to the powder. Q.G1~5f%. If it is within this range, a surface-coated powder which is particularly excellent in water resistance and adhesion to skin can be obtained. Further, it is coated at the same time as a plurality of surface treatment agents such as organic titanate. In the case of treatment, the total amount of the surface treating agent is preferably 001 to 10 mass. At this time, the mass of the polyoxo sulphuric acid syrup containing the polyoxazine sulphate as shown in the above formula (1) is preferably in the range of 1:9 to 9:1, and further to the right. When it is in the range of 1:3 to 3:1, a surface-coated powder which is particularly excellent in dispersibility of an oil agent can be obtained. From the case where the surface-coated powder of the present invention is used as a cosmetic, the surface is coated with the powder according to a conventional method! It is produced by combining or combining two kinds of cosmetic ingredients. The amount of the surface-coated powder to be treated in the present invention is not particularly limited, and varies depending on the dosage form or the object of the cosmetic, and is 1 to 90% by mass. It is preferably 5 to 40% by mass. In the cosmetic, the ingredients that can be formulated can be appropriately formulated according to the type. For example, it can be adjusted: oil agent, surfactant, alcohol, water, moisturizer, gelling agent and tackifier, powders other than the above surface coating treatment, ultraviolet absorber, preservative, antibacterial agent, Antioxidant, skin care ingredients (whitening agents, cell activators, anti-inflammatory agents, blood circulation promoters, skin astringents, anti-lipids, etc.), vitamins, amino acids, nucleic acids, hormones, and the like. Specific examples thereof are the same as those listed in the section "3 Cosmetics containing polyphosphoric acid triester". In the case where the surface-coated powder of the present invention is used as a cosmetic, it can be carried out in various forms and objects in the same manner as described in the section "3 Cosmetics containing polyphosphoric acid triester". (5) The powder dispersing agent containing the polyphosphonium phosphate triester, the powder dispersing agent of the present invention contains one or more of the polyoxanthic acid triacetate represented by the above formula (1), and a desired formula (π ) [Chem. 22]

(式中，R]、R及η與上述式⑴中之定義相同）所示之聚矽氧鱗酸二醋中之1種或2種以上，及/或式（ΙΠ) [化 23] 154116.doc -32- 201136613(in the formula, R, R and η are the same as defined in the above formula (1)), one or more of the polyoxonic acid diacetates, and/or the formula (ΙΠ) [Chem. 23] 154116 .doc -32- 201136613

(式中’ R!、R及η與上述式（I)中之定義相同）所示之聚石夕氧磷酸單酯中之1種或2種以上。式⑴所示之聚矽氧磷酸三酯、式（II)所示之聚矽氧磷酸一西曰及式（III)所示之聚石夕氧鱗酸單醋的調配比例只要式（I) 所示之聚矽氧磷酸三酯發揮作為化妝料之分散劑的效果，則無特別限定，較佳為式⑴所示之聚矽氧磷酸三酯為 60〜100質量％、式（η)所示之聚矽氧磷酸二酯為〇〜35質量 0/〇、及式（III)所示之聚矽氧磷酸單酯為〇〜5質量％。含有上述粉體分散劑之粉體分散體為含有以下成分之油中分散組成物。 (A) 含有上述式⑴所示之聚矽氧磷酸三酯之粉體分散劑 (B) 粉體及 OP田劑本發明之粉體分散體中之含有聚碎氧磷酸三S旨之聚石夕氧填酸醋的調配量並無特別限定，於不含其他粉體分散劑之情形時’較佳為以質量比計相對於粉體_。又，於本發明之粉體分散體令，較佳為進而含有除本發明之粉體分散劑以外之粉油-有所^ 劑，亦根據成為分散媒之伸院基改氧、胺基；⑽聚氧貞^矽氧、烷基改質聚矽裊、聚甘油改質聚⑦氧等改質㈣氧類質= 酸、丙烯酸-聚矽氧接枯土夕烷氧基矽接枝聚合物等聚矽氧樹脂，聚羥基硬 1541I6.doc • 33 - 201136613 ㈣類L旨類，聚氧乙料絲、去水山梨醇脂肪酸西曰聚氧乙烯院基碟酸西旨、脂肪酸聚甘油酿等非離子性界面活性劑類。關於本發明之粉體分散體中使用之粉體，其形狀(球狀針狀、板狀等）或粒徑（煙霧狀、微粒、顏料級等）、粒子結構（多孔質、無孔質等）不限，亦可使用任意者。例如可列舉·無機粉體、有機粉體、界面活性劑金屬鹽粉體、有色顏料、珍珠顏料、金屬粉末顏料、天然色素等。作為具體例，可列舉與經表面被覆處理之粉體相同者。粉體可根據目的或用途適當選擇使用，其中較佳為氧化鈦、氧化鋅、氧化鐵等金屬氧化物。又本發明之粉體分散體中之粉體的調配量並無特別限定，較佳為1〜50質量％，更佳為5〜4〇質量％。作為本發明之粉體分散體所使用之油劑，只要為室溫下為液狀之油劑，則均可使用。作為具體例，可列舉以下者。聚石夕氧油甲基聚#氧炫、甲基苯基聚碎氧燒、甲氫聚石夕氧院、甲基聚三甲基石夕氧燒、二甲基石夕氧貌_甲苯基石夕氧统共聚物等絲度至高黏度之有機料氧院；甲基環四石夕氧烧、+曱基環五石夕氧烧、十二甲基環六石夕烷、四甲基四氫環四矽氧烷、四甲基四苯基環四矽氧燒四甲基四（三氣丙基）環四發氧燒、S曱基五（三氣丙基、五矽氧烷等環狀矽氧烷等。；全氟辛烷等。氣系油劑··全氟聚驗、全氟十氣蔡 I54116.doc -34 - 201136613 烴油：直鏈狀、支鏈狀、進而揮發性烴油等。具體可列舉：α-烯烴低聚物、輕質異構石蠟、輕質流動異構石蠟、角鯊烷、合成角鯊烷、植物性角鯊烷、角鯊烯、流動石蠘、流動異構石鐵、聚丁稀、異十二院等。醋油.己二酸二異丁酯、己二酸2_己基癸酯、己二酸二-2-庚基十一烷基酯、單異硬脂酸Ν_烷基乙二醇酯、異硬脂酸異錄躐酯、三異硬脂酸三經甲基丙烧酯、異壬酸異壬酯、異壬酸異十三烷基酯、二_2_乙基已酸乙二醇酯、2_ 乙基已酸舒、壤醋、三-2-乙基已酸三經甲基丙烧醋、四_2_ 乙基已酸季戊四醇酯、辛酸鯨躐酯、油醇油酸酯、油酸辛基十一烧基、油酸癸Sa、一癸酸新戍二醇§旨、檸樣睃三乙酯、丁二酸2 -乙基己酯、乙酸戊酯、乙酸乙酯、乙酸丁酯、硬脂酸異録躐酯、硬脂酸丁酯、癸二酸二異丙醋、癸二酸二-2-乙基己酯、乳酸鯨蠟酯、乳酸十四烷基酯、棕櫊酸異丙酯、棕櫊酸2-乙基己酯、棕櫚酸2-己基癸酯、棕摘酸2-庚基Η--烧基酯、肉豆蔻酸異丙酯、肉豆蔻酸辛基十二烷基酯、肉豆蔻酸2-己基癸酯、肉豆蔻酸十四烧基酯、二曱基辛酸己基癸酯、月桂酸乙酯、月桂酸己酯、Ν-月桂醯-L-麩胺酸-2-辛基十二烷基酯、蘋果酸二異硬脂酯等。甘油酯油：乙酸甘油酯、三異辛酸甘油酯、三異硬脂酸甘油酯、三異棕橺酸甘油酯、單硬脂酸甘油酯、二-2-庚基十一酸甘油酯、三肉豆蔻酸甘油酯、肉豆蔻酸異硬脂酸二甘油酯等。高級脂肪酸：Η—碳烯酸、油酸、亞麻油酸、次亞麻油 154116.doc -35- 201136613 酸、花生四烯酸、二十碳五烯酸（EPA，Eie〇sapentaen〇ic acid)、_ 十二碳六稀酸（dha，Docosahexaenoic acid)、異硬脂酸、乳酸等。高級醇：油醇、異硬脂醇、己基癸醇、辛基十二烷醇、 2-癸基十四醇、單油基甘油醚（鯊油醇）等。天然動植物油劑及半合成油劑：酪梨油、杏仁油、撖欖油、肝油、杏桃仁油、小麥胚芽油、芝麻油、大米胚芽油、米糠油、山茶油、紅花子油、中國桐油、海龜油、大豆油、茶籽油、樁油、月見草油、玉米油、菜籽油、曰本桐/由、胚芽油、桃仁油、蓖麻油、蓖麻油脂肪酸甲酯、葵化籽油、葡萄籽油、荷荷芭油、澳洲胡桃油、貂油、繡綠菊油（Meaci〇wfoam)、棉籽油、三椰子油脂肪酸甘油酯花生油、液狀羊毛脂、乙酸羊毛醇酯、羊毛脂脂肪酸聚乙二醇酯、蛋黃油等。 — 有機溶劑：正己烷、環己烷等烴，苯、甲苯、二曱笨等芳香族化合物，乙酸乙酯、乙酸丁酯等非芳香族系化合物’氣仿、二氣甲&、二氣乙院等氯系化合物，H 四虱呋喃等醚系化合物’ 2·丙醇、苄醇、苯氧基乙醇、卡必醇類’赛珞蘇類，錠子油等。本發明之粉體分散體中之油劑之調配量並無特別限定，較佳為1〜50質量％，更佳為5〜40質量％。又二本發明之粉體分散體可利用公知之方法而製備。例如可藉由於上述油劑中使粉體分散劑溶解或分散，於其中添加粉體’利用球磨機、珠磨機、砂磨機、塗料振盪器等 154116.doc • 36 - 201136613 分散機器進行混合之方法等，而較容易地獲得。又，所得之粉體分散體可直接調配至化妝料等中。本發明之粉體分散體可用於各種用途，可調配至護膚製品、彩妝製品、頭髮製品、止汗劑製品、防紫外線製品等尤其外用於皮膚或毛髮上之全部化妝料。又，除化妝料以外，亦可應用於墨水、塗料、塑膠用顏料等。雖根據化妝料之種類及劑型而有所不同，但大致相對於化妝料整體可調配0.1〜99質量°/。之上述粉體分散體，更佳為2〜80質量。若少於〇. 1質量％，則存在調配至化妝料中之效果未充分表現之情況。再者，該等粉體分散體可根據目的或用途適當選擇1種或2種以上而使用。於化妝料中，可根據種類適當調配能夠調配之成分。例如可調配：油劑、界面活性劑、醇類、水、保濕劑、凝膠化劑及增黏劑、除上述經表面被覆處理以外之粉體、紫外線吸收劑、防腐劑、抗菌劑、抗氧化劑、美膚用成分 (美白劑、細胞賦活劑、消炎劑、血液循環促進劑、皮膚收斂劑、抗脂溢劑等）、維生素類、胺基酸類、核酸、激素等。具體可列舉與「3含有聚矽氧磷酸三酯之化妝料」之項中所舉出者相同者。又’於將本發明之粉體分散體用作化妝料之情形時，可與「3含有聚矽氧磷酸三酯之化妝料」之項中所記載者同樣地以各種形態、對象而實施。 [實施例] 以下表示實施例，但本發明並不限定於該等實施例。再 154116.doc -37- 201136613 者，於以下實施例中’ ％意指質量％。 1聚矽氧磷酸三酯之製造例 [製造實施例1] 將曱醇改質聚矽氧（式2)265 g、四氩呋喃136 g加以混合，冷卻至-40°C。滴加二異丙基醯胺鋰（LDA，Lithium diisopropylamide)(l mol/THF(四氫咬喃，Tetrahydrofuran) 溶液）200 ml並反應90分鐘後，添加構醯氣（式1)7.8 g並反應1小時。將溫度升高至25°C而進一步熟化2小時後，添加濃鹽酸42 g使反應結束。利用曱醇進行清洗並餾去溶劑，藉此獲得包含聚矽氧磷酸三酯之混合物》所得之混合物之組成比係藉由31P-NMR(核磁共振，Nuclear magnetic resonance)測定，作為三酯體之式⑴為92%，作為二酯體之式（II)為1 %，包含其他聚墙酸之副產物為7〇/〇。 [化 24](In the formula, one or more of the polyoxophosphoric acid monoesters represented by the above-mentioned formulas (R), R and η are the same as defined in the above formula (I)). The ratio of the polyphosphonium phosphate triester represented by the formula (1), the polyphosphonium phosphate monoterpene represented by the formula (II), and the polyoxime monooleic acid represented by the formula (III) is as long as the formula (I) The polyoxophosphoric acid triester shown is not particularly limited as it is a dispersing agent for a cosmetic, and it is preferably 60 to 100% by mass of the polyphosphoric acid triester represented by the formula (1), and the formula (η) The polyphosphonium phosphate diester is 〇~35 mass 0/〇, and the polyphosphonium phosphate monoester represented by the formula (III) is 〇5 mass%. The powder dispersion containing the above powder dispersant is an oil dispersion composition containing the following components. (A) Powder dispersant (B) powder containing the polyphosphonium phosphate triester represented by the above formula (1), and OP field agent. The powder containing the polysodium oxyphosphoric acid trihydrate in the powder dispersion of the present invention The amount of the acid-filled vinegar is not particularly limited, and in the case where the other powder-dispersing agent is not contained, it is preferably a mass ratio with respect to the powder_. Further, in the powder dispersion of the present invention, it is preferred to further contain a powder oil-containing agent other than the powder dispersant of the present invention, and also to change the oxygen and amine groups according to the dispersion medium to be a dispersion medium; (10) Polyoxygen 贞矽矽矽烷基烷基烷基烷基烷基烷基烷基烷基 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Polyoxyl resin, polyhydroxyl hard 1541I6.doc • 33 - 201136613 (4) Class L, polyoxyethylene wire, sorbitan fatty acid, oxime polyoxyethylene, based on the acid dish, fatty acid polyglycerol, etc. Nonionic surfactants. The powder used in the powder dispersion of the present invention has a shape (spherical needle shape, plate shape, etc.) or particle diameter (smoke shape, fine particles, pigment grade, etc.), particle structure (porous, nonporous, etc.) ) Not limited to, you can use any one. For example, an inorganic powder, an organic powder, a surfactant metal salt powder, a colored pigment, a pearl pigment, a metal powder pigment, a natural pigment, or the like can be given. Specific examples thereof are the same as those of the surface-coated powder. The powder may be appropriately selected depending on the purpose or use, and among them, a metal oxide such as titanium oxide, zinc oxide or iron oxide is preferred. Further, the amount of the powder in the powder dispersion of the present invention is not particularly limited, but is preferably from 1 to 50% by mass, more preferably from 5 to 4% by mass. The oil agent used as the powder dispersion of the present invention can be used as long as it is a liquid oil at room temperature. Specific examples include the following. Ju Shi Xi Oxygen Oil Methyl Poly # Oxygen, Methyl Phenyl Polyoxygen Oxide, Hydrogenation, Oxygen, Oxygen, Methyl Polytrim, Oxygen, Dimethyl, Oxygen Organic copolymers such as copolymers with high viscosity to high viscosity; methyl ring four-stone oxy-oxygen, + fluorenyl ring five-stone oxy-oxygen, dodecamethylcyclohexadecene, tetramethyltetrahydrotetracycline a siloxane, a tetramethyltetraphenyl sulfonium tetrahydrogen, a tetramethyltetrakis(trimethyl propyl) ring, a tetrahydrogenation, a sulfonium quinone (trimethyl propyl, a pentoxide, etc.) Alkane, etc.; perfluorooctane, etc. Gas-based oil agent··Perfluoro-polymerization, perfluorinated gas, I54116.doc -34 - 201136613 Hydrocarbon oil: linear, branched, and thus volatile hydrocarbon oil Specific examples include α-olefin oligomers, light isoparaffin waxes, light mobile isoparaffins, squalane, synthetic squalane, phytosqualane, squalene, mobile sarcophagus, and mobile Physic iron, polybutylene, different twelve yards, etc. vinegar oil, diisobutyl adipate, 2-hexyl decyl adipate, di-2-heptyl undecyl adipate, single Barium isostearate_alkyl glycol ester, different Isohexyl lipoate, trimethyl propyl acetoacetate, isodecyl isononanoate, isotridecyl isononanoate, ethylene glycol di-2-ethylhexanoate, 2_ Ethyl hexanoate, vinegar, tris-ethylhexanoic acid trimethyl propyl vinegar, tetrakis-2-ethylhexaerythritol pentaerythritol, octanoic acid whale ester, oleyl oleate, oleic acid octyl Eleven base, lanthanum oleate Sa, decanoic acid neodecanediol §, lemon-like triethyl ester, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, hard Isohexyl lipoate, butyl stearate, diisopropyl vinegar, di-2-ethylhexyl sebacate, cetyl lactate, tetradecyl lactate, isopropyl palmitate Ester, 2-ethylhexyl palmitate, 2-hexyl decyl palmitate, 2-heptyl hydrazine-bromoester, isopropyl myristate, octyldodecyl myristate , 2-hexyl decyl myristate, tetradecyl myristate, hexyl decyl decyl octoate, ethyl laurate, hexyl laurate, Ν-laurel-L-glutamic acid-2- Octyl dodecyl ester, diisostearyl malate, etc. glyceride oil: acetic acid Ester, triisooctanoic acid glyceride, glyceryl triisostearate, glyceryl triisophyllin, glyceryl monostearate, glyceryl di-2-heptyl undecanoate, glyceryl trimyristate, Higher acid fatty acid: Η-carbenoic acid, oleic acid, linoleic acid, sub-linseed oil 154116.doc -35- 201136613 Acid, arachidonic acid, eicosapentaene Acid (EPA, Eie〇sapentaen〇ic acid), _dosa, Docosahexaenoic acid, isostearic acid, lactic acid, etc. Higher alcohols: oleyl alcohol, isostearyl alcohol, hexyl decyl alcohol, octyl Dodecyl alcohol, 2-decyltetradecyl alcohol, monooleyl glyceryl ether (squalene alcohol), and the like. Natural animal and vegetable oils and semi-synthetic oils: avocado oil, almond oil, eucalyptus oil, liver oil, apricot kernel oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, camellia oil, safflower oil, Chinese tung oil, Turtle oil, soybean oil, tea seed oil, pile oil, evening primrose oil, corn oil, rapeseed oil, 曰本桐/由, germ oil, peach kernel oil, castor oil, castor oil fatty acid methyl ester, sunflower oil, grape Seed oil, jojoba oil, Australian walnut oil, eucalyptus oil, Meaci〇wfoam, cottonseed oil, three coconut oil fatty acid glyceride peanut oil, liquid lanolin, lanolin acetate, lanolin fatty acid Ethylene glycol ester, egg butter, etc. —Organic solvents: hydrocarbons such as n-hexane and cyclohexane, aromatic compounds such as benzene, toluene, and dioxane, non-aromatic compounds such as ethyl acetate and butyl acetate, gas, two gas, and two gas. A chlorine-based compound such as a hospital, an ether compound such as H tetrafurfuran, a propanol, a benzyl alcohol, a phenoxyethanol, a carbitol, a celecose, a spindle oil, or the like. The blending amount of the oil agent in the powder dispersion of the present invention is not particularly limited, but is preferably 1 to 50% by mass, more preferably 5 to 40% by mass. Further, the powder dispersion of the present invention can be produced by a known method. For example, the powder dispersant may be dissolved or dispersed in the above oil agent, and the powder may be added thereto by using a ball mill, a bead mill, a sand mill, a paint shaker, etc., 154116.doc • 36 - 201136613 Dispersing machine for mixing Methods, etc., are easier to obtain. Further, the obtained powder dispersion can be directly formulated into a cosmetic or the like. The powder dispersion of the present invention can be used for various purposes, and can be formulated into skin care products, color cosmetics products, hair products, antiperspirant products, ultraviolet protection products, and the like, which are especially applied to the skin or hair. In addition to cosmetics, it can also be used in inks, paints, and pigments for plastics. Although it varies depending on the type of the cosmetic material and the dosage form, it is generally adjustable to 0.1 to 99% by mass relative to the total amount of the cosmetic material. The above powder dispersion is more preferably 2 to 80 mass. If it is less than 0.1% by mass, there is a case where the effect of blending into the cosmetic is not sufficiently exhibited. In addition, one or two or more types of the above-mentioned powder dispersions can be appropriately selected depending on the purpose or use. In the cosmetic, the ingredients that can be formulated can be appropriately formulated according to the type. For example, it can be adjusted: oil agent, surfactant, alcohol, water, moisturizer, gelling agent and tackifier, powders other than the above surface coating treatment, ultraviolet absorber, preservative, antibacterial agent, anti-drug Oxidizing agents, skin-care ingredients (whitening agents, cell activators, anti-inflammatory agents, blood circulation promoters, skin astringents, anti-lipids, etc.), vitamins, amino acids, nucleic acids, hormones, and the like. Specific examples thereof are the same as those mentioned in the section "3 Cosmetics containing polyphosphoric acid triester". In the case where the powder dispersion of the present invention is used as a cosmetic, it can be carried out in various forms and objects in the same manner as those described in the section "3 Cosmetics containing polyphosphoric acid triester". [Examples] Examples are shown below, but the present invention is not limited to the examples. Further, 154116.doc -37-201136613, in the following examples, '% means mass%. Production Example of 1 Polyoxyphosphoric Triester [Production Example 1] 265 g of decyl alcohol modified polyoxo (formula 2) and 136 g of tetrahydrofuran were mixed and cooled to -40 °C. After adding 200 ml of LDP, Lithium diisopropylamide (1 mol/THF (Tetrahydrofuran) solution) and reacting for 90 minutes, 醯g gas (Formula 1) 7.8 g was added and reacted. 1 hour. After the temperature was raised to 25 ° C and further aging for 2 hours, 42 g of concentrated hydrochloric acid was added to complete the reaction. The composition ratio of the mixture obtained by washing with decyl alcohol and distilling off the solvent, thereby obtaining a mixture containing polyphosphoric acid triester, is determined by 31P-NMR (Nuclear magnetic resonance) as a triester body. The formula (1) is 92%, the diester body has a formula (II) of 1%, and the by-product containing other polywall acid is 7〇/〇. [Chem. 24]

[製造實施例2] 將曱醇改質聚矽氧（式3)302 g、四氫呋喃15〇 g加以混 &冷卻至-40 C。滴加正丁基鐘（16 m〇i/己烧溶液）74 ml 並反應9〇分鐘後，添加磷醯氯(式1)5.4 g並反應i小時。將溫度升南至25°C而進-步熟化2小時後，添加水1〇 g使反應、.X»束矛'J用甲醇進行清洗並德去溶劑，藉此獲得包含聚 154116.doc • 38 - 201136613 石夕氧璃酸二醋之混合物。所得之混合物之組成比藉由3 j p_ NMR測定，作為三酯體之式⑴為83%，作為二酯體之式 (II)為 17% 〇 [化 25] C.H,-Si—Ο—£.ρ.〇Ί_ sC-ΟΛΟΟ,Η,ΟΗ °«· ^ L,Ja L,(式”[Production Example 2] A sterol-modified polyfluorene oxide (formula 3) of 302 g and tetrahydrofuran (15 g) were mixed and cooled to -40 C. After dropwise addition of n-butyl clock (16 m〇i/hexane solution) to 74 ml and reaction for 9 minutes, 5.4 g of phosphonium chloride (formula 1) was added and reacted for 1 hour. After the temperature was raised to 25 ° C and the mixture was aged for 2 hours, 1 〇g of water was added to make the reaction, the .X» bunch of spears 'J was washed with methanol and the solvent was removed, thereby obtaining the inclusion of 154116.doc • 38 - 201136613 A mixture of sulphuric acid and vinegar. The composition ratio of the obtained mixture was determined by 3 j p NMR, the formula (1) as the triester body was 83%, and the formula (II) as the diester body was 17% 化 [25] CH, -Si-Ο-£ .ρ.〇Ί_ sC-ΟΛΟΟ,Η,ΟΗ °«· ^ L,Ja L,(式”

POO, + (式υ [製造實施例3] 將甲醇改質聚矽氧（式2)291 g、四氫呋喃87 g、三乙胺 19 g加以混合’冷卻至-40°C。歷時約30分鐘滴加磷酿氣 (式1)8.6 g、四氫呋喃18 g之混合溶液。k_4〇〇c下熟化5小時’並於25°C下熟化12小時後’利用甲醇進行清洗並餾去溶劑’藉此獲得包含聚矽氧磷酸三酯之混合物。所得之混合物之組成比藉由31P-NMR測定，作為三酯體之式⑴為 64°/。，作為二酯體之式（11)為18%，包含其他聚磷酸之副產物為18°/〇 » [化 26]POO, + (Formula 制造 [Production Example 3] Methanol-modified polyoxyl (Formula 2) 291 g, tetrahydrofuran 87 g, and triethylamine 19 g were mixed and cooled to -40 ° C. It took about 30 minutes to drip. Phosphorus (1) 8.6 g, tetrahydrofuran 18 g mixed solution, k_4〇〇c under aging for 5 hours' and aging at 25 ° C for 12 hours, 'washing with methanol and distilling off the solvent' A mixture comprising polyphosphoric acid triester. The composition ratio of the obtained mixture is determined by 31P-NMR, and the formula (1) as a triester is 64°/%, and the formula (11) as a diester is 18%, including Other by-products of polyphosphoric acid are 18°/〇» [Chem. 26]

[製造實施例4] 於25°C下將磷醯氯（式1)6.1 g溶解於四氫呋喃93 g中。歷 154116.doc -39- 201136613 時約2小時，於該溶液中滴加曱醇改質聚矽氧（式4)3〇〇 g、三乙胺8.1 g之混合溶液。熟化15小時後添加水〇7g、三乙胺4.1 g並結束反應》利用甲醇進行清洗後，餾去溶劑，藉此獲得包含聚矽氧磷酸三醋之混合物。所得之混合物之^ 成比藉由31P-NMR測定，作為三酯體之式⑴為11%，作為二酯體之式（II)為66%，作為單酯體之式（111)為3%，包含其他聚墙酸之副產物為20%。 [化 27] pocij (式1) C*Hf—3—0—si—_[Production Example 4] 6.1 g of phosphonium chloride (formula 1) was dissolved in 93 g of tetrahydrofuran at 25 °C. Circa 154116.doc -39- 201136613 About 2 hours, a mixed solution of decyl alcohol modified polyoxo (formula 4) 3 〇〇 g and triethylamine 8.1 g was added dropwise to the solution. After aging for 15 hours, 7 g of hydrazine and 4.1 g of triethylamine were added to complete the reaction. After washing with methanol, the solvent was distilled off, whereby a mixture containing polyphosphoric acid triacetate was obtained. The ratio of the obtained mixture was determined by 31 P-NMR, and the formula (1) as the triester was 11%, the formula (II) as the diester was 66%, and the formula (111) as the monoester was 3%. Contains 20% by-products of other polywall acids. [化27] pocij (Formula 1) C*Hf—3—0—si—_

J!H, S— Οβ,ΟΟ^ΟΗ ί (ΜJ!H, S— Οβ, ΟΟ^ΟΗ ί (Μ

2含有聚矽氧磷酸酯之化妝品之配方例將上述製造實施例中製造之包含聚矽氧磷酸三酯之混合物用於以下配方。因此，於以下實施例中，例如所謂「製 ie貫施例1之產物」意指製造實施例丨中獲得之包含聚石夕氧磷酸三酯之混合物。 [貫施例1〜4、比較例1〜5]護髮油藉由下述製法製備表1所示之配方之護髮油，藉由下述方法對毛髮之濕潤感、無黏膩感程度、毛髮之柔滑度進行 3平價。結果示於表1。 [表1] 154116.doc 201136613 表 1 (%)(2) Formulation of a cosmetic containing polyphosphonium phosphate The mixture containing polyphosphoric acid triester manufactured in the above Production Example was used in the following formulation. Therefore, in the following examples, for example, the "product of the first embodiment" means a mixture comprising the polyoxophosphoric acid triester obtained in the production of the examples. [Scheme 1 to 4, Comparative Examples 1 to 5] Hair Oil The hair oil of the formulation shown in Table 1 was prepared by the following method, and the degree of moisturization and non-stickiness of the hair was as follows. The smoothness of the hair is 3 parity. The results are shown in Table 1. [Table 1] 154116.doc 201136613 Table 1 (%)

No. 成分實施例比較例 1 2 3 4 1 2 3 4 5 1 製造實施例1之產物 10 _ 2 製造實施例2之產物 - 10 3 製造實施例3之產物 - - 10 4 製造實施例4之產物 10 5 二曱基聚矽氧烷 (平均聚合度n=10)(註1) - - - - 10 - - - - 6 二甲基聚矽氧烷 (平均聚合度n=15)(註2) - - - - - 10 - - - 7 二甲基聚矽氧烷 (平均聚合度n=25)(註3) - 10 _ - 8 二甲基聚矽氧烷 (平均聚合度n=40)(註4) 10 - 9 二曱基聚矽氧烷 (平均聚合度n=85)(註5) - 10 10 十曱基環五矽氧烷(註6) 90 90 90 90 90 90 90 90 90 評價項目與評價結果毛髮之濕潤感 ◎ ◎ ◎ 〇 X Δ 〇〇〇無黏腻感程度 ◎ ◎ ◎ 〇 Δ X X X X 毛髮之柔滑度 ◎ ◎ ◎ 〇 X X X X X (註1)KF-96A-6CS(信越化學工業公司製造） (註2)KF-96A-10CS(信越化學工業公司製造） (註3)KF-96A-2〇CS(信越化學工業公司製造） (註4)KF-96 A-50CS(信越化學工業公司製造） (註5)KF-96 A-100CS(信越化學工業公司製造） (註6)KF-995(信越化學工業公司製造） (製造方法） A. 將成分1〜10均勻混合。 B. 將A填充於容器中。 (評價方法）髮束之官能評價將頭髮受損之日本女性之髮束含浸於各護髮油中並乾燥 I541l6.doc • 41· 201136613 24小時後，對髮束進行評價。化妝品評價#家小組2 據以下評價基準對 Γ毛髮之濕潤感」、「無黏腻感程度」、「毛髮之柔滑度」各項目進行7個階段評價，進而利整個小組之料之平均分，依據以下判定基準進行判定。 [評價基準] (評價結果） :(評分）非常良好 :6分良好 :5分稍良好 :4分普通 :3分稍不良 :2分不良 ·· 1分非常不良 :〇分 [判定基準] (評分之平均分） :(判定） 5.0以上 :◎非常良好 3.5以上〜未達5.〇 :〇良好 1.5以上〜未達3.5 :Δ不良未達1.5 :χ非常不良 (結果）根據上述對髮束之官能評價結果，實施例卜4之護髮油為毛髮之濕潤感、無點腻感程度、毛髮之柔滑度優異之護髮油。比較例1〜3之護髮油由於調配有聚矽氧鏈長較短之二甲基聚矽氧烷，故而毛髮之濕潤感或毛髮之柔滑度較 1541l6.doc -42- 201136613 差，又比較例4、5之護髮油由於調配有聚石夕氧鏈長較長之二甲基聚矽氧烷，故而雖然毛髮之濕潤感優異，但存在黏腻感，毛髮之柔滑度較差。 [實施例5~8、比較例6~9] 0/W(水包油，oil-in-water)型護髮素 [表2] 表 2 (%)No. Component Example Comparative Example 1 2 3 4 1 2 3 4 5 1 Production of the product of Example 1 10 _ 2 Production of the product of Example 2 - 10 3 Production of the product of Example 3 - 10 4 Production Example 4 Product 10 5 Dimercapto polyoxyalkylene (average degree of polymerization n=10) (Note 1) - - - - 10 - - - - 6 Dimethyl polyoxane (average degree of polymerization n = 15) (Note 2 ) - - - - - 10 - - - 7 dimethyl polyoxane (average degree of polymerization n = 25) (Note 3) - 10 _ - 8 dimethyl polyoxane (average degree of polymerization n = 40) (Note 4) 10 - 9 Dimercapto polyoxyalkylene (average degree of polymerization n = 85) (Note 5) - 10 10 Decakicyclopentaoxane (Note 6) 90 90 90 90 90 90 90 90 90 Evaluation item and evaluation result The moist feeling of the hair ◎ ◎ ◎ 〇X Δ 〇〇〇 No sticky feeling ◎ ◎ ◎ 〇 Δ XXXX Hair smoothness ◎ ◎ ◎ 〇 XXXXXX (Note 1) KF-96A-6CS (Shin-Etsu Chemical (manufactured by Industrial Co., Ltd.) (Note 2) KF-96A-10CS (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) KF-96A-2〇CS (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 4) KF-96 A-50CS (Shin-Etsu Chemical industry Ltd.) (Note 5) KF-96 A-100CS (manufactured by Shin-Etsu Chemical Industries, Ltd.) (Note 6) KF-995 (Shin-Etsu Chemical Co., Ltd.) (Preparation Method) A. 1~10 ingredients are mixed uniformly. B. Fill A in the container. (Evaluation method) Functional evaluation of hair bundles Hair bundles of Japanese women with damaged hair were immersed in each hair oil and dried. I541l6.doc • 41·201136613 After 24 hours, the hair bundles were evaluated. Cosmetics evaluation #家组2 According to the following evaluation criteria, the moist feeling of the hair, the "degree of no stickiness", and the "smoothness of the hair" are evaluated in seven stages, and the average score of the whole group is further improved. The determination is made based on the following criteria. [Evaluation criteria] (Evaluation results) : (Score) Very good: 6 points Good: 5 points Slightly good: 4 points Normal: 3 points Slightly bad: 2 points bad · 1 point Very bad: 〇 points [Judgement criteria] ( Average score of the score: (decision) 5.0 or more: ◎ very good 3.5 or more ~ not up to 5. 〇: 〇 good 1.5 or more ~ not up to 3.5: Δ is not as good as 1.5: χ very bad (result) according to the above hair bundle As a result of the sensory evaluation, the hair oil of Example 4 is a hair oil which is moisturized to the hair, has no greasy feeling, and is excellent in smoothness of hair. The hair oil of Comparative Examples 1 to 3 was prepared by blending a dimethylpolysiloxane having a short polyether chain length, so that the moist feeling of the hair or the smoothness of the hair was inferior to that of 1541l6.doc -42-201136613, and In the hair oil of Examples 4 and 5, since the dimethyl polyoxyalkylene having a long polyoxo chain length is blended, although the moist feeling of the hair is excellent, there is a sticky feeling, and the smoothness of the hair is poor. [Examples 5 to 8, Comparative Examples 6 to 9] 0/W (oil-in-water) type conditioner [Table 2] Table 2 (%)

No, 成分實施例比較例 5 6 7 8 6 7 8 9 1 鯨蠟硬脂醇 2 2 2 2 2 2 2 2 2 山籥醇 1 1 1 1 1 1 1 1 3 製造實施例1之產物 2 4 製造實施例2之產物 - 2 - - - - - - S 製造實施例3之產物 - - 2 - - - - - 6 製造實施例4之產物 - - - 2 - - - - 7 二甲基聚矽氧烷 (平均聚合度n=15)(註2) - - - 2 - 5 - 8 二甲基聚矽氧烷 (平均聚合度n=40)(註4) - - - - - 2 - 5 9 棕櫊酸2-乙基己酯 3 3 3 3 3 3 3 3 10 氣化烷基三甲基銨水溶液(80%)(註 7) 1 1 1 1 1 1 1 1 11 丙二醇 5 5 5 5 5 5 5 5 12 甲基苯基聚矽氧烷 1 1 1 1 1 1 1 1 13 防腐劑適量適量適量適量適量適量適量適量 14 純化水剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量 15 檸檬酸 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 16 香料適量適量適量適量適量適量適量適量評價項目與評價結果毛髮之濕潤感 ◎ ◎ ◎ 〇 X Δ Δ 〇無黏腻感程度 ◎ ◎ ◎ 〇〇 X X X 毛髮之柔滑度 ◎ ◎ ◎ 〇 X X X X (註7)Genamin KDM-P(Clariant Japan公司製造) -43- 154116.doc 201136613 (製造方法） A. 於8〇C下將成分1〜12均勻溶解。 B. 於80°C下將成分13〜15均勻溶解。 C. 於B中添加A並於8 0。〇下使其乳化。 D ·將C冷卻並添加成分16。 E.將D消泡並填充至容器中。 (評價方法）化妝品評價專家小組2〇人對實施例5〜8、及比較例6〜9之護髮素進行使用測試，依據上述評價基準對「毛髮之濕澗感」、「無黏腻感程度」、「毛髮之柔滑度」各項目分別進行 7個階段之評價，進而使用整個小組之評分之平均分，依據上述判定基準進行判定。 (結果）實施例5〜8之護髮素為毛髮之濕潤感、無黏腻感程度、毛髮之柔滑度優異之護髮素。比較例6、8之護髮素由於調配有聚矽氧鏈長較短的二甲基聚矽氧烷，故而於調配量較少之比較例6中，毛髮之濕潤感或毛髮之柔滑度較差，又即便調配量較多之比較例8之護髮素，亦為毛髮無濕潤感、存在黏腻感、毛髮之柔滑度較差者。又，比較例7、9 之護髮素由於調配有聚矽氧鏈長較長的二曱基聚矽氧烷，故而雖然毛髮之濕潤感優異’但存在黏腻感，毛髮之柔滑度較差》 (%) [實施例9]乳化型化妝水 (成分） 154116.doc • 44 · 201136613 1.鯨蠟醇 0.2 2.製造實施例1之產物 0.5 3.磷脂質-植固醇混合物（8:1)(註8) 0.5 4.聚氧乙烯（40莫耳）氫化蓖麻油 0.1 5.乙酸生育酚 0.5 6.硬脂酸三乙醇胺 0.5 7.純化水剩餘量 8.乙醇 10.0 9,香料適量 (註8) Phytocompo-PP(曰本精化股份有限公司製造） (製造方法） (1) 將成分1〜6加熱至75t並使其均勻地混合溶解。 (2) 將成分7、8加熱至75°C並使其均勻地混合溶解。 (3) 於（1)中添加（2)使其乳化。 (4) 將（3)冷卻並添加成分9而獲得乳化型化妝水。 (結果）實施例9之乳化型化妝水為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之乳化型化妝水。 [實施例10]乳液 (%) 0.5 1.0 (成分） 1.硬脂酸 2·單硬脂酸聚氧乙烯酯(20莫耳）去水山梨醇 3·四油酸聚氧丙烯酯（40莫耳） 154116.doc •45· 201136613 去水山梨醇 1.0 4. 山窬醇 1_5 5. 流動石蠟 2.0 6. 三2-乙基已酸甘油酯 5.0 7. 製造實施例1之產物 5.0 8. 丙烯酸/曱基丙烯酸烷基酯共聚物 0.1 9. 三仙膠 0.1 10. 氫氧化鈉〇·〇5 11. 1，3-丁二醇 8.0 12. 防腐劑適量 13. 香料適量 14. 純化水剩餘量 (製造方法） (1) 於80°C下將成分1〜7均勻混合。 (2) 於80°C下將成分8〜14均勻混合。 (3) 於（1)中添加（2)並使其乳化。 (4)一面攪拌（3)—面冷卻而獲得乳液。 (結果）實施例10之乳液係「濕潤感」、「無黏腻感程度」、「柔滑度」優異之乳液。 [實施例11] o/w型乳霜 (成分）（％) 1. 聚甘油-10五油酸酯 2.5 2. 山窬醇 1.5 154116.doc -46· 201136613 3. 凡士林 3.0 4. 重質流動異構石蠟 1.0 5. 三2-乙基已酸甘油酯 1.0 6. 製造實施例2之產物 5.0 7. 純化水剩餘量 8. 甘油 7.0 9. 丙烯酸/甲基丙烯酸烷基酯共聚物 0.2 1〇_氫氧化鈉 0.09 11. 防腐劑適量 12. 香料適量 (製造方法） (1) 於80°C下將成分1〜6均勻混合。 (2) 於80°C下將成分7〜12均勻混合。 (3) 於（1)中添加（2)並使其乳化。 (4)一面攪拌（3) —面冷卻而獲得乳霜。 (結果）實施例11之0/W型乳霜係「濕潤感」、「無黏腻感程度」、「柔滑度」優異之0/W型乳霜。 [實施例12] W/0(油包水，water-in-oil)型乳霜 (成分） (%) 1.微晶蠟 1.5 2.黃蜜蠟 1.5 3.鯨蠟醇 3.0 4.製造實施例2之產物 5.0 154116.doc •47· 201136613 5. 氫化大豆磷脂質 1.0 6. 角鯊烷 35.〇 7·去水山梨醇三油酸酯 3 〇 8.丙二醇 1〇〇 9 ·防腐劑適量 10. 香料適量 11. 純化水剩餘量 (製造方法） (1) 將成分1〜7加熱至75。(：並使其均勻地混合溶解。 (2) 將成分8、11加熱至75°C並使其均勻地混合溶解。 (3) 於（1)中添加（2)並使其乳化。 (4) 將（3)冷卻並添加成分9、10而獲得w/O型乳霜》 (結果）實施例12之W/0型乳霜係「濕潤感」、「無黏膩感程度」、「柔滑度」優異之W/0型乳霜。 [實施例13]卸妝油 (成分） (%) 1.四油酸聚氧乙烯酯（3〇莫耳）山梨糖醇 8.0 2.二異硬脂酸聚甘油醋 0.5 3 ·流動石躐剩餘量 4.三2-乙基已酸甘油酯 25.0 5 ·製造實施例3之產物 5.0 6.防腐劑適量 154116.doc •48· 201136613 7.香料適量 (製造方法） (1)於常溫下將成分1〜7均勻混合而獲得卸妝由 (結果）實施例13之卸妝油係「濕潤感」、「無黏腻感程度」、滑度」優異之卸妝油。 (%) 3.0 2.0 [實施例14]清潔霜 (成分） 1. 硬脂酸 2. 鯨蠟醇 3. 四油酸聚氧丙稀酯（40莫耳） 1.0 1.0 20.0 20.0 5.0 0.1 7.0 0.05 剩餘量適量適量山梨醇 4. 單硬脂酸聚氧乙烯酯（2〇莫耳）去水山梨醇 5. 二2 -乙基已酸甘油酉旨 6. 流動石墙 7. 製造實施例4之產物 8. 丙烯酸/甲基丙烯酸烷基酯共聚物 9. 1，3·丁二醇 10. 氫氧化鈉 11. 純化水 12. 防腐劑 13. 香料 (製造方法） 154116.doc -49- 201136613 (1) 於80°C下將成分1〜7均勻混合。 (2) 於80°C下將成分8〜13均勻混合。 (3) 於（2)中添加（丨）並使其乳化。 (4) 一面攪拌（3)一面冷卻而獲得清潔霜。 (結果）實施例14之清潔霜係滑度」優異之清潔霜。 [實施例15]定型水「濕潤感」、「無黏腻感程度」、 (成分） 1.乙醇 2 ·氣化硬脂基三曱基錢 3.異硬脂酸聚氧乙稀醋（5〇莫耳）氫化萬麻油 (%) 15.0 0.2 4. 製造貫施例1之產物 5. 純化水 6. 羥基丙基纖維素 7. 高聚合甲基聚矽氧烷乳液（註9) 8 ·防腐劑 0.20.2 剩餘量0.012.0 9.香料 (註 9)BYll-007(T〇ray D〇w (製造方法）適量適量 Coming公司製造） (1)於常溫下將成分1〜9均勻混合而獲得定型水。 (結果） 7〇實施例15之定型水為濕潤感」、「無黏腻感程度」、 154116.doc -50· 201136613 滑度」優異之定型水。 [實施例16]髮蠟 (成分） (%) 1.純化水剩餘量 • 2.丙二醇 10.0 • 3.單硬脂酸聚乙二醇酯 3.0 4.凡士林 10.0 5.石蠟 3.0 6.蘇壤硬脂醇 3.0 7.山蓊醇 3.0 8.製造實施例2之產物 3.0 9.乙醇 5.0 10.純化水 15.0 11 _乙烯吡咯烷酮 1.0 12.丙烯酸/曱基丙烯酸烷基酯共聚物 0.15 13.氫氧化鈉 0.05 14.防腐劑適量 15.香料適量 (製造方法） (1) 於8(TC下將成分1〜3均勻混合。 (2) 於80°C下將成分4〜8均勻混合。 (3) 於（1)中添加（2)並使其乳化。 (4) 於（3)中添加成分9〜15後，一面攪拌一面冷卻而獲得髮樣。 154116.doc 51 201136613 (結果）實施例16之髮蠟為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之髮蠟。 [實施例17] O/W型睫毛膏 (成分）（％) 1. 硬脂酸 2.0 2. 黃蜜蠟 10.0 3. 鯨蠟硬脂醇 1.0 4. 單油酸聚氧乙烯酯（20莫耳）去水山梨醇 1.5 5. 去水山梨醇倍半油酸酯 0.5 6. 製造實施例2之產物 5.0 7. 氧化鐵黑 5.0 8. 無水石夕酸 3.0 9. 純化水剩餘量 10. 1，3-丁二醇 10.0 11. 三乙醇胺 1.5 12. 丙烯酸烷基酯共聚物乳液（註10) 30.0 13. 防腐劑適量 14. 香料適量 (註10)YODOSOL 32A707(45%固形物成分）（日本NSC公司製造） (製造方法） (1)於80°C下將成分1〜3均勻混合。 154116.doc -52- 201136613 (2) 利用輥對成分4〜8進行處理。 (3) 於80°C下將成分9〜14均勻混合。 (4) 將（1)、（2)混合後，添加（3)並使其乳化。 (5) 將（4)冷卻而獲得0/W型睫毛膏。 (結果）實施例17之0/W型睫毛膏為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之0/W型睫毛膏。 [實施例18]膏狀唇彩 (成分） (%) 1.製造實施例4之產物 3.0 2.蘋果酸二異硬脂酯 10.0 3.乳酸硬脂酯 10.0 4.氫化聚異丁烯 30.0 5 ·三異辛酸甘油画旨剩餘量 6.流動石壤 5.0 7.微晶蠟 2.0 8. 12-羥基硬脂酸 0.1 9. α烯烴-乙烯吡咯烷酮共聚物（註11) 0.5 10.無水矽酸（註12) 3.5 11.鐵丹 0.1 12.紅色201號 0.3 13.氧化鐵黑 0.05 14.氧化鈦 0.2 15.大豆破脂質 0.01 1541I6.doc -53- 201136613 3.0 16. 對曱氧基肉桂酸-2-乙基己酯 17. 防腐劑適量 1 8.香料適量 (註 1 l)ANTARON V-220(ISP公司製造） (註12)AEROSIL 200(日本艾羅技公司製造） (製造方法） (1) 於100°C下將成分1〜9溶解混合。 (2) 於（1)中添加成分10〜18並使其均勻地混合分散。 (3) 將（2)注入管中，冷卻而獲得膏狀唇彩。 (結果）實施例18之膏狀唇彩為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之膏狀唇彩。 [實施例19] 口紅 (成分） (%) 1.聚乙烯蠟 10.0 2.巴西棕櫚蠟 5.0 3.石蠟 2.0 4. 2-乙基已酸鯨蠟酯剩餘量 5·製造實施例4之產物 5.0 6 _流動石蠟 10.0 7.異壬酸異十三烷基酯 10.0 8.紅色202號 0.5 9.黃色4號 2.0 10.氧化鈦 0.5 154116.doc •54 201136613 0.1 0.5 適量 11. 氧化鐵黑 12. α-生育酚 13. 香料 (製造方法） (1) 於100°C下將成分1〜7均勻地溶解混合。 (2) 於（1)中添加成分8~13並使其均勻混合。 (3) 將（2)注入容器，冷卻而獲得口紅。 (結果）實施例19之口紅為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之口紅。 [實施例20]油性眼影 (成分） (%) 1.脂肪酸糊精酯（註13) 2.0 2.製造實施例4之產物 2.0 3.蘋果酸二異硬脂酯 2.5 4. 2-乙基已酸鯨蠟酯 13.0 5.月桂酸糊精酯 2.0 6.肉豆蔻酸糊精酯 5.0 7.山蝓酸糊精酯 5.0 8 ·流動石堪剩餘量 9.氫化聚異丁烯 1.5 10.無水矽酸 6.0 11.尼龍粉末 5.0 12.聚矽氧處理滑石（註14) 5.5 1541I6.doc -55- 201136613 13.紅色202號 0.05 14.黃色4號鋁色澱 0.05 15.藍色1號鋁色澱 0.05 16.雲母欽 1.5 17.防腐劑適量 18.香料適量 (註13)Rheopearl TT(千葉製粉公司製造） (註14)二曱基聚矽氧烷5%處理 (製造方法） (1)於100°C下將成分1〜9溶解混合。 (2)於（1)中添加成分10〜18並使其均勻地混合分散。 (3)將（2)注入至容器中，使其冷卻固化而獲得油性眼影 (結果）實施例20之油性眼影為「濕潤感「柔滑度」優異之油性眼影。 [實施例21]固體粉末狀粉底」、「無黏腻感程度 (成分） (%) 1.二曱基聚矽氧烷處理滑石 30.0 2.二曱基聚矽氧烷處理雲母 15.0 3.二曱基聚矽氧烷處理雲母氧化鈦 15.0 4.二甲基聚矽氧烷處理絹雲母剩餘量 5.合成金雲母 5.0 6.氧化鐵黃 2.0 7.鐵丹 0.5 154116.doc -56- 201136613 8.氧化鐵黑 0.2 9.防腐劑適量 10.製造實施例3之產物 3.0 11.流動石蠟 3.0 12 —甲基聚梦氧院 1.0 13. 2-乙基已酸甘油酯 2.0 14.香料適量 (製造方法） (1) 利用亨舍爾混合機（三井三池公司製造）於75°C下將成分 1〜9均勻分散。 (2) 將成分10〜13均勻地混合溶解。 (3) —面利用亨舍爾混合機攪拌（丨）一面添加（2)及14並使其均勻分散。 (4) 利用粉碎機將（3)粉碎。 ⑺將（4)填充於金屬容ϋ中，進行麼縮成$而獲得固體粉末狀粉底。 (結果）實施例21之㈣粉末狀粉底為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之固體粉末狀粉底。 [實施例22]固體粉末狀眼影 (%) 10.0 剩餘量 30.0 (成分） 1·二曱基聚矽氧烷處理合成金雲母 2.二甲基聚矽氧烷處理滑石 3 ·氧化鈦被覆雲母 I541l6.doc -57- 201136613 4.氮化硼 5.0 5 ·聚對苯二曱酸乙二酯-鋁 -環氧積層粉末 5.0 6.群青 2.0 7.紅色202號 0.5 8·聚丙烯酸烷基酯 1.0 9.防腐劑適量 10.製造實施例2之產物 4.0 11.流動石蠟 3.0 12.二曱基聚矽氧烷 2.0 13. 2 -乙基已酸甘油醋 2.0 14.香料適量 (製造方法） (1) 利用亨舍爾混合機（三井三池公司製造）於75°C下將成分 1〜9均勻分散。 (2) 將成分10〜13均勻地混合溶解。 (3) —面利用亨舍爾混合機攪拌（1)一面添加（2)及14並使其均勻分散。 (4) 利用粉碎機將（3)粉碎。 (5) 將（4)填充於金屬容器中，進行壓縮成型而獲得固體粉末狀眼影。 (結果）實施例22之固體粉末狀眼影為「濕潤感」、「無黏腻咸程度」、「柔滑度」優異之固體粉末狀眼影。 154116.doc -58 - 201136613 [實施例23]固體粉末狀腮紅 (成分） (%) 1.雲母 20.0 2.滑石剩餘量 3.氧化鈦被覆雲母 10.0 4.群青 0.5 5.紅色226號 0.2 6.聚丙烯酸烷基酯 1.0 7.防腐劑適量 8.製造實施例1之產物 3.0 9.流動石蠟 2.0 10.二甲基聚矽氧烷 1.0 11 · 2 -乙基已酸甘油g旨 12.香料 (製造方法） 1.0 適量 (1)利用亨舍爾混合機（三井 1〜7均勻分散。三池公司製造）於75。(：下將成分 (2)將成分8〜11加熱至65°c並使其均勻地混合溶解。 (3) 一面利用亨舍爾混合機攪拌（1)一面添加（2)及12並使其均勻分散。 (4) 利用粉碎機將粉碎。 (5)將（4)填充於金屬容器中末狀腿紅。 (結果），進行壓縮成型而獲得固體粉 154116.doc ·59· 201136613 實施例23之固體粉末狀肥紅為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之固體粉末狀肥紅。 [實施例24]棒狀遮瑕膏 (成分）（〇/〇) 1. 石蠟 5.0 2. 聚乙稀蠛 5.0 3. 堪地里拉蠟 2.0 4. 製造實施例4之產物 15.0 5. 三-2-乙基已酸甘油醋 15.0 6. 曱基苯基聚矽氧烷 5.0 7. 乙酸液狀羊毛脂 1〇.〇 8. 對曱氧基肉桂酸2-乙基己酯 5.0 9. 氧化鈦 20.0 10. 氧化鐵黃 2.0 11. 鐵丹 0.5 12. 氧化鐵黑 0.2 13. 雲母 7.0 14. 防腐劑適量 (製造方法） (1) 於100°C下將成分1〜8混合溶解。 (2) 於90°C下將成分9〜14均勻混合於（1)中。 (3) 利用三輥研磨機對（2)進行處理。 (4) 將（3)消泡’於以它下溶解填充至器皿中後，於4〇c下冷卻，而獲得棒狀遮瑕膏。 154M6.doc • 60- 201136613 (結果）潤感」、「無黏腻感程〇 (%) 2.0 5.0 5.0 3.0 3.0 10.0 10.0 貫施例24之棒狀遮瑕膏為「濕度〜」、「柔滑度」優異之棒狀遮瑕膏 [貫奴例25] W/〇型防曬霜 (成分） 1. 氧化鋅 2. 聚矽氧被覆微粒氧化鈦(註14) 3. 二（辛基-癸酸）甘油酯 4·二2-乙基已酸甘油酯 5.標搁酸辛酉旨 6·對甲氧基肉桂酸2-乙基己酯 7·十甲基環五矽氧烷 8.甲基聚矽氧烷_鯨蠟基曱基聚矽氧烷 -聚（氧乙烯-氧丙烯）甲基聚矽氧烷共聚物（註15) 1.8 9.製造實施例3之產物 3.0 10.防腐劑適量 11.氣化鈉 0.3 12.純化水剩餘量 13.二丙二醇 5.0 14.乙醇 5.0 15.香料適量 (註 15)ABIL EM-90(EVONIC GOLDSCHMIDT GMBH公司製造） 154116.doc -61 - 201136613 (製造方法） (1) 將成分3、4加熱溶解後，添加成分1、2並利用輥使其均勻分散。 (2) 於70°C下使成分5〜10溶解後，於6〇°C下添加（1)並使其均勻地混合溶解。 (3) 使成分11〜13混合溶解後，於60°C下添加至（2)中並使其乳化。 (4)於（3)中添加成分14、15並使其均勻混合而獲得W/0型防曬霜。 (結果）實施例25之W/0型防曬霜為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之W/0型防曬霜。 [實施例26] W/0型粉底 (%) (成分） 1.聚氧乙烯曱基矽氧烷-聚氧丙烯油醇酯甲基矽氧烷-二甲基矽氧烷共聚物（註16)2 〇 2· PEG-3二甲基聚矽氧烷（註17) 1〇 3·二甲基聚矽氧烷 π Λ 4. 聚矽氧處理氧化鐵紅（註14) 5. 聚矽氧處理氧化鐵黃（註14) 6·聚矽氧處理氧化鐵黑（註14) 7. 聚矽氧處理氧化鈦（註14) 8. 聚矽氧處理滑石（註14) 9. 三2-乙基已酸甘油酯 154116.doc -62 - 201136613 5.0 0.5 剩餘量 15.0 0.5 適量適量 i〇.製造實施例2之產物 11. 倍半油酸去水山梨醇醋 12. 純化水 Π.1，3-丁二醇 14.氣化鈉 15·防腐劑 16·香料 (s主16)KF-6026(信越化學工業公司製造） (s主17)KF-6015(信越化學工業公司製造） (製造方法） (1) 將成分1〜3均勻混合。 (2) 利用輕將成分4〜11均勻分散。 (3) 於（1)中添加（2)並使其均勻混合。 (4) 於（3)中添加成分12〜16並使其乳化而獲得w/〇型粉底。 (結果）實施例26之购型粉底為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之W/〇型粉底。 [實施例27] 0/W型粉底 (成分） 1. 単油酸聚氧乙稀g旨（2〇莫耳）去水山梨醇 2. 倍半油酸去水山梨醇酿 3·1，3-丁二醇 4.聚矽氧處理氧化鈦（註14) (%) 0.5 0.5 10.0 10.0 201136613 0.4 2.0 0.1 5.0 0.3 1.0 剩餘量 2.0 1.0 0.5 1.0 2.0 1.0 2.0 0.5 適量適量 5. 聚矽氧處理鐵丹（註14) 6. 聚矽氧處理氧化鐵黃（註14) 7. 聚矽氧處理氧化鐵黑（註14) 8. 聚矽氧處理滑石（註14) 9. 羧乙烯聚合物 10. 三乙醇胺 11. 純化水 12. 乙醇 13. 硬脂酸 14. 山窬醇 1 5.流動石蠟 16. 製造實施例2之產物 17. 三2-乙基已酸甘油酯 18_對曱氧基肉桂酸2_乙基己酯 19. 凡士林 20. 防腐劑 21. 香料 (製造方法） (1) 利用報將成分1〜8均勻分散。 (2) 將成分9〜12均勻混合。 (3) 於（2)中添加（丨）並使其均勻混合。 (4) 於8(TC下將成分13〜2〇混合溶解。 (5) 於8G°C下’於⑴中添加⑷並使其乳化。 (6) 將（5)冷卻並添加成分21而獲得〇/霤型粉底。 154116,doc -64· 201136613 (結果）實施例27之〇/W型粉底為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之〇/W型粉底。 [實施例28]油性固體粉底 (成分） (%) 1.滑石 15.0 2.雲母 10.0 3.聚石夕氧處理氧化鈦（註14) 15.0 4.聚矽氧處理鐵丹（註14) 1.0 5·聚矽氧處理氧化鐵黃（註14) 3.0 6.聚矽氧處理氧化鐵黑（註i 4) 0.2 7.聚乙烯蠟 7.0 8.微晶蠟 6.0 9.二2-乙基已酸甘油西旨剩餘量 1 〇.製造貫施例1之產物 5.0 11·二甲基聚矽氧烷 5.0 12.流動石蠟 20.0 聚氧乙稀曱基石夕氧烧_聚氧丙烯油醇酯甲基矽氧烷-二甲基矽氧烷共聚物（註16)2.0 14.防腐劑適量 15 ·香料適量 (製造方法） (1) 於90C下將成分7〜14加熱溶解。 (2) 於（1)中添加成分1〜6並利用輥使其均勻分散。 154116.doc -65· 201136613 (3)於（2)中添加成分15，於80°C下溶解後，填充至金屬容器中，而獲得油性固體粉底。 (結果）實施例28之油性固體粉底為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之油性固體粉底。 [實施例29]妝前乳 (成分） (%) 1.鯨蠟硬脂醇 2.0 2.對曱氧基肉桂酸2-乙基己酯 5.0 3.製造實施例4之產物 8.0 4.三2-乙基已酸甘油酯 3.0 5.純化水剩餘量 6. N-硬脂醯基-N-曱基牛磺酸鈉 0.5 7.羧乙烯聚合物 0.1 8.丙烯酸/曱基丙烯酸烷基酯共聚物 0.1 9.氫氧化納 0.05 10.乙醇 10.0 11.1,3-丁二醇 10.0 12.防腐劑適量 13.香料適量 (製造方法） (1) 於80°C下將成分1〜4均勻溶解。 (2) 於80°C下將成分5〜12均勻溶解。 (3) 於（2)中添加（1)並使其乳化。 154116.doc -66- 201136613 (4)於（3)中添加成分13並冷卻而獲得妝前乳。 (結果）實施例29之妝前乳為「濕潤感」、「無黏腻感程度滑度」優異之妝前乳。 [實施例30]身體乳 (成分）（％) 1. 硬脂酸 1.0 2. 單油酸聚氧乙烯酯（20莫耳）去水山梨醇 0.5 3. 倍半油酸去水山梨醇酯 0.5 4. 山茶醇 0.5 5. 2-乙基已酸甘油酯 2.0 6. 流動石蠟 2.0 7. 製造實施例1之產物 5.0 8. 乙醇 10.0 9. 二丙二醇 10.0 10. 三乙醇胺 1.0 11. 純化水剩餘量 12. 甘油 5.0 13.1，3-丁二醇 5.0 14. 丙烯酸/曱基丙烯酸烷基酯共聚物 0.2 15. 防腐劑適量 16. 香料適量 (製造方法） 1541l6.doc -67- 201136613 (1) 於80°C下將成分1~7均勻溶解。 (2) 於80°C下將成分8〜16均勻溶解。 (3) 於（2)中添加（1)並使其乳化。 (4) 將（3)攪拌冷卻而獲得身體乳。 (結果）實施例30之身體乳為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之身體乳。 [實施例31]卸妝乳 (成分） (%) 1·1，3-丁二醇 15.0 2·丙烯酸烧基酯共聚物乳液（註1〇) 2.5 3. L-精胺酸 0.5 4.純化水剩餘量 5.輕質流動異構石蠟（註18) 3.0 6.製造實施例1之產物 2.0 7.防腐劑適量 8.香料適量 (註18)IP Solvent 1620(出光興產公司製造） (製造方法） (1) 將成分1~4均勻混合。 (2) 於60°C下，於（1)中添加成分5〜8並使其乳化。 (3) —面搜掉（2)—面冷卻而獲得卸妝乳。 (結果）實施例3 1之卸妝乳為「濕潤感」、「無黏腻感程度」、「柔 154116.doc -68 · (%) 10.0 3.0 2.0 2.0 2.0 3.0 5.0 1.0 剩餘量 3.0 5.0 3.0 5.0 201136613 滑度」優異之卸妝乳β [實施例32]防水睫毛膏 (成分） I. 季戊四醇松香酸酯 2 ·堪地里拉樹脂 3. 黃蜜蠟 4. 地蠟 5. 棕橺酸糊精酯 6. 三甲基矽烷氧基矽酸 7. 二曱基二硬脂基銨鋰蒙脫石 8. 碳酸丙烯脂 9. 輕質流動異構石蝶（註} 8) 10. 製造實施例2之產物 II. 氧化鐵黑 12. 二氧化矽 13. 滑石 (製造方法） ⑴將成分1〜5加熱至11〇。〇。 (2)將成分6〜10添加至（1)中並加以混合。 (3)將成分11〜13添加至（2)中並加以混合〇 (4)利用輥對（3)進行處理 (結果）而獲得防水睫毛膏。實度J、施例32之防水睫毛膏No, Ingredient Example Comparative Example 5 6 7 8 6 7 8 9 1 Cetearyl alcohol 2 2 2 2 2 2 2 2 2 2 behenyl alcohol 1 1 1 1 1 1 1 1 3 The product of Example 1 was produced 2 4 Production of the product of Example 2 - 2 - - - - - S The product of Example 3 was produced - 2 - - - - - 6 The product of Example 4 was produced - - 2 - - - - 7 dimethyl polyfluorene Oxyalkane (average degree of polymerization n=15) (Note 2) - - - 2 - 5 - 8 Dimethylpolyoxane (average degree of polymerization n=40) (Note 4) - - - - - 2 - 5 9 2-ethylhexyl palmitate 3 3 3 3 3 3 3 3 10 Aqueous solution of alkyltrimethylammonium chloride (80%) (Note 7) 1 1 1 1 1 1 1 1 11 Propylene glycol 5 5 5 5 5 5 5 5 12 Methylphenyl polyoxane 1 1 1 1 1 1 1 1 13 Preservatives Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 14 Purified water Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Residual amount Remaining amount 15 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 16 The right amount of the right amount of the right amount of the right amount of the right amount of the right amount of the appropriate amount of the evaluation item and the evaluation results of the moist feeling of the hair ◎ ◎ ◎ 〇 X Δ Δ 〇 no sticky feeling ◎ ◎ ◎ 〇〇 XXX Hair smoothness ◎ ◎ ◎ 〇 XXXX (Note 7) Genamin KDM-P (manufactured by Clariant Japan) -43- 154116.doc 201136613 (Manufacturing method) A. Ingredients 1~ at 8〇C 12 evenly dissolved. B. The components 13 to 15 were uniformly dissolved at 80 °C. C. Add A to B and at 80. Emulsify under the armpits. D. Cool C and add ingredient 16. E. Defoam D and fill into the container. (Evaluation method) The cosmetics evaluation expert group 2 tested the use of the conditioners of Examples 5 to 8 and Comparative Examples 6 to 9, and based on the above evaluation criteria, "wet feeling of hair" and "no stickiness" Each of the items of "degree" and "smoothness of hair" was evaluated in seven stages, and the average score of the entire group was used, and the judgment was made based on the above criteria. (Results) The conditioners of Examples 5 to 8 were hair conditioners having a moist feeling of hair, a degree of non-stickiness, and excellent smoothness of hair. The conditioners of Comparative Examples 6 and 8 were formulated with a dimethylpolyoxane having a short polyether chain length, so that in Comparative Example 6 in which the amount of the mixture was small, the moist feeling of the hair or the smoothness of the hair was poor. Moreover, even if the hair conditioner of Comparative Example 8 having a large amount of blending is used, the hair has no moist feeling, a sticky feeling, and a poor smoothness of the hair. Further, since the conditioners of Comparative Examples 7 and 9 were formulated with a dimercaptopolyoxyalkylene having a long polyether chain length, the moist feeling of the hair was excellent, but the feeling of stickiness was felt, and the smoothness of the hair was poor. (%) [Example 9] Emulsion type lotion (ingredient) 154116.doc • 44 · 201136613 1. Cetyl alcohol 0.2 2. Production of product of Example 1 0.5 3. Phospholipid-phytosterol mixture (8:1) (Note 8) 0.5 4. Polyoxyethylene (40 mol) hydrogenated castor oil 0.1 5. Tocopherol acetate 0.5 6. Triethanolamine stearate 0.5 7. Purified water remaining 8. Ethanol 10.0 9, appropriate amount of spices (Note 8) Phytocompo-PP (manufactured by Sakamoto Seiki Co., Ltd.) (Manufacturing method) (1) The components 1 to 6 were heated to 75 t and uniformly mixed and dissolved. (2) The components 7, 8 were heated to 75 ° C and uniformly mixed and dissolved. (3) Add (2) to (1) to emulsify it. (4) The (3) was cooled and the component 9 was added to obtain an emulsified lotion. (Result) The emulsified lotion of Example 9 was an emulsified lotion excellent in "wet feeling", "no stickiness" and "smoothness". [Example 10] Emulsion (%) 0.5 1.0 (ingredient) 1. Stearic acid 2·polyoxyethylene monostearate (20 mol) Dehydrated sorbitol 3·tetraoleic acid polyoxypropylene ester (40 Mo Ear) 154116.doc •45· 201136613 sorbitan 1.0 4. behenyl alcohol 1_5 5. mobile paraffin 2.0 6. triethyl 2-ethyl glyceride 5.0 7. product of manufacture example 5.0 5.0 Acrylic acid / Acryl methacrylate copolymer 0.1 9. Sanxianjiao 0.1 10. Sodium hydroxide 〇·〇5 11. 1,3-butanediol 8.0 12. Preservative amount 13. Proper amount of spices 14. Remaining amount of purified water ( Manufacturing method) (1) Components 1 to 7 were uniformly mixed at 80 °C. (2) The components 8 to 14 were uniformly mixed at 80 °C. (3) Add (2) to (1) and emulsify it. (4) The emulsion is obtained by stirring (3) while cooling the surface. (Result) The emulsion of Example 10 was an emulsion excellent in "wet feeling", "no stickiness", and "smoothness". [Example 11] o/w type cream (ingredient) (%) 1. Polyglycerol-10 pentaoleate 2.5 2. Hawthorn 1.5 154116.doc -46· 201136613 3. Vaseline 3.0 4. Heavy flow Isomerized paraffin 1.0 5. Tri-ethylhexanoic acid glyceride 1.0 6. Product of manufacture example 2 5.0 7. Purified water remaining 8. Glycerin 7.0 9. Acrylic/alkyl methacrylate copolymer 0.2 1〇 _Sodium hydroxide 0.09 11. Suitable amount of preservative 12. Proper amount of flavor (manufacturing method) (1) The components 1 to 6 are uniformly mixed at 80 °C. (2) The components 7 to 12 were uniformly mixed at 80 °C. (3) Add (2) to (1) and emulsify it. (4) One side is stirred (3) - the surface is cooled to obtain a cream. (Result) The 0/W type cream of the type 0/W type cream of Example 11 was a 0/W type cream which was excellent in "wet feeling", "no stickiness degree", and "smoothness". [Example 12] W/0 (water-in-oil) type cream (ingredient) (%) 1. Microcrystalline wax 1.5 2. Yellow beeswax 1.5 3. Cetyl alcohol 3.0 4. Manufacturing implementation Product of Example 2 5.0 154116.doc •47· 201136613 5. Hydrogenated soybean phospholipid 1.0 6. Squalane 35. 〇7·desorbed trioleate 3 〇8. Propylene glycol 1〇〇9 ·Preservative amount 10. Proper amount of flavor 11. Remaining amount of purified water (manufacturing method) (1) Heat the ingredients 1 to 7 to 75. (: and uniformly mix and dissolve. (2) Heat the ingredients 8, 11 to 75 ° C and mix them evenly. (3) Add (2) to (1) and emulsify them. (3) Cooling and adding ingredients 9 and 10 to obtain w/O type cream (Results) The W/0 type cream of Example 12 is "wet feeling", "no stickiness", "smoothness" Excellent "W/0 type cream. [Example 13] Cleansing oil (ingredients) (%) 1. Tetra-oleic acid polyoxyethylene ester (3 〇 Moel) Sorbitol 8.0 2. Diisostearic acid Polyglycerol vinegar 0.5 3 · Remaining amount of mobile sarcophagus 4. Tri-ethyl hexanoic acid glyceride 25.0 5 · Product of manufacture example 3 5.0 6. Preservative amount 154116.doc •48· 201136613 7. Proper amount of spices (manufactured (1) The components 1 to 7 were uniformly mixed at room temperature to obtain a makeup remover. (Results) The cleansing oil of the cleansing oil of Example 13 was "wet", "no stickiness", and slipperiness. (%) 3.0 2.0 [Example 14] Cleansing cream (ingredient) 1. Stearic acid 2. Cetyl alcohol 3. Polyoxypropylene tetraoleate (40 mol) 1.0 1.0 20.0 20.0 5.0 0.1 7.0 0.05 Remaining amount Moderate amount Sorbitol 4. Polyoxyethylene monostearate (2 〇 mol) Dehydrated sorbitol 5. Di-2-ethyl hexanoic acid glycerol. 6. Flowing stone wall 7. Production of product of Example 4. Acrylic/alkyl methacrylate copolymer 9. 1,3·butanediol 10. Sodium hydroxide 11. Purified water 12. Preservative 13. Perfume (manufacturing method) 154116.doc -49- 201136613 (1) The components 1 to 7 were uniformly mixed at 80 ° C. (2) The components 8 to 13 were uniformly mixed at 80 ° C. (3) (() was added and emulsified in (2). (3) A cooling cream was obtained while cooling. (Result) The cleaning cream of Example 14 was excellent in slipperiness. [Example 15] Shaped water "wet feeling", "no stickiness", (ingredient) 1. Ethanol 2 · Gasification of stearyl triterpene 3. Isostearic acid polyoxyethylene vinegar (5 〇 Mo Er) Hydrogenated Wanma oil (%) 15.0 0.2 4. Produce the product of Example 1 Purified water 6. Hydroxypropyl cellulose 7. Highly polymerized methyl polyoxyalkylene emulsion (Note 9) 8 · Preservative 0.20.2 Residual amount 0.012.0 9. Perfume (Note 9) BYll-007 (T〇 Ray D〇w (manufacturing method) (manufactured by Coming) (1) The components 1 to 9 are uniformly mixed at room temperature to obtain shaped water. (Result) 7〇 The setting water of Example 15 was a moisturizing sensation, a “degree of no stickiness”, and a styling water excellent in 154116.doc -50·201136613 slip. [Example 16] Wax (ingredient) (%) 1. Remaining amount of purified water • 2. Propylene glycol 10.0 • 3. Polyethylene glycol monostearate 3.0 4. Vaseline 10.0 5. Paraffin 3.0 6. Sustained hard fat Alcohol 3.0 7. Behenyl alcohol 3.0 8. Product of manufacture of Example 2 3.0 9. Ethanol 5.0 10. Purified water 15.0 11 _ vinylpyrrolidone 1.0 12. Acrylic acid alkyl methacrylate copolymer 0.15 13. Sodium hydroxide 0.05 14. Appropriate amount of preservatives 15. Proper amount of flavor (manufacturing method) (1) Mix components 1 to 3 uniformly at 8 (TC) (2) Mix components 4 to 8 uniformly at 80 ° C. (3) 1) (2) was added and emulsified. (4) After adding the components 9 to 15 in (3), the sample was cooled while stirring to obtain a sample. 154116.doc 51 201136613 (Result) The wax of Example 16 was "Wet feeling", "No stickiness" and "Smoothness". [Example 17] O/W type mascara (ingredient) (%) 1. Stearic acid 2.0 2. Yellow beeswax 10.0 3. Cetearyl alcohol 1.0 4. Polyoxyethylene monooleate (20 mol) Dehydrated sorbitol 1.5 5. Sorbitan sesquioleate 0.5 6. Manufacturing Example 2 Product 5.0 7. Iron oxide black 5.0 8. Anhydrous oxalic acid 3.0 9. Remaining amount of purified water 10. 1,3-butanediol 10.0 11. Triethanolamine 1.5 12. Acryl acrylate copolymer emulsion (Note 10) 30.0 13. Appropriate amount of preservatives 14. Proper amount of flavor (Note 10) YODOSOL 32A707 (45% solid content) (manufactured by NSC Japan) (Manufacturing method) (1) The components 1 to 3 are uniformly mixed at 80 ° C. 154116. Doc -52- 201136613 (2) The components 4 to 8 are treated by a roller. (3) The components 9 to 14 are uniformly mixed at 80 ° C. (4) After mixing (1) and (2), add ( 3) Emulsify it. (5) Cool (4) to obtain 0/W type mascara. (Result) The mascara of Example 17 is "wet" and "no sticky". [0/W type mascara excellent in "smoothness". [Example 18] Cream lip gloss (ingredient) (%) 1. Product of Production Example 4 3.0 2. Diisostearyl malate 10.0 3. Lactic acid Stearyl ester 10.0 4. Hydrogenated polyisobutylene 30.0 5 · Triisooctanoic acid glycerin. Remaining amount 6. Flowing stone soil 5.0 7. Microcrystalline wax 2.0 8. 12-hydroxystearic acid 0.1 9. Alkenes-vinylpyrrolidone Polymer (Note 11) 0.5 10. Anhydrous citric acid (Note 12) 3.5 11. Titan 0.1 12. Red 201 0.3 13. Iron oxide black 0.05 14. Titanium oxide 0.2 15. Soy broken lipid 0.01 1541I6.doc -53 - 201136613 3.0 16. P-Oxyl cinnamic acid 2-ethylhexyl ester 17. Preservatives in an appropriate amount 18. 8. Flavor amount (Note 1 l) ANTARON V-220 (manufactured by ISP) (Note 12) AEROSIL 200 (Japan (Production method) (1) The components 1 to 9 are dissolved and mixed at 100 °C. (2) Adding components 10 to 18 to (1) and uniformly mixing and dispersing them. (3) Inject (2) into the tube and cool to obtain a creamy lip gloss. (Result) The creamy lip gloss of Example 18 was a creamy lip gloss which was excellent in "wet feeling", "no stickiness", and "smoothness". [Example 19] Lipstick (ingredient) (%) 1. Polyethylene wax 10.0 2. Carnauba wax 5.0 3. Paraffin 2.0 4. Residual amount of 2-ethylhexanoic acid cetyl ester 5. Production of product of Example 4 6 _Flower paraffin 10.0 7. Isodecyl isononanoate 10.0 8. Red 202 No. 0.5 9. Yellow No. 4 2.0 10. Titanium oxide 0.5 154116.doc •54 201136613 0.1 0.5 Appropriate amount 11. Iron oxide black 12. α-Tocopherol 13. Perfume (Manufacturing Method) (1) Components 1 to 7 were uniformly dissolved and mixed at 100 °C. (2) Add ingredients 8 to 13 in (1) and mix them evenly. (3) Inject (2) into the container and cool to obtain a lipstick. (Result) The lipstick of Example 19 was a lipstick which was excellent in "wet feeling", "no stickiness", and "smoothness". [Example 20] Oily eye shadow (ingredient) (%) 1. Fatty acid dextrin ester (Note 13) 2.0 2. Production of product of Example 4 2.0 3. Diisostearyl malate 2.5 4. 2-ethyl Cetyl cetyl ester 13.0 5. Lauric acid dextrin ester 2.0 6. Myristate dextrin ester 5.0 7. Hawthorn acid dextrin ester 5.0 8 · Flowing stone residue 9. Hydrogenated polyisobutylene 1.5 10. Anhydrous citric acid 6.0 11.Nylon powder 5.0 12. Polyoxane-treated talc (Note 14) 5.5 1541I6.doc -55- 201136613 13. Red 202 No. 0.05 14. Yellow No. 4 aluminum lake 0.05 15. Blue No. 1 aluminum lake 0.05 16 Mica Qin 1.5 17. Preservatives in an appropriate amount 18. Perfume amount (Note 13) Rheoreal TT (manufactured by Chiba Powder Co., Ltd.) (Note 14) Dimethyl phthalocyanine 5% treatment (manufacturing method) (1) At 100 ° C The components 1 to 9 were dissolved and mixed. (2) Adding components 10 to 18 to (1) and uniformly mixing and dispersing them. (3) (2) was injected into a container and allowed to cool and solidify to obtain an oily eye shadow. (Results) The oily eye shadow of Example 20 was an oily eye shadow excellent in "wetness" and "smoothness". [Example 21] Solid powdery foundation", "No stickiness degree (ingredient) (%) 1. Dimercapto polyoxyalkylene treatment of talc 30.0 2. Dimercapto polyoxyalkylene treatment mica 15.0 3. Two曱-based polyoxyalkylene treatment of mica titanium oxide 15.0 4. Dimethyl polyoxymethane treatment of sericite residual amount 5. Synthesis of phlogopite 5.0 6. Iron oxide yellow 2.0 7. Titan 0.5 154116.doc -56- 201136613 8 . Iron oxide black 0.2 9. Preservatives in an appropriate amount 10. Production of product of Example 3 3.0 11. Flowing paraffin 3.0 12 - Methyl polyoxyl phthalate 1.0 13. 2-ethyl hexanoic acid glyceride 2.0 14. Flavor amount (manufacture (1) The components 1 to 9 were uniformly dispersed at 75 ° C using a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.) (2) The components 10 to 13 were uniformly mixed and dissolved. (3) The Scherr mixer is added (2) and 14 while being uniformly dispersed. (4) The (3) is pulverized by a pulverizer. (7) The (4) is filled in a metal container, and it is condensed into $ A solid powdery foundation was obtained. (Results) (4) The powdery foundation of Example 21 was "wet feeling", "no stickiness", Smoothness of "excellent in the solid powder foundation. [Example 22] Solid powdery eye shadow (%) 10.0 Remaining amount 30.0 (ingredient) 1·Dimercapto polyoxyalkylene treatment of synthetic phlogopite 2. Dimethyl polyoxyalkylene treatment of talc 3 • Titanium oxide coated mica I541l6 .doc -57- 201136613 4. Boron nitride 5.0 5 · Polyethylene terephthalate-aluminum-epoxy laminated powder 5.0 6. Ultramarine 2.0 7. Red 202 0.5 8· Polyalkyl acrylate 1.0 9 Preservatives in an appropriate amount 10. Production of product of Example 2 4.0 11. Flowing paraffin 3.0 12. Dimercapto polyoxyalkylene 2.0 13. 2-Ethyl glycerol vinegar 2.0 14. Proper amount of perfume (manufacturing method) (1) The components 1 to 9 were uniformly dispersed at 75 ° C using a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). (2) The components 10 to 13 are uniformly mixed and dissolved. (3) The surface was stirred by a Henschel mixer (1) and (2) and 14 were added and uniformly dispersed. (4) Crush the (3) with a pulverizer. (5) (4) was filled in a metal container and compression-molded to obtain a solid powdery eye shadow. (Result) The solid powdery eye shadow of Example 22 was a solid powdery eye shadow which was excellent in "wet feeling", "no stickiness degree" and "smoothness". 154116.doc -58 - 201136613 [Example 23] Solid powdery blush (ingredient) (%) 1. Mica 20.0 2. Residual amount of talc 3. Titanium oxide coated mica 10.0 4. Ultramarine 0.5 5. Red 226 No. 0.2 6 Polyalkyl acrylate 1.0 7. Preservatives in an appropriate amount 8. Production of product of Example 1 3.0 9. Flowing paraffin 2.0 10. Dimethyl polyoxane 1.0 11 · 2-ethyl glyceride g 12. Spice (Manufacturing method) 1.0 Appropriate amount (1) Using a Henschel mixer (Mitsui 1 to 7 uniformly dispersed. Manufactured by Miichi Co., Ltd.) at 75. (: The component (2) is heated to 65 ° C in the components 8 to 11 and uniformly mixed and dissolved. (3) One side (2) and 12 are added by stirring with a Henschel mixer (1). (4) The pulverization is carried out by a pulverizer. (5) The (4) is filled in a metal container with a red leg. (Result), compression molding is carried out to obtain a solid powder 154116.doc · 59· 201136613 Example 23 The solid powdery red is a solid powdery red which is excellent in "wet feeling", "no stickiness" and "smoothness". [Example 24] Stick concealer (ingredient) (〇/〇) 1 Paraffin 5.0 2. Polyethylene oxime 5.0 3. Candidella wax 2.0 4. Product 15.0 for the manufacture of Example 4. 5. Tri-2-ethyl glycerol vinegar 15.0 6. Nonylphenyl polyoxane 5.0 7. Acetic acid liquid lanolin 1〇.〇8. p-Oxyl cinnamic acid 2-ethylhexyl ester 5.0 9. Titanium oxide 20.0 10. Iron oxide yellow 2.0 11. Iron oxide 0.5 12. Iron oxide black 0.2 13. Mica 7.0 14. Appropriate amount of preservative (manufacturing method) (1) The components 1 to 8 are mixed and dissolved at 100 ° C. (2) The components 9 to 14 are uniformly mixed in (1) at 90 ° C. (3) ) (2) was treated with a three-roll mill. (4) After defoaming (3) was dissolved in the vessel under it, it was cooled at 4 ° C to obtain a stick concealer. 154M6.doc • 60-201136613 (Results) Sense of Run, "No Sticky Sense" (%) 2.0 5.0 5.0 3.0 3.0 10.0 10.0 The stick concealer of Example 24 is excellent in "humidity ~" and "smoothness" Shape concealer [Sin slave example 25] W/〇 type sunscreen (ingredient) 1. Zinc oxide 2. Polyoxynium oxide coated titanium oxide (Note 14) 3. Di(octyl-decanoic acid) glyceride 4·2 2-ethyl hexanoic acid glyceride 5. Standard acid october 6: p-methoxy cinnamic acid 2-ethylhexyl ester 7 · decamethylcyclopentaoxane 8. methyl polyoxy siloxane / cetyl wax Base mercapto polyoxyalkylene-poly(oxyethylene-oxypropylene) methyl polyoxyalkylene copolymer (Note 15) 1.8 9. Product of manufacture of Example 3.0 3.0 10. Preservative amount 11. Sodium gasification 0.3 12 . Remaining amount of purified water 13. Dipropylene glycol 5.0 14. Ethanol 5.0 15. Flavor amount (Note 15) ABIL EM-90 (manufactured by EVONIC GOLDSCHMIDT GMBH) 154116.doc -61 - 201136613 (Manufacturing method) (1) Ingredient 3 4 Hot dissolved, ingredients 1, 2 and uniformly dispersed using a roll it. (2) After dissolving the components 5 to 10 at 70 ° C, (1) was added at 6 ° C and uniformly mixed and dissolved. (3) After the components 11 to 13 were mixed and dissolved, they were added to (2) at 60 ° C and emulsified. (4) Adding components 14 and 15 to (3) and uniformly mixing them to obtain a W/0 type sunscreen. (Result) The W/0 type sunscreen of Example 25 was a W/0 type sunscreen which was excellent in "wet feeling", "no stickiness" and "smoothness". [Example 26] W/0 type foundation (%) (ingredient) 1. Polyoxyethylene decyl fluorenyl-polyoxypropylene oleyl ester methyl methoxy oxane-dimethyl methoxy olefin copolymer (Note 16 2 〇2· PEG-3 dimethyl polyoxane (Note 17) 1〇3· dimethyl polyoxane π Λ 4. Polyoxane treatment of iron oxide red (Note 14) 5. Polyoxyl Treatment of iron oxide yellow (Note 14) 6·Polyoxygen treatment of iron oxide black (Note 14) 7. Polyoxygenated titanium oxide (Note 14) 8. Polyoxygenated talc (Note 14) 9. Tri 2 - B Glyceric acid glyceride 154116.doc -62 - 201136613 5.0 0.5 Residual amount 15.0 0.5 Appropriate amount of i〇. Product of manufacture example 2. 11. Sesquite oleic acid sorbitan vinegar 12. Purified water Π.1,3- Butanediol 14. Gasification sodium 15. Preservatives 16·Perfume (s main 16) KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.) (s main 17) KF-6015 (manufactured by Shin-Etsu Chemical Co., Ltd.) (manufacturing method) ( 1) Mix ingredients 1 to 3 uniformly. (2) The components 4 to 11 are uniformly dispersed by light. (3) Add (2) to (1) and mix them evenly. (4) Components 12 to 16 were added to (3) and emulsified to obtain a w/〇 type foundation. (Result) The commercially available foundation of Example 26 was a W/〇 type foundation which was excellent in "wet feeling", "no stickiness" and "smoothness". [Example 27] 0/W type foundation (ingredient) 1. Oleic acid polyoxyethylene g (2 〇 Mo) dehydrated sorbitol 2. Sesquite oleic acid desorbed sorbitol 3·1, 3 - Butanediol 4. Polyoxygenated titanium oxide (Note 14) (%) 0.5 0.5 10.0 10.0 201136613 0.4 2.0 0.1 5.0 0.3 1.0 Remaining amount 2.0 1.0 0.5 1.0 2.0 1.0 2.0 0.5 Appropriate amount 5. Polyfluorene treatment of iron (Note 14) 6. Polyoxane treatment of iron oxide yellow (Note 14) 7. Polyoxane treatment of iron oxide black (Note 14) 8. Polyoxane treatment of talc (Note 14) 9. Carboxyrene polymer 10. Three Ethanolamine 11. Purified water 12. Ethanol 13. Stearic acid 14. Behenyl alcohol 1 5. Flowing paraffin 16. Production of product of Example 2. 17. Tri-ethyl hexanoic acid glyceride 18-p-methoxy cinnamic acid 2-ethylhexyl ester 19. Vaseline 20. Preservative 21. Perfume (manufacturing method) (1) The components 1 to 8 were uniformly dispersed by using the report. (2) The components 9 to 12 are uniformly mixed. (3) Add (丨) to (2) and mix them evenly. (4) Mix and dissolve the components 13 to 2 at 8 (TC). (5) Add (4) to (1) at 8 G ° C and emulsify it. (6) Cool (5) and add component 21 to obtain 〇/Slip type foundation. 154116,doc -64· 201136613 (Result) The 〇/W type foundation of Example 27 is “wet sensation”, “no stickiness” and “smoothness” 〇/W type foundation [Example 28] Oily solid foundation (ingredient) (%) 1. Talc 15.0 2. Mica 10.0 3. Polyoxane-treated titanium oxide (Note 14) 15.0 4. Polyoxane-treated iron (Note 14) 1.0 5·Polyoxime treatment of iron oxide yellow (Note 14) 3.0 6. Polyoxane treatment of iron oxide black (Note i 4) 0.2 7. Polyethylene wax 7.0 8. Microcrystalline wax 6.0 9. Di-2-ethylhexanoic acid Glycerol West Remaining Amount 1 制造.Production of the product of Example 1 5.0 11·Dimethylpolyoxane 5.0 12. Flowing paraffin 20.0 Polyoxyethylene sulfhydryl oxylate _ polyoxypropylene oleyl ester methyl hydrazine Oxyalkylene-dimethyloxane copolymer (Note 16) 2.0 14. Preservative amount 15 · Proper amount (manufacturing method) (1) The components 7 to 14 are heated and dissolved at 90 C. (2) In (1) Add ingredients 1 to 6 and use a roller to make It is uniformly dispersed. 154116.doc -65· 201136613 (3) Adding component 15 to (2), dissolving at 80 ° C, and filling it into a metal container to obtain an oily solid foundation. (Results) Example 28 The oily solid foundation is an oily solid foundation excellent in "wet feeling", "no stickiness" and "smoothness". [Example 29] Make-up milk (ingredients) (%) 1. Cetearyl alcohol 2.0 2 . p-Methoxy cinnamic acid 2-ethylhexyl ester 5.0 3. Preparation of product of Example 4 8.0 4. Tri-ethylhexanoic acid glyceride 3.0 5. Purified water remaining 6. N-stearyl sulfhydryl- N-decyl taurine sodium 0.5 7. Carboxyvinyl polymer 0.1 8. Acrylic acid/alkyl methacrylate copolymer 0.1 9. Sodium hydroxide 0.05 10. Ethanol 10.0 11. 1,3-butanediol 10.0 12. Antiseptic Appropriate amount of the agent 13. Proper amount of the fragrance (manufacturing method) (1) The components 1 to 4 are uniformly dissolved at 80 ° C. (2) The components 5 to 12 are uniformly dissolved at 80 ° C. (3) In (2) (1) was added and emulsified. 154116.doc -66- 201136613 (4) Adding component 13 to (3) and cooling to obtain pre-makeup milk. (Result) The makeup of Example 29 was "wet" , "Non-stickiness degree of smoothness" of the excellent makeup before the milk. [Example 30] Body milk (ingredient) (%) 1. Stearic acid 1.0 2. Polyoxyethylene monooleate (20 mol) Dehydrated sorbitol 0.5 3. Sesame oleic acid sorbitan ester 0.5 4. Camelliol 0.5 5. 2-Ethyl glyceride 2.0 6. Flowing paraffin 2.0 7. Preparation of product of Example 1 5.0 8. Ethanol 10.0 9. Dipropylene glycol 10.0 10. Triethanolamine 1.0 11. Purified water remaining 12. Glycerol 5.0 13.1,3-butanediol 5.0 14. Acrylic acid/alkyl methacrylate copolymer 0.2 15. Preservative amount 16. Flavour amount (manufacturing method) 1541l6.doc -67- 201136613 (1) at 80 The components 1 to 7 were uniformly dissolved at °C. (2) The components 8 to 16 were uniformly dissolved at 80 °C. (3) Add (1) to (2) and emulsify it. (4) The body lotion is obtained by stirring (3) with stirring. (Result) The body lotion of Example 30 was a body lotion which was excellent in "wet feeling", "no stickiness" and "smoothness". [Example 31] Make-up remover (ingredient) (%) 1·1,3-butanediol 15.0 2·Acrylic acid-based ester copolymer emulsion (Note 1〇) 2.5 3. L-arginine 0.5 4. Purified water Remaining amount 5. Light-flowing isomerized paraffin (Note 18) 3.0 6. Production of product of Example 1 2.0 7. Preservative amount 8. Spice amount (Note 18) IP Solvent 1620 (manufactured by Idemitsu Kosan Co., Ltd.) (Manufacturing method) (1) Mix ingredients 1 to 4 evenly. (2) Components 5 to 8 were added to (1) at 60 ° C and emulsified. (3) - Surface search (2) - Surface cooling to obtain cleansing milk. (Results) The cleansing milk of Example 3 1 was "wet feeling", "degree of no stickiness", "soft 154116.doc -68 · (%) 10.0 3.0 2.0 2.0 2.0 3.0 5.0 1.0 Remaining amount 3.0 5.0 3.0 5.0 201136613 Slipperiness excellent makeup remover β [Example 32] Waterproof mascara (ingredient) I. Pentaerythritol rosin ester 2 · Candidella resin 3. Yellow beeswax 4. Ground wax 5. Palmitic acid dextrin 6. Trimethyl decyloxy decanoic acid 7. Dimercapto distearyl ammonium montmorillonite 8. Carbonic acid acrylate 9. Light flow isomerization butterfly (Note 8) 10. Production of product II of Example 2 Iron Oxide Black 12. Cerium Oxide 13. Talc (Manufacturing Method) (1) The components 1 to 5 are heated to 11 Torr. Hey. (2) Components 6 to 10 are added to (1) and mixed. (3) Components 11 to 13 were added to (2) and mixed with 〇 (4) The roller pair (3) was treated (result) to obtain a waterproof mascara. Real J, Example 32 waterproof mascara

^ 屬潤感柔滑度」優異之防水睫毛膏。〜 154U6.doc •69- 201136613 (%) 11.0 16.0 8.0 剩餘量 3.0 15.0 5.0 適量適量 [實施例3 3 ]油性眼線液 (成分） 1. 地蠟 2. 聚異丁烯 3·聚乙烯蠟 4. 輕質流動異構石蠟 5. 製造實施例1之產物 6·聚矽氧處理氧化鐵黑（註 7·聚矽氧處理滑石（註 8. 防腐劑 9. 香料 (製造方法） ⑴將成分1〜5加M 並使其均勻混合。 ⑺將成分6〜9加熱至8(TC並使其均勻混合。 (3)於（1)中添加（2)並使其均勻混合。 W利用1¾對（3)進行處理而獲得油性眼線液。 (結果）實施例33之油性眼線液為「濕潤感」、「無黏腻感程度」、「柔滑度」優異之油性眼線液。 3利用聚矽氧磷酸酯進行表面被覆處理之粉體的製造例利用由上述1之製造實施例製造之包含聚矽氧磷酸三酯之產物’藉由以下方法製備表面被覆處理粉體。其他粉體亦以相同之方式製備。 [製造實施例5]氧化鈦之例 1541I6.doc -70- 201136613 於氧化鈦49.0 g中添加溶解有作為表面處理劑之製造實施例1之產物1.0 g與正己烷70 g的溶液，利用塗料振盪器使其尚分散30分鐘。其後，將所得之漿料狀物風乾，於 12 5 C下般燒1小時並利用粉碎機粉碎，而獲得利用2. 〇 %之製造實施例1之產物對粉體進行表面處理的氧化鈦。 [製造實施例6]鐵丹或氧化鐵之例與上述同樣’於鐵丹或氧化鐵47.5 g中，添加溶解有作為表面處理劑之製造實施例2之產物25 g與正己烷7〇经的混合液，利用塗料振盪器使其高分散3〇分鐘。其後，將所得之漿料狀物風乾，於125t下煅燒丨小時並利用粉碎機粉碎’而獲得利用5.0%之製造實施例2之產物對粉體進行表面處理的粉體。 [製造實施例7]滑石、雲母或絹雲母之例與上述同樣，於滑石、雲母或絹雲母49 5 g中，添加溶解有作為表面處理劑之製造實施例1之產物〇·5 g與正己烷 70 g的混合液’利用塗料振盪器使其高分散30分鐘。其後，將所得之漿料狀物風乾，於125〇c下煅燒丨小時並利用粉碎機粉碎，而獲得利用1 .〇%之製造實施例1之產物對粉體進行表面處理的粉體。 [製造實施例8]複合處理之例於異丙醇750 g中’添加作為表面處理劑之製造實施例2 之產物45 g與異丙基三異硬脂基鈦酸酯15 g並使其溶解後，投入至20 L之亨舍爾混合機中。於其中添加氧化鈦 (TIPAQUE CR-50 ’石原產業製造）2940 g，於7(TC下均勻 154I16.doc •71· 201136613 分散。繼而，加熱至12(Tc，一面於減壓下餾去溶劑—面欖拌2小時左右。粉體乾燥後，冷卻至室溫，自混合機中取出’利用霧化器粉碎。於130。(：之恆溫槽中煅燒6小時，而獲得利用1_5%之製造實施例2之產物及0.5%之異丙基三異硬脂基鈦酸酯對粉體進行表面處理的氧化鈦。 [製造實施例9]複合處理之例於異丙醇1250 g中，添加作為表面處理劑之製造實施例 2之產物50 g與異丙基三異硬脂基鈦酸酯5〇 g並使其溶解後’投入至20 L之亨舍爾混合機中。於其中添加氧化缺 (TIPAQUE CR-5〇，石原產業製造）49〇〇 g，於7(rc下均勾分散。繼而，加熱至12〇*t，一面於減壓下餾去溶劑一面搜拌2小時左右。粉體乾燥後，冷卻至室溫，自混合機中取出並利用霧化器粉碎。於13〇*>C之恆溫槽中煅燒6小時，而獲得利用1.0%之製造實施例2之產物及1.0%之異丙基三異硬脂基鈦酸酯對粉體進行表面處理的氧化鈦。 [製造實施例10]複合處理之例於異丙醇750 g中，添加作為表面處理劑之製造實施例2 之產物1 5 g與異丙基三異硬脂基鈦酸酯45 g並使其溶解後，投入至20 L之亨舍爾混合機中。於其中添加氧化鈦 (TIPAQUE CR-5〇 ’石原產業製造）294〇 g，於7〇。〇下均勻分散。繼而，加熱至120°C，一面於減壓下餾去溶劑一面搜拌2小時左右。粉體乾燥後，冷卻至室溫，自混合機中取出並利用霧化器粉碎。於13〇〇c之恆溫槽中煅燒6小時，而獲得利用0.5%之製造實施例2之產物及ι·5%之異丙基三 154116.doc •72· 201136613 異硬脂基鈦酸酯對粉體進行表面處理的氧化鈦。 [製造比較例1] 於氧化鈦49.0 g中，添加溶解有作為表面處理劑之異丙基三異硬脂基鈦酸酯丨.0 g與異丙醇5〇 g的溶液，利用塗料振盈器使其高分散30分鐘其後，將所得之㈣狀物風乾，於125°C下烺燒1小時並利用粉碎機粉碎，而獲得利用 2.0%之異丙基三異硬脂基鈦酸酯對粉體進行表面處理的氧化鈦》 (表面被覆處理粉體（複合處理）之分散性之評價）對製造貫施例8〜10及製造比較例1之表面被覆處理氧化鈦之分散性進行評價。作為分散溶劑，使用化妝品中通用之（1)十曱基環五矽氧烷、（2)三2-乙基已酸甘油酯、（3)使十甲基環五矽氧烷、對甲氧基肉桂酸2_乙基己酯與異壬酸異十二烧基酯以22:6:2質量之比例混合而成者（以下，記作混合溶劑）。於標準瓶中添加表面被覆處理氧化鈦1 g，於其中添加上述分散溶劑30 ml並蓋上蓋子，歷時30分鐘，藉由超音波機（BRANSONIC 1510J-DTH 42 kHz)進行分散。其後，移入至底面積1 cm2、高度30 cm之沈降管中，於室溫下靜置，6天後以目視評價該分散層之體積β此時’將沈降管之刻度之讀取值（分散層之高度）作為判定基準。結果示於表3。 (判定基準） ◎:分散層之高度為25 cm以上 0 :分散層之高度為20 cm以上未達25 cm 154116.doc -73- 201136613 A:分散層之高度為l〇cm以上未達20cm x ··分散層之高度未達10 cm [表3] 表3^ It is a waterproof mascara with excellent smoothness. ~ 154U6.doc •69- 201136613 (%) 11.0 16.0 8.0 Remaining amount 3.0 15.0 5.0 Appropriate amount [Example 3 3 ] Oily eyeliner (ingredient) 1. Ground wax 2. Polyisobutylene 3. Polyethylene wax 4. Light weight Flowing isoparaffin 5. Production of product of Example 1 6: Polyoxane treatment of iron oxide black (Note 7: Polyoxane treatment of talc (Note 8. Preservatives 9. Perfume (manufacturing method) (1) Adding ingredients 1 to 5 M and uniformly mix them. (7) Heat the ingredients 6 to 9 to 8 (TC and mix them evenly. (3) Add (2) to (1) and mix them evenly. W uses 13⁄4 pairs (3) Oily eyeliner was obtained by the treatment. (Result) The oily eyeliner of Example 33 was an oily eyeliner excellent in "wet feeling", "no stickiness", and "smoothness". 3 Surface treatment using polyphosphoric acid phosphate Production Example of Coating Powder The surface-coated powder was prepared by the following method using the product of the polyphosphoric acid triester manufactured by the production example of the above 1. Other powders were also prepared in the same manner. Production Example 5] Example of titanium oxide 1541I6.doc -70-201136613 in titanium oxide 49 A solution of 1.0 g of the product of Production Example 1 as a surface treatment agent and 70 g of n-hexane was added to .0 g, and it was further dispersed by a coating shaker for 30 minutes. Thereafter, the obtained slurry was air-dried. The mixture was fired for 1 hour at 12 5 C and pulverized by a pulverizer to obtain titanium oxide surface-treated with the product of the production example of 2. 。%. [Production Example 6] Iron dan or oxidation In the same manner as described above, a mixture of 25 g of a product of Production Example 2 in which a surface treatment agent was dissolved and n-hexane 7 〇 was added in the same manner as described above, and a coating oscillator was used to make it high. After dispersing for 3 minutes, the obtained slurry was air-dried, calcined at 125 t for 丨 hours, and pulverized by a pulverizer to obtain a powder obtained by surface-treating the powder with 5.0% of the product of Production Example 2. [Production Example 7] Example of talc, mica or sericite In the same manner as described above, in the talc, mica or sericite 49 5 g, the product of the production example 1 in which the surface treatment agent was dissolved was added 〇·5 g and a mixture of n-hexane 70 g The shaker was allowed to disperse for 30 minutes. Thereafter, the obtained slurry was air-dried, calcined at 125 ° C for 丨 hours, and pulverized by a pulverizer to obtain a product of Production Example 1 using 〇%. Powder for surface treatment of powder. [Production Example 8] Example of composite treatment In the case of 750 g of isopropyl alcohol, the product of Production Example 2 was added as a surface treatment agent, 45 g and isopropyl triisostearate. After 15 g of the titanate was dissolved and dissolved, it was put into a 20 L Henschel mixer. 2940 g of titanium oxide (TIPAQUE CR-50 'made by Ishihara Industry Co., Ltd.) was added thereto, and dispersed at 7 (TC 146I16.doc • 71·201136613 under TC. Then, it was heated to 12 (Tc, and the solvent was distilled off under reduced pressure). Mix the dough for about 2 hours. After the powder is dried, cool to room temperature, take it out of the mixer, and pulverize it with a nebulizer. After calcination for 6 hours in a thermostat bath, obtain a 1-5% production. The product of Example 2 and 0.5% of isopropyl triisostearyl titanate were surface-treated titanium oxide. [Production Example 9] An example of a composite treatment was added to isopropyl alcohol 1250 g as a surface. 50 g of the product of the production example 2 and isopropyl triisostearyl titanate 5 〇g and dissolved, and then put into a 20 L Henschel mixer. TIPAQUE CR-5〇, manufactured by Ishihara Industry Co., Ltd., 49〇〇g, is dispersed at 7 (rc). Then, it is heated to 12〇*t, and the solvent is distilled off under reduced pressure for about 2 hours. After drying, it is cooled to room temperature, taken out from the mixer and pulverized by a nebulizer. It is constant at 13〇*>C The cell was calcined for 6 hours to obtain a titanium oxide surface-treated with 1.0% of the product of Production Example 2 and 1.0% of isopropyltriisostearyl titanate. [Production Example 10] Composite An example of the treatment was carried out in 750 g of isopropyl alcohol, and 15 g of the product of Production Example 2 as a surface treatment agent and 45 g of isopropyl triisostearyl titanate were added and dissolved, and then poured into 20 L. In the Henschel mixer, 294 〇g of titanium oxide (TIPAQUE CR-5〇 'Ishihara Industry Co., Ltd.) was added thereto, and it was uniformly dispersed under the crucible. Then, it was heated to 120 ° C under reduced pressure. The solvent was distilled off and mixed for about 2 hours. After the powder was dried, it was cooled to room temperature, taken out from the mixer and pulverized by a nebulizer, and calcined in a constant temperature bath of 13 ° C for 6 hours to obtain 0.5% utilization. The product of the production example 2 and 5% isopropyl propylene 154116.doc • 72·201136613 The surface treated titanium oxide of the isostearyl titanate. [Manufacturing Comparative Example 1] In 49.0 g, isopropyl triisostearyl titanate 丨.0 g and different dissolved as a surface treatment agent were added. A solution of 5 〇g of propanol was dispersed for 30 minutes by using a paint shaker, and then the obtained (tetra) was air-dried, simmered at 125 ° C for 1 hour, and pulverized by a pulverizer to obtain 2.0% of utilization. Titanium oxide surface-treated with isopropyl triisostearyl titanate (Evaluation of dispersibility of surface-coated powder (composite treatment)) For the production of Examples 8 to 10 and manufacturing comparative examples The dispersibility of the surface-coated titanium oxide of 1 was evaluated. As the dispersing solvent, (1) decadecylcyclopentaoxane, (2) tri-2-ethylhexanoic acid glyceride, (3) decamethylcyclopentaoxane, p-methoxy The 2-ethylhexyl cinnamate and the isododecyl isocyanate are mixed at a ratio of 22:6:2 by mass (hereinafter referred to as a mixed solvent). 1 g of surface-coated titanium oxide was added to a standard bottle, and 30 ml of the above-mentioned dispersion solvent was added thereto, and the lid was placed thereon for 30 minutes, and dispersed by an ultrasonic machine (BRANSONIC 1510J-DTH 42 kHz). Thereafter, it was transferred to a settling tube having a bottom area of 1 cm 2 and a height of 30 cm, and allowed to stand at room temperature. After 6 days, the volume of the dispersion layer was visually evaluated β at this time 'the reading value of the scale of the settling tube ( The height of the dispersion layer is used as a criterion for determination. The results are shown in Table 3. (Criteria for judging) ◎: The height of the dispersion layer is 25 cm or more. 0: The height of the dispersion layer is 20 cm or more and less than 25 cm. 154116.doc -73- 201136613 A: The height of the dispersion layer is l〇cm or more and less than 20 cm x · The height of the dispersion layer is less than 10 cm [Table 3] Table 3

分散溶劑製造實施例8 製造實施例9 製造實施例10 製造比較例1 (1) 十甲基環五矽氧烷分散層之高度(cm) 29 27 25 0 判定 ◎ ◎ ◎ X (2) 三2-乙基已酸甘油酯分散層之高度(cm) 29 29 29 16 判定 ◎ ◎ ◎ Δ (3) 混合溶劑分散層之高度(cm) 29 29 28 0 判定 ◎ ◎ ◎ X 4含有利用聚矽氧磷酸酯進行表面被覆處理之粉體的化妝料之配方例將由上述製造實施例製造之表面被覆處理粉體用於以下配方。於以下之實施例中，例如所謂「製造實施例1(2.0%)處理氧化鈦」意指藉由2.0質量％之量的製造實施例1中獲得之產物（包含聚矽氧磷酸三酯之混合物）對氧化鈦進行被覆之表面處理粉體。 [實施例34〜39及比較例10〜12] W/0型粉底 [表4] 154116.doc -74- 201136613 表 4 (%)Dispersion Solvent Production Example 8 Production Example 9 Production Example 10 Production Comparative Example 1 (1) Height of the dispersion layer of decamethylcyclopentaoxane (cm) 29 27 25 0 Judgment ◎ ◎ ◎ X (2) 3 - Height of the ethyl glyceride dispersion layer (cm) 29 29 29 16 Judgment ◎ ◎ ◎ Δ (3) Height of the mixed solvent dispersion layer (cm) 29 29 28 0 Judgment ◎ ◎ ◎ X 4 contains polyoxyl Formulation Example of Cosmetics of Phosphate Surface-Coated Powder The surface-coated powder produced by the above Production Example was used in the following formulation. In the following examples, for example, "manufacturing Example 1 (2.0%) treated titanium oxide" means a product obtained in Production Example 1 in an amount of 2.0% by mass (containing a mixture of polyphosphoric acid triesters) A surface-treated powder coated with titanium oxide. [Examples 34 to 39 and Comparative Examples 10 to 12] W/0 type foundation [Table 4] 154116.doc -74- 201136613 Table 4 (%)

No. 成分實施例比較例 34 35 36 37 38 39 10 11 12 1 製造實施例1(2.0%)處理氧化鈦 10 - 2 製造實施例2(2.0%)處理氧化鈦 - 10 3 製造實施例3(2.0%)處理氧化鈦 - - 10 - - - • - 4 製造實施例4(2.0%)處理氧化鈦 - - - 10 - - - - - 5 製造實施例1(0.5%)處理氧化鈦 - - - - 10 - - - - 6 製造實施例2(0.5%)處理氧化鈦 - - - - - 10 - - - 7 甲基氫聚矽氧烷(0.02%)處理氧化鈦(註1) - - - - - - 10 - - 8 甲基氩聚矽氧烷(2.0%)處理氧化鈦 (註1) - - - - - - - 10 - 9 聚矽氧(2.0%)處理氧化鈦(註2) - - - - - - - - 10 10 氧化鐵紅 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 11 黃色氧化鐵 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 12 氧化鐵黑 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 13 POE甲基矽氧烷-POP油基甲基矽氧烷-二甲基矽氧烷共聚物(註3) 1 1 1 1 1 1 1 1 1 14 二異硬脂酸甘油酯 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 15 卵磷脂 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 16 二甲基聚矽氧烷 3 3 3 3 3 3 3 3 3 17 三2-乙基已酸甘油酯 1 1 1 1 1 1 1 1 1 18 二甲基二硬脂基鋰蒙脫石 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 19 PEG-9聚二甲基矽烷氧基乙基二甲基聚矽氧烷(註4) 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 20 醇 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 21 十曱基環五矽氧烷 8 8 8 8 8 8 8 8 8 22 二乙基已酸新戊二醇酯 10 10 10 10 10 10 10 10 10 23 PEG-9聚二甲基矽烷氧基乙基二甲基聚矽氧烷(註4) 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 24 醇 7 7 7 7 7 7 7 7 7 25 防腐劑適量適量適量適量適量適量適量適量適量 26 氣化納 0.3 0.3 0.3 0.3 0.3 0.3 03 0.3 0.3 27 純化水剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量 28 香料適量適量適量適量適量適量適量適量適量評價項目與判定結果化妝膜之均勻性 ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ 化妝持久效果 ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ 柔滑之使用感 ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ (註1)99P處理(信越化學工業公司製造） (註2)SA處理CR-50(三好化成公司製造) (註3)KF-6〇26(信越化學工業公司製造） (註4)KF-6028(信越化學工業公司製造） -75- 154116.doc 201136613 (製造方法） (1) 利用輥對成分1〜17進行處理。 (2) 利用較對成分18〜21進行處理。 (3) 利用分散機（Dlsper)將（1)、（2)及成分22、23均勻混合。 (4) 於（3)中緩緩添加成分24〜28並使其乳化。 (5) 將（4)消泡並填充至容器中而獲得w/〇型粉底。 (評價）對實施例34〜39、及比較例10〜12之冒/〇型粉底，化妝品評價專家小組20人分別依據以下評價基準對「化妝膜之均勻性」、化妝持久效果」、「柔滑之使用感」各項目進行7 個階段之評價，進而利用整個小組之評分之平均分並依據以下判定基準進行判定。 [評價基準] (評價結果） :(評分）非常良好 .6分良好 :5分稍良好 :4分普通 :3分稍不良 :2分不良 :1分非常不良 :0分 [判定基準] (評分之平均分）：（判定） 5·0以上：◎非常良好 154116.doc -76* 201136613 3.5以上〜未達5 〇 1.5以上〜未達3 $ 未達1.5 (結果）〇良好 △不良 χ非常不良實施例34〜39之W/0型粉底為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之W/0型粉底。比較例10之 W/〇型粉底由於氧化鈦中之曱基氫聚矽氧烷之處理量較少’故而為化妝膜之均勻性、化妝持久效果、柔滑之使用感較差者’又’即便氧化鈦中之處理量較多之比較例丨丄，亦為化妝膜之均勻性、化妝持久效果、柔滑之使用感較差者。進而’比較例12之W/0型粉底亦為化妝膜之均勻性、化妝持久效果、柔滑之使用感較差者。 [實施例40] 0/W型液體粉底 (成分） 1.單油酸聚氧乙烯去水山梨醇酯（2〇E〇) 2·倍半油酸去水山梨醇酯 3. 1，3-丁二醇 4·製造實施例4(3.0%)處理氧化鈦 5.製造實施例4(3 ·0%)處理鐵丹 6·製造實施例4(3.0%)處理氧化鐵黃 7 ·製造貫施例4 (3 · 0 %)處理氧化鐵黑 8.製造實施例4(3.〇%)處理滑石 (%) 0.5 0.510.010.0 0.42.00.1 5.0 9.羧乙烯聚合物 0.3 10.三乙醇胺 154116.doc -77· 201136613 剩餘量 2.0 1.0 0.5 2.0 2.0 2.0 0.5 適量適量 11. 純化水 12. 乙醇 13. 硬脂酸 14. 山薔醇 15. 流動石蠟 16. 三2 -乙基已酸甘油醋 17. 對曱氧基肉桂酸2_乙基己醋 18. 凡士林 19. 防腐劑 20. 香料 (製造方法） (1) 利用棍將成分1〜8均勻分散 (2) 將成分9〜12均勻混合。 (3) 於（2)中添加（1)並使其均勻混合。 (4) 於80°C下將成分13〜19混合溶解。 (5) 於80°C下，於（3)中添加（4)並使其乳化。 (6) 將（5)冷卻並添加成分2〇而獲得〇/貿型粉底。 (結果）實施例40之0/W型粉底為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之0/W型粉底。 [實施例41 ]油性固體粉底 (成分）（％) 1. 滑石 15.0 2. 雲母 10.0 154116.doc _0 201136613 3.製造實施例2(5.0%)處理氧化鈦 15.0 4.製造實施例2(5.0%)處理鐵丹 1.0 5.製造實施例2(5 _0%)處理氧化鐵黃 3.0 6.製造實施例2(5.0。/〇)處理氧化鐵里 0.2 7.聚乙烯蠟 7.0 8.微晶蠟 6.0 9.三2-乙基已酸甘油酯剩餘量 10.二甲基聚矽氧烷 10.0 11.流動石蠟 20.0 12.聚氧乙稀甲基石夕氧烧-聚氧丙稀油醇酉旨甲基石夕氧烧-二甲基石夕氧烧共聚物（註3) 2.0 13.防腐劑適量 14 ·香料適量 (製造方法） (1)於90°C下將成分7〜13加熱溶解。 (2)於（1)中添加成分1〜6並利用輥使其均勻分散。 (3)於（2)中添加成分14並於80°C下溶解後，填充至金屬容器中，而獲得油性固體粉底。 (結果）實施例41之油性固體粉底為化妝瞑之妗— 、〈A勻性、化妝持久效果、柔滑之使用感優異之油性固體粉底。 (%) 5.0 [實施例42]棒狀油性固體遮瑕膏 (成分） 1.石蠟 154116.doc •79- 201136613 5.0 2.0 15.0 25.0 10.0 2. 聚乙烯蠟 3. 堪地里拉蠟 4. 三-2-乙基已酸甘油醋 5. 曱基苯基聚矽氧烷 6. 乙酸液狀羊毛脂 7. 對甲氧基肉桂酸2-乙基己酿 5.0 8. 製造實施例3(7.〇%)處理氧化鈦 20.0 9. 製造實施例3(7.0%)處理氧化鐵黃 2 〇 10. 製造實施例3(7·0%)處理鐵丹〇 5 11. 製造實施例3(7.0%)處理氧化鐵黑〇.2 12. 雲母 7,0 13.防腐劑適量 (製造方法） (1) 於100°C下將成分1〜7混合溶解。 (2) 於90C下將成分8~13於（1)中均勻混合。 (3) 利用三輥研磨機對（2)進行處理。 (4)將（3)消泡並於85°C下溶解填充至器皿中後，於4。〇下冷卻，而獲得棒狀遮瑕膏。 (結果）實施例42之棒狀油性固體遮瑕膏為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之棒狀油性固體遮瑕膏。 [實施例43]固體粉末狀粉底 (%) 30.0 (成分） 1.製造實施例1(1.0%)處理滑石 154116.doc -80- 201136613 2·製造實施例1(1.0%)處理雲母 15.0 3·製造實施例1(1.0%)處理雲母氧化欽 15.0 4.製造實施例1(1.0%)處理絹雲母剩餘量 5-製造實施例1(1.0%)氧化鐵黃 2.0 6.製造實施例1(1.0%)鐵丹 0.5 7.製造實施例1(1.0%)氧化鐵黑 0.2 8.合成金雲母 5.0 9.父聯型聚ί夕氧-網狀型聚碎氧嵌段共聚物 1.0 適量 3.0 3.0 3.0 適量 ι〇·防腐劑 11 ·流動石蠟 12. 二曱基聚矽氧烷 13. 2-乙基已酸甘油酯 14. 香料 (製造方法） (1) 利用亨舍爾混合機（三井三池公司製造）K75〇c下將成分 1〜10均勻分散。 (2) 將成分11〜13均勻地混合溶解。 (3) 一面利用亨舍爾混合機攪拌（1)一面添加（2)及14並使其均勻分散。 (4) 利用粉碎機將（3)粉碎。 (5) 將（4)填充至金屬容器中並進行壓縮成型而獲得固體粉末狀粉底。 (結果）實施例43之固體粉末狀粉底為化妝膜之均勻性、化妝持 154116.doc -81 201136613 久效果、柔滑之使用感優異之固體粉末狀粉底。 [實施例44]固體粉末狀眼影 (成分）（％) 1. 製造實施例2(1.0°/。）處理合成金雲母 10.0 2. 製造實施例2(1.0°/。）處理滑石剩餘量 3. 氧化欽被覆雲母 30.0 4. 氮化硼 5.0 5. 聚對苯二甲酸乙二酯-鋁 -環氧積層粉末 5.0 6. 群青 2.0 7. 紅色202號 0.5 8. 聚丙烯酸烷基酯 1.0 9. 防腐劑適量 10·流動石蠟 3.0 11.二甲基聚矽氧烷 5.0 12.2 -乙基已酸甘油酷 3.0 香料適量 (製造方法） (1) 利用亨舍爾混合機（三井三池公司製造）於75°C下將成八 1〜9均勻分散。 (2) 將成分10〜12均勻地混合溶解。 (3) —面利用亨舍爾混合機攪拌（！）_面添加（2)及13並使其均勻分散。 (4) 利用粉碎機將（3)粉碎。 154116.doc • 82· 201136613 (5)將（4)填充於金屬容器中並進行壓縮成型而獲得固體粉末狀眼影。 (結果）實施例44之固體粉末狀眼影為化妝膜之均勻性、化版持久效果、柔滑之使用感優異之固體粉末狀眼影。 [實施例45]固體粉末狀腮紅 (成分） (%) 1.製造實施例3(1.0%)處理雲母 2〇.〇 2.製造實施例3(1.0%)處理滑石剩餘量 3.氧化鈦被覆雲母 10.0 4.群青 0.5 5.紅色226號 0.2 6 ·聚丙烯酸烧基酯 1.0 7.防腐劑適量 8.流動石蠟 2.0 9.一甲基聚石夕氧烧 3.0 10. 2 -乙基已酸甘油西旨 3.0 11·香料適量 (製造方法） (1) 利用亨舍爾混合機（三井三池公司製造）於75°C下將成分 1~7均勻分散》 (2) 將成分8〜1〇加熱至65艺並使其均勻地混合溶解。一面利用亨舍爾混合機攪拌（1)一面添加（2)及11並使其均勻分散。 154116.doc • 83 - 201136613 (4) 利用粉碎機將（3)粉碎。 (5) 將（4)填充至金屬容器中並進行壓縮成型而獲得固體粉末狀胳紅。 (結果）實施例45之固體粉末狀腮紅為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之固體粉末狀腮紅。 [實施例46]粉末狀蜜粉 (成分）（％) 1·製造實施例1(0.5°/。）處理雲母 20.0 2. 製造實施例1(〇.5°/。）處理滑石剩餘量 3. 雲母鈦 10.0 4. 紅色226號 0.5 5. 流動石蠟〇.5 6. 三2-乙基已酸甘油酯 1.0 7·防腐劑適量 8·香料適量 (製造方法） (1)將成分1〜4均勻混合。 (2) —面利用亨舍爾混合機攪拌（1)一面添加成分5〜8並使其均勻混合》 (3) 利用粉碎機將（2)粉碎而獲得蜜粉。 (結果）實施例46之粉末狀蜜粉為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之粉末狀蜜粉。 154116.doc -84 · 201136613 [實施例47] 口紅 (成分）（％) 1. 聚乙烯蠟 10.0 2. 巴西棕櫚蠟 5.0 3. 石纖 2.0 4. 2-乙基已酸鯨蠟酯剩餘量 5. 流動石蠟 10.0 6. 異壬酸異十三烷基酯 10.0 7. 二甲基聚矽氧烷 5.0 8. 紅色202號 0.5 9. 黃色4號 2.0 10. 製造實施例2(2.0%)處理雲母鈦 3.0 11. 製造實施例2(2.0%)處理氧化鈦 0.5 12. 製造實施例2(2.0%)處理氧化鐵黑 0.1 13·α-生育酚 0.5 14.香料適量 (製造方法） (1) 於100°C下將成分1〜7均勻地溶解混合。 (2) 於（1)中添加成分8〜14並使其均勻混合。 (3) 將（2)注入至容器中，使其冷卻而獲得口紅。 (結果）實施例47之口紅為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之口紅。 [實施例48] 0/W型睫毛膏 154116.doc -85- 201136613 (%) 2.0 10.0 1.0 1.5 0.5 5.0 5.0 3.0 剩餘量 10.0 1.5 30.0 (成分） 1. 硬脂酸 2. 黃蜜蠟 3 ·錄纖硬脂醇 4. 單油酸聚氧乙烯去水山梨醇醋(2〇e〇) 5. 倍半油酸去水山梨醇酯 6. 二曱基聚矽氡烷 7. 製造實施例3 (5 ·G%)處理氧化鐵黑 8 ·無水碎酸 9.純化水 10· 1，3-丁二醇 11.三乙醇胺 12 ·丙烯酸烷基酯共聚物乳液（註5) 13. 防腐劑 14. 香料 (註 5)YODOSOL 造）適量適量 32A707(45%固形物成分）（日本NSC公司製 (製造方法） (1) 於80C下將成分1〜3均勻混合。 (2) 利用輥對成分4〜8進行處理。 (3) 於80°C下將成分9〜14均勻混合。 (4) 將（1 )、（2)加以混合後添加（3)並使其乳化。 (5) 將（4)冷卻而獲得0/W型睫毛膏。 (結果） 154116.doc -86- 201136613 實施例48之Ο/W型睫毛膏為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之0/W型睫毛膏。 (%) 10.0 3.0 2.0 2.0 2.0 3.0 5.0 1.0 剩餘量 3.0 5.0 3.0 [實施例49]防水睫毛膏 (成分） 1. 松香酸季戊四醇醋 2. 堪地里拉樹脂 3. 黃蜜蠟 4. 地蠘 5. 棕櫚酸糊精酯 6·三甲基矽烷氧基矽酸酯 7 —曱基二硬脂基錢經蒙脫石 8. 碳酸丙烯脂 9. 輕質流動異構石蠟（註6) 10. 二甲基聚矽氧烷 11 ·製造實施例1(10%)處理氧化鐵黑 12. 二氧化矽 13. 滑石 (註6)IP Solvent 1620(出光興產公司製造） (製造方法） (1) 將成分1〜5加熱至ii〇°c。 (2) 將成分6〜10添加至（1)中並加以混合。 (3) 將成分11〜13添加至（2)中並加以混合。 (4) 利用三輥研磨機對（3)進行處理而獲得防水睫毛膏。 (結果） 154II6.doc •87· 201136613 實施例49之防水睫毛膏為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之防水睫毛膏。 [實施例50]油性眼線液 (成分） (%) 1.地域 11.0 2.聚異丁烯 16.0 3.聚乙烯蠟 8.0 4.輕質流動異構石蠟（註6) 剩餘量 5.二甲基聚矽氧烷 3.0 6.製造實施例2(0.5%)處理氧化鐵黑 15.0 7.製造實施例2(0.5%)處理滑石 5.0 8.防腐劑適量 9.香料適量 (製造方法） (1) 將成分1〜5加熱至i〇〇°c並使其均勻混合。 (2) 將成分6〜9加熱至80°C並使其均勻混合。 (3) 於（1)中添加（2)並使其均勻混合。 (4) 利用輥對（3)進行處理而獲得油性眼線液。 (結果）實施例50之油性眼線液為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之油性眼線液。 [實施例51] W/0型防曬霜 (%) 2.0 5.0 (成分） 1.製造實施例1(5.0%)處理氧化鋅 2·製造實施例ι(5·〇%)處理微粒氧化鈦 154116.doc •88- 201136613 3·二（辛基-癸酸）甘油酯 5.0 4·二曱基聚矽氧烷 3.0 5.掠摘酸辛酉旨 3.0 6.對曱氧基肉桂酸2_乙基己酯 10.0 7·十甲基環五石夕氧烧 10.0 8.曱基聚矽氧烷_鯨蠟基甲基聚矽氧烷 -聚（氧乙烯-氧丙烯）甲基聚矽氧烷共聚物（註7) 1.8 9 · — 2_乙基已酸甘油醋 3.0 10.防腐劑適量 11.氣化鈉 0.3 12.純化水剩餘量 13.二丙二醇 3.0 14.乙醇 3.0 15.香料適量 (註7)ABIL EM-90(EVONIC GOLDSCHMIDT GMBH公司製造) (製造方法） (1) 將成分3、4加熱溶解後’添加成分1、2並利用三報研磨機均勻分散。 (2) 於70°C下使成分5〜10溶解後，於60°C下添加（1)並使其均勻地混合溶解。 (3) 使成分U〜13混合溶解後，於60°C下添加至（2)中並使其乳化。 (4) 將成分14、15添加至（3)中並使其均勻混合而獲广型防曬霜。 I54116.doc • 89- 201136613 (結果）實施例5 1之W/Ο型防曬霜為化妝膜之均勻性、化妝持久效果、柔滑之使用感優異之W/0型防曬霜。 5含有聚矽氧磷酸酯之粉體分散體之製造例 [實施例52〜60及比較例13] 使由上述1之製造實施例1〜4製造之包含聚矽氧磷酸三酯之產物與表5所示之成分一併製備粉體分散體，藉由以下所示之方法進行評價。對比較例亦以相同之方式進行評價。結果示於表5。於以下之實施例中，例如所謂「製造實施例1之產物」意指製造實施例1中獲得之產物（包含聚矽氧磷酸三酯之混合物）。其後之實施例亦同樣。 (利用沈降管之分散性之簡單評價） [表5] 表5 (份)No. Ingredient Example Comparative Example 34 35 36 37 38 39 10 11 12 1 Manufacturing Example 1 (2.0%) treated titanium oxide 10 - 2 Manufacturing Example 2 (2.0%) treated titanium oxide - 10 3 Manufacturing Example 3 ( 2.0%) Treatment of titanium oxide - 10 - - - - - 4 Manufacturing Example 4 (2.0%) treated titanium oxide - - 10 - - - - - 5 Manufacturing Example 1 (0.5%) treated titanium oxide - - - - 10 - - - - 6 Production Example 2 (0.5%) Treatment of Titanium Oxide - - - - - 10 - - - 7 Methylhydrogenpolysiloxane (0.02%) Treated Titanium Oxide (Note 1) - - - - - - 10 - - 8 Methyl argon polyoxyalkylene (2.0%) treated with titanium oxide (Note 1) - - - - - - - 10 - 9 Polyoxyl (2.0%) treated titanium oxide (Note 2) - - - - - - - - 10 10 Iron oxide red 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 11 Yellow iron oxide 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 12 Iron oxide black 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 POP methyl矽烷 POP POP 油矽矽矽 ( ( ( ) ) ) 1 1 1 1 1 1 1 1 1 14 glyceryl diisostearic acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 15 lecithin 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 16 dimethyl Polyoxyalkylene 3 3 3 3 3 3 3 3 3 17 Triethyl 2-ethyl hexanoate 1 1 1 1 1 1 1 1 1 18 Dimethyl distearyl hectorite 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 19 PEG-9 polydimethyl decyloxyethyl dimethyl polyoxy siloxane (Note 4) 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 20 Alcohol 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 21 Cyclopentaoxane 8 8 8 8 8 8 8 8 8 22 Diethylhexanoic acid neopentyl glycol ester 10 10 10 10 10 10 10 10 10 23 23 PEG-9 polydimethyl decyloxyethyl dimethyl Polyoxyalkylene (Note 4) 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 24 Alcohol 7 7 7 7 7 7 7 7 7 25 Preservatives Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 26 Gasification nano 0.3 0.3 0.3 0.3 0.3 0.3 03 0.3 0.3 27 Purified water Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Residual amount Residual amount 28 Proper amount of appropriate amount of appropriate amount of flavor Appropriate amount Appropriate amount Appropriate amount Appropriate amount Evaluation item and judgment result Uniformity of cosmetic film ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ Make-up effect ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ Smooth Sense ◎ ◎ ◎ 〇 ◎ ◎ X Δ Δ (Note 1) 99P treatment (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) SA treatment CR-50 (manufactured by Sanhao Chemical Co., Ltd.) (Note 3) KF-6〇26 (Shin-Etsu (manufactured by Chemical Industry Co., Ltd.) (Note 4) KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.) -75- 154116.doc 201136613 (Manufacturing method) (1) The components 1 to 17 are treated by a roller. (2) Processing with the comparative components 18 to 21. (3) The (1), (2) and the components 22, 23 are uniformly mixed by a disperser (Dlsper). (4) Add ingredients 24 to 28 slowly in (3) and emulsify them. (5) Defoaming (4) and filling it into a container to obtain a w/〇 type foundation. (Evaluation) For the hair/〇 type foundations of Examples 34 to 39 and Comparative Examples 10 to 12, 20 people in the cosmetics evaluation expert group evaluated the "uniformity of the makeup film", the makeup lasting effect, and the "smoothness" according to the following evaluation criteria. Each item is evaluated in seven stages, and the average score of the entire group is used and judged based on the following criteria. [Evaluation criteria] (Evaluation results): (Score) Very good. 6 points Good: 5 points slightly good: 4 points Normal: 3 points Slightly bad: 2 points Bad: 1 point Very bad: 0 points [Criteria for judgment] (Score The average score): (judge) 5·0 or more: ◎ very good 154116.doc -76* 201136613 3.5 or more ~ not up to 5 〇 1.5 or more ~ not up to 3 $ not up to 1.5 (result) 〇 good △ bad χ very bad The W/0 type foundations of Examples 34 to 39 were a W/0 type foundation having a uniformity of a cosmetic film, a makeup lasting effect, and a smooth feeling of use. The W/〇 type foundation of Comparative Example 10 is less in the treatment of the uniformity of the cosmetic film, the makeup lasting effect, and the smoothness of the use of the ruthenium-based hydrogen polyoxyalkylene in the titanium oxide. In the comparative example in which the amount of treatment in titanium is large, the uniformity of the cosmetic film, the long-lasting effect of the makeup, and the feeling of being smooth are inferior. Further, the W/0 type foundation of Comparative Example 12 was also inferior in the uniformity of the cosmetic film, the makeup lasting effect, and the smooth feeling of use. [Example 40] 0/W type liquid foundation (ingredient) 1. Monooleic acid polyoxyethylene sorbitan ester (2〇E〇) 2· sesquioleic acid sorbitan ester 3. 1,3- Butylene Glycol 4 Production Example 4 (3.0%) Treatment of Titanium Oxide 5. Production Example 4 (3·0%) Treatment of Iron Dan 6 Manufacturing Example 4 (3.0%) Treatment of Iron Oxide Yellow 7 Example 4 (3.0%) Treatment of Iron Oxide Black 8. Production Example 4 (3. %) Treatment of Talc (%) 0.5 0.510.01 0.0 0.42.00.1 5.0 9. Carboxyvinyl Polymer 0.3 10. Triethanolamine 154116. Doc -77· 201136613 Remaining amount 2.0 1.0 0.5 2.0 2.0 2.0 0.5 Appropriate amount 11. Purified water 12. Ethanol 13. Stearic acid 14. Hawthorn 15. Flowing paraffin 16. Tri-2-ethylhexanoic acid vinegar 17. P-methoxy cinnamic acid 2 - ethyl hexanoic acid 18. Vaseline 19. Preservative 20. Perfume (manufacturing method) (1) The components 1 to 8 are uniformly dispersed by a stick (2) The components 9 to 12 are uniformly mixed. (3) Add (1) to (2) and mix them evenly. (4) The components 13 to 19 were mixed and dissolved at 80 °C. (5) (4) was added to (3) at 80 ° C and emulsified. (6) Cool (5) and add 2 parts to obtain a 〇/trade type foundation. (Result) The 0/W type foundation of Example 40 was a 0/W type foundation which was excellent in uniformity of a makeup film, a makeup lasting effect, and a smooth feeling of use. [Example 41] Oily solid foundation (ingredient) (%) 1. Talc 15.0 2. Mica 10.0 154116.doc _0 201136613 3. Production Example 2 (5.0%) treated titanium oxide 15.0 4. Manufacturing Example 2 (5.0%) Treatment of iron oxide 1.0 5. Manufacturing Example 2 (5 _0%) treatment of iron oxide yellow 3.0 6. Production Example 2 (5.0. / 〇) treatment of iron oxide 0.2 7. Polyethylene wax 7.0 8. Microcrystalline wax 6.0 9. Residual amount of tri-ethyl hexanoic acid glycerol 10. Dimethyl polyoxy siloxane 10.0 11. Flowing paraffin 20.0 12. Polyoxyethylene methyl oxalate-polyoxypropylene oleyl alcohol Base Stone Oxygen Burning-Dimethyl Onsonic Copolymer (Note 3) 2.0 13. Preservatives Appropriate amount 14 · Proper amount of flavor (manufacturing method) (1) The components 7 to 13 are heated and dissolved at 90 °C. (2) Components 1 to 6 were added to (1) and uniformly dispersed by a roll. (3) After adding component 14 to (2) and dissolving at 80 ° C, it was filled in a metal container to obtain an oily solid foundation. (Result) The oily solid foundation of Example 41 was an oily solid foundation which was excellent in makeup, 〈匀, makeup lasting effect, and smooth feeling of use. (%) 5.0 [Example 42] Rod-like oily solid concealer (ingredient) 1. Paraffin 154116.doc • 79- 201136613 5.0 2.0 15.0 25.0 10.0 2. Polyethylene wax 3. Candida wax 4. Tri-2- Ethyl glycerol vinegar 5. Nonyl phenyl polyoxy siloxane 6. Acetic acid liquid lanolin 7. P-methoxy cinnamic acid 2-ethyl hexose 5.0 8. Manufacturing Example 3 (7. 〇%) Treatment of titanium oxide 20.0 9. Production Example 3 (7.0%) treatment of iron oxide yellow 2 〇10. Production Example 3 (7.0%) treatment of iron oxide 〇5 11. Production Example 3 (7.0%) treatment of iron oxide Black cockroach. 2 12. Mica 7,0 13. Preservative amount (manufacturing method) (1) The components 1 to 7 are mixed and dissolved at 100 °C. (2) The components 8 to 13 were uniformly mixed in (1) at 90C. (3) The (2) is processed by a three-roll mill. (4) After defoaming (3) and dissolving and filling into a vessel at 85 ° C, at 4. Get cold and get a stick concealer. (Result) The rod-like oily solid concealer of Example 42 was a stick-like oily solid concealer which was excellent in the uniformity of the cosmetic film, the long-lasting effect of the makeup, and the smooth feeling of use. [Example 43] Solid powdery foundation (%) 30.0 (Component) 1. Production Example 1 (1.0%) Treatment of talc 154116.doc -80-201136613 2 Manufacturing Example 1 (1.0%) Treatment Mica 15.0 3· Production Example 1 (1.0%) Treatment of Mica Oxide 15.0 4. Production Example 1 (1.0%) Treatment of Sericite Remaining Amount 5 - Manufacturing Example 1 (1.0%) Iron Oxide Yellow 2.0 6. Manufacturing Example 1 (1.0) %) 铁丹0.5 7. Manufacturing Example 1 (1.0%) Iron Oxide Black 0.2 8. Synthesis of Phlogopite 5.0 9. Parent-linked Poly-Oxygen-Mesh Polyoxygen Block Copolymer 1.0 Appropriate 3.0 3.0 3.0 〇〇防防防防流动流动流动 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 2- 2- 2- 2- 2- 2- 2- 2- 2- The components 1 to 10 are uniformly dispersed under K75〇c. (2) The components 11 to 13 are uniformly mixed and dissolved. (3) Add (2) and 14 while stirring with a Henschel mixer (1) and spread them evenly. (4) Crush the (3) with a pulverizer. (5) The (4) was filled in a metal container and compression-molded to obtain a solid powdery foundation. (Result) The solid powdery foundation of Example 43 was a uniform powder of a cosmetic film and a cosmetic powder 154116.doc -81 201136613 A solid powdery foundation excellent in long-lasting effect and smooth feeling of use. [Example 44] Solid powdery eye shadow (ingredient) (%) 1. Production Example 2 (1.0 ° /.) treatment of synthetic phlogopite 10.0 2. Production Example 2 (1.0 ° /.) Treatment of talc remaining amount 3. Oxide coated mica 30.0 4. Boron nitride 5.0 5. Polyethylene terephthalate-aluminum-epoxy laminated powder 5.0 6. Ultramarine 2.0 7. Red 202 0.5 8. Polyalkyl acrylate 1.0 9. Antiseptic Appropriate amount 10 · Flowing paraffin 3.0 11. Dimethyl polyoxane 5.0 12.2 - Ethyl hexanoic acid glycerin 3.0 Flavor amount (manufacturing method) (1) Using Henschel mixer (manufactured by Mitsui Sanike Co., Ltd.) at 75° Under C, it will be evenly dispersed in eight to nine. (2) The components 10 to 12 are uniformly mixed and dissolved. (3) The surface was stirred (!) with a Henschel mixer (2) and 13 and uniformly dispersed. (4) Crush the (3) with a pulverizer. 154116.doc • 82· 201136613 (5) Fill (4) in a metal container and perform compression molding to obtain a solid powdery eye shadow. (Result) The solid powdery eye shadow of Example 44 was a solid powdery eye shadow which was excellent in uniformity of a cosmetic film, a sustained-release effect, and a smooth feeling of use. [Example 45] Solid powdery eosin (ingredient) (%) 1. Production Example 3 (1.0%) treated mica 2〇.〇2. Production Example 3 (1.0%) treated talc remaining amount 3. Titanium oxide Covered mica 10.0 4. Ultramarine 0.5 5. Red 226 0.2 6 · Polyacrylic acid alkyl ester 1.0 7. Preservative amount 8. Flowing paraffin 2.0 9. Monomethyl polyoxylate 3.0 10. 2 -ethylhexanoic acid Glycerin oxime 3.0 11·Flavoury amount (manufacturing method) (1) The components 1 to 7 are uniformly dispersed at 75 ° C using a Henschel mixer (manufactured by Mitsui Sanike Co., Ltd.) (2) The components 8 to 1 are heated. To 65 art and make it evenly mixed and dissolved. While stirring (1) with a Henschel mixer, add (2) and 11 and uniformly disperse them. 154116.doc • 83 - 201136613 (4) Crush the (3) with a shredder. (5) (4) was filled in a metal container and compression-molded to obtain a solid powdery red. (Result) The solid powdery blush of Example 45 was a solid powdery blush which was excellent in the uniformity of the cosmetic film, the cosmetic-lasting effect, and the smooth feeling of use. [Example 46] Powdered honey powder (ingredient) (%) 1. Manufacturing Example 1 (0.5 ° /.) treatment mica 20.0 2. Production Example 1 (〇. 5 ° /.) Treatment of talc remaining amount 3. Mica Titanium 10.0 4. Red 226 No. 0.5 5. Flowing paraffin 〇.5 6. Tri-ethylhexanoic acid glyceride 1.0 7·Preservative amount 8·Flavor amount (manufacturing method) (1) Uniform ingredients 1 to 4 mixing. (2) The surface is stirred by a Henschel mixer (1) and the components 5 to 8 are added and uniformly mixed. (3) The powder is obtained by pulverizing (2) with a pulverizer. (Result) The powdered powder of Example 46 was a powdery powder having excellent uniformity of the cosmetic film, a long-lasting effect of makeup, and a smooth feeling of use. 154116.doc -84 · 201136613 [Example 47] Lipstick (ingredient) (%) 1. Polyethylene wax 10.0 2. Carnauba wax 5.0 3. Stone fiber 2.0 4. 2-ethylhexanoic acid cetyl ester residual amount 5 Mobile Paraffin 10.0 6. Isotridecyl isononanoate 10.0 7. Dimethylpolyoxane 5.0 8. Red 202 No. 0.5 9. Yellow No. 4 2.0 10. Manufacturing Example 2 (2.0%) treated mica Titanium 3.0 11. Manufacturing Example 2 (2.0%) Treated Titanium Oxide 0.5 12. Production Example 2 (2.0%) Treatment of Iron Oxide Black 0.1 13·α-Tocopherol 0.5 14. Proper Flavor (Manufacturing Method) (1) The components 1 to 7 were uniformly dissolved and mixed at 100 °C. (2) Add ingredients 8 to 14 in (1) and mix them evenly. (3) Inject (2) into the container and let it cool to obtain a lipstick. (Result) The lipstick of Example 47 was a lipstick which was excellent in uniformity of a makeup film, a makeup lasting effect, and a smooth feeling of use. [Example 48] 0/W type mascara 154116.doc -85- 201136613 (%) 2.0 10.0 1.0 1.5 0.5 5.0 5.0 3.0 Remaining amount 10.0 1.5 30.0 (ingredient) 1. Stearic acid 2. Yellow beeswax 3 · Record Fibrinol 4. Monooleic acid polyoxyethylene sorbitan vinegar (2〇e〇) 5. Sesame oleic acid sorbitan ester 6. Dimercapto polydecane 7. Manufacturing Example 3 ( 5 · G%) treatment of iron oxide black 8 · anhydrous acid 9. Purified water 10 · 1,3-butanediol 11. Triethanolamine 12 · alkyl acrylate copolymer emulsion (Note 5) 13. Preservatives 14. Perfume (Note 5) made by YODOSOL) Appropriate amount of 32A707 (45% solid content) (manufactured by NSC Japan (manufacturing method) (1) The components 1 to 3 are uniformly mixed at 80 C. (2) Using the roller pair component 4~ (8) The components 9 to 14 are uniformly mixed at 80 ° C. (4) (1) and (2) are mixed, and (3) is added and emulsified. (5) (4) Cooling to obtain 0/W type mascara. (Result) 154116.doc -86- 201136613 The Ο/W type mascara of Example 48 is excellent in uniformity of makeup film, long-lasting effect of makeup, and smooth use. 0/W Type mascara. (%) 10.0 3.0 2.0 2.0 2.0 3.0 5.0 1.0 Remaining amount 3.0 5.0 3.0 [Example 49] Waterproof mascara (ingredient) 1. Rosin acid pentaerythritol vinegar 2. Candidella resin 3. Yellow beeswax 4. Cellar 5. Palmitic acid dextrin 6. Trimethyl decyloxy phthalate 7 - fluorenyl distearyl montmorillonite 8. propylene carbonate 9. Light flow isomerized paraffin (Note 6) 10. Dimethyl polyoxyl 11 Production Example 1 (10%) Treatment of Iron Oxide Black 12. Cerium Oxide 13. Talc (Note 6) IP Solvent 1620 (manufactured by Idemitsu Kosan Co., Ltd.) (Manufacturing Method) (1) Heating ingredients 1 to 5 to ii °c. (2) Adding components 6 to 10 to (1) and mixing them. (3) Adding components 11 to 13 to (2) and mixing them. (4) Using a three-roll mill pair (3) (Review) 154II6.doc •87· 201136613 The waterproof mascara of Example 49 is a waterproof mascara which is excellent in uniformity of a makeup film, a makeup lasting effect, and a smooth feeling of use. 50] oily eyeliner (ingredient) (%) 1. Area 11.0 2. Polyisobutylene 16.0 3. Polyethylene wax 8.0 4. Light flow isomerized paraffin (Note 6) Remaining 5. Dimethyl polyoxane 3.0 6. Production Example 2 (0.5%) Treatment of iron oxide black 15.0 7. Production Example 2 (0.5%) Treatment of talc 5.0 8. Preservative amount 9. Flavor amount (manufacturing method) (1) Heat the ingredients 1 to 5 to i〇〇°c and mix them evenly. (2) The components 6 to 9 were heated to 80 ° C and uniformly mixed. (3) Add (2) to (1) and mix them evenly. (4) The oily eyeliner is obtained by treating the roller pair (3). (Result) The oily eyeliner of Example 50 is an oily eyeliner excellent in uniformity of a cosmetic film, a long-lasting effect, and a smooth feeling of use. [Example 51] W/0 type sunscreen (%) 2.0 5.0 (ingredient) 1. Production Example 1 (5.0%) treatment of zinc oxide 2. Manufacturing Example ι (5·〇%) treatment of particulate titanium oxide 154116. Doc •88- 201136613 3·Di(octyl-decanoic acid) glyceride 5.0 4· Dimercaptopolyoxyalkylene 3.0 5. Grab acid extract 3.0 6. Pair of methoxy cinnamic acid 2-ethylhexyl ester 10.0 7·Decamethylcyclopentadioxime 10.0 8. Mercapto polyoxyalkylene _ cetyl methyl polyoxyl-poly(oxyethylene-oxypropylene) methyl polyoxyalkylene copolymer (Note 7) 1.8 9 · 2_ethyl glycerol vinegar 3.0 10. Preservative amount 11. Sodium gasification 0.3 12. Purified water remaining 13. Dipropylene glycol 3.0 14. Ethanol 3.0 15. Proper amount (Note 7) ABIL EM-90 (manufactured by EVONIC GOLDSCHMIDT GMBH) (Manufacturing method) (1) After the components 3 and 4 were heated and dissolved, the components 1 and 2 were added and uniformly dispersed by a three-stage mill. (2) After dissolving the components 5 to 10 at 70 ° C, (1) was added at 60 ° C and uniformly mixed and dissolved. (3) After the components U to 13 were mixed and dissolved, they were added to (2) at 60 ° C and emulsified. (4) Add the ingredients 14, 15 to (3) and mix them evenly to obtain a wide-area sunscreen. I54116.doc • 89-201136613 (Results) Example 5 W/Ο type sunscreen is a W/0 type sunscreen which is excellent in uniformity of makeup film, long-lasting effect, and smooth feeling. 5 Production Example of Powder Dispersion Containing Polyphosphonium Phosphate [Examples 52 to 60 and Comparative Example 13] Products and Tables Containing Polyphosphoric Acid Triesters Produced by Production Examples 1 to 4 of the above 1 The powder dispersion was prepared together with the components shown in 5, and evaluated by the method shown below. The comparative examples were also evaluated in the same manner. The results are shown in Table 5. In the following examples, for example, "the product of Production Example 1" means the product obtained in the production of Example 1 (containing a mixture of polyphosphoric acid triester). The same applies to the subsequent embodiments. (Simple evaluation of the dispersion of the settlement tube) [Table 5] Table 5 (parts)

No. 成为實施例比較例 52 53 54 55 56 57 58 59 60 13 1 氧化欽 1 1 1 1 - 1 1 1 _ 1 2 氧化鈦微粒 - - - 1 - - 1 - 3 製造實施例1之產物 0.2 0.2 0.2 0.1 0.2 4 製造實施例2之產物 0? 5 製造實施例3之產物 0? 6 製造實施例4之產物 0.9 0.9 - 7 PEG-9聚二甲基矽烷氧基乙基二曱基聚矽氧烷(註1) 一 0.2 8 十曱基環五矽氧烷 20 - 20 20 20 20 20 20 20 20 9 二曱基聚矽氧烷 - 20 評價項目與評價結果分散性 ◎ ◎ ◎ 〇 ◎ ◎ ◎ 〇〇 X (註1 )KF-6028(信越化學工業公司製造) 154116.doc -90· 201136613 (評價方法）利用超音波機（BRANSONIC 1510J-DTH 42 kHz)將混合 .有成分1〜9之分散物分散1小時後，添加至底面積i cm2、高度30 cm之沈降管中，以目視評價3天後之沈降體積。稃者，所謂沈降體積係指分散層與沈降層之體積之和，根據沈降管之刻度之讀取值進行判定。判定基準如下所述。 ◎:(沈降體積為）20 cm以上。〇 :(沈降體積為）15 cm以上未達20 cm。 △:(沈降體積為）5 cm以上未達15 cm。 X :(沈降體積為）未達5 cm。 [實施例61〜6610〜15及比較例14、15] 使由上述製造實施例1〜4製造之包含聚矽氧磷酸三酯之產物與表6所示之成分一併製備粉體分散體，藉由以下所示之方法進行評價。對比較例亦以相同之方式進行評價。結果不於表6。 (塗佈膜評價） [表6] 154116.doc -91- 201136613 表 6 (%) No. 成分實施例比較例 61 62 63 64 65 66 14 15 1 氧化鈦 65 65 65 65 - - 65 2 氧化鈦微粒 - - - - 45 45 - 45 3 卵磷脂 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 4 二異硬脂酸甘油酯 5 5 5 5 5 5 5 5 5 製造實施例1之產物 6.5 - - - 6.5 - - - 6 製造實施例2之產物 - 6.5 7 製造實施例3之產物 - - 6.5 - - - - - 8 製造實施例4之產物 - - - 20 - 20 - - 9 POE曱基矽氧烷-POP油基曱基矽氧烷-二曱基矽氧烷共聚物(註2) 6.5 6.5 10 二曱基聚矽氧烷 16 16 16 5.2 22 14.6 16 22 11 三2-乙基已酸甘油酯 4 4 4 1.3 18 11.9 4 18 評價項目與判定結果塗佈膜之均勻性 ◎ ◎ ◎ 〇 ◎ 〇 X X (註2)KF-6026(信越化學工業公司製造) (評價方法）將成分1〜11混合並利用1HP之三輥研磨機處理3次。利用塗膠刀（6 μιη)將所得之分散體塗佈於玻璃板上，藉由目視觀察評價均勻性。判定基準如下所述。 ◎:塗佈膜無不均，白度較高。〇 :塗佈膜無不均，但白度稍低。 Α :塗佈膜有不均，白度稍低。 x :塗佈膜有不均，白度較低。 6包含含有聚矽氧磷酸酯之粉體分散體的化妝料之配方例 154116.doc •92· 201136613 [實施例67〜70及比較例16、17]W/Ο型粉底製備表7所示之組成之W/0型粉底，對化妝膜之均勻性與化妝持久效果進行評價。 [表7] 表 7 (%)No. Example Comparative Example 52 53 54 55 56 57 58 59 60 13 1 Oxide 1 1 1 1 - 1 1 1 _ 1 2 Titanium oxide particles - - 1 - - 1 - 3 The product of Example 1 was produced 0.2 0.2 0.2 0.1 0.2 4 Production of the product of Example 2 0? 5 Production of the product of Example 3 0? 6 Preparation of the product of Example 4 0.9 0.9 - 7 PEG-9 polydimethyl decyloxyethyl decyl fluorene Oxyalkane (Note 1) - 0.28 Decylcyclopentaoxane 20 - 20 20 20 20 20 20 20 20 9 Dimercaptopolyoxyalkylene - 20 Evaluation Items and Evaluation Results Dispersibility ◎ ◎ ◎ 〇 ◎ ◎ ◎ 〇〇X (Note 1) KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.) 154116.doc -90· 201136613 (Evaluation method) Mixing with ultrasonic machine (BRANSONIC 1510J-DTH 42 kHz). There are components 1 to 9 After dispersing the dispersion for 1 hour, it was added to a settling tube having a bottom area of i cm 2 and a height of 30 cm, and the sedimentation volume after 3 days was visually evaluated. The so-called sedimentation volume refers to the sum of the volume of the dispersion layer and the sedimentation layer, and is determined based on the read value of the scale of the settling tube. The judgment criteria are as follows. ◎: (settling volume is) 20 cm or more. 〇 : (Settling volume is) 15 cm or more and less than 20 cm. △: (settling volume is) 5 cm or more and less than 15 cm. X : (settling volume) is less than 5 cm. [Examples 61 to 6610 to 15 and Comparative Examples 14 and 15] The powdery dispersion containing the polyphosphonium phosphate triester produced in the above Production Examples 1 to 4 was prepared together with the components shown in Table 6 to prepare a powder dispersion. The evaluation was carried out by the method shown below. The comparative examples were also evaluated in the same manner. The results are not shown in Table 6. (Coating film evaluation) [Table 6] 154116.doc -91- 201136613 Table 6 (%) No. Ingredient Example Comparative Example 61 62 63 64 65 66 14 15 1 Titanium oxide 65 65 65 65 - - 65 2 Titanium oxide Microparticles - - - - 45 45 - 45 3 Lecithin 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 4 Diisostearic acid glyceride 5 5 5 5 5 5 5 5 5 The product of the manufacture example 1 6.5 - - - 6.5 - - - 6 Product of Production Example 2 - 6.5 7 Product of Production Example 3 - - 6.5 - - - - - 8 The product of Example 4 was produced - - - 20 - 20 - - 9 POE decyl decyl oxane - POP oil Rhodium-based oxo-dioxanoxane copolymer (Note 2) 6.5 6.5 10 Dimercaptopolyoxyl 16 16 16 5.2 22 14.6 16 22 11 Tri-ethyl glyceride 4 4 4 1.3 18 11.9 4 18 Evaluation item and judgment result Uniformity of coating film ◎ ◎ ◎ 〇〇〇 XX (Note 2) KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Evaluation method) Mixing components 1 to 11 and using 1HP The three-roll mill was processed three times. The resulting dispersion was applied to a glass plate by a rubber knife (6 μm), and the uniformity was evaluated by visual observation. The judgment criteria are as follows. ◎: There was no unevenness in the coating film, and the whiteness was high. 〇 : There is no unevenness in the coating film, but the whiteness is slightly lower. Α : The coating film is uneven and the whiteness is slightly lower. x : The coating film is uneven and the whiteness is low. 6 Formulation Example of Cosmetic Containing Powder Dispersion of Polyphosphonium Phosphate 154116.doc • 92·201136613 [Examples 67 to 70 and Comparative Examples 16, 17] W/Ο type foundation preparation Table 7 The W/0 type foundation is composed to evaluate the uniformity of the makeup film and the long-lasting effect of the makeup. [Table 7] Table 7 (%)

No. 成分實施例比較例 67 68 69 70 16 17 1 製造例1之產物 1.5 - - - - 2 製造例2之產物 - 1.5 - - - - 3 製造例3之產物修 - 1.5 - - - 4 製造例4之產物 - _ 4.5 - 5 POE甲基矽氧烷·ΡΟΡ油基曱基矽氧烷-二甲基矽氧烷共聚物(註2) - - - 1.5 - 6 PEG-9聚二甲基矽烷氧基乙基二甲基聚矽氧烷(註1) - - - - - 1.5 7 卵磷脂 0.3 0.3 0.3 0.3 0.3 0.3 8 二甲基聚矽氧烷 3 3 3 3 3 3 9 三2-乙基已酸甘油酯 1 1 1 1 1 1 10 氧化欽 10 10 10 10 10 10 11 氧化鈦微粒 2 2 2 2 2 2 12 氧化鐵紅 0.5 0.5 0.5 0.5 0.5 0.5 13 黃色氧化鐵 2.3 2.3 2.3 2.3 2.3 2.3 14 氧化鐵黑 0.2 0.2 0.2 0.2 0.2 0.2 15 二甲基二硬脂基鋰蒙脫石 0.3 0.3 0.3 0.3 0.3 0.3 16 PEG-9聚二曱基矽烷氧基乙基二甲基聚矽氧院(註1) 0.3 0.3 0.3 0.3 0.3 0.3 17 醇 0.3 0.3 0.3 0.3 0.3 0.3 18 十甲基環五矽氧烷 S 8 8 8 8 8 19 二乙基已酸新戊二醇酯 10 10 10 10 10 10 20 PEG-9聚二曱基矽烷氧基乙基二甲基聚矽氧烷(註1) 1.5 1.5 1.5 1.5 1.5 1.5 21 香料適量適量適量適量適量適量 22 醇 7 7 7 7 7 7 23 防腐劑適量適量適量適量適量適量 24 氯化納 0.3 0.3 0.3 0.3 0.3 0.3 25 純化水剩餘量剩餘量剩餘量剩餘量剩餘量剩餘量評價項目與判定結果化妝膜之均勻性 ◎ ◎ ◎ 〇 Δ Δ 化妝持久效果 ◎ ◎ ◎ 〇 Δ Δ (註1 )KF-6028(信越化學工業公司製造) (註2)KF-6026(信越化學工業公司製造) -93- 154116.doc 201136613 (製造方法）利用輕對成分1〜14進行處理。 (2) 利用觀對成分15〜17進行處理。 (3) 利用分散機將（1)、（2)及成分18〜20均勻混合。 (4) 於（3)中緩緩添加成分21〜25並使其乳化。 (5) 將（4)消泡並填充至容器中。 (評價）對實施例67〜70、及比較例I1 2、I7之W/O型粉底，化妝品評價專家小組20人分別依據以下之評價基準對「化妝膜之均勻性」、「化妝持久效果」各項目進行7個階段之評價，進而利用整個小組之評分之平均分’依據以下之判定基準進行判定。 [評價基準] (評價結果） :(評分）非常良好 :6分良好 :5分稍良好 :4分普通 :3分稍不良 :2分不良 :1分非常不良 :〇分 [判定基準] (評分之平均分） :(判定） • 94- 1 .〇以上：◎非常良好 2 154116.doc 201136613 3·5以上〜未達5.0 1.5以上〜未達3.5 未達1.5 .〇良好 :△不良 :χ非常不良貫把例67〜70之W/〇型粉底為粉體分散性優異，化妝旗之均勻性、化妝持久效果良好之聊型粉底。比較例Μ、之W/0里叔底中先前之聚石夕氧分散劑厂粉體之比率較高為〇.1但&體分散性較差，故而並非化妝膜之均勻性、化妝持久效果優異者。 [實施例71]W/〇型粉底 (%) 3.0 0.5 0.5 10.0 10.0 0.4 2.0 0.1 5.0 0.3 1.0 剩餘量 2.0 (成分） 1. 製造實施例2之產物 2. 單油酸聚氧乙烯酯（2〇莫耳）去水山梨醇 3. 倍半油酸去水山梨醇醋 4. 1，3-丁二醇 5. 聚矽氧處理氧化鈦 6. 聚矽氧處理鐵丹 7. 聚矽氧處理氧化鐵黃 8. 聚矽氧處理氧化鐵黑 9. 聚矽氧處理滑石 10. 羧乙烯聚合物 11. 三乙醇胺 12. 純化水 13. 乙醇 154116.doc -95- 201136613 14. 硬脂酸 1.0 0.5 3.0 2.0 2.0 0.5 適量適量 15. 山窬醇 16. 流動石蠟 1 7.三2 -乙基已酸甘油酉旨 18. 對甲氧基肉桂酸2-乙基己商旨 19. 凡士林 20. 防腐劑 21. 香料 (製造方法）包含聚>5夕氧 (1)利用三輥研磨機將成分卜9均勻混合製備改質磷酸三酯之分散體。 (2) 將成分1 0〜13均勻混合。 (3) 於（2)中添加（1)並使其均勻混合。 (4) 於80°C下將成分14〜20混合溶解。 (5) 於80t下，於（3)中添加（4)並使其乳化。、「化妝持 (6) 將（5)冷卻並添加成分21而獲得〇/w型粉底。實施例71之Ο/W型粉底為「化妝膜之均勻性久效果」優異之o/w型粉底。 [實施例72]油性固體粉底 (成分） (%) 1.滑石 15.0 2.雲母 10.0 3.聚矽氧處理氧化鈦 15.0 4.聚矽氧處理鐵丹 1.0 154116.doc •96- 201136613 5.聚矽氧處理氧化鐵黃 3.0 6.聚矽氧處理氧化鐵黑 0.2 7.聚乙烯蠟 7.0 8.微晶蝶 6.0 9.三2-乙基已酸甘油酯剩餘量 1〇·製造實施例3之產物 5.0 11.二甲基聚矽氧烷 5.0 12.流動石蠟 20.0 13.聚氧乙稀甲基碎氧院. •聚氧丙烯油醇酉旨甲基石夕氧撰；-二甲基石夕氧烧共聚物（註2) 2.0 14.防腐劑適量 15.香料適量 (製造方法） (1) 於90°C下將成分7〜14加熱溶解。 (2) 於（1)中添加成分1〜6並利用三輥研磨機均勻混合而製備包含聚矽氧改質磷酸三酯之分散體。 (3) 於（2)中添加成分15並於80°C下溶解後，土吉士真充至金屬容器中，而獲得油性固體粉底。實施例72之油性固體粉底為「化妝膜之玲6 J习性、「持久效果」優異之油性固體粉底。」' 化妝 [實施例73]棒狀油性固體遮瑕膏 (成分） (%) 1·石蠟 5〇 2.聚乙烯蠟 ς Λ I54116.doc •97- 201136613 3. 堪地里拉蠟 2.0 4. 製造實施例4之產物 15 0 5 ·三-2-乙基已酸甘油醋 15.0 6. 甲基苯基聚矽氧烷 5.〇 7. 乙酸液狀羊毛脂 1().0 8. 對甲氧基肉桂酸2-乙基己酯 5·〇 9. 氧化鈦 20.0 10. 氧化鐵黃 2.0 11. 鐵丹 0.5 12. 氧化鐵黑〇.2 13. 雲母 7.0 14. 防腐劑適量 1 5.香料適量 (製造方法） (1) 於100°C下將成分1〜8混合溶解。 (2) 於90°C下，於（1)中添加成分9〜丨5並使其均勻混合。 (3) 利用三輥研磨機對（2)進行處理而製備包含聚矽氧改質磷酸三酯之分散體。 (4) 將（3)消泡並於85。(：下溶解填充至器皿中後，於4t下冷卻而獲得棒狀遮瑕膏。實施例73之棒狀油性固體遮暇膏為「化妝膜之均勾性」、「化妝持久效果」優異之棒狀油性固體遮瑕膏。 [實施例74]W/0型防曬霜 (%) (成分） 154116.doc •98· 201136613 1.氧化鋅 2.0 2.聚矽氧被覆微粒氧化鈦 5.0 3.三（辛基-癸酸）甘油酯 5.0 4.製造實施例3之產物 3.0 5.棕櫚酸辛酯 3.0 6.對曱氧基肉桂酸2-乙基己酉旨 10.0 7·十甲基環五矽氧烷 10.0 8.甲基聚矽氧烷-鯨蠟基甲基聚矽氧烷 -聚（氧乙烯-氧丙烯）曱基聚矽氧烷共聚物（註3) 1.8 9.三2 -乙基已酸甘油酯 3.0 10.防腐劑適量 11.氯化納 0.3 12.純化水剩餘量 13.二丙二醇 5.0 14.乙醇 5.0 15.香料適量 (註3)ABIL EM-90(EVONIC GOLDSCHMIDT GMBH公司製造） (製造方法） (1) 將成分3、4加熱溶解後，添加成分1、2並利用较均勻混合，而製備包含聚矽氧改質磷酸三酯之分散體。 (2) 於70°C下使成分5〜10溶解後，於6〇°C下添加（1)並使其均勻地混合溶解。 154116.doc •99- 201136613 (3)使成分11〜13混合溶解後’於60°C下添加至（2)中並使其乳化。 (4)於（3)中添加成分14、1 5並使其均勻混合而獲得w/〇型防曬霜。實施例74之W/O型防曬霜為「化妝膜之均句性」、「化妝持久效果」優異之W/O型防曬霜。 [實施例75] W/0型粉底 (%) (成分） 1.聚氧乙烯甲基矽氧烷·聚氧丙烯油醇酯甲基矽氧烷-二曱基矽氧烷共聚物（註2) 2 〇 2· PEG-3二甲基聚矽氧烷（註4) ι 3·二曱基聚矽氧烷 4. 聚矽氧處理氧化鐵红 5. 聚矽氧處理氧化鐵黃 6. 聚<6夕氧處理氧化鐵黑 7. 聚矽氧處理滑石 8. 二2-乙基已酸甘油酯 9·倍半油酸去水山梨醇酯 1 〇.純化水 U.丨，3-丁二醇 12·防腐劑 13.香料 2〇.〇 0.5 5.0 5.0 0.5 剩餘量 15.0 適量適量 15.0 14.實施例1之粉體分散體 )KF-6015(信越化學卫業公司製造) 154116.doc •100- 201136613 (製法） (1) 將成分1〜3均勻混合。 (2) 利用輥將成分4〜10均勻分散。 (3) 於（l)t添加（2)並使其均勻混合。 (4) 於（3)中添加成分ιι〜14並使其乳化後，添加成分15而獲得W/0型粉底》實施例75之W/0型粉底為「化妝膜之均勻性」、「化妝持久效果」優異之W/0型粉底。 [產業上之可利用性] 本發明之聚矽氧磷酸三酯由於聚矽氧鏈較多，因此以少置之處理量亦表現出斥水性、分散性，由於具有磷酸基，尤其由於金屬氧化物與粉體表面牢固結合，故而附著性優異。因此，調配有本發明之聚矽氧磷酸三酯之化妝料尤其修復效果、柔滑之使用感、化妝持久效果優異。進而，調配有經本發明之聚矽氧磷酸三酯被覆處理之粉體的化妝料之化妝膜之均勻性、化妝持久效果優異。又，本發明之聚矽氧磷酸三酯尤其若用於金屬氧化物等之粉體的油中分散體中，則表現出高分散能力，進而調配有本發明之聚矽氧磷酸三酯的化妝料之化妝膜之均勻性、化妝持久效果優異。 154I16.doc -101·No. Component Example Comparative Example 67 68 69 70 16 17 1 Product of Production Example 1 1.5 - - - - 2 Product of Production Example 2 - 1.5 - - - - 3 Product of Production Example 3 - 1.5 - - - 4 Manufacture Product of Example 4 - _ 4.5 - 5 POE methyl oxirane ΡΟΡ oleyl decyl oxa oxane-dimethyl methoxy olefin copolymer (Note 2) - - - 1.5 - 6 PEG-9 polydimethyl Nonyloxyethyldimethylpolyoxane (Note 1) - - - - - 1.5 7 Lecithin 0.3 0.3 0.3 0.3 0.3 0.3 8 Dimethylpolyoxane 3 3 3 3 3 3 9 Tri 2 - B Glyceride 1 1 1 1 1 1 10 Oxidation 10 10 10 10 10 10 10 11 Titanium oxide particles 2 2 2 2 2 2 12 Iron oxide red 0.5 0.5 0.5 0.5 0.5 0.5 13 Yellow iron oxide 2.3 2.3 2.3 2.3 2.3 2.3 14 iron oxide black 0.2 0.2 0.2 0.2 0.2 0.2 15 dimethyl distearyl hectorite 0.3 0.3 0.3 0.3 0.3 0.3 16 PEG-9 polydidecyl decyloxy ethyl dimethyl polyoxyn (Note 1) 0.3 0.3 0.3 0.3 0.3 0.3 17 alcohol 0.3 0.3 0.3 0.3 0.3 0.3 18 decamethylcyclopentaoxane S 8 8 8 8 8 19 Diethylhexanoic acid neopentyl glycol ester 10 10 10 10 10 10 20 20 PEG -9 polydidecyl alkoxy B Dimethyl polyoxane (Note 1) 1.5 1.5 1.5 1.5 1.5 1.5 21 Proper amount of proper amount Appropriate amount of proper amount 22 Alcohol 7 7 7 7 7 7 23 Preservatives Appropriate amount Appropriate amount Appropriate amount of appropriate amount 24 Chlorinated sodium 0.3 0.3 0.3 0.3 0.3 0.3 25 Purified water remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Residual amount Evaluation item and judgment result Uniformity of cosmetic film ◎ ◎ ◎ 〇Δ Δ Make-up effect ◎ ◎ ◎ 〇Δ Δ (Note 1) KF-6028 ( (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.) -93- 154116.doc 201136613 (Manufacturing method) The components 1 to 14 are treated with light weight. (2) The components 15 to 17 are treated by the observation. (3) The (1), (2) and the components 18 to 20 are uniformly mixed by a disperser. (4) The components 21 to 25 are gradually added to (3) and emulsified. (5) Defoam and fill (4) into the container. (Evaluation) For the W/O type foundations of Examples 67 to 70 and Comparative Examples I1 and I7, 20 of the cosmetics evaluation expert groups respectively based on the following evaluation criteria, "uniformity of the makeup film" and "lasting effect of makeup" Each project is evaluated in seven stages, and the average score of the entire group is judged based on the following criteria. [Evaluation Criteria] (Evaluation Results) : (Score) Very good: 6 points Good: 5 points slightly good: 4 points Normal: 3 points Slightly bad: 2 points Bad: 1 point Very bad: Score [Judgement criteria] (Score Average score): (Judgement) • 94- 1 .〇 Above: ◎ Very good 2 154116.doc 201136613 3·5 or more ~ Not up to 5.0 1.5 or more ~ Not up to 3.5 Not up to 1.5. 〇 Good: △ Bad: χ Very W/〇 type foundation of the case of 67 to 70 is a poorly-dissipated powder foundation with excellent powder dispersibility, uniformity of makeup flag, and good makeup lasting effect. In the comparative example, the ratio of the powder of the previous polysulfide dispersant in the W/0 unsole is higher than that of the powder. Therefore, the bulk dispersibility is poor, so it is not the uniformity of the cosmetic film and the long-lasting effect of the makeup. Excellent. [Example 71] W/〇 type foundation (%) 3.0 0.5 0.5 10.0 10.0 0.4 2.0 0.1 5.0 0.3 1.0 Remaining amount 2.0 (ingredient) 1. The product of Production Example 2 2. Polyoxyethylene monooleate (2〇 Mohr) sorbitan 3. sesquioleic acid sorbitan vinegar 4. 1,3-butanediol 5. polyfluorene oxide treatment of titanium oxide 6. polyfluorene treatment of iron oxide 7. polyoxane treatment oxidation Iron yellow 8. Polyoxane treated iron oxide black 9. Polyoxane treated talc 10. Carboxyvinyl polymer 11. Triethanolamine 12. Purified water 13. Ethanol 154116.doc -95- 201136613 14. Stearic acid 1.0 0.5 3.0 2.0 2.0 0.5 Appropriate amount 15. Hawthorn 16. Flowing paraffin 1 7. Tris-2-ethylhexanoic acid glycerol 18. Polymethoxy cinnamic acid 2-ethylhexine. 19. Vaseline 20. Preservative 21 Perfume (manufacturing method) comprises poly>5 Oxygen (1) A mixture of modified phosphoric acid triesters is prepared by uniformly mixing the components 9 using a three-roll mill. (2) The components 10 to 13 are uniformly mixed. (3) Add (1) to (2) and mix them evenly. (4) The components 14 to 20 were mixed and dissolved at 80 °C. (5) Add (4) to (3) at 80t and emulsify it. "Cosmetic holding (6) Cooling (5) and adding component 21 to obtain a 〇/w type foundation. The Ο/W type foundation of Example 71 is an "o/w type foundation which is excellent in the uniformity of the makeup film." . [Example 72] oily solid foundation (ingredient) (%) 1. talc 15.0 2. mica 10.0 3. polyoxygenated titanium oxide 15.0 4. polyfluorene treated iron oxide 1.0 154116.doc • 96-201136613 5. Oxygen treatment of iron oxide yellow 3.0 6. Polyoxane treatment of iron oxide black 0.2 7. Polyethylene wax 7.0 8. Microcrystalline butterfly 6.0 9. Tri2-ethyl hexanoic acid glyceride remaining amount 1 制造 Manufacturing Example 3 Product 5.0 11. Dimethyl polyoxane 5.0 12. Flowing paraffin 20.0 13. Polyoxyethylene methyl chlorate. • Polyoxypropylene oleyl alcohol 甲基甲基 methyl oxime oxy; dimethyl shi eve Oxygen-fired copolymer (Note 2) 2.0 14. Preservative amount 15. Flavour amount (manufacturing method) (1) The components 7 to 14 are heated and dissolved at 90 °C. (2) A dispersion containing polyfluorene-modified phosphoric acid triester was prepared by adding the components 1 to 6 to (1) and uniformly mixing them by a three-roll mill. (3) After adding component 15 to (2) and dissolving at 80 ° C, the soil is actually filled into a metal container to obtain an oily solid foundation. The oily solid foundation of Example 72 was "an oily solid foundation excellent in the appearance of a cosmetic film and a "lasting effect". ''Cosmetic [Example 73] Sticky oily solid concealer (ingredient) (%) 1·Paraffin 5〇2. Polyethylene wax ς I54116.doc •97- 201136613 3. Candidella wax 2.0 4. Manufacturing implementation The product of Example 4 15 0 5 · Tri-2-ethyl glycerol vinegar 15.0 6. Methyl phenyl polyoxy siloxane 5. 〇 7. Acetate liquid lanolin 1 (). 0 8. P-methoxy 2-ethylhexyl cinnamate 5·〇9. Titanium oxide 20.0 10. Iron oxide yellow 2.0 11. Iron oxide 0.5 12. Iron oxide black 〇.2 13. Mica 7.0 14. Preservative amount 1 5. Flavor amount ( Manufacturing method) (1) Components 1 to 8 were mixed and dissolved at 100 °C. (2) Adding components 9 to 丨5 to (1) at 90 ° C and uniformly mixing them. (3) A dispersion containing polyfluorene-modified phosphoric acid triester was prepared by treating (2) with a three-roll mill. (4) Defoam (3) at 85. (: After dissolving and filling into a vessel, it was cooled at 4 t to obtain a stick concealer. The rod-like oily solid concealer of Example 73 was excellent in "evenness of makeup film" and "lasting effect of makeup" Oily solid concealer [Example 74] W/0 type sunscreen (%) (ingredient) 154116.doc •98· 201136613 1. Zinc oxide 2.0 2. Polyoxynium oxide coated titanium oxide 5.0 3. Three (sim Glycolic acid glyceride 5.0 4. Production of product of Example 3 3.0 5. Octyl palmitate 3.0 6. Pair of methoxy cinnamic acid 2-ethylhexyl quinone 10.0 7 · decamethylcyclopentaoxane 10.0 8. Methyl polyoxyalkylene-cetyl methyl polyoxyalkylene-poly(oxyethylene-oxypropylene) fluorenyl polyoxyalkylene copolymer (Note 3) 1.8 9. Tri-2-ethylhexanoic acid glycerol Ester 3.0 10. Preservatives appropriate amount 11. Chlorinated sodium 0.3 12. Purified water remaining amount 13. Dipropylene glycol 5.0 14. Ethanol 5.0 15. Flavor amount (Note 3) ABIL EM-90 (manufactured by EVONIC GOLDSCHMIDT GMBH) (Manufacturing method (1) After the components 3 and 4 are heated and dissolved, the components 1 and 2 are added and uniformly mixed to prepare a polyoxonium-modified phosphate triester. (2) After dissolving the components 5 to 10 at 70 ° C, add (1) at 6 ° C and mix them evenly. 154116.doc •99- 201136613 (3) Make the ingredients 11~ 13 After mixing and dissolving, it was added to (2) at 60 ° C and emulsified. (4) Components 14 and 15 were added to (3) and uniformly mixed to obtain a w/〇 type sunscreen. The W/O type sunscreen of Example 74 is a W/O type sunscreen which is excellent in "smoothness of a make-up film" and "lasting effect of makeup" [Example 75] W/0 type foundation (%) (ingredient) 1 . Polyoxyethylene methyl oxa oxide · Polyoxypropylene oleyl alcohol methyl oxane - dimethyl fluorene copolymer (Note 2) 2 〇 2 · PEG-3 dimethyl polyoxy siloxane (Note 4) ι 3·dimercaptopolyoxyalkylene 4. Polyoxygenated iron oxide red 5. Polyoxygenated iron oxide yellow 6. Poly <6 oximeter treated iron oxide black 7. Polyoxygenated talc 8 Diethyl 2-ethyl glyceride 9· sesquioleic acid sorbitan ester 1 纯化. Purified water U. 丨, 3-butanediol 12·Preservative 13. Perfume 2〇.〇0.5 5.0 5.0 0.5 Remaining amount 15.0 Appropriate amount 15.0 14. Powder dispersion of Example 1) KF-6015 (Shin-Etsu Manufactured by Chemical Guardian Co., Ltd.) 154116.doc •100- 201136613 (Method) (1) Mix ingredients 1 to 3 evenly. (2) The components 4 to 10 were uniformly dispersed by a roller. (3) Add (2) to (l)t and mix them evenly. (4) Adding ιι 14 to (3) and emulsifying it, adding component 15 to obtain W/0 type foundation. The W/0 type foundation of Example 75 is "uniformity of makeup film" and "makeup Long-lasting effect "Excellent W/0 type foundation. [Industrial Applicability] Since the polyphosphonium phosphate triester of the present invention has a large amount of polyoxynitride chains, it exhibits water repellency and dispersibility with a small amount of treatment, and has a phosphate group, particularly due to metal oxidation. The material is firmly bonded to the surface of the powder, so that the adhesion is excellent. Therefore, the cosmetic formulated with the polyphosphoric acid triester of the present invention is excellent in the repairing effect, the smooth feeling of use, and the long-lasting effect of makeup. Further, the cosmetic film of the cosmetic powder coated with the polyphosphonium phosphate triester coated with the present invention is excellent in uniformity and long-lasting makeup effect. Further, the polyphosphonium phosphate triester of the present invention exhibits a high dispersibility even when it is used in an oil dispersion of a powder of a metal oxide or the like, and is further formulated with the makeup of the polyphosphonium phosphate triester of the present invention. The uniformity of the cosmetic film and the long-lasting effect of the makeup are excellent. 154I16.doc -101·

Claims

201136613 七、申請專利範圍： 1· 一種化妝料，其含有式（I): [化1]201136613 VII. Patent application scope: 1. A cosmetic material containing formula (I): [Chemical 1]

(式中’各Ri分別獨立表示碳數1〜4之烧基，R表示可具有選自-0-及-CO-中之至少！種的碳數2〜7之2價烴基，η 表不5〜40中之任—整數）所示之聚矽氧磷酸三酯中之1種或2種以上。 2.如凊求項丨之化妝料，其含有聚矽氧磷酸酯，該聚矽氧磷酸酯包含： 60〜1〇〇質量％之式⑴： [化2](wherein each of Ri represents independently a carbon number of 1 to 4, and R represents a divalent hydrocarbon group of 2 to 7 carbon atoms which may have at least one selected from the group consisting of -0 and -CO-, and η represents One or two or more kinds of polyphosphoric acid triesters represented by any one of 5 to 40 and an integer. 2. A cosmetic material according to the present invention, which comprises a polyphosphonium phosphate, the polyphosphonium phosphate comprising: 60 to 1% by mass of the formula (1): [Chemical 2]

(式中，各R〗分別獨立表示碳數卜4之烷基，汉表示可具有選自-0-及- C0-中之至少1種的碳數2〜7之2價烴基，表示5〜40中之任一整數）所示之聚矽氧磷酸三酯中之丨種或2種以上， 0〜35質量％之式（II): [化3]Wherein each R represents an alkyl group having a carbon number of 4, and a binary group having a carbon number of 2 to 7 selected from at least one selected from the group consisting of -0 and -C0-, wherein Any one or more of the polyphosphoric acid triesters represented by any one of 40), 0 to 35 mass% of the formula (II): [Chemical 3]

154116.doc 201136613 (式中，Ri、R及η與上述式⑴由4 >致上（υ中之定義相同）所示之聚矽氧磷酸二酯中之1種或2種以}·，η 丄及 0〜5質量°/〇之式（III): [化4] R—Ο—PO(OH)t (式中，R,、R及η與上述式⑴由★—装门、 4八⑴中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上。 3. 如請求項1或2之化妝料，其進_步含有油劑。 4. 一種粉體，其係藉由式(I): [化5]154116.doc 201136613 (wherein, Ri, R and η are one or two of the polyphosphonium oxyphosphate diesters represented by the above formula (1) as defined by 4 > η 丄 and 0 to 5 mass ° / 〇 of the formula (III): [Chemical 4] R - Ο - PO (OH) t (wherein, R, R and η and the above formula (1) by ★ - gate, 4 One or more of the polyphosphonium phosphate monoesters as defined in the above-mentioned eight (1). 3. The cosmetic of claim 1 or 2, which contains an oil agent. , by the formula (I): [Chemical 5]

(式中，各Rl分別獨立表示碳數丨〜4之烷基，尺表示可具有選自-〇·及·ε〇_中之至少i種的碳數2〜7之2價烴基，η ，丁 5 40中之任一整數）所示之聚矽氧磷酸三酯中之1種或2種以上進行表面被覆處理者。 5·如吻求項4之粉體，其係藉由聚矽氧磷酸酯進行表面被覆處理者’該聚矽氧磷酸酯包含·· 60質量％〜1〇〇質量％之式⑴· [化6](wherein each R1 independently represents an alkyl group having a carbon number of 44, and the ruthen represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may have at least one selected from the group consisting of -〇· and ·ε〇_, η , One or two or more of the polyphosphoric acid triesters represented by any one of the integers of 40 to 40 are subjected to surface coating treatment. 5. The powder of the kiss item 4, which is subjected to surface coating treatment by polyphosphonium phosphate. 'The polyphosphonium phosphate contains · 60% by mass to 1% by mass of the formula (1) · 6]

154116.doc (0 201136613 (式中各11"刀別獨立表示碳數1〜4之烷基，尺表示可具有選自Ο及-CO-中之至少!種的碳數2〜7之2價烴基，打表40十之任_整數）所示之聚石夕氧靖酸三醋中之1種或2種以上， 0〜35質量％之式（II): [化7]154116.doc (0 201136613 (wherein 11" each of the formulas independently represents an alkyl group having a carbon number of 1 to 4, and the ruler indicates a carbon number of 2 to 7 which may have at least one selected from the group consisting of hydrazine and -CO-; One or more of the polysulfate oxylic acid triacetates represented by the hydrocarbyl group, which is shown in Table 40 (integer), and the formula (II) of 0 to 35 mass%: [Chemical 7]

之定義相同）所示之聚石夕及 (式中，R丨、R及η與上述式⑴中氧磷酸二酯中之1種或2種以上，〇〜5質量％之式（in): [化8]In the formula (in the formula), R 丨, R and η are one or more of the oxyphosphoric acid diesters in the above formula (1), and 〇 5% by mass of the formula (in): [化8]

(式中’ R,、R及η與上述式⑴中义義相同）所示之臂石々氧磷酸單酯中之1種或2種以上。 υ π 丁之禾矽 6.如請求項4或5之經表面被覆處理之矽氡磷酸酯外，進而含有作Α η 、”了上述聚〜表面處理劑之有機鈦酸 7. 如請求項6之粉體，其質量比為1:9〜9:1 » 8. 如請求項6或7之粉體，脂基鈦酸酯。中聚矽氧磷酸酯及有機鈦酸酯之其中有機鍊酸醋為異丙基三異硬 154116.doc 201136613 9. 如請求項4至8中任一項之經表面被覆處理之粉體，其中粉體為選自由氧化鈦、氧化鋅及氧化鐵所組成之群中之至少1種。 10. 如請求項4至9中任一項之經表面被覆處理之粉體，其中聚矽氧磷酸酯之被覆量為表面被覆處理粉體之〇·〇丨〜5質量％ » 11 _ 一種化妝料，其含有請求項4至10中任一項之經表面被覆處理之粉體》 12. —種粉體分散劑，其含有式⑴： [化9](in the formula, R, R and η are the same as those in the above formula (1)), and one or more of the tremolite phosphine monophosphates. π π 丁之禾矽 6. In addition to the surface-coated yttrium phosphate of claim 4 or 5, further comprising 有机 η, "the above poly ~ surface treatment agent of organic titanic acid 7. As claimed in claim 6 The powder has a mass ratio of 1:9 to 9:1. 8. 8. The powder of claim 6 or 7, the fatty titanate. The organic polyacid salt of the polyphosphonium phosphate and the organic titanate The vinegar is isopropyl triiso-compound 154116.doc 201136613. The surface-coated powder according to any one of claims 4 to 8, wherein the powder is selected from the group consisting of titanium oxide, zinc oxide and iron oxide. The surface-coated powder according to any one of claims 4 to 9, wherein the coating amount of the polyphosphonium phosphate is 表面·〇丨~5 of the surface-coated powder. Mass % » 11 _ A cosmetic containing the surface-coated powder of any one of claims 4 to 10 12. A powder dispersing agent containing the formula (1): [Chemical 9]

(式中’各R〗分別獨立表示碳數丨〜4之烷基，r表示可具有選自-Ο-及-CO-中之至少1種的碳數2〜7之2價烴基，η 表示5〜40中之任一整數）所示之聚矽氧磷酸三酯中之丄種或2種以上。 13.如請求項12之粉體分散劑’其含有聚矽氧磷酸酯，該聚矽氧磷酸酯包含： 60質量％〜1〇〇質量％之式（I) [化 10](wherein each R represents an alkyl group having a carbon number of 44, and r represents a divalent hydrocarbon group having 2 to 7 carbon atoms which may be selected from at least one selected from the group consisting of -Ο- and -CO-, and η represents Among the polyoxonium phosphate triesters represented by any of the integers 5 to 40, two or more of them are used. 13. The powder dispersant of claim 12, which comprises a polyphosphonium phosphate, the polyphosphonium phosphate comprising: 60% by mass to 1% by mass of the formula (I) [Chemical 10]

154116.doc 201136613 (式中，154116.doc 201136613 (where,

或2種以上， 1式中，各R1分別獨立表示碳數1〜4之烷基，R表示可具 .no . 0〜35質量％之式（Π): [化 11]Or two or more types, in each formula, each R1 independently represents an alkyl group having a carbon number of 1 to 4, and R represents a formula of .0 to 35 mass% (Π): [Chem. 11]

(式中’汉丨、R及η與上述式⑴中之定義相同）所示之聚石夕氧磷酸一醋中之1種或2種以上，及〇〜5質量％之式（πΐ): [化 12](In the formula, "Han, R and η are the same as defined in the above formula (1)), one or more of the polyoxophosphoric acid monoacetate, and the formula of 〇~5 mass% (πΐ): [化12]

(式中，RrR及η與上述式⑴中之定義相同）所示之聚矽氧磷酸單酯中之1種或2種以上。 14. 一種粉體分散體，其含有請求項12或13之粉體分散劑、粉體及油劑。 15. —種化妝料，其含有請求項14之粉體分散體。 154I16.doc 201136613 四、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明：五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： •ϋΓ卜0丨 R， R, R, J 3 154116.doc(In the formula, one or more of the polyphosphoric acid monoesters represented by RrR and η are the same as defined in the above formula (1)). A powder dispersion comprising the powder dispersant of claim 12 or 13, a powder and an oil. 15. A cosmetic comprising the powder dispersion of claim 14. 154I16.doc 201136613 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: • ϋΓ 丨 0丨R, R, R, J 3 154116.doc