201120276 六、發明說明： 【發明所屬之技術領域】 本發明一種内襯層用於當作刺繡固定内襯層，由—纺 織品載體材料構成，該紡織品載體材料用一種附著料施 履，其中該附著料有一種水溶性塑性聚合物。 【先前技術】 上述種類之用於水溶性「刺繡固定内襯層」的水溶性 附著料已見於德專利DE 100 32 769 A卜此外還有—此羽1 二為知 之可固定之水溶性附著物料，它們（特別是不織布）用於將紡 織品層暫時牢牢保持住。 在此，在加工之前或之時，將該内襯層或不織布與— 紡織品層[它做成表布（〇berst〇ff)形式]在一固定壓機中層蟲 在一起。接著將補強過及未補強過的部分放在一起並縫= 且在必要時利用成形熨斗（F〇rnibtigel)成形。 在一道隨後的洗濯程序後將附著料洗出，如此該組合 的層再溶解，且因此衣物變得更有可撓性及更軟。 作不同之收縮（Krumpfen，英：shrink)的布也可如此組 合，而不會在一道看護（Pflege)處理後形成泡泡。 在DE 100 32 269 A1所提的附著料藉著散播施覆、施 熱熔膠（Hot-Melt)、將一水溶性熱熔膠不織布層疊上去、或 將一熱熔膠紡織布直接紡到一水溶性不織布上而將該附著 料施覆。 在DE 100 32 769 A1所提之附著料用的習知聚合物將 以（共）聚醯胺、聚乙烯醇及/或（共）聚酯為基礎，它們不能呈 201120276 水冷性为散液的形式 /式矛i用％轉網版印刷方法印 不織布上，因盔* η — 丨糾到水溶性 為在附者料中的水會造成水溶 狀溶解》 狀个纖布的點 δ亥水溶性的；^ _ 士 ^ 不為布之〉谷掉或印刷的位置使得此用附著 枓施覆的不織布表面觀瞻不佳且不平坦。 附者 μ、Λ種不平坦會轉移到利用此内襯層固定的紡織物層， 述表面的不平垣對製成的布的外觀造成負面影響。 在不織布中溶掉的位置或洞隙係不能接 材料不能用於衣著或刺、繡。 且使此 【發明内容】 由本^明的目的在將先前技術的習知附著料作理及 改善’使它們可無問題地用於水溶性内襯層，特別是不織 布。 追種目的依本發明利用申請專利範圍第丨項的特徵達 成。 依此上述内襯層的特徵為：該附著料做成水性聚合 物分散液及/或聚合物溶液形式。 出乎意料地，一種濃縮程夠高的水性聚合物分散液及/ 或聚合物溶液可印刷到易溶於水的載體材料（特別是不鐵沛） 上，而無上述負面效果。依本發明了解，一種水性的系統 疋可以印刷到可溶於冷水的不織布上◦在此「冷水」係指 溫度高可達40eC的水。 依此可達上述目的》 在印刷時可使用CP5〜CP250的模板（SchaM〇ne)大小。 201120276 依附著料可具多於50%的固體含量，利用這種濃度或 更高的濃度可避免該可溶於冷水的載體材料發脹 (Aufqueller)。 此附著料可具有乙烯基吡咯烷酮或改質的乙烯基吡〇各 院嗣。特別是聚乙烯基吡咯烷酮及共聚合物（C〇p〇lymerisate) 顯示很適合製造水性聚合物分散液及/或聚合物溶液。乙稀 基吡咯烷酮有良好的冷水溶性，但有強吸濕性 (hygraskopisch)且隨著空氣濕度升高變粘。含有聚乙酸乙烯 酯的乙烯基吡咯烷酮比起來未改質的乙烯基吡咯烷酮在室 溫時較無吸濕性，因此，在捲取成布疋捲的狀態，該施覆 過的内襯層不會粘住。 ~此附著料可具多元醇（Pc)lyGl)或聚乙：醇。#著添加多 元醇及/或聚乙二肖，可將一種聚合物(特別是乙烯基吡咯烷 酮)的熔解溫度範圍改善，特別是降低，或者聚合物的熔融 流可配合各種用途。此水溶性附著料利用聚乙二醇而變 軟。=軟化劑宜為聚乙稀乙二醇(pEG)。尤宜使用濃度 〇〜20/。（特宜濃度2〜1〇%)的pEG4〇〇。 如此 附者料中可加入0〜10%重量的印刷補助劑， 例如分散劑（Dlspergator)或稠化劑。 補助幻 此纺織品載體材料可為水溶性者。如此 可溶解。 3載體材料 此紡織品載體材料可由聚 乙稀醇可藉著《合物乙氧基化^\製^載體材料的 95%)而改變，改質過的聚乙稀醇很容易、、容在：二度大 勿/合在冷水（即溫 201120276 1 〇〜40 °C的水）。特別是該紡織品載體材料可做成不織布形 式。此不織布的單位面積重量可為2〇〜12〇克/平方米。’ 該紡織品載體材料以及附著料在10〜4(rc的溫度都 溶於水。 X ° 上4目的也利用-種用㈣覆一紡織品載體材料 者料達成。 上述附著料也適合將非水溶性載體材料作印刷。在非 水溶性的紡織品材料上也施覆由上述附著料固成的固定性 良好的履層，它們在加工後可容易洗出，在此背景之前， 附著料的固體含量可少於5%。 此處所述的内襯層係可固定者，換言之，它可毫無問 題地在-道熱程序與任何種類的纺織品表布接合。此熱程 序（亦即固定或層疊作業）係在80〜14(rc的溫度中。… 此處所述的附著料宜可用於内槪不織布特別是用於 水溶性的内襯不織布及/或刺繡不織布。 、 一種製造上述内的古、土 .. 4門锹層的方法，包含以下步驟：提供一 種紡織品載體材料，以及將該纺織品用一種附著料施覆， 該附著料有—種水性聚合物分散液及/或聚合物溶液。如此 可將-内襯層先製成中間產物形式1用一水性聚合物分 散液及/或一聚合物溶液施覆。此然此中間產物失去了就水 溶性聚合如分散物/或聚合物溶液的水，但變成終產物4 即此處所申請的内襯層。 如今有各種不同的可 椹相M 可㈣地實施本發明的 構想及進一步改良。為^ , '·‘，b，可參考申請專利範圍附屬項以 6 201120276 及以下較佳實施例的說明。 配合該較佳實施例的說明也一般性說明較佳的設計及 進一步特點。 【實施方式】 以在的表1中顯示熔解範圍及熔融流的變化。 混合比例 100%VA64 0% PEG 400 97% VA 64 3% PEG 400 95%VA64 5% PEG 400 90%VA64 10% PEG 400 80% VA 64 20% PEG 400 熔解溫度範圍 rc] 約 140°C 不易定義 125~130〇C 110~115°C 90~100°C 軟 無法定義 MFIi4(TC/2.16 公斤 [克/10分] 10.6 14.9 45.7 82.6 不能測量 MFli6(TC/2.16 公斤 [克/10分] 13.2 22.5 76 186 不能測量 宜使用Luvitec VA 64與0〜20%。PEG(尤宜3〜15% PEG 4 00)的混合物，其他PEG也同樣可用。 [實施例] [實施例1] 將100%棉花構成的水注鞏固過的不織布（單位面積重 量80克/平方法）用一種由水性聚合物分散液構成的附著料 (固體含量45%)印刷。 此聚合物分散液由4克/升的‘Luvitec VA 64、40克/升 的PEG 400與5克/升的一種分散劑，稠化劑及糊助流輔助 劑的混合物構成。 印刷係利用旋轉網版印刷技術達成，它係用一印刷模 板CP110(這相當於20%的開放面積）將25克/平方米的附著 料構成的覆層施覆。在145°C作乾燥。 [實施例2] 7 201120276 用於作刺繡固定内襯層的載體材料者，係爲一種熱結 合的不織布。由於該冷水的聚乙烯醇（PVAL)短纖維製造， 單位面積重量約40克/平方米。 此聚乙烯醇纖維-短纖維係在一道凝膠體紡絲程序製 造，且強度為4克/單尼爾。此不織布用一種附著料（亦即之 60%固體含量的分散液或溶液）印刷。 此附著劑由600克/升的Luvitec VA 64、45克/升PEG 4 0 0和5克/升的分散劑，稠化劑及糊助流輔助劑的混合物 構成。 印刷係利用一旋轉網版印刷技術達成，它係用一印刷 模板CP 52，這相當於15%的開放面積，將15克/平方米的 附著料構成的覆層施覆。在1451作乾燥。 利用上述附著料印刷，出乎意料地，沒有任何問題。 在乾燥後，也看不到各層相枯著的情事。 在以下的表2顯示附著值，這種值係當此處所述種類 的一内襯層與一 Hemden-Popeline，測試布接合時所造成者。 表2 實施例2 PVAL-Vliesstoff DO 102 實施例1 附著料 15克/平方米， 93%VA, 64,6.2% PEG 具有改質之 PA Μ-布， 15克/平方米 25克/平方米， 90%VA64, 9% PEG 400 固體含量 60% 100% M-布 45% 分離力量 120°C/15 秒 Hemden-Popeline-測試布 在120°C固定溫度 1.6N/5cm 在120°C固定溫度 無附著在130°C，C5.2 N/5cm 在120°C固定之溫度 7.8N/5cm 201120276 在表2中所述的改質（modifiziert)的PA(聚醯胺）相當於 DE 100 32 769 A1的實例1的聚醯胺。VA表示乙酸乙稀醋， 其中使用該產物Luvitec VA64. PEG表示聚乙烯乙二醇。 [優點] 當將以共聚酯為基礎的冷水溶性的聚合物粉 (Schattifix 699型）作燒結時’燒結條件不多於載體材料開始 收縮（Schrumpf)的限度的1 50°C。當燒結時，寬度損失很大。 這點利用本發明的混合物及此處所述的方法不再有問 題β 1 50°C以下的乾燥溫度可良好地實施，印刷的點的燒於 作用很好。 習知技術的繁複的方法一將紡絲不織布用水溶性聚人 物分別紡成，然後將它們與水溶性不織布層疊_利用此處 所述的方法大大簡化。 我們也可將上述種類的聚合物的混合溶在一起，& & 造成褐色之變色現象。這種聚合物混合物可呈熱炫膠方式 或在磨成粉的狀態當作粉末點施覆，這種附加的工作途& 會使程序成本提高，其中該變色係一種不想要的附加性質。 由於各成分可一起攪拌，因此，此處所述的方法可簡 單地實施，在除空氣後，產生一淺白分散液或一清澈溶液。 利用1〜3 %改質纖維素構成的稍化劑’可調整印刷用的7人 物之所需枯度。還可各依需要將小量的其他的印刷辅口 入° 此可印刷的附著劑須含多於5〇〇/。的固體含量，俾处： 冷水溶性的載體材料良好地印刷。固體含量大於’ 、/ 3 A會產 201120276 生高粘度的混合物， 體含量的混合物印席 它較難使用於印刷，也可將 到非水溶性載體材料上。 具較低固 的設計及進一步特點可參考說明 關於本發明其他有利 書和申請專利範圍。 述實施例只用於說明本發明，但本發明範圍不限於 這些實施例。 【圖式簡單說明】 無 【主要元件符號說明】 無201120276 VI. Description of the Invention: [Technical Field] The present invention relates to an inner liner layer for use as an embroidery fixing inner liner, which is composed of a textile carrier material, and the textile carrier material is applied by an adhesive material, wherein The adhesive has a water-soluble plastic polymer. [Prior Art] The above-mentioned water-soluble adhesive materials for water-soluble "embroidery fixed inner liner" have been found in German Patent DE 100 32 769 A. In addition, this feather 1 is a water-soluble adhesive material which can be fixed. They (especially non-woven) are used to temporarily hold the textile layer firmly. Here, the inner or non-woven fabric is layered together with the textile layer [in the form of a table cloth] in a stationary press before or at the time of processing. The reinforced and unreinforced portions are then placed together and sewn = and if necessary formed with a forming iron (F〇rnibtigel). The adherent is washed out after a subsequent washing procedure, so that the combined layers are redissolved, and thus the garment becomes more flexible and softer. Cloths with different shrinkage (Krumpfen, English: shrink) can also be combined in such a way that bubbles are not formed after a Pflege process. The adhesive material proposed in DE 100 32 269 A1 is coated by spreading, hot-melt, hot-melt hot-melt adhesive non-woven fabric, or a hot-melt adhesive woven fabric directly spun to one. The adhering material was applied on a water-soluble non-woven fabric. The conventional polymers for the attachments mentioned in DE 100 32 769 A1 will be based on (co)polyamines, polyvinyl alcohols and/or (co)polyesters, which are not water-cooling in 201120276. The form/type spear i is printed on the non-woven fabric by the % screen printing method, because the helmet * η - 丨 corrects the water solubility to the water in the attached material will cause water-soluble dissolution. ; ^ _ 士 ^ The position of the cloth that is not covered or printed so that the surface of the non-woven fabric coated with the 枓 is poorly viewed and uneven. Attachment μ, the unevenness of the seed is transferred to the textile layer fixed by the inner liner, and the unevenness of the surface adversely affects the appearance of the produced cloth. The position or the gap that is dissolved in the non-woven fabric cannot be connected. The material cannot be used for clothing or thorn or embroidery. Further, it is to be noted that the prior art conventional attachment materials are conditioned and improved by the purpose of the present invention, so that they can be used without problems in a water-soluble inner liner layer, particularly a nonwoven fabric. The purpose of the seeding is achieved according to the invention using the features of the third paragraph of the patent application. Accordingly, the inner liner layer is characterized in that the adherend is in the form of an aqueous polymer dispersion and/or a polymer solution. Unexpectedly, an aqueous polymer dispersion and/or polymer solution of sufficiently high concentration can be printed onto a water-soluble carrier material (especially non-ferrous) without the above-mentioned negative effects. It is understood in accordance with the present invention that an aqueous system can be printed onto a non-woven fabric that is soluble in cold water. "Cold water" means water having a temperature of up to 40 eC. According to this, the above purpose can be achieved. The size of the template (SchaM〇ne) of CP5~CP250 can be used for printing. 201120276 Adhesives can have a solids content of more than 50%. With this concentration or higher, the cold water-soluble carrier material can be prevented from swelling. This attachment may have a vinylpyrrolidone or a modified vinylpyrazine. In particular, polyvinylpyrrolidone and a copolymer (C〇p〇lymerisate) have been shown to be suitable for the preparation of aqueous polymer dispersions and/or polymer solutions. Ethyl pyrrolidone has good cold water solubility, but has strong hygroscopicity and becomes sticky with increasing air humidity. The vinylpyrrolidone containing polyvinyl acetate is less hygroscopic than the vinylpyrrolidone which is not modified at room temperature, and therefore, the coated inner liner does not stick in the state of being wound into a fabric roll. live. ~ This additive may have a polyol (Pc) lyGl) or a polyethylidene: alcohol. The addition of a polyol and/or a polyethylene oxide can improve the melting temperature range of a polymer (especially vinylpyrrolidone), in particular, or the melt flow of the polymer can be used in various applications. This water-soluble adherent softens with polyethylene glycol. = The softener is preferably polyethylene glycol (pEG). It is especially desirable to use a concentration of 〇~20/. (Special concentration 2~1〇%) of pEG4〇〇. Thus, 0 to 10% by weight of a printing auxiliary agent such as a dispersing agent (Dlspergator) or a thickening agent may be added to the accompanying material. Subsidy This textile carrier material can be water soluble. So soluble. 3 carrier material The textile carrier material can be changed by the polyethylene glycol by the "ethoxylation of the compound / 95% of the carrier material", the modified polyethylene glycol is easy, and accommodate: Second degree do not / close in cold water (ie temperature 201120276 1 〇 ~ 40 ° C water). In particular, the textile carrier material can be formed in a non-woven fabric form. The basis weight of the non-woven fabric can be 2 〇 12 12 g / m 2 . The textile carrier material and the adherent are in the range of 10 to 4 (the temperature of rc is soluble in water. The X target is also used for the purpose of 4 (4) covering a textile carrier material. The above-mentioned adhesive material is also suitable for water-insoluble. The carrier material is printed. The water-repellent textile material is also coated with a well-fixed crawler layer which is solidified by the above-mentioned adhesive materials, and can be easily washed out after processing. Before this background, the solid content of the adhesive material can be Less than 5%. The inner liner described here can be fixed, in other words, it can be joined to any kind of textile table cloth without any problems in the heat process. This heat program (ie fixed or laminated) The operation is in the temperature of 80 to 14 (rc). The adhesive material described herein is preferably used for the inner non-woven fabric, especially for water-soluble lining non-woven fabrics and/or embroidery non-woven fabrics. , the method of 4 锹 layer, comprising the steps of: providing a textile carrier material, and applying the textile with an adhesive material, the aqueous material polymer dispersion and/or polymer solution .Such as The inner liner layer can be first formed into an intermediate product form 1 with an aqueous polymer dispersion and/or a polymer solution. The intermediate product is thus lost in water soluble polymerization such as a dispersion/polymer solution. Water, but becomes the final product 4, which is the inner liner applied here. Nowadays, there are various different phases M. (4) The concept and further improvement of the invention can be implemented. For ^, '·', b, refer to the patent application. The scope of the sub-items is described in the preferred embodiment of the present invention. The description of the preferred embodiment also generally illustrates the preferred design and further features. [Embodiment] The melting range and melting are shown in Table 1 Variation of flow. Mixing ratio 100% VA64 0% PEG 400 97% VA 64 3% PEG 400 95% VA64 5% PEG 400 90% VA64 10% PEG 400 80% VA 64 20% PEG 400 Melting temperature range rc] About 140 °C is not easy to define 125~130〇C 110~115°C 90~100°C Soft MFIi4 cannot be defined (TC/2.16 kg [g/10 min] 10.6 14.9 45.7 82.6 MFli6 cannot be measured (TC/2.16 kg [g/10 Minutes] 13.2 22.5 76 186 Cannot measure Luvitec VA 64 with 0~20%. A mixture of PEG (especially 3 to 15% PEG 4 00), other PEGs are also available. [Examples] [Example 1] A non-woven fabric (100 g/flat weight per unit area) of 100% cotton Method) Printing with an adherent composed of an aqueous polymer dispersion (solid content 45%). This polymer dispersion consisted of a mixture of 4 g/l of 'Luvitec VA 64, 40 g/l of PEG 400 and 5 g/l of a dispersant, a thickener and a paste aid aid. The printing system was achieved using a rotary screen printing technique which applied a coating of 25 g/m 2 of adhesive material using a printing template CP110 (which corresponds to an open area of 20%). Dry at 145 °C. [Embodiment 2] 7 201120276 A carrier material for use as an embroidery fixing inner liner is a thermally bonded nonwoven fabric. Due to the production of the cold water polyvinyl alcohol (PVAL) staple fiber, the weight per unit area is about 40 g/m2. The polyvinyl alcohol fiber-staple fiber was produced in a gel spinning process and had a strength of 4 g/denier. This nonwoven fabric is printed with an adherent (i.e., a 60% solids dispersion or solution). This adhesive consisted of a mixture of 600 g/L Luvitec VA 64, 45 g/L PEG 40 and 5 g/L dispersant, thickener and paste flow aid. The printing system was achieved using a rotary screen printing technique which used a printing template CP 52, which corresponds to an open area of 15%, and applied a coating of 15 g/m 2 of adhesive. Dry at 1451. Printing with the above-mentioned adhesive material unexpectedly did not cause any problem. After drying, there is no such thing as the layers are dry. The attached values are shown in Table 2 below, which is the result of when a liner of the type described herein is bonded to a Hemden-Popeline, test cloth. Table 2 Example 2 PVAL-Vliesstoff DO 102 Example 1 Adhesive 15 g/m2, 93% VA, 64, 6.2% PEG with modified PA Μ-cloth, 15 g/m2 25 g/m2, 90% VA64, 9% PEG 400 Solid content 60% 100% M-cloth 45% Separation force 120°C/15 seconds Hemden-Popeline-test cloth fixed temperature at 120°C 1.6N/5cm Fixed temperature at 120°C Attached at 130 ° C, C5.2 N/5cm fixed at 120 ° C temperature 7.8N/5cm 201120276 The modified (modifiziert) PA (polyamide) described in Table 2 is equivalent to DE 100 32 769 A1 Example 1 of polyamine. VA represents ethyl acetate vinegar, wherein the product Luvitec VA64. PEG is used to represent polyethylene glycol. [Advantages] When the cold-water-soluble polymer powder (Schattifix 699 type) based on the copolyester is sintered, the sintering condition is not more than 150 ° C of the limit of the starting shrinkage of the carrier material. When sintered, the width loss is large. This is no longer a problem with the mixture of the present invention and the method described herein. The drying temperature of β 1 50 ° C or less can be satisfactorily carried out, and the burning point of the printed dots is excellent. A complicated method of the prior art is to separately spun a spun silk non-woven fabric with a water-soluble polyester and then laminating them with a water-soluble non-woven fabric - greatly simplified by the method described herein. We can also dissolve the mixture of the above types of polymers, && to cause brown discoloration. This polymer mixture can be applied as a powder in a hot glue or as a powder in a pulverized state. This additional work & will increase the cost of the process, which is an unwanted additional property. Since the ingredients can be stirred together, the process described herein can be carried out simply by removing a light white dispersion or a clear solution after removal of air. The desired degree of dryness of the seven persons for printing can be adjusted by using a sizing agent composed of 1 to 3% of modified cellulose. A small amount of other printing auxiliary can also be added as needed. The printable adhesive must contain more than 5 〇〇/. Solid content, 俾: Cold water-soluble carrier material is well printed. A solids content greater than ', / 3 A will yield a high viscosity mixture of 201120276. The mixture of body content is difficult to use for printing and can also be applied to water-insoluble carrier materials. The design with lower solids and further features can be referenced to other advantageous books and patent applications of the present invention. The examples are merely illustrative of the invention, but the scope of the invention is not limited to the examples. [Simple diagram description] None [Main component symbol description] None