EP2488691A2 - Water-soluble adhesive compound coating for water-soluble interlining materials - Google Patents
Water-soluble adhesive compound coating for water-soluble interlining materialsInfo
- Publication number
- EP2488691A2 EP2488691A2 EP10771328A EP10771328A EP2488691A2 EP 2488691 A2 EP2488691 A2 EP 2488691A2 EP 10771328 A EP10771328 A EP 10771328A EP 10771328 A EP10771328 A EP 10771328A EP 2488691 A2 EP2488691 A2 EP 2488691A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- soluble
- adhesive
- adhesive composition
- carrier material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4266—Natural fibres not provided for in group D04H1/425
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4309—Polyvinyl alcohol
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/641—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the chemical composition of the bonding agent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D05—SEWING; EMBROIDERING; TUFTING
- D05C—EMBROIDERING; TUFTING
- D05C17/00—Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
- D06M17/06—Polymers of vinyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7166—Water-soluble, water-dispersible
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/06—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
Definitions
- the invention relates to an insert for use as an embroidery fixation insert, consisting of a textile carrier material which is coated with an adhesive mass, wherein the adhesive composition comprises a water-soluble, thermoplastic polymer.
- lining fabrics or nonwovens are laminated together with a textile layer configured as an outer material in a fixing press. Subsequently, reinforced and unreinforced parts are joined together, sewn and shaped if necessary by shaping.
- the polymers known from DE 100 32 769 A1 for adhesive compositions based on (co) polyamides, polyvinyl alcohols and / or (co) polyesters can not be imprinted on water-soluble nonwovens in the form of an aqueous dispersion by a rotary screen printing method, since the water in the Adhesive mass leads to selective dissolution of the water-soluble nonwoven fabric. Triggered or printed areas of the water soluble nonwoven result in an unsightly, rough surface of the adhesive coated nonwoven fabric.
- the invention is therefore based on the object to design the adhesive compositions known from the prior art in such a way and further that they can be easily used for water-soluble deposits, especially for nonwovens.
- the aforementioned insert is characterized in that the adhesive composition is designed as an aqueous polymer dispersion and / or as a polymer solution.
- Nonwovens is imprintable. This is under cold water, a water
- a stencil size of CP 5 - CP 250 can be used.
- the adhesive mass could have a solids content of more than 50%. This or a higher concentration swells the
- the adhesive composition could have vinylpyrrolidone or modified vinylpyrrolidone.
- Polymer solution have in particular polyvinylpyrrolidone and
- Vinylpyrrolidones with polyvinyl acetate moieties are less hygroscopic at room temperature than unmodified vinylpyrrolidones. Therefore, the coated deposits do not stick when rolled up.
- the adhesive composition could comprise polyols or polyglycols.
- polyols and / or polyglycols By adding polyols and / or polyglycols, the melting range of a polymer, in particular the vinylpyrrolidones, can be changed, in particular lowered, or the melt flow of the polymer can be adapted to the respective applications.
- the water-soluble adhesive is softened by polyglycols.
- Polyethylene glycol (PEG) is preferably used as plasticizer.
- PEG 400 in a concentration of 0-20%, particularly preferably in a concentration of 2-10%.
- the adhesive mass could be admixed with 0-10% by weight of printing auxiliaries, such as dispersants or thickeners.
- the textile carrier material could be water-soluble. As a result, the carrier material can be dissolved.
- the textile carrier material could be made of polyvinyl alcohol.
- the polyvinyl alcohol of the carrier material could be modified by ethoxylation of the polymers or by saponification with a degree of saponification greater than 95%. Modified polyvinyl alcohols dissolve well in cold water, namely water at a temperature of 10 to 40 ° C.
- the textile carrier material could be designed as a nonwoven fabric.
- the nonwoven fabric could have a basis weight of 20 to 120 g / m 2 .
- Temperatures of 10 to 40 ° C be water-soluble.
- Solved coating of a textile substrate is also suitable for printing on not
- the solids content of the adhesive mass could be less than 50%.
- the deposits described here are fixable, that is, they can be easily connected in a thermal process with textile materials of any kind.
- the thermal process namely fixation or lamination, is carried out at temperatures of 80 to 140 ° C.
- the adhesive compositions described here are preferably usable for nonwoven insert fabrics, in particular for water-soluble inlay and / or embroidery nonwovens.
- a method of making a liner of the type described herein could include the steps of providing a textile substrate and coating the polymeric substrate with an adhesive comprising an aqueous polymer dispersion and / or a polymer solution.
- an insert is first produced as an intermediate, with a aqueous polymer dispersion and / or a polymer solution is coated. This intermediate then loses the water of the aqueous
- Table 1 below shows the change in melting range and melt flow.
- Table 1 Preference is given to using a mixture of Luvitec VA 64 with 0-20% PEG 400, more preferably 3-15% PEG 400. Other PEGs can also be used. embodiments
- Basis weight of 80 g / m 2 was printed with an adhesive mass of an aqueous polymer dispersion having a solids content of 45%.
- the polymer dispersion consisted of 400 g / l Luvitec VA 64, 40 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and
- the printing was carried out by means of a rotary screen printing technique. It was applied with a printing template CP 110, which corresponds to an open area of 20%, a coating of adhesive mass of 25 g / m 2 . The drying took place at 145.degree.
- Embodiment 2 is a diagrammatic representation of Embodiment 1:
- the carrier material for an embroidery fixation insert was a thermally bonded nonwoven fabric produced from cold-water-soluble polyvinyl alcohol (PVAL) staple fibers having a weight per unit area of about 40 g / m 2 .
- PVAL cold-water-soluble polyvinyl alcohol
- the polyvinyl alcohol staple fibers were prepared in a gel spinning process and had a strength of 4 g / denier.
- This nonwoven fabric was printed with an adhesive mass, namely a dispersion or solution, with 60% solids content.
- the adhesive consisted of 600 g / l Luvitec VA 64, 45 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and paste flow aids.
- the printing was carried out by means of a rotary screen printing technique. A coating of adhesive mass of 15 g / m 2 was applied using a CP 52 printing stencil, which corresponds to an open area of 15%. The drying took place at 145.degree.
- the printing with the above adhesives prepared surprisingly no problems. After drying, no sticking of the layers was observed.
- Table 2 The modified (mod.) PA (polyamide) mentioned in table 2 corresponds to the polyamide according to example 1 from DE 100 32 769 A1.
- VA stands for vinyl acetate, using the product Luvitec VA 64.
- PEG stands for polyethylene glycol.
- This polymer mixture can be used as a hot-melt or in the ground state as
- Powder point to be applied This additional operation makes the process more expensive, the discoloration representing an undesired additional property.
- the method described here is easy to implement because the components can be stirred together. After venting creates a slightly whitish dispersion or a clear solution. With 1 - 3% modified cellulosic thickener, the necessary viscosity of the mixture can be achieved Print to be set. Depending on requirements, further printing auxiliaries can be added in small amounts.
- the printable adhesive mass should have a solids content of more than 50% in order to print good cold water-soluble carrier materials can.
- Solids greater than 75% provide a high viscosity blend that is relatively difficult to use for printing. It is also possible to print on mixtures with lower solids contents on non-water-soluble carrier materials.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Details Of Garments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Automatic Embroidering For Embroidered Or Tufted Products (AREA)
- Laminated Bodies (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
Abstract
In order to achieve the aim of designing and further developing the adhesive compounds known from the prior art such that they can easily be used for water-soluble interlinings, in particular for non-woven fabrics, an interlining for use as a fixing interlining for embroidery, consisting of a textile carrier material coated with an adhesive compound, the adhesive compound containing a water-soluble, thermoplastic polymer, is characterised in that the adhesive compound is designed as an aqueous polymer dispersion and/or as a polymer solution.
Description
Wasserlösliche Haftmassenbeschichtung Water-soluble adhesive coating
für wasserlösliche Einlagestoffe for water-soluble interlinings
Beschreibung description
Technisches Gebiet Technical area
Die Erfindung betrifft eine Einlage zur Verwendung als Stickerei-Fixiereinlage, bestehend aus einem textilen Trägermaterial, welches mit einer Haftmasse beschichtet ist, wobei die Haftmasse ein wasserlösliches, thermoplastisches Polymer aufweist. The invention relates to an insert for use as an embroidery fixation insert, consisting of a textile carrier material which is coated with an adhesive mass, wherein the adhesive composition comprises a water-soluble, thermoplastic polymer.
Stand der Technik Wasserlösliche Haftmassen für wasserlösliche Stickerei-Fixiereinlagen der eingangs genannten Art sind bereits aus der DE 100 32 769 A1 bekannt. Des Weiteren sind fixierbare wasserlösliche Haftmassen bekannt, die auf PRIOR ART Water-soluble adhesive compositions for water-soluble embroidery fixation liners of the type mentioned in the introduction are already known from DE 100 32 769 A1. Furthermore, fixable water-soluble adhesive compositions are known
Einlagestoffen, insbesondere auf Vliesstoffen, dem temporären Festhalten von textilen Lagen dienen. Einlagestoffen, especially on nonwovens, the temporary retention of textile layers serve.
Dabei werden vor oder während der Verarbeitung Einlagestoffe bzw. Vliesstoffe mit einer als Oberstoff ausgestalteten textilen Lage in einer Fixierpresse zusammenlaminiert. Im Anschluss daran werden verstärkte und unverstärkte Teile zusammengefügt, vernäht und bei Bedarf durch Formbügeln geformt. In this case, before or during processing, lining fabrics or nonwovens are laminated together with a textile layer configured as an outer material in a fixing press. Subsequently, reinforced and unreinforced parts are joined together, sewn and shaped if necessary by shaping.
BESTÄTIGUNGSKOPIE
Nach einem anschließenden Waschprozess wird die Haftmasse ausgewaschen. Hierdurch werden zusammengefügte Lagen wieder gelöst und somit Kleidungsstücke flexibler und weicher. Auch unterschiedlich krumpfende Stoffe können so zusammengefügt werden, ohne dass eine Blasenbildung nach Pflegebehandlungen auftritt. CONFIRMATION COPY After a subsequent washing process, the adhesive is washed out. As a result, joined layers are released again and thus garments more flexible and softer. Even different shrinking substances can be joined together without blistering after care treatments occurs.
Die aus der DE 100 32 769 A1 bekannten Haftmassen werden durch The adhesive compositions known from DE 100 32 769 A1 are known
Streubeschichtung, Hot-Melt-Auftrag, Auflaminieren eines wasserlöslichen Schmelzklebevliesstoffes oder ein direktes Aufspinnen eines Spread coating, hot-melt application, lamination of a water-soluble hot melt adhesive fabric or direct spinning of a
Schmelzklebespinnvliesstoffes auf einen wasserlöslichen Vliesstoff Hot melt spunbonded nonwoven fabric onto a water soluble nonwoven fabric
aufgebracht. applied.
Die aus der DE 100 32 769 A1 bekannten Polymere für Haftmassen auf Basis von (Co-)Polyamiden, Polyvinylalkoholen und / oder (Co-)Polyestern sind in Form einer wässrigen Dispersion nicht durch ein Rotationssiebdruckverfahren auf wasserlösliche Vliesstoffe aufdruckbar, da das Wasser in der Haftmasse zu punktuellen Auflösung des wasserlöslichen Vliesstoffes führt. Angelöste oder bedruckte Stellen des wasserlöslichen Vliesstoffs führen zu einer unansehnlichen, unruhigen Oberfläche des mit Haftmasse beschichteten Vliesstoffes. The polymers known from DE 100 32 769 A1 for adhesive compositions based on (co) polyamides, polyvinyl alcohols and / or (co) polyesters can not be imprinted on water-soluble nonwovens in the form of an aqueous dispersion by a rotary screen printing method, since the water in the Adhesive mass leads to selective dissolution of the water-soluble nonwoven fabric. Triggered or printed areas of the water soluble nonwoven result in an unsightly, rough surface of the adhesive coated nonwoven fabric.
Diese Unruhe überträgt sich auf die durch die Einlage fixierte textile Lage. Die genannte Unruhe der Oberfläche führt zu einer negativen Beeinträchtigung des optischen Erscheinungsbildes der fertigen Ware. This restlessness is transferred to the textile layer fixed by the insert. The aforementioned restlessness of the surface leads to a negative impairment of the visual appearance of the finished product.
Angelöste Stellen oder Löcher im Vliesstoff sind nicht akzeptabel und schließen eine Verwendung des Materials für die Bekleidung oder für Stickereien aus.
Darstellung der Erfindung Marked spots or holes in the nonwoven fabric are unacceptable and preclude use of the material for clothing or embroidery. Presentation of the invention
Der Erfindung liegt daher die Aufgabe zu Grunde, die aus dem Stand der Technik bekannten Haftmassen derart auszugestalten und weiterzubilden, dass sie problemlos für wasserlösliche Einlagen, insbesondere für Vliesstoffe, verwendet werden können. The invention is therefore based on the object to design the adhesive compositions known from the prior art in such a way and further that they can be easily used for water-soluble deposits, especially for nonwovens.
Die vorliegende Erfindung löst die zuvor genannte Aufgabe durch die Merkmale des Patentanspruchs 1. The present invention achieves the aforementioned object by the features of patent claim 1.
Danach ist die eingangs genannte Einlage dadurch gekennzeichnet, dass die Haftmasse als wässrige Polymerdispersion und/ oder als Polymerlösung ausgestaltet ist. Thereafter, the aforementioned insert is characterized in that the adhesive composition is designed as an aqueous polymer dispersion and / or as a polymer solution.
Überraschend wurde gefunden, dass eine ausreichend hoch konzentrierte wässrige Polymerdispersion und/ oder Polymerlösung auf leicht Surprisingly, it has been found that a sufficiently highly concentrated aqueous polymer dispersion and / or polymer solution are readily dissolved
wasserlöslichen Trägermaterialien, insbesondere Vliesstoffen, ohne die oben genannten negativen Effekte aufgedruckt werden kann. Erfindungsgemäß ist erkannt worden, dass ein wässriges System auf kaltwasserlöslichen water-soluble carrier materials, in particular nonwovens, without the negative effects mentioned above can be printed. According to the invention, it has been recognized that an aqueous system is soluble in cold water
Vliesstoffen aufdruckbar ist. Dabei wird unter Kaltwasser Wasser einer Nonwovens is imprintable. This is under cold water, a water
Temperatur bis zu 40° C verstanden. Temperature up to 40 ° C understood.
Folglich ist die eingangs genannte Aufgabe gelöst. Consequently, the object mentioned above is achieved.
Beim Bedrucken kann eine Schablonengröße von CP 5 - CP 250 verwendet werden. When printing, a stencil size of CP 5 - CP 250 can be used.
Die Haftmasse könnte einen Feststoffgehalt von mehr als 50 % aufweisen. Durch diese oder eine höhere Konzentration wird ein Aufquellen des The adhesive mass could have a solids content of more than 50%. This or a higher concentration swells the
kaltwasserlöslichen Trägermaterials vermieden.
Die Haftmasse könnte Vinylpyrrolidone oder modifizierte Vinylpyrrolidone aufweisen. Zur Herstellung der wässrigen Polymerdispersion und/ oder cold water-soluble carrier material avoided. The adhesive composition could have vinylpyrrolidone or modified vinylpyrrolidone. For the preparation of the aqueous polymer dispersion and / or
Polymerlösung haben sich insbesondere Polyvinylpyrrplidon und Polymer solution have in particular polyvinylpyrrolidone and
Copolymerisate als geeignet erwiesen. Vinylpyrrolidone sind gut Copolymers proved to be suitable. Vinyl pyrrolidones are good
kaltwasserlöslich, sind aber stark hygroskopisch und werden mit steigender Luftfeuchte klebrig. Vinylpyrrolidone mit Polyvinylacetatanteilen sind weniger hygroskopisch bei Raumtemperatur als nicht modifizierte Vinylpyrrolidone. Daher verkleben die beschichteten Einlagen nicht im aufgerollten Zustand. cold water soluble, but are highly hygroscopic and become sticky with increasing humidity. Vinylpyrrolidones with polyvinyl acetate moieties are less hygroscopic at room temperature than unmodified vinylpyrrolidones. Therefore, the coated deposits do not stick when rolled up.
Die Haftmasse könnte Polyole oder Polyglykole aufweisen. Durch einen Zusatz von Polyolen und/ oder Polyglykolen kann der Schmelzbereich eines Polymers, insbesondere der Vinylpyrrolidone, geändert, insbesondere gesenkt, werden bzw. der Schmelzfluss des Polymers den jeweiligen Anwendungen angepasst werden. Die wasserlösliche Haftmasse wird durch Polyglykole weichgemacht. Bevorzugt wird Polyethylenglykol (PEG) als Weichmacher verwendet. The adhesive composition could comprise polyols or polyglycols. By adding polyols and / or polyglycols, the melting range of a polymer, in particular the vinylpyrrolidones, can be changed, in particular lowered, or the melt flow of the polymer can be adapted to the respective applications. The water-soluble adhesive is softened by polyglycols. Polyethylene glycol (PEG) is preferably used as plasticizer.
Besonders bevorzugt wird PEG 400 in einer Konzentration von 0 - 20%, besonders bevorzugt in einer Konzentration von 2 - 10% verwendet. Particular preference is given to using PEG 400 in a concentration of 0-20%, particularly preferably in a concentration of 2-10%.
Des Weiteren könnten der Haftmasse 0 - 10 Gewichts% an Druckhilfsmitteln, wie Dispergatoren oder Verdicker, beigemengt sein. In addition, the adhesive mass could be admixed with 0-10% by weight of printing auxiliaries, such as dispersants or thickeners.
Das textile Trägermaterial könnte wasserlöslich sein. Hierdurch kann das Trägermaterial aufgelöst werden. The textile carrier material could be water-soluble. As a result, the carrier material can be dissolved.
Das textile Trägermaterial könnte aus Polyvinylalkohol gefertigt sein. Der Polyvinylalkohol des Trägermaterials könnte durch eine Ethoxylierung der Polymeren oder durch eine Verseifung mit einem Verseifungsgrad von mehr als 95 % modifiziert sein. Modifizierte Polyvinylalkohole lösen sich gut in kaltem Wasser, nämlich Wasser mit einer Temperatur von 10 bis 40° C. Insbesondere
könnte das textile Trägermaterial als Vliesstoff ausgestaltet sein. Der Vliesstoff könnte ein Flächengewicht von 20 bis 120 g/m2 aufweisen. The textile carrier material could be made of polyvinyl alcohol. The polyvinyl alcohol of the carrier material could be modified by ethoxylation of the polymers or by saponification with a degree of saponification greater than 95%. Modified polyvinyl alcohols dissolve well in cold water, namely water at a temperature of 10 to 40 ° C. In particular the textile carrier material could be designed as a nonwoven fabric. The nonwoven fabric could have a basis weight of 20 to 120 g / m 2 .
Sowohl das textile Trägermaterial als auch die Haftmasse könnten bei Both the textile carrier material and the adhesive composition could at
Temperaturen von 10 bis 40° C wasserlöslich sein. Temperatures of 10 to 40 ° C be water-soluble.
Die eingangs genannte Aufgabe wird auch durch eine Haftmasse zur The object mentioned above is also characterized by an adhesive mass
Beschichtung eines textilen Trägermaterials gelöst. Die genannte Haftmasse eignet sich auch zur Bedruckung von nicht Solved coating of a textile substrate. The adhesive mentioned is also suitable for printing on not
wasserlöslichen Trägermaterialien. Auch auf nicht wasserlöslichen, textilen Trägermaterialien ließen sich gut fixierbare Beschichtungen aus der genannten Haftmasse aufbringen, die sich nach der Verarbeitung leicht auswaschen ließen. Vor diesem Hintergrund könnte der Feststoffgehalt der Haftmasse geringer als 50 % sein. water-soluble carrier materials. Also on non-water-soluble, textile support materials could be applied well fixable coatings of said adhesive, which could be washed out easily after processing. Against this background, the solids content of the adhesive mass could be less than 50%.
Die hier beschriebenen Einlagen sind fixierbar, das heisst, sie können in einem thermischen Prozess mit textilen Oberstoffen beliebiger Art problemlos verbunden werden. Der thermische Prozess, nämlich die Fixierung oder Laminierung, wird bei Temperaturen von 80 bis 140° C durchgeführt. The deposits described here are fixable, that is, they can be easily connected in a thermal process with textile materials of any kind. The thermal process, namely fixation or lamination, is carried out at temperatures of 80 to 140 ° C.
Die hier beschriebenen Haftmassen sind bevorzugt für Einlagevliesstoffe, insbesondere für wasserlösliche Einlage- und/ oder Stickereivliesstoffe verwendbar. The adhesive compositions described here are preferably usable for nonwoven insert fabrics, in particular for water-soluble inlay and / or embroidery nonwovens.
Ein Verfahren zur Herstellung einer Einlage der hier beschriebenen Art könnte die folgenden Schritte umfassen: Bereitstellen eines textilen Trägermaterials und Beschichten des textilen Trägermaterials mit einer Haftmasse, welche eine wässrige Polymerdispersion und/ oder eine Polymerlösung aufweist. Hierdurch ist eine Einlage zunächst als Zwischenprodukt herstellbar, die mit einer
wässrigen Polymerdispersion und / oder einer Polymerlösung beschichtet ist. Dieses Zwischenprodukt verliert dann das Wasser der wässrigen A method of making a liner of the type described herein could include the steps of providing a textile substrate and coating the polymeric substrate with an adhesive comprising an aqueous polymer dispersion and / or a polymer solution. As a result, an insert is first produced as an intermediate, with a aqueous polymer dispersion and / or a polymer solution is coated. This intermediate then loses the water of the aqueous
Polymerdispersion und/ oder der Polymerlösung und wird zum Endprodukt, nämlich der hier beanspruchten Einlage. Polymer dispersion and / or the polymer solution and is the final product, namely the claimed here deposit.
Es gibt nun verschiedene Möglichkeiten, die Lehre der vorliegenden Erfindung in vorteilhafter Weise auszugestalten und weiter zu bilden. Dazu ist einerseits auf die nachgeordneten Ansprüche, andererseits auf die nachfolgende There are now various possibilities for embodying and further developing the teaching of the present invention in an advantageous manner. This is on the one hand to the subordinate claims, on the other hand, the following
Erläuterung bevorzugter Ausführungsbeispiele zu verweisen. To explain explanation of preferred embodiments.
In Verbindung mit der Erläuterung der bevorzugten Ausführungsbeispiele werden auch im Allgemeinen bevorzugte Ausgestaltungen und Weiterbildungen der Lehre erläutert. In connection with the explanation of the preferred embodiments, generally preferred embodiments and further developments of the teaching are also explained.
Ausführung der Erfindung Embodiment of the invention
In der nachfolgenden Tabelle 1 ist die Veränderung des Schmelzbereiches und des Schmelzflusses gezeigt. Table 1 below shows the change in melting range and melt flow.
Tabelle 1
Bevorzugt wird eine Mischung von Luvitec VA 64 mit 0 - 20% PEG 400, besonders bevorzugt 3 - 15% PEG 400, verwendet. Andere PEGs können ebenfalls verwendet werden. Ausführungsbeispiele Table 1 Preference is given to using a mixture of Luvitec VA 64 with 0-20% PEG 400, more preferably 3-15% PEG 400. Other PEGs can also be used. embodiments
Ausführungsbeispiel 1 : Embodiment 1
Ein wasserstrahlverfestigter Vliesstoff aus 100% Baumwolle mit einem A hydroentangled 100% cotton nonwoven fabric with a
Flächengewicht von 80 g/m2 wurde mit einer Haftmasse aus einer wässrigen Polymerdispersion mit einem Feststoffgehalt von 45% bedruckt. Basis weight of 80 g / m 2 was printed with an adhesive mass of an aqueous polymer dispersion having a solids content of 45%.
Die Polymerdispersion bestand aus 400 g/l Luvitec VA 64, 40 g/l PEG 400 und 5 g/l einer Mischung aus Dispergatoren, Verdickern sowie The polymer dispersion consisted of 400 g / l Luvitec VA 64, 40 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and
Pastenlaufhilfsmitteln. Paste run aids.
Die Bedruckung erfolgte mittels einer Rotationssiebdrucktechnik. Es wurde mit einer Druckschablone CP 110, was einer offenen Fläche von 20% entspricht, eine Beschichtung aus Haftmasse von 25 g/m2 aufgetragen. Die Trocknung erfolgte bei 145°C. The printing was carried out by means of a rotary screen printing technique. It was applied with a printing template CP 110, which corresponds to an open area of 20%, a coating of adhesive mass of 25 g / m 2 . The drying took place at 145.degree.
Ausführungsbeispiel 2: Embodiment 2:
Als Trägermaterial für eine Stickerei-Fixiereinlage wurde ein thermisch gebundener, aus kaltwasserlöslichen Polyvinylalkohol-(PVAL)-Stapelfasern hergestellter Vliesstoff mit einem Flächengewicht von ca. 40 g/m2 eingesetzt. The carrier material for an embroidery fixation insert was a thermally bonded nonwoven fabric produced from cold-water-soluble polyvinyl alcohol (PVAL) staple fibers having a weight per unit area of about 40 g / m 2 .
Die Polyvinylalkoholfasern-Stapelfasern wurden in einem Gel-Spinnverfahren hergestellt und wiesen eine Festigkeit von 4 g/denier auf. Dieser Vliesstoff wurde mit einer Haftmasse, nämlich einer Dispersion bzw. Lösung, mit 60% Feststoffgehalt bedruckt.
Die Haftmasse bestand aus 600 g/l Luvitec VA 64, 45 g/l PEG 400 und 5 g/l einer Mischung aus Dispergatoren, Verdickern und Pastenlaufhilfsmitteln. Die Bedruckung erfolgte mittels einer Rotationssiebdrucktechnik. Es wurde mit einer Druckschablone CP 52, was einer offenen Fläche von 15 % entspricht, eine Beschichtung aus Haftmasse von 15 g/m2 aufgetragen. Die Trocknung erfolgte bei 145°C. Das Bedrucken mit den genannten Haftmassen bereitete überraschend keine Probleme. Nach dem Trocknen war auch keine Verklebung der Lagen zu beobachten. The polyvinyl alcohol staple fibers were prepared in a gel spinning process and had a strength of 4 g / denier. This nonwoven fabric was printed with an adhesive mass, namely a dispersion or solution, with 60% solids content. The adhesive consisted of 600 g / l Luvitec VA 64, 45 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and paste flow aids. The printing was carried out by means of a rotary screen printing technique. A coating of adhesive mass of 15 g / m 2 was applied using a CP 52 printing stencil, which corresponds to an open area of 15%. The drying took place at 145.degree. The printing with the above adhesives prepared surprisingly no problems. After drying, no sticking of the layers was observed.
In der nachfolgenden Tabelle 2 sind Haftwerte dargestellt, die sich ergeben, wenn eine Einlage der hier beschriebenen Art mit einem Hemden-Popeline- Teststoff verbunden wird. In the following Table 2, adhesion values are shown which result when an insert of the type described here is connected to a shirt poplin test fabric.
Tabelle 2
Das in der Tabelle 2 genannte modifizierte (mod.) PA (Polyamid) entspricht dem Polyamid gemäß Beispiel 1 aus der DE 100 32 769 A1. VA steht für Vinylacetat, wobei das Produkte Luvitec VA 64 verwendet wird. PEG steht für Polyethylenglykol. Vorteile: Table 2 The modified (mod.) PA (polyamide) mentioned in table 2 corresponds to the polyamide according to example 1 from DE 100 32 769 A1. VA stands for vinyl acetate, using the product Luvitec VA 64. PEG stands for polyethylene glycol. Advantages:
Beim Ansintern von kaltwasserlöslichem Polymerpulver auf Co-Polyester-Basis (Typ Schättifix 699) waren die Sinterbedingungen mit mehr als 150°C an der Grenze des Schrumpfbeginns des Trägermaterials. Beim Ansintern trat ein starker Breitenverlust auf. When sintering cold-water-soluble polymer powder based on co-polyester (type Schättifix 699), the sintering conditions of more than 150 ° C. were at the limit of the shrinkage start of the support material. During sintering, a large width loss occurred.
Dies ist mit der erfindungsgemäßen Mischung und dem hier beschriebenen Verfahren nicht mehr problematisch. Trocknungstemperaturen von unter 150°C sind gut realisierbar. Das Ansintern aufgedruckter Punkte ist sehr gut. This is no longer problematic with the mixture according to the invention and the method described here. Drying temperatures of less than 150 ° C are easy to implement. The sintering of printed dots is very good.
Das aufwändige Verfahren, einen Spinnvliesstoff aus wasserlöslichen The elaborate process, a spunbonded fabric made of water-soluble
Polymeren separat zu erspinnen, und diese dann mit dem wasserlöslichen Vliesstoff zu laminieren, wird durch das hier beschriebene Verfahren wesentlich vereinfacht. Spinning polymers separately and then laminating them with the water-soluble nonwoven fabric is greatly simplified by the process described herein.
Man kann Polymermischungen der oben genannten Art auch You can also polymer blends of the above type
zusammenschmelzen. Hierbei tritt eine bräunliche Verfärbung auf. Diese Polymermischung kann als Hot-Melt oder im vermahlenen Zustand als fuse together. This causes a brownish discoloration. This polymer mixture can be used as a hot-melt or in the ground state as
Puderpunkt aufgetragen werden. Dieser zusätzliche Arbeitsgang verteuert das Verfahren, wobei die Verfärbung eine ungewünschte Zusatzeigenschaft darstellt. Powder point to be applied. This additional operation makes the process more expensive, the discoloration representing an undesired additional property.
Das hier beschriebene Verfahren ist einfach realisierbar, da die Komponenten zusammengerührt werden können. Nach einer Entlüftung entsteht eine leicht weißliche Dispersion oder eine klare Lösung. Mit 1 - 3% Verdicker aus modifizierter Zellulose kann die notwendige Viskosität der Mischung zum
Drucken eingestellt werden. Je nach Bedarf können noch weitere Druckhilfsmittel in geringen Mengen beigemengt werden. The method described here is easy to implement because the components can be stirred together. After venting creates a slightly whitish dispersion or a clear solution. With 1 - 3% modified cellulosic thickener, the necessary viscosity of the mixture can be achieved Print to be set. Depending on requirements, further printing auxiliaries can be added in small amounts.
Die druckfähige Haftmasse soll einen Feststoffgehalt von mehr als 50 % haben, um gut kaltwasserlösliche Trägermaterialien bedrucken zu können. The printable adhesive mass should have a solids content of more than 50% in order to print good cold water-soluble carrier materials can.
Feststoffgehälter von mehr als 75% liefern eine hochviskose Mischung, die nur relativ schwierig zum Drucken verwendet werden kann. Auf nicht wasserlösliche Trägermaterialien sind auch Mischungen mit niedrigeren Feststoffgehältern aufdruckbar. Solids greater than 75% provide a high viscosity blend that is relatively difficult to use for printing. It is also possible to print on mixtures with lower solids contents on non-water-soluble carrier materials.
Hinsichtlich weiterer vorteilhafter Ausgestaltungen und Weiterbildungen der erfindungsgemäßen Lehre wird einerseits auf den allgemeinen Teil der With regard to further advantageous embodiments and developments of the teaching of the invention is on the one hand to the general part of
Beschreibung und andererseits auf die beigefügten Patentansprüche Description and on the other hand to the appended claims
verwiesen. directed.
Abschließend sei ganz besonders hervorgehoben, dass die zuvor Finally, it should be emphasized that the previously
ausgewählten Ausführungsbeispiele lediglich zur Erörterung der selected embodiments only for the discussion of
erfindungsgemäßen Lehre dienen, diese jedoch nicht auf diese teachings of the invention, but these do not serve this
Ausführungsbeispiele einschränken.
Restricting embodiments.
Claims
Patentansprüche . Einlage zur Verwendung als Stickerei-Fixiereinlage, bestehend aus einem textilen Trägermaterial, welches mit einer Haftmasse beschichtet ist, wobei die Haftmasse ein wasserlösliches, thermoplastischesClaims. Insert for use as an embroidery fixation insert, consisting of a textile carrier material which is coated with an adhesive composition, wherein the adhesive composition is a water-soluble, thermoplastic
Polymer aufweist, dadurch gekennzeichnet, dass die Haftmasse als wässrige Polymerdispersion und/ oder als Polymerlösung ausgestaltet ist. Having polymer, characterized in that the adhesive composition is designed as an aqueous polymer dispersion and / or as a polymer solution.
2. Einlage nach Anspruch 1 , dadurch gekennzeichnet, dass die Haftmasse einen Feststoffgehalt von mehr als 50 % aufweist. 2. Insert according to claim 1, characterized in that the adhesive mass has a solids content of more than 50%.
3. Einlage nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Haftmasse Vinylpyrrolidon aufweist. 3. insert according to claim 1 or 2, characterized in that the adhesive composition comprises vinylpyrrolidone.
4. Einlage nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Haftmasse Polyole oder Polyglykole aufweist. 4. insert according to one of claims 1 to 3, characterized in that the adhesive composition comprises polyols or polyglycols.
5. Einlage nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das textile Trägermaterial wasserlöslich ist. 5. insert according to one of claims 1 to 4, characterized in that the textile carrier material is water-soluble.
6. Einlage nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das textile Trägermaterial aus Polyvinylalkohol gefertigt ist. 6. insert according to one of claims 1 to 5, characterized in that the textile carrier material is made of polyvinyl alcohol.
7. Einlage nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass sowohl das textile Trägermaterial als auch die Haftmasse bei7. insert according to one of claims 1 to 6, characterized in that both the textile carrier material and the adhesive mass at
Temperaturen on 10 bis 40° C wasserlöslich sind. Temperatures are soluble in water at 10 to 40 ° C.
8. Einlage nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das textile Trägermaterial als kaltwasserlöslicher Vliesstoff ausgestaltet ist. 8. insert according to one of claims 1 to 7, characterized in that the textile carrier material is configured as cold water-soluble nonwoven fabric.
9. Haftmasse zur Beschichtung eines eines textilen Trägermaterials zur Verwendung ein einer Einlage nach einem der voranstehenden 9. Adhesive composition for coating a textile support material for use of a liner according to one of the preceding
Ansprüche, umfassend eine wässrige Polymerdispersion und/ oder Polymerlösung. Claims comprising an aqueous polymer dispersion and / or polymer solution.
10. Haftmasse nach Anspruch 9, dadurch gekennzeichnet, dass der Feststoffgehalt geringer als 50 % ist. 10. Adhesive composition according to claim 9, characterized in that the solids content is less than 50%.
1 1. Verfahren zur Herstellung einer Einlage nach einem der 1 1. A method for producing an insert according to one of
Ansprüche 1 bis 8, umfassend die Schritte: Bereitstellen eines textilen Trägermaterials und Beschichten des textilen Trägermaterials mit einer Haftmasse, welche eine wässrige Polymerdispersion und/ oder eine Polymerlösung aufweist. Claims 1 to 8, comprising the steps of providing a textile support material and coating the textile support material with an adhesive which comprises an aqueous polymer dispersion and / or a polymer solution.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009049802A DE102009049802A1 (en) | 2009-10-16 | 2009-10-16 | Water-soluble adhesive coating for water-soluble interlinings |
PCT/EP2010/006206 WO2011045017A2 (en) | 2009-10-16 | 2010-10-12 | Water-soluble adhesive compound coating for water-soluble interlining materials |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2488691A2 true EP2488691A2 (en) | 2012-08-22 |
Family
ID=43733985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10771328A Withdrawn EP2488691A2 (en) | 2009-10-16 | 2010-10-12 | Water-soluble adhesive compound coating for water-soluble interlining materials |
Country Status (9)
Country | Link |
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EP (1) | EP2488691A2 (en) |
JP (1) | JP5625204B2 (en) |
KR (1) | KR101482948B1 (en) |
CN (1) | CN102575417B (en) |
AR (1) | AR078642A1 (en) |
BR (1) | BR112012008738A2 (en) |
DE (1) | DE102009049802A1 (en) |
TW (1) | TWI424110B (en) |
WO (1) | WO2011045017A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010046386A1 (en) * | 2010-09-24 | 2012-03-29 | Carl Freudenberg Kg | Thermally fixable interlining material and use |
CN104073999B (en) * | 2014-06-27 | 2016-04-06 | 昆山胜昱无纺布有限公司 | The composite of water-soluble fabric and water-soluble fabric streamline |
CN104074000B (en) * | 2014-06-27 | 2017-01-11 | 昆山胜昱无纺布有限公司 | Water-soluble fabric assembly line |
CN104088102A (en) * | 2014-07-02 | 2014-10-08 | 苏州市叶绣工艺厂 | Embroidery cloth suitable for public |
US20230002966A1 (en) * | 2021-06-30 | 2023-01-05 | CreateMe Technologies LLC | Stabilizer coating for machine embroidering |
Family Cites Families (12)
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US3961125A (en) * | 1972-12-18 | 1976-06-01 | Kurashiki Boseki Kabushiki Kaisha | Temporary interlining coated with foamed adhesive |
JPS5898464A (en) * | 1981-12-07 | 1983-06-11 | 日本バイリ−ン株式会社 | Production of base fabric for chemical lace |
JPS60162850A (en) * | 1984-01-30 | 1985-08-24 | 金井 宏之 | Water-soluble fiber sheet |
GB2188566A (en) * | 1986-04-02 | 1987-10-07 | Clark & Sons Ltd William | Interlining materials |
JPH03146759A (en) * | 1989-10-30 | 1991-06-21 | Reiko Co Ltd | Steric embroidery product and steric embroidering |
JP3128326B2 (en) * | 1992-05-11 | 2001-01-29 | 株式会社クラレ | Water-soluble sheet and method for producing the same |
DE69616550T2 (en) * | 1995-06-30 | 2002-04-11 | Kimberly-Clark Worldwide, Inc. | WATER-DISPERSIBLE, FIBROUS, COMPONENTLY COMPOSITE nonwovens |
JP2002539335A (en) * | 1999-08-26 | 2002-11-19 | シイベル・ヘグナー・アンド・カンパニー・リミテッド | Method of manufacturing embroidery products and carrier web for mechanical embroidery |
DE10032769C2 (en) | 2000-07-05 | 2003-12-04 | Freudenberg Carl Kg | Water soluble embroidery fixer and process for making it |
US6443081B1 (en) * | 2000-10-13 | 2002-09-03 | Laura J. Quint | Applique art kit assembly and method of creating an applique art object |
DE10344573A1 (en) * | 2002-10-01 | 2004-04-15 | Textilforschungsinstitut Thüringen-Vogtland e.V. | Embroidery process carried out on large industrial machines is for embroidering elastic textiles or non-textiles and requires no major adaptation of machinery |
CN101189386A (en) * | 2005-06-03 | 2008-05-28 | 可乐丽股份有限公司 | Ground fabric for masking for use in method of transfer piece dyeing of embroidered part |
-
2009
- 2009-10-16 DE DE102009049802A patent/DE102009049802A1/en not_active Withdrawn
-
2010
- 2010-10-12 KR KR20127012565A patent/KR101482948B1/en not_active IP Right Cessation
- 2010-10-12 CN CN201080043390.0A patent/CN102575417B/en not_active Expired - Fee Related
- 2010-10-12 EP EP10771328A patent/EP2488691A2/en not_active Withdrawn
- 2010-10-12 WO PCT/EP2010/006206 patent/WO2011045017A2/en active Application Filing
- 2010-10-12 JP JP2012533520A patent/JP5625204B2/en not_active Expired - Fee Related
- 2010-10-12 BR BR112012008738A patent/BR112012008738A2/en not_active IP Right Cessation
- 2010-10-14 AR ARP100103762 patent/AR078642A1/en unknown
- 2010-10-14 TW TW99135025A patent/TWI424110B/en not_active IP Right Cessation
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2011045017A2 * |
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BR112012008738A2 (en) | 2016-05-10 |
KR101482948B1 (en) | 2015-01-15 |
KR20120089724A (en) | 2012-08-13 |
JP2013507538A (en) | 2013-03-04 |
TW201120276A (en) | 2011-06-16 |
CN102575417B (en) | 2015-04-08 |
WO2011045017A3 (en) | 2011-07-14 |
AR078642A1 (en) | 2011-11-23 |
WO2011045017A2 (en) | 2011-04-21 |
DE102009049802A1 (en) | 2011-04-21 |
JP5625204B2 (en) | 2014-11-19 |
TWI424110B (en) | 2014-01-21 |
CN102575417A (en) | 2012-07-11 |
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