TW201031713A - The coloring composition for color filters and color filters - Google Patents

The coloring composition for color filters and color filters Download PDF

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Publication number
TW201031713A
TW201031713A TW099102653A TW99102653A TW201031713A TW 201031713 A TW201031713 A TW 201031713A TW 099102653 A TW099102653 A TW 099102653A TW 99102653 A TW99102653 A TW 99102653A TW 201031713 A TW201031713 A TW 201031713A
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Taiwan
Prior art keywords
group
color filter
acrylate
coloring composition
meth
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TW099102653A
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Chinese (zh)
Inventor
Mayumi Ogura
Shingo Ikeda
Takashi Nakamura
Mayuko Okamoto
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Toyo Ink Mfg Co
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Priority claimed from JP2009031880A external-priority patent/JP5540519B2/en
Priority claimed from JP2009281395A external-priority patent/JP2011123331A/en
Application filed by Toyo Ink Mfg Co filed Critical Toyo Ink Mfg Co
Publication of TW201031713A publication Critical patent/TW201031713A/en

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/201—Filters in the form of arrays
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/23—Photochromic filters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optical Filters (AREA)
  • Materials For Photolithography (AREA)

Abstract

The coloring composition for color filters in the present invention includes a maleic anhydride, a copolymer (A) of at least one kind of ethylene unsaturated monomer other than maleic anhydride, a pigment (B), a resin adhesive and a monomer for active energy linear polymerization or a monomer for thermal polymerization.

Description

201031713 六、發明說明： 【發明所屬之技術領域】 t0001]本發明係關於一種彩色濾光片用著色組成物，其係用在 形成彩色液晶顯示裝置及固體攝像裝置所用之彩色滅光 片；以及關於一種利用該彩色濾先片用著色組成物所獲 得的彩色濾光片》 【先前技術】 [0002]201031713 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a coloring composition for a color filter which is used for forming a color liquid crystal display device and a color extinction film for use in a solid-state imaging device; A color filter obtained by using the colored composition for color filter sheets [Prior Art] [0002]

液晶顯示裝置係由2片偏光板夾住之液晶層控制通過第一 片偏光板的光之偏光程度，並控制通過第二片偏光板之 光量’藉此來進行顯不之顧示裝置β藉由於該2片偏光板 ，由於彩 此對於彩 間設置彩色濾光片而可進行.彩:色類示。近年麥 色液晶顯示裝置使用於電視或個人電jjii，因 色遽光片，南亮度化'，高對比也4 求·升‘。 彩色溏光器係由在玻璃.等透明基板或配置有薄膜電晶體 (TFT)之驅動用基板上，胃直接参中介氮巧矽膜等鈍化膜 ，平行或交叉配置有2種以細帶（條紋） 狀之濾光片區段者所組成排列配置有微 細的遽光片區段者所組成。段之寬度係微細至 數微米〜數百微米，而且依各色相而以特定排列整齊地 配置。 使用於此類液晶顯示裝置的液晶，容易受到内建於液晶 顯示裝置之彩色濾光片等零件之電性質影響，彩色濾光 片之電性質使得因液晶污染所造成的液晶配向紊亂產生 ，亦或對切換性能造成不良影響，可能引起顯示故障。 為了解決此類問題’對於構成彩色濾光片之著色層（濾 光片區段）要求絕緣性’須增加膜厚以提高絕緣性，或 表單編號Α0101 第3頁/共76頁 201031713 須形成低介電率之著色膜。為了解決此類課題，已 將Green (綠）像素之色層疊層有覆膜層之兩層之介寸 切，設定在特定範圍的方法等（參考專利文獻丨）。正 其中尤以下述方式最近備受矚目，即於配置有薄犋曰 體（TFT)之驅動用基板上，直接或中介氮化矽犋==曰化 膜形成濾光片區段，黏合形成有該濾光片區段之式板 與藉由蒸鍍或濺鍍形成有用以驅動液晶之透明電極之基 板的方式（參考專利文獻2)。於該方式中，由於在配置 有薄膜電晶體（TFT)之驅動用基板上形成濾光片區段， 因此畫素口徑比（開口率）大幅增加，雖可達成高亮声 及低耗電，但另一方面，其構造上易受到彩色濾光片之 電性質所影響。 , 作為解決此類問題的方法/已·揭'示有利用’特定起始劑的 方法等（參考專利文獻3)，但在現狀下並未充分改善彩 色濾光片之電性質所造成的影響。 〔先行技術文獻〕 iriieiiectUQ! 參 〔專利文獻〕 . 〔專利文獻1〕曰本特開2(^4^1^^537號公報 〔專利文獻2〕日本特開2004-94263號公報 〔專利文獻3〕日本特開2001-32461 1號公報 【發明内容】 [0003] 本發明之目的在於提供一種可形成不會引起液晶配向紊 亂、或對切換桂能造成不良影響之彩色濾光片之彩色濾 光片用著色組成物，及彩色濾光片。 [0004] 若依據本發明，前述目的可藉由一種彩色濾光片用著色 表單編號A0101 第4頁/共76頁 組成物來解決，其特徵在於含有：順丁烯二酸酐與順丁 烯二酸酐以外之1種以上的乙烯性不飽和單體之共聚物（ A);顏料；樹脂黏結劑（B);及聚合性單體，其係選 自由活性能量線聚合性單體或熱聚合性單體所組成的群 組。 於本發明之一個態樣中，前述聚合性單體為活性能量線 聚合性單體；前述著色組成物進一步含有活性能量線聚 合起始劑。 又，於本發明之一個態樣中，前述順丁烯二酸酐以外之1 種以上的乙烯性不飽和單體係選自由苯乙烯、α—曱基 苯乙烯及茚所組成的群組中之單體。 又，於本發明之一個態樣中，前述樹脂黏結劑（Β)含有 鹼可溶性樹脂。 進一步於本發明之一個態樣中，前述鹼可溶性樹脂具有 羥基。 又，於本發明之一個態樣中，前述共聚物（Α)與樹脂黏 結劑（Β)之重量比（A) : (Β)在5 : 95〜70: 30之範 圍内。 進一步於本發明之一個態樣中，前述共聚物（Α)之含有 量係以彩色濾光片用著色組成物中之固體部分重量作基 準而為10〜20重量％。 又，於本發明之一個態樣中，活性能量線聚合起始劑係 以一般式（1)所示之锍（sulfonium)有機棚錯合物或氧 銃（oxosulfonium)有機领錯合物。 一般式（1 ): 表單編號A0101 第5頁/共76頁 201031713 [0005] 鼸13 d14_<%ί_·12 V— 1¾ 〇 1¾ (於一般式（1)中，R11、R12及R13係分別獨立地表示選 自由亦可具有置換基之烷基、亦可具有置換基之芳香基 、亦可具有置換基之芳烷基、亦可具有置換基之烯基、 亦可具有置換基之炔基、亦可具冇置換基之脂環基、亦 可具有置換基之烷氧基、亦可具有置換基之烯丙氧基、 亦可具有置換基之烷基硫代基及亦可具有置換基之胺基 所組成的群組中之基，R14係表示氧原子或孤立電子對。 其中亦可具有置換基之芳香基係僅止於R11、R12及R13中 的1個）。 又，於本發明之一個態樣中，一般式（1)中之x_係以下 述一般式（2 )所示之硼酸鹽。 一般式（2): 表單編號A0101 第6頁/共76頁 201031713 [0006]The liquid crystal display device controls the degree of polarization of the light passing through the first polarizing plate by the liquid crystal layer sandwiched by the two polarizing plates, and controls the amount of light passing through the second polarizing plate to thereby display the display device. Since the two polarizing plates are provided for coloring the color filter, the color: color display can be performed. In recent years, the color liquid crystal display device has been used in televisions or personal electric jjii, because of the color-lighting film, the south brightness is ', and the high contrast is also 4. The color chopper is provided on a transparent substrate such as glass or a driving substrate on which a thin film transistor (TFT) is disposed, and a passive film such as a nitride film is directly applied to the stomach, and two kinds of thin bands are arranged in parallel or in cross ( The stripe-shaped filter segments are composed of a group of fine pupils arranged in a row. The width of the segments is as fine as several micrometers to several hundreds of micrometers, and is arranged neatly in a specific arrangement depending on the respective hue. The liquid crystal used in such a liquid crystal display device is easily affected by the electrical properties of components such as color filters built in the liquid crystal display device, and the electrical properties of the color filter cause liquid crystal alignment disorder caused by liquid crystal contamination. Or it may adversely affect the switching performance and may cause display failure. In order to solve such problems, 'insulation is required for the color layer (filter section) constituting the color filter', the film thickness must be increased to improve the insulation, or the form number Α0101 Page 3 / 76 pages 201031713 must be formed low The color film of the dielectric. In order to solve such a problem, a green layer of a green (green) pixel layer has a layer of two layers of a coating layer, and a method of setting it in a specific range (refer to Patent Document 丨). Among them, the following has been attracting attention recently, that is, on a driving substrate on which a thin germanium (TFT) is disposed, a direct or intermediate tantalum nitride == bismuth film is formed to form a filter segment, and a bond is formed. The template of the filter segment and a substrate for forming a transparent electrode for driving liquid crystal by vapor deposition or sputtering (refer to Patent Document 2). In this aspect, since the filter segment is formed on the driving substrate on which the thin film transistor (TFT) is disposed, the aperture ratio (opening ratio) of the pixel is greatly increased, and although highlight sound and low power consumption can be achieved, another On the one hand, it is structurally susceptible to the electrical properties of the color filter. As a method for solving such a problem, a method of using a specific initiator is described (refer to Patent Document 3), but the influence of the electrical properties of the color filter is not sufficiently improved in the current situation. . [Prior Art Document] iriieiiectUQ! [Patent Document] [Patent Document 1] 曰本特开 2 (Patent Document 2) [Patent Document 2] JP-A-2004-94263 (Patent Document 3) 】 JP-A-2001-32461 No. 1 SUMMARY OF THE INVENTION [0003] It is an object of the present invention to provide a color filter that can form a color filter that does not cause disorder of liquid crystal alignment or adversely affects switching energy. The coloring composition for a sheet, and a color filter. According to the present invention, the foregoing object can be solved by a color filter using a coloring form number A0101, page 4 / page 76 composition, characterized in that a copolymer (A) comprising: maleic anhydride and one or more ethylenically unsaturated monomers other than maleic anhydride; a pigment; a resin binder (B); and a polymerizable monomer, which is selected A group consisting of a free active energy ray polymerizable monomer or a thermally polymerizable monomer. In one aspect of the invention, the polymerizable monomer is an active energy ray polymerizable monomer; and the coloring composition further contains an active agent Energy line aggregation Further, in one aspect of the invention, the one or more ethylenically unsaturated monosystems other than the maleic anhydride are selected from the group consisting of styrene, α-mercaptostyrene, and hydrazine. Further, in one aspect of the invention, the resin binder (Β) contains an alkali-soluble resin. Further, in one aspect of the invention, the alkali-soluble resin has a hydroxyl group. In one aspect, the weight ratio (A) of the copolymer (Α) to the resin binder (Β): (Β) is in the range of 5: 95 to 70: 30. Further in one aspect of the invention The content of the copolymer (Α) is 10 to 20% by weight based on the weight of the solid portion in the coloring composition for a color filter. Further, in one aspect of the present invention, active energy ray polymerization The initiator is a sulfonium organic shed complex or an oxosulfonium organic collar complex represented by the general formula (1). General formula (1): Form No. A0101 Page 5 of 76 201031713 [0005] 鼸13 d14_<%ί_·12 V— 13⁄4 〇13⁄4 (in one In the formula (1), R11, R12 and R13 each independently represent an arylalkyl group which may be an alkyl group which may have a substituent group, may have a substituent group, or may have a substituent group, or may have a substitution. The alkenyl group may have an alkynyl group having a substituent group, an alicyclic group which may have a hydrazine substituent group, an alkoxy group which may have a substituent group, an allyloxy group which may have a substituent group, or may have a substitution The group in the group consisting of an alkylthio group and an amine group which may also have a substituent group, and R14 represents an oxygen atom or an isolated electron pair. Among them, the aromatic group having a substituent group may be only one of R11, R12 and R13. Further, in one aspect of the invention, the x_ in the general formula (1) is a borate represented by the general formula (2). General formula (2): Form number A0101 Page 6 of 76 201031713 [0006]

[0007] 於一般式（2)中，R21、R22、R23及R24係分別獨立地表 示選自由亦可具有置換基之烷基、亦可具有置換基之芳 香基、亦可具有置換基之芳烷基、亦可具有置換基之烯 基、亦可具有置換基之炔基所組成的群組中之基，R21、 R22、R23及R24並非全部具有置換基亦可，而不同時為芳 香基。 又，於本發明之一個態樣中，本發明之著色組成物含有 溶劑，而溶劑含有環己基乙酯（cyclohexylethyl acetate ) ° 進一步於本發明之一個態#卩ί 1•明之著色組成物含 有第3級膦化合物。 又，於本發明之一個態樣中，前述第3級膦化合物為三苯 膦。 又，於本發明之一個態樣中，本發明之著色組成物進一 步作為分散劑而含有聚酯分散劑，其係在分子内具有2個 羥基及1個硫醇基之化合物的存在下，將乙烯性不飽和單 體進行自由基聚合而生成，並令單一末端區域具有2個羥 表單編號Α0101 第7頁/共76頁 201031713 基之乙烯基共聚物中之羥基與四羧酸二酐中之酸酐基反 應而成。 又/於本發明之一個態樣中，前述四羧酸二酐含有芳香 族四叛酸二酐。 進一步又於本發明之一個態樣中，本發明之著色組成物 作為上述活性能量線聚合性單體或熱聚合性單體而含有1 種或2種以上選自由三聚氣胺化合物、苯并脈胺（benzo-guanamine)、環氧化合物、氧雜環丁烧化合物、苯盼 化合物、苯并噁嗪化合物、嵌段化羧酸化合物、嵌段化 異氰酸酯化合物、丙烯酸酯系單體及矽烷耦合劑所組成 的群組中之化合物，並採噴墨方式而使用。 若依據本發明之第2側面而提供一種彩色濾光片，其特徵 在於具備濾光片區段，其係利用本發明之彩色濾光片用 著色組成物而形成。 若依據本發明之第3侧面而提供一種彩色濾光片，其特徵 在於至少具備1個濾光片區段，其係利用本發明之彩色濾 光片用著色組成物而形成於薄膜電晶體（TFT)方式之彩 色液晶顯示裝置之驅動用基板上》 於本發明中可組合2個或其以上的態樣。 [0008] 利用本發明之彩色濾光片用著色組成物所形成的著色層 (濾光片區段），係顯示出低介電率特性，介電正切亦 小，因此可提供不易對液晶造成不良影響之彩色濾光片 【實施方式】 [0009] 首先，詳細說明關於本發明之彩色濾光片用著色組成物 表單編號A0101 第8頁/共76頁 201031713 本發明之彩色濾光片用著色組成物含有：順丁烯二酸酐 與順丁烯二酸酐以外之1種以上的乙烯性不飽和單體之共 聚物（A);顏料；樹脂黏結劑（B);及聚合性單體， 其係選自由活性能量線聚合性單體或熱聚合性單體所組 成的群組。 而且，於本發明中，標示為「（甲基）丙烯醯」、「（ 曱基）丙烯基」、「（曱基）丙烯酸」、「（甲基）丙 0 烯酸酯」、「（甲基）丙烯醯氧」或「（甲基）丙烯醯 胺」時’只要無特別說明，均分別表示「丙烯醯及/或甲 基丙烯醯」、「丙烯基及/或、甲基丙烯基」、「丙締酸及 /或甲基丙烯酸」、「丙烯酸酯及/或〖甲基两烯酸酯」、 「丙烯醯氧及/或曱基丙烤醯氧」或r丙稀·醯胺及/或甲 基丙稀醯胺」。 [順T稀二酸酐與順丁缔二酸酐以外之1種以上的乙稀性 不飽和單體之共聚物（Α) ]Γ € ：： ；ί φ 作為順丁#二酸酐以外之%求飽和單體可舉出例如 . . ϊ 1 m =#% ： 11«^« 甲基（甲基）丙稀酸醋、I乙基（甲基）丙浠酸醋、丙基 (甲基）丙烯酸酯、異丙基（甲基）丙烯酸酯、丁基（ 曱基）丙烯酸酯、異丁基（曱基）丙烯酸酯、t_丁基（ 甲基）丙烯酸酯、異戊基（甲基）丙烯酸酯、辛基（曱 基）丙烯酸酯、異辛基（甲基）丙烯酸酯、2一乙基己基 (曱基）丙稀酸酯、十六炫基（甲基）丙歸酸酯、癸基 (甲基）丙稀酸醋、異癸基（甲基）丙稀酸月桂基 (甲基）丙婦酸酯、十三（甲基）丙稀酸酯、異肉豆蔻 表單編珑A0101 第9頁/共76頁 201031713 基（甲基）丙稀酸酯、硬酯醯（曱基）丙烤酸酯或硬酯 酿（曱基）丙烯酸酯等直鏈狀或分枝狀烷基（甲基）丙 烯酸酯類； 環己基（甲基）丙烯酸酯、t一丁基環己基（甲基）丙缚 酸醋、二環戊基（甲基）丙烯酸醋、二環五氧乙基（甲 基）丙烯酸酯、二環戊稀基（甲基）丙烯酸酯、二環戊 烯氡乙基（曱基）丙稀酸酯或異冰片基（甲基）丙稀酸 酯等環狀烷基（曱基）丙烯酸酯類； 二氟乙基（甲基）丙烯酸酯、辛氟戊基（甲基）丙稀酸 醋、全氟辛基乙基（甲基）丙浠酸酯或四氟丙基（甲基 )丙烯酸酯等氟烷基（甲基）丙烯醆_類、，〔甲基）丙 烯醯氧改性聚二曱基碎氧院（石夕高分子單體）類； • if 齋.靈智 ' 四氫糠，基_ C甲基）丙缔酸醋或方二甲“基氧雜環丁基 (甲基）丙烯酸酯等具有雜環之（甲基）丙烯酸酯類； 苄基（甲基）丙烯酸酯、苯氧乙基（甲基）丙烯酸酯、 苯氧基聚乙二醇（甲基）丙难醭_、對葙基苯氧乙基（ 甲基）丙烯酸酯、對枯基苯氧秦聚乙二醇（甲基）丙烯 酸酯或壬基笨氧基聚乙二醇<甲基）丙烯酸酯等具有芳 香族環之（甲基）丙烯酸酯類； 2 —甲氧基乙基（曱基）丙烯酸酯、2_乙氧基（甲基） 丙稀酸醋、3—曱氧基丁基（甲基）丙烯酸醋、2-甲氧 基丙基（甲基）丙稀酸酿、二乙二醇單甲基謎（甲基） 丙烯酸酯、二乙二醇單乙基醚（甲基）丙烯酸酯、三乙 二醇單甲基鍵（甲基）丙烯酸酯、三乙二醇單乙基醚（ 甲基）丙烯酸酯、二乙二醇單—2_乙基己基醚（甲基） 丙烯酸葡、二乙二醇單甲基醚（曱基）丙烯酸酯、三丙 表單編號A0101 第1〇頁/共76頁 二醇單（甲基）丙稀酸醋、聚乙二醇單月桂基謎（甲基 )丙烯酸酯或聚乙二醇單硬酯基醚（曱基）丙烯酸醋等 (聚）烯烴基二醇單烷基醚（甲基）丙烯酸酯類； (甲基）丙稀酸、丙稀酸二聚物、衣康酸、順丁婦二酸 、富馬酸、巴豆酸、2—(甲基）丙歸醯氧敌酸乙酯、2 -(甲基）丙烯醯氧酞酸丙酯、2—(甲基）丙烯醯氡醜 酸六氫乙酯、2—(甲基）丙烯醯氧酞酸六氫丙酯、環氧 乙烷改性琥珀酸（甲基）丙烯酸酯、沒一羧基乙基（甲 基）丙烯酸酯或ω—竣基己内酯（甲基）丙煉酸酯等具 有羧基之（甲基）丙烯後酯類； 2—羥基乙基（甲基）丙燦酸凿、2—羥基丙基（曱基） 丙烯酸酯、2 —輕基丁基（甲棊）丙烯酸ύΐί、·1 一羥基丁 ...... 基（甲基）丙烯酸酯、2—有烯酿氧么基二2 —羥基乙基 (甲基）丙烯酸酯、二乙二醇單（甲基）丙烯酸酯、二 丙二醇單（甲基）两(烯酸酯、聚乙二醇單（甲基）丙婦 酸酯、丙二醇單（甲基）4瞒醇單（曱基 )丙烯酸酯、聚伸丁二醇稀酸酯、聚（乙 .. '1 f f · — 二醇一丁二醇）單（曱基y·丙#酸%1、聚（乙二醇〜伸 丁二醇）單（甲基）丙烯酸酯、·聚（丙二醇一伸丁二醇 )單（曱基）丙烯酸酯或丙三醇（甲基）丙烯酸酯等具 有羥基之（甲基）丙烯酸酯類； 苯乙烯、α—甲基苯乙烯、茚、乙醢伸萘基、二乙烯基 苯或雙苯環丁烯等具有芳香族環之烯烴類； 醋酸乙烯及丙酸乙烯等脂肪酸乙烯類； 乙基乙烯醚、η~丙基乙烯醚、異丙基乙烯醚、η—丁基 乙烯醚及異丁基乙烯醚等乙烯醚類； 表單編號Α0101 第11頁/共76頁 201031713 2 —經基乙基乙稀謎、2 —(或3 —)輕基丙基乙稀鍵、或 2_ (或3 —或4 —)經基丁基乙稀鍵等具有輕基之乙稀謎 系類、2 —羥基乙基烯丙醚、2—（或3 —）羥基丙基烯丙 謎、或2 _ (或3 —或4 一）經基丁基稀丙鍵等具有經基之 烯丙趟類； (甲基）丙烯醯胺、N，N —二甲基（甲基）丙烯醯胺、 N，N —二乙基（甲基）丙烯醯胺、N —異丙基（甲基）丙 烯醯胺、二丙酮醇（曱基）丙烯醯胺或丙烯醯嗎啉等（ 甲基）丙烯醯胺類； N— (2 —羥基乙基）（甲基）丙烯酸醯、N— (2 —羥基 丙基）（曱基）丙烯酸醯、N— (2—羥基丁基）或（曱 基）丙烯醯胺等具有羥基之（甲基）丙烯醯胺類； N，N —二甲基胺乙基（甲基）丙烯酸酯、N，N —二乙基 胺乙基（曱基）丙烯酸酯、N，N —二曱基胺丙基（曱基 )丙烯酸酯、N，N —二乙基胺丙基（曱基）丙烯酸酯等 具有N，N —二烷基胺基之烷基（甲基）丙烯酸酯類；或 者 N，N-二甲基胺乙基（曱基）丙烯醯胺、N，N —二乙基 胺乙基（曱基）丙烯醯胺、N，N —二曱基胺丙基（甲基 )丙烯醯胺、N，N—二乙基胺丙基（甲基）丙烯醯胺等 具有N，N-二烷基胺基之（甲基）丙烯醯胺類等； 該等可單獨或混合2種以上來使用，但未必要限定於該等 〇 該等之中，尤以順丁烯二酸酐、與選自由苯乙烯、 甲基苯乙烯及茚所組成的群組中具有苯環之烯烴之共聚 物，由於具有如下述一般式（3)所示之極性極小的重複 表單編號Α0101 第12頁/共76頁 201031713 單位，因此介電率低、從電特性的觀點來看較為適宜。 一般式（3): [0010] „ Η ^ * Η —c---c-C~-€— 參In the general formula (2), R21, R22, R23 and R24 each independently represent an aromatic group which may also have an alkyl group which may have a substituent group, may also have a substituent group, or may have a substituent group. a group of an alkyl group, an alkenyl group which may have a substituent group, or an alkynyl group which may have a substituent group, and R21, R22, R23 and R24 may not all have a substituent group, and may not be an aromatic group at the same time. . Further, in one aspect of the invention, the coloring composition of the present invention contains a solvent, and the solvent contains cyclohexylethyl acetate. Further, in one aspect of the present invention, the colored composition contains the first Grade 3 phosphine compound. Further, in one aspect of the invention, the third-stage phosphine compound is triphenylphosphine. Further, in one aspect of the present invention, the colored composition of the present invention further contains, as a dispersing agent, a polyester dispersing agent in the presence of a compound having two hydroxyl groups and one thiol group in the molecule. The ethylenically unsaturated monomer is formed by radical polymerization, and the single terminal region has two hydroxyl form numbers, Α0101, page 7/76, 201031713, the hydroxyl group in the vinyl copolymer and the tetracarboxylic dianhydride. The anhydride group is reacted. Still further, in one aspect of the invention, the tetracarboxylic dianhydride comprises an aromatic tetrahedonic dianhydride. Furthermore, in one aspect of the present invention, the coloring composition of the present invention contains one or more selected from the group consisting of a trimeric gas amine compound and a benzoic acid as the active energy ray-polymerizable monomer or the thermally polymerizable monomer. Benzene-guanamine, epoxy compound, oxetane compound, benzene-promoting compound, benzoxazine compound, block carboxylic acid compound, blocked isocyanate compound, acrylate monomer, and decane coupling The compound in the group consisting of the agents is used by an inkjet method. According to a second aspect of the present invention, there is provided a color filter comprising a filter segment formed by using a coloring composition for a color filter of the present invention. According to a third aspect of the present invention, there is provided a color filter comprising at least one filter segment formed on a thin film transistor by using a coloring composition for a color filter of the present invention ( In the present invention, two or more aspects can be combined. [0008] The coloring layer (filter segment) formed by the coloring composition for a color filter of the present invention exhibits a low dielectric constant property and a small dielectric tangent, thereby providing a liquid crystal barrier Color filter for adverse effect [Embodiment] First, the coloring composition for color filter of the present invention is shown in detail. Form No. A0101, page 8 / page 76, 201031713 Coloring for color filters of the present invention The composition contains a copolymer (A) of one or more kinds of ethylenically unsaturated monomers other than maleic anhydride and maleic anhydride; a pigment; a resin binder (B); and a polymerizable monomer. It is selected from the group consisting of active energy ray polymerizable monomers or thermally polymerizable monomers. Further, in the present invention, it is indicated as "(meth)acrylofluorene", "(indenyl)propenyl", "(indenyl)acrylic acid", "(methyl)propionate", "(A) In the case of "acryloyloxy" or "(meth)acrylamide", unless otherwise specified, "acrylonitrile and/or methacryl", "propylene" and/or methacryl", respectively, are indicated. , "Propanic acid and / or methacrylic acid", "Acrylate and / or methyl methacrylate", "acrylic oxygen and / or mercapto propylene oxide" or r propylene amide and / or methyl propyl amide. [Copolymer of one or more ethylenically unsaturated monomers other than cis T dibasic anhydride and cis succinic anhydride] Γ € :: ; ί φ is saturated as % other than cis dianhydride The monomer may, for example, be . . ϊ 1 m =#% : 11«^« methyl (meth) acrylate vinegar, I ethyl (methyl) propyl citrate, propyl (meth) acrylate , isopropyl (meth) acrylate, butyl (decyl) acrylate, isobutyl (meth) acrylate, t butyl (meth) acrylate, isoamyl (meth) acrylate , octyl (decyl) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (mercapto) acrylate, hexadecyl (methyl) propyl acrylate, sulfhydryl ( Methyl) acrylate vinegar, isodecyl (meth) acrylate, lauryl (methyl) propionate, tris(methyl) acrylate, isoform, form A0101, page 9 / Total 76 pages 201031713 Base (methyl) acrylate, stearyl sulfonate or steryl aryl (meth) acrylate or other linear or branched alkyl (methyl) Acrylates; ring Base (meth) acrylate, t-butylcyclohexyl (methyl) acrylate vinegar, dicyclopentyl (meth) acrylate, dicyclopentaethoxyethyl (meth) acrylate, dicyclopentan a cyclic alkyl (fluorenyl) acrylate such as a dilute (meth) acrylate, a dicyclopentene oxime ethyl (fluorenyl) acrylate or an isobornyl (meth) acrylate; Fluorine such as fluoroethyl (meth) acrylate, octylfluoropentyl (meth) acrylate vinegar, perfluorooctyl ethyl (methyl) propyl phthalate or tetrafluoro propyl (meth) acrylate Alkyl (meth) propylene hydrazine _,, [meth) propylene oxime modified polydiphenyl methicone (Shixi polymer monomer); • if 斋. Lingzhi 'tetrahydro hydrazine, based _ C methyl) propionic acid vinegar or dimethyl dimethyl oxetanyl (meth) acrylate and other heterocyclic (meth) acrylates; benzyl (meth) acrylate, phenoxy Ethyl (meth) acrylate, phenoxy polyethylene glycol (methyl) propylene difficult 醭, p-nonyl phenoxyethyl (meth) acrylate, p-cumyl phenoxy phthalate ( methyl) (meth) acrylate having an aromatic ring such as acrylate or decyloxy polyethylene glycol <meth) acrylate; 2-methoxyethyl (fluorenyl) acrylate, 2_B Oxy (meth) acrylate vinegar, 3-methoxy butyl (meth) acrylate vinegar, 2-methoxy propyl (methyl) acrylate acid, diethylene glycol monomethyl mystery ( Methyl) acrylate, diethylene glycol monoethyl ether (meth) acrylate, triethylene glycol monomethyl bond (meth) acrylate, triethylene glycol monoethyl ether (meth) acrylate , diethylene glycol mono-2-ethylhexyl ether (methyl) acrylate, diethylene glycol monomethyl ether (mercapto) acrylate, tripropylene form number A0101, page 1 / total 76 diol Mono(meth)acrylic acid vinegar, polyethylene glycol monolaurin (meth) acrylate or polyethylene glycol monostearyl ether (mercapto) acrylic acid vinegar (poly) olefinic diol monoalkane Ether (meth) acrylates; (methyl) acrylic acid, acrylic acid dimer, itaconic acid, cis-butanic acid, fumaric acid, crotonic acid, 2-(methyl) propyl Oxygen Ethyl phthalate, 2-(methyl) propylene decanoate, 2-(meth) propylene hexahydroethyl hexahydroethyl ester, 2-(methyl) propylene hexahydro hexanoate Ethylene oxide modified succinic acid (meth) acrylate, no carboxyethyl (meth) acrylate or ω-mercaptocaprolactone (methyl) propyl sulphate, etc. ) post-propylene esters; 2-hydroxyethyl (methyl) propionic acid chisel, 2-hydroxypropyl (fluorenyl) acrylate, 2-light butyl (meth) acrylate, 1 1 hydroxy butyl ...... base (meth) acrylate, 2- olefinic oxyalkyl bis 2-hydroxyethyl (meth) acrylate, diethylene glycol mono (meth) acrylate, dipropylene glycol single (Methyl) bis (enoate, polyethylene glycol mono (methyl) propionate, propylene glycol mono (methyl) 4 decyl mono (decyl) acrylate, polybutane diol diester, Poly (B.. '1 ff · - diol monobutylene glycol) mono (fluorenyl y · propylene # acid % 1, poly (ethylene glycol ~ butylene glycol) mono (meth) acrylate, · poly (propylene glycol-butanediol) single (曱a (meth) acrylate having a hydroxyl group such as acrylate or glycerol (meth) acrylate; styrene, α-methyl styrene, anthracene, acetamidine, divinylbenzene or diphenyl An olefin having an aromatic ring such as cyclobutene; a fatty acid such as vinyl acetate or vinyl propionate; ethyl vinyl ether, η-propyl vinyl ether, isopropyl vinyl ether, η-butyl vinyl ether and isobutylene Vinyl ethers such as vinyl ethers; Form No. Α0101 Page 11 of 76 201031713 2 — via ethyl ethyl ethane, 2 — (or 3 —) light propyl ethyl bond, or 2_ (or 3 — Or 4 -) a butyl group with a light base such as a butyl group, a 2-hydroxyethyl allyl ether, a 2-(or 3-) hydroxypropyl ally, or a 2 _ (or 3 — or 4 — a allylic fluorene having a benzyl group such as a butyl propyl group; (meth) acrylamide, N, N dimethyl methacrylate, N, N — Diethyl (meth) acrylamide, N-isopropyl (meth) acrylamide, diacetone alcohol (mercapto) acrylamide or propylene morpholine (methyl) acrylamide N-(2-hydroxyethyl)(meth)acrylic acid, N-(2-hydroxypropyl)(fluorenyl)acrylic acid, N-(2-hydroxybutyl) or (fluorenyl)acrylamide And other (meth) acrylamides having a hydroxyl group; N,N-dimethylaminoethyl (meth) acrylate, N,N-diethylaminoethyl (decyl) acrylate, N, N - an alkyl (meth) acrylate having an N,N-dialkylamino group such as dimercaptopropyl propyl (decyl) acrylate or N,N-diethylaminopropyl propyl (decyl) acrylate Or N,N-dimethylaminoethyl(decyl)propenylamine, N,N-diethylaminoethyl(decyl)propenylamine, N,N-didecylaminopropyl ( (meth) acrylamide, etc. having N,N-dialkylamino group, such as methacrylamide, N,N-diethylaminopropyl (meth) acrylamide, etc.; Or a mixture of two or more types, but it is not necessarily limited to the ones, and the maleic anhydride, and a group selected from the group consisting of styrene, methyl styrene, and hydrazine have a benzene ring. Total olefin Since the polymer has a repeating form number Α0101, page 12/76, 201031713, which is extremely small in polarity as shown in the following general formula (3), the dielectric constant is low and is preferable from the viewpoint of electrical characteristics. General formula (3): [0010] „ Η ^ * Η —c---c-C~-€—

[0011] 於一般式（3) ，R41為氫原子或_CH,，R42及R43分別為 i 氫原子，或R42與R43相互結合而表示一ΓΠ.,_。 與乙烯性不飽和單體共聚之順丁烯二酸酐由於具有酸酐 ，因此藉由與樹脂黏結劑併用，可形成塗膜硬化性及顯 影性良好的彩色濾光片用著色組成物。 該順丁烯二酸酐與順丁烯二酸酐以外之1種以上的乙烯性 不飽和單體之莫耳比，係就順丁烯二酸酐：順丁烯二酸 酐以外之1種以上的乙烯性不飽和單體而言，宜為1 : 10 〜1 : 0.5，從彩色濾光片用著色組成物之良好顯影性與 對液晶的不良影響更少的觀點來看，其中尤以1 : 8〜1 : 1更適宜。 可用於本發明之市售的共聚物可舉出「SMA1 000」、「 SMA2000」、「SMA3000」、「SMA EF30」、「SMA EF40」、「SMA EF60」及「SMA EF80」等（Sartomer Japan公司製），但不限定於該等，可使用任意的共聚物 (A)，該等可單獨或混合2種以上來使用。 表單編號A0101 第13頁/共76頁 201031713 共聚物（A)之含有量侍、以彩色滅光片用著色組成物中之 固體部分重4為基準，絲1G〜2〇重量％ 1前述共聚 物（A) t含有量小於10重量％，難以藉由添加來獲得電 特性改善的效果，大於2G重量％時，在分散穩定性、顯 影性等可能發現不良狀況。 [樹脂黏結劑（B)] 樹脂黏結劑係在可見光區400〜70〇nm之全波長區中，穿 透率宜為80%以上，更宜為95%以上之樹脂。可舉出例 如熱塑性樹脂、熱硬化性樹脂或感光性樹脂“其中尤以 樹脂黏結劑（B)含有齡ί可溶性樹脂為宜，進而言之， 以前述驗可溶性樹脂具有¢-, -% 藉由使用該鹼可溶性樹脂，影形減濾光片區 段時’可期待僅使用本發象物（Af所無法達到之 顯影性及改善顯影後之殘渣的效果。 進而言之’藉由含具有羥基之鹼可溶性樹脂，並利用本 發明之特徵之共聚物(A) 3叙册與樹脂黏結劑（B)之 羥基之架橋反應，可使得對於嗾璃蹲透T明基板或配置有 薄膜電晶體（f FT )之驅動Vi破考之密接性提升。 作為可於本發明使用之熱塑性樹脂，可舉出例如丁端駿 樹脂、苯乙烯一順丁烯二酸共聚物、氣化聚乙烯、氣化 聚丙烯、聚氯乙烯、氣乙烯一醋酸乙烯共聚物、聚酷賤 乙烯、聚教s旨樹脂、聚酯樹脂、丙稀酸系樹脂、醇竣樹 脂、聚笨乙烯樹脂、聚醯胺樹脂、橡膠系樹脂、環化橡 膠系樹脂、纖維素類、聚乙烯、聚丁二烯、聚醢亞胺樹 脂等《又，作為熱硬化性樹脂可舉出例如環氧樹脂、笨 并胺樹脂、松香改性順丁烯二酸樹脂、松香改彳i富馬竣 表單編號A0101 第14頁/共76頁 樹脂、三聚氰胺樹脂、尿素樹脂及酚樹脂等。 作為感光性樹脂係使用使得具有羥基、羧基、胺基等反 應性置換基之高分子，與具有異氰酸酯基、醛基、環氧 基等反應性置換基之（甲基）丙烯酸化合物或肉桂酸反 應，於該高分子導入有（甲基）丙烯醯基、苯乙烯基等 光架橋性基之樹脂。又，亦使用藉由具有羥烷基（甲基 )丙烯酸酯等具有羥基之（甲基）丙烯酸化合物，來將 含有苯乙烯無水馬來酸共聚物或α _烯烴一順丁烯二 酸酐等酸酐之高分子予以半酯化者。 驗可溶性樹脂係溶解於驗水溶液之樹脂，可舉出例如具 有羧基、砜基等酸性官能基之重量平均分子量1，000〜 500, 000，更宜為5, 000〜100, 000之樹脂。作為鹼可溶 性樹脂，具體可舉出具有酸性官能基之丙烯酸樹脂、苯 乙烯/苯乙烯砜酸共聚物、苯乙烯/ (甲基）丙烯酸共聚 物等。其中尤以具有酸性官能基之丙烯酸樹脂、及選自 苯乙烯/笨乙烯碾酸共聚物之至少1:種樹脂，特別是具有 酸性官能基之丙烯酸樹脂由於鄉熱性、透明性高，因此 適宜使用。 又，鹼可溶性樹脂中，尤以構成樹脂之乙烯性不飽和單 體具有羥基者為宜，可使用2 —羧基乙基（曱基）丙烯酸 酯、3_羧基丙基（曱基）丙烯酸酯、4一羧基丁基（曱 基）丙烯酸酯、醋酸單（曱基）丙烯酸酯、4一羧基乙烯 苯、2 —羧基一 3_笨氧基丙基丙烯酸酯或該等單體之己 内醋附加物等。 藉由使用此類具有羥基之鹼可溶性樹脂，藉由彩色濾光 片形成中之加熱，本發明之共聚物（Α)之順丁烯二酸酐 表單編號Α0101 第15頁/共76頁 201031713 之酸針部位、與樹脂黏結劑（B )之經基可因酯交換反應 而架橋，可使得對於玻璃等透明基板或配置有薄膜電晶 體（TFT)之驅動用基板等之密接性提升。 關於具有羥基之鹼可溶性樹脂的含量並未特別限制，對 於樹脂黏結劑（B)總量，宜為〇〜9〇重量％。此係由於 大於90重量％時，彩色i光片用著色組成物之分散穩定 性可能惡化。 又’本發明之共聚物（A)與樹脂黏結劑（B)之重量比 (A ) . ( B )宜在5 : 9 5〜7 0..: 的範圍内。前述共聚 物（A)之比率小於5時，難以‘由添加來獲得電特性改 善效果’大於70時，疏水糨片用著色 組成物中之其他構成成分之_在分散穩 定性、或是對於玻璃等透明墓板-全配蔓着為膜電晶體（ TFT)之堪動用基板等之密接性方面發現問題。 [顏料] 作為本發明之彩色濾光片物所|有的顏料， 可單獨或混合2種以上之有來使用。顏料之 中’尤以呈色性高且耐熱翁為宜，特別宜為耐 熱分解性高的顏料，通常使用有機顏料。 以下’以彩色索引（C. I.)號碼’表示可使用於本發明 之彩色濾光片用著色組成物物之有機顏料之具體例。 用以形成紅色濾光片區段之紅色彩色濾光片用著色組成 物，可使磁例如C. I. pigment Red 7、9、14、41、 48 : 1、48 : 2、48 : 3、48 : 4、81 : 1、81 : 2、81 : 3 、97、122、123、146、149、168、177、178、179、 180、184、185、187、192、200、202、208、210、 表單鎢號A0101 第16頁/共76頁 201031713 215、216、217、220、223、224、226、227、228、 240、246、254、255 ' 264、272及279等紅色顏料。紅 色彩色滤光片用著色組成物可與黃色顏料或橘色顏料同 時使用。 用以形成黃色濾光片區段之黃色彩色濾光片用著色組成 物，可使用例如C. I. Pigment Yellow 1、2、3、4 、5、6、10、12、13、14、15、16、17、18、20、24 、31、32、34、35、35 : 1、36、36 : 1、37、37 : 1、[0011] In the general formula (3), R41 is a hydrogen atom or _CH, and R42 and R43 are each a hydrogen atom, or R42 and R43 are bonded to each other to represent a ΓΠ., _. Since the maleic anhydride copolymerized with the ethylenically unsaturated monomer has an acid anhydride, it can form a coloring composition for a color filter having good film curability and development properties by using a resin binder in combination. The molar ratio of one or more kinds of ethylenically unsaturated monomers other than maleic anhydride to maleic anhydride is one or more kinds of ethylenic acid other than maleic anhydride: maleic anhydride The unsaturated monomer is preferably 1:10 to 1:0.5, from the viewpoint of good developability of the coloring composition for color filters and less adverse effect on the liquid crystal, especially 1:8~ 1 : 1 is more suitable. Commercially available copolymers which can be used in the present invention include "SMA1 000", "SMA2000", "SMA3000", "SMA EF30", "SMA EF40", "SMA EF60" and "SMA EF80" (Sartomer Japan In addition, it is not limited to these, and any copolymer (A) can be used, and these can be used individually or in mixture of 2 or more types. Form No. A0101 Page 13 of 76 sheets 201031713 The content of the copolymer (A) is based on the weight of the solid portion of the coloring composition in the color extinction sheet, and the filament 1G~2〇% by weight 1 (A) When the content of t is less than 10% by weight, it is difficult to obtain an effect of improving electrical properties by addition, and when it is more than 2% by weight, a problem may be found in dispersion stability, developability, and the like. [Resin Adhesive (B)] The resin binder is a resin having a permeation rate of preferably 80% or more, more preferably 95% or more in the entire wavelength region of 400 to 70 Å in the visible light region. For example, a thermoplastic resin, a thermosetting resin, or a photosensitive resin may be mentioned. "In particular, the resin binder (B) preferably contains an aged resin, and in other words, the above-mentioned soluble resin has ¢-, -% by When the alkali-soluble resin is used, when the filter section is reduced, it is expected to use only the hair styling material (the developability which cannot be achieved by Af and the effect of improving the residue after development. In other words, by having a hydroxyl group) The alkali-soluble resin, and the copolymerization of the copolymer (A) 3 characterized by the characteristics of the present invention and the hydroxyl group of the resin binder (B) can be used to make the glass substrate transparent or to be provided with a thin film transistor ( f FT ) The adhesion of the Vi-breaking test is improved. As the thermoplastic resin which can be used in the present invention, for example, Ding Duanjun resin, styrene-maleic acid copolymer, vaporized polyethylene, vaporized polypropylene can be mentioned. , polyvinyl chloride, ethylene-vinyl acetate copolymer, polycarbene ethylene, poly-stadium resin, polyester resin, acrylic resin, alcohol resin, polystyrene resin, polyamide resin, rubber system Resin, Further, as the thermosetting resin, for example, an epoxy resin, a stupid amine resin, and a rosin-modified maleene can be mentioned as the thermosetting resin. Diacid resin, rosin modified 富i Fuma 竣 Form No. A0101 Page 14 of 76 Resin, melamine resin, urea resin, phenol resin, etc. Used as a photosensitive resin to have reactivity such as hydroxyl group, carboxyl group, amine group, etc. The polymer of the substituent group is reacted with a (meth)acrylic compound or a cinnamic acid having a reactive substituent such as an isocyanate group, an aldehyde group or an epoxy group, and a (meth)acryl fluorenyl group or a styrene is introduced into the polymer. a resin having a light-bridged group, etc. Further, a (meth)acrylic acid compound having a hydroxyl group such as a hydroxyalkyl (meth) acrylate is used to contain a styrene-free maleic acid copolymer or α _ The polymer of an acid anhydride such as an olefin or a maleic anhydride is semi-esterified. The soluble resin is a resin which is dissolved in the aqueous solution, and examples thereof include a weight of an acidic functional group such as a carboxyl group or a sulfone group. The average molecular weight is from 1,000 to 500,000, more preferably from 5,000 to 100,000. As the alkali-soluble resin, specifically, an acrylic resin having an acidic functional group, a styrene/styrenesulfonate copolymer, a styrene/(meth)acrylic acid copolymer, etc., particularly an acrylic resin having an acidic functional group, and at least one type of resin selected from the group consisting of styrene/stuppy ethylene acid copolymers, particularly acrylic acid having an acidic functional group. The resin is preferably used because it is high in heat and transparency. Further, in the alkali-soluble resin, it is preferred that the ethylenically unsaturated monomer constituting the resin has a hydroxyl group, and 2-carboxyethyl (indenyl) acrylate can be used. , 3-carboxypropyl (decyl) acrylate, 4-carboxybutyl (decyl) acrylate, mono(indenyl) acrylate, 4-carboxyvinyl benzene, 2-carboxy- 3 - phenyloxy A acrylate or an internal vinegar add-on of such monomers, and the like. By using such an alkali-soluble resin having a hydroxyl group, the copolymer of the present invention is heated by color filter formation, and the copolymer of the present invention has a maleic anhydride form number of Α0101, page 15 of 76, 201031713. The base of the needle and the resin binder (B) can be bridged by a transesterification reaction, and the adhesion to a transparent substrate such as glass or a driving substrate on which a thin film transistor (TFT) is disposed can be improved. The content of the alkali-soluble resin having a hydroxyl group is not particularly limited, and is preferably 〇9 to 9% by weight based on the total amount of the resin binder (B). When the amount is more than 90% by weight, the dispersion stability of the coloring composition for a color i-ray sheet may be deteriorated. Further, the weight ratio (A) of the copolymer (A) of the present invention to the resin binder (B) is preferably in the range of 5:9 5 to 7 0..:. When the ratio of the copolymer (A) is less than 5, it is difficult to obtain an effect of improving the electrical characteristics by the addition of more than 70, and the other constituents in the coloring composition for the hydrophobic sheet are in dispersion stability or for glass. The transparent slabs are all found to have problems in the adhesion of substrates such as film substrates (TFTs). [Pigment] The pigments of the color filter of the present invention may be used singly or in combination of two or more. Among the pigments, it is preferable to have high color rendering properties and heat-resistant articles, and it is particularly preferable to use a pigment having high thermal decomposition resistance, and an organic pigment is usually used. The following is a specific example of an organic pigment which can be used for the coloring composition for a color filter of the present invention by a color index (C.I.) number. A coloring composition for a red color filter for forming a red filter segment, such as CI pigment Red 7, 9, 14, 41, 48: 1, 48: 2, 48: 3, 48: 4 , 81 : 1, 81 : 2, 81 : 3, 97, 122, 123, 146, 149, 168, 177, 178, 179, 180, 184, 185, 187, 192, 200, 202, 208, 210, form Tungsten No. A0101 Page 16 of 76 pages 201031713 Red pigments such as 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 246, 254, 255 '264, 272 and 279. The coloring composition for the red color filter can be used at the same time as the yellow pigment or the orange pigment. For coloring compositions for yellow color filters for forming yellow filter segments, for example, CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14, 15, 16 may be used. 17, 18, 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1,

40、42、43、53、55、60、61、62、63、65、73、74 、77、81、83、86、93、94、95、97、98、100、1〇1 、104、106、108、109、 、117、118、119、120、 、129、137、138、139、 aia v ii5' ii6e 127、128 152 > 153 、154、155、156 v 161、162、164、166、167 ' 168 、169、170、171、172、173、174、175、176、177 、179、180、18卜·182麵fiJfll、193、194 、199、213:或214等黃色❹rfy 用以形成橘色濾光片區段色濾光片用著色組成 物，可使用例如C. I. Pigment Orange 36、43、51 、55、59、61、71或73等橘色顏料。 作為用以形成綠色濾光片區段之綠色彩色濾光片用著色 組成物’可使用例如C. I. Pigment Green 7、10、 36、37或58等綠色顏料。綠色彩色濾光片用著色組成物 可與上述黃色顏料同時使用。 用以形成藍色濾光片區段之藍色彩色濾光片用著色組成 物，可使用例如C. I. Pigment Blue 15、15 : 1、15 表單編號A0101 第17頁/共76頁 201031713 :2 ' 15 : 3 ' 15 : 4、15 : 6 ' 16、22、60、64或80等 藍色顏料。藍色彩色濾光片用著色組成物可與C. I. Pigment Violet 1、19、23、27、29、30、32、37、 40、42或50等紫色顏料同時使用。 用以形成青色濾光片區段之青色彩色濾光片用著色組成 物，可使用例如C. I. Pigment Blue 15 : 1、15 : 2 、15:4、15:3、15:6、16或81等青色顏料。用以形 成洋紅色濾光片區段之洋紅色彩色濾光片用著色組成物 ，可使用例如C. I. Pigment V.iolet 1 或 19，或者C. I. Pigment Red 81、144、146、177或 169等紫色顏 料及紅色顏料》洋紅色彩色濾光片用著色組成物可與黃 色顏料同時使用。 又，作為無機顏料可舉出琉酸把、鋅白、〜疏酸船、黃色 錯、鋅黃、紫紅漆（紅色氧化鐵（111 ))、编紅、群青 、紺青、氧化鉻綠、鈷綠、棕土、鈦黑、合成鐵黑、氧 化鈦或四氧化鐵等金屬氧化物耠、金屬硫化物粉、金屬 粉等。無機顏料係為了取得彩度與亮度的均衡，同時確 保良好的塗布性、感度、顯影性等，而與有機顏料組合 使用。 於本發明之彩色濾光片用著色組成物中，為了調色亦可 於不降低耐熱性的範圍内含有染料。 [顏料分散劑] 分散顏料時，可適當地使用色素衍生物或樹脂型顏料分 散劑、界面活性劑等顏料分散劑。顏料分散劑對顏料的 分散良好，防止分散後顏料再凝結的效果甚大，因此可 獲得透明性良好的彩色濾光片。顏料分散劑係對於顏料 表單編號A0101 第18頁/共76頁 201031713 100重量部，宜以0. 1〜30重量部的量使用。 (色素衍生物） 於本發明之彩色濾光片用著色組成物中，以改善顏料分 散性為目的而可使用色素衍生物。作為色素衍生物可舉 出於有機顏料、蒽醌、吖啶酮或三嗪中，導入有鹼性置 換基、酸性置換基或亦可具有置換基之鄰苯二甲醯亞胺 甲基之化合物。 本發明中，其中尤以鹼性衍生物為宜，鹼基性衍生物係 下述一般式（4)所示之化合物，係具有鹼性基之特定母 體骨架之衍生物。若具有鹼性基之色素衍生物均可，並 未特別限定，可適宜使用具有下述一般式（4)所示之鹼 性基之三嗪環骨架之色素衍生物= 一般式（4):40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94, 95, 97, 98, 100, 1〇1, 104, 106, 108, 109, 117, 118, 119, 120, 129, 137, 138, 139, aia v ii5' ii6e 127, 128 152 > 153, 154, 155, 156 v 161, 162, 164, 166 , 167 ' 168 , 169 , 170 , 171 , 172 , 173 , 174 , 175 , 176 , 177 , 179 , 180 , 18 · 182 face fiJfll , 193 , 194 , 199 , 213 : or 214 etc . For the color filter composition of the orange filter section color filter, an orange pigment such as CI Pigment Orange 36, 43, 51, 55, 59, 61, 71 or 73 can be used. As the coloring composition for the green color filter for forming the green color filter section, a green pigment such as C.I. Pigment Green 7, 10, 36, 37 or 58 can be used. The coloring composition for the green color filter can be used together with the above yellow pigment. For coloring compositions for blue color filters for forming blue filter segments, for example, CI Pigment Blue 15, 15: 1, 15 Form No. A0101 Page 17 / Total 76 pages 201031713 : 2 ' 15 : 3 ' 15 : 4, 15 : 6 ' Blue pigments such as 16, 22, 60, 64 or 80. The coloring composition for blue color filters can be used simultaneously with a violet pigment such as C.I. Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42 or 50. For the coloring composition for the cyan color filter for forming the cyan filter section, for example, CI Pigment Blue 15 : 1, 15 : 2, 15: 4, 15: 3, 15: 6, 16 or 81, etc. can be used. Cyan pigment. For coloring the magenta color filter for forming a magenta filter segment, for example, a purple pigment such as CI Pigment V.iolet 1 or 19, or CI Pigment Red 81, 144, 146, 177 or 169 can be used. And red pigments. The coloring composition for magenta color filters can be used simultaneously with yellow pigments. Further, examples of the inorganic pigment include citric acid, zinc white, sulphuric acid boat, yellow smear, zinc yellow, purple lacquer (red iron oxide (111)), braided red, ultramarine blue, indigo, chrome oxide green, and cobalt green. , metal oxides such as brown earth, titanium black, synthetic iron black, titanium oxide or iron oxide, metal sulfide powder, metal powder, and the like. The inorganic pigment is used in combination with an organic pigment in order to achieve a balance between chroma and brightness while ensuring good coatability, sensitivity, developability and the like. In the colored composition for a color filter of the present invention, a dye may be contained in a range which does not lower the heat resistance for coloring. [Pigment Dispersant] When the pigment is dispersed, a pigment dispersant such as a dye derivative or a resin type pigment dispersant or a surfactant may be suitably used. The pigment dispersant has a good dispersion of the pigment and prevents the pigment from re-coagulation after dispersion, so that a color filter having good transparency can be obtained. The pigment dispersant is used for the pigment. Form No. A0101 Page 18 of 76 201031713 100 parts by weight, preferably used in an amount of 0.1 to 30 parts by weight. (Pigment Derivative) In the coloring composition for a color filter of the present invention, a dye derivative can be used for the purpose of improving the dispersibility of the pigment. The pigment derivative may be a compound in which an organic substituent, an anthracene, an acridone or a triazine is introduced with a basic substituent, an acidic substituent or a phthalimidomethyl group which may have a substituent. . In the present invention, a basic derivative is particularly preferable, and the base derivative is a compound represented by the following general formula (4), which is a derivative of a specific parent skeleton having a basic group. The dye derivative having a basic group is not particularly limited, and a dye derivative of a triazine ring skeleton having a basic group represented by the following general formula (4) can be suitably used: General formula (4):

P-L (於一般式（4)中，P為m價之有機顏料殘基、蒽醌骨架 、吖啶酮骨架或三嗪骨架等，m為1〜4的整數，L係選自 由一般式（5)、（6)或（7)所示之群組之置換基。） 一般式（5): -PL (In the general formula (4), P is an m-valent organic pigment residue, an anthracene skeleton, an acridone skeleton or a triazine skeleton, and m is an integer of 1 to 4, and L is selected from the general formula (5). a substitution group of the group shown by (6) or (7).) General formula (5): -

[0013] 一般式（6 ): 表單編號A0101 第19頁/共76頁 201031713 [0014]General Formula (6): Form No. A0101 Page 19 of 76 201031713 [0014]

[0015] [0016] 一般式（7):[0016] General Formula (7):

[0017] 於一般式（5)〜（7)中， X為一SOg_、_CO_、—CH^_、_CH^NHCOCH^ CH2NHS〇2CH2—或直接結合； 為一ΝΗ —、_0_或直接結合； η為1〜10的整數； Υ1 為一ΝΗ-、一NR9 —Z-NR1Q-或直接結合； 碳數2 R9及R1()分別獨立而為氫原子、碳數1〜36之烷基 〜36之烯基、或苯基； Z為碳數1〜20之亞烷基，宜為碳數1〜10之亞烷基，或為 碳數6〜20之亞芳基，宜為碳數6〜10之亞芳基，作為例 表單編號A0101 第20頁/共76頁 子可舉出亞甲基、乙烯基 '丙烯基、伸苯基。 R及R分別獨立而為氫原子、碳數丨〜3〇之烷基，宜為碳 數1〜6之烷基、碳數2〜30之亞烷基，或“及以表示相互 結合，進一步含氮 '氧或硫原子之雜環； R、R、R及R6分別獨立而為氫原子、碳數丨—20之烷基 、碳數2〜20之亞烷基、碳數6〜2〇之亞芳基； R7為氫原子、碳數1〜20之烷基、碳數2〜2〇之亞烷基； R8係以上述一般式（5)所示之置換基、或上述一般式（ 6)所示之置換基； Q為羥基、碳數1〜20之烷氧基，宜為碳數〗〜5之烷氧基 ’係以上述一般式（5)所示之置換基、或上述一般式（ 6)所示之置換基’作為該炫氧基的相;^可舉:出甲氧基、 乙.氧基。： f 作為為了形成一般式(5)〜（7)所示之置換基而使用 之胺成分’可舉出倒如二曱胺基、二乙胺基、N，N —乙 基異丙胺、N，N—乙基丙Nf 丁胺、N，N — 曱基異丁胺、Ν，Ν—丁基£ 二異丁胺、二丙胺、Ν， V p^pfiTly第三丁基乙胺、[0017] In the general formulas (5) to (7), X is a SOg_, _CO_, -CH^_, _CH^NHCOCH^CH2NHS〇2CH2- or a direct combination; a ΝΗ-, _0_ or direct combination; η is an integer of 1 to 10; Υ1 is a ΝΗ-, a NR9-Z-NR1Q- or a direct bond; carbon number 2 R9 and R1() are independently a hydrogen atom, an alkyl group having a carbon number of 1 to 36~36 Alkenyl or phenyl; Z is an alkylene group having 1 to 20 carbon atoms, preferably an alkylene group having 1 to 10 carbon atoms, or an arylene group having 6 to 20 carbon atoms, preferably a carbon number of 6~ The arylene group of 10, as an example form No. A0101, page 20 / page 76, may be a methylene group, a vinyl 'propenyl group, or a phenyl group. R and R are each independently a hydrogen atom, an alkyl group having a carbon number of 〇3 to 3, preferably an alkyl group having 1 to 6 carbon atoms, an alkylene group having 2 to 30 carbon atoms, or "and indicating mutual bonding, further a heterocyclic ring containing nitrogen 'oxygen or sulfur atom; R, R, R and R6 are each independently a hydrogen atom, an alkyl group having a carbon number of -20, an alkylene group having a carbon number of 2 to 20, and a carbon number of 6 to 2 Å. Arylene; R7 is a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkylene group having 2 to 2 carbon atoms; and R8 is a substituent represented by the above general formula (5) or the above general formula ( 6) a substituted group shown; Q is a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms, preferably an alkoxy group having a carbon number of 〜5 is a substituent represented by the above general formula (5), or the above The substituent " represented by the general formula (6) is used as the phase of the oxyoxy group; and the methoxy group and the ethoxy group are mentioned: f is as shown in the general formulae (5) to (7). The amine component used for the substituent group may be exemplified by a diammonium group, a diethylamine group, an N,N-ethylisopropylamine, an N,N-ethylpropenyl Nf butylamine, or an N,N-decyl group. Butylamine, hydrazine, hydrazine-butyl £ diisobutylamine, dipropylamine, hydrazine, V p^pfiTl Y tert-butylethylamine,

Jim. ：!>ί%丙胺、二丁胺、二 第二丁胺、二異丁胺、二異丁胺、Ν，Ν —異丁基第二丁 胺、二戊胺、二異戊胺、二己胺、二（2—乙基己基）胺 、二辛胺、Ν，Ν—甲基十八胺、二癸胺、二芳胺、Ν，Ν 一甲基_1，2—二曱基丙胺、Ν，Ν—曱基己胺、二油胺 、二硬酯胺、Ν，Ν—二曱胺甲胺、Ν，Ν-二甲胺乙胺、 Ν，Ν —二甲胺甲胺、Ν，Ν—二甲胺丁胺、Ν，Ν —二乙胺 乙胺、Ν，Ν —二乙胺丙胺、ν, Ν —二乙胺己胺、Ν，Ν — 二乙胺丁胺、Ν，Ν —二乙胺戊胺、Ν，Ν—二丙胺丁胺、 表單編號Α0101 第21頁/共76頁 .· 201031713 N，N —二丁胺丙胺、N, N —二丁胺乙胺、N，N —二丁胺 丁胺、N，N—二異丁胺戊胺、N，N—曱基一月桂胺丁胺 、N，N—乙基一己胺乙胺、N，N —二硬酯胺乙胺、N，N —二油胺乙胺、N，N —二硬酯胺丁胺、哌啶、2_曱基哌 啶、4—甲基哌啶、2，4 一二甲基哌啶、2，6 —二甲基 旅咬、3，5 —二曱基痕咬、3 —旅咬甲醇、甲基β底咬酸、 異哌啶曱酸、異哌啶曱酸曱基、異哌啶甲酸乙基、2_哌 啶曱醇、吡咯、3 —羥基吡咯、Ν —胺乙基哌啶、Ν —胺乙 基一4 —甲基哌啶、Ν —胺乙基嗎啉、Ν—胺基丙基哌啶、 Ν —胺基丙基一2 —曱基哌啶酸、Ν —胺基丙基一4一曱基 哌啶酸、Ν-胺基丙基嗎啉、Ν—曱基哌嗪、Ν—丁基哌嗪 、Ν —甲基高哌嗪、1—環戊基哌嗪、1 —胺基_4 一甲基 派唤或1 —環戊基派唤等。 本發明之具有鹼性置換基之顏料衍生物、蒽醌衍生物及 三嗪衍生物能夠以各種合成途徑來合成。例如於有機色 素、蒽醌或三嗪中，導入下述一般式（8)〜（11)所示 之置換基後，使得與上述置換基反應而形成一般式（5) 〜（7)所示之置換基之上述胺成分，即例如Ν，Ν-二甲 胺丙胺、Ν —甲基旅嗓、二乙胺或4—[4 —經基一6 — [3 — (二丁胺）丙胺]_1，3，5 —三嗪一2 —胺基]苯胺等反 應而獲得。 一般式（8) : -S02C1 一般式（9) : -C0C1 一般式（10) : -CHqNHC0CHoC1Jim. :!> ί% propylamine, dibutylamine, dibutylamine, diisobutylamine, diisobutylamine, hydrazine, hydrazine-isobutyl butylamine, diamylamine, diisoamylamine , dihexylamine, bis(2-ethylhexyl)amine, dioctylamine, hydrazine, hydrazine-methyloctadecylamine, diamine, diarylamine, hydrazine, hydrazine monomethyl-1,2-di Propylamine, hydrazine, hydrazine-mercaptohexylamine, dioleylamine, distearylamine, hydrazine, hydrazine-dimethylamine methylamine, hydrazine, hydrazine-dimethylamine ethylamine, hydrazine, hydrazine-dimethylamine methylamine , hydrazine, hydrazine - dimethylamine, hydrazine, hydrazine - diethylamine ethylamine, hydrazine, hydrazine - diethylamine propylamine, ν, hydrazine - diethylamine hexamine, hydrazine, hydrazine - diethylamine butylamine, Ν,Ν —Diethylamine pentylamine, hydrazine, hydrazine-dipropylamine butylamine, Form No. Α0101 Page 21 of 76.· 201031713 N,N —Dibutylamine propylamine, N, N —Dibutylamine ethylamine , N,N-dibutylamine butylamine, N,N-diisobutylamine pentylamine, N,N-fluorenyl laurate, N,N-ethylhexylamine ethylamine, N,N - II Stearylamine ethylamine, N,N-dioleylamine, N,N-distearate butylamine, piperidine, 2-mercaptopiperidine, 4-methylpiperidine , 2,4 - dimethyl piperidine, 2,6 - dimethyl brigade bite, 3,5 - diterpene bite bite, 3 - brigade bite methanol, methyl beta bottom bite acid, isopiperidinic acid, Isopiperidinium decanoate, isopiperidinecarboxylic acid ethyl, 2-piperidinol, pyrrole, 3-hydroxypyrrole, guanidine-aminoethylpiperidine, guanidine-aminoethyl-4-methylpiperidine, Ν-amine ethylmorpholine, anthraquinone-aminopropyl piperidine, hydrazine-aminopropyl-2-oxanyl piperidic acid, hydrazine-aminopropyl-4-indolyl piperidic acid, hydrazine-amine Propyl morpholine, hydrazine-hydrazinopiperazine, hydrazine-butyl piperazine, hydrazine-methyl homopiperazine, 1-cyclopentylpiperazine, 1-amino-4-methyl-pyrene or 1- Cyclopentyl is called and so on. The pigment derivative, the anthracene derivative and the triazine derivative having a basic substituent in the present invention can be synthesized by various synthetic routes. For example, in the organic dye, hydrazine or triazine, after introducing a substituent represented by the following general formulas (8) to (11), the substituent is reacted with the above-mentioned substituent to form a general formula (5) to (7). The above-mentioned amine component of the substituent, that is, for example, hydrazine, hydrazine-dimethylamine propylamine, hydrazine-methyl guanidine, diethylamine or 4-[4-amino- 6-[3-(dibutylamine)propylamine] It is obtained by a reaction such as _1,3,5-triazine-2-amino]aniline. General formula (8) : -S02C1 General formula (9) : -C0C1 General formula (10) : -CHqNHC0CHoC1

L L 一般式（11 ) : -CH2C1 一般式（8)〜（11)之置換基與上述胺成分反應時，一 表單編號A0101 第22頁/共76頁 般式（8)〜（11 )之置換基的一部分加水分解，混合有 氣置換為羥基之物亦可。該情況下，一般式（8 )及一般 式（9)分別為砜酸基及羧酸基，任一者維持游離酸，或 為1〜3價的金屬或與上述單胺的鹽類均可。 又，有機色素為偶氮系色素時，預先於二偶氮成分或耦 合成分中導入一般式（5)〜（7)所示之置換基，其後 進行耦合反應，藉此亦可製造偶氮系衍生物。 本發明之具有鹼性基之三嗪衍生物能夠以各種合成途徑 來合成。例如以三聚氯氰為出發原料，使得三聚氣氰之 至少1個氯，與形成一般式（5)〜（7)所示之置換基之 胺成分，即例如N，N —二甲胺丙胺、N —甲基略°秦等反應 ，接著使得三聚氯氰剩餘的氣與各種胺戍醉等反應而獲 得。 於本發明之著色組成物中，具有鹼置換基之色素衍生物 之調配量係對於顏料100重量部，宜為1〜50重量部，更 宜為3〜30重量部，最宜為5〜25逢量:部。若對於顏料LL General formula (11): -CH2C1 When the substituents of the general formulae (8) to (11) are reacted with the above amine component, a form number A0101 page 22/76 page is replaced by the formula (8) to (11) A part of the base is hydrolyzed and mixed with a gas substituted with a hydroxyl group. In this case, the general formula (8) and the general formula (9) are each a sulfone acid group and a carboxylic acid group, and either one of them maintains a free acid, or a metal having a valence of 1 to 3 or a salt of the above monoamine . In addition, when the organic dye is an azo dye, a substituent represented by the general formulas (5) to (7) is introduced into the diazo component or the coupling component in advance, and then a coupling reaction is carried out, whereby an azo can be produced. a derivative. The triazine derivative having a basic group of the present invention can be synthesized by various synthetic routes. For example, starting from cyanuric chloride, at least one chlorine of the trimeric cyanogen, and an amine component forming a substituent represented by the general formulas (5) to (7), for example, N,N-dimethylamine. The reaction of propylamine, N-methyl oxime, and the like, followed by reacting the remaining gas of cyanuric chloride with various amines and the like. In the coloring composition of the present invention, the amount of the pigment derivative having an alkali substituent is preferably from 1 to 50 parts by weight, more preferably from 3 to 30 parts by weight, most preferably from 5 to 25 parts by weight on 100 parts by weight of the pigment. Everything: Ministry. If for pigments

jfc . I !： , S 100重量部，鹼性衍生物小於l·重量部，則會有分散性惡 化的情況，若超過5 0重量部，則會有耐熱性、对光性惡 化的情況。其中尤以鹼性置換基具有三嗪構造之物，在 分散穩定性方面最適宜。 (樹脂型顏料分散劑） 樹脂型顏料分散劑係具有具吸附於顏料的性質之顏料親 和性部位、及與共聚物（A)及樹脂黏結劑（B)具相溶 性之部位，吸附於顏料，發揮穩定顏料對於該等樹脂中 之分散的作用。 作為樹脂型顏料分散劑可舉出例如聚乙烯系、聚氨酯系 表單編號A0101 第23頁/共76頁 201031713 、聚酯系、聚醚系、福馬林縮合系、矽基系或該等之複 合系聚合物。 作為顏料親和部位可舉出羧基、羥基、磷酸基、磷酸酯 基、颯酸基、羥基、胺基、4級銨鹽基或醯胺基等極性基 、或者聚過氧乙烷、聚過氧丙烷或該等之複合系等親水 性聚合物鏈等； 作為與共聚物（A)及樹脂黏結劑（B)具相溶性之部位 ，可舉出長鏈烷基鏈、聚乙烯鏈、聚醚鏈或聚酯鏈等。 作為樹脂型顏料分散劑，具體而言可舉出如下： 笨乙烯一順丁烯二酸酐共聚物、烯烴一順丁烯二酸酐共 聚物、聚（曱基）丙烯酸鹽、笨乙烯一（甲基）丙烯酸 共聚物、（甲基）丙烯酸一（曱基）丙烯酸烷基酯共聚 物、（甲基）丙烯酸一聚乙烯系高分子共聚物、含磷酸 酯丙烯酸樹脂、含芳香族羧基丙烯酸樹脂、聚苯乙烯砜 酸鹽、丙烯醯胺一（甲基）丙烯酸共聚物、羧基甲基纖 維素、具有羧基之聚氨酯、萘颯酸鹽之福馬林縮合物或 藻朊酸蘇打等陰離子系樹脂型顏料分散劑； 聚乙烯醇、聚亞烷聚胺、聚丙烯醯胺或聚合物澱粉等非 離子系樹脂型顏料分散劑；或者 聚乙烯亞胺、胺基烷基（曱基）丙烯酸酯共聚物、聚乙 烯咪唑啉、具有胺基之聚氨酯、聚（低級烷亞胺）與具 有游離羧基之聚酯之反應物等陽離子系樹脂型顏料分散 劑，該等可單獨或混合2種以上來使用。 作為市售的樹脂型顏料分散劑可舉出如下： Disperbyk-101、103、107、108、110、111、116、 130、140、154、161、162、163、164、165、166、 表單編號A0101 第24頁/共76頁 201031713 170、171、174、180、181、182、183、184、185、 190、2000、2001、2020、2090、2091、2164或2163 ，或Anti-Terra —U、203或204、或BYK —P104、 P104S或220S、或Lactimon或Lactimom —WS，或Jfc. I !: , S 100 parts by weight, if the basic derivative is less than 1 part by weight, the dispersibility may deteriorate. If it exceeds 50 parts by weight, heat resistance and light deterioration may occur. Among them, a substance having a triazine structure, particularly a basic substituent, is most suitable for dispersion stability. (Resin-type pigment dispersant) The resin-type pigment dispersant has a pigment affinity site having a property of adsorbing to a pigment, and a site compatible with the copolymer (A) and the resin binder (B), and is adsorbed to the pigment. The effect of stabilizing pigments on the dispersion in these resins is exerted. Examples of the resin-based pigment dispersant include a polyethylene-based, polyurethane-based form No. A0101, page 23, page 76, 201031713, a polyester-based, a polyether-based, a fumarin condensation system, an anthracene-based system, or a composite system thereof. polymer. Examples of the pigment affinity site include a polar group such as a carboxyl group, a hydroxyl group, a phosphate group, a phosphate group, a decanoic acid group, a hydroxyl group, an amine group, a quaternary ammonium salt group or a guanamine group, or a polyperoxyethane or polyperoxy group. a hydrophilic polymer chain such as propane or a composite thereof; and a long-chain alkyl chain, a polyethylene chain, and a polyether as a site compatible with the copolymer (A) and the resin binder (B); Chain or polyester chain, etc. Specific examples of the resin type pigment dispersant include the following: an ethylene-maleic anhydride copolymer, an olefin-maleic anhydride copolymer, a poly(indenyl)acrylate, and a stupid ethylene-methyl group. Acrylic copolymer, (meth)acrylic acid alkyl (meth)acrylate copolymer, (meth)acrylic acid-polyethylene polymer copolymer, phosphate ester-containing acrylic resin, aromatic carboxyl group-containing acrylic resin, poly Dispersion of anionic resin type pigment such as styrene sulfonate, acrylamide-(meth)acrylic acid copolymer, carboxymethyl cellulose, polyurethane having carboxyl group, hamarinate condensate or alginic acid soda Nonionic resin type pigment dispersant such as polyvinyl alcohol, polyalkylene polyamine, polypropylene decylamine or polymer starch; or polyethyleneimine, aminoalkyl (meth) acrylate copolymer, poly a cationic resin type pigment dispersant such as a vinyl imidazoline, a polyurethane having an amine group, a poly(lower alkylenimine), and a polyester having a free carboxyl group, which may be used alone or in combination 2 Or more. Commercially available resin type pigment dispersants are as follows: Disperbyk-101, 103, 107, 108, 110, 111, 116, 130, 140, 154, 161, 162, 163, 164, 165, 166, form number A0101 Page 24 of 76 201031713 170, 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2090, 2091, 2164 or 2163, or Anti-Terra — U, 203 or 204, or BYK - P104, P104S or 220S, or Lactimon or Lactimom - WS, or

Bykumen等畢克化學公司製樹脂型顏料分散劑； SOLSPERSE-3000、9000、13240、13650、13940、 17000 、 18000 、 20000 、 21000 、 24000 、 26000 、 27000 、 28000 、 31845 、 32000 、 32500 、 32600 、 34750、36600、38500、41000、41090或53095等日本Resin type pigment dispersing agent such as Bykumen; SOLSPERSE-3000, 9000, 13240, 13650, 13940, 17000, 18000, 20000, 21000, 24000, 26000, 27000, 28000, 31845, 32000, 32500, 32600, 34750 , 36600, 38500, 41000, 41090 or 53095 etc. Japan

Lubrizol公司製之樹脂型顏料分散劑；或者 EFKA-46、47、48、452、4Ρ4〇α8-、4⑽9? LP4010、 LP4050、LP4055、400、403、450、451、 1 453、4540、4550、υ>45^^·^^Γ^^1501、1502 或1503等EFKA化學公司製樹脂型顏料分散劑；不限定於 該等’可使用任意的樹脂型顏料分散劑，該等亦可單獨 或混合2種以上來使用。brel1 ： , 其中尤其適宜的樹脂型分叙^Gfif^^W02008/0〇7776 .#·% f f! 所記載的分子内，具有2個經及4¾硫醇基之化合物的 存在下，將乙烯性不飽和單體進行自由基聚合而生成， 並令單一末端區域具有2個羥基之乙烯基共聚物中之羥基 與四羧酸二酐中之酸酐基反應而成之聚酯分散劑。使用 該等聚酯分散劑之彩色濾光片著色組成物不僅顏料的分 散穩定性良好，而且可縮小介電正切，因此不易受到電 機特性的影響。作為該等樹脂型分散劑之合成方法，可 利用W02008/007776號公報所記載的方法來合成。 (界面活性劑） 表單編號A0101 第25頁/共76頁 201031713 作為界面活性劑可舉出如下： 聚環氧乙烷醚硫酸鹽、十二烷基苯磺酸鈉、苯乙烯一丙 烯酸共聚物之丙烯酸鹽、烷基萘磺酸鈉、烷基二苯醚二 磺酸鈉、月桂基硫酸乙醇胺、月桂基硫酸三乙醇胺、月 桂基硫酸銨、硬脂酸乙醇胺、硬脂酸銨、月桂基硫酸鈉 、苯乙烯一丙烯酸共聚物之單乙醇胺或聚環氧乙烷醚磷 酸醚等陰離子性界面活性劑； 聚環氧乙烯油醚、聚環氧乙烯月桂醚、聚環氧乙稀壬基 苯醚、聚環氧乙烷醚磷酸酯、聚環氧乙烯山梨糖醇酐甘 油硬脂酸或聚乙二醇單月桂酯等非離子性界面活性劑； 烷基4級銨鹽或其等之環氧乙烷附加物等陽離子界面活性 劑；. 圓‘ Μ 烷基二甲胺醋酸季銨羧酸内鹽等烷基李敍魏酸内鹽；或 者烷基咪唑啉等雙性界面活性劑等；此等可單獨或混合2 種以上使用。 [溶劑] 於本發明之彩色濾光片用著色組成物中可含有溶劑，以 便容易使顏料充分分散於共聚物（Α)及樹脂黏結劑（Β )中，於玻璃等透明基板上，塗布為乾燥膜厚0. 2〜5 而形成濾光片區段。 作為溶劑可舉出1，2，3 —三氣丙烷、1，3 —丁二醇二 乙酸鹽、2 —庚酮、3，3，5 —三甲基一2 —環己烯一1 — 酮、3，5，5三曱基環己酮、3—乙氧基丙酸乙基、3 — 甲氧基_3—甲基乙酸丁酯、3 —曱氧基丁醇、3 —甲氧基 乙酸丁酯、4 —庚酮、間二甲苯、間二乙苯、間二氣笨、 N, N —二曱基乙醯胺、正丁苯、正乙酸丙酯、N—吡咯酮 表單編號A0101 第26頁/共76頁 、鄰二甲苯、鄰氯曱苯、鄰二乙苯、鄰二氯苯、對氯甲 苯、對二乙苯、二級丁苯、三級丁苯、異佛酮、乙二醇 二***、乙二醇二丁醚、乙二醇單***乙酸鹽、乙二醇 單第三丁醚、乙二醇單丁醚乙酸鹽、乙二醇單丙醚、二 異丁酮、環己醇乙酸鹽、二丙二醇二甲醚、二丙二醇甲 醚乙酸鹽、二丙二醇單丁醚、二丙酮醇、丙二醇二乙酸 鹽、丙二醇苯基醚、丙二醇單***、丙二醇單丙醚、丙 二醇單甲醚、丙二醇單甲醚乙酸鹽、丙二醇單甲醚丙酸 鹽、笨基醇、曱基異丁酮、曱基環己醇、醋酸正戊酯、 醋酸正丁酯、醋酸異戊酯、醋酸異丁酯、醋酸丙酯及二 鹼基酸酯等，該等可單獨或混合使用。 宜至少含有環己基乙酯而組成，藉此，可擭得平坦性良 好之使用本發明之彩色濾光片用著色組成物之著色層。 作為該環己基乙酯之含有量係以彩色濾光片用著色組成 物之總量作為基準而為3〜35重量％，更宜為5〜25重量 %。環己基乙酯之含有量超過35重量％_1，在預烘烤所 塗布的塗膜時，有機溶劑未能乞分蒸發而殘存於乾燥塗 膜内，可能會殘留有膠黏性（乾燥塗膜表面的黏著性） 〇 又，本發明之著色組成物作為噴墨墨水使用時，作為溶 劑係從對於樹脂之溶解性、對於裝置構件之膨潤作用、 黏度及喷嘴中之墨水乾燥性的觀點來選擇溶劑，可單獨 或混合2種以上來使用例如醇系溶劑、二醇系溶劑、酯系 溶劑、酮系溶劑等。 作為醇系溶劑可舉出例如己醇、庚醇、辛醇、壬醇、癸 醇、十一醇、環己醇、苄醇、胺醇等。 表單編號A0101 第27頁/共76頁 201031713 作為二醇系溶劑可舉出例如乙二醇單甲基醚、乙二醇單 乙基醚、乙二醇單異丙基醚、乙二醇單丁基醚、乙二醇 單己基醚、甲氧基甲氧乙醇、二乙二醇單曱基醚、二乙 二醇單乙基醚、二乙二醇單丁基醚、二乙二醇單甲基醚 乙酯、二乙二醇單乙基醚乙酯、二乙二醇單丁基醚乙酯 、三乙二醇單甲基醚、三乙二醇單乙基醚、丙二醇單曱 基醚、二丙二醇單甲基醚乙酯、丙二醇單乙基醚、丙二 醇異丙基醚、丙二醇單丁基醚、丙二醇單甲基醚乙酯、 丙二醇單乙基醚乙酯、1 —丁氧基乙氧基丙醇、1 —曱氧 基一2 _丙基乙S旨、1，3 — 丁二醇二乙醋、1，6 —己二 醇二乙酯等。 作為酯系溶劑可舉出例如乳酸乙基、乳醜丙烷、乳酸丁 作為酮系溶劑可舉出例如環己酮、乙基胺酮、二丙酮醇 、二異丁酮、異佛酮、甲基環己酮、苯乙酮等。 其中，從顏料分散性及喷墨墨水噴出性的觀點考量，作 為1種類單獨或2種以上之混合物，尤以使用70%以上之 常壓（1氣壓）下沸點為200°C〜300°C之溶劑為宜。進一 步而言，該溶劑之常壓（1氣壓）下沸點若為200°C〜280 °C，則具有適度的乾燥性，因此可提高生產性，故更適 宜。 進一步而言，為了獲得良好的顏料分散性或喷出性，可 適宜地使用二乙二醇單乙基醚乙酯、二乙二醇單丁基醚 乙酯、二丙二醇單曱基醚乙酯、二丙二醇單曱基醚乙酯 、1，3 — 丁二醇二乙酯、1，6 —己二醇二乙酯等。 [活性能量線聚合性單體] 表單編號A0101 第28頁/共76頁 本發明之彩色濾光片用著色組成物所含有的活性能量線 聚合性單體，係意味藉由照射活性能量線而硬化並生成 透明樹脂，具有乙烯性不飽和雙重結合之化合物，亦包 含單體中一般稱為寡聚物、平均分子量小於1 000程度之 低聚物，且具有乙烯性不飽和雙重結合之物。 作為活性能量線聚合性單體可舉出： 甲基（甲基）丙烯酸酯、乙基（曱基）丙烯酸酯、丙基 (甲基）丙烯酸酯、異丙基（甲基）丙烯酸酯、丁基（ 甲基）丙烯酸酯、異丁基（甲基）丙烯酸酯、t一丁基（ 甲基）丙烯酸酯、異戊基（甲基）丙烯酸酯、辛基（甲 基）丙烯酸酯、異辛基（甲基）丙烯酸酯、2 —乙基己基 (甲基）丙烯酸酯、十六烷基（甲基）丙烯酸酯、癸基 (甲基）丙烯酸酯、異癸基（甲基）丙烯酸酯、月桂基 (甲基）丙烯酸酯、十三（甲基）丙烯酸酯、異肉豆蔻 基（甲基）丙烯酸酯、硬酯醯（曱基）丙烯酸酯或硬酯 醯（甲基）丙烯酸酯等直鏈狀或分枝狀您=4 (曱基）丙 烯酸酯類； 環己基（曱基）丙烯酸酯、三級丁基環己基（甲基）丙 烯酸酯、二環戊基（甲基）丙烯酸酯、二環五氧乙基（ 曱基）丙烯酸酯、二環戊烯基（曱基）丙烯酸酯、二環 戊烯氧乙基（甲基）丙烯酸酯或異冰片基（曱基）丙烯 酸酯等環狀烷基（甲基）丙烯酸酯類； 三氟乙基（甲基）丙烯酸酯、辛氟戊基（甲基）丙烯酸 酯、全氟辛基乙基（曱基）丙烯酸酯或四氟丙基（甲基 )丙烯酸酯等氟烷基（甲基）丙烯酸酯類； (甲基）丙烯醯氧改性聚二曱基矽氧烷（矽高分子單體 表單編號A0101 第29頁/共76頁 201031713 )類； 四氫糠基（甲基）丙烯酸酯或3—甲基—3 —氧雜環丁基 (甲基）丙烯酸酯等具有雜環之（曱基）丙烯酸酯類； 苄基（甲基）丙烯酸酯、笨氧乙基（曱基）丙烯酸酯、 苯氧基聚乙二醇（甲基）丙烯酸酯、對枯基苯氧乙基（ 甲基）丙烯酸酯、對枯基苯氧基聚乙二醇（甲基）丙烯 酸酯或壬基苯氧基聚乙二醇（甲基）丙烯酸酯等具有芳 香族環之（曱基）丙烯酸酯類； 2—甲氧基乙基（甲基）丙稀酸醋、2 —乙氧基（甲基） 丙婦酸8旨、3 —甲氧基丁基（甲基）丙缔酸酿、2 —曱氧 © 基丙基（甲基）丙稀酸酯，二:乙二酵译.甲基喊（甲基） 丙烯酸酯、二乙二醇單乙基蜮（甲基·).丙烯酸酯、三乙 一醇早甲基鍵(甲基、）丙蛛故醋、三6二:_單乙基趟（ 曱基）丙浠酸酯、二6二醇單一2—乙基己基醚（甲基） 丙烯酸酯、二乙二醇單甲基醚（甲基）丙烯酸酯、三丙 二醇單（甲基）丙烯酸酯4丨聚象肩基醚（甲基 )丙烯酸醋或聚乙二酵單硬酯基醚：（甲基）丙烯酸酯等 (聚）烯烴基:二醇單烷基故<甲基）丙烯酸酯類； Θ (甲基）丙烯酸、丙稀酸二聚物、衣康酸、順丁稀二酸 、富馬酸、巴豆酸、2—(曱基）丙烯醯氧酞酸乙酯、2 一（甲基）丙烯醯氧酞酸丙酯、2—(甲基）丙烯醯氧狄 酸六氫乙酯、2—（曱基）丙烯醯氧酞酸六氫丙酯 '環氧 乙烷改性琥珀酸（甲基）丙烯酸醋、沒一羧基乙基（曱 基）丙烯酸酯或ω —羧基己内酯（甲基）丙烯酸酯等具 有羧基之（甲基）丙烯酸酯類； 2—羥基乙基（甲基）丙烯酸酯、2 —羥基丙基（甲基） 表單編號Α0101 第30頁/共76頁 丙烯酸酯、2 —羥基丁基（甲基）丙烯酸酯、4-羥基丁 基（甲基）丙稀酸醋、2 —丙婦酿氧乙基一 2 —經基乙基 (甲基）丙烯酸酯、二乙二醇單（甲基）丙烯酸酯、二 丙二醇單（曱基）丙烯酸酯、聚乙二醇單（甲基）丙稀 酸酯、丙二醇單（甲基）丙烯酸酯、聚丙二醇單（甲基 )丙烯酸酯、聚伸丁二醇單（甲基）丙烯酸酯、聚（乙 二醇一丁二醇）單（曱基）丙烯酸酯、聚（乙二醇—伸 丁二醇）單（曱基）丙烯酸曄、聚（丙二醇一伸丁二醇 )單（甲基）丙烯酸酯或丙三醇（甲基）丙烯酸酯等具 有羥基之（曱基）丙v烯酸酶類； 乙二醇二（甲基）丙烯酸酯二乙二酵二·（曱基）丙烯 酸酯、三乙二醇二（曱基）丙烯酸.輯、·聚乙;=1醇二（甲 基）丙烯酸醋、丙二醇二（甲基）丙烯臉'輯、二丙二醇 : ，:::夕. 二（甲基）丙烯酸醋、三丙二醇二（甲基）丙烯酸酯、 聚丙二醇二（甲基）丙烯酸酯、聚（乙二醇一呙二醇） 二（甲基）丙烯酸酯、聚乙二醇）二 (甲基）丙烯酸酯、聚（ 乙二醇）二（ 甲基）丙烯酸酿、聚四甲(甲基）丙烯酸酯 、1，3_ 丁二醇二（甲基）丙烯酸酯、新戊二醇二（曱 基）丙烯酸酯、1，6—己二醯二（曱基）丙烯酸酯、1， 9 —壬二醇二（曱基）丙婦酸酯或2 —曱基，2_ 丁基一丙 二醇二（曱基）丙稀酸醋等（聚）稀炫基一醇一（甲基 )丙稀酸酯類； 二羥曱基二環戊二（曱基）丙烯酸酯、羥基三甲基乙酸 新戊二醇二（甲基）丙烯酸酯、硬酯酸改性新戊四醇二 (甲基）丙烯酸酯、環氧乙烷改性雙酚八二（曱基）丙烯 表單編號Α0101 第31頁/共76頁 201031713 酸酯、環氧丙烷改性雙酚A二（甲基）丙烯酸酯、氧化伸 丁基改性雙酚A二（甲基）丙烯酸酯、環氧乙烷改性雙酚 F二（甲基）丙烯酸酯、環氧丙烷改性雙酚F二（曱基） 丙烯酸酯、氧化伸丁基改性雙酚F二（甲基）丙烯酸酯、 二丙烯酸鋅、環氧乙烷改性磷酸三丙烯酸酯或丙三醇二 (甲基）丙烯酸酯等二（甲基）丙烯酸酯類； 二甲基胺乙基（曱基）丙烯酸酯、二乙基胺乙基（曱基 )丙烯酸酯、二甲基胺丙基（甲基）丙烯酸酯或二乙基 胺丙基（甲基）丙烯酸酯等具有三級胺基之（甲基）丙 烯酸酯類； 丙三醇三（甲基）丙烯酸酯、三羥甲基丙烷（曱基）丙 烯酸酯、新戊四醇（曱基）丙烯酸酯、新戊四醇四（曱 基）丙烯酸酯、二新戊四醇五（曱基）丙烯酸酯或二新 戊四醇六（甲基）丙烯酸酯等三官能（曱基）丙烯酸酯 丙三醇三縮水甘油基醚一（曱基）丙烯酸附加物、丙三 醇二縮水甘油基醚一（曱基）丙烯酸附加物、聚丙三醇 聚縮水甘油基醚一（曱基）丙烯酸附加物、1，6_ 丁二 醇二縮水甘油基醚、烷基縮水甘油基醚一（甲基）丙烯 酸附加物、芳香基縮水甘油基醚一（曱基）丙烯酸附加 物、苯基縮水甘油基醚_(甲基）丙烯酸附加物、環氧 苯乙烯_(曱基）丙烯酸附加物、雙酚A二縮水甘油基醚 _(曱基）丙烯酸附加物、環氧丙烯改性雙酚二縮水甘 油基醚（甲基）丙烯酸附加物、雙酚A二縮水甘油基醚一 (曱基）丙烯酸附加物、表氣醇改性苯二曱酸一（甲基 )丙烯酸附加物、表氣醇改性六氫苯二曱酸一（甲基） 表單編號A0101 第32頁/共76頁 201031713 丙烯酸附加物、乙二醇二縮水甘油基醚—（甲基）丙烯 酸附加物、聚乙二醇二縮水甘油基醚_(曱基）丙烯酸 附加物、丙二醇二縮水甘油基醚_(甲基）丙烯酸附加 物、聚丙二醇二縮水甘油基醚一（甲基）丙烯酸附加物 、紛搭型環氧樹脂—（甲基）丙稀酸附加物、甲盼型環 氧樹脂一（甲基）丙烯酸附加物或其他環氧樹脂—（甲 基）丙烯酸附加物等環氧（甲基）丙烯酸酯類； (甲基）丙烯醯氧改性聚異氰酸、（甲基）丙烯醯氧改 性聚氨酯、（甲基）丙烯醯乳改性聚酯、（甲基）丙烯 醯氧改性三聚氰胺、（甲基）丙烯醢氧改性矽、（甲基 )丙烯醯氧改性改性丁二稀.典（巧:基冬稀醯氡改性松 香等（甲基)丙烯酿氧改性._旨寡..聚,_類；/v 苯乙烯、α —甲基苯乙烯、醋酸乙烯、Γ甲基）丙烯酸 乙烯及（甲基）丙烯酸烯丙基等乙烯類； 羥基乙基乙烯醚、乙二醇二乙烯醚或新戊四醇三乙烯醚 等乙烯醚類； (甲基）___丙稀酿胺、N—·經Resin type pigment dispersant manufactured by Lubrizol; or EFKA-46, 47, 48, 452, 4Ρ4〇α8-, 4(10)9? LP4010, LP4050, LP4055, 400, 403, 450, 451, 1 453, 4540, 4550, υ&gt ; 45^^·^^Γ^^1501, 1502 or 1503, etc. Resin type pigment dispersing agent manufactured by EFKA Chemical Co., Ltd.; is not limited to these 'any resin type pigment dispersing agent can be used, and these may be used alone or in combination 2 More than one kind to use. Brel1 : , which is particularly suitable for the resin type. ^Gfif^^W02008/0〇7776 .#·% ff! In the molecular range, in the presence of two compounds with a 43⁄4 thiol group, the ethyl group A polyester dispersant obtained by radical polymerization of an unsaturated monomer and having a hydroxyl group in a vinyl copolymer of two hydroxyl groups in a single terminal region and an acid anhydride group in a tetracarboxylic dianhydride. The color filter coloring composition using these polyester dispersants not only has good dispersion stability of the pigment, but also can reduce the dielectric tangent, and thus is not easily affected by the characteristics of the motor. The synthesis method of these resin-type dispersants can be synthesized by the method described in WO2008/007776. (Surfactant) Form No. A0101 Page 25 of 76 sheets 201031713 As the surfactant, the following are mentioned: Polyethylene oxide ether sulfate, sodium dodecylbenzenesulfonate, styrene-acrylic acid copolymer Acrylate, sodium alkylnaphthalene sulfonate, sodium alkyl diphenyl ether disulfonate, ethanolamine lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, ethanolamine stearate, ammonium stearate, sodium lauryl sulfate An anionic surfactant such as monoethanolamine or polyethylene oxide ether phosphate of styrene-acrylic acid copolymer; polyethylene oxide oleyl ether, polyethylene oxide lauryl ether, polyethylene oxide phenyl ether, Nonionic surfactant such as polyethylene oxide ether phosphate, polyethylene oxide sorbitan glyceryl stearic acid or polyethylene glycol monolauryl ester; alkyl 4-grade ammonium salt or its equivalent epoxy B a cationic surfactant such as an alkane addenda; an alkyl lysine inner salt such as a quaternary ammonium carboxylic acid quaternary ammonium salt; or an amphoteric surfactant such as an alkyl imidazoline; It can be used alone or in combination of two or more. [Solvent] The coloring composition for a color filter of the present invention may contain a solvent so that the pigment is easily dispersed in the copolymer and the resin binder, and coated on a transparent substrate such as glass. The filter film section is formed by drying the film thickness of 0.2 to 5. Examples of the solvent include 1,2,3-tripropane, 1,3-butanediol diacetate, 2-heptanone, and 3,3,5-trimethyl-2-cyclohexene-1-one. , 3,5,5-trimethylcyclohexanone, 3-ethoxypropionic acid ethyl, 3-methoxy-3-methyl-butyl acetate, 3-methoxybutanol, 3-methoxy Butyl acetate, 4-heptanone, m-xylene, m-diethylbenzene, m-diox, N,N-dimercaptoacetamide, n-butylbenzene, n-propyl acetate, N-pyrrolidone Form No. A0101 Page 26 of 76, o-xylene, o-chlorophenyl, o-diethylbenzene, o-dichlorobenzene, p-chlorotoluene, p-diethylbenzene, dibutylbenzene, tertiary butylbenzene, isophorone, Ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol monopropyl ether, diisobutyl ketone Cyclohexanol acetate, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monobutyl ether, diacetone alcohol, propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol Monomethyl ether Propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether propionate, stupyl alcohol, mercapto isobutyl ketone, nonylcyclohexanol, n-amyl acetate, n-butyl acetate, isoamyl acetate, isobutyl acetate , propyl acetate, dibasic acid ester, etc., these may be used singly or in combination. It is preferable to have at least a cyclohexylethyl ester composition, whereby the coloring layer of the coloring composition for a color filter of the present invention can be obtained with good flatness. The content of the cyclohexylethyl ester is from 3 to 35% by weight, more preferably from 5 to 25% by weight, based on the total mass of the coloring composition for a color filter. The content of the cyclohexylethyl ester exceeds 35% by weight _1. When the applied coating film is prebaked, the organic solvent is not evaporated and remains in the dried coating film, and adhesiveness may remain (dry coating film) Adhesiveness of the surface) When the coloring composition of the present invention is used as an inkjet ink, it is selected as a solvent from the viewpoints of solubility to a resin, swelling effect on a device member, viscosity, and ink dryness in a nozzle. The solvent may be used alone or in combination of two or more kinds thereof, for example, an alcohol solvent, a glycol solvent, an ester solvent, a ketone solvent, or the like. The alcohol solvent may, for example, be hexanol, heptanol, octanol, decyl alcohol, decyl alcohol, undecyl alcohol, cyclohexanol, benzyl alcohol or amine alcohol. Form No. A0101 Page 27 of 76 sheets 201031713 Examples of the glycol solvent include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monoisopropyl ether, and ethylene glycol monobutylene. Ether, ethylene glycol monohexyl ether, methoxymethoxyethanol, diethylene glycol monodecyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monomethyl Ethyl ether, diethylene glycol monoethyl ether ethyl ester, diethylene glycol monobutyl ether ethyl ester, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monodecyl ether , dipropylene glycol monomethyl ether ethyl ester, propylene glycol monoethyl ether, propylene glycol isopropyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether ethyl ester, propylene glycol monoethyl ether ethyl ester, 1-butoxy B Oxypropanol, 1-methoxyl-2 propyl propyl, 1,3, butanediol diacetate, 1,6-hexanediol diethyl ester, and the like. Examples of the ester-based solvent include lactic acid ethyl group, lactic acid propylene, and lactic acid butyl. Examples of the ketone solvent include cyclohexanone, ethyl ketone, diacetone alcohol, diisobutyl ketone, isophorone, and methyl group. Cyclohexanone, acetophenone, and the like. In particular, from the viewpoint of the pigment dispersibility and the inkjet ink discharge property, the boiling point of 200 ° C to 300 ° C is usually used as a mixture of one type or two or more types at a normal pressure (1 atmosphere) of 70% or more. The solvent is preferably used. Further, when the boiling point of the solvent at normal pressure (1 atm) is 200 ° C to 280 ° C, it has moderate dryness, so that productivity can be improved, so that it is more suitable. Further, in order to obtain good pigment dispersibility or squirting property, diethylene glycol monoethyl ether ethyl ester, diethylene glycol monobutyl ether ethyl ester, dipropylene glycol monodecyl ether ethyl ester may be suitably used. , dipropylene glycol monodecyl ether ethyl ester, 1,3-butanediol diethyl ester, 1,6-hexanediol diethyl ester, and the like. [Active energy ray polymerizable monomer] Form No. A0101 Page 28 of 76 The active energy ray-polymerizable monomer contained in the coloring composition for a color filter of the present invention means that the active energy ray is irradiated. A compound which hardens and forms a transparent resin having a double bond of ethylenic unsaturation, and also contains an oligomer which is generally called an oligomer, has an average molecular weight of less than 1,000, and has an ethylenically unsaturated double bond. Examples of the active energy ray-polymerizable monomer include methyl (meth) acrylate, ethyl (mercapto) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, and butyl. (meth) acrylate, isobutyl (meth) acrylate, t-butyl (meth) acrylate, isopentyl (meth) acrylate, octyl (meth) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, hexadecyl (meth) acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, Lauryl (meth) acrylate, thirteen (meth) acrylate, isomyristyl (meth) acrylate, stearin oxime (meth) acrylate or hard oxime (meth) acrylate Chain or branched, you = 4 (fluorenyl) acrylates; cyclohexyl (decyl) acrylate, tert-butyl butyl cyclohexyl (meth) acrylate, dicyclopentyl (meth) acrylate, Bicyclopentaethoxyethyl (decyl) acrylate, dicyclopentenyl (mercapto) acrylate, a cyclic alkyl (meth) acrylate such as dicyclopentene oxyethyl (meth) acrylate or isobornyl (mercapto) acrylate; trifluoroethyl (meth) acrylate, octfluent Fluoroalkyl (meth) acrylates such as (meth) acrylate, perfluorooctylethyl (fluorenyl) acrylate or tetrafluoropropyl (meth) acrylate; (methyl) propylene oxime Modified polydidecyl fluorene oxide (矽 polymer monomer form No. A0101, page 29 / page 76, 201031713); tetrahydroindenyl (meth) acrylate or 3-methyl-3-oxy heterocycle a heterocyclic (fluorenyl) acrylate such as butyl (meth) acrylate; benzyl (meth) acrylate, phenoxyethyl (decyl) acrylate, phenoxy polyethylene glycol (A) Acrylate, p-cumylphenoxyethyl (meth) acrylate, p-cumylphenoxy polyethylene glycol (meth) acrylate or nonyl phenoxy polyethylene glycol (meth) acrylate (Alkyl) acrylates having an aromatic ring such as ester; 2-methoxyethyl (meth) acrylate vinegar, 2-ethoxyl Methyl) propyl acetoate 8 , 3-methoxy butyl ( methyl ) propionic acid broth , 2 - oxime propyl propyl ( methyl ) acrylate , 2 : acetylene translation . Base shouting (meth) acrylate, diethylene glycol monoethyl hydrazine (methyl). acrylate, triethyl alcohol early methyl bond (methyl,) propane vinegar, three 6 two: _ single B Base (mercapto) propionate, di 6 glycol mono-2-ethylhexyl ether (meth) acrylate, diethylene glycol monomethyl ether (meth) acrylate, tripropylene glycol mono (methyl Acrylate 4丨 poly-collixyl ether (meth)acrylic acid vinegar or poly(ethylene glycol) monostearyl ether: (meth) acrylate or the like (poly) olefin group: diol monoalkyl group < methyl Acrylates; Θ (meth)acrylic acid, acrylic acid dimer, itaconic acid, butyl butyric acid, fumaric acid, crotonic acid, 2-(indenyl) propylene oxime oxime, 2 propyl (meth) propylene sulfonate, hexahydroethyl 2-(methyl) propylene phthalate, hexahydropropyl 2-(indenyl) propylene sulfonate oxirane Modified succinic acid (meth) acrylate vinegar, no one a (meth) acrylate having a carboxyl group such as carboxyethyl (indenyl) acrylate or ω-carboxycaprolactone (meth) acrylate; 2-hydroxyethyl (meth) acrylate, 2- hydroxy propyl Base (methyl) Form No. Α0101 Page 30 of 76 Acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate vinegar, 2- propylene fossil Ethyl-2-yltransethylethyl (meth) acrylate, diethylene glycol mono (meth) acrylate, dipropylene glycol mono (decyl) acrylate, polyethylene glycol mono (meth) acrylic acid Ester, propylene glycol mono (meth) acrylate, polypropylene glycol mono (meth) acrylate, polybutane diol mono (meth) acrylate, poly (ethylene glycol monobutyl diol) mono (indenyl) acrylic acid Ester, poly(ethylene glycol-butane diol) mono(indenyl) yttrium acrylate, poly(propylene glycol monobutylene glycol) mono(meth) acrylate or glycerol (meth) acrylate, etc. (fluorenyl) propanyl enoate; ethylene glycol di(meth) acrylate diethylene glycol disaccharide Acrylate, triethylene glycol bis(indenyl)acrylic acid, series, polyethylene; =1 alcohol di(meth)acrylic acid vinegar, propylene glycol di(meth)acrylic face, dipropylene glycol: ,:::夕. Di(meth)acrylic acid vinegar, tripropylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, poly(ethylene glycol monodecanediol) di(meth)acrylate, polyethyl b. Glycol) di(meth)acrylate, poly(ethylene glycol) di(meth)acrylic acid, polytetramethyl (meth)acrylate, 1,3-butanediol di(meth)acrylate, new Pentyl glycol bis(indenyl) acrylate, hexamethylene bis(indenyl) acrylate, 1,9-nonanediol bis(indenyl)propionate or 2-mercapto, 2- butyl (poly)throlyl-alcohol mono(methyl) acrylates; dihydroxyindenyl dicyclopentadienyl (mercapto) acrylate, hydroxy trimethyl Neopentyl glycol di(meth)acrylate, stearic acid modified neopentyl alcohol di(meth)acrylate, ethylene oxide modified bisphenol octa Propylene Form No. Α0101 Page 31 of 7631731713 Acidate, propylene oxide modified bisphenol A di(meth) acrylate, butyl oxide modified bisphenol A di(meth) acrylate, epoxy Ethane modified bisphenol F di(meth) acrylate, propylene oxide modified bisphenol F bis(indenyl) acrylate, butyl oxide modified bisphenol F di(meth) acrylate, diacrylic acid Di(meth)acrylates such as zinc, ethylene oxide modified phosphoric acid triacrylate or glycerol di(meth)acrylate; dimethylamine ethyl (mercapto) acrylate, diethylamine a (meth) acrylate having a tertiary amino group such as ethyl (mercapto) acrylate, dimethylaminopropyl (meth) acrylate or diethylaminopropyl (meth) acrylate; Triol tri(meth)acrylate, trimethylolpropane (mercapto) acrylate, neopentyl alcohol (mercapto) acrylate, neopentyltetrakis(mercapto) acrylate, dipentaerythritol Trifunctional (fluorenyl) propylene such as penta(indenyl) acrylate or dipentaerythritol hexa(meth) acrylate Ethylglycerol triglycidyl ether mono(indenyl)acrylic acid addenda, glycerol diglycidyl ether mono(indenyl)acrylic acid addenda, polyglycerol polyglycidyl ether mono(indenyl)acrylic acid , 1,6-butanediol diglycidyl ether, alkyl glycidyl ether mono(meth)acrylic acid addenda, aryl glycidyl ether mono(indenyl)acrylic acid addenda, phenyl glycidyl ether _(Meth)acrylic acid addenda, epoxy styrene _(mercapto) acrylate addenda, bisphenol A diglycidyl ether _(mercapto) acrylate addenda, propylene oxide modified bisphenol diglycidyl Ether (meth)acrylic acid addenda, bisphenol A diglycidyl ether mono(indenyl)acrylic acid addenda, surface gas alcohol modified phthalic acid mono(meth)acrylic acid addenda, surface alcohol modified six Hydroquinone mono(methyl) Form No. A0101 Page 32 of 76 201031713 Acrylic Addenda, Ethylene Glycol Diglycidyl Ether - (Meth) Acrylate Addenda, Polyethylene Glycol Diglycidyl Ether _(mercapto) acrylic addenda, propylene Diglycidyl ether_(meth)acrylic acid addenda, polypropylene glycol diglycidyl ether mono(meth)acrylic acid addendum, lapped epoxy resin-(meth)acrylic acid addenda, acetaminophen Epoxy (meth) acrylate addenda or other epoxy resin - (meth) acrylate addenda and other epoxy (meth) acrylates; (methyl) propylene oxime modified poly isocyanic acid, ( Methyl) propylene oxime modified polyurethane, (meth) propylene oxime modified polyester, (meth) propylene oxime modified melamine, (meth) propylene oxime modified ruthenium, (meth) propylene oxime Oxygen-modified modified dibutyl sulphur. Code: Qiao: xylan-modified rosin and other (methyl) propylene brewing oxygen modification. _ oligo.. poly, _ class; / v styrene, α - A Ethylene such as styrene, vinyl acetate, hydrazine methyl) acrylate and allyl (meth) acrylate; vinyl ethers such as hydroxyethyl vinyl ether, ethylene glycol divinyl ether or neopentyl alcohol trivinyl ether ; (methyl)___ propylene thin amine, N-·

^ T US. ^ . 1 « II # I 丙烯醯胺或N 一乙烯甲醯胺等醯胺類；邊 丙烯腈等。該等可單獨或混合2種以上使用。 [熱聚合性單體] 本發明之彩色濾光片用著色組成物所含有的熱聚合性單 趙係指在常溫下為非反應性，例如於以上（更宜為 150C以上）之溫度下，顯示出架橋反應、聚合反應、縮 合聚合反應或附加聚合反應之化合物。可用於本發明之 著色組成物之前述熱聚合性單體的分子量並未特別限定 ，宜為50〜2, 000，更宜為】〇〇〜！，〇〇〇。 表單編號A0101 第33頁/共76頁 201031713 作為熱聚合性單體可使用例如三聚氰胺化合物、苯并胍 胺、環氧化合物、氧雜環丁烷化合物、笨酚化合物、苯 并噁嗪化合物、嵌段化羧酸化合物、嵌段化異氰酸酯化 合物及矽烷耦合劑。更宜至少包含三聚氰胺化合物、笨 并胍胺化合物。由於三聚氰胺化合物、苯并胍胺化合物 能夠以少許的添加量賦予高耐受性，因此可減低熱聚合 性單體的添加量，有助於喷墨記錄用墨水組成物之顏料 濃度提高或經時穩定性的提升。 作為三聚氰胺化合物或笨并胍胺化合物可舉出例如具有 亞胺基、羥甲基、烷氧甲塞之物*其中尤以含有烧氧基 烷基之三聚氰腦化合物或笨并胍胺化合物.為宜。使用含 有烷氧基烷基之三聚氰胺化合物或笨并胍胺:ft*合物時， 含有本發明之著色組成物之塗料或墨水的保存穩定性顯 著提升。 作為含有烷氧基烷基之三聚氰胺化合物或笨并胍胺化合 物，可舉出例如六甲氧基甲!基&策氣撼|〖六丁氧基羥 甲基三聚氰胺、四甲氧基ϋ'基采并胍胺、四丁氧基羥 甲基苯并胍胺等，但未必备限★兵婊等。 作為三聚氰胺化合物之市售品的具體例舉出如下。但未 必要限定於該等。 三和化學公司製NIKALAC MW-30M、MW-30、MW-22、 MS-21、MS-11、MW —24X、MS —001、MX-002、MX -730 ' MX750 ' MX-708 > MX-706 ' MX-042 ' MX-035、MX-45、MX- 500、MX- 520、MX-43、MX-417 、MX-410、MX —30 ;日本Scitex工業公司製兮八以-ERU300、301、303、350、370、325、327、703、712 表單編號A0101 第34頁/共76頁 、01、285、232、235、236、238、211、254、204 ' 202、207、MYCOAT506、508、212、715 等。 其中尤其適宜者為含有烷氧基烷基之三聚氰胺化合物， 即三寿口4匕學公司製NIKALAC MW-30M ' MW-30 ' MW-22 、MS-21、MX-45、MX-500、MX —520、MX-43、MX -302、日本Scitex工業公司製SAIMERU300、301、 303、350、285、232、235、236、238、MYCOAT506、 508 等。 作為苯并胍胺化合物之市售品的具體例可舉出例如三和 化學公司製NIKALAC BX-4000、SB — 401、BX-37、^ T US. ^ . 1 « II # I Amidoxime or N-vinylformamide such as decylamine; acrylonitrile. These may be used alone or in combination of two or more. [Thermopolymerizable monomer] The thermally polymerizable monozole which is contained in the coloring composition for a color filter of the present invention is non-reactive at normal temperature, for example, at a temperature above (more preferably 150 C or more). A compound exhibiting a bridging reaction, a polymerization reaction, a condensation polymerization reaction or an additional polymerization reaction. The molecular weight of the above-mentioned thermally polymerizable monomer which can be used in the colored composition of the present invention is not particularly limited, and is preferably from 50 to 2,000, more preferably 〇〇~! , hehe. Form No. A0101 Page 33 / Total 76 pages 201031713 As the thermally polymerizable monomer, for example, a melamine compound, a benzoguanamine, an epoxy compound, an oxetane compound, a phenol compound, a benzoxazine compound, or the like can be used. A segmented carboxylic acid compound, a blocked isocyanate compound, and a decane coupling agent. More preferably, it contains at least a melamine compound, a stupid and a guanamine compound. Since the melamine compound and the benzoguanamine compound can impart high tolerance in a small amount of addition, the amount of the thermally polymerizable monomer can be reduced, and the pigment concentration of the ink composition for inkjet recording can be improved or the time is lapsed. Increased stability. The melamine compound or the cuminamide compound may, for example, be an imine group, a methylol group or an alkoxymethyl group; the melamine compound or the benzoate compound containing an alkoxyalkyl group in particular. It is appropriate. When a melamine compound containing alkoxyalkyl group or a benzoic acid: ft* compound is used, the storage stability of the coating or ink containing the colored composition of the present invention is remarkably improved. Examples of the melamine-containing melamine compound or the benzoic acid-containing amide compound include hexamethoxymethyl group and gas oxime | hexabutoxymethylol melamine and tetramethoxy fluorene. The combination of indoleamine, tetrabutoxymethylolbenzamide, etc., but not limited to ★ soldiers and so on. Specific examples of the commercial product of the melamine compound are as follows. However, it is not necessary to be limited to these. Sanwa Chemical Co., Ltd. NIKALAC MW-30M, MW-30, MW-22, MS-21, MS-11, MW — 24X, MS — 001, MX-002, MX - 730 ' MX750 ' MX-708 > MX -706 'MX-042 ' MX-035, MX-45, MX-500, MX- 520, MX-43, MX-417, MX-410, MX-30; Japan Scitex Industrial Co., Ltd. 301, 303, 350, 370, 325, 327, 703, 712 Form No. A0101 Page 34 / Total 76, 01, 285, 232, 235, 236, 238, 211, 254, 204 '202, 207, MYCOAT506, 508, 212, 715, etc. Particularly suitable among them is a melamine compound containing an alkoxyalkyl group, that is, NIKALAC MW-30M 'MW-30 'MW-22, MS-21, MX-45, MX-500, MX manufactured by Sanshoukou 4匕学公司. - 520, MX-43, MX-302, SAIMERU 300, 301, 303, 350, 285, 232, 235, 236, 238, MYCOAT 506, 508, etc., manufactured by Scitex Industrial Co., Ltd., Japan. Specific examples of the commercial product of the benzoguanamine compound include, for example, NIKALAC BX-4000, SB-401, BX-37, manufactured by Sanwa Chemical Co., Ltd.

255、SB-ERU105、 SB —355、SB —303、SB30!.>.bl 203、SB，201 ;日本Sci 106、1128等。 其中尤其適宜者為含有烷氧基烷基之苯并胍胺化合物， 即三和化學公司製NIKALAC BX —400&、SB — 401、日本255, SB-ERU105, SB-355, SB-303, SB30!.>.bl 203, SB, 201; Japan Sci 106, 1128, and the like. Particularly suitable among them are benzoguanamine compounds containing an alkoxyalkyl group, namely NIKALAC BX-400 & SB-401, manufactured by Sanwa Chemical Co., Ltd., Japan

Sc i tex工業公.司製SAIMElifTlB|@cfud 作為環氧化合物可舉出例^|:_二籍水甘油基醚、雙 甲酚芴二縮水甘油基醚、雙乙醇苟二縮水甘油基 鰱、新戊二醇二縮水甘油基喊、1，6—己二醇二縮水甘 油基醚、丙三醇聚縮水甘油基醚、三羥甲基丙烷聚縮水 甘油基醚、新戊四醇聚縮水甘油基醚、二丙三醇聚縮水 甘油基醚、山梨糖醇聚縮水甘油基醚、二縮水甘油基對 苯二甲酸酯、二縮水甘油基鄰苯二甲酸酯、乙二醇二縮 水甘油基醚、二乙二醇二縮水甘油基醚、聚乙二醇二縮 水甘油基醚及聚丙二醇二縮水甘油基醚等聚酵的縮水甘 油基謎、聚縮水甘油基異氣駿g旨等，但未必要限定於該 表單編號A0101 第35頁/共76頁 201031713 等。 氧雜環丁烷化合物可舉出例如3 —乙基_3_羥基曱基氧 雜環丁烧、1, 4 一雙[〔（3 —乙基氧雜環丁烧一3 —基） 甲氧基〕甲基]苯、雙〔1—乙基（3—氧雜環丁基）〕曱 基鍵、3 —乙基一3 — (2 —乙基己氧基甲基）氧雜環丁烧 、3_乙基一3 —（苯氧基曱基）氧雜環丁烧、3 —乙基一 3—(環己氧基）甲基氧雜環丁烷、氧雜環丁基倍半矽氧 烷、氧雜環丁基矽化物、酚醛氧雜環丁烷、1, 3 —雙〔 (3—乙基氧雜環丁烷一3 —基）甲氧基〕笨、1，4雙[〔 (3—乙基氧雜環丁烷一3 —基）曱氧基〕曱基]聯苯、1 —乙基一3_氧雜環丁基甲基丙稀酸甲醋、苯_1，4_二 羧酸雙〔1_乙基（3 _氧雜環丁基）甲基〕酯等，但未 必要限定於該等。 作為苯酚化合物可使用例如在酸性觸媒下，使苯酚類與 醛類反應所得之酚醛型苯酚化合物，或於鹼性觸媒下反 應所得之可溶型苯酚化合物之任一者。作為苯酚類可舉 出例如鄰甲酚、對甲酚、對苯基苯酚、對壬基苯酚、2， 3 —茗盼、苯盼、甲基曱盼、3, 5 —茗盼、間苯二盼、兒 茶酚、對苯二酚、雙苯酚A、雙苯酚F、雙笨酚B、雙笨酚 E、雙苯酚Η、雙苯酚S等。作為醛類可舉出曱醛、乙醛。 苯酚類與醛類可分別單獨使用1種，或混合2種以上使用 〇 作為苯并噁嗪化合物之市售品的具體例，可舉出例如四 國化成工業公司製苯并噁嗪P — d型、苯并噁嗪F —a型等 ，但未必要限定於該等。 作為嵌段化羧酸化合物，羧酸化合物可舉出例如1，2 — 表單編號A0101 第36頁/共76頁 苯二甲酸、1，3—苯二甲酸、1，4—苯二曱酸、1，2， 4—苯三曱酸、苯四甲酸、環己烷二羧酸、琥珀酸、己二 酸、丁烷四羧酸、順丁烯二酸、富馬酸、巴豆酸、C1 — CIC酸、CIC酸、C3 — CIC酸、Bis —CIC酸等，但未必要 限定於該等。作為嵌段劑可舉出例如乙基乙烯醚、η—丙 基乙烯醚、異丙基乙烯醚、η — 丁基乙烯醚、異丁基乙烯 醚、三級丁基乙烯醚、2_乙基己基乙烯醚等，但未必要 限定於該等。又，可單獨使用1種或混合2種以上同時使 用。 作為嵌段化異氰酸酯化合物之異氰酸酯化合物，可舉出 例如環己二異氰酸酯、異佛酮二異氰酸酯、曱苯胺二異 氰酸酯、二苯基甲烷一4，二異氡δ隻酯、二苯基曱 烷一2，4’一異氰酸酯、雙（4 —異氰酸酯環己基）甲烷 、四甲基二曱苯二異氰酸酯等二異氰酸酯、該等二異氰 酸酯之異氰酸酯體、三羥甲丙烷加成物型、雙脲型、具 有異氰酸酯殘基之預聚物聚醇所獲得 的低聚物）及具有異氰酸酮等，但未必 要限定於該等。 ' 作為嵌段劑可舉出例如笨酚（解離溫度180°C以上）、ε 一己内醯胺（解離溫度160〜180°C)、肟（解離溫度 130〜160°C )或活性甲烷（100〜120°C )等，但未必要 限定於該等。又，可單獨使用1種或混合2種以上同時使 用。 作為矽烷耦合劑可舉出例如乙烯三（yS —曱氧基以氧基 )矽烷、乙烯乙氧基矽烷、乙烯三甲氧基矽烷等乙烯矽 烷類；T —甲基丙烯氧基丙烯三曱氧基矽烷等（曱基） 表單編號A0101 第37頁/共76頁 丙烯酸矽烷類；yS — (3，4 一環氧環烷基）乙基三曱氧 基矽烷、万一（3，4 一環氧環烷基）曱基三甲氧基矽烷 、点一（3，4 一環氧環烧基）乙基三乙氧养梦烧、yS — (3，4_環氧環烷基）曱基三乙氧基矽烷、τ—環氧丙 氧基丙基三甲氧基矽烷、7—環氧丙氧基丙基三乙氧基 矽烷等環氧矽烷類；Ν—々（胺乙基）r—胺丙基三曱氧 基矽烷、N —/5 (胺乙基）r_胺丙基三乙氧基矽烷、N —/3 (胺乙基）T —胺丙基曱基二乙氧基碎烧、T —胺 丙基三乙氧基梦炫、T _胺丙基三曱氧基石夕炫*、N —苯基 —7"—胺丙基三甲氧基發按·、N —苯基一 τ —胺丙基三乙 氧基矽烷等胺矽烷類；以7 —疏基丙基三甲氧基矽烷、 酼基丙基三甲乙基矽烷等硫代矽烷類。 該等熱聚合性單體中，關於三聚氰胺或笨并脈胺化合物 、環氧化合物、苯酚化合物、嵌段化異氰酸酯化合物等 ，於本發明之墨水組成物中，宜以1重量％〜40重量％的 量而含有。又，矽烷耦合劑宜於本發明之墨水組成物中 ，以1重量％〜40重量％的量而含有。當含有量不足時， 會有对熱性或对藥性不佳的情況β又，當含有量多於40 %時，會產生黏度增加或保存穩定性降低的情況。 [活性能量線聚合起始劑] 於彩色濾光片用著色組成物中，若藉由照射紫外線等活 性能量線來將該著色組成物硬化時，會添加活性能量線 聚合起始劑。 作為活性能量線聚合起始劑可使用： 4_苯氧基二氣代苯乙酮、4_t_ 丁基二氣代苯乙酮、二 乙氧基苯乙明、1_ (4_異丙基苯基）一2_經基一2 — 表單編號A0101 第38頁/共76頁 201031713 甲基丙院―卜網、1 —«環己基笨酮、2-节基二甲美 胺1 (4~"嗎啉笨基）—丁烷一1—鲷或2—甲基― [4-(甲硫基）笨基—2_嗎琳丙炫—卜轉乙酿苯系 活性能量線聚合起始劑； ' 苯并、苯并甲醚、笨并乙喊、笨并異丙醚或苄基二甲基 縮酮等苯并系活性能量線聚合起始劑； 二笨甲嗣、苯醯安息香酸、苯醯安息香酸甲基、4—苯基 二苯曱鲷、羥基二笨甲酮、丙烯醯化二笨甲_或4一苯醯 ❹ 4 一甲基二苯基硫化物等二苯甲網系活性能量線聚合 起始劑； 噻噸酮、2 —氣噻噸_、2—甲.基噻噸射、異丙基噻噸鲷 、2，4二異丙基噻噸酮等噻嘀“，系:^性:能量.線聚合起始 劑； 2，4，6 —三氣一次級三嗪、2 —苯基一4，6 —雙（三氣 甲基）一次級三嗪、2—（對甲氧基苯基）4，6 —雙（三 ❹ 氣甲基）一次級三嗪、2-k;始▼丨擊6-雙（三氣 甲基> —次級三嗪、2 —胡夸雙（三氣曱基） 一次級三嗪、2，ί—雙—6-苯乙烯基次 級三0秦、2—(萘并一1—yl) —4，6 —雙（三氣甲基） —次級三嗪、2— (4-甲氧基萘并一 l—yl) — 4，6 — 雙（三氣甲基）一次級三嗪、2，4 —三氣甲基一（胡椒 基）一6 —三嗪或2，4一三氣甲基（4, 一曱氧基苯乙烯 基）一6—三嗪等三嗪系活性能量線聚合起始劑； 硼酸酯系活性能量線聚合起始劑； 味嗤系活性能量線聚合起始劑；或者 咪唑系活性能量線聚合起始劑等。 表單蹁號A0101 第39頁/共76頁 201031713 其中尤以使用一般式（1)所示之銕有機硼錯合物或氧锍 有機硼錯合物為宜。 一般式（1 ): [0018]ScIM tex Industrial Co., Ltd. SAIMElifTlB|@cfud As an epoxy compound, there are exemplified ^|: _ bis-glycidyl ether, biscresol bis diglycidyl ether, diethanol hydrazine diglycidyl hydrazine, Neopentyl glycol diglycidyl ketone, 1,6-hexanediol diglycidyl ether, glycerol polyglycidyl ether, trimethylolpropane polyglycidyl ether, neopentyl alcohol polyglycidyl Ether, diglycerol polyglycidyl ether, sorbitol polyglycidyl ether, diglycidyl terephthalate, diglycidyl phthalate, ethylene glycol diglycidyl Polyglycidyl-based mystery, polyglycidyl-based gas, etc., such as alkyl ether, diethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, and polypropylene glycol diglycidyl ether, However, it is not necessarily limited to the form number A0101, page 35/76, 201031713, and the like. The oxetane compound may, for example, be 3-ethyl-3-hydroxylated oxetane, 1,4 bis[[(3-ethyloxeene-3-yl)methoxy] Methyl]benzene, bis[1-ethyl(3-oxetanyl)]indenyl bond, 3-ethyl-3-(2-ethylhexyloxymethyl)oxetane , 3-ethyl 3-(phenoxyindenyl)oxetan, 3-ethyl-3-(cyclohexyloxy)methyloxetane, oxetanyl sesquiterpene Oxyalkane, oxetanyl halide, phenolic oxetane, 1,3-bis[(3-ethyloxetan-3-yl)methoxy] stupid, 1,4 pairs [ [(3-Ethyloxetane-3-yl)decyloxy]fluorenyl]biphenyl, 1-ethyl-3-oxo-butylmethyl methacrylate, benzene, benzene Dicarboxylic acid bis[1-ethyl(3-oxetanyl)methyl]ester, etc., but is not necessarily limited to these. As the phenol compound, for example, a phenolic phenol compound obtained by reacting a phenol with an aldehyde under an acidic catalyst or a soluble phenol compound obtained by reacting with a basic catalyst can be used. Examples of the phenols include o-cresol, p-cresol, p-phenylphenol, p-nonylphenol, 2,3-pin, benzophenone, methyl hydrazine, 3,5-p-pre, and m-phenylene. Hope, catechol, hydroquinone, bisphenol A, bisphenol F, bisphenol B, bisphenol E, diphenol quinone, bisphenol S, and the like. Examples of the aldehydes include furfural and acetaldehyde. Specific examples of the phenols and the aldehydes may be used singly or in combination of two or more kinds of phthalic acid as a commercial product of the benzoxazine compound, and examples thereof include benzoxazine P-d manufactured by Shikoku Kasei Kogyo Co., Ltd. Type, benzoxazine F-a type, etc., but it is not necessarily limited to these. As the block carboxylic acid compound, the carboxylic acid compound may, for example, be 1, 2 - Form No. A0101, page 36 / page 76 of phthalic acid, 1,3-benzene phthalic acid, 1,4-benzoic acid, 1,2,4-Benzene tridecanoic acid, pyromellitic acid, cyclohexanedicarboxylic acid, succinic acid, adipic acid, butane tetracarboxylic acid, maleic acid, fumaric acid, crotonic acid, C1 — CIC acid, CIC acid, C3 - CIC acid, Bis-CIC acid, etc., but it is not necessarily limited to these. Examples of the block agent include ethyl vinyl ether, η-propyl vinyl ether, isopropyl vinyl ether, η-butyl vinyl ether, isobutyl vinyl ether, tertiary butyl vinyl ether, and 2-ethyl group. Hexyl vinyl ether or the like, but it is not necessarily limited to these. Further, one type may be used alone or two or more types may be used in combination. Examples of the isocyanate compound of the blocked isocyanate compound include cyclohexane diisocyanate, isophorone diisocyanate, indole amide diisocyanate, diphenylmethane-4, diisononium δ ester, and diphenyl decane. Diisocyanate such as 2,4'-monoisocyanate, bis(4-isocyanatecyclohexyl)methane or tetramethyldiphenylene diisocyanate, isocyanate of the diisocyanate, trimethylolpropane addition type, diurea type, The oligomer obtained by the prepolymer polyalcohol having an isocyanate residue) and the isocyanate or the like are not necessarily limited thereto. 'As a block agent, for example, a phenol (dissociation temperature of 180 ° C or more), ε-caprolactam (dissociation temperature of 160 to 180 ° C), hydrazine (dissociation temperature of 130 to 160 ° C), or active methane (100) may be mentioned. ~120 ° C), etc., but it is not necessarily limited to these. Further, one type may be used alone or two or more types may be used in combination. Examples of the decane coupling agent include ethylene decane such as ethylene tris(yS-decyloxy group oxy) decane, ethylene ethoxy decane, and ethylene trimethoxy decane; T-methacryloxypropylene tridecyloxy group;矽, etc. (曱基) Form No. A0101 Page 37 of 76 Acrylic decanes; yS — (3,4-epoxycycloalkyl)ethyltrimethoxy decane, in case (3,4 epoxide) Cycloalkyl)decyltrimethoxydecane, point one (3,4-epoxycycloalkyl)ethyltriethoxymethane, yS — (3,4-epoxycycloalkyl)decyltriethyl Epoxy decanes such as oxydecane, τ-glycidoxypropyltrimethoxydecane, 7-glycidoxypropyltriethoxydecane; hydrazine-hydrazine (amine ethyl) r-amine C Tris-methoxydecane, N-5 (aminoethyl)r-aminopropyltriethoxydecane, N-/3 (aminoethyl) T-aminopropyl-decyldiethoxylate, T-Aminopropyltriethoxymolecular, T_Aminopropyltrimethoxyxanthine*, N-phenyl-7"-aminopropyltrimethoxy fluorene, N-phenyl-τ- Amine decane such as amine propyl triethoxy decane ; To 7-- mercapto propyl trimethoxy Silane, Hai ethyl trimethoxy silane-class silane-thio and the like. Among the above-mentioned thermally polymerizable monomers, melamine or a benzoic amine compound, an epoxy compound, a phenol compound, a blocked isocyanate compound and the like are preferably used in the ink composition of the present invention in an amount of from 1% by weight to 40% by weight. Contains the amount. Further, the decane coupling agent is preferably contained in the ink composition of the present invention in an amount of from 1% by weight to 40% by weight. When the content is insufficient, there is a case where the heat or the drug is not good, and when the content is more than 40%, the viscosity is increased or the storage stability is lowered. [Active Energy Ray Polymerization Initiator] When the coloring composition is cured by irradiation with an active material such as ultraviolet rays, an active energy ray polymerization initiator is added to the coloring composition for a color filter. As the active energy ray polymerization initiator, 4_phenoxy dioxoacetophenone, 4_t_butyl diacetoacetophenone, diethoxyphenemidine, 1_(4-isopropylphenyl) can be used. ) 2_经基基2 - Form No. A0101 Page 38 / Total 76 pages 201031713 Methyl propyl - NET, 1 - « cyclohexyl ketone, 2-mercaptodimethylamine 1 (4 ~ " Morpholine stupid)-butane- 1 - hydrazine or 2-methyl-[4-(methylthio) stupyl- 2 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Benzene-based active energy ray polymerization initiators such as benzo, benzoxyl ether, stupid and screaming, stupid and isopropyl ether or benzyldimethylketal; diazepam, benzoquinone benzoic acid, benzene Dibenzoyl network activity such as benzoic acid methyl, 4-phenyldiphenyl hydrazine, hydroxy dimercapto ketone, propylene oxime dimercapto or benzophenone 4 monomethyldiphenyl sulfide Energy ray polymerization initiator; thioxanthone, 2-oxothioxanthene, 2-methylthioxene oxime, isopropyl thioxanthene, 2,4 diisopropyl thioxanthone, etc. :^ Sex: energy. Line polymerization initiator; 2, 4, 6 - three gas primary grade three Pyrazine, 2-phenyl- 4,6-bis(trimethylmethyl)primary triazine, 2-(p-methoxyphenyl) 4,6-bis(trimethylene)methyl triazine, 2-k; start ▼ slam 6-double (tri-gas methyl group) - secondary triazine, 2 - huqu bis (trimethyl sulfhydryl) - a secondary triazine, 2, ί - bis-6 styrene Sub-trioxin, 0-(naphtho-l-yl)-4,6-bis(tris-methyl)-secondary triazine, 2-(4-methoxynaphthalene-l-yl) — 4,6 — bis(tri-gasmethyl) primary triazine, 2,4-trimethylmethyl-(piperidinyl)-6-triazine or 2,4-trimethylmethyl (4, anthracene oxygen) Triazine-based active energy ray polymerization initiator; benzoate-based active energy ray polymerization initiator; miso-active energy ray polymerization initiator; or imidazole-based active energy Line polymerization initiator, etc. Form No. A0101 Page 39/76 Page 201031713 It is preferable to use a ruthenium organoboron complex or an oxonium organoboron complex represented by the general formula (1). (1): [0018]

[0019] 於一般式（1)中，R11、R12及R13係分別獨立地表示選自 由亦可具有置換基之烷基'亦可具有置換基之芳香基、 亦可具有置換基之芳烷基、亦可具有置換基之烯基、亦 可具有置換基之炔基、亦可具有置換基之脂環基、亦可 具有置換基之烷氧基、亦可具有置換基之烯丙氧基、亦 可具有置換基之烷基硫代基及亦可具有置換基之胺基所 組成的群組中之基，R14係表示氧原子或孤立電子對，其 中亦可具有置換基之芳香基係僅止於R11、R12及R13中的1 個。X —為陰離子。 舉出一般式（1)之R11、R12及R13的例子，亦可具有置換 基之烷基可舉出甲基、乙基、丙基、異丙基、丁基、異 丁基、二級丁級、三級丁基、戊基、己基、辛基、癸基 、十二基、十八基、氣曱基、溴甲基、羥甲基、氰曱基 、硝曱基、曱氧曱基、胺曱基、二曱胺曱基、丙酮基、 表單編號A0101 第40頁/共76頁 乙氧羧基甲基、二乙胺羧基曱基、對羥基苯基曱基、曱 基硫代甲基、乙基硫代曱基、丁基硫代甲基、苯基硫代 甲基、甲基亞磺基甲基、甲基砜基甲基、苯并亞磺基甲 基、對甲苯亞磺基甲基、柳基、聯大茴香醯基等；亦可 具有置換基之芳香基可舉出苯基、對曱苯基、茬基、異 亞丙基、異丙苯基、聯苯基、萘基、蒽基、菲基、氣苯 基、溴苯基、氟苯基等；亦可具有置換基之芳烷基可舉 出苯乙基、二苯曱基等；亦可具有置換基之烯基可舉出 乙烯基、2—丙烯基、異丙烯基、丁烯基、桂皮基等；亦 可具有置換基之炔基可舉出乙炔基、丙炔基等；亦可具 有置換基之脂環基可舉出環己基、環戊基、環己烯基、 降莰基、莰基、薄荷基、蒎基、金剛烷基等；亦可具有 置換基之烷氧基可舉出甲氧基、三級丁氧基、苯并氧基 等；亦可具有置換基之烯丙氧基可舉出苯氧基、對甲苯 氧基、對氟苯氧基、對硝氧基等；亦可具有置換基之烷 基硫代基可舉出甲基硫代基、乙基硫代基、丁基硫代基 等；亦可具有置換基之胺基可舉:出二曱胺基、哌啶基、 嗎啉基、環己胺基、苯氨基等。作為特別適宜的置換基 ，可舉出亦可具有置換基之苄基及亦可具有置換基之苯 曱醯基，作為該等的例子，亦可具有置換基之苄基可舉 出苄基、對氣苄基、對溴苄基、對氰苄基、間硝苄基、 對硝苄基、對甲基苄基、對三級丁基苄基等，亦可具有 置換基之苯曱醯基可舉出苯曱醯基、對氣苯曱醯基、對 溴苯甲醯基、對氰苯甲醯基、間硝苯曱醯基、對硝苯曱 醯基等。又，R11、R12及R13亦可為其2個以上的基集合之 環狀構造，作為此類例子可舉出伸丁基、伸戊基、2 —伸 表單編號A0101 第41頁/共76頁 201031713 丁烯基、伸乙二氧基、伸乙二硫代基等。其他適宜的置 換基可舉出吱喃基、°夫喃甲基、嗟吩基、cenyl基、。底咬 基等。 更宜為X—是下述一般式（2)所示之硼酸鹽之活性能量線 聚合起始劑，藉由使用該類活性能量線聚合起始劑，本 發明之彩色濾光片之電效果更良好。 _一般式（2 ): [0020]In the general formula (1), R11, R12 and R13 each independently represent an arylalkyl group which may be selected from an alkyl group which may also have a substituent group, or may have a substituent group, or may have a substituent group. Further, it may have an alkenyl group having a substituent group, an alkynyl group which may have a substituent group, an alicyclic group which may have a substituent group, an alkoxy group which may have a substituent group, an allyloxy group which may have a substituent group, It may also be a group in the group consisting of an alkylthio group having a substituent group and an amine group which may also have a substituent group, and R 14 represents an oxygen atom or an isolated electron pair, wherein the aromatic group which may also have a substituent group is only Stop at 1 of R11, R12 and R13. X - is an anion. Examples of R11, R12 and R13 of the general formula (1), and alkyl groups which may have a substituent group may, for example, be a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group or a secondary butyl group. Grade, tertiary butyl, pentyl, hexyl, octyl, decyl, dodecyl, octadecyl, gas sulfhydryl, bromomethyl, hydroxymethyl, cyanoguanidine, nitroxyl, anthracenyl , Amidino, Diamine, Acetone, Form No. A0101 Page 40 of 76 Ethoxycarboxymethyl, Diethylamine Carboxymethyl, p-Hydroxyphenylindenyl, Mercaptothiomethyl , ethylthiodecyl, butylthiomethyl, phenylthiomethyl, methylsulfinylmethyl, methylsulfonylmethyl, benzosulfinylmethyl, p-toluenesulfinyl a methyl group, a sulfhydryl group, a fentanyl group or the like; and an aryl group which may have a substituent group may, for example, be a phenyl group, a p-phenylene group, a fluorenyl group, an isopropylidene group, a cumyl group, a biphenyl group or a naphthalene group. a base, a fluorenyl group, a phenanthryl group, a gas phenyl group, a bromophenyl group, a fluorophenyl group, etc.; an aralkyl group which may have a substituent group may, for example, a phenethyl group, a diphenylfluorenyl group or the like; Base can be given vinyl, 2-propyl Alkenyl group, isopropenyl group, butenyl group, cinnamyl group, etc.; an alkynyl group which may have a substituent group may, for example, be an ethynyl group or a propynyl group; and an alicyclic group which may have a substituent group may, for example, a cyclohexyl group or a ring. a pentyl group, a cyclohexenyl group, a decyl group, a decyl group, a menthyl group, a fluorenyl group, an adamantyl group or the like; and an alkoxy group which may have a substituent group may, for example, a methoxy group, a tertiary oxy group, a benzo group An oxy group or the like; an allyloxy group which may have a substituent group may, for example, be a phenoxy group, a p-tolyloxy group, a p-fluorophenoxy group or a p-nitrooxy group; or an alkylthio group which may have a substituent group; Examples of the methylthio group, the ethylthio group, the butylthio group and the like; and the amine group which may have a substituent group may be a diammonium group, a piperidinyl group, a morpholinyl group or a cyclohexylamino group. , phenylamino and the like. The benzyl group which may have a substituent group and the phenyl fluorenyl group which may have a substituent may be mentioned as a particularly preferable substituent group, and as such an example, the benzyl group which may have a substituent group is a benzyl group, a benzyl fluorenyl group which may have a substituent group, such as a gas benzyl group, a p-bromobenzyl group, a p-cyanobenzyl group, a m-nitrobenzyl group, a p-nitrobenzyl group, a p-methylbenzyl group, a p-tert-butylbenzyl group or the like. Examples thereof include a benzoinyl group, a p-benzoquinone group, a p-bromobenzylidene group, a p-cyanobenzoyl group, a m-nitrobenzoyl group, and a p-nitrobenzoin group. Further, R11, R12 and R13 may have a ring structure of two or more base sets thereof, and examples of such an example include a butyl group, a pentyl group, and a 2-sheet form number A0101. Page 41 of 76 201031713 Butenyl, ethylenedioxy, ethylenedithio and the like. Other suitable substituents include a fluorenyl group, a fluoromethyl group, an anthranyl group, and a cenyl group. Bottom bite base. More preferably, X is an active energy ray polymerization initiator of a borate represented by the following general formula (2), and an electric effect of the color filter of the present invention by using the active energy ray polymerization initiator Better. _General formula (2): [0020]

BmM-η_amM k mam 驅 R» 於一般式（2 )中， R21、r22、1{23及[?24係分別獨立地表示選自由亦可具有置 換基之烷基、亦可具有置換基之芳香基、亦可具有置換 基之芳烷基、亦可具有置換基之烯基、亦可具有置換基 之炔基所組成的群組中之基，R21、R22、R23及R24並非全 部具有置換基亦可，而不同時為芳香基。 舉出R21、R22、R23及R24的基為例，亦可具有置換基之烷 基可舉出曱基、乙基、丙基、異丙基、丁基、異丁基、 二級丁級、三級丁基、戊基、己基、辛基、癸基、十二 基、十八基、氣甲基、溴曱基、羥曱基、氰曱基、硝曱 基、甲氧甲基、胺甲基、二甲胺甲基、丙酮基、乙氧羧 表單編號A0101 第42頁/共76頁 基曱基、二乙胺羧基甲基、對羥基苯基甲基、甲基硫代 甲基、乙基硫代甲基、丁基硫代甲基、苯基硫代甲基、 甲基亞磺基甲基、甲基砜基甲基、苯并亞磺基甲基、對 曱苯亞磺基曱基、柳基、聯大茴香醯基等；亦可具有置 換基之芳香基可舉出苯基、對甲苯基、茬基、異亞丙基 、異丙苯基、聯苯基、萘基、蒽基、菲基、氣苯基、溴 笨基、氟苯基等；亦可具有置換基之芳烷基可舉出苯乙 基、二苯曱基等；亦可具有置換基之烯基可舉出乙烯基 、2—丙烯基、異丙烯基、丁烯基、桂皮基等；亦可具有 置換基之炔基可舉出乙炔基、丙炔基等。因此，作為符 合本發明之化合物的具體例可舉出下述組合所組成的銃 錯合物及氧銃錯合物，即陽離子部為三曱基疏、二甲基 丁基锍、二十二基苄基锍、二三級丁基苄基鈹、二曱基 苄基锍、二甲基（對氣苄基）銃、二丁基（對氣τ基） 锍、二甲基（對氰苄基）銃、二曱基苯甲醯銃、二三級 丁基苯甲醯銃、二曱基（對氣束_:酸'）疏、二甲基（對 氯苯甲醯）銃、二甲基（間甲务苯'曱醯）锍、二甲基（ 對氰苯甲醯）疏、二甲基（2 —苯基一3，3 —二氰丙一2 一乙）锍、二丁基乙氧基锍、二曱基苯氧基锍、曱基（ 二甲胺）（對曱苯）銃、二甲基曱基硫代銃、二甲基苯 基硫代疏、甲基苯基苄基鈹、甲基苯基（對氰苄基）銃 、甲基苯基苯曱醯銃、甲基苯基（2_苯基一 3，3 —二氰 丙一 2_乙）锍、曱基苯基乙氧基銃、乙基苯基苯氧基锍 、二甲胺雙（對甲苯）銕、甲基苯基甲基硫代锍、二苯 氧基（對甲苯）锍、三苯氧基銕、雙（二曱胺）（對甲 苯）銃、伸丁基笨曱醯銃 '三苄基锍、二甲基烯锍、二 表單編號A0101 第43頁/共76頁 201031713 丁基烯鍍、二曱基氰甲基銕、二曱基乙醯甲基銕、二甲 基乙氧羧基锍、二甲基（2_乙氧羧基）異丙基锍、二曱 基甲基硫代甲基二苄基苯甲醯銃、二烯苯曱醯銃、二甲 基乙烯基伸丁基三級丁氧基锍、二甲基（對曱苯）锍、 二乙基乙基硫代銃、二三級丁基_N_環己基胺基锍、三 曱基氧銕、二乙基丁基氧銃、二甲基苄基氡锍、二甲基 苯甲醯氧锍、二甲基苯氧基氧銕、甲基苯基苄基氧锍、 曱基苯基苯甲醯氧銕、二苯氧基（對曱苯）氧锍等各種 銃及氧锍、以及習知的锍及氧銃陰離子，與陰離子部為 三級丁基三乙基硼酸鹽、苯基三乙基硼酸鹽、三丁基τ 基硼酸鹽、二乙基二丁基硼酸鹽、二丁基二苯基硼酸鹽 、丁基三苯基硼酸鹽、节基三苯基硼酸鹽、乙烯基三苯 基硼酸鹽、乙炔基三苯基硼酸鹽、丁基三異亞丙基硼酸 鹽、丁基三（對甲氧苯基）硼酸鹽、丁基三（對氟苯基 )硼酸鹽、丁基三[3，5—雙（三氟曱基）苯基]硼酸鹽 等各種硼酸鹽陰離子、以及習知之四芳硼酸鹽除外之硼 酸鹽陰離子的組成，但本發明不:限定於該等例。 該等活性能量線聚合起始劑之合成手段據知有日本特開 平5- 213861號公報、日本特開平5 —255347號公報、日 本特開平8 — 15521號公報等所記載的方法。 活性能量線聚合起始劑係以彩色濾光片用著色組成物中 之顏料的重量為基準，能夠以5〜200重量％的量，更宜 以10〜150重量％的量來使用。 該等活性能量線聚合起始劑係單獨或混合2種以上而使用 ，作為增感劑亦可同時使用α —醯氧基醚、醯基磷化氫 氧化物、甲苯基乙醛酸、苄基、9，10 —菲并杜烯醌、樟 表單編號Α0101 第44頁/共76頁 腦酮、乙基蒽醌、4，4 一二曱基異酞酚酮、3，3’，4, 4’ _四（三級丁基過氧羧基）二苯甲酮或4，4 —二甲基 胺二苯甲酮等化合物。 增感劑的含有量係以著色組成物中之活性能量線聚合起 始劑的重量為基準，能夠以0.1〜60重量％的量來使用。 [其他添加劑] 作為其他添加劑，例如儲藏穩定劑可舉出苄基三甲基氯 化物或二甲基羥胺等4級銨氣化物、乳酸或草酸等有機酸 、前述有機酸之甲基醚；三級丁基焦兒茶酚及等兒茶酚 、三丁基膦、三苯基膦、四乙基膦或四苯基膦等有機膦 、或者亞磷酸鹽等。 其中尤其藉由使用第3級膦化合物，更宜使用三苯基膦， 本發明之彩色濾光片用著色組成物之關於低介電率的效 果良好。_ [著色組成物的調製] I 3 11 ri- 1 彩色濾光片用著色組成物可調製作為溶影型、鹼顯 影型或喷墨型彩色濾光片用著色組成物。溶劑顯影型或 鹼顯影型彩色濾光片用著色組成物係於含有順丁烯二酸 酐與順丁烯二酸酐以外之1種以上的乙烯性不飽和單體之 共聚物（Α)、樹脂黏結劑（Β)、活性能量線聚合性單 體、活性能量線聚合起始劑及有機溶劑之組成物中，使 顏料分散後所得之物。 又，喷墨型彩色濾光片用著色組成物係於含有順丁烯二 酸酐與順丁烯二酸酐以外之1種以上的乙烯性不飽和單體 之共聚物（Α)、樹脂黏結劑（Β)、活性能量線聚合性 單體或熱聚合性單體及有機溶劑之組成物中，使顏料分 表單編號Α0101 第45頁/共76頁 201031713 散後所得之物。 本發明之彩色濾光片用著色組成物係混合顏料或含2種以 上的顏料之顏料組成物（以下簡寫為顏料組成物）、順 丁烯二酸酐與順丁烯二酸酐以外之1種以上的乙烯性不飽 和單體之共聚物（A)、樹脂黏結劑（B)，並因應需要 而混合溶劑、其他顏料分散劑及添加劑等，利用三輥研 磨機、二輥研磨機、捏合機、橫型砂磨機、縱型砂磨機 、環形珠研磨機或磨碎機等予以分散，調製出顏料組成 物分散於清漆而成之顏料分散體，接著混合調整前述顏 料分散體、活性能量線聚合性單體、活性能量線聚合起 始劑，並可因應需要混合調整溶劑、順丁烯二酸酐與順 丁烯二酸奸以外之1種以上的乙烯性不飽和單體之共聚物 (A)、其他顏料分散劑及添加劑等。 亦可混合製造數種顏料個別分散於共聚物（A)及/或樹 脂黏結劑（B)之物。活性能量線聚合起始劑亦可於調製 彩色濾光片用著色組成物的階段加入，或後來再加入於 已調製之彩色濾光片用著色組成物中。 本發明之彩色濾光片用著色組成物係以離心分離、燒結 過濾器、薄膜過濾器等手段，去除5 以上之粗粒子， 更宜去除1/zm以上之粗粒子，尤宜去除0.5/zm以上之粗 粒子及混入的微塵。 [彩色濾光片之製造方法] 接著，說明關於使用本發明之彩色濾光片用著色組成物 之彩色濾光片的製造方法。 本發明之彩色濾光片係於基板上具備濾光片區段，可具 備例如黑矩陣及紅色、綠色、藍色的濾光片區段。前述 表單編號A0101 第46頁/共76頁 201031713 濾光片區段係藉由旋轉塗布、壓模塗布方式或噴墨方式 ’塗布本發明之著色組成物，並依需要進行顯影而形成 於基板上。 作為彩色滤光片的基板係使用對於可見光之穿透率高的 驗石灰玻璃、低驗蝴石夕酸玻璃、無驗銘蝴石夕酸玻璃等之 玻璃板，或聚碳酸酯、聚甲基丙烯酸甲基、聚乙二醇等 之樹脂板。又’於玻璃板或樹脂板表面，為了製成面板 後之液晶驅動’亦可形成氧化姻、氧化錫等所組成的透 明電極。 ❹ 顯影時’作為鹼顯影；劑係使用碳酸納、氩氧化鈉等之水 溶液’亦可使用二甲基苄基，思?·、三乙醇味等有機鹼。又 ，於顯影液中亦可添加消泡或聲薄性劑V 作為顯影處理方法可適用顯影法、滴 下（浸潰）顯影法及挽動（盛液）顯影法等❶ 而且，為了提高紫外線曝光感度’亦可將上述彩色遽光 片用著色組成物予以塗布滅_ 11 ackiife或鹼可溶性BmM-η_amM k mam drives R» in the general formula (2), and R21, r22, 1{23 and [?24 are each independently selected from the group consisting of an alkyl group which may also have a substituent group, and may also have a substituent. a group or a group of an aralkyl group having a substituent group, an alkenyl group which may have a substituent group, or an alkynyl group which may have a substituent group, and R21, R22, R23 and R24 not all have a substituent group Also, not at the same time, an aromatic base. The radicals of R21, R22, R23 and R24 are exemplified, and the alkyl group which may have a substituent may be a mercapto group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group or a secondary butyl group. Tert-butyl, pentyl, hexyl, octyl, decyl, dodecyl, octadecyl, methoxymethyl, bromoindolyl, hydroxydecyl, cyanogenic, decyl, methoxymethyl, amine Methyl, dimethylamine methyl, acetonyl, ethoxycarboxylate Form No. A0101 Page 42 of 76 hydrazino, diethylamine carboxymethyl, p-hydroxyphenylmethyl, methylthiomethyl, Ethylthiomethyl, butylthiomethyl, phenylthiomethyl, methylsulfinylmethyl, methylsulfonylmethyl, benzosulfinylmethyl, p-nonylsulfinyl Sulfhydryl, lysine, fentanyl, etc.; and aryl, which may also have a substituent, may be phenyl, p-tolyl, fluorenyl, isopropylidene, cumene, biphenyl or naphthyl. , fluorenyl, phenanthryl, phenyl, bromo, fluorophenyl, etc.; aralkyl groups which may further have a phenylethyl group, a diphenyl fluorenyl group, etc.; Vinyl, 2-propenyl Isopropenyl, butenyl, and the like basal Guangxi; alkynyl group may have a substituent include the ethynyl, propynyl and the like. Therefore, specific examples of the compound according to the present invention include a ruthenium complex and an oxonium complex which are composed of the following combinations, that is, the cation moiety is trimethyl sulfhydryl, dimethyl butyl hydrazine, and twenty-two Base benzyl hydrazine, di-tertiary butyl benzyl hydrazine, dimercaptobenzyl hydrazine, dimethyl (p-benzyl) hydrazine, dibutyl (p-haloxy) hydrazine, dimethyl (p-cyanobenzyl) Base) bismuth, dimercaptobenzonitrile, di- or tri-butyl benzamidine, di-mercapto (for gas beam _: acid'), dimethyl (p-chlorobenzoquinone) oxime, dimethyl Base (m-phenylene benzene), dimethyl (p-cyanobenzoic acid), dimethyl (2-phenyl- 3,3-dicyano-2-ene) fluorene, dibutyl Ethoxy ruthenium, dimercaptophenoxy oxime, decyl (dimethylamine) (p-phenylene) oxime, dimethyl thio thiopurine, dimethylphenyl thiosali, methyl phenyl benzyl Base, methylphenyl (p-cyanobenzyl) fluorene, methylphenyl benzoquinone, methylphenyl (2-phenyl- 3,3-dicyanopropan-2-yl) fluorene, fluorenyl Phenylethoxy oxime, ethyl phenyl phenoxy oxime, dimethylamine bis (p-toluene) , methylphenylmethylthioindole, diphenoxy (p-toluene) anthracene, triphenyloxyanthracene, bis(diamine) (p-toluene) anthracene, butyl butyl alum锍, dimethyl olefin oxime, two form number A0101, page 43 / page 76, 201031713 butyl ene plating, dimercapto cyanomethyl hydrazine, dimethyl hydrazine methyl hydrazine, dimethyl ethoxy carboxy fluorene, Dimethyl (2-ethoxycarboxy) isopropyl hydrazine, dimercaptomethyl thiomethyl dibenzyl benzamidine, diphenyl phenyl hydrazine, dimethyl vinyl butyl butyl tertiary butoxide Base, dimethyl (p-phenylene) oxime, diethyl ethyl thioindole, di-tertiary butyl _N_cyclohexylamino hydrazine, tridecyl oxonium, diethyl butyl oxonium, Dimethylbenzyl hydrazine, dimethyl benzyl hydrazine, dimethyl phenoxy oxime, methyl phenyl benzyl oxonium, nonylphenyl benzoyl oxime, diphenoxy ( Various anthraquinones and oxindoles such as fluorene oxime, and conventional oxime and oxonium anions, and anionic moieties are tributyl butyl triethyl borate, phenyl triethyl borate, tributyl τ Borate, diethyldibutylborate Dibutyldiphenylborate, butyltriphenylborate, benzyltriphenylborate, vinyltriphenylborate,ethynyltriphenylborate,butyltriisopropylidene borate Various borates such as butyl tris(p-methoxyphenyl)borate, butyl tris(p-fluorophenyl)borate, butyl tris[3,5-bis(trifluorodecyl)phenyl]borate The anion, and the composition of the borate anion other than the conventional tetraarylborate, is not limited to these examples. The method described in the above-mentioned Japanese Patent Application Laid-Open No. Hei No. Hei. No. Hei. No. Hei. The active energy ray polymerization initiator can be used in an amount of 5 to 200% by weight, more preferably 10 to 150% by weight, based on the weight of the pigment in the colored filter composition. These active energy ray polymerization initiators may be used singly or in combination of two or more. As the sensitizer, α-methoxyl ether, decylphosphoric acid hydroxide, tolyl glyoxylic acid, or benzyl group may be used together. , 9,10 - phenanthrene, 樟 form number Α 0101, page 44 / page 76 cerebral ketone, ethyl hydrazine, 4,4 dimethyl decyl oxime ketone, 3, 3', 4, 4 '_Four (tertiary butylperoxycarboxy) benzophenone or a compound such as 4,4-dimethylamine benzophenone. The content of the sensitizer can be used in an amount of 0.1 to 60% by weight based on the weight of the active energy ray polymerization initiator in the coloring composition. [Other Additives] Examples of the other additives include a 4-stage ammonium vapor such as benzyltrimethyl chloride or dimethylhydroxyamine, an organic acid such as lactic acid or oxalic acid, and a methyl ether of the above organic acid; Grade butyl pyrocatechol and an organophosphine such as catechol, tributylphosphine, triphenylphosphine, tetraethylphosphine or tetraphenylphosphine, or a phosphite. Among them, in particular, by using a phosphine compound of the third order, triphenylphosphine is more preferably used, and the coloring composition for a color filter of the present invention has a good effect on a low dielectric constant. _ [Preparation of coloring composition] I 3 11 ri-1 Coloring composition The coloring composition can be used as a coloring composition for a condensing type, an alkali developing type or an ink jet type color filter. The coloring composition for a solvent developing type or an alkali developing type color filter is a copolymer (Α) containing a copolymer of one or more kinds of ethylenically unsaturated monomers other than maleic anhydride and maleic anhydride, and resin bonding. A composition obtained by dispersing a pigment in a composition of an active agent, an active energy ray-polymerizable monomer, an active energy ray polymerization initiator, and an organic solvent. In addition, the coloring composition for an inkjet type color filter is a copolymer (Α) or a resin binder containing one or more kinds of ethylenically unsaturated monomers other than maleic anhydride and maleic anhydride ( Β), an active energy ray-polymerizable monomer or a composition of a thermally polymerizable monomer and an organic solvent, and the pigment is obtained by the form number Α0101, page 45/76, 201031713. The coloring composition for a color filter of the present invention is a pigment composition or a pigment composition containing two or more kinds of pigments (hereinafter abbreviated as a pigment composition), one or more kinds of maleic anhydride and maleic anhydride. a copolymer of an ethylenically unsaturated monomer (A), a resin binder (B), and a solvent, other pigment dispersant, an additive, etc., if necessary, using a three-roll mill, a two-roll mill, a kneader, A horizontal sand mill, a vertical sand mill, a ring bead mill or an attritor is dispersed to prepare a pigment dispersion in which a pigment composition is dispersed in a varnish, and then the pigment dispersion and the active energy ray are mixed and adjusted. a polymerizable monomer, an active energy ray polymerization initiator, and a copolymer of a solvent, a maleic anhydride, and a maleic unsaturated monomer other than maleic acid (A) ), other pigment dispersants and additives. It is also possible to mix and produce several kinds of pigments which are individually dispersed in the copolymer (A) and/or the resin binder (B). The active energy ray polymerization initiator may also be added at the stage of modulating the coloring composition for the color filter, or later added to the coloring composition for the prepared color filter. In the coloring composition for a color filter of the present invention, coarse particles of 5 or more are removed by means of centrifugation, a sintered filter, a membrane filter, etc., and it is more preferable to remove coarse particles of 1/zm or more, and it is preferable to remove 0.5/zm. The above coarse particles and the mixed dust. [Method of Manufacturing Color Filter] Next, a method of manufacturing a color filter using the coloring composition for a color filter of the present invention will be described. The color filter of the present invention is provided with a filter segment on the substrate, and may have, for example, a black matrix and a filter segment of red, green, and blue. The above-mentioned form No. A0101, page 46/76, 201031713 The filter section is coated on the substrate by coating the coloring composition of the present invention by spin coating, die coating or ink jet method, and developing as needed. . As the substrate of the color filter, a glass plate such as a limestone glass having a high transmittance of visible light, a low-inspection quartz acid glass, a non-existing quartz glass, or a polycarbonate or a polymethyl group is used. A resin plate such as methyl acrylate or polyethylene glycol. Further, a transparent electrode composed of oxidized sulphur, tin oxide or the like may be formed on the surface of the glass plate or the resin plate to drive the liquid crystal after the panel is formed. ❹ At the time of development, as an alkali development; an aqueous solution such as sodium carbonate or sodium aroxide may be used as the agent. An organic base such as dimethylbenzyl, triethyl or triethanol may be used. Further, a defoaming or a thinner V may be added to the developing solution as a developing treatment method, and may be applied to a developing method, a dropping (immersion) developing method, and a pulling (liquid) developing method, etc. Further, in order to increase ultraviolet exposure Sensitivity' can also be used to coat the above colored calender with a coloring composition _ 11 ackiife or alkali soluble

樹脂，例如聚乙烯醇或水、;等予以塗布乾 Η [ 4 I 1 燥，形成防止氧所造成的聚啥旅礙乏膜後，再進行紫外 線曝光。 於透明基板或反射基板上形成濾光片區段前，若預先形 成黑矩陣，可更加提高液晶顯示面板的對比。作為黑矩 陣係利用絡或絡/氧化鉻之多層膜、氮化鈦等之無機膜， 或分散有遮光劑之樹脂膜，但不限定於該等。又，預先 於前述透明基板或反射基板上形成薄膜電晶想（TFT)， 其後形成濾光片區段亦可。藉由在該形成有tft的基板（ 以下稱為TFT基板，TFT基板係薄膜電晶體（TFT)方式 表單編號A0101 第47頁/共76頁 201031713 之彩色液晶顯示裝置之驅動用基板）上形成濟光片 ，可提高液晶顯示面板之開口率 使得亮度提升。 區段 在此，說明於TFT基板上形成濾光片區段的方法。、 於m基板表面上’或於m基板表面形成有氮化::等 鈍化膜之基板表面上，因應需要，，分形成濾光片區 段（像素）部分之方式形成遮光層’於該基板上塗布本 發明之著色組成物後’進行預烘烤…吏溶劑蒸發而形成 塗膜。接著，於該塗膜，中介光罩進行曝光後，使用鹼 顯影液進行顯影，溶解去除塗臈的未曝光部，其後進行 後烘烤’形成濾光片區.段' c像素）以轉定排列所配置的 丨:巧;' +d:尸ϊ ΐ ''^：'!· '' ?'ΐ ϊ Ίί-： 濾光片區段（像素）陣列6當時所俺用的光罩除了設有 用以形成像素的圖案以外，亦設有通孔或「3」字形凹 陷的圖案。 一 作為TFT基板可使甩與前述彩色濾光片的基板相同之物， 於該等基板，亦可預先施以利用矽烷耦合劑等之藥品處 理、電漿處理、離子電鍍、滅鑓#爲：辄策4法、真空蒸 鍍等適宜的預處理。塗布庫度也乾痛棱膜厚宜為ο. 1〜ίο . ^·\. I' f8# /z m，更宜為〇. 5〜6. 0 /z m'〆 * 於彩色濾光片上，因應需要而形成有覆膜或柱狀間隔物 、透明導電膜、液晶配向層等。 形成有彩色濾光片之基板係利用密封劑來與對向基板黏 合，從設置於密封部之注入口注入液晶後密封注入口， 並因應需要，將偏光膜或相位差膜黏合於基板外側’藉 此來備製液晶顯示面板。 該液晶顯示面板可使用於使用扭轉向列（TN)、超扭轉 向列（STN)、平面切換（IPS)、垂直對準（VA)、光 表單編號A0101 第48頁/共76頁 學補償彎曲（OCB)等之彩色濾光片來進行彩色化之液晶 顯示模式。 〔實施例〕 以下根據實施例來說明本發明，但本發明不受此限定。 再者，實施例及比較例中，「部」係意味「重量部」。 於實施例及比較例之前，說明關於順丁烯二酸酐與順丁 烯二酸酐以外之1種以上的乙烯性不飽和單體之共聚物（ A)、作為樹脂黏結劑（B)之丙烯酸樹脂溶液、聚酯分 散劑、活性能量線聚合性起始劑之製造方法。樹脂分子 量係使用HLC-8220GPC (TOSOH股份有限公司製）作為 裝置，連接2排TSK-GEL SUPEK HZI4-N作為管柱使用， 並使用T H F作為溶媒所測定到換算為聚笨乙烯之重量平均 分子量。 [微細化顏料的製造] (微細化顏料製造例1) I -圍 i 'r 1 將鹵化銅酞菁系綠色顏料PG36 (-東洋墨箱ft造公司製「 Lionol、Green 6YK」.....:）120部、經粉碎的食鹽1500部及 二乙二醇250部置入不銹鋼製1加侖捏合機（井上製作所 製），以60°C混合攪拌15小時。將此混合物放入温水 5000部中，一面加熱至約70°C，一面以高速混合器攪拌 約1小時而製成漿狀，重複過濾、水洗以去除食鹽及溶劑 後，以80°C乾燥24小時，獲得117部的微細化顏料（PG —1 )。 (微細化顏料製造例2) 將喹酞酮系黃色顏料PY138 (BASF公司製「Paliotol Yellow K0961 -HD」）100部、色素衍生物（化合物1 表單編號A0101 第49頁/共76頁 201031713 )3部、經粉碎的食鹽800部及二乙二醇180部置入不銹鋼 製1加侖捏合機（井上製作所製），以7〇。(：混合攪拌4小 時。將此混合物放入溫水3000部中，一面加熱至約8〇。匚 ’一面以高速混合器攪拌約1小時而製成漿狀，重複過濾 、水洗以去除食鹽及溶劑後，以8〇。(：乾燥24小時，獲得 98部的微細化顏料（ργ —1 )。 (微細化顏料製造例3 ) 將金屬錯合物系黃色顏料PY150 (LANXESS公司「E4GN 」）100部、經粉碎的食鹽1500部及二乙二醇180部置入 不銹鋼製1加侖捏合機（井上製作所製），以l〇〇°C混合 攪拌6小時。將此混合攪拌物草入溫水5G00部中，一面加 熱至約70°c，一面以高速混合象樣拌绔1小時而製成漿狀 ’重複過濾、水洗以去除食鹽及溶劑後，以80°C乾燥24 小時，獲得95部的微細化顏料（PY —2)。 (微細化顏料製造例4) 將銅酞菁系藍色顏料PB15 : K東洋鲞水製造公司製「 I.Resin, such as polyvinyl alcohol or water, etc., is coated with dry Η [ 4 I 1 dry, formed to prevent oxygen from colliding with the film, and then exposed to ultraviolet light. Before the filter segments are formed on the transparent substrate or the reflective substrate, if a black matrix is formed in advance, the contrast of the liquid crystal display panel can be further improved. The black matrix is a multilayer film using a complex or a complex of chromic oxide, an inorganic film such as titanium nitride, or a resin film in which a light-shielding agent is dispersed, but is not limited thereto. Further, a thin film electromorphic (TFT) is formed on the transparent substrate or the reflective substrate, and a filter segment may be formed thereafter. By forming a substrate on which tft is formed (hereinafter referred to as a TFT substrate, a TFT substrate-based thin film transistor (TFT) method form No. A0101, page 47/76, 201031713, a substrate for driving a color liquid crystal display device) The light sheet can increase the aperture ratio of the liquid crystal display panel to increase the brightness. Section Here, a method of forming a filter segment on a TFT substrate will be described. And forming a light shielding layer on the surface of the substrate on the surface of the m substrate or on the surface of the substrate on which the passivation film such as nitridation: is formed on the surface of the m substrate, if necessary, by forming a portion of the filter segment (pixel) After the coloring composition of the present invention is applied, it is pre-baked... the solvent is evaporated to form a coating film. Next, after the exposure film is exposed to the coating film, development is performed using an alkali developing solution to dissolve and remove the unexposed portion of the coated layer, and then post-baking is performed 'forming a filter region. Segment 'c pixels) to be rotated排列 所 巧 巧 巧 巧 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' In addition to the pattern for forming the pixels, a pattern of through holes or "3-" shaped depressions is also provided. A TFT substrate may be the same as the substrate of the color filter, and the substrate may be subjected to a drug treatment such as a decane coupling agent, a plasma treatment, an ion plating, or a ruthenium. Suitable pretreatments such as the method 4 and vacuum evaporation. The coating degree is also dry and the thickness of the prism is preferably ο. 1~ίο . ^·\. I' f8# /zm, more preferably 〇. 5~6. 0 /z m'〆* on the color filter A film or a column spacer, a transparent conductive film, a liquid crystal alignment layer, or the like is formed as needed. The substrate on which the color filter is formed is bonded to the opposite substrate by a sealant, and the liquid crystal is injected from the injection port provided in the sealing portion to seal the injection port, and if necessary, the polarizing film or the retardation film is bonded to the outside of the substrate. Thereby, a liquid crystal display panel is prepared. The liquid crystal display panel can be used to compensate for bending using twisted nematic (TN), super twisted nematic (STN), plane switching (IPS), vertical alignment (VA), light form number A0101, page 48/76 pages. A color filter such as (OCB) is used to colorize the liquid crystal display mode. [Examples] Hereinafter, the present invention will be described based on examples, but the present invention is not limited thereto. In the examples and comparative examples, the "part" means "weight portion". Before the examples and comparative examples, a copolymer (A) of one or more kinds of ethylenically unsaturated monomers other than maleic anhydride and maleic anhydride, and an acrylic resin as a resin binder (B) will be described. A method for producing a solution, a polyester dispersant, and an active energy ray polymerizable initiator. The resin molecular weight was measured by using HLC-8220GPC (manufactured by TOSOH Co., Ltd.) as a device, and two rows of TSK-GEL SUPEK HZI4-N were connected as a column, and the weight average molecular weight converted to polystyrene was measured using T H F as a solvent. [Production of Micronized Pigment] (Micronized Pigment Production Example 1) I - Ii r 'r 1 Halogenated copper phthalocyanine-based green pigment PG36 (-"Lionol, Green 6YK" manufactured by Toyo Ink Co., Ltd.... .:) 120 parts, 1500 parts of crushed salt and 250 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 60 ° C for 15 hours. The mixture was placed in 5000 parts of warm water, heated to about 70 ° C, and stirred in a high-speed mixer for about 1 hour to form a slurry. The mixture was repeatedly filtered and washed with water to remove salt and solvent, and then dried at 80 ° C. In hours, 117 micronized pigments (PG-1) were obtained. (Micronized Pigment Production Example 2) 100 parts of a quinophthalone-based yellow pigment PY138 ("Paliotol Yellow K0961 - HD" manufactured by BASF Corporation) and a dye derivative (Compound 1 Form No. A0101, page 49 / page 76, 201031713) 3 A portion of 800 parts of shredded salt and 180 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.) at 7 inches. (: mixing and stirring for 4 hours. The mixture was placed in 3000 parts of warm water and heated to about 8 Torr. The mixture was stirred in a high-speed mixer for about 1 hour to form a slurry, which was repeatedly filtered and washed with water to remove salt and After the solvent, it was 8 Torr. (: Drying was carried out for 24 hours to obtain 98 fine pigments (ργ-1). (Micronized pigment production example 3) Metal complex yellow pigment PY150 (LANXESS "E4GN") 100 parts, 1500 parts of crushed salt and 180 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 100 ° C for 6 hours. The mixed mixture was poured into warm water. In the 5G00 part, one side was heated to about 70 ° C, and mixed with a high-speed mixed pattern for 1 hour to form a slurry. Repeated filtration, washing with water to remove salt and solvent, and drying at 80 ° C for 24 hours, 95 parts were obtained. Fine-pigmented pigment (PY-2). (Micronized pigment production example 4) Copper phthalocyanine-based blue pigment PB15: K Toyo Sasaki Manufacturing Co., Ltd. "I.

Lionol Blue ES」）100#&素衍生物（化合物2) 5 部、經粉碎的食鹽1000部及部置入不銹鋼製 1加侖捏合機（井上製作所製），以50°C混合攪拌12小時 。將此混合物放入溫水3000部中，一面加熱至約70°C， 一面以高速混合器攪拌約1小時而製成漿狀，重複過濾、 水洗以去除食鹽及溶劑後，以80°C乾燥24小時，獲得98 部的微細化顏料（PB—1)。 (微細化顏料製造例5) 將二噁嗪系紫色顏料PV23 (東洋墨水製造公司製「1^_ onol Violet RL」）300部放入96%硫酸3〇〇〇部中，攪 表單編號A0101 第50頁/共76頁 拌1小時後注入於5°C的水中。攪拌丨小時後予以過濾以 溫水洗淨直到洗淨液成為中性’以7(rc乾燥。將所獲得 的酸糊處理顏料120部、色素衍生物（化合物3) 5部經 粉碎的食鹽1500部及二乙二醇1〇〇部置入不銹鋼製1加侖 捏合機（井上製作所製），以70°C混合攪拌20小時。將 此混合物放入溫水5000部中’ 一面加熱至約7〇， 面 以高速混合器攪拌約1小時而製成漿狀，重複過濾、水洗 以去除食鹽及溶劑後，以8(TC乾燥24小時，獲得115部的 微細化顏料（PV—1 )。 (微細化顏料製造例6) 將二酮《比哈並吼哈系紅色顏科p R 、（千:葉啦殊化學公司 製「IRGAPHOR RED B-CF爹卜州都“色素衍生物（化 合物4) 10部、經粉碎的食鹽1〇仰部及二」乙二醇12〇部置 入不銹鋼製1加侖捏合機（井上製作所·製），W7〇〇C混合 攪拌8小時。將此混合物放入溫水2〇〇〇部令，一面加熱至 約8 0 C ’ 一面以舞速混合.讀知娜耘製成漿狀，重 複過滤 '水洗以去除食里犮乾燥24小時 ，獲得1 ο 〇部的微細化顏料:f f1¾ ^ (微細化顏料製造例7) 將蔥親系紅色顏料PR177 (千葉特殊化學公司製「€服〇_ MOPHTAL RED A2B」）100部、色素衍生物（化合物5) 10部、經粉碎的食鹽800部及二乙二醇18〇部置入不錢鋼 製1加侖捏合機（井上製作所製），以”它混合授拌5小 時。將此混合物放入溫水4000部中，一面加熱至約8〇°c ，一面以咼速混合器授拌約1小時而製成漿狀，重複過渡 、水洗以去除食鹽及溶劑後’以8〇t乾燥24小時，獲得 表單編號A0101 第51頁/共76頁 201031713 100部的微細化顏料（PR —2)。 [順丁烯二酸酐與順丁烯二酸酐以外之1種以上的乙烯性 不飽和單體之共聚物（A)] (順丁烯二酸酐一茚共聚物（A — 1)之製造例） 於裝有冷卻管及滴下漏斗之反應容器中置入曱基乙酮500 部，一面於容器注入氮氣，一面加熱至80°C，以相同溫 度，歷經1小時滴下茚348部、順丁烯二酸酐294部及2， 2’一偶氮雙異丁腈10. 0部之混合物，進行聚合反應。滴 下後，進一步以l〇〇°C反應3小時後，添加以曱基乙酮50 部溶解有偶氮雙異丁腈2.0部之物，進一步以100°C繼續 反應5小時，獲得重量平均吩子量（Mw) 1 3, 000之順丁 烯二酸酐一茚共聚物溶液》 冷卻至室溫後，將共聚物溶液取樣約2g，以180°C加熱乾 燥20分鐘，測定未揮發成分，根據其測定值添加曱基乙 酮，以使先前合成之樹脂溶液中之未揮發成分成為20重 量％，調製成順丁烯二酸酐一茚共聚物（A — 1)。而且 ，藉由紅外分光進行測定，確認有酸酐基的峰值。 [樹脂黏結劑的製造] (丙烯酸樹脂（B —1)之製造例1) 於反應容器置入丙二醇單曱醚乙酸酯800部，一面於容器 注入氮氣，一面加熱至100°C，於相同溫度下，歷經1小 時滴下甲基丙烯酸80.0部、甲基丙烯酸曱酯85.0部、丁 基丙烯酸甲酯85. 0部及2，2’一偶氮雙異丁腈10.0部之 混合物，進行聚合反應。滴下後，進一步以100°C反應3 小時後，添加以丙二醇單乙基醚乙酯50部溶解有偶氮雙 異丁腈2. 0部之物，進一步以100°C繼續反應1小時，獲得 表單編號A0101 第52頁/共76頁 重量平均分子量乂河评）40，000之丙稀酸樹脂（B—1)溶 液。 冷卻至室溫後，將樹脂溶液取樣約2g，以180°C加熱乾燥 20分鐘，測定未揮發成分，根據其測定值添加丙二醇單 乙基醚乙酯，以使先前合成之樹脂溶液中之未揮發成分 成為20重量％，調製成丙烯酸樹脂（B—1 )溶液。 (丙烯酸樹脂（B — 2)之製造例2) 於安裝有溫度計、冷卻管、氮氣導入管、滴下管、攪拌 裝置之分離式的4支燒瓶中，置入丙二醇單乙基醚乙酯 70. 0部，升溫至80°C，將燒瓶内進行氮置換後，藉由滴 下管歷經2小時滴下n_ 丁基曱基丙烯酸酯13. 3部、2 —羥 乙基甲基丙烯酸酯4. 6部、甲基丙烯酸4. 3部、對枯基酚 環氧乙烷變性丙烯酸酯（東亞合成股份有限公司製「 ARONIXM110」）7. 4部及2，2 ’ 一偶氮雙異丁腈0. 4部 之混合物。谪下結束後，進一步繼續反應3小時，獲得重 量平岣分子量（Mw) 26, 000之丙烯酸樹(B-2)溶液 〇 · -- .... . I I i i w 冷卻至室溫後，將樹脂溶液取樣約2g，以180°C加熱乾燥 20分鐘，測定未揮發成分，根據其測定值添加丙二醇單 乙基醚乙酯，以使先前合成之樹脂溶液中之未揮發成分 成為20重量％，調製成丙烯酸樹脂（B-2)溶液。 (丙烯酸樹脂（B —3)之製造例3) 於反應容器置入二乙二醇單甲醚乙酸酯800部，一面於容 器注入氮氣，一面加熱至100°C，於相同溫度下，歷經1 小時滴下曱基丙烯酸80. 0部、甲基丙烯酸曱酯85.0部、 丁基丙烯酸曱酯85. 0部及2，2’一偶氮雙異丁腈10.0部 表單編號A0101 第53頁/共76頁 201031713 之混合物，進行聚合反應。滴下後，進一步以100°C反應 3小時後，添加以二乙二醇單乙基醚乙酯50部溶解有偶氮 雙異丁腈2. 0部之物，進一步以100°C繼續反應30分鐘， 獲得重量平均分子量（Mw) 12,000之丙烯酸樹脂（B —3 )溶液。 冷卻至室溫後，將樹脂溶液取樣約2g，以180°C加熱乾燥 20分鐘，測定未揮發成分，根據其測定值添加二乙二醇 單乙基醚乙酯，以使先前合成之樹脂溶液中之未揮發成 分成為20重量％，調製成丙烯酸樹脂（B —3)溶液。 (丙烯酸樹脂（B —4)之製造例4) 於安裝有溫度計、冷卻管、氮氣導入管、滴下管、攪拌 裝置之分離式的4支燒瓶中，置八二乙二S?單乙基醚乙酯 70. 0部，升溫至80°C，將燒瓶内進行氣f換後，藉由滴 下管歷經2小時滴下η—丁基曱基丙烯酸酯13. 3部、2 —羥 乙基曱基丙烯酸酯4. 6部、甲基丙烯酸4. 3部、對枯基酚 . ... | 環氧乙烷變性丙烯酸酯（東亞合减股份濃敵公司製「 ARONΙΧΜ110」）7. 4部及2，2’ 一偶氮雙異丁腈0.4部 之混合物。滴下結束後，進一步繼續反應2小時，獲得重 量平均分子量（Mw) 1 0,000之丙烯酸樹脂（B — 4)溶液 〇 冷卻至室溫後，將樹脂溶液取樣約2g，以180°C加熱乾燥 20分鐘，測定未揮發成分，根據其測定值添加二乙二醇 單乙基醚乙酯，以使先前合成之樹脂溶液中之未揮發成 分成為20重量％，調製成丙烯酸樹脂（B-4)溶液。 [聚酯分散劑的製造] (聚酯分散劑1之製造例1 ) 表單編號A0101 第54頁/共76頁 於安裝有氣體導入管、溫度計、電容器、攪拌機之反應 容器中，置入丙烯酸曱酯45.0部、甲基丙烯酸15.0部、 丙烯酸乙酯40. 0部，以氮氣進行置換。將反應容器加熱 至80°C，於3-巯一1，2—丙二醇6.0部，添加環己酮 45. 3部中溶解有2，2 偶氮雙異丁腈0. 4部之溶液，反 應10小時。藉由固體成分測定，確定95%已反應。此時 ，重量平均分子量為4000。接著，使用RIKACID BT-100 (新日本理化製；1，2，3，4 —丁烷四羧酸二酐） 8. 8部、環己酮69. 2部，並追加1, 8 —二吖雙環一[5. 4. 0J-7 —十一炔0. 2部作為觸媒，以120°C反應7小時 。在酸價測定中確定98%以上的酸酐已半酯化，結束反 應。反應結束後，添加環己酮，調製成未揮發成分為50 重量％，獲得酸價129mgKOH/g、重量平均分子量8, 100 之聚酯分散劑一 1的溶液。 (聚酯分散劑之製造例2) 於安裝有氣體導入管、溫度計、電容器、攪拌機之反應 容器中，置入曱基丙烯酸甲酯55. 0部、曱基丙烯酸5. 0部 、丙烯酸乙酯40. 0部，以氮氣進行置換。將反應容器加 熱至80°C，於3 —M-1, 2—丙二醇6.0部，添加環己酮 45. 3部中溶解有2，2’ 一偶氮雙異丁腈0. 4部之溶液，反 應10小時。藉由固體成分測定，確定95%已反應。此時 ，重量平均分子量為4000。接著，使用焦蜜石酸二酐（ DAICEL化學工業製）9. 69部、環己酮70. 1部，並追加 1，8 —二吖雙環一[5. 4. 0]—7 —十一炔0.7部作為觸 媒，以120°C反應7小時。在酸價測定中確定98%以上的 酸酐已半酯化，結束反應。反應結束後，添加環己酮， 表單編號A0101 第55頁/共76頁 201031713 調製成未揮發成分為50重量％，獲得酸價71mgK0H/g、 重量平均分子量8, 100之聚酯分散劑_ 2的溶液。 首先，於以下記載關於鹼顯影型彩色濾光片用著色組成 物之實施例。 實施例1 : 將下述組成之混合物均勻地攪拌混合後，使用直徑lmm之 氧化锆珠，以IGER研磨機（IGER Japan公司製「Mini Model Μ — 250 ΜΚ11」）分散2小時後，以5mm的過渡器 過濾，製作綠色顏料分散體1 (DG—1)。 •第1顏料：微細化顏料（PG—1) 8. 3部 •第2顏料：微細化顏料（PY-1 ) 5· 4部 •色素衍生物：下述化合物一1 1. 4部 •共聚物（A): 共聚物（A-1)(未揮發成分20%) 27. 4部 •樹腊黏結劑（B )溶液： 丙烯酸樹脂溶液（B-1 )(未揮發成分20% ) 7· 3部 •溶劑： 丙二醇單乙基醚乙酯（PGMAC) 50. 3部 接著，將下述組成之混合物攪拌混合均勻後，以1 的 過濾器過濾，獲得綠色彩色濾光片用綠色組成物（CG— 1 Λ - J ^ •綠色顏料分散體（DG—1) 52. 0部 •活性能量線聚合性單體 4. 8部 (新中村化學公司製「NK酯ATMPT」 三烴曱基丙烷三丙烯 酸酯） •活性能量線聚合起始劑 2. 8部 表單編號A0101 第56頁/共76頁 201031713 (千葉特化公司製「IRGACURE —379」2—(二曱胺）一 2 — [4 一曱基苯基]甲基]—1 — [4—(嗎琳基）苯基]—1 —丁酮） •增感劑 0. 2部 (保土谷化學公司製「EAB-F」4，4’一二乙基胺二苯 甲酮） •溶劑： 丙二醇單乙基醚乙酯（PGMAC) 40.2部 實施例2〜16、比較例1〜4 :Lionol Blue ES") 100# & Derivatives (Compound 2) 5 parts, 1000 parts of crushed salt and a 1 gallon kneader made of stainless steel (manufactured by Inoue Seisakusho Co., Ltd.) were mixed and stirred at 50 ° C for 12 hours. The mixture was placed in 3000 parts of warm water, heated to about 70 ° C, and stirred in a high-speed mixer for about 1 hour to form a slurry. The mixture was repeatedly filtered, washed with water to remove salt and solvent, and dried at 80 ° C. In 24 hours, 98 micronized pigments (PB-1) were obtained. (Micronized Pigment Production Example 5) 300 parts of a dioxin-based violet pigment PV23 ("1^_ onol Violet RL" manufactured by Toyo Ink Co., Ltd.) was placed in a 96% sulfuric acid triterpenoid, and the form number A0101 was stirred. 50 pages/76 pages were mixed for 1 hour and then poured into water at 5 °C. After stirring for a few hours, it was filtered and washed with warm water until the washing liquid became neutral '7 (r dry. 120 parts of the obtained acid paste-treated pigment, pigment derivative (compound 3) 5 parts of crushed salt 1500 A 1 gallon kneading machine made of stainless steel (manufactured by Inoue Seisakusho Co., Ltd.) was placed in a stainless steel 1 part, and the mixture was stirred and mixed at 70 ° C for 20 hours. The mixture was placed in warm water of 5000 parts and heated to about 7 一面. The surface was stirred in a high-speed mixer for about 1 hour to form a slurry. After repeated filtration and washing with water to remove salt and solvent, the mixture was dried at 8 (TC for 24 hours to obtain 115 fine pigments (PV-1). Production Example 6) The diketone "Biha and Hip-Hop is a red Yankee p R, (Thousand: IgAPHOR RED B-CF 爹Buzhou Du" pigment derivative (Compound 4) 10 parts The pulverized salt 1 〇 部 and the 2 乙二醇 乙二醇 乙二醇 乙二醇 置 置 置 置 置 置 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 不锈钢 乙二醇 乙二醇 乙二醇 乙二醇 乙二醇The crotch order is heated to about 80 C ' on one side and mixed at the dance speed. Read Zhina It is made into a slurry, and it is repeatedly filtered, washed with water to remove the mash, and dried for 24 hours to obtain a micronized pigment of 1 ο :: f f13⁄4 ^ (Micronized Pigment Production Example 7) Red onion red pigment PR177 (Chiba Special Chemicals) 100 parts of the company's "€ 〇 MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO MO It is made by the Inoue Co., Ltd., and it is mixed and mixed for 5 hours. The mixture is placed in 4000 parts of warm water and heated to about 8 ° C. while being mixed with an idle mixer for about 1 hour to form a slurry. Repeat the transition, wash with water to remove salt and solvent, and then dry at 8 〇t for 24 hours to obtain the micronized pigment (PR-2) of Form No. A0101, page 51 / page 76, 201031713. [Maleic anhydride Copolymer (A) of one or more types of ethylenically unsaturated monomers other than maleic anhydride (manufactured example of maleic anhydride monoterpene copolymer (A-1)) 500 parts of mercaptoacetone was placed in the reaction vessel in which the funnel was dropped, and nitrogen was injected into the container. The mixture was heated to 80 ° C, and a mixture of 348 parts, 294 maleic anhydride, and 2, 2'-azobisisobutyronitrile was passed at the same temperature for 1 hour to carry out a polymerization reaction. After further reacting at 10 ° C for 3 hours, 2.0 parts of azobisisobutyronitrile was dissolved in 50 parts of mercaptoacetone, and the reaction was further continued at 100 ° C for 5 hours to obtain a weight averaged spectrometer. Amount (Mw) 1 3,000 of maleic anhydride-ruthenium copolymer solution. After cooling to room temperature, the copolymer solution was sampled to about 2 g, and dried by heating at 180 ° C for 20 minutes to determine the non-volatile content. The measured value was added with mercaptoacetone so that the non-volatile component in the previously synthesized resin solution became 20% by weight to prepare a maleic anhydride monofluorene copolymer (A-1). Further, the measurement was carried out by infrared spectroscopy to confirm the peak of the acid anhydride group. [Production of Resin Adhesive] (Production Example 1 of Acrylic Resin (B-1)) 800 parts of propylene glycol monoterpene ether acetate were placed in a reaction container, and the mixture was heated to 100 ° C while injecting nitrogen gas into the container. At a temperature, a mixture of 80.0 parts of methacrylic acid, 85.0 parts of methacrylate, 85.0 parts of methyl butyl acrylate and 10.0 parts of 2,2'-azobisisobutyronitrile was dropped over 1 hour to carry out polymerization. . After the dropwise addition, the mixture was further reacted at 100 ° C for 3 hours, and then a portion of azobisisobutyronitrile (2.0 parts) was dissolved in 50 parts of propylene glycol monoethyl ether ethyl ester, and the reaction was further continued at 100 ° C for 1 hour. Form No. A0101 Page 52 of 76 Weight average molecular weight 乂河评) 40,000 acrylate resin (B-1) solution. After cooling to room temperature, the resin solution was sampled to about 2 g, and dried by heating at 180 ° C for 20 minutes, and the non-volatile component was measured, and propylene glycol monoethyl ether ethyl ester was added according to the measured value to make the previously synthesized resin solution The volatile component was 20% by weight to prepare an acrylic resin (B-1) solution. (Production Example 2 of Acrylic Resin (B-2)) In a separate four-stage flask equipped with a thermometer, a cooling tube, a nitrogen introduction tube, a dropping tube, and a stirring device, propylene glycol monoethyl ether ethyl ester 70 was placed. 0份。 2. Part 2, 2-hydroxyethyl methacrylate 4. 6 parts by the dropwise addition of the n-butyl methacrylate after the lapse of 2 hours. 4,4,2,2,2,2,2,2,2,2,2,2,4,4,4,4,4,4,4 a mixture of parts. After the end of the crucible, the reaction was further continued for 3 hours to obtain a solution of an acrylic tree (B-2) having a weight average molecular weight (Mw) of 26,000 〇· --. . . II iiw After cooling to room temperature, the resin was The solution was sampled at about 2 g, and dried by heating at 180 ° C for 20 minutes, and the non-volatile component was measured, and propylene glycol monoethyl ether ethyl ester was added according to the measured value so that the non-volatile component in the previously synthesized resin solution became 20% by weight. A solution of acrylic resin (B-2). (Production Example 3 of Acrylic Resin (B-3)) 800 parts of diethylene glycol monomethyl ether acetate was placed in a reaction container, and while being filled with nitrogen gas in a container, the mixture was heated to 100 ° C at the same temperature. 0. 0 parts of methacrylic acid, 85.0 parts of methacrylate, 85.0 parts of butyl acrylate, 0. 0 parts and 2, 2'-azobisisobutyronitrile 10.0 parts Form No. A0101 Page 53 / Total A mixture of 76 pages 201031713 was subjected to polymerization. After the dropwise addition, the mixture was further reacted at 100 ° C for 3 hours, and then an amount of 2.0 parts of azobisisobutyronitrile was dissolved in 50 parts of diethylene glycol monoethyl ether ethyl ester, and the reaction was further continued at 100 ° C. In minutes, a solution of an acrylic resin (B-3) having a weight average molecular weight (Mw) of 12,000 was obtained. After cooling to room temperature, the resin solution was sampled to about 2 g, and dried by heating at 180 ° C for 20 minutes, and the non-volatile components were measured, and diethylene glycol monoethyl ether ethyl ester was added according to the measured value to prepare the previously synthesized resin solution. The non-volatile component in the middle was 20% by weight, and was prepared into a solution of an acrylic resin (B-3). (Production Example 4 of Acrylic Resin (B-4)) In a separate four-stage flask equipped with a thermometer, a cooling tube, a nitrogen introduction tube, a dropping tube, and a stirring device, octaethylenediethyl succinate was placed. The ethyl ester was 70. 0, and the temperature was raised to 80 ° C. After the gas was changed in the flask, η-butyl methacrylate was added dropwise by dropping the tube for 2 hours. 6 parts of acrylate, 4.3 parts of methacrylic acid, p-cumyl phenol. ... | Ethylene oxide modified acrylate (ARON ΙΧΜ 110 made by East Asia Joint Stock Co., Ltd.) 7. 4 and 2 , a mixture of 2'-azobisisobutyronitrile 0.4 parts. After the completion of the dropwise addition, the reaction was further continued for 2 hours to obtain a solution of an acrylic resin (B-4) having a weight average molecular weight (Mw) of 10,000. After cooling to room temperature, the resin solution was sampled to about 2 g, and dried by heating at 180 ° C for 20 minutes. The non-volatile component was measured, and diethylene glycol monoethyl ether ethyl ester was added according to the measured value so that the non-volatile component in the previously synthesized resin solution became 20% by weight to prepare an acrylic resin (B-4) solution. [Production of Polyester Dispersant] (Production Example 1 of Polyester Dispersant 1) Form No. A0101 Page 54 of 76 In a reaction vessel equipped with a gas introduction tube, a thermometer, a capacitor, and a stirrer, yttrium acrylate was placed. 45.0 parts of ester, 15.0 parts of methacrylic acid, and 40.0 parts of ethyl acrylate were replaced with nitrogen. The reaction vessel is heated to 80 ° C, in the portion of 3-巯-1,2-propanediol, and the cyclohexanone is added in a portion of the mixture of 2,2 azobisisobutyronitrile. 10 hours. It was determined by solid content measurement that 95% had reacted. At this time, the weight average molecular weight was 4,000. Next, use RIKACID BT-100 (Nippon Chemical and Chemical Co., Ltd.; 1, 2, 3, 4 - butane tetracarboxylic dianhydride) 8. 8 parts, cyclohexanone 69. 2 parts, and add 1, 8 - 2 Double ring one [5. 4. 0J-7 - eleven alkyne 0.2 part was used as a catalyst and reacted at 120 ° C for 7 hours. It was confirmed in the acid value measurement that 98% or more of the acid anhydride was half-esterified, and the reaction was terminated. After completion of the reaction, cyclohexanone was added to prepare a nonvolatile content of 50% by weight to obtain a solution of a polyester dispersant-1 having an acid value of 129 mgKOH/g and a weight average molecular weight of 8,100. (Production Example 2 of Polyester Dispersing Agent) In a reaction vessel in which a gas introduction tube, a thermometer, a capacitor, and a stirrer are attached, a methyl methacrylate 55.0 part, a decyl acrylate 5. 0 part, ethyl acrylate is placed. 40. Part 0, replaced with nitrogen. 4的溶液。 The reaction vessel was heated to 80 ° C, in the portion of 3-M-1, 2-propanediol 6.0, cyclohexanone was added in 45. 3 parts of 2,2'-azobisisobutyronitrile dissolved in 0.4 parts , the reaction was 10 hours. It was determined by solid content measurement that 95% had reacted. At this time, the weight average molecular weight was 4,000. Next, using 9.69 parts of pyromellitic dianhydride (manufactured by DAICEL Chemical Industry Co., Ltd.) and 70.1 parts of cyclohexanone, and adding 1,8-di-bicyclo-bicyclo-[5. 4. 0]-7- The alkyne 0.7 was used as a catalyst and reacted at 120 ° C for 7 hours. It was confirmed in the acid value measurement that 98% or more of the acid anhydride was half-esterified, and the reaction was terminated. After completion of the reaction, cyclohexanone was added, Form No. A0101, page 55/76, 201031713, to prepare a nonvolatile content of 50% by weight to obtain a polyester dispersant having an acid value of 71 mg K0H/g and a weight average molecular weight of 8,100. The solution. First, an embodiment of a coloring composition for an alkali developing type color filter will be described below. Example 1 : A mixture of the following composition was uniformly stirred and mixed, and then zirconia beads having a diameter of 1 mm were used, and dispersed by an IGER mill ("Mini Model Μ - 250 ΜΚ 11" manufactured by Iger Japan Co., Ltd.) for 2 hours, and then 5 mm. The transition vessel was filtered to produce a green pigment dispersion 1 (DG-1). • 1st pigment: fine pigment (PG-1) 8. 3 parts • 2nd pigment: fine pigment (PY-1) 5· 4 parts • Pigment derivative: the following compound-1 1. 4 parts • Copolymerization (A): Copolymer (A-1) (20% non-volatile content) 27. Part 4: Tree wax binder (B) Solution: Acrylic resin solution (B-1) (20% non-volatile content) 7· 3 parts • Solvent: propylene glycol monoethyl ether ethyl ester (PGMAC) 50. 3 parts, the mixture of the following composition was stirred and mixed uniformly, and then filtered with a filter of 1 to obtain a green color filter green composition ( CG— 1 Λ - J ^ • Green pigment dispersion (DG-1) 52. 0 • Active energy ray polymerizable monomer 4. 8 (Nippon Nakamura Chemical Co., Ltd. “NK ester ATMPT” Trihydrocarbyl propane III Acrylate) • Active energy ray polymerization initiator 2. Part No. Form No. A0101 Page 56 / Total 76 pages 201031713 ("IRGACURE - 379" manufactured by Chiba Special Chemical Co., Ltd. 2 - (diamine) 2 - [4曱Phenyl phenyl]methyl]-1 — [4-(m-allinyl)phenyl]-1-butanone) • Sensitizer 0.2. 2 (EAB-F) 4, manufactured by Hodogaya Chemical Co., Ltd. 4'-diethylamine dibenzophenone) • Solvent: propylene glycol monoethyl ether ethyl ester (PGMAC) 40.2 parts Examples 2 to 16 and Comparative Examples 1 to 4:

以表1〜4所示之組成比，調配下述色素衍生物（化合物 —1〜化合物一 6)、及表]〜4所示之顏料、分散劑、共 聚物（A)、樹脂黏結劑（B)、活性能量線聚合性單體 、第3級膦化合物、活性能量線聚合性起始劑、增感劑及 溶劑，與實施例1同樣地獲得顏料分散體，並接著獲得彩 色濾光片用著色組成物。 化合物一1 :In the composition ratios shown in Tables 1 to 4, the following pigment derivatives (Compound-1 to Compound-1) and the pigments, dispersants, copolymers (A) and resin binders shown in Tables 4 to 4 were blended ( B), an active energy ray polymerizable monomer, a third-stage phosphine compound, an active energy ray-polymerizable initiator, a sensitizer, and a solvent, and a pigment dispersion was obtained in the same manner as in Example 1, and then a color filter was obtained. Use a coloring composition. Compound-1:

[0022] 化合物一2: 表單編號A0101 第57頁/共76頁 201031713 [0023] 〇Compound 2: Form No. A0101 Page 57 of 76 201031713 [0023] 〇

[0024] Cu-Pc :銅敗菁 [0025] 化合物3 :Cu-Pc: copper phthalocyanine [0025] Compound 3:

[0029] 化合物5 : 表單編號A0101 第58頁/共76頁 201031713 [0030]Compound 5: Form No. A0101 Page 58 of 76 201031713 [0030]

[0031] 化合物6 : [0032]Compound 6: [0032]

Cu—Pe+- S02—NH-4 CH2V-N 、/ 2 、 [0033] Cu-Pc :銅酞菁 C2H5 c2h5 4 ❿ 表單編號A0101 第59頁/共76頁 201031713 [0034] 表1:Cu-Pe+-S02-NH-4 CH2V-N, / 2, [0033] Cu-Pc: copper phthalocyanine C2H5 c2h5 4 ❿ Form No. A0101 Page 59 of 76 201031713 [0034] Table 1:

霣_ mm 獅13 議14 霣娜 CG-1 CG-2 OG-2 CG-3 CG-4 嫌^8 m 讎 tafeamPG-1) 43 43 43 43 43 麵t*麵(旧） 28 2B 2fi 2S 麵 t* 娜(FY-0 mm 化雏-1 0.7 07 07 0.7 07 mm bik-111 0.7 激働卜1 Q7 嫌删-2 機(Α-1) 14.2 共齡-a 14.2 共獅-3) 14.2 12B m mm mmm) 彻瞻獅-1) 38 3B 38 3.4 a4 _賺臟-幺 m PGMAC 26,1 26.1 25,1 272 272 彩mm 用總脑 m mms DG-1 DG-2 DG-3 DG-4 DG-5 52i0 52ΰ 52.0 520 520 M-402 4B 4.8 4.8 4.8 45 第娜纖 三7¾¾ 挪 IRG379 2B 1% 2.8 2S 2S 翻-1 賴 EAB-F 02 0.2 0.2 0.2 0.2 m PGMAC 40.2 似2 Φ2 m 402 S3EE mo 100.0 \m mo 1CO.O霣_ mm Lion 13 Discussion 14 霣 CG-1 CG-2 OG-2 CG-3 CG-4 ^ ^8 m 雠tafeamPG-1) 43 43 43 43 43 face t* face (old) 28 2B 2fi 2S face t* 娜(FY-0 mm 幼-1 - 0.7 07 07 0.7 07 mm bik-111 0.7 働 働 1 Q7 删 -2 -2 machine (Α-1) 14.2 Age-a 14.2 Total lion-3) 14.2 12B m mm mmm) 彻 狮-1) 38 3B 38 3.4 a4 _ earn dirty - 幺m PGMAC 26,1 26.1 25,1 272 272 color mm with total brain m mms DG-1 DG-2 DG-3 DG-4 DG-5 52i0 52ΰ 52.0 520 520 M-402 4B 4.8 4.8 4.8 45 Dina fiber three 73⁄43⁄4 move IRG379 2B 1% 2.8 2S 2S turn-1 Lai EAB-F 02 0.2 0.2 0.2 0.2 m PGMAC 40.2 Like 2 Φ2 m 402 S3EE Mo 100.0 \m mo 1CO.O

[0035] 表 2: 瓣16 mu wm 腳19 娜ho CG-6 CG-7 OG-8 OG-9 CG-10 mms mm 新 43 43 43 43 43 25 2B 2B 麵tt觸㈣-2) ZB 28 mm 織-1 0.7 0.7 0.7 0.7 0.7 删 bvk-111 鼸删-1 雜^βΜ-2 Q7 Q7 Q7 Q7 Q4 纖w 纖(Α-1) 戀(A-a ^KA-3) m 123 % % m mm mmtiB) mmmiB-)) a4 m酣獅-0 S4 es &6 7.0 m PGMAC 27.2 27.2 27.2 275 26-8 mm tn««.£Dcfr mmst DG-6 DG-7 DG-8 DG-9 EX3-10 52.0 52J0 52D 523 52j0 M-402 45 4*8 4B 4B 第3明lf〇g ΞΊΒΙ Q4 三鄉 用 m IRG379 23 2B 2S 2B 2B 删-i _ EAB-F 0.2 0.2 02 0.2 02 测 PGM/C 40.2 40.2 40,2 40.2 392 费Ξ^ϋ 100.0 im m 1003 100.0 表單編號A0101 第60頁/共76頁 201031713[0036] [0037] 表3: SMn MM\2 S^13 比_ 腳|2 CG-11 CG-12 OG-13 A3~ CG-C1 """43 CG-C2 Έ~ mam 醎(餓 麒 麵 ^&^KPG-1) 43 43 激細br色嫌Kfy-i> 28 28 IB ZQ 28 mm 化雜-1. 0.7 07 0.7 0.7 0,7 测 byk-111 雜獅-1 mmm-2 0.4 0.4 Q4 Q4 Q4 mm 纖(A-1) 纖(A-公 ^mA-3) ιαο im 10.0 mm m 邴隨励-2) 7.0 7.0 7.0 169 7.0 m\ PGMAC 26.8 26^ 26.8 26B m 彩 DG-11 DG-12 DG-13 DG-C1 DG-C2 52ΰ 52JQ 52.0 520 520 M-402 4,8 4·8 48 AB 45 第3娜纖 三Ί» Ξ^ϊ Q4 Q4 Q.A Q4 Q4 mvcilSra 娜 IRG379 2.8 翻-1 2B n 2Z 2B _ EAB-F 0.2 0.2 02 0.2 0.2 m P&JifC 395 395 19S m m 15^e 200 200 mo im 100,0 xm _ mo f if 參 表4· 彩騰麵 誦4 麵 _ΙΙ5 腦6 騰 CB-T cB-a CR-1 GR-2 GR-α &t^6h§· 謝 麵 H6®(FB-1) 40 4ΰ 獅 KiMPv-1) 02 02 MI6SB(fr-i) 4,9 24 24 黼 ίί&®^-2) 0£ in 2ΰ 讎 I» 獼(W-1) 1.1 1.1 SFiyjros 麵 麵 ime Q.4 0,4 她 05 05 05 讎 雜働I-2 17 1.7 1.1 1.1 1.1 麵(A) 纖(A-3) 42 109 109 14.7 m 12:4 124 23.4 m PGMAQ 16S m 205 205 205 mm mm m MB DB-1 DB-C1 DR-1 DR-2 OR-α 42Λ 42Λ 51ΰ 510 51D 纖(A-3) 100 mma) 1Q0 W 1.0 ID 雜 M-402 5.6 5.6 4.0 4.0 4.0 第3咖織 Q4 Q4 α4 Q4 04 麵-1 10 肋 a4 a4 a4 m EPB-F 02 02 Q4 Q4 04 涵 PGMC m m 14S m 148 辑跑 2Q0 200 25.0 25.0 25.0 m 10〇β 100.0 m lOOfi 表單編號.Α0101 第61頁/共76頁 201031713 [0038] 於以下表示表1〜4中的簡寫。 •分散劑：「byk—111」 BYK公司製含填酸基顏料分散劑「Disperbyklll」 •共聚物（A): 「共聚物（A —2)」：Sartomer Japan公司製「 SMA2000P」（SMA基底樹脂、順丁烯二酸酐苯乙烯共 聚物、共聚比1 : 2)溶解於環己酮，調整為未揮發成分 20重量％。 「共聚物（A —3)」：Sartomer Japan公司製「 SMA1 000P」（SMA基底樹脂、順丁烯二酸酐苯乙烯共 聚物、共聚比1 : 1)溶解於環己酮，調整為未揮發成分 20重量％。 •比較共聚物： 「比較共聚物一1」：Sartomer Japan公司製「 SMA1440」（SMA酯樹脂、順丁烯二酸酐-苯乙烯共聚物 的半酯、酸價185mgK0H/g)溶解於環己酮，調整為未揮 發成分20重量％。 •活性能量線聚合性單體： 「M —402」 東亞合成公司製「ARONIX M-402」二季戊四醇丙烯酸 己酯 •活性能量線聚合起始劑： 「IRGACURE — 379」 千葉特化公司製「IRGACURE — 379」2-(二曱胺）一2 -[4 一曱基苯基]甲基]—1 —[4-(嗎啉基）苯基]_1 _ 丁酮 表單編號A0101 第62頁/共76頁 「起始劑一1」 依據日本特開平5 — 21 3861號公報記載方法所合成的二曱 基苯曱醯毓丁基三苯基硼酸鹽 •增感劑：「EAB — F」 保土谷化學公司製「EAB —F」4，4’_雙（二乙基胺） 二苯甲酮 •溶劑：「PGMAC」 丙二醇單乙基醚乙酯 接下來，於以下記载關於在喷墨方式所使用的著色組成 物之實施例。 實施例17 : 將下述組成之混合物均勻地攪拌混合後，it用直徑1mm之 氧化锆珠，以IGER研磨機（IGER Japan公司製「Mini Model Μ —250 MKII」）分散2小時後，以5em的遇遽 器過濾，製作綠色顏料分散體1 (DG-14)。 •第1顏料：微細化顏料（PG-1 ) 8. 3部 •第2顏料：微細化顏料（PY-1 ) 5. 4部 •色素衍生物：化合物一1' 1.4部 •共聚物（Λ): 共聚物（A —4)(未揮發成分20%) 27.4部 •樹脂黏結劑（B )溶液： 丙烯酸樹脂溶液（B — 3)(未揮發成分20%) 7. 3部 •溶劑： 二乙二醇單乙基醚乙酯 50.3部 接著，將下述組成之混合物攪拌混合均勻後，以1mm的過 濾器過濾，獲得綠色彩色濾光片用綠色組成物（CG—14 表單編號A0101 第63頁/共76頁 201031713 •綠色顏料分散體（DG —14) 52· 0部 •活性能量線聚合性單體或熱聚合性單體： MX —43 6. 2部 (三和化學公司製「NIKALAC MX-43」含有烷氧基烷基 之三聚氰胺化合物） •溶劑： 二乙二醇單乙基醚乙酯 41.8部 實施例17〜27、比較例5〜6 : 以表5〜6所示之組成比，調配上述色素衍生物、顏料、 分散劑、共聚物（A)、樹脂黏結劑（B)、活性能量線 聚合性單體或熱聚合性單體及溶劑，與實施例17同樣地 獲得顏料分散體，並接著獲得彩色濾光片用著色組成物 表5:Table 2: Petal 16 mu wm Feet 19 Na ho CG-6 CG-7 OG-8 OG-9 CG-10 mms mm New 43 43 43 43 43 25 2B 2B Face tt Touch (4)-2) ZB 28 mm Weaving -1 0.7 0.7 0.7 0.7 0.7 Deleting bvk-111 鼸 -1 -1 Miscellaneous ^βΜ-2 Q7 Q7 Q7 Q7 Q4 Fibrous fiber (Α-1) Love (Aa ^KA-3) m 123 % % m mm mmtiB) mmmiB-)) a4 m lion lion - 0 S4 es & 6 7.0 m PGMAC 27.2 27.2 27.2 275 26-8 mm tn««.£Dcfr mmst DG-6 DG-7 DG-8 DG-9 EX3-10 52.0 52J0 52D 523 52j0 M-402 45 4*8 4B 4B 3rd lf〇g ΞΊΒΙ Q4 Sanxiang use m IRG379 23 2B 2S 2B 2B Delete-i _ EAB-F 0.2 0.2 02 0.2 02 Measure PGM/C 40.2 40.2 40, 2 40.2 392 Fee Ξ ^ ϋ 100.0 im m 1003 100.0 Form No. A0101 Page 60 / Total 76 Page 201031713 [0036] [0037] Table 3: SMn MM\2 S^13 ratio _ Foot | 2 CG-11 CG-12 OG-13 A3~ CG-C1 """43 CG-C2 Έ~ mam 醎(Hungry ^面^&^KPG-1) 43 43 broiler brilliance Kfy-i> 28 28 IB ZQ 28 Mm compound-1. 0.7 07 0.7 0.7 0,7 measured byk-111 lion-1mmm-2 0.4 0.4 Q4 Q4 Q4 mm fiber (A-1) Fiber (A-Male^mA-3) ιαο im 10.0 mm m 邴 励-2) 7.0 7.0 7.0 169 7.0 m\ PGMAC 26.8 26^ 26.8 26B m Color DG-11 DG-12 DG-13 DG-C1 DG- C2 52ΰ 52JQ 52.0 520 520 M-402 4,8 4·8 48 AB 45 3rd 3rd Ί»Ξ^ϊ Q4 Q4 QA Q4 Q4 mvcilSra 娜 IRG379 2.8 Turn-1 2B n 2Z 2B _ EAB-F 0.2 0.2 02 0.2 0.2 m P&JifC 395 395 19S mm 15^e 200 200 mo im 100,0 xm _ mo f if 参表4· 彩腾面诵4面_ΙΙ5 Brain 6 Teng CB-T cB-a CR-1 GR-2 GR-α &t^6h§· Xie Fu H6®(FB-1) 40 4ΰ Lion KiMPv-1) 02 02 MI6SB(fr-i) 4,9 24 24 黼ίί&®^-2) 0£ in 2ΰ 雠I» 猕 (W-1) 1.1 1.1 SFiyjros face ime Q.4 0,4 she 05 05 05 雠 働 I-2 17 1.7 1.1 1.1 1.1 face (A) fiber (A-3) 42 109 109 14.7 m 12:4 124 23.4 m PGMAQ 16S m 205 205 205 mm mm m MB DB-1 DB-C1 DR-1 DR-2 OR-α 42Λ 42Λ 51ΰ 510 51D fiber (A-3) 100 mma) 1Q0 W 1.0 ID Miscellaneous M-402 5.6 5.6 4.0 4.0 4.0 3rd woven Q4 Q4 α4 Q4 04 Face-1 10 rib a4 a4 a4 m EPB- F 02 02 Q4 Q4 04 culvert PGMC mm 14S m 148 Run 2Q0 200 25.0 25.0 25.0 m 10〇β 100.0 m lOOfi Form No. Α0101 Page 61 / Total 76 pages 201031713 [0038] The following shows the tables in Tables 1~4 Shorthand. • Dispersant: “byk—111” Disperbyklll, an acid-based pigment dispersant manufactured by BYK Co., Ltd. • Copolymer (A): “Copolymer (A-2)”: “SMA2000P” (SMA base resin) manufactured by Sartomer Japan The maleic anhydride styrene copolymer and the copolymerization ratio 1: 2) were dissolved in cyclohexanone and adjusted to 20% by weight of the nonvolatile component. "Copolymer (A-3)": "SMA1 000P" (SMA base resin, maleic anhydride styrene copolymer, copolymerization ratio 1:1) manufactured by Sartomer Japan Co., Ltd. was dissolved in cyclohexanone and adjusted to nonvolatile content. 20% by weight. •Comparative Copolymer: "Comparative Copolymer 1": "SMA1440" (semi-ester of SMA ester resin, maleic anhydride-styrene copolymer, acid value 185 mg K0H/g) manufactured by Sartomer Japan Co., Ltd. dissolved in cyclohexanone , adjusted to 20% by weight of the non-volatile component. • Active energy ray polymerizable monomer: "M-402" "ARONIX M-402" dipentaerythritol hexyl acrylate manufactured by Toagosei Co., Ltd. • Active energy ray polymerization initiator: "IRGACURE - 379" IMGACURE manufactured by Chiba Special Chemical Co., Ltd. — 379"2-(Didecylamine)- 2 -[4-monodecylphenyl]methyl]-1 -[4-(morpholinyl)phenyl]_1 _butanone Form No. A0101 Page 62 of Page 76 "Starting Agent-1" Dimercaptophenyl butyl butyl triphenyl borate/sensitizer synthesized according to the method described in JP-A-5-21861, "EAB - F" Chemical company "EAB-F" 4,4'_bis(diethylamine) benzophenone solvent: "PGMAC" Propylene glycol monoethyl ether ethyl ester Next, as described below in the inkjet system An example of a colored composition used. Example 17: A mixture of the following composition was uniformly stirred and mixed, and then it was dispersed by an IGER mill ("Mini Model Μ-250 MKII" manufactured by Iger Japan Co., Ltd.) for 1 hour with a zirconia bead having a diameter of 1 mm, and 5 cm. Filtered with a masher to make a green pigment dispersion 1 (DG-14). • 1st pigment: fine pigment (PG-1) 8. 3 parts • 2nd pigment: fine pigment (PY-1) 5. 4 parts • Pigment derivative: compound-1' 1.4 part • copolymer (Λ ): Copolymer (A-4) (non-volatile content 20%) 27.4 parts • Resin binder (B) solution: Acrylic resin solution (B-3) (non-volatile content 20%) 7. 3 parts • Solvent: 2 50.3 parts of ethylene glycol monoethyl ether ethyl ester. Then, the mixture of the following composition was stirred and mixed uniformly, and then filtered with a filter of 1 mm to obtain a green composition for a green color filter (CG-14 Form No. A0101, No. 63) Page / Total 76 pages 201031713 • Green pigment dispersion (DG-14) 52· 0 • Active energy ray polymerizable monomer or thermal polymerizable monomer: MX—43 6. 2 (NIKALAC, manufactured by Sanwa Chemical Co., Ltd.) MX-43" alkoxyalkyl group-containing melamine compound) • Solvent: Diethylene glycol monoethyl ether ethyl ester 41.8 parts Examples 17 to 27, Comparative Examples 5 to 6: Compositions shown in Tables 5 to 6 To blend the above pigment derivative, pigment, dispersant, copolymer (A), resin binder (B), active energy ray polymerization single Or thermal polymerizable monomer and a solvent, the pigment dispersion obtained in Example 17 in the same manner, and then obtain a coloring composition for color filter TABLE 5:

獅 117 獅H8 靡}19 腳120 腳121 CG-14 CG-15 GG-16 CG-17 CG-18 CG-19 srnm mm m A2 43 4.3 A2 43 43 1% 2fl 四 2B 2B 2B mm 化部H Q7 a7 Q7 Q7 07 Q7 m\ 颺讎H Q7 雜删卜2 Q7 Q7 纖w 142 142 纖(A_a 142 12fl m 128 mm mm-2 (B) mmm^) 35 ZB 3fl 3.4 a4 34 酗醐關細-4〉 测 ΖίΙΟΕϋΖ* 262 m 262 273 27.3 27.3 1,3-S3izt 彩 獅 DG-14 DG-15 DG-16 DG-17 DG-18 DG-19 52.0 52.0 52.0 520 52.0 52.0 雜 MK-43 62 6·2 62 U 62 EX-252 B2 M-402 m\ ZZZmZMZM 41B 41 fl 41fi 41.8 41.8 41.8 1,3-RUtZS 100.0 1刚 100D 100B 删 100D 表單編號A0101 第64頁/共76頁 201031713 [0039] φ 表6: 彩&1)^鹏_ _|23 獅 124. 咖防 獅 126 「獅 15 ism CG-20 OG-21 OG-22 CG-23 0G-C3 CG-G4 mm mm m mmmipG-λ) 4.3 43 A3 4.3 43 A3 級册*色θΗίγ-ι) 28 ,28 2S 28 28 鯽tt糖(Pr-a 2S mim 化部!-1 Q7 Q7 Q7 Q7 Q7 07 mi 5¾働卜i— 騙删-2 Q7 α7 Q7 Q7 Q7 纖(A) 纖(A-1) 纖(A，a ^ϋ(Α-3) 128 m 128 M2 imm 臓彌)-2 142 ®) 彻雖獅-3> 3.4 14 162 38 酗输励-4) 3L4 38 额1 ζζ^ΐίΐζ^ζ* 273 273 262 273 m ί.3-?〇ίΖΖβ m 用著繼 urn wms DG-20 DG-21 OG-22 DG-23 DG-C3 0G-C4 52.0 52.0 52.0 52.7 52.0 520 雜 ΜΧ-43 62 62 Ώ 62 62 ΕΧ-252 Μ-402 62 m 41S 413 41B 41B 1,3-fclCZS 413 1001) 1Q0 B . iooD | mj 1咖 1咖 [0040]Lion 117 Lion H8 靡}19 Feet 120 Feet 121 CG-14 CG-15 GG-16 CG-17 CG-18 CG-19 srnm mm m A2 43 4.3 A2 43 43 1% 2fl 4 2B 2B 2B mm Department H Q7 A7 Q7 Q7 07 Q7 m\ Yang Hao H Q7 Miscellaneous buck 2 Q7 Q7 fiber w 142 142 fiber (A_a 142 12fl m 128 mm mm-2 (B) mmm^) 35 ZB 3fl 3.4 a4 34 酗醐关细-4 〉 Ζ ΙΟΕϋΖ ΙΟΕϋΖ 262 m 262 273 27.3 27.3 1,3-S3izt lion DG-14 DG-15 DG-16 DG-17 DG-18 DG-19 52.0 52.0 52.0 520 52.0 52.0 Miscellaneous MK-43 62 6·2 62 U 62 EX-252 B2 M-402 m\ ZZZmZMZM 41B 41 fl 41fi 41.8 41.8 41.8 1,3-RUtZS 100.0 1 just 100D 100B Delete 100D Form No. A0101 Page 64 / Total 76 pages 201031713 [0039] φ Table 6: Color &1)^鹏_ _|23 lion 124. 咖防狮126 "Lion 15 ism CG-20 OG-21 OG-22 CG-23 0G-C3 CG-G4 mm mm m mmmipG-λ) 4.3 43 A3 4.3 43 A3 grade book *color θΗίγ-ι) 28 ,28 2S 28 28 鲫tt sugar (Pr-a 2S mimization department!-1 Q7 Q7 Q7 Q7 Q7 07 mi 53⁄4働i i- scam deletion-2 Q7 α7 Q7 Q7 Q7 fiber (A) fiber (A-1) fiber (A, a ^ϋ(Α-3) 128 m 128 M2 imm 臓)-2 142 ®) Thorough lion-3> 3.4 14 162 38 酗 励 -4) 3L4 38 Amount 1 ζζ^ΐίΐζ^ζ* 273 273 262 273 m ί.3-?〇ίΖΖβ m with urn wms DG-20 DG-21 OG-22 DG-23 DG-C3 0G-C4 52.0 52.0 52.0 52.7 52.0 520 chowder-43 62 62 Ώ 62 62 ΕΧ-252 Μ-402 62 m 41S 413 41B 41B 1,3-fclCZS 413 1001) 1Q0 B . iooD | mj 1 coffee 1 coffee [0040]

於以下表示表5〜6中的簡寫。 ♦共聚物（Α): 「共聚物（A —5)」sSartomeg Japan令司製「 ί nfpilof'fi ifil SMA2 00 0P」（SMA基底樹脂/’順丁烯二被If 苯乙稀共 ...... -:丨. 1柳-寶辟^^ 气卢. ❹ 聚物、共聚比1 : 2)溶解表教诫整為未揮發成分 20重量％。 「共聚物（A —6)」：Sartomer Japan公司製「 SMA1 000P」（SMA基底樹脂、順丁稀二酸酐笨乙稀共 聚物、共聚比1 : 1)溶解於環己酮，調整為未揮發成分 20重量％。 •比較共聚物： 「比較共聚物-2」：Sartomer Japan公司製「SMA1440 」（SMA酯樹脂、順丁烯二酸酐-苯乙烯共聚物的半酯、 表單褊號A0101 第65頁/共76頁 201031713 酸價185mgK0H/g)溶解於環己酮，調整為未揮發成分2〇 重量％。 •活性能量線聚合性單體或熱聚合性單體： 「MX-43」 三和化學公司製「NIKALAC MX-43」含有烷氧基烷基之 二聚氮胺化合物 「EX- 252」 長瀨產業股份有限公司製「DENACOL EX-252」氫化雙 笨酚A二縮水甘油基醚 「M-402」 東亞合成公司_「ARONIX M-402j二季:戍四醇丙烯酸 [分散穩定性] 針對實施例及比較例所獲得的彩色濾光片用著色組成物 藉由下述方法，依據黏度穩定性來評估分散穩定性。 利用Ε型黏度計（東機產業:公司ilELD型黏度計」）， 於25°C ’以旋轉數20印111的1条*#?，測定s彩色濾光片用著色 組成物調製隔天之初期黏度，及表40。(：經1週促進經時後 之經時黏度。從該初期黏度及經時黏度的值，利用下式 算出經時黏度變化率。The abbreviations in Tables 5 to 6 are shown below. ♦ Copolymer (Α): "Copolymer (A-5)" sSartomeg Japan made " ί nfpilof'fi ifil SMA2 00 0P" (SMA base resin / 'butylene II by If styrene... ... -:丨. 1柳-宝辟^^ 气卢. ❹ Polymer, copolymerization ratio 1: 2) Dissolve the formula to 20% by weight of non-volatile components. "Copolymer (A-6)": "SMA1 000P" (SMA base resin, butyl butyric acid anhydride, copolymerization ratio 1:1) manufactured by Sartomer Japan Co., Ltd. was dissolved in cyclohexanone and adjusted to be nonvolatile. The composition was 20% by weight. •Comparative Copolymer: "Comparative Copolymer-2": "SMA1440" manufactured by Sartomer Japan Co., Ltd. (Semi-ester of SMA ester resin, maleic anhydride-styrene copolymer, Form No. A0101 Page 65 of 76 201031713 The acid value of 185 mg K0H/g) was dissolved in cyclohexanone and adjusted to 2% by weight of the nonvolatile component. • Active energy ray polymerizable monomer or thermal polymerizable monomer: "MX-43" "NIKALAC MX-43" manufactured by Sanwa Chemical Co., Ltd. contains alkoxyalkyl diamine compound "EX- 252" DENCO CO., LTD. The coloring composition for a color filter obtained in the comparative example was used to evaluate the dispersion stability according to the viscosity stability by the following method. Using a Ε-type viscometer (Tokyo Industry: company ilELD type viscometer), at 25° C' is printed on the first day of the next day with the coloring composition of the s color filter by one of the *#?? (: The viscosity with time after the passage of time was promoted for one week. From the values of the initial viscosity and the viscosity with time, the rate of change in viscosity with time was calculated by the following formula.

經時黏度變化率=丨（[初期黏度][經時黏度])/[初 始黏度]丨xlOOChange rate of viscosity over time = 丨 ([initial viscosity] [time-dependent viscosity]) / [initial viscosity] 丨 xlOO

[塗膜之相對介電率、介電正切評估] 於為了電極用而經銘蒸锻之l〇〇mmxlOOmm、厚度〇. 7mm 之玻璃基板上，利用旋轉塗布機，以乾燥後膜厚會成為 厚度2. 之旋轉數，塗布實施例1〜16及比較例1〜4 表單编號A0101 第66頁/共76頁 所獲得的驗顯影型彩色濾光片用著色組成物，獲得塗布 基板。接著，減壓乾燥後，使用超高壓水銀燈，以積算 光量300mj、照度30mW進行紫外線曝光《其後’以230°C 加熱塗布基板1小時，予以放置冷卻後，於所獲得的硬化 塗膜上，蒸鍍面積3.464xl(T4m2之電極用鋁，製作鋁電 接爽住硬化塗膜的取樣。關於實施例17〜26及比較例5、 6之噴墨用墨水，於為了電極用而經鋁蒸艘之lOOmmx WOmm、厚度〇· 7mm之玻璃基板上，利用旋轉塗布機，以 乾*燦後祺厚會成為厚度2· Oem之旋轉數塗布，獲得塗布 基板°接著，減壓乾燥後，以23(TC加熱塗布基板30分鐘 ’予以放置冷卻後，於所獲得.的碌北塗嫉年:，蒸鍍面積 之電極用鋁，製作鋁電極夾佐硬化塗膜的 取樣。 使用随抗分析儀（Solartron公司製「12..60型」），以 施加電壓100mV測定所獲得的取樣從10Hz到1MHz的靜電 電容’算出20Hz時之相對介電¥改5分靡麵L值，以下述 基準進行3階段評估〇 f ropert/ (相對介電率） Ofiii-3 ◎:相對介電率小於3. 0 〇：相對介電率3. 0以上、小於4. 0 △:相對介電率4. 0以上、小於5. 0 X :相對介電率5. 0以上 (介電正切） ◎:介電正切小於〇. 02 〇：介電正切0. 02以上、小於0. 03 △.介電正切0.03以上、小於0. 04 表單编珑A0101 第67頁/共76頁 201031713 X :介電正切0· 04以上 [塗膜的密接性、顯影殘渣評估] 於lOOmmxlOOmm、厚度〇 7腿之玻璃基板（基板1 )上及 TFT方式液晶驅動用基板表面形成有氮化矽膜之基板（基 板2)上，利用旋轉塗布機，以乾燥後膜厚會成為厚度 2. 0/zm之旋轉數，塗布實施例及比較例所獲得的彩色濾 光片用著色組成物，減壓乾燥後，使用超高壓水銀燈， 中介光罩，以積算光量3〇〇mj '照度3〇mW進行紫外線曝 光。其後’使用0. 2重量％碳酸鈉水溶液作為顯影液，去 除塗膜未硬化部分而形成圖案。針對該塗膜之密接性及 未硬化部分之顯影殘渣，藉由目視，以下述基準進行3階 段評估。 (密揍性） ◎:完全確認不到圖案剝離 〇：稍微確認圖案剝雜 △:確認圖案剝離 mtesiedua! (顯影殘逢.). hcforiy ◎:無未硬化部分之顯影殘邊 〇：稍微有未硬化部分之顯影殘渣 △:確認未硬化部分之顯影殘渣 [平坦性] 於lOOmmxlOOmm、厚度0. 7mm之玻璃基板（基板1)上及 TFT方式液晶驅動用基板表面形成有氮化矽膜之基板（基 板2)上，分別利用旋轉塗布機，於玻璃基板，形成乾燥 後膜厚2. 0/zm之塗膜，於TFT方式液晶驅動用基板表面形 成有氮化矽膜之基板，形成乾燥後膜厚3. 0/zm之塗膜。 表單編號A0101 第68頁/共76頁 分別將塗布基板予以減壓乾燥後，使用超高壓水銀燈， 以積算光量150mJ進行紫外線曝光，以230°C加熱1小時 ，放置冷卻後，從塗布基板的基板中央往對角線方向， 每隔2cm測定膜厚，依據下式算出膜厚均勻性，評估平坦 性。 膜厚均勻性[%]= (ΤΙ—T2) /T) xlOO 膜厚均勻性[%]宜小，以下述基準進行3階段評估。 ◎:膜厚均勻性[%]小於4. 0% 〇：膜厚均勻性[%]4. 0%以上、小於8. 0% △:膜厚均勻性[%]8· 0%以上、小於12. 0% [喷出穩定性] 採喷墨方式使用時，是否能夠穩定喷出墨水甚為重要。 於SII公司512噴頭（習稱12pl/ldrop)填充所獲得的 墨水，以電壓15V進行連續噴出穩定性評估。 該評估係從128喷嘴全部連續進行喷出，每5分鐘在普通 紙進行印字，觀察印字狀況。評估内容福I印字間隔出 現偏差時，判斷液滴有偏向飛行。又，有漏印字時，判 斷喷嘴堵塞。評佑持續進行達30分鐘。評估基準如下。 ◎ : 30分鐘都無偏向飛行、喷嘴堵塞 〇：於一部分喷嘴有偏向飛行 △:於一部分喷嘴有堵塞 X:偏向飛行及喷嘴堵塞都有 於表7、8表示以上的評估結果。 表單編號Α0101 第69頁/共76頁 201031713 表7: 共_ (A) 共微(投:棚銳結 _ (麵 mm m^· 請 穩 定 性 相 對 電 率 t 電 正 切 mm 戀 獲 M2 wm mz 挪2 麵 (A-1) 79:21 14,8% 5.4% △ Δ 0 0 0 0 0 〇 膽12 (A-3 79： 21 14.8% 5.2% 0 Δ 0 〇 0 〇 〇 0 鲫13 (A-3) · 79: 21 脳 5.4% 0 Δ 0 0 0 0 0 0 wm (A-® 79:21 133% 43% 〇 Δ 0 0 0 0 0 〇 義 (A-® 79： 21 133% 4.2% 0 0 0 0 0 〇 0 0 '獅)6 (A-3 79： 21 133% 3.2% 0 0 0 0 0 0 0 0 靡(7 (A-3) 79:21 133% 35% 0 0 0 0 0 0 0 0 讎 18 (A-® 59 ： 41 10.0% 2.8% 0 0 © @ © © 0 0 纖 (A-3) 59:41 臟 2.4% 0 0 @ @ © 0 0 讎0 (A-3) 59:41 10.2% 2A% % 0 @ @ @ @ 0 0 賺1 (A-3) 59:41 10.2% 2L·% © 0 @ @ © @ 0 0 讎2 (A-® 59:41 10.2% 2.7% © @ @ @ @ 0 0 誦3 (A-® 59 Ηί 10.2% 2.2% ® @ % © @ @ ® @j 腳H I 〇： m Ofl% 3.2% X X 0 0 0 0 @ © 臟 * 0： £30 〇J〇% 3B% X X 0 0 0 0 ® @ 纖4 (A-® 49:51 臟 25% @ @ # ® @ © @ Lmm 1 o： m m 3·6% X X 0 0 0 0 @ © 麵5 (A-® 45:55 11.1% 2i0% @ @ ® @ 酿6 (A-3) 45:55 11.1% 2.2% © % @ © @ @ mm I o： m 0« 3.4% X X 0 0 0 0 @ @ [0041] 纖 (A) 觸卿·孅 麵Idg} (_ *«A) I 穩 定 性 丨相 對 1 率 t 電 正 切 _ 齡ι TOH7 (A-1) 79 2t 14.8% 4Β% Δ Δ ® 酶ns (A-2) 79 21 14.8% 47% 0 Δ 辦H9 (A-3) 79 21 148% 48% 0 Δ © 議J20 (A-3) 79 21 13.3% 3.9% 0 Δ @ mem (A-3) 79 21 13.3% 3Β% 0 0 獅122 (A-3) 79： 21 13.34 4.5% 0 0 酬 123 <A-3) 79 :21 13,3% 43% 0 0 © 纖J24 (A-3) 79： 21 13.3% 3,7% 0 0 ® mrnss (A-3) 79 ; 21 13.3% 36% 0 0 0 諭 126 (A-3) 79 :21 13.3% 3.7% 0 0 @ 讎15 m 0 ： 100 0% 3.9% X X @ 腳J6 * 0 ： 100 0% 3Β% X X ® [0042] 實施例1〜26所獲得的彩色濾光片用著色組成物，係由於 併用順丁烯二酸酐與順丁烯二酸酐以外之1種以上的乙烯 性不飽和單體之共聚物（A)、顏料、樹脂黏結劑（B) ，因此與比較例1〜6所獲得之物相比，其相對介電率小 表單編號A0101 第70頁/共76頁 201031713 ，電特性良好。 其t尤其在併用具有羥基之鹼可溶性樹脂（B)作為樹脂 黏結劑（B)之實施例7〜16，顯示出彩色濾光片用著色 組成物之密接性更良好的效果。又，於使用相同共聚物 (A)時，在共聚物（A)與樹脂黏結劑（B)之含有量為 5 : 95〜70 : 30之範圍内之實施例8〜16，密接性良好， 可獲得完全未確認到顯影殘渣的著色層。 又，加入第3級膦化合物作為添加劑之實施例10〜16係相 對介電率更低，結果良好，進一步而言，於使用銃有機 硼錯合物作為活性能量線聚合性起始劑之實施例12〜16 ，就介電正切而言，其值亦小，顯示出電特性更良好的 特徵。 又，含有環己基乙酯作為溶劑之實施例13〜16係平坦性 良好，顯示出其特徵在於適合於使用本發明之彩色濾光 片用著色組成物，在薄膜電晶體（TFT)方式彩色液晶顯 示裝置之驅動用基板上形成著色層的情洗I* 又，作為分散劑，實施例5〜16、20〜26使用一種聚酯分 散劑，其係在分子内具有2個經基及1個硫醇基之化合物 的存在下，將乙烯性不飽和單體進行自由基聚合而生成 ，並令單一末端區域具有2個羥基之乙烯基共聚物中之羥 基與四羧酸二酐中之酸酐基反應而成；前述實施例5〜16 、20〜26係彩色濾光片用著色組成物之穩定性良好，同 時進一步顯示出介電正切亦小的特徵。 【圖式簡單說明】 【主要元件符號說明】 表單編號A0101 第71頁/共76頁[Evaluation of relative dielectric transmittance and dielectric tangent of coating film] On a glass substrate of l〇〇mmxlOOmm and thickness 〇.7mm which is steamed and forged for the electrode, the film thickness is formed by a spin coater after drying. The number of rotations of the thickness of 2. The coating composition was obtained by coating the coloring compositions for the development-type color filters obtained in the form Nos. A to 1 and 16 and Comparative Examples 1 to 4, Form No. A0101, page 66, and page 76. Then, after drying under reduced pressure, ultraviolet light exposure was carried out using an ultrahigh pressure mercury lamp at an integrated light amount of 300 mj and an illuminance of 30 mW. Thereafter, the substrate was heated and applied at 230 ° C for 1 hour, and then left to stand on the hardened coating film. The vapor deposition area was 3.464×l (the aluminum for the electrode of T4m2 was sampled by the aluminum electric connection hardening coating film. The inkjet inks of Examples 17 to 26 and Comparative Examples 5 and 6 were steamed for aluminum for the electrode. On a glass substrate of lOOmmx WOmm and thickness 〇7mm, using a spin coater, the thickness of the coating is 2% Oem, and the coated substrate is obtained by a spin coating. Then, after drying under reduced pressure, 23 (TC heated coated substrate for 30 minutes) was placed and cooled, and the obtained electrode was coated with aluminum. The electrode of the vapor deposition area was made of aluminum, and a sample of the aluminum electrode clip hardened coating film was prepared. "12..60 type" manufactured by Solartron Co., Ltd., the electrostatic capacitance obtained from the measurement of the applied voltage of 100 mV from 10 Hz to 1 MHz is calculated as the relative dielectric value at the time of 20 Hz, and the value of the surface L is changed by 5 minutes. Stage evaluation 〇f ropert至以上的小于小于为0. 0。 The relative dielectric ratio is more than 3. 0, less than 4. 0 △: relative dielectric ratio of 4. 0 or more, less than 5. 0. X: Relative dielectric constant of 5.0 or more (dielectric tangent) ◎: Dielectric tangent is less than 〇. 02 〇: Dielectric tangent 0. 02 or more, less than 0. 03 △. Dielectric tangent 0.03 or more, less than 0. 04 Form Compilation A0101 Page 67 / Total 76 Page 201031713 X : Dielectric Tangent 0·04 or more [Adhesiveness of coating film, evaluation of development residue] On glass substrate (substrate 1) of lOOmmxlOOmm, thickness 〇7 legs and TFT mode On the substrate (substrate 2) on which the tantalum nitride film was formed on the surface of the liquid crystal driving substrate, the film thickness after drying was 2. 0/zm, and the coating examples and comparative examples were obtained by a spin coater. The weight of the sodium sulphate is 0. 2% by weight of sodium carbonate, after the use of 0. 2% by weight of sodium carbonate, the amount of light is 3 〇〇mj. The aqueous solution is used as a developing solution to remove the unhardened portion of the coating film to form a pattern. The adhesion to the coating film is not In the development of the residue, the three-stage evaluation was carried out by the following criteria. (Closeness) ◎: The pattern peeling was not confirmed at all: The pattern peeling was slightly confirmed △: The pattern peeling mtesiedua was confirmed. Hcforiy ◎: development residual ridge without uncured portion 显影: development residue with uncured portion slightly △: confirmation of development residue of unhardened portion [flatness] glass substrate of 100 mm x 100 mm, thickness of 0.7 mm (substrate 1) On the substrate (the substrate 2) on which the tantalum nitride film is formed on the surface of the TFT liquid crystal driving substrate, a coating film having a film thickness of 2.00/zm after drying is formed on the glass substrate by a spin coater. A film of a tantalum nitride film is formed on the surface of the liquid crystal driving substrate to form a coating film having a film thickness of 3. 0/zm after drying. Form No. A0101, page 68, page 76, respectively, the coated substrate was dried under reduced pressure, and then an ultrahigh pressure mercury lamp was used to perform ultraviolet exposure with a total amount of light of 150 mJ, and heated at 230 ° C for 1 hour, and then left to cool from the substrate of the coated substrate. The thickness of the film was measured every 2 cm in the diagonal direction, and the film thickness uniformity was calculated according to the following formula to evaluate the flatness. Film thickness uniformity [%] = (ΤΙ - T2) / T) xlOO Film thickness uniformity [%] is preferably small, and a three-stage evaluation is performed on the basis of the following criteria. ◎: film thickness uniformity [%] is less than 4. 0% 〇: film thickness uniformity [%] 4. 0% or more, less than 8. 0% △: film thickness uniformity [%] 8 · 0% or more, less than 12. 0% [Discharge Stability] When using the inkjet method, it is important to be able to stably eject ink. The ink obtained by filling the SII 512 nozzle (known as 12 pl/ldrop) was evaluated for continuous discharge stability at a voltage of 15V. The evaluation was carried out continuously from all 128 nozzles, and printing was performed on plain paper every 5 minutes to observe the printing condition. When the evaluation content shows a deviation, the droplet is judged to have a biased flight. Also, when there is a missing print, the nozzle is judged to be clogged. The evaluation lasts for 30 minutes. The evaluation criteria are as follows. ◎ : No deviation flight for 30 minutes, nozzle clogging 〇: Partial nozzles are deflected to fly △: Some nozzles are blocked X: Both deflected flight and nozzle clogging are shown in Tables 7 and 8. Form No. Α0101 Page 69/Total 76 Page 201031713 Table 7: Total _ (A) Common micro (pen: shed sharp knot _ (face mm m^· Please stability relative electric rate t electric tangent mm love M2 wm mz 2 face (A-1) 79:21 14,8% 5.4% △ Δ 0 0 0 0 0 〇 12 12 (A-3 79: 21 14.8% 5.2% 0 Δ 0 〇0 〇〇0 鲫13 (A- 3) · 79: 21 脳 5.4% 0 Δ 0 0 0 0 0 0 wm (A-® 79:21 133% 43% 〇Δ 0 0 0 0 0 〇 (A-® 79: 21 133% 4.2% 0 0 0 0 0 〇0 0 'Lion) 6 (A-3 79: 21 133% 3.2% 0 0 0 0 0 0 0 0 靡(7 (A-3) 79:21 133% 35% 0 0 0 0 0 0 0 0 雠18 (A-® 59 : 41 10.0% 2.8% 0 0 © @ © © 0 0 Fiber (A-3) 59:41 Dirty 2.4% 0 0 @ @ © 0 0 雠0 (A-3) 59:41 10.2% 2A% % 0 @ @ @ @ 0 0 Earn 1 (A-3) 59:41 10.2% 2L·% © 0 @ @ © @ 0 0 雠2 (A-® 59:41 10.2% 2.7 % © @ @ @ @ 0 0 诵3 (A-® 59 Ηί 10.2% 2.2% ® @ % © @ @ ® @j HI 〇: m Ofl% 3.2% XX 0 0 0 0 @ © Dirty* 0: £ 30 〇J〇% 3B% XX 0 0 0 0 ® @ 纤 4 (A-® 49:51 dirty 25% @ @ # ® @ © @ Lmm 1 o: mm 3·6% XX 0 0 0 0 @ © 5 (A-® 45:55 11.1% 2i0% @ @ ® @ 酿6 (A-3) 45:55 11.1% 2.2% © % @ © @ @ mm I o: m 0« 3.4% XX 0 0 0 0 @ @ [0041] Fiber (A) Touching 孅Idg} (_ *«A) I Stability 丨 Relative 1 rate t Electric tangent _ Age ι TOH7 (A-1) 79 2t 14.8% 4Β% Δ Δ ® Enzyme ns (A-2) 79 21 14.8% 47% 0 Δ H9 (A-3) 79 21 148% 48% 0 Δ © J20 (A-3) 79 21 13.3% 3.9% 0 Δ @ mem (A-3) 79 21 13.3% 3Β% 0 0 Lion 122 (A-3) 79: 21 13.34 4.5% 0 0 Reward 123 <A-3) 79 : 21 13,3% 43% 0 0 © Fiber J24 (A-3) 79: 21 13.3% 3,7% 0 0 ® mrnss (A-3) 79 ; 21 13.3% 36% 0 0 0 谕 126 (A-3) 79 : 21 13.3% 3.7% 0 0 @ 雠 15 m 0 : 100 0% 3.9% XX @ Foot J6 * 0: 100 0% 3Β% XX ® [0042] The coloring composition for color filters obtained in Examples 1 to 26 is a combination of one or more kinds of ethylene other than maleic anhydride and maleic anhydride. The copolymer (A) of the unsaturated monomer, the pigment, and the resin binder (B) are therefore relatively low in relative dielectric ratio compared with the materials obtained in Comparative Examples 1 to 6. Form No. A0101 Page 70 of 76 Page 201031713, good electrical characteristics. In particular, in Examples 7 to 16 in which the alkali-soluble resin (B) having a hydroxyl group was used in combination as the resin binder (B), the effect of further improving the adhesion of the coloring composition for a color filter was exhibited. Further, in the case of using the same copolymer (A), in Examples 8 to 16 in which the content of the copolymer (A) and the resin binder (B) was in the range of 5:95 to 70:30, the adhesion was good. A coloring layer in which development residue was not confirmed at all was obtained. Further, Examples 10 to 16 in which the third-stage phosphine compound was added as an additive were lower in relative dielectric ratio, and the results were good, and further, the use of cerium organoboron complex as an active energy ray polymerization initiator was carried out. In Examples 12 to 16, in terms of dielectric tangent, the value was also small, indicating that the electrical characteristics were better. Further, Examples 13 to 16 containing cyclohexylethyl ester as a solvent are excellent in flatness, and are characterized by being suitable for use in the coloring composition for a color filter of the present invention, and in a thin film transistor (TFT) type color liquid crystal. In the driving substrate of the display device, a coloring layer is formed on the substrate, and as a dispersing agent, in Examples 5 to 16, 20 to 26, a polyester dispersing agent having two meridians and one in the molecule is used. In the presence of a thiol group-containing compound, an ethylenically unsaturated monomer is subjected to radical polymerization to form a hydroxyl group in a vinyl copolymer having two hydroxyl groups in a single terminal region and an acid anhydride group in a tetracarboxylic dianhydride. The reaction was carried out; the coloring compositions for the color filters of the above Examples 5 to 16 and 20 to 26 were excellent in stability, and further exhibited a feature that the dielectric tangent was also small. [Simple diagram description] [Main component symbol description] Form No. A0101 Page 71 of 76

Claims (1)

201031713 七、申請專利範圍： 1 . 一種彩色濾光片用著色組成物，其特徵在於含有：順丁烯 二酸酐與順丁烯二酸酐以外之1種以上的乙烯性不飽和單 體之共聚物（A);顏料；樹脂黏結劑（B);及聚合性單 體，其係選自由活性能量線聚合性單體或熱聚合性單體所 組成的群組。 2 .如申請專利範圍第1項所述之彩色濾光片用著色組成物， 其中前述聚合性單體為活性能量線聚合性單體；前述著色 組成物進一步含有活性能量線聚合起始劑。 3.如申請專利範圍第1項所述之彩色濾光片用著色組成物， 其中順丁烯二酸酐以外之1種以上的乙烯性不飽和單體係 選自由苯乙烯、甲基苯乙烯及茚所組成的群組中之單 體。 4 .如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 ，其中樹脂黏結劑（Β)含有鹼可溶性樹脂。 5.如申請專利範圍第4項所述之彩色濾光片用著色組成物， 其中鹼可溶性樹脂具有羥基。 6 .如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 ，其中共聚物（Α)與樹脂黏結劑（Β)之重量比（Α): (Β)在5 : 95〜70 : 30之範圍内。 7 .如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 ，其中共聚物（Α)之含有量係以彩色濾光片用著色組成 物中之固體部分重量作基準而為10〜20重量％。 8 .如申請專利範圍第2項所述之彩色濾光片用著色組成物， 其中活性能量線聚合起始劑係以一般式（1)所示之銃 表單編號Α0101 第72頁/共76頁 201031713 (3111{〇11丨11111)有機棚錯合物或氧疏（€^081111：011111111)有機 硼錯合物； 一般式（1 ):201031713 VII. Patent application scope: 1. A coloring composition for a color filter, characterized by comprising a copolymer of maleic anhydride and one or more ethylenically unsaturated monomers other than maleic anhydride (A); a pigment; a resin binder (B); and a polymerizable monomer selected from the group consisting of active energy ray-polymerizable monomers or thermally polymerizable monomers. The colored composition for a color filter according to claim 1, wherein the polymerizable monomer is an active energy ray-polymerizable monomer; and the coloring composition further contains an active energy ray polymerization initiator. 3. The colored composition for a color filter according to claim 1, wherein one or more ethylenically unsaturated single systems other than maleic anhydride are selected from the group consisting of styrene and methyl styrene. The monomer in the group consisting of 茚. 4. The coloring composition for a color filter according to claim 1 or 2, wherein the resin binder (Β) contains an alkali-soluble resin. 5. The coloring composition for a color filter according to Item 4, wherein the alkali-soluble resin has a hydroxyl group. 6. The coloring composition for a color filter according to claim 1 or 2, wherein the weight ratio of the copolymer (Α) to the resin binder (Β): (Β) at 5: 95 ~70: 30 within range. 7. The coloring composition for a color filter according to claim 1 or 2, wherein the content of the copolymer is based on the weight of the solid portion in the coloring composition for the color filter. It is 10 to 20% by weight. 8. The coloring composition for a color filter according to claim 2, wherein the active energy ray polymerization initiator is represented by the general formula (1) 铳 form number 101 0101, page 72 / total 76 pages 201031713 (3111{〇11丨11111) organic shed complex or oxygen spar (€^081111:011111111) organoboron complex; general formula (1): d14 οί_d12 If 一 Im : Ο. n mmD14 οί_d12 If one Im : Ο. n mm (於一般式（1)中，R11、R12及R13係分別獨立地表示選 自由亦可具有置換基之烷基、亦可具有置換基之芳香基、 亦可具有置換基之芳烷基、亦可具有置換基之烯基、亦可 具有置換基之炔基、亦可具有置換基之脂環基、亦可具有 〇 置換基之烷氧基、亦可具有置換基之烯丙氧基、亦可具有 置換基之烷基硫代基及亦可具有置換基之胺基所組成的群 組中之基，R14係表示氧原子或孤立電子對，其中亦可具 有置換基之芳香基係僅止於R11、R12及R13中的1個，X — 為陰離子）。 9 .如申請專利範圍第8項所述之彩色濾光片用著色組成物， 其中一般式（1)中之X_係以一般式（2)所示之硼酸鹽 9 一般式（2): 表單編號A0101 第73頁/共76頁 22201031713 i〇 . π · 12 . 13 . 表單編號Α0101 麵21 η一 鑛 〇 1m (於一般式（2)中，R21 、分 別獨立地表 示選自由亦可具有置換基之垸基、亦可具有置換基之芳香 基、亦可具有置換基之芳g基、赤可具有置換基之烯基、 亦可具有置換基之块基所組成的群組中之基，R21、R22、 R23及R24並非全部具有置換基亦可，而不同時為芳香基） 。 （ '-府… 如申請專利範圍第1或2項所述c彩色i光片用著色組成物 ’其中溶劑係含有環己基乙醋（CyCl〇heXyiethyi acetate)而成。 如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 其中進一步含有第3級膦化合物而成。 如申請專利範圍第11項所述之彩色濾光片用著色組成物， 其中第3級膦化合物為三苯膦。 如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 ’其中進一步作為分散劑而含有聚酯分散劑，其係在分子 第74頁/共76頁 201031713 内具有2個羥基及1個硫醇基之化合物的存在下，將乙烯性 不飽和單體進行自由基聚合而生成，並令單一末端區域具 有2個羥基之乙烯基共聚物中之羥基與四羧酸二酐中之酸 酐基反應而獲得。 14 .如申請專利範圍第13項所述之彩色濾光片用著色組成物， 其中四羧酸二酐含有芳香族四羧酸二酐。 15 .如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 ，其中作為上述活性能量線聚合性單體或熱聚合性單體而 含有1種或2種以上選自由三聚氰胺化合物、苯并胍胺（ benzoguanamine)、環氧化合物、氧雜環丁燒化合物、 苯酚化合物、苯并噁嗪化合物、嵌段化羧酸化合物、嵌段 化異氰酸酯化合物、丙烯酸酯系單體及矽烷耦合劑所組成 的群組中之化合物，並採喷墨方式而使用。 16 . —種彩色濾光片，其特徵在於具備濾光片區段，其係利用 如申請專利範圍第1或2項所述之彩色濾光片用著色組成物 而形成。 ^ 17 . —種彩色濾光片，其特徵在於具構金光片區段，其係利用 如申請專利範圍第1或2項所述之ϋ濾光片用著色組成物 而形成於薄膜電晶體（TFT)方式之彩色液晶顯示裝置之 驅動用基板上。 表單編號A0101 第75頁/共76頁(In the general formula (1), R11, R12 and R13 each independently represent an arylalkyl group which may be an alkyl group which may have a substituent group, may have a substituent group, or may have a substituent group, An alkenyl group which may have a substituent group, an alkynyl group which may have a substituent group, an alicyclic group which may have a substituent group, an alkoxy group which may have a hydrazine substituent group, an allyloxy group which may have a substituent group, An alkyl group having a substituent group and a group of an amine group which may also have a substituent group, and R 14 represents an oxygen atom or an isolated electron pair, wherein the aromatic group which may have a substituent group is only In one of R11, R12 and R13, X - is an anion). 9. The coloring composition for a color filter according to claim 8, wherein X_ in the general formula (1) is a borate represented by the general formula (2), and the general formula (2): Form No. A0101 Page 73 / Total 76 Page 22201031713 i〇. π · 12 . 13 . Form No. Α0101 Face 21 η 一矿〇1m (In the general formula (2), R21, respectively, independently selected from a thiol group of a substituent group, an aryl group having a substituent group, an aryl group having a substituent group, an alkenyl group having a substituent group, or a group of a group having a substituent group R21, R22, R23 and R24 may not all have a substituent group, and may not be an aromatic group at the same time. ( '--... The coloring composition for c-color i-ray sheets described in the first or second aspect of the patent application' wherein the solvent contains CyCl〇heXyiethyi acetate. The coloring composition for a color filter according to any one of the preceding claims, wherein the coloring composition for a color filter according to claim 11, wherein the third-stage phosphine compound is Triphenylphosphine. The coloring composition for a color filter as described in claim 1 or 2, further comprising a polyester dispersant as a dispersing agent, which is contained in the molecular page 74/76, 201031713 In the presence of a compound having two hydroxyl groups and one thiol group, an ethylenically unsaturated monomer is subjected to radical polymerization to form a hydroxyl group and a tetracarboxylic acid in a vinyl copolymer having two hydroxyl groups in a single terminal region. The coloring composition for a color filter according to Item 13, wherein the tetracarboxylic dianhydride contains an aromatic tetracarboxylic dianhydride. Patent application The coloring composition for a color filter according to the above aspect, wherein the active energy ray-polymerizable monomer or the thermally polymerizable monomer is one or more selected from the group consisting of a melamine compound and a benzoguanamine. a group consisting of a benzoguanamine, an epoxy compound, an oxetane compound, a phenol compound, a benzoxazine compound, a blocked carboxylic acid compound, a blocked isocyanate compound, an acrylate monomer, and a decane coupling agent a compound in the group, which is used by an ink jet method. A color filter comprising a filter segment using color filter as described in claim 1 or 2. The sheet is formed by using a coloring composition. ^ 17 . A color filter comprising a gold-light sheet segment using the coloring composition for a ruthenium filter according to claim 1 or 2. The film is formed on a driving substrate of a thin film transistor (TFT) type color liquid crystal display device. Form No. A0101 Page 75 of 76
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