TW201232170A - Coloring composition, color filter, and display component - Google Patents

Abstract

The present invention provides a coloring composition that can inhibit from generating aggregate contaminants over time and decreasing contrast ratio. The coloring composition is characterized by comprising (A) a coloring agent, (B) a binder resin, (C) a crosslinking agent, and (D) at least one compound selected from the group consisting of the following (d-1) to (d-8): (d-1) an aliphatic carboxylic acid having a specific substituent group, or a salt thereof; (d-2) an aliphatic sulfonic acid having a specific substituent group, or a salt thereof; (d-3) an alicyclic carboxylic acid having a specific substituent group, or a salt thereof; (d-4) an alicyclic sulfonic acid having a specific substituent group, or a salt thereof; (d-5) an aromatic hydrocarbon having a specific substituent group, or a salt thereof; (d-6) an aromatic hydrocarbon having a specific substituent group and a sulfo group, or a salt thereof; (d-7) a compound having a carboxyl group and a heterocyclic group and consisting of a specific atomic number, or a salt thereof; and (d-8) a compound having a sulfo group and a heterocyclic group and consisting of a specific atomic number, or a salt thereof.

Description

201232170 六、發明說明： 【發明所屬之技術領域】 本發明係有關著色組成物、彩色濾光片及顯 ’詳言之，係有關形成有用於透過型或反射型之 晶顯示元件、固態影像元件、有機EL顯示元件、 等所使用之彩色濾光片的著色層時所使用的著色 、具備使用該著色性組成物所形成之著色層的彩 片、以及具備該彩色濾光片的顯示元件。 【先前技術】 當使用著色感放射線性組成物製造彩色濾光 ’已知有於基板上塗布著色感放射線性組成物並 燥後’對乾燥塗膜照射放射線（以下稱為「曝光 所要的圖案形狀並進行顯影，而製得各色畫素έ 專利文獻1〜2) °又已知有利用分散有碳黑的光聚 成物來形成黑色矩陣的方法（專利文獻3)。更已知 著色熱硬化性樹脂組成物並以噴墨方式來製得各 的方法（專利文獻4)。 此外’顏料分散型或溶有染料之彩色濾光片 、、且成物中，其保存穩定性常發生問題。對此，例 文獻5中提出使用芳香族羧酸系化合物。 [先前技術文獻] [專利文獻] [專利文獻1]曰本特開平2_144502號公報 [專利文獻2]曰本特開平3_532〇1號公報 [專利文獻3 ]日本特開平6 3 5丨8 8號公報 示元件 彩色液 電子紙 組成物 色濾光 片之際 將其乾 )形成 )方法（ 合性組 有使用 色晝素 用著色 如專利 201232170 [專利文獻4]日本特開2000-3 10706號公報 [專利文獻5]曰本特開201 0- 1 4961號公報 【發明内容】 [發明所欲解決之課題] 然而’已知含有專利文獻5中所提出之芳香族缓酸系 化合物的著色組成物在使用以金屬酞菁素為代表的金屬 •曰s物作為著色劑時’隨著時間經過會容易發生凝集雜 質的產生、對比比率的降低。 因此，本發明之課題在於提供一種可抑制經時性之凝 集雜質的產生及對比比率的降低之著色組成物。本發明之 課題在於進一步提供具備含有該著色組成物之著色層而 成之彩色濾光片、及具備該彩色濾光片之顯示元件。 [解決課題之手段] 本發明人等戮力進行研究的結果發現，使其含有具 備對金屬具有配位能力之官能基與特定酸性官能基之化 合物’便可解決上述課題。 即，本發明係提供一種著色組成物，其特徵為含有 (A)著色劑、（B)黏著劑樹脂、（〇交聯劑、及（D)選自包含 下述（d-Ι)〜（d-8)之群組的至少丨種化合物（以下亦稱為「 (D)特定化合物」）， di)具有選自包含〇Rl基及_SR2基之群組的至少1種之 脂肪族羧酸或其鹽（以下亦稱為「化合物（dd)」） (d~2)具有選自包含-OR1基、-SR2基及_q_nR3H4^ $ AA E , 丞艾群組 V 1種之脂肪族磺酸或其鹽（以下亦稱為「化人物 (d'2)」） ° 201232170 (d-3)具有選自包含_〇Ri基及_SR2基之群組的至少1種 脂環式羧酸或其鹽（以下亦稱為「化合物（d_3)」） 之 (d-4)具有選自包含_〇Ri基、_SR2基及_q_nr3r4基之 的至少1種之脂環式磺酸或其鹽（以下亦稱為「化合 (“)」） 勿 (d-5)由具有-SR2基之基團與具有羧基之基團取代之芳 族烴或其鹽（以下亦稱為「化合物（d_5)j ) (d-6)由選自包含具有_〇Ri基之基團、具有_SR2基之基 及具有-Q-NR3R4基之基團之群組的至少1種、與具有碲醆 基之基團取代之芳香族烴或其鹽（以下亦稱為「化 (“)」） 。物 (d 7)具有羧基及雜環基，且氫原子與羧基除外之總原子 數為3〜20之化合物或其鹽（以下亦稱為「化合物（d7)j ) (d 8)具有嶒酸基及雜環基，且氫原子與磺酸基除外史绅 原子數為3〜20之化合物或其鹽（以下亦稱為「化合物（d J ) ) [准R〜R彼此獨立表示氫原子或取代或未取代之1價垵 基’ Q表示單鍵或羰基]。 b外本‘明係提供具備使用上述著色組成物所形 成之著色層而成之彩色濾光片、及具備該彩色濾光片之 貝不元件。此處「著色層」係指彩色濾光片所使用之各 色晝素、黑色矩陣、黑色間隔件等。 [發明之效果] 本發明著色組成物其保存穩定性優良，可抑制經時 之凝集雜質的產生 '對比比率的降低。 201232170 因此’本發明著色組成物可極佳地使用於以彩色液 晶顯示元件用彩色濾光片、固態影像元件之色分解用彩 色濾光片、有機EL顯示元件用彩色濾光片、電子紙用彩 色慮光片為首的各種彩色渡光片的製作β 【實施方式】 [實施發明之形態] 以下，對本發明詳細進行說明。 [著色組成物] 以下，對本發明著色組成物的構成成分進行說明。 -(A)著色劑- 构不赞明宁的（Α)著 別限定 質。具 色素的 度、高 成物特 凝集雜 錯合物 作 屬酞菁 作 顏料之 铜酞菁 素、鹵 化銘醜 ......-|工只不付 ，可依據彩色濾光片的用途來適當選擇色彩戋材 體而言，作為著色劑均可使用顏料、染枓及天然 任一種，惟因彩色濾光片係要求高色純度、高= 對比等’故較佳為顏料及/或染料。本發日月著色組 別在使用錯合物作為著色劑日夺，可抑制經時性之 質的產生、董t比比率的降低而屬有用。作為上述 ，可例舉如錯合物顏料、錯合物染料等。 ^ 為上述錯合物顏料並未特別限定，惟 素顏料、金屬偶氮顏料等。 土 為金屬酞菁素顏料之具_列，可例舉 銅酞菁素、充㈣色顏料之_化鋅 ： 素、.化鎮酞菁素、•一菁*、_二= 化飢酞菁素、_化猛酞菩I ^ 莕去函化鐵駄菁素、齒 菁素鹵化鎳酞菁素、齒化 育i 幽化鍺酞 201232170 菁素、_化銦酞菁素等。 此外’作為金屬偶氮顏料之具體實例，可例舉充作 黃色顏料之偶氮巴比妥酸之錦錯合物、日本特開2〇〇ι· 3 54869號公報所揭示之偶氮巴比妥酸之金屬錯合物、日 本特開2006U6506號公報所揭示之偶氮巴比妥酸之 錯合物等。 i嗓 作為上述錯合物染料並未特別限定，惟可 際公開第關43442號小冊所揭示之姑染料、 = 公報、日本特開__29㈣號公報所= 之亞甲基二吡咯(dipyrr〇methene)系錯合物染料 開2〇09-5 1896號公報所揭示之金屬醜菁素染料、曰二 開2〇09·163226號公報所揭示之偶氮金屬染料，此外還^ :舉C丄溶劑橙56、c丄溶劑黃82(皆為色指數⑺I )名) 此等著色劑當中，構成錯合物之中心原子為Cu、zn ，〇、Al、C〇、Mg、In、Fe^ 疋化合物良好地搭配而較佳。又金屬酖菁素可與 =物i好地搭配而較佳。金屬駄菁素當中，_化鋅敌 普素’特別是含有溴化辞酞菁素、溴化 著色組成物會有較高之隨時間經過凝集雜質=普2 比率降低的趨勢’而藉由使 、對比 決所述問題。演化氯化辨…係分類為= 即可解 名⑴摘㈣之_，較川 201232170201232170 VI. Description of the Invention: [Technical Field] The present invention relates to a coloring composition, a color filter, and a display, in particular, a crystal display element for forming a transmissive or reflective type, and a solid-state image element. A coloring used for a coloring layer of a color filter to be used, an organic EL display element, a coloring layer having a coloring layer formed using the coloring composition, and a display element including the color filter. [Prior Art] When a color filter is produced using a coloring sensitizing radiation composition, it is known to apply a radiation-sensitive radiation composition on a substrate and dry it, and then irradiate the dried coating film with radiation (hereinafter referred to as "the desired pattern shape of the exposure". Further, it is known that a method of forming a black matrix by using a light-polymerized product in which carbon black is dispersed is known (Patent Document 3). Each of the resins is prepared by an inkjet method (Patent Document 4). Further, in the case of a pigment dispersion type or a dye-containing color filter, the storage stability often causes problems. In this regard, the use of an aromatic carboxylic acid-based compound is proposed in the example of the invention. [PRIOR ART DOCUMENT] [Patent Document 1] [Patent Document 1] JP-A-KOKAI Publication No. 2-144502 (Patent Document 2) 曰本特开平3_532〇1 [Patent Document 3] Japanese Patent Laid-Open No. Hei 6 3 5 丨 8 8 discloses a method in which a color liquid electronic paper is formed by a color filter (formed as a dry filter) method (a combination of a coloring group using a coloring patent) 201 [Patent Document 4] Japanese Laid-Open Patent Publication No. 2000-3 10706 [Patent Document 5] Japanese Patent Application Laid-Open No. Hei. No. Hei. In the coloring composition of the aromatic acid-lowering compound proposed in the above-mentioned article, when a metal ruthenium compound represented by a metal phthalocyanine is used as a coloring agent, the generation of agglomerated impurities and the contrast ratio are likely to occur over time. In view of the above, it is an object of the present invention to provide a colored composition which can suppress the generation of agglomerated impurities and the reduction of a contrast ratio with time. The object of the present invention is to provide a colored layer containing the colored composition. A color filter and a display element including the color filter. [Means for Solving the Problem] As a result of intensive studies by the present inventors, it has been found that it contains a functional group having a coordinating ability to a metal and a specific acidity. The compound of the functional group can solve the above problems. That is, the present invention provides a coloring composition characterized by containing (A) a coloring agent, and (B) an adhesive tree. (〇) a crosslinking agent, and (D) is selected from at least a compound of the following group (d-Ι) to (d-8) (hereinafter also referred to as "(D) specific compound"), di An aliphatic carboxylic acid having at least one selected from the group consisting of ruthenium R1 groups and _SR2 groups or a salt thereof (hereinafter also referred to as "compound (dd)") (d~2) having a selected from -OR1 Base, -SR2 group and _q_nR3H4^ $ AA E , aliphatic sulfonic acid or its salt of V group 1 (hereinafter also referred to as "character (d'2)") ° 201232170 (d-3) (d-4) having at least one alicyclic carboxylic acid or a salt thereof (hereinafter also referred to as "compound (d_3)") selected from the group consisting of a 〇Ri group and a _SR2 group, has a selected from the group consisting of _ At least one alicyclic sulfonic acid or a salt thereof (hereinafter also referred to as "combination (")") of the 〇Ri group, the _SR2 group and the _q_nr3r4 group, (d-5) is a group having a -SR2 group An aromatic hydrocarbon substituted with a group having a carboxyl group or a salt thereof (hereinafter also referred to as "compound (d_5)j) (d-6) is selected from a group having a group having a group having a _〇Ri group and having a group of _SR2 groups And at least one group of groups having a -Q-NR3R4 group, and a group having a mercapto group A substituted aromatic hydrocarbon or a salt thereof (hereinafter also referred to as "chemical (")"). The compound (d 7) having a carboxyl group and a heterocyclic group, and having a total atomic number of 3 to 20 excluding a hydrogen atom and a carboxyl group, or a salt thereof (hereinafter also referred to as "compound (d7)j) (d 8) has a citric acid a compound having a hydrogen atom and a sulfonic acid group and having a hydrogen atom and a sulfonic acid group other than 3 to 20 or a salt thereof (hereinafter also referred to as "compound (d J )). [Quasi R R R independently of each other represents a hydrogen atom or The substituted or unsubstituted monovalent fluorenyl group 'Q represents a single bond or a carbonyl group.] b. The present invention provides a color filter having a colored layer formed using the above colored composition, and has the color filter. The film is not a component. Here, the "colored layer" refers to each color element, black matrix, black spacer, and the like used in the color filter. [Effects of the Invention] The colored composition of the present invention is excellent in storage stability, and can suppress the decrease in the generation ratio of the aggregated impurities over time. 201232170 Therefore, the coloring composition of the present invention can be excellently used for color filters for color liquid crystal display elements, color filters for color decomposition of solid-state image elements, color filters for organic EL display elements, and electronic paper. [Production of Various Color Light-Emitting Sheets] Illustrated by a Color Light-Emitting Sheet [Embodiment] [Embodiment of the Invention] Hereinafter, the present invention will be described in detail. [Coloring Composition] Hereinafter, the constituent components of the colored composition of the present invention will be described. - (A) Coloring Agent - The structure is not praised by Α (Α). The degree of pigmentation, the high-density special agglomerate complex is a copper phthalocyanine which is a phthalocyanine as a pigment, and the halogenated ugly ugly...-|Work only does not pay, can be used according to the use of color filters In order to properly select the color casket body, pigments, dyes, and natural ones can be used as the coloring agent, but the color filter is required to have high color purity, high=contrast, etc., so it is preferably a pigment and/or dye. In the present day and the month, the coloring group is used as a coloring agent, and it is useful to suppress the occurrence of the quality of the time and the decrease in the ratio of the ratio of the torsion. As the above, a complex pigment, a complex dye, or the like can be exemplified. ^ The above-mentioned complex pigment is not particularly limited, and is a pigment, a metal azo pigment, or the like. The soil is a metal phthalocyanine pigment, which may be exemplified by copper phthalocyanine, Zn-rich Zn, phthalocyanine, phthalocyanine, phthalocyanine, phthalocyanine素, _ 酞 酞 I I ^ 荇 函 函 駄 駄 駄 、 、 、 、 、 、 、 、 、 、 、 、 、 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞 锗酞Further, as a specific example of the metal azo pigment, a azo barbituric acid yam complex which is used as a yellow pigment, and an azo barbit disclosed in Japanese Laid-Open Patent Publication No. Hei 2 No. 3 54869 can be exemplified. A metal complex of a toluic acid, a complex of azo barbituric acid disclosed in Japanese Laid-Open Patent Publication No. 2006-6506, and the like. i 嗓 嗓 嗓 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 434 The methene dye is a metal ugly dye disclosed in the publication of Japanese Patent Publication No. Hei 09-5 1896, and the azo metal dye disclosed in the Japanese Patent Publication No. Hei. No. 09-163226. Solvent Orange 56, c 丄 Solvent Yellow 82 (all color index (7) I) name) Among these colorants, the central atom constituting the complex is Cu, zn, 〇, Al, C〇, Mg, In, Fe^ 疋The compounds are well matched and preferred. Further, the metal phthalocyanine can be preferably combined with the substance i. Among the metal phthalocyanins, _zinc-zepopin', especially containing brominated phthalocyanine, brominated coloring composition, has a higher tendency to decrease in the ratio of agglomerated impurities = normal ratio over time' Compare the problems mentioned. Evolutionary chlorination is classified as = can be solved (1) extract (four) _, chuanchuan 201232170

X XX X

[式⑴中’X彼此獨立表示氫原子 部x中的10〜15個為溴原子 、“子或溴 、i~6個為氯原七ί 本發明中可與上述錯合 ’、子]。 、無機顏料、油溶性染料Q '、s彳用週知之 染料等。 料、直接染料、酸性染 =發明中，者色劑可單獨或2種 本發明中，當使用 工此合使 對顏料以再結晶法、：：：：為：色劑時，亦 i ^L焱法、洛劑清洗法、 :加熱法或此等之組合進行精製後使用。又 可視需求以樹脂將其粒子表面改質後使 的粒子表面改質的樹脂可例舉如日本特開200 號A報所述之載色基樹脂Oehicle resins}、或市 顏料分散用樹脂。又，顏料係較佳以所謂的丨 nulling)將一次粒子微小化後使用。鹽磨方法可： 曰本特開平08-1791 1 1號公報所揭示之方法。 (A)著色劑的含有比例’由形成輝度高、色差 子，全 機顏料 、驗性 3 ° 視需求 華法、 顏料亦 將顏料 108817 的各種 磨（salt 用例如 度優良 201232170 ^ '或形成遮光性優良的黑色矩陣的觀點而言，通 吊在著色性組成物的固體含量中為5〜7〇質量％，較佳為 質4 /〇此處所謂「固體含量」係指後述之溶劑以 外的成分。 -(B)黏著劑樹脂_ $為本發明著色組成物中的（B)黏著劑樹脂並未特 別限足准較佳為具有羧基、酚性羥基等酸性官能基的 樹知其中較佳為具有羧基之聚合物（以下稱為「含有羧 基之二合物」），刊舉如具有HgJ以上羧基$乙烯性不 飽和單體（以下稱為「不飽和單體（bl)」）與其他可共聚合 的乙烯丨生不飽和單體（以下稱為「不飽和單體（b2)」）的共 聚物。 作為上述不飽和單體（bl)可例舉如（甲基）丙烯酸、馬 來酸、馬來酸肝、單[2·(曱基）丙烯酸乙基]琥錢醋、‘ 羧基聚己内酯單（甲基）丙烯酸酯、對乙烯基苯曱酸等。 此等不飽和單體（bl)可單獨或混合兩種以上使用。 又作為上述不飽和單體（b2)可例舉如…苯基馬來 亞酿胺N_環己基馬來亞醯胺之N-位取代馬來亞醯胺； 如苯乙烯、α~甲基笨乙烯、對-經基苯乙烯、對-羥基-α_ 甲基苯乙烯、對_乙烯苄基縮水甘油酯、苊烯 (acenaphthylene)之芳香族乙烯基化合物·， 如（甲基）丙烯酸甲醋、（甲基）丙烯酸正丁醋、（曱基） 丙烯齪2乙基己酯、（甲基）丙烯酸2·羥乙酯、（曱基）丙烯 酉义烯丙S曰（曱基）丙烯酸苄酯、聚乙二醇（聚合度2〜1〇) 甲醚（甲基）丙烯酸_、聚丙二醇（聚合度2~1〇)甲醚（曱基） -10- 201232170 丙烯酸酯、聚乙二醇（聚合度2〜10)單（甲基）丙烯酸酯、嗲 丙二醇（聚合度2〜10)單（甲基）丙烯酸酯、（甲基）丙烯醆環 己酯、（甲基）丙烯酸異莰酯、三環[5 2丨〇2,6]癸烷^基^ 甲基）丙烯酸酯、二環戊烯基（曱基）丙烯酸酯、甘油=( 甲基）丙烯酸酯、（甲基）丙烯酸4_羥苯酯、對芡酚之環氧 乙烷改性（甲基）丙烯酸酯、（甲基）丙烯酸縮水甘油酯、 3，4-環氧環己基甲基（曱基）丙烯酸酯、3_[(曱基）丙烯醯氧 基曱基]環氧丙院、3-[(甲基）丙烯醯氧基甲基]_3_乙基環 氧丙烷之（甲基）丙烯酸酯； %•己基乙稀喊、異获基乙稀喊、三環[5.2.1.〇2,6]癸 烷-8-基乙烯醚、五環十五基乙烯醚、3_(乙烯基環氧曱基 )-3 -乙基環氧丙烷之乙烯醚；如聚苯乙烯、聚（甲基）丙烯 酸曱酯、聚（曱基）丙烯酸正丁酯、聚矽氧烷之聚合物分 子鏈末端具有單（甲基）丙烯醯基之巨單體等。 此等不飽和單體（b2)可單獨或混合兩種以上使用。 不飽和單體（bl)與不飽和單體（b2)的共聚物中，該共 聚物中的不飽和單體（bl)的共聚合比例較佳為5〜7〇質量 %，更佳為1 0〜60質量％。於此範圍使不飽和單體（b 1)共 聚合便可製得鹼性顯影性及保存穩定性優良的著色性組 成物。 不飽和單體（bl)與不飽和單體（b2)的共聚物的具體 實例可例舉如日本特開平7-140654號公報、曰本特開平 8-259876號公報、日本特開平1〇_313〇8號公報、日本特 開平10-300922號公報、日本特開平1 1_174224號公報、 曰本特開平1 1-2584 15號公報、日本特開2000-561 18號公 201232170 報、日本特開2002-296778號公報、日本特開2〇〇4_i〇i728 號公報等所揭示的共聚物。 又’本發明中亦可如日本特開平5-19467號公報、日 本特開平6-230212號公報、日本特開平7_2〇7211號公報 、曰本特開平09-325494號公報、日本特開平n_14〇144 號公報、日本特開2008_18 1095號公報等所揭示般，將側 鍵上具有（曱基）丙烯醯基等聚合性不飽和鍵之含有竣基 之聚合物用作黏著劑樹脂。 本發明中的（B)黏著劑樹脂，其以GPC(溶出溶劑：四 氫呋喃）測定之換算成聚苯乙烯的重量平均分子量（Mw) 通常為1,000〜1〇〇，_，較佳為3，_〜5〇 〇〇〇。Mw若過小 ，會有所得之被膜的殘膜率等降低、圖案形狀、耐熱性 等受損，或電特性惡化之虞，另一方面若過大，則有解 析度降低、圖案形狀受損，或以狹縫喷嘴方式進行塗布 時容易產生乾燥雜質之虞。 又，本發明中的（B)黏著劑樹脂的重量平均分子量與 以GPC(溶出溶劑：四氫呋喃）測定之換算成聚苯乙烯的數 量平均分子量（以下稱為「Mn」）的比（Mw/Mn)較佳為 1.0〜5_0，更佳為1.0〜3 〇。 本發明中的（B)黏著劑樹脂能以習知方法來製造，亦 能以例如日本特開2〇03_222717號公報、日本特開 2006-259680號公報、國際公開第〇7/〇29871號小冊等所 揭露之方法來控制其構造或Mw、Mw/Mn。 本發明中（B)黏著劑樹脂可單獨或混合兩種以上使 用。 -12- 201232170 本發明中⑻黏著劑樹脂的含量相色劑⑽ 質量份，較佳為10〜1，000質量份，特 w 村1主為2〇〜500質量份 。黏著劑樹脂的含量若過少，合古 m t有例如驗性顯影性降低 、所付之者色性組成物的保存穩定性降低之虞，另一方 面若過多，則因著色劑濃度相對降低，而有：以達成作 為薄膜的目標色濃度之虞。 -(c)交聯劑- 本發明中（C)交聯劑係指具有2個以上可聚合基團的 化合物。可聚合基團可例舉如乙烯性不飽和基團、環氧 乙烧基（oxiranyD、氧環丁院基（Gxetanyl)、N•院氧基甲胺 基等。本發明中，作為（C)交聯劑較佳為具有2個以上（甲 基）丙烯醯基的化合物、或具有2個以上N_烷氧基甲胺基 的化合物。 作為上述「具有2個以上（曱基）丙烯醯基的化合物」 的具體貫例，可例舉脂肪族多羥基化合物與（甲基）丙烯 酸反應所得之多官能（曱基）丙烯酸酯、經己内酯改性之 多官能（甲基）丙烯酸酯、經環氧烷改性之多官能（甲基） 丙烯酸酯、使具有羥基之（甲基）丙烯酸酯與多官能異氰 酸醋反應所得之多官能胺基甲酸酯（曱基）丙烯酸酯、使 具有羥基之（曱基）丙烯酸酯與酸酐反應所得之具緩基之 多官能（曱基）丙烯酸酯等。 於此，作為上述脂肪族多羥基化合物可例舉諸如， 如乙二醇、丙二醇、聚乙二醇、聚乙二醇之二元脂肪族 多羥基化合物；甘油、三羥曱基丙烷、新戊四醇、二新 戊四醇之二元以上的脂肪族多經基化合物。上述具有_ -13- 201232170 基之（甲基）内烯酸酯可例舉如（曱基）丙烯酸2-羥甲酯 '三 I 土 元二（甲基）丙烯酸酯、新戊四醇三（甲基）丙烯酸 酉曰一新戊四醇五（甲基）丙烯酸酯、丙三醇二甲基丙烯 fee S曰專上述多官能異氰酸酯可例舉如曱苯二異氰酸略 /亞甲基—異氰酸酯、二苯基亞甲基二異氰酸酯、異 佛爾酮-異氰酸酯等。酸酐可例舉諸如，如琥珀酸酐、 馬來駄酐、戊二酸酐、伊康酸酐、鄰苯二甲酸酐、六氫 鄰苯-甲§文酐之雙質子酸酐；苯均四酸酐、二苯基四羧 酸二酐、二苯甲酮四羧酸二酐之四質子酸二酐。 又，上述經己内酯改性之多官能（甲基）丙烯酸酯， 可例舉如日本特開平U_44955號公報之段落 [0015] [0018]所記載的化合物。上述經環氧烷改性之多 官能（曱基）丙烯暖醋可例舉雙龄A之環氧乙烧及/或環氣 丙烷改性二(甲基)丙烯酸醋、異三聚氰酸脂環氧乙烷及/ 或環氧丙烧改性三C甲其、兩，膝缺_ —基)丙烯酉义酉曰、三羥甲基丙烷之環 氧乙烧及/或％_氧丙烧改性=(甲其、壬陡綠 J /凡f又炫_ (甲丞）丙烯酸酯、新戊四醇 之環氧t烧及/或帛氧丙燒改性三（f基）丙烯酸醋、新戊 四醇之％氧乙燒及/或環氧丙烧改性四（甲基）丙烯酸醋、 二新戊四醇之環氣乙、 f乳乙烷及/或％乳丙烷改性五（甲基）丙烯 酸酯、二新戊四醇之環氯乙、拉0 /七 衣乳乙烷及/或環氡丙烷改性六（甲 基）丙烯酸酯等。 此外，作為上述「且右9u 江具有2個以上N_烷氧基甲胺基的化 合物」’可例舉如具有二穿4 ftfc 4垃 /、名一水氰胺構造、苯并胍胺 (benZ〇gUanamlne)構造、尿素構造的化合物等。此外，三 聚氰胺構造、苯并胍胺構造係指具有⑽以上三料或= -14- 201232170 基取代三听環作五1 择 作為基本骨架的化學構造，係為亦包含三 聚亂胺、笨莽腻日公—# & 月女或其專之縮合物的概念。作為具有2 個以上Ν -燒盡其K n/l> w 乳基甲胺基之化合物的具體實例，可例舉 N，N，N ’，N ’，N ’，N，，丄,a ,,，N_^、（烷氧基曱基）三聚氰胺、 N，N，N，N -四（烷氧基曱基）苯并胍胺、N，N，N，，N，-四（烷氧 基甲基）乙炔脲等。 此等（C)交聯劑當中，較佳為3價以上之脂肪族多羥 基化合物與（甲基）丙烯酸反應所得之多官能（曱基）丙烯 酸S曰經己内酯改性之多官能（甲基）丙烯酸酯、多官能 月女基曱fee S曰（甲基）丙烯酸酯、具有羧基之多官能（甲基） 丙烯酸醋、义1^，1^，小，小’，，化，_六（烷氧基甲基）三聚氰胺 、N，N，N’，N’-四（烷氧基曱基）苯并胍胺。以著色層的強度 高、著色層的表面平滑性優良，且未曝光部分的基板上 及遮光層上難以發生浮汙（scumming)、膜殘留等觀點而 吕，3價以上之脂肪族多羥基化合物與（甲基）丙烯酸反應 所得之多官能（甲基）丙烯酸酯當中，特佳為三羥甲基丙 烷三丙烯酸酯、新戊四醇三丙烯酸酯、二新戊四醇五丙 烯魷酯、二新戊四醇六丙烯酸酯；具有羧基之多官能（ 甲基）丙烯酸酯當中，特佳為新戊四醇三丙烯酸酯與琥珀 酸酐反應所得之化合物、二新戊四醇五丙烯酸酯與琥珀 酸酐反應所得之化合物。 本發明中’（C)交聯劑可單獨或2種以上混合使用。 本發明中的（C)交聯劑的含量係相對（A)著色劑1 〇〇 夤量伤，較佳為10〜1，〇〇〇質量份，特佳為2〇〜5〇〇質量份 。此時，交聯劑的含量若過少，會有無法獲得充分的硬 -15- 201232170 化性之虞。另—方 發明著色性組成物 ，而有未曝光部分 膜殘留等的傾向。 -(D)特定化合物. 面’交聯劑的含量 驗性顯影性時，則 的基板上或遮光層 若過多，當赋予本 鹼性顯影性會降低 上容易發生浮汙、 ⑼特定化合物係*類成上述⑹）〜（d 8)的任一種 的。物本發明中只要含有此等當中的至少1種即可。 * =合物（cM)〜（d_6)係具有_〇R，基.sr2基及_q nr3 土田中的任取代基作為對金屬具有配位能力之官能 基特别由對金屬之配位能力之觀點而言，係以具有_sr2 基、-Q-NR3R4基為佳。 面於此，R〜R4彼此獨立表示氫原子或取代或未取代之 Η貝烃基而作為所述烴基，可例舉碳數^20(較佳為碳 數1〜8)之脂肪族烴基、碳數3〜2〇(較佳為碳數3〜6)之脂環 式:^!基奴數6〜20(較佳為碳數6〜14)之芳基、碳數7〜2〇( 較佳為碳數7〜14)之芳烷基等。作為碳數丨〜2〇之脂肪族烴 基，可列舉碳數1〜20之烷基、碳數2〜2〇之烯基、碳數2〜2〇 之炔基等，具體而言，可例舉甲基、乙基、丙基、乙烯 基、烯丙基、乙炔基、2-丙炔基等。作為碳數3〜2〇之脂 %式基，可列舉碳數3〜8之環烧基、碳數3〜8之環稀茂 專’具體而言，可例舉環丙基、環戊基、環己基、環丙 烯基、環戊烯基、環己烯基等。此外，烷基、烯基及炔 基可呈直鏈狀或支鏈狀’稀基及炔基可於分子内及末端 之任一者具有不飽和鍵。又，作為碳數6〜20之芳基，可 例舉苯基、萘基、蒽基、菲基、聯苯基等。作為碳數7〜2 〇 -16- 201232170 之芳烧基’則可例舉苯甲基、苯乙基、三苯曱基等。 又’此等經基可具有取代基，作為所述取代基，可 例舉如羥基、烷氧基、_素基、硝基、氰基、醯胺基、 磺酸基、烷基（較佳為Ci_6烷基）_羰基、芳基（較佳為c6 i4 芳基）-羰基等。再者，此等取代基之位置及數目係任意 者，當具有2個以上取代基時，該取代基可相同或相異。 此等當中，作為R1〜R4，特佳為氫原子、碳數】〜8之 烷基、碳數3〜8之環烷基、碳數6〜14之芳基、碳數7〜14 之芳烷基。 Q係表示單鍵或羰基，惟可依據化合物的種類 選擇。 田 万面，化合物（d-7)〜（d-8)係 刀 、/^_雜碌丞作為對 活屬具有配位能六令&使 酸性官能基。 s此基，並具備羧基或磺酸基作為 =雜環’可列舉碳原子與選自氮原子、氧原子及 :雜广少1種原子鍵結所形成的單環式雜環或多環 環，較佳為元環;麵環。作為單環式雜 環氧乙燒環、氮丙環等之具有：環’具體實例可例舉 喃if、Y a 專之具有—個雜原子之3元雜環；呋 及噻吩環、吡咯環、2H_。比 一故 ^ 二氫㈣環、咯咬環等 /、-氧。…哀、2- 二氡00,專之〃、有一個雜原子之5元雜環； 氣戊％、污唾環、異噚唑 、異嗓。坐環、〖…環、味”，3,環、。塞。坐環 環、咪唾唆環…比唾環… '、咪嗤啉環、2十坐淋 啶環等之I右@ M 啉裱、3 -吡唑啉環、吡唑 寺之具有兩個雜原子之5元雜環；咬咕（“Μ環、 -17- 201232170 二唾壞、。塞二唑環、噚二唑環等一 · 〇th - iS 寸心八有二個雜原子5元雜 %，比南％、2H_吡喃環、吡啶 ^ ^ ^ , 瓜疋％等之具有一個 :雜環；硫代'鳴環，衰、例… 农—衣、味福啉環等之具有兩個雜原子之6元雜琿. :二三::：之具有三個雜原子之6元雜環等。此：： 口 =雜環，可例舉2〜3個單環式雜環彼此稠合者、 或平衣式雜環與1〜2個芳香族環 而Λ夕-供/ …如本裱、萘環等）稠合 而成之- ％糸雜環、三環系雜環等 可例舉苯并呋咕俨里贫ϋ 0土土 為一 ％糸雜％， 笨并嗔吩产“、、異本4夫喃環、h笨并嗟吩環、2- …产…弓丨°朵環、3，°朵環、異。弓卜朵環，環、 吲沐啉％、異吲哚啉環、2Η_< 〇4 ^ a 兄 70 埽裱、咬咣（chromane) %、異兔。元％、1H_2_笨并吡喃環、 /1 tr A ^ 圭你％、異喹啉環、 圭“具有-個雜原子之雜環 噻吐環、1H·。引嗤環、1>8•嗓啶環、 农本开 走3琳ί辰、啥。坐琳環 、喹唑啉啶環、啐啉環、呔听 雜環；嗓呤環、蜱咬環等之呈：具有兩個雜原子之 衣專之具有四個雜原子之雜環等。 又：為三壞系雜環，可例舉味唾環、二苯并派喃環、· 啶%…丫啶裱等之具有一個雜原子之雜環；卜咔啉環、 嘧啶環、1,7-啡啉環、1 1〇_啡嗷 ，#啉環、噻蒽環、啡嘮噻環 、4糾環、啡㈣環、㈣㈣之具有兩個 之雜 環等。 此卜化口物（d-Ι)〜（d-8)可為鹽之形態。鹽可例舉 銨鹽、有機銨鹽等，特佳為有機銨鹽。 作為有機録離子並未特別限定，較佳 二、三 或四烷基銨離子，特佳為四院基 況基叙離子。再者，與氮原 -18- 201232170 子鍵結之烷基可相同或相里 X相呉，較佳為碳數1〜20之直鏈狀 、支鏈狀或環㈣基’更佳為碳數卜12之直㈣基。具 體而言，可例舉四乙基銨1 丁基銨、二甲基(雙十八基 )鍵、四己基銨、三丁基（甲基）錄、四（十二基）敍、四辛 基鉍、二甲基（十六基）銨、三辛基（甲基）銨、四異戊基銨 、一乙基銨、三丁基銨、三己基銨、三辛基銨等。 以下，對化合物（d-1)〜（d_8)具體進行說明。 [化合物（d-ι)及（d-3)] 化合物（d-1)及（d-3)係具有選自包含_〇Rl基及_SR2 土 =群組的至少1種之脂肪族羧酸或脂環式羧酸或其等 之鹽，而由進一步抑制凝集雜質產生及對比比率降低之 觀點而言，較佳為下述式（2)所示之化合物或其鹽： γ1 -COOH (2) [述式（2)中’γ1表示經-OR1或_SR2取代之碳數1〜20之烷 基或經'〇Rl或-Sr2取代之碳數3〜8之環烷基]。 作為具有-OR1基之化合物（d-丨），可例舉如乙醇酸、 乳酸 、44- " 甘油酸、羥基丁酸、曱羥戊酸、泛解酸、2-甲氧 基丙馼、曱氧基丁酸、甲氧基戊酸、2_苯氧基丙酸、苯 氧基丁酸、苯氧基戊酸、2_苯曱氧基丙酸、苯曱氧基丁 酸、笨甲氧基戊酸。 又作為具有-SR2基之化合物（d-1)，可例舉如2-曱硫 基丙酸、〇 ¥0 _ , 曱’IL基丁酸、3 -曱硫基丁酸、2 -曱硫基戍酸、 3、甲硫基戊酸、4-甲硫基戊酸、2_苯硫基丙酸、2-苯硫基 戍& 3 -苯硫基戊酸、4 -苯硫基戊酸、2 -苯甲硫基丙酸、 2苯甲碳基丁酸、3-苯曱硫基丁酸、2_苯甲硫基戊酸、3_ -19- 201232170 苯曱硫基戊酸、4-苯曱硫基戊酸、2-氫硫基丁酸、下述 化合物群a所示之化合物。 [化合物群a][In the formula (1), "X" independently indicates that 10 to 15 of the hydrogen atom portion x is a bromine atom, "sub or bromine, and i to 6 are chlorine atoms." In the present invention, the above-mentioned mismatch can be made with the above. , inorganic pigments, oil-soluble dyes Q ', s彳 using well-known dyes, etc. Materials, direct dyes, acid dyeing = in the invention, the colorant can be used alone or in two kinds of the present invention, when using the combination of the pigment The recrystallization method, :::: is: when the coloring agent is used, it is also used after the purification by the i ^ L 焱 method, the cleaning agent cleaning method, the heating method, or the like. The surface of the particles can be modified by the resin as needed. The resin which is modified by the surface of the particles to be granulated is exemplified by a carrier resin such as O. cer., or a resin for dispersing a pigment. Further, the pigment is preferably so-called 丨nulling) The primary particle is miniaturized and used. The salt milling method can be as follows: (A) The content ratio of the coloring agent is high, the color difference, the whole machine pigment, Authentic 3 ° depending on the demand, the pigment will also be used in various kinds of pigment 108817 (salt use case From the viewpoint of forming a black matrix excellent in light-shielding property, the solid content of the coloring composition is 5 to 7 〇 mass%, preferably 4 〇 所谓The content is a component other than the solvent to be described later. - (B) Adhesive resin _ $ (B) The adhesive resin is not particularly limited as long as it has a carboxyl group, a phenolic hydroxyl group, etc. The acid functional group is preferably a polymer having a carboxyl group (hereinafter referred to as "a carboxyl group-containing dimer"), and has a carboxyl group or an ethylenically unsaturated monomer having a HgJ or higher (hereinafter referred to as "unsaturated". a copolymer of a monomer (bl)" and another copolymerizable ethylene-terminated unsaturated monomer (hereinafter referred to as "unsaturated monomer (b2)"). The unsaturated monomer (bl) may be exemplified. Such as (meth)acrylic acid, maleic acid, maleic acid liver, mono [2·(indenyl)acrylic acid ethyl] sylvestre vinegar, 'carboxypolycaprolactone mono(meth) acrylate, p-vinyl benzene Niobic acid, etc. These unsaturated monomers (bl) may be used singly or in combination of two or more. The unsaturated monomer (b2) may, for example, be an N-position substituted maleimide of phenyl maleic amine N-cyclohexylmaleimide; for example, styrene, α-methyl stupid Ethylene, p-paraphenylene, p-hydroxy-α-methylstyrene, p-vinylbenzyl glycidyl ester, aromatic vinyl compound of acenaphthylene, such as methyl methacrylate (Meth)acrylic acid n-butyl vinegar, (mercapto) propylene oxime 2 ethylhexyl ester, (meth)acrylic acid 2 hydroxyethyl ester, (mercapto) propylene decyl allyl propylene sulfonium sulfonate , polyethylene glycol (degree of polymerization 2~1〇) methyl ether (meth)acrylic acid _, polypropylene glycol (degree of polymerization 2~1〇) methyl ether (mercapto) -10- 201232170 acrylate, polyethylene glycol ( Degree of polymerization 2 to 10) mono (meth) acrylate, propylene glycol (degree of polymerization 2 to 10) mono (meth) acrylate, (meth) propylene decyl hexyl ester, isodecyl (meth) acrylate, Tricyclo[5 2丨〇2,6]decane^yl^methyl)acrylate, dicyclopentenyl (mercapto) acrylate, glycerol = (meth) acrylate, (methyl) 4-hydroxyphenyl enoate, ethylene oxide modified (meth) acrylate of nonylphenol, glycidyl (meth)acrylate, 3,4-epoxycyclohexylmethyl (fluorenyl) acrylate , 3_[(fluorenyl) propylene fluorenyl fluorenyl] propylene acrylate, 3-[(meth) propylene methoxymethyl] _ 3 _ ethyl propylene oxide (meth) acrylate; Hexyl sulphur, shouting, singular, tricyclic [5.2.1.〇2,6]decane-8-yl vinyl ether, pentacyclopentadecyl vinyl ether, 3_(vinyl epoxy fluorenyl) a vinyl ether of -3 -ethyl propylene oxide; such as polystyrene, decyl poly(meth) acrylate, n-butyl poly(decyl) acrylate, polyoxymethane, having a single molecular chain at the end of the polymer chain Base) A macromonomer of acrylonitrile. These unsaturated monomers (b2) can be used individually or in mixture of 2 or more types. In the copolymer of the unsaturated monomer (b1) and the unsaturated monomer (b2), the copolymerization ratio of the unsaturated monomer (b1) in the copolymer is preferably from 5 to 7 % by mass, more preferably 1 0 to 60% by mass. In this range, the unsaturated monomer (b 1) is copolymerized to obtain a color-developing composition excellent in alkali developability and storage stability. Specific examples of the copolymer of the unsaturated monomer (b1) and the unsaturated monomer (b2) are exemplified by Japanese Laid-Open Patent Publication No. Hei. No. 7-140654, Japanese Patent Application Laid-Open No. Hei 8-259876, and Japanese Patent Application No. Hei. Japanese Unexamined Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A copolymer disclosed in Japanese Laid-Open Patent Publication No. 2002-296778, and the like. In the present invention, Japanese Laid-Open Patent Publication No. Hei 5-19467, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A thiol group-containing polymer having a polymerizable unsaturated bond such as a (fluorenyl) acrylonitrile group on a side bond is used as an adhesive resin, as disclosed in Japanese Laid-Open Patent Publication No. Hei. In the (B) adhesive resin of the present invention, the weight average molecular weight (Mw) converted into polystyrene by GPC (solution solvent: tetrahydrofuran) is usually 1,000 to 1 Å, _, preferably 3, _. ~5〇〇〇〇. When the Mw is too small, the residual film ratio of the obtained film may be lowered, the pattern shape, heat resistance, and the like may be impaired, or the electrical properties may be deteriorated. On the other hand, if the thickness is too large, the resolution may be lowered and the pattern shape may be impaired. When coating is performed by a slit nozzle method, it is easy to generate dry impurities. In addition, the ratio of the weight average molecular weight of the (B) adhesive resin to the number average molecular weight (hereinafter referred to as "Mn") of polystyrene measured by GPC (solution solvent: tetrahydrofuran) in the present invention (Mw/Mn) It is preferably 1.0 to 5_0, more preferably 1.0 to 3 〇. The (B) adhesive resin in the present invention can be produced by a known method, and can also be exemplified by, for example, Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. 2006-259680, No. The method disclosed in the book, etc., controls its structure or Mw, Mw/Mn. In the present invention, (B) the adhesive resin may be used singly or in combination of two or more. -12- 201232170 In the present invention, (8) the content of the adhesive resin (10) parts by mass, preferably 10 to 1,000 parts by mass, and the total amount of the main component of the village is 2 to 500 parts by mass. When the content of the adhesive resin is too small, for example, the aging property is lowered, and the storage stability of the color composition is lowered. On the other hand, if the amount is too large, the concentration of the colorant is relatively lowered. Yes: to achieve the target color density as a film. - (c) Crosslinking agent - In the present invention, the (C) crosslinking agent means a compound having two or more polymerizable groups. The polymerizable group may, for example, be an ethylenically unsaturated group, an oxiranyl group, an oxiranyl group, a Gxetanyl group, a N-houseoxymethylamino group or the like. In the present invention, as (C) The crosslinking agent is preferably a compound having two or more (meth)acryl fluorenyl groups or a compound having two or more N-alkoxymethylamino groups. The above-mentioned "having two or more (fluorenyl) acrylonitrile groups Specific examples of the compound may, for example, be a polyfunctional (mercapto) acrylate obtained by reacting an aliphatic polyhydroxy compound with (meth)acrylic acid, a polycaprol (meth) acrylate modified with caprolactone, An alkylene oxide-modified polyfunctional (meth) acrylate, a polyfunctional urethane (mercapto) acrylate obtained by reacting a hydroxyl group-containing (meth) acrylate with polyfunctional isocyanuric acid, A polyfunctional (fluorenyl) acrylate having a slow-reacting group obtained by reacting a hydroxy group (fluorenyl) acrylate with an acid anhydride. Here, as the above aliphatic polyhydroxy compound, for example, ethylene glycol or propylene glycol can be exemplified. , polyethylene glycol, polyethylene glycol binary Aliphatic polyhydroxy compound; divalent or higher aliphatic poly-based compound of glycerol, trihydroxydecylpropane, neopentyl alcohol, and dipentaerythritol. The above has a (meth) group of _ -13- 201232170 The enoate can be exemplified by 2-hydroxymethyl (meth) acrylate, tri-I-di-di (meth) acrylate, and neopentyl alcohol tris(ny) pentoxide. The above-mentioned polyfunctional isocyanate is exemplified by phthalic acid ester, glycerol dimethyl propylene, and the above polyfunctional isocyanate, such as fluorene diphenyl isocyanate / methylene - isocyanate, diphenyl methylene diisocyanate, isophor Ketone-isocyanate, etc. The acid anhydride may, for example, be a bis-protic anhydride such as succinic anhydride, maleic anhydride, glutaric anhydride, itaconic anhydride, phthalic anhydride, hexahydro-o-benzene-form anhydride; a tetracarboxylic acid dianhydride of tetracarboxylic acid anhydride, diphenyltetracarboxylic dianhydride, and benzophenone tetracarboxylic dianhydride. Further, the above-mentioned caprolactone-modified polyfunctional (meth) acrylate may, for example, be exemplified. The compound described in paragraph [0015] [0018] of JP-A-44955, the above-mentioned alkylene oxide. The polyfunctional (fluorenyl) propylene warm vinegar can be exemplified by double-aged A ethylene oxide and/or cyclopropane modified di(meth)acrylic acid vinegar, iso-cyanurate ethylene oxide and/or Or propylene-acrylic acid modified three C-methyl, two, knee-deficient _-based propylene oxime, trimethylolpropane epoxicone and / or % oxypropylene burning modified = (a壬 壬 绿 绿 绿 / 绿 绿 绿 炫 炫 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Oxygen bromide and/or propylene oxide modified tetrakis(meth)acrylate vinegar, dipentaerythritol ring ethylene B, f lactide and/or % lactula modified penta (meth) acrylate, Cyclohexyl chloride of dipentaerythritol, pull 0/seven emulsified ethane and/or cyclopropane modified hexa(meth) acrylate, and the like. In addition, as the above-mentioned "compound having two or more N-alkoxymethylamino groups in the right 9u River", it may be exemplified by having a double-wearing 4 ftfc 4 waste/, a melamine structure, and a benzoguanamine ( BenZ〇gUanamlne) Structure, compound of urea structure, etc. In addition, the melamine structure and the benzoguanamine structure refer to a chemical structure having a tertiary material of (10) or more or a substituent of -14-201232170, which is used as a basic skeleton, and also includes a trimeric polyamine, a clumsy腻日公—# & The concept of the moon female or its special condensate. Specific examples of the compound having two or more hydrazine-burning K n/l > milylmethylamino groups may, for example, be N, N, N ', N ', N ', N, 丄, a , , N_^, (alkoxycarbonyl) melamine, N,N,N,N-tetrakis(alkoxyindenyl)benzoguanamine, N,N,N,,N,-tetra(alkoxy) Methyl) acetylene urea and the like. Among these (C) crosslinking agents, a polyfunctional (mercapto)acrylic acid S oxime obtained by reacting an aliphatic polyhydroxy compound having a valence of three or more with (meth)acrylic acid is preferably polycapped with caprolactone ( Methyl) acrylate, polyfunctional moon-based 曱fee S 曰 (meth) acrylate, polyfunctional (meth) acrylate with carboxyl group, meaning 1 ^, 1 ^, small, small ',, _ Hexa(alkoxymethyl)melamine, N,N,N',N'-tetrakis(alkoxyindenyl)benzoguanamine. The trivalent or higher aliphatic polyhydroxy compound is excellent in the strength of the colored layer, the surface smoothness of the colored layer, and the fact that the unexposed portion of the substrate and the light shielding layer are less likely to cause scumming or film retention. Among the polyfunctional (meth) acrylates obtained by the reaction with (meth)acrylic acid, trimethylolpropane triacrylate, neopentyl alcohol triacrylate, dipentaerythritol penta propylene acrylate, and the like are particularly preferred. Pentaerythritol hexaacrylate; among the polyfunctional (meth) acrylates having a carboxyl group, a compound obtained by reacting pentaerythritol triacrylate with succinic anhydride, dipentaerythritol pentaacrylate and succinic anhydride The resulting compound is reacted. In the present invention, the '(C) crosslinking agent may be used singly or in combination of two or more kinds. The content of the (C) crosslinking agent in the present invention is relative to (A) the colorant 1 〇〇夤, preferably 10 to 1, 〇〇〇 by mass, particularly preferably 2 〇 to 5 〇〇 by mass. . At this time, if the content of the crosslinking agent is too small, sufficient hardness of the hard -15-201232170 cannot be obtained. Further, the coloring composition is invented, and there is a tendency that the unexposed portion of the film remains. - (D) Specific compound. When the content of the surface-crosslinking agent is inspectability, if the amount of the substrate or the light-shielding layer is too large, the alkali developability is lowered and the floating property is likely to occur. (9) Specific compound system* It is classified into any of the above (6)) to (d 8). In the present invention, at least one of these may be included. * = compound (cM) ~ (d_6) has any substituent in the _〇R, s.r2, and _q nr3 fields as a functional group having a coordinating ability to a metal, particularly by the coordination ability to a metal. From the viewpoint, it is preferred to have a _sr2 group and a -Q-NR3R4 group. In this case, R to R4 each independently represent a hydrogen atom or a substituted or unsubstituted mussel hydrocarbon group, and as the hydrocarbon group, an aliphatic hydrocarbon group having a carbon number of 20 (preferably, a carbon number of 1 to 8) and carbon may be mentioned. An alicyclic ring having a number of 3 to 2 Torr (preferably a carbon number of 3 to 6): an aryl group having a number of 6 to 20 (preferably a carbon number of 6 to 14) and a carbon number of 7 to 2 Å (more) It is preferably an aralkyl group having a carbon number of 7 to 14). Examples of the aliphatic hydrocarbon group having a carbon number of 〇2 to 2〇 include an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 2 carbon atoms, and an alkynyl group having 2 to 2 carbon atoms. Specifically, for example, Methyl, ethyl, propyl, vinyl, allyl, ethynyl, 2-propynyl and the like. Examples of the aliphatic group having a carbon number of 3 to 2 Å include a cycloalkyl group having 3 to 8 carbon atoms and a ring of 3 to 8 carbon atoms. Specifically, a cyclopropyl group or a cyclopentyl group is exemplified. , cyclohexyl, cyclopropenyl, cyclopentenyl, cyclohexenyl and the like. Further, the alkyl group, the alkenyl group and the alkynyl group may be linear or branched. The dilute group and the alkynyl group may have an unsaturated bond in either the molecule or the terminal. Further, examples of the aryl group having 6 to 20 carbon atoms include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthryl group, and a biphenyl group. The aryl group which has a carbon number of 7 to 2 〇 -16 to 201232170 may, for example, be a benzyl group, a phenethyl group or a triphenyl fluorenyl group. Further, such a radical may have a substituent, and examples of the substituent include a hydroxyl group, an alkoxy group, a sulfenyl group, a nitro group, a cyano group, a decylamino group, a sulfonic acid group, and an alkyl group. It is a Ci_6 alkyl)-carbonyl group, an aryl group (preferably a c6 i4 aryl group)-carbonyl group or the like. Further, the positions and numbers of the substituents are arbitrary, and when there are two or more substituents, the substituents may be the same or different. Among them, R1 to R4 are particularly preferably a hydrogen atom, an alkyl group having a carbon number of -8, a cycloalkyl group having 3 to 8 carbon atoms, an aryl group having 6 to 14 carbon atoms, and a aryl group having 7 to 14 carbon atoms. alkyl. The Q system represents a single bond or a carbonyl group, but may be selected depending on the kind of the compound. Tian Wan, compound (d-7) ~ (d-8) is a knife, / ^ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The s group having a carboxyl group or a sulfonic acid group as a =heterocyclic ring may be a monocyclic heterocyclic ring or a polycyclic ring formed by bonding a carbon atom to a nitrogen atom, an oxygen atom, and a hetero atom. Preferably, it is a meta-ring; a face ring. Examples of the monocyclic heteroepoxy Ethylene ring, the nitrogen propylene ring, and the like include a ring' specific example, and a 3-membered heterocyclic ring having a hetero atom; a furyl group and a pyrrole ring; , 2H_. Than a ^ dihydro (tetra) ring, a bite ring, etc. /, - oxygen. ... mourning, 2- 2 氡 00, special 〃, a 5-membered heterocyclic ring with a hetero atom; pentyl, sputum, isoxazole, isoindole. Seat ring, 〖...ring, taste", 3, ring, plug. Ring ring, sputum ring... than salivary ring... ', imipenem ring, 2 sitting guanidine ring, etc. I right @ M porphyrin裱, 3-pyrazoline ring, 5-membered heterocyclic ring with two heteroatoms of pyrazole; biting 咕 ("Μ ring, -17- 201232170 di-salt, soxadiazole ring, oxadiazole ring, etc.一· 〇th - iS 寸心八 has two heteroatoms 5 yuan heterozygous, than the south %, 2H_ pyran ring, pyridine ^ ^ ^, 疋%%, etc. have one: heterocyclic ring; thio 'ring ring, Decay, example... 6-membered heteropolysaccharide with two heteroatoms, such as agro-coating and misoproline ring. : 2:3::: 6-membered heterocyclic ring with three heteroatoms, etc. This:: mouth = miscellaneous The ring may, for example, be a condensed form of 2 to 3 monocyclic heterocyclic rings, or a blister-type heterocyclic ring and 1 to 2 aromatic rings, and may be fused to a ruthenium, a ruthenium, or the like. The - 咕俨 咕俨 糸 ϋ ϋ 糸 糸 苯 苯 苯 苯 苯 苯 苯 苯 苯 苯 苯 苯 ϋ 苯 ϋ ϋ ϋ ϋ 苯 苯 ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ h stupid and 嗟 环 ring, 2- ... production ... bow 丨 ° ring, 3, ° ring, different. Bow Bu ring, ring, 吲 吲 啉%, isoindoline ring, 2Η_< 〇4 ^ a brother 70 埽裱, chromane %, different rabbits. %%, 1H_2_ stupid pyran ring, /1 tr A ^ 圭%%, different Quinoline ring, gui" "Heterocyclic oxime ring with 1 hetero atom, 1H·. The ring of 嗤, 1 > 8 • acridine ring, Nongben opened 3 lin ί Chen, 啥. A ring of a ring, a quinazolinium ring, a porphyrin ring, a fluorene heterocyclic ring, an anthracene ring, a bite ring, etc., a heterocyclic ring having four heteroatoms, and the like. Further, it is a trivalent heterocyclic ring, and examples thereof include a heterocyclic ring having a hetero atom such as a taste ring, a dibenzopyran ring, a pyridinium group, a pyridinium ring, a pyrimidine ring, and 1, 7-phenanthroline ring, 1 1 〇 _ 嗷 嗷 嗷, # 啉 。 、 # # # # # # # # # # # 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The bubbling material (d-Ι)~(d-8) may be in the form of a salt. The salt may, for example, be an ammonium salt or an organic ammonium salt, and particularly preferably an organic ammonium salt. The organic recording ion is not particularly limited, and is preferably a di-, tri- or tetraalkylammonium ion, and particularly preferably a four-chamber basic ion. Further, the alkyl group bonded to the nitrogen atom-18-201232170 may be the same or the phase X phase, preferably a linear, branched or cyclic (tetra) group having a carbon number of 1 to 20, more preferably carbon. A number of 12 straight (four) base. Specifically, tetraethylammonium 1 butylammonium, dimethyl (bisoctadecyl) bond, tetrahexylammonium, tributyl (methyl), tetra (tweldium), and tetraoctyl can be exemplified. Base, dimethyl (hexadecyl) ammonium, trioctyl (methyl) ammonium, tetraisoamylammonium, monoethyl ammonium, tributyl ammonium, trihexylammonium, trioctyl ammonium, and the like. Hereinafter, the compounds (d-1) to (d_8) will be specifically described. [Compound (d-ι) and (d-3)] The compounds (d-1) and (d-3) have at least one aliphatic carboxylic acid selected from the group consisting of 〇R1 group and _SR2 soil=group. The acid or alicyclic carboxylic acid or a salt thereof is preferably a compound represented by the following formula (2) or a salt thereof from the viewpoint of further suppressing generation of aggregated impurities and a decrease in the contrast ratio: γ1 -COOH ( 2) [γ1 in the above formula (2) represents an alkyl group having 1 to 20 carbon atoms substituted by -OR1 or _SR2 or a cycloalkyl group having 3 to 8 carbon atoms substituted by 'R1 or -Sr2'. The compound (d-oxime) having a -OR1 group may, for example, be glycolic acid, lactic acid, 44- " glyceric acid, hydroxybutyric acid, hydroxyvaleric acid, pantoic acid, 2-methoxypropionate,曱oxybutyric acid, methoxy valeric acid, 2-phenoxypropionic acid, phenoxybutyric acid, phenoxyvaleric acid, 2-benzoyloxypropionic acid, benzoquinoxybutyric acid, stupid Oxyvaleric acid. Further, the compound (d-1) having a -SR2 group may, for example, be 2-indolethiopropionic acid, 〇¥0 _ , 曱'IL-based butyric acid, 3-mercaptothiobutyric acid, 2-indene sulfur Base acid, 3, methylthiovaleric acid, 4-methylthiovaleric acid, 2-phenylthiopropionic acid, 2-phenylthiosulfonium & 3-phenylthiopentanoic acid, 4-phenylthiopenta Acid, 2-phenylthiopropionic acid, 2 benzylidene butyric acid, 3-phenylindole thiobutyric acid, 2-phenylthio valeric acid, 3_ -19- 201232170 phenyl sulfenyl valeric acid, 4 - benzoquinone valeric acid, 2-hydrothiobutyric acid, a compound represented by the following compound group a. [Compound group a]

HS^COOH HS，/Sx/'C〇〇H HS^^^^^COOHHS^COOH HS,/Sx/'C〇〇H HS^^^^^COOH

HS</^x^/Nv^'Nv^Sx/^'Sn^'n'COOH v^^^COOH 作為具有-OR1基之化合物（d-3)，可例舉如2-羥基環 己烷羧酸、3-羥基環己烷羧酸、4-羥基環己烷羧酸、莽 草酸（環己稀環三經基酸）、奎尼酸（quinic acid，環己烧環 四羥基酸）、2-曱氧基環己烷羧酸、3-曱氧基環己烷羧酸 、4-甲氧基環己烷羧酸、2-苯氧基環己烷羧酸、3-苯氧基 環己烷羧酸、4-苯氧基環己烷羧酸、2-苯甲氧基環己烷 羧酸、3 -苯曱氧基環己烷羧酸、4-苯曱氧基環己烷羧酸 〇 又作為具有-SR2基之化合物（d-3)，可例舉如2-氫硫 基環己烷羧酸、3-氫硫基環己烷羧酸、4-氫硫基環己烷 羧酸、2-曱硫基環己烷羧酸、3-甲硫基環己烷羧酸、4-曱硫基環己烷羧酸、2-苯硫基環己烷羧酸、3-苯硫基環 己烷羧酸、4-苯硫基環己烷羧酸、2-苯曱硫基環己烷羧 酸、3-苯曱硫基環己烷羧酸、4-苯甲硫基環己烷羧酸。 [化合物（d-2)及（d-4)] 化合物（d-2)及（d-4)係具有選自包含-OR1基、-SR2基 及-Q - N R3 R基之群組的至少1種之脂肪族績酸或脂環式 磺酸或其等之鹽，而由進一步抑制凝集雜質產生及對比 -20- 201232170 比率降低之觀點而言，較佳為下述式（3)所示之化合物或 其鹽： Y2-S03H (3) [上述式（3)中，γ2表示由選自包含〇R]基、_sr2基及 -q-nr3r基之群組的至少】種取代之碳數丨〜2〇之烷基、由 選自包含或-0R】基、-SR2基及_q_nr3r4基之群組的至少t 種取代之碳數3〜20之飽和脂環式烴基]。 作為化合物（d-2)’可例舉如下述化合物群示之化 合物。 [化合物群b]HS</^x^/Nv^'Nv^Sx/^'Sn^'n'COOH v^^^COOH as the compound (d-3) having a -OR1 group, such as 2-hydroxycyclohexane Carboxylic acid, 3-hydroxycyclohexanecarboxylic acid, 4-hydroxycyclohexanecarboxylic acid, shikimic acid (cyclohexadecyl tricarboxylic acid), quinic acid (cyclohexanyltetrahydroxy acid), 2-decyloxycyclohexanecarboxylic acid, 3-decyloxycyclohexanecarboxylic acid, 4-methoxycyclohexanecarboxylic acid, 2-phenoxycyclohexanecarboxylic acid, 3-phenoxy ring Hexanecarboxylic acid, 4-phenoxycyclohexanecarboxylic acid, 2-benzyloxycyclohexanecarboxylic acid, 3-benzophenoxycyclohexanecarboxylic acid, 4-benzofluorenylcyclohexanecarboxylate The acid oxime and the compound (d-3) having a -SR2 group may, for example, be 2-hydrothiocyclohexanecarboxylic acid, 3-hydrothiocyclohexanecarboxylic acid or 4-hydrothiocyclohexane. Carboxylic acid, 2-decylthiocyclohexanecarboxylic acid, 3-methylthiocyclohexanecarboxylic acid, 4-decylthiocyclohexanecarboxylic acid, 2-phenylthiocyclohexanecarboxylic acid, 3-benzene Thiocyclohexanecarboxylic acid, 4-phenylthiocyclohexanecarboxylic acid, 2-phenylsulfonylcyclohexanecarboxylic acid, 3-phenylsulfonylcyclohexanecarboxylic acid, 4-phenylthiocarbamate ring Hexanecarboxylic acid. [Compound (d-2) and (d-4)] The compounds (d-2) and (d-4) have a group selected from the group consisting of -OR1 group, -SR2 group and -Q - N R3 R group. At least one kind of aliphatic acid or alicyclic sulfonic acid or a salt thereof, and from the viewpoint of further suppressing generation of aggregated impurities and lowering the ratio of -20 to 201232170, it is preferably the following formula (3) The compound or a salt thereof: Y2-S03H (3) [In the above formula (3), γ2 represents a carbon substituted by at least one selected from the group consisting of a ruthenium R group, a _sr2 group, and a -q-nr3r group. An alkyl group having a number of 丨~2〇, a saturated alicyclic hydrocarbon group having 3 to 20 carbon atoms substituted with at least t selected from the group consisting of -OR groups, -SR2 groups and _q_nr3r4 groups. The compound (d-2)' may, for example, be a compound represented by the following compound group. [Compound group b]

OH HS^Y^s〇3H ho S°3H έΗ 〜S03H HOv、s〇3hOH HS^Y^s〇3H ho S°3H έΗ ~S03H HOv, s〇3h

HS^Vx-/^s〇3HHS^Vx-/^s〇3H

SH HS、 SO3H h2nSH HS, SO3H h2n

XjiXji

so3Hso3H

H2N^^s〇3H n' 、so3h h2n、 、so3h 作為化合妨J /Ή e、 二 勿（d-4)’可例舉如4-胺基環己烷磺酸、2,5_ 衣燒嗜S楚、2-氫硫基環己烷磺酸、3 _氣护美 己烷磺酸、2-遒访A „ «杈3虱硫基％ ,,, . π基核戊烷磺酸、3-氫硫基環戊烷磺酸H2N^^s〇3H n', so3h h2n, and so3h can be exemplified as 4-aminocyclohexanesulfonic acid, 2,5_ S Chu, 2-Hexylthiocyclohexanesulfonic acid, 3 _ gas protective hexane sulfonic acid, 2-遒 A A „ «杈3虱thiol%,,, . π-nuclear pentane sulfonic acid, 3 -Hexylthiocyclopentane sulfonic acid

、下述化合物群 R 奸不之化合物。 -21- 201232170 [化合物群c ]The following compound group R is not a compound. -21- 201232170 [Compound group c]

/S〇3h/S〇3h

βΟζΗ conh2 [化合物（d-5)] 化合物（d-5)係由具有-SR2基之基團與具有羧基之基 團取代之芳香族烴或其鹽，而由進一步抑制凝集雜質產 生及對比比率降低之觀點，較佳為下述式（4)所示之化合 物或其鹽：βΟζΗ conh2 [Compound (d-5)] The compound (d-5) is an aromatic hydrocarbon or a salt thereof substituted with a group having a -SR2 group and a group having a carboxyl group, and further suppresses generation of agglomerated impurities and a contrast ratio From the viewpoint of reduction, a compound represented by the following formula (4) or a salt thereof is preferred:

(上述式（4)中，Z表示單鍵、伸甲基或碳數2〜3之伸烷基 ，A表示經基、鹵素基、烧基或烧氧基，η表示0〜4之整 數，R2係與前述同義）。 作為上述式（4)所示之化合物，可例舉如2-氫硫基-2-苯基乙酸、2-氫硫基-3-苯基丙酸、2-氫硫基-3-苯基丁酸 、3-氫硫基-3-苯基丁酸、2-曱硫基-2-苯基乙酸、2-曱硫 基-3 -本基丙酸、2 -曱硫基-3 -苯基丁酸、3 -曱硫基-3 -苯基 丁酸、2-苯硫基-2-苯基乙酸、2-苯硫基-3-苯基丙酸、2-苯硫基丁酸、3 -苯硫基丁酸、2-苯硫基-3 -苯基丁酸、3 -苯硫基-3-苯基丁酸、2 -苯曱硫基-2-苯基乙酸、2 -苯曱硫 基-3-苯基丙酸、2-笨曱硫基-3-苯基丁酸、3-苯甲硫基- 3-苯基丁酸、下述化合物群d所示之化合物。 -22- 201232170(In the above formula (4), Z represents a single bond, a methyl group or a C 2 to 3 alkyl group, A represents a trans group, a halogen group, a alkyl group or an alkoxy group, and η represents an integer of 0 to 4, The R2 system is synonymous with the foregoing). The compound represented by the above formula (4) may, for example, be 2-hydrothio-2-phenylacetic acid, 2-hydrothio-3-phenylpropionic acid or 2-hydrothio-3-phenyl group. Butyric acid, 3-hydrothio-3-phenylbutyric acid, 2-indolylthio-2-phenylacetic acid, 2-indolylthio-3-propionic acid, 2-indolylthio-3-benzene Butyric acid, 3-nonylthio-3-phenylbutyric acid, 2-phenylthio-2-phenylacetic acid, 2-phenylthio-3-phenylpropionic acid, 2-phenylthiobutyric acid, 3-phenylthiobutyric acid, 2-phenylthio-3-phenylbutyric acid, 3-phenylthio-3-phenylbutyric acid, 2-phenylsulfonylthio-2-phenylacetic acid, 2-benzene A compound represented by the following compound group d is thiol-3-phenylpropionic acid, 2-doxinyl-3-phenylbutyric acid, 3-phenylmethylthio-3-phenylbutyric acid. -22- 201232170

COOHCOOH

[化合物群d] COOH[Compound group d] COOH

SHSH

COOHCOOH

SHSH

COOHCOOH

SHSH

SHSH

COOHAj/SCH3 COOH0LSCH3COOHAj/SCH3 COOH0LSCH3

COOHCOOH

SCH3SCH3

XOOHXOOH

[化合物（d-6)] 化合物（d-6)係由選自包含具有-OR1基之基團、具有 -SR2基之基團及具有-Q-NR3R4基之基團之群組的至少1 種與具有磺酸基之基團取代之芳香族烴或其鹽，而由進 一步抑制凝集雜質產生及對比比率降低之觀點而言，較 佳為具有選自包含-OR1基、-SR2基及-Q-NR3R4基之群組 的至少1種之芳基磺酸或其鹽。 作為化合物（d - 6 )，可例舉如鄰酌續酸、間S分績酸、 對酚磺酸、4-羥基-3-曱氧基苯磺酸、3,5-二氣-2-羥基苯 磺酸、4-羥基-1，3-苯二磺酸、5-羥基-1，3-苯二磺酸、2-羥基-7-萘磺酸、6-羥基-2-萘磺酸、4-羥基-1-萘磺酸、7-輕基-1-奈續酸、1-故基-2-奈續酸、2 -經基-1-奈橫酸、5_ 羥基-1-萘磺酸、4-羥基-2-萘磺酸、5-羥基-2-萘磺酸、8-經基-2-奈項酸、8 -經基-1-奈績酸、3 -輕基-2-蔡項酸' 3_ 輕基奈項酸、6 -輕基-1-秦績酸、7 -苯胺基-1-奈紛- 3-項酸、本基J酸（J-acid，2 -胺-5-奈盼-7-續酸）、2，4-二确基 -23- 201232170 -1 -奈酌 - 7 -石頁酸、2，4 --一石肖基-1 -奈S分-7 -石黃酸、2 -經基-4 -甲氧基二苯曱酮-5-磺酸、2,4-二硝基-1-萘酚-7-磺酸、4-ΐ^έ 基 -1 ， 5 - 奈二 續酸、 7 - 經基 -1 ， 3 - 奈二 礦酸、 2-技基-3,6-奈二續酸、1 -經基-2，3 -奈二續酸、4 -經基-1，3 -奈二項酸 、1-輕基-2,5 -奈二續酸、1-¾基-2,6 -奈二績酸、1-經基 -2，7 -奈二礦酸、8 -經基-1，7 -奈二續酸、4 -經基-1，2 -奈二 石黃酸、5-沒基-1，7-奈二續酸、1 -沒基-3，6 -奈二墙酸、4· 經基-2,6-奈二績酸、1-經基-3,8_奈二績酸、4-輕基-1，8_ 萘二磺酸、4-羥基-1，7-萘二磺酸、4-羥基-1，6-萘二磺酸 、5-經基-1，2 -奈二續酸、8 -輕基-2,4 -秦二項酸、5 -經基 -1，4 -秦二績酸、5 -經基-2,3 -奈二續酸、8 -輕基-1，3 -蔡二 續酸、8 -經基-1，2-奈二續酸、2 -經基-1，3-奈二續酸、2-經基-1，4 -奈二續酸、2 -經基-1，5-奈二續酸、2 -經基-1，6 _ 奈二續酸、2·經基-1，7 -奈二確酸、2-¾基-1，8 -奈二續酸 、3 -輕基-1,2 -奈二續酸、6 -經基-1，7 -奈二績酸、3-¾基 -2，6 -奈二績酸、7 -經基-1，6·奈二續酸、3 -經基-1，8 ·奈二 磺酸、3-羥基-1，7-萘二磺酸、3·羥基-1，6-萘二磺酸、3-罗坐基-1，5 -奈二續酸、6 -經基-1，2-秦二績酸、6_經基-1，3_ 奈二續酸、6_經基-1，4 -奈二續酸、6 -輕基-2,3 -奈二績酸 、7-羥基-1，2_萘二磺酸、鄰胺基苯磺酸、間胺基苯磺酸 、對胺基苯磺酸、鄰曱苯胺-4-磺酸、間甲苯胺-4-磺酸、 對曱苯胺-2-磺酸、鄰曱氧苯胺-5-磺酸、3-胺基-6-甲氧基 苯磺酸、2-胺基-5-曱氧基苯磺酸、4-胺基-3-曱氧基苯磺 酸、2-胺基-4- f氧基苯磺酸、3-硝基苯胺-4-磺酸、4-氣 苯胺-3-磺酸、2,5-二氯對胺基苯磺酸、4,5-二氣苯胺·2- -24- 201232170 磺酸、4-乙醯胺-2-胺基苯磺酸、4-胺基-2-氣甲苯-5-磺酸 、5 -胺基-2-氯曱本_4_績酸、3 -胺基-6-氯-4-續酸基安息 香酸、2 -胺基-1，4 -本二橫酸、2 -胺基-1，5 -苯二績酸、3 _ 胺基-1，2-苯二續酸、4 -胺基-1，2 -苯二績酸、2 -胺基-1，3-苯二續酸、5 -胺基-1，3 -苯二續酸、2 -胺基-1 -奈續酸、6_ 胺基-1 -奈續酸、I -胺基奈續酸' 8 -胺基·1-奈項酸、6 ** 胺基-2-奈績酸、4 -胺基-1-奈續酸、5 -胺基-1·蔡績酸、8-胺 基 - 2 - 奈 續酸、 5-胺基-2-奈 續酸、 2 - 胺基 - 7 - 奈 續酸、2_ 胺基-8 -奈續酸、4-胺基-2-奈續酸、3 -胺基-2-奈績酸、3_ 胺基-1 -奈項酸、2 -胺基-1，5-奈二項酸、4 -胺基-1，7-奈二 績酸、4 -胺基-1，6 -奈二項酸、1 _胺基-2，7 -奈二績酸、3 _ 胺基-1，5-秦二續酸、7 -胺基-1，3 -奈二績酸、4 -胺基-2,5· 奈二續酸、1-胺基-3,6 -蔡二績酸、3 -胺基-2,7 -茶二續酸 、6 -胺基-1，3 -奈二續酸、4 -胺基-1，5 -奈二續酸、1-胺基 -2，3-奈二續酸、4 -胺基-1，3 -奈二續酸、1-胺基-2,5 -奈二 石黃酸、1-胺基-2,6 -奈二續酸、8 -胺基-1，7 -奈二績酸、4_ 胺基-1，2-奈二續酸、4 -胺基-2,8 -蔡二績酸、4 -胺基-2,6_ 奈二續酸、4 -胺基-1，8 -奈二續酸、5 -胺基-1，2 -奈二績酸 、5 -胺基-1，3 -奈二續酸、5 -胺基-1，4 -奈二續酸、5 -胺基 -2，3 -奈二績酸、8 -胺基-1，3 -奈二確酸、8_胺基-1，2 -奈二 石黃酸、2 -胺基-1，3 -奈二橫酸、2 -胺基-1，4 -奈二績酸、2_ 胺基-1，6-奈二續酸、2 -胺基-1，7 -奈二績酸、2 -胺基-1，8_ 奈二績酸、3 -胺基-1，2 -奈二續酸、6 -胺基-1，7 -奈二績酸 、3 -胺基-2，6 -奈-一續酸、3 -胺基-2，5 -奈二績酸、3 -胺基 _1，8 -奈二績酸、3 -胺基-1，7 -奈二續酸、3 -胺基-1，6 -蔡二 -25- 201232170 石黃酸、6·胺基]，2-萘二續酸、6-胺基-i，4-萘二確酸、6 胺基-2,3_萘二續酸、7胺基]，2•萘二續酸、*(胺 )苯磺酸、4-(胺基甲基）_2_甲基1 A ^ ’ 丞本石只酸、4·氫硫基苯碍酸 、4-甲硫基苯磺酸。 K < [化合物（d-7)] 化合购)係具有缓基及雜環基，且氫原子與幾基 除外之總原子數為3〜20之化合物或其鹽而由進—+ : 制凝集雜質產生及對比比率降低之觀點而言，較佳= 有叛基、且氫原子與缓基除外之總原子數為3〜2〇(較佳^ 5〜15)之單環式雜環化合物或其鹽。 作^化合物⑷7)，可例舉如2_°夫錢酸、3·咬喃後 酸、四虱-2-0夫喃雜西参、α 複 風-3_呋喃鲮酸、噻吩-2-羧酸 、嗟吩_ 3 -缓酸、四氮。案吩2纽缺 力_竣酉夂、四氫噻吩-3 -羧酸、[Compound (d-6)] The compound (d-6) is at least 1 selected from the group consisting of a group having a group having an -OR1 group, a group having a -SR2 group, and a group having a -Q-NR3R4 group. An aromatic hydrocarbon or a salt thereof substituted with a group having a sulfonic acid group, and preferably further having a selected from the group consisting of -OR1 group, -SR2 group and - from the viewpoint of further suppressing generation of aggregated impurities and lowering of contrast ratio At least one arylsulfonic acid or a salt thereof of the group Q-NR3R4. The compound (d-6) may, for example, be an ortho-reactive acid, an intermediate S-acid, p-phenolsulfonic acid, 4-hydroxy-3-indolylbenzenesulfonic acid or 3,5-di-2- Hydroxybenzenesulfonic acid, 4-hydroxy-1,3-benzenedisulfonic acid, 5-hydroxy-1,3-benzenedisulfonic acid, 2-hydroxy-7-naphthalenesulfonic acid, 6-hydroxy-2-naphthalenesulfonic acid , 4-hydroxy-1-naphthalenesulfonic acid, 7-light-based-1-nanoic acid, 1-propenyl-2-nanoic acid, 2-cyano-1-na-transacid, 5-hydroxy-1-naphthalene Sulfonic acid, 4-hydroxy-2-naphthalenesulfonic acid, 5-hydroxy-2-naphthalenesulfonic acid, 8-carbyl-2-naphthoic acid, 8-cyano-1-nacene acid, 3-light group- 2-Cai-acid '3_ light-based naphthic acid, 6-light-based-1-hhenic acid, 7-anilino-1-na-n- 3-acid, base J acid (J-acid, 2 - Amine-5-napan-7-supply acid), 2,4-di-decyl-23-201232170 -1 - 奈 - 7 - sulphuric acid, 2,4 - monosyl group-1 - Nai S -7 -hemeic acid, 2-cyano-4-methoxybenzophenone-5-sulfonic acid, 2,4-dinitro-1-naphthol-7-sulfonic acid, 4-ΐ^έ Base-1,5-naphthalene acid, 7-mercapto-1,3-naphthalene acid, 2-technyl-3,6-naphthoic acid, 1-radio-2,3-na Continued acid, 4-carbyl-1,3-naphthoic acid, 1-light-based-2,5-na Acid, 1-3⁄4 yl-2,6-naphthoic acid, 1-transyl-2,7-naphthoic acid, 8-trans-yl-1,7-naphthoic acid, 4-cyano-1 , 2 - naphthoic acid, 5-diyl-1,7-naphthoic acid, 1-butyryl-3,6-naphedoic acid, 4·yl 2,6-naphthoic acid , 1-carbyl-3,8-nabis acid, 4-light-based-1,8-naphthalene disulfonic acid, 4-hydroxy-1,7-naphthalene disulfonic acid, 4-hydroxy-1,6-naphthalene Disulfonic acid, 5-carbyl-1,2-naphthoic acid, 8-light-based-2,4-dibasic acid, 5-cyano-1,4-dipic acid, 5-cyano-2 , 3 - naphthalene acid, 8-light base-1,3 - Cai two acid, 8-perylene-1,2-naphthalene acid, 2-cyano-1,3-naphthalene acid, 2- Meridyl-1,4-naphthoic acid, 2-butyryl-1,5-naphthoic acid, 2-radio-1,6-naphthalene acid, 2·radio-1,7-na Di-acid, 2-3⁄4 base-1,8-naphthalene acid, 3-light-group-1,2-naphthoic acid, 6-mercapto-1,7-nabene acid, 3-3⁄4 base -2,6-Nylidene acid, 7-mercapto-1,6·naphthalene acid, 3-carbyl-1,8-naphthalene disulfonic acid, 3-hydroxy-1,7-naphthalene disulfonic acid , 3·hydroxy-1,6-naphthalenedisulfonic acid, 3-rhodium-1,5-naphthalene acid, 6-mercapto-1,2-Qin Acidic acid, 6_ mercapto-1,3_naphthalene acid, 6-carbyl-1,4-naphthalene acid, 6-light-group-2,3-nabene acid, 7-hydroxy-1, 2_naphthalene disulfonic acid, o-aminobenzenesulfonic acid, m-aminobenzenesulfonic acid, p-aminobenzenesulfonic acid, o-anisidine-4-sulfonic acid, m-toluidine-4-sulfonic acid, p-anisidine- 2-sulfonic acid, o-nonylaniline-5-sulfonic acid, 3-amino-6-methoxybenzenesulfonic acid, 2-amino-5-nonyloxybenzenesulfonic acid, 4-amino-3- Phenoxybenzenesulfonic acid, 2-amino-4-foxybenzenesulfonic acid, 3-nitroaniline-4-sulfonic acid, 4-airaniline-3-sulfonic acid, 2,5-dichloro-p-amine Alkylbenzenesulfonic acid, 4,5-di-aniline, 2--24- 201232170 sulfonic acid, 4-acetamido-2-aminobenzenesulfonic acid, 4-amino-2-gastoluene-5-sulfonic acid , 5-amino-2-chloroindole _4_ acid, 3-amino-6-chloro-4-supply acid benzoic acid, 2-amino-1,4-di-di-acid, 2- Amino-1,5-benzenedicarboxylic acid, 3_amino-1,2-benzenedicarboxylic acid, 4-amino-1,2-benzoic acid, 2-amino-1,3-benzene Dihydro acid, 5-amino-1,3-benzenedicarboxylic acid, 2-amino-1 -nanoic acid, 6-amino-1 -nanoic acid, I-aminoneptanoic acid '8-amine Base·1-naphthoic acid, 6 ** Amino-2-Nan , 4-amino-1-n-propionic acid, 5-amino-1-caco acid, 8-amino-2-n-nanoic acid, 5-amino-2-n-propionic acid, 2-amino group- 7 - n-acid, 2_amino-8-nanoic acid, 4-amino-2-n-acid, 3-amino-2-naic acid, 3-amino-1-naphthoic acid, 2 - Amino-1,5-naphedoic acid, 4-amino-1,7-naphthoic acid, 4-amino-1,6-naphthoic acid, 1 -amino-2,7-na Dibasic acid, 3 _ amino-1,5-hominic acid, 7-amino-1,3-naphthoic acid, 4-amino-2,5·naphthalene acid, 1-amino group -3,6 - Cai Erji acid, 3-amino-2,7-tea diacid, 6-amino-1,3-naphthalene acid, 4-amino-1,5-naphthalene acid, 1-amino-2,3-naphthoic acid, 4-amino-1,3-naphthoic acid, 1-amino-2,5-naphthoic acid, 1-amino-2, 6-naphthalene acid, 8-amino-1,7-naphthoic acid, 4_amino-1,2-naphthoic acid, 4-amino-2,8-cai-di-acid, 4-amino group -2,6_ naphthalene acid, 4-amino-1,8-naphthalene acid, 5-amino-1,2-naphthoic acid, 5-amino-1,3-naphthoic acid , 5-amino-1,4-naphthoic acid, 5-amino-2,3-naphthoic acid, 8-amine -1,3 -nadicarboxylic acid, 8-amino-1,2-naphthoic acid, 2-amino-1,3-nadanedioic acid, 2-amino-1,4-na Acidic acid, 2_amino-1,6-naphthalene acid, 2-amino-1,7-naphthoic acid, 2-amino-1,8-nabene acid, 3-amino-1, 2-naphthalene acid, 6-amino-1,7-naphthoic acid, 3-amino-2,6-naphthyl-acid, 3-amino-2,5-naphthic acid, 3-amino-1,8-naphthoic acid, 3-amino-1,7-naphthalene acid, 3-amino-1,6-cai-25-201232170 Rhein, hexamine Base, 2-naphthalene dihydro acid, 6-amino-i,4-naphthalene diacid, 6-amino-2,3-naphthalene diacid, 7-amino], 2 • naphthalene diacid, * (Amine) benzenesulfonic acid, 4-(aminomethyl)_2-methyl 1 A ^ ' 丞 石 stone only acid, 4 thiol benzoic acid, 4-methyl thiobenzene sulfonic acid. K < [compound (d-7)] is a compound having a sulfhydryl group and a heterocyclic group and having a total atomic number of 3 to 20 excluding a hydrogen atom and a few groups, or a salt thereof, From the viewpoint of generation of agglomerated impurities and reduction of the contrast ratio, it is preferred to have a monocyclic heterocyclic compound having a total number of atoms other than a hydrogen atom and a slow group of 3 to 2 Å (preferably 5 to 15). Or its salt. The compound (4) 7) can be exemplified by 2_°funic acid, 3·biting acid, tetraterpene-2-0-fusan, ginseng-3_furanic acid, thiophene-2-carboxylate Acid, porphin _ 3 - acid retardant, tetranitrogen. Case No. 2 New Strength _竣酉夂, tetrahydrothiophene-3-carboxylic acid,

COOH 於驗於驗酸、下述化合物。COOH was tested for acid and the following compounds.

.Ν SH.Ν SH

[化合物 化合物(d-8)係具有磺酸基及 酸基除外之總原子數為3心之化=且虱原子與= 步抑制凝集雜質產决 或/、鹽，而由進 為具有續酸基且Λ對比比率降低之觀點而言，較佳 3〜2〇(較佳為5 J虱原子與續酸基除外之總原子數為 U:二:環式雜環化合物或其鹽。 。物㈣)，可例舉如2-呋喃磺酸、3_fl夫喃磺 -26- 201232170 酸、四氫-2-呋喃磺酸、四氬_3_呋喃磺酸、噻吩_2_磺酸 、噻吩-3-磺酸、四氫噻吩-2-磺酸、四氫噻吩_3_磺酸、 吡啶-3-磺酸、吡啶-4-磺酸、下述化合物。 -〇3^"^s〇3- 本發明中，（D)特定化合物可單獨或2種以上混合使 用》 本發明中（D)特疋化合物的含量相對（A)著色劑i 〇〇 質量，較佳為0.^30質量份，特佳為丨〜1〇質量份。此時 ，（D)特定化合物的含量若過少，會有無法獲得所要之效 果之虞，另-方面若過多’則有形成之著色層在鹼性顯 影時容易由基板脫落之傾向。 -(E)分散劑- 本發明中㈣_作為著色料，可視f求使用⑻ 分散劑。作為（E)分散劑可使用陽離子系、陰離子系、非 離子系等的適當分散劑，惟以含有胺價（單位mgK〇H/g， 下同）為5以上之分散劑（以下有稱為「特定分散劑」）為佳 。此因兹認為使（D)特定化合物中的缓基、績酸基等與特 定分散劑互相作用’可提高著色組成物的保存穩定：。 =此，胺價係表示中和分散劑固體含量lg所需之酸與當 $之ICOH的mg數。 特定分散劑之胺價在使微粒化金屬錯合物顏料穩定 分散之意義上，較佳為1〇mgK〇H/g以上，特佳為7〇mg K〇H/g以上。另一方面，特定分散劑之胺價在確保著色 -27- 201232170 組成物之鹼性顯影性之意義上，則較佳為2〇〇mgK〇H/g 以下，特佳為150mgKOH/g以下。 特疋分散劑更佳為含有具有表現胺價之鹼性基團的 聚合物鏈、與不具有鹼性基團之聚合物鏈的共聚物。作 為所述特定分散劑，可例舉如嵌段共聚物型分散劑、接 枝共聚物型分散劑等。作為嵌段共聚物型分散劑，較佳 為由嵌段A與嵌段B構成的AB嵌段共聚物或BAB嵌段共 聚物，該嵌段A係具備來自（二烷基）胺基烷基（甲基）丙烯 酸酯等具有鹼性基團之（曱基）丙烯酸酯的重複單位，該 嵌奴B則具備來自具有烷基、芳基、芳烷基、聚己内酯構 造、聚_構造等之（甲基）丙烯酸酯的重複單位。且，作 為接枝共聚物型分散劑較佳為以聚（伸烷基醯亞胺）、聚（ 烯丙基胺）等為聚合物主鏈，且由所述聚合物主鏈的一或 多處分支有聚己内酯鏈、聚醚鏈等的接枝共聚物。 此種敗段共聚物型或接枝共聚物型特定分散劑可於 市面上購付，可例舉如DisPerbyk-2000(不揮發成分=40〇/〇 胺 4貝 4mgKOH/g，Βγκ公司製）、Disperbyk-2001(不揮[Compound compound (d-8) is a compound having a sulfonic acid group and an acid group, and the total number of atoms is 3 cents = and the ruthenium atom and the step inhibit the agglomerated impurities, or the salt, and the acid has a continuous acid. From the viewpoint of a reduction in the ratio of the ruthenium ratio, it is preferably 3 to 2 Å (preferably, the total number of atoms excluding the 5 J 虱 atom and the carboxylic acid group is U: 2: a cyclic heterocyclic compound or a salt thereof). (d)), for example, 2-furansulfonic acid, 3_flf-sulfonyl-26-201232170 acid, tetrahydro-2-furansulfonic acid, tetra-argon-3-furansulfonic acid, thiophene-2-sulfonic acid, thiophene- 3-sulfonic acid, tetrahydrothiophene-2-sulfonic acid, tetrahydrothiophene_3_sulfonic acid, pyridine-3-sulfonic acid, pyridine-4-sulfonic acid, the following compound. - 〇3^"^s〇3- In the present invention, (D) the specific compound may be used singly or in combination of two or more kinds. In the present invention, the content of the (D) special compound is relative to (A) the color of the coloring agent i 〇〇 Preferably, it is 0.^30 parts by mass, particularly preferably 丨~1〇 parts by mass. In this case, if the content of the (D) specific compound is too small, the desired effect may not be obtained, and if the amount is too large, the colored layer formed tends to fall off from the substrate when it is alkaline. - (E) Dispersant - In the present invention (4) _ as a coloring material, it is possible to use (8) a dispersing agent. As the (E) dispersing agent, a suitable dispersing agent such as a cationic type, an anionic type, or a nonionic type can be used, but a dispersing agent containing an amine valence (unit: mgK〇H/g, the same below) of 5 or more (hereinafter referred to as "Specific dispersant" is preferred. This reason is considered to promote the storage stability of the coloring composition by allowing the slow group, the acid group, and the like in the (D) specific compound to interact with a specific dispersing agent. = This, the amine valence represents the acid required to neutralize the solids content of the dispersant lg and the number of mg of ICOH. The amine valence of the specific dispersant is preferably 1 〇 mg K 〇 H / g or more, particularly preferably 7 〇 mg K 〇 H / g or more, in the sense of stably dispersing the microparticulate metal complex pigment. On the other hand, the amine valence of the specific dispersing agent is preferably 2 〇〇 mg K 〇 H / g or less, and particularly preferably 150 mg KOH / g or less in the sense of ensuring the alkali developability of the coloring composition of -27 to 201232170. The terpene dispersant is more preferably a copolymer having a polymer chain having a basic group exhibiting an amine value and a polymer chain having no basic group. The specific dispersant may, for example, be a block copolymer type dispersant or a graft copolymer type dispersant. As the block copolymer type dispersant, an AB block copolymer or a BAB block copolymer composed of a block A and a block B having a (dialkyl)aminoalkyl group is preferable. a repeating unit of a (meth) acrylate having a basic group such as a (meth) acrylate, which has an alkyl group, an aryl group, an aralkyl group, a polycaprolactone structure, and a poly-structure. The repeating unit of the (meth) acrylate. Further, as the graft copolymer type dispersant, poly(alkyleneimine), poly(allylamine) or the like is preferably used as a polymer main chain, and one or more of the polymer main chain is used. A graft copolymer of a polycaprolactone chain, a polyether chain or the like is branched at the branch. Such a dispersing copolymer type or a graft copolymer type specific dispersing agent can be commercially available, and may be, for example, DisPerbyk-2000 (nonvolatile content = 40 〇 / decylamine 4 lb 4 mg KOH / g, manufactured by Β γ κ) , Disperbyk-2001 (do not wave

發成分=46%，胺價=19mgK〇H/g，Βγκ公司製）、BYK LpN 6919(不揮發成分=60〇/〇，胺價=72mgKOH/g，BYK公司製 )BYK-LPN21116(不揮發成分=4〇%，胺價=29mgK〇H/g ，BYK公司製）等。 特定分散劑可單獨或2種以上混合使用。 ^本發明中’可與分散劑共同使用分散助劑。作為分 政助劑可例舉如顏料衍生物，具體可例舉銅酞菁素、吡 各并tb咯一酮、喹啉黃之磺酸衍生物等。 -28- 201232170 (E)分散劑的含I h t , A 里相對（A)著色劑loo質量 1 00皙昙认本，. 只里份， 為 〇.5〜1〇0質量份，更佳為1〜7〇質量份，特佳為：較佳 份。此時，分散劑的含量若過多，則 、，質襲 之虞。 ^生_影性 -(F)光聚合起始齊| _ 本發明著色性組成物中可使之含有（F)光 劑。由此，便可賦予著色組成物感放射線性。，合起始 使用的（F)光聚合起始劑為一化合物，其可透$發明所 ’可見光綠 、紫外線、遠紫外線、電子線、X線等放射線的曝光而產 生可起始上述（C)交聯劑之聚合的活性物種。 作為此種光聚合起始劑，可例舉如噻噸酮系化合物 、苯乙酮系化合物、雙味嗤系化合物、三_系化合物、 〇-醯肟系化合物 '鏽鹽系化合物、安息香系化合物、二 本曱_系化合物、α _二酮系化合物、多核酿系化合物、 二偶氮系化合物、醯亞胺磺酸鹽系化合物、鏽鹽系化合 物等。 本發明中，光聚合起始劑可單獨或2種以上混合使用 。作為光聚合起始劑，較佳為選自噻噸酮系化合物、苯 乙鲖系化合物、雙咪唑系化合物、三啩系化合物、0_醯 肪系化合物之群組的至少1種。 本發明之較佳光聚合起始劑當中，作為噻噸酮系化 合物之具體實例，可例舉噻噸酮、2-氣噻噸酮、2-曱基 °塞°頓_、2 -異丙基嗟噸酮、4 -異丙基嘆嘲酮、2，4 -二氯°塞 噸酮、2,4-二甲基噻噸酮、2,4-二乙基噻噸酮、2,4-二異 丙基°塞嘲酮等。 -29- 201232170 又作為上述苯乙朗I系化合物之具體實例，可例舉2 甲基- 硫基）苯基]-2 -咪福琳丙貌- 同、2_苯f基 -2 -二尹胺基-1-(4 -味福#苯基）丁貌-i_酮、2_(4_甲基苯γ 基）-2-(二甲胺基）-1-(4-咮福啉苯基）丁烷酮等。 再作為上述雙咪唑系化合物之具體實例，可例舉 2,2’ -雙（2-氯苯基）-4,4’，5,5’-四苯基_丨，2，_雙σ米嗤、2,2, 雙（2,4-二氯苯基）-4,4’，5,5’-四苯基_1，2，_雙0米0坐、2 2，· 雙（2,4,6 -三氯苯基）-4,4’，5,5’-四苯基_1，2，_雙〇米β坐等。 此外，使用雙咪唑系化合物作為光聚合起始劑時可併 用氫供體，如此’由可改良感度之觀點而言係較佳。此處 所谓「虱供體」係指可對經曝光而由雙咪唾系化合物產生 之自由基提供氫原子之化合物。作為氫供體可例舉如2_氫 硫基苯并噻唑、2-氫硫基苯并嘮唑等硫醇系氫供體、4,4，_ 雙（二甲胺基）二苯甲酮、4,4，_雙（二乙胺基）二苯曱酮等胺 系氫供體。本發明中，氫供體可單獨或2種以上混合使用 ，惟組合使用1種以上硫醇系氩供體與丨種以上胺系氫供體 時’由可進一步改良感度之觀點而言係較佳。 再者，作為上述三啩系化合物之具體實例，可例舉 2,4,6-三（三氯甲基）_s_三听、2_甲基_4,6_雙（三氣曱基^ 三啡、2-[2-(5-曱基呋喃-2-基）乙烯基卜4,6_雙（三氣曱基 )-s-二啩、2-[2-(呋喃-2-基）乙烯基]_46雙（二 三听、卿二乙胺基苯基)乙稀基(二 甲，）-s-三听、2_[2-(3,4-二甲氧基苯基）乙稀基]_4,6雙（ 二氯曱基）-s-三汫、2-(4-甲氧基苯基）_4,6_雙（三氣甲美 )-s-三啩、2-(4-乙氧基苯乙烯基）_4,6_雙（三氣曱基卜％二 -30- 201232170 啩、2-(4-正丁氧基苯基）-4,6-雙（三氣曱基）-S-三啩等具有 鹵代曱基之三啩系化合物。 又作為0-醯肟系化合物之具體實例，可例舉丨，2-辛 二鲷，1-[4-(笨硫基）苯基]-，2-(〇-苯曱醯月亏）、乙銅，1_[9一 乙基- 6- (2-曱基苯曱醯基）-9H-。卡。坐-3-基]-，l-(〇 -乙醢月亏） 、乙酮，1-[9 -乙基- 6-(2 -甲基-4-四氫呋喃曱氧基苯甲醯基 )-9H -味咬-3-基]-，l-(〇-乙醯辟）、乙酮，ι_[9-乙基_6_{2_曱 基-4-(2，2-二曱基-1，3-二草烷基）曱氧基苯甲醯基卜9H_ 味°坐-3-基-乙酿月亏）等。 本發明中，當使用苯乙酮系化合物等 叉u不0生糸1匕兮 物以外之光聚合起始劑時，可併用敏化劑。作為此種敏 化劑，可例舉如4,4，-雙（二曱胺基）二苯甲酮、4,4，_雙（二 乙胺基）二苯曱酮、4-二乙胺基苯乙酮、4-二甲胺基苯丙 酮、4-二甲胺基笨甲酸乙酯、4_二甲胺基苯曱酸2_乙基己 酯、2,5-雙（4-二乙胺基亞苄基）環己酮、7二乙胺基_3_(心 二乙胺基苯甲醯基）香豆素、4_(二乙胺基）查耳酮等。 本發月中，光聚合起始劑的含量相對（C)交聯劑1 〇〇 質量份，較佳為〇.01〜12〇質量份，特佳為卜丨㈧質量份。 此時’光聚合起始劑的含晉泣、典，卜 . 叫J 3里右過少，會有曝光所致之硬 化不完全之虞，另一古z从 方面右過多’則有形成之著色層在 顯影時容易由基板脫落之傾向。 _(〇)溶劑- =日月著色組成物係含有上述⑷〜（d)成分、及㈣ 添加的其他成分，但搞a w ㊉係摻混溶劑而調製為液狀組4 物0 -31- •201232170 作為上述溶劑只要可分散或溶解構成著色組成物的 (A)〜（D)成分或其他成分、不與此等成分並具有適度的揮 發性，則可適當選擇使用。 作為此種溶劑可例舉如乙二醇單曱醚、乙二醇單乙 醚、乙二醇單正丙醚、乙二醇單正丁醚、二乙二醇單曱 醚、二乙二醇單***、二乙二醇單正丙醚、二乙二醇單 正丁醚、三乙二醇單曱醚、三乙二醇單***、丙二醇單 曱醚、丙二醇單***、丙二醇單正丙醚、丙二醇單正丁 醚、二丙二醇單甲醚、二丙二醇單***、二丙二醇單正 丙醚、二丙二醇單正丁醚、三丙二醇單曱醚、三丙二醇 單***等之（聚）伸烷基二醇單烷基醚類； 乳酸甲酯、乳酸乙酯等之乳酸烷基酯類；曱醇、乙 醇、丙醇、丁醇、異丙醇、異丁醇、三級丁醇、辛醇、 2- 乙基己醇、環己醇等之（環）烷醇類；二丙酮醇等之酮醇 類； 乙二醇單曱醚乙酸酯、乙二醇單***乙酸酯、乙二 醇單正丙醚乙酸酯、乙二醇單正丁醚乙酸酯、二乙二醇 單曱醚乙酸酯、二乙二醇單***乙酸酯、二乙二醇單正 丙醚乙酸酯、二乙二醇單正丁醚乙酸酯、丙二醇單曱醚 乙酸酯、丙二醇單***乙酸酯、3 -曱氧基丁基乙酸酯、 3- 曱基-3-曱氧基丁基乙酸酯等之（聚）伸烷基二醇單烷基 醚乙酸酯類； 二乙二醇二甲醚、二乙二醇甲基***、二乙二醇二 ***、四氫呋喃等之其他醚類； 甲乙酮、環己酮、2 -庚酮、3 -庚酮等之酮類； -32- 201232170 丙二醇二乙酸酯、1，3-丁二醇二乙酸酯、1,6 -己二醇 二乙酸酯等之二乙酸酯類； 3 -曱氧基丙酸曱酯、3 -曱氧基丙酸乙酯'3 -乙氧基丙 酸曱酯、3 -乙氧基丙酸乙酯、乙氧基乙酸乙酯、3 -曱基- 3-甲氧基丁基丙酸酯等之烷氧基羧酸酯類； 乙酸乙酯、乙酸正丙酯、乙酸異丙酯、乙酸正丁酯 、乙酸異丁酯、曱酸正戊酯、乙酸異戊酯、3 -曱氧基丁 基乙酸酯、3 -甲基-3 -曱氧基丁基乙酸酯、丙酸正丁酯、 3 -曱氧基丁基乙酸酯、3 -甲基-3 -曱氧基丁基丙酸酯、丁 酸乙酯、丁酸正丙酯、丁酸異丙酯、丁酸正丁酯、乙基 乙二醇酯、乙氧基乙酸乙酯、3 -曱氧基丙酸甲酯、3 -曱 氧基丙酸乙酯、3 -乙氧基丙酸曱酯、3 -乙氧基丙酸乙酯 、丙酮酸曱酯、丙酮酸乙酯、丙酮酸正丙酯、乙醯乙酸 曱酯、乙醯乙酸乙酯、2 -羥基-2 -曱基丙酸乙酯、2 -羥基 -3-曱基丁酸曱酯、2-氧代丁酸乙酯等之其他酯類； 曱苯、二曱苯等之芳香族烴類； Ν,Ν-二曱基甲醯胺、Ν,Ν-二甲基乙醯胺、N-曱基吡 咯烷酮等之醯胺或内醯胺類等。 此等溶劑中，由溶解性、顏料分散性、塗布性等觀 點而言，係以丙二醇單曱醚、丙二醇單***、乙二醇單 曱醚乙酸酯、丙二醇單曱醚乙酸酯、丙二醇單***乙酸 酯、3 -曱氧基丁基乙酸酯、二乙二醇二曱醚、二乙二醇 曱基***、環己酮、2-庚酮、3-庚酮、1，3 -丁二醇二乙酸 酯、1，6 -己二醇二乙酸酯、乳酸乙酯、3 -曱氧基丙酸乙酯 、3 -乙氧基丙酸曱酯、3 -乙氧基丙酸乙酯、3 -曱基-3 -曱 -33- .201232170 氧基丁基丙酸酯、乙酸正丁酯、乙酸異丁酯、甲酸正戊 酯、乙酸異戊酯、丙酸正丁酯、丁酸乙酯、丁酸異丙酯 、丁酸正丁酯、丙酮酸乙酯等為佳。 本發明中溶劑可單獨或混合兩種以上使用。 溶劑的含量並未特別限定，但由所得之著色性組成 物的塗布性、敎性等觀點而言，除該著色性組成物的 溶劑以外的各成分的總濃度較佳為5〜5〇質量％的量特 佳為10〜40質量％的量。 -添加劑- 本發明著色組成物可視需求含有各種添加劑。 作為添加劑，可例舉如玻璃、氧化鋁等之填充劑； 聚乙烯醇、聚（氟烷基丙烯酸酯）類等高分子化合物；氟 系界面活性劑、矽系界面活性劑等之界面活性劑；乙烯 基一曱氧基矽烧、乙烯基三乙氧基矽燒、乙烯基三（2·甲 氧基乙氧基）矽烷、N-(2-胺乙基）-3-胺基丙基曱基二甲氧 基矽烷、N-(2-胺乙基）-3-胺基丙基三甲氧基矽烷、3_胺 基丙基三乙氧基矽烷、3-環氧丙氧基丙基三曱氧基矽烷 氧丙氧基丙基甲基二甲氧基石夕貌、2_(3,4-環氧環 己基）乙基二曱氧基石夕院、3 -氣丙基甲基二甲氧基石夕烧、 3 -氯丙基三曱氧基石夕炫、3 -甲基丙烯隨氧基丙基三甲氧 基石夕烷、3-氫硫基丙基三曱氧基矽烷等之密著促進劑； 2’2-硫基雙（4-甲基-6-三級丁基酚）、2,6-二-三級丁基紛等 之抗氧化劑，2-(3-三級丁基-5 -甲基-2 -經笨基）_5_氯苯并 一上、烧氧基一本甲酮類荨之紫外線吸收劑；聚丙稀酸 納等之抗凝集劑；丙二酸、己二酸、伊康酸、轉康酸、 -34- 201232170 富馬酸、中康酸、2-胺基乙醇、3_胺基_卜丙醇、5_胺基 -1-戊醇、3-胺基_ι，2-丙二醇、2_胺基_i，3_丙二醇、4胺 基_1，2-丁二醇等之殘渣改善劑等；單[2 (曱基）丙烯醯氧 基乙基]琥珀酸酯、單[2-(甲基）丙烯醯氧基乙基]鄰苯二 甲酸醋、ω-幾基聚己内酯單（甲基）丙烯酸酯等之顯影性 改善劑；日本特開2008-242078號公報等所揭示之具有反 應性官能基之矽氧烷寡聚物等。 本發明著色組成物可由適當方法來調製，作為其調 製方法，例如可將（Α)〜（D)成分與（G)溶劑、任意添加的 其他成分共同混合來調製。當使用顏料作為（Α)著色劑時 ，較佳為將顏料在（G)溶劑中、（幻分散劑的存在下，視 情況與（Β)成分的一部分，利用例如珠磨機、輥磨機等粉 碎並混合、分散而製成顏料分散液，次之對該顏料分散 液添加（Β)〜（C)成分、及視需求而進一步追加之溶劑、其 他成分並予以混合來調製之方法。此時，（D)特定化合物 可於调製顏料分散液時添加、或在調製顏料分散液後， 混合顏料分散液與剩餘成分時添加。 [彩色濾光片及其製造方法] 本發明彩色渡光片係具備使用本發明著 形成之著色層。 作為製造彩色濾光片之方法第一可例 一可例舉以下方法。 板表面上，視需求以劃分形成有畫素之部分Hair component = 46%, amine price = 19 mg K 〇 H / g, manufactured by Β γ κ, BYK LpN 6919 (nonvolatile content = 60 〇 / 〇, amine price = 72 mg KOH / g, manufactured by BYK) BYK-LPN 21116 (nonvolatile Ingredients = 4% by weight, amine price = 29 mg K 〇 H / g, manufactured by BYK Co., Ltd., and the like. The specific dispersing agents may be used singly or in combination of two or more kinds. In the present invention, a dispersing aid can be used together with a dispersing agent. The pigmentary derivative may, for example, be a pigment derivative, and specific examples thereof include copper phthalocyanine, pyridyl tb-mono-ketone, and quinoline yellow sulfonic acid derivative. -28- 201232170 (E) Dispersant containing I ht , A relative to (A) colorant loo quality 1 00 皙昙 recognition, only aliquots, 〇.5~1〇0 parts by mass, more preferably 1 to 7 〇 parts by mass, particularly preferably: preferred parts. In this case, if the content of the dispersant is too large, the quality of the dispersant may be affected. ^生_影性 - (F) Photopolymerization Start | | The coloring composition of the present invention may contain (F) a light agent. Thereby, the coloring composition can be imparted with radiation linearity. The (F) photopolymerization initiator used as a starting compound is a compound which can be formed by exposure of radiation of visible light green, ultraviolet light, far ultraviolet light, electron beam, X-ray or the like of the invention. The active species of the polymerization of the crosslinking agent. The photopolymerization initiator may, for example, be a thioxanthone compound, an acetophenone compound, a disaccharide-based compound, a tri-based compound, an anthraquinone-based compound, a rust salt compound or a benzoin system. a compound, a diterpene-based compound, an α-diketone-based compound, a polynuclear brewing compound, a diazo compound, a quinone sulfonate compound, a rust salt compound, and the like. In the present invention, the photopolymerization initiator may be used singly or in combination of two or more kinds. The photopolymerization initiator is preferably at least one selected from the group consisting of a thioxanthone compound, a phenethyl quinone compound, a biimidazole compound, a triterpenoid compound, and an oxo compound. Among the preferred photopolymerization initiators of the present invention, as specific examples of the thioxanthone-based compound, a thioxanthone, a 2-oxethione, a 2-hydrazino group, a 2-isopropyl group can be exemplified. Ketoxanone, 4-isopropyl succinone, 2,4-dichlorooxone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, 2,4 - Diisopropyl ° zebradine and the like. -29- 201232170 Further, as a specific example of the above-mentioned phenethylamine I-based compound, 2 methyl-thio)phenyl]-2-mifolin-propyl-form, 2-phenylene-f-group-2-di-yin Amino-1-(4--Fufu#phenyl)butyrene-i-ketone, 2-(4-methylphenylyl)-2-(dimethylamino)-1-(4-indolinphyrin benzene Base) butanone and the like. Further, as a specific example of the above biimidazole-based compound, 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-indole, 2,_double sigma meter can be exemplified.嗤, 2, 2, bis(2,4-dichlorophenyl)-4,4',5,5'-tetraphenyl_1,2,_double 0 m 0 sitting, 2 2, · double (2 , 4,6-trichlorophenyl)-4,4',5,5'-tetraphenyl-1,2,_bi-p-methane beta. Further, when a bisimidazole compound is used as a photopolymerization initiator, a hydrogen donor can be used in combination, and thus it is preferable from the viewpoint of improving sensitivity. Here, the "ruthenium donor" means a compound which can supply a hydrogen atom to a radical generated by a double-micro-salt compound by exposure. The hydrogen donor may, for example, be a thiol-based hydrogen donor such as 2-hydrothiobenzothiazole or 2-hydrothiobenzoxazole, or 4,4,-bis(dimethylamino)benzophenone. An amine-based hydrogen donor such as 4,4,_bis(diethylamino)benzophenone. In the present invention, the hydrogen donor may be used singly or in combination of two or more kinds, but when one or more kinds of thiol-based argon donors and hydrazine-based amine-based hydrogen donors are used in combination, 'from the viewpoint of further improving the sensitivity good. Further, as a specific example of the above triterpenoid compound, 2,4,6-tris(trichloromethyl)_s_triodecan, 2-methyl-4,6-bis (trioxanyl group) can be exemplified. Trimorphine, 2-[2-(5-fluorenylfuran-2-yl)vinyl b 4,6-bis(triseodecyl)-s-diindole, 2-[2-(furan-2-yl) )vinyl]_46 bis (secondary listen, qingdiethylaminophenyl) ethylidene (dimethyl,)-s-triple, 2_[2-(3,4-dimethoxyphenyl) Dilute base]_4,6 bis(dichloroindenyl)-s-triterpene, 2-(4-methoxyphenyl)_4,6_bis (three gas carbamide)-s-triterpene, 2-( 4-ethoxystyryl)_4,6_double (three gas 曱 卜 %% -30- 201232170 啩, 2-(4-n-butoxyphenyl)-4,6-bis (three gas 曱A triterpenoid compound having a halogenated fluorenyl group, such as a group, a sulfonium group, etc. Further, as a specific example of the 0-fluorene-based compound, hydrazine, 2-octanediamine, 1-[4-(stupyl sulfur) can be exemplified. Phenyl]-, 2-(〇-benzoquinone), copper, 1_[9-ethyl-6-(2-mercaptophenyl)-9H-. Card. -yl]-,l-(〇-乙醢月亏), ethyl ketone, 1-[9-ethyl-6-(2-methyl-4-tetrahydrofuranyloxybenzylidene)-9H-flavor Bite-3-yl]-, L-(〇-乙醯辟), ethyl ketone, ι_[9-ethyl_6_{2_mercapto-4-(2,2-dimercapto-1,3-dioxaalkyl) decyloxy In the present invention, when a photopolymerization initiator other than a acetophenone-based compound or the like is used, a photopolymerization initiator other than the acetophenone-based compound is used. A sensitizer may be used in combination. As such a sensitizer, for example, 4,4,-bis(diamidoamino)benzophenone, 4,4,-bis(diethylamino)diphenylhydrazine may, for example, be mentioned. Ketone, 4-diethylaminoacetophenone, 4-dimethylaminopropiophenone, 4-dimethylaminoethyl benzoate, 4-dimethylaminobenzoic acid 2-ethylhexyl ester, 2, 5-bis(4-diethylaminobenzylidene)cyclohexanone, 7-diethylamino _3_(diethylaminobenzimidyl)coumarin, 4-(diethylamino)chalcone In the present month, the content of the photopolymerization initiator is preferably 〇.01 to 12 〇 parts by mass, and particularly preferably 丨 (eight) parts by mass, based on 1 part by mass of the crosslinking agent (C). 'The photopolymerization initiator contains Jinqi, Dian, Bu. It is called J 3, the right is too small, there will be incomplete hardening caused by exposure, another ancient z from the aspect of too much 'is formed The color layer tends to be detached from the substrate during development. _(〇) Solvent-=The sun and moon coloring composition contains the above-mentioned components (4) to (d) and (iv) other components added, but the awant ten-based blending solvent Preparation into a liquid group 4 material 0 - 31 - • 201232170 As the above solvent, as long as it can disperse or dissolve the components (A) to (D) constituting the coloring composition or other components, and does not have moderate volatility with these components, You can choose to use it as appropriate. The solvent may, for example, be ethylene glycol monoterpene ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol monoterpene ether or diethylene glycol alone. Ether, diethylene glycol mono-n-propyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monoterpene ether, triethylene glycol monoethyl ether, propylene glycol monoterpene ether, propylene glycol monoethyl ether, propylene glycol mono-n-propyl ether, Propylene glycol mono-n-butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, tripropylene glycol monoterpene ether, tripropylene glycol monoethyl ether, etc. Alcohol monoalkyl ethers; alkyl lactate such as methyl lactate or ethyl lactate; decyl alcohol, ethanol, propanol, butanol, isopropanol, isobutanol, tertiary butanol, octanol, 2 - (cyclo)alkanols such as ethylhexanol and cyclohexanol; ketols such as diacetone alcohol; ethylene glycol monoterpene ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol single N-propyl ether acetate, ethylene glycol mono-n-butyl ether acetate, diethylene glycol monoterpene ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol single Propyl ether acetate, diethylene glycol mono-n-butyl ether acetate, propylene glycol monoterpene ether acetate, propylene glycol monoethyl ether acetate, 3-methoxybutyl acetate, 3-mercapto-3 a (poly)alkylene glycol monoalkyl ether acetate such as decyloxybutyl acetate; diethylene glycol dimethyl ether, diethylene glycol methyl ether, diethylene glycol diethyl ether, Other ethers such as tetrahydrofuran; ketones such as methyl ethyl ketone, cyclohexanone, 2-heptanone, and 3-heptanone; -32- 201232170 propylene glycol diacetate, 1,3-butanediol diacetate, 1 , diacetate such as 6-hexanediol diacetate; 3 - decyloxy propionate, 3 - methoxy propionate ethyl 3'-ethoxypropionate, 3-B Alkoxycarboxylates such as ethyl oxypropionate, ethyl ethoxyacetate, 3-mercapto-3-methoxybutylpropionate; ethyl acetate, n-propyl acetate, acetic acid Propyl ester, n-butyl acetate, isobutyl acetate, n-amyl decanoate, isoamyl acetate, 3-decyloxybutyl acetate, 3-methyl-3-decyloxybutyl acetate , n-butyl propionate, 3-methoxybutyl acetate, 3-methyl-3-decyloxy Butyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl glycol ester, ethyl ethoxyacetate, 3-methoxyoxypropionic acid Methyl ester, ethyl 3-methoxyoxypropionate, decyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, decyl pyruvate, ethyl pyruvate, n-propyl pyruvate, B Other esters such as decyl acetate, ethyl acetate, ethyl 2-hydroxy-2-mercaptopropionate, 2-hydroxy-3-indolyl decanoate, ethyl 2-oxobutanoate An aromatic hydrocarbon such as toluene or diphenylbenzene; anthracene or indoleamine such as hydrazine, hydrazine-dimercaptomethylamine, hydrazine, hydrazine-dimethylacetamide or N-decylpyrrolidone; Wait. Among these solvents, propylene glycol monoterpene ether, propylene glycol monoethyl ether, ethylene glycol monoterpene ether acetate, propylene glycol monoterpene ether acetate, and propylene glycol are used from the viewpoints of solubility, pigment dispersibility, and coating properties. Monoethyl ether acetate, 3-methoxybutyl butyl acetate, diethylene glycol dioxime ether, diethylene glycol decyl ether, cyclohexanone, 2-heptanone, 3-heptanone, 1,3 - Butanediol diacetate, 1,6-hexanediol diacetate, ethyl lactate, ethyl 3-methoxyoxypropionate, decyl 3-ethoxypropionate, 3-ethoxyl Ethyl propionate, 3-indolyl-3-indole-33-.201232170 oxybutyl propionate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, n-butyl propionate Ester, ethyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl pyruvate, etc. are preferred. In the present invention, the solvent may be used singly or in combination of two or more. The content of the solvent is not particularly limited, but the total concentration of each component other than the solvent of the coloring composition is preferably 5 to 5 Å by mass from the viewpoints of coatability and enthalpy of the obtained color-developing composition. The amount of % is particularly preferably an amount of 10 to 40% by mass. - Additive - The colored composition of the present invention may contain various additives as needed. The additive may, for example, be a filler such as glass or alumina; a polymer compound such as polyvinyl alcohol or poly(fluoroalkyl acrylate); a surfactant such as a fluorine-based surfactant or a lanthanoid surfactant; Vinyl-methoxy oxime, vinyl triethoxy oxime, vinyl tris(2.methoxyethoxy)decane, N-(2-aminoethyl)-3-aminopropyl Mercapto dimethoxydecane, N-(2-aminoethyl)-3-aminopropyltrimethoxydecane, 3-aminopropyltriethoxydecane, 3-glycidoxypropyl Trimethoxy methoxy methoxy propyl propyl dimethyl methoxy oxime, 2 - (3, 4-epoxycyclohexyl) ethyl bis oxetite, 3 - propyl propyl dimethyl oxy A cryptic promoter such as keshixi, 3 - chloropropyltrimethoxy oxyxanthine, 3-methyl propylene with oxypropyltrimethoxy oxacyclohexane, 3-hydrothiopropyltrimethoxy decane ; 2'2-thiobis(4-methyl-6-tertiary butylphenol), 2,6-di-tertiary butyl equivalent antioxidant, 2-(3-tertiary butyl-5 -Methyl-2 - via stupid base) _5_Chlorobenzoxan, alkoxylated one ketone oxime External absorbent; anti-aggregating agent such as sodium polyacrylate; malonic acid, adipic acid, itaconic acid, transconic acid, -34- 201232170 fumaric acid, mesaconic acid, 2-aminoethanol, 3 _Amino-propanol, 5-amino-1-pentanol, 3-amino-I, 2-propanediol, 2-amino-i, 3-propanediol, 4-amino-1, 2-butane a residue improving agent such as an alcohol; a mono [2 (fluorenyl) propylene methoxyethyl] succinate, a mono [2-(methyl) propylene oxyethyl] phthalic acid vinegar, ω- A developability improving agent such as a polycaprolactone mono(meth)acrylate; and a siloxane alkane oligomer having a reactive functional group disclosed in JP-A-2008-242078. The colored composition of the present invention can be prepared by a suitable method, and as a method of the preparation, for example, a component (?) to (D) can be prepared by mixing (G) a solvent and any other component added arbitrarily. When a pigment is used as the (Α) colorant, it is preferred to use the pigment in (G) solvent, (in the presence of a dispersing agent, as appropriate, part of the (Β) component, using, for example, a bead mill, a roll mill The pulverization, mixing, and dispersion are carried out to prepare a pigment dispersion liquid, and then a method of adding (Β) to (C) components to the pigment dispersion liquid, and further adding a solvent and other components as needed, and mixing them are prepared. When the (D) specific compound is added during the preparation of the pigment dispersion, or after the preparation of the pigment dispersion, the pigment dispersion and the remaining components are mixed. [Color filter and its manufacturing method] Color light of the present invention The film system has a coloring layer formed by using the present invention. As a method for manufacturing a color filter, the following method can be exemplified. On the surface of the board, a pixel portion is formed by division according to requirements.

首先，於基板表面上， 的方式形 含有例如 組成物後 -35- 201232170 對該塗膜隔著光罩 影’再溶解除去塗 ，由此便形成以既 列。 次之，使用綠 同樣地進行各著色 曝光、顯影及後焕 畫素陣列及藍色的 及藍色之三原色的 。惟，本發明中形 又，黑色矩陣 金屬薄膜，利用光 可使用含有黑色著 形成上述晝素時同 亦可適用於所述黑 作為形成彩色 璃、矽、聚碳酸酯 胺、聚醯亞胺等。 又’此等基板 劑等的藥品處理、 應法、真空蒸鍍等 將著色性組成 筒塗布法、旋轉塗 塗布法等適當的塗 模具塗布法。 進行曝光後，使用 膜的未曝光部分。 定排列配置有紅色 色或藍色的各著色 感放射線性組成物 烤，而在同一基板 畫素陣列。由此， 晝素陣列配置於基 成各色晝素的順序 可藉由將以濺鍍或 微影法製成所要的 色劑的著色感放射 樣的方式來形成。 色矩陣的形成。 濾光片之際所使用 、聚酯、芳香族聚 上亦可視需求預先 電漿處理、離子鍵 適當的前處理。 物塗布於基板之際 布法（旋塗法）、狹 布法’惟特佳採用 鹼性顯影液進行顯 其後，進行後烘烤 畫素圖案的晝素陣 性組成物，與上述 的塗布、預烘烤、 上依序形成綠色的 便製得紅色、綠色 板上的彩色濾光片 並未限於上述者。 蒸鍍而成膜的鉻等 圖案來形成，惟亦 線性組成物，以與 本發明著色組成物 的基板可例舉如玻 醯胺、聚醯胺醯亞 實施採用矽烷偶合 敷、濺鍍、氣相反 可採用喷霧法、滾 縫模具塗布法、桿 旋轉塗布法、狹縫 -36- 201232170 預烘烤通常係組合減覆乾燥與加熱乾燥來進行。 壓乾燥通常係進行至達到50〜200Pa為止。又，加執乾燥 之條件通常為70〜IHTctnw分鐘左右。 知 塗布厚度為乾燥後的膜厚，其通%為〇6〜8〇μπι 佳為 1.2~5·〇μηι。 作為形成晝素及/或，、色矩陣之際所使用之放 的光源可例舉如氣燈、㈣燈、鶴絲燈、高塵水銀燈、 超高壓水銀燈、金屬齒化物燈、中塵水銀燈、低壓 燈等之燈光源或氬離子雷射、YAG雷射、XeC1準分子雷 射、氮氣雷射等之雷射光源等，而較佳為波長處於I 450nm之範圍的放射線。 放射線的曝光量一般而言較佳為10〜10,000J/m2。 #又，上述鹼性顯影液較佳為例如碳酸鈉、氫氧化 氫氧化鉀、氫氧化四甲銨、膽鹼' Μ·二雜氮雙琿 _[5::〇]-7_十一烯、二雜氮雙環-[4.3.0)-5-壬烯等： —述鹼性顯影液中亦可適量添加例如甲醇、乙醇 性有機溶劑或界面活性劑等。此外，鹼性顯影後通 常進行水洗。 遇 g &作為顯影處理法可應用喷淋（Sh〇Wer)顯影法、噴霧 "法况潰（dlp)顯影法、浸置（paddle ;液池法）顯影法 顯衫條件較佳為常溫下5〜300秒。 後供烤之條件通常為120〜280°C下10〜60分鐘左右。 如此形成之畫素的膜厚通常為〇 5〜5 〇μιη，較佳 1 ·〇〜3.0μιη。 馬 -37- 201232170 又’作為製造彩色渡光片的第二方法可採用日本特 開平7-3 18723號公報、日本特開2000_310706號公報等所 揭露之以喷墨方式來製得各色晝素的方法。該方法中， 係首先於基板表面上形成同時兼具遮光功能的間壁 (partition)。次之，在所形成的間壁内以喷墨裝置噴出含 有例如紅色著色劑之本發明熱固性組成物之液狀組成物 後’進行預烘烤使溶媒蒸發。次之，對該塗膜視需求進 行曝光’隨後進行後烘烤使之硬化，便形成紅色的晝素 圖案。 次之’使用綠色或藍色的各著色熱固性組成物，與 上述同樣地在同一基板上依序形成綠色的畫素圖案及藍 色的畫素圖案。由此，便製得紅色、綠色及藍色之三原 色的晝素圖案配置於基板上的彩色濾光片。惟，本發明 中形成各色晝素的順序並未限於上述者。 此外，上述間壁不僅發揮遮光功能，還發揮不使喷 出至劃分區域内的各色著色組成物混色用的功能，故相 較於上述第一方法中所使用的黑色矩陣，其膜厚較厚。 因此，間壁通常使用黑色感放射線性組成物而形成。 形成彩色濾光片之際所使用的基板或放射線的光源 ’及預烘烤、後烘烤的方法或條件係與上述第一方法相 同。如此一來，由噴墨方式形成之畫素的膜厚便與間壁 的局度為相同程度。 於如此所得之晝素圖案上視需求形成保護膜後，再 以濺鍍形成透明導電膜。形成透明導電膜後，可進一步 形成間隔件而製成彩色濾光片。間隔件通常係使用感放 -38- 201232170 射線性組成物而形成，惟亦可製成具有遮光性的間隔件（ 黑色間隔件）。此時係使用含有黑色著色劑的著色感放射 線性組成物，惟本發明著色組成物亦可適用於所述黑色 間隔件的形成。 如此所得之本發明彩色濾光片其輝度及色純度極高 ，因此極有用於彩色液晶顯示元件、彩色攝像管元件、 色澤感應器、有機EL顯示元件、電子紙等。 [顯示元件] 本發明顯示元件係具備本發明彩色濾光片。作為顯 示元件可例舉彩色液晶顯示元件、有機El顯示元件、電 子紙等。 具備本發明彩色濾光片的彩色液晶顯示元件可採用 適當的構造。例如可採用將彩色濾光片形成於除配置有 薄膜電晶體（TFT)之驅動用基板以外的基板上，且驅動用 基板與形成有彩色濾光片的基板隔著液晶層對向的構造 ，更且亦可採用配置有薄膜電晶體（TFT)之驅動用基板的 表面上形成有彩色濾光片的基板、與形成有IT〇(摻有錫 之氧化銦）電極的基板隔著液晶層對向的構造。後者的構 造具有可格外提高開口率，並可獲得明亮、高精細的液 晶顯示元件的優點。 具備本發明彩色濾光片之彩色液晶顯示元件除冷陰 極螢光管（CCFL : Cold Cathode Fluorescent Lamp)之外， 還可具備以白色led為光源之背光單元。作為白色LED ，可例舉如將紅色LED、綠色LED與藍色LED組合、混色 而獲得白色光之白色LED、將藍色LED、紅色LED與綠色 -39- 201232170 螢光體組合、混色而獲得白色光之白色LED、將藍色LED 、紅色發光螢光體與綠色發光螢光體組合、混色而獲得 白色光之白色LED、經藍色LED與YAG系螢光體混色而獲 得白色光之白色LED、將藍色LED、橙色發光螢光體與綠 色發光螢光體組合、混色而獲得白色光之白色LED、將 紫外線LED、紅色發光螢光體、綠色發光螢光體與藍色 發光螢光體組合、混色而獲得白色光之白色LED等。 具備本發明彩色濾光片的彩色液晶顯示元件可適用 TN(Twisted Nematic)型、STN(Super Twisted Nematic)型 、IPS(In-Planes Switching)型、VA(Vertical Alignment) 型、OCB(Optically Compensated Birefringence)型等適當 的液晶模式。 此外，具備本發明彩色濾光片的有機EL顯示元件可 採用適當構造’可例舉如日本特開平1 1 -307242號公報所 揭露的構造。 又，具備本發明彩色濾光片的電子紙可採用適當構 造，可例舉如日本特開2007-4 1 1 69號公報所揭露的構造。 [實施例] 以下舉出實施例’對本發明的實施方式更具體地進 行說明。惟，本發明並未限於下述實施例。 <黏著劑樹脂之合成> 合成例1 對具備冷卻管與攪拌機之燒瓶加入丙二醇單曱醚乙 酸酯100質量份並進行氮氣置換。加熱至80°c，於同一溫 度下以1小時滴入丙二醇單甲醚乙酸酯100質量份、曱基 -40- 201232170 丙烯酸20質量份、苯乙烯1〇質量份、甲基丙烯酸笨甲酯5 質量份、曱基丙烯酸2-羥乙酯15質量份、甲基丙稀酸2-乙基己酯23質量份、N-苯基馬來醯亞胺12質量份、單 甲基）丙烯酸乙基]琥珀酸酯15質量份及2,2，_偶氮雙（2,4_ 二曱基戊腈）6質量份之混合溶液，保持該溫度進行聚合2 小時。其後’將反應溶液溫度升溫至1 00〇c並進—步進行 聚合1小時’即得黏著劑樹脂溶液（固體含量濃度3質量 。/〇)。所得之黏著劑樹脂其Mw=12,2〇〇、Mn = 6,50〇。以該 黏著劑樹脂作為「黏著劑樹脂（B丨）」。 合成例2 對具備冷卻管與攪拌機之燒瓶加入丙二醇單甲醚乙 IslS曰100質里份並進行氮氣置換。加熱至，於同一溫 度下以1小時滴入丙二醇單甲醚乙酸酯1 〇〇質量份、甲基 丙烯酸20質量份、苯乙烯1〇質量份、甲基丙烯酸笨曱酯5 質量伤、甲基丙烯酸2-羥乙酯15質量份、甲基丙烯酸2-乙基己酯38質量份、N-苯基馬來醯亞胺12質量份、及2,2'-偶氮雙（2,4-二甲基戊腈）6質量份之混合溶液，保持該溫 度進行聚合2小時。其後，將反應溶液溫度升溫至丨〇〇 並進步進行聚合1小時，即得黏著劑樹脂溶液（固體含 量濃度=33質量％)。所得之黏著劑樹脂其Mw=n，〇〇〇、 Mn = 6000。以該黏著劑樹脂作為「黏著劑樹脂（B2)」。 <顏料分散液之調製> 調製例1 使用作為（A)著色劑之C.I·顏料綠58/C.I.顏料黃150 = 8 0/20(虞里比）混合物15質量份、作為（E)分散劑之 -41 - 201232170 LPN21 1 16(ΒΥΚ公司製）12質量份（固體含量濃度=40質量 %)、作為（B)黏著劑樹脂之黏著劑樹脂（B1)溶液16質量份 、作為（G)溶劑之丙二醇單甲醚乙酸酯57質量份，以珠磨 機予以混合、分散1 2小時來調製顏料分散液（A_丨）。此外 ’換算成固體含量之分散劑BYK_LpN21丨丨6的胺價為 72.5mgKOH/g。 調製例2 使用作為（A)著色劑之C>1 •顏料綠58 15質量份、作為 (E)分散劑之BYK_LPN21U6(BYK公司製）12質量份、作為 (B)黏著劑樹脂之黏著劑樹脂（B1)溶液16質量份、作為 1質量份、作為（G)溶 ’以珠磨機予以混合 (D)特定化合物之2_氫硫基安息香酸 劑之丙一醇單甲鍵乙酸醋56質量份 、分散12小時來調製顏料分散液（a_2)。 調製例3 使用作為（Α)著色劑之c.I.顏料綠58/C I.顏料黃丨5〇 = 60/40(質*比）混合物15f量份、作為⑻分散劑之Βγκ_ lpn21 i 16(ΒΥΚ公司製）12質量份、作為（β)黏著劑樹脂之 黏者劑樹脂_溶液16質量份、作為(D)特定化合物之2_ 氣硫基安息香酸1質量份、作為⑼溶劑之丙二醇單甲鱗 =酿56質量份’以珠磨機予以混合、分散⑴、時來調 製顏料分散液（A-3)。 <著色組成物之調製及評定> 實施例1 [著色組成物之調製] 作為（B)黏著劑樹脂 將顏料分散液（A-1)200質量份 -42- 201232170 之黏著劑樹脂（B2)溶液45質量份、作為（C)交聯劑之東亞 合成股份有限公司製M-402(二新戊四醇六丙烯酸g旨與二 新戊四醇五丙烯酸酯之混合物）1 5質量份、作為（D)特定 化合物之2-氫硫基安息香酸1質量份、作為（F)光聚合起 始劑之2-苯甲基-2-二曱胺基-1-(4-咮福啉苯基）丁烷 酮20質量份、作為氟系界面活性劑之DIC股份有限公司製 Megafac F-554 1質量份、作為（G)溶劑之丙二醇單甲醚乙 酸酯混合成固體含量濃度為20質量％，以調製液狀組成 物（S -1)。 [黏度之評定]First, on the surface of the substrate, for example, after the composition is contained, -35 - 201232170, the coating film is redissolved and removed by a photomask, thereby forming a matrix. Next, green color exposure, development, and post-ghost arrays, and blue and blue primary colors are similarly used. However, in the present invention, the black matrix metal film can be formed by using light containing black to form the above-mentioned halogen, and can also be applied to the black to form colored glass, enamel, polycarbonate amine, polyimine, etc. . Further, such a drug treatment such as a substrate agent, a method, a vacuum deposition method, or the like, a suitable coating method such as a coloring composition coating method or a spin coating method. After the exposure, the unexposed portion of the film was used. The aligned arrays are arranged in red or blue for each of the colored radiation-sensitive components to be baked while on the same substrate as the pixel array. Thus, the order in which the halogen array is disposed in the respective color elements can be formed by irradiating the coloring matter of the desired toner by sputtering or lithography. The formation of a color matrix. For the filter used, polyester, aromatic polymerization can also be pre-treated by plasma treatment and ion pre-treatment. When the material is applied to the substrate, the cloth method (spin coating method) and the narrow cloth method are used to perform the post-bake pixel pattern of the elemental composition, and the above coating is performed. The pre-bake, the green color on the green, the color filter on the green plate is not limited to the above. The film is formed by vapor deposition of a pattern such as chromium, but is also a linear composition. The substrate to which the colored composition of the present invention is applied may, for example, be a phthalocyanine coupling, a sputtering, or a gas. Instead, a spray method, a roll seam die coating method, a rod spin coating method, and a slit-36-201232170 prebaking can be used in combination with dry reduction drying and heat drying. Press drying is usually carried out until it reaches 50 to 200 Pa. Further, the conditions for drying and drying are usually about 70 to IHTctnw minutes. It is known that the coating thickness is the film thickness after drying, and the pass % is 〇6~8〇μπι preferably 1.2~5·〇μηι. The light source used for forming the halogen and/or the color matrix may, for example, be a gas lamp, a (four) lamp, a crane lamp, a high dust mercury lamp, an ultrahigh pressure mercury lamp, a metal toothed lamp, a medium dust mercury lamp, A light source such as a low-voltage lamp or a laser source such as an argon ion laser, a YAG laser, a XeC1 excimer laser, a nitrogen laser, or the like, and preferably a radiation having a wavelength in the range of I 450 nm. The exposure amount of the radiation is generally preferably from 10 to 10,000 J/m2. # Further, the above alkaline developing solution is preferably, for example, sodium carbonate, potassium hydroxide hydroxide, tetramethylammonium hydroxide, choline 'Μ·diazabiguanide_[5::〇]-7-undecene. Further, diazo-bicyclo-[4.3.0)-5-decene or the like: In the alkaline developing solution, for example, methanol, an alcoholic organic solvent or a surfactant may be added in an appropriate amount. Further, it is usually washed with water after alkaline development. In the case of g & as a development treatment, spray (Sh〇Wer) development method, spray "damp development (dlp) development method, immersion (paddle; liquid pool method) development method is preferred. 5 to 300 seconds. The conditions for post-baking are usually about 10 to 60 minutes at 120 to 280 °C. The film thickness of the pixel thus formed is usually 〇 5 to 5 〇 μιη, preferably 1 · 〇 to 3.0 μιη. In the second method of producing a color light-emitting sheet, the ink-jet method disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. method. In this method, a partition which simultaneously has a light-shielding function is formed on the surface of the substrate. Next, after the liquid composition containing the thermosetting composition of the present invention containing, for example, a red coloring agent is ejected by an ink jet device in the formed partition, the pre-baking is carried out to evaporate the solvent. Next, the coating film is exposed as needed. Then, post-baking is performed to harden it to form a red halogen pattern. The next step was to use a green or blue colored thermosetting composition to sequentially form a green pixel pattern and a blue pixel pattern on the same substrate as described above. As a result, a color filter in which the elementary patterns of the three primary colors of red, green, and blue are disposed on the substrate is obtained. However, the order in which the various color elements are formed in the present invention is not limited to the above. Further, the partition wall not only exhibits a light-shielding function, but also functions to prevent color mixing of the coloring compositions discharged into the divided regions, so that the film thickness is thicker than that of the black matrix used in the first method. . Therefore, the partition walls are usually formed using a black sensitizing radioactive composition. The light source of the substrate or radiation used for forming the color filter and the method or conditions for prebaking and postbaking are the same as those of the first method described above. As a result, the film thickness of the pixel formed by the ink jet method is the same as the thickness of the partition wall. After forming a protective film on the thus obtained halogen pattern as needed, a transparent conductive film is formed by sputtering. After the transparent conductive film is formed, a spacer can be further formed to form a color filter. The spacer is usually formed using a radiation-sensitive composition -38-201232170, but it can also be made into a light-shielding spacer (black spacer). In this case, a colored radiation linear composition containing a black colorant is used, but the colored composition of the present invention can also be applied to the formation of the black spacer. The color filter of the present invention thus obtained has extremely high luminance and color purity, and thus is extremely useful for color liquid crystal display elements, color image sensor elements, color sensors, organic EL display elements, electronic paper, and the like. [Display Element] The display element of the present invention is provided with the color filter of the present invention. The display element may, for example, be a color liquid crystal display element, an organic EL display element, an electronic paper or the like. The color liquid crystal display element having the color filter of the present invention can be suitably constructed. For example, a color filter may be formed on a substrate other than the driving substrate on which the thin film transistor (TFT) is disposed, and the driving substrate and the substrate on which the color filter is formed may be opposed to each other via the liquid crystal layer. Further, a substrate on which a color filter is formed on a surface of a driving substrate on which a thin film transistor (TFT) is disposed, and a substrate on which an IT 〇 (tin-doped indium oxide) electrode is formed may be interposed with a liquid crystal layer. The construction of the direction. The latter structure has the advantage that the aperture ratio can be particularly increased and a bright, high-definition liquid crystal display element can be obtained. A color liquid crystal display element having the color filter of the present invention may be provided with a backlight unit having a white LED as a light source in addition to a cold cathode fluorescent lamp (CCFL). The white LED may be a white LED in which a red LED, a green LED, and a blue LED are combined and mixed to obtain a white light, and a blue LED, a red LED, and a green-39-201232170 phosphor are combined and mixed. White light white LED, blue LED, red light emitting phosphor and green light emitting phosphor are combined and mixed to obtain white light white LED, and blue LED and YAG fluorescent body are mixed to obtain white light white. LED, blue LED, orange light-emitting phosphor and green light-emitting phosphor are combined and mixed to obtain white light white LED, ultraviolet LED, red light-emitting phosphor, green light-emitting phosphor and blue light-emitting fluorescent light The body is combined and mixed to obtain a white LED such as white light. The color liquid crystal display element having the color filter of the present invention can be applied to TN (Twisted Nematic) type, STN (Super Twisted Nematic) type, IPS (In-Planes Switching) type, VA (Vertical Alignment) type, OCB (Optically Compensated Birefringence). A suitable liquid crystal mode such as a type. In addition, the organic EL display element having the color filter of the present invention may have a suitable structure, and the structure disclosed in Japanese Laid-Open Patent Publication No. Hei No. Hei. Further, the electronic paper comprising the color filter of the present invention can be suitably constructed, and the structure disclosed in Japanese Laid-Open Patent Publication No. 2007-4 1 169 can be exemplified. [Examples] Hereinafter, embodiments of the present invention will be described more specifically by way of Examples. However, the invention is not limited to the following examples. <Synthesis of Adhesive Resin> Synthesis Example 1 100 parts by mass of propylene glycol monoterpene ether acetate was placed in a flask equipped with a cooling tube and a stirrer, and nitrogen substitution was performed. Heating to 80 ° C, 100 parts by mass of propylene glycol monomethyl ether acetate, 20 parts by mass of fluorenyl-40-201232170 acrylic acid, 1 part by mass of styrene, and methyl methacrylate at a temperature of 1 hour. 5 parts by mass, 15 parts by mass of 2-hydroxyethyl methacrylate, 23 parts by mass of 2-ethylhexyl methacrylate, 12 parts by mass of N-phenylmaleimide, and monomethyl) acrylate B A mixed solution of 15 parts by mass of succinate and 6 parts by mass of 2,2,-azobis(2,4-dithiopentyl nitrile) was maintained at this temperature for 2 hours. Thereafter, the temperature of the reaction solution was raised to 100 ° C and polymerization was carried out for 1 hour to obtain an adhesive resin solution (solid content concentration: 3 mass % / 〇). The obtained adhesive resin had Mw = 12, 2 Å and Mn = 6, 50 Å. This adhesive resin is used as "adhesive resin (B丨)". Synthesis Example 2 To a flask equipped with a cooling tube and a stirrer, propylene glycol monomethyl ether, IslS曰, was added in an amount of 100 parts and replaced with nitrogen. Heating to, at the same temperature, 1 part by mass of propylene glycol monomethyl ether acetate, 20 parts by mass of methacrylic acid, 1 part by mass of styrene, 5 parts by weight of styrene methacrylate, 1 15 parts by mass of 2-hydroxyethyl acrylate, 38 parts by mass of 2-ethylhexyl methacrylate, 12 parts by mass of N-phenylmaleimide, and 2,2'-azobis (2,4) - 6 parts by mass of a mixed solution of dimethyl valeronitrile, and the polymerization was carried out for 2 hours while maintaining the temperature. Thereafter, the temperature of the reaction solution was raised to 丨〇〇 and the polymerization was progressed for 1 hour to obtain an adhesive resin solution (solid content concentration = 33% by mass). The resulting adhesive resin had Mw = n, 〇〇〇, Mn = 6000. This adhesive resin is used as the "adhesive resin (B2)". <Preparation of Pigment Dispersion> Preparation Example 1 15 parts by mass of a mixture of CI·Pigment Green 58/CI Pigment Yellow 150 = 8 0/20 (Miri) was used as the (A) colorant, and (E) was dispersed. -41 - 201232170 LPN21 1 16 (manufactured by Seiko Co., Ltd.) 12 parts by mass (solid content concentration = 40% by mass), and (B) 16 parts by mass of the adhesive resin (B1) solution of the adhesive resin, as (G) 57 parts by mass of a solvent of propylene glycol monomethyl ether acetate was mixed and dispersed in a bead mill for 12 hours to prepare a pigment dispersion liquid (A_丨). Further, the amine value of the dispersant BYK_LpN21丨丨6 converted to a solid content was 72.5 mgKOH/g. Preparation Example 2 As the (A) coloring agent, C > 1 • Pigment Green 58 15 parts by mass, (E) Dispersing agent, BYK_LPN21U6 (manufactured by BYK Corporation), 12 parts by mass, and (B) Adhesive resin as an adhesive resin (B1) 16 parts by mass of the solution, as 1 part by mass, as (G) dissolved in a bead mill, (D) a specific compound of 2-hydrothio-benzoic acid agent, propanol monomethyl acetate acetate 56 mass The pigment dispersion (a_2) was prepared by dispersing for 12 hours. Preparation Example 3 Using cI Pigment Green 58/C I. Pigment Astragalus 5〇=60/40 (mass* ratio) mixture as a (Α) colorant, 15 f parts by weight, and (8) dispersing agent Βγκ_ lpn21 i 16 (ΒΥΚ公司12 parts by mass, 16 parts by mass of the adhesive resin _ solution of the (β) adhesive resin, 1 part by mass of 2_gasthio benzoic acid as the (D) specific compound, and propylene glycol monomethyst as the solvent (9) = Brewing 56 parts by mass 'mixed and dispersed (1) in a bead mill to prepare a pigment dispersion (A-3). <Preparation and Evaluation of Coloring Composition> Example 1 [Preparation of Colored Composition] As a (B) adhesive resin, a pigment dispersion (A-1) 200 parts by mass - 42 - 201232170 of an adhesive resin (B2) 45 parts by mass of a solution of M-402 (a mixture of dipentaerythritol hexaacrylate g and dipentaerythritol pentaacrylate) as a (C) crosslinking agent, 15 parts by mass, (D) 2-hydroxythiobenzoic acid as a (D) specific compound, 2-benzyl-2-diguanylamino-1-(4-indololin benzene as (F) photopolymerization initiator 20 parts by mass of butanone, 1 part by mass of Megafac F-554 manufactured by DIC Co., Ltd. as a fluorine-based surfactant, and propylene glycol monomethyl ether acetate as a solvent (G) mixed to a solid content of 20 masses % to prepare a liquid composition (S-1). [Assessment of viscosity]

利用E型黏度計（東京計器製）來量測調製後即刻之液 狀組成物（s-i)的黏度。此外，將所得之液狀組成物 填充於遮光玻璃容器中，以密閉狀態於4〇下靜置7曰後 ’再次利用E型黏度計（東京計器製）量測黏度。其後，算 出保存7曰後之黏度相對調製後即刻之黏度的增加率，當 增加率小於5 %時評為「A」，5 %以上小於1 0 %時評為「B 」’ 1 〇%以上時則評為「C」。評定結果係示於表1。 [雜質之評定] 將保存於401下7日後的液狀組成物（S-1)利用旋轉塗 布機塗布於玻璃基板上後，以9 〇 〇c之加熱板進行預烘烤1 刀知即形成膜厚2.5μπι之塗膜。次之，將基板冷卻至室溫 後’利用高壓水銀燈，在未隔著光罩下對塗膜以6〇〇J/m2 曝光里曝光含365nm、405nm及436nm之各波長的放射線 對所得之綠色硬化膜以偏光顯微鏡（倍率200倍）進行觀 “ S —視野中可確認之雜質為零時判定為A，一視野中 -43- 201232170 可確認之雜質為u個時判定為B，而一視野中可確認之雜 質為10個以上時則判定為c。評定結果係示於表i。 [對比之評定] 將調製後即刻之液狀組成物（s_1}利用旋轉塗布機 塗布於玻璃基板上後，以9〇〇c之加熱板進行預烘烤1分鐘 即形成膜厚2.5μηι之塗膜。次之，將基板冷卻至室溫後， 利用高壓水銀燈，在未隔著光罩下對塗膜以6〇〇j/m2之曝 光量曝光含365nm、405nm及436nm之各波長的放射線。 其後，對塗膜以顯影壓力lkgf/cm2(喷嘴直徑lmm)排出包 含23。(：、〇.04質量％氫氧化鉀水溶液之顯影液藉以進行 喷淋顯影。其後’以超純水清洗該基板並加以風乾後， 進步在23〇 c之潔淨烘箱内進行後烘烤2〇分鐘，即形成 綠色硬化膜。 以2片偏向板夾持形成有硬化膜之基板，由背面側照 射螢光燈（波長範圍380〜780nm)同時旋轉前側之偏向板 ，利用輝度計LS-lOCHMinolu(股）製）量測所穿透之光強 度的最大值與最小值《爾後，以最大值除以最小值所得 之值作為對比。評定結果係示於表1。 對40°C下保存7日後之液狀組成物（n)同樣進行對 比的量測。評定結果係示於表1。 實施例2〜8及比較例1〜3 除將貫施例1中顏料分散液的種類及（D)成分的種類 改為如表1所示者以外’係以與實施例1同樣的方式來調 製液狀組成物（S - 2)〜（S - 8)及（s -1 〇)〜（§ _ 12)。此外，在調 製液狀組成物（S - 5)及（S - 6)時，作為溶劑係使用丙二醇單 -44 - 201232170 曱醚乙酸醋/丙二醇單曱醚=85/15(質量比）混合溶劑。又 ，實施例7及8中，（D)成分係於調製顏料分散液時添加， 而未於調製著色組成物時添加。 次之，除使用各個液狀組成物（s_2)〜（s_8)或（Sl〇)〜 (S -1 2)來取代液狀組成物（s -1)以外，係以與實施例1同樣 的方式進行評定。評定結果係示於表i。 實施例9 將作為（A)著色劑之c.I.溶劑橙56(Cr錯合物）25質量 份、作為（B)黏著劑樹脂之黏著劑樹脂（B2)溶液45質量份 1 5質量份、作為（C)交聯劑之東亞合成股份有限公司製 M-402(二新戊四醇六丙烯酸酯與二新戊四醇五丙烯酸酯 之混合物）1 5質量份、作為（D)特定化合物之2_氫硫基安 息香酸0.8質量份、作為（F)光聚合起始劑之2_苯曱基·2_ 二曱胺基-1-(4 -咪福啉苯基）丁烷-i_酮2〇質量份、作為敷 系界面活性劑之DIC股份有限公司製μ e g a f a c F - 5 5 4 1質 量份、作為（G)溶劑之乳酸乙酯混合成固體含量濃度為2〇 質量％來調製液狀組成物（S-9)。 對40°C下保存7曰後的液狀組成物（S-9)以與實施例 1同樣的方式進行雜質之評定。評定結果係示於表1。 比較例4 除使用鄰苯二甲酸單甲酯來取代實施例9中之2-氫 硫基安息香酸以外，係以與實施例9同樣的方式來調製液 狀組成物（S-13)。對40°C下保存7日後的液狀組成物（S-9) 以與實施例1同樣的方式進行雜質之評定。評定結果係示 於表1。 -45- 201232170 【Id 對比比率 (40°C下保存7曰後） 12450 12300 12000 8200 11900 11750 13100 12650 1 4300 7600 1250 1 對比比率 (調製後即刻） 12400 12200 12200 10600 11800 11600 13200 12800 1 5800 10000 3700 1 雜質評定 < C PQ < < < < < U 0Q U U 黏度穩定性 < < < < < < C < 1 U < < 1 (D)成分 Q Q CO Q 寸 Q Q ν〇 Q T-H Q 1…丨Η Q 1-^ Q 丙二酸 鄰苯二曱酸單甲酯 鄰苯二曱酸單甲酯 (A)成分 顏料分散液(A-1) 顏料分散液(A-1) 顏料分散液(A-1) 顏料分散液(Α-1) 顏料分散液(Α-1) 顏料分散液(A-1) 顏料分散液(A-2) 顏料分散液(Α-3) C.I.溶劑橙56 顏料分散液(Α-1) 顏料分散液(Α-1) 顏料分散液(Α-1) C.I.溶劑橙56 液狀組成物 T-H (/) CN C/3 cn ώ ¢/) 〇} CO 〇〇 〇\ C/) S-10 1-Η 1 00 S-12 S-13 實施例1 實施例2 實施例3 實施例4 實施例5 |實施例6 I 實施例7 實施例8 實施例9 比較例1 比較例2 比較例3 比較例4 .9寸— 201232170 表1中，各成分係如下述： D1 : 2-氫硫基安息香酸（d-5) D2 : 1 1-氫硫基十一酸（d-1) D 3 _ 4 -氮硫基必驗酸（d - 7) D4 : 10-羥基癸酸（d-1) D5 :吡啶-3-磺酸三丁基銨（d-8) D6 :下式所示之化合物之三丁基銨鹽（d-4)The viscosity of the liquid composition (s-i) immediately after the modulation was measured using an E-type viscometer (manufactured by Tokyo Keiki Co., Ltd.). In addition, the obtained liquid composition was filled in a light-shielding glass container, and it was left to stand at 7 Torr in a sealed state, and then the viscosity was measured again using an E-type viscometer (manufactured by Tokyo Keiki Co., Ltd.). Thereafter, the increase rate of the viscosity after the storage of 7 相对 is calculated relative to the viscosity immediately after the preparation, and is evaluated as “A” when the increase rate is less than 5%, and is evaluated as “B” when the increase rate is less than 10%. Then rated as "C". The results of the evaluation are shown in Table 1. [Evaluation of Impurities] The liquid composition (S-1) stored after 7 days after 401 was applied onto a glass substrate by a spin coater, and then prebaked by a hot plate of 9 〇〇c. A film having a film thickness of 2.5 μm. Next, after cooling the substrate to room temperature, the green color of each of the wavelengths of 365 nm, 405 nm, and 436 nm was exposed to the coating film at 6 〇〇J/m 2 without using a high-pressure mercury lamp. The cured film was observed by a polarizing microscope (magnification: 200 times). "S - when the impurity confirmed in the field of view is zero, it is judged as A, and in a field of view -43-201232170, when the impurity can be confirmed as u, it is judged as B, and a field of view is obtained. When the number of impurities which can be confirmed is 10 or more, it is judged as c. The evaluation results are shown in Table i. [Evaluation of Contrast] After the liquid composition (s_1) immediately after preparation is applied onto a glass substrate by a spin coater The film was pre-baked for 1 minute with a heating plate of 9 〇〇c to form a film having a film thickness of 2.5 μm. Next, after cooling the substrate to room temperature, the film was coated without a light barrier by using a high-pressure mercury lamp. Radiations of respective wavelengths of 365 nm, 405 nm, and 436 nm were exposed at an exposure amount of 6 〇〇j/m 2 . Thereafter, the coating film was discharged at a developing pressure lkgf/cm 2 (nozzle diameter 1 mm) containing 23 (:, 〇.04 Development solution of mass% potassium hydroxide aqueous solution for spray development Thereafter, the substrate was washed with ultrapure water and air-dried, and post-baking was carried out in a clean oven at 23 ° C for 2 minutes to form a green cured film. The cured film was formed by sandwiching two polarizing plates. The substrate is irradiated with a fluorescent lamp (wavelength range of 380 to 780 nm) from the back side while rotating the front side of the deflecting plate, and the maximum and minimum values of the transmitted light intensity are measured by a luminance meter LS-lOCHMinolu (manufactured by a luminometer). The value obtained by dividing the maximum value by the minimum value was used as a comparison. The evaluation results are shown in Table 1. The liquid composition (n) after 7 days of storage at 40 ° C was similarly measured. The evaluation results are shown in Tables 2 to 8 and Comparative Examples 1 to 3 In the same manner as in Example 1, except that the type of the pigment dispersion liquid and the type of the component (D) in Example 1 were changed to those shown in Table 1 The way to modulate the liquid composition (S-2) ~ (S-8) and (s-1 〇) ~ (§ _ 12). In addition, in the preparation of liquid compositions (S-5) and (S- 6), as a solvent, use propylene glycol mono-44 - 201232170 曱 ether acetate vinegar / propylene glycol monoterpene ether = 85 / 15 (mass ratio) mixed Further, in Examples 7 and 8, the component (D) is added when the pigment dispersion liquid is prepared, and is not added when the coloring composition is prepared. Second, except for using each liquid composition (s_2) to (s_8) Or (S1〇)~(S-12), except the liquid composition (s-1), was evaluated in the same manner as in Example 1. The evaluation results are shown in Table i. 25 parts by mass of cI solvent orange 56 (Cr complex) as the coloring agent (A), and 45 parts by mass of the adhesive resin (B2) solution as the (B) adhesive resin, as (C) cross-linking M-402 (a mixture of dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate) prepared by East Asia Synthetic Co., Ltd., 15 parts by mass, as a (D) specific compound, 2-hydrothio-benzoin 0.8 parts by mass of acid, 2 parts by mass of 2-phenylindole-2-indanyl-1-(4-midofolinylphenyl)butane-i-ketone as (F) photopolymerization initiator Applying a surfactant, DIC Co., Ltd., μ egafac F - 5 5 4 1 part by mass, and ethyl lactate as a (G) solvent to form a solid content concentration of 2 〇 mass % to prepare a liquid composition (S-9). The liquid composition (S-9) after storage at 40 ° C for 7 Å was subjected to evaluation of impurities in the same manner as in Example 1. The results of the evaluation are shown in Table 1. Comparative Example 4 A liquid composition (S-13) was prepared in the same manner as in Example 9 except that the monomethyl phthalate was used instead of the 2-hydrothiobenzoic acid in Example 9. The liquid composition (S-9) after storage for 7 days at 40 ° C was evaluated for impurities in the same manner as in Example 1. The results of the evaluation are shown in Table 1. -45- 201232170 [Id contrast ratio (after 7曰 at 40°C) 12450 12300 12000 8200 11900 11750 13100 12650 1 4300 7600 1250 1 Contrast ratio (immediately after modulation) 12400 12200 12200 10600 11800 11600 13200 12800 1 5800 10000 3700 1 Impurity evaluation < C PQ <<<<< U 0Q UU viscosity stability <<<<<<<<<<< CO Q inch QQ ν〇Q TH Q 1...丨Η Q 1-^ Q Malonate phthalic acid monomethyl phthalate monomethyl ester (A) component pigment dispersion (A-1) pigment Dispersion (A-1) Pigment dispersion (A-1) Pigment dispersion (Α-1) Pigment dispersion (Α-1) Pigment dispersion (A-1) Pigment dispersion (A-2) Pigment dispersion (Α-3) CI solvent orange 56 pigment dispersion (Α-1) pigment dispersion (Α-1) pigment dispersion (Α-1) CI solvent orange 56 liquid composition TH (/) CN C/3 cn ¢ ) /) 〇} CO 〇〇〇 \ C / ) S-10 1-Η 1 00 S-12 S-13 Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Example 5 | Example 6 I Example 7 Example 8 Example 9 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 .9 Inch — 201232170 In Table 1, the components are as follows: D1 : 2-Hetylthiobenzoic acid (d-5) D2 : 1 1-Hexylthioundecanoic acid (d-1) D 3 _ 4 -N-sulfur Acidic acid (d-7) D4: 10-hydroxydecanoic acid (d-1) D5: tributylammonium pyridine-3-sulfonate (d-8) D6: tributyl group of the compound represented by the following formula Ammonium salt (d-4)

conh2 【圖式簡單說明】 無。 【主要元件符號說明】 無0 -47-Conh2 [Simple diagram description] None. [Main component symbol description] No 0 -47-

Claims (1)

201232170 七、申請專利範圍： 1.一種著色組成物，其特徵為含有（A)著色劑、（B)黏著劑 樹脂、（c)交聯劑、及（D)選自包含下述（d_1}〜（d_8)之群 組的至少1種化合物， (d-l)具有選自包含_OR】基及_SR2基之群組的至少1種 之脂肪族羧酸或其鹽 (d-2)具有選自包含_〇Ri基-SR2基及_q_nr3r4基之群 組的至少1種之脂肪族磺酸或其鹽 (d-3)具有選自包含_〇Ri基及_SR2基之群組的至少五種 之脂環式幾酸或其鹽 (d-4)具有選自包含_〇Rl基、_sr2基及_q nr3r4基之群 組的至少1種之脂環式磺酸或其鹽 (d 5)由具有_SR2基之基團與具有叛基之基團取代之芳 香族煙或其鹽 (d-6)經選自包含且古八 匕3具有-OR1基之基團、具有_SR2基之基 團及具有4甘 ^ 基之基團之群組的至少1種、與具有 磺酸基之基團取代夕& 代之方香族烴或其鹽 (U &基及雜環基，且氫原子與羧基除外之總原 子數為3〜20之化合物或其鹽 (d-8)具有石夤酸基及雜声甘 ^ 久雜椒基，且氫原子與磺酸基除外之 總原子數為3〜2〇 化合物或其鹽 [惟，R丨〜R4彼此獨立矣_ — 煙基，Q表示氣原子或取代或未取代之1價 V衣不早鍵或羰基]。 2.如申請專利範圍篦 作Α員之著色組成物，其中含有錯合物 作為刖述（A)者色劑。 -48- 201232170 3. 如申請專利範圍第2項之著色組成物，其中構成前述錯 合物之中心原子為Cu、Zn、Ni、Cr、Al、Co、Mg、In 、F e 或 B。 4. 如申請專利範圍第2項之著色組成物，其中前述錯合物 為金屬献菁素。 5. 如申請專利範圍第1至4項中任一項之著色組成物，其 進一步含有（E)胺價為5mgKOH/g以上之分散劑。 6. —種彩色濾光片，其具備使用如申請專利範圍第1至4 項中任一項之著色組成物所形成之著色層。 7. —種顯示元件，其具備如申請專利範圍第6項之彩色濾 光片。 -49- 201232170 四、指定代表圖： (一） 本案指定代表圖為：無。 (二） 本代表圖之元件符號簡單說明： 無。 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式:201232170 VII. Patent application scope: 1. A coloring composition characterized by containing (A) a coloring agent, (B) an adhesive resin, (c) a crosslinking agent, and (D) selected from the following (d_1) At least one compound of the group of (d_8), (dl) having at least one aliphatic carboxylic acid selected from the group consisting of _OR group and _SR2 group, or a salt thereof (d-2) At least one aliphatic sulfonic acid or a salt thereof (d-3) from the group consisting of 〇Ri group-SR2 group and _q_nr3r4 group has at least one group selected from the group consisting of 〇Ri group and _SR2 group The five alicyclic acid or a salt thereof (d-4) has at least one alicyclic sulfonic acid or a salt thereof selected from the group consisting of a 〇R1 group, a _sr2 group, and a _q nr3r4 group (d) 5) an aromatic cigarette or a salt thereof (d-6) substituted with a group having a _SR2 group and a group having a rebel group, and having a group selected from the group consisting of and having an -OR1 group, having _SR2 At least one of a group of a group having a group and a group having a group of 4 groups, and a group having a sulfonic acid group, a substituted aromatic hydrocarbon or a salt thereof (U & base and heterocyclic ring) Base, and the total number of atoms excluding hydrogen and carboxyl is 3 The compound of 20 or a salt thereof (d-8) has a sulphate group and a sulphonic acid, and the total number of atoms excluding a hydrogen atom and a sulfonic acid group is 3 to 2 〇 compounds or salts thereof [only, R 丨 R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R The complex compound is used as a coloring agent for the description (A). -48- 201232170 3. The coloring composition of claim 2, wherein the central atom constituting the complex is Cu, Zn, Ni, Cr, Al. , Co, Mg, In, F e or B. 4. The colored composition of claim 2, wherein the complex is a metal phthalocyanine. 5. If the scope of claims 1 to 4 is A coloring composition further comprising (E) a dispersing agent having an amine value of 5 mgKOH/g or more. 6. A color filter which is used as claimed in any one of claims 1 to 4; a coloring layer formed by coloring a composition. 7. A display element having a color filter as in claim 6 -49- 201232170 IV. Designated representative map: (1) The representative representative of the case is: No. (2) The symbol of the representative figure is simple: No. 5. If there is a chemical formula in this case, please reveal the best display invention. Characteristic chemical formula: