TW200942152A - Sheet material, electromagnetic shielding sheet material, wallpaper, and electromagnetic shielding tape for electrical wiring - Google Patents

Sheet material, electromagnetic shielding sheet material, wallpaper, and electromagnetic shielding tape for electrical wiring Download PDF

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Publication number
TW200942152A
TW200942152A TW097150643A TW97150643A TW200942152A TW 200942152 A TW200942152 A TW 200942152A TW 097150643 A TW097150643 A TW 097150643A TW 97150643 A TW97150643 A TW 97150643A TW 200942152 A TW200942152 A TW 200942152A
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Taiwan
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fiber
sheet
base fabric
sheet material
electromagnetic wave
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TW097150643A
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Chinese (zh)
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TWI435688B (en
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Takashi Ishida
Koutaro Matsumoto
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Nippon Oil Corp
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • H05K9/0001Rooms or chambers
    • H05K9/0003Shielded walls, floors, ceilings, e.g. wallpaper, wall panel, electro-conductive plaster, concrete, cement, mortar

Abstract

A sheet material is provided which is thin and lightweight, and yet has a large quantity of adhered metal. The sheet material comprises a base fabric 2 comprising at least one of fiber array layers 12A, 12B, 12C and 12D in which continuous long fibers are stretched and aligned in substantially straight lines in a single direction, wherein at least one surface of the base fabric 2 is plated with metal.

Description

200942152 六、發明說明: 【發明所屬之技術領域】 [0001] 【先前技術】 [0002] 在以轉蔽在許乡猶賴私㈣_。例如, ί 小型電子通訊機器上’為了高性能化而有 ϊίη電子化後賴器與工廠⑽電力線釋出的電磁波所造 ^的雜訊與誤動作。在汽車的領域内也使料多的電子 j 由於近年來的健康意識,或對 變得重部的電子零件之影響的抑制 交付置要X在工廠4地也有許多的設備電子化,必須要有對 器使用者、電磁波過敏症患者的憂慮,在家i内、醫P 内·#地對於電磁波屏蔽的需求正在變高。 醫院 [0003] ❿ 這些電磁波屏蔽上,多使用對金屬纖維、不織布等構 日ϋ電鍍後的狀⑽如,參考日本_ 2_韻877號公報二 【發明内容】 [0004] 屬量1 目於藉由電鑛步驟附著於基材的金 梯L Ϊ 越多電磁波屏蔽特性也越向上提升。但是, 材料。纖維粗且剛直而成為高厚度的 構成-般紡黏不織布的高分子纖維,其表面積受限於直徑ϋ 200942152 * 般來說’電磁波屏蔽用的片材之紐制無電解電鍍, 2 =解電射,由於金屬是在被働與電鍍液的接液部分 (风,右纖維的表面積小,相對而言金屬的附著量也會變少。所 ^右了增加附著量而增加基材的膜厚,因為電錢液的滲透 姑ίif限’結果變成無法充分使電鍍液渗透至基材内部、只是 位面積重#(單位面躺重量)與基材厚度。 但是,電磁波屏蔽依據用途而被強烈要求輕量、例 義二動ί?中’零件的密集度已經達到極限,且還被要求更 ❹之畲胃魅^化,必雜力避免未貢獻電磁波屏蔽功能的基材 ϋϊίί增加。在汽車電子零件用之電磁波屏蔽方面,亦為 的輕量化而希望基材越薄越好。 著量鑑於上述問題,目的在於提供輕量、薄片且金屬附 屏蔽效果的各種i用ΪΓ目的在於提供使用該片材發揮電磁波 [0007] 層由施形態’片材包含基布’基布至少包含1 ❹且基布至少-邊的直線狀延伸排列的纖維排列層, [0008] 能使 纖維i無:ί =纖朝皁方向約為直線狀排列, -以rft抵的㈣侧。祕長纖維延伸,纖_直徑被緊缩, :口纖維的比表面積(單位體積的表面 著量相當依存於纖維的比表面積n因 =生的金屬附 之比表面積,與使用以㈣編如心疋在基布表面附近的纖維 方向約Λ吉錄肋站伯u 猎由使連續的長纖維朝單 内的纖維填充效率提高,得以做出纖薄的 = ίίί,伸’纖維朝片材内侧方向整齊延伸, 200942152 K在ίΐί全且金屬附著效率變得更高這個優點 『片”,’與爛來的纖薄性特質相輔相成,也有 [0009] 基布包含複數層的纖維排列層,將—部 维排列層以長纖維延伸方向互相不同的方式堆… ❹ 線用磁波屏蔽用片材、壁紙、電 [0011] 曰如^上說明,依照本發明,能提供輕量、薄纽 種i用=本發™使用崎發揮電磁波屏 【實施方式】 [0014] 胸本發明片材的一實施形態。圖1為本發明-實 © ί:==圖。片材1包含由不織布構成的基布乂 為以後述方式畴於_表_金屬,但翔,1 際』 緣故’而用層的形式力叫示。電鍍部3a 3b/由Γ電圖解 基布2的兩面上形成,僅在任—單面上 附著^ 要能使3a、% _電微賊絲,Z使 :果 中’鋼主要負責電磁波屏蔽效果,錄主 [0015] 稱附ίίίΙΐΓΐ藉由改變基布2浸泡於電鍍液内的時間來 調整。方將基布以短時間浸泡於電鑛液内,能得到不至於 200942152 布原有透氣性的金屬附著量。若浸泡更長時間,亦能使金屬的附 著量達到各纖維上附著的電鍍部互相連結之程度。 [0016] 2 圖2為基布的分解立體圖。基布2為複數層由連續的長纖維 朝單方向約為直線狀延伸排列的纖維排列層堆叠組成。在圖中雖 顯示為4片纖維排列層12A、12B、12C、12D,但可適當決定堆 疊片數,依據不同用途即使僅有一片也無所謂,詳後述。纖維排 列層12A、12B、12C、12D彼此間被熱壓接,共同形成一張基布 φ [〇〇17] 圖3為將基布的纖維排列層之一部分擴大顯示的局部立體 圖。該圖中雖只顯示出纖維排列層12A、12B,但其他的纖維排夕 層也為同樣的構造。如圖所示’纖維排觸12A為多數互相平平 且直線狀延伸的纖維13A之集合體。同樣的,纖維排列層12B . 多數互相平姐直線狀延伸的鱗13B之集合體。亦有將纖維 1=、13B在巾賴疊’形成兩相上的堆疊之情況。纖維排列力 5 η,、聚丙烯、聚酯、聚醯胺、聚氣乙烯系樹脂、 ίϊϋ摘旨等熱塑性樹脂以及其變性樹脂製成。也可以使 © 辦烯腈系樹脂等與濕式或乾式纺絲法相關 = 纖列層咖的纖維別之延伸方向15Β互本 昼 -定要與相鄰纖維排列層互;垂;維:= :也可連續將兩片或兩片以上的纖維:列層:相同:延::: [0018] 200942152 基布的單位面積重量以5g/m2以上、60g/m2以下為佳。亦可 在基布的一面或是兩面設有黏著膠帶、黏著材等等黏^機構。 [0019] * 各纖維排列詹12A、12B、12C、12D的纖維13a、13B、13C、 13D朝延伸方向15A、15B、15C、15D延伸排列著。因此,與以往 的熔喷法等製作的不織布相比,纖維的直線性與方向性極高',而 且纖維的雄、集度也南。結果就疋,能使基布2的纖維之比^面積 相對於以往的不織布來說增加。例如,以以往的紡黏法製作的不 .織布其纖維直徑一般為20μπι左右,但本實施形態的不織布能以 ❹ΙΟμηι左右的纖維直徑製作。其原因考以後述方式,把從喷嘴擠出 的纖維再用後續步驟加以延伸。若纖維直徑在2〇jUm的情況下與 纖維直徑在ΙΟμπι的情況下之每單位長度纖維重量相同,直徑” 2〇μπι的纖維1根相當於直徑10μιη的纖維4根。但是,因表^面積 與周長成比例,所以變成纖維直徑在l〇pm的情況下具有纖維直 徑在20,情況下的2倍表面積。因為電解電鍍是透過化學反應, 在與電鍍液接觸的被鍍物形成金屬的技術,所以金屬是在各纖^ 的表面形成。因此,所形成的金屬之體積與表面積,並非依賴於 基布,表面積,而是構成基布2的纖維之總表面積。故,在本實 施形態的基布2中能使更多金屬附著於纖維層。 ❹[0020] 又,在依照本實施形態的不織布中,因為纖維互相約為平行 的呈直線狀重疊,纏絡少,纖維在纖維排列層的表面以密集的狀 態露出。雖然因為電鍍液會滲透入基布的内部,金屬也會在基布 的内部形成,但是最容易附著金屬的還是纖維排列層的表面與附 近丨然後,在本實施形態中,因為基布表面的纖維之接液面積有 所增加’所以金屬的附著效率增大。換言之,相對於以往的基布 需要從基布表面朝厚度方向將金屬附著到相當的深度,本實施形 態j基布在表面的附著效率高,即使將金屬以比以往更淺的深度 ,著也能得到充分的附著量。其結果,就是促進片材的薄片化盥 輕量化。 200942152 [0021] 本實施形態的基布由延伸的方式形成,原本就比以 ί 2布纖薄(厚度小)。故,完成的片材比起以往更薄。又,由於 纖f度讓電鐘液的渗透效率提高,金屬附著效率也更加 =署二?成更加薄片化與輕量化。這-點,對於小型 是摘電話等等來說是重要的優點。而且,這 -與ΐ管、運送等處理上的容易度也有關。一般在以 -遍中’單位面積重量在3Gg/m2左右的情況下,厚度為 左^但是本實施形態的基布在單位面積重量為聊 ©障況下’厚度能降低到ΙΟΟμηι左右。 [0022] 、祕二,本Ϊ施形態的基布由連續的長纖維構成,浸入電鑛 於纖堆洛’從防止污染電鍍液的觀點來看亦為有利。由 初Γ也有即使在長期的使用下’基布仍容易保持最 初的狀態、不容易發生強度降低的優點。 [0023] ’、 唆屮’本實施形態的基布實際上不含有在常溫下具揮發性或 加劑,以及具揮發性或滲出性的加工_。-般不^ © 提ί紡絲性、加卫性或延伸性,本身就含有各種的添加物, ,為=複雜賴絡在—起,有必要防止靜電或降低延伸時的 這些目的而使用含有油成分的添加劑或加卫助劑。但是,_ 中為了提高金屬的附著性,有必要將被鑛物的Σ面 •因各步驟必要的加工助劑。舉例而言’以往的不織布, 或洗淨達到潔淨的狀態。本實施形 二22直線狀侧、排列不均現象少,在延伸時纖‘ΪΪ 金屬匕而且/也因為不容易帶靜電*不需要油成分。因此, 金屬對基布的附者性良好。 [0024] [〇〇25^下來’說明關於使用上述片材料種實施形態° 200942152 之概=ί ^用本ί Ξ之片材作為電磁波屏蔽用#材的行動電話 42設細神43與操作部 示)也與_部43 ί揚聲料及職,中未顯 要產生源的天線匡體42的内部,更有為電磁波主 杧體42的内面透過接著劑、黏著膠帶等黏接 磁波屏蔽用片材46。雖紋㈣為與基地台通ϊΐί 45位於雷HI因而置於電磁波屏蔽用片材46的外侧’但電路板 幻位於電磁波屏蔽用片材46 电錢 [0026] ❹ 難以動電話41中,從天線47釋放的電磁波變得 的内部’緩和細電路板45上麟置的各種元 的重量增加也小’而且又因為輕量,對於行動電話 [0027] ϋ。本發明之片材作為電磁波屏蔽的壁紙之概略剖面 帶壁紙本體52與電磁波屏蔽用片材53以黏著膠 =構造。麵51以壁紙本體52面向房間的内部空 Ζ 57 ’用接者劑56與鋼筋混凝土製的牆壁 電器產品產生的電磁波為簡ζ或6么= 可說是即使以混凝土也很難屏蔽。將本實施形態的 [ί〇28Γ,應用於住家或醫院⑽壁,能提高牆壁的電磁屏蔽性能。 於太不只應用於混凝土製牆壁,亦同樣能應用 =把住=的砂㈣•壁。又,也可關應需求用於天花板或地板, 更可以預紐设在建築體内部。又,也可以用 等各種可期望具電磁波屏蔽效果的建築物二。門或暴風 帶』,應用本發明之片材作為電線用電磁波屏蔽膠 帶的例子。圖6A為概念性侧視圖,圖6B為概念性剖面圖。電線 200942152 61為由數條被覆電線62集合之構 被覆電線62之間由稱為介為^ t #其整體被外皮63所包覆。 62的集合體上,有螺μ 填材料所充填。在被覆電線 用電磁波屏蔽膠165不工只能電磁波屏蔽膠帶65。電線 蔽從被覆魏62產生的電磁^。魏線62价也能有效的屏 [0030] 、在本實施形態使用的電磁波屏蔽膠帶6 式纖層互相垂直,可二堇由1片纖維排 ❹ 繞方向產生,電線用電磁波屏蔽膠帶65的纏 致為佳1中的箭頭表示纖維 [0031] 垂直:基ί其層的纖維排列層互相 數伸方㈣成互相平行的方式將複 曰=賴增重疊形成的基布。又,雖然在本實施形 ❹ “ίίίΐ集合的構造’但亦能以在—條裸線上以螺i式纏繞 傳向外界的電磁波。例如以電力輸配線、工』 外部=、,:線4作域表例子。又,可反過來料希望受到 g部電磁波影響的電線抑制由外界傳向電線的電磁波之^良^ 如吨魏的峨傳鱗作域糊。 ,、 -田來針對以上說賴基布2的製造方法加以說明。圖7顧 作構成基布的纖維排列層之製造裝置的概略圖。纖唯排 裝置21包含主要_模24與輸送帶25所構成織的= =兀22,U及由延伸缸筒26a、26b、拉取軋輥27a、27b 的延伸單το 23。溶嘴模24的前端(下端)包含多數相對於紙面垂 200942152 直方向並列的喷嘴28(在圖中僅顯示 3示)送入·化樹脂3〇從噴嘴28擠出中士 壓埶、·*· 32 32b。加熱到樹脂溶點以上的高 [熱空―送人―職室32a、32b = ,與_ 32a、32b連通的狹縫说、口 纖維31之擠出方向約為平行的高速氣流。ί 壯能同ί”、’ f喷嘴28擠出的纖維31被維持在可牽伸的熔化 狀心’透過尚速氣流的摩捧力對繡维3 .僻仆古、*々& ^ +手4刀對纖維31賦予牽伸,使纖維31細 ❹ ϋ同叙流的溫度比_31的紡絲溫度高_以上 i^c以上。在使贿喷模24形成纖維31的方法中,因為^由以 能使剛從喷嘴28播出的纖維31之溫度充曰分高 31的熔點,所以能使纖維31的分子定向變小。 動、24的下方配置著輸送帶25。輸送帶25繞掛在由驅 =、(圖中未顯示)旋轉的輸送帶輥29或其他親上轉動,並藉由輸 ,甲輥29的旋轉來驅動輸送帶25,把從喷嘴28擠出的 j 朝圖式的右方向運送。 、、· [0034] ^纖維31沿著從喷嘴28兩侧的狹縫33a、33b喷出之高壓埶空 成的高速氣流流動。高速氣流由狹縫33a、33b嘴出的'高'壓 匯流,並在與輸送帶25的運送面約為垂直的方向流動。 古、,嘴模24與輸送帶25之間,設有喷霧嘴35。噴霧嘴35為朝 =迷氣流噴出霧狀水滴的器具,藉此冷卻纖維31,急速的凝固。 =然實際上設有多個喷霧嘴35,但在圖7中僅顯示1個。從噴霧 ^ 35喷出的流體’只要是能冷卻纖維31者即可’並不一定需要 3有水分等物,亦可為冷空氣。 [0036] 訊在炫噴模24附近’由狹縫33a、33b產生高速氣流的區域, 攻有彳隋圓柱形的氣流振動機構34。氣流振動機構34繞著軸34a 11 200942152 •==直轴1:^=上的纖.㈣之 平行。-般來說,在氣體嫌_ 排列層之寬方向約為 喷时钟在踏壁的時 氣机振動機構34利用此康達效應改變纖維31 L、、*,'、、康達效應。 況,氣流振動機構34之橢圓形的長轴與高&=。圖5的情 -向)-致時,纖維31朝向輸送帶25約為;^落;上下方 構34繞著34a旋棘90 -,曰名、&4£广私直洛下。當氣流振動機 -速氣流方向垂直時,纖維\朝輸^ 2=4 =圓,長軸與高 ❹偏移,且偏移量在此時達到最大。若氣、方向d(圖中右側) :動纖r朝輸送帶25的七 也,,將凝_維31在縱方 、i5維上轉,麵㈣有—料㈣錢魏細來, [0037] U帶25上收躺纖維31,藉由輸 ,:被已加制延伸溫度的延伸缸筒 向延伸缸筒26b。之後,纖維31移到延伸缸 移 ❹5i:i73f;貼1貼ί兩個延伸W6a、-上。 '為在縱方向為部分輸送’_31成 -網布。 强豐狀心的障況下,鄰接之纖維31彼此炫接的 [0038] 貼在延伸缸筒加、·同時輪送所得到的網布,再以 Μ他々*轉逆延伸缸同施、挪局,因此網布朝縱方向 i:方延:、ΐ維排列層38。如此,藉由將經過紡絲的網布 伸’能使絲的排列性更加向上提升。由於纖維31被充 了拉伸應力小延伸度大的纖維31。這是以上述 > 3 k喷霧鳴35喷出霧狀的水滴’使高速氣流包含霧狀的 12 200942152 液體來實現。用上述方法形成的纖維排列層,输 單方向集中。 纖維的方向會朝著 [0039] 如前述,在製造此纖維排列層的各步驟中並 分的添加劑或加玉助劑。具體來說,是在纖維31= 時(紡絲轉),未㈣含有油齡的添加_加:胃ϋ 在輸送帶25上的收集、纖維延伸之各步驟中, 劑或加工助劑。因此4成後的纖維排列層 = 添加劑或加工助劑。 二 [0041] 將如此製造的纖維排列層,以纖維方向 堆疊並熱壓接,減上述布2。 ㈣直的方式依序 【圖式簡單說明】 圖1為與本發明一實施形態有關的片材之剖面圖。 圖2為圖1所示基布的分解立體圖。 圖3為圖1所示的基布的局部分解立體圖。 之概財發明之㈣料魏波祕W材的行動電話 ❹圖。圖5為使用本發明之片材作為電磁波屏蔽的壁紙之概略剖面 圖6A為使用本發日月之片材的電線之概略圖。 圖6B為圖6A所示電線的剖面圖。 圖7為用於製作纖維排列層的製造裝置之概略圖。 【主要元件符號說明】 片材 基布 電鍍部 纖維排列層 1 2 3a、3b200942152 VI. Description of the invention: [Technical field to which the invention pertains] [0001] [Prior Art] [0002] In the case of the transfer in Xuxiang, it is still private (4)_. For example, on the small electronic communication device, the noise and malfunction caused by the electromagnetic waves emitted by the electric power line and the factory (10) power line are used for high performance. In the field of the automobile, there is a lot of electronic equipment. Because of the health awareness in recent years, or the suppression of the influence of the electronic parts that have become heavy, there are many devices in the factory. Concerns about the users of the device and the patients with electromagnetic allergies, the demand for electromagnetic wave shielding is increasing in the home and in the hospital. Hospital [0003] ❿ These electromagnetic wave shields are often used for the plating of metal fibers, non-woven fabrics, etc. (10). For example, refer to Japanese _ 2_韵877号号 2 [Summary of the Invention] [0004] The more the electromagnetic wave shielding characteristics of the gold ladder L 附着 attached to the substrate by the electric ore step, the higher the electromagnetic shielding property is. However, the material. The fiber is thick and straight and becomes a high-strength polymer fiber of the general spunbonded nonwoven fabric, and its surface area is limited by the diameter ϋ 200942152 * Generally, the electroless plating of the sheet for electromagnetic wave shielding, 2 = de-energizing Shot, because the metal is in the wetted part of the beak and the plating solution (the wind, the surface area of the right fiber is small, and the amount of metal adhesion is also relatively small. The right increase in the amount of adhesion increases the film thickness of the substrate. Because the penetration of the electro-hydraulic liquid is limited, the result becomes insufficient to allow the plating solution to penetrate into the inside of the substrate, only the weight of the area (the weight of the unit surface) and the thickness of the substrate. However, electromagnetic wave shielding is strongly required depending on the application. In the lightweight, the case of the two movements, the density of the parts has reached the limit, and it is also required to be more ambiguous. It must be avoided to avoid the substrate that does not contribute to the electromagnetic wave shielding function. In terms of electromagnetic shielding for parts, it is also lightweight, and it is desirable that the substrate be as thin as possible. In view of the above problems, the aim is to provide various kinds of i-uses for lightweight, thin-film and metal-shielding effects. Providing electromagnetic waves using the sheet [0007] The layer is composed of a sheet comprising a base fabric comprising a base fabric comprising at least one strand and at least one side of the base fabric extending linearly. i no: ί = the direction of the soap is about linear, - the side of the (four) with rft. The length of the fiber is extended, the diameter of the fiber is tightened, and the specific surface area of the fiber (the surface area per unit volume is quite dependent) The specific surface area of the fiber n is = the ratio of the surface area of the metal to the raw surface, and the direction of the fiber used in the vicinity of the surface of the base fabric is (4) Λ 录 录 录 站 u u 由 由 由 由 连续 连续 连续 连续 连续 连续 连续 连续 连续The fiber filling efficiency is improved, and it is possible to make a slim = ίίί, extending the fiber to the inside of the sheet and extending neatly, 200942152 K in the ίΐί full and the metal adhesion efficiency becomes higher, the advantage of "slice", 'with rotten The slimness characteristics complement each other, and there are also [0009] the base fabric contains a plurality of layers of fiber alignment layers, and the inter-dimensional alignment layers are stacked in such a manner that the length directions of the long fibers are different from each other... ❹ Magnetic wave shielding sheets, wallpapers, electricity [ 0011] According to the present invention, it is possible to provide a light-weight, thin-brown type of use---the present invention is to use an electromagnetic wave screen of the present invention. [Embodiment] [0014] An embodiment of a sheet of the invention of the present invention is shown in FIG. :== Fig. The sheet 1 comprises a base fabric composed of a non-woven fabric, which is referred to as a _table_metal, but a singularity, and is called a layer in the form of a layer. The plating portion 3a 3b/ ΓElectrical diagram base cloth 2 is formed on both sides, only on any one-sided surface ^ can make 3a,% _ electric micro-thief wire, Z make: fruit 'steel is mainly responsible for electromagnetic wave shielding effect, recorded the main [0015] The adjustment is adjusted by changing the time during which the base cloth 2 is immersed in the plating solution. The base cloth is immersed in the electric ore liquid for a short time, and the metal adhesion amount which is not the original gas permeability of the 200942152 cloth can be obtained. If it is immersed for a longer period of time, the amount of metal attached can be such that the plating portions attached to the respective fibers are connected to each other. 2 is an exploded perspective view of the base fabric. The base fabric 2 is composed of a plurality of layers of fiber alignment layers in which a plurality of continuous long fibers are arranged in a straight line extending in a single direction. Although four fiber array layers 12A, 12B, 12C, and 12D are shown in the drawing, the number of stacks can be appropriately determined, and it is not necessary to have only one sheet depending on the application, which will be described later. The fiber array layers 12A, 12B, 12C, and 12D are thermocompression bonded to each other to form a base fabric φ [〇〇17] Fig. 3 is a partial perspective view showing an enlarged portion of the fiber array layer of the base fabric. Although only the fiber alignment layers 12A and 12B are shown in the figure, the other fiber layers are also of the same structure. As shown in the figure, the fiber contact 12A is an aggregate of a plurality of fibers 13A which are flat and linearly extended. Similarly, the fiber arranging layer 12B is a collection of a plurality of scales 13B extending linearly from each other. There are also cases where the fibers 1 =, 13B are stacked on the two sides of the towel. It is made of a thermoplastic resin such as polypropylene ray, polyester, polyester, polyamide, polystyrene resin, or a modified resin. It is also possible to make the acrylonitrile-based resin or the like related to the wet or dry spinning method = the fiber extending direction of the fiber layer is 15 Β Β 昼 定 定 定 定 定 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 相邻 维 维 维 维 维 维 维: Two or more sheets of fibers may be continuously: Column layer: same: extension::: [0018] 200942152 The basis weight of the base fabric is preferably 5 g/m 2 or more and 60 g/m 2 or less. It is also possible to provide adhesive tape, adhesive material, etc. on one or both sides of the base fabric. [0019] * The fibers 13a, 13B, 13C, 13D of the respective fiber arrays Zhan 12A, 12B, 12C, and 12D are arranged to extend in the extending directions 15A, 15B, 15C, and 15D. Therefore, the linearity and the directivity of the fiber are extremely higher than those of the nonwoven fabric produced by the conventional melt blow method, and the maleness and the degree of the fiber are also south. As a result, the ratio of the fiber area of the base fabric 2 can be increased with respect to the conventional nonwoven fabric. For example, the nonwoven fabric produced by the conventional spunbonding method generally has a fiber diameter of about 20 μm, but the nonwoven fabric of the present embodiment can be produced with a fiber diameter of about ημηι. The reason for this is to extend the fiber extruded from the nozzle in a subsequent step. If the fiber diameter is 2〇jUm and the fiber weight per unit length is the same as the fiber diameter in the case of ΙΟμπι, the fiber of the diameter "2〇μπι corresponds to 4 fibers of 10 μm diameter. However, due to the area of the surface It is proportional to the circumference, so it has a fiber diameter of 1 pm and has a fiber diameter of 20, which is 2 times the surface area. Since electrolytic plating is a technique of forming a metal by a chemical reaction and a plated material in contact with a plating solution, Therefore, the metal is formed on the surface of each fiber. Therefore, the volume and surface area of the formed metal do not depend on the base cloth and the surface area, but the total surface area of the fibers constituting the base fabric 2. Therefore, the base of the present embodiment is In the cloth 2, more metal can be attached to the fiber layer. [0020] Further, in the nonwoven fabric according to the present embodiment, since the fibers are linearly overlapped with each other in parallel, the entanglement is small, and the fibers are arranged in the fiber arranging layer. The surface is exposed in a dense state. Although the plating solution penetrates into the interior of the base fabric, the metal is formed inside the base fabric, but the metal is most likely to adhere. Then, in the present embodiment, since the liquid contact area of the fibers on the surface of the base fabric is increased, the adhesion efficiency of the metal is increased. In other words, the base fabric is required from the conventional base fabric. The surface of the present invention has a high adhesion efficiency on the surface of the base fabric in the thickness direction, and a sufficient adhesion amount can be obtained even if the metal has a shallower depth than the conventional one. The sheet is lightened and lightened. 200942152 [0021] The base fabric of the present embodiment is formed by an extension method, which is thinner than the ί 2 cloth (thickness is small). Therefore, the finished sheet is thinner than before. Moreover, since the fiber f degree improves the penetration efficiency of the electric clock liquid, the metal adhesion efficiency is also more tangled into a thinner and lighter weight. This is an important advantage for small phones and the like. Moreover, this is also related to the ease of handling such as manifolding, transportation, etc. Generally, in the case where the weight per unit area is about 3 Gg/m2 in the -pass, the thickness is left, but the base fabric of the present embodiment The weight per unit area is less than the thickness of the ΙΟΟμηι. [0022], secret two, the base fabric of this configuration is composed of continuous long fibers, immersed in electric ore in the fiber pile 'from pollution prevention plating It is also advantageous from the viewpoint of the liquid. From the beginning, the base fabric is easy to maintain the initial state even if it is used for a long period of time, and the strength is not easily reduced. [0023] ', 唆屮' The cloth does not actually contain volatility or addition at room temperature, and has a process of volatility or exudation. _--------------------------------------------------------------------------------------- For the purpose of preventing static electricity or reducing the purpose of stretching, it is necessary to use an additive or a auxiliaries containing an oil component. However, in order to improve the adhesion of the metal, it is necessary to The surface of the minerals • The processing aids necessary for each step. For example, 'the previous non-woven fabric, or washed to a clean state. In the present embodiment, the linear shape of the second embodiment 22 is small, and the unevenness of the arrangement is small. When the fiber is stretched, it is not required to carry static electricity. Therefore, the metal is excellent in attachment to the base fabric. [0024] [〇〇25^下下] Description of the use of the above-mentioned sheet material type embodiment 200942152 Overview = ί ^ Use this sheet of 作为 作为 as the electromagnetic wave shielding #材的电话电话42 细神43 and the operation department In addition, the inside of the antenna body 42 in which the source is not generated, and the inner surface of the electromagnetic wave main body 42 is permeable to the magnetic wave shielding sheet by an adhesive or an adhesive tape. 46. Although the pattern (4) is located at the outer side of the electromagnetic wave shielding sheet 46 with the base station ϊΐ 45, it is placed on the outer side of the electromagnetic wave shielding sheet 46. However, the circuit board is located in the electromagnetic wave shielding sheet 46. [0026] 难以 In the difficult telephone 41, the slave antenna The electromagnetic wave released by 47 becomes the internal 'lower weight of the various elements on the thin circuit board 45. The weight increase is also small' and because of the light weight, for the mobile phone [0027] ϋ. The sheet of the present invention is a schematic cross-section of a wallpaper for electromagnetic wave shielding. The wallpaper body 52 and the electromagnetic wave shielding sheet 53 are formed by an adhesive = structure. The surface 51 is such that the electromagnetic wave generated by the connector body 56 and the reinforced concrete wall electrical product with the wallpaper body 52 facing the room is simple or 6 = it can be said that it is difficult to shield even with concrete. Applying the "[25] to the wall of the home or hospital (10) of this embodiment can improve the electromagnetic shielding performance of the wall. It is not only used in concrete walls, but also in the sand (four) wall. In addition, it can also be used for ceilings or floors, and can be pre-installed inside the building. Further, it is also possible to use various types of buildings which can be expected to have an electromagnetic wave shielding effect. A door or a storm belt, the sheet of the present invention is applied as an example of an electromagnetic wave shielding tape for electric wires. Fig. 6A is a conceptual side view, and Fig. 6B is a conceptual cross-sectional view. The electric wire 200942152 61 is composed of a plurality of covered electric wires 62. The covered electric wires 62 are covered by a skin 63 as a whole. The assembly of 62 is filled with a screw-fill material. In the covered electric wire, the electromagnetic wave shielding adhesive 165 is used only in the electromagnetic wave shielding tape 65. The wire is shielded from the electromagnetic generated by the coated Wei 62. The screen of the Wei line 62 can also be effective [0030]. The electromagnetic wave shielding tape 6 used in the present embodiment is perpendicular to each other, and can be produced by a fiber winding direction, and the electromagnetic wave shielding tape 65 of the electric wire is wrapped. The arrow in Fig. 1 indicates that the fiber [0031] is perpendicular: the base fabric in which the fiber alignment layers of the layers are mutually parallel (4) in a manner parallel to each other to form a base fabric. In addition, although in the present embodiment, the structure of the ί " ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί In the case of the domain table, in turn, it is expected that the wire affected by the electromagnetic wave of the g part suppresses the electromagnetic wave transmitted from the outside to the wire, such as the ton of Wei, which is the domain paste of the ton. A method of manufacturing the base fabric 2 will be described. Fig. 7 is a schematic view showing a manufacturing apparatus of the fiber array layer constituting the base fabric. The fiber array apparatus 21 includes the main mold 24 and the conveyor belt 25 to form a weave ==兀22, U and the extension single το 23 of the extension cylinders 26a, 26b and the take-up rolls 27a, 27b. The front end (lower end) of the nozzle mold 24 includes a plurality of nozzles 28 juxtaposed in a straight direction with respect to the paper surface sag 200942152 (only shown in the figure) (3)) The resin is supplied, and the sergeant is pressed from the nozzle 28, and the sergeant is pressed, and the heat is applied to the resin melting point or higher. [Hot air-delivery-office 32a, 32b =, and _ The slits of 32a and 32b are connected, and the extrusion direction of the port fibers 31 is about parallel high-speed airflow. The fiber 31 which can be extruded with the ί", 'f nozzle 28 is maintained in the meltable heart of the draftable 'through the speed of the air force of the force of the pair of embroidery. 3. 僻古古, *々& ^ + hand 4 The blade imparts a draft to the fiber 31 so that the temperature of the fiber 31 is higher than the spinning temperature of _31 by more than or equal to i^c. In the method of forming the fibers 31 into the bristle spray mold 24, the molecular orientation of the fibers 31 can be made small by melting the temperature of the fibers 31 which have just been discharged from the nozzles 28 to a height 31. A conveyor belt 25 is disposed below the movements 24 . The conveyor belt 25 is wound around a conveyor belt roller 29 or other parent that is rotated by a drive, (not shown), and is driven by the rotation of the nail roller 29 to drive the conveyor belt 25 to be extruded from the nozzle 28. j is transported in the right direction of the schema. [0034] The fiber 31 flows along a high-speed airflow which is ejected from the slits 33a, 33b on both sides of the nozzle 28. The high-speed airflow is converged by the 'high' pressure of the slits 33a, 33b, and flows in a direction approximately perpendicular to the conveying surface of the conveyor belt 25. In ancient times, a spray nozzle 35 is provided between the nozzle mold 24 and the conveyor belt 25. The spray nozzle 35 is an appliance that ejects misty water droplets toward the airflow, thereby cooling the fibers 31 and rapidly solidifying. = Actually, a plurality of spray nozzles 35 are actually provided, but only one is shown in FIG. The fluid ejected from the spray ^ 35 may be any one that can cool the fiber 31. It is not necessarily required to have water or the like, and may be cold air. [0036] In the vicinity of the squirting die 24, a region where the high-speed airflow is generated by the slits 33a, 33b attacks the airflow vibrating mechanism 34 having a cylindrical shape. The air stream vibrating mechanism 34 is parallel to the shaft 34a 11 200942152 •==straight axis 1:^=the upper fiber (4). In general, the width of the gas _ aligning layer is about the time when the jet clock is at the tread wall. The gas vibration mechanism 34 uses the Coanda effect to change the fibers 31 L,, *, ', and the Coanda effect. In other words, the long axis of the elliptical shape of the air stream vibrating mechanism 34 is high &=. In the case of Fig. 5, the fiber 31 is oriented toward the conveyor belt 25; the upper and lower structures 34 are wound around the 34a spine 90-, and the nickname, & When the airflow vibrator-speed airflow direction is vertical, the fiber \ toward the input ^ 2 = 4 = circle, the long axis is offset from the high ,, and the offset reaches the maximum at this time. If the gas, the direction d (the right side in the figure): the moving fiber r to the conveyor belt 25 of the seven, the condensation _ dimension 31 in the vertical direction, i5 dimension up, the surface (four) has - material (four) Qian Wei fine, [0037 The U-belt 25 is provided with the draping fiber 31, and is transported by the extension cylinder that has been extended to the extension cylinder 26b. Thereafter, the fiber 31 is moved to the extension cylinder ❹ 5i: i73f; the sticker 1 is attached to the two extensions W6a, -. 'For the part to convey in the longitudinal direction'_31 into a mesh. In the case of a strong heart-shaped heart, the adjacent fibers 31 are spliced together with each other [0038] attached to the extension cylinder, and the mesh obtained by the same rotation, and then the extension of the cylinder Moved, so the mesh is oriented in the vertical direction i: square extension: ΐ dimension array 38. Thus, by arranging the spun mesh, the alignment of the filaments can be further increased. Since the fiber 31 is filled with the fiber 31 having a small tensile stress and a large elongation. This is achieved by the above-mentioned > 3 k spray sound 35 ejecting a mist-like water droplet 'the high-speed air stream containing a misty 12 200942152 liquid. The fiber alignment layer formed by the above method is concentrated in one direction. The direction of the fibers will be toward the additive or jade auxiliary in the steps of producing the fiber alignment layer as described above. Specifically, in the case where the fiber 31 = (spinning), the (four) contains the oil age of the addition_addition: the stomach sputum on the conveyor belt 25, the fiber stretching step, the agent or processing aid. Therefore, after 4% of the fiber alignment layer = additive or processing aid. [0041] The fiber alignment layers thus produced are stacked in the fiber direction and thermocompression bonded to reduce the cloth 2 described above. (4) Straight mode in order [Simplified description of the drawings] Fig. 1 is a cross-sectional view of a sheet according to an embodiment of the present invention. Fig. 2 is an exploded perspective view of the base fabric shown in Fig. 1. Fig. 3 is a partially exploded perspective view of the base fabric shown in Fig. 1. (4) The mobile phone of Wei Bo secret W material. Fig. 5 is a schematic cross-sectional view of a wallpaper using the sheet of the present invention as an electromagnetic wave shield. Fig. 6A is a schematic view of an electric wire using a sheet of the present invention. Figure 6B is a cross-sectional view of the electric wire shown in Figure 6A. Fig. 7 is a schematic view showing a manufacturing apparatus for producing a fiber alignment layer. [Description of main component symbols] Sheet base fabric Plating section Fiber alignment layer 1 2 3a, 3b

12A、12B、12C、12D 13 20094215212A, 12B, 12C, 12D 13 200942152

13A、13B、13C、13D 纖維 15A、15B、15C、15D 延伸方向 21 纖維排列層製造裝置 22 紡絲單元 23 延伸單元 24 熔喷模 25 輸送帶 26a、26b 延伸缸筒 27a、27b 拉取軋輥 28 喷嘴 29 輸送帶棍 30 熔化樹脂 31 纖維 32a ' 32b 儲氣室 33a、33b 狹缝 34 氣流振動裝置 34a 轴 35 喷霧嘴 36 推壓輥 37 推壓輥 38 縱延伸纖維排列層 41 行動電話 42 框體 43 顯示部 44 操作部 45 電路板 46 電磁波屏蔽用片材 47 天線 51 壁紙 52 壁紙本體 14 200942152 53 電磁波屏蔽用片材 54 黏著膠帶 55 牆壁 56 接著劑 57 房間的内部空間 61 電線 62 被覆電線 63 外皮 64 介在 65 電線用電磁波屏蔽膠帶 ❿ 1513A, 13B, 13C, 13D Fibers 15A, 15B, 15C, 15D Extension direction 21 Fiber alignment layer manufacturing apparatus 22 Spinning unit 23 Extension unit 24 Melt blowing mold 25 Conveying belts 26a, 26b Extension cylinders 27a, 27b Pulling rolls 28 Nozzle 29 conveyor belt 30 melted resin 31 fiber 32a ' 32b gas storage chamber 33a, 33b slit 34 air flow vibrating device 34a shaft 35 spray nozzle 36 pressing roller 37 pressing roller 38 longitudinally extending fiber array layer 41 mobile phone 42 frame Body 43 Display portion 44 Operating portion 45 Circuit board 46 Electromagnetic wave shielding sheet 47 Antenna 51 Wallpaper 52 Wallpaper body 14 200942152 53 Electromagnetic wave shielding sheet 54 Adhesive tape 55 Wall 56 Adhesive 57 Room internal space 61 Wire 62 Covered wire 63 Skin 64 with electromagnetic wave shielding tape for 65 wires ❿ 15

Claims (1)

200942152 . 七、申請專利範圍: 維排=㈣帛1項之狀,財絲耗賴數層該纖 _長纖他的該纖維排列層,以該 &lt; 其中該—部分喊維排列層 ❹他的纖維排列層’關長纖維之延伸方向互相垂直的方式 為5g/i : 1專^ :;項之片材’其中該基布的單位面積重量 黏接=請專麵第1項之片材,其中該基布的其中一面設有 材。6·一種電磁波屏蔽用片材,包含如申請專利範圍第t項之片 7.一種壁紙,包含如申請專利範圍S 1項之片材。 片材&amp;-種電線用電磁波屏蔽膠帶,包含如中請專利範圍第i項之 ❾ 八、圖式: 16 0200942152 . Seven, the scope of application for patents: dimension row = (four) 帛 1 item shape, the financial wire is consuming several layers of the fiber _ long fiber his fiber aligning layer, with the < 其中 — 部分 部分 维 排列 排列The fiber alignment layer 'the direction in which the length of the fibers is perpendicular to each other is 5g/i : 1 special ^ :; the sheet of the item 'where the weight per unit area of the base fabric is bonded = please refer to the sheet of the first item Wherein one side of the base fabric is provided with a material. 6. A sheet for electromagnetic wave shielding comprising a sheet as in the t-th article of the patent application. 7. A wallpaper comprising a sheet as claimed in claim S1. Sheet &amp;-Electrical wave shielding tape for wire, including item i of the patent scope ❾ VIII, drawing: 16 0
TW097150643A 2007-12-26 2008-12-25 Sheet material, electromagnetic shielding sheet material, wallpaper, and electromagnetic shielding tape for electrical wiring TWI435688B (en)

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WO2011010697A1 (en) * 2009-07-24 2011-01-27 旭化成せんい株式会社 Electromagnetic shielding sheet
FR2954378B1 (en) 2009-12-18 2013-08-30 Zodiac Pool Care Europe IMMERSE SURFACE CLEANING APPARATUS WITH HYDRAULIC CABRAGE
JP6233957B2 (en) * 2013-08-26 2017-11-22 槌屋ティスコ株式会社 Laminated sheet, molded product and method for producing the same
KR101423169B1 (en) 2014-03-04 2014-07-28 톱텍에이치앤에스 주식회사 A Method for Manufacturing of Shield Sheet for Preventing Electromagnetic Wave

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JPS6178627A (en) * 1984-09-26 1986-04-22 Kyowa Sangyo Kk Method of welding cloth
JPH0331557Y2 (en) * 1984-10-29 1991-07-04
JPS62204399A (en) * 1986-03-05 1987-09-09 株式会社東芝 Measuring apparatus with disconnection detecting function
JPH034079Y2 (en) * 1986-06-18 1991-02-01
JPH0513983A (en) * 1991-07-05 1993-01-22 Kitagawa Ind Co Ltd Elastic conductive member and manufacture thereof
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