200918695 九、發明說明： 【發明所屬之技術領域】 本發明係，-種含有咖啡㈣、_製備綠，以及一種含有 咖a#清的新紗線。 【先前技術】 近年來-種能夠隨著皮膚溫度變化進行熱量調節的功能性纺織 品的設計和研製吸引了人們越來越多的注意。在此領域進行的大量嘗 試不亞於在電子、太陽能裝置以及建築等方面所做的研究。然而 功應用的很少且這些應用仍在研究中。 & ^所周知’各種材料例如織物、服$和其他服射 2與所述材料有關的性能特性。這些性能特性包括，例如二臭來 “度控制、防紫外線，和/或防止外界因素的影響。 … =些㈣在沒有輯鱗_鱗加㈣職具林 性3=未經處理的材料例如萊卡製成的衣服具有彈 防紫外線的特性。此夕tmr斗’其可能不具有其他例如除臭或 ^。才科的性能特性通常是有限的，且不能充分地增強所述材二2 會揮發。 辦界自然銥境時’化學試劑可能 200918695200918695 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a coffee containing a coffee (four), a green preparation, and a new yarn containing a coffee. [Prior Art] In recent years, the design and development of functional textiles capable of performing heat adjustment with changes in skin temperature have attracted more and more attention. A lot of trials in this area are no less than research in electronics, solar installations and construction. However, there are few applications and these applications are still under study. & ^ is well known to the performance characteristics associated with various materials such as fabrics, garments, and other garments. These performance characteristics include, for example, two odors to "degree control, UV protection, and / or to prevent the influence of external factors. ... = some (four) in the absence of scales _ scale plus (four) job forest 3 = untreated materials such as Lycra The finished garment has the property of being UV-resistant. This may not have other properties such as deodorization or deodorization, and the performance characteristics of the genus are generally limited and cannot sufficiently enhance the volatilization of the material. When conducting a natural environment, 'chemical reagents may 200918695
==:r:需==在“ ’其具有期望的例如織紋和 一一一，〜使用後仍能保持==:r: need == in " ' it has the desired texture such as texture and one by one, ~ can still be maintained after use
已經嘗試過在生產織物前，崩 線上。活性炭是一種具有不 d AA曰Ϊ方法疋將活性炭層夾在兩層織物中間’而應用這種技術得 ^的具有除臭功能的織物报重，穿起來比較麻煩。另-種已經嘗試的 方法疋將雜炭摻進包覆所樣_覆蓋層。然而_方法 線的物理性質。 、" ^類活動給環境產生了衫令人不愉㈣氣味。這些氣體的性質 由於氣體顆粒的物理狀態和化學性f或形成原因（生物分解作用、化 學製劑、吸煙等）不同而有报大區別。此外，這些令人不愉快的氣味 也產生於我們每天生活的空間和環境，例如浴室、麟、垃圾、 煙霧的封閉環i竟（酒吧）等等。因此，人們開發出許多方法來阻 種令人不愉快的氣味。 【發明内容】 長久以來咖啡渣被看作咖啡飲品製成之後的垃圾’然而本發明透 過將咖啡渣用於製備紗線中而提供一種回收利用咖啡渣的環保方法。 200918695 本發明係關於一種製備含有 一種含有咖抛的材料；⑹將此的紗線的方法，包括⑷提供 備母粒；⑺將所述母粒抽絲成紗it尚分子聚合物顆粒混合以製 的咖啡渔、微膠囊化的供培過的咖啡,、杳本===料=是烘培過 f的從咖餅提取的具有香味的;機====Attempts have been made to collapse on the line before the fabric is produced. Activated carbon is a fabric with a deodorizing function that has a non-d AA 曰Ϊ method and sandwiches the activated carbon layer in the middle of two layers of fabrics, and it is troublesome to wear. Another method that has been tried is to incorporate the charcoal into the cladding layer. However, the physical properties of the _ method line. , " ^ class activities give the environment an unpleasant (four) smell. The nature of these gases differs greatly depending on the physical state and chemical nature of the gas particles or the cause of formation (biodegradation, chemicals, smoking, etc.). In addition, these unpleasant odors are also generated by the space and environment we live in every day, such as the closed loop of the bathroom, the rubbish, the garbage, the smoke, and so on. Therefore, many methods have been developed to prevent unpleasant odors. SUMMARY OF THE INVENTION Coffee grounds have long been regarded as garbage after the production of coffee drinks. However, the present invention provides an environmentally friendly method for recycling coffee grounds by using coffee grounds in the preparation of yarns. 200918695 The present invention relates to a method for preparing a yarn containing a coffee throwing material; (6) comprising: (4) providing a masterbatch; (7) drawing the masterbatch into a yarn and mixing the molecular polymer particles. Coffee fishing, microencapsulated coffee for cultivating, 杳 = = = = material = is a baked fragrant extract from the coffee cake; machine ====
Γί_成分，之触不含有軸分_合物中—得ί 酿。’ ^明所用—分子聚合物職選自聚丙稀、尼龍或聚 =明還提供紗，其包括紗線和含有咖啡渔的材料。在較佳的實 =式:種:=:::香氣。所述材料中還含有碳: 顆粒 紗線種具有咖啡香氣的紗線’包括由上述方法製成的 /、有咖非香氣的咖啡渣材料。其中該材料中還含⑴ 此外，該卿射时製作衣服。 平織ίϊίίζ提供包含4上述祕的雜。該熱是不織布 【實施方式】 實包例1·製備含有咖啡渣和碳化咖徘顆粒的材料 製備含有咖啡渣的材料 200918695 術語“含有咖啡渣的材料，，包括但不限於烘培過的咖啡逢、微膠囊化 的咖啡潰、微賴化的料精油或微膠囊化的從咖啦巾提取的具有 香味的有機化合物。咖啡渣可以是咖啡店裏磨碎的咖啡豆或咖啡渣渾 經過烘培後而製成。咖啡精油可以從㈣豆中提取。最後將供培過的 咖啡渣或咖啡精油裝入微膠囊。 二、 篩選咖渣或材料 咖啡豆廢料經乾淨的自來水漂洗之後乾燥磨碎成尺寸在2〇至 广 100#m之間的顆粒’將磨碎的咖徘豆直接過篩。除此之外，也可以 i ，咖啡渣滓乾燥並磨碎，再篩選磨碎的混合物。所產生的混合物可被 篩選成在80至100"m之間的不同大小的精細顆粒。 三、 除去過篩後混合物中的有機成分 過篩後的混合物經有機溶劑萃取除去其中的有機成分。脂肪類成 分在索氏提取器中用乙《萃取除去，萃取溫度控制在6代以下。在 之後所有操作中通人雜氣體來盡可能避免與空氣接觸，並且所有溶 劑在使用前需要蒸餾，質類成分用丙酮進行處理，雜在_中的 脂溶性成分在含有5%以上乙醇化氫氧化鉀驗巾回流發生息化反 應，從而除去脂質。皂化反應後的溶液用〇. IN鹽酸酸化後用嗎提 取脂肪酸。除去論雜，含有水雜齡的水減在賴條件下濃 縮乾燥後用絕對酒精提取除去甘油。 四、製備碳化顆粒 從第二步得到的混合物經财碳财法進行碳化。勤，喻啡混 合物在©定床反應时缺氧條件下加熱發生熱解反應，並最終轉化成 我們希望的產物。熱解反應包括碳化侧、氣化作用和活性炭加工過 程’熱解產物是活性炭。咖啡材料的碳化作用通常在氯化辞 '氣化錢、 200918695 氯化弼或魏學試_參與下完成。碳化材料在. 炫爐中先«人氧氣及惰性氣_條件下進行處理 卜 去幾乎所核__化合姊f增加表^^件下可除 在將碳=材料活化之前’先用酸洗或驗洗使其帶有電荷，酸驗 選用取決於碳化反射除去其他齡賴的^Γί_ ingredients, the touch does not contain the axis _ _ _ _ _ The molecular polymer is selected from the group consisting of polypropylene, nylon or poly. The yarn is also provided, including yarns and materials containing coffee fish. In the preferred real = formula: species: =::: aroma. The material also contains carbon: granules Yarns having a coffee aroma' include a coffee slag material made by the above method. Among them, the material also contains (1) In addition, the singer makes clothes when shooting. The plain weave ίϊίίζ provides a miscellaneous containing 4 of the above secrets. The heat is non-woven [embodiment] Example 1 Preparation of a material containing coffee grounds and carbonized coffee grains to prepare a material containing coffee grounds 200918695 The term "a material containing coffee grounds, including but not limited to roasted coffee" Microencapsulated coffee crushed, micro-laid essential oil or microencapsulated scented organic compound extracted from coffee towel. Coffee grounds can be roasted coffee beans or coffee grounds in a coffee shop. It is made later. The coffee essential oil can be extracted from the (four) beans. Finally, the coffee grounds or coffee essential oil for cultivation is filled into the microcapsules. 2. The coffee beans or coffee beans are filtered and washed with clean tap water, then dried and ground into size. The granules between 2〇 and 广100#m will be directly sieved through the ground coffee beans. In addition, i, the coffee grounds can be dried and ground, and the ground mixture is screened. The mixture can be screened into fine granules of different sizes between 80 and 100 " m. 3. Removal of the organic component in the mixture after sieving, the sieved mixture is extracted by organic solvent to remove it. The organic component. The fat component is extracted by extraction in the Soxhlet extractor. The extraction temperature is controlled below 6 generations. In all subsequent operations, the heterogas is introduced to avoid contact with air as much as possible, and all solvents are used before use. Distillation is required, the quality component is treated with acetone, and the fat-soluble component contained in the _ is contained in a 5% or more ethanolated potassium hydroxide test towel, and the lipid is removed to remove the lipid. The solution after the saponification reaction is used. After acidification with hydrochloric acid, the fatty acid is extracted. The water containing the water age is concentrated and dried under the condition of lyophilization, and then extracted by absolute alcohol to remove glycerol. 4. Preparation of carbonized granules The mixture obtained from the second step is financed by the carbon method. Carbation. The mixture of the morphine and the morphine mixture is heated under anoxic conditions for pyrolysis and finally converted into the desired product. The pyrolysis reaction includes carbonization, gasification and activated carbon processing. The product is activated carbon. The carbonization of the coffee material is usually completed with the participation of chlorination, gasification, 200918695 cesium chloride or Wei Xue test. In the blazing furnace, the first «human oxygen and inert gas _ conditions to deal with almost all nuclear __ compound 姊 f increase the table ^ ^ parts can be removed before the carbon = material activation 'first pickling or test Wash it with charge, acid test depends on carbonization reflection to remove other ages ^
侧采_紐，但_ _是通人驗_ π或-氧化㈣體處理碳化材料。這種技術被普遍用在吻啡混合物 活化以及之後哺化過程。炭材在__〗刚。c的蒸汽中進行反°應被 活化，同時控制流化床反應H中的域壓使熱量分配均勻，從而辦 氣固兩相的接觸面。航和炭材之_反應發生在内表面，從而^以 為釋放的H2、C〇2、C0氣體提供更多的吸收位點。 最初’碳化材料與蒸汽發生如下氣化反應，該反應又被稱為 氣反應· C + H2〇 ->C0 + H2 -175, 440 kJ/(kg mol) 以上反應是一個吸熱反應，反應產物⑺和恥可以進行二次燃 燒，反應放出的熱量用來維持整個反應的溫度，反應如下： 2C0 + 〇2 2C〇2 +393, 790 kJ/(kg mol) 2H2 + 〇2 -> 2H2O +396, 650 kJ/(kg mol). 五、製備母粒 75%的碳化顆粒和25%的具有咖啡香氣的材料混合磨碎成小於5 微米（//m)的細顆粒’磨碎後的顆粒和高分子聚合物顆粒（聚丙烯、 尼龍或聚酯）以重量比為1 : 9的比例混合製備母粒。也可以用75% 的碳化顆粒和25%的具有咖啡香氣的材料直接與高分子聚合物顆粒 (聚丙烯、尼龍或聚酯）混合製備母粒。 200918695 六、製備紗線 母粒製成工業上可接受的純度，並且以同樣的方式在每批 加入高分子熔融體，包括色母粒等，以使纖维著色。在鯉砬尹 品》（第六版，料，Prentl㈣犯印;^ 所提_，母粒之所以如此設計是為了使、_可以在正麵生產過程 :^丁擠壓。如Μ要，_可_成峨或錢製縣纖絲並賦予 到的纖維可以用於紡紗卫藝的混纺階段，也可直接 做成千織物和針織物，而無需改變任何生產方法。 【圖式簡單說明】 圖片。 圖1是放大議倍的含有咖啡渣之紗線的掃插電子顯微 圖2疋放大25GG倍的含有咖輕之紗線 插電子顯微圖片 圖3 疋放大测倍的含杨η#狀紗線的掃福 電子顯微圖片。 【主要元件符號說明】 10.含有咖啡渣的紗線 2〇: —條紗線 30 . a加啡渣Side mining _ 纽, but _ _ is a pass _ π or - oxidized (four) body treatment of carbonized materials. This technique is commonly used in the activation of kiss cocktails and subsequent feeding processes. The carbon material is just __〗. The reverse phase of the steam in c should be activated while controlling the domain pressure in the fluidized bed reaction H to distribute the heat evenly, thereby operating the gas-solid two-phase contact surface. The reaction between the aerogel and the carbon material occurs on the inner surface, thus providing more absorption sites for the released H2, C〇2, and C0 gases. Initially, the carbonization material and the steam undergo the following gasification reaction, which is also called gas reaction · C + H2 〇 - > C0 + H2 - 175, 440 kJ / (kg mol) The above reaction is an endothermic reaction, the reaction product (7) and shame can be used for secondary combustion. The heat released by the reaction is used to maintain the temperature of the whole reaction. The reaction is as follows: 2C0 + 〇2 2C〇2 +393, 790 kJ/(kg mol) 2H2 + 〇2 -> 2H2O + 396, 650 kJ/(kg mol). 5. Preparation of 75% of the carbon particles of the masterbatch and 25% of the material with coffee aroma. The fine particles of less than 5 microns (//m) are ground to grind the particles. The masterbatch is prepared by mixing with high molecular polymer particles (polypropylene, nylon or polyester) in a weight ratio of 1:9. It is also possible to prepare masterbatches by directly mixing with high molecular polymer particles (polypropylene, nylon or polyester) with 75% of carbonized particles and 25% of coffee aroma. 200918695 VI. Preparation of Yarns Masterbatch is made into an industrially acceptable purity, and polymer melts, including masterbatches, etc., are added in each batch in the same manner to color the fibers. In 鲤砬尹品(Sixth Edition, material, Prentl (four) smear; ^ mentioned _, the reason why the masterbatch is designed so that, _ can be in the front production process: ^ butyl extrusion. If you want, _ The fiber can be used in the blending stage of spinning and weaving, or it can be directly made into thousands of fabrics and knitted fabrics without changing any production method. [Simple description] Fig. 1 is a scanning electron micrograph of a yarn containing coffee grounds magnified according to Fig. 2 疋 magnified 25GG times the photo of the yarn containing the light of the coffee light Fig. 3 疋 magnification measurement of the containing Yang η# Sweeping electron micrograph of the yarn. [Main component symbol description] 10. Yarn containing coffee grounds 2 〇: - yarn 30. a plus brown slag