200905034 九、發明說明： 【發明所屬之技術領域】 本發明涉及一種具有如申請專利範圍第丄項之前令 特徵的用於紡織基布染色的方法和一種具有如申請專：範 圍第13項之前言的特徵的用以實施該方法的設備。 【先前技術】 為了將紡織基布（substrates)染色，和特別是為了將 這樣的紡織基布染色中使用活性染料作為染料，已知 纺織基布與一包含染料或多染料的染液接觸，#色的访織 基布在經過一預定的染色時間以後被沖洗。 對此人們根據分別選擇的方法和相應提供的設備區分 「種壓吸捲取染色法(pad r〇u扑―)、一種壓吸蒸處染色 (pad steam dyeing)和一種盡染法（exhausti〇n 办^叫），但 所有方法的共同點的是，在實際的染色過程結束時需要沖 洗’以便從在這種情況下著色的紡織基布上排除未固色的 染料。 §亥在每種傳統的染色方法中需S的沖洗過程，其在活 性染色的範圍内也稱為肥4洗蘇過程（sGaping _叫原 、J开^成夕人重複的沖淡過程，從而為此有彳艮大的水需要 量。這樣例如有m一紡織織物的一股的盡染的範圍 内要在1 . 4至1 · 6的染液比例下工作，亦即對於一公斤 待染色的紡織基布需要在約4 “公升）與“之間的水， 而對於實際的沖洗過程總共絕對需要這樣的染液比例，其 7 200905034 在1 : 80與丨：200之間變化，其 必須多次（例如在四次與八次之 體染液比例係由 的。換言之，該沖洗過程總的看來—4複冲洗過程來得到 處理步驟，且另一方面是彳卩釭甚u方面是很耗費時間的 疋很耗費水的處理步驟。 【發明内容】 本發明的目的在於，提供 兮太氺幼铋技士 ΛΛ，九A f疋型式的方法，利用 忒方法紡織基布的染色、特別是 ^ 色，可成為特別經濟的。 、織土布用活性染料的染 按照本發明通過具有如申請專利範 方法達到該目的。 員的特徵的 二=用於：織基布染色、特別是纺織基布用活性 法設疋為，使紡織基布與-包含至少一種毕料 …^ 預疋的染色時間以後，在這期間 通韦在一 &尚的溫度下虛理糞士 ,^ T處理基布’沖洗著色的紡織基布。 旦不二已知的和開頭所述的染色方法，在本發明的方法 ’ #枓結束後將未被紡織基布固色的和在染液中仍存 在的至少-種染料通過化學的和/或物理的處理而破壞成 使染液此後在悬·L Θ A* a 又上疋無色的，從而接著用這樣脫色 的、原來的染液沖洗紡織基布。 本發明的方法對盡染法的應用具體意味著，在這裡在 -木法中在木色結束時不在通道中排走染液而是使染液經 受化學的和/或物理的處理，以便由此使原來的帶色的染 液在最大知度上脫色並然後可以繼續用於沖洗著色的纺織 200905034 基布。然後可以連續地或按批次地經常重複該脫色過程， 直到完全排除在紡織基布上仍存的未固定的染料為止，從 而總的看來在很有利的情況下在本發明的方法中不僅對於 木色而且對於沖洗只需要一唯一的染液。因此通過本發明 的方法的應用有可能，在！ ： 4至i : 6的染液比例的情況 下對紡織基布和特別是要用活性染料染色的紡織基布進行 杂色和沖洗，從而與開頭所述現有技術相比對於一公斤的 紡織基布在染色和沖洗時需要四升至六升的水。 久I如呆按壓吸捲取染色法或壓吸蒸處染色法將紡織 基布染色，則在本發明的方法中需要的是，取依據壓擠程 $將染液施加到紡織基布上。為此大致每公斤的紡織基布 而要，、百至九百克的染液。在經過一預定的堆放時間（dweU tllne)或蒸煮時間以後，接著較佳是以丨：4至丨：6的染 液比例沖洗這樣著色的紡織基布，此時接著在本發明方法 的该方法中在最有利的情況下第—和唯—的沖洗液在這種 月况下具有未被紡織基布固色的和包含於沖洗液的染料， 後將通過化學的和/或物理的處王里而破壞成使沖洗液此 1在最大％度上是無色的，接著用在最大程度上脫色的染 液重新沖洗紡織基布。該染料的破壞和用接著脫色的沖液 重新的沖洗若需要可以重複多次。因此本發明方法的該方 、、φ厂，統的麼吸捲取染色法或壓吸蒸處染色法相比，關於 ’洗時的水消耗量也是明顯更有利的，特別是在本發明的 方法中可以用1 : 4.6至1 : 6.9的染液比例工作。 本發明的方法除上述優點外還具有其他的優點。例如 9 200905034 I先確5忍’通過大大減少#水需要量，《使本發明的方法 與=統的方法相比具有的，與之相應地也決定大大減少廢 水里，运不僅在減少環境負擔方面而且在顯著更有利的成 本結構方面表現出來。由於在本發明的方法中在最有利的 it况下/、用一唯一的沖洗浴工作，決定在這種情況下只需 要僅僅一次加熱該唯一的沖洗浴，而在現有技術中，其用 4至8自沖洗浴工_，在這一點上總是必須一再將這些沖 洗浴從室溫加熱到例如啊。特別是由於本發明的方:放 棄沖洗（用肥息洗條）時的染液更換’本發明的方法還允 許大大地節省時間，從而通過應用本發明的方法顯著地提 南每預定的時間單位内待染色基布的生產能力。這又導致 人員數量的明顯的節省，由此顯著有利地影響本發明方法 的經濟性。對於專業人員來說還可以令人驚喜地看到，按 照本發明方法染色的和特別是沖洗的紡織基布具有一堅牢 度水準，較佳是關於耐濕摩擦牢度、耐乾摩擦牢度、财洗 條牢度㈣水牢度以及耐汗潰牢度的堅牢度水準，它們與 傳統方法染色的紡織基布並沒有差別。 _在本發明的方法的第-進-步實施例中，將纺織基布 在π過預疋的染色时間以後從染液中並從而從用於染色的 裝置中取出並轉送入另—田 神疋八为用於沖洗的裝置中。在該另一裝 置中然後實施實際的沖洗讲# ... 先過程使在紡織基布上粘附的和 未固色的染料首先轉送入沖洗液中，料使這樣載有未固 色的染料的沖洗液接著經受化學的和/或物理的處理，以 便在處理以後沖洗液在最大程度上是無色的並且如果需要 10 200905034 法的進一步構成的優 其與實際的染色裝置 因此可以特別節省成 可以用於重新的沖洗。該本發明的 點是，在另一裝置中實施沖洗過程方 相比在技術上具有較不複雜的結構， 本地進行這樣的工作過程。 面、二：！：方法的一特別適用的進-步實施例，在這方 :广處理破壞未被纺織基布固色的和在染液或沖洗 =在的至少一種染料…該化學處理特別是一種氧 化的處理。 基本上對於該化學的和較佳μ㈣mm考μ 2化學藥品，其允許將染料破壞使得在這時產生無色的 刀產物，其中為此較佳是使用過氧化氮或過醋酸或次氣 酸鈉。 但在本發明的方法中特別適用的是，上述染液的氧化 :理在實際的染色結束時包括用臭氧的處理或只通過用臭 虱處理實現，㈣確認，正是臭氧在極短的時間内，即在 幾私直到幾分鐘内破壞大量不同的染料和染料組，而使得 產生無色的染料分解產物，其對紡織基布沒有或只有微小 的親和性。 基本上在本發明的方法中有可能在實際的染色結束時 在單浴中處理染液，而使未固色的染料，其仍處於染液中 和在紡織基布的表面上，通過化學的和/或物理的處理脫 色。但特別適用的是，將本發明的方法改變成使染液與著 色的紡織基布分離並然後實現染液的化學的和/或物理的 處理，以便與之相應地優點將染液經由一旁路導向實際的 200905034 染色裝置，並且在該旁路中通過適當的化學的和/或物理 @處理改變在染液中包含的染料，而使得通過該處理產生 染液的無色的分解產物。與之相應地接著使染液脫色，然 制之用作為無色的沖洗液，以便重新從著色的紡織基布 中沖洗掉未固色的染料。緊接著同以上對原來的染液描述 的那樣處理同時附帶產生的帶色的沖洗液，以便可以將其 因此在化學的和/或物理的處理以後重新作為無色的沖洗 液用於繼續的沖洗。 應該明確地說明，在本文中採用的用肖“和/或，，意 味著，各個元件在相應的列舉中視為是添加的或可選擇 的’其中在添加的名稱中，於是所述列舉的至少兩個元件 相互組合，而在個別應用的用言中，染料當然不只是覆蓋 -唯-的染料而且也覆蓋不同的染料的混合物。 所謂物理的處理在本申請專利範圍内應該被理解為全 部的處理，其適於破壞染料，使得借此產生無色的分解產 物因此接者可以將這樣脫色的染料用於實際的沖 程。 …寺別適用的疋’右該物理的處理這樣實現，即用紫外 光#田射當時待處理的帶色的染料和/或在這時採用電化學 方法，其中利用特別的金剛石塗層的電極 術語也稱為⑽（化學汽相沉積）電極。其在專業 ::述在本發明的方法中已說明的那樣，將著色的紡 ^ " 染色結I時在有利的情況下只用脫色的染液沖 ’’但其令在本發明的方法中並不排除，在染色結束時， 200905034 八中#乂 k疋涉及盡染，排走染液並由一唯一的沖洗液取 代’它然後在與著色的紡織基布接觸以後經受化學的和/ 或物理的處理’以便由此破壞其中包含的未固色的染料， 直到產生無色的分解產物並從而產生無色的染液。如果染 液中殘餘染料濃度是如此之高’以致為脫色借助於化學的 和/或物理的處理的費用過高並因此從經濟上的權衡—次 染液更換是更有利的，則可應用本發明方法的該替代方 案。 一 k仕本發明的方法的一種變型方案中是特別適用的和 經濟上有利的，即其中在第一步驟中用已脫色的染液沖洗 :方織基布’然後在第二步驟中分離載有未固色的染料的沖 γ、在第—步，驟中通過化學的和/或物理的處理將處於 沖洗液中的未固色染料破壞成使得沖洗液在最大程度上是 無色的’並且在第四步驟中用在相當大程度上無色的沖： 液沖洗紡織基布。 取決於哪種紡織基布按照本發明的方法 以哪樣的色澤深度來染色，本 一”抖矛 出 ♦赞明的方法的-個方案提 弟—至第四步驟重複多次、特別是重複2次至15次。 =上已證明是特別有利的，本發明的方法的一個實 鈀形式提出，作為染液的化學處 學虛㈣“ p &理和/或作為沖洗液的化 =里貫施用臭氧的處理’此時用臭氧的處理具有決定性 的饭點，臭氧在極短的時間内，、 為了在本發明的方法中降低"“梅、内-再分解。 用，提供在為相應的染色裝置、用以及文王費 色裝置^洗裝置配置的反應器中 13 200905034 實施用臭氧的處理，其中 洗液連續& ^ 、寺脫色的乐液和/或待脫色的沖 實施形ϋ Φ # ^ D 。換s之，在該本發明的方法的 /工中，將著色的紡織基 和/或鱼、、ψ t v 邓興木液用臭軋的處理階段 證父氧:::…氧的處理階段分開，從而相應地保 布上不^也作用到這樣的染料上，其已固色在纺織基 確保:沒:::：的方法的上述特別有利的進-步構成中 -著色㈣織餘臭氧的脫色的洗液（染液或沖洗液) 的出口實施對二If觸’已證明特別有利的是，在反應器 臭氧敎#/ 、乳處理過的染液的氧化還原電位測定、 值測定。如果相應的測量值說明在相 應處理過的染液中具有殘餘臭氧的存在，則可以 間的溫升從染液中排除該 且、 以i言详、h丨 餘臭氧，延在設備方面例如可 G樣達到’即在這裡今署 終# 4 置另—旁路’其然後由此含有殘 餘臭乳的洗液觸發而經由相應的閥裝置。 作為其他的可能性或附加於 ，本φ、士接·T4万案’在本發明的方 :二作，即根據測定的氧化還原電位、測定的臭氧 浪度和/或測定的pH值抻制a c * 吴乳 P值技制向反應器中輸入的臭氧詈， 以便在確認在脫色的染液中 吴乳置 應器中輸人的臭氧量。 》餘臭氧時相應地減小向反 基本上本發明的方：^ ΰΓ> 以在每種染色方法十應用，例 如特別是在開頭簡述的壓歿接 中庫用HP 及掩取染色法錢吸蒸處染色法 中應用。，方“在染料塗數和固色以後在 置上可連續或間斷地沖洗這樣著 2 14 200905034 :㈣：方法的該方案中，然後使沖洗液經受上述的化學的 和/或物理的處理，以便由此破壞沖洗液中包含的的=的 1:用7液在最大程度上是無色的。同樣本發明的；法同 樣應用在這樣的染色上，其在一 ήΛ r ® ^ ^ 捲木色機上在常溫或高 圍内實施。但特別適料是，本發明的方法在盡毕 1中應用，因為在這種情況下如開頭所述提供-㈣ 為了脫色可相應地經物理地和/或化學地處理。同 發明的方法可應用於紡織基布 7 l 士技口 叩97得裝形式無任何限制。例 線捲同樣可以用於紗線染色中，其處於交叉繞 作Ρ色或絞紗染色中，但此時也適用的是，將纺基布 :為平面構型織物並且較佳是作為連續的織物絞 ，色因為在廷種情況中特別明顯地顯示出 上现的水郎省。 :發明還涉及一種用以實施上述本發明方法的設備， 曰Ο可以特別經濟地實施本發明的方法。 一本發明的用於實施上述本發明方法的設備特別是具有 :用以容納待染色的紡織基布的容器和一用於染液的循環 其中容器和/或循環系統配置有一由染液流過的反 Μ益用以實施待脫色的溶液（染色過程結束時的染液和/ 或沖洗液）的化學的和/或物理的處理。 上述本發明的設備具有同以上對本發明的方法描述 全部的優點。本發明的設備特別允許合理地應用 、十. 决得糸色的紡織基布，其中著色的紡織基布的干擾和特、 疋不付合要求的破壞是如下述來避免，即為了染液的脫 、职*色 15 200905034 在單獨的反應器中實施實際的物理的和/或化學的處 理。 2樣本發明的設備的一個實施形式也是可能的，其中 :於合、·内待染色的或待沖洗的紡織基布的容器構成用於實 施化學的和/或物理的處理的反應器。換言之，在該實施 开〔式中，$&容器本身或以上s本發曰月&方法描述的與其 分開設置的另-裝置構成實際的反應器，將著色的但仍未 沖=纺織基布轉送於該另—裝置中以便沖洗，從而在染 y、中緊接著染色之後或在另一裝置中實施化學和/ 物理的處理。 本發明的叹備的一特別適合的和節省空間的實施形式 建在這裡在容器的進行實㈣染色和沖洗的底部區域 内°又：用於染液的第-管線系統’其將反應器經由第一閥 ^木液泵連接於容器的底部區域，同時反應器經由第二 :線系統和第二閥連接於容器用以供給在處理後儘可能： 一的染液或沖洗液。因此總的來說，$器的底部區域經由 ―間^-染液果連接於反應器而反應器本身又經由一閥連 :於谷器’從而在該作為旁路連接的反應器中實現用於化 子的和/或物理的染液⑽色的實際的處理步驟。因此相應 =料在實際的染色結束時借助於染液H適度打開的 -閥供給反應器，在那裡實施化學的和/或物理的染液 終理以便破壞染料並因此使其脫色，&而接著經由第二閥 ，這樣脫色的染液重新供給容器，以便開始實際的沖洗過 16 200905034 方案中確保所需要的溫度 色的流回容器的染液中排 的氧化劑的殘餘物，本發 為第二管線系統配置一埶 為了在上述本發明的設備的 怪定性並且還為了如有必要從脫 除不符合要求的臭氧和/或其他 明的設備的另一實施形式提出， 交換器。 統配…， 備的另一實施形式中，第二管線系 一個感測器用以檢測氧化還原電位、臭氧濃 j /或PH i ’從而在一這樣载有殘餘氧化劑或殘餘臭 ，的染液與著色的纺織基布接觸（這可能導致缺陷）之前， 個感測器檢測出不符合要求的氧化劑的殘餘 的抑 符合要求的臭氧的殘餘物。為了排除一這樣 ==，：述至少-個感測器沿染液的流動方向看設置 ΐ不;其中較佳是該第二間則構成為使得在確認 :合：求的氧化劑和特別是臭氧的殘餘濃度時經由第 的染液流至例如-熱交換器，以便消除該不符 殘餘物並接著僅將無殘餘物的染液輪送給容器。 本發明的設備的各實施形式中，其中借助於用臭氧的 Γ色=液或從沖洗液中破壞未固色染料，使得由此產生 成刀’建議為反應器配置-用於產生臭氧的裝置， 置本身在現有技術中已是已知的。但當然也 二：；！通過在這裡設置-相應的臭氧儲罐為反 &農二二n果染液在實際的染色過程結束時仍具有 色染料，則特別建議該方案，從而與之相應 4以量用於反應器中，以便通過臭氧處理破壞 17 200905034 該殘餘：未固色的染料，使得由此產生無色的成分。 為安全起見建議，在本發明的設備的另一實施形式中， 反應器配置有第：r瞢绐έ . 1Λ S線系統，其將反應器中的空氣空間經 由一騎臭氧消除器和_第三閥連接於—排氣風扇。在這 方面還特別有利的A，在廢氣中設置-感測器用以檢測臭 氧濃度，⑵而必要時在相應f集臭氧的廢氣可以進入大氣 之前產生一相應，聲音的或光學的報警信號。 旦為了始終提供為染液或沖洗液處理所需的足夠的臭氧 里’本發明的設備的另—實施形式設^ ’臭、氧產生器連接 於用於富集氧氣的空氣的源，從而與之相應地直接在其 應用之前由此特別快地產生實際的臭氧。 豆二：上所述，本發明的設備特別用於這樣的染色方法， 作’纟中與之相應地本發明的設備則相應地 k合於待染色的物料的構成。 境樣第—種可能性提出，其中用於容納待染色的纺織 1的容器具有一為底部區域配置的儲存系統，同時在容 :的上面設置一轉向裝置用於紡織基布的織物絞紗。此外 :歲物紋紗的轉向裝置具有一被驅動的心軸和/或一喷 , ' ，攸而在染色過程中並且也在沖洗過程中連續地傳 迠及合攏織物絞紗。 〜可能性’其特別用於在展寬的和交織的狀態下 織物的染色，設定，苴中机 '、中°又置一圓柱形的容器，其配備一 木色經輛用以套接一織物絞紗。 第〜種可能性這樣進一步構成本發明的設備，使容器 18 200905034 具有至少一個支架用以套接至少一個捲筒、特別是至少一 個交叉捲繞捲筒’從而與之相應地該本發明設備的方案適 用於捲筒紗染色。 為了在本發明的方法中或在待染色的紡織基布的處理 中在本發明的設備中防止在其中不符要求地出現方法過程 的干擾，循環系統配置有一染液循環泵、一熱交換器、一 染液槽桶和/或一棉絨捕集器（lint catcher)(廢纖捕集器）， 其中在貫際的染色過程中的染液、在染色過程結束時脫色 的染液或已脫色的沖洗液通過該循環系統流通。 本發明的方法和本發明的設備的有利的進一步構成說 明於諸附屬申請專利範圍中。 【實施方式】 以下借助本發明的設備的一個實施例更詳細地說明本 發明的方法和本發明的設備。於此範例中，唯—的圖式顯 示一本發明設備的示意圖。 在唯-的圖中’整體以n標示之設備的實施形式基本 上具有-傳統的染色裝£ 1〇’其設有一容器Η用以套接 :染色的織物絞紗13。在染色和沖洗過程中織物絞紗η 連續地通過容器12輸送，直中 ^ , ” 不實施形式中一被驅 動的心軸14用於輪送該織物絞紗13。 中,HI2、的底部區域15配置有—染液循環“ 16,其 液：料：液：環系統16將個別的處理染液借助於-染 盾％录和—熱交換器18從容器中排出，並在染 19 200905034 液加熱以後重新輸入容器12中。將織物絞紗13在處理過 #中借助於心車由】4以一預定的速度沿箭頭彳肖1 %輸送，° 其中輸运速度通常在2〇〇 m/min與8〇〇 m/min之間改變。 此外染液德環系統16配置有一未畫出的棉織捕集器和一 染液槽桶。 —在-通向染色裝置1G的旁路中設置—反應器6， 中貫現染液或沖洗液的化學的和/或物理的處理，其中在 所示實施形式中使未固色的染料經受用臭氧的化學處理， 以=此破壞染料，使得產生無色的組分。反應器 :官道3連接於-臭氧產生器2,同時經由管道"心 氧氣的空氣輸Μ氧產生此外反應器6在輸 由第一管線系統19連接於μ 社徇入鈿經 、 運接於令态12的底部區域15，同時π 木液的流動方向從容器丨2 ' m 0反應裔6看，設置有-閥2〇、 此外反應器6經由第二管線系統2 方向看，經由—咸測考7 *哲 又/口木液的流動 部區域15。 D °第—閥22連接於容器12的底 最後，第三管線系統23 其將反應器6中存在的空氣空反通向-排氣風扇9， 連接於排ϋ J1? θ。 、 4，、二由—殘餘臭氧消除器8 埂按、排軋風扇9，同時排 圖中顯示的設備操作如下广°大氣那邊是敞開的。 首先將染色裝置 此目的將織物絞紗13組成連的::物絞紗13 ’其中為 器〗2内。然後將容器下部區織物絞紗並且定位在容 °°域/主入染液，同時染液經由 20 200905034 木液循％系統16持續地在實際的染色過程 以“輪I織物絞紗13。-種這樣的染色裝置1〇及= 操作方式很久以來已屬於現有技術。 '、 中仇:二在染色裝置1〇中染色完成以後’將處於容器12 器Γ、甬過過'20的打開和借助於染液泵4並經由熱交換 k。第—f線系統19連續地輸向反應器6， 應器6中，仅—a v ^ ^ 仍包3殘餘的未吸收和固色的染色的染液在反 6中被供給臭氧。這時連續地由富集氧氣的經由管道 1 =給=空氣在臭氧產生器製成臭氧並借助於管道3以一 預疋的置加入反應器中。臭氣詈祐批制，你，g 開反應II 6的毕、夜B 使得一方面使離 的-液疋無色的，而另-方面在第二管線系統 的感測器上不再顯示殘餘臭氧。但如果在這裡仍 有殘餘臭氧被檢测出，則自動地關閉闕2〇 ^ & 置於管線系統19知μ 士 ^ 士 > 、 和21中，並且在處理過程中是打開的。 同時停止泵4’從而暫時中斷在反應器中的程序。 這樣借助於臭氧處理脫色的染液經由第二管線系統η200905034 IX. OBJECTS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a method for dyeing a textile base fabric having the features of the first claim of the patent application, and a preface to the thirteenth item of the application scope: A device for carrying out the method. [Prior Art] In order to dye textile substrates, and in particular to use reactive dyes as dyes in dyeing such textile substrates, it is known that textile substrates are in contact with a dye solution containing dyes or multiple dyes, # The colored visit woven base fabric is rinsed after a predetermined dyeing time. In this regard, according to the method selected separately and the corresponding equipment provided, "the type of pressure suction winding method (pad r〇u flutter), a type of pad steam dyeing and one exhaust method (exhausti〇) are distinguished. n do ^ call), but all methods have in common that it needs to be rinsed at the end of the actual dyeing process to exclude unfixed dyes from the textile base fabric colored in this case. In the traditional dyeing method, the flushing process of S is required, which is also called the fat 4 washing process in the range of active dyeing (sGaping _ called the original, J open ^ 夕 重复 repeat repeating process, so there is a big The water requirement is such that, for example, a range of dyeing fabrics of m-woven fabrics should be operated at a dye liquor ratio of 1.4 to 1.6, that is, for one kilogram of textile base fabric to be dyed, Approximately 4 "liters" and "between the water, and for the actual flushing process a total of such a dye ratio is absolutely required, its 7 200905034 varies between 1:80 and 丨:200, which must be multiple times (eg in four The ratio of the second and eighth body dyeing solutions is based on. Moreover, the rinsing process generally appears to be a four-flushing process to obtain a processing step, and on the other hand, is a very time-consuming and very costly processing step. The purpose is to provide a method for the design of the 兮太氺 铋 铋 ΛΛ ΛΛ 九 九 九 九 九 九 九 九 九 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织The invention achieves the object by having the method as claimed in the patent application. The second feature of the member is: for the woven base fabric dyeing, in particular, the textile base fabric is set by the active method, so that the textile base fabric and the at least one type of material are included... ^ After the pre-dip dyeing time, during this period, Tongwei smudges the faeces at a temperature of amps, and treats the base fabric's rinsing of the colored textile base fabric. It is known and described at the beginning. a dyeing method, after the end of the method of the present invention, at least one dye that is not fixed by the textile base fabric and still present in the dye liquor is destroyed by chemical and/or physical treatment to cause the dye liquor to be thereafter Hanging L Θ A* a The upper enamel is colorless, and the woven textile fabric is then rinsed with the thus-destained, original dyeing solution. The application of the method of the invention to the exhaust dyeing process means, in this case, that the wood is not in the channel at the end of the wood color. Instead of the dyeing solution, the dye liquor is subjected to a chemical and/or physical treatment in order to thereby decolorize the original coloured dye liquor to the maximum extent and can then continue to be used for rinsing the coloured textile 200905034 base fabric. The decolorization process can then be repeated frequently, either continuously or in batches, until the unfixed dye still present on the textile substrate is completely excluded, so that in general it is advantageous in the method of the invention not only For wood color and only a single dye solution is required for flushing. Therefore, the application of the method of the present invention is possible, at! : textile base fabric and especially textile base fabric to be dyed with reactive dyes in the case of a dye liquor ratio of 4 to i: 6 for variegation and rinsing, for a kilogram of textile base compared to the prior art described at the outset The cloth requires four to six liters of water for dyeing and rinsing. For a long time, if the textile base fabric is dyed by a suction/sucking dyeing method or a pressure suction steaming method, it is required in the method of the present invention to apply the dyeing liquid to the textile base fabric according to the pressing process. For this reason, roughly every kilogram of textile base fabric, from one hundred to nine hundred grams of dye liquor. After a predetermined stacking time or cooking time, it is preferred to rinse the thus colored textile base fabric at a dye liquor ratio of 丨:4 to 丨:6, in which case the method of the method of the invention is followed. In the most advantageous case, the first and only rinsing liquids in this month have dyes that are not fixed by the textile base fabric and are contained in the rinsing liquid, and then pass through the chemical and/or physical king. It is destroyed so that the rinsing liquid 1 is colorless at the maximum %, and then the woven base fabric is re-rinsed with the dye solution which is most decolored. Destruction of the dye and re-rinsing with a subsequent decolorized rinse can be repeated as many times as needed. Therefore, compared with the method of the method of the present invention, the φ factory, or the suction suction dyeing method, the water consumption during washing is also significantly more advantageous, especially in the method of the present invention. It can work with a dye ratio of 1: 4.6 to 1: 6.9. The method of the present invention has other advantages in addition to the above advantages. For example, 9 200905034 I first ensured that the water demand was greatly reduced. And in terms of a significantly more favorable cost structure. Since in the most advantageous case of the method of the invention, a single flushing bath is used, it is decided that in this case only one single heating bath needs to be heated only once, whereas in the prior art, it uses 4 To 8 self-punching bathers _, at this point it is always necessary to heat these flushing baths from room temperature to, for example. In particular, due to the method of the present invention: the dyeing liquid replacement when abandoning the flushing (with a fertilizer strip), the method of the invention also allows a significant time saving, thereby significantly increasing the number of predetermined time units by applying the method of the invention. The production capacity of the base fabric to be dyed. This in turn leads to a significant saving in the number of persons, which significantly influences the economics of the method of the invention. It can also be surprisingly seen by the skilled person that the woven fabrics which are dyed and in particular rinsed according to the method of the invention have a fastness level, preferably with respect to wet rubbing fastness, dry rubbing fastness, wealth Wash fastness (4) The fastness of water fastness and perspiration fastness, which is no different from the traditional method of dyeing textile base fabric. In a first-for-step embodiment of the method of the invention, the textile base fabric is removed from the dye liquor and thus from the apparatus for dyeing and transferred to another Tiantian after the dyeing time of π pre-pre-twisting疋8 is used in the device for rinsing. In the other device, the actual rinsing process is then carried out so that the adhered and unfixed dyes on the woven base fabric are first transferred into the rinsing liquid, so that the dyes are loaded with unfixed dyes. The rinsing liquid is then subjected to a chemical and/or physical treatment so that the rinsing liquid is colorless to the greatest extent after the treatment and if it is required to further the composition of the 200905034 method, it can be particularly saved with the actual dyeing device. Used for re-rinsing. The point of the present invention is that the rinsing process is carried out in another device, and such a working process is performed locally as compared with a technically less complicated structure. Face, two:! A particularly suitable further embodiment of the method, in which: extensive treatment destroys at least one dye that is not fixed by the textile base fabric and in the dye liquor or rinse = the chemical treatment, in particular an oxidation treatment . Essentially for this chemically and preferably μ(tetra)mm2 chemical, it allows the dye to be destroyed such that a colorless knife product is produced at this point, wherein for this purpose it is preferred to use nitrogen peroxide or peracetic acid or sodium hypo-sodium hydride. However, it is particularly suitable in the method of the invention that the oxidation of the dye liquor described above comprises the treatment with ozone at the end of the actual dyeing or only by treatment with skunks, and (iv) confirmation that it is ozone in a very short time. Internally, i.e., destroying a large number of different dyes and dye groups in a few minutes to a few minutes, resulting in a colorless dye decomposition product with little or no affinity for the textile base fabric. It is basically possible in the process of the invention to treat the dye liquor in a single bath at the end of the actual dyeing, while leaving the unfixed dye still in the dye liquor and on the surface of the textile substrate, by chemical And/or physical treatment bleaching. However, it is particularly suitable to modify the method of the invention to separate the dye liquor from the colored textile base fabric and then to effect a chemical and/or physical treatment of the dye liquor in order to provide a corresponding advantage to the dye liquor via a bypass. The actual 200905034 dyeing device is directed and the dye contained in the dye liquor is altered by appropriate chemical and/or physical @ treatment in the bypass such that a colorless decomposition product of the dye liquor is produced by this treatment. Correspondingly, the dye solution is then decolorized and used as a colorless rinse to re-wash the unfixed dye from the colored textile base fabric. This is followed by the treatment of the original dyeing solution, which is accompanied by the resulting coloured rinsing fluid, so that it can be reused as a colourless rinsing fluid for subsequent rinsing after chemical and/or physical treatment. It should be expressly stated that the use of "and/or" in this context means that the individual elements are considered to be added or optional in the corresponding list, wherein in the added name, then at least the recited The two elements are combined with one another, and in the context of the individual application, the dyes of course do not only cover the dye-only dye but also cover a mixture of different dyes. The so-called physical treatment should be understood as all within the scope of the patent application. Processing, which is suitable for destroying the dye, whereby a colorless decomposition product is produced, so that the dye can be used for the actual stroke. The application of the 疋' right physics is achieved by using ultraviolet light. #田射 The colored dye to be treated at the time and/or electrochemical method at this time, wherein the electrode term using a special diamond coating is also called (10) (chemical vapor deposition) electrode. As already explained in the method of the present invention, the colored spun dyed < dyed knot I is advantageously used only with the decolorized dye solution. The method does not exclude that at the end of the dyeing, 200905034 八中#乂k疋 involves exhaustion, drains the dye solution and replaces it with a single rinse solution. It then undergoes chemical exposure after contact with the colored textile base fabric. And / or physical treatment 'to thereby destroy the unfixed dye contained therein until a colorless decomposition product is produced and thereby produce a colorless dye liquor. If the concentration of residual dye in the dye liquor is so high 'so that it is decolored Where the cost of chemical and/or physical treatment is too high and therefore economically traded - secondary dye replacement is more advantageous, then this alternative of the method of the invention can be applied. It is particularly suitable and economically advantageous in the variants, in which in the first step a rinse with a bleached dye liquor is used: a woven base fabric 'and then in a second step the separation of the dyes carrying the unfixed dyes γ In the first step, the unfixed dye in the rinsing liquid is destroyed by chemical and/or physical treatment so that the rinsing liquid is colorless to the greatest extent' and in the fourth step To a considerable extent, colorless rushing: liquid rinsing textile base fabrics. Depending on which textile base fabric is dyed according to the method of the present invention, this method of "sharp spears out" ♦ praising the method Teddy - to the fourth step repeated many times, in particular repeated 2 to 15 times. It has proven to be particularly advantageous, a solid palladium form of the process of the invention is proposed as a chemical chemistry of the dye liquor (IV) "p & and / or as a rinse solution = treatment of continuous application of ozone" At this time, the treatment with ozone has a decisive meal, and ozone is degraded in a very short period of time in order to reduce the "mei, internal-re-decomposition" in the method of the present invention. For use in a reactor configured for a corresponding dyeing device, use, and a Wenwang color-receiving device, 13 200905034, the treatment with ozone, wherein the lotion is continuous & ^, the temple bleaching liquid and/or to be bleached The shape of the punch is Φ # ^ D . In the process of the present invention, the colored textile base and/or the fish, the ψtv Dengxing wood liquor are separated by the processing stage of the treatment phase of the odorant:::... oxygen, thereby Correspondingly, the cloth is not applied to such dyes, which have been fixed in the textile base to ensure that the above-mentioned particularly advantageous step-by-step formation of the method of no:::: - coloring (four) decolorization of the residual ozone It has proven to be particularly advantageous for the outlet of the lotion (dye or rinse) to be tested for the redox potential of the reactor ozone 敎#/, the milk-treated dye solution, and the value determination. If the corresponding measured value indicates the presence of residual ozone in the corresponding treated dye liquor, the temperature rise between the two can be excluded from the dye liquor, and the ozone can be omitted. The G-like sample is reached by the corresponding valve device, which is then triggered by the wash solution containing the residual odor. As another possibility or in addition, the present φ, 士接·T4 million case's in the present invention: two, that is, according to the measured oxidation-reduction potential, the measured ozone wave and/or the measured pH value Ac * Wu milk P value technology to input ozone into the reactor, in order to confirm the amount of ozone input in the Wu milk dispenser in the bleached dye solution. The remaining ozone is correspondingly reduced to the opposite side of the present invention: ^ ΰΓ > to apply in each of the dyeing methods, for example, especially in the pressure splicing described at the beginning, using HP and masking the dyeing method. Application in the suction method of suction. , in the "coating number and fixing after the dye can be placed continuously or intermittently in such a way 2 14 200905034: (d): in this solution of the method, then the rinsing liquid is subjected to the above chemical and / or physical treatment, In order to thereby destroy the =1 contained in the rinsing liquid: the 7 liquid is colorless to the utmost extent. Also the method of the invention is applied to such dyeing, which is in a ήΛr ® ^ ^ roll wood color The machine is carried out at ambient temperature or in a high range. However, it is particularly expedient that the method of the invention is applied at the end of the first paragraph, since in this case it is provided as described at the outset - (iv) for decolorization, correspondingly physically and/or Or chemically treated. The method of the invention can be applied to the textile fabric 7 l 士 叩 叩 97. The form of the coil can also be used in the dyeing of the yarn, which is in the cross-winding or twisting Yarn dyeing, but it is also suitable at this time to use a spun fabric: a flat fabric and preferably as a continuous fabric strand, because the color is particularly obvious in the case of the plant. The invention also relates to a method for implementing the above The apparatus according to the invention, the method of the invention can be carried out particularly economically. The apparatus for carrying out the method according to the invention described above has, in particular, a container for containing a textile base fabric to be dyed and a dyeing medium for dyeing The circulation of the liquid wherein the vessel and/or the circulation system is provided with a chemical and/or physical solution for the solution to be bleached (dye and/or rinse at the end of the dyeing process). The above-described apparatus of the present invention has all of the advantages described above with respect to the method of the present invention. The apparatus of the present invention specifically allows for the rational application, the woven textile base fabric, and the interference and speciality of the colored textile base fabric. The damage that is not required is avoided as follows, that is, in order to remove the dye liquor, the actual physical and/or chemical treatment is carried out in a separate reactor. An embodiment is also possible in which the container of the textile base fabric to be dyed or to be washed forms a reactor for carrying out chemical and/or physical treatment. In other words, in the implementation, the $&the container itself or the other device described separately from the above method constitutes the actual reactor, which will be colored but still not punched = textile base The cloth is transferred to the other device for rinsing to perform chemical and/or physical treatments after dyeing y, followed by dyeing or in another device. A particularly suitable and space-saving implementation of the sigh of the present invention The form is built here in the bottom region of the container for the actual (iv) dyeing and rinsing. Again: the first-line system for dyeing liquids. It connects the reactor to the bottom region of the vessel via the first valve, while The reactor is connected to the vessel via a second: line system and a second valve for supplying as much dyeing or rinsing liquid as possible after processing. Thus, in general, the bottom region of the device is via the "dye-dyeing solution" If the reactor is connected to the reactor and the reactor itself is connected via a valve: in the trough 'to achieve the actual processing steps for the chemical and/or physical dye (10) color in the reactor connected as a bypass . Correspondingly, the material is supplied to the reactor at the end of the actual dyeing by means of a moderately open valve of the dye liquor H, where a chemical and/or physical dyeing process is carried out in order to destroy the dye and thus discolor it, & Then, via the second valve, the decolorized dye solution is re-supplied to the container to start the actual rinsing. In the 2009 20093434 solution, the required temperature color is ensured to flow back to the oxidant residue in the dye liquor of the container. The two-line system configuration is for the purpose of the ambiguity of the apparatus of the invention described above and also for the purpose of removing the non-compliant ozone and/or other means of equipment, if necessary, the exchanger. In another embodiment, the second pipeline is a sensor for detecting an oxidation-reduction potential, ozone concentration, or PH i ', thereby carrying a residual oxidant or residual odor, and Before the colored textile base fabric contacts (which may cause defects), the sensors detect residual ozone residues that do not meet the required oxidant residue. In order to exclude one such ==,: at least one sensor is disposed along the flow direction of the dye liquor; wherein preferably the second chamber is configured to confirm: the oxidant and especially the ozone The residual concentration is passed through the first dye liquor to, for example, a heat exchanger to eliminate the discrepancies and then only the residue-free dye liquor is fed to the vessel. In various embodiments of the apparatus according to the invention, in which the unfixed dye is destroyed by means of ozone/liquid from ozone or from the rinsing liquid, the resulting knives are proposed as reactor configurations - means for generating ozone The setting itself is already known in the prior art. But of course also two:;! By setting here - the corresponding ozone storage tank for the anti-amp; agricultural two-nose dyeing solution still has a color dye at the end of the actual dyeing process, it is especially recommended that the solution is used in a corresponding amount of 4 In order to destroy by ozone treatment 17 200905034 This residue: unfixed dye, resulting in a colorless component. For safety reasons, it is proposed in a further embodiment of the apparatus according to the invention that the reactor is provided with a: rΛ. 1Λ S line system which passes the air space in the reactor via an ozone eliminator and The three valves are connected to the exhaust fan. A particularly advantageous aspect in this aspect is that a sensor is provided in the exhaust gas for detecting the ozone concentration, and (2) and a corresponding, audible or optical alarm signal is generated before the corresponding exhaust gas of the ozone collector can enter the atmosphere. In order to always provide sufficient ozone for the treatment of the dye liquor or rinse solution, the other embodiment of the apparatus of the invention provides a source of odor and oxygen generator connected to the source of oxygen-enriched air, thereby Correspondingly, the actual ozone is produced particularly quickly before its application. Bean 2: As described above, the apparatus of the present invention is particularly useful for such a dyeing method, and accordingly, the apparatus of the present invention corresponds to the composition of the material to be dyed. The first possibility is that the container for accommodating the textile 1 to be dyed has a storage system arranged for the bottom portion, while a steering device is provided on the upper surface of the fabric for the skein of the textile base fabric. In addition: the steering device of the aged yarn has a driven mandrel and/or a spray, which continuously transfers and closes the fabric skein during the dyeing process and also during the rinsing process. ~ Possibilities 'It is especially used for dyeing of fabrics in a widened and interwoven state, setting, 苴中机', medium ° and a cylindrical container, which is equipped with a wooden color to splicing a fabric Skein. The first possibility thus further constitutes the apparatus of the invention such that the container 18 200905034 has at least one bracket for nesting at least one reel, in particular at least one cross-wound reel, and thus corresponding to the apparatus of the invention The solution is suitable for yarn dyeing. In order to prevent undesired disturbances in the process process in the process of the invention or in the treatment of the textile base fabric to be dyed, the circulation system is provided with a dye liquor circulation pump, a heat exchanger, a dye bath tank and / or a lint catcher (waste fiber trap), wherein the dye liquor in the continuous dyeing process, the dye liquor bleached at the end of the dyeing process or has been bleached The rinsing liquid is circulated through the circulation system. Advantageous further developments of the method of the invention and the apparatus of the invention are described in the scope of the appended claims. [Embodiment] The method of the present invention and the apparatus of the present invention will be explained in more detail below by means of an embodiment of the apparatus of the present invention. In this example, the only drawing shows a schematic diagram of an apparatus of the invention. In the sole view, the embodiment of the device, generally indicated by n, has essentially a conventional dyeing package, which is provided with a container for nesting: dyed fabric skein 13. The fabric skein η is continuously conveyed through the container 12 during the dyeing and rinsing process, in a non-implementation form, a driven mandrel 14 is used to carry the fabric skein 13. Medium, HI2, bottom region 15 configuration has - dye liquor cycle "16, its liquid: material: liquid: ring system 16 will separate the individual dyed liquor by means of - dye shield % recorded - heat exchanger 18 from the container, and dyed 19 200905034 liquid Re-input into the container 12 after heating. The fabric skein 13 is conveyed in the treated # by means of a car to the arrow 1 at a predetermined speed, wherein the transport speed is usually 2 〇〇 m / min and 8 〇〇 m / min. Change between. In addition, the dyed German ring system 16 is provided with an unillustrated cotton hopper and a dye tank. - a chemical and/or physical treatment of the dyeing or rinsing liquid in the reactor 6 in the bypass to the dyeing device 1G, wherein the unfixed dye is subjected to the use in the embodiment shown The chemical treatment of ozone, in order to destroy the dye, results in a colorless component. Reactor: The official channel 3 is connected to the -Ozone generator 2, and at the same time, the oxygen is generated through the pipeline "heart oxygen; and the reactor 6 is connected to the sputum by the first pipeline system 19; In the bottom region 15 of the state 12, while the flow direction of the π wood liquid is seen from the container 丨 2 ' m 0 reaction 6, the valve 2 is provided, and the reactor 6 is viewed through the second pipeline system 2, via - Salt test 7 * Zhehe / mouth wood liquid flow area 15. The D ° first valve 22 is connected to the bottom of the vessel 12. Finally, the third line system 23 reverses the air present in the reactor 6 to the exhaust fan 9, which is connected to the drain J1??. 4, 2, and 2 - Residual ozone eliminator 8 埂 Press and arrange the fan 9, and the equipment shown in the above diagram is operated as follows. The atmosphere is open. First, the dyeing apparatus is used to form the skein 13 of the fabric: the skein 13' therein which is inside the apparatus 2. The fabric in the lower zone of the container is then skeined and positioned in the zone/main draw liquor, while the dye liquor is continuously passed through the 20 200905034 wood liquor cycle system 16 in the actual dyeing process to "wheel I fabric skein 13.- Such a dyeing device 1 and the operation mode have long been in the prior art. ', Zhong Qiu: 2 after the dyeing device 1 染色 dyeing is completed, 'will be in the container 12, 甬 passed the '20 opening and In the dyeing pump 4 and via heat exchange k. The f-line system 19 is continuously fed to the reactor 6, in the reactor 6, only -av ^ ^ still contains 3 residual unabsorbed and fixed dyed dye liquor Ozone is supplied in the counter 6. At this time, the oxygen is continuously supplied to the reactor via the pipe 1 = give air in the ozone generator and is introduced into the reactor by means of the pipe 3 in a pre-filled manner. Batch, you, g open the reaction II 6 and night B to make the liquid-free liquid on the one hand, and no longer show residual ozone on the sensor of the second pipeline system on the other hand. Where residual ozone is still detected, it is automatically turned off 阙2〇^ & The system 19 is known to be in the >, and 21, and is open during processing. At the same time, the pump 4' is stopped to temporarily interrupt the procedure in the reactor. Thus, the decolorized dye liquor is passed through the ozone treatment via the second Pipeline system η
和打開的閥2 2進人空哭b M r L ^ 器的底°p區域15中並沖洗著色的織 物絞紗1 3，後者以一預定的 了貝疋的迷度沿箭頭方向19a持續地 送。And open the valve 2 2 into the bottom of the bottom of the mp sm 15 and wash the colored fabric skein 13 3, the latter with a predetermined bellows in the direction of the arrow 19a continuously give away.
<預疋的時間以後’該時間取決於待染色的基 布、所選擇的染料、色澤深度、染液比例和/或容器U 的裝載量以及輸送速度，現在結束沖洗過程，此時經由殘 餘臭氧消除益8破壞系姑由防丁 „ 啜系統中留下的殘餘臭氧、特別是處於 反應盗中的殘餘臭乳’從而經由排氣風扇9可以從系統中 21 200905034 排出無臭氧的廢氣。 然後可以對容器〗2通風，並從容考f 〇 取出著色的和<after the time of the pre-tanning, the time depends on the base fabric to be dyed, the selected dye, the color depth, the dye liquor ratio and/or the loading amount of the container U and the conveying speed, and now the flushing process is ended, at this time via the residue The ozone depletion benefit 8 destroys the residual ozone left in the system, especially the residual stinky milk in the reaction, so that the ozone-free exhaust gas can be discharged from the system through the exhaust fan 9 . Can ventilate the container 〗 2, and take out the colored and s
無瑕疫地沖洗後的織物絞紗，從而特別B 〜疋以在—總體上 為1 : 4至1 : 6的總染液比的情況下實施上述的染色過程 和沖洗過程。 【圖式簡單說明】 圖1係顯示一本發明設備的示意圖。 【主要元件符號說明】 1 管道 2 臭氧產生器 3 管道 4 染液泵 5 熱交換器 6 反應器 7 感測器 8 殘餘臭氧消除 9 排氣風扇 10 染色裝置 11 染色設備 12 容器 13 織物絞紗 14 心軸 22 200905034 15 16 17 18 19 19a 20 21 22 23 容器底部區域 染液循環系統 染液循壤果 熱交換器 第一管線系統 輸送方向箭頭 閥 第二管線系統 閥 第三管線系統 23The fabric skein after rinsing without plague, so that the above dyeing process and rinsing process are carried out in particular, in the case of a total dye ratio of 1:4 to 1:6. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing an apparatus of the present invention. [Explanation of main components] 1 Pipeline 2 Ozone generator 3 Pipeline 4 Dyeing pump 5 Heat exchanger 6 Reactor 7 Sensor 8 Residual ozone elimination 9 Exhaust fan 10 Dyeing device 11 Dyeing equipment 12 Container 13 Fabric skein 14 Mandrel 22 200905034 15 16 17 18 19 19a 20 21 22 23 Container bottom area dyeing circulation system dyeing liquid-passing fruit heat exchanger first line system conveying direction arrow valve second line system valve third line system 23