TW200836619A - Method and device for protecting crop plants - Google Patents
Method and device for protecting crop plants Download PDFInfo
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- TW200836619A TW200836619A TW096141480A TW96141480A TW200836619A TW 200836619 A TW200836619 A TW 200836619A TW 096141480 A TW096141480 A TW 096141480A TW 96141480 A TW96141480 A TW 96141480A TW 200836619 A TW200836619 A TW 200836619A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/10—Devices for affording protection against animals, birds or other pests
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2027—Poisoning or narcotising insects by vaporising an insecticide without heating
- A01M1/2055—Holders or dispensers for solid, gelified or impregnated insecticide, e.g. volatile blocks or impregnated pads
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
- A01M29/30—Scaring or repelling devices, e.g. bird-scaring apparatus preventing or obstructing access or passage, e.g. by means of barriers, spikes, cords, obstacles or sprinkled water
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
- A01M29/30—Scaring or repelling devices, e.g. bird-scaring apparatus preventing or obstructing access or passage, e.g. by means of barriers, spikes, cords, obstacles or sprinkled water
- A01M29/34—Scaring or repelling devices, e.g. bird-scaring apparatus preventing or obstructing access or passage, e.g. by means of barriers, spikes, cords, obstacles or sprinkled water specially adapted for insects
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Insects & Arthropods (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Toxicology (AREA)
- Birds (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Protection Of Plants (AREA)
- Catching Or Destruction (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
200836619 九、發明說明: 【發明所屬之技術領域】 本發明係關於保護農作物之方法。本發明進—步係關於 實施該方法之裝置。 【先前技術】 在世界範圍内,諸如昆蟲、蟎或真菌等有害生物體係收 •穫之重大威脅且需要大量使用諸如殺蟲劑及殺真菌劑等植 物保護劑(農藥)。 瞻雖然在此領域中之不斷研究及發展已產生對人類之毒性 顯著降低且環境相容性顯著改良之產品,但仍然存在的問 超疋二加用方法在植物中會造成一定程度之農藥殘留。 此抑制了某些高效農藥之使用。就其他農藥而言,此可能 延遲水果及蔬菜之可能的消費或加工,此對於各自產品的 收穫、儲存及出售皆為不期望的。 因此’仍非常需要可保護農作物以防有害生物體且容許 瞻選擇某些有效農藥而不會在植物中造成大量農藥殘留之方 法。 吾人已知(例如自WO 2005/060472)浸潰有某些殺蟲劑之 ' 蚊帳可增強蚊帳之功效且可使睡眠者免於可傳播諸如瘧疾 、 等疾病之昆蟲叮刺。 然而,該等網狀物主要在室内使用且雖然其應顯示洗滌 堅牢度(即甚至在數次洗滌後其應保持其殺蟲活性),但是 該等網狀物不會連續曝露於光、雨水及風中。 JP-A 08-163 950揭示一種藉由將聚烯烴樹脂與擬除蟲菊 126151.doc 200836619 酯殺蟲劑混合製造之用於控制昆蟲部分且尤其農業及園藝 用途之樹脂網狀物。然而,根據該文件之揭示内容,該網 狀物之主要預期用途係”室内,,使用,例如在溫室、廢及住 宅中。 獨〇3/觀27揭示-種包括具有適於阻止低飛類昆蟲進 入露天區域之高度的大體上垂直之結構的栅攔結構。該結 構浸潰有殺蟲劑。由於該柵攔結構,因此無需空氣、水及200836619 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a method for protecting crops. The invention is directed to a device for carrying out the method. [Prior Art] In the world, pest systems such as insects, mites or fungi receive significant threats and require the use of a large amount of plant protection agents (pesticides) such as insecticides and fungicides. Although continuous research and development in this field has produced products that have significantly reduced toxicity to humans and significantly improved environmental compatibility, there are still many methods for the use of pesticides in plants that cause a certain degree of pesticide residues. . This inhibits the use of certain highly effective pesticides. For other pesticides, this may delay the possible consumption or processing of fruits and vegetables, which is undesirable for the harvest, storage and sale of the respective products. Therefore, there is still a great need for a method that protects crops from harmful organisms and allows for the selection of certain effective pesticides without causing significant pesticide residues in the plants. It is known (for example from WO 2005/060472) that the impregnation of certain insecticides can enhance the efficacy of mosquito nets and protect sleepers from insect stings that can spread diseases such as malaria. However, such webs are primarily used indoors and although they should exhibit wash fastness (i.e., they should retain their insecticidal activity even after several washes), the webs are not continuously exposed to light or rain. In the wind. JP-A 08-163 950 discloses a resin network for controlling insect parts, particularly agricultural and horticultural uses, by mixing a polyolefin resin with a pyrethroid 126151.doc 200836619 ester insecticide. However, according to the disclosure of this document, the main intended use of the mesh is "indoor, use, for example in greenhouses, waste and dwellings." A substantially vertical structure of the barrier structure in which the insect enters the open area. The structure is impregnated with insecticide. Due to the barrier structure, air and water are not required.
光能容易地透過該結構,因為該結構沒有完全將植物覆 蓋。因此,該結構之雨水堅牢度可(例如)藉由使其非常防 水而改良。 然而’若整株植物欲藉由經浸潰之網狀結構保護,則不 得不滿足數個部分矛盾之要求。第一,需要空氣、光及水 可自由到達植物以確保其生長及保持良好狀態;第二,必 須阻止有害生物體進入該结槿· — 、口構,及弟二,控制劑之浸潰需 要具有一定程度之耐候性。 現已發現所有此等要求皆可蕻ώ n # 白J精由用一浸潰有某些農藥黏 結劑組合之帳篷狀裝置對植物實施保護而滿足。 【發明内容】 因此,在本發明一態樣中 物體之方法,該方法包括用 置覆盍一或多株植物之步驟 且可透光、空氣及水。 ’提供保護農作物以防有害生 包括穩定結構及網眼織物之裝 ’其中該網眼織物浸潰有農藥 根據本發明,可以容易且有 I文之方式保護農作物以防有 害生物體而不會對工人有健唐合 建康危害且不會在植物中或由此 126151.doc 200836619 所得之產品中造成農藥殘留。 在本發明另一態樣中,提供該用於保護農作物以防有害 生物體之裝置的使用。 在本發明又一態樣中,提供用於保護農作物以防有害生 物體之裝置,該裝置包括穩定結構及網眼織物,其中該網 眼織物浸潰有農藥且可透光、空氣及水。 【實施方式】Light can easily pass through the structure because the structure does not completely cover the plants. Therefore, the rain fastness of the structure can be improved, for example, by making it very resistant to water. However, if the whole plant is to be protected by the impregnated network structure, it must satisfy several contradictory requirements. First, it is necessary for air, light and water to reach the plants freely to ensure their growth and maintain good condition. Second, it is necessary to prevent harmful organisms from entering the knots, the mouth structure, and the second, the control agent's impregnation needs. Has a certain degree of weather resistance. All of these requirements have been found to be 蕻ώ n #白J精 is satisfied by the protection of plants with a tent-like device impregnated with a combination of certain pesticide binders. SUMMARY OF THE INVENTION Accordingly, in one aspect of the invention, the method includes the steps of: tiling one or more plants and is permeable to light, air, and water. 'Providing protection of crops to prevent harmful growth including stable structures and mesh fabrics' wherein the mesh fabric is impregnated with pesticides. According to the present invention, crops can be easily and in a manner that protects against harmful organisms without Workers are affected by Jiantang Hejiankang and will not cause pesticide residues in plants or in products obtained from 126151.doc 200836619. In another aspect of the invention, the use of the device for protecting crops against harmful organisms is provided. In still another aspect of the invention, an apparatus for protecting crops from harmful objects is provided, the apparatus comprising a stabilizing structure and a mesh fabric, wherein the mesh fabric is impregnated with pesticides and is permeable to light, air and water. [Embodiment]
本文所用術語"農作物”意指任何種類之農業作物,其包 括但不限於縠物、纟稻、豆科植物、棉花、煙草、蔬菜及 水果植物。 較佳為高值作物,如蔬菜、水果植物及用於飲料、藥物 及煙草卫業之植物及自其可獲得應用於化妝品、清潔及保 健調配物或其他化學及/或生物工藝過程之(例如)天然染料 及天然化合物的植物。 蔬菜植物或作物包括(例如)馬鈐著,較佳為殺粉質馬铃 箸、甘薯及餐用馬鈴薯;根菜,較佳為胡蘿萄、蓝菁甘該 (根甜菜、茬地蕪菁、蕪菁、蔓^ 月 lBrassica rapa· var. rapa f. teltowiensis))、鴉蔥、菊芋、根 很^芹、歐洲防風草根、The term "crop" as used herein means any kind of agricultural crop including, but not limited to, booties, japonica, legumes, cotton, tobacco, vegetables, and fruit plants. Preferred for high value crops such as vegetables and fruits. Plants and plants for the beverage, pharmaceutical and tobacco industries and plants from which, for example, natural dyes and natural compounds are available for use in cosmetic, cleansing and health care formulations or other chemical and/or biological processes. Or the crop includes, for example, a horse, preferably a powder-killing horse bell, a sweet potato, and a potato for meal; a root vegetable, preferably a carrot, a blue-green, a sweet beet, a beet, a turnip, a turnip, a vine ^ 月lBrassica rapa· var. rapa f. teltowiensis)), crow onion, Jerusalem artichoke, root is very celery, parsnip root,
小紅蘿蔔及辣根;塊莖蔬菜,較佳A 平乂佳為球呈甘藍、紅甜菜、 塊根芽、小紅蘿萄;鱗莖蔬菜’較佳為並葱及洋苗(洋苗 栽子及採種用洋蔥);甘藍菜’較佳為頭狀花序㈣歸 (白球甘藍、紅球甘藍、羽衣甘藍、 贩業甘藍)、花椰荽、 抱子甘藍、花莖甘藍、彩葉甘誌· 化椰未 κ lr 、 ^ m ^ ^(BrasSlca oleracea. var. sabelhca)、莖用甘藍、海甘誌 子持甘藍(Brassica I2615I.doc 200836619 oleracea L. c〇nvar. 〇leracea var dc广果菜, ,佳為番祐(野生番祐、叢生番莊、牛排番莊、溫室生番 茄、雞尾酒番茄、加工番茄及新鮮出售之番茄)、甜瓜、 茄、茄子、辣椒(鈐狀椒、紅辣椒、西班牙胡椒)、乾辣 2、南瓜、西萌蘆及黃瓜(野生黃瓜、溫室生黃瓜、蛇形 黃瓜、西印度黃瓜);豆類蔬菜,較佳為四季豆(如刀豆、 山毛櫸豆、笛豆、棉豆;蒸煮用乾豆,具有綠色及黃色豆 英之種類)、蔓生菜豆(如刀豆、山毛櫸豆、笛豆、棉豆, 具有綠色、藍色及黃色豆英之種類)、蠶豆(菜豆、胡豆、 具有白色及黑色斑駁花之種類)、豌豆(野豌豆、鷹嘴豆、 皺粒大婉豆、整莢碗豆、糖英婉豆、去殼用碗豆,具有淺 f色及深綠色未成熟種子之種類)及小扁豆;葉菜及莖 采,較佳為大白菜、萵苣、長葉葛苣、野苣、卷心萵苣、 ^菜、櫟葉萬苣、菊苣、意大利菊苣、紅捲鬚萵苣、芝麻 釆、巨賛菜、菠菜、瑞士甜菜(葉及莖)及歐芹;其他蔬 士’較佳為蘆荀、大黃、細香蔥、朝鮮莉、薄荷、向曰 癸 '佛羅儉薩(Fl〇rence)茴香、蒔蘿、獨行菜、芬菜、馨 粟、花生、芝麻及色拉用菊苣。 水果植物包括(例如)薔薇科水果,如蘋果、梨及榲棹; 核果,如杏、櫻桃、李+ · 夺 彳于及桃子,漿I,尤其係樹莓,如 f每、覆盆子、羅甘莓及链莓;真正漿果,如藍莓及酸果 :’其他漿果’如醋栗及桑播;附果’如草每;韻廬科水 包括倭瓜及南瓜;甜瓜及西瓜’·柑橘及其他 …帶水果’如«'酸橙'柚子、中國掛橘、克萊門氏 126151.doc 200836619 小柑橘(clementine)、紅橘、橙、鱷梨、番石榴、金橘、洛 根(bn)、篇枝及西番蓮果;棗椰子、無花果、葡萄、2 欖及石榴;及熱帶水果,如香蕉、椰子、榴蓮、蛋黃果、 芒果、倒撚子、木瓜、菠蘿及羅望子。 用於飲料及煙草工業之植物包括茶樹種類、咖啡樹及可 可樹種類及煙草。 其他較佳者係觀賞作物、堅果、藥草及香料。Small carrots and horseradish; tubers and vegetables, preferably A. Pingshuo is a cabbage, red beet, root bud, small red radish; bulb vegetables are preferably scallions and sunflower seedlings. With onion); cabbage blue 'preferably head flower (four) return (white cabbage, red cabbage, kale, cabbage), broccoli, Brussels sprouts, broccoli, colored leaves, sweet peppers, broccoli Lr , ^ m ^ ^ (BrasSlca oleracea. var. sabelhca), stem with cabbage, Haigan Zhizi holding cabbage (Brassica I2615I.doc 200836619 oleracea L. c〇nvar. 〇leracea var dc wide fruit,, Jia Weifan ( Wild Panyou, Congsheng Panzhuang, Steak Panzhuang, Greenhouse Tomato, Cocktail Tomato, Processed Tomato and Freshly Solder Tomato), Melon, Eggplant, Eggplant, Chili (Chopped Pepper, Red Pepper, Spanish Pepper), Dry Spicy 2 , pumpkin, western sprouts and cucumbers (wild cucumbers, greenhouse cucumbers, snake-shaped cucumbers, West Indian cucumbers); beans and vegetables, preferably green beans (such as beans, beech, flutes, cotton beans; cooking and drying Bean, with green and yellow beans Beans (such as peas, beech, natto, cotton beans, with green, blue and yellow beans), broad beans (beans, peas, with white and black mottled flowers), peas (wild Peas, chickpeas, wrinkled large kidney beans, whole pods of beans, sugary kidney beans, shelled beans, light f colors and dark green immature seeds) and lentils; leafy vegetables and stems, Preferred are Chinese cabbage, lettuce, long leaf lettuce, wild chicory, iceberg lettuce, ^ vegetable, eucalyptus, chicory, Italian chicory, red tendril lettuce, sesame meal, giant zucchini, spinach, Swiss chard (leaf) And stems) and parsley; other vegetables are better for reed, rhubarb, chives, Korean radish, mint, 曰癸 曰癸 'Fr〇rence fennel, dill, lone dish, fen Vegetables, sweet millet, peanuts, sesame seeds and salads with chicory. Fruit plants include (for example) Rosaceae fruits such as apples, pears and alfalfa; drupes such as apricots, cherries, plums + · succulents and peaches, pulp I, Especially raspberries such as f, raspberry, raspberry and raspberry; real berries Such as blueberries and cranberries: 'other berries' such as gooseberry and mulberry; fruit with 'grass per grass; rhyme water includes melon and pumpkin; melon and watermelon '· citrus and other ... with fruit 'such as «' lime 'Pomelo, Chinese hanging orange, Clemmen 126151.doc 200836619 Clementine (clementine), red orange, orange, avocado, guava, kumquat, Logan (bn), branch and passion fruit; jujube Coconut, fig, grape, 2 and pomegranate; and tropical fruits such as banana, coconut, durian, yolk, mango, scorpion, papaya, pineapple and tamarind. Plants used in the beverage and tobacco industry include tea tree species, Coffee tree and cocoa tree types and tobacco. Other preferred are ornamental crops, nuts, herbs and spices.
觀賞作物包括(但不限於)紫苑、杜鵑花、秋海棠、黃揚 樹、仙人掌、五彩芋、馬蹄蓮、金盞草、康乃馨、菊花、 錦紫蘇、射1菜、大麗花、離菊、黃花菜、飛燕草、石竹 類屬植物、復活節百合花、蕨類植物、榕屬植物、毛地 黃、倒掛金鐘、梔子花、天竺葵、大丁草、劍帛、木槿、 風仙花、蝴蝶花、常春藤、萬壽菊、旱金蓮花、三色堇、 牡丹、矮牽牛《匕、¥夾竹桃屬植物、石竹、一品紅、迷迭 香、玫瑰、印度橡膠樹、琴柱草、景天、金魚草、馬鞭 草、長春花、水竹草及百日菊。 堅果包括杏仁、巴西堅果、灰胡桃、腰果、栗子、馬卡 達姆堅果(macadamia)、美洲山核桃、阿月渾子及胡桃。 藥草及香料包括茴芹、香脂草、羅勒、黃春菊、香菜、 假刑介、芹菜、細香蔥、芫荽、傘花茴香、錫蘭九裏香、 蒲公英、蒔蘿、茴香、牛膝草、薄荷、芸香、鼠尾草、弗 吉尼亞木蘭、龍蒿、π里香、冬青樹及蒿草。 在杈佳實軛例中,該等農作物係農作物之秧苗,更佳 者係上述農作物之秧苗。亦較佳地,該等農作物在苗床或 126151.doc 200836619 小塊地上種植及/或形成苗圃之一部分。 本文所用術5吾保濩(pr〇tecti〇n或pr〇tecting),,意指控制或 驅除作用。 ^文所用術語"有害生物體"意指害蟲,尤其係節肢動物 害蟲,包括昆蟲及蜘蛛類節肢動物及有害微生物,尤其係 包括孢子、細菌及病毒之真菌。 本文所用術浯覆盍”意指織物或網狀物在欲保護之植物 $有害生物體間形成物理屏障,但並不意味著植物與該覆 盍材料物理接觸或阻止有害生物體到達植物。 網眼織物由非剛性材料製成。較佳為選自由以下組成之 群之紡織品材料或塑膠材料:紗線、單絲、纖維(如短纖 2及連績散纖維(CBF))、織物、針織品(尤其係網織品材 料)、無紡布、箔、阶斗、、上女η进 一 ,布及塗覆組合物。該網織品材 料可错由此項技術中熟知 力次I備,例如,所期雙 之網織品可藉由織造、 + 部分獲得。 m工、·扁或猎由縫合網織品之各 該纺織品材料或塑膠材料可由 成’亦可為呈紡布或I '、、'、δ成纖維製 键《、灿綠+ 次"、、布形式之紡織品摻合物(例如針 …口、V'線或纖維)。天然纖維係(例如 黃麻、亞麻、芋麻、大府禪毛、絲或诸如 人成纖飧m 麻及'年麻專轫皮纖維。舉例而言, 口成纖维為1醯私、聚芳醯胺、聚輯 (例如聚丙烯、聚乙歸、聚氯乙㈣/婦猜、聚稀煙 (TefJon)))^ " 齓乙烯(特氟隆 )))及纖維此合物(例如合成纖維與 物)。較佳者為聚_、„烴 ^維之^ I ^日尤佳者為聚對苯 I26151.doc 200836619 一甲酸乙二@旨。 術語材料亦包括諸如多孔猪之非纺織品基材。 此外’料材料括含麟素㈣,例㈣ 網狀物之棉材料。 衣服或棉 較佳地,該材料係紡織品材 烯、聚乙稀、聚醋或聚酿胺。 /材科’例如聚丙 更佳者係由聚醋(尤其聚對苯二甲酸乙二 品。在另一較佳實 " 、,罔織 該材枓係含纖維素材料。 穩定結:給網眼織物提供支樓以使其覆蓋欲保 物。在-貝施例中,穩定結構可為簡單的杆,其 地中且織物自其懸掛並讀佳藉助例如帳篷樁固定至 地二以形成帳蓬狀結構。數枝杆亦可用於該帳蓬狀結構。 在另-實施例中,該穩定結構包括—或多個其 織物之夹具狀結構。 ^ ^ 在又一實施例中,該穩定結構係網眼材料可佈置於盆上 以形成封閉内部用於騎_或多株植物以防有害生物體 框架。 亦可能藉助罐、澆灌之古加々姑, ^凡廣之支木或稭助欲保護之植物本身 (例如在果樹之情形下)提供該穩定結構。 該穩定結構可在保護性織物之内部或外部且可藉助分離 之結構心牛(如杆、夾具等)形成或在另一實施例 狀結構。 較佳地,用包含農藥之組合物處理該材料,然而,本發 明並不限於此等實施例。例如’亦可在製造纖維期間將農 126151.doc 200836619 藥引入纖維中。 久=材料顯示良好的害蟲控制效果且可對農作物提供持 質二:施例中,將農藥引入材料(例"入塑膠基 貝中)中或%加於材料之表面或二者。 佳實施例中,用包含以下之組合物處理材料: a) 至少一種農藥(組份a);及 b) 至y種聚合黏結劑(組份b )。 以該組合物之重量計,該農藥組合物通常包含"0195 重量%(較佳為(U_45會旦。/ s a * ^ 3 0*001 95 〇 5 里〇,更佺為0·5·30重量%,最佳為 0.5-25重1%)之至少一種農藥。 以該組合物之固體含晉曲— 組份: 计該辰樂組合物較佳包含以下 a) 0.1-45重量。/。(較佳為 曰 〇 , 1為0.%30重置%,更佳為1-25重量〇/〇) 之至>、一種農藥(組份Α);及 b) 5^9重量%(較佳為I%重量%,更佳為_重量%)之 種聚合黏結劑(組份B), 曰等且知之總1為該農藥組合物之固體含量的100重 篁% 〇 筚ί::!佳實施例中’以該組合物之固體含量計,該農 樂組合物包含以下組份: a) 20-70重量。/❶(較佳 s , (?乂佳為25_65重虿%,更佳為30-65重量❹/〇)之 V 一種農藥(組份A);及 b) 30-80重量%(較佳窗 (乂佺為35-75重置%,更佳為35·7〇重量0/〇)之 126151.doc -13- 200836619 至少一種聚合黏結劑(組份B), 其中該#組份之總量為該農藥組合物之固體 q版各里的100重 量%。 本文所用術語”農藥"包括殺蟲劑、驅蟲劑、殺真菌啕 滅螺劑及殺鼠劑。 α Θ 、 右在上下文中無另外說明,則本文所用術語"殺蟲劑"包 括具有殺節肢動物(尤其殺昆蟲、殺蟎及殺螨蟲)活 匕 劑。 ’ ‘之試 若在上下文中無另外說明,則本文所用術語"殺真菌劑” 包括具有权真囷、殺細菌及殺病毒活性之試劑。 較佳地’該農藥為殺蟲劑或驅蟲劑。 該農藥組合物尤其適用於如本發明所用之聚酯網織品。 本發明之農藥組合物可在紡織品材料或塑膠材料形成期 望產品之前(即,仍為紗線或呈片狀)或在形成期望產品之 後施加於該等材料。 農藥(组份Α) 較佳地,該農藥係對昆蟲具有快速麻痹或殺死效果且低 喷乳動物毒性之殺蟲劑及/或驅蟲劑。適宜殺蟲劑及/或驅 **劑已為熟習此項技術者所熟知。適宜殺蟲劑及驅蟲劑 (例如)在 E.C. Tomlin等人,The Pesticide Manua卜第十四 版,The British Crop Pr〇tecti〇n Council,Famham 2006及 其中所引文獻中予以揭示。 較佳之殺轰劑及/或驅蟲劑係如下所述: 擬除蟲菊酯類化合物,例如 126151.doc •14· 200836619 依芬寧(Etofenprox) : 2-(4-乙氧基苯基)-2•曱基丙基·3_ 本氧基节基鍵; 芬化利(Fenvalerate) : (RS)-2-(4_ 氯苯基)-3•甲基丁酸 (RS)-a-氰基-3-苯氧基苄基酯; 益化利(Esfenvalerate) : (S)-2-(4-氯苯基)-3-甲基丁酸 (S)-a-氰基-3-苯氧基节基g旨; 芬普寧(Fenpropathrin) : 2,2,3,3-四甲基環丙烷-甲酸 (RS)-a-氰基-3-苯氧基苄基酯; 賽滅寧(Cypermethrin) : (1RS)_ 順,反·3·(2,2-二氯乙烯 基)-2,2-一甲基壤丙烧甲酸(RS)-a-氮基-3-苯氧基节基酉旨; a-亞滅寧(a-Cypermethrin):包括(S)-a-(lR)及(R)-a_(ls) 非對映異構體之外消旋異構體,較佳具有500奈米至6微米 之粒徑; ζ-賽滅寧; 百滅寧(Permethrin) : (1RS)-順,反 _3-(2,2_ 二氣乙烯基)_ 2,2-二甲基環丙烷甲酸3-苯氧基苄基酯; 賽洛寧(Cyhalothrin) : (Z)_(lRS)_j^-3-(2-氯-3,3,3-三氣 丙小烯基)-2,2-二甲基環丙烷曱酸(RS)-a-氰基-3-苯氧基节 基醋(λ-cyhalothrin); λ·賽洛寧(λ-Cyhalothrine) : α-氰基_3_苯氧基苄基-3γ2_ 氣·3,3,3 -三I丙-1-細基)·2,2-«一*甲基環丙燒曱酸醋,例如 (Z)-(1R,3R),R-酯與(Z)-(1S,3S),S-酯之1 : i混合物; 第滅靈(〇6以&11^111411):(111)-順-3-(2,2-二溴乙烯基)-2,2_ 二甲基環丙烷甲酸(S)-a-氰基-3-苯氧基苄基酯; 126151.doc -15- 200836619 乙氱菊酯(Cycloprothrin) : (RS)-2,2-二氣小(4-乙氧基苯 基)環丙烷甲酸(RS)-a-氰基-3-苯氧基苄基酯; 福化利(Fluvalinate) : N-(2-氯-α,α,α,α-三氟-對曱苯基)-D-纈胺酸α-氰基—3-苯氧基苄基酯; 畢芬寧(Bifenthrin) : 0(Z)-(lRS)H3-(2-氯-3,3,3_ 三氟小 丙烯基)-2,2-二曱基環丙烷甲酸(2-甲基聯苯基_3·基曱基) 酯; 2-甲基-2_(4-溴二氟甲氧基苯基)丙基(3-苯氧基苄基) 醚; 泰滅寧(Tralomethrin) : (1R·順 ^((rRSKrjyj,-四漠乙 基))-2,2-二甲基環丙烷甲酸(S)-a-氰基-3-苯氧基节基_ ; 西拉福芬(Silafluofen) : 4-乙氧基苯基{3-(4•敗苯氧基 苯基)丙基}二甲基矽烷; D-分殺寧(Fenothrin): (1R-順,反)-菊酸3-苯氧基节基g旨; 赛酚寧(Cyphenothrin) : (1R-順,反)·菊酸(Rs)_心氰基 苯氧基苄基酯; D-苄呋菊酯(D-resmethrin) : (1R-順,反)_菊酸5_节基·3•咬 喃基甲基酯; 阿納寧(Acrinathrin) : (1R-順(Ζ))-(2,2-二甲基 _3_(氧代 3-(1,1,1,3,3,3-六氟丙氧基)丙烯基(環丙烷甲酸(8)·α·氣美 3-苯氧基苄基酯; 賽扶寧(Cyfluthrin) : 3-(2,2-二氯乙烯基)_2,2_二甲基澤 丙烷曱酸(RS)-a-氰基-4-氟-3-苯氧基苄基酯; 七氤菊酯(Tefluthrin) ·· (1RS-順(Z))-3_(2-氯-3 3 3•二知 ’ ’-二氣- 126151.doc -16- 200836619 丙小烯基)-2,2-二曱基環丙烧甲酸2,3,5,6 -四H-4-曱基节基 酯; 四氟苯菊酯(Transfluthrin) : (1R-反)_3-(2,2-二氯乙烯 基)·2,2·二甲基環丙烷甲酸2,3,5,6_四氟节基酯; 治滅寧(Tetramethrin) : (1RS)·順,反-菊酸3,4,5,6-四氫苯 二甲醯亞胺基甲基酯; 亞烈寧(Allethrin) : (1RS)-順,反-菊酸(rs)-3_烯丙基-2-甲基-4-氧代環戊-2-烯基酯; 普亞列寧(Prallethrin) : (1R)_順,反-菊酸(s)-2-甲基-4-氧 代-3-(2-丙炔基)環戊-2-烯基酯; 益避寧(Empenthrin) : (1R)-順,反-菊酸(rs)_1-乙炔基-2-甲基-2-戊烯基酯; 依普寧(Imiprothrin) : (1R)-順,反-2,2-二甲基-3-(2-甲基-1-丙烯基)-環丙烷甲酸2,5-二氧代-3-(丙-2-炔基)咪唑啶-1-基甲基酯; D_Flamethrin : (1R)-順,反-菊酸5-(2-丙炔基)-糠基酯及 2,2,3,3-四甲基環丙烷甲酸5_(2_丙炔基)糠基酯; 比普西芬(Pyriproxyfen) : 4-苯氧基苯基(RS)_2-(2-°比啶 基氧基)丙基醚; 除蟲菊粉;Ornamental crops include (but are not limited to) asters, azaleas, begonias, yellow poplars, cactus, colorful dragonflies, calla lily, calendula, carnations, chrysanthemums, coleus, shots, dahlia, chrysanthemum, day lily, delphinium , Dianthus, Easter Lily, Fern, Brassica, Foxglove, Fuchsia, Gardenia, Geranium, Gerbera, Sword, Hibiscus, Hydrangea, Pansy, often Ivy, marigold, nasturtium, pansy, peony, petunia, 匕, ¥ oleander, Dianthus, Poinsettia, Rosemary, Rose, Indian Rubber Tree, Psyllium, Sedum, Snapdragon, Verbena , periwinkle, water bamboo grass and zinnia. Nuts include almonds, brazil nuts, ash walnuts, cashews, chestnuts, macadamia, pecans, pistachio and walnuts. Herbs and spices include anise, balsamic, basil, chamomile, coriander, sin, celery, chives, alfalfa, umbellifera, ceylon, dandelion, dill, fennel, hyssop, mint , musk, sage, Virginia magnolia, tarragon, π lin, holly and wormwood. In the case of the yoke yoke, the crops of the crops are better, and the seedlings of the above crops are better. Also preferably, the crops are planted on the seedbed or on a small plot of 126151.doc 200836619 and/or form part of the nursery. As used herein, pr〇tecti〇n or pr〇tecting means “control or repellent action”. The term "harmful organism" as used in the text means pests, especially arthropod pests, including insects and spider arthropods and harmful microorganisms, especially fungi including spores, bacteria and viruses. As used herein, "clothing" means that a fabric or mesh forms a physical barrier between the pests to be protected, but does not imply that the plant physically contacts the barrier material or prevents harmful organisms from reaching the plant. The ocular fabric is made of a non-rigid material. It is preferably a textile material or a plastic material selected from the group consisting of yarns, monofilaments, fibers (such as staple fiber 2 and continuous fiber (CBF)), fabric, knitting. Products (especially netting materials), non-woven fabrics, foils, stepping buckets, upper females, fabrics and coating compositions. The fabric materials can be mistaken by the well-known techniques in the art, for example The double mesh fabric can be obtained by weaving, + partial. The m-work, the flat or the hunting of the textile material or the plastic material of the suture mesh can be made into a woven fabric or I', ', δ fiber-forming key, 'green + secondary', textile blends in the form of cloth (such as needles, mouths, V' lines or fibers). Natural fiber systems (such as jute, linen, ramie, Dafu Zen hair, silk or such as human fiber 飧m hemp and 'year hemp special leather fiber For example, the mouth fiber is 1 醯 private, poly linalin, poly (for example, polypropylene, polyethyl, polychloroethylene (four) / woman guess, TefJon) ^ " 齓Ethylene (Teflon)) and fibers (such as synthetic fibers and materials). Preferred are poly-, „hydrocarbon ^ Wei ^ ^ ^ ^ especially good for poly-p-phenylene I26151.doc 200836619 monocarboxylic acid B two @purpose. The term material also includes non-textile substrates such as porous pigs. In addition, the material includes a cotton material containing linseed (4), and (4) mesh. Clothes or cotton Preferably, the material is a textile material, a polyethylene, a polyester, or a polyamine. /Materials, such as more polypropylene, are made of polyacetate (especially polyethylene terephthalate. In another preferred embodiment), weaving the cellulose-containing material of this material. Stable knot: the net The eye fabric provides a wrap to cover the object. In the case of Becker, the stabilizing structure can be a simple rod in which the fabric is suspended from it and read by a tent, for example, to the ground to form an account. A canopy structure. Several branches can also be used for the tent-like structure. In another embodiment, the stabilizing structure comprises - or a plurality of jig-like structures of the fabric thereof. ^ ^ In yet another embodiment, the stabilizing structure The mesh material can be arranged on the basin to form a closed interior for riding or multi-plants to prevent harmful organisms. It is also possible to use the cans, watering Gujiayu, ^Wanguangzhimu or straw aids. The protected plant itself (for example in the case of fruit trees) provides the stabilizing structure. The stabilizing structure may be internal or external to the protective fabric and may be formed by means of a separate structural heart (such as a rod, clamp, etc.) or in another implementation Example structure. Preferably, a group containing pesticides The material is treated, however, the invention is not limited to such embodiments. For example, 'Pharmaceutical 126151.doc 200836619 may also be introduced into the fiber during the manufacture of the fiber. Long time = material shows good pest control effect and can be provided for crops Holder 2: In the example, the pesticide is introduced into the material (for example, into the plastic base) or % is added to the surface of the material or both. In a preferred embodiment, the material is treated with the following composition: a) At least one pesticide (component a); and b) to y polymeric binder (component b). The pesticidal composition usually comprises "0195 wt% based on the weight of the composition (preferably (U_45会旦./ sa * ^ 3 0*001 95 〇5 〇, more 0 0·5·30) 5% by weight, preferably 0.5 to 25 % by weight of the at least one pesticide. Solids containing the composition - The composition: Preferably, the composition comprises the following a) 0.1-45 by weight. /. (preferably 曰〇, 1 is 0.%30 reset %, more preferably 1-25 weight 〇/〇) to >, one pesticide (component Α); and b) 5^9 wt% ( Preferably, I% by weight, more preferably _% by weight, of a polymeric binder (Component B), 曰, etc., and a total of 1 is 100% by weight of the solid content of the pesticide composition 〇筚ί:: In a preferred embodiment, the agricultural composition comprises the following components in terms of the solids content of the composition: a) 20-70 by weight. /❶ (preferably s, (? 乂 preferably 25_65 weight %, more preferably 30-65 weight ❹ / 〇) V a pesticide (component A); and b) 30-80% by weight (better window (乂佺 35-75 reset %, more preferably 35·7〇 weight 0 / 〇) 126151.doc -13- 200836619 at least one polymeric binder (component B), wherein the total amount of the # component 100% by weight of the solid q plate of the pesticide composition. The term "pesticide" as used herein includes insecticides, insect repellents, fungicidal quenching agents and rodenticides. α Θ , right in the context Unless otherwise stated, the term "insecticide" as used herein includes live mites with arthropods (especially insecticidal, acaricidal and acaricidal). ' 'The test is used in this article if it is not otherwise stated in the context. The term "fungicide" includes agents having the potent, bactericidal, and virucidal activity. Preferably, the pesticide is an insecticide or an insect repellent. The pesticide composition is particularly useful for use in the polymerization of the present invention. Ester netting. The pesticidal composition of the present invention can be formed before the textile material or the plastic material forms the desired product (ie, Still in the form of a yam or in the form of a sheet or after forming a desired product. Pesticide (component Α) Preferably, the pesticide has a rapid paralysis or killing effect on insects and is toxic to low-spray animals. Insecticides and/or insect repellents. Suitable insecticides and/or repellents are well known to those skilled in the art. Suitable insecticides and insect repellents (for example) in EC Tomlin et al., The Pesticide The fourteenth edition of Manua, published by The British Crop Pr〇tecti〇n Council, Famham 2006 and the references cited therein. Preferred bactericides and/or insect repellents are as follows: Pyrethroids Compounds, for example 126151.doc •14· 200836619 Etofenprox: 2-(4-ethoxyphenyl)-2•mercaptopropyl·3_-enoxy-based linkage; Fenvalerate : (RS)-2-(4_chlorophenyl)-3•methylbutyric acid (RS)-a-cyano-3-phenoxybenzyl ester; Esfenvalerate: (S)-2 -(4-chlorophenyl)-3-methylbutyric acid (S)-a-cyano-3-phenoxyl group g; Fenpropathrin: 2,2,3,3-tetra Cyclopropane-formic acid (RS)-a-cyano-3-phenoxy Cypermethrin: (1RS)_ cis, trans·3·(2,2-dichlorovinyl)-2,2-methyl-methyl-propionic acid (RS)-a-nitrogen -3-phenoxyl group; a-Cypermethrin: including (S)-a-(lR) and (R)-a_(ls) diastereomers Isomers, preferably having a particle size of from 500 nm to 6 μm; ζ-赛灭宁; Permethrin: (1RS)-cis, anti-3-3-(2,2_diethylene) _ 2,2-Dimethylcyclopropanecarboxylic acid 3-phenoxybenzyl ester; Cylonthrin: (Z)_(lRS)_j^-3-(2-chloro-3,3,3- Tris-propyl small alkenyl)-2,2-dimethylcyclopropane decanoic acid (RS)-a-cyano-3-phenoxy benzyl vinegar (λ-cyhalothrin); λ·赛洛宁(λ- Cyhalothrine) : α-cyano-3-phenyloxybenzyl-3γ2_gas·3,3,3-tri-I-propan-1-yl)·2,2-«-*methylcyclopropanone citrate , for example, (Z)-(1R,3R), R-ester with (Z)-(1S,3S), S-ester 1:1 mixture; Dioxin (〇6 to &11^111411):( 111)-cis-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylic acid (S)-a-cyano-3-phenoxybenzyl ester; 126151.doc -15 - 200836619 Permethrin (Cycloprothrin) : (RS)-2,2-di-gas small (4-ethoxyphenyl)cyclopropanecarboxylic acid (RS)-a-cyano-3-phenoxybenzyl ester; Fuhualide : N-(2-chloro-α,α,α,α-trifluoro-p-phenylene)-D-proline acid α-cyano-3-phenoxybenzyl ester; Bifenthrin: 0(Z)-(lRS)H3-(2-chloro-3,3,3_trifluoropropenyl)-2,2-dimercaptocyclopropanecarboxylic acid (2-methylbiphenyl-3-enyl) Ethyl 2-(2-bromodifluoromethoxyphenyl)propyl (3-phenoxybenzyl) ether; ,- four desert ethyl))-2,2-dimethylcyclopropanecarboxylic acid (S)-a-cyano-3-phenoxyl group _; silafluofen: 4-ethoxyl Phenyl {3-(4• phenoxyphenyl)propyl}dimethyl decane; D-Fenothrin: (1R-cis, trans)-3-phenoxyl group Cyphenothrin: (1R-cis, trans) · chrysanthemic acid (Rs) _ heart cyanophenoxybenzyl ester; D-resmethrin: (1R-cis, Anti) _ chrysanthemic acid 5 _ 基 · 3 • ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Ac Ac Ac Ac -Dimethyl_3_(oxo-3-(1,1,1,3,3,3-hexafluoropropoxy)propenyl (cyclopropanecarboxylic acid (8)·α·Gamei 3-phenoxybenzyl Base ester; Cyfluthrin: 3-(2,2-dichlorovinyl)_2,2-dimethylzepropanoic acid (RS)-a-cyano-4-fluoro-3-phenoxy Benzyl ester; Tefluthrin · (1RS-cis(Z))-3_(2-chloro-3 3 3•二知' '-二气- 126151.doc -16- 200836619 Alkenyl)-2,2-dimercaptocyclopropanecarboxylic acid 2,3,5,6-tetra-H-4-mercaptol ester; Tefluthrin: (1R-reverse)_3- (2,2-dichlorovinyl)·2,2·dimethylcyclopropanecarboxylic acid 2,3,5,6-tetrafluorobenzyl ester; Tetramethrin: (1RS)·Shun, anti- Chrysanthemum 3,4,5,6-tetrahydrobenzhydryl iminomethyl ester; Allethrin: (1RS)-cis, trans-chrysanthemic acid (rs)-3_allyl- 2-methyl-4-oxocyclopent-2-enyl ester; Prallethrin: (1R)_cis, trans-chrysanthemic acid (s)-2-methyl-4-oxo-3 -(2-propynyl)cyclopent-2-enyl ester; Empenthrin: (1R)-cis, trans-chrysanthemic acid (rs)_1-ethynyl-2-methyl-2-pentyl Alkenyl ester (Imiprothrin) : (1R)-cis, trans-2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylic acid 2,5-dioxo-3-(propyl- 2-alkynyl imidazolidin-1-ylmethyl ester; D_Flamethrin: (1R)-cis, trans-chrytonic acid 5-(2-propynyl)-nonyl ester and 2,2,3,3-tetra 5-(2-propynyl) decyl ester of methylcyclopropanecarboxylic acid; Pyriproxyfen: 4-phenoxyphenyl (RS) 2 - (2-pyridyloxy) propyl ether ; pyrethrum powder;
d-d,反-賽酚寧:(lRS,3RS;lRS,3SR)-2,2-:T*-3-(2-T 基丙―1-烯基)環丙烷甲酸(RS)-a-氰基-3-苯氧基苄基酯; DDT ; 賽扶寧; 126151.doc -17- 200836619 胺基甲酸酯類化合物,例如 阿蘭克(Alanycarb) : S-曱基-Ν[[Ν·曱基-Ν-[Ν·节基-N(2- 乙氧基·羰基乙基)胺基-硫代]胺甲醯基]硫代亞胺逐乙酸 酯; 免敵克(Bendiocarb) : 2,2-二甲基-1,3 -苯并間二氧環戊 細-4-基-甲基胺基甲酸醋; 加保利(Carbaryl) : N-甲基胺基甲酸1-萘基酯; 滅必虱(Isoprocarb):曱基胺基甲酸2-(1·甲基乙基)苯基 酯; 丁基加保扶(Carbosulfan) : 2,3_ 二氫-2,2-二甲基-7-苯并 呋喃基[(二丁基胺基)硫代]曱基胺基甲酸酯; 芬諾克(Fenoxycarb) : [2-(4-苯氧基苯氧基)乙基]胺基曱 酸乙酯; 引多殺克(Indoxacarb):甲基-7-氯-22,3,4,5·四氫-2-[甲 氧基羰基(-4-三氟-曱氧基苯基)]; 安丹(Propoxur) ·· 2-異丙基氧基苯盼甲基胺基甲酸酯; 比加普(卩11^111卜&1*1)):2-二曱基胺基-5,6-二甲基-4-嘴。定 基-二甲基胺基甲酸酯; 賽多保(Thiodiocarb) : N,N’(硫代雙((甲基亞胺基)幾基氧 基)雙硫代乙亞胺酸二曱基酯; 納乃得(Methomyl) : S-甲基N-((曱基胺甲醯基)氧基)硫 代乙醯胺化物; 愛芬克(Ethiofencarb):甲基胺基曱酸2-((乙基硫代)甲 基)苯基酯; 126151.doc 18 200836619 芬硫克(Fenothiocarb) : N,N-二甲基硫代胺基甲酸S_(4-苯氧基丁基)-酯; 培丹(Canap) : S,S’-(2,5_二甲基胺基)三亞曱基)雙(硫代 胺基甲酸酯)氫氯酸鹽; 丁基滅必乱(Fenobucarb):曱基胺基曱酸2-第二丁基苯 基酯; ‘ XMC :甲基胺基曱酸3,5-二甲基苯基酯; 滅殺威(Xylylcarb):曱基胺基甲酸3,4-二甲基苯基酯; 得滅克(aldicarb)、本夫克(benfbracarb)、加保扶(carbofliran)、 丁基加保扶、滅賜克(methiocarb)、丁基滅必風、歐殺滅 (oxamyl)、納乃得、硫地克(thiodicarb)及三阿劄美 (triazamate); 有機填化合物,例如: 三氯松(Tdchlorfon) ··磷酸(2,2,2-三氯-1-羥乙基)-二甲基 酯; φ 撲滅松(Fenitrothion) : 二甲基0-(4-硝基-間甲苯基) 硫代磷酸酯; 大利松(Diazinon) : 二乙基- 0-(2-異丙基-6-甲基-4- • 嘧啶基)硫代磷酸酯; - 必芬松(Pyridaphenthion) : 0·(1,6 -二氫-6-氧代-1·苯基 〇 比 嗓咬(pyrazidin)-3-基)0,0-二乙基硫代填酸醋; 必減松(Pirimiphos-Ethyl) : 0,0 二乙基 0-(2-(二乙基胺 基)6-甲基-嘧啶基)硫代磷酸酯; 亞特松(Pirimiphos-Methyl) : 0- [2-(二乙基胺基)-6-曱基- 126151.doc -19- 200836619 4-嘧啶基]0,0-二甲基硫代磷酸酯; 芬滅松(Etrimphos) : 0-6 -乙氧基-2-乙基-嘴°定_4-基 二甲基-硫代磷酸酯; 芬殺松(Fenthion) : 二曱基_〇·[-3-甲基-4-(甲基琉 代)苯基硫代磷酸酯; 巴賽松(Phoxim) : 2_(二乙乳基鱗基亞硫酿基氣基亞胺 基)-2-苯基乙腈; 陶斯松(Chlorpyrifos) : 二乙基-0-(3,5,6-三氯 _2“比 σ定基)硫代填酸醋, 甲基毒死蜱(Chlorpyriphos-methyl) : 二甲基 (3,5,6-三氯-2-吡啶基)硫代磷酸酯; 殺螟腈(Cyanophos) : 二甲基0-(4-氰基苯基)硫代碟 酸酯; 白克松(Pyraclofos) : (R,S)[4-氣苯基]-π比吐-4-基]乙 基-S-正-丙基硫代磷酸酯; 毆殺松(Acephate) : 0,S-二甲基乙醯基胺基硫代碟酸 酯; 亞滅松(Azamethiphos) : S_(6-氯-2,3-二氫-氧代-i,3_p号唾 并[4,5-b]吡啶-3-基甲基硫代磷酸酯; 馬拉松(Malathion) ··魏基琥珀酸二乙基酯之二甲芙 硫代磷酸酯; 亞培松(Temephos) : (0,0f(硫代二-4-1-伸苯基)〇,〇,〇 〇-四甲基二硫代磷酸酯; 大滅松(Dimethoate) : ((0,0-二甲基s-(正曱基胺甲醯基 126151.doc -20- 200836619 乙基)二硫代磷酸酯; 福木松(Formothion) : S[2-甲醯基甲基胺基]-2-氧代乙 基]二甲基二硫代磷酸酯; 賽達松(Phenthoate) : 二曱基S-(a-乙氧基魏基亞苄 基)二硫代磷酸酯; 阿發松(lodofenphos) ·· 0-(2,5-二氣-4-埃苯基)-0,0-二曱 ' 基-硫代磷酸酯; 亞素靈(Monocrotophos)、達馬杉(methamidophos)、甲 基巴拉松(parathion_methyl)、布飛松(profenfos)及託福松 (terbufos); 對成蚊具有殺菌效果之殺蟲劑,例如: 1-(α-(氯- 01-¾丙基亞节基胺基-氧基)對甲苯基)-3-(2,6 -二 氟苯甲醯基)脲; 二福隆(Diflubenzuron) : N-(((3,5-二氣-4-( 1,1,2,2-四氟 乙氧基)苯基胺基)羰基)2,6-二氟苯甲醯胺; _ 殺蟲隆(Triflimmron) : 2-氯-N-(((4-(三氟甲氧基)苯基)- 胺基-)羰基)苯甲醯胺或諸如N-環丙基·1,3,5-三嗪-2,4,6-三 胺等三嗪環; 煙驗乙醯膽驗受體激動劑,例如亞滅培(acetamiprid)、 • 可尼丁(clothianidin)、達特南(dinotefuran)、益達胺 (imidacloprid)、浠咬蟲胺(nitenpyram)、嗟蟲琳 (thiacloprid)、塞美索佔(thiamethoxam)、煙驗、免速達 (bensultap)、硫環蘭(thiocyclam)、賜語殺(spinosyns); 氯通道活化劑,例如阿巴美丁(abamectin)、伊曼美丁 126151.doc -21- 200836619 (emamectin)苯甲酸鹽、密滅汀(milbemectin); 保幼激素模擬物,例如烯蟲乙S旨、烯蟲炔S旨、曱氧普林 (methoprene)、芬諾西克(fenoxycarb)、比普西芬; 選擇性進食阻斷劑,例如冰晶石、比美卓秦(Pymetr〇zine)、 氟啶蟲醯胺; 蟎類生長抑制劑,例如克芬蟎(cl〇fentezine)、合賽多 (hexythiazox)、伊妥 σ惡峻(etoxazole); 細菌殺蟲劑,例如蘇雲金芽孢桿菌(Bacillus thuringiensis)、蘇 雲金芽孢桿菌鯰澤亞種(Β· t· aizawai)、蘇雲金芽孢桿菌庫 爾斯塔克亞種(B.t. kurstaki)、蘇雲金芽孢桿菌粉蟲變種 (B.t· tenebrionis)、球形芽孢桿菌(B· sphaericus); 氧化填酸化抑制劑,ATP形成干擾劑,例如戴芬西隆 (diafenthiuron)、三嗤錫(azocyclotin)、錫滿丹(cyhexatin)、 芬布賜(fenbutatin oxide)、歐蜗多(propargite)、三氣殺虫高 石風(tetradifon); ^ 氧化填酸化之解偶聯劑,例如克芬那比(chlorfenapyr)、 DNOC (4,6-二硝基-鄰甲酚); 幾丁質生物合成抑制劑,例如克福隆(chlorfluazuron)、 IL 佐隆(fluazuron)、二福隆、氟芬隆(flufenoxuron)、六伏 , 隆(hexaflumuron)、諾華隆(novaluron)、多氟蟲醯脲 (noviflumuron)、得福隆(teflubenzuron)、殺蟲隆(triflumuron)、 布芬淨(buprofezin); 蜆皮激素激動劑及蜆皮干擾劑,例如西洛美秦 (cyromazine)、印苦楝子素、環蟲醯肼、鹵芬載 12615I.doc -22- 200836619 (halofenozide)、曱氧蟲醯肼、得布芬載(tebufenazide); 奥克巴胺能(octopamineergic)激動劑,例如三亞虫高 (amitraz); 偶聯位點II電子轉移抑制劑,例如經甲隆(hydramethylnon)、 阿色奎西(acequinocyl)、嘴蜗酉旨(fluacrypyrim); 偶聯位點I電子轉移抑制劑,例如芬那劄奎(fenazaquin)、 芬普蜗(fenpyroximate)、σ密蜗醚(pyrimidifen)、比達本 (pyridaben)、得布芬比(tebufenpyrad)、峻蟲醢胺 (tolfenpyrad)、魚藤酮(rotenone); 電壓依賴性鈉通道阻斷劑,例如引多殺克; 脂質合成抑制劑,例如螺二克芬(spirodiclofen)、螺甲 虫萵醋(spiromesifen); 線粒體複合物IV電子轉移抑制劑,例如磷化物、氰化 物、膦; 神經元抑制劑,例如畢芬載(bifenazate); 烏頭酸酶抑制劑,例如氟乙醯化物; 增效劑,例如增效醚、DEF ((BuS)2P(CO)SBu); 斯里蘭卡肉桂驗(Ryanodine)受體調節劑,例如氟蟲醯胺 (flubendiamide); 作用方式未知之化合物,例如苯蜗特(benzoximate)、滅 蜗猛(chinomethionat)、大克蜗(dicofol)、唆蟲丙醚 (pyridalyl); 混雜非特異性抑制劑,例如硼砂、酒石酸銻鉀。 適宜驅蟲劑較佳選自N,N-二乙基-間甲苯甲醯胺 126151.doc -23- 200836619 (DEET)、N,N-二乙基苯乙醯胺(DEPA)、1胃(3-環己小基_幾 基)-2-甲基胡椒驗、(2 -經曱基環己基)乙酸内|旨、2-乙基_ 1,3-己二醇、避蟲酮、甲基新癸醯胺(MNDA)、不用於民蟲 控制之擬除蟲菊酯,例如{(+/-)-3-烯丙基-2-甲基-4-氧代環 戍-2-(+)-稀基-(+)-反-菊酸醋(賜百寧(Esbiothrin))、源自植 物浸出液或與植物浸出液相同之驅蟲劑,如檸檬油精、τ " 香酚、(+)-赤桉醇(Eucamalol)(l)、( + 1-表-赤桉醇或來自 如檸檬桉(Eucalyptus maculata)、白背蔓荊(Vitex rotimdifolia)、馬 丁香(Cymbopogan martinii)、檸檬香茅(Cymbop0gan citratus)(檸檬草(lemon grass))、香茅(Cymbopogan nartdus)(香茅 (cittonella))等植物之粗植物浸出液、IR3535(丁基乙醯基 胺基丙酸乙酯)、羥哌酯(1-哌啶甲酸2-(2-羥乙基)·1-甲基丙 基酯)。 適宜滅螺劑係(例如)耐克螺(niclosamide)。 適宜殺真菌劑係(例如) ^ 唆類,例如白特丹羅(Bitertanol)、溴康嗤(Bromoconazole)、 環克嗤(Cyproconazole)、地芬康吐(Difenoconazole)、二石肖 基克吐(Dinitroconazole)、環氧康嗤(Epoxiconazole)、芬布 康嗤(Fenbuconazole)、氟奎康峻(Fluquinconazole)、護石夕 得(Flusilazole)、護汰芬(Flutriafol)、六康嗤(Hexaconazole)、 依滅列(Imazalil)、種菌唾(Ipconazole)、麥康嗤(Metconazole)、 麥環丁尼(Myclobutanil)、潘康唾(Penconazole)、普克利 (Propiconazole)、撲克拉(Prochloraz)、撲硫康 °坐 (Prothioconazole)、石夕氟嗤(Simeconazole)、得克利 126151.doc -24- 200836619 (Tebuconazole)、四克利(Tetraconazol)、三泰芬(Triadimefon)、 三泰隆(Triadimenol)、三氟味°坐(Triflumizol)、三替康。坐 (Triticonazol);Dd, trans-cyprodinil: (lRS, 3RS; lRS, 3SR)-2,2-:T*-3-(2-T-propyl-l-alkenyl)cyclopropanecarboxylic acid (RS)-a-cyanide Benzyl-3-phenoxybenzyl ester; DDT; Saifuning; 126151.doc -17- 200836619 Carbamate compounds, such as Alanycarb: S-mercapto-purine [[Ν·曱基-Ν-[Ν·节基-N(2-ethoxycarbonylethyl)amino-thio]aminemethanyl]thioimine acetate; Bendiocarb: 2, 2-Dimethyl-1,3-benzo-dioxocyclopentan-4-yl-methylamino carboxylic acid vinegar; Carbaryl: N-methylaminocarbamic acid 1-naphthyl ester; Isoprocarb: 2-(1·methylethyl)phenyl thioglycolate; Carbosulfan: 2,3_Dihydro-2,2-dimethyl-7- Benzofuranyl[(dibutylamino)thio]nonylaminoformate; Fenoxycarb: [2-(4-phenoxyphenoxy)ethyl]amino decanoic acid Ethyl ester; Indoxacarb: methyl-7-chloro-22,3,4,5·tetrahydro-2-[methoxycarbonyl(-4-trifluoro-decyloxyphenyl)] ; Anpo (Propoxur) · 2-Isopropyloxyphene methylaminocarbamic acid ; Bi Jiapu (111 ^ 11 Jie Bu & 1 * 1)): 2- Yue two amino-5,6-dimethyl-4- yl mouth. Stationary-dimethyl carbazate; Thiodiocarb: N,N' (dithio(bis((methylimido)))oxy) bis thioacetimidate ; Methomyl : S-methyl N-((decylamine-mercapto)oxy) thioacetamidine; Ethiofencarb: methylamino phthalic acid 2-(( Ethylthio)methyl)phenyl ester; 126151.doc 18 200836619 Fenothiocarb: N,N-dimethylthiocarbamic acid S_(4-phenoxybutyl)-ester; Canap: S,S'-(2,5-dimethylamino)triazinyl)bis(thiocarbamate)hydrochloride; fenbucarb: 曱2-Aminobutyl phthalate; 'XMC: 3,5-dimethylphenyl methyl decanoate; Xylylcarb: hydrazinocarbamic acid 3, 4 - dimethyl phenyl ester; aldicarb, benfbracarb, carbofliran, butyl plus guaiacarb, metiocarb, butyl chlorhexidine, eucalypt Oxamyl, naphthalene, thiodicarb and triazamate; organic filling Compounds such as: Tdchlorfon · Phosphoric acid (2,2,2-trichloro-1-hydroxyethyl)-dimethyl ester; φ Finitrothion: Dimethyl 0-(4- Nitro-m-tolyl) phosphorothioate; Diazion: Diethyl- 0-(2-isopropyl-6-methyl-4-pyrimidinyl) phosphorothioate; - Bifen Pyridaphenthion: 0·(1,6-dihydro-6-oxo-1·phenylindole (pyrazidin-3-yl)0,0-diethylthio acid vinegar; Pirimiphos-Ethyl: 0,0 Diethyl 0-(2-(diethylamino)6-methyl-pyrimidinyl) phosphorothioate; Pirimiphos-Methyl: 0- [2-(Diethylamino)-6-fluorenyl- 126151.doc -19- 200836619 4-pyrimidinyl]0,0-dimethylthiophosphate; Etrimphos : 0-6 -Ethoxy-2-ethyl-mouth 1,4-methyl thiophosphate; Fenthion: Dimethyl 〇 [ [-3-methyl-4-(A Phenyl thiophosphate; Phoxim: 2_(diethyl squary sulfenyl sulphate)-2-phenylacetonitrile; Chlorpyrifos: 2 Base-0-(3,5 , 6-trichloro-2 "specific sigma" thioacetate, Chlorpyriphos-methyl: dimethyl (3,5,6-trichloro-2-pyridyl) phosphorothioate; Cyanophos: dimethyl 0-(4-cyanophenyl) thioate; Pyraclofos: (R, S) [4-phenylphenyl]-π ratio -4- Ethyl-S-n-propyl phosphorothioate; Acephate: 0,S-dimethylethenylthio thioate; Azamethiphos: S_( 6-Chloro-2,3-dihydro-oxo-i, 3_p-des-[4,5-b]pyridin-3-ylmethylphosphorothioate; Marathon ··Weiji succinic acid II Ethyl ester of dimethyl thiophosphate; Temephos: (0,0f (thiodi-4-1-phenylene) hydrazine, hydrazine, hydrazine-tetramethyldithiophosphoric acid Ester; Dimethoate: ((0,0-dimethyls-(n-decylaminecarbaryl 126151.doc -20- 200836619 ethyl) dithiophosphate; Formosaion) : S[2-Methylmethylamino]-2-oxoethyl]dimethyldithiophosphate; Phenthoate: Dimercapto S-(a-ethoxywei) Benzylidene disulfide Phosphate; lodofenphos · · 0-(2,5-dioxa-4-Epyl)-0,0-dioxin'-thiophosphate; Monocrotophos, up to Methaldophos, parathion_methyl, profenfos and terbufos; insecticides that have a bactericidal effect on adult mosquitoes, for example: 1-(α-(chlorine - 01-3⁄4) Propyl arginylamino-oxy)p-tolyl)-3-(2,6-difluorobenzhydryl)urea; Diflubenzuron: N-((3,5-digas) 4-(1,1,2,2-tetrafluoroethoxy)phenylamino)carbonyl)2,6-difluorobenzamide; _ Triflimmron: 2-chloro-N- (((4-(Trifluoromethoxy)phenyl)-amino-)carbonyl)benzamide or such as N-cyclopropyl·1,3,5-triazine-2,4,6-three A triazine ring such as an amine; a acetaminophen receptor agonist such as acetamiprid, clothianidin, dinotefuran, imidacloprid, biting insect Amine (nitenpyram), thiacloprid, thiamethoxam, smoke test, benzultap, thiocyc Lam), spinosyns; chloride channel activators, such as abamectin, imanmetin 126151.doc -21- 200836619 (emamectin) benzoate, milbemectin; Juvenile hormone mimics, such as methionine, methionine, mesoprene, fenoxycarb, bepexine; selective eating blockers, such as cryolite, Pyretrazine (Pymetr〇zine), fluramide; steroid growth inhibitors, such as cl〇fentezine, hexythiazox, etoxazole; bacterial insecticide Agents such as Bacillus thuringiensis, Bacillus thuringiensis (鲶·t·aizawai), Bacillus kurstaki, Bacillus thuringiensis (Bt kurstaki) Tenebrionis), B. sphaericus; oxidative acidification inhibitor, ATP forming interfering agents such as diafenthiuron, azocyclotin, cyhexatin, fenbuxine Fenbutatin oxide) (ite), three gas-killing tetradifon; ^ oxidative acid-filling uncoupler, such as chlorfenapyr, DNOC (4,6-dinitro-o-cresol); chitin Synthetic inhibitors such as chlorfluazuron, fluzuron, flufenoxuron, flufenoxuron, hexaflumuron, novaluron, polyflufenic acid urea ( Noviflumuron), teflubenzuron, triflumuron, buprofezin; ecdysone agonist and molting agent, such as cyromazine, azadirachtin, ring Insects and halogens contain 12615I.doc -22- 200836619 (halofenozide), aerobic worms, tebufenazide, octopaminergic agonists, such as amitraz Coupling site II electron transfer inhibitors, such as hydramethylnon, acequinocyl, fluacrypyrim; coupling site I electron transfer inhibitors, such as fennazak (fenazaquin), fenpyroximate, σ cryptoether (pyr Imidifen), pyripaben, tebufenpyrad, tolfenpyrad, rotenone; voltage-dependent sodium channel blockers, such as indomethacin; lipid synthesis inhibitors For example, spirodiclofen, spiromesifen; mitochondrial complex IV electron transfer inhibitors, such as phosphides, cyanides, phosphines; neuronal inhibitors, such as bifenazate; aconite Acidase inhibitors, such as fluoroacetamide; synergists, such as piperonyl ether, DEF ((BuS)2P(CO)SBu); Sri Lankan Ryanodine receptor modulators, such as flubendiamide Compounds of unknown function, such as benzoximate, chinomethionat, dicofol, pyridalyl; promiscuous non-specific inhibitors such as borax, barium tartrate Potassium. Suitable insect repellents are preferably selected from the group consisting of N,N-diethyl-m-toluamide, 126151.doc -23-200836619 (DEET), N,N-diethyl phenyl acetamide (DEPA), 1 stomach ( 3-cyclohexyl-based benzylamine-2-methylpyrazine, (2-pyridylcyclohexyl)acetic acid, 2-ethyl-1,3-hexanediol, ketidone, A Neomycin (MNDA), a pyrethroid not used for control of insects, such as {(+/-)-3-allyl-2-methyl-4-oxocycloindole-2-( +)-Diluted-(+)-anti-chrysanthemic acid (Esbiothrin), an insect repellent derived from plant extracts or the same as plant extracts, such as lemon olein, τ " phenol, ( +)-Eucamalol (l), ( + 1-epi-erythritol or from Eucalyptus maculata, Vitex rotimdifolia, Cymbopogan martinii, lemon scent Crude plant extract of plants such as Cymbop0gan citratus (lemon grass), Cymbopogan nartdus (cittonella), IR3535 (ethyl butyl ethionyl propionate), hydroxy Piperyl ester (2-(2-hydroxyethyl)·1-methylpropyl ester of 1-piperidinecarboxylic acid). The snail system is, for example, niclosamide. Suitable fungicides are, for example, oximes, such as Bitertanol, Bromoconazole, Cyproconazole, and Fenconazole. Difenoconazole, Dinitroconazole, Epoxiconazole, Fenbuconazole, Fluquinconazole, Flusilazole, Flutriafol ), Hexaconazole, Imazalil, Ipconazole, Metconazole, Myclobutanil, Penconazole, Propiconazole, Prochloraz, Prothioconazole, Simeconazole, Decker 126151.doc -24-200836619 (Tebuconazole), Tetraconazol, Triadimefon, III Triadimenol, Triflumizol, Tritecon. Sit (Triticonazol);
史卓比尿(Strobilurine)類,例如嗤史卓賓(Azoxystrobin)、 二莫西史卓賓(Dimoxystrobin)、氟咢史卓賓(Fluoxastrobin)、 克收欣(Kresoxim-methyl)、麥脫明諾史卓賓(Metominostrobin)、 歐沙史卓賓(Orysastrobin)、比可西史卓賓(Picoxystrobin)、 派拉克史卓賓(Pyraclostrobin)或三氟敏(Trifloxystrobin); 醯基丙胺酸類,例如本達樂(Benalaxyl)、滅達樂 (Metalaxyl)、高效甲霜靈(Mefenoxam)、曱吱醢胺 (Ofurace)、歐殺斯(Oxadixyl); 胺衍生物類,例如阿迪莫夫(Aldimorph)、多寧 (Dodine)、嗎菌靈(Dodemorph)、芬普福(Fenpropimorph)、 芬普比定(Fenpropidin)、雙脈辛胺(Guazatine)、亞胺歐它 丁(Iminoctadine)、螺 σ惡胺(Spiroxamin)、三得芬(Tridemorph); 苯胺基鳴唆類,例如比利美沙尼(Pyrimethanil)、米潘尼 比林(Mepanipyrim)或西波定(Cyprodinyl); 二甲酿亞胺類,例如依普同(Iprodion)、麥克σ坐林 (Myclozolin)、撲滅寧(Procymidon)、免克寧(Vinclozolin); 肉桂醢胺類及衍生物,例如二曱馬夫(Dimethomorph)、 氟米脫弗(Flumetover)或氟馬夫(Flumorph); 抗生素類,例如環己醯亞胺、灰黃黴素(Griseofulvin)、 春雷黴素(Kasugamycin)、納他黴素(Natamycin)、保粒黴 素(Polyoxin)或鏈黴素(Streptomycin); 126151. doc -25- 200836619 二硫代胺基甲酸酯類,例如富爾邦(Ferbam)、納邦 (Nabam)、锰乃浦(Maneb)、锰粉克(Mancozeb)、美坦 (Metam)、免得爛(Metiram)、曱基鋅乃浦(Propineb)、福代 鋅(Polycarbamat)、得恩地(Thiram)、益穗(Ziram)、鋅乃浦 (Zineb); 雜環化合物,例如敵菌靈(Anilazin)、免賴得(Benomyl)、 伯斯卡利得(Boscalid)、貝芬替(Carbendazim)、萎鏽靈 (Carboxin)、嘉得信(Oxycarboxin)、賽吐法米(Cyazofamid)、 邁隆(Dazomet)、腈硫酉昆(Dithianon)、凡殺同(Famoxadon)、 芬納米同(Fenamidon)、芬瑞莫(Fenarimol)、麥穗寧 (Fuberidazol)、福多寧(Flutolanil)、福拉比(Furametpyr)、 亞賜圃(Isoprothiolan)、滅普寧(Mepronil)、尼瑞莫(Nuarimol)、 咬苯甲醯胺(Picobenzamid)、撲殺熱(Probenazol)、普奎那 兹(Proquinazid)、比芬諾(Pyrifenox)、百快隆(Pyroquilon)、 快諾芬(Quinoxyfen)、石夕硫芬(Silthiofam)、腐絕(Thiabendazol)、 賽氟滅(Thifluzamid)、甲基多保淨(Thiophanat-methyl)、 他得寧(Tiadinil)、三賽唑(Tricyclazol)、賽福寧(Triforine Μ); 瑣基苯基衍生物,例如百瞒克(Binapacryl)、白粉克 (Dinocap)、大脫蜗(Dinobuton)、硝基献-異丙基; 苯基α比洛類,例如芬比克隆尼(Fenpiclonil)、氟二°惡尼 (Fludioxonil); 無機化合物,例如波爾多液(Bordeaux mixture)、乙酸 銅、氫氧化銅、辛酸銅、氧氯化銅、硫酸銅、硫酸銅(三 驗價)、硫續, 126151.doc •26- 200836619 次績酸衍生物,例如蓋它福(Captafol)、蓋普丹(Captan)、 益發靈(Dichlofluanid)、福爾培(Folpet)、對甲抑菌靈 (Tolylfluanid);Strobilurine, such as Azoxystrobin, Dimoxystrobin, Fluoxastrobin, Kresoxim-methyl, Metominostrobin, Europe Orysastrobin, Picoxystrobin, Pyraclostrobin or Trifloxystrobin; Mercaptoalanines such as Benalaxyl, Metalaxyl, Highly Effective Mefenoxam, Ofurrace, Oxadixyl; Amine derivatives such as Aldimorph, Dodine, Dodemorph, Fenfen (Fenpropimorph), Fenpropidin, Guazatine, Iminoctadine, Spiroxamin, Tridemorph; Anilino-based guanidines, For example, Pyrimethanil, Mepanipyrim or Cyprodinyl; Dimethylimine, such as Iprodion, Myclozolin, and chlorpyrifos (Procymidon), Vinclozolin; Cinnamamines and derivatives, such as Dimethomorph, Flumetover or Flumorph; Antibiotics such as cycloheximide , Griseomycin, Kasugamycin, Natamycin, Polyoxin or Streptomycin; 126151. doc -25- 200836619 Dithioamine Carbamates, such as Ferbam, Nabam, Maneb, Mancozeb, Metam, Metiram, Mercapium Zinc (Propineb), Polycarbamat, Thiram, Ziram, Zineb; Heterocyclic compounds such as Anilazin, Benomyl, Bo Boscalid, Carbendazim, Carboxin, Oxycarboxin, Cyazofamid, Dazomet, Dithianon, Famoxadon, Fenamidon, Fenarimol, Mai Sui Ning (Fuberidazol), Flutolanil, Furametpyr, Isoprothiolan, Mepronil, Nuarimol, Picobenzamid, culling fever Probenazol), Proquinazid, Pyriferoox, Pyroquilon, Quinoxyfen, Silthiofam, Thiabendazol, Thifluzamid ), Thiophanat-methyl, Tiadinil, Tricyclazol, Triforine(R); Triacylphenyl derivatives, such as Binapacryl, Dinocap, Dinobuton, Nitro-isopropyl; Phenyl alpha-pyrazine, such as Fenpiclonil, Fludioxonil; Inorganic compounds, for example Bordeaux mixture, copper acetate, copper hydroxide, copper octoate, copper oxychloride, copper sulfate, copper sulfate (three-price), sulphur, 126151.doc •26-200836619 Captafol, Captan, Benefit Dichlofluanid, Folpet, Tolylfluanid;
其他殺真菌劑,例如苯并嗟二嗤(Acibenzolar-S-methyl)、本賽夫利卡(Benthiavalicarb)、卡波帕麥 (Carpropamid)、四氯異苯腈(Chlorothalonil)、環氟菌胺 (Cyflufenamid)、西莫生尼(Cymoxanil)、邁隆、大克美秦 (Diclomezine)、大克賽美(Diclocymet)、益發靈(Diclofluanid)、二 乙芬卡(Diethofencarb)、護粒松(Edifenphos)、衣沙布山 (Ethaboxam)、芬黑沙米(Fenhexamid)、三苯醋錫(Fentin-Acetat)、芬咢尼(Fenoxanil)、富米綜(Ferimzone)、扶吉胺 (Fluazinam)、福賽得(Fosetyl)、福賽得紹(Fosetyl-Aluminium)、填酸、衣普法利卡(Iprovalicarb)、六氣苯 (Hexachlorbenzene)、美查芬隆(Metrafenon)、賓克隆 (Pencycuron)、普潘莫卡(Propamocarb)、熱必斯 (Phthalid)、甲基特科拉夫斯(Toloclofos-Methyl)、奎脫辛 (Quintozene)、唑沙麥(Zoxamid)。 在另一較佳實施例中,該農藥係至少一種N-芳肼衍生 物,較佳為式I之N-芳肼衍生物,Other fungicides, such as Acibenzolar-S-methyl, Benthiavalicarb, Carpropamid, Chlorothalonil, cycloflufenamide ( Cyflufenamid), Cymoxanil, Milon, Diclomezine, Diclocymet, Diclofluanid, Diethofencarb, Edifenphos, Ethaboxam, Fenhexamid, Fentin-Acetat, Fenoxanil, Ferimzone, Fluazinam, Forsyth (Fosetyl), Fosetyl-Aluminium, acid filling, Iprovalicarb, Hexachlorbenzene, Metrafenon, Pencycuron, Ppanmoka (Propamocarb), Phthalid, Toloclofos-Methyl, Quintozene, Zoxamid. In another preferred embodiment, the pesticide is at least one N-aryl quinone derivative, preferably an N-aryl hydrazine derivative of formula I,
其中 A為 C-R2 或 N ; 126151.doc -27- (I) 200836619 B 為 C-R3 或 n ; D 為 C-R4 或 n ; 限制條件係至少A、B或D之一必須不為N ; z為i素、CN、N〇2、Cl_C6_燒基、Ci_C6-齒代烧基、 Ci-Cr烷氡基或心-匕-鹵代烷氧基; η為〇、1或2之整數; Q為 NR5R6 X1 N=( N=<[或Wherein A is C-R2 or N; 126151.doc -27- (I) 200836619 B is C-R3 or n; D is C-R4 or n; the constraint is that at least one of A, B or D must not be N z is i, CN, N〇2, Cl_C6_alkyl, Ci_C6-dentate, Ci-Cr alkanoyl or cardio-halo-haloalkoxy; η is an integer of 〇, 1 or 2; Q For NR5R6 X1 N=( N=<[or
RR
RR
山丫〇 R 其中 R係氣; 視情況經一或多個鹵素取代iCi_Ci〇_烷基;c^c6_環烷 基,C1-C4-烷氧基;CVC4-鹵代烷氧基;(Ci_C4_烷 基)SOx,(C^Cr鹵代烷基)sox;視情況經一至三個下列基 團取代之苯基:鹵素、Cl-C4_烷基、Ci-C4•鹵代烷基、 c4_烷氧基、CVC4-鹵代烷氧基、(Ci-C^烷基)SOx、(CrC^ 齒代烧基)SOx、N〇2或CN基團;視情況經一至三個下列基 團取代之苯氧基:鹵素、Ci-C4-烷基、Ci-CU-鹵代烷基、 CrC4_烷氧基、Cl_C4_鹵代烷氧基、(Ci_c4_烷基)s〇x、(C1_ 代烧基)SOx、N〇2或CN基團;視情況經一或多個下 列基團取代之c3_c12-環烷基:鹵素、Ci-C6_烷基、 自代烧基、Κ4·烧氧基、Ci-C4-鹵代烧氧基、((^、(^-烧 土)S 0 X (C1 - C 4 - _代烧基)S 0 x,視情況經一至三個下列美 126151.doc -28 - 200836619 團取代之苯基:鹵素、Cl-c4·烷基、q-cv鹵代烷基、Cl_ cu-烧氧基、CVC4·鹵代烷氧基、^[〇2或01^基團;視情況經 一至三個下列基團取代之苯氧基:鹵素、Ci_C4-烷基、C” c4-i代烷基、(^匕-烷氧基、Ci_c4_鹵代烷氧基、n〇2* CN基團;或 視情況經一或多個下列基團取代之苯基:鹵素、Ci_C4_ 烷基、CVC4-鹵代烷基、Cl-C4-烷氧基、CVCV鹵代烷氧 基、N02或CN基團;或 cr17r18r19 ; R17及R18各自獨立地係可經1至3個_素原子取代之Ci_ c6-烧基、C3-C6-烯基、c3-c6-炔基或c3-c6-環烷基; R19係氫或CVCV烷基; R1及R7各自獨立地係氫或Ci_c4烷基; R及R各自獨立地係 氫; φ 視情況經一或多個下列基團取代之Cl-c1(r烷基:鹵素、 經基、CVCV 烷氧基、(Cl-Czr 烷基)s〇x、c〇NR8R9、 co2r10、Rii、Rl2 ; 視情況經一至三個下列基團取代之C3_C6_環烷基:_ W 素、Cl_C4_烷基、CVCV鹵代烷基、CVC4·烷氧基、cvcv 鹵代烧氧基、NO^CN基團; 視情況經一或多個下列基團取代之苯基:鹵素、C^Cc 烧基、CVc4_鹵代烷基、Ci_c4_烷氧基、CrCU-鹵代烷氣 基、N〇2或CN基圈; 126151.doc -29· 200836619 視情況經一或多個下列基團取代之吡啶基:_素、c卜 c4-烷基、CVC4-鹵代烷基、Ci-Cr烷氧基、c^CV鹵代烷 氧基、N02或CN基團; 視情況經一或多個下列基團取代之c3_Cl0_烯基:齒素、 經基、CVC4·烧氧基、(CVC4-燒基)s〇x、c〇NR8R9、 C02R10、R11、R12 ; 視情況經一至三個下列基團取代之C3_C6_環烷基··齒 • 素、Cl_C4-烷基、Ci-CV鹵代烷基' 烷氧基、CVCc 鹵代烷氧基、N02或CN基團; 視情況經一或多個下列基團取代之苯基:鹵素、Ci_C4、 烷基、CkCV鹵代烷基、CVC:4·烷氧基、Cl-C4-鹵代烷氧 基、no2*cn基團; 視情況經一或多個下列基團取代之吡啶基:齒素、C广 c4-烷基、Ci-CV鹵代烷基、CrCV烷氧基、Ci-CV鹵代燒 氧基、N02或CN基團; φ 視情況經一或多個下列基團取代之C3-C1(r炔基:鹵素、 羥基、CrCV 烷氧基、(CVC4-烷基)SOx、CONR8R9、 C02R10、R11、R12 ; 視情況經一至三個下列基團取代之C3-C6-環烷基:_ * 素、Ci-C4-烷基、Ci-CV鹵代烷基、CVC4-烷氧基、CVc4· 鹵代烷氧基、N02或CN基團; 視情況經一或多個下列基團取代之苯基:鹵素、c^cv 烷基、CrC4-鹵代烷基、C^CV烷氧基、(VC4·鹵代烷氣 基、N02或CN基團; 126151.doc -30- 200836619 視情況經一或多個下列基團取代之吼咬基:齒素、c丨_ C4-烷基、CVC4-鹵代烷基、Ci-CV烷氧基、CVC4-鹵代烷 氧基、no2*cn基團; 視情況經一或多個下列基團取代之C3-C! 2-環烧基:鹵 素、羥基、CVC4-烷氧基、(CVCV烷基)s〇x、CONR8R9、 C02R10、R11、R12 ; 視情況經一至三個下列基團取代之C3-C6_環烷基:鹵 素、CkCV烷基、CVC4_鹵代烷基、CVC4-烷氧基、Ci-CV 鹵代烷氧基、N02或CN基團; 視情況經一或多個下列基團取代之苯基:函素、Ci-C4_ 烷基、c^cv _代烷基、CVCV烷氧基、Cl_c4_鹵代烷氧 基、:^〇2或〇>^基團; 視情況經一或多個下列基團取代之吡啶基:鹵素、 C4-烷基、(VCV鹵代烧基、Cl_c4-烧氧基、Ci-C4-鹵代烷 氧基、N〇24CN基團; R5及R6可共同形成以下結構所表示之環: 严)% 、_/r R、R及R各自獨立地係氫、鹵素、CN、N〇2、(Ci_C4_ 烧基)sox、(cvc4·鹵代烧基)SGx、Ci_C6n Ci_C6_ 齒 代烷基、CrC6·烷氧基或Ci_C6_自代烷氧基; R8、R9及R1G各自獨立地係氫或Ci_C4-烷基; 126151.doc -31 - 200836619 /(CH2)pN CH P x X(CH2)/「 R11 係 NR13R14、 N \Hawthorn R wherein R is a gas; optionally substituted by one or more halogens iCi_Ci〇_alkyl; c^c6_cycloalkyl, C1-C4-alkoxy; CVC4-haloalkoxy; (Ci_C4_alkane) Base) SOx, (C^Cr haloalkyl) sox; phenyl substituted by one to three of the following groups as appropriate: halogen, Cl-C4_alkyl, Ci-C4•haloalkyl, c4-alkoxy, CVC4 a haloalkoxy group, a (Ci-C^alkyl)SOx, a (CrC^ dentate) SOx, N〇2 or CN group; a phenoxy group optionally substituted with one to three of the following groups: halogen, Ci-C4-alkyl, Ci-CU-haloalkyl, CrC4-alkoxy, Cl_C4_haloalkoxy, (Ci_c4_alkyl)s〇x, (C1_alkylene)SOx, N〇2 or CN a c3_c12-cycloalkyl group substituted by one or more of the following groups: halogen, Ci-C6-alkyl, self-alkylating group, hydrazine 4 alkoxy group, Ci-C4-halo alkoxy group, ((^, (^-calcined) S 0 X (C1 - C 4 - _ 代 alkyl) S 0 x, phenyl substituted by one to three of the following 126151.doc -28 - 200836619 group: halogen , Cl-c4·alkyl, q-cv haloalkyl, Cl_ cu-alkoxy, CVC 4 ·haloalkoxy, ^[ a 2 or 01^ group; a phenoxy group substituted by one to three of the following groups: halogen, Ci_C4-alkyl, C"c4-i-alkyl, (^-alkoxy, Ci_c4_haloalkoxy) a phenyl group, or a phenyl group substituted by one or more of the following groups: halogen, Ci_C4_alkyl, CVC4-haloalkyl, Cl-C4-alkoxy, CVCV haloalkoxy, N02 or CN group; or cr17r18r19; R17 and R18 are each independently Ci_c6-alkyl, C3-C6-alkenyl, c3-c6-alkynyl or c3-c6 substituted by 1 to 3 _ atoms -cycloalkyl; R19 is hydrogen or CVCV alkyl; R1 and R7 are each independently hydrogen or Ci_c4 alkyl; R and R are each independently hydrogen; φ, optionally substituted by one or more of the following groups: C1 (r alkyl: halogen, thiol, CVCV alkoxy, (Cl-Czr alkyl)s〇x, c〇NR8R9, co2r10, Rii, Rl2; C3_C6_ substituted by one to three of the following groups, as appropriate Cycloalkyl: _W, Cl_C4_alkyl, CVCV haloalkyl, CVC4.alkoxy, cvcv halooxyl, NO^CN group; phenyl substituted by one or more of the following groups, as appropriate : halogen, C^Cc alkyl, CVc4_halogen Alkyl, Ci_c4_alkoxy, CrCU-haloalkane, N〇2 or CN based ring; 126151.doc -29· 200836619 Pyridyl group substituted by one or more of the following groups, as appropriate: _, c a c4-alkyl, CVC4-haloalkyl, Ci-Cr alkoxy, c^CV haloalkoxy, N02 or CN group; optionally c3_Cl0-alkenyl substituted by one or more of the following groups: dentate, Passage group, CVC4·alkoxy group, (CVC4-alkyl)s〇x, c〇NR8R9, C02R10, R11, R12; C3_C6_cycloalkyl············ , Cl_C4-alkyl, Ci-CV haloalkyl 'alkoxy, CVCc haloalkoxy, N02 or CN group; phenyl substituted by one or more of the following groups, optionally: halogen, Ci_C4, alkyl, CkCV Haloalkyl, CVC: 4·alkoxy, Cl-C4-haloalkoxy, no2*cn group; pyridyl group optionally substituted by one or more of the following groups: dentate, C-c-c4-alkyl, Ci-CV haloalkyl, CrCV alkoxy, Ci-CV halo alkoxy, N02 or CN group; φ C3-C1 substituted by one or more of the following groups (r alkynyl: halogen, hydroxy ,CrCV alkoxy , (CVC4-alkyl)SOx, CONR8R9, C02R10, R11, R12; C3-C6-cycloalkyl substituted by one to three of the following groups: _*, Ci-C4-alkyl, Ci-CV Haloalkyl, CVC4-alkoxy, CVc4. haloalkoxy, N02 or CN groups; phenyl substituted by one or more of the following groups, optionally: halogen, c^cv alkyl, CrC4-haloalkyl, C ^CV alkoxy, (VC4.haloalkethane, N02 or CN group; 126151.doc -30- 200836619) Bite base substituted by one or more of the following groups: dentate, c丨_C4- Alkyl, CVC4-haloalkyl, Ci-CV alkoxy, CVC4-haloalkoxy, no2*cn group; C3-C! 2-cycloalkyl:halogen optionally substituted with one or more of the following groups , hydroxy, CVC4-alkoxy, (CVCV alkyl)s〇x, CONR8R9, C02R10, R11, R12; C3-C6_cycloalkyl substituted by one to three of the following groups: halogen, CkCV alkyl , CVC4_haloalkyl, CVC4-alkoxy, Ci-CV haloalkoxy, N02 or CN group; phenyl substituted by one or more of the following groups, optionally: Cis, Ci-C4_alkyl, c ^cv _ alkyl, CVCV alkoxy , Cl_c4_haloalkoxy, :^〇2 or 〇>^ group; pyridyl group optionally substituted by one or more of the following groups: halogen, C4-alkyl, (VCV halogenated alkyl, Cl_c4- Alkoxy group, Ci-C4-haloalkoxy group, N〇24CN group; R5 and R6 together form a ring represented by the following structure: ))%, _/r R, R and R are each independently hydrogen and halogen , CN, N〇2, (Ci_C4_alkyl) sox, (cvc4·haloalkyl)SGx, Ci_C6n Ci_C6_dentate alkyl, CrC6·alkoxy or Ci_C6_self alkoxy; R8, R9 and R1G Each independently hydrogen or Ci_C4-alkyl; 126151.doc -31 - 200836619 /(CH2)pN CH P x X(CH2)/" R11 NR13R14, N \
係 2 1 RDepartment 2 1 R
5 NI1R5 NI1R
R 、R 、R15 及 R16 各白 §镯立地係氫或Ci-CV烷其· X係 Ο、S 或 NR15 ; 丞, X1係氯、溴或氟; r為0或1之整數; P及m各自獨立地係〇 、 、2或3之整數,前提條件係僅 P、m或r之一可為〇且進一 步刖k條件係p+m+r之和必須為 4、5 或 6 ; 、一 X為〇、1或2之整數;或 其對映異構體或鹽。 在一較佳實施例中,式I中之(^係 N=( nr5r6R, R, R15 and R16 are each white hydrogen or Ci-CV alkane X system S, S or NR15; 丞, X1 is chlorine, bromine or fluorine; r is an integer of 0 or 1; P and m Each of them is independently an integer of 〇, 2, or 3, provided that only one of P, m, or r can be 〇 and further 刖k condition is the sum of p+m+r must be 4, 5, or 6; X is an integer of 〇, 1 or 2; or an enantiomer or salt thereof. In a preferred embodiment, (^ N = ( nr5r6)
R 更佳地, 少一種N-芳肼衍生物係式ia化合物R. More preferably, one less N-aryl hydrazine derivative ia compound
(la) 其中 r4係氯或三氟曱基; 126151.doc -32- 200836619 Z1及Z2各自獨立地係氣或漠; R6係可經1至3個鹵素原子敢 7于取代iCrCV烷基、c3-c6-烯 基、C3-C6-炔基或 C3_C6-環、p I 斗' /一 长烷基或經Ci-c4-烷氧基取代之 C2-C4·烧基;(la) wherein r4 is a chloro or trifluoromethyl group; 126151.doc -32- 200836619 Z1 and Z2 are each independently gas or desert; R6 is capable of substituting iCrCV alkyl, c3 via 1 to 3 halogen atoms a -c6-alkenyl group, a C3-C6-alkynyl group or a C3_C6-ring, a p-I' or a long alkyl group or a C2-C4.alkyl group substituted with a Ci-c4-alkoxy group;
RlRl8各自獨立地係可經1至3個画素原子取代之Cl_ c6-烧基、c3-c6•烯基、c3_C6_炔基或C3_c6•環烷基; R係氮或C1 - C 6 -烧基;RlRl8 is each independently a Cl_c6-alkyl group, a c3-c6•alkenyl group, a c3_C6-alkynyl group or a C3_c6•cycloalkyl group which may be substituted with 1 to 3 pixel atoms; a R-based nitrogen or a C1-C6-alkyl group ;
或其對映異構體或鹽。 在上文所示之式I及式la之釋義中,該等取代基具有以下 含義: ”鹵素"意指氟、氯、溴及碘。 本文所用術語"烷基”係指具有1至4或6個碳原子之具支 鏈或無支鏈飽和烴基團,尤其係Ci_C6_烷基,例如甲基、 乙基、丙基、1-甲基乙基、丁基、I甲基丙基、2·甲基丙 基、1,1-二甲基乙基、戊基、J•甲基丁基、2_甲基丁基、 3 -甲基丁基、2,2-二甲基丙基、1·乙基丙基、己基、ι,ΐ-二 曱基丙基、1,2-二曱基丙基、甲基戊基、甲基戊基、 3·甲基戊基、4-甲基戊基、ι,ι·二甲基丁基、L2•二甲基丁 基、1,3-二甲基丁基、2,2-二甲基丁基、2,3_二甲基丁基、 3,3-二曱基丁基、1-乙基丁基、2-乙基丁基、ι,ι,2-三甲基 丙基、1,2,2-三甲基丙基、1-乙基-甲基丙基及乙基_2_ 甲基丙基。 π烧氧基”係指於烧基之任一鍵結處藉由氧鍵鍵合之具有 1至4個碳原子之直鏈或具支鏈烷基(甲基、乙基、丙基、!_ 126151.doc -33- 200836619 甲基乙基、丁基、1_甲基丙基、2_甲基丙基、U•二甲基 乙基)。實例包括甲氧基、乙氧基、丙氧基及異丙氧基。 ”環烷基”係指單環3至6員飽和碳原子環,即環丙基、環 丁基、環戊基及環己基。 考慮到式1化合物之預期用途,尤佳者係該等取代基之 以下含義,在每一情形下彼等皆係獨立或組合使用: _ 較佳者係其中R4為三氟甲基之式I化合物。 _ 其他較佳者係其中ζϋ者均為氯之式⑽合物。 而且車又佳者係其中R6為Cl_C6_燒基(尤其為乙基)之式^ 化合物。 其他較佳者係其中R%RU二者均為甲基之式以匕合物。 而且,較佳者係其中Rl7及R18形成未經取代或經丨至3個 δ素原子(尤其係氯及〉臭)取代之環丙基環之式^化合物。 •而且尤仏者係其中R17及R18形成經2個鹵素原子取代之 環丙基環之式I化合物。 _ 而且,尤佳者係其中!^7及R18形成經2個氯原子取代之環 丙基環之式I化合物。 尤k者係其中汉17及R18形成2,2-二氯環丙基環之式η • 物。 其他車父佳者係其中Rl9為烧基(尤其為甲基)之式I化 合物。 尤佺者係其中汉17、r18&r19皆為曱基之式I化合物。 I而且,尤佳者係其中!^7、ru&r19形成卜甲基_2,2_二氯 玉衣丙基部分之式I化合物。 126151.doc -34- 200836619 其他較佳者係如下之式I化合物·· R4係三氟甲基; Z及Z各自獨立地係氯或演; R6係(Vcv烷基; 形成經1至2個_素原子 R及R18係Ci-C6_烧基或可共同 取代之CVC6-環烷基; R19係cvc6-烷基;Or an enantiomer or salt thereof. In the definitions of Formula I and Formula la shown above, the substituents have the following meanings: "Halogen" means fluorine, chlorine, bromine and iodine. The term "alkyl" as used herein means having 1 to a branched or unbranched saturated hydrocarbon group of 4 or 6 carbon atoms, especially a Ci_C6-alkyl group such as methyl, ethyl, propyl, 1-methylethyl, butyl, I methylpropyl , 2·methylpropyl, 1,1-dimethylethyl, pentyl, J•methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropane Base, 1·ethylpropyl, hexyl, iota, fluorenyl-dimercaptopropyl, 1,2-dimercaptopropyl, methylpentyl, methylpentyl, 3·methylpentyl, 4- Methylpentyl, ι,ι·dimethylbutyl, L2•dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethyl Butyl, 3,3-dimercaptobutyl, 1-ethylbutyl, 2-ethylbutyl, ι,ι,2-trimethylpropyl, 1,2,2-trimethylpropyl , 1-ethyl-methylpropyl and ethyl-2-methylpropyl. π alkoxy" means a straight or branched alkyl group having 1 to 4 carbon atoms bonded by an oxygen bond at any bond of the alkyl group (methyl, ethyl, propyl, !_ 126151) .doc -33- 200836619 Methyl ethyl, butyl, 1-methylpropyl, 2-methylpropyl, U•dimethylethyl) Examples include methoxy, ethoxy, propoxy And isopropoxy. "Cycloalkyl" means a ring of 3 to 6 membered saturated carbon atoms of a monocyclic ring, ie, cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. In view of the intended use of the compound of formula 1, especially Preferred are the following meanings of the substituents, and in each case they are used independently or in combination: _ Preferred are compounds of formula I wherein R4 is trifluoromethyl. _ Other preferred are those All of them are chlorine (10) compounds. Moreover, the car is preferably a compound in which R6 is a Cl_C6_alkyl group (especially ethyl). Other preferred ones are those in which R%RU is methyl. Further, a compound of the formula wherein R17 and R18 form a cyclopropyl ring which is unsubstituted or substituted with 3 δ-α atoms (especially chlorine and odor) is formed. • and especially the compound of the formula I in which R17 and R18 form a cyclopropyl ring substituted by two halogen atoms. _ Moreover, it is especially preferred that ^7 and R18 form a cyclopropane substituted by two chlorine atoms. a compound of formula I in the base ring. The group of y is the type η of the 2,2-dichlorocyclopropyl ring of Han 17 and R18. Among other car owners, Rl9 is a burning group (especially methyl). The compound of the formula I is a compound of the formula I in which the Han 17, 17 and r19 are all sulfhydryl groups. I and, in particular, those in which ^^, ru & r19 form a methyl-2,2_dichloro jade a propyl moiety of a compound of formula I. 126151.doc -34- 200836619 Other preferred are compounds of formula I below: R4 is a trifluoromethyl group; Z and Z are each independently a chlorine or a R6 system (Vcv) An alkyl group; a CVC6-cycloalkyl group formed by 1 to 2 atomic atoms R and R18 series Ci-C6-alkyl or co-substituted; R19-based cvc6-alkyl;
或其對映異構體或鹽。 尤佳者係N-乙基·2,2·二甲基丙醯胺_2_(2,6•二氯 二氟對甲苯基)腙及Ν·乙基-2,2-二氯-1ββ甲基環丙烷_甲隨 胺_2_(2,6-二氯·α,α,α-三氟對曱苯基)腙。 此外,考慮到在本發明中之用途,尤佳者係式Ia_i化合物 (N乙基_2,2-一甲基丙醯胺-2-(2,6-二氯- a,a,a-s氟對# 基)·膝): ^Or an enantiomer or salt thereof. Especially preferred is N-ethyl·2,2·dimethylpropionamide_2_(2,6•dichlorodifluoro-p-tolyl) oxime and oxime·ethyl-2,2-dichloro-1ββ- The base cyclopropane_methyl is a 2-(6,6-dichloro-α,α,α-trifluoro-p-phenyl) anthracene. Further, in view of the use in the present invention, a compound of the formula Ia_i (Nethyl 2,2-monomethylpropanamide-2-(2,6-dichloro-a, a, as fluorine) is preferred. Pair #基)· knee): ^
此外,考慮到在本發明中之用途,尤佳者係式la-2化合物 (N-乙基·2,2_二氯甲基環-丙烷甲醯胺_2·(2,6•二氯_α,α,‘ 三氟對甲苯基)腙)·· I26151.doc -35、 200836619 (la-H) 考慮到其用途,尤佳者係編輯於下表中之Ia-A化合物。 另外,表中所提及適合用作取代基之基團自身(獨立於該 等基團於其中被提及之組合)係所論述取代基之尤佳實施Further, in view of the use in the present invention, a compound of the formula la-2 (N-ethyl·2,2-dichloromethylcyclo-propanecarbamamine-2·(2,6•dichloro) is preferred. _α,α,'trifluoro-p-tolyl)腙·· I26151.doc -35, 200836619 (la-H) For the purposes of its use, it is preferred to edit the Ia-A compound in the table below. In addition, the groups mentioned in the table which are suitable as substituents themselves (independent of the combination in which the groups are mentioned) are particularly preferred for the substituents discussed.
例0 考慮到其用途,尤佳者亦為下表化合物之氫氯酸、馬來 酸、二馬來酸、富馬酸、二富馬酸、甲烷次磺酸、甲烷磺 酸及號ίέ酸加合物。Example 0 Considering its use, it is also preferred that the following compounds are hydrochloric acid, maleic acid, dimaleic acid, fumaric acid, difumaric acid, methane sulfenic acid, methanesulfonic acid and citric acid. Adduct.
表ATable A
編號 R6 R17 R18 R19 Z1 Z2 A-1 ch3 2,2-二氯環丙基 H Cl Cl A-2 ch3 2,2-二溴環丙基 H Cl Cl A-3 ch3 ch3 ch3 ch3 Cl Cl A-4 ch3 CH2CH3 ch3 ch3 Cl Cl A-5 ch3 2,2-二氯環丙基 ch3 Cl Cl A-6 ch3 2,2-二溴環丙基 ch3 Cl Cl A-7 ch3 2,2·二氯環丙基 H Br Br A-8 ch3 2,2·二溴環丙基 H Br Br A-9 ch3 ch3 ch3 ch3 Br Br 126151.doc -36- 200836619No. R6 R17 R18 R19 Z1 Z2 A-1 ch3 2,2-Dichlorocyclopropyl H Cl Cl A-2 ch3 2,2-Dibromocyclopropyl H Cl Cl A-3 ch3 ch3 ch3 ch3 Cl Cl A- 4 ch3 CH2CH3 ch3 ch3 Cl Cl A-5 ch3 2,2-dichlorocyclopropyl ch3 Cl Cl A-6 ch3 2,2-dibromocyclopropyl ch3 Cl Cl A-7 ch3 2,2·dichlorocyclohexane Propyl H Br Br A-8 ch3 2,2·dibromocyclopropyl H Br Br A-9 ch3 ch3 ch3 ch3 Br Br 126151.doc -36- 200836619
編號 R6 R17 R18 R19 Z1 Z2 A-10 ch3 CH2CH3 ch3 ch3 Br Br A-11 ch3 2,2-二氣壤丙基 CH3 Br Br A-12 ch3 2,2-二溴環丙基 ch3 Br Br A-13 ch2ch3 2,2-二氣環丙基 H Cl Cl A-14 CH2CH3 2,2-二漠環丙基 H Cl Cl A-15 CH2CH3 ch3 ch3 ch3 Cl Cl A-16 CH2CH3 CH2CH3 ch3 ch3 Cl Cl A-17 CH2CH3 2,2-二氣環丙基 ch3 Cl Cl A-18 CH2CH3 2,2-二溴環丙基 ch3 Cl Cl A-19 CH2CH3 2,2-二氯環丙基 H Br Br A-20 CH2CH3 2,2-二溴環丙基 H Br Br A-21 CH2CH3 ch3 ch3 ch3 Br Br A-22 CH2CH3 CH2CH3 ch3 ch3 Br Br A-23 CH2CH3 2,2-二氯環丙基 ch3 Br Br A-24 CH2CH3 2,2-二溴環丙基 ch3 Br Br A-25 CH2CH2CH3 2>二氯環丙基 H Cl Cl A-26 CH2CH2CH3 2,2-二溴環丙基 H Cl Cl A-27 CH2CH2CH3 ch3 ch3 ch3 Cl Cl A-28 CH2CH2CH3 CH2CH3 ch3 ch3 Cl Cl A-29 CH2CH2CH3 2,2-二氯環丙基 ch3 Cl Cl A-30 CH2CH2CH3 2,2-二溴環丙基 ch3 Cl Cl A-31 CH2CH2CH3 2,2-二氯壤丙基 H Br Br A-32 CH2CH2CH3 2,2-二漠環丙基 H Br Br A-33 CH2CH2CH3 ch3 ch3 ch3 Br Br 本發明農藥組合物之較佳殺蟲劑及/或驅蟲劑可為一種 或混合物。一實施例係具有不同分子大小及/或不同物理 化學特性之農藥的混合物。較佳之農藥混合物係具有相似 126151.doc -37- 200836619 =遷移特性之殺蟲劑及/或驅蟲劑的混合物。此殺蟲劑 及/或驅蟲劑之群可包括諸如亞減寧、赛扶寧、第滅靈、 依芬寧及百滅料之合成擬除蟲“、諸如畢芬寧等之龙 他擬除蟲菊醋及諸如丁基加保扶(灿。suiphane)及克芬那 =之非擬除蟲菊醋。在—較佳實施例中,使用亞滅寧盘 克分那比之混合物。 〃No. R6 R17 R18 R19 Z1 Z2 A-10 ch3 CH2CH3 ch3 ch3 Br Br A-11 ch3 2,2-dioxyl propyl CH3 Br Br A-12 ch3 2,2-dibromocyclopropyl ch3 Br Br A- 13 ch2ch3 2,2-di-cyclopropylpropyl H Cl Cl A-14 CH2CH3 2,2-di-di-cyclopropyl H Cl Cl A-15 CH2CH3 ch3 ch3 ch3 Cl Cl A-16 CH2CH3 CH2CH3 ch3 ch3 Cl Cl A- 17 CH2CH3 2,2-di-cyclohexyl propyl ch3 Cl Cl A-18 CH2CH3 2,2-dibromocyclopropyl ch3 Cl Cl A-19 CH2CH3 2,2-dichlorocyclopropyl H Br Br A-20 CH2CH3 2,2-dibromocyclopropyl H Br Br A-21 CH2CH3 ch3 ch3 ch3 Br Br A-22 CH2CH3 CH2CH3 ch3 ch3 Br Br A-23 CH2CH3 2,2-dichlorocyclopropyl ch3 Br Br A-24 CH2CH3 2,2-Dibromocyclopropyl ch3 Br Br A-25 CH2CH2CH3 2>Dichlorocyclopropyl H Cl Cl A-26 CH2CH2CH3 2,2-Dibromocyclopropyl H Cl Cl A-27 CH2CH2CH3 ch3 ch3 ch3 Cl Cl A-28 CH2CH2CH3 CH2CH3 ch3 ch3 Cl Cl A-29 CH2CH2CH3 2,2-Dichlorocyclopropyl ch3 Cl Cl A-30 CH2CH2CH3 2,2-Dibromocyclopropyl ch3 Cl Cl A-31 CH2CH2CH3 2,2- Diclofenac H Br Br A-32 CH2CH2CH3 2,2-di-di-cyclopropyl H Br Br A-33 CH2CH2CH3 ch3 ch3 ch3 Br Br The pesticide combination of the invention Preferred insecticides and/or insect repellents may be one or a mixture. One embodiment is a mixture of pesticides having different molecular sizes and/or different physicochemical properties. A preferred pesticide mixture is a mixture of insecticides and/or insect repellents having similar 126151.doc -37 - 200836619 = migration characteristics. The group of insecticides and/or insect repellents may include synthetic pseudo-insects such as acetaminophen, sevokonin, dichlorfen, fenfenin, and chlorpyrifos, such as phenanthrene, etc. Chrysanthemum vinegar and non-pyrogenic vinegar such as butyl plus suiphane and kefenal. In a preferred embodiment, a mixture of arsenic and gram is used.
:藥亦可呈以水為主之農藥濃縮物或以溶齊“較佳為有 機#劑)Μ之農藥濃縮物或以水與溶劑(較佳為有機溶劑) 之混合物為主之濃縮物中之—形式包含於農藥組合物中。 以水為主之濃縮物可呈包含適宜分散劑(若需要)之懸浮液 或分散液形式或呈包含乳㈣、溶劑及共耗(若合適)之 礼液形式。可藉由將農藥之固溶體溶於極性有機溶劑(例 如聚乙烯基吡咯啶酮(PVP))中獲得奈米微粒之農藥調配 物。以水為主或以溶劑為主之濃縮物中之農藥的濃度通常 係介於0.5·60%之間,較佳為卜4〇%,更佳為3 2〇%。 以水為主之懸浮液或分散液中之農藥的粒徑通常係介於 50奈米至20微米之間,較佳為5〇奈米至8微米更佳為別 奈米至4微米,最佳為5〇奈米至5〇〇奈米。 聚合黏結劑(組份Β) 聚合黏結劑(組份Β)可為此項技術中熟知之任一聚合黏 結劑。尤佳者係用於浸潰或塗覆紡織品材料或塑膠材料領 域之聚合黏結劑。 較佳黏結劑係(例如)可藉由至少一種選自由以下組成之 群之乙烯系不飽和單體之聚合(較佳為自由基聚合)獲得之 126151.doc -38- 200836619 黏結劑:丙烯酸酯(較佳為丙烯酸之Ci_Ci2_酯或具有交丰 酯官能團之丙烯酸酯)、甲基丙烯酸酯(較佳為甲基丙烯J 之酯或具有交聯酯官能團之甲基丙烯酸酯)、丙^ 酸、甲基丙烯酸、丙烯腈、馬來酸、4來酸酐、馬來酸之 單酯或二酯、苯乙烯、苯乙烯衍生物(例如甲基苯乙烯)、 丁二烯、乙酸乙烯酯、乙烯醇、乙烯、丙烯、烯丙醇、乙 烯基吡咯啶酮、氯乙烯及二氯乙烯。 聚合(較佳為自由基聚合)可(例如)以本體聚合、氣相聚 合、溶劑聚合、乳液聚合或懸浮液聚合形式實施。 藉由上述單體之聚合(較佳為自由基聚合)製備適宜聚合 物之條件及其他必需及適宜的組份已為熟習此項技術 熟知。 藉由上述單體之聚合(較佳為自由基聚合)獲得之適宜聚 合黏結劑係均聚物或共聚物,其較佳選自由以下組成之 群:聚丙烯酸酯;聚甲基丙烯酸酯;聚丙烯腈;聚馬來酸 酐;聚馬來酸;聚馬來酸酯及聚馬來酸醯胺;聚苯乙烯,· 聚(甲基)笨乙烯,聚丁二烯;聚乙酸乙烯酯;聚乙烯醇以 藉由上述單體之群之至少兩種不同的乙烯系不飽和單體 之聚口所獲得之共聚物及該等均聚物及/或共聚物之摻合 物,例如聚(苯乙烯-丙烯酸酯)、聚(苯乙烯_丁二烯)、乙 烯丙稀酸酯-共聚物、乙烯_乙酸乙烯酯-共聚物,其可部 分或完全水解。 八他適且之聚合黏結劑係選自聚胺基甲酸酯及/或聚異 氰脲fees曰、包含聚胺基甲酸酯及/或聚異氰脲酸酯之摻合 12615I.doc -39- 200836619 物’較佳為包含聚胺基甲酸酯及/或聚異氰脲酸酯及聚碳 酸酯之摻合物; 礦物蠟、錘蠟、聚矽氧、聚矽氧烷、氟化聚丙烯酸酯及 甲基丙烯酸酯、氟聚矽氧及 碳氟樹脂(如在(例如)WO 01/37662及WO 92/16103中所 揭不); 二聚氰胺甲醛縮合樹脂、羥曱基脲衍生物;及 可固化聚酯;或 包S至少一種該等聚合黏結劑之摻合物或製備品。 上述聚合黏結劑為此項技術中所熟知且可購得或可藉由 此項技術中熟知之製備方法製備。 其他適宜之聚合黏結劑係呈包含增稠劑(如羧甲基纖維 素)及(視情況)交聯劑(如三聚氰胺樹脂)之調配物形式之聚 乙酸乙烯酯,·彳固化聚酯;包含反應性聚矽氧(有機聚矽 氧烷)、$乙烯醇、$乙酸乙烯酯或丙烯酸系#聚物之調 配物。 父聯可用熱的方法或藉由…光或藉由雙^固化技術實 施。視情況,觸媒或交聯劑可與聚合黏結劑一起使用。、 較佳之聚合黏結劑係選自由丙稀酸系黏結劑及聚胺基甲 酉文酯及/或聚異氰脲酸酯黏結劑組成之群。 最佳之聚合黏結劑係視情況經氟化之丙稀酸系黏結劑。 尤佳之丙烯酸系㈣劑係如下所述(組份Βι)。 丙烯酸系黏結劑(紐份B1) 最佳者係丙婦酸系黏結劑,其可為均聚物或共聚 126I5I.doc 200836619 中共聚物較佳。 丙烯酸系黏結劑較佳藉由至少一種式π之單體(組份 Β1Α)之自由基聚合(更佳為自由基乳液聚合)獲得,The medicine may also be a water-based pesticide concentrate or a pesticide concentrate which is dissolved in a "preferably organic #" agent or a mixture mainly composed of water and a solvent (preferably an organic solvent). The form is contained in the pesticide composition. The water-based concentrate may be in the form of a suspension or dispersion containing a suitable dispersing agent (if needed) or in the form of a milk (4), a solvent and a co-consumption (if appropriate). Liquid form. A pesticide formulation of nanoparticulates can be obtained by dissolving a solid solution of a pesticide in a polar organic solvent such as polyvinylpyrrolidone (PVP). Water-based or solvent-based concentration. The concentration of the pesticide in the material is usually between 0.5 and 60%, preferably 4%, more preferably 32%. The particle size of the pesticide in the water-based suspension or dispersion is usually The system is between 50 nm and 20 microns, preferably 5 to 800 microns, more preferably from 5 to 5 microns, most preferably from 5 to 5 nanometers. Component Β) The polymeric binder (component Β) can be any of the polymeric binders well known in the art. Especially preferred for impregnation or coating. A polymeric binder in the field of a textile material or a plastic material. Preferably, the binder is obtained, for example, by polymerization (preferably radical polymerization) of at least one ethylenically unsaturated monomer selected from the group consisting of 126151.doc -38- 200836619 Adhesive: acrylate (preferably Ci_Ci2_ ester of acrylic acid or acrylate with cross-ester functional group), methacrylate (preferably ester of methacrylic J or cross-linking) Ester functional group methacrylate), propyl acid, methacrylic acid, acrylonitrile, maleic acid, 4 to anhydride, maleic acid monoester or diester, styrene, styrene derivative (eg methylbenzene) Ethylene), butadiene, vinyl acetate, vinyl alcohol, ethylene, propylene, allyl alcohol, vinyl pyrrolidone, vinyl chloride and dichloroethylene. Polymerization (preferably radical polymerization) can be, for example, on the body In the form of polymerization, gas phase polymerization, solvent polymerization, emulsion polymerization or suspension polymerization. Conditions for preparing a suitable polymer by polymerization of the above monomers (preferably, radical polymerization) and other necessary and suitable components It is well known in the art. Suitable polymeric binders are homopolymers or copolymers obtained by polymerization of the above monomers, preferably free radical polymerization, preferably selected from the group consisting of polyacrylates. Polymethacrylate; polyacrylonitrile; polymaleic anhydride; polymaleic acid; polymaleate and polymaleic acid decylamine; polystyrene, poly(methyl) stupid ethylene, polybutylene Polyvinyl acetate; polyvinyl alcohol as a copolymer obtained by the agglomeration of at least two different ethylenically unsaturated monomers of the above group of monomers and the homopolymers and/or copolymers thereof Blends such as poly(styrene-acrylate), poly(styrene-butadiene), ethylene acrylate-copolymer, ethylene-vinyl acetate-copolymer, which may be partially or completely hydrolyzed. The suitable polymeric binder is selected from the group consisting of polyurethanes and/or polyisocyanurate claims, blends comprising polyurethanes and/or polyisocyanurates 12615I.doc-39 - 200836619 The article 'preferably comprises a blend of polyurethane and/or polyisocyanurate and polycarbonate Mineral waxes, hammer waxes, polyfluorene oxides, polyoxyalkylenes, fluorinated polyacrylates and methacrylates, fluoropolyoxyl and fluorocarbon resins (as in, for example, WO 01/37662 and WO 92/) A melamine formaldehyde condensation resin, a hydroxymethyl urea derivative; and a curable polyester; or a blend or preparation of at least one of the polymeric binders. The above polymeric binders are well known in the art and are commercially available or can be prepared by methods well known in the art. Other suitable polymeric binders are polyvinyl acetate in the form of a formulation comprising a thickening agent (such as carboxymethylcellulose) and (as appropriate) a crosslinking agent (such as a melamine resin), including a cured polyester; A formulation of reactive polyoxo (organopolyoxyalkylene), vinyl alcohol, vinyl acetate or acrylic #polymer. The parent can be implemented by a thermal method or by light or by a double curing technique. Catalysts or crosslinkers can be used with polymeric binders, as appropriate. Preferably, the polymeric binder is selected from the group consisting of acrylic binders and polyamidomethacrylate and/or polyisocyanurate binders. The most preferred polymeric binder is a fluorinated acrylic acid binder, as appropriate. The preferred acrylic (four) agent is as follows (component Βι). Acrylic binder (News B1) The most preferred is a propylene glycol binder, which may be a homopolymer or a copolymer of 126I5I.doc 200836619. The acrylic binder is preferably obtained by radical polymerization (more preferably free radical emulsion polymerization) of at least one monomer of the formula π (component Β1Α).
其中 R20、R21及R22獨立地選自可視情況經氟取代且可為直鏈 或具支鍵之C〗-至Ci〇 -烧基,例如甲基、乙基、正丙基、異 丙基、正丁基、異丁基、第二丁基、第三丁基、正戊基、 異戊基(i-pentyl)、第二戊基、新戊基、i,2-二甲基丙基、 異戊基(i-amyl)、正己基、異己基、第二己基、正庚基、 正辛基、2-乙基己基、正壬基、正癸基,較佳為Cf至 烧基’例如甲基、乙基、正丙基、異丙基、正丁基、異丁 基、第二丁基、第三丁基;經取代或未經取代之芳基,較 佳為經取代或未經取代之C6-至C 1 芳基,更佳為經取代或 未經取代之c6-芳基,例如苯基或甲苯基; R20及R21又可為Η。 較佳地,R20為Η或甲基。R21較佳為Η ; R22較佳為甲 基、乙基、正丁基或2-乙基己基。 更佳地,R20為Η或曱基;R21為Η且R22為曱基、乙基、 正丁基或2·乙基己基。 最佳地,式II之單體(組份ΒΑ)係選自由丙烯酸2-乙基己 酯、丙烯酸正丁酯、丙烯酸甲酯、甲基丙烯酸甲酯及丙烯 126151.doc -41- 200836619 酸乙si組成之群。最佳地,I用藉由至少兩種不同的式n 之丙烯酸系單體聚合獲得之共聚物。 最佳地,丙烯酸系黏結劑用作可藉由以下之乳液聚合獲 得之組份B :Wherein R20, R21 and R22 are independently selected from C- to Ci-alkyl groups which may be substituted by fluorine and may be linear or branched, such as methyl, ethyl, n-propyl, isopropyl, n-Butyl, isobutyl, t-butyl, tert-butyl, n-pentyl, i-pentyl, second amyl, neopentyl, i,2-dimethylpropyl, Isoamyl, n-hexyl, isohexyl, second hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-decyl, n-decyl, preferably Cf to alkyl' Methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, t-butyl; substituted or unsubstituted aryl, preferably substituted or unsubstituted Substituted C6- to C1 aryl, more preferably substituted or unsubstituted c6-aryl, such as phenyl or tolyl; R20 and R21 are in turn hydrazine. Preferably, R20 is deuterium or methyl. R21 is preferably hydrazine; R22 is preferably methyl, ethyl, n-butyl or 2-ethylhexyl. More preferably, R20 is fluorenyl or fluorenyl; R21 is hydrazine and R22 is fluorenyl, ethyl, n-butyl or 2-ethylhexyl. Most preferably, the monomer of the formula II (component oxime) is selected from the group consisting of 2-ethylhexyl acrylate, n-butyl acrylate, methyl acrylate, methyl methacrylate and propylene 126151.doc -41-200836619 acid B The group consisting of si. Most preferably, I uses a copolymer obtained by polymerizing at least two different acrylic monomers of the formula n. Most preferably, the acrylic binder is used as component B which can be obtained by emulsion polymerization as follows:
bla)至少一種式11之單體作為組份B1ABla) at least one monomer of formula 11 as component B1A
其中 R20、R21及R22獨立地選自可為直鏈或具支鏈之Ci_至C, 焼基,例如甲基、乙基、正丙基、異丙基、正丁基、異丁 基 '第二丁基、第三丁基、正戊基、異戊基(―邮)、第 二戊基、新戊基、1,2-二甲基丙基、異戊基(i_amyl)、正己 基、異己基、第二己基、正庚基、正辛基、2-乙基己基、 正壬基、正癸基,較佳為Ci_至C4_烷基,例如甲基、乙 基、正丙基、異丙基、正丁基、異丁基、第二丁基、第三 丁基;經取代或未經取代之芳基,較佳為經取代或未經取 代之〇6-至(:1()-芳基,更佳為經取代或未經取代之〔π芳 基,例如苯基或甲苯基; R2G及R2i又可為Η。 較佳地,R20為Η或甲基。R2!較佳為Η ; R22較佳為甲 基、乙基、正丁基或2-乙基己基。 更佳地,R20為Η或甲基;為Ha R22為甲基、乙基、 正丁基或2·乙基己基。 126151.doc -42- 200836619 bib)至少一種式ΙΠ之單體作為組份BibWherein R20, R21 and R22 are independently selected from Ci_ to C which may be straight or branched, and a fluorenyl group such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl Second butyl, tert-butyl, n-pentyl, isopentyl (P-mail), second pentyl, neopentyl, 1,2-dimethylpropyl, isoamyl (i_amyl), n-hexyl , isohexyl, second hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-decyl, n-decyl, preferably Ci_ to C4-alkyl, such as methyl, ethyl, n-propyl Base, isopropyl, n-butyl, isobutyl, t-butyl, t-butyl; substituted or unsubstituted aryl, preferably substituted or unsubstituted 〇6- to (: 1()-aryl, more preferably substituted or unsubstituted [π aryl, such as phenyl or tolyl; R2G and R2i may be oxime. Preferably, R20 is hydrazine or methyl. R2! Preferably, R22 is preferably methyl, ethyl, n-butyl or 2-ethylhexyl. More preferably, R20 is deuterium or methyl; HaR22 is methyl, ethyl, n-butyl or 2. Ethylhexyl. 126151.doc -42- 200836619 bib) At least one monomer of the formula is used as a group Bib
(III) 其中 R 、R24、R25及R26獨立地選自由以下組成之群·· H ;可 為直鏈或具支鏈之Cl•至Cl〇_烷基,例如甲基、乙基、正丙 基、異丙基、正丁基、異丁基、第二丁基、第三丁基、正 戊基、異戊基(i-pentyl)、第二戊基、新戊基、丨,2-二甲基 丙基、異戊基(i-amyl)、正己基、異己基、第二己基、正 庚基正辛基、乙基己基、正壬基及正癸基;較佳地, R 尺、R及尺係選自由以下組成之群:Η;可為直鏈 或具支鏈之Ci-至C4-烷基,例如甲基、乙基、正丙基、異 丙基、正丁基、異丁基、第二丁基及第三丁基;經取代或 未經取代之芳基,較佳為經取代或未經取代之c6-sc1()-芳 基’更佳為經取代或未經取代之C6·芳基,例如苯基或甲 苯基;(III) wherein R, R24, R25 and R26 are independently selected from the group consisting of: H; which may be a linear or branched Cl• to Cl〇-alkyl group such as methyl, ethyl or n-propyl Base, isopropyl, n-butyl, isobutyl, t-butyl, tert-butyl, n-pentyl, i-pentyl, second pentyl, neopentyl, anthracene, 2- Dimethylpropyl, i-amyl, n-hexyl, isohexyl, second hexyl, n-heptyl n-octyl, ethylhexyl, n-decyl and n-decyl; preferably, R , R and the ruler are selected from the group consisting of: hydrazine; may be a straight or branched Ci- to C4-alkyl group, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, Isobutyl, t-butyl and t-butyl; substituted or unsubstituted aryl, preferably substituted or unsubstituted c6-sc1()-aryl' is more preferably substituted or not Substituted C6.aryl, such as phenyl or tolyl;
更佳地,R23為Η或甲基;R24、R25及R26較佳彼此獨立地 為Η ;最佳地,R23為Η或甲基且R24、1^5及1126為]^1 ; blc)視情況至少一種式IV之單體作為組份B1C 126151.doc -43- 200836619More preferably, R23 is hydrazine or methyl; R24, R25 and R26 are preferably each independently Η; optimally, R23 is hydrazine or methyl and R24, 1^5 and 1126 are ]^1; blc) In the case of at least one monomer of the formula IV as component B1C 126151.doc -43- 200836619
(IV) 其中 R及R獨立地選自由以下組成之群:H;可為直鏈或 具支鏈之匕-至c1()-烷基,例如甲基、乙基、正丙基、異丙 基、正丁基、異丁基、第二丁基、第三丁基、正戊基、異 戊基(i-pentyl)、第二戊基、新戊基、丨,2_二甲基丙基、異 戊基(i-amyl)、正己基、異己基、第二己基、正庚基、正 辛基、2-乙基己基、正壬基及正癸基;較佳地,R27及R28 選自由以下組成之群:H;可為直鏈或具支鏈之Ci•至c4· 烷基,例如甲基、乙基、正丙基、異丙基、正丁基、異丁 基、第二丁基及第三丁基;經取代或未經取代之芳基,較 佳為經取代或未經取代之芳基,更佳為經取代或 未經取代之C6-芳基,例如苯基或甲苯基; 最佳地,R27及R28均為Η ; X係選自由以下組成之群:Η、OH、NH2、〇r29〇h、縮 水甘油基、經丙基、 —0 、〇 、 下式之基團(IV) wherein R and R are independently selected from the group consisting of H; may be straight or branched 匕- to c1()-alkyl, such as methyl, ethyl, n-propyl, isopropyl Base, n-butyl, isobutyl, t-butyl, tert-butyl, n-pentyl, i-pentyl, second pentyl, neopentyl, hydrazine, 2 dimethyl propyl Base, i-amyl, n-hexyl, isohexyl, second hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-decyl and n-decyl; preferably, R27 and R28 Selected from the following group: H; may be a linear or branched Ci• to c4· alkyl group, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, Dibutyl and tert-butyl; substituted or unsubstituted aryl, preferably substituted or unsubstituted aryl, more preferably substituted or unsubstituted C6-aryl, such as phenyl Or tolyl; optimally, R27 and R28 are both oxime; X is selected from the group consisting of hydrazine, OH, NH2, 〇r29〇h, glycidyl, propyl, —0, hydrazine, Group
126151.doc 200836619 其中 R30係選自由以下組成之群· 群· 了為具支鏈或直鏈之Cl_至 C10-烷基,例如甲基、乙其 〇基、正丙基、異丙基、正丁基、 異丁基、第二丁基、f三丁基、正戊基、異戊基⑴ pentyl)、第二戊基、新戊基、α二甲基丙基、異戍基(i_ amyl)、正己基、異己基、 昂一己基、正庚基、正辛基、2- 乙基己基、正壬基、正癸其击产、乂土 、土 車乂仏為可為具支鍵或直鍵之 CV至基’例如甲基、乙基、正丙基、異丙基、正丁 基、異丁基、第二丁基及第三丁基;經取代或未經取代之 方基,較佳為經取代或未經取代之。-至C『芳基,更佳為 經取代或未經取代之Cr芳基,例如苯基或甲苯基; R29係選自由以下組成之群:Ci_至CiQ-伸烷基,例如亞 甲基、伸乙基、伸丙基、伸丁基、伸戊基、伸己基、伸庚 基、伸辛基、伸壬基、伸癸基,較佳為至c4-伸烷基, 例如亞甲基、伸乙基、伸丙基、伸丁基;經取代或未經取 代之伸芳基’較佳為經取代或未經取代之(::6-至(:1()_伸芳 基’更佳為經取代或未經取代之C6-伸芳基,例如伸苯 基;X最佳為乙醯乙醯基; bid)可與上述單體共聚之其它單體,其選自: bldl)極性單體,較佳為(甲基)丙烯腈及/或(甲基)丙 烯酸甲酯作為組份B 1D1 ;及/或 bld2)非極性單體,較佳為苯乙烯及/或a-甲基苯乙 烯作為組份B1D2。 該丙烯酸系黏結劑較佳藉由以下之乳液聚合獲得: 126151.doc •45- 200836619 bla) 10-95重量%(較佳為π·%重量%,更佳為5〇屬重量 %)之組份B1A ; bib) 1-5重量%之組份bjb ; blc) 0·5重1%(較佳為丨“重量%,更佳為〇·2_3重量%)之組 份 B1C ; bid)可與上述單體共聚之其它單體,其選自: bldl) 0-30重里%(較佳為〇_25重量%,更佳為^⑽重 量%)之組份B1D1 ;及/或 bld2) 0-40重量%(較佳為〇·3〇重量%,更佳為5_2〇重 量%)之組份B1D2 ; 其中該等組份ΒΙΑ、Β1Β及(視情況)B1C及B1D之總量為 100重量%。 在另一較佳實施例中,該丙烯酸系黏結劑藉由以下之乳 液聚合獲得: 1^1勾1〇-95重量%(較佳為30_95重量%,更佳為5〇_9〇重量 %)之至少一種上述丙烯酸系黏結劑(組份B1A),其包 含·· blal)以丙烯酸系黏結劑計,1〇-9〇重量%(較佳為15_ 85重量%,更佳為30_85重量%)之丙烯酸正丁 酯; b 1 a2)以丙烯酸糸黏結劑計,1 〇 _ 9 〇重量% (較佳為12 _ 85重量%,更佳為15-60重量%)之至少一種非 丙烯酸正丁酯之式II單體; bib)以丙烯酸系黏結劑計,1乃重量%之至少一種式m之 126151.doc -46- 200836619 單體(組份BIB); blc)以丙烯酸系黏結劑計,〇_5重量%(較佳為〇 ι·4重量 /〇,更佳為0.2-3重量。/。)之至少一種式ΐΗ之單體(組份 B1C); bid)可與上述單體共聚之其它單體(組份B1D),其選自: bldl)以丙烯酸系黏結劑計,〇-30重量%(較佳為〇_25 * 重量% ’更佳為5-20重量%)之至少一種極性單 φ 體’較佳為(甲基)丙烯腈及/或(甲基)丙稀酸甲 酯(組份B1D1);及/或 bld2)以丙烯酸系黏結劑計,0-40重量。較佳為〇_3〇 重1%,更佳為5-20重量%)之至少一種非極性 單體(較佳為苯乙烯及/或a-曱基苯乙烯)(組份 B1D2); 其中該等組份ΒΙΑ、B1B及(視情況)Blc及B1D之總量為 1 00重量%。 • ㈣婦酸系黏結劑可進一步包含熟習此項技術者所熟知 之其它添加劑,例如,薄膜形成劑及增塑劑,例如己二酸 . 酉旨、鄰苯二甲酸酯、二乙二醇丁醚、二酯混合物,該二酯 混合物較佳藉由二羧酸與直鏈或具支鏈之醇反應來製備。 . 適宜之二羧酸及醇已為熟習此項技術者所熟知。 包含本發明中提出中請之黏結劑之殺蟲劑組合物係耐侯 性的’同時容許以受控速率連續釋放該殺蟲劑以提供該殺 蟲劑之所需的生物可利用度。不必添加(例如)分散劑,分 散劑之作用係當該組合物施加於織物後且當該織物潤濕時 126151.doc -47. 200836619 =黏結劑賦予該殺蟲劑之疏水性以容許以限制方式釋放 权触劑。因在匕,較#地,本發明 <殺蟲劑組合物除聚合黏 結劑外不包含分散劑。 最佺地,該丙烯酸系黏結劑係藉由以下組份之乳液聚合 獲得: bla) 50-90重量%之至少一種式„之單體(組份bia)126151.doc 200836619 wherein R30 is selected from the group consisting of Cl_ to C10-alkyl having a branched or straight chain, such as methyl, decyl, n-propyl, isopropyl, n-Butyl, isobutyl, t-butyl, f-tributyl, n-pentyl, isopentyl (1) pentyl), second pentyl, neopentyl, alpha dimethyl propyl, isodecyl (i_ Amyl), n-hexyl, isohexyl, hexamethylene, n-heptyl, n-octyl, 2-ethylhexyl, n-decyl, orthoquinone, bauxite, earthworms Or a straight-bonded CV to a base such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl and t-butyl; substituted or unsubstituted peryl Preferably, it is substituted or unsubstituted. - to C "aryl, more preferably substituted or unsubstituted Cr aryl, such as phenyl or tolyl; R29 is selected from the group consisting of Ci_ to CiQ-alkyl, such as methylene , ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, decyl, decyl, preferably to c4-alkyl , ethyl, propyl, butyl; substituted or unsubstituted aryl 'preferably substituted or unsubstituted (:: 6- to (: 1 () _ aryl) More preferably a substituted or unsubstituted C6-exoaryl group, such as a phenylene group; X is preferably an ethyl acetonitrile; bid) another monomer copolymerizable with the above monomers, selected from the group consisting of: bldl) A polar monomer, preferably (meth)acrylonitrile and/or methyl (meth)acrylate as component B 1D1 ; and/or bld 2 ) a non-polar monomer, preferably styrene and/or a-A The styrene is used as the component B1D2. The acrylic adhesive is preferably obtained by the following emulsion polymerization: 126151.doc • 45- 200836619 bla) Group of 10-95% by weight (preferably π·% by weight, more preferably 5 〇 重量 %) Part B1A; bib) 1-5 wt% component bjb; blc) 0·5 weight 1% (preferably 丨 "% by weight, more preferably 〇 · 2 _ 3 wt%" component B1C; bid) can be The other monomer copolymerized by the above monomer is selected from the group consisting of: bldl) 0-30% by weight (preferably 〇255% by weight, more preferably ^(10)% by weight) of component B1D1; and/or bld2) 0- 40% by weight (preferably 〇·3〇% by weight, more preferably 5-2〇% by weight) of component B1D2; wherein the total amount of these components ΒΙΑ, Β1Β and (as appropriate) B1C and B1D is 100% by weight In another preferred embodiment, the acrylic adhesive is obtained by the following emulsion polymerization: 1^1 hook 1〇-95% by weight (preferably 30-95% by weight, more preferably 5〇_9〇 by weight) %) at least one of the above-mentioned acrylic adhesives (component B1A), which contains ·· blal), based on the acrylic adhesive, 1〇-9〇% by weight (preferably 15_85% by weight, more preferably 30_85 by weight) %) n-butyl acrylate ; b 1 a2) at least one non-acrylic acid n-butyl ester of the formula II in terms of yttrium yttrium binder, 1 〇 _ 9 〇 by weight (preferably 12 _ 85% by weight, more preferably 15 to 60% by weight) Bib) at least one formula m 126151.doc -46-200836619 monomer (component BIB); blc) based on the acrylic binder, 〇_5 wt% based on the acrylic binder (preferably 〇ι·4 wt/〇, more preferably 0.2-3 wt.) of at least one monomer of the formula (component B1C); bid) other monomers copolymerizable with the above monomers ( Component B1D) selected from the group consisting of: bldl) at least one polar mono φ body of 〇-30% by weight (preferably 〇25*% by weight 'more preferably 5-20% by weight) based on the acrylic binder Preferably, (meth)acrylonitrile and/or methyl (meth) acrylate (component B1D1); and/or bld2) is from 0 to 40% by weight based on the acrylic binder. 3 〇 1%, more preferably 5-20% by weight of at least one non-polar monomer (preferably styrene and / or a-mercapto styrene) (component B1D2); wherein the components ΒΙΑ , B1B and (as appropriate) Blc and B1D The total amount is 100% by weight. • (4) The vodonic acid binder may further comprise other additives well known to those skilled in the art, such as film formers and plasticizers, such as adipic acid. Dicarboxylate, diethylene glycol butyl ether, diester mixture, the diester mixture is preferably prepared by reacting a dicarboxylic acid with a linear or branched alcohol. Suitable dicarboxylic acids and alcohols are well known to those skilled in the art. The insecticidal composition comprising the binder of the present invention is weather resistant' while allowing the pesticide to be continuously released at a controlled rate to provide the bioavailability required for the insecticide. It is not necessary to add, for example, a dispersing agent, which acts when the composition is applied to the fabric and when the fabric is wet. 126151.doc -47. 200836619 = the adhesive imparts hydrophobicity to the insecticide to allow for limitation Way to release the right touch agent. The present invention <Insecticide Composition does not contain a dispersing agent other than the polymeric binder. Most desirably, the acrylic binder is obtained by emulsion polymerization of the following components: bla) 50-90% by weight of at least one monomer of the formula (component bia)
RR
OR22 (II) 其中 R20為Η或甲基;為H&R22為甲基、乙基、正丁基或 2-乙基己基,最佳地,組份B1A為丙烯酸2_乙基己酯、丙 烯酸正丁 S旨、丙烯酸甲酯、甲基丙烯酸甲酯或丙烯酸乙 酯; bib) 1-5重量%之至少一種式m之單體(組份b1b)OR22 (II) wherein R20 is hydrazine or methyl; H&R22 is methyl, ethyl, n-butyl or 2-ethylhexyl, and most preferably, component B1A is 2-ethylhexyl acrylate, acrylic acid N-butyl, methyl acrylate, methyl methacrylate or ethyl acrylate; bib) 1-5 wt% of at least one monomer of the formula m (component b1b)
(HI) 其中R23為Η或甲基·’ R24、R25及R26各自皆為Η; blc) 1-10重量%(較佳為1-7重量%,更佳為2-5重量%)之至 少一種式IV之單體(組份B 1C) 126151.doc -48- 200836619(HI) wherein R 23 is hydrazine or methyl · ' R 24 , R 25 and R 26 are each hydrazine; blc) is at least 1-10% by weight (preferably 1 to 7% by weight, more preferably 2 to 5% by weight) a monomer of formula IV (component B 1C) 126151.doc -48- 200836619
(IV) NH2、QR29〇H、縮水甘 其中R27及R28均為Η且X為H、ΟΉ、 油基或下式之基團 —0(IV) NH2, QR29〇H, condensed sugar, wherein R27 and R28 are both Η and X is H, oxime, oil base or a group of the formula -0
其中m選自由以下組成之群:可為具支鏈或直鏈之Wherein m is selected from the group consisting of: may be branched or linear
Cl -至Ci〇 -烧基’例如曱基、f其 τ ^乙基、正丙基、異丙基、正丁 基、異丁基、第二丁基、第三丁基、正戊基、異戊基⑴ Pentyl)、第二戊基、新戊基、1,2_二甲基丙基、異戊基(i_ ―)、正己基、異己基、第二己基、正庚基、正辛基、2_ 乙基己基、正壬基、正癸基’較佳為可為具支鏈或直鏈之 cec4-烧基,例如甲基、乙基、正丙基、異丙基、正丁 j、異丁基、第二丁基及第三丁基;經取代或未經取代之 方基,較佳為經取代或未經取代之^•至〜芳基,更佳為 經取代或未經取代之CV芳基,例如苯基或甲苯基; R29係選自由以下組成之群:。至〜伸烧基,例如亞 甲基、伸乙基、伸丙基、伸丁基、伸戍基、伸己基、伸庚 土伸辛基#壬基、伸癸基,較佳為Cl·至伸烧基, 4如亞甲纟#乙基、伸丙基、伸丁基;經取代或未經取 代之伸芳基’較佳為經取代或未經取代之C6jCi〇_伸芳 126151.doc •49- 200836619 基,更佳為經取代或未經取代之C6_伸芳基,例如伸苯 基; X最佳為乙醯乙醯基; bid)可與上述單體共聚之其它單體,其選自: bldl) 0-30重量%(較佳為〇_25重量%,更佳為5_2〇重 1 %)之組份B1D1,較佳為(甲基)丙婦腈及/或 (甲基)丙烯酸甲酯;及/或 φ bld2) 〇-4〇重量%(較佳為0-30重量%,更佳為5_2〇重 量%)之組份B1D2,較佳為苯乙烯及/或心甲基 苯乙烯; 其中組份BA、BB及(視情況)BC及BD之總量為1〇〇重量%。 在另一最佳實施例中,作為組份BA之丙烯酸正丁醋的 量為30-90重量%,且其他組份B1B及(視情況)另一式π之 單體(組份ΒΙΑ)、Β 1C及BID係如上述選擇,其中組份 ΒΙΑ、B1B及(視情況)B1C及BID之總量為1〇〇重量〇/〇。 ⑩ 本發明之丙稀酸糸黏結劑較佳藉由上述單體之乳液聚合 來獲得。適宜之製程條件已為熟習此項技術者所熟知且在 (例如)WO-A 2005/064072中予以揭示。 在本發明丙烯酸系黏結劑中,通常可添加高達i 〇重量 ‘ %(較佳為〇·〇5-5重量%)之包含反應性或交聯基團之單或二 烯系不飽和單體。具體而言,該等單體之實例係α,β_烯系 不飽和C3_5_羧酸之醯胺,尤其係丙烯醯胺、甲基丙稀醯胺 及馬來酸二酿胺及其N-經甲基衍生物(例如,經甲基丙 烯醯胺、N-羥甲基甲基丙稀醯胺)、α,β-單烯系不飽和c3 5- 126151.doc •50· 200836619 竣酸之N-烧氧基甲基酿胺(例如,N_甲氧基甲基丙烯醯胺 及N-正丁氧基甲基丙烯醯胺)、乙烯基磺酸、丙烯酸及甲 基丙烯酸與烷二醇(例如乙二醇、M•丁二醇、丨,6_己二醇 及3·氯-1,2_丙二醇)之單酯以及α,β•烯系不飽和單羧酸及二 =酸之烯丙基及甲基烯丙基酷(例如,馬來酸二烯丙醋、 富馬酸二甲基烯丙醋、丙烯酸稀丙g|及甲基丙烯酸烯丙 酉s、鄰苯二甲酸二烯丙酯、對苯二曱酸二烯丙酯)、對-二_ _ 乙烯基苯、亞曱基-雙-丙烯醯胺及乙二醇二烯丙醚。 所獲得之未交聯乳液聚合物之分子量通常為4〇,〇〇〇至 25〇,〇〇0(藉由GPC確定)。分子量通常藉由使用常用量之傳 統鏈終止劑來控制。傳統鏈終止劑係(例如)硫代有機化合 物。 本發明之丙烯酸系黏結劑可以其水性分散液形式獲得且 本發明殺蟲劑組合物中較佳使用水性分散液形式。 聚胺基甲酸酯黏結劑及/或聚異氰脲酸酯黏結劑(組份Μ) • 在另一較佳實施例中,聚合黏結劑係聚胺基甲酸酯及/ ^聚異虱脲酸酯。該等聚胺基甲酸酯及/或聚異氰脲酸酯 可單獨用作聚合黏結劑或與其他聚合黏結劑(尤其上述之 聚合黏結劑)結合使用,例如與上述丙烯酸系黏結劑結合 ^ 使用。 ° 因此’適宜之聚合黏結劑係: 至少一種聚胺基甲酸酯作為組份Β2,其可藉由以下組份反 應獲得: b2a)至少一種二異氰酸酯或聚異氰酸酯(組份Β2Α),較佳 126151.doc -51 · 200836619 t脂族、環脂族、芳脂族及/或芳香族異氰酸_,更 锃為一異鼠酸酯(其可視情況縮二脲化及/或異氰脲酸 化)\最佳為L異氰酸基_3二5_三甲基_5·異氰酸基亞 甲基環己烧(IPDI)及1,6-己二異氰酸酉旨(HMm); )至夕種一元醇、二元醇或多元醇(組份B2B),較佳 為具有2至14個(較佳為4至1〇個)碳原子之脂族、環脂 族及/或芳脂族二元醇,更佳y,卜己二醇或新戊二 醇; b2c)視情況其他組份(組份B2C),魏為己二酸或幾基二 咪唑(CDI);及 b2d)視情況其他添加劑(組份B2D)。 聚胺基甲酸酯較佳藉由以下組份反應獲得·· b2a)以聚胺基甲酸酯計’ 55,重量%(較佳為7㈣重量 〇/。’更佳為75,重量%)之至少一種二異氰酸醋或聚 異氰酸酯(組份B2a),較佳為脂族、環脂族、芳脂族 及/或芳香族異氰酸醋,更佳為可視情況縮二脲化及/ 或異氰脲酸化之二異氰酸酯,更佳為在伸烷基單元 中具有4至丨2個碳原子之伸烷基二異氰酸酯,如丨,^-十二院二異氰酸西旨、2_乙基],4·丁二異氛酸酉旨、I甲 基-1,5-戊二異氰酸醋、Μ.丁二異氰酸醋、離胺酸酯 (lysinester)二異氰酸醋(LDI)、己二異氰酸酯 (HMDI)、環己烧],3-及/或·1>4•二異氮酸醋、Μ·及 2,6-六氫-甲苯二異氰酸酯以及相應異構體混合物、 4,4’-2,2|-及2,4匕二環己基甲烧二異氰酸酯以及相應混 126151.doc -52- 200836619Cl - to Ci 〇 -alkyl group such as fluorenyl, f its τ ^ ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, tert-butyl, n-pentyl, Isoamyl (1) Pentyl), second amyl, neopentyl, 1,2-dimethylpropyl, isopentyl (i_ ―), n-hexyl, isohexyl, second hexyl, n-heptyl, n-octyl The base, 2-ethylhexyl, n-decyl, n-decyl group is preferably a cec4-alkyl group having a branched or straight chain, such as methyl, ethyl, n-propyl, isopropyl, n-butyl , isobutyl, t-butyl and tert-butyl; substituted or unsubstituted radical, preferably substituted or unsubstituted ^ to ~ aryl, more preferably substituted or not Substituted CV aryl, such as phenyl or tolyl; R29 is selected from the group consisting of: To a stretching group, such as methylene, ethyl, propyl, butyl, hydrazine, hexyl, hexylene, hydrazine Stretching base, 4 such as methylene oxime #ethyl, propyl, butyl; substituted or unsubstituted aryl aryl 'preferably substituted or unsubstituted C6jCi 〇 _ _ _ 126151.doc • 49- 200836619, more preferably a substituted or unsubstituted C6_ extended aryl group, such as a phenyl group; X is preferably an acetamidine group; bid) other monomers copolymerizable with the above monomers, It is selected from the group consisting of: bldl) 0-30% by weight (preferably 〇255% by weight, more preferably 5_2 〇1%) of component B1D1, preferably (meth) acrylonitrile and/or (A) Methyl acrylate; and/or φ bld2) 〇-4〇% by weight (preferably 0-30% by weight, more preferably 5_2% by weight) of component B1D2, preferably styrene and/or heart Methylstyrene; wherein the total amount of components BA, BB and, as the case may be, BC and BD is 1% by weight. In another preferred embodiment, the amount of n-butyl acrylate as component BA is 30-90% by weight, and the other components B1B and (as appropriate) another monomer of π (component ΒΙΑ), Β 1C and BID are selected as above, wherein the total amount of components ΒΙΑ, B1B and, as the case may be, B1C and BID is 1 〇〇 weight 〇/〇. The strontium acrylate binder of the present invention is preferably obtained by emulsion polymerization of the above monomers. Suitable process conditions are well known to those skilled in the art and are disclosed, for example, in WO-A 2005/064072. In the acrylic adhesive of the present invention, a mono or diene unsaturated monomer containing a reactive or crosslinking group up to an amount of i 〇 by weight (%, preferably 5% 5% by weight) may be usually added. . In particular, examples of such monomers are the decylamines of α,β-ethylenically unsaturated C3_5-carboxylic acids, especially acrylamide, methacrylamide and maleic acid and its N- By methyl derivatives (for example, methacrylamide, N-methylolmethyl amide), α,β-monoethylenic c3 5- 126151.doc •50· 200836619 N-alkoxymethyl-branched amines (for example, N-methoxymethyl acrylamide and N-n-butoxymethyl acrylamide), vinyl sulfonic acid, acrylic acid and methacrylic acid and alkanediol (eg, ethylene glycol, M•butanediol, hydrazine, 6-hexanediol, and 3·chloro-1,2-propylene glycol) monoesters and α,β• ethylenically unsaturated monocarboxylic acids and di-acids Allyl and methallyl cool (for example, maleic acid dipropylene vinegar, dimethyl methacrylate fumarate, acrylic acid propylene gamma | and methacrylic acid allyl s s, phthalic acid II Allyl ester, diallyl terephthalate), p-di-vinylbenzene, fluorenylene-bis-acrylamide and ethylene glycol diallyl ether. The molecular weight of the uncrosslinked emulsion polymer obtained is usually 4 Å, 〇〇〇 to 25 〇, 〇〇0 (determined by GPC). The molecular weight is usually controlled by using a conventional amount of a conventional chain terminator. Conventional chain terminators are, for example, thioorganic compounds. The acrylic adhesive of the present invention can be obtained in the form of an aqueous dispersion thereof and is preferably used in the form of an aqueous dispersion in the insecticidal composition of the present invention. Polyurethane Adhesive and/or Polyisocyanurate Adhesive (Component Μ) • In another preferred embodiment, the polymeric binder is a polyurethane and/or polyisophthalide Urea ester. The polyurethanes and/or polyisocyanurates may be used alone as polymeric binders or in combination with other polymeric binders (especially polymeric binders described above), for example in combination with the above acrylic binders^ use. ° [A suitable polymeric binder system: at least one polyurethane as component Β2, which can be obtained by the following component reaction: b2a) at least one diisocyanate or polyisocyanate (component Α 2 Α), preferably 126151.doc -51 · 200836619 t aliphatic, cycloaliphatic, araliphatic and / or aromatic isocyanic acid _, more 一 is iso- eric acid ester (which may be diuretized and / or isocyanuramide as the case may be) Acidification) \Optimized as L isocyanate _3 bis 5 - trimethyl _ 5 · isocyanatomethylene cyclohexane (IPDI) and 1,6-hexane diisocyanate (HMm) ; a monohydric alcohol, a diol or a polyol (component B2B), preferably an aliphatic, cycloaliphatic and/or having 2 to 14 (preferably 4 to 1 fluorene) carbon atoms; Aryl aliphatic diol, more preferably y, hexanediol or neopentyl glycol; b2c) other components (component B2C), Wei adipic acid or a few diimidazole (CDI); and b2d ) Other additives as appropriate (component B2D). The polyurethane is preferably obtained by the following component reaction: b2a) by weight of the polyurethane '55, wt% (preferably 7 (four) weight 〇 /. 'more preferably 75, weight %) At least one of diisocyanate or polyisocyanate (component B2a), preferably aliphatic, cycloaliphatic, araliphatic and/or aromatic isocyanuric acid, more preferably diuretized as appropriate Or an isocyanuric acid diisocyanate, more preferably an alkyl diisocyanate having 4 to 2 carbon atoms in the alkylene unit, such as hydrazine, ^-12th diisocyanate, 2 _Ethyl],4·butyl diiso-acidic acid, I methyl-1,5-pentane diisocyanate, Μ.butyl diisocyanate, lysinester diisocyanate Vinegar (LDI), hexamethylene diisocyanate (HMDI), cyclohexane, 3- and / or · 1 > 4 • diisoxamic acid vinegar, hydrazine and 2,6-hexahydro-toluene diisocyanate and corresponding isomerization Mixture, 4,4'-2,2|- and 2,4匕 dicyclohexylmethane diisocyanate and corresponding mixing 126151.doc -52- 200836619
合物、1-異氰酸基-3,3’5-三甲基_5_異氰酸基甲基環己 烧(IPDI)、2,4-及/或 2,6_ 甲苯二異氛酸醋、4,4,_、2,4· 及/或2,2_一苯基甲烷二異氰酸酯(單體態之mdi)、多 苯基多亞甲基聚異氰酸酿(聚合態之Mm)及/或包含至 少兩種上述異氰酸酯之混合物;此外,可使用包含 醋-、脲-、腺基甲酸醋·、碳化二亞胺、脈二晒環-及/ 或胺基甲酸酯基團之二及/或聚異氰酸g旨;最佳為卜 異氰酸基·3,3,5·三甲基I異氰酸基亞甲基環己烧 (IPDI)及1,6_己二異氰酸酯(hmdi); b2b)以聚胺基甲酸酯計,1〇,重量%(較佳為12_85重量 %,更佳為15-65重量%)之至少一種二元醇、三元醇 或多元醇(組份B2B),較佳為具有2至14個(較佳為4至 10個)碳原子之脂族、環脂族及/或芳脂族:元醇,更 佳為多元醇,其係選自由以下組成之群:聚鱗醇(例 如聚四氫呋喃)、聚酯醇、聚硫醚多元醇、含羥基之 聚縮醛及含羥基之脂族聚碳酸酯或至少兩種上述多 元醇之混合物。較佳者係聚酯醇及/或聚醚醇。該等 多經基化合物之羥基數目通常為20至850毫克〖〇11/克 且較仏為25至80 ¾克ICOH/克。此外,使用分子量通 常介於60至<400(較佳為60至300)克/莫耳之二元醇及/ 或三元醇。適宜之二元醇係具有2至14個(較佳為4至 10個)碳原子之脂族、環脂族及/或芳脂族二元醇,例 如乙二醇、1,3-丙二醇、1,10-癸二醇、鄰-、間_、對_ 一 己烧、一乙^一醇、二丙二醇且較佳為14 丁 126151.doc -53- 200836619 二醇、新戊二醇、1,6-己二醇及雙_(2_羥基_乙基)對 苯二酚;三元醇,如1,2,4-、1,3,5_三羥基_環己烷、 甘油及三羥甲基丙烷及基於氧化乙烯及/或丨,2-氧化 丙烯之含羥基之低分子量聚氧化烯烴與上述二元醇 及/或三元醇之混合物; b2c)以聚胺基甲酸酯計,〇_1〇重量%(較佳為〇1_5重量%, 更佳為1-5重量❶/〇)之其它組份(組份B2C),較佳為己 二酸或羰基二咪唑(CDI);及 b2d)以聚胺基甲酸酯計,0_10重量較佳為〇1_5重量%, 更佳為0.5-5重量%)之其它添加劑(組份B2D); 其中組份B2A、B2B、B2C及B2D之總量為1〇〇重量〇/〇。 該等聚胺基甲酸酯係藉由此項技術中所熟知之方法擎 備。此外,在製備聚胺基甲酸酯之製程中可使用熟習此 技術者所熟知之添加劑。 、 組份B亦可為聚異氰脲酸酯或聚異氰脲酸酯與聚胺基甲 酸酯之混合物,較佳為上述聚胺基甲酸酯。 聚異氰脲酸酯係包含下式之基團之聚合物:, 1-isocyanato-3,3'5-trimethyl-5-isocyanatomethylcyclohexene (IPDI), 2,4- and/or 2,6-toluenediiso-acid Vinegar, 4,4,_, 2,4· and/or 2,2-monophenylmethane diisocyanate (mdi in monomeric state), polyphenylpolymethylene polyisocyanate (polymerized Mm) And/or comprising a mixture of at least two of the above-mentioned isocyanates; in addition, vinegar-, urea-, glycolate, carbodiimide, nitrodi- and/or urethane groups may be used. Bis and / or polyisocyanate g; the best is isocyanate · 3,3,5 · trimethyl I isocyanatomethylene cyclohexane (IPDI) and 1,6_ Diisocyanate (hmdi); b2b) at least one diol, triol or 1% by weight, preferably 12-85% by weight, more preferably 15-65% by weight, based on the polyurethane The polyol (component B2B) is preferably an aliphatic, cycloaliphatic and/or araliphatic group having 2 to 14 (preferably 4 to 10) carbon atoms: a polyhydric alcohol, more preferably a polyhydric alcohol. It is selected from the group consisting of polysquaria (for example, polytetrahydrofuran), polyester alcohol, polythioether polyol, and hydroxyl group-containing poly Aldehyde and hydroxyl-containing aliphatic polycarbonates or mixtures of at least two of the above-mentioned polyhydric alcohols. Preferred are polyester alcohols and/or polyether alcohols. The number of hydroxyl groups of the poly-based compounds is usually from 20 to 850 mg [〇 11 / gram and is more than 25 to 80 3⁄4 g ICOH / gram. Further, a glycol and/or a triol having a molecular weight of usually from 60 to < 400 (preferably from 60 to 300) g/mol is used. Suitable diols are aliphatic, cycloaliphatic and/or araliphatic diols having 2 to 14 (preferably 4 to 10) carbon atoms, such as ethylene glycol, 1,3-propanediol, 1,10-decanediol, o-, m-, p-hexyl, monoethylidene, dipropylene glycol and preferably 14 126151.doc -53-200836619 diol, neopentyl glycol, 1, 6-hexanediol and bis-(2-hydroxy-ethyl) hydroquinone; triols such as 1,2,4-, 1,3,5-trihydroxy-cyclohexane, glycerol and trishydroxyl a mixture of methyl propane and a hydroxyl group-containing low molecular weight polyalkylene oxide based on ethylene oxide and/or hydrazine, 2-propylene oxide with the above diol and/or triol; b2c) based on the polyurethane, 〇_1〇% by weight (preferably 〇1_5 wt%, more preferably 1-5 wt❶/〇) of other components (component B2C), preferably adipic acid or carbonyl diimidazole (CDI); And b2d) other additives (component B2D) based on the polyurethane, preferably 0 to 10% by weight, more preferably 0.5 to 5% by weight, based on the polyurethane; wherein the components B2A, B2B, B2C and B2D The total amount is 1 〇〇 weight 〇 / 〇. These polyurethanes are prepared by methods well known in the art. Further, additives which are well known to those skilled in the art can be used in the preparation of the polyurethane. Component B may also be a mixture of polyisocyanurate or polyisocyanurate and a polyurethane, preferably the above-mentioned polyurethane. Polyisocyanurate is a polymer comprising a group of the formula:
其中端視在製備異氰脲酸酯中所使用之異氰酸酯而定, 係伸烧基或伸芳基殘基。 126151.doc -54- 200836619 聚異氰脲酸酯通常藉由異氰酸酯之環三聚反應製備。較 佳之異氰酸酯係與上述(組份B2A)相同之異氰酸酯。製備 聚異氰脲酸酯之製備方法及條件已為熟習此項技術者所熟 知。 農樂組合物 本發明農藥組合物可為水性組合物或乾燥組合物(即不 ' 包含水之組合物)。 _ 在一較佳實施例中,該等農藥組合物係水性組合物,基 於本發明殺蟲劑組合物中組份的總量,其較佳包含55_97 重量%(更佳為85-95重量%)之水及3_45重量%(較佳為5_15 重畺/〇)之固體,其中該總量為i 〇〇重量%。該等固體較佳 係選自由以下組成之群:至少一種上述農藥(組份A)及至 少一種上述聚合黏結劑(組份B)、及(視情況)至少一種下述 固定劑(組份C)及(視情況)端視上述最終產品之用途而定之 其他組份。 • 將該等農藥組合物施加於材料之處理浴較佳為水性調配 物,該等水性調配物以本發明殺蟲劑組合物中組份之總量 计υ έ 95 99.5重畺%(較佳為95·99重量%,更佳為重 ΐ%)之水及0.5-5重量%(較佳為卜5重量%)之固體。固體較 • 佳係選自由以下組成之群:至少一種上述式丨之農藥化合 物(組份Α)、及至少一種上述聚合黏結劑(組份β)、及(視情 況)至少一種下述固定劑(組份c)及(視情況)端視上述最終 產品之用途而定之其他組份。 該聚合黏結劑較佳係與固定劑C一起施用,而該固定劑 126151.doc -55- 200836619 係用以改良農藥在材料上之附著力。該固定劑可包含游離 異氰酸酯基。 適宜之固定劑係(例如)包含游離異氰酸酯基之異氰酸酯 或異氛脲酸醋。較佳地,該等異氰脲酸酯係基於在伸烷基 單元中具有4至12個碳原子之伸烷基二異氰酸酯,例如, 1,12_十二烷二異氰酸酯、2-乙基-i,4-丁二異氰酸酯、2-甲 基-1,5-戊二異氰酸酯、i,4_丁二異氰酸酯、離胺酸酯二異 氰酸酯(LDI)、1,6-己二異氰酸酯(HMDI)、環己烷4,3_及/ 或-1,4-二異氰酸酯、2,4·及2,6-六氫-甲苯二異氰酸酯以及 相應異構體混合物、4,4,-、2,2,-及2,4,-二環己基甲烷二異 氰酸酯以及相應混合物、^異氰酸基_3,3,5•三甲基_5-異氰 酸基甲基環己烷(IPDI)、2,4·及/或2,6_甲苯二異氰酸酯、 4,4 -、2,4’及/或2,2’-二苯基甲烷二異氰酸醋(單體態之 MDI)、多苯基多亞甲基聚異氰酸酯(聚合態之μ〇ι)及/或包 含至少兩種上述異氰酸酯之混合物。更佳地,該等異氰脲 酸酯係基於1,6-己二異氰酸酯(HMm)。 更佳地,該異氰脲酸酯係用基於氧化乙烯/或丨,2_氧化丙 烯之聚氧化烯烴(較佳為聚氧化乙烯)親水化之異氰脲酸 酯。 用作固疋劑之異氰脲酸酯可藉由此項技術中熟知之方法 製備。以用作製備異氰脲酸酯之原料之異氰酸酯的量計, 較佳為5·25重量%(更佳為7-2〇重量%,最佳為丨〇_ i 5重量%) 之異氰酸酯基為游離異氰酸酯基。 最佳地,用作固定劑之異氰脲酸酯係溶於極性非質子 126151.doc -56- 200836619 劑中,例如THF、DMF或碳酸丙二酯或碳酸乙二醋。Wherein it depends on the isocyanate used in the preparation of the isocyanurate, which is a pendant or aryl residue. 126151.doc -54- 200836619 Polyisocyanurates are usually prepared by cyclotrimerization of isocyanates. A preferred isocyanate is the same isocyanate as described above (Component B2A). Methods and conditions for preparing polyisocyanurates are well known to those skilled in the art. Farm music composition The pesticidal composition of the present invention may be an aqueous composition or a dry composition (i.e., a composition that does not contain water). In a preferred embodiment, the pesticidal compositions are aqueous compositions, preferably comprising from 55 to 97% by weight (more preferably from 85 to 95% by weight, based on the total of the components of the insecticidal composition of the present invention). And a solid of 3 to 45% by weight (preferably 5 to 15% by weight/〇), wherein the total amount is i 〇〇 by weight. Preferably, the solids are selected from the group consisting of at least one of the above pesticides (Component A) and at least one of the above polymeric binders (Component B), and (as appropriate) at least one of the following fixatives (Component C) And (as appropriate) other components depending on the use of the above final product. • The treatment bath in which the pesticide compositions are applied to the material is preferably an aqueous formulation which is based on the total amount of the components of the insecticidal composition of the invention έ 95 99.5 % by weight (preferably It is 95.9% by weight, more preferably 5% by weight of water and 0.5 to 5% by weight (preferably 5% by weight) of solid. Preferably, the solid is selected from the group consisting of at least one of the above-mentioned pesticide compounds (component Α), and at least one of the above polymeric binders (component β), and (as appropriate) at least one of the following fixatives (Component c) and (as appropriate) other components depending on the use of the above final product. Preferably, the polymeric binder is applied with Fixative C, and the fixative 126151.doc -55-200836619 is used to improve the adhesion of the pesticide to the material. The fixative may comprise a free isocyanate group. Suitable fixing agents are, for example, isocyanates containing a free isocyanate group or an anaerobic acid vinegar. Preferably, the isocyanurate is based on an alkyl diisocyanate having 4 to 12 carbon atoms in the alkylene unit, for example, 1,12-dodecane diisocyanate, 2-ethyl- i,4-butyl diisocyanate, 2-methyl-1,5-pentane diisocyanate, i,4-butane diisocyanate, leucoyl diisocyanate (LDI), hexamethylene diisocyanate (HMDI), Cyclohexane 4,3_ and/or -1,4-diisocyanate, 2,4· and 2,6-hexahydro-toluene diisocyanate and mixtures of corresponding isomers, 4,4,-, 2,2, -and 2,4,-dicyclohexylmethane diisocyanate and the corresponding mixture, isocyanato-3,3,5•trimethyl-5-isocyanatomethylcyclohexane (IPDI), 2, 4·and/or 2,6-toluene diisocyanate, 4,4 -, 2,4' and/or 2,2'-diphenylmethane diisocyanate (MDI in monomeric state), polyphenylene Polymethylene polyisocyanate (polymerized state) and/or a mixture comprising at least two of the above isocyanates. More preferably, the isocyanurates are based on 1,6-hexamethylene diisocyanate (HMm). More preferably, the isocyanurate is an isocyanurate which is hydrophilized based on a polyalkylene oxide (preferably polyethylene oxide) based on ethylene oxide/or oxime, 2-propylene oxide. The isocyanurate used as a solidifying agent can be prepared by a method well known in the art. The isocyanate group is preferably 5.25% by weight (more preferably 7-2% by weight, most preferably 丨〇_i 5% by weight) based on the amount of the isocyanate used as the raw material for preparing the isocyanurate. It is a free isocyanate group. Most preferably, the isocyanurate used as a fixing agent is dissolved in a polar aprotic 126151.doc -56-200836619 agent such as THF, DMF or propylene carbonate or ethylene carbonate.
所用最佳固定劑係基於HMDI之異氰脲酸酯,其中hMDI 係用聚氧化乙烯親水化且溶於碳酸丙二酯(7〇重量%之 HMDI於30重量%之碳酸丙二酯中)中。以作為原料用於製 備異氰脲酸酯之異氰酸酯的量計,游離異氰酸g旨基的量係 11-12重量%。The best fixative used is an isocyanurate based on HMDI, wherein hMDI is hydrophilized with polyethylene oxide and dissolved in propylene carbonate (7% by weight of HMDI in 30% by weight of propylene carbonate) . The amount of free isocyanate g is 11-12% by weight based on the amount of isocyanate used to prepare the isocyanurate as a raw material.
若使用固定劑,則以該組合物之固體含量計,該農藥組 合物較佳包含以下組份: &)20_70重量%(較佳為25_65重量%,更佳為3〇_65重量%) 之至少一種農藥(組份A);及 b) 29-72重量%(較佳為34_7〇重量%,更{圭為3366重量 之至少一種上述聚合黏結劑(組份B); 〇 1·8重量%(較佳為i ·5重量%,更佳為^重量之至少 一種固定劑(組份C); 其中該等組份之總量為該農藥組合物固體含量之⑽重量 輛現最終產品之用途而定,該農筚 -戍多m ^綠合物可進-步包含 次夕種選自以下之組份:水 抗衡墼对新w α珠劑、填料、 貝诏、防霧化劑、發泡劑 满亦,丨^ /且清劑、成核劑、偶 二Π增:_電劑)、穩定劑(例如抗氧化劑、碳 劑、脫模 具有uv保護特性之試 劑、防黏劑、抗遷移劑、消”卜鋪展 剤防/可劑、增稠劑、其他 126l51.doc -57- 200836619 权生物劑、潤濕劑、增塑劑及薄膜形成劑、黏著劑或抗黏 者劑、光免(螢光增白)劑、芳香劑、顏料及染料。If a fixative is used, the pesticidal composition preferably comprises the following components, based on the solids content of the composition: &) 20-70% by weight (preferably 25-65% by weight, more preferably 3〇_65% by weight) At least one pesticide (component A); and b) 29-72% by weight (preferably 34-7% by weight, more {3366% by weight of at least one of the above polymeric binders (Component B); 〇1·8 % by weight (preferably i · 5% by weight, more preferably at least one fixing agent (component C); wherein the total amount of the components is (10) by weight of the solid content of the pesticide composition. Depending on the application, the 筚-戍多 m ^ green compound may further comprise a component selected from the following: water counterbalance to new w α beads, filler, shellfish, anti-fogging agent , foaming agent is also full, 丨 ^ / and clearing agent, nucleating agent, even two Π :: _ electric agent), stabilizer (such as antioxidants, carbon, uv protection properties of the mold, anti-adhesive agent , anti-migration agent, elimination, spread, anti-agent, thickener, other 126l51.doc -57- 200836619 weight biological agent, wetting agent, plasticizer and film former , adhesives or anti-adhesive agents, light-free (fluorescent whitening) agents, fragrances, pigments and dyes.
適宜之消泡劑係(例如)矽消泡劑。用於保護uv-敏感性 殺蟲劑及/或驅蟲劑之適宜uv_保護劑係(例如)對胺基苯甲 ΜΡΑΒ A)、辛基甲氧基sin_th、芪、苯乙烯基或苯并三 上行生物笨并p号唾衍生物、經經基取代之二苯甲酮、水 杨I ig 、、二取代之二°秦、肉桂酸衍生物(視情況經2_氰基取 代)、吡唑啉衍生物、丨,Γ_聯苯基_4,4,·雙·2(甲氧基苯基)_ 乙烯基或其它UV保護劑。適宜之光亮劑係二氫喹啉_衍 生物、1,3-二芳基咄唑啉衍生物、嵌二萘、萘二甲酸醯亞 胺、4,4 -二苯乙烯聯笨、4,4,_二胺基_2,2,-笑二磺酸、異丙 苯2生物及經-CH=CH_橋鍵鏈接之苯并噚唑、苯并異噚唑 或苯并咪唾系統或其它螢光增白劑。 本發明農藥組合物中所用之典型顏料係彼等用於顏料染 色或印刷製程或用於塑膠之著色且已為熟習此項技術: 熟知之顏料。 ^ 顏料根據其化學性質可分為無機顏料或有機顏料。無機 顏料主要用作白色顏料(例如呈金紅石或銳鈦礦形式:二 氧化鈇、ZnO、白幻或黑色顏料(例如炭黑)。亦可使用: 色無機顏料’但因其具有潛在之毒性危險,其並 : ::為賦予顏色’有機顏料或染料均較佳。有機顏料:: 早或雙偶氮、萘紛、苯并咪嗤酮、(硫代)敕、二鬼嘻、三 :啶酮、St菁、異吲哚啉酮、茈、哌瑞酮、金屬錯: 二酮^各並㈣型顏料。可使用粉末或液體形式呈^ 126151.doc -58· 200836619Suitable antifoaming agents are, for example, deuterium defoamers. Suitable uv_protecting agents for protecting uv-sensitive insecticides and/or insect repellents are, for example, p-aminobenzamide A), octylmethoxy sin_th, anthracene, styryl or benzo Three ascending biological stupid and p-salt derivative, benzophenone substituted by thiol, salicin I ig, disubstituted di-chin, cinnamic acid derivative (optionally substituted by 2-cyano), pyridyl An oxazoline derivative, anthracene, fluorene-biphenyl-4,4,bisbis(2-methoxyphenyl)-vinyl or other UV protectant. Suitable brighteners are dihydroquinoline derivatives, 1,3-diaryloxazoline derivatives, inlaid naphthalene, naphthalene naphthalate, 4,4-stilbene, 4,4 , _diamino 2,2,- laughing disulfonic acid, cumene 2 organism and benzoxazole linked via a -CH=CH_ bridge, benzoisoxazole or benzopyrene system or other Fluorescent whitening agent. Typical pigments used in the pesticidal compositions of the present invention are used in pigment dyeing or printing processes or in the coloring of plastics and are well known in the art: well known pigments. ^ Pigments can be classified into inorganic pigments or organic pigments depending on their chemical properties. Inorganic pigments are mainly used as white pigments (for example in the form of rutile or anatase: cerium oxide, ZnO, white magic or black pigments (eg carbon black). Also available: coloured inorganic pigments' but due to its potential toxicity Dangerous, and: :: for coloring - organic pigments or dyes are preferred. Organic pigments:: early or bisazo, naphthalene, benzoxanthone, (thio) oxime, sneaky, three: Pyridone, St cyanine, isoindolinone, anthracene, piperidone, metal sterol: diketones and (4) type pigments, can be used in powder or liquid form ^ 126151.doc -58· 200836619
==)之顏料。較佳之顏㈣顏料黃83、顏料黃I 23 : ‘料”顏料""Μ、顏料紅146、顏料紫19、顏料紫 顏枓監15/1、顏料藍15/3、顏料 、翁… 颂枓綠7、顏料黑7。其它 週且之顏料已為熟習此項技術者所熟知。 可用於本發明之典型染料係粉末或液體形式之還原染 料、陽離子染料及分散染料。還 ’、 、、主 疋原木枓可用作顏料或在甕 /貝^原)及氧化程序後使用。較佳者係使用還原染料形 式。避原染料可為陰丹士林藍(indanthr〇ne)型,例如,ci 4、6或14;或為陰丹士林特黃⑺嶋命叫型, 例如’ C.L Vat Yellow丄;或為陰丹士林橙黃㈣‘叫 型,例如,C.L Vat 0range 2及9 ;或為異苯并葱嗣(異宜和 藍⑹型,例如,C.L Vat Violet i ;或為二苯并葱酮(宜和 血酮)型,例如,C.i· Vat Blue 16、19、20及 22、C.I. Vat==) pigment. Preferred color (4) Pigment Yellow 83, Pigment Yellow I 23 : 'Materials' pigment ""Μ, Pigment Red 146, Pigment Violet 19, Pigment Violet 枓15/1, Pigment Blue 15/3, Pigment, Weng...颂枓Green 7, Pigment Black 7. Other pigments are well known to those skilled in the art. Typical dyes for use in the present invention are vat dyes, cationic dyes and disperse dyes in powder or liquid form. Also, ', The main sapwood can be used as a pigment or in the sputum/bean and the oxidation process. Preferably, the vat dye form is used. The virgin dye can be indanthrone blue type, for example , ci 4, 6 or 14; or for the indanthrene yellow (7) fate, such as 'CL Vat Yellow丄; or for the indanthrene orange (four) 'call type, for example, CL Vat 0range 2 and 9; Or isobenzoic onion (isoform and blue (6) type, for example, CL Vat Violet i; or dibenzoxanthone (suitable and ketone) type, for example, Ci·Vat Blue 16, 19, 20 and 22 CI Vat
Green卜2及m Vat mack 9;或為蒽醌咔唑型例 C.I. Vat Orange 11 及 15、C.I. Vat Brown 1、3及 44、 C.I. Vat Green 8及c.L Vat Black 27 ;或為苯并蒽酮吖啶酮 型,例如,C.I. Vat Green 3及 13及 C.I· Vat Black 25 ;或為 蒽醌唑型,例如,C.L Vat Red 10;或為茈四碳酸二醯亞 胺型,例如,C.I. Vat Red 23及32 ;或咪唑衍生物,例 如,C.I· Vat Yellow 46或胺基三唤衍生物,例如,cj. vatGreen Bu 2 and m Vat mack 9; or carbazole type CI Vat Orange 11 and 15, CI Vat Brown 1, 3 and 44, CI Vat Green 8 and cL Vat Black 27; or benzoxanone oxime a ketone type, for example, CI Vat Green 3 and 13 and CI·Vat Black 25; or a carbazole type, for example, CL Vat Red 10; or a diterpene tetramine type, for example, CI Vat Red 23 And 32; or an imidazole derivative, for example, CI·Vat Yellow 46 or an amino-terminated derivative, for example, cj. vat
Blue 66。其它適宜之還原染料已為熟習此項技術者所熟 知。 典型之分散及陽離子染料已為熟習此項技術者所熟知。 若使用纖維素基材作為材料,則該等纖維素基材較佳用 126151.doc - 59- 200836619 還原染料、直接染料、反應性染料或硫磺染料染色。 在另一實施例中,本發明之農藥組合物係包含 一 王夕一種Blue 66. Other suitable vat dyes are well known to those skilled in the art. Typical dispersion and cationic dyes are well known to those skilled in the art. If a cellulosic substrate is used as the material, the cellulosic substrates are preferably dyed with a vat dye, a direct dye, a reactive dye or a sulfur dye, 126151.doc - 59-200836619. In another embodiment, the pesticidal composition of the present invention comprises a
顏料及/或至少一種染料之上述農藥組合物。相對於該農 藥固體含量之總重量,本發明之農藥組合物較佳包含⑺ 300重量%(更佳為20-150重量%)之顏料及/或染料。S 若該組合物以試劑盒形式遞送,則在使用之前可對該材The above-mentioned pesticidal composition of a pigment and/or at least one dye. The pesticidal composition of the present invention preferably comprises (7) 300% by weight (more preferably 20 to 150% by weight) of the pigment and/or dye relative to the total weight of the solid content of the medicament. S If the composition is delivered in the form of a kit, the material may be used prior to use.
料(例如紡織品材料或塑膠材料)實施浸潰(意指(例如)染色 或其他處理)。 在另一實施例中,本發明之經浸潰材料進一步包含一或 多種選自以下之組份:防腐劑、清潔劑、穩定劑、具1 UV保羞特性之试劑、光売劑、鋪展劑、抗遷移劑、消泡 黏著劑、顏料m上述該等組份之適宜實例已為 此項技術者所熟知。 、 在本發明另一實施例中,該經浸潰材料除包含上述該至 少-種農藥及該至少-種聚合黏結劑外亦包含至少一: 料及/或至少-種染料。該至少—種顏料的量通常係q 命材料(乾燥)重量之O.m重量%,較佳為〇1_5重量:, ϋ為G.2-3.5重Ϊ %。該至少—種染料的量通 (乾無)重量之重量%,較佳為(Μ-5重量%,更佳^ ::.5重量%。該材料較佳包含至少-種顏料或至少 木π上文已闡述適宜之顏料及染料。 用於浸潰該材料形成網眼織物之製程 K地,用於浸潰材料(例如紡織品材料或㈣材料汰 I26151.doc 200836619 製程包括以下步驟: 1)形成水性調配物或熔體,其中水性調配物較佳,其包 含至少一種農藥及至少一種聚合黏結劑(較佳為上述聚 合黏結劑)及視情況其他成份; i i)耩由以下將该水性調配物施加於該材料·· iia)使該材料通過該水性調配物;或 ub)使該材料接觸一部分或全部浸於該水性調配物中 • 之輥並將該水性調配物汲取至該材料與該輥接觸 之側;或 iic) 雙側塗覆該材料;或 iid) 將該水性調配物喷塗至該材料上,其中該喷塗用 任一適宜喷塗之裝置手動或自動實施,例如,用 喷霧罐或工廠常用之裝置實施; iie) 施加呈泡沫形式之該水性調配物;或 iif) 將該材料浸於該水性調配物中;或 i i δ)將5亥水性调配物刷塗於該材料上或該材料中;或 iih)將該水性調配物傾倒於該材料上;或藉由壓延或 用刮刀施加該熔體; 1U)視情況去除多餘水性調配物或多餘溶體(?);及 • iv)將該材料乾燥及/或固化。 在本發明之上下文中,水性調配物可為溶液、乳液或懸 浮液/分散液。 該水性調配物或熔體較佳包含較佳以水性調配物形式使 用之該農藥組合物。 126151.doc • 61 - 200836619 在本發明之上下文中,’•浸潰’’係用於施加該農藥組合物 之製程。若需要,此製程可包括將所施加之農藥組合物固 4匕之製程以在該材料上獲得一塗層。π經浸潰材料”係其上 施加有該農藥組合物之材料。若需要,該’’經浸潰材料π可 藉由將所施加之農藥組合物固化來實施塗覆。 該農藥組合物亦可藉由轉移印刷、喷墨印刷、絲網製版 • 及粉末印刷施加於該材料上。 施加該農藥組合物之細節已為熟習此項技術者所熟知並 在(例如)WO 2005/064072中予以揭示。 本發明方法可用於保護農作物。 該方法可用於保護植物免於在植物栽培過程中遇到之任 一種類的害蟲及疾病。 此等害蟲包括: 來自鱗翅目(Lepidoptera)之昆蟲,例如小地老虎(Agrotis ypsilon)、黃地老虎(Agrotis segetum)、棉葉波紋葉蛾 ⑩ (Alabama argillacea)、黎豆夜蛾(Anticarsia gemmatalis)、 蘋實巢蛾(Argyresthia conjugella)、丫 紋夜蛾(Autographa gamma)、松尺蠖(Bupalus piniarius)、黃卷蛾(Cacoecia murinana)、煙捲蛾(Capua reticulana)、冬尺蠖蛾(Cheimatobia ^ brumata)、雲杉卷葉蛾((1:11〇!^1:〇1^111^£111111€6^11&)、西方雲 杉卷葉蛾(Choristoneura occidentalis)、美洲黏嘉(Cirphis unipuncta)、蘋果蠹蛾(Cydia pomonella)、歐洲松毛蟲 (Dendrolimus pini)、瓜野填(Diaphania nitidalis)、巨座玉 米模(Diatraea grandiosella)、埃及金剛鑽(Earias insulana)、南 126151.doc -62- 200836619The material (e.g., textile material or plastic material) is impregnated (meaning, for example, dyeing or other treatment). In another embodiment, the impregnated material of the present invention further comprises one or more components selected from the group consisting of preservatives, detergents, stabilizers, reagents having 1 UV shame property, optical tweezers, spreading Suitable examples of such agents, agents, anti-migration agents, antifoaming agents, pigments m are well known to those skilled in the art. In another embodiment of the invention, the impregnated material comprises at least one: and/or at least one dye in addition to the at least one pesticide and the at least one polymeric binder. The amount of the at least one pigment is usually O.m% by weight of the weight of the material (dry), preferably 〇1_5 by weight: ϋ is G.2-3.5 Ϊ%. The amount of the at least one dye is (% by weight) by weight, preferably (Μ-5 wt%, more preferably: ::. 5 wt%. The material preferably comprises at least one pigment or at least wood π Suitable pigments and dyes have been described above. Process for impregnating the material to form a mesh fabric, for impregnating materials (eg textile materials or (4) materials) I26151.doc 200836619 The process comprises the following steps: 1) formation An aqueous formulation or melt, wherein the aqueous formulation preferably comprises at least one pesticide and at least one polymeric binder (preferably the above polymeric binder) and optionally other ingredients; ii) hydrazine from the following aqueous formulation Applying to the material i.i.) passing the material through the aqueous formulation; or ub) contacting the material with a portion or all of the immersion in the aqueous formulation and extracting the aqueous formulation to the material and the roller Contacting the side; or iic) coating the material on both sides; or iid) spraying the aqueous formulation onto the material, wherein the spraying is performed manually or automatically using any suitable spraying device, for example, by spraying Fog tank or factory often Implemented by the device; iie) applying the aqueous formulation in the form of a foam; or iif) immersing the material in the aqueous formulation; or ii δ) applying a 5 kPa aqueous formulation to the material or the material Or; or iih) pour the aqueous formulation onto the material; or by calendering or applying the melt with a spatula; 1 U) optionally removing excess aqueous or excess solution (?); and • iv) The material is dried and/or cured. In the context of the present invention, aqueous formulations may be solutions, emulsions or suspensions/dispersions. Preferably, the aqueous formulation or melt comprises the pesticidal composition preferably used in the form of an aqueous formulation. 126151.doc • 61 - 200836619 In the context of the present invention, '•impregnation' is used in the process of applying the pesticide composition. If desired, the process can include a process of solidifying the applied pesticide composition to obtain a coating on the material. The π-impregnated material is a material to which the pesticide composition is applied. If desired, the immersion material π can be applied by curing the applied pesticide composition. The pesticide composition is also applied. The material can be applied to the material by transfer printing, ink jet printing, screen making, and powder printing. Details of the application of the pesticide composition are well known to those skilled in the art and are described, for example, in WO 2005/064072 The method of the present invention can be used to protect crops. The method can be used to protect plants from any kind of pests and diseases encountered during plant cultivation. Such pests include: insects from Lepidoptera, such as small Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa Gamma), Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatobia ^ brumata, Cedar leaf moth ((1:11〇!^1:〇1^111^£111111€6^11&), western spruce leaf moth (Choristoneura occidentalis), American C. (Cirphis unipuncta), apple moth (Cydia pomonella), Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Earias insulana, South 126151.doc -62- 200836619
美玉米苗斑頌(Elasmopalpus lignosellus)、鹽澤枝燈蛾 (Estigmene acrea)、女貞細卷蛾(Eupoecilia ambiguella)、 歐洲松梢小卷蛾(Evetria bouliana)、粒膚地老虎(Feltia subterranean)、大躐填(Galleria mellonella)、李小食心蟲 (Grapholitha flmebrana)、梨小食心蟲(Grapholitha molesta)、棉 铃蟲(Heliothis armigera)、美洲煙葉蛾(Heliothis virescens)、 美洲棉鈐蟲(Heliothis zea)、菜煩(Hellula undalis)、落葉 松尺蛾(Hibernia defoliaria)、美國白蛾(Hyphantria cunea)、蘋 果巢蛾(Hyponomeuta malinellus)、蕃痴蠹蛾(Keiferia lycopersicella)、鐵杉尺蠖(Lambdina fiscellaria)、甜菜夜 蛾(Laphygma exigua)、咖啡點潛蛾(Leucoptera coffeella)、旋 紋潛葉蛾(Leucoptera scitella)、蘋細蛾(Lithocolletis blancardella)、葡萄漿果小卷蛾(Lobesia botrana)、黃綠條 埃(Loxostege sticticalis)、舞毒蛾(Lymantria dispar)、僧尼 毒蛾(Lymantria monacha)、窄翅潛葉蛾(Lyonetia clerkella)、 天幕毛蟲(Malacosoma neustria)、甘藍夜蛾(Mamestra brassicae)、黃杉毒蛾(Orgyia pseudotsugata)、歐洲玉米填 (Ostrinia nubilalis)、冬夜蛾(Panolis flammea)、紅鈴蟲 (Pectinophora gossypiella)、豆雜角夜蛾(Peridroma saucia)、圓黃掌舟蛾(Phalera bucephala)、馬鈴薯塊莖蛾 (Phthorimaeaoperculella)、橘細潛蛾(Phyllocnistis citrella)、大 菜粉蛾(Pieris brassicae)、苜蓿綠夜蛾(piathypena scabra)、小 菜蛾(Plutella xylostella)、大豆夜蛾(pseucj〇plusia includens)、 松梢卷葉蛾(Rhyacionia frustrana)、馬鈴薯塊莖蛾 126151.doc -63- 200836619 (Scrobipalpula absoluta)、麥蛾(Sitotroga cerealella)、葡萄 長須卷葉蛾(Sparganothis pilleriana)、草地黏蟲(Spodoptera frugiperda)、海灰翅夜蛾(Spodoptera littoralis)、斜紋夜蛾 (Spodoptera litura)、松異周蛾(Thaumatopoea pityocampa)、櫟 綠卷葉蛾(Tortrix viridana)、粉紋夜蛾(Trichoplusia ni)及 雲杉小卷葉蛾(Zeiraphera canadensis);Elasmopalpus lignosellus, Estigmene acrea, Eupoecilia ambiguella, Evetria bouliana, Feltia subterranean, Galleria mellonella, Grapholitha flmebrana, Grapholitha molesta, Heliothis armigera, Heliothis virescens, Heliothis zea, and annoying (Hellula undalis), Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lambdina fiscellaria, beet armyworm ( Laphygma exigua), Leucoptera coffeella, Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, narrow-winged leaf (Lyonetia clerkella), Malacosoma neustria, Mamestra brassicae, Orgyia pseudotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella ), Peridroma saucia, Phalera bucephala, Phthorimaeaoperculella, Phyllocnistis citrella, Pieris brassicae, Spodoptera litura (piathypena scabra), Plutella xylostella, Pseudos genus (pseucj〇plusia includens), Rhyacionia frustrana, Potato tuber moth 126151.doc -63-200836619 (Scrobipalpula absoluta), wheat moth (Scrobipalpula absoluta) Sitotroga cerealella), Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, alfalfa Tortrix viridana, Trichoplusia ni Spruce small leaf roller (Zeiraphera canadensis);
甲蟲(鞘翅目(Coleoptera)),例如梨長吉丁(Agrilus sinuatus)、具條叩曱(Agriotes lineatus)、暗紋叩甲 (Agriotes obscurus)、六月金龜(Amphimallus solstitialis)、 異形方胸材小蠹(Anisandrus dispar)、棉鈴象甲(Anthonomus grandis)、蘋果花象甲(Anthonomus pomorum)、亞麻藍跳 曱(Aphthona euphoridae)、紅尾 σΡ 頭蟲(Athous haemorrhoidalis)、甜 菜隱食甲(Atomaria linearis)、大松小蠢(Blastophagus piniperda)、埋葬蟲(Blitophaga undata)、蠶豆象(Bruchus rufimanus)、碗豆象(Bruchus pisorum)、歐洲兵豆象 (Bruchus lentis)、蘋果卷葉象甲(Byctiscus betulae)、甜菜 大龜甲(Cassida nebulosa)、豆葉甲(Cerotoma trifurcata)、 金花金龜(Cetonia aurata)、白菜籽龜象(Ceuthorrhynchus assimilis)、甘藍莖龜象(Ceuthorrhynchus napi)、甜菜莖跳 甲(Chaetocnema tibialis)、煙草金針蟲(Conodems vespertinus)、天 門冬葉甲(Crioceris asparagi)、叩頭蟲亞種(Ctenicera ssp·)、長角葉甲(Diabrotica longicornis)、黃瓜半星葉曱 (Diabrotica semipunctata)、黃瓜十二星葉甲(Diabrotica 12-punctata)、巴西葉甲(Diabrotica speciosa)、玉米根葉甲 126151.doc -64- 200836619Beetle (Coleoptera), such as Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Alien square chest (Anisandrus dispar), Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis, Dasong Blastophagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum, Bruchus lentis, Byctiscus betulae, beet tortoiseshell (Byctiscus betulae) Cassida nebulosa), Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Tobacco Needle Conodems vespertinus, Crioceris asparagi, and scorpion subspecies (C Tenicera ssp·), Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata, Diabrotica speciosa, Corn root 126151 .doc -64- 200836619
(Diabrotica virgifera)、墨西哥豆瓢蟲(Epilachna varivestis)、煙草跳甲(Epitrix hirtipennis)、棉籽灰象 (Eutinobothrus brasiliensis)、松樹皮象(Hylobius abietis)、 埃及苜蓿象甲(Hypera brunneipennis)、苜稽葉象甲(Hypera postica)、雲杉八齒小蠹(Ips typographus)、具條負泥蟲 (Lema bilineata)、黑角負泥蟲(Lema melanopus)、馬鈴薯 甲盛(Leptinotarsa decemlineata)、甜菜金針蟲(Limonius californicus)、稻象甲(Lissorhoptrus oryzophilus)、玉米叩 甲(Melanotus communis)、油菜露尾甲(Meligethes aeneus)、忽 布總角金龜(Melolontha hippocastani)、歐洲總金龜 (Melolontha melolontha)、稻負泥蟲(Oulema oryzae)、黑虫主 象鼻蟲(Ortiorrhynchus sulcatus)、草莓根象甲(Otiorrhynchus ovatus)、辣根猿葉甲(Phaedon cochleariae)、梨切葉象 (Phyllobius pyri)、油菜藍跳甲(Phyllotreta chrysocephala)、金 龜屬種類(Phyllophaga sp·)、庭園麗金龜(Phyllopertha horticola)、大豆淡足跳甲(Phyllotreta nemorum)、黃曲條 跳甲(Phyllotreta striolata)、曰本麗金龜(Popillia japonica)、婉 豆葉象甲(Sitona lineatus)及榖象(Sitophilus granaria); 織、蚊(雙翅目(Diptera)),例如埃及伊蚊(Aedes aegypti)、白紋伊蚊(Aedes albopictus)、剌擾伊蚊(Aedes vexans)、墨西哥橘實题(Anastrepha ludens)、五斑按蚊 (Anopheles maculipennis)、庫態按蚊(Anopheles crucians)、淡 色按蚊(Anopheles albimanus)、岡比亞按蚊(Anopheles gambiae)、費氏按蚊(Anopheles freeborni)、白踝按蚊 -65- 126151.doc 200836619 (Anopheles leucosphyms)、微小按蚊(Anopheles minimus)、四 斑按蚊(Anopheles quadrimaculatus)、紅頭麗繩(Calliphora vicina)、地中海實 4¾ (Ceratitis capitata)、蛆症金繩 (Chrysomya bezziana)、螺旋金繩(Chrysomya hominivorax)、(Diabrotica virgifera), Epilachna varivestis, Epitrix hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera brunneipennis, and cockroach (Hypera postica), spruce Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius californicus ), Lisorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, Melolontha melolontha, rice worm ( Oulema oryzae), Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae, Phyllobius pyri, Phyllotreta chrysocephala ), the species of the genus Phyllophaga sp., and the Phyllopertha hortic Ola), Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sitophilus granaria; (Diptera), such as Aedes aegypti, Aedes albopictus, Aedes vexans, Anastrepha ludens, Anopheles sinensis (Anopheles sinensis) Anopheles maculipennis), Anopheles crucians, Anopheles albimanus, Anopheles gambiae, Anopheles freeborni, Anopheles sinensis -65-126151.doc 200836619 ( Anopheles leucosphyms), Anopheles minimus, Anopheles quadrimaculatus, Calliphora vicina, Ceratitis capitata, Chrysomya bezziana, spiral gold rope Chrysomya hominivorax),
肉旋金繩(Chrysomya macellaria)、鹿绳(Chrysops discalis)、黃赭色斑 it (Chrysops silacea)、大西洋斑虹: (Chrysops atlanticus)、羊旋皮绳(Cochliomyia hominivorax)、 高粱癭蚊(Contarinia sorghicola)、嗜人瘤罐(Cordylobia anthropophaga)、毛庫蠓(Culicoides furens)、五帶淡色庫 蚊(Culex pipiens)、黑須庫蚊(Culex nigripalpus)、致倦庫 蚊(Culex quinquefasciatus)、媒庫蚊(Culex tarsalis)、純色 脈毛蚊(Culiseta inornata)、黑尾脈毛蚊(Culiseta melanura)、瓜實繩(Dacus cucurbitae)、油橄欖實繩(Dacus oleae)、芸苔莢癭蚊(Dasineura brassicae)、慧地種繩(Delia antique)、麥地種绳(Delia coarctata)、灰地種 4¾ (Delia platura)、甘藍地種繩(Delia radicum)、人膚罐(Dermatobia hominis)、黃腹廏繩(Fannia canicularis)、三點禾绳 (GeomyzaTripunctata)、大馬胃蠅(Gasterophilus intestinalis)、 刺舌場(Glossina morsitans)、須舌繩(Glossina palpalis)、 引舌繩(Glossina fuscipes)、Glossina tachinoides、騷擾角 繩(Haematobia irritans)、鞍癭癭蚊(Haplodiplosis equestris)、 潛繩屬(Hippelates spp·)、種織(Hylemyiaplatura)、蚊皮罐 (Hypoderma lineata)、勒蠓(Leptoconops torrens)、美洲斑 潛繩(Liriomyza sativae)、非洲菊斑潛繩(Liriomyza 126151.doc -66- 200836619Chrysomya macellaria, Chrysops discalis, Chrysops silacea, Chrysops atlanticus, Cochliomyia hominivorax, Contarinia sorghicola ), Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex nigripalpus, Culex quinquefasciatus, Culex pipiens (Culex tarsalis), Culiseta inornata, Culiseta melanura, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Delia antique, Delia coarctata, Delia platura, Delia radicum, Dermatobia hominis, and yellow-bellied reins (Fannia) Canicularis), Geomyza Tripunctata, Gasterophilus intestinalis, Glossina morsitans, Glossina palpalis, tongue Glossina fuscipes, Glossina tachinoides, Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia platura, Hypoderma lineata, Le Ept (Leptoconops torrens), Liriomyza sativae, African chrysanthemum (Liriomyza 126151.doc -66- 200836619
trifolii)、羊綠蠅(Lucilia caprina)、銅綠繩(Lucilia cuprina)、絲光綠繩(Lucilia sericata)、Lycoria pectoralis、 曼蚊(Mansonia titillanus)、黑森癭蚊(Mayetiola destructor)、 家繩(Muscadomestica)、廢腐绳(Muscinastabulans)、羊鼻 繩(Oestrus ovis)、禾繩(Opomyza florum)、瑞典麥杆蠅 (Oscinella frit)、甜菜潛葉繩(Pegomya hysocyami)、蔥繩 (Phorbia antiqua)、甘蘭種题(Phorbia brassicae)、麥種繩 (Phorbia coarctata)、銀足白岭(Phlebotomus argentipes)、 哥倫比亞鱗蚊(Psorophora columbiae)、胡蘿蔔莖繩(Psila rosae)、異色鱗蚊(Psorophora discolor)、混合墨蚊 (Prosimulium mixtum)、櫻桃實蠅(Rhagoletis cerasi)、蘋 果實绳(Rhagoletis pomonella)、紅尾肉 4¾ (Sarcophaga haemorrhoidalis)、肉繩種類(Sarcophaga sp.)、帶蚋 (Simulium vittatum)、廄刺繩(Stomoxys calcitrans)、牛 it (Tabanus bovinus)、黑 it (Tabanus atratus)、具帶馬 it (Tabanus lineola)及 Tabanus similis、沼澤大蚊(Tipula 薊馬(纓翅目(Thysanoptera)),例如蘭花薊馬 (Dichromothrips corbetti)、薊馬亞種(Dichromothrips ssp)、煙草褐薊馬(Frankliniella fusca)、苜稽薊馬 (Frankliniella occidentalis)、麥花薊馬(Frankliniella tritici)、橘 實薊馬(Scirtothrips citri)、稻薊馬(Thrips oryzae)、棕櫚薊 馬(Thrips palmi)及棉薊馬(Thrips tabaci); 白蟻(等翅目(Isoptera)),例如原始歐洲木白蟻(Calotermes 126151.doc •67· 200836619 flavicollis)、歐美散白蟻(Leucotermes flavipes)、南美異白蟻 (Heterotermes aureus)、黃肢散白蟻(Reticulitermes flavipes)、 南方散白蟻(Reticulitermes virginicus)、南歐網紋白蟻 (Reticulitermes lucifugus)、非洲白蟻(Termes natalensis)及 家白蟻(Coptotermes formosanus);Trifolii), Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralis, Mansonia titillanus, Mayetiola destructor, Muscadomestica , Muscinastabulans, Oestrus ovis, Opomyza florum, Oscinella frit, Pegomia hysocyami, Phorbia antiqua, Ganlan (Phorbia brassicae), Phorbia coarctata, Phlebotomus argentipes, Psorophora columbiae, Psila rosae, Psorophora discolor, mixed ink Mosquito (Prosimulium mixtum), Rhagoletis cerasi, Rhagoletis pomonella, Sarcophaga haemorrhoidalis, Sarcophaga sp., Simulium vittatum, thorn rope ( Stomoxys calcitrans), Taitus bovinus, Tabanus atratus, Tabanus lineola and Tabanus simil Is, swamp big mosquito (Tipula thrips (Thysanoptera), such as Dichromothrips corbetti, Dichromothrips ssp, Frankliniella fusca, 苜 蓟 ( ( Frankliniella occidentalis), Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci; termites (equal wings) Isoptera), such as the original European wood termites (Calotermes 126151.doc •67·200836619 flavicollis), Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, southern scattered Termite (Reticulitermes virginicus), Reticulitermes lucifugus, Termes natalensis and Coptotermes formosanus;
緯螂(蜚蠊目(Blattaria)·蜚蠊科(Blattodea)),例如德國小 蠊(Blattella germanica)、亞洲小蠊(Blattella asahinae)、美 洲大蠊(Periplaneta americana)、曰本大蠊(Periplaneta japonica)、褐色大蠊(Periplaneta brunnea)、煙色大蠊 (Periplaneta fUligginosa)、澳洲大蠊(Periplaneta australasiae)及 東方蜚蠊(Blatta orientalis); 墙象(半翅目(Hemiptera)包括同翅目(Homoptera)),例如 擬緣蝽(Acrostemum hilare)、麥長蝽(Blissus leucopterus)、黑 斑煙盲蝽(Cyrtopeltis notatus)、赤星椿象(Dysdercus cingulatus)、棉紅蝽(Dysdercus intermedius)、麥扁盾培 (Eurygasterintegriceps)、棉蝽(Euschistus impictiventris)、棉鈴 喙緣蝽(Leptoglossus phyllopus)、美國牧草盲蝽(Lygus lineolaris)、牧草盲蝽(Lygus pratensis)、稻綠蜂(Nezara viridula)、方背皮蝽(Piesma quadrata)、稻蝽(Solubea insularis)、 紅肩蝽(Thyanta perditor)、紅豆草財(Acyrthosiphon onobrychis)、落葉松球财(Adelges laricis)、甘藍虫牙 (Aphidula nasturtii)、蠶立財(Aphis fabae)、草莓根财 (Aphis forbesi)、蘋果坊(Aphis pomi)、棉虫牙(Aphis gossypii)、醋栗对(Aphis grossulariae)、茶蔗虫牙(Aphis 126151.doc -68 - 200836619Blattaria (Blattodea), such as Blattella germanica, Blattella asahinae, Periplaneta americana, Periplaneta japonica ), Periplaneta brunnea, Periplaneta fUligginosa, Periplaneta australasiae, and Blatta orientalis; Walls (Hemiptera) include Homoptera (Homoptera) )), for example, Acrostemum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, and wheat scutellum ( Eurygasterintegriceps), Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara viridula, and Piesma Quadrata), Sorbae insularis, Thyanta perditor, Acyrthosiphon onobrychis , Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, gooseberry pair Aphis grossulariae), tea cane teeth (Aphis 126151.doc -68 - 200836619
schneideri)、繡線菊虫牙(Aphis spiraecola)、接骨木虫牙(Aphis sambuci)、碗豆财(Acyrthosiphon pisum)、茄溝無網虫牙 (Aulacorthum solani)、銀葉粉風(Bemisia argentifolii)、薊 短尾虫牙(Brachycaudus cardui)、杏圓尾坊(Brachycaudus helichrysi)、桃黑短尾财(Brachycaudus persicae)、李短尾 虫牙(Brachycaudus prunicola)、甘藍虫牙(Brevicoryne brassicae)、 角釘毛虫牙(Capitophorus horni)、Cerosipha gossypii、草莓 毛管对(Chaetosiphon fragaefolii)、茶薦隱瘤額财(Cryptomyzus ribis)、銀樅椎球虫牙(Dreyfusia nordmannianae)、雲杉椎球 虫牙(Dreyfusia piceae)、根瘤圓尾財(Dysaphis radicola)、 Dysaulacorthum pseudosolani、車前圓尾财(Dysaphis plantaginea)、梨西圓尾虫牙(Dysaphis pyri)、蠶豆葉蟬 (Empoasca fabae)、梅大尾虫牙(Hyalopterus pruni)、茶藶苦 菜财(Hyperomyzus lactucae)、麥長管财(Macrosiphum avenae)、大戟長管财(Macrosiphum euphorbiae)、薔薇長 管虫牙(Macrosiphon rosae)、蠢豆修尾虫牙(Megoura viciae)、 Melanaphis pyrarius、薔薇麥財(Metopolophium dirhodum)、桃 虫牙(Myzus persicae)、冬蔥瘤額財(Myzus ascalonicus)、櫻 桃黑瘤額财(Myzus cerasi)、核黃瘤額财(Myzus varians)、 蒿苣财(Nasonoviaribis,nigri)、褐稻風(Nilaparvata lugens)、萵 苣根瘿綿坊(Pemphigus bursarius)、嚴飛乱(Perkinsiella saccharicida)、蛇麻’庑額財(Phorodon humuli)、蘋木藏 (Psylla mali)、梨木乱(Psylla piri)、冬蔥溢瘤坊(Rhopalomyzus ascalonicus)、玉米溢管虫牙(Rhopalosiphum maidis)、粟溢 126151.doc •69· 200836619Schneideri), Aphis spiraecola, Aphis sambuci, Acyrthosiphon pisum, Aulacorthum solani, Bemisia argentifolii, 蓟 short tail Brachycaudus cardui, Brachycaudus helichrysi, Brachycaudus persicae, Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni, Cerosipha Gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordmannianae, Dreyfusia piceae, Dysaphis radicola, Dysaulacorthum Pseudosolani, Dysaphis plantaginea, Dysaphis pyri, Empoasca fabae, Hyalopterus pruni, Hyperomyzus lactucae, long tube Macrosiphum avenae, Macrosiphum euphorbiae Macrosiphon rosae, Megoura viciae, Melanaphis pyrarius, Metopolophium dirhodum, Myzus persicae, Myzus ascalonicus, cherry melanoma Myzus cerasi, Myzus varians, Nasonoviaribis, nigri, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida ), Phoodon humuli, Psylla mali, Psylla piri, Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Su Yi 126151 .doc •69· 200836619
管虫牙(Rhopalosiphum padi)、郁李 Μ 管蚜(Rhopalosiphum insertum)、梨砧草财(Sappaphis mala)、蘋紅紮圓尾虫牙 (Sappaphis mali)、麥二叉虫牙(Schizaphis graminum)、榆梨 棉財(Schizoneura lanuginosa)、麥長管财(Sitobion avenae)、溫 室白粉風(Trialeurodes vaporariomm)、橘二岔财(Toxoptera aurantii)及葡萄根瘤蚜(Viteus vitifolii)、溫帶臭蟲(Cimex lectularius)、熱帶臭蟲(Cimex hemipterus)、老獵培 (Reduvius senilis)、錐獵蝽屬(Triatoma spp.)及齒背獵培 (Arilus critatus); 螞蟻、蜜蜂、黃蜂、葉蜂(膜翅目(Hymenoptera)),例如 新疆菜葉蜂(Athalia rosae)、熱帶切葉蟻(Atta cephalotes)、 Atta capiguara、熱帶切葉蟻(Atta cephalotes)、光亮切葉 蟻(Atta laevigata)、強壯切葉蟻(Atta robusta)、切葉蟻 (Atta sexdens)、德州切葉蟻(Atta texana)、舉尾蟻屬 (Crematogaster spp.)、李小葉蜂(Hoplocampa minuta)、蘋 實葉蜂(Hoplocampa testudinea)、廚蟻(Monomorium pharaonis)、熱帶火蟻(Solenopsis geminata)、紅火蟻 (Solenopsis invicta)、黑火蟻(Solenopsis richteri)、加州火 蟻(Solenopsis xyloni)、紅收穫蟻(Pogonomyrmex barbatus)、 加州收穫蟻(Pogonomyrmex californicus)、大頭蟻(Pheidole megacephala)、西方蟻蜂(Dasymutilla occidentals)、熊蜂屬 (Bombus spp·)、黃胡蜂(Vespula squamosa)、常見黃胡蜂 (Paravespula vulgaris)、樹黃胡蜂(Paravespula pennsylvaniea)、德國 黃胡蜂(Paravespula germanica)、白斑臉黃胡蜂(Dolichovespula 126151.doc -70- 200836619 maculata)、黃邊胡蜂(Vespa crabro)、赭色馬蜂(Polistes rubiginosa)、佛羅里達弓背蟻(Camponotus floridanus)及阿 矛艮廷蟻(Linepithema humile);Rhopalosiphum padi, Rhopalosiphum insertum, Sappaphis mala, Sappaphis mali, Schizaphis graminum, Avocado Schizoneura lanuginosa), Sitobion avenae, Trialeurodes vaporariomm, Toxoptera aurantii and Viteus vitifolii, Cimex lectularius, Cimex hemipterus ), Reduvius senilis, Triatoma spp., and Arilus critatus; ants, bees, wasps, Hymenoptera, such as Xinjiang leaves Bee (Athalia rosae), Atta cephalotes, Atta capiguara, Atta cephalotes, Atta laevigata, Atta robusta, Atta Sexdens), Atta texana, Crematogaster spp., Hoplocampa minuta, Hoplocampa testudinea, Kitchen ants (Monomorium pharaonis), tropical fire ants (Solenopsis geminata), red fire ants (Solenopsis invicta), black fire ants (Solenopsis richteri), California fire ants (Solenopsis xyloni), red harvest ants (Pogonomyrmex barbatus), California harvest ants ( Pogonomyrmex californicus), Pheidole megacephala, Dasymutilla occidentals, Bombus spp., Vespula squamosa, Paravespula vulgaris, Paravespula pennsylvaniea, Paravespula germanica, Dolichovespula 126151.doc -70-200836619 maculata, Vespa crabro, Polistes rubiginosa, Camponotus floridanus and A. Linepithema humile;
蟪蟀、4皇蟲、蚱猛(直翅目(Orthoptera)),例如家蟠蟀 (Acheta domestica)、歐洲樓蛄(Gryllotalpa gryllotalpa)、 飛虫皇(Locusta migratoria)、雙帶蚱猛(Melanoplus bivittatus)、 赤腿蚱猛(Melanoplus femurrubrum)、墨西哥蚱猛(Melanoplus mexicanus)、遷徙蚱猛(Melanoplus sanguinipes)、落機山蚱 猛(Melanoplus spretus)、土煌(Nomadacris septemfasciata)、美 洲虫> 掹(Schistocerca americana)、非洲沙漠虫皇(Schistocerca gregaria)、摩洛哥戟紋虫皇(Dociostaurus maroccanus)、溫室 沙螽(Tachycines asynamorus)、塞内加爾小車虫皇(Oedaleus senegalensis)、臭腹腺虫皇(Zonozerus variegatus)、斑角蔵虫皇 (Hieroglyphus daganensis)、印度黃檀壇(Kraussaria angulifera)、意 大利虫皇(Calliptamus italicus)、澳洲疫蝗(Chortoicetes terminifera)及南非虫皇(Locustana pardalina); 蛛形綱(Arachnoidea),例如虫知蛛類節肢動物,(瞒目 (Acarina)),例如軟蜱科(Argasidae)、硬蜱科(Ixodidae)及 矫蜗科(Sarcoptidae)等科,例如美洲花蜱(Amblyomma americanum)、熱帶花蜱(Amblyomma variegatum)、海灣花 蜱(Amblyomma maculatum)、波斯隱 °彖蜱(Argas persicus)、具 環方頭蜱(Boophilus annulatus)、消色牛蜱(Boophilus decoloratus)、微小牛蜱(Boophilus microplus)、森林革蜱 (Dermacentor silvarum)、安氏革蜱(Dermacentor andersoni)、 126151.doc -71 - 200836619蟪蟀, 4 king worms, Orthoptera, such as Acheta domestica, Gryllotalpa gryllotalpa, Locusta migratoria, and Melanoplus bivittatus ), Melanoplus femurrubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasciata, American worms 掹( Schistocerca americana), Schistocerca gregaria, Dociostaurus maroccanus, Tachycines asynamorus, Oedaleus senegalensis, Zonozerus Variegatus), Hieroglyphus daganensis, Kraussaria angulifera, Calliptamus italicus, Chortoicetes terminifera and Locustana pardalina; Arachnoidea ), for example, the genus Arthropod, (Acarina), such as the soft scorpion (Argasidae), Ixodidae, and Sarcopteridae, such as Amblyomma americanum, Amblyomma variegatum, Amblyomma maculatum, Persian (Argas persicus), Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Dermacentor andersoni, 126151 .doc -71 - 200836619
變異革蜱(Dermacentor variabilis)、長 σ彖璃眼蜱(Hyalomma truncatum)、蓖子硬蜱(Ixodes ricinus)、淺紅硬蜱(Ixodes rubicundus)、黑腳硬蜱(Ixodes scapularis)、全環硬蜱 (Ixodes holocyclus)、太平洋硬蜱(Ixodes pacificus)、毛白 鈍緣蜱(Ornithodorus moubata)、赫姆純緣蜱(Ornithodorus hermsi)、回歸熱純緣蜱(Ornithodorus turicata)、柏氏禽刺 虫茜(Ornithonyssus bacoti)、耳殘嗓碑(Otobius megnini)、雞 皮刺瞒(Dermanyssus gallinae)、羊癢蜗(Psoroptes ovis)、 血紅扇頭蜱(Rhipicephalus sanguineus)、具尾扇頭蜱 (Rhipicephalus appendiculatus)、外翻扇頭蜱(Rhipicephalus evertsi)、济蜗(Sarcoptes scabiei)及癭蜗科種類(Eriophyidae spp·),例如蘋刺癭瞒(Aculus schlechtendali)、橘鏽蜗 (Phyllocoptrata oleivora)及柑芽癭蠕(Eriophyes sheldoni); 樹線瞒科種類(Tarsonemidae spp·),例如仙客來細蜗 (Phytonemus pallidus)及多食附線蜗(Polyphagotarsonemus latus);細須蜗科種類(Tenuipalpidae spp·),例如紫偽葉蜗 (Brevipalpus phoenicis);葉蜗科種類(Tetranychidae spp.),例如朱砂葉蜗(Tetranychus cinnabarinus)、神澤氏 葉蜗(Tetranychus kanzawai)、太平洋紅葉蹒(Tetranychus paciflcus)、棉紅葉蜗(Tetranychus telarius)及棉葉蜗 (Tetranychus urticae)、蘋果全爪瞒(Panonyclius ulmi)、橘 全爪蜗(Panonychus citri)及草地小爪瞒(oligonychus pratensis);虫知 蛛目(Araneida),例如黑寡婦物蛛(Latrodectus mactans)及 北美隱盾褐檢蛛(Loxosceles reclusa); 126151.doc -72- 200836619 蚤(蚤目(Siphonaptera)),例如貓櫛首蚤(Ctenocephalides felis)、犬櫛首蚤(Ctenocephalides canis)、印鼠客蚤(Xenopsylla cheopis)、人蚤(Pulexirritans)、穿皮潛蚤(Tunga penetrans)及 歐洲鼠蚤(Nosopsyllus fasciatus); 蠹蟲、家衣魚(纓尾目(Thysanura)),例如西洋衣魚 (Lepisma saccharina)及小灶衣魚(Thermobia domestica);Dermacentor variabilis, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicundus, Ixodes scapularis, full-ring hard palate (Ixodes holocyclus), Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata, Ornithonyssus Bacoti), Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, everted fan Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp., such as Aculus schlechtendali, Phyllocoptrata oleivora, and Eriophyes sheldoni Tree species (Tarsonemidae spp.), such as Phytonemus pallidus and Polyphagotarsonemus lat Us); Tenuipalpidae spp., such as Brevipalpus phoenicis; Tetranychidae spp., such as Tetranychus cinnabarinus, Tetranychus Kanzawai), Tetranychus paciflcus, Tetranychus telarius and Tetranychus urticae, Panonyclius ulmi, Panonychus citri, and grasshopper Oligonychus pratensis); Araneida, such as Latrodectus mactans and Loxosceles reclusa; 126151.doc -72- 200836619 Si (Siphonaptera), for example Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Pulexirritans, Tunga penetrans, and Nosopsyllus fasciatus; Aphids, house fish (Thysanura), such as Lepisma saccharina and Thermobia domestica;
娱4公(唇足綱(Chilopoda)),例如姑蜒(Scutigera coleoptrata); 千足轰(倍足綱(Diplopoda)),例如Narceus屬; 虫矍螋(革翅目(Dermaptera)),例如歐洲球螋(forficula auricularia);及 風(毛風目(Phthiraptera)),例如人頭蟲(Pediculus humanus capitis)、人體風(Pediculus humanus corporis)、 陰鼠(Pthirus pubis)、牛風(Haematopinus eurysternus)、緒 風(Haematopinus suis)、牛顎風(Linognathus vituli)、牛毛 風(Bovicola bovis)、雞羽乱(Menopon gallinae)、雞體乱 (Menacanthusstramineus)及牛管乱(Solenopotes capillatus); 線蟲,例如大豆異皮線蟲(Heterodera glycines)、燕麥異 皮線蟲(H. avenae)、甜菜異皮線蟲(Η· schachtii)、三葉草 異皮線蟲(Η· trifolii)、婉豆異皮線蟲(Η· gottingiana)、木 豆異皮線蟲(Η· cajani)、玉米異皮線蟲(Η· zeae)、馬鈴薯 金線蟲(Globodera rostochiensis)、馬钤薯白線蟲(G. pallida)、煙草線蟲(G. tabacum·)、落花生根瘤線蟲 (Meloidogyne arenaria)、南方根瘤線蟲(M. incognita)、爪 126151.doc -73- 200836619Entertainment 4 (Chilopoda), such as Aunt (Scutigera coleoptrata); Thousands (Diplopoda), such as the genus Narceus; worm (Dermaptera), such as the European ball For (forficula auricularia); and wind (Phthiraptera), such as Pediculus humanus capitis, Pediculus humanus corporis, Pthirus pubis, Haematopinus eurysternus, Haematopinus suis, Linognathus vituli, Bovicola bovis, Menopon gallinae, Menacanthusstramineus, and Solenopotes capillatus; nematodes, such as soybeans Heterodera glycines, H. avenae, H. schachtii, C. elegans (Η·trifolii), 婉·gottingiana, 木·gottingiana Nematode (Η·cajani), Heterodera elegans (Η zeae), Glododera rostochiensis, G. pallida, Tobacco nematode (G) Tabacum·), Meloidogyne arenaria, M. incognita, claw 126151.doc -73- 200836619
口圭根瘤線蟲(Μ· javanica)、北方根瘤線蟲(Μ· hapla)、馬鈴 薯根瘤線蟲(Μ· chitwoodi)、馬鈐薯莖線蟲(Ditylenchus destructor)、鱗球莖莖線蟲(D. dipsaci)、水稻莖線蟲(D· angustus)、小麥粒線蟲(Anguina tritici)、剪股穎粒線蟲(A· agrostis)、維氏粒線蟲(Afrina/Anguina wevelli)、穿刺短體 線蟲(Pratylenchus penetrans)、最短尾短體線蟲(P. brachyurus)、咖啡短體線蟲(P. coffeae)、玉米短體線蟲(P· zeae)、古德伊短體線蟲(P. goodeyi)、索氏短體線蟲(P. thornei)、傷殘短體線蟲(P. vulnus)、香蕉穿孔線嘉 (Radopholus similis)、水稻潛根線蟲(Hirschmanniella oryzae)、尖細潛根線蟲(Η· mucronata)、刺尾潛根線蟲(Η· spinicauda)、哥倫比亞紐帶線蟲(Hoplolaimus columbus)、 塞氏紐帶線蟲(H. seinhorsti)、印度紐帶線蟲(Η· indicus)、 腎形線蟲(Rotylenchulus reniformis)、柑橘半穿刺線蟲 (Tyienchulus semipenetrans) ' 多帶螺旋線蟲(Helicotylenchus multicinctus)、多帶螺旋線蟲(Η· multicinctus)、橫帶螺旋 線蟲(H· mucronatus)、雙宮螺旋線蟲(H· dihystera)、假強 壯螺旋線蟲(H. pseudorobustus)、Criconemella C. xenoplax axestis、C. spharocephalum 〇 可控制其他有害真菌。 此等真菌包括彼等來自子囊菌綱(Ascomycetes)、半知菌 綱(Deuteromycetes)、藻狀菌綱(Phycomycetes)及擔子菌綱 (Basidiomycetes)等綱者。具體實例包括在水果及蔬菜上之 鏈格孢屬(AlternaHa)種類、在草莓、蔬菜、觀賞植物及葡 126151.doc -74- 200836619Nematode worm (Μ·javanica), northern root nodule nematode (Μ·hapla), potato root nodule nematode (Μ·chitwoodi), Destlenchus destructor, D. dipsaci, rice stem Nematodes (D. angustus), Anguina tritici, A. agrostis, Afrina/Anguina wevelli, Pratylenchus penetrans, shortest tail short body Nematodes (P. brachyurus), P. coffeae, P. zeae, P. goodeyi, P. thornei, Endemic nematodes (P. vulnus), Radopholus similis, Hirschmanniella oryzae, Nematochaetes, cron·mucronata, ica· spinicauda , Hoplolaimus columbus, H. seinhorsti, Nematodes (Indica), Rotylenchulus reniformis, Tyienchulus semipenetran s) 'Helicotylenchus multicinctus, Helicobacter multicinctus, H. mucronatus, H. dihystera, H. pseudorobustus ), Criconemella C. xenoplax axestis, C. spharocephalum 〇 can control other harmful fungi. Such fungi include those from Ascomycetes, Deuteromycetes, Phycomycetes, and Basidiomycetes. Specific examples include Alterna Ha species on fruits and vegetables, in strawberries, vegetables, ornamental plants, and Portuguese 126151.doc -74-200836619
萄上之灰葡萄孢菌(Botrytis cinerea)(灰黴菌)、在花生上之 花生尾孢菌(Cercospora arachidicola)、在葫蘆上之二孢白 粉菌(Erysiphe cichoracearum)及單絲殼白粉菌 (Sphaerotheca fuliginea)、在穀物上之禾布氏白粉菌 (Blumeria graminis)(白粉菌)、在各種植物上之鐮孢菌黴屬 (Fusarium)及輪生菌屬(Verticillium)種類、在穀物上之長 螺孢菌屬(Helminthosporium)種類、在香蕉及花生上之球 腔菌屬(Mycosphaerella)種類、在馬鈴薯及番茄上之晚疫病 菌(Phytophthora infestans)、在葡萄上之霜黴病茵 (Plasmopara viticola)、在蘋果上之白叉絲單囊殼菌 (Podosphaera leucotricha)、在小麥及大麥上之眼斑病菌 (Pseudocercosporella herpotrichoides)、在蛇麻草及黃瓜上 之擬霜黴菌(Pseudoperonospora)種類、在穀物上之柄鏽菌 屬(Puccinia)種類、在水稻上之稻痕病菌(Pyricularia oryzae)、在棉花、水稻及草坪上之絲核菌屬(Rhizoctonia) 種類、在小麥上之穎枯殼針孢菌(Septoria nodorum)、在葡 萄上之葡萄白粉病菌(Uncimila necator)、在榖物及甘蔗上 之黑粉菌屬(Ustilago)種類及在蘋果及梨上之黑星菌屬 (Venturia)種類(黑星病)。 本發明裝置包括上述穩定結構及網眼織物。其可用於在 自播種或種植至收穫之整個時間段内覆蓋一或多株特別易 吸引某些害蟲之欲保護植物或僅在該等植物生長過程中之 某些階段内覆蓋該等植物。 該織物較佳為網狀物,因為網狀物不會干擾植物與其環 126151.doc -75- 200836619 境間空氣、濕度及光之交換, 蟲保護。 同時其仍可提供良好之抗害 令人驚奇地,即使在真菌性疾、忘 展病之t月形下使用網狀物亦 可達成良好保護。 藉由以下實例進-步閣釋本發明而非由此限制本發明。 實例 黏結劑:Botrytis cinerea (Botrytis cinerea), Cercospora arachidicola on peanuts, Erysiphe cichoracearum and Sphaerotheca fuliginea on gourd ), Blumeria graminis (white powder fungus) on cereals, Fusarium and Verticillium species on various plants, and spirochetes on cereals Species of Helminthosporium, Mycosphaerella species on bananas and peanuts, Phytophthora infestans on potatoes and tomatoes, Plasmopara viticola on grapes, Podosphaera leucotricha on apple, Pseudocercosporella herpotrichoides on wheat and barley, Pseudoperonospora on hops and cucumber, rust on grain Species of Puccinia, Pyricularia oryzae on rice, Rhizoctonia on cotton, rice and lawn ) species, Septoria nodorum on wheat, Uncimila necator on grapes, Ustilago on sugar and sugar cane, and apples and pears The species of the genus Ventura (black star disease). The device of the present invention comprises the above-described stabilizing structure and mesh fabric. It can be used to cover one or more plants that are particularly susceptible to attracting certain pests during the entire period from seeding or planting to harvesting or to cover the plants only during certain stages of their growth. The fabric is preferably a mesh because the mesh does not interfere with the exchange of air, humidity and light between the plant and its ring, worm protection. At the same time, it still provides good resistance. Surprisingly, good protection can be achieved even in the case of fungal diseases and t-months. The invention is illustrated by the following examples without restricting the invention. Example Bonding agent:
A)聚合物分散液之製備 一般程序: 將250克水及3克具有30奈米中等粒徑之苯乙烯晶種(33 重量%)加熱至85°C並添加5重量%之進料2。在10分鐘後, 開始添加包含下述單體之進料1及進料2。 進料2包含溶於39.9克水中之3.0克過二硫酸鈉。 進料1之組成列於表1中。 在3小時内添加進料1及2,並再聚合0·5小時。A) Preparation of polymer dispersion General procedure: 250 g of water and 3 g of styrene seeds (33 wt%) having a medium particle size of 30 nm were heated to 85 ° C and 5 wt% of feed 2 was added. After 10 minutes, feed 1 and feed 2 containing the following monomers were added. Feed 2 contained 3.0 grams of sodium peroxodisulfate dissolved in 39.9 grams of water. The composition of Feed 1 is listed in Table 1. Feeds 1 and 2 were added over 3 hours and re-polymerized for 0.5 hours.
126151.doc -76- 200836619126151.doc -76- 200836619
长<(ιιΐ^00ΙΑ#φ>)日 -嘀滅 w It:f/: BMA- Acac ο 卜 CO o 守 y— 1 C σ> τ— CO t— ω < q τ— CO c> 寸 CD in d CO d CO d CO d in d C\j i— cq d o cvi τ- Ο d in t— q q q < ο cvi eg T— LO d in d LO d q t— 寸 d 卜 d CM d AMol _1 〇 CO o CO MaMol in CO l〇 CO i〇 CO O cd o CO O CNJ GMA ιο CO o HPMA in cvi in c\i o CO 25 20.0 σ> CO 15.3 15.3 50.0 卜」 ㈣ ω 65.0 60.0 30.0 60.0 70.0 ㈣ 44.5 60.0 23.0 23.0 25.5 25.5 60.0 55.0 57.0 68.0 81.0 EHA 'r- CO CO iri 30.0 CO to ㈣ z < ㈣ o od o GO 11^ o od 13.0 13.0 16.0 ω o tri 16.6 o lO 14.7 13.0 13.0 20.0 20.0 100J 10.0J 10.0 20.0 MMA ^°J 23.9 130.0 | [30.0」 33.0 20.0 [20.0 I 110.0 10.0 [26.0 ! 15.0 單體組合物 < CM < CO < 寸 < in < CO < A7 00 < σ> < A 10 A11 A12 A13 A14 A 15 A16 A17 126151.doc -77- 200836619 相對於1 00重量份數之表1單體組合物,起始劑過二硫酸 鈉的量係0.3重量份數,乳化劑包括0.4重量份數之Dowfax 2A1 (Dow)及 0·6重量份數之Lumiten IRA (BASF AG)。 縮寫. MMA : 甲基丙烯酸甲酯 S : 苯乙烯 AN · 丙稀猜 EA : 丙稀酸乙酯Long <(ιιΐ^00ΙΑ#φ>) Day-annihilation w It:f/: BMA- Acac ο 卜 CO o 守 y-1 C σ> τ—CO t— ω < q τ—CO c> CD in d CO d CO d CO d in d C\ji— cq do cvi τ- Ο d in t— qqq < ο cvi eg T— LO d in d LO dqt — inch d b d CM d AMol _1 〇CO o CO MaMol in CO l〇CO i〇CO O cd o CO O CNJ GMA ιο CO o HPMA in cvi in c\io CO 25 20.0 σ> CO 15.3 15.3 50.0 卜” (iv) ω 65.0 60.0 30.0 60.0 70.0 (4) 44.5 60.0 23.0 23.0 25.5 25.5 60.0 55.0 57.0 68.0 81.0 EHA 'r- CO CO iri 30.0 CO to (4) z < (d) o od o GO 11^ o od 13.0 13.0 16.0 ω o tri 16.6 o lO 14.7 13.0 13.0 20.0 20.0 100J 10.0J 10.0 20.0 MMA ^°J 23.9 130.0 | [30.0" 33.0 20.0 [20.0 I 110.0 10.0 [26.0 ! 15.0 Monomer Composition < CM < CO < Inch < In < CO < A7 00 < σ >< A 10 A11 A12 A13 A14 A 15 A16 A17 126151.doc -77- 200 836619 The amount of the initiator sodium peroxodisulfate is 0.3 parts by weight relative to 100 parts by weight of the monomer composition of Table 1, and the emulsifier comprises 0.4 parts by weight of Dowfax 2A1 (Dow) and 0.6 parts by weight. The number of Lumiten IRA (BASF AG). Abbreviation. MMA : Methyl methacrylate S : Styrene AN · Acrylic EA : Ethyl acrylate
EHA : 丙烯酸2-乙基己酯 BA : 丙烯酸正丁酯 F1 : 具有丙烯酸基之可共聚二苯甲酮 GMA : 甲基丙烯酸縮水甘油酯 BMA-Acac : 丁二醇單丙烯酸酯乙醯乙酸酯EHA : 2-ethylhexyl acrylate BA : n-butyl acrylate F1 : copolymerizable benzophenone with acrylic acid GMA : glycidyl methacrylate BMA-Acac : butanediol monoacrylate acetamidine acetate
Amol : N-經甲基丙烯醯胺 MAMol : N_羥曱基甲基丙烯醯胺 HPMA : 甲基丙烯酸羥丙基酯 AS: 丙烯酸 AM : 丙烯醯胺Amol : N-methacrylamide amide MAMol : N-hydroxymethyl methacrylamide HPMA : Hydroxypropyl methacrylate AS: Acrylic AM : Acrylamide
Dowfax 2A1:Dowfax 2A1:
126151.doc -78 - 200836619126151.doc -78 - 200836619
Lumiten IRA:Lumiten IRA:
實例A1及A8 包含Fl-1可聚合光起始劑之水性聚合物分散液,FI-1可 聚合光起始劑隨後用作交聯劑且係下式之光起始劑:Examples A1 and A8 comprise an aqueous polymer dispersion of a Fl-1 polymerizable photoinitiator, and the FI-1 polymerizable photoinitiator is subsequently used as a crosslinking agent and is a photoinitiator of the formula:
其中 r8係具有1至3 0個碳原子之有機基; R9 係Η或甲基;且 R10係視情況經取代之苯基或C〗-至C4-烷基。Wherein r8 is an organic group having 1 to 30 carbon atoms; R9 is a hydrazine or a methyl group; and R10 is optionally substituted phenyl or C- to C4-alkyl.
用途實例 用實例A17之水性分散液對之前未洗滌之市售白色聚酯 網狀材料(纖維纖度75丹尼爾,156網目,重量28-32克/米2) 實施殺蟲劑處理。水性處理浴藉由以下製備··將水性分散 液與市售殺蟲劑及/或驅蟲劑之乳液混合,用緩衝溶液調 節pH值並(若需要)添加固定劑。根據可能之吸液率(LU* 於60與100%之間)調節該等處理浴之濃度。藉由使用實驗 至規模之浸染機-拉幅機設備(Mathis AG,Switzerland)施 加該等處理浴。將該網狀材料完全浸於處理浴中並將過量 126151.doc -79- 200836619 液體藉由使該網狀材料通過反向運動之圓筒移除。可藉由 選擇該等圓筒間之規定距離(並因此選擇規定壓力)控制吸 液率。吸液率藉由稱重網狀物之浸潰片並減去乾燥未處理 網狀物片之重量量測,並以液體重量對網狀物重量之%终 出。乾燥/固化步驟在容許控制處理溫度及時間之實驗室 拉幅機中實施。 ‘ 為在實驗室生物分析中處理昆蟲,將浸潰有殺蟲劑之持 馨 久殺蟲網狀物(LLIN,@ 200毫克有效成份/米2)剪切至適人 陪替氏(petri)培養皿。將網狀物置於培養皿之底部並將1〇 隻昆蟲引入位於網上之每個培養皿中。在處於試驗條件後 數分鐘、數小時及(可能)數天時對死亡率/垂死率予以評 估。重複次數取決於所測試之處理次數。 對於野外試驗,端視作物類型可利用數種方法。方法〇 至e)係典型實例: a) 將上述持久殺蟲網狀物直接鬆散地置於甘藍菜之苗床 〇 上並使其沒有被風移動之危險。光、空氣及水可自由到達 植物。植物發芽及生長可使網狀物升高,但並不限制生 長。 在收穫之前記錄典型害蟲之滋生並與在未保護之苗床上 — 生長之植物及在未處理之網下生長之植物的值進行比較。 b) 以使上述持久殺蟲網狀物可覆蓋全部植物之方式將該 4網狀物置於用於栽培番茄植物之杆上。光、空氣及水可 自由到達該等番茄植物。 在收穫之前記錄典型害蟲之滋生並與在未實施保護下及 126151.doc -80- 200836619 在未處理之網保護下生長之植物的值進行比較。 C)將^述持久殺蟲網狀物置於木製支擇框架上以覆蓋栽 培有草莓植物之苗庆。杏扣片 床先、二氣及水可自由到達植物。 :收穫之前記錄典型害蟲之滋生並與在未實施保護下及 未處理之網保護下生長之植物的值進行比較。 句將在煙草苗圃中之煙草植物置於覆蓋有上述持久殺蟲 難物之金屬絲框架下。光、m水可自由到達植物。Use Example An aqueous dispersion of the commercially available white polyester web material (fiber denier 75 denier, 156 mesh, weight 28-32 g/m 2 ) which had not been previously washed was subjected to the insecticide treatment using the aqueous dispersion of Example A17. The aqueous treatment bath is prepared by mixing an aqueous dispersion with a commercially available emulsion of an insecticide and/or an insect repellent, adjusting the pH with a buffer solution, and if necessary, adding a fixing agent. The concentration of the treatment baths is adjusted according to the possible aspiration rate (LU* between 60 and 100%). These treatment baths were applied by using an experimental to scale dip dyeing machine - tenter apparatus (Mathis AG, Switzerland). The web material is completely immersed in the treatment bath and the excess 126151.doc -79 - 200836619 liquid is removed by passing the web material through a counter-moving cylinder. The rate of liquid absorption can be controlled by selecting a predetermined distance between the cylinders (and thus selecting a prescribed pressure). The rate of liquid absorption is determined by weighing the impregnated web of the web and subtracting the weight of the dried untreated web and by the weight of the liquid against the weight of the web. The drying/curing step is carried out in a laboratory tenter that allows control of the processing temperature and time. ' To process insects in laboratory bioassays, cut the insect-carrying chlorpyrifos network (LLIN, @200 mg active ingredient/m 2 ) to a suitable petri Petri dish. The mesh was placed at the bottom of the dish and 1 insect was introduced into each dish on the web. Mortality/dying rates were assessed at minutes, hours, and (possibly) days after the test conditions. The number of repetitions depends on the number of treatments tested. For field trials, several methods are available for end-point crop types. Method 〇 to e) is a typical example: a) The above-mentioned persistent insecticidal mesh is loosely placed directly on the seedling bed of the cabbage and is not at risk of being moved by the wind. Light, air and water are free to reach plants. Plant germination and growth can increase the net, but does not limit growth. The growth of typical pests was recorded prior to harvest and compared to the values of plants grown on unprotected seedbeds and plants grown under untreated nets. b) placing the 4 mesh on a rod for cultivating a tomato plant in such a manner that the above-mentioned persistent insecticidal mesh can cover all of the plants. Light, air and water are free to reach these tomato plants. The growth of typical pests was recorded prior to harvest and compared to the values of plants grown under unprotected protection and under 126151.doc -80-200836619 under unprotected net protection. C) Place the persistent insecticidal mesh on a wooden support frame to cover the seedlings of the strawberry plant. Apricot Buckle The bed, the second gas and the water are free to reach the plants. : The breeding of typical pests was recorded prior to harvest and compared to the values of plants grown under unprotected and untreated nets. The tobacco plants in the tobacco nursery are placed under a wire frame covered with the above-mentioned persistent insecticide. Light and m water can reach plants freely.
•’彔轴之滋生並與未實施未處理之網保護之植物 的值進行比較。 e)將±述持久殺蟲網狀物置於即將開花之頻果樹上。 光、空氣及水可自由到達該等樹。 穫之别°己錄典型害蟲之滋生並與在未實施保護下及 在未處理之網保護下生長之植物的值進行比較。• The growth of the 'axis is compared to the value of plants that have not been treated with untreated nets. e) Place the ± persistent insecticidal mesh on the fruit tree that is about to bloom. Light, air and water are free to reach these trees. The unique pests have been recorded and compared to the values of plants grown under unprotected and protected under untreated nets.
126151.doc 81-126151.doc 81-
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CN (1) | CN101534632A (en) |
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