TW200819496A

TW200819496A - Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor

Info

Publication number: TW200819496A
Application number: TW096125089A
Authority: TW
Inventors: Emmett Dudley Crawford
Original assignee: Eastman Chem Co
Priority date: 2006-10-27
Filing date: 2007-07-10
Publication date: 2008-05-01
Also published as: WO2008051320A1; WO2008051321A1; WO2008054560A2; CA2666571A1; BRPI0717761A2; CA2666585A1; WO2008054559A1; KR20090079211A; BRPI0717755A2; WO2008051321A8; JP2010507716A; WO2008054560A3; KR20090079212A; TW200819497A; MX2009003375A; EP2074158A1; MX2009003369A; JP2010507717A; EP2074174A1

Abstract

Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 90 to about 100 mole% of terephthalic acid residues; (ii) about 0 to about 10 mole% of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a glycol component comprising: (i) about 1 to less than 90 mole% 2,2,4,4-tetramethyl-l ,3-cyclobutanediol residues; and (ii) about 0 to about 89 mole% cyclohexanedimethanol residues; (iii) greater than 10 mole% ethylene glycol residues, and (iv) less than about 2 mole% of a modifying glycol having from 3 to 16 carbon atoms; (c) titanium atoms and phosphorus atoms, wherein the total mole% of the dicarboxylic acid component is 100 mole%, and wherein the total mole% of the glycol component is 100 mole%; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 DEG C. The polyesters may be manufactured into articles.

Description

200819496 九、發明說明：【發明所屬之技術領域】本發明一般而言係關於具有高伊佐德氏缺口衝擊強度 (notched IZ0d impact strength)、特定玻璃轉移溫度特定固有黏度、撓曲模數、良好透明度及良好色彩中之兩者或兩者以上之某種組合之由對苯二甲酸或其g旨及直混合 =、2,2,4,4_四甲mm、乙三醇及視情況之μ· 環己烧二甲醇所製成之聚醋組合物或化學等效物，該等組 ( 合使其易成形為物品，例如熱成型薄片及薄膜應用。【先前技術】〜 ( 某些商用聚合物(諸如雙酚A聚碳酸酯)具有熱成型薄膜及薄片所需之玻璃轉移溫度及伊佐德氏缺口衝擊強度，但據信需要在熱成型之前進行乾燥。據信其他商用聚合物 (諸如丙烯酸系物及某些抗衝擊改質之丙烯酸系物）具有熱成型薄膜及薄片所需之玻璃轉移溫度，且據信無需在熱成型之前進行乾燥；然而，據信其具有通常小於2行_版之室溫伊佐德氏缺口衝擊強度，此通常不利於某此最終用途應用。因此，商業上需要_種聚合物材料，其具有使直有利地用於某些應用(例如熱成型薄膜及薄片應用)之特性组該特性組合包括高伊佐德氏缺口衝擊強度、特定玻璃，移溫度⑹、特定固有黏度、特定撓曲模數、良度及良好色彩中之兩者或兩者以上之組合。二:=广需要一種聚合物材料，其具有使其有利地用於某二應用(例如熱成型薄膜及薄片應用)之特性組合，該 122661.doc 200819496 特性組合包括高伊佐德氏缺口衝擊強度、特定玻璃轉移温度（Tg)、特定固有黏度、特定撓曲模數、良好透明度及良好色彩中之三者或三者以上之組合。據信錫基催化劑可使2,2,4,4-四甲基環丁二醇有效地併入聚醋中。然而’據信在乙二醇存在下，錫基催化劑可使得產生黃色至琥耗之聚g旨。據報導，鈦基催化劑無法使2’2,4,4-四甲基_：ι，3_環丁二醇有效地併入聚酯中。參見 Kelsey 專人，Macromolecules 2000，5810。此外’在-實施例中’此項技術中需要包含2,2,4,4·四甲基-1，3-環丁二醇、乙二醇及視情況之環己烷二甲醇之具有良好色彩及/或良好透明度之聚§旨及製備該等聚醋之方法。 L) 此外，在-實施例中，此項技術中需要一種更易於產4 本發明之聚酯而無以下至少一種現象發生之方法：起泡、形成斜面、形成色彩、發泡、放出廢氣及熔體含量不穩芳 (亦即聚醋或聚醋之產生及處理系統之波動)。此項技則亦需要—種更易於大量（例如料生產規模及/或商業性当產）產生本發明之聚酿而無上述至少-種困難發生之；5 法。【發明内容】據信，由對苯二甲酸、i • /、-曰及/或其混合物、乙二醇、 2,2,4,4-四甲基-1，3-環丁-辦贫、目、主衣丁一知及視,丨月況之環己烷二甲形成之包含某些熱穩定卞甘c & 士 ^疋Μ、其反應產物及其混合物之某止」 5^酉旨組合物在高 >(尹佐_ /' 德氏缺口衝擊強度、特定玻璃轉移活 122661.doc 200819496 度⑹、特定固有黏度、良好透明度、良好色彩及曲模數中之-或多個方面優於某些商用聚合物。 & 在本發明之某些實施例中’本發明之某些聚醋及醋組合物在高伊佐德氏缺口衝擊強度、特定固有黏声、转定玻璃轉移溫度(Tg)、特定撓曲模數、良好透明度及良好色彩中之兩者或兩者以上之組合方面優於某些商用‘合物0 〇200819496 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention generally relates to having high Izod impact strength, specific glass transition temperature, specific intrinsic viscosity, flexural modulus, and good transparency. And some or a combination of two or more of good color, terephthalic acid or its g and straight mixing =, 2, 2, 4, 4_tetramethyl, glycerol and optionally μ • Polyurethane compositions or chemical equivalents made from cyclohexane dimethanol, which are easy to form into articles such as thermoformed sheets and films. [Prior Art] ~ (Some Commercial Polymerizations Materials such as bisphenol A polycarbonate have glass transition temperatures and Izod notched impact strengths required for thermoformed films and sheets, but it is believed that drying is required prior to thermoforming. Other commercial polymers (such as acrylic acid) are believed to be acceptable. The system and certain impact-modified acrylics have glass transition temperatures required for thermoforming films and sheets, and it is believed that drying is not required prior to thermoforming; however, it is believed to have Room temperature Izod notched impact strength in 2 lines, which is generally not conducive to some end use applications. Therefore, there is a need in the world for polymeric materials that have a direct advantage for certain applications (eg, heat). Characterization of the formed film and sheet application The combination of characteristics includes high Izod notched impact strength, specific glass, shifting temperature (6), specific intrinsic viscosity, specific flexural modulus, goodness, and good color. Combination of the above. Two: = a broad need for a polymer material having a combination of properties that make it advantageous for use in a second application, such as thermoformed film and sheet applications, the 122661.doc 200819496 characteristic combination including High Izod Combination of notched impact strength, specific glass transition temperature (Tg), specific intrinsic viscosity, specific flexural modulus, good transparency, and good color. It is believed that tin-based catalysts can make 2, 2, 4 4-Tetramethylcyclobutanediol is effectively incorporated into the vinegar. However, it is believed that in the presence of ethylene glycol, the tin-based catalyst can produce a yellow to a sulphate. It is reported that titanium-based The agent was unable to effectively incorporate 2'2,4,4-tetramethyl-:ι,3-cyclobutanediol into the polyester. See Kelsey, Macromolecules 2000, 5810. Also in the 'in the examples' Techniques requiring good color and/or good transparency of 2,2,4,4·tetramethyl-1,3-cyclobutanediol, ethylene glycol and, optionally, cyclohexanedimethanol. Further, in the embodiment, there is a need in the art for a method which is easier to produce the polyester of the present invention without at least one of the following phenomena: foaming, forming a bevel Forming color, foaming, releasing exhaust gas and unstable melt content (that is, fluctuations in the production and processing system of polyester or polyester). This technique also requires that it is easier to produce a large amount of material (e.g., scale of production and/or commercial production) of the present invention without at least the above-mentioned difficulties; SUMMARY OF THE INVENTION It is believed that terephthalic acid, i • /, —曰 and/or mixtures thereof, ethylene glycol, 2,2,4,4-tetramethyl-1,3-cyclobutane-poor目,目,主衣丁一知 and 视, 丨况之环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环环The composition is in the high > (Yin Zuo _ / 'D's notched impact strength, specific glass transfer activity 122661.doc 200819496 degrees (6), specific intrinsic viscosity, good transparency, good color and modulus number - or aspects Better than certain commercial polymers. & In certain embodiments of the present invention, certain of the polyester and vinegar compositions of the present invention have high Izod's notched impact strength, specific intrinsic viscous sound, and converted glass transition temperature. (Tg), a combination of two or more of a specific flexural modulus, good transparency, and good color is superior to some commercial 'compounds'

在本發明之某些實施例中，本發明之某些聚酯及/或聚酯組合物在高伊佐德氏缺口衝擊強度、特定固有黏度、特定玻璃轉移溫度(Tg)、特定撓曲模數、良好透明度：良好色形中之二者或三者以上方面優於某些商用聚合物。在本發明之某些實施你】中，纟發明t某些聚醋及/或聚酯組合物在高伊佐德氏缺口衝擊強度、特定固有黏度、特定玻璃轉移溫度（Tg)、特定撓曲模數、良好透明度:良好色彩中之四者或四者以上之組合方面優於某些商用聚合物。在本發明之其他實施例中，本發明之某些聚酯及/或聚酯組合物在所有以下特性之組合方面均優於某些商用聚合物：高伊佐德氏缺口衝擊強度、特定固有黏度、特定破螭轉移溫度（Tg)、特定撓曲模數、良好透明度及良好色彩。在一實施例中，含有2,2,4,4-四甲基-1,3-環丁二醇及乙二醉之共聚酯可由鈦基催化劑來製備。在另一實施例中，除鈦基催化劑以外，亦可藉由使用錫基催化劑進一步改良 2,2,4,4-四甲基- l，3-環丁二醇之併入。據信該等共聚酯之 122661.doc 200819496 色彩可經由在聚合反應期間添加特定含量之含鱗化合物而得以改良。在一實施例中，據信當在製備本發明聚酯之製程期間使用本文所述之至少-種鱗化合物時，可更易於產生聚醋而無至少一種以下現象發生：起泡、形成斜面、形成色彩、發泡、排出廢氣及熔體含量不穩定（亦即聚酯或聚酯之產生及處理系統之波動）。在另一實施例中，據信本發明之至少一種方法提供更易於大量（例如先導生產規模及/或商業性生產）產生適用於本發明之聚酯的方式而無至少一種上述困難發生。如本文所用之術語，，大量”包括以大於1〇〇磅之ΐ產生之適用於本發明之聚酯的量。在一實施例中，如本文所用之術語”大量”包括以大於1〇〇〇磅之量產生之適用於本發明之聚S旨的量。在一態樣中，製備適用於本發明之聚酯之方法可包含分批法或連續法。在一態樣中’製備適用於本發明之聚酯之方法包含連續 I 法。在一態樣中，本發明係關於包含至少一種聚酯之聚酯組合物，該聚酯包含： 0)二羧酸組份，其包含： (0約90至約100莫耳％之對苯二甲酸殘基； (11)約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b)二醇組份，其包含： 122661.doc -10- 200819496 ⑴約1至小於90莫耳％之2,2,4,4-四甲基二醇殘基；及 (i〇約〇至約89莫耳％之環己烷二甲醇殘基； (in)大於丨〇莫耳％之乙二醇殘基，及 (1V)小於約2莫耳％之具有3至16個碳原子之改質性二醇； (c)鈦原子及磷原子，· 其中二羧酸組份之總莫耳％為1〇〇莫耳％，且其中二醇組份之總莫耳％為1 〇〇莫耳％ ;且 /、中如於25C下，在濃度為0·25 g/5〇 ml26〇/4〇(重量比）酚/ 四氯乙烷中所測定，聚酯之固有黏度為〇.5〇至12乩^。在一態樣中，本發明係關於包含至少一種聚酯之聚酯組合物，該聚酯包含： (a) 二羧酸組份，其包含： (1)約90至約1〇〇莫耳％之對苯二曱酸殘基； (ii)約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約20至約40莫耳〇/〇之2,2,4,4_四曱基環丁二醇殘基；及 (ii) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； 122661.doc -11- 200819496 (c)鈦原子及鱗原子；且其中二醇組份其中二羧酸組份之總莫耳％為100莫耳％，之總莫耳％為1 00莫耳％ ;且其:如於2rc下，在濃度狀25 g/5G加之_(重量比）紛/ 四風乙烧中所測定，㈣之固有黏度為^⑴2心。在-態樣中，本發明係關於包含至少—種聚g旨之聚g旨組合物，該聚酯包含： (a) 二羧酸組份，其包含：In certain embodiments of the invention, certain polyester and/or polyester compositions of the invention have high Izod notched impact strength, specific intrinsic viscosity, specific glass transition temperature (Tg), specific flexural modulus Good transparency: Two or more of good color shapes are superior to certain commercial polymers. In certain embodiments of the present invention, the invention has certain high viscosity and specific intrinsic viscosity, specific glass transition temperature (Tg), specific flexural mode of certain polyester and/or polyester compositions. Number, good transparency: Four or more combinations of good colors are superior to certain commercial polymers. In other embodiments of the invention, certain polyester and/or polyester compositions of the present invention are superior to certain commercial polymers in all of the following combinations of properties: high Izod notched impact strength, specific intrinsic viscosity , specific break transfer temperature (Tg), specific flexural modulus, good transparency and good color. In one embodiment, the copolyester containing 2,2,4,4-tetramethyl-1,3-cyclobutanediol and ethylene dilute can be prepared from a titanium-based catalyst. In another embodiment, in addition to the titanium-based catalyst, the incorporation of 2,2,4,4-tetramethyl-l,3-cyclobutanediol can be further improved by the use of a tin-based catalyst. It is believed that the color of the copolyesters 122661.doc 200819496 can be improved by the addition of specific levels of scaly compounds during the polymerization. In one embodiment, it is believed that when at least the scaly compound described herein is used during the preparation of the polyester of the present invention, the vinegar can be more readily produced without at least one of the following phenomena: blistering, beveling, Forming color, foaming, exhaust gas, and melt content are unstable (ie, fluctuations in the production and processing of polyester or polyester). In another embodiment, it is believed that at least one of the methods of the present invention provides a means for producing a polyester suitable for use in the present invention that is more readily available (e.g., by a pilot production scale and/or commercial production) without at least one of the above difficulties occurring. As used herein, the term "a large amount" includes the amount of polyester suitable for use in the present invention produced in greater than one pound. In one embodiment, the term "mass" as used herein includes greater than one inch. The amount of the pounds produced is the amount suitable for the present invention. In one aspect, the method of preparing the polyester suitable for use in the present invention may comprise a batch process or a continuous process. The process of the polyester of the present invention comprises a continuous process I. In one aspect, the invention is directed to a polyester composition comprising at least one polyester comprising: 0) a dicarboxylic acid component comprising: (0 about 90 to about 100 mole % terephthalic acid residues; (11) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 2 carbon atoms And (b) a diol component comprising: 122661.doc -10- 200819496 (1) from about 1 to less than 90 mol% of a 2,2,4,4-tetramethyl diol residue; and (i)约约约约89摩尔% cyclohexanedimethanol residue; (in) an ethylene glycol residue greater than 丨〇 mol%, and (1V) less than about 2 mol% of having 3 to 16 carbons original a modified diol; (c) a titanium atom and a phosphorus atom, wherein the total molar % of the dicarboxylic acid component is 1 〇〇 mol %, and wherein the total molar % of the diol component is 1 〇〇mol%; and /, in the case of 25 ° C, at a concentration of 0. 25 g / 5 〇 ml 26 〇 / 4 〇 (by weight) phenol / tetrachloroethane, the inherent viscosity of the polyester is一.5〇至12乩^ In one aspect, the invention relates to a polyester composition comprising at least one polyester comprising: (a) a dicarboxylic acid component comprising: (1) From about 90 to about 1 mole percent of a terephthalic acid residue; (ii) from about 0 to about 10 mole percent of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms And (b) a diol component comprising: (1) from about 20 to about 40 moles per mole of 2,2,4,4-tetradecylcyclobutanediol residues; and (ii) about 20 Up to about 40 mole % of cyclohexanedimethanol residue; (iii) ethylene glycol residue, and (iv) less than about 2 mole % of a modified diol having from 3 to 16 carbon atoms; .doc -11- 200819496 (c) titanium atom and squamous atom; and wherein the diol component is the total molar of the dicarboxylic acid component 100% by mole, the total molar % is 100% by mole; and: as in 2rc, measured in the concentration of 25 g/5G plus _ (weight ratio) / four winds in the burning, (four) The intrinsic viscosity is ^(1)2. In the aspect, the present invention relates to a composition comprising at least a polyg-glycol comprising: (a) a dicarboxylic acid component comprising:

(0約90至約1〇〇莫耳％之對苯二甲酸殘基； ⑴）約0至約10莫耳％之具有至多20個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約20至約4〇莫耳％之2,2,4,4-四甲基環丁二醇殘基；及 (ii) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及 (iv) 小於約2莫耳。/。之具有3至16個碳原子之改質性二醇； (c)鈦原子及磷原子；其中二羧酸組份之總莫耳％為1〇〇莫耳％，且其中二醇組份之總莫耳％為100莫耳％ ; 其中如於25 C下，在濃度為〇·25 g/50 ml之60/40(重量比）酚/ 四氯乙烧中所測定，聚酯之固有黏度為〇5〇至12 dL/g ;且視情況地’其中在聚酯之聚合反應之前及/或期間添加至 122661.doc -12- 200819496 少一種分枝劑。在L樣中，本發明係關於包含至少一種聚酯之聚酯組? 合物，該聚自旨包含： (a) 二羧酸組份，其包含： (I) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (II) 約0至約1〇莫耳％之具有至多20個碳原子之芳族及/或知族二魏酸殘基；及 (b) 二醇組份，其包含： (I) 約20至約40莫耳％之2,2,4,4-四甲基β1，3_環丁二醇殘基；及 (II) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； (c) 鈦原子及磷原子；其中二羧酸組份之總莫耳％為1〇〇莫耳％，且其中二醇組份之總莫耳％為100莫耳％ ; 其中如於25C下，在濃度為〇·25 g/50 ml之60/40(重量比）酚/ 四氯乙烷中所測定，聚酯之固有黏度為〇.5〇至12 dL/g ;且其中聚自曰具有至少一種選自以下特性之特性：約i〇〇。〇至約 110 C 之 Tg(如由 TA 2100 Thermal Analyst Instrument 以 20 C/min之掃描速率所量測）；在23它下等於或大於 290,000 psi之撓曲模數（如由ASTM 〇79〇所定義”及等於或大於10 ft-lb/in之伊佐德氏缺口衝擊強度（在23。〇下，以 122661.doc -13- 200819496 使用1/8忖厚棒之l〇密耳（mil)缺口，根據ASTm D256所測定）。在一態樣中，本發明係關於聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 一竣酸組份，其包含： (i)約9〇至約100莫耳％之對苯二甲酸殘基； (π)約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及(0 about 90 to about 1 mole % terephthalic acid residue; (1)) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms And (b) a diol component comprising: (1) from about 20 to about 4 mole % of 2,2,4,4-tetramethylcyclobutanediol residues; and (ii) from about 20 to about 40 mole % cyclohexane dimethanol residue; (iii) ethylene glycol residue, and (iv) less than about 2 moles. /. a modified diol having 3 to 16 carbon atoms; (c) a titanium atom and a phosphorus atom; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and wherein the diol component is The total molar % is 100% by mole; wherein, as in 25 C, the inherent viscosity of the polyester is determined in 60/40 (by weight) phenol/tetrachloroethane at a concentration of 〇·25 g/50 ml. It is from 5 〇 to 12 dL/g; and optionally, one of the branching agents is added to 122661.doc -12-200819496 before and/or during the polymerization of the polyester. In the L-form, the present invention relates to a polyester composition comprising at least one polyester comprising: (a) a dicarboxylic acid component comprising: (I) from about 90 to about 1 Torr. Mole % of terephthalic acid residues; (II) from about 0 to about 1 mole % of aromatic and/or genomic diwei acid residues having up to 20 carbon atoms; and (b) diol a component comprising: (I) from about 20 to about 40 mole % of a 2,2,4,4-tetramethyl β 1,3 -cyclobutanediol residue; and (II) from about 20 to about 40 moles 5% by weight of cyclohexanedimethanol residue; (iii) ethylene glycol residue, and (iv) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; (c) titanium atom And a phosphorus atom; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and wherein the total molar % of the diol component is 100 mol%; wherein, at 25 C, the concentration is 〇 · The intrinsic viscosity of the polyester is 〇.5〇 to 12 dL/g as determined in 60/40 (weight ratio) phenol/tetrachloroethane of 25 g/50 ml; and wherein the poly(R) has at least one selected from the group consisting of Characteristics of the following characteristics: about i〇〇. 〇 to a Tg of about 110 C (as measured by a TA 2100 Thermal Analyst Instrument at a scan rate of 20 C/min); at 23 it is a deflection modulus equal to or greater than 290,000 psi (as by ASTM 〇79〇) Definition" and Izod's notched impact strength equal to or greater than 10 ft-lb/in (at 23 〇, to 122661.doc -13-200819496 using 1/8 忖 thick rod l mil mil gap In accordance with ASTM D256. In one aspect, the invention is directed to a polyester composition comprising: (I) at least one polyester comprising: (a) a decanoic acid component comprising: i) from about 9 〇 to about 100 mol% of terephthalic acid residues; (π) from about 0 to about 1 mol% of aromatic and/or aliphatic dicarboxylic acids having up to 2 carbon atoms Residue;

(b) 二醇組份，其包含： ⑴約2〇至約40莫耳％之2,2,4,4-四甲基·1，3·環丁二醇殘基；及 (ii) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； (c)鈦原子及碟原子；及 (Π)至少一種磷化合物，其係選自烷基磷酸酯、芳基磷酉文S曰、混合型烷基芳基磷酸酯、其反應產物及其混合物中之至少一者；其中二叛酸組份之總莫耳⑼莫耳％，且其中二醇組份之總莫耳％為1 〇〇莫耳％ ; 其中2,2,4,4-四百分數總和為耳％，且甲基-1，3-環丁二醇與環己烷二甲醇之莫耳二醇組份之總莫耳％之40莫耳％至小於7〇莫 122661.doc -14- 200819496 其中如於25C下，在濃度為〇·25 g/5〇 mi之60/4〇(重量比）酚/ 四氯乙烷中所測定，聚酯之固有黏度為〇 5〇至12 dL/g ; 其中聚酯具有至少一種選自以下特性之特性：約1〇〇。〇至約 110°c 之 Tg(如由 TA 2100 Thermal Analyst Instrument 以 2(TC/min之掃描速率所量測）；在23t：下等於或大於 290,000 pS1之撓曲模數（如由ASTM D79〇所定義）；及等於或大於10 ft-lb/in之伊佐德氏缺口衝擊強度（在23。〇下，以使用1/8吋厚棒之1〇密耳缺口，根據ASTM D256所測定）。在一態樣中，本發明係關於聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a)二羧酸組份，其包含： (I) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (η)約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b)二醇組份，其包含·· ⑴約2〇至約40莫耳％之2,2,4,4_四甲基。，弘環丁二醇殘基；及 (II) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； (匀視情況地，至少一種分枝劑； (II) 至少一種磷化合物，其係選自烷基磷酸酯、芳基磷酸酯、混合型烷基芳基磷酸酯、其反應產物及其混 122661.doc -15- 200819496 合物t之至少一者；及 (III)鈦原子及磷原子；且其中二醇組份其中二羧酸組份之總莫耳％為100莫耳％之總莫耳％為1 〇〇莫耳％ ; 其中2,2,4,4_四甲基_1，3 百分數總和為二醇組份耳％ ;且 -環丁二醇與環己燒二甲醇之莫耳之總莫耳％之4〇莫耳％至小於70莫(b) a diol component comprising: (1) from about 2 〇 to about 40 mol% of a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and (ii) about 20 to about 40 mole % of cyclohexanedimethanol residue; (iii) ethylene glycol residue, and (iv) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; (c) a titanium atom and a dish atom; and (Π) at least one phosphorus compound selected from the group consisting of alkyl phosphates, aryl phosphonium S曰, mixed alkyl aryl phosphates, reaction products thereof, and mixtures thereof At least one of them; the total molar amount of the two oxo-acid components (9) mol%, and wherein the total molar % of the diol component is 1 〇〇 mol%; wherein 2, 2, 4, 4- 4 The sum of the percentages is % of the ear, and the total mole % of the molar component of methyl-1,3-cyclobutanediol and cyclohexanedimethanol is from 40 mol% to less than 7〇122661.doc - 14- 200819496 Wherein the inherent viscosity of polyester is 〇5〇 to 12 as determined at 25C in 60/4〇 (by weight) phenol/tetrachloroethane at a concentration of 〇·25 g/5〇mi. dL/g; wherein the polyester has at least one property selected from the group consisting of about 1 Torr. 〇 to a Tg of about 110°c (as measured by the TA 2100 Thermal Analyst Instrument at 2 (TC/min scan rate); at 23t: equal to or greater than 290,000 pS1 of flexural modulus (eg by ASTM D79〇) And Izod's notched impact strength equal to or greater than 10 ft-lb/in (at 23 〇, using a 1/8 吋 thick rod of 1 mil nick, as determined by ASTM D256). In one aspect, the invention is directed to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: (I) from about 90 to about 1 Torr (0) about 0 to about 1 mole % of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and (b) a diol component comprising (1) from about 2 Torr to about 40 mole % of 2,2,4,4-tetramethyl., a cyclobutanediol residue; and (II) from about 20 to about 40 a molar % cyclohexane dimethanol residue; (iii) an ethylene glycol residue, and (iv) less than about 2 mole % of a modified diol having from 3 to 16 carbon atoms; At least one branching agent; (II) at least one phosphating And a compound selected from the group consisting of alkyl phosphates, aryl phosphates, mixed alkyl aryl phosphates, reaction products thereof, and at least one of the blends of 122661.doc -15-200819496; and (III) a titanium atom and a phosphorus atom; and wherein the total molar % of the diol component in which the total molar % of the dicarboxylic acid component is 100 mol% is 1 〇〇 mol %; wherein 2, 2, 4, 4 _ The sum of the tetramethyl-1,3 percentages is the diol component ear%; and the total molar amount of the molar amount of the cyclobutanediol and the cyclohexane-small dimethanol is from 4% to less than 70%.

，、中如於25C下，在/辰度為〇·25 g/5〇 mk6〇/4〇(重量比）盼/ 四氣乙烷中所測定，聚酯之固有黏度為〇5〇至^几仏。在悲樣中，本發明係關於一種包含以下步驟之方法： (I)在至少一種選自15CTC至25(rc之溫度下，在至少一種選自〇 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a) 二叛酸組份，其包含： (I) 約90至約100莫耳％之對苯二曱酸殘基； (II) 約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,4-四甲基·1，3· 環丁二醇殘基；及 (ii) 約0至約89莫耳％之環己烷二甲醇殘基； (iii) 大於10莫耳％之乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； 122661.doc -16- 200819496 其中步驟（i)中所添加耳比為 1.01-3.0/1 〇 · 其中步驟⑴中之混合物係於熱·· ⑴至夕冑包含至少_種鈦化合物之催化劑，及視情況之至少一種選自以下各物之催化劑：錫化合物、蘇化合物、鋅化合物、録化合物、铦化合In the case of 25C, the intrinsic viscosity of the polyester is 〇5〇 to ^ as determined by 〇·25 g/5〇mk6〇/4〇 (weight ratio)/four gas ethane. How many. In a sad manner, the invention relates to a process comprising the steps of: (I) heating at least one temperature selected from the group consisting of 15 CTC to 25 (rc, at least one pressure selected from the range of 〇psig to 75 psig) a mixture, wherein the mixture comprises: (a) a di-retensive acid component comprising: (I) from about 90 to about 100 mole % terephthalic acid residues; (II) from about 0 to about 1 mole % of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and (b) a diol component comprising: (1) from about 1 to less than 90 mol% of 2, 2, 4 , 4-tetramethyl·1,3·cyclobutanediol residue; and (ii) from about 0 to about 89 mole % of cyclohexanedimethanol residue; (iii) greater than 10 mole % of ethylene An alcohol residue, and (iv) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; 122661.doc -16- 200819496 wherein the ear ratio added in step (i) is 1.01-3.0 /1 〇· wherein the mixture in the step (1) is a catalyst comprising at least one of the titanium compounds, and optionally at least one catalyst selected from the group consisting of tin compounds, threo compounds, zinc Compounds, recorded compound, Tian compound

物鐘化合物、鎂化合物、錯化合物、鐘化合物、銘化合物及具有氫氧化鐘或氳氧化納之銘化合物，及（u)至少一種磷化合物、其反應產物及其混合物； (π)在23〇t至32〇t之溫度下，在至少一種選自步驟⑴ 之最終壓力至0.02托（torr)絕對壓力範圍内之壓力下將步驟（I)之產物加熱1至6小時以形成最終聚酯；a compound of a clock, a magnesium compound, a wrong compound, a clock compound, a compound of the formula and a compound having a hydrazine hydroxide or a ruthenium oxide, and (u) at least one phosphorus compound, a reaction product thereof, and a mixture thereof; (π) at 23 〇 Heating the product of step (I) for 1 to 6 hours at a temperature of t to 32 Torr at a pressure selected from the range of the final pressure of step (1) to a pressure of 0.02 torr absolute to form a final polyester;

之一醇組份/二幾酸組份之莫以下各物之存在下加其中最終聚酯中之二羧酸組份之總莫耳％為1〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1〇〇莫耳％ ; 其中如於25。(：下，在濃度為〇·25 g/50 ml之60/40(重量比）酚/ 四氣乙烷中所測定，聚酯之固有黏度為〇.5〇至12儿/§。在一態樣中，本發明係關於一種包含以下步驟之方法： (I)在至少一種選自150°C至25(TC之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a)二羧酸組份，其包含： (i)約90至約100莫耳％之對苯二甲酸殘基； 122661.doc -17- 200819496 (11)約〇至約10莫耳％之具有至多20個碳原子之芳族及/或脂族二羧酸殘基；及 (b)二醇組份，其包含： (I) 約1至小於90莫耳％之2,2,4,4-四甲基_1，3-環丁二醇殘基；及 (II) 約1至約89莫耳％之環己烷二甲醇殘基； (in)大於10莫耳％之乙二醇殘基，及 (iv)小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟（I)中所添加之二醇組份/二羧酸組份之莫耳比為 1.01-3.0/1.0 ; 其中步驟（I)中之混合物係於以下各物之存在下加孰： (i)至少一種包含至少一種鈦化合物之催化劑，及視情況之至少一種選自以下各物之催化劑：錫化合物、鎵化合物、辞化合物、録化合物、鈷化合物、鐘化合物、鎮化合物、錯化合物、鐘化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； (Π)在230°C至320°C之溫度下，在至少一種選自步驟⑴ 之最終壓力至0.02托絕對壓力範圍内之壓力下將步驟⑴ 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1 〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1 〇〇莫耳％ ;且 122661.doc -18- 200819496 其中如於25°C下，在濃度為0.25 g/50 ml之60M0(重量比）酚/ 四氯乙烷中所測定，聚酯之固有黏度為〇5〇至12 dL/g。在一態樣中，本發明係關於一種製備聚酯之方法，其包含以下步驟： (I)在至少一種選自150°C至250°C之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸組份，其包含： (1)約90至約1〇〇莫耳％之對苯二甲酸殘基； (ii)約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約20至約4〇莫耳％之2,2,4,4_四甲基·丨…環丁二醇殘基；及 (ii) 約20至約4〇莫耳％之環己烷二甲醇殘基； (iii) 乙二醇殘基，及〇 (iv)小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟⑴中所添加之：醇組份/H组份之莫耳比為 1·01_3·0/1.0 ; 其中步驟⑴中之混合物係於以下各物之存在下加熱： ⑴至少-種包含至少一種鈦化合物之催化劑，及視^况之至y 一種選自以下各物之催化劑：錫化 122661.doc -19- 200819496 合物、鎵化合物、鋅化合物、銻化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、銘化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； (II)在230 C至320°C之溫度下，在至少一種選自步驟⑴ 之最終壓力至0.02托絕對壓力範圍内之壓力下將步驟⑴ 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1 〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1〇〇莫耳％ ;且其中如於25 C下’在濃度為0.25 g/50 ml之60/40(重量比）酴/ 四氯乙烧中所測定’聚酯之固有黏度為〇·5〇至1.2 dL/g。在一態樣中，本發明係關於一種製備聚酯之方法，其包含以下步驟： (I)在至少一種選自150°C至25(TC之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸組份，其包含： (1)約90至約1〇〇莫耳〇/0之對苯二曱酸殘基； (η)約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,4-四甲基-1，3-環丁二醇殘基；及 (ii)約0至約89莫耳％之環己烷二甲醇殘基； 122661.doc -20- 200819496 (iii)大於1〇莫耳％之乙二醇殘基，及 (IV)小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟（I)中所添加之二醇組份/二羧酸組份之莫耳比為 1.01-3.0/1.0 ; 其中步驟（I)中之混合物係於以下各物之存在下加熱： (1)至夕種包含至少一種欽化合物、至少一種錫化合物之催化劑，及視情況之至少一種選自以下各物之催化劑：鎵化合物、鋅化合物、錄化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； (II)在230C至320C之溫度下，在至少一種選自步驟⑴ 之最終壓力至0.02托絕對壓力範圍内之壓力下將步驟⑴ 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1〇〇莫耳％ ;且其中如於25C下，在濃度為0.25 g/50 ml之60/40(重量比）紛/ 四氣乙烷中所測定，聚酯之固有黏度為0.50至12 dL/g。在一態樣中，本發明係關於一種製備聚酯之方法，其包含以下步驟： (I) 在至少一種選自150°C至250°C之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物， 122661.doc •21 - 200819496 其中該混合物包含： (a) 二羧酸組份，其包含： (I) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (⑴約0至約10莫耳％之具有至多20個碳原子之芳族及/或脂族二鲮酸殘基；及 (b) 二醇組份，其包含： ⑴約20至約4〇莫耳％之2,2,4,4_四甲基]，3_環丁二醇殘基；及 (II) 約20至約40莫耳％之環己烷二甲醇殘基； (iii) 約30至約60莫耳％之乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟（I)中所添加之二醇組份/二羧酸組份之莫耳比為 1.01-3.0/1.0 ; 其中步驟（I)中之混合物係於以下各物之存在下加熱： (1)至少一種包含至少一種鈦化合物、至少一種錫化合物之催化劑，及視情況之至少一種選自以下各物之催化劑·鎵化合物、鋅化合物、錄化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鐘化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； (II)在23 0 C至3 20 C之溫度下，在至少一種選自步驟（I) 之最終壓力至〇·〇2托絕對壓力範圍内之壓力下將步驟⑴ 122661.doc -22- 200819496 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為i 〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為i 〇〇莫耳％ ;且其中如於25°C下，在濃度為0.25 g/50 ml之60/4〇(重量比）酚/ 四氯乙烷中所測定，聚酯之固有黏度為0_50至12几/§。在一態樣中，本發明係關於一種製備聚酯之方法，其包含以下步驟：The total molar % of the dicarboxylic acid component of the final polyester is 1% molar % in the presence of one of the alcohol component/diacid component; and wherein the final polyester is The total molar % of the diol component is 1% mol%; wherein, as in 25. (:, in the concentration of 〇·25 g/50 ml of 60/40 (weight ratio) phenol / tetra-ethane ethane, the inherent viscosity of the polyester is 〇.5〇 to 12 children / §. In one aspect, the invention relates to a process comprising the steps of: (I) heating at least one temperature selected from the group consisting of from 150 ° C to 25 (TC) in at least one pressure selected from the range of from 0 psig to 75 psig. a mixture, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: (i) from about 90 to about 100 mole percent terephthalic acid residues; 122661.doc -17-200819496 (11) about An aromatic and/or aliphatic dicarboxylic acid residue having up to about 10 moles of up to about 10 carbon atoms; and (b) a diol component comprising: (I) from about 1 to less than 90 moles % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (II) from about 1 to about 89 mole % of cyclohexanedimethanol residue; (in) greater than 10 mole % of ethylene glycol residue, and (iv) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; wherein the diol component added in step (I) / The molar ratio of the dicarboxylic acid component is from 1.01 to 3.0/1.0; wherein the mixture in the step (I) The ruthenium is added in the presence of: (i) at least one catalyst comprising at least one titanium compound, and optionally at least one catalyst selected from the group consisting of tin compounds, gallium compounds, compound compounds, recorded compounds, cobalt a compound, a clock compound, a symbiotic compound, a dysfunctional compound, a clock compound, an aluminum compound, and an aluminum compound having lithium hydroxide or sodium hydroxide; and (ii) at least one phosphorus compound; (Π) at 230 ° C to 320 ° C The product of step (1) is heated at a temperature of at least one pressure selected from the final pressure of step (1) to a pressure in the range of 0.02 Torr absolute for 1 to 6 hours to form a final polyester; wherein the dicarboxylic acid component of the final polyester The total molar % is 1 〇〇 mol %; and wherein the total molar % of the diol component in the final polyester is 1 〇〇 mol %; and 122661.doc -18- 200819496 where 25° The intrinsic viscosity of the polyester is 〇5〇 to 12 dL/g as determined in C, 60 M0 (by weight) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml. In one aspect, the invention a method for preparing a polyester, which comprises Step: (I) heating a mixture at a temperature selected from the group consisting of 150 ° C to 250 ° C in at least one pressure selected from the range of 0 psig to 75 psig, wherein the mixture comprises: (a) dicarboxyl An acid component comprising: (1) from about 90 to about 1 mole percent terephthalic acid residue; (ii) from about 0 to about 10 mole percent of an aromatic having up to 2 carbon atoms And/or an aliphatic dicarboxylic acid residue; and (b) a diol component comprising: (1) from about 20 to about 4 mole % of 2,2,4,4-tetramethyl·丨...cyclobutane a diol residue; and (ii) from about 20 to about 4 mole percent of a cyclohexanedimethanol residue; (iii) an ethylene glycol residue, and hydrazine (iv) less than about 2 mole percent having 3 a modified diol of up to 16 carbon atoms; wherein the molar ratio of the alcohol component/H component added in the step (1) is 1.01_3·0/1.0; wherein the mixture in the step (1) is as follows Heating in the presence of a substance: (1) at least one type of catalyst comprising at least one titanium compound, and, depending on the condition, a catalyst selected from the group consisting of tin-plated 122661.doc -19-200819496, gallium compound, zinc Compound, hydrazine compound , a cobalt compound, a manganese compound, a magnesium compound, a bismuth compound, a lithium compound, an indole compound, and an aluminum compound having lithium hydroxide or sodium hydroxide; and (ii) at least one phosphorus compound; (II) at 230 C to 320 ° C The product of step (1) is heated at a temperature of at least one pressure selected from the final pressure of step (1) to a pressure in the range of 0.02 Torr absolute for 1 to 6 hours to form a final polyester; wherein the dicarboxylic acid group in the final polyester The total molar % of the part is 1 〇〇 mol %; and wherein the total molar % of the diol component in the final polyester is 1 〇〇 mol %; and wherein the concentration is 0.25 at 25 C 60/40 (by weight) g/50 ml 酴/ measured in tetrachloroethane. The inherent viscosity of the polyester is 〇·5〇 to 1.2 dL/g. In one aspect, the invention relates to a method of preparing a polyester comprising the steps of: (I) at least one temperature selected from the group consisting of from 150 ° C to 25 (TC), at least one selected from the group consisting of 0 psig to 75 Heating a mixture at a pressure in the range of psig, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: (1) from about 90 to about 1 Torrole/0 terephthalic acid residue (η) from about 0 to about 1 mole % of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and (b) a diol component comprising: (1) about 1 Up to less than 90 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and (ii) from about 0 to about 89 mole % of cyclohexane dimethanol residue 122661.doc -20- 200819496 (iii) an ethylene glycol residue greater than 1 mole %, and (IV) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; The molar ratio of the diol component/dicarboxylic acid component added in the step (I) is from 1.01 to 3.0/1.0; wherein the mixture in the step (I) is heated in the presence of the following: (1) The evening plant contains at least one compound of at least one tin compound a catalyst, and optionally at least one catalyst selected from the group consisting of a gallium compound, a zinc compound, a recorded compound, a cobalt compound, a manganese compound, a magnesium compound, a cerium compound, a lithium compound, an aluminum compound, and having lithium hydroxide or hydrogen An aluminum compound of sodium oxide; and (ii) at least one phosphorus compound; (II) at a temperature of from 230 C to 320 C, at least one pressure selected from the final pressure of step (1) to a pressure within a range of 0.02 Torr absolute (step 1) The product is heated for 1 to 6 hours to form the final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% molar %; and wherein the total diol component of the final polyester is The % of the ear is 1% molar; and the inherent viscosity of the polyester is 0.50 as determined at 25C in a concentration of 0.25 g/50 ml of 60/40 (weight ratio) / tetra-ethane. Up to 12 dL/g. In one aspect, the invention relates to a method of preparing a polyester comprising the steps of: (I) at least one temperature selected from the group consisting of 150 ° C to 250 ° C, at least one Heating from a pressure in the range of 0 psig to 75 psig Mixture, 122661.doc • 21 - 200819496 wherein the mixture comprises: (a) a dicarboxylic acid component comprising: (I) from about 90 to about 1 mole percent terephthalic acid residue; ((1) about 0 to about 10 mole % of an aromatic and/or aliphatic dicarboxylic acid residue having up to 20 carbon atoms; and (b) a diol component comprising: (1) from about 20 to about 4 mole % 2,2,4,4-tetramethyl], 3_cyclobutanediol residues; and (II) from about 20 to about 40 mole % of cyclohexanedimethanol residue; (iii) about 30 to About 60 mole % of the ethylene glycol residue, and (iv) less than about 2 mole % of the modified diol having 3 to 16 carbon atoms; wherein the diol component added in the step (I) The molar ratio of the /dicarboxylic acid component is from 1.01 to 3.0/1.0; wherein the mixture in the step (I) is heated in the presence of the following: (1) at least one comprising at least one titanium compound, at least one tin compound a catalyst, and optionally at least one catalyst selected from the group consisting of gallium compounds, zinc compounds, recorded compounds, cobalt compounds, manganese compounds, magnesium compounds, antimony compounds, clock compounds, aluminizing And an aluminum compound having lithium hydroxide or sodium hydroxide; and (ii) at least one phosphorus compound; (II) at a temperature of from 23 ° C to 3 20 C, at least one selected from the group consisting of step (I) The product of step (1) 122661.doc -22-200819496 is heated for 1 to 6 hours under pressure to a pressure within the absolute pressure range to form the final polyester; wherein the total amount of the dicarboxylic acid component in the final polyester The molar % is i 〇〇 mol %; and wherein the total molar % of the diol component in the final polyester is i 〇〇 mol %; and wherein, at 25 ° C, at a concentration of 0.25 g / The inherent viscosity of the polyester is from 0 to 50 to 12/s as determined in 50 ml of 60/4 Torr (by weight) phenol/tetrachloroethane. In one aspect, the invention is directed to a method of making a polyester comprising the steps of:

(I)在至少一種選自150°C至25(TC之溫度下，在至少一種選自〇 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸組份，其包含： (I) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (II) 約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二魏酸殘基；及 (b) 二醇組份，其包含： ⑴約2〇至約40莫耳％之2,2,4,心四甲基m袁丁二醇殘基；及 (H)約2〇至約爾耳％之環己烧二甲醇殘基； (iii) 乙一醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇； --野組to / —熳0更組份之莫耳比為 l.OU.O/Lo ; 、其中步驟⑴中之混合物係於以下各物之存在下加 122661.doc -23 - 200819496 熱： (0至少一種包含至少一種鈦化合物、至少一種锡化合物之催化劑，及視情況之至少一種選自以下各物之催化劑：鎵化合物、鋅化合物、錄化合物、鈷化合物、錳化合物、鎂化合物、錯化人物、鋰化合物、銘化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； (H)在23(TC至32(TC之溫度下，在至少一種選自步驟⑴ . 之最終壓力至0.02托絕對壓力範圍内之壓力下將步驟⑴ 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1〇〇莫耳0/〇 ; 其中最終聚酯中之2,2,4,4-四甲基-1，3-環丁二醇與環己烧二甲醇之莫耳百分數總和為二醇組份之總莫耳。/❶之4〇莫耳 %至小於70莫耳％，且其中如於25°C下，在濃度為0.25 g/50 ml之60/40(重量比）酚/ ( 四氯乙烷中所測定，聚酯之固有黏度為0.50至1.2 dL/g。在一態樣中，對於適用於本發明之聚酯及適用於本發明之方法而a ’如由CIE(國際照明委員會；][nternati〇nai(I) heating a mixture at a temperature selected from the group consisting of 150 ° C to 25 (TC) in at least one pressure selected from the group consisting of 〇 psig to 75 psig, wherein the mixture comprises: (a) a dicarboxylic acid group And comprising: (I) from about 90 to about 1 mole percent of a terephthalic acid residue; (II) from about 0 to about 10 mole percent of an aromatic having up to 2 carbon atoms and/or Or an aliphatic diwei acid residue; and (b) a diol component comprising: (1) from about 2 〇 to about 40 mol% of 2,2,4, cardiotetramethyl m-butanediol residue; And (H) about 2 to about 1% of the cyclohexane-small dimethanol residue; (iii) an ethyl alcohol residue, and (iv) less than about 2 mole % of a modification having from 3 to 16 carbon atoms The diol of the wild group to / - 熳 0 is a molar ratio of l. OU. O / Lo; wherein the mixture in step (1) is in the presence of the following substances plus 122661.doc -23 - 200819496 Heat: (0 at least one catalyst comprising at least one titanium compound, at least one tin compound, and optionally at least one catalyst selected from the group consisting of gallium compounds, zinc compounds, recorded compounds, cobalt compounds, manganese a compound, a magnesium compound, a distorted person, a lithium compound, a compound and an aluminum compound having lithium hydroxide or sodium hydroxide; and (ii) at least one phosphorus compound; (H) at a temperature of 23 (TC to 32 (TC) The product of step (1) is heated for 1 to 6 hours at a pressure of at least one selected from the final pressure of step (1) to a pressure in the range of 0.02 Torr to form a final polyester; wherein the dicarboxylic acid component of the final polyester The total molar % is 1% molar %; and wherein the total molar % of the diol component in the final polyester is 1 〇〇 mole 0 / 〇; wherein 2, 2, 4 of the final polyester The sum of the molar percentages of 4-tetramethyl-1,3-cyclobutanediol and cyclohexane-sintered dimethanol is the total molar amount of the diol component. /❶4〇% by mole to less than 70% by mole And wherein the inherent viscosity of the polyester is 0.50 to 1.2 dL/g as determined at 25 ° C in a concentration of 0.25 g / 50 ml of 60 / 40 (by weight) phenol / (tetrachloroethane). In one aspect, for a polyester suitable for use in the present invention and a method suitable for use in the present invention, a 'as by CIE (International Commission on Illumination;) [nternati〇nai

Commission on Illumination)(已譯）之 L*a*b*色彩系統所測定，適用於本發明之聚酯之b*值[在一實施例中，在調色劑存在及/或不存在下]可為-12至小於12，其中L*表示明度座標，a*表示紅色/綠色座標，且b*表示黃色/藍色座標。在一實施例中，適用於本發明之聚酯之b*值[在一實施例 122661.doc -24- 200819496 中，在調色劑存在及/或不存在下]可為〇至1〇。在一中’適用於本發明之聚醋之b*值[在一實施例巾，例劑存在及/或不存在下]可為0至5。凋色在-態樣中’本發明包括可包含本發明之任何聚❽且人物之熱成型薄片。、口種無論在一態樣中，適用於本發明之聚酯可包含至少一疋否作為熱穩定劑存在之磷酸酯。The b* value of the polyester of the present invention as determined by the L*a*b* color system of Commission on Illumination (translated) [in one embodiment, in the presence and/or absence of toner] It can be from -12 to less than 12, where L* represents the luma coordinate, a* represents the red/green coordinate, and b* represents the yellow/blue coordinate. In one embodiment, the b* value of the polyester suitable for use in the present invention [in an embodiment 122661.doc -24-200819496, in the presence and/or absence of toner) may be from 〇 to 1 〇. The b* value of the polyester used in the present invention [in the case of an embodiment, in the presence and/or absence of an agent] may be from 0 to 5. The invention is in the form of a thermoformed sheet which may comprise any of the polybenzazoles of the invention and which is human. In any aspect, the polyester suitable for use in the present invention may comprise at least one phosphate which is present as a heat stabilizer.

在一態樣中，適用於本發明之聚醋可包含至少-種本文所述作為熱穩定劑存在之磷酸酯。在二樣中適用於本發明之聚酯不含分枝劑，或者，在聚醋之聚合反應之前或期間添加至少-種分枝劑。在心樣中，適用於本發明之聚酯含有至少一種分枝劑，而無需顧及添加其之方法或次序。在怨樣中’適用於本發明之某些聚酯可為非晶形或半曰曰貝在恶樣中’適用於本發明之某些聚酯可具有相對低之、纟口曰曰度。因此’適用於本發明之某些聚酯可具有實質非曰曰开y之幵》悲’意謂該等聚酯包含聚合物之實質無序區。在悲樣中’適用於本發明之本發明的聚酯、聚酯組合物及/或：法可包含至少_種磷化合物。在心樣中’適用於本發明之本發明的聚酯、聚酯組合物及/或方法可包含磷原子。在L樣中，本發明之聚酯及/或聚酯組合物可包含鈦原子及錫原子。 122661.doc -25- 200819496 策中本發明之聚醋、聚g旨組合物及/或方法可包含磷原子、锡原子及鈦原子。樣中’適用於本發明之本發明的聚酯、聚酯組合物及/或方法彳包含磷原子及鈦原子。在一態樣中，本發明可包含磷原子、錫原子及鈦原子。在悲樣中’本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種磷化合物。In one aspect, the polyester suitable for use in the present invention may comprise at least one of the phosphates described herein as a heat stabilizer. In either case, the polyester suitable for use in the present invention does not contain a branching agent, or at least a branching agent is added before or during the polymerization of the polyester. In the heart, the polyester suitable for use in the present invention contains at least one branching agent, regardless of the method or sequence in which it is added. In the case of complaints, certain polyesters suitable for use in the present invention may be amorphous or semi-mussels in a bad form. Certain polyesters suitable for use in the present invention may have relatively low, mouth-twisting. Thus, certain polyesters which are suitable for use in the present invention may have substantial non-opening y, meaning that the polyesters comprise substantial disordered regions of the polymer. In the case of a sad sample, the polyester, polyester composition and/or method applicable to the present invention may comprise at least one phosphorus compound. The polyester, polyester composition and/or method of the present invention which is suitable for use in the present invention may comprise a phosphorus atom. In the L-form, the polyester and/or polyester composition of the present invention may contain a titanium atom and a tin atom. 122661.doc -25- 200819496 The polylactic acid composition and/or method of the present invention may comprise a phosphorus atom, a tin atom and a titanium atom. The polyester, polyester composition and/or method of the present invention which is suitable for use in the present invention contains a phosphorus atom and a titanium atom. In one aspect, the invention may comprise a phosphorus atom, a tin atom, and a titanium atom. In the case of a sadness, any of the polyesters, polyester compositions and/or methods of the present invention may comprise at least one phosphorus compound.

在一悲樣中’本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種鈦化合物。在一態樣中，本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種鈦化合物及至少一種磷化合物。在一態樣中，本發明之任何聚酯、聚酯組合物及/或方法可包含（i)至少一種鈦化合物，及視情況之至少一種選自以下各物之化合物：錫化合物、鎵化合物、鋅化合物、錄化合物、録化合物、猛化合物、鎭化合物、鍺化合物、裡化合物、鋁化合物及具有氫氧化經或氫氧化鈉之鋁化合物；及（ii)至少一種鱗化合物。術語”鱗化合物”意欲包括其反應產物。在一態樣中，本發明之任何聚酯、聚酯組合物及/或方法可包含（i)至少一種鈦化合物、至少一種錫化合物及視情況之至少一種選自以下各物之化合物：鎵化合物、鋅化合物、銻化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物。 122661.doc -26- 200819496 〜樣中，適用於本發明之任何聚酯、聚酯組合物及/ 或製備該等聚酯心方凌可包含至少一種錫化合物及至少一種鈦化合物。。樣中，相於I發明之任何聚醋H组合物及/ 或製備該等聚_之方法可包含至少—種錫化合物、至少一種欽化合物及至少一種磷化合物。广L樣中，至少一種適用於本發明之磷化合物包含磷In a sad manner, any of the polyesters, polyester compositions and/or methods of the present invention may comprise at least one titanium compound. In one aspect, any of the polyesters, polyester compositions and/or methods of the present invention can comprise at least one titanium compound and at least one phosphorus compound. In one aspect, any of the polyester, polyester compositions and/or methods of the present invention may comprise (i) at least one titanium compound, and optionally at least one compound selected from the group consisting of tin compounds, gallium compounds , a zinc compound, a recorded compound, a recorded compound, a stimulating compound, an anthraquinone compound, an anthraquinone compound, an internal compound, an aluminum compound, and an aluminum compound having a hydrogen peroxide or sodium hydroxide; and (ii) at least one scale compound. The term "scale compound" is intended to include the reaction product thereof. In one aspect, any of the polyester, polyester compositions and/or methods of the present invention may comprise (i) at least one titanium compound, at least one tin compound, and optionally at least one compound selected from the group consisting of gallium: a compound, a zinc compound, a cerium compound, a cobalt compound, a manganese compound, a magnesium compound, a cerium compound, a lithium compound, an aluminum compound, and an aluminum compound having lithium hydroxide or sodium hydroxide; and (ii) at least one phosphorus compound. 122661.doc -26-200819496 Any of the polyesters, polyester compositions and/or the preparation of the polyesters of the present invention may comprise at least one tin compound and at least one titanium compound. . In any of the above, any of the polyester H compositions of the invention and/or the method of preparing the same may comprise at least one tin compound, at least one compound and at least one phosphorus compound. In the broad L sample, at least one phosphorus compound suitable for use in the present invention contains phosphorus

:夂匕亞秘酉夂、膦酸、次膦酸、亞膦酸及其各種酯及鹽。該 \ •曰可為烧基@曰、支鏈燒基醋、經取代之烧基醋、雙官能燒基酉曰⑨基_旨、芳基醋及經取代之芳基醋。在L樣中，至少一種適用於本發明之磷化合物包含至夕種k自α下各物中至少一者之石舞化合斗勿：經取代或未、、工取代之烧基鱗酸g旨、經取代或未經取代之芳基鱗酸醋、經取代或未經取代之混合型烷基芳基磷酸酯、二亞磷酸 s曰、破酸鹽、膦氧化物及混合㈣基芳基亞鱗酸_、其反應產物及其混合物。磷酸酯包括其中磷酸經完全酯化或僅部分醋化之醋。在一恶樣中，至少一種適用於本發明之磷化合物包含至少一種選自以下各物中至少一者之磷化合物··經取代或未經取代之烷基磷酸醋、經取代或未經取代之芳基磷酸酯、經取代或未經取代之混合型烷基芳基磷酸酯、其反應產物及其混合物。磷酸酯包括其中磷酸經完全酯化或僅部分酯化之酯。在一態樣中，至少一種適用於本發明之磷化合物係選自 122661.doc •27- 200819496 以下各物中之至少-者：燒基碟酸醋、芳基構酸賴、混入型院基芳基鱗酸s旨、其反應產物及其混合物。 σ 在一態樣中’至少—種適用於本發明之構化合物可包A 至少一種芳基鱗酸i旨。在t樣中，至7種適用於本發明之填化合物可包含至少一種未經取代之芳基磷酸酯。在-態樣中，至少一種適用於本發明之磷化合物可包含至少一種未經苄基取代之芳基磷酸酯。 ί 在-態樣中，至少-種適用於本發明之磷化合物可包含至少一種三芳基磷酸酯。在恶樣中，至少一種適用於本發明之磷化合物可包含至少一種未經苄基取代之三芳基磷酸酯。在^"樣中，至少一種適用於本發明之磷化合物可包含至少一種烧基磷酸酯。在心樣中，至少一種適用於本發明之磷化合物可包含填酸三苯酯及/或MerP〇1 Α。纟一實施例中，本發明之任 J 何t S日組合物均可包含鱗酸三苯酯。在一悲樣中，本文所述之任何製備任何聚酯組合物及/ 或聚醋之方法均可包含至少一種混合型烷基芳基亞磷酸西曰、諸如又（2,4_ 一異丙苯基苯基）異戊四醇二亞磷酸酯（亦稱為 overphos S-9228，Dover Chemicals，CAS#154862_ 43-8)。在一悲樣中，本文所述之任何製備任何聚酯組合物及/ 或聚酯之方法均可包含至少一種膦氧化物。 122661.doc -28- 200819496 在。樣t纟文所述之任何製備任何聚ι组合物及/ 或聚酯之方法均可舍+ 5小 ^ ^ 至乂一種磷酸鹽，諸如KH2P〇4及: 夂匕 sub-secret, phosphonic acid, phosphinic acid, phosphinic acid and various esters and salts thereof. The \ 曰 can be a base @曰, a branched ketone vinegar, a substituted ketone vinegar, a bifunctional ketone ketone, an aryl vinegar, and a substituted aryl vinegar. In the L-form, at least one of the phosphorus compounds suitable for use in the present invention comprises at least one of the species of the genus k from the genus of the genus, and the sulphuric acid sulphate is substituted or unsubstituted. , substituted or unsubstituted aryl lauric acid, substituted or unsubstituted mixed alkyl aryl phosphate, diphosphoric acid s hydrazine, acid salt, phosphine oxide and mixed (tetra) aryl arylene Squaric acid _, its reaction products and mixtures thereof. Phosphates include vinegars in which the phosphoric acid is fully esterified or only partially acetified. In a wicked form, at least one phosphorus compound suitable for use in the present invention comprises at least one phosphorus compound selected from at least one of the following: substituted or unsubstituted alkyl phosphate vinegar, substituted or unsubstituted An aryl phosphate, a substituted or unsubstituted mixed alkyl aryl phosphate, a reaction product thereof, and a mixture thereof. Phosphates include esters in which the phosphoric acid is fully esterified or only partially esterified. In one aspect, at least one phosphorus compound suitable for use in the present invention is selected from the group consisting of 122661.doc • 27-200819496, at least one of which is: a saucy vinegar, an aryl acid lysate, a mixed-type hospital base. Aryl sulphate, its reaction products and mixtures thereof. σ In one aspect, at least one compound suitable for use in the present invention may comprise A at least one aryl squaraine. In the t-form, up to seven suitable compounds for use in the present invention may comprise at least one unsubstituted aryl phosphate. In the aspect, at least one phosphorus compound suitable for use in the present invention may comprise at least one aryl phosphate which is not substituted with a benzyl group. In the aspect, at least one of the phosphorus compounds suitable for use in the present invention may comprise at least one triaryl phosphate. In the abatement, at least one phosphorus compound suitable for use in the present invention may comprise at least one triaryl phosphate which is not substituted with a benzyl group. In the "like, at least one phosphorus compound suitable for use in the present invention may comprise at least one alkyl phosphate. In the core, at least one of the phosphorus compounds suitable for use in the present invention may comprise triphenyl titanate and/or MerP〇1®. In one embodiment, any of the compositions of the present invention may comprise triphenyl phthalate. In a sad manner, any of the methods described herein for preparing any polyester composition and/or polyester may comprise at least one mixed alkyl aryl phosphite, such as bis (2,4- cumene). Phenylphenyl)isopentyl alcohol diphosphite (also known as overphos S-9228, Dover Chemicals, CAS #154862_43-8). In a sad manner, any of the methods described herein for preparing any polyester composition and/or polyester may comprise at least one phosphine oxide. 122661.doc -28- 200819496 at . Any of the methods for preparing any of the compositions and/or polyesters described in the article can be carried out + 5 small ^ ^ to 乂 a phosphate such as KH2P〇4 and

Zll3(P〇4)2。在樣中，本文所述之任何製備任何聚酯組合物及/ 或《之方法均包含至少一種本文所述之鱗化合物。據信，適用於本發明之任何製備聚酯之方法均可用於製備適用於本發明之任何聚酯。 f 在一態樣中，本發明之任何方法之步驟（I)中所用之壓力 1 係由至少一種選自0 Psig至75 psig之壓力組成。在一實施例中，本發明之任何方法之步驟⑴中所用之壓力係由至少一種選自0 psig至50 psig之壓力組成。在一恶樣中，本發明之任何方法之步驟（π)中所用之壓力係由至少一種選自20托絕對壓力至〇〇2托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟中所用之壓力係由至少一種選自10托絕對壓力至〇托絕對 I 壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自5托絕對壓力至〇〇2 托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自3托絕對壓力至〇·〇2托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自2〇托絕對壓力至〇· 1托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自10托絕對壓力至0.1托絕對壓力之壓力組成；在一實 122661.doc -29- 200819496 施例中，本發明之任何了方去之步驟（π)中所用之壓力係由至少一種選自5托絕斟厭^ ^ 、逢力至0·1托絕對壓力之壓力組成；在θ ^例中，本發明之任何方法之步驟⑴）中所用之壓力係由至少-種選自3托絕對壓力至〇ι托絕對壓力之壓力組成。在一態樣中，本發明夕& γ 1 月之任何方法之步驟（1)中所添加之二醇組份/二緩酸組份之莫耳比為1〇_3 〇/1〇 ;在一本發明之任何方法之牛驟…士〜乂驟（I)中所添加之二醇組份/二叛酸組份之莫耳比為1.0_2.5/1 〇 •扁 ^ ^ , 丄·υ ,在一悲樣中，本發明之任何方法之步驟⑴中所添加之二醇組份/二竣酸組份之莫耳比為 1·0_2·0/1·〇 ;在一離；(¾ 由 ,_ 〜、樣中，本發明之任何方法之步驟⑴ 中所添加之二醇組份/二羧酸組份之莫耳比為ι·〇_ 1-75/1.0 ;在一態樣中，本个知听之任何方法之步驟⑴中所添加之二醇組份/二缓酸組份之莫耳比為m Μ』。在-態樣t，本發明之任何方法之步驟⑴中所添加之二醇組份/二羧酸組份之莫耳比為1〇1_3〇/1〇 ;在—態= 中，本發明之任何方法之步驟⑴中所添加之二醇会且广/二缓酸組份之莫耳比為UW.W.O;在一態樣中，本發= 任何方法之步驟⑴中所添加之二醇組份/二幾酸組份之莫耳比為1.01-2.0/1.0 ;在一態樣中，本發明之任何方法之步驟⑴中所添加之二醇組份/二缓酸組份之莫耳比為1 〇' αη.ο;在一態樣中，本發明之任何方法之步驟⑴中: 添加之二醇組份/二羧酸組份之莫耳比為1〇1_15/1 〇。在製備適用於本發明之聚酯之任何方法實施例中，+騾 122661.d( •30- 200819496 (II)之加熱時間可為1至5小時。在製備適用於本發明之聚酯之任何方法實施例中，步驟（„)之加熱時間可為丨至4小時。在製備適用於本發明之聚酯之任何方法實施例中，步驟（II)之加熱時間可為1至3小時。在製備適用於本發明之聚酯之任何方法實施例中，步驟（11)之加熱時間可為15至 3小時。在製備適用於本發明之聚g旨之任何方法實施例中’步驟（II)之加熱時間可為1至2小時。在一態樣中，在本發明之方法中添加磷化合物可使得最終聚酯巾全部碟原？與全部錫原子之重量t匕為0-20^。在貝加例中在本發明之方法中添加石粦化合物可使得最終聚酯中全部磷原子與全部錫原子之重量比為^^丄。在一態樣中，在本發明之方法中添加磷化合物可使得最終聚酯中全部磷原子與全部錫原子之重量比為0_15:1。在貝施例中在本發明之方法中添加填化合物可使得最終聚酯中全部磷原子與全部錫原子之重量比為。在一態樣中，在該（等）方法中添加磷化合物可使得最終聚酯中全部磷原子與全部錫原子之重量比為0_10:丨。在一實施例中，在本發明之方法中添加填化合物可使得最終: 酯中全部磷原子與全部錫原子之重量比為。 … 在一態樣中，在該（等）方法中添加磷化合物可使得田炊聚酉旨中全部填原子與全部錫原子之重量比為(M:1。在^實施例中纟本發月之方法中添加磷化合物可使得最終中全部磷原子與全部錫原子之重量比為卜5:1。、…曰在悲樣中’在該(等)方法中添加磷化合物可使得最終 122661.doc -31 - 200819496 聚酯中全部磷原子與全部錫原子之重量比為〇_3:丨。在一實施例中，在該（等）方法中添加磷化合物可使得最終聚酯中全部磷原子與全部錫原子之重量比為。舉例而t，最、終聚醋中所存在之錫原、子及碟原子之重量可以PPm為單位來量測且可使得最終聚醋中全部填原子與全部錫原子之重量比為任何上述重量比。Zll3 (P〇4) 2. In any of the examples, any of the polyester compositions and/or methods described herein comprise at least one of the scale compounds described herein. Any method of preparing a polyester suitable for use in the present invention is believed to be useful in the preparation of any of the polyesters suitable for use in the present invention. f In one aspect, the pressure 1 used in step (I) of any of the methods of the invention consists of at least one pressure selected from 0 Psig to 75 psig. In one embodiment, the pressure used in step (1) of any of the methods of the present invention consists of at least one pressure selected from 0 psig to 50 psig. In a wicked manner, the pressure used in step (π) of any method of the invention consists of at least one pressure selected from the group consisting of 20 Torr absolute to 〇〇 2 Torr absolute; in one embodiment, the invention The pressure used in the steps of any method consists of at least one pressure selected from the group consisting of a pressure of 10 Torr absolute to a pressure of Torrential I; in one embodiment, the pressure used in step (II) of any method of the invention is At least one pressure composition selected from the group consisting of 5 Torr absolute pressure to Torr 2 Torr absolute pressure; in one embodiment, the pressure used in step (II) of any of the methods of the present invention is at least one selected from the group consisting of 3 Torr absolute pressure to 〇·〇2 Torr the pressure composition of the absolute pressure; in one embodiment, the pressure used in step (II) of any of the methods of the present invention is at least one selected from the group consisting of 2 Torr absolute pressure to 〇 1 Torr absolute pressure. Pressure composition; in one embodiment, the pressure used in step (II) of any of the methods of the present invention consists of at least one pressure selected from the group consisting of 10 Torr absolute pressure to 0.1 Torr absolute pressure; in a solid 122661.doc -29 - 2 00819496 In the embodiment, the pressure used in the step (π) of any of the present invention consists of at least one pressure selected from the group consisting of 5 斟斟 ^ ^ ^ ^, tens to 0 1 1 Torr absolute pressure; In the example, the pressure used in the step (1)) of any of the methods of the present invention consists of at least one pressure selected from the group consisting of a pressure of 3 Torr to an absolute pressure of 〇ιTorr. In one aspect, the molar ratio of the diol component/dioxanic acid component added in the step (1) of any method of the present invention is 〇1333/1〇; In any method of the invention, the molar ratio of the diol component/two resorcinic acid component added in the step (I) is 1.0_2.5/1 〇•扁^ ^ , 丄· υ In a sad case, the molar ratio of the diol component/dicic acid component added in the step (1) of any method of the present invention is 1·0_2·0/1·〇; (3⁄4 From, _~, in the sample, the molar ratio of the diol component/dicarboxylic acid component added in the step (1) of any method of the present invention is ι·〇_ 1-75/1.0; In the sample, the molar ratio of the diol component/di-acidifying component added in the step (1) of any method of the present invention is m Μ 』. In the aspect t, the step (1) of any method of the present invention The molar ratio of the diol component/dicarboxylic acid component added is 1〇1_3〇/1〇; in the state=, the diol added in the step (1) of any method of the present invention is wide / Motility ratio of the second acid component is UW.WO; in one aspect, the hair = any The molar ratio of the diol component/diacid component added in the step (1) of the method is 1.01 to 2.0/1.0; in one aspect, the diol group added in the step (1) of any method of the present invention The moie ratio of the part/di-acidifying component is 1 〇'αη.ο; in one aspect, in the step (1) of any method of the invention: the molar component of the added diol component/dicarboxylic acid component The ratio is 1〇1_15/1 〇. In any method embodiment for preparing a polyester suitable for use in the present invention, the heating time of +骡122661.d (•30-200819496 (II) may be from 1 to 5 hours. In any method embodiment suitable for use in the polyester of the present invention, the heating time of the step (() can be from 4 to 4 hours. In any of the method embodiments for preparing the polyester suitable for use in the present invention, the heating of step (II) The time may be from 1 to 3 hours. In any of the process examples for preparing the polyester suitable for use in the present invention, the heating time of step (11) may be from 15 to 3 hours. Any of the purposes of preparing the poly g suitable for use in the present invention In the method embodiment, the heating time of the step (II) may be from 1 to 2 hours. In one aspect, phosphorus is added to the method of the present invention. The composition can make the total weight of the final polyester towel and all the tin atoms t 0 0 ^ ^. In the Bega example, the addition of the stone enamel compound in the method of the present invention can make all the phosphorus atoms in the final polyester. The weight ratio to all tin atoms is ^^. In one aspect, the addition of the phosphorus compound in the method of the present invention allows the weight ratio of all phosphorus atoms to all tin atoms in the final polyester to be 0-15:1. In the embodiment, the compound is added in the method of the present invention such that the weight ratio of all phosphorus atoms to the total tin atoms in the final polyester is. In one aspect, the addition of the phosphorus compound in the method can cause final polymerization. The weight ratio of all phosphorus atoms to all tin atoms in the ester is 0_10: 丨. In one embodiment, the addition of a compound to the process of the present invention results in a final weight ratio of all phosphorus atoms to all tin atoms in the ester. ... In one aspect, the addition of a phosphorus compound in the (etc.) method allows the weight ratio of all filled atoms to all tin atoms in the field to be (M: 1. In the embodiment, the present month The method of adding a phosphorus compound can make the weight ratio of all phosphorus atoms to all tin atoms in the final is 5:1., 曰 in the sad case, adding phosphorus compound in the method can make the final 122661.doc -31 - 200819496 The weight ratio of all phosphorus atoms to all tin atoms in the polyester is 〇_3: 丨. In one embodiment, the addition of a phosphorus compound in the (etc.) method allows all phosphorus atoms in the final polyester to The weight ratio of all tin atoms is. For example, t, the weight of the tin, the sub, and the dish atoms present in the final and final condensed vinegar can be measured in units of PPm and can make all the atoms and all tin in the final poly vinegar The atomic weight ratio is any of the above weight ratios.

在一態樣中，在本發明之方法中添加磷化合物可使得最終聚酯中全部磷原子與全部鈦原子之重量比為〇·2〇:ι。在只施例中纟本备a月之方法中添力^礙化合物可使得最終聚酯中全部磷原子與全部鈦原子之重量比為。、在-態樣中，在本發明之方法中添加礙化合物可使得最終聚醋中全部磷原子與全部鈦原子之重量比為〇·ΐ5:ι。在 -實施例中’在本發明之方法中添加磷化合物可使得最終聚醋中全部填原子與全部鈦原+之重量比^_ΐ5:ι。、、在-悲樣中’在該(等)方法中添加磷化合物可使得最終聚醋中全部填原子與全部鈦原子之重量比為。在二實施例中，在本發明之方法中添加璘化合物可使得最酯中全部磷原子與全部鈦原子之重量比為Μ。。。 Λ 在-態樣中’在該(等)方法中添加磷化合物可使得最终聚醋中全部鱗原子與全部鈦原子之重量比為〇_5:卜在實施例中’在本發明之方法中添加碟化合物可使得最終聚gt 中全部磷原子與全部鈦原子之重量比為。 …日在-態樣中’在該(等)方法中添加磷化合物可使得最終聚醋中全㈣原子與全部鈦原子之重量比為咖。在一: 122661.doc -32- 200819496 施例中，在該（等）方法中添加鱗化合物可使得最終聚全部麟原子與全部鈦原子之重量比為丨_3:1。舉例而言，最終聚酯中所存在之鈦原子及磷原子之重量可以ppm為單位來量測且可使得最終聚醋中全部鱗原子: 全部鈦原子之重量比為任何上述重量比。、在〜樣中，以最終聚酯之重量計，適用於本發明之聚醋中之錫原子的量可為〇至4GG ppm錫原子。在一態樣中，以最終聚S旨之重量計，適用於本發明之聚酉旨中之錫原子的量可為15至400 ppm錫原子。在一態樣巾’以最終聚酯之重量計，則於本發明之聚醋中之鈦原子的量可為〇至400 ppm鈦原子。在-態樣中，以最終聚醋之重量計，適用於本發明之聚 Sl中之鈦原子的量可為15至40G ppm鈦原子。在一態樣中’以最終聚g旨之重量計，適用於本發明之聚酯中之磷原子的量可為1至500 ppm磷原子。在-態樣中’以最終聚醋之重量計，適用於本發明之聚醋中=麟原子的量可為⑴⑼ppm麟原子，且以最終聚醋之重j旨中之鈦原子的量可為1至1GG ppm鈦原子。 :一:、樣中’以最終聚酿之重量計，適用於本發明之聚 ^子的量可為1至_ PPm餐子，μ最终聚醋之^^聚_中之鈦原子的量可為⑴⑽啊鈦原子。中以取終聚醋之重量計’適用於本發明之聚子的1可為1至500 ppm磷原子，且以最終聚酯之重量計，聚醋中之鈦原子的量可為i至⑽ppm鈦原^ 122661.doc -33- 200819496 在-態樣中，以最終聚酯醋中之❹、子的量可1相於本發明之聚曹旦4 h 為至5GG pp_原子；以最終聚醋之重里汁，適用於本發明之聚曰T之錫原子的罝可為1至400 ppm錫原且以最終旦^^ 17_ <里里。t象i日中之鈦原子的里可為1至1 00 Ppm鈦原子。 /In one aspect, the phosphorus compound is added to the process of the present invention such that the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 〇·2〇:ι. In the only example, the method of adding a compound to the method of a month can make the weight ratio of all phosphorus atoms in the final polyester to all titanium atoms. In the aspect, the compound is added in the method of the present invention such that the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 〇·ΐ5:ι. In the embodiment, the addition of the phosphorus compound in the method of the present invention allows the weight ratio of all the atoms in the final polycondensate to the total weight of the titanium to be +_ΐ5:ι. Adding a phosphorus compound to the method in the case of a sad sample allows the weight ratio of all the atoms to be filled in the final polyester to all the titanium atoms. In the second embodiment, the addition of the ruthenium compound in the process of the present invention allows the weight ratio of all phosphorus atoms in the most ester to all titanium atoms to be Μ. . . Λ In the aspect - the addition of the phosphorus compound in the method allows the weight ratio of all scale atoms in the final polyester to all titanium atoms to be 〇_5: in the embodiment of the invention The addition of the dish compound allows the weight ratio of all phosphorus atoms to all titanium atoms in the final polygt. The addition of the phosphorus compound in the (method) method allows the weight ratio of the total (tetra) atom to the total titanium atom in the final polyester to be the coffee. In one: 122661.doc -32- 200819496, in the example, the addition of the scaly compound in the (etc.) method allows the weight ratio of the final polynuclear atom to all titanium atoms to be 丨_3:1. For example, the weight of the titanium atom and the phosphorus atom present in the final polyester can be measured in ppm and can be such that all of the scale atoms in the final polyester: all titanium atoms are in any of the above weight ratios. In the sample, the amount of tin atoms suitable for use in the polyacetic acid of the present invention may be from 4 to GG ppm of tin atoms, based on the weight of the final polyester. In one aspect, the amount of tin atoms suitable for use in the polymerization of the present invention may range from 15 to 400 ppm of tin atoms, based on the weight of the final poly(S). The amount of titanium atoms in the polyacetate of the present invention may be from 〇 to 400 ppm of titanium atoms, based on the weight of the final polyester. In the aspect, the amount of titanium atoms suitable for use in the poly sl of the present invention may be from 15 to 40 G ppm of titanium atoms based on the weight of the final polyester. In one aspect, the amount of phosphorus atoms suitable for use in the polyester of the present invention may be from 1 to 500 ppm of phosphorus atoms, based on the weight of the final polymer. In the aspect, the amount of the arsenic atom in the polyacetic acid of the present invention may be (1) (9) ppm of the argon atom, and the amount of the titanium atom in the weight of the final vinegar may be 1 to 1 GG ppm titanium atom. A: In the sample, the amount of the poly-substrate suitable for the present invention can be 1 to _ PPm, and the amount of titanium atoms in the final poly- vine can be For (1) (10) ah titanium atom. 1 may be from 1 to 500 ppm of phosphorus atoms based on the weight of the final condensed vinegar, and the amount of titanium atoms in the vinegar may be from i to (10) ppm based on the weight of the final polyester. Titanium ^ 122661.doc -33- 200819496 In the same state, the amount of ruthenium in the final polyester vinegar can be 1 phase in the polycalyx of the present invention 4 h to 5 GG pp_ atom; The vinegar heavy juice, the tin atom suitable for the polyfluorene T of the present invention may be from 1 to 400 ppm tin original and in the final denier. The titanium atom in the day i may be 1 to 100 Ppm of titanium atoms. /

在—態樣中’聚8旨組合物適用於各種製品，該等製品包括(但不限於)擠出物品、壓延物品及/或模製物品(包括(但不限於)射出成形物品、擠出物品、澆鑄擠出物品、型面擠出物品、熔融紡絲物品、熱成型物品、擠出成形物品、射出吹塑成形物品、射出拉伸吹塑成形物品、冑出吹塑成形物品及擠出拉伸吹塑成形物品)。該等物品可包括(但不限於）薄膜、瓶子、容器、薄片及/或纖維。在一態樣中，適用於本發明之聚酯組合物可用於各種類型之薄膜及/或薄片，其包括（但不限於）擠出薄膜及/或薄片、壓延薄膜及/或薄片、壓縮成形薄膜及/或薄片、溶液澆鑄薄膜及/或薄片。製備薄膜及/或薄片之方法包括（但不限於）擠出、壓延、壓縮成形及溶液澆鑄。在一態樣中，本發明係關於包含本發明之聚酯及/或聚酉旨組合物之熱成型薄膜及/或薄片。在一態樣中，本發明係關於併入有本發明之熱成型薄膜及/或薄片之製品。在一態樣中，本發明提供一種製備含有乙二醇、 2,2,4,4-四甲基-^-環丁二醇及視情況之環己烷二甲醇之具有改良色彩及/或透明度的聚酯之方法。 122661.doc -34- 200819496 又’在一態樣中，提供一之方法，其中取消熱成型之驟0 種製備熱成型薄膜及/或薄片前之乾燥薄膜及/或薄片的步在一態樣中，適用於本發明之聚酉旨可為非晶形或半晶質。在-態樣中’冑用於本發明之某些聚醋可具有相對低之結晶度。因& ’適用於本發明之某些聚醋可具有實質上非晶形之形態’意謂該等聚酯包含聚合物之實質無序區。【實施方式】參考以下本發明之某些實施例及卫作實例之詳細說明可更易於瞭解本發明。根據本發明之目的，本發明之某些實施例已描述於發明内容中且在下文中進一步描述。本文中亦描述本發明之其他實施例。據信，由對苯二甲酸、其酯及/或其混合物、乙二醇、 2,2,4,4-四曱基- l，3-環丁二醇及視情況之環己烷二甲醇形成之包含某些熱穩定劑、其反應產物及其混合物的本發明之某些聚酯及/或聚酯組合物可具有以下特性中兩者或兩者以上之獨特組合：高伊佐德氏缺口衝擊強度、特定固有黏度、特定玻璃轉移溫度（Tg)、特定撓曲模數、良好透明度及良好色彩。在本發明之某些實施例中，本發明之某些聚酯及/或聚酯組合物可具有以下特性中三者或三者以上之獨特組合：高伊佐德氏缺口衝擊強度、特定固有黏度、特定玻璃轉移溫度（Tg)、特定撓曲模數、良好透明度及良好色彩。在本發明之某些實施例中，本發明之某些聚酯及/或聚 122661.doc -35- 200819496 酯組合物可具有以下特性中四者或四者以上之獨特組合·· 高伊佐德氏缺口衝擊強度、特定固有黏度、特定玻璃轉移溫度（Tg)、特定撓曲模數、良好透明度及良好色彩。在本發明之其他實施命】中，本發明之某⑧聚醋及/或聚 I组合物可具有以下所有特性之獨特組合··高伊佐德氏缺口衝擊強度、特^固有黏度、特定玻璃轉移溫度（Tg)、特定撓曲模數、良好透明度及良好色彩。儘管含有上述某些或全部特性之聚酯及/或聚酯組合物適用於夕種應用，但該等特性尤其適用於熱成型薄片應In the aspect, the composition is suitable for use in a variety of articles including, but not limited to, extruded articles, calendered articles, and/or molded articles (including but not limited to, injection molded articles, extruded Articles, cast extruded articles, profile extruded articles, melt spun articles, thermoformed articles, extruded articles, injection blow molded articles, injection stretch blow molded articles, drawn blow molded articles, and extruded Stretch blow molded articles). Such items may include, but are not limited to, films, bottles, containers, sheets, and/or fibers. In one aspect, the polyester compositions suitable for use in the present invention can be used in various types of films and/or sheets including, but not limited to, extruded films and/or sheets, calendered films and/or sheets, compression molded Film and/or flakes, solution cast films and/or flakes. Methods of making films and/or sheets include, but are not limited to, extrusion, calendering, compression forming, and solution casting. In one aspect, the invention is directed to a thermoformed film and/or sheet comprising the polyester and/or composition of the invention. In one aspect, the invention is directed to an article incorporating the thermoformed film and/or sheet of the present invention. In one aspect, the present invention provides an improved color and/or preparation of cyclohexanedimethanol containing ethylene glycol, 2,2,4,4-tetramethyl-^-cyclobutanediol and optionally cyclohexanedimethanol. The method of transparency of polyester. 122661.doc -34- 200819496 yet, in one aspect, a method is provided in which the steps of preparing the thermoformed film and/or the dried film and/or sheet before the sheet are eliminated. Among them, the polyphthalate suitable for use in the present invention may be amorphous or semicrystalline. Some of the polyesters used in the present invention may have a relatively low degree of crystallinity. Some of the polyesters suitable for use in the present invention may have a substantially amorphous morphology' meaning that the polyesters comprise substantially disordered regions of the polymer. [Embodiment] The present invention can be more easily understood by referring to the following detailed description of certain embodiments of the invention and the examples. In accordance with the purpose of the present invention, certain embodiments of the invention are described in the Summary of the Invention and are further described below. Other embodiments of the invention are also described herein. It is believed that terephthalic acid, its esters and/or mixtures thereof, ethylene glycol, 2,2,4,4-tetradecyl-l,3-cyclobutanediol and optionally cyclohexanedimethanol Certain polyester and/or polyester compositions of the present invention comprising certain heat stabilizers, reaction products thereof, and mixtures thereof may have a unique combination of two or more of the following characteristics: high Izod's gap Impact strength, specific intrinsic viscosity, specific glass transition temperature (Tg), specific flexural modulus, good transparency, and good color. In certain embodiments of the invention, certain polyester and/or polyester compositions of the present invention may have a unique combination of three or more of the following characteristics: high Izod notched impact strength, specific intrinsic viscosity , specific glass transition temperature (Tg), specific flexural modulus, good transparency and good color. In certain embodiments of the invention, certain polyesters and/or poly 122661.doc-35-200819496 ester compositions of the invention may have a unique combination of four or more of the following characteristics: · Gao Yzod Notched impact strength, specific intrinsic viscosity, specific glass transition temperature (Tg), specific flexural modulus, good transparency, and good color. In other embodiments of the present invention, a certain 8 polyester and/or poly I composition of the present invention may have a unique combination of all of the following characteristics: high Izod's notched impact strength, specific intrinsic viscosity, specific glass transfer Temperature (Tg), specific flexural modulus, good transparency and good color. Although polyester and/or polyester compositions containing some or all of the above characteristics are suitable for use in evening applications, such characteristics are particularly suitable for thermoformed sheets.

在一實施例中，據信當在製備本發明聚s旨之製程期間使 1至少-種包含本文所述之至少—種磷化合物之熱穩定劑日寸可更易於產生聚酯而無至少一種以下現象發生··起泡、形成斜面、形成色彩、發泡、排出廢氣及熔體含量不穩定（亦即聚1旨或聚酯之產生及處理系統之波動）。在另一實施例中，據信本發明之至少_種方法提供更易於大量 (例如先導生產規模及/或商業性生產）產生適用於本發明之聚酯的方式而無至少一種上述困難發生。如本文所用之術語”大量”包括以大於1〇〇碎之量產生之適用於本發明之聚s旨的量。在—實施例中，如本文所用之術語"大量"包括以大於1000磅之量產生之適聚酯的量。之在-實施例中，製備適用於本發明之聚酯之方人分批法或連續法。 3 122661.doc -36- 200819496 在一實施例中，製備適用於本發明之聚酯之方法包含連續法。在一實施例中’含有2,2,4,4-四甲基環丁二醇及乙二醇之共聚酯可用鈦基催化劑來製備。在另一實施例中，除鈦基催化劑以外，亦可藉由使用錫基催化劑來進一步改良2,2,4,4-四甲基_153_環丁二醇之併入。據信該等共聚酯之色彩可經由在聚合反應期間添加特定含量之含磷化合物而得以改良。當在本發明之聚酯及/或聚酯組合物及/或製備聚酯之方法中添加錫時，其係以錫化合物之形式添加至製備聚酯之中/4、加至本發明之I ®曰及/或本發明之聚醋組合物及/或本發明之方法中之錫化合物的量可以最終聚酯中所存在之錫原子的形式來量測，例如以ppm為單位量測重量 ° 當在本發明之聚酯及/或聚酯組合物及/或製備聚酯之方法中添加鈦時，其係以鈦化合物之形式添加至製備聚酯之方法中。添加至本發明之聚酯及/或本發明之聚酯組合物及/或本發明之方法中之鈦化合物的量可以最終聚酯中所在之鈦原子的形式來董測，例如以叩㈤為單位量測重量° 當在本發明之聚酯及/或聚酯組合物及/或製備聚酯之方法中添加磷時，其係以磷化合物之形式添加至製備聚酯之方法中。在一實施例中，該磷化合物可包含至少一種磷酸酉曰添加至本發明之聚酯及/或本發明之聚酯組合物及/或 122661.doc -37- 200819496 本發明之方法中之磷化合物[例如磷酸酯]的量可以最終聚酯中所存在之磷原子的形式來量測，例如以ppm為單位量測重量。如本文所用之術語，，聚酯”意欲包括，，共聚酯”，且應瞭解意謂藉由一或多種雙官能緩酸及/或多官能幾酸與一或多In one embodiment, it is believed that at least one of the heat stabilizers comprising at least one of the phosphorus compounds described herein may be more susceptible to polyester production during the preparation of the process of the present invention without at least one The following phenomena occur: foaming, formation of slopes, formation of color, foaming, exhaust gas discharge, and unstable melt content (i.e., fluctuations in the production and processing of the polyester or the polyester). In another embodiment, it is believed that at least one of the methods of the present invention provides a means to produce a polyester suitable for use in the present invention in a relatively large amount (e.g., by pilot production scale and/or commercial production) without at least one of the above difficulties occurring. The term "mass" as used herein includes an amount that is produced in an amount greater than one mash that is suitable for use in the present invention. In the examples, the term "large amount" as used herein includes an amount of a suitable polyester produced in an amount greater than 1000 pounds. In the examples, a batch or continuous process for preparing the polyester of the present invention is prepared. 3 122661.doc -36- 200819496 In one embodiment, a method of preparing a polyester suitable for use in the present invention comprises a continuous process. In one embodiment, a copolyester containing 2,2,4,4-tetramethylcyclobutanediol and ethylene glycol can be prepared using a titanium-based catalyst. In another embodiment, in addition to the titanium-based catalyst, the incorporation of 2,2,4,4-tetramethyl-153-cyclobutanediol can be further improved by the use of a tin-based catalyst. It is believed that the color of the copolyesters can be improved by the addition of specific levels of phosphorus-containing compounds during the polymerization. When tin is added to the polyester and/or polyester composition of the present invention and/or the method for preparing the polyester, it is added as a tin compound to the preparation of the polyester/4, and is added to the invention I. The amount of the cerium and/or the vinegar composition of the present invention and/or the tin compound of the method of the present invention can be measured in the form of tin atoms present in the final polyester, for example, in ppm. When titanium is added to the polyester and/or polyester composition of the present invention and/or the method of preparing the polyester, it is added to the method of producing a polyester in the form of a titanium compound. The amount of the titanium compound added to the polyester of the present invention and/or the polyester composition of the present invention and/or the method of the present invention can be measured in the form of a titanium atom in the final polyester, for example, 叩(五) Unit Measurement Weight When phosphorus is added to the polyester and/or polyester composition of the present invention and/or the method of preparing the polyester, it is added to the method of preparing the polyester in the form of a phosphorus compound. In one embodiment, the phosphorus compound may comprise at least one phosphonium phosphate added to the polyester of the present invention and/or the polyester composition of the present invention and/or the phosphoric acid in the method of the invention of 122661.doc-37-200819496 The amount of the compound [e.g., phosphate ester] can be measured in the form of a phosphorus atom present in the final polyester, for example, in ppm. As used herein, the term "polyester" is intended to include, "copolyester" and is understood to mean one or more by one or more difunctional acid and/or polyfunctional acids.

種雙官能經基化合物及/或多官能經基化合物（例如分枝劑）之反應所製備之合成聚合物。通常，雙官能羧酸可為二羧酸且雙官能經基化合物可為二經醇，諸如二醇及二元醇。如本文所用之術語，，二醇”包括（但不限於）二元醇、二醇及/ 或多官能羥基化合物，例如分枝劑。或者，雙官能叛酸可為經基羧酸，諸如對羥基苯甲酸，且雙官能羥基化合物可為具有2個羥基取代基之芳族核，諸如氫醌。如本文所用之術語”殘基，，意謂經由自相應單體之聚縮合反應及/或酯化反應併入聚合物中之任何有機結構。如本文所用之術語，，重複單元”意謂具有經由羰氧基鍵結之二綾酸殘基及二元醇殘基之有機結構。因此，舉例而言，二羧酸殘基可衍生自二羧酸單體或其相關之酸南化物、酯、鹽、酐及/或其混合物。此外，如本文所用之術語”二酸，，包括多官能酸，例如分枝劑。因此，如本文所用之術語"二羧酸"意欲包括適用於與二元醇製備聚醋之反應製程中的二叛酸及二叛酸之任何衍生物，包括其相關酸齒化物、酯、半酯、鹽、半鹽、肝、混合肝及/或其混合物。如本文所用之術二苯二甲酸"意欲包括適用於與二元醇製備聚6旨之反應製程中之對苯二甲酸本身及其殘基以及料二甲酸之任何衍生 122661.doc -38- 200819496 物，包括其相關酸鹵化物'酯、半酯、鹽、半鹽、酐、混合酐及/或其混合物或其殘基。用於本發明之聚酯通常可由二羧酸及二元醇以實質上相等之比例進行反應且以其相應殘基之形式併入聚酯聚合物中來製備。因&，本發明之聚酯可含有實質上等莫耳比例之I殘基（100莫耳％)及二元醇（及/或多官能羥基化合物）殘基（100莫耳％)以使得重複單元之總莫耳數等於100莫耳 %。因此，本揭示案中所提供之莫耳百分數可以酸殘基之A synthetic polymer prepared by the reaction of a difunctional thiol compound and/or a polyfunctional thiol compound such as a branching agent. Typically, the difunctional carboxylic acid can be a dicarboxylic acid and the difunctional thio-based compound can be a di-alcohol such as a diol and a glycol. As used herein, a diol "includes, but is not limited to, a diol, a diol, and/or a polyfunctional hydroxy compound, such as a branching agent. Alternatively, the bifunctional retinoic acid can be a transbasic carboxylic acid, such as a pair. Hydroxybenzoic acid, and the difunctional hydroxy compound can be an aromatic nucleus having two hydroxy substituents, such as hydroquinone. The term "residue," as used herein, means via a polycondensation reaction from a corresponding monomer and/or The esterification reaction is incorporated into any organic structure in the polymer. The term "repeating unit" as used herein means an organic structure having a dicarboxylic acid residue and a diol residue bonded via a carbonyloxy group. Thus, for example, a dicarboxylic acid residue may be derived from two A carboxylic acid monomer or its associated acid amide, ester, salt, anhydride and/or mixture thereof. Further, the term "diacid" as used herein, includes polyfunctional acids, such as branching agents. Thus, the term "dicarboxylic acid" as used herein is intended to include any derivative of di- and other oxonic acid, including its associated acid-toothed esters, esters, which are suitable for use in the reaction of glycols to prepare polyesters. , half ester, salt, half salt, liver, mixed liver and/or mixtures thereof. As used herein, the term "dicarboxylic acid" is intended to include any derivative of terephthalic acid itself and its residues and the dicarboxylic acid in the reaction process for the preparation of a diol. 122661.doc -38- 200819496, including its related acid halide 'esters, half esters, salts, half salts, anhydrides, mixed anhydrides and/or mixtures thereof or residues thereof. The polyesters useful in the present invention can generally be prepared by reacting dicarboxylic acids and diols in substantially equivalent proportions and incorporating them into the polyester polymer in the form of their corresponding residues. The polyester of the present invention may contain a substantially molar ratio of I residues (100 mol%) and diol (and/or polyfunctional hydroxy compound) residues (100 mol%), such that & The total number of moles of the repeating unit is equal to 100% by mole. Thus, the percentage of moles provided in the present disclosure may be acid residues

總莫耳數、二元醇殘基之總莫耳數或重複單S之總莫耳數計。舉例而言，以全部酸殘基計含有10莫耳％間苯二甲酸之聚酯意謂在總共100莫耳％酸殘基中，該聚酯含有10莫耳％之間#二甲酸殘基。因此，每100莫耳酸殘基中存在 1〇莫耳間苯二甲酸殘基。在另一實例中，以全部二元醇殘基計含有30莫耳％ 2,2,4,4_四甲基環丁二醇之聚酯意月在、’、么/、100莫耳％一元醇殘基中，該聚酯含有莫耳％之，’4,4四甲基_1，3-環丁二醇殘基。因此，每1⑻莫耳二元醇殘基中存在30莫耳2,2,4,4·四甲基·M環丁二醇殘基。在本發明之其他態樣中，適用於本發明之聚酯組合物中之聚酯的1可為以下範圍中之至少一者：8〇至2〇〇。〇 ; 8〇至 190°C，· 80至 18〇〇c ; 8〇至 17〇t：;⑼至 16〇。〇;肋至 155X： ; 8〇至 15(rc ; 8(^145χ： ; 8()至14吖·，⑽至^代； 8〇^135°C ； 80^130〇C ； 80^125〇C ； 80J.120°C ； 80 J. H5°C ； 80^n〇〇c ； 80^1〇5°C ； 8〇5.1〇〇〇C ； 80J.95〇C ； 8〇至 9〇°C ; 80 至 85。〇 ; 85 至 200。(：； 85 至 i9(rc ; 85至 122661.doc -39- 200819496 180C ; 85 至 170°C ; 85 至 160°C ; 85 至 155°C ; 85 至 150°C ; 85 至 145°C ; 85 至 140°C ; 85 至 138。(3 ; 85 至 135°C ; 85 至 130C ; 85 至 125°C ; 85 至 120°C ; 85 至 115°C ; 85 至 ll〇°C ; 85 至 105°C ; 85 至 100°C ; 85 至 95°C ; 85 至 90°C ; 90 至 200°C ; 90至 190°C ; 90至 180°C ; 90至 170°C ; 90至 160°C ; 90 至 155°C ; 90 至 150°C ; 90 至 145°C ; 90 至 140°C ; 90 至 138°C ; 90至 135°C ; 90至 130°C ; 90至 125°C ; 90至 120°C ; 90 至 115°C ; 90 至 110°C ; 90 至 l〇5°C ; 90 至 1〇〇。〇 ; 90 至 95°C ; 95 至 200°C ; 95 至 190°C ; 95 至 180°C ; 95 至 170°C ; 95 至 160°C ; 95 至 155°C ; 95 至 150°C ; 95 至 145°C ; 95 至 140°C ; 95 至 138°C ; 95 至 135°C ; 95 至 130°C ; 95 至 125°C ; 95 至 120°C ; 95 至 115°C ; 95 至 110°C ; 95 至 105°C ; 95 至 100°C ； 100 至 200°C ; 100 至 190〇C ; 100 至 180°C ; 100至 170°C ； 100 至 160°C 100 至 155°c 100 至 150°C 100至 145〇C ； 100 至 140〇C 100 至 138°C 100 至 135°C 100至 130°C ； 100 至 125〇C 100 至 120〇C 100 至 115°C 100至 110°C ； 105 至 200〇C 105 至 190〇C 105 至 180〇C 105至 170°C ； 105 至 160〇C 105 至 155〇C 105 至 150〇C 105至 145〇C ； 105 至 140°C 105 至 138〇C 105 至 135〇C 105至 130°C ； 105 至 125〇C 105 至 120〇C 105 至 115〇C 105至 110°C ； 110 至 200°C 110 至 190°C 110 至 180°C 110至 170°C ； 110 至 160〇C 110 至 155°C 110 至 150〇C 110至 145〇C ； 110 至 140〇C 110 至 138〇C 110 至 135〇C 110至 130°C ； 110 至 125°C ； ;110 至 120〇C ； 110 至 115〇C ； 115至 122661.doc -40 - 200819496 200°C ； 115 至 190°C ;115 至 180〇C ; 115 至 170°C ; 115至 160°C ； 115 至 155〇C ;115 至 150〇C ; 115 至 145〇C ; 115至 140°C ； 115 至 138〇C ;115 至 135〇C ; 110 至 130〇C ; 115至 125〇C ； 115 至 120〇C ;120 至 200〇C ; 120 至 190°C ; 120至 180°C ； 120 至 170°C ;120 至 160°C ; 120 至 155°C ; 120至 150°C ； 120 至 145〇C ;120 至 140〇C ; 120 至 138°C ; 120至 135〇C ； 120 至 130°C ;125 至 200〇C ; 125 至 190°C ; 125至 180°C ； 125 至 170°C ;125 至 165〇C ; 125 至 160〇C ; 125至 155〇C ； 125 至 150〇C ;125 至 145〇C ; 125 至 140〇C ; 125至 138〇C ; 125 至 135°C ;127 至 200〇C ; 127 至 190〇C ; 127至 180°C ； 127 至 170°C ;127 至 160〇C ; 127 至 150°C ; 127至 145〇C ； 127 至 140°C ;127 至 138〇C ; 127 至 135〇C ; 130至 200°C ； 130 至 190〇C ;130 至 180°C ; 130 至 170°C ; 130至 160°C ； 130 至 155〇C ;130 至 150°C ; 130 至 145°C ; 130至 140°C ； 130 至 138°C ;130 至 135°C ; 135 至 200〇C ; 135至 190〇C ; 135 至 180°C ;135 至 170〇C ; 135 至 160°C ; 135至 155〇C ； 135 至 150〇C ;135 至 145〇C ; 135 至 140〇C ; 140至 200°C ； 140 至 190°C ;140 至 180°C ; 140 至 170°C ; 140至 160°C ； 140 至 155〇C ;140 至 150〇C ; 140 至 145〇C ; 148至 200°C ； 148 至 190°C ;148 至 180°C ; 148 至 170°C ; 148至 160〇C ; 148 至 155〇C ;148 至 150〇C ; 148°C 以上至 200°C ; 148〇C 以上至190°C ;148°C以上至18〇°C ; 148°C以上至 170〇C ; 148°C 以上至 160°C ; 148°C 以上至 155°C ; 150至 200°C ； 150 至 190°C ;150 至 180°C ; 150 至 170°C ; 150至 122661.doc •41 - 200819496 160°C ; 155 至 190°C ; 155 至 180°C ; 155 至 170°C ;及 155 至 165〇C。在本發明之其他態樣中，適用於本發明之聚酯之二醇組份包括（但不限於）以下範圍組合中之至少一者：約1至小於 90莫耳％之2,2,4,4-四甲基-1，3-環丁二醇、大於1〇莫耳％之乙二醇殘基與約0至約89莫耳％之環己烷二甲醇；}至85莫耳％之2,2,4,4-四甲基- i，3-環丁二醇與15至99莫耳％之乙二醇；1至80莫耳％之252,4,4_四甲基環丁二醇與2〇至99 莫耳％之乙二醇；1至75莫耳％之2,2,4，心四甲基―丨，％環丁二醇與25至99莫耳％之乙二醇；1至7〇莫耳％之2,2,4，扣四甲基-1，3-環丁二醇與3〇至99莫耳％之乙二醇；1至65莫耳％之2,2,4,4-四甲基_1，3_環丁二醇與35至99莫耳。之乙二醇· 。1至60莫耳。/。之2,2,4,心四甲基環丁二醇與4〇至99莫耳 %之乙一醇，；1至55莫耳。/。之^七心四甲基十^環丁二醇 ” 45至99莫耳％之乙二醇；u 5〇莫耳％之2,2，七心四甲基· 1，3-環丁二醇與5()至99莫耳％之乙二醇，· u45莫耳％土之 2’2’4’4-四甲基]，3_環丁二醇與”至的莫耳％之乙二醇；1 至4〇莫耳％之2,2,4,4，基]，3_環丁二醇與6〇至99莫耳％之至抑耳％之2,2,4,4四甲基^環丁二 5㈣莫耳％之乙二醇；咖莫耳％之2,2从四; 1，3-環丁二醇與7〇至99 土旲耳乂之乙一醇；1至25莖且〇/七 2,2,4,4-四甲基3_環丁 ^ 5莫耳/〇之，3 $衣丁二醇與75至99莫耳％之乙一至20莫耳％之2,2,4扣 ^ ^ 1 ，罗土 ―1，3-環丁二醇與80至99莫耳〇/ 之乙二醇；；1至15莫 y異耳、耳0之2,2,4,4-四甲基-1，3-環丁二醇與 122661.doc •42- 200819496 85至99莫耳％之乙二醇；】至1〇莫耳％之2,2,4,4-四^基 1’3_環丁二醇與90至99莫耳％之乙二醇；及⑴莫耳％之 2,2,4,4-四曱基_i，3_環丁二醇與％至99莫耳。之乙二醇。The total number of moles, the total number of moles of diol residues, or the total number of moles of repeating single S. For example, a polyester containing 10 mole % isophthalic acid based on total acid residues means that in a total of 100 mole % acid residues, the polyester contains 10 mole % of # dicarboxylic acid residues. . Therefore, 1 mole of m-isophthalic acid residue is present per 100 moles of acid residue. In another example, the polyester containing 30 moles of 2,2,4,4-tetramethylcyclobutanediol in terms of total diol residues is at, ', /, 100 mole % Among the monohydric alcohol residues, the polyester contains a molar %, '4,4 tetramethyl-1,3-cyclobutanediol residue. Thus, 30 moles of 2,2,4,4·tetramethyl·M cyclobutanediol residues are present per 1 (8) mole of diol residues. In other aspects of the invention, the polyester 1 suitable for use in the polyester composition of the invention may be at least one of the following: 8 Å to 2 Torr. 〇 ; 8〇 to 190°C, · 80 to 18〇〇c; 8〇 to 17〇t:; (9) to 16〇. 〇; rib to 155X: ; 8〇 to 15 (rc; 8(^145χ: ; 8() to 14吖·, (10) to ^ generation; 8〇^135°C; 80^130〇C; 80^125〇 C; 80J.120°C; 80 J. H5°C; 80^n〇〇c; 80^1〇5°C; 8〇5.1〇〇〇C; 80J.95〇C; 8〇 to 9〇° C; 80 to 85. 〇; 85 to 200. (: 85 to i9 (rc; 85 to 122661.doc -39-200819496 180C; 85 to 170 ° C; 85 to 160 ° C; 85 to 155 ° C; 85 to 150 ° C; 85 to 145 ° C; 85 to 140 ° C; 85 to 138. (3; 85 to 135 ° C; 85 to 130 C; 85 to 125 ° C; 85 to 120 ° C; 85 to 115 °C; 85 to ll〇 °C; 85 to 105 ° C; 85 to 100 ° C; 85 to 95 ° C; 85 to 90 ° C; 90 to 200 ° C; 90 to 190 ° C; 90 to 180 ° C; 90 to 170 ° C; 90 to 160 ° C; 90 to 155 ° C; 90 to 150 ° C; 90 to 145 ° C; 90 to 140 ° C; 90 to 138 ° C; 90 to 135 ° C; 90 to 130 ° C; 90 to 125 ° C; 90 to 120 ° C; 90 to 115 ° C; 90 to 110 ° C; 90 to l 〇 5 ° C; 90 to 1 〇〇. 〇; 90 to 95 ° C; 95 to 200 ° C; 95 to 190 ° C; 95 to 180 ° C; 95 to 170 ° C; 95 to 160 ° C; 155 ° C; 95 to 150 ° C; 95 to 145 ° C; 95 to 140 ° C; 95 to 138 ° C; 95 to 135 ° C; 95 to 130 ° C; 95 to 125 ° C; 95 to 120 ° C; 95 to 115 ° C; 95 to 110 ° C; 95 to 105 ° C; 95 to 100 ° C; 100 to 200 ° C; 100 to 190 ° C; 100 to 180 ° C; 100 to 170 ° C; 100 to 160 ° C 100 to 155 ° c 100 to 150 ° C 100 to 145 ° C; 100 to 140 ° C 100 to 138 ° C 100 to 135 ° C 100 to 130 ° C; 100 to 125 ° C 100 to 120 〇C 100 to 115°C 100 to 110°C; 105 to 200〇C 105 to 190〇C 105 to 180〇C 105 to 170°C; 105 to 160〇C 105 to 155〇C 105 to 150〇C 105 To 145〇C; 105 to 140°C 105 to 138〇C 105 to 135〇C 105 to 130°C; 105 to 125〇C 105 to 120〇C 105 to 115〇C 105 to 110°C; 110 to 200 °C 110 to 190 ° C 110 to 180 ° C 110 to 170 ° C; 110 to 160 ° C 110 to 155 ° C 110 to 150 ° C 110 to 145 ° C; 110 to 140 ° C 110 to 138 ° C 110 To 135〇C 110 to 130°C; 110 to 125°C; 110 to 120〇C; 110 to 115〇C; 15 to 122661.doc -40 - 200819496 200 ° C; 115 to 190 ° C; 115 to 180 ° C; 115 to 170 ° C; 115 to 160 ° C; 115 to 155 ° C; 115 to 150 ° C; To 145〇C; 115 to 140°C; 115 to 138〇C; 115 to 135〇C; 110 to 130〇C; 115 to 125〇C; 115 to 120〇C; 120 to 200〇C; 120 to 190 °C; 120 to 180 ° C; 120 to 170 ° C; 120 to 160 ° C; 120 to 155 ° C; 120 to 150 ° C; 120 to 145 ° C; 120 to 140 ° C; 120 to 138 ° C 120 to 135 ° C; 120 to 130 ° C; 125 to 200 ° C; 125 to 190 ° C; 125 to 180 ° C; 125 to 170 ° C; 125 to 165 ° C; 125 to 160 ° C; To 155〇C; 125 to 150〇C; 125 to 145〇C; 125 to 140〇C; 125 to 138〇C; 125 to 135°C; 127 to 200〇C; 127 to 190〇C; 127 to 180 °C; 127 to 170 ° C; 127 to 160 ° C; 127 to 150 ° C; 127 to 145 ° C; 127 to 140 ° C; 127 to 138 ° C; 127 to 135 ° C; 130 to 200 ° C 130 to 190 ° C; 130 to 180 ° C; 130 to 170 ° C; 130 to 160 ° C; 130 to 155 ° C; 130 to 150 ° C; 130 to 145 ° C; 130 to 140 ° C; 130 to 138 ° C; 130 to 135 ° C; 135 to 200 ° C; 135 to 190 ° C; 135 to 180 ° C; 135 to 170 ° C; 160 ° C; 135 to 155 ° C; 135 to 150 ° C; 135 to 145 ° C; 135 to 140 ° C; 140 to 200 ° C; 140 to 190 ° C; 140 to 180 ° C; 140 to 170 ° C; 140 to 160 ° C; 140 to 155 ° C; 140 to 150 ° C; 140 to 145 ° C; 148 to 200 ° C; 148 to 190 ° C; 148 to 180 ° C; 148 to 170 ° C ; 148 to 160〇C; 148 to 155〇C; 148 to 150〇C; 148°C or more to 200°C; 148〇C or more to 190°C; 148°C or more to 18〇°C; To 170〇C; 148°C or more to 160°C; 148°C or more to 155°C; 150 to 200°C; 150 to 190°C; 150 to 180°C; 150 to 170°C; 150 to 122661 .doc •41 - 200819496 160°C; 155 to 190°C; 155 to 180°C; 155 to 170°C; and 155 to 165〇C. In other aspects of the invention, the diol component of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following ranges: from about 1 to less than 90 mole percent of 2, 2, 4 , 4-tetramethyl-1,3-cyclobutanediol, greater than 1 mole % of ethylene glycol residues and from about 0 to about 89 mole % of cyclohexanedimethanol;} to 85 mole % 2,2,4,4-Tetramethyl-i,3-cyclobutanediol with 15 to 99 mol% of ethylene glycol; 1 to 80 mol% of 252,4,4-tetramethylcyclo Butanediol with 2〇 to 99 mol% of ethylene glycol; 1 to 75 mol% of 2,2,4, heart tetramethyl-hydrazine, % cyclobutanediol and 25 to 99 mol% of B Glycol; 1 to 7 mol% of 2,2,4, decansed tetramethyl-1,3-cyclobutanediol and 3 to 99 mol% of ethylene glycol; 1 to 65 mol% 2,2,4,4-Tetramethyl-1,3-cyclobutanediol with 35 to 99 moles. Ethylene glycol·. 1 to 60 moles. /. 2, 2, 4, tetramethylcyclobutanediol with 4 to 99 moles of ethyl alcohol, 1 to 55 moles. /. ^七心四methyl十^cyclobutanediol" 45 to 99 mole % of ethylene glycol; u 5 〇 mole % of 2, 2, heptatetramethyl 1,3-cyclobutanediol With 5 () to 99 mol% of ethylene glycol, · u45 mol% soil 2'2'4'4-tetramethyl], 3_cyclobutanediol and "to the molar % of the second Alcohol; 2 to 2, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4乙环环丁二5(四)mol% glycol; gammon 2%, 2 from 4; 1,3-cyclobutanediol and 7〇 to 99 旲旲乂乙And 〇/seven 2,2,4,4-tetramethyl 3_cyclobutane 5 molar / hydrazine, 3 $ butyl diol and 75 to 99 mol% of B to 1 to 20 mol% of 2, 2,4 deduction ^ ^ 1 , arson - 1,3-cyclobutanediol and 80 to 99 moles / ethylene glycol; 1 to 15 moles of y ears, ears 0 of 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol with 122661.doc •42- 200819496 85 to 99 mol% of ethylene glycol;] to 1 mol% of 2,2,4,4-four ^1'3_cyclobutanediol with 90 to 99 mol% of ethylene glycol; and (1) mol% of 2,2,4,4-tetradecyl_i,3_cyclobutanediol and % To 99 moles . Ethylene glycol.

在本發明之其他態樣中，冑用於本發明之聚醋之二醇植〇份包括（但不限於）以下範圍組合中之至少一者·· 3至1〇莫耳 %之2,2,4,4_四f基·1，3-環丁二醇與90至97莫耳％之乙二私，3至9莫耳。/。之^七心四甲基-^-環丁二醇與“至^莫耳°/❶之乙二醇；及3至8莫耳％之2,2,4,4四甲基·^•環丁二醇與92至97莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚酯之二醇组份包括（但不限於）以下範圍組合中之至少一者：約5至小於 9〇莫耳％之2,2,4,4_四甲基w·環丁二醇與大㈣莫耳％至 %莫耳。/。之乙二醇；5至85莫耳％之2,2,4,4_四甲基#環丁二醇與15至95莫耳 — · 兵斗/〇之乙—私，5至8〇莫耳0/〇之2,2，“_ :甲基·丨，3_環了：醇與跑95莫耳％之乙：醇；5至75莫之2,2,4,心四甲基-1，3.環丁二醇與25至95莫耳％之乙二 =至7〇莫耳%之2,2,4,四甲基二醇與30至二之乙二醇；5至65莫耳％之2,2,4,4-四甲基]，3·環丁二醇與35至95莫耳％之乙二甲# 5至60莫耳％之2,2,4,4·四與條％莫耳％之乙二醇；5至55莫耳％，，，四甲基-1，3-環丁二醇與45至95莫耳. 及5至50莫耳％之2 一知，耳％之乙二醇。 m核丁二醇㈣至95莫在本發明之其他態樣中適用於本發明之聚醋之二醇組 122661.doc -43· 200819496 份包括（但不限於）以下範圍組合中之至少_者·. 5至小㈣莫耳％之2,2,4,4-四甲基環丁二醇與大於5〇莫耳。/。至％莫耳％之乙二醇；5至45莫耳％之2,2,4,4•四甲基％·環丁二醇與55至95莫耳％之乙二醇；5至4()莫耳％之2,2,44_四甲基-i，3-環丁二醇與60至95莫耳％之乙二醇；5至35莫耳❶乂之2,2,4,4-四甲基-u-環丁二醇與65至95莫耳％之乙二醇. f 5至小於35莫耳％之2,2,4,4•四甲基·u•環丁二醇與大於μ 莫耳％至95莫耳％之乙二醇；5錢莫耳％之2,2,4,4_四甲基-1，3-環丁二醇與70至95莫耳％之乙二醇；5至25莫料之 2,2,4,4-四甲基.以環丁二醇與乃至％莫耳％之乙二^ $ 至2〇莫耳％之2,2,4,4_四甲基.以環丁二醇與_95莫耳。/〇之乙二酵；5至15莫耳％之2,2,4,4_四甲基#環丁二醇與 85至95莫耳％之乙二醇；5至10莫耳％之2,2,4,4-四甲基 W環丁二醇與9G至95莫耳％之乙二醇；大於5莫耳小於1〇莫耳％之2,2,4,4·四甲基]，3-環丁二醇與小於90莫耳％至大於95莫耳％之乙二醇；55莫耳％至9.5莫耳％之^4 四甲基環丁二醇與94.5莫耳％线5莫耳％之乙二醇；及6至9莫耳％之2,2,4,4_四甲夷〗3声_ %之乙二醇。 ▲-，-衣丁二醇與94至91莫耳 ::發明之其他態樣中，適用於本發明之聚醋之二醇租不限於）以下範圍組合中之至少—者：約1〇至小至、之2’2,4,4-四甲基-1，3-環丁二醇與大於10莫耳％至約90莫耳％之乙二醇；1〇至莫耳 1 〇夫 + /〇之 2,2,4,4-四甲基- ，％丁二醇與15至90莫耳％之乙二醇；1〇至8〇莫耳％之 122661.doc -44- 200819496 2,2,4,4-四甲基-u·環丁二醇與2〇至9〇莫耳％之乙二醇；⑺ 至75莫耳％之2,2,4,4_四甲基^3.環丁二醇與25至9〇莫耳％之乙二醇；10至70莫耳％之2,2,4,4_四甲基·u環丁二醇與 3〇至9〇莫耳％之乙二醇；10至65莫耳％之2,2,4,4_四甲基、_ 1，3-環丁二醇與35至9()莫耳％之乙二醇；莫耳:之 2,2,4,4_四甲基.以環丁二醇與懈9()莫耳％之乙二醇；1〇至55莫耳％之2,2,4,4_四甲基Μ·環丁二醇與45至列莫耳％之乙二醇；Π)至50莫耳％之2,2,4,4_四甲基#環丁二醇與 5〇至9〇莫耳％之乙二醇；10至小㈣莫耳。/。之2’2,4,4·四甲基-1，3-環了二醇與大於5〇莫耳％至9〇莫耳％之乙二醇；w 至45莫耳％之2,2,4,4-四甲基-1，3·環丁二醇與55至9〇莫耳％之^醇；W莫耳。/。之⑽心甲基^環丁二醇與 90莫耳％之乙二醇·⑺至”莫耳％ 1，3_環丁二醇與65至9〇莫、至"’甲基- 之一甲“3-環丁二醇*二5=於35莫耳％ ”大於65莫耳％至90莫耳％醇；10至30莫耳％之2,2,4,4-四甲基」， 70至90莫耳％之乙二醇· 1〇至 ·' 1 . _ 夫寸/0< 2,2,4,4-四甲基- ，二丁二醇與75至90莫耳%之乙二醇；i。至2。莫耳k 。广甲基十3_環丁二醇與8〇至9〇 1〇至！5莫耳％之2,2,4，心乙一％，及 %之乙二醇。 -，3·核丁二醇與85至90莫耳在本發明之其他態樣中，適用份包括（但不限於）以下範圍組合中之至少=酉曰之二醇組耳％至小於90莫耳％之2,2,4,4 .大於10莫，3 ^ 丁二醇與大於 122661.doc -45- 200819496 1 0莫耳％至小於9〇莫耳％一乙一醇；大於10莫耳％至85莫耳％之2,2,4,4-四甲基-1 3·王夢丁 _ & 、 ^ ，衣丁一醇與15至小於90莫耳。/0之乙二醇；大於10莫耳％至80莫耳吳斗/〇之2,2,4,4-四甲基_；!，3_環 =醇與2。至小於9。莫耳%之乙二醇；大於1〇莫耳㈣耳之2,2,4,4-四甲基-1，3·環丁二醇與25至小於90莫耳％ …醇，·大於10莫耳％至7〇莫耳%之2,2,4,4_四甲基Μ· '丁一酵與30至小於9〇莫耳％之乙二醇，·大㈣莫耳％至 65莫耳％之22,4,4 -四甲美γ 、 0/ > ，甲基]，3,丁二醇與35至小於90莫耳〇之乙一醇；大於1〇莫耳％至6〇莫 1，3-環丁二醇與4〇至小於9〇之，，，四基_ ^ c 旲斗/之乙二醇；大於ίο莫耳0/〇耳❶耳％之2,2,4,4·四甲基-1，3·環丁二醇與45至小於90莫】二醇；大於1G莫耳％至5㈣耳％之2,2，Μ·以基· ，% 丁 —㈣5G至小於9G莫耳％之乙二醇·大於至小於50莫耳％之2,2,4,4_四 ^ 、斗耳。/。至小於90莫耳％之乙H 1 丁二㈣大於50莫、乙一転，大於1〇莫耳％至45莫耳％之乂四甲基+3·環丁二醇與55至小於9〇莫耳％之乙二醇，大於10莫耳％至40莫耳一醇與6。至小於9。莫耳』，，4,4·”基-1，3·環丁二 0/之… 0莫耳/〇之乙二醇；大於莫耳。/。至35莫耳 _ ’ ’，4·四甲基_1’3_環丁二醇與65至小於90莫耳％之乙至小於34莫耳%之2,2,4,…基大於66莫耳％至9〇莫衣丁-知與 ?知，大於〗〇莫耳〇/。至30莫。’，4,4-四甲基#環丁二醇與7〇至之乙二醇；大㈣莫耳％至25莫耳％之2,2,4,4_以基^ 丁-醇與75至小於9G莫耳％之乙：醇·大㈣莫耳^^ 122661.doc -46- 200819496 莫耳％之2,2,4,4-四甲基]，3_環丁二醇與8〇至小於％莫耳。A 之乙二醇；及大於1〇莫耳％至15莫耳0/〇之2,2,4,4_四甲基· 1，3-環丁二醇與85至小於9〇莫耳％之乙二醇。土在本發明之其他態樣中，適用於本發明之聚_之二醇& 份包括（但不限於）以下範圍組合中之至少一者··約Η至小於9〇莫耳％之2,2,4,4_四甲基]，3_環丁二醇與大於1〇莫耳％至約89莫耳％之乙二醇；11至85莫耳％之2,2,4,4·四甲Α 1，3·環丁二醇與15至89莫耳％之乙二醇；"至肋莫耳二 2,2,4,4·四甲基妙環丁二醇與2G至89莫耳％之乙二醇；u 至乃莫耳％之2,2,4,4-四甲基#環丁二醇與μ·莫耳％之乙二醇；U至70莫耳。/。之山义四甲基^-環丁二醇與 3〇至89莫耳％之乙二醇；11至65莫耳％之2,2,4,4_四甲基· 1，3-環丁二醇與35至89莫耳％之乙二醇；莫耳％之 2,2,4,4-四甲基{3-環丁二醇與的至89莫耳％之乙二醇；u 至55莫耳…，以+四甲基〜-環丁二醇與似的莫耳％之乙二醇；U5〇莫耳％之2,2,4,4•四甲基^環丁二醇與 50至89莫耳％之乙-酿· +之乙一％，u至小於50莫耳〇/〇之2,2,4,4_四甲基-1’3-環丁二醇與大於5〇莫耳％至89莫耳％之乙二醇· Η 至45莫耳％之2,2,4,4·四甲基]，3-環丁二醇與55至89莫耳％之乙二醇』至40莫耳％之2,2,4,4·四甲基#環丁 ⑼謂莫耳％之乙二醇；11至35莫耳％之2,2,4,4-四甲某 Μ-環丁二醇與65至89莫耳％之乙二醇；u錢莫耳。:之 2’2’4’4·四f基· τ二醇與7()至89莫耳％之乙二醇至24莫耳％之2,2,4,4_四^環丁二醇與76至89莫耳％ 122661.doc •47· 200819496 =二醇；及莫耳%之2,2,4,4•四甲基仏環與75至89莫耳％之乙二醇。在本發明之其他態樣中，適心本發明之聚酯之二醇组份包括(但不限於)以下範圍組合中之至少一者· 於 9〇莫耳％之2,2,4 4-四甲其！ 1^ ㈣：。，哀丁二醇與大於10莫耳％至丁一、t °之乙二醇’· 12至85莫耳^…，心四甲基-以-環 =兵15至88莫耳％之乙二醇，·以⑼莫耳％之2,2乂心四甲基-1，3-環丁二醇與2〇至88莫耳％之乙二醇· μ f =%之2,2,4,4·四甲基·1，3_環丁二醇與25至88莫耳％之乙二醇，12至70莫耳％之22,4,4-四甲其13#^ 莖且0/ 四丁二醇與30至88 t 二醇；12至65莫耳％之2,2,4,4·四甲基#環丁一醇與35至88莫耳％之7 -妒· …s 私，12至60莫耳％之2,2,4,4-四土，&丁-醇與40至88莫耳％之乙二醇；12至55莫耳 A 之 2,2,4,4_ 四甲其 1 1 rps-r· 土_，衣丁二醇與45至88莫耳％之乙二醇，· 12至50莫耳％之2,2,4,4_四甲土 1,3衣丁二醇與50至88 ;:。之乙二醇；12至小於50莫耳％之2,2,4,4_四甲m =二醇與大於50莫耳％至88莫耳％之乙二醇；i2至仰 =〜，4,4·四甲基#環丁二醇與55至、醇；12至40莫耳％之2,2,4,4_四乙一莫耳。/。之乙二醇；12至35……哀丁二醇與60至88 一、耳。之2,2,4,4_四甲基_；[ 3-環丁二醇與65至88莫耳％之7 ^ 丁 f A12至3G莫耳％之2,2,4,4-四土-1，3,丁二醇與7〇至88莫耳％之乙二醇；η至 4之2,2,4,4 -四甲美_彳1班、斗土，_衣丁二醇與76至88莫耳〇/0之乙二及12至25莫耳％之2,2,4,4-四甲基環丁二醇與心 12266l.doc -48- 200819496 88莫耳％之乙二醇。 ^本發明之其他態樣中，適用於本發明之聚酯之二醇也伤匕括（但不限於）以下範圍組合中之至少—者：㈣至小於90莫耳〇/0之2,2,4,4-四甲美！ 3 s 一至約85莫耳％之乙-醇.^_ 醇與大於10莫耳％、之乙一和，U至85莫耳％之2 2 4 4_ 環丁二醇與15至85莫耳％之,—^ T基一兵耳/〇之乙一醇；15至80莫耳％之，’，-四甲基-u·環丁二醇與2()至85莫耳％之乙至75莫耳％之2,2,4,4-四甲基w-環丁二醇與w莫耳％之乙二醇H5至70莫耳％之2’2,4,4_四甲基醇 30至85莫耳％之r 一舻· 1C 衣』一％與 13 r 丁乙一私，15至65莫耳％之2,2,4,4·四甲基_ _哀丁二醇與35至85莫耳％之乙二醇，· Η·莫耳。/。之，，认四甲基_U·環丁二醇與4()至85 至55莫耳％之2,2,4,4_四己一％，15 土，-衣丁二醇與45至85莫耳％之乙一％，15至5〇莫耳％之 50至85莫耳％之乙-萨.ις 甲基_1，3-核丁二醇與 A 13 h —I 15至小於5G莫耳％之2,2,4,4_四甲丁：醇與大於5G莫耳％至85莫耳％ ::5莫:%之2,2,4,4,甲基·— 之乙二_ ; 15至40莫耳％之2,2,4,4_四^基 60至85莫耳〇/0之r 一舻· μ 衣Ί —知與 j 3 一 ’至35莫耳。之2,2,4,4-四甲基_ Μ_核丁二醇與65至85莫耳％之一環丁二醇與7。至8二= 之一甲基·環丁二醇一之乙一醇，及15至24莫耳％之2,2,4,4^、與76至85莫耳％之乙二醇。土，3-% 丁二醇 122661.doc -49- 200819496 在本發明之其他態樣中，適用於本發明之Μ之二㈣份包括（但不限於）以下範圍組合中之一、 ^ 一考•約2 0至小In other aspects of the invention, the glycerol phytochemicals used in the present invention include, but are not limited to, at least one of the following ranges of combinations: 3 to 1 〇% of 2, 2 4,4_tetraf-group·1,3-cyclobutanediol with 90 to 97 mol% of ethylene, 3 to 9 m. /. ^7-heart tetramethyl-^-cyclobutanediol with "to ^ Mo Mo / ❶ glycol; and 3 to 8 mol% of 2, 2, 4, 4 tetramethyl · ^ • ring Butanediol and 92 to 97 mole % of ethylene glycol. In other aspects of the invention, the diol component of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following combinations of ranges : about 5 to less than 9 〇 mol% of 2,2,4,4_tetramethyl w·cyclobutanediol and large (tetra) mol% to % mol% of ethylene glycol; 5 to 85 Mo 2% of the ear, 2,4,4_tetramethyl#cyclobutanediol and 15 to 95 moles - · Bing / 〇 — B - private, 5 to 8 〇 Mo Er 0 / 〇 2, 2, "_: methyl · 丨, 3_ ring: alcohol and run 95 moles of B: alcohol; 5 to 75 moles of 2, 2, 4, heart tetramethyl-1, 3. cyclobutanediol and 25 to 95 mol% of ethylene = 2 to 7 mol% of 2, 2, 4, tetramethyl glycol and 30 to 2 ethylene glycol; 5 to 65 mol% of 2, 2, 4, 4-tetramethyl], 3·cyclobutanediol and 35 to 95 mol% of ethyl dimethyl #5 to 60 mol% of 2, 2, 4, 4·4 and strip % mol% of E2 Alcohol; 5 to 55 mol%,, tetramethyl-1,3-cyclobutanediol and 45 to 95 mol. and 5 to 50 mol% Known, ear% ethylene glycol. M-nuclear butanediol (tetra) to 95% is suitable for use in the polyester diol group 122661.doc-43·200819496 of the present invention in other aspects of the invention including, but not limited to, at least · 5 to small (four) Mo Er% of 2,2,4,4-tetramethylcyclobutanediol with more than 5 〇 Mo. /. To % mol% of ethylene glycol; 5 to 45 mol% of 2,2,4,4•tetramethyl%·cyclobutanediol and 55 to 95 mol% of ethylene glycol; 5 to 4 ( 2% of 2,2,44_tetramethyl-i,3-cyclobutanediol with 60 to 95 mole % of ethylene glycol; 5 to 35 moles of 2, 2, 4, 4 - tetramethyl-u-cyclobutanediol with 65 to 95 mol% of ethylene glycol. f 5 to less than 35 mol% of 2,2,4,4•tetramethyl·u•cyclobutanediol Ethylene glycol with a % to 95 mol% greater than μ mol; 2,2,4,4_tetramethyl-1,3-cyclobutanediol and 5 to 95 mol% of 5 mol% Ethylene glycol; 5 to 25 moles of 2,2,4,4-tetramethyl. Cyclobutanediol and even % mole% of the ethane 2 to 2 〇% of the 2,2,4 , 4_ tetramethyl. with cyclobutanediol and _95 mol. / 〇乙二 ;; 5 to 15 mol% of 2, 2, 4, 4 _ tetramethyl # cyclobutanediol and 85 to 95 mol% of ethylene glycol; 5 to 10 mol% of 2 , 2,4,4-tetramethyl W cyclobutanediol and 9G to 95% by mole of ethylene glycol; more than 5 moles less than 1 mole% of 2,2,4,4·tetramethyl] , 3-cyclobutanediol with less than 90 mol% to more than 95 mol% of ethylene glycol; 55 mol% to 9.5 mol% of ^4 tetramethylcyclobutanediol and 94.5 mol% line 5 Mole% of ethylene glycol; and 6 to 9 moles of 2, 2, 4, 4_ four armored 3 sounds _% of ethylene glycol. ▲-,-butylbutanediol and 94 to 91 moles: In other aspects of the invention, the glycol diols suitable for use in the present invention are not limited to at least one of the following combinations of ranges: about 1 Torr to Small to 2'2,4,4-tetramethyl-1,3-cyclobutanediol with more than 10 mol% to about 90 mol% of ethylene glycol; 1 〇 to Moer 1 coward + /〇2,2,4,4-tetramethyl-, % butanediol with 15 to 90 mol% of ethylene glycol; 1〇 to 8〇 mol% of 122661.doc -44- 200819496 2, 2,4,4-Tetramethyl-u·cyclobutanediol with 2〇 to 9〇% of ethylene glycol; (7) to 75mol% of 2,2,4,4_tetramethyl^3 Cyclobutanediol with 25 to 9 mole % of ethylene glycol; 10 to 70 mole % of 2,2,4,4_tetramethyl·ucyclobutanediol and 3 to 9 moles % of ethylene glycol; 10 to 65 mol% of 2,2,4,4-tetramethyl, 1,3-1,3-cyclobutanediol and 35 to 9 () mol% of ethylene glycol; : 2,2,4,4_tetramethyl. Cyclobutanediol and slack 9 () molar % of ethylene glycol; 1 〇 to 55 mol% of 2,2,4,4_4 Base Μcyclobutanediol with 45 to Lem% of ethylene glycol; Π) to 50 mol% of 2,2,4,4_tetramethyl#cyclobutanediol and 5〇 to 9 〇耳 % glycol; 10 to small (four) Mo. /. 2'2,4,4·tetramethyl-1,3-cyclohexane diol with more than 5 〇 mol% to 9 〇 mol% of ethylene glycol; w to 45 mol% of 2, 2, 4,4-Tetramethyl-1,3.cyclobutanediol and 55 to 9 mole % of alcohol; W Moer. /. (10) Heart methyl^cyclobutanediol with 90 mol% of ethylene glycol · (7) to "mol% 1,3_cyclobutanediol with 65 to 9 〇 mo, to " 'methyl - one A "3-cyclobutanediol * bis 5 = 35 mol %" is greater than 65 mol % to 90 mol % alcohol; 10 to 30 mol % of 2,2,4,4-tetramethyl", 70 to 90 mol% of ethylene glycol · 1 〇 to · ' 1 . _ husband / 0; 2, 2, 4, 4-tetramethyl-, dibutyl diol and 75 to 90 mol% of B Glycol; i. To 2. Moer k. Wide methyl 10 3 -cyclobutanediol with 8 〇 to 9 〇 1 〇 to! 5 moles of 2, 2, 4, heart B%, and % of ethylene glycol. -, 3·nuclear butanediol and 85 to 90 moles In other aspects of the invention, suitable proportions include, but are not limited to, at least = 酉曰 diol group ear % to less than 90 2%, 2, 4, 4 of the ear, greater than 10 moles, 3 ^ butanediol and greater than 122661.doc -45- 200819496 1 0 mole % to less than 9 mole % % ethyl alcohol; greater than 10 mole % Up to 85 mol% of 2,2,4,4-tetramethyl-1 3·Wang Meng Ding _ &, ^, pentyl alcohol and 15 to less than 90 m. /0 of ethylene glycol; greater than 10 moles to 80 moles of Wudou / 〇 2,2,4,4-tetramethyl _;!, 3_ ring = alcohol and 2. To less than 9. Mole % of ethylene glycol; more than 1 〇 Mo (4) 2,2,4,4-tetramethyl-1,3·cyclobutanediol and 25 to less than 90 mol% alcohol, · more than 10 Molar% to 7〇Mole% of 2,2,4,4_tetramethylhydrazine· 'Ding Yi leaven with 30 to less than 9〇 mol% of ethylene glycol, · big (four) Moer% to 65 Mo 22% of the ear, 4,4 - tetramethyl γ, 0/ > , methyl], 3, butanediol and 35 to less than 90 moles of ethyl alcohol; greater than 1 mole % to 6 moles 1,3-cyclobutanediol with 4 〇 to less than 9 ,,,, tetra group _ ^ c 旲 / / glycol; greater than ίο Mo 0 / 〇 ear % 2%, 2, 4, 4·tetramethyl-1,3·cyclobutanediol and 45 to less than 90 moles of diol; greater than 1G mole% to 5 (four) ear% of 2,2, Μ·I group·, % ——(4) 5G to less than 9G mol% of ethylene glycol · greater than to less than 50 mol% of 2, 2, 4, 4_ four ^, bucket ears. /. To less than 90 mol% of B H 1 butyl (tetra) is greater than 50 mol, B 転, greater than 1 〇 mol % to 45 mol % of 乂 tetramethyl + 3 · cyclobutanediol and 55 to less than 9 〇 Mo Ethylene glycol in the ear, greater than 10 mol% to 40 mol% alcohol and 6. To less than 9. Moer, ,, 4,4·"-base-1,3·cyclobutene 2/... 0 Mo/〇 glycol; greater than Mohr./. to 35 Moer _ ' ', 4·4 Methyl 1 '3_cyclobutanediol with 65 to less than 90 mol% of B to less than 34 mol% of 2,2,4,... base is greater than 66 mol% to 9 〇衣 - Know, greater than 〖〇莫耳〇/. to 30 Mo. ', 4,4-tetramethyl #cyclobutanediol and 7 〇 to ethylene glycol; large (four) Moer% to 25 mol% of 2 , 2, 4, 4_ to base ^ butanol and 75 to less than 9G mol% of B: alcohol · big (four) Moer ^ ^ 122661.doc -46- 200819496 Mo Er% of 2,2,4,4 -tetramethyl], 3_cyclobutanediol and 8 〇 to less than % molar. A glycol; and more than 1 〇 mol% to 15 mol 0/〇 2, 2, 4, 4 _ Tetramethyl·1,3-cyclobutanediol and 85 to less than 9 mole % of ethylene glycol. Soil In other aspects of the invention, the poly-diol & (but not limited to) at least one of the following combinations of ranges: from about 2 to 2,4,4-tetramethyl], 3 to cyclobutanediol, and more than 1 mole. % to about 89 mol% of ethylene glycol; 11 to 85 mol% of 2, 2,4,4·tetramethyl hydrazine 1,3·cyclobutanediol and 15 to 89 mol% of ethylene glycol; " to ribbed 2,2,4,4·tetramethyl methylene ring Glycol with 2G to 89% by mole of ethylene glycol; u to mole% of 2,2,4,4-tetramethyl#cyclobutanediol and μ·mol% of ethylene glycol; U to 70 mol. /. of the mountain tetramethyl-cyclobutanediol and 3 to 89 mol% of ethylene glycol; 11 to 65 mol% of 2,2,4,4_tetramethyl 1,3-cyclobutanediol with 35 to 89 mol% of ethylene glycol; mol% of 2,2,4,4-tetramethyl{3-cyclobutanediol to 89% by mole Ethylene glycol; u to 55 mol..., with + tetramethyl--cyclobutanediol and ethylene glycol-like %; U5 〇 mol% of 2,2,4,4•tetramethyl ^cyclobutanediol with 50 to 89 mol% of B-brewed + 5%, u to less than 50 mol 〇 / 〇 2,2,4,4_tetramethyl-1'3-cyclobutyl Glycol with more than 5 〇 mol% to 89 mol% of ethylene glycol · Η to 45 mol% of 2,2,4,4·tetramethyl], 3-cyclobutanediol and 55 to 89 Ear% of ethylene glycol to 40% by mole of 2,2,4,4·tetramethyl#cyclobutyl (9) is a molar % of ethylene glycol; 11 to 35 moles of 2, 2, 4, 4-四甲一Μ- Butanediol with 65 to 89 mol% of ethylene glycol; u Qianmoer.: 2'2'4'4·tetrafyl·taudiol and 7 () to 89 mol% of ethylene glycol Up to 24 mol% of 2,2,4,4_tetra-cyclobutanediol and 76 to 89 mol% 122661.doc •47· 200819496=diol; and mol% of 2,2,4,4 • Tetramethyl anthracene ring with 75 to 89 mole % ethylene glycol. In other aspects of the invention, the diol component of the polyester of the invention is commensurate with, but not limited to, at least one of the following combinations of ranges: 2, 2, 4 4- Four of them! 1^ (4):. , succinyl diol with more than 10 mol% to butyl, t ° ethylene glycol '· 12 to 85 m ^ ^, heart tetramethyl-to-ring = soldiers 15 to 88 mol% of the second Alcohol, · (9) Mo Er% of 2, 2 乂 heart tetramethyl-1,3-cyclobutanediol and 2 〇 to 88 mol% of ethylene glycol · μ f =% of 2, 2, 4, 4·tetramethyl·1,3_cyclobutanediol with 25 to 88 mol% of ethylene glycol, 12 to 70 mol% of 22,4,4-tetramethyl 13#^ stem and 0/four Butanediol with 30 to 88 t diol; 12 to 65 mol% of 2,2,4,4·tetramethyl#cyclobutanol and 35 to 88 mol% of 7 -妒· ...s private, 12 to 60 mol% of 2,2,4,4-four soils, &butanol and 40 to 88 mol% of ethylene glycol; 12 to 55 mol A of 2,2,4,4_four It is 1 1 rps-r· soil _, butyl diol and 45 to 88 mol% ethylene glycol, · 12 to 50 mol% of 2, 2, 4, 4 _ tetramethine 1, 3 clothes Butanediol with 50 to 88;:. Ethylene glycol; 12 to less than 50 mol% of 2,2,4,4_tetramethyl m=diol and more than 50 mol% to 88 mol% of ethylene glycol; i2 to elevation=~, 4 4, tetramethyl #cyclobutanediol with 55 to, alcohol; 12 to 40 mol% of 2,2,4,4_tetraethylene-mole. /. Ethylene glycol; 12 to 35... butyl diol with 60 to 88 Å, ear. 2,2,4,4_tetramethyl-; [3-cyclobutanediol with 65 to 88 mol% of 7 ^ butyl f A12 to 3G mol% of 2,2,4,4-four earth -1,3, butanediol and 7 to 88 mol% of ethylene glycol; η to 4 of 2, 2, 4, 4 - tetramethyl _ 彳 1 class, soil, _ butyl diol and 76 to 88 moles / 0 of the second and 12 to 25 moles of 2,2,4,4-tetramethylcyclobutanediol and heart 12266l.doc -48- 200819496 88 moles of the second alcohol. In other aspects of the invention, the diols of the polyesters suitable for use in the present invention also include, but are not limited to, at least one of the following ranges: (iv) to less than 90 moles/0 of 2, 2 , 4, 4- four beautiful! 3 s to about 85 mol% of ethyl alcohol. ^_ alcohol with more than 10 mol %, 乙一和, U to 85 mol% of 2 2 4 4 _ cyclobutanediol and 15 to 85 mol% , -^ T base one ear / 〇乙一 ;; 15 to 80 mol%, ', - tetramethyl-u · cyclobutanediol and 2 () to 85 mol% of B to 75 m % of 2,2,4,4-tetramethyl w-cyclobutanediol with w mol% of ethylene glycol H5 to 70 mol% of 2'2,4,4-tetramethylol 30 to 85莫 % 之舻 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 % of ethylene glycol, · Η · Mo Er. /. , tetramethyl-U-cyclobutanediol and 4 () to 85 to 55 mol% of 2,2,4,4_tetrahexan%, 15 soil, - butyl diol and 45 to 85% by mole of B%, 15 to 5 〇% by mole of 50 to 85 moles of B-Sa. ς 甲基 methyl 1,3-1,3-butanediol with A 13 h —I 15 to less than 5G 2%, 2,4,4_tetramethyl butyl: alcohol with more than 5G mol% to 85 mol% ::5 Mo:% of 2, 2, 4, 4, methyl · - B2 15 to 40 moles of 2, 2, 4, 4_ four ^ 60 to 85 moles / 0 of a 舻 · μ Ί - know and j 3 a ' to 35 moles. 2,2,4,4-Tetramethyl-indole-nuclear butanediol with 65 to 85 mol% of a cyclobutanediol and 7. To 8 sec = one methyl cyclobutanediol monoethyl alcohol, and 15 to 24 mol% of 2, 2, 4, 4^, and 76 to 85 mol% of ethylene glycol. Soil, 3-% butanediol 122661.doc -49- 200819496 In other aspects of the invention, two (four) parts suitable for use in the present invention include, but are not limited to, one of the following combinations of ranges, ^ • About 20 to small

於莫耳％之2,2,4,4_四曱基^環丁二醇與大於Μ莫耳％至約80莫耳％之乙二醇；20至85莫耳％之2,2,4,4_四甲基 M-環丁二醇與15至80莫耳％之乙二醇；莫耳^ 2,2,4,4-四甲基-D·環丁二醇與2〇至8〇莫耳％之乙二醇.π 至75莫耳％之2,2,4,4·四甲基^環丁二醇與25謂莫耳％之乙二醇；20至70莫耳％之2,2,4,4_四甲基]’3_環丁二醇盘 30至8〇莫耳％之乙二醇；2〇至65莫耳％之22,4,4_四甲基_ 環丁二醇與35至80莫耳％之乙二醇；2〇至6〇莫耳％之 2’2’4’4-四甲基'3-環丁二醇與4〇至8〇莫耳％之乙二醇；2〇以莫耳％之2,2,4,4·四甲基.以環丁二醇與似⑼莫耳％之乙二醇；20至50莫耳％之2,2,4,4_四甲基#環丁二 5〇至8〇莫耳％之乙二醇旧至小㈣莫耳％之2,2,4,4·/甲基環丁二醇與大㈣莫耳％至8()莫耳％之乙二醇；⑼ 至45莫耳之2,2,4,4_四甲基環丁二醇與μ請莫耳％之乙二醇^至4〇莫耳％之2,2,4,4.四甲基.i,3•環丁二醇血 60至80莫耳％之乙二醇；2〇至 w 夫今/0之2,2,4,4-四甲基- ，3-壤丁二醇與65至8〇莫 *斗/〇之乙一醇；20至30莫耳％之广义四甲基#環丁二醇與7〇至8〇莫耳％之乙二醇；及 %之乙二醇。甲基#% 丁二醇與75謂莫耳月之其他態樣中，適用於本發明之聚s旨之二醇組 (但不限於)以下範圍組合中之至少-者：約25至小 122661.doc -50- 200819496 Γ 於9〇莫耳％之2,2,4,4_四甲基環丁二醇與大㈣莫耳％ J75莫耳%之乙二醇；25至85莫耳%之2,2,4,4-四甲基十3_ 壤丁二醇與15至75莫耳％之乙二醇；25至8〇莫耳％之 2,2,4,4-四甲基-1，3_環丁二醇與20至75莫耳％之乙二醇；25 至75莫耳％之2,2,4,4·四甲基十3-環丁二醇與25至75莫耳％之乙U至70莫耳％之2,2,4,4_四甲基#環丁二 3〇至75莫耳。之乙：醇；25至65莫耳％之2,2’4,4_四甲基、_ 二醇與35至75莫耳%之乙二醇；25至6〇莫耳%之，’’四甲基_1，3，丁二醇與4()至75莫耳％之乙二醇；^ 至55莫耳％之2,2,4,4•四甲基^環丁二醇與mm莫耳％ =乙二醇；25至5G莫耳％之2,2,4,4·四W環丁二醇盥、耳之乙一知，25至小於50莫耳％之2,2,4,4_四甲土 _1，3-核丁二醇與大於5G莫耳％至75莫耳％之乙至45莫耳％之2,2,4,4·四甲基W•環丁二醇與55至75莫耳％之^醇；25錢莫耳％之2,2,4,4_四甲基]，3_環丁二醇與 s75莫耳％之乙二醇；25至35莫耳％之2,2,4,4-四甲基· ::二丁 —酵與Μ至75莫耳%之乙二醇；及25至3〇莫耳%之，，四甲基丄3-環丁二醇與70至75莫耳％^_。 ^本發明之其他態樣中，適用於本發明之聚酿之二醇组括(但不限於)以下範圍組合中之至少-者：約3〇幻 Π莫耳—四甲基*環丁二醇二丁：物5至7㈣㈣耳^ ，以，4-四f基+3·環丁二醇與2〇至7〇莫耳％之乙二醇；％ 122661.doc -51 - 200819496 耳%之2,2,4,4,甲基十3-環丁二醇與25至70莫耳％之乙二醇1至7〇莫耳％之2,2从四甲基·^環丁二 3〇至莫耳％之乙二醇；3()至65莫耳％之2,2,4,4_四甲基_ 1，3-環丁二醇與35至7〇莫耳％ 1 土 9 9 . ^ 、乙—醇，· 30至60莫耳％之，2，M_四甲基]，3·環丁二醇與w莫耳。之乙二醇；30 至55莫耳％之2,2,4,4-四甲基_；[3产丁 T丞1，3·% 丁二醇與45至7〇莫 5之〇=;3°至5〇莫耳%之2,2,4,4-四甲基糾^ A 1、耳/°之乙—酵；3G至小於5㈣耳％之2,2,4,4_四甲基，Γ環丁二醇與大於50莫V莫耳%之乙二醇；3〇至45莫耳。/。之2,2,4,4-四甲基_丨3淨 > ^ ，衣丁二醇與Μ至70莫耳％之=;3〇至4。莫耳…二—基-⑶環 60至70莫耳％之乙二醇；3〇至 I、 ! . _ 夬 + /〇之 2,2,4,4_四甲基· 1，3-% 丁二醇與65至7〇莫耳％之乙二醇。 =發明之其他態樣中，適用於本發明之㈣之二醇电伤υ括（但不限於）以下範圍組心主少一者••约is萃r 於90莫耳。/。之2 2,4,4-四甲基_丨3 ρ ^ 至約65Μ且。/ ^ 丁二醇與大於10莫耳％ i 1 丁 °之m至85莫耳％之2，以，4-四甲基_ ”7 醇與15至65莫耳％之乙二醇莫耳％之至，四甲基#環丁二醇與2。至65莫耳%之 =莫耳。/❶之一甲基·U3_環丁二醇與咖之乙二醇；35至7〇莫耳％、2,2,4,4_tetradecylcyclobutanediol with more than Μmol% to about 80 mol% of ethylene glycol; 20 to 85 mol% of 2,2,4 , 4_tetramethyl M-cyclobutanediol with 15 to 80 mol% of ethylene glycol; Mo 2 ^ 2,2,4,4-tetramethyl-D·cyclobutanediol and 2〇 to 8 〇 mol% of ethylene glycol. π to 75 mol% of 2,2,4,4·tetramethyl^cyclobutanediol and 25 mol% of ethylene glycol; 20 to 70 mol% 2,2,4,4_tetramethyl]'3_cyclobutanediol tray 30 to 8 〇 mol% of ethylene glycol; 2 〇 to 65 mol% of 22,4,4_tetramethyl _ Cyclobutanediol with 35 to 80 mol% of ethylene glycol; 2〇 to 6〇 mol% of 2'2'4'4-tetramethyl'3-cyclobutanediol with 4〇 to 8〇莫Ethylene glycol in the ear; 2% 2,2,4,4·tetramethyl in mol%, ethylene glycol in cyclobutanediol and (9) mol%; 20 to 50 mol% , 2,4,4_tetramethyl#cyclobutane 5〇 to 8〇mol% of ethylene glycol old to small (four) mole% of 2,2,4,4·/methylcyclobutanediol Large (four) molar % to 8 () molar % of ethylene glycol; (9) to 45 moles of 2,2,4,4_tetramethylcyclobutanediol and μ please Mo % of ethylene glycol ^ to 4〇莫耳% of 2,2,4,4. .i, 3 • cyclobutanediol blood 60 to 80 mol% of ethylene glycol; 2〇 to w fujin/0 of 2, 2,4,4-tetramethyl-, 3-dit-butanediol and 65 to 8 〇 * 〇 / 〇乙 ; ;; 20 to 30% by mole of generalized tetramethyl #cyclobutanediol and 7 〇 to 8 〇 mol% of ethylene glycol; and % of ethylene glycol. Among other aspects of methyl #% butanediol and 75, Mohr's, it is suitable for the diol group of the present invention (but not limited to) at least one of the following ranges: about 25 to 122661 .doc -50- 200819496 2 2,2,4,4_tetramethylcyclobutanediol and large (tetra) mol% J75% by weight of ethylene glycol; 25 to 85 mol% 2,2,4,4-Tetramethyl-10-3-tert-butylene glycol with 15 to 75 mol% of ethylene glycol; 25 to 8 mol% of 2,2,4,4-tetramethyl- 1,3_cyclobutanediol with 20 to 75 mol% of ethylene glycol; 25 to 75 mol% of 2,2,4,4·tetramethyltri-3-cyclobutanediol with 25 to 75 mo Ears of B% to 70% of 2,2,4,4_tetramethyl#cyclobutene 3 to 75 moles. B: Alcohol; 25 to 65 mol% of 2,2'4,4_tetramethyl, _diol and 35 to 75 mol% of ethylene glycol; 25 to 6 mol%, '' Tetramethyl-1,3,butanediol with 4 () to 75 mol% of ethylene glycol; ^ to 55 mol% of 2,2,4,4•tetramethyl^cyclobutanediol and mm Moer % = ethylene glycol; 25 to 5G mol% of 2, 2, 4, 4 · tetra W cyclobutanediol oxime, ear one know, 25 to less than 50 mol% of 2, 2, 4, 4_tetramethyl _1,3-nuclear butanediol with more than 5G mol% to 75 mol% of B to 45 mol% of 2,2,4,4·tetramethyl W•cyclobutanediol With 55 to 75 mol% of alcohol; 25 money mol% of 2,2,4,4_tetramethyl], 3_cyclobutanediol and s75 mol% of ethylene glycol; 25 to 35 Mo 2% of 2,2,4,4-tetramethyl-:-dibutyl-fermentation and hydrazine to 75 mol% of ethylene glycol; and 25 to 3 mol% of tetramethyl hydrazine Cyclobutanediol with 70 to 75 mol %^. In other aspects of the invention, the diols suitable for use in the present invention include, but are not limited to, at least one of the following ranges: about 3 〇 Π Π — 四 - tetramethyl * Cyclobutane Dibutyl alcohol: 5 to 7 (four) (four) ear ^, to 4-tetrafyl + 3 · cyclobutanediol and 2 to 7 moles of ethylene glycol; % 122661.doc -51 - 200819496 2,2,4,4,methyl-tricyclobutanediol with 25 to 70 mol% of ethylene glycol 1 to 7 mol% of 2,2 from tetramethyl·^cyclobutane 3〇 To the molar % of ethylene glycol; 3 () to 65 mol% of 2,2,4,4_tetramethyl-1,3-cyclobutanediol and 35 to 7 moles % 1 soil 9 9 ^, B-alcohol, · 30 to 60 mol%, 2, M_tetramethyl], 3·cyclobutanediol and w-mole. Ethylene glycol; 30 to 55 mol% of 2,2,4,4-tetramethyl-; [3 butyl T 丞 1,3·% butanediol and 45 to 7 〇 Mo 5 〇 =; 3° to 5〇% of 2,2,4,4-tetramethyl-correction A 1 , ear/° of B-fermented; 3G to less than 5 (four) ear of 2,2,4,4_four Base, anthracene cyclobutanediol with greater than 50 moles of V moles of ethylene glycol; 3 to 45 moles. /. 2,2,4,4-tetramethyl-丨3 net > ^ , butyl ethene and hydrazine to 70 mol% = 3 〇 to 4. Mohr...di-base-(3) ring 60 to 70 mol% of ethylene glycol; 3〇 to I, !. _ 夬+ /〇2,2,4,4_tetramethyl·1,3-1,3- Butanediol with 65 to 7 moles of ethylene glycol. In other aspects of the invention, the diol electrical injury (4) which is suitable for use in the present invention includes, but is not limited to, the following range: one of the main groups is less than one. /. 2 2,4,4-tetramethyl_丨3 ρ ^ to about 65 Μ and. / ^ Butanediol with more than 10 mol % i 1 d ° ° to 85 mol % of 2, to 4-tetramethyl _ -7 alcohol and 15 to 65 mol % of ethylene glycol molar % Up to, tetramethyl #cyclobutanediol with 2 to 65 mol% = Moer. / ❶ one methyl · U3_ cyclobutanediol and coffee glycol; 35 to 7 〇 Mo %,

30至65莫耳％之乙-醢甲基丁二醇與 ^ ” 私，35至65莫耳％之2,2,4’4-四甲A 1，3-% 丁二醇與35至65莫土 2,2,4,4-四甲A 13rT .乙—知，35至60莫耳％之甲基_1’3,丁二醇與4〇至65莫耳％之乙二醇飞 122661.doc -52- 200819496 至55莫耳％之2,2,4,4·四甲基]，3_環丁二醇與45·莫耳％之乙二醇；35至50莫耳％之2,2,4,4_四甲基-環丁二醇與 50至65莫耳％之乙二醇；35至小於5()莫耳％之2,2,4,心四甲基Μ環丁二醇與大於50莫耳％至65莫耳％之乙二醇；35 至45莫耳％之2,2,4,4.四甲基十3-環丁二醇與55至65莫耳％之乙二醇；35至40莫耳％之2,2,4,4四甲基·^•環丁二醇愈 60至65莫耳％之乙二醇。 ^ 在本發明之其他態樣巾，_於本發明之㈣之二醇组份包括（但不限於）以下範圍組合中之至少小於9〇莫耳™四甲基環丁二醇與大於轉耳：；至約莫耳％之乙二醇；40至85莫耳％之2,2,4,4_四甲其環丁二醇與15至60莫耳％之乙二醇；4〇至8〇莫耳％之 2.2.4.4- 四甲基.以環丁二醇與2〇至6〇莫耳❶之乙二醇；扑至75莫耳％之2,2,4,4四甲基-u-環丁二醇與25至的莫耳％之乙二醇；40至70莫耳％之2,2,4,4•四甲基·^-環丁二醇愈 3〇至6〇莫耳％之乙：醇w莫耳％之2,2,4,4•四甲基_ 1，3-環丁二醇與35至6〇莫耳％之乙二醇，· 4〇至⑼莫耳％之 2.2.4.4- 四甲基_M-環丁二醇與4〇至6〇莫耳％之乙二醇；仂至55莫耳％之2,2,4,4·四甲基十3·環丁二醇與45至6〇莫耳％之乙二酵；4〇至小於50莫耳％之2,2,4,4-四甲基],3·環丁二醇與大於50莫耳％至60莫耳％之乙二醇；4〇至5〇莫耳％之 2.2.4.4- 四甲基.u.環丁二醇與5()至6()莫耳％之乙二醇 40至45莫耳％之2244 -四甲其IQ 丁 %之乙二醇。，，甲基丁二醇與55至60莫耳 122661.doc -53- 200819496 2發明之其他態樣中’適用於本發明之㈣之二耗刀匕括（但不限於）以下範圍組合中之至少_者：約於90莫耳。/〇之2 2 小至约… ，2,4,4四甲基-1，3,丁二醇與大於1〇莫耳％ 13 r 丁之乙二醇；45至85莫耳％之2,2,4,4_四甲基_ ，-:丁二醇與15至55莫耳％之乙二醇；45至8〇莫耳％之，2,4，心四甲基#環丁二醇㈣至55莫耳％之乙至75莫耳％之2,2,4,4·四甲基^環丁二醇與25至55莫耳％之乙二醇；45至70莫耳％之2’2，M_四甲基 3。至55莫耳％之乙二醇；45 :丁-知與】^戸丁- > 吳斗/〇之2,2,4,4-四甲基_ ，·: 丁二醇與35至55莫耳％之乙二醇；45至6〇莫耳%之，从四甲基^環丁二醇與如至㈣耳从乙二醇：大於45莫耳％至55莫耳％之2,2,4,4.四甲基 … 至小於55莫耳％之乙二醇；45 ^ ,衣一転與45 w至55莫耳。之2,2,4,4-四甲其 ;，3·環丁二醇與45至55莫耳。之乙：醇；及45至5。莫耳%土之，2，Μ·四甲基-1，3·環丁二醇與5〇至6〇莫耳％之乙二醇。 ι. ::發明之其他態樣中，適用於本發明之聚醋组伤包括（但不限於）以下範圍組、、 ^ 〇/ ^ r 您至少一者·大於50莫耳/。至小於90莫耳％之2,24 、㈣耳。至小於50莫耳％之乙^基·丁二醇與大於且乙—醇；大於50莫耳％至85莫耳之Μ’4,4·四甲基-1，3·環丁二醇與！5至小於50莫耳％之乙-醇；大於50莫耳％至8〇莫耳％之2,2,4,4_四甲基Μ·環丁一醇與20至小於50莫耳％莫一一基:3= 之乙二醇，·大於5。莫耳%至7。莫:酵與25至小於5°莫耳。斗至70莫耳％之2,2,4,4-四f基.！，3_ 122661.doc -54- 200819496 缞丁二醇與30至小於50莫耳％之乙二醇；大於5〇莫耳％至 654耳％之2’2’4,4•四甲基·u•環丁二醇與^小於5〇莫耳 %之乙二醇；大於5〇莫耳％至6〇莫耳。/❶之2,2,4,4_四甲基· 1，3_環丁二醇與40至小於5〇莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之㈣之二醇组伤包括（但不限於）以下範圍組合中之至少―者：約Μ至小於列莫耳。/。之从Μ-四甲基〜·環丁二醇與大㈣莫耳％至約45莫耳％之乙二醇；55至85莫耳％之2,2,4,4-四甲基· 環丁二醇與15至45莫耳％之乙二醇；55至8〇莫耳。/。之 UK四甲基.以環丁二醇與2〇至45莫耳％之乙二醇⑶ 至75莫耳％之2,2,4,4·四甲基Μ環丁二醇與25至45莫耳％之乙二醇；W莫耳％之2,2,4,4•四甲基·μ•環丁咖莫耳％之乙二醇；55至65莫耳％之2,2,4，心四甲：核丁二醇與35純莫耳％之乙二醇；^錢莫耳％之，’，4四甲基·1，3’Τ二醇與4()至45莫耳％之乙二醇。 =本發明之其他態樣中’適用於本發明之聚酯之二醇紐伤包括(但不限於)以下範圍組合中之至少一者 :; 於9〇莫耳％之2,2,4,4·四甲基Μ.環丁二醇與大於10莫料至約40莫耳％夕r 一 ^ 兴升/〇、 —知，約60至約85莫耳％之2,2,4,4_四甲㈣^之5醇與約15至約4〇莫耳％之乙二醇；約6〇至約。，’4’4_四甲基-1，3·環丁二醇與約20至約40莫耳 ^之乙二醇’· 6〇至75莫耳％之2,2,4,4_四甲基#環丁二與25至40莫耳％之7 — 一醇 —醇；及60至70莫耳％之2,2,4,4_四甲基哀丁二醇與3〇至4〇莫耳％之乙二醇。 122661.doc -55- 200819496 在本發明之其他態樣中’適用於本發明之聚酷之二醇也份包括（但不限於）以下範圍組合中之至少一者：約“至小於9〇莫耳％之2,2,4,4·四甲基_Μ·環丁二醇與大於戦耳％至約35莫耳％之乙二醇；65至85莫耳％之2,2,4,4_四甲美 1，3_環丁二醇與15至35莫耳％之乙二醇；“謂莫耳二 2’2,4,4-四甲基·Μ環丁二醇與2()至35莫耳％之乙二醇；& 至75莫耳％之2,2,4,4·四甲基-1，3·環丁二醇與25至35莫耳％之乙二醇；及65至70莫耳％之2,2,4,4_四甲基_u_環丁與30至35莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚自旨之二醇也份包括（但+限於）以下範圍組合中之至少一者：約7〇至小於9〇莫耳。/。之2,2,4,4_四甲基]，3_環丁二醇與大㈣莫耳％至約30莫耳％之乙二醇；約7〇至約85莫耳％之2,2,4,心四甲基-1，3-環丁二醇與約15至約3〇莫耳％之乙二醇；約7〇至約 8〇莫耳。/。之2,2,4,4-四曱基]，3_環丁二醇與約2()至約3〇莫耳 k乙二醇；約70至約75莫耳％之2,2,4,4_四甲基#環丁二醇與約25至約30莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚酯之二醇租份包括(但不限於)以下範圍組合中之至少一者：約75至: 於90莫耳。/。之以心四甲基以環丁二醇與大於⑺莫耳％至約25莫耳％之乙二醇；及75至Μ莫耳％之2,2,4,4_四甲基_ 1，3_環丁二醇與15至25莫耳0/〇之乙二醇。土在本發明之其他態樣中，適用於本發明之聚s|之二⑼ 份包括(但不限於)以下範圍组合中之至少一者 '約8〇至小 122661.doc -56 - 200819496 醇與大於1 0莫耳〇/〇於90莫耳％之2,2,4,4_四甲基心少環丁至約20莫耳。/〇之乙二醇。在本發明之其他態樣中，㈣於本發明之聚g旨之二醇电份包括（但不限於）以下範圍組合中之至少一者：37至8〇莫耳％之2,2,4,4·四甲基]，3_環丁二醇與2_3莫耳％之乙二酵；至小於45莫耳％之2,2,4,4_四甲基#環丁二醇血大於55莫耳％至6〇莫耳％之乙二醇；大於45莫耳％至55莫耳％之2,2,4,4_四甲基環丁二醇與45至小於μ莫耳％之乙二及46至55莫耳％之2,2,4,4_四甲基#環丁二醇與μ 54莫耳％之乙二醇；及46至65莫耳。土吳斗/〇之2,2,4,4-四甲基q 環丁二醇與35至54莫耳％之乙二醇。， =本發明之其他態樣中，適心本發明之㈣之二醇租二匕括⑷不限於)以下範圍組合中之至少一者：〇〇m 耳％之2,2,4，心四甲基-1，3-環丁二醇與85至99·99莫耳％之二：醇；〇.〇1至小於15莫耳。/。之…沣四甲基仏環丁二醇與大於85莫耳％至99 99莫一〇/〇之2,2,4,4_四甲基]、乙一醇；〇·01至14莫耳 # · ，3_%丁一醇與86至99·99莫耳。/❶之丨〆· 乙一醇，0.01至13莫耳j 87至99.99莫耳％之乙1 ，甲基十3·環丁二醇與 A 13 r 丁、 —醇，〇.01 至 12 莫耳％之2,2,4,心 11莫耳0/〇之2,2,4,4-四甲美丨3严一 1 莫耳％之乙土 -，31 丁二醇與89至99.99 乙—％，0.0H0莫耳％之2,2,4,4_四7基_13产丁-醇與90至99.99莫耳％之乙 5 之2,2,4,4_四甲基13 ίβ —至小於Η)莫耳％土，衣丁一醇與大於9〇莫耳％至99 99莫 122661.doc -57- 200819496 耳。/。之乙二醇，· 0.01至9莫耳％之2,2,4,4_四甲基環丁二醇與91至99.99莫耳Γ 一 ^ 、之乙一醇，〇·〇1至8莫耳。/〇之2,2,4,4- 四甲基-u-環丁二醇與92至99.99莫耳％之乙二醇；〇〇1至 7莫耳％之2,2,4,4,基十3-環丁二醇與93至99.99莫耳％之乙二醇；〇.〇1至5莫耳％之2,2,4,4_四甲基^環丁二醇與95至99.99莫耳％之乙二醇；〇〇1至小於以耳％之从七扣四甲基-以環丁二醇與大於㈣耳^料的莫耳。/。之乙二醇；0.01至4.5莫耳％之2,2,4,4·四甲基-以環丁二醇與95·5至99.99莫耳％之乙二醇；_至4莫耳％之2,2,4,4_四甲基-ι，3-環丁二醇與96至99 99莫耳％之乙二醇·30 to 65 mol% of B-methylbutanediol and ^" private, 35 to 65 mol% of 2,2,4'4-tetramethyl A 1,3-% butanediol and 35 to 65 Molybdenum 2,2,4,4-tetramethyl A 13rT. B- know, 35 to 60 mol% of methyl-1'3, butanediol and 4 to 65 mol% of ethylene glycol fly 122661 .doc -52- 200819496 to 55 mol% of 2,2,4,4·tetramethyl], 3_cyclobutanediol and 45·mol% of ethylene glycol; 35 to 50 mol% of 2 , 2,4,4_tetramethyl-cyclobutanediol with 50 to 65 mol% of ethylene glycol; 35 to less than 5 () mol% of 2,2,4, cardiac tetramethylguanidine Glycol with greater than 50 mol% to 65 mol% of ethylene glycol; 35 to 45 mol% of 2,2,4,4. tetramethyltri-3-cyclobutanediol with 55 to 65 mol% Ethylene glycol; 35 to 40 mol% of 2,2,4,4 tetramethyl·^•cyclobutanediol is 60 to 65 mol% of ethylene glycol. ^ Other aspects of the invention The diol component of (4) of the present invention includes, but is not limited to, at least less than 9 〇mol TM tetramethylcyclobutanediol in the combination of the following ranges and greater than the ear:; to about 2% of the mole Alcohol; 40 to 85 mol% of 2,2,4,4_tetramethylcyclobutanediol and 15 to 60 Mole % of ethylene glycol; 4 〇 to 8 〇 mol% of 2.2.4.4- tetramethyl. Cyclobutanediol and 2 〇 to 6 〇 ❶ ❶ 乙二醇 ;; 2,2,4,4 tetramethyl-u-cyclobutanediol with 25 to mol% of ethylene glycol; 40 to 70 mol% of 2,2,4,4•tetramethyl·^ - 4 to 6 moles of cyclobutanediol. B: 2, 2, 4, 4, tetramethyl 1,3- 1,3-cyclobutanediol and 35 to 6 moles of alcohol % of ethylene glycol, · 4〇 to (9) mol% of 2.2.4.4- tetramethyl-M-cyclobutanediol and 4〇 to 6〇% of ethylene glycol; 仂 to 55 mol% 2,2,4,4·tetramethyl-tris-cyclobutanediol and 45 to 6 〇 mol% of the second fermentation; 4 〇 to less than 50 mol% of 2,2,4,4-tetra Base, 3·cyclobutanediol with more than 50 mol% to 60 mol% of ethylene glycol; 4〇 to 5〇 mol% of 2.2.4.4-tetramethyl.u. cyclobutanediol and 5 () to 6 () mol% of ethylene glycol 40 to 45 mol% of 2244 - tetramethyl its IQ D% of ethylene glycol.,, methyl butanediol with 55 to 60 m. 122661.doc - 53-200819496 2 In other aspects of the invention, 'the second knives applicable to the invention are (but not limited to) the following At least _ in the combination: about 90 moles. / 〇 2 2 2 to about ..., 2,4,4 tetramethyl-1,3, butanediol and more than 1 〇 mole % 13 r Ethylene glycol; 45 to 85 mol% of 2,2,4,4_tetramethyl-, -: butanediol and 15 to 55 mol% of ethylene glycol; 45 to 8 mol%, 2,4, heart tetramethyl #cyclobutanediol (iv) to 55 mol% of B to 75 mol% of 2,2,4,4·tetramethyl^cyclobutanediol and 25 to 55 mol% Ethylene glycol; 45 to 70 mol% of 2'2, M_tetramethyl 3. To 55 mol% of ethylene glycol; 45: Ding-zhi and 】^戸丁- > Wudou/〇之2,2,4,4-tetramethyl-, ·: butanediol and 35 to 55 Mol% of ethylene glycol; 45 to 6 〇 mol%, from tetramethylcyclobutanediol and as far as (4) ears from ethylene glycol: greater than 45 mol% to 55 mol% of 2, 2 , 4, 4. tetramethyl... to less than 55 mol% of ethylene glycol; 45 ^, a coat of clothing and 45 w to 55 m. 2, 2, 4, 4-tetramethyl; 3, cyclobutanediol and 45 to 55 moles. B: Alcohol; and 45 to 5. Moer% soil, 2, Μ·tetramethyl-1,3·cyclobutanediol and 5 〇 to 6 〇 mol% of ethylene glycol. ι. :: In other aspects of the invention, the polyacetal group suitable for use in the present invention includes, but is not limited to, the following range of groups, ^ 〇 / ^ r, at least one of which is greater than 50 moles /. Up to less than 90% of the 2,24, (four) ears. Up to less than 50 mol% of ethyl butyl butyl glycol and greater than and ethyl alcohol; greater than 50 mol% to 85 mol Μ '4,4·tetramethyl-1,3·cyclobutanediol and ! 5 to less than 50 mol% of ethyl alcohol; more than 50 mol% to 8 mol% of 2,2,4,4_tetramethylhydrazine·cyclobutanol and 20 to less than 50 mol% One base: 3 = ethylene glycol, · greater than 5. Moor % to 7. Mo: Leaven with 25 to less than 5 ° Mo. Fight to 70% of the 2, 2, 4, 4-four f base.! , 3_ 122661.doc -54- 200819496 Butylene glycol with 30 to less than 50 mol% of ethylene glycol; more than 5 〇 mol% to 654 ear% of 2'2'4,4•tetramethyl·u • Cyclobutanediol with less than 5 〇 mol% of ethylene glycol; greater than 5 〇 mol% to 6 〇 mol. /❶2,2,4,4_tetramethyl·1,3_cyclobutanediol and 40 to less than 5 〇 mol% of ethylene glycol. In other aspects of the invention, the diol group injury suitable for use in (4) of the present invention includes, but is not limited to, at least one of the following combinations of ranges: about Μ to less than Lem. /. From Μ-tetramethyl-·cyclobutanediol with large (tetra) mol% to about 45 mol% of ethylene glycol; 55 to 85 mol% of 2,2,4,4-tetramethyl·ring Butanediol with 15 to 45 mole % of ethylene glycol; 55 to 8 moles of Mo. /. UK tetramethyl. Cyclobutanediol with 2〇 to 45 mol% of ethylene glycol (3) to 75 mol% of 2,2,4,4·tetramethylguanidinium diol and 25 to 45 Mole % of ethylene glycol; W Momon% 2,2,4,4•tetramethyl·μ•cyclobutanol% of ethylene glycol; 55 to 65 mol% of 2,2,4 , Xinsijia: nuclear butanediol and 35 pure Moe% of ethylene glycol; ^ Qian Moer%, ', 4 tetramethyl·1,3' decanediol and 4 () to 45 mol% Ethylene glycol. In other aspects of the invention, the diol stimuli of the polyester suitable for use in the present invention include, but are not limited to, at least one of the following combinations of ranges:; 2, 2, 4 of 9 〇 mol%, 4·tetramethyl hydrazine. Cyclobutanediol with more than 10 moles to about 40 moles 夕r a ^ 升 / 〇, - know, about 60 to about 85 moles of 2, 2, 4, 4 _ tetra (4) ^ 5 alcohol with about 15 to about 4 〇 mol% of ethylene glycol; about 6 〇 to about. , '4'4_tetramethyl-1,3·cyclobutanediol with about 20 to about 40 moles of ethylene glycol '·6〇 to 75 mole% of 2,2,4,4_four Methyl #cyclobutane and 25 to 40 mol% of 7-monohydrin-alcohol; and 60 to 70 mol% of 2,2,4,4-tetramethylamylbutanediol and 3 to 4 〇 Mole% of ethylene glycol. 122661.doc -55- 200819496 In other aspects of the invention 'the poly diols useful in the present invention also include, but are not limited to, at least one of the following combinations of ranges: about "to less than 9 〇 Mo 2%, 2,4,4·tetramethyl-oxime-cyclobutanediol and more than about 35% by mole of ethylene glycol; 65 to 85% by mole of 2, 2, 4, 4_tetramethazine 1,3_cyclobutanediol and 15 to 35 mol% of ethylene glycol; "Mer 2 2,4,4-tetramethyl-indolecyclobutanediol and 2 (" ) to 35 mol% of ethylene glycol; & to 75 mol% of 2,2,4,4·tetramethyl-1,3·cyclobutanediol and 25 to 35 mol% of ethylene glycol And 65 to 70 mol% of 2,2,4,4_tetramethyl_u_cyclobutane and 30 to 35 mol% of ethylene glycol. In other aspects of the invention, the diols suitable for use in the present invention include, but are not limited to, at least one of the following combinations of ranges: from about 7 Torr to less than 9 Torr. /. 2,2,4,4_tetramethyl], 3_cyclobutanediol and large (tetra) mol% to about 30 mol% of ethylene glycol; about 7 〇 to about 85 mol% of 2, 2 4, cardiac tetramethyl-1,3-cyclobutanediol with about 15 to about 3 moles of ethylene glycol; about 7 to about 8 moles. /. 2,2,4,4-tetradecyl], 3_cyclobutanediol and from about 2 () to about 3 Torr molar k glycol; from about 70 to about 75 mole % of 2, 2, 4 , 4_tetramethyl #cyclobutanediol with from about 25 to about 30 mole % of ethylene glycol. In other aspects of the invention, the diol lease of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following combinations of ranges: from about 75 to: at 90 moles. /. Heart tetramethyl with cyclobutanediol and greater than (7) mole% to about 25 mole% of ethylene glycol; and 75 to Μmol% of 2,2,4,4_tetramethyl-1 3_cyclobutanediol with 15 to 25 moles of ethylene glycol. Soil In other aspects of the invention, two (9) parts of the polys[s] suitable for use in the present invention include, but are not limited to, at least one of the following ranges of combinations 'about 8 〇 to small 122661. doc - 56 - 200819496 alcohol With a molar ratio of more than 10 moles/〇 at 90 moles of 2,2,4,4_tetramethyl heart to about 20 moles. / 〇 glycol. In other aspects of the invention, (d) the diol component of the present invention includes, but is not limited to, at least one of the following combinations of ranges: 37 to 8 〇 mol% of 2, 2, 4 , 4·tetramethyl], 3_cyclobutanediol and 2_3 mol% of the second fermentation; to less than 45 mol% of 2,2,4,4_tetramethyl#cyclobutanediol blood greater than 55 Mol % to 6 〇 mol % of ethylene glycol; greater than 45 mol % to 55 mol % of 2,2,4,4_tetramethylcyclobutanediol and 45 to less than μ mol% of B 2 and 46 to 55 mol% of 2,2,4,4_tetramethyl#cyclobutanediol with μ 54 mol% of ethylene glycol; and 46 to 65 m. Earth Wudou/〇2,2,4,4-tetramethyl q-cyclobutanediol and 35 to 54 mol% of ethylene glycol. In other aspects of the present invention, the diol of the (4) of the present invention is (4) not limited to at least one of the following combinations of ranges: 2, 2, 4, 4 of 〇〇m ear % Methyl-1,3-cyclobutanediol and 85 to 99.99 mole% of the two: alcohol; 〇.〇1 to less than 15 moles. /.沣 tetramethyl hydrazine cyclobutanediol with more than 85 mol% to 99 99 mol 〇 / 〇 2, 2, 4, 4 4 tetramethyl], ethyl alcohol; 〇 · 01 to 14 moer # · , 3_% butanol and 86 to 99. 99 moles. / ❶ 丨〆 · Ethyl alcohol, 0.01 to 13 moles j 87 to 99.99 moles of B 1, methyl decylene cyclanediol and A 13 r butyl, - alcohol, 〇. 01 to 12 mole % of 2, 2, 4, heart 11 Moer 0 / 〇 2, 2, 4, 4- 甲丨丨 3 Yan 1 1 Moer % of the soil -, 31 butanediol and 89 to 99.99 B - %, 0.0H0 moles of 2, 2, 4, 4_ four 7 bases _13 butyl alcohols with 90 to 99.99 mol% of the 5 of 2, 2, 4, 4_ tetramethyl 13 ίβ — To less than Η) Moer% soil, pentitol monol and greater than 9 〇 Moer% to 99 99 Mo 122661.doc -57- 200819496 Ear. /. Ethylene glycol, 0.01 to 9 mole % of 2,2,4,4_tetramethylcyclobutanediol and 91 to 99.99 moles of ethylene glycol, 〇·〇1 to 8 moles . /〇2,2,4,4-tetramethyl-u-cyclobutanediol with 92 to 99.99 mol% of ethylene glycol; 〇〇1 to 7 mol% of 2,2,4,4, Base 10 - cyclobutanediol with 93 to 99.99 mol% of ethylene glycol; 〇.〇1 to 5 mol% of 2,2,4,4_tetramethyl^cyclobutanediol and 95 to 99.99 Mole% of ethylene glycol; 〇〇1 to less than the ear% of the seven-bonded tetramethyl--cyclobutanediol and more than (four) ear material of the molar. /. Ethylene glycol; 0.01 to 4.5 mol% of 2,2,4,4·tetramethyl-cyclohexanediol and 95·5 to 99.99 mol% of ethylene glycol; _ to 4 mol% 2,2,4,4_tetramethyl-ι,3-cyclobutanediol and 96 to 99 99 mol% of ethylene glycol

莫耳％之/，2,4,4·四甲基-1，3·環丁二醇與96.5至99.99莫耳％之乙一醇，0.01至3莫耳0/〇之2,2,4,4_四甲基_1，3_環丁二醇與97至99.99莫耳％之乙二醇；〇〇1至25莫耳％之2244四甲基-1，3-環丁二醇與97 5至99 99莫耳％之乙二醇；〇別至2 莫耳％之2’2’4,4-四甲基-u-環丁二醇與98至99 99莫耳。，❶之乙二醇；〇.〇m5莫耳％之2,2,4,4_四甲基_u·環丁二醇與基-1，3-環丁二醇與99至99 99莫耳％之乙二醇；及〇〇1至〇 5 莫耳％之2,2,4’4-四f基-U3•環丁二醇與99 5至99 99莫耳％之乙二醇。在其中2,2,4,4-四甲基環丁二醇殘基之莫耳％以等於 100莫耳％之二醇組份莫耳百分數計為〇.〇1至5莫耳％且其 T需要存在環己烷二甲醇之實施例中，適用於本發明之聚酯之二醇組份包括（但不限於）以下範圍組合中之至少一 122661.doc -58- 200819496 者：0.01 至 5 莫：I：〇/Λ 夕〇〇 1 1 、耳之2,2,4,4·四甲基-1，3-環丁二醇殘基、 89至94.99莫耳％之乙二醇殘基與5至1〇甲醇；〇.〇1至5莫耳％之2,2,44_四衣己坑一，，四Τ暴_1，3-裱丁二醇殘基、89至94.99莫耳％夕，一 ^笔林、斗/之乙一醇殘基與5至10莫耳％之環己燒二甲醇；〇·〇1至5草耳％夕，。j 王：> 旲斗/〇之2,2,4,4_四甲基-L3·環丁二醇殘基、84至89·99莫耳％之乙—醢錄且^ 、今之乙一醇殘基與10至15莫耳％之環己炫二甲醇；G.G1至5莫耳％之2,2,4,4四甲基〜.環丁二 =殘基、79至84·99莫耳％之乙二醇殘基㈣錢莫耳％之環^烷二甲醇；0.01至5莫耳％之2,2,4,4_四甲基#環丁一醇殘基、74至79.99莫耳％之7 一龄戌甘夫吁❶之乙一知殘基與2〇至25莫耳％之環己烷二甲醇；〇.01至5茬耳0/夕0，1 1 、王J旲斗/〇之2,2,4,4-四甲基_1，3_環丁一醇殘基、69至74·99莫耳〇/0夕,一鮮戒甘fc 。、今/之乙一醇殘基與25至30莫耳 %之環己烷二甲醇；〇.01至5箪耳0/夕〇1 j 、 ^ 旲斗/〇之2,2,4,4-四甲基_l，3-環丁一醇殘基、64至69.99莫耳％夕7 ^ 〇旲斗Λ之乙一醇殘基與30至35莫耳 %之環己烷二甲醇；〇.〇1至5簟耳0/夕0 0 /」、一旲耳/〇之2,2,4,4-四甲基-込弘環丁二醇殘基、59至64.99莫耳％之7 t 〇夭寸/0之乙一醇殘基與35至40莫耳 ^之玉衣己烧一甲醇，〇·〇1至5莫耳9 9/1/1 m好一兴+ /〇之2,2,4,4-四甲基-L3·環丁二醇殘基、54至59.99莫耳％之7 一鮮成* t 。之乙一醇殘基與40至45莫耳 %之環己烷二甲醇；0.01至5莫耳、、斗之2,2,4,4-四甲基_1，3_環丁二醇殘基、49至54.99莫耳〇/0之7 —鮮我甘t 。夭吁/()之乙一醇殘基與45至50莫耳 %之環己烷二甲醇；0.01至5莫耳0/ 、一吳斗/〇之2,2,4,4-四甲基-込弘環丁二醇殘基、44至49.99莫耳〇/0夕7 ^务廿、斗❶之乙一醇殘基與50至55莫耳之環己烧一甲醇，0.01至5莫耳％之^ 〜夫汁/0之2,2,4,4-四甲基_1，3_環丁二醇殘基、39至44.99莫耳。/。之7 t 夫今/〇之乙一醇殘基與55至6〇莫耳 12266l.cj〇c -59- 200819496Molar%, 2,4,4·tetramethyl-1,3·cyclobutanediol and 96.5 to 99.99 mol% of ethyl alcohol, 0.01 to 3 mol 0/〇 2, 2, 4, 4_tetramethyl-1,3_cyclobutanediol with 97 to 99.99 mol% of ethylene glycol; 〇〇1 to 25 mol% of 2244 tetramethyl-1,3-cyclobutanediol with 97 5 to 99 99 mol% of ethylene glycol; 2 to 2 mol% of 2'2'4,4-tetramethyl-u-cyclobutanediol and 98 to 99 99 mol. , ❶ 乙二醇 ethylene glycol; 〇. 〇 m5 mol% of 2,2,4,4_tetramethyl _u·cyclobutanediol and 1,3-1,3-cyclobutanediol with 99 to 99 99 Mo Ethylene glycol of the ear; and 〇〇1 to 〇5 2% 2,2,4'4-tetraf-U3•cyclobutanediol and 99 5 to 99 99 mol% ethylene glycol. The molar % of the 2,2,4,4-tetramethylcyclobutanediol residue is 〇.1 to 5 mol% based on the molar percentage of the diol component equal to 100 mol% and T requires the presence of cyclohexanedimethanol. The diol component of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following combinations of ranges: 122661.doc - 58 - 200819496: 0.01 to 5 Mo: I: 〇 / Λ 〇〇 1 1 , 2, 2, 4, 4 · tetramethyl-1,3-cyclobutanediol residues, 89 to 94.99 mol % of ethylene glycol residues With 5 to 1 〇 methanol; 〇. 〇 1 to 5 moles of 2, 2, 44 _ four clothes, one pit, four violent _ 1,3-butanediol residues, 89 to 94.99 moles % 夕, a ^ pen Lin, bucket / of the ethyl alcohol residue and 5 to 10 mol% of cyclohexane burnt dimethanol; 〇 · 〇 1 to 5 grass ear % eve. j 王:> 2,2,4,4_tetramethyl-L3·cyclobutanediol residue, 84 to 89·99 mol% of the 旲〇〇且 ^ ^ ^ ^ ^ ^ ^ ^ Alcohol residue with 10 to 15 mol% cyclohexene dimethanol; G.G1 to 5 mol% of 2,2,4,4 tetramethyl~.cyclobutane=residue, 79 to 84·99 Mole% of the ethylene glycol residue (4) Qianmoer% of the cycloalkane dimethanol; 0.01 to 5 mol% of the 2,2,4,4_tetramethyl #cyclobutanol residue, 74 to 79.99摩尔%7 一戌夫 ❶ ❶ 一一一一一与与与与与与与与与 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 2,2,4,4-tetramethyl-1,3_cyclobutanol residues, 69 to 74.99 moles/0 eve, a fresh ring, fc. , the current / ethyl alcohol residue and 25 to 30 mol% of cyclohexane dimethanol; 〇.01 to 5 箪 ear 0 / 〇〇 1 j , ^ 旲 / / / 2, 2, 4, 4- Tetramethyl-l,3-cyclobutanol residue, 64 to 69.99 moles of ^ 7 ^ 〇旲 Λ 乙乙乙与与与与与与 30 30 30 30 30 30 30 30 30 30 30 〇〇〇〇〇〇〇〇〇〇〇 1 to 5 ears 0 / eve 0 0 /", 2,2,4,4-tetramethyl-indole Cyclobutanediol residue, 59 to 64.99 mol% 7 t 〇夭 / / / / / / / / / / / / / / / / 4,4-Tetramethyl-L3.cyclobutanediol residue, 54 to 59.99 mol% of 7% fresh*t. The ethyl alcohol residue and 40 to 45 mol% of cyclohexane dimethanol; 0.01 to 5 moles, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues 49 to 54.99 Mo Er / 0 of 7 - fresh me Gan t.夭 / / () of the ethyl alcohol residue with 45 to 50 mol% of cyclohexane dimethanol; 0.01 to 5 mol 0 /, a Wudou / 〇 2,2,4,4-tetramethyl-込Hongcyclobutanediol residue, 44 to 49.99 moles / 0 7 7 ^ 廿廿, ❶ ❶ 乙醇醇与与与 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 0.01 0.01 0.01 0.01 0.01 ^ 〜 _ _ / 2, 2, 4, 4-tetramethyl-1, 3 - cyclobutanediol residues, 39 to 44.99 moles. /. 7 t Fujin / 〇乙醇醇醇与 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266 266

%之環己烷二甲醇；0·01至5莫耳％夕9 9J 旲斗/0之2,2,4,4-四甲基_153_環丁二醇殘基、34至39.99莫耳％夕7 t 夫斗/〇之乙一醇殘基與60至65莫耳 %之環己烷二甲醇；0.01至5莫耳％$ 7 91 、旲斗/〇之2,2,4,4_四甲基-1，3_環丁二醇殘基、29至34.99莫耳％之,—辟成* t 夫今/〇之乙一醇殘基與65至7〇莫耳 A之環己烧二甲醇；0.01至5莫耳％$ ^ ^ 一旲斗/〇之2,2,4,4_四甲基-ΐ，3·環。丁二醇殘基、24至29.99莫耳％之乙二醇殘基與7〇至π莫耳 %之環己烷二甲醇；0.01至5莫耳0/ ^ 吳斗/〇之2,2,4,4·四甲基-1，3-環丁二醇殘基、19至24.99莫耳％之7 -龄成* «：〇斗之乙一知殘基與75至80莫耳 %之環己烷二甲醇；〇.01至5蕈耳％夕？ ο 1 j 、一王d旲斗/〇之2,2,4,4_四甲基環丁二醇殘基、14至19.99莫耳％之乙二醇殘基與8〇至85莫耳处環己燒二甲醇；o.om莫耳％之2,2,4,4_四甲基]，3_環。丁'醇殘基、9至14.99莫耳％之乙二醇殘基與85至9〇莫耳义之％^己烧二甲龄；0.01至5草五〇/夕〇〇 λ 一）兵耳/〇之2,2,4,4-四甲基β1，3_環丁：醇殘基、4至9.99莫耳％之乙二醇殘基與9〇至％莫耳％之環己院二甲醇；〇.(^5莫耳％之2,2,4,4四甲基-^-環丁二醇殘基、95至99·99莫耳％之乙二醇殘基與〇至5莫耳％之環己烷二甲醇。在本發明之其他態樣中，適用於本發明之聚酯之二醇组伤包括（但不限於）以下範圍組合中之至少—者：Μ至叫莫 p之2’2’4’4_四甲基π環丁二醇、2〇至4〇莫耳％之環己二二甲醇與30至60莫耳％之乙二醇；2〇至35莫耳％之醆=4,4-四甲基-i，3-環丁二醇、2〇至4〇莫耳％之環己烷二甲 ^、30至6〇莫耳％之乙二醇；跑⑽莫耳Μ]，〕〆，心四甲二醇、2〇至40莫耳％之環己烧二甲醇與30至60 122661.doc -60- 200819496 莫耳％之乙二醇；及20至25莫耳。/。之…洚四甲基^環丁二酵、20至40莫耳％之環己燒二甲醇與3〇至6〇莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚g旨之二醇組份包括（但不限於）以下範圍組合中之至少一者：25至4〇莫耳％之2,2,4,4-四甲基Μ環丁二醇、至4〇莫耳％環己烧二甲醇與30至55莫耳％乙二醇；25至35莫耳％之2,2,4,4_四甲基-U·環丁二醇、2G賤莫耳％之環己烧二甲醇與扣至 I5莫耳％之乙二醇；及25至3〇莫耳％之2,2,4,4-四甲基-1，3· 環丁二醇、20至40莫耳％之環己燒二甲醇與3〇U莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚S旨之二醇组份包括（但不限於）以下範圍組合中之至少一者：30至4〇莫耳％之2,2’4’4·四甲基-1，3·環丁二醇、20至40莫耳％之環己炫二甲醇與30至50莫耳％之乙二醇；3〇至35莫耳％之之^以-四甲基-^ —環丁二醇⑶至利莫耳^之環己烷二甲醇與30至50莫耳％之乙二醇。在本發明之其他態樣中，適用於本發明之聚S旨之二醇电份包括（但不限於）以下範圍組合中之至少一者：20至切莫耳％之2,2,4,4-四甲基-1，3·環丁二醇、20至35莫耳％之環己烧二甲醇與30至60莫耳％之乙二醇；2〇至4〇莫耳％之 2’2’4’4-四甲基{3-環丁二醇、2〇至3〇莫耳％之環己院二甲醇與30至⑽耳％之乙二醇；及2Q錢莫耳％^，2，仏四甲基-1，3·環丁二醇、2〇至25莫耳％之環己烧二甲醇㈣至 122661.doc •61 - 200819496 60莫耳％之乙二醇。、在本發明之其他態樣中，適用於本發明之聚酯之二醇組份包括（但不限於）以下範圍組合中之至少-者：2〇至40莫耳❶/〇之2,2,4,4-四f基·1，3·環丁二醇、25至40莫耳％之環已院二甲醇與3〇至55莫耳％之乙二醇；20至40莫耳％之 2广4,4-四甲基#環丁二醇、25至35莫耳％之環己炫二甲醇與30至55莫耳％之乙二醇；及2()至4()莫耳％之2,2,4,4_四甲基·1，3-環丁二醇、25至3〇莫耳％之環己燒二甲醇鱼 55莫耳％之乙二醇。 μ ^ 在本發明之其他態樣中’適用於本發明之聚酿之二醇也份包括（但不限於）以下範圍組合中之至少υ至⑽ 耳％之2,2,4 4-四甲美1 3 γ 丁、，4四甲基-1，3_核丁二醇、3〇至4〇莫耳％之環己烧二甲醇與30至50莫耳％之乙二醇；2〇至4〇莫耳％之 Τ’4·四甲基丄3·環了二醇、3⑴5莫耳％之環己炫二甲鮮與30至50莫耳％之乙二醇。在一實施例中，適用於本發明之聚醋之二醇組份包含 2,2,4,4-四甲基-1，3·環丁二醇及環己烧二甲醇，盆中 2,2,4,4_四甲基d，％環丁二八數總和為全部二醇組份之”:。甲私之莫耳百分耳％。 «總莫耳从㈣耳％至小於70莫在其中2,2,4,4-四甲基十3_環丁二醇殘基之莫耳%以等於 _莫耳从二醇崎之莫耳百分數計狀q 其中需要存在環己烷二甲醇^ 兵耳/〇且明之聚_之二醇組份亦中，^ 了包括其中存在〇_〇1至小於5莫耳％ 122661.doc -62- 200819496 之2,2，M-四f基環丁二醇殘基的實施例，且環己燒 -甲醇殘基及/或乙二醇殘基之相應減少將涵蓋於本發明二^組份亦可含有以下範圍之一者之2,2,4,4_四甲基· 1，3-環丁二醇殘基·· 〇〇1至1〇莫耳％ · 〇〇1至9.5莫耳％ ; 〇·〇1至9莫耳％ ; 0.01至8 5莫耳％ · 〇〇1至8莫耳％ · 〇〇1至 U莫耳％; 莫耳％ ; 〇〇1至6 5莫耳％ · 〇〇1至6莫% cyclohexane dimethanol; 0·01 to 5 mol % 夕 9 9J 旲斗 / 0 of 2, 2, 4, 4-tetramethyl _ 153 _ cyclobutanediol residue, 34 to 39.99 mol % 夕 7 t 〇 / 〇乙醇醇与与与 60 60 60 60 60 60 60 60 60 60 60 60 60 60 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 Tetramethyl-1,3_cyclobutanediol residue, 29 to 34.99 mol%, 辟成* t Fujin/〇乙一醇与与 65 65 65 65 65 65 65 Methanol; 0.01 to 5 mol %$ ^ ^ 2,2,4,4_tetramethyl-hydrazine, 3· ring. Butanediol residue, 24 to 29.99 mole % of ethylene glycol residue and 7 to π mole % of cyclohexanedimethanol; 0.01 to 5 moles 0 / ^ Wudou / 〇 2, 2, 4,4·tetramethyl-1,3-cyclobutanediol residue, 19 to 24.99 mol% of 7-year-old* «: 〇之之与与与与 75 75 75 75 75 75 75 75 Alkanediethanol; 〇.01 to 5 % ear% 夕? ο 1 j , a king d 旲 / 〇 2, 2, 4, 4 4 tetramethylcyclobutanediol residues, 14 to 19.99 mol% of ethylene glycol residues and 8 〇 to 85 m Cyclohexane dimethanol; o.om mol% of 2,2,4,4_tetramethyl], 3_ ring. Ding 'alcohol residue, 9 to 14.99 mol% of ethylene glycol residue and 85 to 9 〇 Mo Yiyi% ^ hexane burning dimethyl age; 0.01 to 5 grass 〇 / 〇〇〇〇 λ /〇2,2,4,4-tetramethyl β1,3_cyclobutane: alcohol residue, 4 to 9.99 mol% of ethylene glycol residue and 9〇 to % mol% of the ring Methanol; 〇. (^5 mol% of 2,2,4,4 tetramethyl-^-cyclobutanediol residues, 95 to 99.99 mol% of ethylene glycol residues and 〇 to 5 mo 5% by weight of cyclohexanedimethanol. In other aspects of the invention, the diol group injury of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following combinations of ranges: Μ to 莫2'2'4'4_tetramethyl πcyclobutanediol, 2 〇 to 4 〇 mol% of cyclohexanedimethanol and 30 to 60 mol% of ethylene glycol; 2 〇 to 35 m % of 醆 = 4,4-tetramethyl-i,3-cyclobutanediol, 2 〇 to 4 〇 mol% of cyclohexane dimethyl hydride, 30 to 6 〇 mol% of ethylene glycol; (10) Molyde],] 〆, heart tetramethyl diol, 2 〇 to 40 mol% of cyclohexane dimethanol and 30 to 60 122661.doc -60-200819496 摩尔% of ethylene glycol; and 20 to 25 moles.洚 tetramethyl Cyclobutane, 20 to 40 mol% of cyclohexane dimethanol and 3 〇 to 6 〇 mol% of ethylene glycol. In other aspects of the invention, suitable for use in the present invention The diol component of the polyglycol includes, but is not limited to, at least one of the following combinations of ranges: 25 to 4 mol% of 2,2,4,4-tetramethylguanidinium diol, to 4〇mol% cyclohexane dimethanol and 30 to 55 mol% ethylene glycol; 25 to 35 mol% of 2,2,4,4_tetramethyl-U·cyclobutanediol, 2G贱 Mo 5% of the ring of hexane, diethanol and ethylene glycol deducted to I5 mol%; and 25 to 3 mol% of 2,2,4,4-tetramethyl-1,3·cyclobutanediol, 20 to 40 mol% of cyclohexane dimethanol and 3 〇U mol% of ethylene glycol. In other aspects of the invention, the diol component suitable for use in the present invention includes (but not Limited to at least one of the following combinations of ranges: 30 to 4 〇 mol% of 2, 2'4'4·tetramethyl-1,3·cyclobutanediol, 20 to 40 mol% of cyclohexyl Dimethanol with 30 to 50 mol% of ethylene glycol; 3 to 35 mol% of tetramethyl-^-cyclobutanediol (3) to cyclohexane Dimethanol and 30 to 50 mole % of ethylene glycol. In other aspects of the invention, the diol component of the poly(S) suitable for use in the present invention includes, but is not limited to, at least one of the following combinations of ranges : 20 to Chemol% 2,2,4,4-tetramethyl-1,3·cyclobutanediol, 20 to 35 mol% of cyclohexane dimethanol and 30 to 60 mol% of B Diol; 2〇 to 4〇% 2'2'4'4-tetramethyl{3-cyclobutanediol, 2〇 to 3〇% by mole of cycloheximide dimethanol and 30 to (10) ears % of ethylene glycol; and 2Q money Moer %^, 2, 仏tetramethyl-1,3·cyclobutanediol, 2〇 to 25 mol% of cyclohexane dimethanol (4) to 122661.doc •61 - 200819496 60% of the ethylene glycol. In other aspects of the invention, the diol component of the polyester suitable for use in the present invention includes, but is not limited to, at least one of the following ranges: 2 〇 to 40 摩尔 / 〇 2, 2 , 4,4-tetraf-group·1,3·cyclobutanediol, 25 to 40 mol% of ring dimethanol and 3 to 55 mol% of ethylene glycol; 20 to 40 mol% 2G 4,4-tetramethyl#cyclobutanediol, 25 to 35 mol% of cycloheximide dimethanol and 30 to 55 mol% of ethylene glycol; and 2 () to 4 () mol% 2,2,4,4_tetramethyl·1,3-cyclobutanediol, 25 to 3 〇 mol% of cyclohexane-sintered dimethanol fish, 55 mol% of ethylene glycol. μ ^ In other aspects of the invention, the diols suitable for use in the present invention also include, but are not limited to, at least υ to (10)% of the following range of combinations, 2, 2, 4 4-tetra US 1 3 γ butyl, 4 tetramethyl-1,3_nuclear butanediol, 3 〇 to 4 〇 mol% of cyclohexanol dimethanol and 30 to 50 mol% of ethylene glycol; 4 〇耳 % Τ 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 In one embodiment, the diol component suitable for use in the present invention comprises 2,2,4,4-tetramethyl-1,3·cyclobutanediol and cyclohexane dimethanol, 2 in the pot. 2,4,4_Tetramethyl d, the sum of the two octagonal octagonal numbers is "all of the diol components": "% of the molars of the moles." The molar % of the 2,2,4,4-tetramethyltris-cyclobutanediol residue is equal to the molar percentage of the mersole from the glycol. The cyclohexane dimethanol is required to be present. ^ The diol component of the scorpion / 〇〇明明亦、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、 Examples of butanediol residues, and corresponding reductions in cyclohexane-methanol residues and/or ethylene glycol residues will be encompassed by the present invention. The components may also contain one of the following ranges 2, 2, 4,4_tetramethyl·1,3-cyclobutanediol residue··〇〇1 to 1〇mol%·〇〇1 to 9.5 mol%; 〇·〇1 to 9 mol%; 0.01 To 8 5 mol % · 〇〇 1 to 8 mol % · 〇〇 1 to U 莫 %; Moer % ; 〇〇 1 to 6 5 mol % · 〇〇 1 to 6 Mo

耳0/❻’ 0.01至5.5莫耳。/。；〇 01至5莫耳％ ; 〇〇1至小於5莫耳 % ’ 0.01至4.5莫耳〇/❶；0 〇1至4莫耳％ ; 〇〇1至3 5莫耳％ ; 〇·01 至 3莫耳％ ; 〇·01 至 2·5莫耳％ ; 〇·〇1 至 2.0莫耳％ ; 0·01 5莫耳/。，〇·〇ι至2莫耳％ ; 〇〇1至丨5莫耳％ ; 〇至L〇莫耳％ ;及0 · 〇 1至〇. 5莫耳％。在某些實施例中，只要二醇組份之總量等於1〇〇莫耳％且只要最終聚_巾6二醇之總量大於1〇莫耳％，貝^醇組份之剩餘部分可包括（但$限於）任何量之環己m享及/ 或乙二醇殘基。對於本發明之實施例而言，如於25下，在产 g/5〇如之60/40(重量比）齡/四氯乙燒中所測定用於本發明之聚酯可展現至少一種以下固有黏度· 〇 5〇至12 dL/g ’· 〇·50至 hl dL/g ; 〇 5〇至 i dL/g ; 〇 5〇至小於工让化； 0.505.0.98 dL/g ; 0.50^0.95 dL/g ； 0.50J.0.90 dL/g ； 0.50 至〇·85 dL/g ; 0.50至 0·80 dL/g ; 〇 5〇至〇 75 dL/g ; 〇 5〇至 J 於〇·75 dL/g，〇·5〇至 0 72 dL/g ; 〇 5〇至〇 7〇 dL/g ; 〇至小於 0.70 dL/g ; 〇·50 至〇·68 dL/g ; 〇 5〇至小於〇 68 122661.doc -63- 200819496 dL/g，〇·50 至 0.65 dL/g ; 〇·55 至 i 2 dL/g ; 〇 55 至 i」 dL/g，0.55 至 1 dL/g ; 0.55 至小於！ dL/g ; 〇 55 至〇 98 dL/g ; 〇·55 至〇·95 dL/g ; 〇·55 至〇 9〇 dL/g ; 〇 55 至〇 85 dL/g; 〇·55 至 0·80 dL/g; 〇·55 至 0.75 dL/g; 〇 55 至小於〇75 dL/g; 〇·55 至〇_72 dL/g; 〇·55 至〇·7〇 dL/g; 〇 55 至小於〇7〇 dL/g ; 〇·55 至 0·68 dL/g ; 〇·55 至小於〇·68 dL/g ; 〇 55 至〇 65 dL/g，〇·58 至 1·2 dL/g ; 0.58 至 1.1 dL/g ; 0.58 至 1 dL/g ; 0.58至小於 1 dL/g ; 0.58 至〇·98 dL/g ; 〇·58 至〇·95 dL/g ; 〇·58至 0.90 dL/g ; 0·58至〇·85 dL/g ; 〇.58至〇·8〇 dL/g ; 〇 58 至〇·75 dL/g ; 0·58 至小於〇·75 dL/g ; 〇·58 至〇·72 dL/g ; 〇·58 至 0.70 dL/g; 0·58 至小於〇·70 dL/g; 0.58 至 0.68 dL/g; 〇·58 至小於 0.68 dL/g; 0.58 至 0·65 dL/g; 0.60 至 1.2 dL/g ; 0.60至 1.1 dL/g ; 〇·6〇至 1 dL/g ; 0·60至小於 1 dL/g ; 0.60至〇_98 dL/g ; 0.60至〇·95 dL/g ; 0·60至 0.90 dL/g ; 0·60 至〇·85 dL/g; 0.60 至 0.80 dL/g; 0.60 至 0·75 dL/g; 0.60 至小於 0·75 dL/g ; 0·60 至 0.72 dL/g ; 0.60 至 0·70 dL/g ; 0.60 至小於 0.70 dL/g ; 0.60 至 0.68 dL/g ; 0.60 至小於 0.68 dL/g ; 〇·6〇至 0.65 dL/g ; 0.65 至 1.2 dL/g ; 〇·65 至 1.1 dL/g ; 0.65 至 1 dL/g ; 〇·65 至小於 1 dL/g ; 〇·65 至 0·98 dL/g ; 0.65 至 0.95 dL/g ; 〇·65 至 0.90 dL/g ; 0.65 至 0.85 dL/g ; 0.65 至 0.80 dL/g ; 0.65 至 0·75 dL/g ; 0.65 至小於 0.75 dL/g ; 〇·65 至〇·72 dL/g ; 〇·65 至 0·70 dL/g ; 0.65 至小於 0.70 dL/g，〇·68 至 1.2 dL/g ; 〇·68 至 1·1 dL/g ; 0.68 至 1 dL/g ; 〇·68 至小於 1 dL/g ; 0.68 至 0.98 dL/g ; 0.68 至 0.95 dL/g ; 122661.doc -64- 200819496 0.68至 0.90 dL/g ; 0.68至〇_85 dL/g ; 0.68至〇·80 dL/g ; 〇 68 至 0.75 dL/g，0.68至小於 0.75 dL/g ; 〇·68至〇·72 dL/g。Ear 0/❻' 0.01 to 5.5 m. /. 〇01 to 5 mol%; 〇〇1 to less than 5 mol% '0.01 to 4.5 m〇〇/❶; 0 〇1 to 4 mol%; 〇〇1 to 3 5 mol%; 〇·01 To 3 mol%; 〇·01 to 2. 5 mol%; 〇·〇1 to 2.0 mol%; 0·01 5 mol/. , 〇·〇ι to 2 mol%; 〇〇1 to 丨5 mol%; 〇 to L〇 mol%; and 0 · 〇 1 to 〇. 5 mol%. In certain embodiments, as long as the total amount of the diol component is equal to 1 〇〇 mol% and as long as the total amount of the final PEG 6 diol is greater than 1 〇 mol %, the remainder of the melamine component may be Including (but not limited to) any amount of cyclohexene and/or ethylene glycol residues. For the examples of the present invention, as described in 25, the polyester used in the present invention may exhibit at least one of the following in the production of g/5 such as 60/40 (weight ratio) age / tetrachloroethane. Intrinsic viscosity · 〇5〇 to 12 dL/g '· 〇·50 to hl dL/g ; 〇5〇 to i dL/g ; 〇5〇 to less than work; 0.505.0.98 dL/g ; 0.50^0.95 dL/g ; 0.50J.0.90 dL/g; 0.50 to 〇·85 dL/g; 0.50 to 0·80 dL/g; 〇5〇 to 〇75 dL/g; 〇5〇 to J 〇·75 dL /g, 〇·5〇 to 0 72 dL/g; 〇5〇 to 〇7〇dL/g; 〇 to less than 0.70 dL/g; 〇·50 to 〇·68 dL/g; 〇5〇 to less than 〇 68 122661.doc -63- 200819496 dL/g, 〇·50 to 0.65 dL/g ; 〇·55 to i 2 dL/g ; 〇55 to i” dL/g, 0.55 to 1 dL/g; 0.55 to less than ! dL/g ; 〇55 to 〇98 dL/g; 〇·55 to 〇·95 dL/g; 〇·55 to 〇9〇dL/g; 〇55 to 〇85 dL/g; 〇·55 to 0· 80 dL/g; 〇·55 to 0.75 dL/g; 〇55 to less than d75 dL/g; 〇·55 to 〇72 dL/g; 〇·55 to 〇·7〇dL/g; 〇55 to Less than 〇7〇dL/g; 〇·55 to 0·68 dL/g; 〇·55 to less than 〇·68 dL/g; 〇55 to 〇65 dL/g, 〇·58 to 1·2 dL/g 0.58 to 1.1 dL/g; 0.58 to 1 dL/g; 0.58 to less than 1 dL/g; 0.58 to 〇·98 dL/g; 〇·58 to 〇·95 dL/g; 〇·58 to 0.90 dL/ g; 0·58 to 〇·85 dL/g; 〇.58 to 〇·8〇dL/g; 〇58 to 〇·75 dL/g; 0·58 to less than 〇·75 dL/g; 〇·58 〇·72 dL/g ; 58·58 to 0.70 dL/g; 0·58 to less than 〇·70 dL/g; 0.58 to 0.68 dL/g; 〇·58 to less than 0.68 dL/g; 0.58 to 0· 65 dL/g; 0.60 to 1.2 dL/g; 0.60 to 1.1 dL/g; 〇·6〇 to 1 dL/g; 0·60 to less than 1 dL/g; 0.60 to 〇_98 dL/g; 0.60 to 〇·95 dL/g; 0·60 to 0.90 dL/g; 0·60 to 〇·85 dL/g; 0.60 to 0.80 dL/g; 0.60 to 0·75 dL/g; 0.60 to small 0.75 dL/g; 0·60 to 0.72 dL/g; 0.60 to 0·70 dL/g; 0.60 to less than 0.70 dL/g; 0.60 to 0.68 dL/g; 0.60 to less than 0.68 dL/g; ·6〇 to 0.65 dL/g; 0.65 to 1.2 dL/g; 〇·65 to 1.1 dL/g; 0.65 to 1 dL/g; 〇·65 to less than 1 dL/g; 〇·65 to 0·98 dL / g ; 0.65 to 0.95 dL / g ; 〇 · 65 to 0.90 dL / g ; 0.65 to 0.85 dL / g ; 0.65 to 0.80 dL / g ; 0.65 to 0 · 75 dL / g ; 0.65 to less than 0.75 dL / g ; 〇·65 to 〇·72 dL/g; 〇·65 to 0·70 dL/g; 0.65 to less than 0.70 dL/g, 〇·68 to 1.2 dL/g; 〇·68 to 1·1 dL/g; 0.68 to 1 dL/g; 〇·68 to less than 1 dL/g; 0.68 to 0.98 dL/g; 0.68 to 0.95 dL/g; 122661.doc -64-200819496 0.68 to 0.90 dL/g; 0.68 to 〇_85 dL/g; 0.68 to 〇·80 dL/g; 〇68 to 0.75 dL/g, 0.68 to less than 0.75 dL/g; 〇·68 to 〇·72 dL/g.

除非另有說明’否則預期適用於本發明之組合物可具有本文所述之固有黏度範圍中之至少一者及本文所述之組合物單體範圍中之至少-者。除非另有說明’否則亦預期適用於本發明之組合物可具有本文所述之\範圍中之至少一者及本文所述之組合物單體範圍中之至少一者。除非另有說明，否則亦預期適用於本發明之組合物可具有本文所述之固有黏度範圍中之至少一者、本文所述之Tg範圍中之至少一者及本文所述之組合物單體範圍中之至少一者。在-實施例中，可使用對苯二甲酸作為起始物質。在另貝施例中可使用對笨二甲酸二甲酉旨作為起始物質。在又一實施例中，可使用對苯二甲酸與對苯二甲酸二甲酉旨之混合物作為起始物質及/或作為中間物質。在某些實施例中’對苯二甲酸或其醋(諸如對苯二甲酸二甲醋）或對苯二甲酸殘基與其g旨之混合物可組成用以形成適用於本發明之聚酯之二羧酸組份的一部分或全部。在某些實施例中，對苯二甲酸殘基可組成用以形成仙於本發明之聚醋之二羧酸組份的一部分或全部。在某些實施例’可使用更高量之對苯二甲酸以產生更高衝擊強度之聚 =。對於本揭不案之目的*言，術語"對苯二甲酸"與"對苯二甲酸H，在本文巾可互換使用。在—實施例中，對苯二甲酸二為用以製備適詩本發明之聚自旨之二缓酸組份的部分或全部。在所有實施例中，可使㈣至⑽ 122661.doc -65- 200819496 莫耳％ ;或80至100莫耳0/ ·十直m 冥耳/〇,或90至_莫耳％，·或99至100 莫耳/。，或100莫耳％範圍内 κ對本一甲酸及/或對苯二甲酉文二甲酯及/或其混合物。除對苯二甲酸之外，適用於 _ > A 十私π之永酉日之二羧酸組份可包含至多10莫耳％、至多5簟耳0/七石夕王夕5冥耳/〇或至多1莫耳％之一或夕種改質性芳族二羧酸。一杂 ^ 只％例含有0莫耳％之改質 /族二賴。因此，若存在，則預期-或多種改質性芳 2幾酸之量的範圍可為任何該等上述端點值，包括例如 •至10莫耳％、0·01至5莫耳％A〇〇lii莫耳％。在施例中，可用於本發明之改質 g f生方叔一羧酸包括（但不限於）具有至多20個碳用子丘^氣古以子且可為直鏈、對位或對稱之彼等 ^矢一竣酸。可用於本發明之改質性芳族二幾酸之實例包括(但不限於)間苯二甲酸、4,4，-聯苯基二甲酸、、，4-蔡二甲酸、1，5-萘二甲酸、2 6-关_ ψ舱 0 " ，6奈一甲酸、2，厂萘二甲酸及反 5 式-甲酸及其酷。力_ ^L·. J * 1 曰在實施例十，改質性芳族二缓酸為間苯二甲酸。適用於本發明之聚醋之叛酸組份可進-步經至多1〇莫耳 _如至多5莫耳％或至多1莫耳％)之—或多種含有2-16個奴原子之脂族二羧酸改質，該等脂族二羧酸諸如環己烷二 :酸、丙二酸、丁二酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸及十二烧二竣酸。某些實施例亦可包含〇〇ι至 _耳〇/。（諸如mo莫耳％、H0莫耳％、5至1〇莫耳％) 之-或多種改質性脂族二竣酸。又—實施例含有〇莫耳％之改質性脂族二叛酸。二缓酸組份之總莫耳％為⑽莫耳 122661.doc -66- 200819496 。/〇。在一實施例中，本發明之改質性脂族二羧酸組份中提供有己二酸及/或戊二酸。本發明之改質性二羧酸可包括茚滿二羧酸，例如茚滿_ 1，3-二羧酸及/或苯基茚滿二羧酸。在一實施例中，二叛酸可選自1，2,3-二甲基-3-苯基茚滿-4’，5-二叛酸及；[，；[，3_二甲基-5-叛基-3_(4-叛基苯基）茚滿二羧酸中之至少一者。對於本發明之目的而言，Shaikh等人之標題為”cop〇lymers fCompositions suitable for use in the present invention are expected to have at least one of the intrinsic viscosity ranges described herein and at least one of the monomer ranges recited herein, unless otherwise stated. Compositions suitable for use in the present invention may also have at least one of the ranges described herein and at least one of the ranges of the monomer compositions described herein, unless otherwise stated. Unless otherwise indicated, it is contemplated that compositions suitable for use in the present invention may have at least one of the intrinsic viscosity ranges described herein, at least one of the Tg ranges described herein, and the monomer compositions described herein. At least one of the ranges. In the examples, terephthalic acid can be used as the starting material. The use of dimethyl sulfonate as a starting material can be used in another embodiment. In still another embodiment, a mixture of terephthalic acid and dimethyl phthalate may be used as a starting material and/or as an intermediate material. In certain embodiments, 'terephthalic acid or its vinegar (such as dimethyl phthalate) or a mixture of terephthalic acid residues and gram thereof may be combined to form a polyester suitable for use in the present invention. Part or all of the carboxylic acid component. In certain embodiments, the terephthalic acid residue may constitute part or all of the dicarboxylic acid component used to form the polyester of the present invention. Higher amounts of terephthalic acid can be used in certain embodiments to produce a higher impact strength. For the purpose of this disclosure, the terms "terephthalic acid" and "terephthalic acid H are used interchangeably herein. In the examples, the terephthalic acid is used to prepare a part or all of the diacid component of the present invention. In all embodiments, (4) to (10) 122661.doc -65 - 200819496 mole %; or 80 to 100 moles 0 / · 10 straight m 〇 / 〇, or 90 to _ 莫 %, · or 99 To 100 m /. , or in the range of 100 mole % κ to the present monocarboxylic acid and / or terephthalic acid dimethyl ester and / or a mixture thereof. In addition to terephthalic acid, the dicarboxylic acid component suitable for _ > A π π π may contain up to 10 mol %, up to 5 簟 ear 0 / seven stone 夕夕夕 5 耳 / 〇 or up to 1 mol% of one or a modified aromatic dicarboxylic acid. A miscellaneous ^ only % of the examples contain 0 mol% of the modified / family of the second. Thus, if present, the amount of the desired or more modified aryl 2 acid can be any such endpoint value, including, for example, up to 10 mole %, 0. 01 to 5 mole % A 〇〇lii Moer%. In the examples, the modified gf-tertogenic tertiary carboxylic acid useful in the present invention includes, but is not limited to, having up to 20 carbons, and may be linear, para- or symmetrical. Etc. Examples of the modified aromatic diacids useful in the present invention include, but are not limited to, isophthalic acid, 4,4,-biphenyldicarboxylic acid, 4-cyanodicarboxylic acid, 1,5-naphthalene. Dicarboxylic acid, 2 6-off _ ψ cabin 0 ", 6-n-carboxylic acid, 2, plant naphthalene dicarboxylic acid and anti-5-formic acid and its cool. Force _ ^L·. J * 1 实施 In Example 10, the modified aromatic bis-acid is isophthalic acid. The tick-removing component of the vinegar suitable for use in the present invention may be subjected to up to 1 Torr (e.g., up to 5 mol% or up to 1 mol%) - or a plurality of aliphatics having 2-16 slave atoms Dicarboxylic acid modification, such aliphatic dicarboxylic acids such as cyclohexane di: acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, sebacic acid and ten Di-burning diterpenic acid. Some embodiments may also include 〇〇ι to _ deaf/. (such as mo mole %, H0 mole %, 5 to 1 mole %) - or a plurality of modified aliphatic dicarboxylic acids. Further - the examples contain a modified aliphatic diremediate acid of 〇mol%. The total molar % of the bis-acidic component is (10) Mo Er 122661.doc -66- 200819496 . /〇. In one embodiment, the modified aliphatic dicarboxylic acid component of the present invention is provided with adipic acid and/or glutaric acid. The modified dicarboxylic acid of the present invention may include an indan dicarboxylic acid such as indane-1,3-dicarboxylic acid and/or phenylindane dicarboxylic acid. In one embodiment, the ditoxaic acid may be selected from the group consisting of 1,2,3-dimethyl-3-phenylindan-4',5-di-oroxic acid; [,;[,3-dimethyl- At least one of 5-rebase-3(4-dezinophenyl)indan dicarboxylic acid. For the purposes of the present invention, the title of Shaikh et al. is "cop〇lymers f

Containing Indan Moieties and Blends Thereof”之美國專利申請公開案第2006/0004151A1號（讓渡於General ElectricU.S. Patent Application Publication No. 2006/0004151A1 to Containing Indan Moieties and Blends Thereof (transfer to General Electric)

Company)中所述之任何茚滿二羧酸均可用作本發明範疇内之至 >、種改質性二羧酸；美國專利申請公開案第 2006/000415 1A1號關於其中所述之任何茚滿二羧酸而以引用的方式併入本文中。可使用對|二甲酉复之酉旨A其他&質性二魏酸或其相應醋及/或鹽來替代二羧酸。二羧酸酯之合適實例包括（但不限 ;)甲酉曰一乙酉曰、二丙酯、二異丙酯、二丁酯及二苯酯。在一實施例中，該等酯係選自以下各酯中之至少一者·甲酯、乙酯、丙酯、異丙酯及苯酯。對於所要聚酉旨而言，順/反2,2,4,4-四甲基]，3_環丁二醇莫耳比可因各純形式及其混合物而不同。在某些實施例中，順及/或反2,2,4,4-四甲基]，3_環丁二醇之莫耳百分數為大於5〇莫耳％之順式與小於50莫耳％之反式；或大於55 莫耳％之順式與小於45莫耳％之反式；或3〇至7〇莫耳％之順式與70至3〇草w 〇/ w j-. 、。之反式；或40至60莫耳。/。之順式與6〇 122661.doc -67- 200819496 至40莫耳％之反式；或5()至7()莫耳％之反式與⑼至％莫耳 %之順式；或50至70莫耳％之順式與5〇至3〇莫耳％之反式；或60至70莫耳％之順式與3〇至4〇莫耳％之反式；或大於70莫耳％之順式與小於3〇莫耳％之反式；其中順與反 2,2,4,4-四甲基{3.環丁二醇之總莫耳百分數等於⑽莫耳 L在另一實施例巾，順/反2,2,4,4_四甲基·^環丁二醇之莫耳比可在5G/5G至之範圍内變化，例如在她〇至 20/80之間。 fAny of the indane dicarboxylic acids described in the company can be used in the context of the present invention, and the modified bis-carboxylic acid; U.S. Patent Application Publication No. 2006/000415 1A1, Indane dicarboxylic acid is incorporated herein by reference. Instead of the dicarboxylic acid, it is possible to use a dimethyl hydrazine A other & urethmic diveric acid or its corresponding vinegar and/or salt. Suitable examples of dicarboxylic acid esters include, but are not limited to, formazan, dipropyl ester, diisopropyl ester, dibutyl ester and diphenyl ester. In one embodiment, the esters are selected from at least one of the following esters: methyl ester, ethyl ester, propyl ester, isopropyl ester, and phenyl ester. For the purpose of the polymerization, the cis/trans 2,2,4,4-tetramethyl], 3-cyclobutanediol molar ratio may vary depending on the pure form and the mixture thereof. In certain embodiments, the percent molar of the cis- or trans- 2,2,4,4-tetramethyl],3-cyclobutanediol is greater than 5 〇 mol % of cis and less than 50 mol Trans-type of %; or more than 55% of cis and less than 45% of trans; or 3〇 to 7〇% of cis and 70 to 3 ww 〇/ w j-. . Trans; or 40 to 60 m. /. The cis is the trans form with 6〇122661.doc -67-200819496 to 40 mol%; or 5 () to 7 () mol% trans and (9) to % mol% cis; or 50 to 70 mil% cis and 5 〇 to 3 〇 mol% trans; or 60 to 70 mol% cis and 3 〇 to 4 〇 mol% trans; or greater than 70 mol% Cis with a trans form of less than 3 〇 mol%; wherein the total molar percentage of cis and trans 2,2,4,4-tetramethyl{3.cyclobutanediol is equal to (10) mole L in another embodiment The molar ratio of the cis/trans 2,2,4,4_tetramethylcyclobutanediol can vary from 5G/5G to, for example, between 20 and 80. f

環己烧二甲醇可為順式、反式或其混合物，例如6〇·4〇至40:60之順/反比率或70:3〇至3〇:7〇之順/反比率。在另一實施例中，反環己烷二甲醇可以6〇至8〇莫耳％之量存在，且順環己烷二甲醇可以20至40莫耳％之量存在，其中順環己烷二曱醇與反環己烷二甲醇之總百分數等於1〇〇莫耳 %。在特定實施例中，反環己烷二甲醇可以6〇莫耳％之量存在且順環己烷二曱醇可以40莫耳％之量存在。在特定實施例中’反環己烧二甲醇可以7G莫耳％之量存在且順環己烷二甲醇可以30莫耳％之量存在。本發明之二醇組份中可存在環己烷二甲醇之任何1，丨_異構體、丨,2_異構體、丨，3-異構體、1，4·異構體或其混合物。la_環己烷二甲醇無順及反異構體存在。在一實施例中，適用於本發明之聚酯包含丨，4_環己烷二甲醇。在另一實施例中，適用於本發明之聚酯包含丨，4-環己烷二甲醇及1，3-環己烷二甲醇。順/反匕仁環己烷二甲醇之莫耳比可在50/50至0/100之範圍内變化，例如在40/60至 122661.doc -68- 200819496 20/80之間。在—實施例中，適用於太中之_ t ^月之聚酯組合物之聚酯部分甲之一醇組份可含有3〇丨刀改質性nee%或小於30莫耳％之一或多種 ^該⑷改質性二醇並非丁一醇或環己烷二甲醇或乙二昝+ 本發明之平故&人％ ,在一實施例中，適用於之^^日組合物之聚酯部且〇/十丨^ I刀肀之一知組份可含有25莫耳/。或小於25莫耳％之一或多旲性-„4、，飞夕種改質性二醇，該（等）改質性一％亚非2,2,4,4_四甲基q 3俨丁貝武，，衣丁二醇或環己烷二甲醇或乙一醇；在一實施例中，雙用於本發明之聚酯組合物之 I酉曰口P刀中之二醇組份々夕有20莫耳％或小於20莫耳％之一或多種改質性二醇，該 > 之其_1 1_ 負性一醇並非2,2,4,4_四甲土 -，·衣丁二醇或環己烷二中，適用#太i nn 醉次乙一知，在一實施例 Τ 週用於本發明之聚酯可合右ϊ认"# 改皙性1 + sT 3有小於15莫耳％之一或多種The cyclohexane dimethanol may be in cis, trans or a mixture thereof, for example, a cis/inverse ratio of 6 〇·4 至 to 40:60 or a cis/inverse ratio of 70:3 〇 to 3 〇:7 。. In another embodiment, the anticyclohexanedimethanol may be present in an amount from 6 to 8 mole percent, and the paracyclohexanedimethanol may be present in an amount from 20 to 40 mole percent, wherein the perylene cyclohexane The total percentage of decyl alcohol and transcyclohexane dimethanol is equal to 1 〇〇 mol%. In a particular embodiment, the anticyclohexanedimethanol can be present in an amount of 6 mole percent and the cis-cyclohexanediol can be present in an amount of 40 mole percent. In a particular embodiment, <RTI ID=0.0>>>>>> Any of the 1, oxime isomer, oxime, 2-isomer, oxime, 3-isomer, 1,4-isomer of cyclohexanedimethanol may be present in the diol component of the present invention or mixture. La-cyclohexanedimethanol is free of the presence of the reverse isomer. In one embodiment, the polyester suitable for use in the present invention comprises hydrazine, 4_cyclohexanedimethanol. In another embodiment, the polyester suitable for use in the present invention comprises decyl, 4-cyclohexanedimethanol and 1,3-cyclohexanedimethanol. The molar ratio of cis/trans-purine cyclohexanedimethanol can vary from 50/50 to 0/100, for example between 40/60 and 122661.doc-68-200819496 20/80. In an embodiment, the polyester portion of the polyester composition suitable for the _ t ^ month of Taizhong may contain 3 改% or less than 30% by mole or A plurality of (4) modifying diols are not butanol or cyclohexanedimethanol or ethanediazine + the present invention & %, in one embodiment, suitable for the polymerization of the composition One of the ester moieties and one of the 〇/十丨^ I knives may contain 25 mol/. Or less than 25 mol%, one or more ---4, 飞种改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改改俨丁贝武,, butyl diol or cyclohexane dimethanol or ethylene glycol; in one embodiment, the diol component of the I PP knife used in the polyester composition of the present invention has 20 mol% or less than 20 mol% of one or more modified diols, the _1 1_ negative monol of the > is not 2,2,4,4_tetramine-, · 衣丁二In the case of alcohol or cyclohexane, it is suitable for use in the case of the invention. In one embodiment, the polyester used in the present invention can be combined with the right ϊ # # # # # # # 有有有有有有有有有有有One or more of the ear %

匕又買Γ生 '—知。在另一 ^ i:L· 2n\ rU Λ 中，適用於本發明之聚酯可含 !:〇莫耳%或小於1〇莫耳，。之-或多種改質性二醇。在： ::例中，適用於本發明之聚醋可含有5莫耳%或小於$ 莫耳/。之一或多種改質性二醇。你力貫施例中，適用於本毛明之聚S|可含有3莫耳％或小於3莫耳％之—或多種改質性二醇。在另—實施例中，適用於本發明之聚醋可含有 2莫耳％或小於2莫耳％之一士夕旲斗之一或多種改質性二醇。在另一施例中，適用於本發明之聚醋可含有〇莫耳％之改質性二醇。適用於本發明之聚酯中所適用之改質性二醇係指不同於 2,2,4,4-四甲基-1，3·環丁二醇、環己烷二甲醇及乙二醇且 122661.doc -69- 200819496 可含有2至16個碳原子之二元醇。合適改質性二醇之實例包括（但不限於）二乙二醇、12_丙二 ^ ^ i，3·丙二醇、新戊 :酵、“4-丁二醇、1>5_戊二醇、“_己二醇、對二甲苯二醇、聚丁二醇及其混合物。在另一實施例中1質性二醇包括（但不限於）1，3-丙二醇及丨，4_丁二醇 Τβ<^主少一者。在一實施例中，至少一種改質性一醢糸一又貝Γ生一知為一乙二醇。在一實施以獨立單體形式添加 ’而係在聚合反例中，二乙二醇並應期間形成。He bought the twins again. In another ^ i: L · 2n \ rU , , the polyester suitable for use in the present invention may contain :: 〇 mol % or less than 1 〇 mol. - or a plurality of modified diols. In the ::: example, the polyacetic acid suitable for use in the present invention may contain 5 mol% or less than mol%. One or more modified diols. In the case of your application, the poly-S| which is suitable for the present hair may contain 3 mol% or less than 3 mol% - or a plurality of modified diols. In another embodiment, the polyester suitable for use in the present invention may contain one mole or more of a modified diol of 2 mole % or less than 2 mole %. In another embodiment, the polyacetic acid suitable for use in the present invention may contain a molar amount of a modified diol. The modified diol suitable for use in the polyester of the present invention means different from 2,2,4,4-tetramethyl-1,3·cyclobutanediol, cyclohexanedimethanol and ethylene glycol. And 122661.doc -69- 200819496 may contain a glycol of 2 to 16 carbon atoms. Examples of suitable modifying diols include, but are not limited to, diethylene glycol, 12-propanol, propylene glycol, neopentyl glycol, "4-butanediol, 1> 5-pentanediol , "_hexanediol, p-xylene glycol, polybutylene glycol, and mixtures thereof. In another embodiment, the monovalent diol includes, but is not limited to, 1,3-propanediol and hydrazine, and 4-butanediol Τβ < In one embodiment, at least one of the modifiers is known as monoethylene glycol. In one embodiment, the addition of 'in the form of a separate monomer' is in the polymerization reaction, and diethylene glycol is formed during the period.

以二元醇或二酸殘基之總莫耳百分數計，適用於本發明之聚醋組合物中之聚醋可分別包含0至1〇莫耳例如請至5莫耳％、0.0^莫耳％、〇〇5至5莫耳％、〇〇5υ莫耳 %或0.1至G.7莫耳％)之—或多種具有3個或3個以上叛基取代基、經基取代基或其組合之分枝單體的殘基，本文中亦稱為分枝劑。在某些實施例中，分枝單體或分枝劑可在聚酯之聚合反應之前及/或期間及/或之後添加。因此，適用於本發明之聚酯可為直鏈或分枝的。分枝單體之實例包括（但不限於）多官能酸或多官能醇，諸如偏苯一酸、偏苯三酸酐、均苯四酸二酐、三羥甲基丙烷、甘油、異戊四醇、檸檬酸、酒石酸、3_羥基戊二酸及類似物。在—實施例中，分枝單體殘基可包含G.1至〇·7莫耳之或多種選自以下至少一者之殘基··偏苯三酸酐、均苯四s文一酐、甘油、山梨糖醇、ι，2,6-己烷三醇、異戊四醇、二羥甲基乙烷及/或均苯三酸。分枝單體可添加至聚S日反應此合物中，或以濃縮物形式與聚酯摻合，如例如 122661.doc 200819496 、、，專利第5,654,347號及第5,696，176號中所述，其關於分枝單體之揭示内容以引用的方式併入本文中。 ^月之聚i曰可包含至少一種增鏈劑。合適增鏈劑包括处四~限於）夕g ^ (包括（但不限於）雙官能）異氰酸酯、多官月匕衣氧化物（例如包括環氧化盼盤清漆）及苯氧基樹脂。在某些實施例中，增鏈劑可在聚合製程結束時或在聚合製程後添加。右在聚合製程之後添加，貝J可在轉化製程（諸如射出成形或擠出）期間藉由混合或藉由添加來併入增鏈劑。增鏈劑之使用量可視所用之具體單體組成及所要之物特欧而I化，但以聚醋之總重量計，一般為約〇· 1重量％至約10重量％，諸如約0.1重量％至約5重量％。適用於本發明之聚醋之玻璃轉移溫度⑹係使用丁^而！The polyester used in the polyester vinegar composition of the present invention may comprise 0 to 1 moles, for example, up to 5 mole %, 0.0 moles, based on the total mole percent of the diol or diacid residue. %, 〇〇 5 to 5 mol %, 〇〇 5 υ mol % or 0.1 to G. 7 mol %) - or a plurality of having 3 or more ruthenyl substituents, via substituents or combinations thereof The residue of the branched monomer is also referred to herein as a branching agent. In certain embodiments, the branching monomer or branching agent can be added before and/or during and/or after polymerization of the polyester. Thus, the polyesters suitable for use in the present invention may be straight or branched. Examples of branched monomers include, but are not limited to, polyfunctional acids or polyfunctional alcohols such as trimellitic acid, trimellitic anhydride, pyromellitic dianhydride, trimethylolpropane, glycerol, isovalerol, citric acid , tartaric acid, 3-hydroxyglutaric acid and the like. In an embodiment, the branched monomer residue may comprise G.1 to 77 molar or a plurality of residues selected from at least one of the following: trimellitic anhydride, pyromellitic anhydride, glycerin, sorbus Sugar alcohol, iota, 2,6-hexanetriol, pentaerythritol, dimethylolethane and/or trimesic acid. The branched monomer may be added to the poly-S day reaction mixture, or may be blended with the polyester in the form of a concentrate, as described in, for example, 122661.doc 200819496, the patents 5,654,347 and 5,696,176. Its disclosure regarding branched monomers is incorporated herein by reference. ^月聚聚曰 can contain at least one chain extender. Suitable chain extenders include, in addition to, but not limited to, oxime (including, but not limited to, difunctional) isocyanates, polyglycol oxides (e.g., including epoxidized tray varnishes), and phenoxy resins. In certain embodiments, the chain extender can be added at the end of the polymerization process or after the polymerization process. The right is added after the polymerization process, and the binder can be incorporated by mixing or by addition during the conversion process (such as injection molding or extrusion). The amount of the chain extender used may be determined by the specific monomer composition used and the desired content, but is generally from about 1% by weight to about 10% by weight, such as about 0.1% by weight based on the total weight of the vinegar. % to about 5% by weight. The glass transition temperature (6) of the vinegar which is suitable for the present invention is used for D;

Analyst Instrument之TA峨292〇以邮心之掃描速率來測定。由於某些適用於本發明之聚酯在1 7〇。。下所展現之長的半結晶期（例如大於5分鐘），因此其可製備物品，包括（作不限於）射出成形部件、射出吹塑成形物品、射出拉伸吹塑成形物品、撩出薄膜、擠出薄片、擠出吹塑成形物品、擠出拉伸吹塑成形物品及纖維。可熱成型薄片為本發提供之製品的實例。本發明之聚酯可為非晶形或半晶質。在一態樣中，適用於本發明之某些聚酯可具有相對低之社晶度。iUb，適用於本發明之某些聚酯可具有實質形之形態，意謂該等聚醋包含聚合物之實質無序區。M 在-實施例中，"非晶形I，聚酯在17Gt下可具有大於5分 122661.doc 71 200819496 鐘之半結晶期，或在17(TC下可具有大於1〇分鐘之半結晶期，或在170°C下可具有大於50分鐘之半結晶期，或在 17〇°C下可具有大於1〇〇分鐘之半結晶期。在本發明之一實施例中，在17(TC下之半結晶期可大於！，〇〇〇分鐘。在本發明之另一實施例中，適用於本發明之聚酯之半結晶期在 170°C下可大於1〇,〇〇〇分鐘。如本文所用，聚酯之半結晶期可使用熟習此項技術者熟知之方法來量測。舉例而言，聚酯之半結晶期可藉由在溫控熱階段經由雷射器及光偵測器量測作為時間函數之樣本透光率來測定。此量測可如下進行：藉由將聚合物暴露於溫度Tmax，且接著將其冷卻至所要溫度。接著可由熱階段使樣本保持在所要溫度，同時量測作為時間函數之透光率。最初，樣本具有高透光率，透明可視，而當樣本結晶時變得不透明。半結晶期為透光率介於初始透光率與最終透光率之間一半時之時間。 Tmax係定義為熔融樣本之結晶型區（若存在結晶型區）所需之溫度。樣本可經加熱至Tmax以調適樣本，之後再進行半結晶期之量測。絕對Tmax溫度因各自組成而異。舉例而言，PCT可經加熱至大於29(rc之某一溫度以熔融結晶型區。在一實施例中，適用於本發明之某些聚酯透明可視。術浯"透明可視”在本文中定義為當視覺檢查時，無可感知之雲斑、模糊及/或混濁存在。在另一實施例中，當將聚酯與聚碳酸酯（包括（但不限於）雙酚A聚碳酸酯）摻合時，摻合物透明可視。 122661.doc -72· 200819496 在一實施例中，適用於本發明之聚酯及/或本發明之聚酯組合物[在一實施例中，在調色劑存在及/或不存在下]可具有可使用 Hunter Associates Lab Inc·，Rest〇n，Va所製造之Hunter Lab Ultrascan光譜色度計測定之色值乙*、？及 b*。色值測定值為對聚g旨顆粒或平板或由其射出成形或擠出之其他物件所量測之數值的平均值。其係藉由CIE(國際照明委員會，已譯）之L*a*b*色彩系統來測定，其中^表示明度座軚，a*表示紅色/綠色座標，且b*表示黃色/藍色座標。在某些實施例中，適用於本發明之聚酯[在一實施例中，在調色劑存在及/或不存在下]2b*值可為_12至小於 12且L*值可為50至90。在其他實施例中，適用於本發明之聚酯[在一實施例中，在調色劑存在及/或不存在下]2b*值可存在於以下範圍之一者中：_1〇至1〇 ; _1〇至小於i〇 ; _ι〇 -10至 4 ; -10至 ;-5 至 5 ; -5 至至9; -10至 8; ·1〇至 7; _1〇至 6; _1〇至5; 3 ; -10 至 2 ; _5 至 9 ; ·5 至 8 ; -5 至 7 ; ·5 至 6 4 ; _5 至 3 ’· -5 至 2 ’· 〇至 9 ; 〇至 8 ; 〇至 7 ; 〇至 6 ; 〇至 5 ; 〇至 4; 〇至3; 0至2; u10;⑴；…"至7;⑴"至 5’ 1至4’ 1至3’及1至2。在其他實施例中，適用於本發明之聚酯之L*值可存在於以下範圍之一者中：切至⑼，· 5〇至 70，· 50至 80 ; 50至 90 ; 60至 70，· 60至 80 ; 60至 9〇 ; 7〇至 80 ; 79至 90 ° 據信用於製備含有乙二醇之聚醋的錫催化劑或鈦催化劑會使得發生有害之色彩相互作用。在本發明之―實施例中，據信如本文所述使用至少一種鈦化合物及至少一種錫 122661.doc -73- 200819496 化合物與至少一種磷化合物組合所製成之適用於本發明之聚s曰的b*色值與在該等聚酯之產生中單獨使用錫催化劑相比係顯著之改良。亦據信將至少一種鈦催化劑與至少一種磷化合物組合用於製備適用於本發明之聚酯與在該等聚酯之產生中單獨使用鈦催化劑相比係顯著之改良。如ASTM D2 5 6中戶斤述之伊佐德、氏缺口衝$強度為量測動性之常用方法。在本文中，伊佐德氏缺口衝擊強度係於 23 C下，以根據ASTM D256所測定之3.2 mm(l/8吋）厚棒中之1 〇禮耳缺口來量測的。在一實施例中，適用於本發明之某些聚酯於23°C下，以根據AStM D256所測定之3.2 mm(1/8吋）厚棒中之1〇密耳缺口可展現至少5〇〇 j/m(i〇〜 lb/in)之伊佐德氏缺口衝擊強度。在一實施例中，適用於本發明之某些聚酯於23°C下，以根據八8丁]^ £)256所測定之 3·2 mm(1/8吋）厚棒中之1〇密耳缺口可展現約ι〇仏比/匕至、、、勺3 5 fMb/ιη之伊佐德氏缺口衝擊強度。在另一實施例中，適用於本發明之某些聚酯於23。〇下，以根據astm D256所測定之3.2 mm(l/8吋）厚棒中之1〇密耳缺口可展現約10 ft-lb/’in至不斷裂之伊佐德氏缺口衝擊強度。在一實施例中，適用於本發明之某些聚酯於23。〇下可展現大於1.2 g/ml之密度。在一實施例中，適用於本發明之某些聚酯於23。〇下可展現等於或大於290,000 psi之撓曲模數（如ASTM 〇79〇所定義）。在另一實施例中，適用於本發明之某些聚酯於23。〇下可展現約290,000 psi至約37〇,〇〇〇 psi之撓曲模數（如 122661.doc •74- 200819496 ASTM D790所定義）。在另一實施例中，適用於本發明之某些聚酯於23°C下可展現約290,000 psi至約350,000 psi之撓曲模數（如ASTM D790所定義）。適用於本發明之某些聚酯可具有以下特性中之至少一者：約 100°C 至約 1 l〇°C 之 Tg(如由 TA 2100 Thermal Analyst Instrument以20°C/min之掃描速率所量測）；於23°C下等於或大於290,000 psi之撓曲模數（如ASTM D790所定義）；及等於或大於10 ft-lb/in之伊佐德氏缺口衝擊強度（於23°C 下，使用1/8-吋厚棒，以10密耳缺口，根據ASTM D25 6所測定）。適用於本發明之其他聚酯可具有以下特性中之至少一者：約 100°C 至約 110°C 之 Tg(如由 TA 2100 Thermal Analyst Instrument以20°C /min之掃描速率所量測）；於23°C下約 290.000 psi至約3 70,000 psi之撓曲模數（如ASTM D790所定義）；及大於10 ft-lb/in至不斷裂之伊佐德氏缺口衝擊強度 (於23 °C下，使用1/8吋厚棒，以10密耳缺口，根據ASTM D256所測定）。適用於本發明之其他聚酯可具有以下特性中之至少一者：約 100°C 至約 110°c 之 Tg(如由 TA 2100 Thermal Analyst Instrument以20°C/min之掃描速率所量測）；於23°C下約 290.000 psi至約370,000 psi之撓曲模數（如ASTM D790所定義）；及大於10 ft-lb/in至3 5 ft-lb/in之伊佐德氏缺口衝擊強度（於23 °C下，使用1/8吋厚棒，以10密耳缺口，根據ASTM D256所測定）。 122661.doc -75- 200819496 在某些實施例中，使用適用於本發明之聚酯組合物可最小化及/或取消熔融加工及/或熱成型之前的乾燥步驟。在一實施例中，適用於本發明之磷化合物可為有機化合物，諸如含有鹵化或非鹵化有機取代基之磷酸酯。適用於本發明之磷化合物包含此項技術中熟知之多種磷化合物，諸如膦、亞磷酸酯、亞膦酸酯、亞膦酸二酯、次膦酸g旨、膦酸酯、膦氧化物及磷酸酯。適用於本發明之磷化合物之實例可包括磷酸三丁酯、碟酸三乙酯、磷酸三丁氧基乙酯、磷酸第三丁基苯基二苯酯、磷酸2-乙基己基二苯酯、磷酸乙基二甲酯、磷酸異癸基二苯酯、磷酸三月桂酯、磷酸三苯酯、磷酸三甲苯_、磷酸三-二甲苯酯、磷酸第三丁基苯基二苯酯、間苯二紛雙（磷酸二苯酯）、磷酸三苄酯、磷酸苯基乙酯、硫代磷酸三甲酯、硫代磷酸苯基乙酯、膦酸二甲基甲酯、膦酸二乙基甲酯、膦酸二乙基戊酯、膦酸二月桂基甲酯、膦酸二苯基甲酯、膦酸二苄基甲酯、膦酸二苯基甲苯酯、膦酸二甲基甲苯酯、硫代膦酸二甲基甲酯、膦酸苯基二苯酯、膦酸 T基一笨_、膦酸甲基二苯S旨、三甲基膦氧化物、三笨基膦氧化物、三节基膦氧化物、4-甲基二苯基膦氧化物、亞磷酸三乙酯、亞磷酸三丁酯、亞磷酸三月桂酯、亞磷酸三苯酯、亞磷酸三苄酯、亞磷酸苯基二乙酯、亞磷酸苯基二甲酯、亞磷酸苄基二甲酯、二甲基曱基亞膦酸二酯、二乙基戊基亞膦酸二酯、二苯基甲基亞膦酸二酯、二苄基曱基亞膦酸二酯、二甲基甲苯基亞膦酸二酯、亞膦酸甲基二甲 122661.doc -76 - 200819496 酯、亞膦酸甲基二乙酯、亞膦酸苯基二苯酯、亞膦酸甲基一苯s旨、亞膊酸卞基一本s旨、三苯基鱗、三节基膦及甲基二苯膦。在一實施例中，在製備適用於本發明之聚酯及/ 或本發明之聚酯組合物之製程中不包括作為熱穩定劑之三苯基膦氧化物。在一實施例中’適用於本發明之磷化合物可為任何上述磷基酸’其中酸化合物中之一或多個氫原子（與氧或碌原子鍵結者）已置換為烷基、支鏈烷基、經取代之燒基、烧 ( 基醚、經取代之烷基醚、烷基_芳基、經烷基取代之芳基、芳基、經取代之芳基及其混合物。在另一實施例中，適用於本發明之鱗化合物包括（但不限於）上述化合物，其中化合物中與氧原子鍵結之至少一個氫原子已置換為金屬離子或鈹離子。该荨醋可含有烧基、支鏈烧基、經取代之烧基、烧基鱗、芳基及/或經取代之芳基。該等酯亦可具有至少一個烧基及至少一個芳基。特定磷化合物中所存在之酯基的數 i 目可為零直至所用磷化合物中所存在之羥基數目可容許之最大數目。舉例而言，烷基磷酸酯可包括單烷基磷酸酯、一烷基磷酸酯及三烷基磷酸酯中之一或多者；芳基磷酸酯包括單芳基磷酸酯、二芳基磷酸酯及三芳基磷酸酯中之一或多者；且烷基磷酸酯及/或芳基磷酸酯亦包括（但不限於）具有至少一個烷基及一個芳基之混合型烷基芳基磷酸酯。在 g施例中’適用於本發明之填化合物包括（但不限於）磷酸、亞磷酸、次膦酸、膦酸或亞膦酸之烷基酯、芳 122661.doc -77· 200819496 基醋或混合型燒基芳基醋或偏醋。該等烧基或芳基可含有一或多個取代基。在一態樣中，適用於本發明之磷化合物包含至少一種選自以下各物中至少一者之磷化合物：經取代或未經取代之烷基磷酸酯、經取代或未經取代之芳基磷酸酯 '經取代或未經取代之混合型烷基芳基磷酸酯、二亞磷酸酯、磷酸鹽、膦氧化物，及混合型芳基烷基亞磷酸酯、其反應產物及其混合物。磷酸酯包括其中磷酸經完全酯化或僅部分酯 f 化之_。舉例而言，在一實施例中，適用於本發明之磷化合物可包括至少一種磷酸酯。在一態樣中，適用於本發明之磷化合物包含至少一種選自以下各物中至少一者之磷化合物：經取代或未經取代之燒基磷酸酯、經取代或未經取代之芳基磷酸酯、經取代或未經取代之混合型烷基芳基構酸酯、其反應產物及其混合物。磷酸酯包括其中磷酸經完全酯化或僅部分酯化之醋。 I 舉例而言，在一實施例中，適用於本發明之磷化合物可包括至少一種鱗酸S旨。在另一實施例中，適用於本發明之磷酸酯可包括（但不限於）烧基磷酸酯、芳基磷酸酯、混合型烷基芳基磷酸酯及/或其混合物。在某些實施例中’適用於本發明之磷酸酯為其中磷酸酯上之基團包括烧基、烧氧基烧基、苯基或經取代之苯基的彼等構酸酯。該等鱗酸酯在本文中一般稱為烧基構酸酯及/ 122661.doc •78- 200819496 或芳基磷酸酯。某些較佳實施例包括三烷基磷酸酯、三芳基磷酸酯、烷基二芳基磷酸酯、二烷基芳基磷酸酯及該等磷酸酯之混合物，其中烷基較佳為含有2至12個碳原子之彼等烧基’且芳基較佳為苯基。代表性烧基及支鏈烷基較佳為含有1-12個碳原子之彼等烷基’包括（但不限於）乙基、丙基、異丙基、丁基、己基、環己基、2-乙基己基、辛基、癸基及十二烷基。經取代之烧基包括（但不限於）含有羧酸基團及其酯、羥基、胺基、酮基及其類似基團中之至少一者的彼等烷基。代表性烷基芳基及經取代之烷基芳基為其中烷基部分含有1-12個碳原子且芳基為苯基或經取代之苯基的彼等基團，其中諸如烷基、支鏈烷基、芳基、羥基及其類似基團之基團取代苯環上任何碳位置處之氫。較佳芳基包括苯基或經取代之苯基，其中諸如烷基、支鏈烷基、芳基、羥基及其類似基團之基團取代苯環上任何位置處之氫。在一實施例中，適用於本發明之磷酸酯包括（但不限於）磷酸二丁基苯酯、磷酸三苯酯、磷酸三曱苯酯、磷酸三丁酯、磷酸三-2_乙基己酯、磷酸三辛酯及/或其混合物，尤其包括磷酸三丁酯與磷酸三甲苯酯之混合物及磷酸異十六烷基二苯酯與磷酸2-乙基己基二苯酯之混合物。在一實施例中，至少一種適用於本發明之鱗化合物包含至少一種芳基磷酸酯。在一實施例中，至少一種適用於本發明之磷化合物包含至少一種未經取代之芳基磷酸酯。 122661.doc -79- 200819496 種適用於本發明之磷化合物包含至芳基磷酸酯。用於本發明之磷化合物均可包含至在一實施例中，在本發穩定劑之磷酸酯包括（但不基磷酸酯、三芳基磷酸酉旨基方基麟酸醋。Analyst Instrument's TA峨292〇 is measured at the scanning rate of the postal heart. Since some of the polyesters suitable for use in the present invention are at 17 Torr. . The long semi-crystalline period (for example, greater than 5 minutes) exhibited, so that it can prepare articles including, without limitation, injection molding parts, injection blow molded articles, injection stretch blow molded articles, pour-out films, Extrusion sheets, extrusion blow molded articles, extrusion stretch blow molded articles, and fibers. Thermoformable sheets are examples of articles provided by the present invention. The polyester of the present invention may be amorphous or semicrystalline. In one aspect, certain polyesters suitable for use in the present invention may have a relatively low degree of crystallinity. iUb, certain polyesters suitable for use in the present invention may have a substantially morphological form, meaning that the polyesters comprise substantially disordered regions of the polymer. M In the embodiment, "amorphous I, the polyester may have a semi-crystallization period of greater than 5 minutes 122661.doc 71 200819496 clock at 17 Gt, or a semi-crystallization period of greater than 1 minute at 17 (TC) Or may have a half crystallization period of greater than 50 minutes at 170 ° C, or a half crystallization period of greater than 1 〇〇 minutes at 17 ° C. In one embodiment of the invention, at 17 (TC) The half crystallization period may be greater than !, 〇〇〇 min. In another embodiment of the invention, the semi-crystalline period of the polyester suitable for use in the present invention may be greater than 1 Torr at 170 ° C. As used herein, the semi-crystalline phase of the polyester can be measured using methods well known to those skilled in the art. For example, the semi-crystallization phase of the polyester can be via a laser and a photodetector during the temperature-controlled thermal phase. The measurement is measured as the sample transmittance as a function of time. This measurement can be performed by exposing the polymer to temperature Tmax and then cooling it to the desired temperature. The sample can then be held at the desired temperature by the thermal phase, Simultaneously measure the light transmittance as a function of time. Initially, the sample has high light transmission. Rate, transparent visible, and becomes opaque when the sample crystallizes. The semi-crystallization period is the time when the light transmittance is half between the initial light transmittance and the final light transmittance. Tmax is defined as the crystalline region of the molten sample ( If there is a temperature required for the crystalline region, the sample can be heated to Tmax to adjust the sample, followed by a semi-crystallization period. The absolute Tmax temperature varies with the composition. For example, PCT can be heated to greater than 29 (a certain temperature of rc to melt the crystalline zone. In one embodiment, some of the polyesters suitable for use in the present invention are transparently visible. The term "transparently visible" is defined herein as being visually inspectable. Perceived cloud spots, blurring, and/or turbidity. In another embodiment, the blend is transparent when blended with polycarbonate (including but not limited to bisphenol A polycarbonate) 122661.doc -72· 200819496 In one embodiment, a polyester suitable for use in the present invention and/or a polyester composition of the present invention [in one embodiment, in the presence and/or absence of a toner] Can have access to Hunter Associates Lab Inc. The color values measured by the Hunter Lab Ultrascan Spectrophotometer manufactured by Rest〇n, Va, B, *, and b*. The color value is the value of the particles or the plate or other objects formed or extruded by the injection. The average of the measured values, which is determined by the L*a*b* color system of CIE (International Commission on Illumination, translated), where ^ denotes the brightness coordinates, a* denotes the red/green coordinates, and b * indicates yellow/blue coordinates. In some embodiments, the polyester suitable for use in the present invention [in one embodiment, in the presence and/or absence of toner] the 2b* value may be from _12 to less than 12 and the L* value can be from 50 to 90. In other embodiments, the polyester suitable for use in the present invention [in one embodiment, in the presence and/or absence of toner] 2b* values may be present in one of the following ranges: _1 〇 to 1 〇 ; _1〇 to less than i〇; _ι〇-10 to 4; -10 to; -5 to 5; -5 to to 9; -10 to 8; ·1 to 7; _1 to 6; _1 to 5 ; 3 ; -10 to 2 ; _5 to 9 ; · 5 to 8 ; -5 to 7 ; · 5 to 6 4 ; _5 to 3 '· -5 to 2 '· 〇 to 9 ; 〇 to 8 ; ; 〇 to 6 ; 〇 to 5 ; 〇 to 4; 〇 to 3; 0 to 2; u10; (1);..." to 7; (1) " to 5' 1 to 4' 1 to 3' and 1 to 2. In other embodiments, the L* value of the polyester suitable for use in the present invention may be present in one of the following ranges: cut to (9), ·5 to 70, ·50 to 80; 50 to 90; 60 to 70, • 60 to 80; 60 to 9 Torr; 7 to 80; 79 to 90 ° It is believed that tin catalysts or titanium catalysts used to prepare polyethylene glycol-containing polyesters can cause unwanted color interactions. In an "embodiment" of the invention, it is believed to be useful in the present invention as described herein using at least one titanium compound and at least one tin 122661.doc-73-200819496 compound in combination with at least one phosphorus compound. The b* color value is a significant improvement over the use of a tin catalyst alone in the production of such polyesters. It is also believed that the combination of at least one titanium catalyst with at least one phosphorus compound for the preparation of a polyester suitable for use in the present invention is a significant improvement over the use of a titanium catalyst alone in the production of such polyesters. For example, ASTM D2 5 6 is a commonly used method for measuring the dynamics of Izod and the gap. In this paper, Izod's notched impact strength is measured at 23 C and measured as a 1 〇 ear ear gap in a 3.2 mm (l/8 Å) thick rod as determined by ASTM D256. In one embodiment, certain polyesters suitable for use in the present invention exhibit at least 5 Å at a temperature of 23 ° C in a 3.2 mm (1/8 Å) thick bar as measured according to ASTM M D256. Izod's notched impact strength of 〇j/m (i〇~ lb/in). In one embodiment, some of the polyesters suitable for use in the present invention are at a temperature of 23 ° C, one of the 3·2 mm (1/8 吋) thick rods determined according to 八八 ] ^ ) 256 The mil notch can exhibit an Izod notched impact strength of about ι 〇仏 / 匕 to , , , , 3 5 fMb / ιη. In another embodiment, certain polyesters suitable for use in the present invention are at 23. Under the armpit, a 1 mil nip in a 3.2 mm (l/8 Å) thick rod as measured by astm D256 exhibits an Izod notched impact strength of about 10 ft-lb/'in to no break. In one embodiment, certain polyesters suitable for use in the present invention are at 23. The underarm can exhibit a density greater than 1.2 g/ml. In one embodiment, certain polyesters suitable for use in the present invention are at 23. The underarm can exhibit a flexural modulus equal to or greater than 290,000 psi (as defined by ASTM 〇79〇). In another embodiment, certain polyesters suitable for use in the present invention are at 23. 〇 can exhibit a flexural modulus of approximately 290,000 psi to approximately 37 〇, 〇〇〇 psi (as defined by ASTM D790, 122661.doc • 74-200819496). In another embodiment, certain polyesters suitable for use in the present invention exhibit a flexural modulus (as defined by ASTM D790) of from about 290,000 psi to about 350,000 psi at 23 °C. Certain polyesters suitable for use in the present invention may have at least one of the following characteristics: a Tg of from about 100 ° C to about 1 l ° ° C (as measured by a TA 2100 Thermal Analyst Instrument at a scan rate of 20 ° C/min) Measurement); a flexural modulus equal to or greater than 290,000 psi at 23 ° C (as defined by ASTM D790); and an Izod notched impact strength equal to or greater than 10 ft-lb/in (at 23 ° C) , using a 1/8-thick bar, with a 10 mil notch, as determined by ASTM D25 6). Other polyesters suitable for use in the present invention may have at least one of the following characteristics: a Tg of from about 100 ° C to about 110 ° C (as measured by a TA 2100 Thermal Analyst Instrument at a scan rate of 20 ° C / min) ; a flexural modulus of from about 290.000 psi to about 3 70,000 psi at 23 ° C (as defined by ASTM D790); and an Izod notched impact strength of greater than 10 ft-lb/in to no break (at 23 ° C) Next, use a 1/8 inch thick rod with a 10 mil notch, as determined by ASTM D256). Other polyesters suitable for use in the present invention may have at least one of the following characteristics: a Tg of from about 100 ° C to about 110 ° C (as measured by a TA 2100 Thermal Analyst Instrument at a scan rate of 20 ° C/min) ; a flexural modulus of from about 290.000 psi to about 370,000 psi at 23 ° C (as defined by ASTM D790); and an Izod notched impact strength of greater than 10 ft-lb/in to 35 ft-lb/in ( At 23 ° C, use a 1/8 吋 thick rod with a 10 mil notch, as determined by ASTM D256). 122661.doc -75- 200819496 In certain embodiments, the use of the polyester composition suitable for use in the present invention minimizes and/or eliminates the drying step prior to melt processing and/or thermoforming. In one embodiment, the phosphorus compound suitable for use in the present invention may be an organic compound such as a phosphate containing a halogenated or non-halogenated organic substituent. Phosphorus compounds suitable for use in the present invention comprise a plurality of phosphorus compounds well known in the art, such as phosphines, phosphites, phosphonites, phosphinates, phosphinic acid, phosphonates, phosphine oxides and Phosphate ester. Examples of the phosphorus compound suitable for use in the present invention may include tributyl phosphate, triethyl silicate, tributoxyethyl phosphate, t-butylphenyl diphenyl phosphate, 2-ethylhexyl diphenyl phosphate. , ethyl dimethyl phosphate, isodecyl diphenyl phosphate, trilauryl phosphate, triphenyl phosphate, trimethyl phosphate _, tri-xylylene phosphate, t-butylphenyl diphenyl phosphate, Benzodiazepine (diphenyl phosphate), tribenzyl phosphate, phenylethyl phosphate, trimethyl thiophosphate, phenylethyl thiophosphate, dimethyl methylphosphonate, diethyl phosphonate Methyl ester, diethyl amyl phosphonate, dilauryl methyl phosphonate, diphenyl methyl phosphonate, dibenzyl methyl phosphonate, diphenyl toluene phosphonate, dimethyl toluene phosphonate , dimethyl thiophosphonate, phenyl diphenyl phosphonate, phosphonic acid T-based _, phosphonic acid methyl diphenyl S, trimethyl phosphine oxide, tri-phenylphosphine oxide, Trisylphosphine oxide, 4-methyldiphenylphosphine oxide, triethyl phosphite, tributyl phosphite, trilauryl phosphite, triphenyl phosphite, tribenzyl phosphite Ester, phenyldiethyl phosphite, phenyl dimethyl phosphite, benzyl dimethyl phosphite, dimethyl decylphosphonic acid diester, diethyl amyl phosphinate diester, diphenyl Methylphosphinic acid diester, dibenzyl decylphosphonic acid diester, dimethyltolylphosphinic acid diester, phosphinic acid methyl dimethyl 122661.doc -76 - 200819496 ester, phosphinic acid Methyl diethyl ester, phenyl diphenyl phosphinate, methyl phenyl phosphite, benzoic acid, triphenyl sulphate, trisylphosphine and methyl diphenyl phosphine. In one embodiment, the triphenylphosphine oxide as a heat stabilizer is not included in the process for preparing the polyester suitable for use in the present invention and/or the polyester composition of the present invention. In one embodiment, 'the phosphorus compound suitable for use in the present invention may be any of the above-mentioned phosphonic acids' in which one or more hydrogen atoms (bonded with oxygen or a halogen atom) in the acid compound have been replaced with an alkyl group, a branch An alkyl group, a substituted alkyl group, an alkyl group, a substituted alkyl ether, an alkyl-aryl group, an alkyl-substituted aryl group, an aryl group, a substituted aryl group, and a mixture thereof. In the examples, the scaly compound suitable for use in the present invention includes, but is not limited to, the above compounds, wherein at least one hydrogen atom bonded to the oxygen atom in the compound has been replaced with a metal ion or a cesium ion. a branched alkyl group, a substituted alkyl group, a decyl group, an aryl group and/or a substituted aryl group. The esters may also have at least one alkyl group and at least one aryl group. The esters present in the specific phosphorus compound The number of bases can be zero until the maximum number of hydroxyl groups present in the phosphorus compound used can be tolerated. For example, alkyl phosphates can include monoalkyl phosphates, monoalkyl phosphates, and trialkyl phosphates. One or more of the esters; aryl phosphate Including one or more of a monoaryl phosphate, a diaryl phosphate, and a triaryl phosphate; and the alkyl phosphate and/or aryl phosphate also includes, but is not limited to, having at least one alkyl group and one Mixed aryl aryl phosphates of aryl groups. In the g application, 'filling compounds suitable for use in the present invention include, but are not limited to, alkyl esters of phosphoric acid, phosphorous acid, phosphinic acid, phosphonic acid or phosphinic acid. , 芳122661.doc -77· 200819496 based vinegar or mixed aryl vinegar or partial vinegar. The alkyl or aryl group may contain one or more substituents. In one aspect, suitable for use in the present invention The phosphorus compound comprises at least one phosphorus compound selected from the group consisting of substituted or unsubstituted alkyl phosphates, substituted or unsubstituted aryl phosphates' substituted or unsubstituted mixtures Type alkyl aryl phosphates, diphosphites, phosphates, phosphine oxides, and mixed aryl alkyl phosphites, reaction products thereof, and mixtures thereof. Phosphates include those in which the phosphoric acid is fully esterified or only partially Ester f--. For example, in an embodiment The phosphorus compound suitable for use in the present invention may comprise at least one phosphate ester. In one aspect, the phosphorus compound suitable for use in the present invention comprises at least one phosphorus compound selected from at least one of the following: substituted or unsubstituted a pyridyl phosphate, a substituted or unsubstituted aryl phosphate, a substituted or unsubstituted mixed alkyl aryl acid ester, a reaction product thereof, and a mixture thereof. The phosphate ester includes a phosphoric acid ester thereof. Or a partially esterified vinegar. For example, in one embodiment, a phosphorus compound suitable for use in the present invention may include at least one sulphuric acid. In another embodiment, a phosphate ester suitable for use in the present invention These may include, but are not limited to, alkyl phosphates, aryl phosphates, mixed alkyl aryl phosphates, and/or mixtures thereof. In certain embodiments, the phosphates suitable for use in the present invention are those on which phosphates are present. The group includes an alkylate, an alkoxyalkyl group, a phenyl group or a substituted phenyl ester of a substituted phenyl group. Such carboxylic acid esters are generally referred to herein as alkyl acrylates and / 122661.doc • 78- 200819496 or aryl phosphates. Some preferred embodiments include a trialkyl phosphate, a triaryl phosphate, an alkyl diaryl phosphate, a dialkyl aryl phosphate, and a mixture of such phosphates, wherein the alkyl group preferably contains 2 to The one of the 12 carbon atoms is a ketone group and the aryl group is preferably a phenyl group. Representative alkyl and branched alkyl groups are preferably those having from 1 to 12 carbon atoms, including but not limited to ethyl, propyl, isopropyl, butyl, hexyl, cyclohexyl, 2 Ethylhexyl, octyl, decyl and dodecyl. Substituted alkyl groups include, but are not limited to, those alkyl groups containing a carboxylic acid group and at least one of an ester, a hydroxyl group, an amine group, a ketone group, and the like. Representative alkylaryl and substituted alkylaryl are those wherein the alkyl moiety contains from 1 to 12 carbon atoms and the aryl is phenyl or substituted phenyl, such as alkyl, The groups of the alkyl, aryl, hydroxy, and the like replace the hydrogen at any carbon position on the phenyl ring. Preferred aryl groups include phenyl or substituted phenyl groups in which a group such as an alkyl group, a branched alkyl group, an aryl group, a hydroxyl group and the like is substituted for a hydrogen at any position on the benzene ring. In one embodiment, phosphate esters suitable for use in the present invention include, but are not limited to, dibutyl phenyl phosphate, triphenyl phosphate, triphenyl phenyl phosphate, tributyl phosphate, tris-2-ethyl phosphate Esters, trioctyl phosphate and/or mixtures thereof, especially comprising a mixture of tributyl phosphate and tricresyl phosphate and a mixture of isohexadecyl diphenyl phosphate and 2-ethylhexyl diphenyl phosphate. In one embodiment, at least one scaly compound suitable for use in the present invention comprises at least one aryl phosphate. In one embodiment, at least one phosphorus compound suitable for use in the present invention comprises at least one unsubstituted aryl phosphate. 122661.doc -79- 200819496 A phosphorus compound suitable for use in the present invention comprises an aryl phosphate. The phosphorus compound used in the present invention may be included. In one embodiment, the phosphate ester in the present stabilizer includes (but not a phosphate, a triarylphosphonium phosphate).

在實知例中，在本發明中適用作熱穩定劑及/或色彩穩定劑之磷酸S旨包括（但不限於）以下中之至少一者··三芳基破酸i旨、院基二芳基碟酸§旨及混合型烧基芳基構酸醋。在一實施例中，在本發明中適用作熱穩定劑及/或色彩穩定劑之磷酸酯可包括（但不限於）以下中之至少一者：三芳基磷酸酯及混合型烷基芳基磷酸酯。In a practical example, the phosphoric acid S used as a heat stabilizer and/or a color stabilizer in the present invention is intended to include, but is not limited to, at least one of the following: triaryl cleavage, Base plate acid § and mixed type aryl aryl vinegar. In one embodiment, the phosphate ester suitable for use as a heat stabilizer and/or color stabilizer in the present invention may include, but is not limited to, at least one of the following: a triaryl phosphate and a mixed alkyl aryl phosphate. ester.

在一態樣中，至少_ 少一種未經节基取代之在一態樣中，任何適少一種烷基磷酸酯。明中適用作熱穩定劑及/或色彩限於）以下中之至少一者：三烧燒基一芳基磷酸s旨及混合型烧在一實施例中’至少一種適用於本發明之磷化合物可包含（但不限於）三芳基磷酸酯，諸如磷酸三苯酯。在一實施例中’至少一種熱穩定劑包含（但不限於）Merp〇i A。在一實施例中’至少一種適用於本發明之熱穩定劑包含（但不限於）鱗酸三苯酯及Merpol A中之至少一者。Merpol A為一種可賭自 Stepan Chemical Co及/或 E.I. duPont de Nemours & Co.之磷酸酯。據信Merpol A之CAS登記號為CAS登記號 # 37208-27-8 〇在一態樣中，任何適用於本發明之磷化合物均可包含至少一種未經苄基取代之三芳基磷酸酯。 122661.doc -80- 200819496 在一實施例中，本發明之聚酯組合物及/或方法可包含鱗酸2-乙基己基二苯酯。在一實施例中，本文所述之任何製備任何聚酯組合物及/ 或聚酯之方法均可包含至少一種混合型烷基芳基亞磷酸酯，諸如雙（2,4-二異丙苯基苯基）異戊四醇二亞磷酸酯（亦稱為 Doverphos S-9228 (Dover Chemicals，CAS# 154862· 43_8))。在一實施例中，本文所述之任何製備任何聚酯組合物及/ 或1 S曰之方法均可包含至少一種膦氧化物。在一實施例中，本文所述之任何製備任何聚酯組合物及/ 或聚酯之方法均可包含至少一種磷酸鹽，諸如KH2P〇4及 Zn3(P〇4)2。術語"熱穩定劑”意欲包括其反應產物。如結合本發明之熱穩定劑所用之術語，，反應產物"係指熱穩定劑與用於製備聚酯之任何單體之間之聚縮合反應或酯化反應的任何產物，以及催化劑與其他任何類型添加劑之間之聚縮合反應或酯化反應的產物。在本t月之一實施例中，適用於本發明之構化合物可充當熱穩定齊1。在本發明之一實施例中，適用於本發明之磷化合物雖不充當熱穩定劑，但可充當色彩穩定劑。在本發之κ化例中’適用於本發明之石粦化合物可充當熱穩定劑與色彩穩定劑兩者。田將4添加至本發明之聚酯及/或聚酯組合物及/或製備聚S曰之方法中時，其係以磷化合物之形式（例如至少一種 122661.doc -81- 200819496 磷酸酯）添加。添加至本發明之聚酯及/或本發明之聚酯組合物及/或本發明之方法中之構化合物（例如至少一種填酸酯）的量可以最終聚自旨中所存在之填原子的形式來量測，例如以ppm為單位量測重量。在聚合反應期間及/或製備後所添加之磷化合物之量以聚酯組合物之總重量計可包括（但不限於）：1至5000 ppm、1 至 1000 ppm、1 至 900 ppm、1 至 800 ppm、1 至 700 ppm、1 至 600 ppm、1 至 500 ppm、1 至 400 ppm、1 至 350 f ppm、1 至 300 ppm、1 J. 250 ppm、1 至 200 ppm、1 至 150 ppm、1 至 100 ppm ； 10 至 5000 ppm、10 至 1000 ppm、10 至 900 ppm、10至 800 ppm、10至 700 ppm、10至 600 ppm、10 至 500 ppm、10至 400 ppm、10至 350 ppm、10至 300 ppm、 10 至 250 ppm、10 至 200 ppm、10 至 150 ppm、10 至 100 ppm 〇在一實施例中，以聚酯組合物之總重量計且如以最終聚酯中之磷原子形式所量測，在聚合反應期間所添加之本發 \ 明之磷酸酯的量係選自以下：1至5000 ppm、1至1000 ppm、1 至 900 ppm、1 至 800 ppm、1 至 700 ppm、1 至 600 ppm、1 至 500 ppm、1 至 400 ppm、1 至 350 ppm、1 至 300 ppm、1 至 250 ppm、1 至 200 ppm、1 至 150 ppm、1 至 100 ppm、1 至 60 ppm ； 2 至 5000 ppm、2 至 1000 ppm、2 至 900 ppm、2至 800 ppm、2至 700 ppm、2至 600 ppm ' 2至 500 ppm、2至 400 ppm、2至 350 ppm、2至 300 ppm、2至 250 ppm、2 至 200 ppm、2 至 150 ppm、2至 100 ppm、2至 60 122661.doc -82- 200819496 ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm 2 至 20 ppm ； 3 至 5000 3 至 800 ppm、3 至 700 3 至 400 ppm、3至 350 3 至 200 ppm、3 至 150 3 至 20 ppm ; 4至 5000 4 至 800 ppm、4 至 700 4 至 400 ppm、4 至 350 4 至 200 ppm、4 至 150 4至 20 ppm ； 5 至 5000 5至 800 ppm、5至 700 5至 400 ppm、5至 350 5至 200 ppm、5至 150 5 至 20 ppm ； 6至 5000 6 至 800 ppm、6 至 700 6 至 400 ppm、6至 350 6 至 200 ppm、6 至 150 6至 20 ppm ； 7至 5000 7至 800 ppm、7至 700 7至 400 ppm、7至 350 7至 200 ppm、7至 150 7 至 20 ppm ； 8 至 5000 8 至 800 ppm、8 至 700 8 至 400 ppm、8 至 350 8 至 200 ppm、8 至 150 ppm、3至 1000 ppm、 ppm、3 至 600 ppm、 ppm、3 至 300 ppm、 ppm、3 至 100 ppm ppm、4至 1000 ppm、 ppm、4 至 600 ppm、 ppm、4 至 300 ppm、 ppm、4 至 1 00 ppm ppm ; 5至 1000 ppm、 ppm、5 至 600 ppm、 ppm、5 至 300 ppm、 ppm、5 至 1 00 ppm ppm、6至 1000 ppm、 ppm、6 至 600 ppm、 ppm、6 至 300 ppm、 ppm、6 至 1 00 ppm ppm、7至 1000 ppm、 ppm、7 至 600 ppm、 ppm、7 至 300 ppm、 ppm、7 至 1 00 ppm ppm、8 至 1000 ppm、 ppm、8 至 600 ppm、 ppm、8 至 300 ppm、 ppm、8 至 100 ppm 3 至 900 3 至 500 3 至 250 、3 至 60 4至 900 4 至 500 4 至 250 、4 至 60 5 至 900 5 至 500 5 至 250 ' 5 至 60 6 至 900 6 至 500 6 至 250 > 6 至 60 7至 900 7 至 500 7 至 250 ' 7 至 60 8 至 900 8 至 500 8 至 250 、8 至 60 122661.doc -83- 200819496 ppm、8至 20 ppm ； 9至 5000 ppm、9至 1000 ppm、9至 900 ppm、9 至 800 ppm、9 至 700 ppm、9 至 600 ppm、9 至 500 ppm、9 至 400 ppm、9 至 350 ppm、9 至 300 ppm、9 至 250 ppm、9 至 200 ppm、9 至 150 ppm、9 至 100 ppm、9 至 60 ppm、9至 20 ppm ； 10 至 5000 ppm、10 至 1000 ppm、10 至 900 ppm、10至 800 ppm、10至 700 ppm、10至 600 ppm、10 至 500 ppm、10至 400 ppm、10至 350 ppm、10至 300 ppm、 10 至 250 ppm、10 至 200 ppm、10 至 150 ppm、10 至 100 ppm、10 至 60 ppm、10 至 20 ppm ； 50 至 5000 ppm、50 至 1000 ppm、50至 900 ppm、50至 800 ppm、50至 700 ppm、 50 至 600 ppm、50 至 500 ppm、50 至 400 ppm、50 至 350 ppm、50至 300 ppm、50至 250 ppm、50至 200 ppm、50至 15 0 ppm、50 至 100 ppm、50 至 80 ppm ; 100 至 5000 ppm、 100 至 1000 ppm、100 至 900 ppm、100 至 800 ppm、100 至 700 ppm、100 至 600 ppm、100 至 500 ppm、100 至 400 ppm、100 至 350 ppm、100 至 300 ppm、100 至 250 ppm、 100 至 200 ppm、100 至 150 ppm ; 150 至 5000 ppm、150 至 1000 ppm、150 至 900 ppm、150 至 800 ppm、150 至 700 ppm ' 150 至 600 ppm、150 至 500 ppm、150 至 400 ppm、 150至 350 ppm、150至 300 ppm、150至 250 ppm、150至 200 ppm; 200 至 5000 ppm、200 至 1000 ppm、200 至 900 ppm、 200至 800 ppm、200至 700 ppm、200至 600 ppm、200至 500 ppm、200 至 400 ppm、200 至 350 ppm ' 200 至 300 ppm、 200至 250 ppm ; 250至 5000 ppm、250至 1000 ppm、250至 122661.doc -84- 200819496 900 ppm、250 至 800 ppm、250 至 700 ppm、250 至 600 ppm、250 至 500 ppm、250 至 400 ppm、250 至 350 ppm、 250至 300 ppm ; 300至 5000 ppm、300至 1000 ppm、300至 900 ppm、300 至 800 ppm、300 至 700 ppm、300 至 600 ppm、300 至 500 ppm、300 至 400 ppm、300 至 350 ppm ; 350至5000 ppm、 350至1000 ppm、 350至900 ppm、 350至 800 ppm、350 至 700 ppm、350 至 600 ppm、350 至 500 ppm、350至 400 ppm 〇在一實施例中，用於本發明之方法中用以製備適用於本發明之聚酯的合適催化劑包括至少一種鈦化合物。本發明之聚酯組合物亦可包含至少一種適用於本發明之方法中之鈦化合物。可將其他催化劑與至少一種鈦化合物組合用於本發明中。其他催化劑可包括（但不限於）基於以下化合物之彼4催化劑：錫化合物、鎵化合物、辞化合物、銻化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物。在一實施例中，催化劑可為至少一種錫化合物與至少一種鈦化合物之組合。以催化劑金屬計，且以最終聚合物之重量計，催化劑量之範圍可為10 ppm至20,000 ppm，或10至10 000 ppm，或 10至 5000 ppm，或10至 1000 ppm，或 1〇至5〇〇，或 1〇至300 ppm ’或1〇至25〇 ppm。該方法可以分批法或連續法進行。在一實施例中，該方法係以連續法進行。在一實施例中，催化劑包含鈦化合物。在一實施例中， 122661.doc -85- 200819496 欽化合物可用於酯化反應或聚縮合反應或兩者反應中。在一實施例中，催化劑包含用於酯化反應中之鈦化合物。在一實施例中，催化劑包含用於聚縮合反應中之鈦化合物。在另一實施例中，催化劑基本上由適用於本發明之聚酯及/ 或本發明之製備聚酯之方法中所適用之鈦化合物組成。在貝施例中’以二魏酸或二魏酸酯之重量計，鈦化合物之使用量一般為約0·005%至約0·2〇/〇。在一實施例中，以聚酯之總重量計，聚酯中一般可存在小於約7〇〇 ppm之元素鈦作為殘基。當在本發明之聚酯及/或聚酯組合物及/或製備聚酯之方法中添加鈦時，其係以鈦化合物之形式添加至製備聚酯之方法中。添加至本發明之聚I旨及/或本發明之聚g旨組合物及/或本發明之方法中之鈇化合物的量可以最終聚酯中所存在之鈦原子形式來量測，例如以ppm為單位來量測重量。在另一實施例中，催化劑基本上由用於酯化反應中之鈦化合物組成，以最終聚酯之重量計，如以最終聚酯中之鈦原子形式所量測，其使用量為：10 ppm至20,000 ppm或10 至 10,000 ppm，或 10 至 5000 ppm 或 10 至 4500 ppm 或 10 至 4000 ppm或 10至 3500 ppm或 10至 3000 ppm或 10至 2500 ppm 或 10 至 2000 ppm 或 10 至 1500 ppm 或 10 至 1000 ppm 或 10 至 500 ppm’ 或 10 至 300 ppm 或 10 至 250 ppm，或 15 ppm 至 20,000 ppm 或 15 至 1〇,〇〇〇 ppm，或 15 至 5000 ppm 或 15 至 4500 ppm或 15至 4000 ppm或 15至 3500 ppm或 15至 3000 ppm 122661.doc -86 - 200819496 或 15 至 2500 ppm 或 15 至 2000 ppm 或 15 至 1500 ppm 或 15 至 1000 ppm 或 15 至 500 ppm，或 15至 400 ppm 或 15至 300 ppm 或 1 5 至 250 ppm，或 20 ppm 至 20,000 ppm 或 20 至 10,000 ppm，或 20 至 5000 ppm 或 20 至 4500 ppm 或 20 至 4000 ppm 或 20至 3500 ppm或 20至 3000 ppm或 20至 2500 ppm或 20至 2000 ppm 或 20 至 1500 ppm 或 20 至 1000 ppm 或 20 至 500 ppm，或 20至 300 ppm或 20至 250 ppm，25 ppm至 20,000 ppm或 25至 10,000 ppm 5 或 25 至 5000 ppm或 25 至 4500 ppm或 25 至 4000 ppm或 25 至 3500 ppm或 25 至 3000 ppm或 25 至 2500 ppm或 25 至 2000 ppm 或 25 至 1500 ppm 或 25 至 1000 ppm 或 25 至 500 ppm 或 25至 400 ppm 或 25至 300 ppm 或 25至 250 ppm，或 30 ppm至 20,000 ppm或 30至 10,000 ppm或 30至 5000 ppm或 30 至 4500 ppm 或 30 至 4000 ppm 或 30 至 3500 ppm 或 30 至 3000 ppm或 30至 2500 ppm或 30至 2000 ppm或 30至 1 500 ppm或 30 至 1000 ppm 或 30 至 500 ppm 或 30 至 300 ppm 或 30 至 25 0 ppm，或 35 ppm 至 20,000 ppm 或 35 至 10,000 ppm 或 35 至 5000 ppm或 35 至 4500 ppm或 35 至 4000 ppm或 35 至 3500 ppm 或 35 至 3000 ppm 或 35 至 2500 ppm 或 35 至 2000 ppm 或 35 至 1500 ppm或 35至 1000 ppm或 35 至 500 ppm或 35 至 300 ppm或 35至 250 ppm，或 40 ppm至 20,000 ppm或 40至 10,000 ppm或 40至 5000 ppm或 40至 4500 ppm或 40至 4000 ppm或 40至 3500 ppm或 40至 3000 ppm或 40至 2500 ppm或 40至 2000 ppm或 40 至 1500 ppm或 40至 1000 ppm或 40至 500 ppm或 40至 300 ppm 或 40至 250 ppm或 40至 200 ppm，或 45 ppm至 20,000 ppm或 122661.doc 87- 200819496 45 至 10,000 ppm，或 45 至 5000 ppm或 45 至 4500 ppm或 45 至 4000 ppm或 45 至 3500 ppm或 45 至 3000 ppm或 45 至 2500 ppm 或 45 至 2000 ppm 或 45 至 1500 ppm 或 45 至 1000 ppm 或 45 至 500 ppm 或 45 至 300 ppm 或 45 至 250 ppm，或 50 ppm 至 20,000 ppm 或 50 至 10,000 ppm，或 50 至 5000 ppm 或 50 至 4500 ppm或 50至 4000 ppm或 50至 3500 ppm或 50至 3000 ppm 或 50 至 2500 ppm 或 50 至 2000 ppm 或 50 至 1500 ppm 或 50 至 1000 ppm或 50至 500 ppm或 50至 300 ppm或 50至 250 ppm或 50至 200 ppm或 50至 150 ppm或 50至 125 ppm 〇在另一實施例中，本發明之聚酯可使用除鈦化合物以外之至少一種錫化合物作為催化劑來製備。舉例而言，參見美國專利第2,720,507號，其中有關錫催化劑之部分以引用的方式併入本文中。該等催化劑為含有至少一個有機基團之錫化合物。該等催化劑包括具有下述通式之二價錫化合物或四價錫化合物： A. M2(Sn(OR)4) B. MH(Sn(OR)4) C. M，（Sn(OR)4) D. M，(HSn(OR)4)2 E. M2(Sn(OR)6) F. MH(Sn(OR)6) G. M，(Sn(OR)6) H. M，(HSn(OR)6)2 I. Sn(OR)2 122661.doc -88- 200819496 J. Sn(OR)4 K. SnR，2 L. S nRf 4In one aspect, at least one less than one unsubstituted group is substituted, in any aspect, any suitable alkyl phosphate. It is suitable for use as a heat stabilizer and/or color limited to at least one of the following: trialkyl-monoarylphosphoric acid s and mixed-type calcination in one embodiment 'at least one phosphorus compound suitable for use in the present invention These include, but are not limited to, triaryl phosphates such as triphenyl phosphate. In one embodiment, at least one heat stabilizer comprises, but is not limited to, Merp〇i A. In one embodiment, at least one heat stabilizer suitable for use in the present invention comprises, but is not limited to, at least one of triphenyl phthalate and Merpol A. Merpol A is a phosphate ester that can be staked from Stepan Chemical Co and/or E.I. duPont de Nemours & Co. It is believed that the CAS registration number of Merpol A is CAS Registry Number # 37208-27-8 〇 In one aspect, any phosphorus compound suitable for use in the present invention may comprise at least one triaryl phosphate which is not substituted with a benzyl group. 122661.doc -80- 200819496 In one embodiment, the polyester compositions and/or methods of the present invention may comprise 2-ethylhexyl diphenyl phthalate. In one embodiment, any of the methods of preparing any of the polyester compositions and/or polyesters described herein can comprise at least one mixed alkyl aryl phosphite, such as bis(2,4-diisopropylbenzene). Phenylphenyl)isopentyl alcohol diphosphite (also known as Doverphos S-9228 (Dover Chemicals, CAS # 154862. 43_8)). In one embodiment, any of the methods described herein for preparing any polyester composition and/or 1 S 均可 may comprise at least one phosphine oxide. In one embodiment, any of the methods described herein for preparing any polyester composition and/or polyester may comprise at least one phosphate such as KH2P〇4 and Zn3(P〇4)2. The term "heat stabilizer" is intended to include the reaction product thereof. As the term is used in connection with the heat stabilizer of the present invention, the reaction product" refers to the polycondensation between the heat stabilizer and any monomer used to prepare the polyester. Any product of the reaction or esterification reaction, and the product of the polycondensation or esterification reaction between the catalyst and any other type of additive. In one embodiment of this month, the compound suitable for use in the present invention acts as a heat stabilizer 1. In one embodiment of the present invention, a phosphorus compound suitable for use in the present invention, although not serving as a heat stabilizer, can function as a color stabilizer. In the κ-formation of the present invention, the sarcophagus compound is suitable for use in the present invention. It can serve as both a heat stabilizer and a color stabilizer. When Tian 4 is added to the polyester and/or polyester composition of the present invention and/or the method for preparing the poly(S), it is in the form of a phosphorus compound (for example, Addition of at least one of the 122661.doc-81-200819496 phosphate esters. Addition to the polyester of the present invention and/or the polyester composition of the present invention and/or the compound of the method of the present invention (eg, at least one acid ester) The amount can be measured finally in the form of a filled atom present in the purpose, for example, in ppm. The amount of phosphorus compound added during and/or after the polymerization is in the form of a polyester composition. Total weights may include (but are not limited to): 1 to 5000 ppm, 1 to 1000 ppm, 1 to 900 ppm, 1 to 800 ppm, 1 to 700 ppm, 1 to 600 ppm, 1 to 500 ppm, 1 to 400 ppm , 1 to 350 f ppm, 1 to 300 ppm, 1 J. 250 ppm, 1 to 200 ppm, 1 to 150 ppm, 1 to 100 ppm; 10 to 5000 ppm, 10 to 1000 ppm, 10 to 900 ppm, 10 to 800 ppm, 10 to 700 ppm, 10 to 600 ppm, 10 to 500 ppm, 10 to 400 ppm, 10 to 350 ppm, 10 to 300 ppm, 10 to 250 ppm, 10 to 200 ppm, 10 to 150 ppm, 10 to 100 ppm 〇 In one embodiment, based on the total weight of the polyester composition and as measured as the phosphorus atom in the final polyester, the amount of the phosphate added during the polymerization is selected. From the following: 1 to 5000 ppm, 1 to 1000 ppm, 1 to 900 ppm, 1 to 800 ppm, 1 to 700 ppm, 1 to 600 ppm, 1 to 500 PPM, 1 to 400 ppm, 1 to 350 ppm, 1 to 300 ppm, 1 to 250 ppm, 1 to 200 ppm, 1 to 150 ppm, 1 to 100 ppm, 1 to 60 ppm; 2 to 5000 ppm, 2 to 1000 PPM, 2 to 900 ppm, 2 to 800 ppm, 2 to 700 ppm, 2 to 600 ppm '2 to 500 ppm, 2 to 400 ppm, 2 to 350 ppm, 2 to 300 ppm, 2 to 250 ppm, 2 to 200 Ppm, 2 to 150 ppm, 2 to 100 ppm, 2 to 60 122661.doc -82- 200819496 ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm 2 to 20 ppm 3 to 5000 3 to 800 ppm, 3 to 700 3 to 400 ppm, 3 to 350 3 to 200 ppm, 3 to 150 3 to 20 ppm; 4 to 5000 4 to 800 ppm, 4 to 700 4 to 400 ppm, 4 Up to 350 4 to 200 ppm, 4 to 150 4 to 20 ppm; 5 to 5000 5 to 800 ppm, 5 to 700 5 to 400 ppm, 5 to 350 5 to 200 ppm, 5 to 150 5 to 20 ppm; 6 to 5000 6 to 800 ppm, 6 to 700 6 to 400 ppm, 6 to 350 6 to 200 ppm, 6 to 150 6 to 20 ppm; 7 to 5000 7 to 800 ppm, 7 to 700 7 to 400 ppm, 7 to 350 7 to 200 ppm, 7 to 150 7 to 20 Ppm; 8 to 5000 8 to 800 ppm, 8 to 700 8 to 400 ppm, 8 to 350 8 to 200 ppm, 8 to 150 ppm, 3 to 1000 ppm, ppm, 3 to 600 ppm, ppm, 3 to 300 ppm, Ppm, 3 to 100 ppm ppm, 4 to 1000 ppm, ppm, 4 to 600 ppm, ppm, 4 to 300 ppm, ppm, 4 to 100 ppm ppm; 5 to 1000 ppm, ppm, 5 to 600 ppm, ppm, 5 to 300 ppm, ppm, 5 to 100 ppm ppm, 6 to 1000 ppm, ppm, 6 to 600 ppm, ppm, 6 to 300 ppm, ppm, 6 to 100 ppm ppm, 7 to 1000 ppm, ppm, 7 Up to 600 ppm, ppm, 7 to 300 ppm, ppm, 7 to 100 ppm ppm, 8 to 1000 ppm, ppm, 8 to 600 ppm, ppm, 8 to 300 ppm, ppm, 8 to 100 ppm 3 to 900 3 to 500 3 to 250 , 3 to 60 4 to 900 4 to 500 4 to 250 , 4 to 60 5 to 900 5 to 500 5 to 250 ' 5 to 60 6 to 900 6 to 500 6 to 250 > 6 to 60 7 to 900 7 to 500 7 to 250 ' 7 to 60 8 to 900 8 to 500 8 to 250 , 8 to 60 122661.doc -83 - 200819496 ppm, 8 to 20 ppm; 9 to 5000 ppm, 9 to 1000 ppm, 9 to 900 ppm, 9 to 800 ppm, 9 700 ppm, 9 to 600 ppm, 9 to 500 ppm, 9 to 400 ppm, 9 to 350 ppm, 9 to 300 ppm, 9 to 250 ppm, 9 to 200 ppm, 9 to 150 ppm, 9 to 100 ppm, 9 to 60 ppm, 9 to 20 ppm; 10 to 5000 ppm, 10 to 1000 ppm, 10 to 900 ppm, 10 to 800 ppm, 10 to 700 ppm, 10 to 600 ppm, 10 to 500 ppm, 10 to 400 ppm, 10 to 350 ppm, 10 to 300 ppm, 10 to 250 ppm, 10 to 200 ppm, 10 to 150 ppm, 10 to 100 ppm, 10 to 60 ppm, 10 to 20 ppm; 50 to 5000 ppm, 50 to 1000 ppm, 50 to 900 ppm, 50 to 800 ppm, 50 to 700 ppm, 50 to 600 ppm, 50 to 500 ppm, 50 to 400 ppm, 50 to 350 ppm, 50 to 300 ppm, 50 to 250 ppm, 50 to 200 ppm, 50 to 15 0 ppm, 50 to 100 ppm, 50 to 80 ppm; 100 to 5000 ppm, 100 to 1000 ppm, 100 to 900 ppm, 100 to 800 ppm, 100 to 700 ppm, 100 to 600 ppm, 100 to 500 ppm, 100 Up to 400 ppm, 100 to 350 ppm, 100 to 300 ppm, 100 to 250 ppm, 100 to 200 ppm, 100 to 150 ppm; 150 to 5000 ppm, 150 to 1000 ppm, 150 to 900 ppm 150 to 800 ppm, 150 to 700 ppm '150 to 600 ppm, 150 to 500 ppm, 150 to 400 ppm, 150 to 350 ppm, 150 to 300 ppm, 150 to 250 ppm, 150 to 200 ppm; 200 to 5000 ppm, 200 to 1000 ppm, 200 to 900 ppm, 200 to 800 ppm, 200 to 700 ppm, 200 to 600 ppm, 200 to 500 ppm, 200 to 400 ppm, 200 to 350 ppm ' 200 to 300 ppm, 200 to 250 ppm; 250 to 5000 ppm, 250 to 1000 ppm, 250 to 122661.doc -84 to 200819496 900 ppm, 250 to 800 ppm, 250 to 700 ppm, 250 to 600 ppm, 250 to 500 ppm, 250 to 400 ppm, 250 to 350 Ppm, 250 to 300 ppm; 300 to 5000 ppm, 300 to 1000 ppm, 300 to 900 ppm, 300 to 800 ppm, 300 to 700 ppm, 300 to 600 ppm, 300 to 500 ppm, 300 to 400 ppm, 300 to 350 Ppm; 350 to 5000 ppm, 350 to 1000 ppm, 350 to 900 ppm, 350 to 800 ppm, 350 to 700 ppm, 350 to 600 ppm, 350 to 500 ppm, 350 to 400 ppm, in one embodiment, for Suitable catalysts for the preparation of the polyesters suitable for use in the process of the invention include at least one titanium compound . The polyester composition of the present invention may also comprise at least one titanium compound suitable for use in the process of the present invention. Other catalysts may be used in combination with at least one titanium compound in the present invention. Other catalysts may include, but are not limited to, the following four catalysts based on the following compounds: tin compounds, gallium compounds, rhodium compounds, rhodium compounds, cobalt compounds, manganese compounds, magnesium compounds, antimony compounds, lithium compounds, aluminum compounds, and having hydroxide Aluminum compound of lithium or sodium hydroxide. In one embodiment, the catalyst can be a combination of at least one tin compound and at least one titanium compound. The amount of catalyst can range from 10 ppm to 20,000 ppm, or from 10 to 10 000 ppm, or from 10 to 5000 ppm, or from 10 to 1000 ppm, or from 1 to 5, based on the catalyst metal, based on the weight of the final polymer. 〇〇, or 1 to 300 ppm ' or 1 to 25 ppm. The method can be carried out in a batch process or in a continuous process. In one embodiment, the method is carried out in a continuous process. In an embodiment, the catalyst comprises a titanium compound. In one embodiment, 122661.doc -85-200819496 can be used in an esterification reaction or a polycondensation reaction or both. In one embodiment, the catalyst comprises a titanium compound for use in an esterification reaction. In one embodiment, the catalyst comprises a titanium compound for use in a polycondensation reaction. In another embodiment, the catalyst consists essentially of a titanium compound suitable for use in the polyester of the present invention and/or the method of making a polyester of the present invention. In the case of the shell, the amount of the titanium compound used is generally from about 0. 005% to about 0.2% by weight based on the weight of the diweiric acid or diweiling acid ester. In one embodiment, less than about 7 〇〇 ppm of elemental titanium may generally be present as a residue in the polyester, based on the total weight of the polyester. When titanium is added to the polyester and/or polyester composition of the present invention and/or the method of preparing the polyester, it is added to the method of producing a polyester in the form of a titanium compound. The amount of the ruthenium compound added to the composition of the present invention and/or the composition of the present invention and/or the method of the present invention can be measured in the form of titanium atoms present in the final polyester, for example, in ppm. The weight is measured in units. In another embodiment, the catalyst consists essentially of the titanium compound used in the esterification reaction, as measured by the weight of the final polyester, as measured as the titanium atom in the final polyester, in an amount of 10 Ppm to 20,000 ppm or 10 to 10,000 ppm, or 10 to 5000 ppm or 10 to 4500 ppm or 10 to 4000 ppm or 10 to 3500 ppm or 10 to 3000 ppm or 10 to 2500 ppm or 10 to 2000 ppm or 10 to 1500 ppm Or 10 to 1000 ppm or 10 to 500 ppm' or 10 to 300 ppm or 10 to 250 ppm, or 15 ppm to 20,000 ppm or 15 to 1 〇, 〇〇〇ppm, or 15 to 5000 ppm or 15 to 4500 ppm or 15 to 4000 ppm or 15 to 3500 ppm or 15 to 3000 ppm 122661.doc -86 - 200819496 or 15 to 2500 ppm or 15 to 2000 ppm or 15 to 1500 ppm or 15 to 1000 ppm or 15 to 500 ppm, or 15 to 400 ppm or 15 to 300 ppm or 15 to 250 ppm, or 20 ppm to 20,000 ppm or 20 to 10,000 ppm, or 20 to 5000 ppm or 20 to 4500 ppm or 20 to 4000 ppm or 20 to 3500 ppm or 20 to 3000 Pppm or 20 to 2500 ppm or 20 to 2000 ppm or 20 to 1500 ppm or 20 to 1000 ppm or 20 to 500 ppm, or 20 to 300 ppm or 20 to 250 ppm, 25 ppm to 20,000 ppm or 25 to 10,000 ppm 5 or 25 to 5000 ppm or 25 to 4500 ppm or 25 to 4000 ppm Or 25 to 3500 ppm or 25 to 3000 ppm or 25 to 2500 ppm or 25 to 2000 ppm or 25 to 1500 ppm or 25 to 1000 ppm or 25 to 500 ppm or 25 to 400 ppm or 25 to 300 ppm or 25 to 250 ppm , or 30 ppm to 20,000 ppm or 30 to 10,000 ppm or 30 to 5000 ppm or 30 to 4500 ppm or 30 to 4000 ppm or 30 to 3500 ppm or 30 to 3000 ppm or 30 to 2500 ppm or 30 to 2000 ppm or 30 to 1 500 ppm or 30 to 1000 ppm or 30 to 500 ppm or 30 to 300 ppm or 30 to 25 0 ppm, or 35 ppm to 20,000 ppm or 35 to 10,000 ppm or 35 to 5000 ppm or 35 to 4500 ppm or 35 to 4000 Ppm or 35 to 3500 ppm or 35 to 3000 ppm or 35 to 2500 ppm or 35 to 2000 ppm or 35 to 1500 ppm or 35 to 1000 ppm or 35 to 500 ppm or 35 to 300 ppm or 35 to 250 ppm, or 40 ppm To 20,000 ppm or 40 to 10,000 ppm or 40 to 5000 ppm or 40 to 4500 ppm or 40 to 4000 ppm or 40 to 3500 ppm or 40 to 3000 ppm or 40 to 2500 ppm or 40 to 2000 ppm or 40 to 1500 ppm or 40 to 1000 ppm or 40 to 500 ppm or 40 to 300 ppm or 40 to 250 ppm or 40 to 200 ppm, or 45 ppm to 20,000 ppm or 122661.doc 87-200819496 45 to 10,000 ppm, or 45 to 5000 ppm or 45 to 4500 ppm or 45 to 4000 ppm or 45 to 3500 ppm or 45 To 3000 ppm or 45 to 2500 ppm or 45 to 2000 ppm or 45 to 1500 ppm or 45 to 1000 ppm or 45 to 500 ppm or 45 to 300 ppm or 45 to 250 ppm, or 50 ppm to 20,000 ppm or 50 to 10,000 ppm , or 50 to 5000 ppm or 50 to 4500 ppm or 50 to 4000 ppm or 50 to 3500 ppm or 50 to 3000 ppm or 50 to 2500 ppm or 50 to 2000 ppm or 50 to 1500 ppm or 50 to 1000 ppm or 50 to 500 Ppm or 50 to 300 ppm or 50 to 250 ppm or 50 to 200 ppm or 50 to 150 ppm or 50 to 125 ppm. In another embodiment, the polyester of the present invention may use at least one tin compound other than the titanium compound. Prepared as a catalyst. For example, see U.S. Patent No. 2,720,507, the entire disclosure of which is incorporated herein by reference. The catalysts are tin compounds containing at least one organic group. The catalysts include a divalent tin compound or a tetravalent tin compound having the following general formula: A. M2 (Sn(OR)4) B. MH(Sn(OR)4) C. M, (Sn(OR)4 D. M,(HSn(OR)4)2 E. M2(Sn(OR)6) F. MH(Sn(OR)6) G. M,(Sn(OR)6) H. M,(HSn (OR)6)2 I. Sn(OR)2 122661.doc -88- 200819496 J. Sn(OR)4 K. SnR,2 L. S nRf 4

M. R’2SnO N.M. R’2SnO N.

〆 \)Ac， 122661.doc -89 200819496 其中Μ為驗金屬，例如鋰、鈉或鉀；^^，為鹼土金屬，諸如 Mg、Ca或Sr ;各R表示含有1至8個碳原子之烷基，各R，基團表示選自由以下基團組成之彼等基團中之取代基：含有 1至8個碳原子之烷基（亦即R基團）及含有6至9個碳原子之苯系列之芳基（例如苯基、甲苯基、苄基、苯乙基等基團）；且Ac表示源自含有2至18個碳原子之有機酸的醯基 (例如乙酿基、丁醯基、月桂醯基、苄醯基、硬脂醯基等）。新穎之雙金屬醇鹽催化劑可如Meerwein，Ann· 476，113 (1929) 所述來製備。如由Meerwein所示，該等催化劑不僅為兩種金屬醇鹽之混合物。其為具有鹽樣結構之確定化合物。該等催化劑為上文所述式A至式η之化合物。 Meerwein未具體描述之彼等催化劑可藉由類似於Meerwein 所述之工作實例及方法之程序來製備。其他錫化合物亦可藉由各種方法來製備，諸如以下文獻中所述之方法：關於二芳基二鹵化錫（式P)之製備，參見〆\)Ac, 122661.doc -89 200819496 wherein Μ is a metal such as lithium, sodium or potassium; ^^ is an alkaline earth metal such as Mg, Ca or Sr; each R represents an alkane having 1 to 8 carbon atoms The group, each R, group means a substituent selected from the group consisting of: an alkyl group having 1 to 8 carbon atoms (ie, an R group) and a 6 to 9 carbon atom. An aryl group of a benzene series (for example, a group such as a phenyl group, a tolyl group, a benzyl group, a phenethyl group, etc.); and Ac represents a fluorenyl group derived from an organic acid having 2 to 18 carbon atoms (e.g., an ethylene group, a butyl group, Laurel, benzylidene, stearin, etc.). Novel bimetallic alkoxide catalysts can be prepared as described by Meerwein, Ann. 476, 113 (1929). As indicated by Meerwein, the catalysts are not only a mixture of two metal alkoxides. It is a defined compound having a salt-like structure. These catalysts are the compounds of formula A to formula η described above. These catalysts, not specifically described by Meerwein, can be prepared by procedures analogous to the working examples and methods described by Meerwein. Other tin compounds can also be prepared by various methods, such as those described in the following literature: For the preparation of diaryltin dihalide (formula P), see

Ber· 62, 996 (1929) ; J. Am. Chem. Soc. 49，1369 (1927); 關於二烧基二i化錫（式P)之製備，參見1八1(：1^111.8〇〇· 47, 2568 (1925); C.A· 41，90 (1947);關於二芳基氧化錫 (式 M)之製備，參見j· Am. Chem. Soc· 48，1054 (1926);關於四务基錫化合物（式K)之製備，參見c.A. 32，5387 (1938);關於錫醇鹽（式j)之製備，參見CA· 24，586 (1930) ’關於烧基錫鹽（式Q)之製備，參見[A· 31，4290 ; 關於烧基錫化合物（式K及L)之製備，參見c.A. 35，2470 122661.doc -90- 200819496 (1941) · C.A. 33，53 57 (1939);關於混合型烷基芳基錫（式 K 及 L)之製備，參見 CA· 31，429〇 (1937) ca (1944);關於該等引文未包括之其他錫化合物之製備，參 ^ Krauses V. Grossed ^Die Chemie der Metal-OrganischenBer. 62, 996 (1929); J. Am. Chem. Soc. 49, 1369 (1927); For the preparation of di-based di-tin-tin (formula P), see 1 8.1 (:1^111.8〇〇) · 47, 2568 (1925); CA· 41,90 (1947); for the preparation of diaryltin oxides (formula M), see j. Am. Chem. Soc 48, 1054 (1926); For the preparation of tin compounds (formula K), see cA 32,5387 (1938); for the preparation of tin alkoxides (formula j), see CA 24,586 (1930) 'Preparation of alkyltin salts (formula Q) See [A·31, 4290; for the preparation of alkyltin compounds (formula K and L), see cA 35, 2470 122661.doc -90-200819496 (1941) · CA 33,53 57 (1939); For the preparation of alkylaryl tins (formula K and L), see CA 31,429 (1937) ca (1944); for the preparation of other tin compounds not included in such citations, see Krauses V. Grossed ^ Die Chemie der Metal-Organischen

Verbindungen"，其由 Gebrode卜Borntrager 公開於 Berlin， 1937中。 5 錫醇鹽（式I及J)及雙金屬醇鹽（式八至抝含有可表示直鏈與支鏈烷基之R取代基，該等醇鹽例如二乙醇鹽、四甲醇鹽、四丁醇鹽、四_第三丁醇鹽、四己醇鹽等。烷基衍生物（式K及L)含有一或多個經由c_Sn直接鍵聯與錫連接之㈣，例如二丁基錫、：己基錫、四丁基錫、四乙基錫、⑸甲基錫、二辛基錫等。四烷基中之兩者可經氧原子置換以形成具有式Μ之化合物，例如二甲基氧化錫、一乙基氧化錫、二丁基氧化錫、二庚基氧化錫等。在一實施例中，錫催化劑包含二甲基氧化錫。錯合物可如下形成··使二烷基氧化錫與鹼金屬醇鹽在醇溶液中反應（例如使二丁基氧化錫與乙醇納反應等）以形成具有式Ν之化合物，該等化合物為尤其適用之催化劑。此式意欲表示所述反應產物。含㈣基及烧氧基之錫化合物亦為適用之催化劑（參見式0)，例如二乙基二乙醇錫、二丁基二丁醇錫'二己基二甲醇錫等。二烷基氧化錫與羧酸或氫氣酸反應所得之鹽亦具有作為催化劑之特別價值；參見式。該等催化縮合劑之實例包括二丁基二乙酸錫、二乙基二丁酸錫、二丁基二月桂酸 122661.doc -91 - 200819496 錫、二甲基二苯曱酸錫、二丁基二氯化錫、二乙基二氣化錫一辛基一氣化錫、一己基二硬脂酸錫等。、可製備具有式K、L及Μ之錫化合物，其中一或多似’基團表示苯系列之芳&，例如苯基、甲苯基、苄基等。實例包括二苯基錫、四苯基錫、二苯基二丁基錫、二甲苯基二乙基錫、二苯基氧化錫、二节基錫、四节基錫、二乙基）氧化錫、二苄基氧化錫等。適用於本發明之催化劑之實例包括（但不限於）以下中之一或多者：丁基三-2-乙基己酸錫、二丁基二乙酸錫、二丁基氧化錫及二甲基氧化錫。在一實施例中，適用於本發明之催化劑包括（但不限於）以下中之一或多者：丁基三_2_乙基己酸錫、二丁基二乙酸錫、二丁基氧化錫及二甲基氧化錫。使用錫基催化劑製備聚酯之方法已熟知且描述於上述美國專利第2,720,507號中。適用於本發明之含鈦化合物包括任何含鈦化合物，其包括（但不限於）·鈦酸四乙酯、乙醯基鈦酸三丙酯、鈦酸四丙酯、鈦酸四丁酯、聚鈦酸丁酯、鈦酸2-乙基己酯、辛二醇鈦酸酯、乳酸酯鈦酸酯、三乙醇胺鈦酸酯、乙醯基丙酮酸醋鈦酸醋、乙基乙醯乙酸酯鈦酸酯、異硬脂醯基鈦酸酉曰、乙醯基鈦酸三異丙酯、四異丙醇鈦乙醇酸鈦、丁醇欽、己二醇鈦酸酯及鈦酸四異辛酯、二氧化鈦、二氧化鈦/ 二氧化矽共沈澱物，及二氧化鈦/二氧化锆共沈澱物。本發明包括（但不限於）美國專利6,559,272中所述之二氧化鈦/ 122661.doc -92- 200819496 二氧化矽共沈澱物催化劑。適用於本發明之《組合物中之“部分可藉由文獻中已知之方法來製備，諸如藉由均質溶液方法、熔融轉醋化方法及兩相界面方法。合適方法包括(但不限於)在職至 ⑽之溫度下、在o.m6〇mmHR壓力下使一或多種二幾酸與-或多種二醇反應足夠時間以形成聚醋之步驟。關於產生聚醋之方法，參見美國專利第3,772,彻號，有關該等方法之揭示内容以引用的方式併入本文中。Verbindungen", which is published by Berlin, 1937 by Gebrode Bu Bortrager. 5 tin alkoxides (formula I and J) and bimetal alkoxides (formulas octadecyl) contain R substituents which may represent straight-chain and branched alkyl groups, such as diethanolates, tetramethanolates, tetrabutyls Alkoxide, tetra-butoxide, tetrahexolate, etc. The alkyl derivative (formula K and L) contains one or more (iv), which is directly bonded to the tin via c_Sn, such as dibutyltin, hexyltin. , tetrabutyltin, tetraethyltin, (5) methyltin, dioctyltin, etc. Both of the tetraalkyl groups may be replaced by an oxygen atom to form a compound having the formula, such as dimethyltin oxide, monoethyl Tin oxide, dibutyl tin oxide, diheptyl tin oxide, etc. In one embodiment, the tin catalyst comprises dimethyl tin oxide. The complex compound can be formed as follows: · Dialkyl tin oxide and alkali metal alkoxide Reacting in an alcohol solution (for example, reacting dibutyltin oxide with sodium ethoxide, etc.) to form a compound having the formula, which is a particularly suitable catalyst. This formula is intended to represent the reaction product. The tin compound of oxy group is also a suitable catalyst (see formula 0), such as diethyldiethyl Alcohol tin, dibutyl dibutoxide tin 'dihexyl dimethanol tin, etc. The salt obtained by reacting a dialkyl tin oxide with a carboxylic acid or a hydrogen acid also has a special value as a catalyst; see formula. Examples include tin dibutyl diacetate, tin diethyl dibutyrate, dibutyl dilaurate 122661.doc -91 - 200819496 tin, tin dimethyl dibenzoate, dibutyl tin dichloride, two Ethyl di-stannated tin-octyl-mono-lithium tin, monohexyl distearate, etc., can prepare tin compounds having the formula K, L and bismuth, wherein one or more of the 'groups' represent the benzene series of aryl & amp For example, phenyl, tolyl, benzyl, etc. Examples include diphenyltin, tetraphenyltin, diphenyldibutyltin, xylyldiethyltin, diphenyltin oxide, di-n-butyltin, Four base tin, diethyl) tin oxide, dibenzyl tin oxide, and the like. Examples of catalysts suitable for use in the present invention include, but are not limited to, one or more of the following: butyl tri-2-ethylhexanoate, dibutyltin diacetate, dibutyltin oxide, and dimethyl Tin oxide. In one embodiment, catalysts suitable for use in the present invention include, but are not limited to, one or more of the following: butyl tri-2-ethylhexanoate, dibutyltin diacetate, dibutyltin oxide And dimethyl tin oxide. A process for the preparation of a polyester using a tin-based catalyst is well known and described in the above-mentioned U.S. Patent No. 2,720,507. Titanium-containing compounds suitable for use in the present invention include any titanium-containing compound including, but not limited to, tetraethyl titanate, tripropyl ethanotitanate, tetrapropyl titanate, tetrabutyl titanate, poly Butyl titanate, 2-ethylhexyl titanate, octanediol titanate, lactate titanate, triethanolamine titanate, acetoxyacetate vinegar titanic acid, ethyl acetoacetate Ester titanate, isostearyl bismuth strontium titanate, triisopropyl acetoxytitanate, titanium tetraisopropoxide titanium glycolate, butanol, hexanediol titanate and tetraisobutyl titanate Ester, titanium dioxide, titanium dioxide / ceria coprecipitate, and titanium dioxide / zirconia coprecipitate. The present invention includes, but is not limited to, the titanium dioxide/122661.doc-92-200819496 ceria coprecipitate catalyst described in U.S. Patent No. 6,559,272. The "parts of the composition" suitable for use in the present invention can be prepared by methods known in the literature, such as by a homogeneous solution process, a melt transacetification process, and a two-phase interface process. Suitable methods include, but are not limited to, a step of reacting one or more diacids with - or a plurality of diols for a time sufficient to form a polyacetate at a temperature of (10) at a temperature of (10). For a method of producing a polyester, see U.S. Patent No. 3,772, The disclosure of such methods is incorporated herein by reference.

如美國專利第2,720,507號（其以引用的方式併入本文中）中進-步所詳述’聚酿一般而言可如下製備：在惰性氣氛中，在縮合反應過程期間it漸升至高達約225〇c_31〇<t溫度之高溫下，在本文所述之鈦催化劑及/或欽及錫催化劑存在下使二羧酸或二羧酸酿與二醇縮合，且在縮合反應之後半部分期間於低壓下進行縮合反應。在另-態樣中’本發明係關於_種製備本發明之共聚醋之方法。在-實施例中’該方法係關於製備包含對苯二甲酸、2,2,4,4-四甲基-1，3-環丁二醇及環己烷二甲醇之共聚酯。該方法包含如下步驟： (A) 在150至250 C之溫度下，在至少一種錫催化劑及至少一種磷酸酯存在下將包含適用於本發明之聚酯中之單體的混合物加熱足夠時間以產生初始聚酯； (B) 藉由在230至320°C之溫度下將其加熱丨至6小時而使步驟（A)之產物聚縮合；及 (C)移除任何未反應之二醇。 122661.doc -93- 200819496 酯化反應步驟（A)之反應時間視所選溫度、壓力及二醇與二羧酸之饋料莫耳比而定。在一實施例中，步驟（A)可進行至2,2,4,4_四甲基^义環丁二醇已反應50重量％或50重量％以上時為止。步驟（A)可在〇 psig至100 psig範圍内之壓力下進行。如結合適用於本發明之任何催化劑所用之術語"反應產物"係指催化劑與用於製備聚酯之任何單體之聚縮合反應或酯化反應的任何產物，以及催化劑與任何其他類型添加劑之聚縮合反應或醋化反應的產物。通常，步驟（B)與步驟（C)可同時進行。該等步驟可藉由此項技術中已知之方法來進行，諸如藉由將反應混合物置於0_002 psig至大氣壓力以下之壓力範圍下，或對混合物吹熱氮氣。在一實施例中，本發明係關於一種製備聚酯之方法（下文稱為”鈦包含法’’），其包含以下步驟： (I)在至少一種選自150X：至250。〇之溫度下，在至少〜種選自0 psig至75 psig範圍内之壓力下加熱一混合.物，其中該混合物包含：〇)二羧酸組份，其包含： (i)約90至約100莫耳％之對苯二甲酸殘基； (11)約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二緩酸殘基；及 (b)二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,4_四甲基-1，3、 122661.doc -94- 200819496 環丁二醇殘基；及 (11)約0至約89莫耳％之環己烷二甲醇殘基； (ill)大於1〇莫耳％之乙二醇殘基，及 (IV)小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟（I)中所添加之二醇組份/二羧酸組份之莫耳比為 1·01_3.0/1.0 ; 其中步驟（I)中之混合物係在以下各物存在下加熱： (1)至少一種包含至少一種鈦化合物之催化劑，及視h況至少一種選自以下各物之催化劑：錫化合物、鎵化合物、鋅化合物、銻化合物、鈷化合物、錘化合物、鎂化合物、鍺化合物、鋰化合物、銘化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物’及（ii)至少一種填化合物、其反應產物及其混合物； (II)在230 C至320 C之溫度下’在至少一種選自步驟⑴ 之最終壓力至0.02托絕對壓力範圍内之壓力下將步驟⑴之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1〇〇莫耳％ ;且其中最終♦酉曰中之·一醇組份之總莫耳％為1〇〇莫耳％;且其中如於25°c下，在濃度為0.25 g/50 1111之60/40(重量比）盼/ 四氯乙烷中所測定，聚酯之固有黏度為0.50至1.2 dL/g。在一實施例中，本發明係關於一種製備聚酯之方法（下 122661.doc -95- 200819496 文稱為"錫與鈦包含法π)，其包含以下步驟： (I)在至少一種選自15 0°C至250。(：之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a)二羧酸組份，其包含： (1)約90至約100莫耳％之對苯二甲酸殘基； (ii)約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 C - (b)二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,4_四甲基環丁二醇殘基；及 (ii) 約0至約89莫耳％之環己烷二甲醇殘基； (iii) 大於10莫耳％之乙二醇殘基，及 (W)小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中步驟（I)中所添加之二醇組份/二羧酸組份之莫 C. 耳比為 1.01-3.0/1.0 ; 其中步驟（I)中之混合物係在以下各物存在下加熱： (i)至少一種包含至少一種鈦化合物、至少一種錫化合物之催化劑，及視情況至少一種選自以下各物之催化劑：鎵化合物、鋅化合物、銻化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、鋁化合物及具有氫氧化鋰或氫氧化鈉之 122661.doc •96- 200819496 鋁化合物；及（π)至少一種磷化合物、其反應產物及其混合物； (Π)在230°c至320°c之溫度下’在至少一種選自步驟⑴ 之最終壓力至0.02托絕對壓力範圍内之塵力下將步驟⑴ 之產物加熱1至6小時以形成最終聚酯；其中最終聚酯中之二羧酸組份之總莫耳％為1〇〇莫耳％ ;且其中最終聚酯中之二醇組份之總莫耳％為1〇〇莫耳％ ;且其中如於25C下，在濃度為0.25 g/50 ml之60/40(重量比）盼/ 四氯乙烷中所測定，聚酯之固有黏度為〇.5〇至12(11^4。在稱為欽包含法”及11欽與錫包含法”之本發明方法中，可在步驟（I)、步驟（II)及/或步驟⑴與（π)中及/或在步驟⑴ 與（II)之後添加至少一種填化合物，例如至少一種構酸酯。在本發明之適用於製備適用於本發明之聚酯之任何方法中，可在酷化反應、聚縮合反應或兩者反應期間添加至少一種鱗化合物、其反應產物及其混合物，及/或其可在聚合反應之後添加。在一實施例中，適用於本發明之任何方法中之磷化合物可在酯化反應期間添加。在一實施例中，若填化合物係在醋化反應與聚縮合反應之後添加，則其添加量以最終聚酯之總重量計為〇至2重量。/。。在一實施例中，若麟化合物係在酯化反應與聚縮合反應兩者之後添加’則其添加量以最終聚酯之總重量計為〇〇丨至2重量0/〇。在一實施例中，鱗化合物可包含至少一種構酸酯。在一實施例中’構化合物可包含至少一種在酯化反應步驟期間所 122661.doc 97- 200819496 添加之填化合物。在一實施例中，填化合物可包含至少一種例如在酯化反應步驟期間所添加之磷酸酯。據信’可使用製備適用於本發明之聚g旨之任何方法來製備任何適用於本發明之聚酯。本發明之任何方法之酯化反應步驟（I)之反應時間視所選溫度、壓力及二醇與二羧酸之饋料莫耳比而定。在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自20托絕對壓力至0.02托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II) 中所用之壓力係由至少一種選自1〇托絕對壓力至0 02托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自5托絕對壓力至〇·〇2托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（II)中所用之壓力係由至少一種選自3托絕對壓力至0·02托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（Π)中所用之壓力係由至少一種選自 20托絕對壓力至〇· 1托絕對壓力之壓力組成；在一實施例中’本發明之任何方法之步驟（π)中所用之壓力係由至少一種選自10托絕對壓力至〇·!托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟（π)中所用之壓力係由至少一種選自5托絕對壓力至〇·丨托絕對壓力之壓力組成；在一實施例中，本發明之任何方法之步驟中所用之壓力係由至少一種選自3托絕對壓力至托絕對壓力之壓力組成。 122661.doc -98- 200819496 在-實施例中，本發明之任何方法之二醇組份/二羧酸έ J斤添加之熳I組伤之莫耳比為1 .〇_2.0/1 .〇 ;在一實施例中，本發明之任钿貫&例々任何方法之步驟⑴中所添加㈣組份之莫耳比為! I，且伤’- 之任何方法之步驟⑴中B 實細例中，本發明莫耳比為】m 之二醇組份/二羧酸組份之之牛驟⑴φό ..，在一實施例中，本發明之任何方法之’)中所添加之二醇組份/二缓酸組 U1-1.5/1.0 ;在_眚姑加士丄、斗比為中所添加^ aMm 明之任何方法之步驟⑴ 12/1〇。—知組份/二幾酸組份之莫耳比為丨^· συ之適士用於本發明之聚醋之任何方法實施例中，步驟間可為⑴小時或…小時或⑴小時或15 至3小時或1至9 f η士，、夺。在一實施例中，步驟（II)之加熱時間可為1.5至3小時。心樣中’適用於本發明之聚S旨、聚S旨組合物及/或本發明之方法可包含鱗原子。二，適用於本發明之聚酯及/或聚酯組合物及/ 或方法可包含鈦原子及錫原子。在-態樣中’適用於本發明之聚醋、聚醋組合物及/或本發明之方法可包含磷原子及鈦原子。在一態4策中，、^j 、用於本發明之聚酯、聚酯組合物及/或卷月之方法可包含磷原子、錫原子及鈦原子。在—實施例中 , 士、+ T ’本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種璘化合物。 122661.doc -99- 200819496 在一實施例中，本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種鈦化合物。在一實施例中，本發明之任何聚酯、聚酯組合物及/或方法可包含至少一種鈦化合物及至少一種磷化合物。在一實施例中，適用於本發明之任何聚酯、聚酯組合物及/或製備該等聚酯之方法可包含至少一種錫化合物及至少一種鈦化合物。在-實施例中，適用於本發明之任何聚_、聚_組合物及/或製備該等聚S旨之方法可包含至少一種錫化合物、至少一種欽化合物及至少一種磷化合物。 v ^ I ^ ^ Ίϋ ^ ^ 最終聚酯中全部磷原子與全部錫原子之重量比為。在一實施例中，在本發明之方法中添加填化合物可使得最終聚醋中全部磷原子與全部錫原子之重量比為㈣·As described in detail in the U.S. Patent No. 2,720,507, the disclosure of which is incorporated herein by reference in its entirety in its entirety in its entirety, it can be generally prepared as follows: in an inert atmosphere, it gradually rises up to about during the course of the condensation reaction. Dicarboxylic acid or dicarboxylic acid is condensed with a diol in the presence of a titanium catalyst and/or a tin catalyst as described herein at a high temperature of 225 〇c_31〇<t temperature, and during the half period after the condensation reaction The condensation reaction is carried out at a low pressure. In another aspect, the present invention relates to a method of preparing the copolymerized vinegar of the present invention. In the examples, the method relates to the preparation of a copolyester comprising terephthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol and cyclohexanedimethanol. The method comprises the steps of: (A) heating a mixture comprising monomers suitable for use in the polyester of the invention in the presence of at least one tin catalyst and at least one phosphate at a temperature of from 150 to 250 C for a time sufficient to produce The initial polyester; (B) polycondensation of the product of step (A) by heating it to a temperature of from 230 to 320 ° C for 6 hours; and (C) removing any unreacted diol. 122661.doc -93- 200819496 The reaction time of the esterification reaction step (A) depends on the selected temperature, pressure and the molar ratio of the diol to the dicarboxylic acid feed. In one embodiment, step (A) can be carried out until 2,2,4,4-tetramethylcyclobutanediol has been reacted at 50% by weight or more. Step (A) can be carried out at a pressure in the range of 〇 psig to 100 psig. The term "reaction product" as used in connection with any catalyst suitable for use in the present invention refers to any product of the polycondensation or esterification reaction of the catalyst with any monomer used to prepare the polyester, as well as the catalyst and any other type of additive. The product of a polycondensation or acetation reaction. Generally, step (B) and step (C) can be carried out simultaneously. These steps can be carried out by methods known in the art, such as by placing the reaction mixture at a pressure in the range of from 0 to 002 psig to atmospheric pressure, or by blowing nitrogen to the mixture. In one embodiment, the invention relates to a method of preparing a polyester (hereinafter referred to as "titanium inclusion method") comprising the following steps: (I) at a temperature selected from at least one selected from the group consisting of 150X: to 250. Heating a mixture of at least ~ at a pressure selected from the range of 0 psig to 75 psig, wherein the mixture comprises: 〇) a dicarboxylic acid component comprising: (i) from about 90 to about 100 mole percent a terephthalic acid residue; (11) from about 0 to about 1 mole % of an aromatic and/or aliphatic sulphuric acid residue having up to 2 carbon atoms; and (b) a diol component , which comprises: (1) from about 1 to less than 90 mol% of 2,2,4,4-tetramethyl-1,3,122661.doc-94-200819496 cyclobutanediol residues; and (11) about 0 Up to about 89 mole % cyclohexane dimethanol residue; (ill) greater than 1 mole % ethylene glycol residue, and (IV) less than about 2 mole % having 3 to 16 carbon atoms a modified diol; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1.01_3.0/1.0; wherein the mixture in the step (I) is in the following Heating in the presence of: (1) at least one inclusion to a catalyst for a titanium compound, and a catalyst selected from the group consisting of a tin compound, a gallium compound, a zinc compound, a ruthenium compound, a cobalt compound, a hammer compound, a magnesium compound, a ruthenium compound, a lithium compound, a Ming compound, and An aluminum compound having lithium hydroxide or sodium hydroxide' and (ii) at least one filling compound, a reaction product thereof, and a mixture thereof; (II) at a temperature of 230 C to 320 C 'in at least one selected from the group (1) The product of step (1) is heated for 1 to 6 hours under pressure to a pressure in the range of 0.02 Torr absolute to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 〇〇 mol % And wherein the total molar % of the final component is 1% molar; and wherein, at 25 ° C, the concentration is 0.25 g / 50 1111 60 / 40 (weight The inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in tetraethylene chloride. In one embodiment, the invention relates to a method for preparing a polyester (lower 122661.doc-95-200819496) The text is called "tin and titanium contain the method π), which The method comprises the steps of: (I) heating a mixture at a temperature selected from the group consisting of from 15 ° C to 250 ° C (at a temperature selected from the range of from 0 psig to 75 psig, wherein the mixture comprises: a) a dicarboxylic acid component comprising: (1) from about 90 to about 100 mole percent terephthalic acid residues; (ii) from about 0 to about 10 mole percent having up to 2 carbon atoms An aromatic and/or aliphatic dicarboxylic acid residue; and a C-(b) diol component comprising: (1) from about 1 to less than 90 mol% of 2,2,4,4-tetramethylcyclobutane a diol residue; and (ii) from about 0 to about 89 mole % of a cyclohexanedimethanol residue; (iii) greater than 10 mole % of the ethylene glycol residue, and (W) less than about 2 moles % of a modified diol having 3 to 16 carbon atoms; wherein the diol component/dicarboxylic acid component added in the step (I) has a molar C. ear ratio of 1.01 to 3.0/1.0; The mixture in (I) is heated in the presence of: (i) at least one catalyst comprising at least one titanium compound, at least one tin compound, and optionally at least one catalyst selected from the group consisting of gallium compounds, zinc Compound , a ruthenium compound, a cobalt compound, a manganese compound, a magnesium compound, a ruthenium compound, a lithium compound, an aluminum compound, and an aluminum compound having lithium hydroxide or sodium hydroxide 122661.doc • 96-200819496; and (π) at least one phosphorus compound, a reaction product thereof and a mixture thereof; (Π) heating the product of the step (1) at a temperature of from 230 ° C to 320 ° C at a dust pressure of at least one selected from the final pressure of the step (1) to a pressure of 0.02 Torr absolute Up to 6 hours to form the final polyester; wherein the total mole % of the dicarboxylic acid component in the final polyester is 1% mol%; and wherein the total mole % of the glycol component in the final polyester is 1〇〇mol%; and wherein, at 25C, the inherent viscosity of the polyester is 〇.5〇 measured at a concentration of 0.25 g/50 ml of 60/40 (weight ratio)/tetrachloroethane. To 12 (11^4. In the method of the present invention, which is called the inclusion method and 11 and the tin inclusion method, it may be in step (I), step (II) and/or steps (1) and (π) and/or in steps (1) and (in II) After adding at least one filling compound, for example at least one acid ester. In any of the methods of the present invention suitable for the preparation of a polyester suitable for use in the present invention, at least one scale compound, its reaction product, and mixtures thereof, and/or thereof may be added during the cooling reaction, the polycondensation reaction, or both. It can be added after the polymerization reaction. In one embodiment, a phosphorus compound suitable for use in any of the methods of the present invention may be added during the esterification reaction. In one embodiment, if the compound is added after the acetation reaction and the polycondensation reaction, the amount added is from 〇 to 2 by weight based on the total weight of the final polyester. /. . In one embodiment, the ruthenium compound is added after both the esterification reaction and the polycondensation reaction, and is added in an amount of from 〇 to 2% by weight based on the total weight of the final polyester. In an embodiment, the scaly compound can comprise at least one acid ester. In one embodiment, the 'compound compound may comprise at least one compound which is added during the esterification reaction step 122661.doc 97-200819496. In one embodiment, the fill compound may comprise at least one phosphate ester added, for example, during the esterification reaction step. It is believed that any of the polyesters suitable for use in the present invention can be prepared by any method suitable for the preparation of the present invention. The reaction time of the esterification reaction step (I) of any of the processes of the present invention depends on the selected temperature, pressure and molar ratio of the diol to the dicarboxylic acid feed. In one embodiment, the pressure used in step (II) of any of the methods of the present invention consists of at least one pressure selected from the group consisting of 20 Torr absolute to 0.02 Torr absolute; in one embodiment, any method of the invention The pressure used in step (II) consists of at least one pressure selected from the group consisting of 1 Torr absolute pressure to 0 02 Torr absolute pressure; in one embodiment, the pressure used in step (II) of any method of the invention And consisting of at least one pressure selected from the group consisting of 5 Torr absolute pressure to 〇·〇 2 Torr absolute pressure; in one embodiment, the pressure used in step (II) of any method of the invention is at least one selected from the group consisting of 3 Torr. Absolute pressure to 0. 02 Torr absolute pressure composition; in one embodiment, the pressure used in the step (Π) of any method of the invention is at least one selected from the group consisting of 20 Torr absolute to 〇 1 Torr absolute pressure The pressure composition; in one embodiment, the pressure used in the step (π) of any method of the invention consists of at least one pressure selected from the group consisting of 10 Torr absolute pressure to 〇·! Torr absolute pressure; in one embodiment , The pressure used in step (π) of any method of the invention consists of at least one pressure selected from the group consisting of 5 Torr absolute pressure to 〇·丨托 absolute pressure; in one embodiment, used in the steps of any of the methods of the invention The pressure system consists of at least one pressure selected from the group consisting of 3 to 15 absolute pressures to absolute pressure. 122661.doc -98- 200819496 In an embodiment, the diol component of any of the methods of the present invention/the bismuth dicarboxylate added has a molar ratio of 〇2.0/1.〇 In an embodiment, the molar ratio of the component (4) added in the step (1) of any method of the present invention is !I, and the step (1) of any method of the injury '- is actually fine. In one embodiment, the molar ratio of the present invention is diol of the diol component/dicarboxylic acid component of the m (1) φ ό.., in one embodiment, the diol added in the ') method of any of the inventions Component/di-acidic acid group U1-1.5/1.0; Steps (1) 12/1〇 of any method of adding ^ aMm in _ 眚加加丄, 斗比为. - the method of any of the methods of the present invention, wherein the molar ratio of the component/diacid component is 丨^·συ is used in any of the method examples of the polyester of the present invention, and the step may be (1) hour or ... hour or (1) hour or 15 Up to 3 hours or 1 to 9 f η,, win. In one embodiment, the heating time of step (II) may be from 1.5 to 3 hours. The method of the present invention is applicable to the poly(S) composition of the present invention and/or the method of the present invention may comprise a scaly atom. Second, the polyester and/or polyester compositions and/or methods suitable for use in the present invention may comprise titanium atoms and tin atoms. The polyacetal, polyester composition and/or method of the present invention which is suitable for use in the present invention may comprise a phosphorus atom and a titanium atom. In one state, the method of using the polyester, polyester composition and/or the moon of the present invention may comprise a phosphorus atom, a tin atom and a titanium atom. In the examples, any polyester, polyester composition and/or method of the invention may comprise at least one hydrazine compound. 122661.doc -99- 200819496 In one embodiment, any of the polyesters, polyester compositions and/or methods of the present invention may comprise at least one titanium compound. In one embodiment, any of the polyesters, polyester compositions and/or methods of the present invention may comprise at least one titanium compound and at least one phosphorus compound. In one embodiment, any of the polyesters, polyester compositions, and/or methods of making the polyesters suitable for use in the present invention may comprise at least one tin compound and at least one titanium compound. In the examples, any of the poly-, poly-compositions and/or methods for preparing the poly-supplements suitable for use in the present invention may comprise at least one tin compound, at least one compound, and at least one phosphorus compound. v ^ I ^ ^ Ίϋ ^ ^ The weight ratio of all phosphorus atoms in the final polyester to all tin atoms. In one embodiment, the addition of the compound to the method of the present invention allows the weight ratio of all phosphorus atoms to total tin atoms in the final polyester to be (4).

-實施例中，在本發明之方法中添加碟化合物可使得最炊聚醋中全料原子與全部錫原子之重量比為㈣]二實施例中，在本發明之方法中添加磷化合物可醋中全部構原子與全部錫原子之重量比為Μ5:ι。：？施例中’在該（等）方法中添加磷化合物可使得最終^ 全部磷原子與全部錫原子之重量比為〇_1〇: 曰中中在本毛月之方法中添加碟化合物可使 :^ 部鱗原子與全部锡原子之重量比為M〇: 、j中全中，在該（等）方法+ % i i 只施例〒你、”万去中添加碟化合物可使得最鱗原子與全部锡原子之重量比朴5:1。在—實施 122661.doc •100- 200819496 本么明之方法中添加磷化合物可使得最終聚酯中全部磷原 ^與全部錫原子之重量比為。在—實施例中，在該 (等）方法中添加磷化合物可使得最終聚酯中全部磷原子與 σ錫原子之重里比為:1。在一實施例中，在該（等）方法中添加魏合物可使得最終聚S旨中全部磷原子與全部錫原子之重量比為^:丨。舉例而言，最終聚酯中所存在之錫 ^子及磷原子之重量可以ppm為單位來量測且可使得最終In the embodiment, the method of adding the dish compound in the method of the present invention is such that the weight ratio of the whole atom to the total tin atom in the most ruthenium vinegar is (4). In the second embodiment, the phosphorus compound can be added to the vinegar in the method of the present invention. The weight ratio of all constituent atoms to all tin atoms is Μ5:ι. :? In the example, the addition of the phosphorus compound in the method can make the weight ratio of the total phosphorus atom to the total tin atom 〇_1〇: Adding a dish compound in the method of the present month can be: ^ The weight ratio of the squamous atom to all the tin atoms is M〇: , j in the whole, in the (etc.) method + % ii only the example 〒 you, "When you add a dish compound to make the most scale atom and all The weight ratio of tin atoms is 5:1. In the method of implementing 122661.doc •100-200819496, the method of adding phosphorus compounds can make the weight ratio of all phosphorus atoms in the final polyester to all tin atoms. In an embodiment, the phosphorus compound is added to the method to make the weight ratio of all phosphorus atoms to σ tin atoms in the final polyester: 1. In one embodiment, a Wei compound is added in the method. The weight ratio of all phosphorus atoms to all tin atoms in the final poly(S) can be made into: 丨. For example, the weight of tin and phosphorus atoms present in the final polyester can be measured in ppm and can be measured. Make the end

1 6旨中全部碟原子與全部錫原子之重量比為任何上述重量比。 ^一實施例中，以最終聚s旨之重量計，㈣於本發明之聚酉曰中之錫原子的量可為〇至4〇〇錫原子。在實施例中，以最終聚醋之重量計，適用於本發明之聚酯中之錫原子的量可為15至400 ppm錫原子。 j-實施例中，以最終聚酯之重量計，冑用於本發明之聚酯中之鈦原子的量可為〇至4〇〇 ppm鈦原子。在-實施例中，以最終聚g旨之重量計，適用於本發明之聚酉曰中之鈦原子的量可為1 5至400 ppm鈦原子。在一實施财，以最終聚酯之重量計，適用於本發明之聚酯中之磷原子的量可為1至5〇〇卯爪磷原子。在一實施例中，以最終聚g旨之重量計，適用於本發明之 «中^錫原子的量可^至彻ppm錫原子；且以最終聚The weight ratio of all the disc atoms to all the tin atoms is any of the above weight ratios. In one embodiment, the amount of tin atoms in the polyfluorene of the present invention may be from 〇 to 4 锡 tin atoms, based on the weight of the final poly s. In the examples, the amount of tin atoms suitable for use in the polyester of the present invention may range from 15 to 400 ppm of tin atoms, based on the weight of the final polyester. In the j-embodiment, the amount of titanium atoms used in the polyester of the present invention may be from 〇 to 4 〇〇 ppm of titanium atoms based on the weight of the final polyester. In the examples, the amount of titanium atoms suitable for use in the polybenzazole of the present invention may be from 15 to 400 ppm of titanium atoms, based on the weight of the final polyg. In one implementation, the amount of phosphorus atoms suitable for use in the polyester of the present invention may range from 1 to 5 paw phosphorus atoms, based on the weight of the final polyester. In one embodiment, the amount of the atomic tin atom suitable for use in the present invention is up to a ppm of tin atoms, and is finally aggregated.

酯之重量計，適用於本發明之最終聚酯中之磷原子的旦口為1至500 ppm碟原子。、、里T 在-實施例中，以最終聚s旨之重量計，適用於本發明之 122661.doc -101- 200819496 聚醋中之磷原子的量可為！至· pp_原子；且以最炊聚酉旨之重量計，聚醋中之鈦原子的量 ' q王it}〇 ppm鈦原子。在-實施例中’以最終聚醋之重量計，適用於本發明之聚醋中之構原子的量可為PPm磷原子；且以最終聚醋之重㈣’聚醋中之錫原子的量可&至彻_錫原子。The phosphorus atom in the final polyester of the present invention has a denier of from 1 to 500 ppm of the disc atom, based on the weight of the ester. In the examples, the amount of phosphorus atoms in the polystyrene of the present invention can be used in the weight of the final polymer of 122661.doc-101-200819496. To pp_ atom; and the amount of titanium atom in the vinegar 'q king it} 〇 ppm titanium atom, based on the weight of the most condensed. In the examples - the amount of the constituent atoms in the polyester used in the present invention may be PPm phosphorus atom by weight of the final polyester; and the amount of tin atoms in the polyester in the weight of the final polyester (iv) Can & to the _ tin atom.

在-實施财，以最終聚s旨之重量計，適用於本發明之聚酯中之磷原子的量可為⑴⑼ppm磷原子；且以最終聚醋之重量彳’聚S旨中之鈦原子的量可為⑴⑽pp讀原子0 在-實施例中，以最終聚s旨之重量計，適用於本發明之聚酯中之磷原子的量可為1至500 ppm磷原子；以最終聚酯之重量計，適用於本發明之聚酯中之錫原子的量可為1至 400 ppm錫原子；且以最終聚酯之重量計，聚酯中之鈦原子的量可為1至100 ppm鈦原子。本發明另外係關於由上述方法所製備之聚酯組合物。本發明另外係關於一種聚合物摻合物。該摻合物包含： (a) 5至95重量％之至少一種上述聚酯；及 (b) 5至95重量％之至少一種聚合物組份。聚合物組份之合適實例包括（但不限於）：耐綸（nyl〇n); 不同於本文所述彼等聚酯之聚酯；聚醯胺，諸如DuP〇nt之 ZYTEL® ;聚苯乙烯；聚苯乙烯共聚物；苯乙烯丙浠腈共聚物；丙烯腈丁二烯苯乙烯共聚物；聚（曱基丙烯酸甲 122661.doc -102- 200819496The amount of phosphorus atoms in the polyester suitable for use in the present invention may be (1) (9) ppm of phosphorus atoms; and the weight of the final polyester is 钛' The amount may be (1) (10) pp read atom 0. In the embodiment, the amount of phosphorus atom suitable for use in the polyester of the present invention may be from 1 to 500 ppm phosphorus atom, based on the weight of the final poly s; The amount of tin atoms suitable for use in the polyester of the present invention may range from 1 to 400 ppm of tin atoms; and the amount of titanium atoms in the polyester may range from 1 to 100 ppm of titanium atoms based on the weight of the final polyester. The invention further relates to a polyester composition prepared by the above process. The invention further relates to a polymer blend. The blend comprises: (a) from 5 to 95% by weight of at least one of the above polyesters; and (b) from 5 to 95% by weight of at least one polymer component. Suitable examples of polymer components include, but are not limited to, nylon (nyl〇n); polyesters other than the polyesters described herein; polyamines, such as DuP〇nt's ZYTEL®; polystyrene Polystyrene copolymer; styrene acrylonitrile copolymer; acrylonitrile butadiene styrene copolymer; poly(mercapto acrylate 122661.doc -102- 200819496

酯）；丙烯酸系共聚物；聚（醚醯亞胺），諸如ULTEM® (General Electric之聚（醚醯亞胺）；聚苯醚，諸如聚（2,6-二甲基苯醚）或聚（苯醚）/聚苯乙烯摻合物，諸如NORYL 1000® (General Electric之聚（2,6-二甲基苯醚）與聚苯乙烯Ester); acrylic copolymer; poly(ether oxime imine), such as ULTEM® (General Electric poly(ether quinone imine); polyphenylene ether, such as poly(2,6-dimethylphenyl ether) or poly (Phenyl Ether) / Polystyrene Blend, such as NORYL 1000® (General Electric Poly(2,6-Dimethylphenyl Ether) and Polystyrene

樹脂之摻合物）；聚苯硫鱗；聚苯硫鱗/颯；聚（酯-碳酸酯）；聚碳酸酯，諸如LEXAN®(General Electric之聚碳酸酯），聚颯；聚職醚；及芳族二經基化合物之聚（驗·酮）；或以上任何聚合物之混合物。該等摻合物可藉由此項技術中已知之習知加工技術（諸如熔體摻合或溶液摻合）來製備。在一實施例中，聚酯組合物中無聚碳酸酯存在。若在本發明之聚酯組合物以摻合物形式使用聚碳酸酯，則該等掺合物透明可視。然而，適用於本發明之聚酯組合物亦涵蓋不包括聚碳酸醋以及包括聚碳酸I旨。a blend of resins; polyphenylene sulfide scale; polyphenylene sulfide scale/rhodium; poly(ester-carbonate); polycarbonate, such as LEXAN® (General Electric polycarbonate), polyfluorene; polyether ether; And a poly(dione) of the aromatic di-based compound; or a mixture of any of the above polymers. Such blends can be prepared by conventional processing techniques known in the art, such as melt blending or solution blending. In one embodiment, no polycarbonate is present in the polyester composition. If the polyester composition of the present invention is used in the form of a blend, the blends are transparent. However, the polyester compositions suitable for use in the present invention also cover the inclusion of polycarbonate and include polycarbonate.

適用於本發明之聚碳酸酯可根據已知程序來製備，例如藉由使二羥基芳族化合物與碳酸酯前驅體（諸如碳醯氯、函甲酸醋或碳酸醋、分子量調控劑、冑受體及催化齊”反應。製備聚碳酸酯之方法於此項技術中已知且描述於例如美國專利4,452,933中，其中有關聚碳酸g旨製備之揭示内办係以引用的方式併入本文中。 I 合適碳酸g旨前驅體之實例句杯 <只例a括（但不限於）碳醯溴、氯及其混合物；碳酸二I酷· - ·▲ 一义本酉日，一（鹵苯基）碳酸酯，例如一 (二氯苯基）碳酸g旨、二（二淳金〜 (烧基苯基）碳酸s旨，例如二（？苯基）碳酸g旨；二（蔡广酯；二（氯萘基）碳酸酯及其混合物·— 灭酉文 σ物，及一羥酚之雙南甲酸 122661.doc 200819496 合適分子量調控劑之實例包括（但不限於）酚、環己醇、甲醇、烧基化驗（諸如辛基酚、對第三丁基紛）及其類似物。在一實施例中，分子量調控劑為酚或烷基化酚。酸受體可為有機酸受體或無機酸受體。合適有機酸受體可為二級胺且包括（但不限於）諸如0比咬、三乙胺、二曱基苯胺、三丁胺及其類似物之物質。無機酸受體可為鹼金屬或驗土金屬之氫氧化物、碳酸鹽、碳酸氫鹽或鱗酸鹽。可使用之用以製備適用於本發明之聚碳酸酯之催化劑包括（但不限於）通常有助於單體與碳醯氣之聚合反應的彼等催化劑。合適催化劑包括（但不限於）三級胺，諸如三乙胺、二丙胺、N，N-二甲基苯胺；四級銨化合物，諸如四乙基溴化銨、十六烷基三乙基溴化銨、四正庚基碘化銨、四正丙基溴化銨、四曱基氯化銨、四曱基氫氧化銨、四正丁基碘化銨、苄基三甲基氯化銨；及四級鱗化合物，諸如正丁基三苯基溴化鱗及甲基三苯基溴化鱗。適用於本發明之聚酯摻合物中之聚碳酸酯亦可為共聚酯碳酸酉旨，諸如美國專利 3，169，121、3,2〇7,814、4，194,〇38、 4，156’〇69、4’43 0,484、4,465,820 及 4,981，898 中所述之彼等共聚S旨碳酸，丨中各美國專利中有關共聚㈣酸酿之揭示内容係以引用的方式併入本文中。適用於本發明之共聚醋碳酸醋可市售及/或可藉由此項 ^術中已知之方法來製備。舉例而言，其通常可藉由至少一種二羥基芳族化合物與碳醢氯及至少一種二羧酸氣化物 122661.doc 200819496 (尤其為異酞醯基氯、對酞醯基氯或兩者）之混合物反應而獲得。此外’適用於本發明之聚酯組合物及聚合物摻合組合物亦了 3有〇 · 〇 1至2 5重量％之總體組合物共用添加劑，諸如著色劑、調色劑、染料、脫模劑、阻燃劑、增塑劑、成核劑、穩定劑（除本文所述之填化合物以外包括（但不限於）UV穩定劑、熱穩定劑及/或其反應產物）、填充劑及抗衝擊改質劑。此項技術中熟知且適用於本發明之典型市售 (抗衝擊改質劑之實例包括（但不限於）乙浠/丙烯三聚物、官旎化聚烯烴（諸如含有丙烯酸甲酯及/或甲基丙烯酸縮水甘油酯之彼等官能化聚烯烴）、苯乙烯基嵌段共聚物抗衝擊改質劑及各種丙烯酸系核/殼型抗衝擊改質劑。亦涵蓋該等添加劑之殘基作為聚酯組合物之部分。此外，可將使聚合物著色之某些藥劑添加至溶體中。在一實施例中，將調藍劑添加至熔體中以減少所得聚酯聚合 , 物溶體相產物之b *。該等調藍劑包括藍色無機調色劑及有 ( 機調色劑。此外’亦可使用紅色調色劑來調節a*色彩。可使用有機調色劑，例如藍色及紅色有機調色劑，諸如美國專利第5,372,864號及第5,384,377號中所述之彼等調色劑，該等專利以引用的方式全文併入本文中。該等有機調色劑可以預混組合物之形式饋入。預混組合物可為紅色與藍色化合物之純摻合物，或可將組合物預溶解或磨裝於聚:原料之一者（例如乙二醇）中。當然，所添加之調色劑組份的總量視基本聚酯之固有黃 122661.doc 200819496 H之量及調色劑之功效而定…般使用至高約15 ppm 二口有機調色劑組份濃度及約^ ppm之最低濃度。調 '添加劑之總量通常在0.5至1〇啊之範圍内。。色Μ可添加至酯化反應區中或添加至聚縮合反應區車乂佳地，將5周色劑添加至醋化反應區中或添加至早期聚縮合反應區中’諸如添加至預聚合反應器中。，Polycarbonates suitable for use in the present invention can be prepared according to known procedures, for example by reacting a dihydroxy aromatic compound with a carbonate precursor such as carbon chloroform, carboxylic acid vinegar or carbonate, molecular weight regulator, guanidine receptor And a catalytic catalyzed reaction. A process for the preparation of a polycarbonate is known in the art and is described, for example, in U.S. Patent No. 4,452,933, the disclosure of which is incorporated herein by reference. The example cup of a suitable carbonic acid precursor is a case including, but not limited to, carbon bromide, chlorine, and mixtures thereof; carbonic acid II I····▲ yiyiben, one (halophenyl) Carbonic acid esters, for example, mono(dichlorophenyl)carbonate, bis (diphenyl ruthenium ~ (alkylphenyl) carbonate s, for example, bis (? phenyl) carbonate g; two (Cai Guang ester; Chloronaphthyl)carbonate and mixtures thereof - sulphide sigma, and monohydric acid of monohydric phenol 122661.doc 200819496 Examples of suitable molecular weight regulators include, but are not limited to, phenol, cyclohexanol, methanol, burning Base tests (such as octylphenol, tributyl butyl) and Analogous. In one embodiment, the molecular weight regulator is a phenol or an alkylated phenol. The acid acceptor can be an organic acid acceptor or a mineral acid acceptor. Suitable organic acid acceptors can be secondary amines and include (but not Limited to substances such as 0 bite, triethylamine, dinonylaniline, tributylamine and the like. The inorganic acid acceptor may be a hydroxide, carbonate, bicarbonate or an alkali metal or soil test metal. Phosphates. Catalysts which can be used to prepare polycarbonates suitable for use in the present invention include, but are not limited to, those which generally aid in the polymerization of the monomers with carbon helium. Suitable catalysts include (but not Limited to tertiary amines such as triethylamine, dipropylamine, N,N-dimethylaniline; quaternary ammonium compounds such as tetraethylammonium bromide, cetyltriethylammonium bromide, tetra-glycol Ammonium iodide, tetra-n-propylammonium bromide, tetradecyl ammonium chloride, tetradecyl ammonium hydroxide, tetra-n-butylammonium iodide, benzyltrimethylammonium chloride; and quaternary scale compounds, Such as n-butyltriphenyl bromide scale and methyltriphenyl bromide scale. Suitable for the polyester blending of the present invention. The polycarbonate may also be a copolyester carbonate, such as U.S. Patents 3,169,121, 3,2,7,814, 4,194, 〇38, 4,156'〇69, 4'43 0,484, 4,465,820 and 4,981,898, the copolymerization of the carbonic acid, and the disclosure of the copolymerization of the (iv) acid brewing in each of the U.S. patents are incorporated herein by reference. It is commercially available and/or can be prepared by methods known in the art. For example, it can generally be obtained by at least one dihydroxy aromatic compound and carbon ruthenium chloride and at least one dicarboxylic acid vaporization 122661.doc 200819496 Obtained by reacting a mixture of (especially isodecyl chloride, p-nonyl chloride or both). Further, the polyester composition and the polymer blending composition suitable for the present invention also have an overall composition-sharing additive such as a coloring agent, a toner, a dye, and a demolding agent, in an amount of from 1 to 25 % by weight. Agents, flame retardants, plasticizers, nucleating agents, stabilizers (including but not limited to UV stabilizers, heat stabilizers and/or their reaction products), fillers and anti-drugs Impact modifier. Typical commercially available and suitable for use in the present invention (examples of impact modifiers include, but are not limited to, acetam/propylene terpolymers, bureaucratized polyolefins (such as containing methyl acrylate and/or The functionalized polyolefin of glycidyl methacrylate, the styrene-based block copolymer impact modifier and various acrylic core/shell impact modifiers. The residues of these additives are also included as A portion of the polyester composition. Further, certain agents that color the polymer may be added to the solution. In one embodiment, a bluing agent is added to the melt to reduce polymerization of the resulting polyester, the solution The b b of the phase product. The bluing agents include a blue inorganic toner and an organic toner. In addition, a red toner can also be used to adjust the a* color. An organic toner such as blue can be used. Color and red organic toners, such as those described in U.S. Patent Nos. 5,372,864 and 5,384,377, the entireties of each of each of Feed in the form of a composition. Premixed combination It may be a pure blend of red and blue compounds, or the composition may be pre-dissolved or ground in one of the materials: one of the materials (eg, ethylene glycol). Of course, the total amount of added toner components Depending on the amount of the inherent polyester and the effectiveness of the toner, it is used up to a concentration of about 15 ppm of the two-component toner component and a minimum concentration of about ^ ppm. The total amount is usually in the range of 0.5 to 1 。. The color enamel may be added to the esterification reaction zone or added to the polycondensation reaction zone, and the 5 week colorant may be added to the acetalization reaction zone or Added to the early polycondensation reaction zone' such as added to the prepolymerization reactor.

本發明之組合物中可使用增強材料。增強材料可包括 (但不限於）碳絲、石夕酸鹽、雲母、黏土、滑石粉、二氧化夕火石玻璃碎片、玻璃微珠及纖維，及聚合物纖维及其組合。在一實施例中，增強材料包括玻璃，諸如纖維玻璃絲；玻璃與滑石粉、玻璃與雲母以及玻璃與聚合物纖維之混合物。本發明另夕卜係關於包含本發明之聚酷組合物及/或聚人物摻合物之薄膜及/或薄片。使聚g旨及/或摻合物形成薄：及或薄片之方法於此項技術中熟知。本發明之薄膜及/或薄片之實例包括（但不限於）擠出薄膜及/或薄片、壓延薄膜或薄片壓塑薄膜及/或薄片、溶液澆鑄薄膜及/或薄片製備薄膜及/或薄片之方法包括（但不限於）擠出、壓延、壓塑及溶液澆鑄。者由適用於本發明之薄膜及/或薄片所製得之可能物品的實例包括（但不限於）··單軸拉伸薄膜、雙軸拉伸薄膜、收縮溥膜（不管為單軸或雙軸拉伸）、液晶顯示器薄膜（包括 (但不限於）擴散片、補償膜及保護膜）、熱成型薄片、製版膜、戶外標誌、天窗、塗層、塗覆物品、噴漆物品、層壓 122661.doc 200819496 板、層壓物品及/或多層薄膜或薄片。如本文所用之，，製版膜”為一種其上或其中印刷有熱可固化之墨水（例如熱固性墨水或氣固性墨水）或輻射可固化之墨水（例如紫外線可固化性墨水）之薄膜。"可固化，，係指能夠經受聚合反應及/或交聯反應。除墨水以外，製版膜亦可視情況包括清漆、塗層、層壓板及黏著劑。例示性熱固性墨水或氣固性墨水包括分散於一或多種標準載劑樹脂中之顏料。該顏料可為4B調色劑（pR57)、⑼調色劑（PR48)、色澱紅C(PR53)、立索爾紅（Hth〇1 red) (PR49)、氧化鐵（PR101)、永久紅R(pR4)、永久紅 20(卩05)、吡唑啉酮橙（1>013)、二芳基黃（1>¥12，13，14)、單偶氮黃（PY3,5,98)、酞菁綠（PG7)、酞箐藍（3型（pBl5)、深藍（PB62)、永久紫（PV23)、二氧化鈦（pw6)、碳黑（爐腫/通道）（PB7)、PMTA 粉紅、PMTA 綠、PMTA 藍、ρΜΤΑ 紫 (PR81、PG1、PB1、PV3)、亞鐵氰化銅染料錯合物 (PR169、PG45、PB62、PV27)或其類似物。（以上括號中之標識係指由Society of Dyers and Colourists所編製之通用色彩指數）。可使用該等顏料及其組合以獲得各種色彩，包括（但不限於）白色、黑色、藍色、紫色、紅色、綠色、黃色、青色、深紅色或橙色。其他例示性墨水（包括輻射固化性墨水）係揭示於美國專利第5,382,292號中’其中該等墨水之揭示内容係以引用的方式併入本文中。標準墨水中所用之典型載劑樹脂之實例包括具有硝化纖 122661.doc -107- 200819496 維、醯胺、胺基甲酸酯、環氧化物、丙烯酸酯及/或酯官能基之彼等載劑樹脂。標準載劑樹脂包括以下各物中之一或多者：硝化纖維、聚醯胺、聚胺基甲酸酯、乙基纖維素、乙酸丙酸纖維素、（甲基）丙浠酸酯 '聚（乙烯醇縮丁酸）、聚（乙酸乙烯酯）、聚（氯乙烯）及其類似物。該等樹脂可與廣泛使用之摻合物（包括硝化纖維/聚醯胺及硝化纖維/ 聚胺基甲酸酯）摻合。墨水樹脂通常可溶劑化或分散於一或多種溶劑中。所用 ( 之典型溶劑包括（但不限於）水、醇類（例如乙醇、丨_丙醇、異丙醇等）、乙酸酯類（例如乙酸正丙酯）、脂族烴類、芳族烴類（例如甲苯）及酮類。該等溶劑之併入量通常可足以提供具有如由此項技術中已知之#2 Zahn杯所量測之至少15 秒（諸如至少20秒、至少25秒或25至35秒）之黏度的墨水。在一實轭例中，聚酯具有足以容許熱成型且足以便於印刷之T g值。在一實施例中，製版膜具有至少一種選自可熱成型性、 ( 韌性、透明度、耐化學性、Tg及可撓性之特性。製版膜可用於多種應用中，諸如模内裝飾物品、壓印物品、硬塗層物品❶製版膜可為平滑的或具有紋理。例示性製版膜包括（但不限於）：名牌；薄膜開關面板（例如’用於電器之薄膜開關面板）；現場展示包I ;洗衣機上之平坦或模内裝飾面板；冰箱上之平坦觸摸面板(例如電容式接觸塾陣列）；供箱上之平坦面板；汽車之内部裝飾件⑼如聚醋層麼板）；汽車之儀錶群；蜂巢式電話機 122661.doc 200819496 蓋；採暖與通風控制顯示器；汽車控制臺面板，·汽車齒輪換f面板；汽車儀錶面板之控制顯示器或報警信號， ·家用電态上之飾面、刻度盤或顯示器·洗衣機上之飾面、刻度盤或顯示器；洗碟德μ +处1 t 磲機上之飾面、刻度盤或顯示器；電子裝置之j鍵盤’行動電話、個人數位助理（pDA或掌上型電腦）或遠程控制器之小鍵盤；電子裝置之顯示器；掌上型電子衣置（諸如電活及PDA)之顯示器；行動電話或標準電話之面板及外殼；電子裝置上之標諸；及掌上型電話之標Reinforcing materials can be used in the compositions of the present invention. Reinforcing materials may include, but are not limited to, carbon filaments, agglomerates, mica, clay, talc, oxidized olivine glass cullet, glass microbeads and fibers, and polymeric fibers and combinations thereof. In one embodiment, the reinforcing material comprises glass, such as fiberglass; glass and talc, glass and mica, and a mixture of glass and polymeric fibers. The invention is further directed to films and/or flakes comprising the polycool compositions and/or poly blends of the present invention. Methods of forming poly-glycols and/or blends into thin: and or flakes are well known in the art. Examples of films and/or sheets of the present invention include, but are not limited to, extruded films and/or sheets, calendered or sheet-formed films and/or sheets, solution cast films, and/or sheet-formed films and/or sheets. Methods include, but are not limited to, extrusion, calendering, compression molding, and solution casting. Examples of possible articles made from films and/or sheets suitable for use in the present invention include, but are not limited to, uniaxially stretched films, biaxially oriented films, shrinkable films (whether uniaxial or double) Axial stretching), liquid crystal display film (including but not limited to diffuser, compensation film and protective film), thermoformed sheet, plate-making film, outdoor sign, skylight, coating, coated article, painted article, laminated 122661 .doc 200819496 Plates, laminates and / or multilayer films or sheets. As used herein, a stencil film is a film on which a heat curable ink (eg, a thermosetting ink or a gas-solid ink) or a radiation curable ink (eg, an ultraviolet curable ink) is printed. Curable, means capable of undergoing polymerization and/or crosslinking. In addition to ink, the plate-making film may optionally include varnishes, coatings, laminates and adhesives. Exemplary thermosetting inks or gas-solid inks include dispersion a pigment in one or more standard carrier resins. The pigment may be 4B toner (pR57), (9) toner (PR48), lake red C (PR53), and Litho red (Hth〇1 red). (PR49), iron oxide (PR101), permanent red R (pR4), permanent red 20 (卩05), pyrazolone orange (1 > 013), diaryl yellow (1 > ¥ 12, 13, 14) , monoazo yellow (PY3,5,98), phthalocyanine green (PG7), indigo (type 3 (pBl5), dark blue (PB62), permanent violet (PV23), titanium dioxide (pw6), carbon black (furnace) Swollen/channel) (PB7), PMTA pink, PMTA green, PMTA blue, ρΜΤΑ violet (PR81, PG1, PB1, PV3), copper ferrocyanide dye Compound (PR169, PG45, PB62, PV27) or an analogue thereof (the above brackets refer to the general color index compiled by Society of Dyers and Colourists). These pigments and combinations thereof can be used to obtain various colors. , including but not limited to, white, black, blue, purple, red, green, yellow, cyan, magenta, or orange. Other exemplary inks (including radiation curable inks) are disclosed in U.S. Patent No. 5,382,292 The disclosures of such inks are incorporated herein by reference. Examples of typical carrier resins used in standard inks include nitrocellulose 122661.doc-107-200819496, guanamine, urethane, Carrier resins for epoxide, acrylate and/or ester functional groups. Standard carrier resins include one or more of the following: nitrocellulose, polyamido, polyurethane, ethyl Cellulose, cellulose acetate propionate, (meth)propionate 'poly(vinyl butyric acid), poly(vinyl acetate), poly(vinyl chloride) and the like. Blends of widely used blends (including nitrocellulose/polyamide and nitrocellulose/polyurethane). Ink resins are usually solvated or dispersed in one or more solvents. Typical solvents include ( But not limited to) water, alcohols (such as ethanol, hydrazine-propanol, isopropanol, etc.), acetates (such as n-propyl acetate), aliphatic hydrocarbons, aromatic hydrocarbons (such as toluene) and ketones The incorporation of such solvents may generally be sufficient to provide a viscosity of at least 15 seconds (such as at least 20 seconds, at least 25 seconds, or 25 to 35 seconds) as measured by a #2 Zahn cup as is known in the art. ink. In a solid yoke, the polyester has a Tg value sufficient to permit thermoforming and sufficient to facilitate printing. In one embodiment, the stencil film has at least one property selected from the group consisting of thermoformability, (toughness, transparency, chemical resistance, Tg, and flexibility. The stencil film can be used in a variety of applications, such as in-mold decorative articles, pressure Printed articles, hard-coated articles, stencils may be smooth or textured. Exemplary stencils include, but are not limited to: brand names; membrane switch panels (eg, 'membrane switch panels for appliances); on-site display kits I Flat or in-mold decorative panel on the washing machine; flat touch panel on the refrigerator (such as capacitive contact 塾 array); flat panel on the box; interior decoration parts of the car (9) such as vinegar layer board; Group; cellular telephone 122661.doc 200819496 cover; heating and ventilation control display; car console panel, · car gear for f panel; car dashboard control display or alarm signal, · household electrical finish, dial Or a finish, a dial or a display on a washing machine; a veneer, a dial, or a display on a 1 t machine; electronic device j keyboard 'mobile phone, personal digital assistant (pDA or palm-sized computer) or remote controller keypad; electronic device display; handheld electronic clothing (such as electric live and PDA) display; mobile phone or standard phone Panel and housing; the standard on the electronic device; and the standard of the palm phone

誌、0 多層薄膜或多層薄片係指以型面形式擠出之薄片，該型面由藉助於立式肋狀物彼此連接之多層組成。多層薄膜或多層薄片之實例包括（但不限於）戶外遮蔽物（例如溫室及商用遮篷）。包含適用於本發明之聚酯組合物之擠出物品的實例包括 (但不限於）製版應用之熱成型薄片、熱成型薄膜；戶外標誌；天窗；多層薄膜；塑料玻璃層壓板之塑料薄膜及液晶顯示器（LCD)薄膜（包括（但不限於）LCD之擴散片、補償膜及保護膜）。在一實施例中，本發明包含一種通常為片材形式，其中甘欠有裝飾材料，包含本文所述之任何組合物的熱塑性物品0 如本文所用之，，戶外標誌，，係指由本文所述之聚g旨形成之表面’或含有經本文所述之聚酯或聚酯膜塗覆之符號（例如數字、字母、標語、圖片等）、圖案或圖樣之表面。在 122661.doc -109- 200819496 一實施例中，戶外標識包含一種含有聚酯之印刷符號、圖案或圖樣。在一實施例中，該標誌能夠在足夠長之時期 (例如一天至數年或更長時間）内耐受典型之天氣條件，諸如雨、雪、冰、冰潼、高濕度、熱、風、日光或其組合。例示性戶外標誌包括（但不限於）告示牌、霓虹燈標誌、電致發光標誌、、電標諸、、螢光標諸及發光二極體（LED)顯示器。其他例示性標誌包括（但不限於）塗漆標誌、乙烯裝飾標誌、熱成型標誌及硬塗層標誌。在一實施例中，戶外標誌具有至少一種選自可熱成型性、韋刃性、透明度、财化學性及之特性。如本文所用之，，自動販賣機顯示面板”係指自動販賣機之正面或側面面板’其允許顧客觀看出售物品或有關該等物品之廣告。在一實施例中，自動販賣機顯示面板可為消費者可經其看到出售物品之自動販賣機透明可視面板。在其他實施例中’自動販賣機顯示面板可具有足夠之剛性以將内含物包含於機器内及/或防止破壞及/或偷盜。在一實施例中，自動販賣機顯示面板可具有此項技術中熟知之尺寸，諸如快餐、飲料、爆米花或貼紙/票券自動販買機之平面顯示面板，以及例如泡泡糖機或散裝糖果機之囊形顯示面板。在一實施例中，自動販賣機顯示面板視情況可含有廣告媒體或產品鑑定標記。該等資訊可由此項技術中熟知之方法（例如絲網法）塗佈。在一實施例中，自動販賣機顯示面板可耐受_100至 122661.doc 200819496 面板具有抗UV性 m°c範圍内之溫度。在另—實施例中，如本文所揭示， 1 '、、力例如至少-種―添加劑’可使自動販賣機顯示在只知*例中，自動販賣機顯示面板具有至少一種選自可熱成型性、韌性、透明度、耐化學性及Tg之特性。如本文所用之，，現場展示包裝"係指具有至少一個用於展 =之透明可視面板的完全或部分密閉箱。現場展示包A multilayer film or a multilayer film refers to a sheet extruded in the form of a profile composed of a plurality of layers joined to each other by means of vertical ribs. Examples of multilayer films or multilayer sheets include, but are not limited to, outdoor shelters (e.g., greenhouses and commercial awnings). Examples of extruded articles comprising the polyester composition suitable for use in the present invention include, but are not limited to, thermoformed sheets for thermoplating applications, thermoformed films; outdoor signs; skylights; multilayer films; plastic films and liquid crystals of plastic glass laminates. Display (LCD) film (including but not limited to LCD diffuser, compensation film and protective film). In one embodiment, the invention comprises a sheet form, typically a decorative material, a thermoplastic article 0 comprising any of the compositions described herein, as used herein, an outdoor sign, which is referred to herein. The surface formed by the present invention or the surface (including numerals, letters, slogans, pictures, etc.), patterns or patterns coated with the polyester or polyester film described herein. In one embodiment, 122661.doc-109-200819496, the outdoor sign contains a printed symbol, pattern or pattern containing polyester. In an embodiment, the sign can withstand typical weather conditions for a sufficiently long period of time (eg, one day to several years or longer), such as rain, snow, ice, hail, high humidity, heat, wind, Daylight or a combination thereof. Exemplary outdoor signs include, but are not limited to, billboards, neon signs, electroluminescent signs, electrical standards, fluorescent cursors, and light emitting diode (LED) displays. Other exemplary signs include, but are not limited to, painted signs, vinyl decorative signs, thermoformed signs, and hard coated signs. In one embodiment, the outdoor sign has at least one property selected from the group consisting of thermoformability, sharpness, transparency, and chemical properties. As used herein, a vending machine display panel refers to a front or side panel of a vending machine that allows a customer to view items for sale or advertisements relating to such items. In an embodiment, the vending machine display panel can be The vending machine transparent viewing panel through which the consumer can see the item being sold. In other embodiments, the 'automatic vending machine display panel can be sufficiently rigid to contain the contents in the machine and/or prevent damage and/or In one embodiment, the vending machine display panel can be of a size well known in the art, such as a flat display panel for fast food, beverages, popcorn or sticker/ticket vending machines, and, for example, a bubble gum machine or bulk. The capsule display panel of the confectionery machine. In one embodiment, the vending machine display panel may optionally contain advertising media or product identification indicia. Such information may be applied by methods well known in the art, such as wire mesh. In an embodiment, the vending machine display panel can withstand _100 to 122661.doc 200819496 panel has UV resistance within a range of m°c In another embodiment, as disclosed herein, 1 ', force, such as at least one - additive' may cause the vending machine to be displayed in the example only, the vending machine display panel having at least one selected from the group consisting of Thermoformability, toughness, transparency, chemical resistance, and Tg characteristics. As used herein, on-site display packaging refers to a full or partial closed box having at least one transparent visible panel for display.

衣通吊用於零售店中以達成吸引顧客眼球之目#。例示性現：展示包敦包括密閉壁固定件、臺面、密閉海報架、展不相(例如獎品展示箱）、#誌框架及電腦碟片(諸如CD及 DVD)箱。現場展示包裝可包括搁架及其他容器，諸如雜諸或小冊子之支架。視待展示之物品而定，-般熟習此項技術者可易於設想現場展示包裝之外形及尺寸。舉例而言，展示可小如珠寶盒’或對於展示多個獎品而言可為較大之密閉櫃。在-實施例中’現場展示包裝具有至少_種選自韌性、透明度、耐化學性、1及水解穩定性之特性。如本文所用之"電器部件”係指結合電器使用之硬質零件。在-實施例中，電器部件可部分地或完全地與電器分開。在另-實施例中，電器部件為通常由聚合物製成^部件。在一實施例中，電器部件透明可視。例示性電器部件包括需有㈣及耐久性之彼等部件，諸如、•口口艮叩加工器、混合器、摻合機及切碎機使用之杯及碗；可耐受冰箱及冷凍器溫度（例如大於or(例如2。〇)至 122661.doc -111- 200819496 5 C範圍内之冰箱溫序度或例如小於0°C溫度（諸如-2(TC至耗圍内之溫度，例如，。c)之冷涞器溫度)之部件，諸如冰相及冷凍器托盤、箱櫃及擱架；纟高達之溫产下 =有=水解穩定性之部件，諸如洗衣機門、蒸汽:潔余亞及咖啡壺；及真空清潔罐及吸塵杯。在K施例中，該等電器部件具有至少一種選自動性、透明度、耐化學性、Tg、水解穩定性及洗碟機穩定性之特性。電器部件亦可選自蒸汽清潔冑，在一實施例中其可具有至少-種選自㈣、透明I、耐化學性、及水解穩定性之特性。 " 在一實施例中，適用於電器部件之聚酯具有105°c至 140°C之Tg，且電器部件係選自真空清潔罐及吸塵杯。在另一實施例中，適用於電器部件之聚酯具有12〇至15〇。〇之 Tg ’且電器部件係選自蒸汽清潔罐、茶壺及咖啡壺。如本文所用之天固"係指緊固於屋頂表面之可透光性面板，以使得該面板形成天花板之一部分。在一實施例中， 5亥面板為硬質面板，例如具有足以達成穩定性及耐久性之尺寸’且該等尺寸可易於由熟習此項技術者來測定。在一貝施例中，天窗面板具有大於3/1 6忖之厚度，諸如至少1 /2 吋之厚度。在一實施例中，天窗面板透明可視。在一實施例中，天窗面板可透射至少35%之可見光、至少50%、至少75%、至少80%、至少9〇%或甚至至少95%之可見光。在另一實施例中’天窗面板包含至少一種可使天窗面板阻擋至多 122661.doc -112- 200819496 80%、90%或至多95%紫外光之UV添加劑。在一實施例中，天窗具有至少一種選自可熱成型性、韌性、透明度、耐化學性及Tg之特性。如本文所用之"戶外遮蔽物”係指具有至少一個硬質面板’能夠對例如日光、雨、雪、風、寒冷等各因素提供至少某些保護之屋頂及/或牆壁結構。在一實施例中，戶外遮蔽物具有至少一個屋頂及/或一或多個牆壁。在一實施例中，戶外遮蔽物具有足以達成穩定性及耐久性之尺寸， ( 且該等尺寸可易於由熟習此項技術者來測定。在一實施例中，戶外遮蔽物面板具有大於3/16吋之厚度。在一實施例中，戶外遮蔽物面板透明可視。在一實施例中，戶外遮蔽物面板可透射至少35%之可見光、至少 50%、至少75%、至少80¼、至少90。/。或甚至至少95。/〇之可見光。在另一實施例中，戶外遮蔽物面板包含至少一種可使戶外遮蔽物阻擋至多8〇%、90%或至多95%紫外光之UV 添加劑。 ί 例示性戶外遮蔽物包括安全玻璃、客運候車室（例如巴士候車室）、電話亭及吸煙室。在一實施例中，若遮蔽物為客運候車室、電話亭或吸煙室，則該遮蔽物具有至少一種選自可熱成型f生、韌性、透明度、耐化學性及L之特 f生在一實施例中，若遮蔽物為安全玻璃，則該遮蔽物具有至少一種選自韌性、透明度、耐化學性及&之特性。如本文所用之”遮篷”係指能夠對例如日光、雨、雪、風、寒冷等各因素提供至少某些保護之屋頂結構。在一實 122661.doc -113 - 200819496 施例中’屋頂結構全部或部分地包含至少一個硬質面板， Y J如/、有足以達成穩定性及耐久性之尺寸，且該等尺寸可易於由熟習此項技術者來測定。在一實施例中，遮篷面板具有大於3/16吋之厚度，諸如至少1/2吋之厚度。在一實施例中，遮篷面板透明可視。在一實施例中，遮篷面板可透射至少35%之可見光、至少5〇%、至少75%、至）8〇%、至少90%或甚至至少95%之可見光。在另一實加例中’遮篷面板包含至少一種可使遮篷阻播至多、 9〇%或至多95%之紫外光的UV添加劑。例不性遮篷包括有蓋行人道、採光屋頂、日光房、飛機座舱盖及天篷。在一實施例中，遮篷具有至少一種選自韌性、透明度、耐化學性、Tg及可撓性之特性。如本文所用之”音障”係指一種硬質結構，其與相同距離之兩點之間在無音障時之聲音傳輸相比能夠減少該結構一側上之一點至另一側上之另一點的聲音傳輸量。減少聲音傳輸之有效性可藉由此項技術中已知之方法來評估。在一實施例中’聲音傳輸減少量之範圍為25%至90%。在另一實施例中，音障可如以下文獻中所述以聲音傳輸等級值來評級：ASTM E90，f，Standard Test Method for Laboratory Measurement of Airborne Sound Transmission Loss of Building Partitions and Elements，’’ 及 ASTM E413，Classification of Rating Sound Insulation”。STC 55 Ρ早壁可將喷射引擎之聲音自約130 dBA減少至60 dBA，此聲音為典型辦公室内之音級。隔音室可具有〇_2〇 dBA範圍 122661.doc -114- 200819496 内之音、級。一般熟習此項技術者可建構並布置音障以達成所要之STC等級。在一實施例中，音障具有至少2〇2STc 等級，諸如20至60範圍内之STC等級。在一實施例中’音障包含複數個經連接及布置以達成所要障壁概況之面板。音障可沿街道及公路使用以消減汽車噪音。或者，音障可以離散面板之形式或嵌入牆壁、地板、天花板、門及/或窗之結構中之形式用於家庭或辦公室。 ( 在一實施例中，音障透明可視。在一實施例中，音障可透射至少35%之可見光、至少50%、至少75%、至少8〇%、至少90%或甚至至少95%之可見光。在另一實施例中音障包含至少一種可使音障阻擋至多8〇%、9〇%或至多95% 之紫外光的UV添加劑。在一實施例中，音障具有至少一種選自韌性、透明度、耐化學性及Tg之特性。如本文所用之"溫室”係指用於培養及/或保護植物之密閉 t 結構。在一實施例中，溫室能夠維持培養植物所需之濕度及/或氣體（氧氣、二氧化碳、氮氣等）含量，同時能夠對例如曰光、雨、雪、風、寒冷等各因素提供至少某些保護。在一實施例中，溫室之屋頂全部或部分地包含至少一個硬質面板’其例如具有足以達成穩定性及耐久性之尺寸，且該等尺寸可易於由熟習此項技術者來測定。在一實施例中，溫室面板具有大於3/16吋之厚度，諸如至少1/2吋之厚度0 122661.doc -115- 200819496 在一實施例中，溫室面板透明可視。在另一實施例中，溫室中實質上所有之屋頂及牆壁均透明可視。在一實施例中’溫室面板可透射至少35%之可見光、至少50%、至少 750/。、至少80%、至少9〇%或甚至至少95%之可見光。在另一實施例中’溫室面板包含至少一種可使溫室面板阻擋至多80%、90%或至多95%之紫外光的UV添加劑。在一實施例中，溫室面板具有至少一種選自韌性、透明度、耐化學性及Tg之特性。如本文所用之”光學媒體”係指藉由以雷射光束（例如可見光波長區内之光，諸如具有6〇〇至70〇 nm範圍内之波長的光）照射而於其中記錄資訊的資訊儲存媒體。藉由雷射光束之照射，使記錄層之照射區域局部受熱以改變其物理或化學特徵，且在記錄層之照射區域中形成凹點。由於所形成之凹點的光學特徵與未經照射區域之光學特徵不同，因此數位資訊得以經光學方法記錄。所記錄之資訊可藉由再現程序碩取，該程序通常包含如下步驟：以具有與用於“己錄程序之波長相同之波長的雷射光束照射記錄層；及偵測凹點與其外周部之間的光反射差異。 ^ 在一實施例中，光學媒體包含一透明碟片，其具有一螺旋形預刻溝槽；一置於該預刻溝槽内之記錄染色層，於其上藉由以雷射光束照射來記錄資訊；及一光反射層。光學媒體視情況可由消費者記錄。在一實施例中，光學媒體：選自緊密光碟（CD)及數位視訊光碟（DVD)。光學媒體可以預錄資訊形式出售，或以可記錄光碟形式出售。 122661.doc -116- 200819496 在一實施例中，以下至少一者包含本發明之聚酯：基板、光學媒體之至少一個保護層及光學媒體之記錄層。在一實施例中，光學媒體具有至少一種選自韌性、透明度、耐化學性、1^及水解穩定性之特性。如本文所用之，，玻璃層壓板”係指玻璃上之至少一層塗層’其中塗層中之至少一層包含聚酯。塗層可為薄膜或薄片。玻璃可為透明的’有色的或反射性的。在一實施例中’層壓板與玻璃永久黏結，例如在加熱及壓力下施加層壓板以形成單一固體層壓玻璃產物。可將玻璃之一面或兩面層壓。在某些實施例中，玻璃層壓板含有一層以上之包含本發明之聚g旨組合物的塗層。在其他實施例中，玻璃層壓板包含多層玻璃基板及一層以上之包含本發明之聚g旨組合物的塗層。例示性玻璃層壓板包括窗（例如高層建築、建築物入口之窗）；運輸應用（例如汽車、巴士、噴射式飛機、裝甲車）之安全玻璃、擋風玻璃；防彈玻璃、保險玻璃（例如用於銀行）；抗颶風玻璃；飛機座艙蓋、鏡、太陽玻璃板、平板顯示器及防爆窗。玻璃層壓板透明可視，可經磨砂，触刻或圖案化。在一實施例中，玻璃層壓板可耐受-l〇(TC至12〇。〇範圍内之溫度。在另一實施例中，如本文所揭示，可藉由添加例如至少一種UV添加劑而使玻璃層壓板具有抗UV性。將本發明之薄膜及/或薄片層壓至玻璃之方法為一般熟習此項技術者所熟知。可藉由真空層壓法進行層壓而無需 122661.doc -117- 200819496 使用黏著層。為在玻璃層與層壓板之間獲得有效黏結，在一實施例中，玻璃具有低表面粗糙度。或者，可使用雙面膠帶、黏著層或明膠層(藉由塗覆例如熱熔體、壓敏黏著劑或熱敏黏著劑或uv或電子束可固化之黏著劑而獲得）來將本發明之層壓板黏結至玻璃。黏著層可塗覆於玻璃薄片、層壓板或兩者，且可由剝離層來保護，剝離層可在層壓之前移除。在一實施例中，玻璃層壓板具有至少一種選自韌性、透明度、耐化學性、水解穩定性及Tg2特性。對於本發明之目的而言，術語"wt”意謂，，重量”。以下實例進一步說明如何製備及評估本發明之聚醋，且希望僅為本發明之例示而不希望限制其範疇。除非另有說明’否則份數為重量份，溫度以攝氏度計或為室溫，且壓力為大氣壓或接近大氣壓。實例以下實例一般而言說明如何製備本發明之共聚s旨以及與基於2,2,4,4-四甲基-1，3-環丁二醇之其他共聚酯相比，使用2,2,4,4-四甲基-1，3-環丁二醇、1，4-環己烷二甲醇及乙二醇對各種共聚酯特性（諸如玻璃轉移溫度、伊佐德氏缺口衝擊強度及撓曲模數）之影響。此外，基於以下實例，熟習此項技術者將瞭解如何使用某些催化劑系統及熱穩定劑來製備本發明之聚酯。量測方法聚酯之固有黏度係於25°C下，在濃度為0.5 g/l〇〇瓜丨之 122661.doc -118- 200819496 60/40(重量比）酚/四氯乙烷中測定，且以dL/g為單位報導。除非另有說明，否則玻璃轉移溫度（Tg)係使用ThermalYitong crane is used in retail stores to achieve the goal of attracting customers' eyes. Illustrative Present: Showcases including the confining wall fixtures, countertops, closed poster frames, exhibitions (such as prize display cases), #志架, and computer discs (such as CD and DVD) boxes. The on-site display package can include shelves and other containers, such as shelves for miscellaneous or booklets. Depending on the item to be displayed, it is easy for the person skilled in the art to visualize the shape and size of the package on site. For example, the display may be as small as a jewelry box or may be a larger enclosure for displaying multiple prizes. In the embodiment, the on-site display package has at least one property selected from the group consisting of toughness, transparency, chemical resistance, and hydrolytic stability. "Electrical component" as used herein refers to a hard component used in conjunction with an appliance. In an embodiment, the electrical component may be partially or completely separate from the appliance. In another embodiment, the electrical component is typically a polymer The components are made transparent. In one embodiment, the electrical components are transparent. Exemplary electrical components include those that require (d) and durability, such as, • mouth 艮叩 processor, mixer, blender, and cut Cups and bowls for crushers; can withstand refrigerator and freezer temperatures (eg greater than or (eg, 2. 〇) to 122661.doc -111 - 200819496 5 C range of refrigerator temperature or for example less than 0 ° C temperature (such as -2 (TC to the temperature inside the temperature, for example, c) the temperature of the cold header), such as ice phase and chiller trays, bins and shelves; 纟 up to the temperature of the production = there = hydrolysis stability Sexual components, such as washing machine doors, steam: Jieyuya and coffee makers; and vacuum cleaning cans and vacuum cups. In K, these electrical components have at least one selected for autonomy, transparency, chemical resistance, Tg, Hydrolytic stability and dishwasher stability The electrical component may also be selected from the group consisting of steam cleaning cartridges, which in one embodiment may have at least one selected from the group consisting of (4), transparent I, chemical resistance, and hydrolytic stability. " In an embodiment, The polyester suitable for the electrical component has a Tg of 105 ° C to 140 ° C, and the electrical component is selected from the group consisting of a vacuum cleaning can and a vacuum cup. In another embodiment, the polyester suitable for the electrical component has 12 to 15 〇.〇Tg' and the electrical components are selected from the group consisting of steam cleaning cans, teapots and coffee makers. "Tiangu" as used herein refers to a opaque panel fastened to the roof surface such that the panel forms a ceiling. In one embodiment, the 5H panel is a rigid panel, for example having a size sufficient for stability and durability' and the dimensions can be readily determined by those skilled in the art. In one embodiment, the sunroof The panel has a thickness greater than 3/16 ,, such as a thickness of at least 1 /2 。 In one embodiment, the sunroof panel is transparent. In one embodiment, the sunroof panel can transmit at least 35% of visible light, at least 50% At least 75%, 80% less, at least 9% or even at least 95% of visible light. In another embodiment, the 'sunroof panel contains at least one that can block the sunroof panel up to 122661.doc -112 - 200819496 80%, 90% or up to 95% Ultraviolet UV additive. In one embodiment, the sunroof has at least one property selected from the group consisting of thermoformability, toughness, transparency, chemical resistance, and Tg. As used herein, "outdoor shelter" A hard panel 'can provide at least some protection of the roof and/or wall structure for various factors such as daylight, rain, snow, wind, cold, etc. In one embodiment, the outdoor shelter has at least one roof and/or one or more Walls. In one embodiment, the outdoor shelter has dimensions sufficient to achieve stability and durability (and such dimensions can be readily determined by those skilled in the art. In one embodiment, the outdoor shelter panel has greater than 3/. In one embodiment, the outdoor shelter panel is transparent. In one embodiment, the outdoor shelter panel can transmit at least 35% of visible light, at least 50%, at least 75%, at least 801⁄4, at least 90. In particular, the outdoor shelter panel comprises at least one UV additive that blocks the outdoor shelter from up to 8%, 90% or up to 95% ultraviolet light. Exemplary outdoor shelters include safety glass, passenger waiting rooms (such as bus waiting rooms), telephone booths, and smoking rooms. In one embodiment, if the shelter is a passenger waiting room, a telephone booth, or a smoking room, the shelter has at least one In one embodiment, if the mask is a safety glass, the mask has at least one selected from the group consisting of thermoformable, toughness, transparency, chemical resistance, and L. , transparency, chemical resistance, and the characteristics of & "canopy" as used herein refers to a roof structure capable of providing at least some protection to various factors such as sunlight, rain, snow, wind, cold, etc. .doc -113 - 200819496 In the example, the 'roof structure contains all or part of at least one hard panel, YJ is /, has dimensions sufficient for stability and durability, and the dimensions can be easily obtained by those skilled in the art. In one embodiment, the awning panel has a thickness greater than 3/16 ,, such as a thickness of at least 1/2 。. In one embodiment, the awning panel is transparent. In one embodiment, the awning panel At least 35% of visible light, at least 5%, at least 75%, to 8%, at least 90% or even at least 95% of visible light can be transmitted. In another embodiment, the awning panel comprises at least one UV additive that allows the awning to block up to 9, 9% or up to 95% of the UV light. Unusual awnings include covered walkways, daylighting roofs, sunrooms, aircraft canopies and canopies. In one embodiment, the awning has at least one property selected from the group consisting of toughness, transparency, chemical resistance, Tg, and flexibility. As used herein, "sound barrier" refers to a rigid structure that reduces the sound of one point on one side of the structure to another point on the other side of the structure at two points of the same distance compared to sound transmission without sound barriers. The amount of transmission. Reducing the effectiveness of sound transmission can be assessed by methods known in the art. In one embodiment, the amount of sound transmission reduction is in the range of 25% to 90%. In another embodiment, the sound barrier can be rated as a sound transmission rating value as described in the following documents: ASTM E90, f, Standard Test Method for Laboratory Measurement of Airborne Sound Transmission Loss of Building Partitions and Elements, '' and ASTM E413 , Classification of Rating Sound Insulation. The STC 55 Ρ early wall reduces the sound of the jet engine from approximately 130 dBA to 60 dBA, which is the sound level in a typical office. The soundproof room can have a range of 〇_2〇dBA 122661. Doc-114-200819496 The sound, level. Generally, those skilled in the art can construct and arrange a sound barrier to achieve the desired STC level. In one embodiment, the sound barrier has a level of at least 2 〇 2 STc, such as in the range of 20 to 60. STC rating. In one embodiment, the 'sound barrier' includes a plurality of panels that are connected and arranged to achieve a desired barrier profile. The sound barrier can be used along streets and highways to reduce vehicle noise. Alternatively, the sound barrier can be in the form of discrete panels or embedded in walls, floors. In the form of a ceiling, door and/or window structure for use in a home or office. (In an embodiment The sound barrier is transparently visible. In one embodiment, the sound barrier can transmit at least 35% of visible light, at least 50%, at least 75%, at least 8%, at least 90%, or even at least 95% of visible light. In another embodiment, the sound barrier The UV additive comprising at least one ultraviolet light that can block the sound barrier by up to 8%, 9%, or up to 95%. In one embodiment, the sound barrier has at least one property selected from the group consisting of toughness, transparency, chemical resistance, and Tg. As used herein, "greenhouse" refers to a closed t-structure used to culture and/or protect plants. In one embodiment, the greenhouse is capable of maintaining the humidity and/or gas (oxygen, carbon dioxide, nitrogen, etc.) required to grow the plant. The content, while at the same time providing at least some protection to various factors such as calendering, rain, snow, wind, cold, etc. In one embodiment, the roof of the greenhouse comprises, in whole or in part, at least one rigid panel which is, for example, sufficient to achieve stability. The dimensions of the properties and durability, and such dimensions can be readily determined by those skilled in the art. In one embodiment, the greenhouse panel has a thickness greater than 3/16 ,, such as at least 1/2 吋. Thickness 0 122661.doc -115- 200819496 In one embodiment, the greenhouse panel is transparently visible. In another embodiment, substantially all of the roof and walls in the greenhouse are transparent. In one embodiment, the greenhouse panel can be Transmit at least 35% of visible light, at least 50%, at least 750/., at least 80%, at least 9%, or even at least 95% of visible light. In another embodiment, the greenhouse panel comprises at least one UV additive that blocks the greenhouse panel from up to 80%, 90% or up to 95% ultraviolet light. In one embodiment, the greenhouse panel has at least one property selected from the group consisting of toughness, transparency, chemical resistance, and Tg. As used herein, "optical media" refers to information storage in which information is recorded by irradiation with a laser beam (eg, light in the visible wavelength region, such as light having a wavelength in the range of 6 〇〇 to 70 〇 nm). media. The irradiation region of the recording layer is locally heated to change its physical or chemical characteristics by irradiation of the laser beam, and pits are formed in the irradiation region of the recording layer. Since the optical characteristics of the formed pits are different from those of the unirradiated areas, the digital information can be optically recorded. The recorded information can be obtained by a reproduction program, which generally includes the steps of: illuminating the recording layer with a laser beam having the same wavelength as the wavelength used for the recorded program; and detecting the pit and its outer periphery The difference in light reflection between the two. ^ In one embodiment, the optical medium comprises a transparent disk having a spiral pre-groove; a recording dye layer disposed in the pre-groove, on which The information is recorded by laser beam illumination; and a light reflecting layer. The optical medium can be recorded by the consumer as appropriate. In one embodiment, the optical medium is selected from the group consisting of compact disc (CD) and digital video disc (DVD). It may be sold as pre-recorded information or sold as a recordable disc. 122661.doc -116- 200819496 In one embodiment, at least one of the following comprises a polyester of the invention: a substrate, at least one protective layer of optical media, and optics Recording layer of the media. In one embodiment, the optical medium has at least one property selected from the group consisting of toughness, transparency, chemical resistance, and hydrolytic stability. As used herein, "Glass laminate" means at least one coating on the glass' wherein at least one of the coatings comprises polyester. The coating can be a film or a sheet. The glass can be transparent 'colored or reflective. In one embodiment, the laminate is permanently bonded to the glass, for example by applying a laminate under heat and pressure to form a single solid laminated glass product. One or both sides of the glass can be laminated. In certain embodiments, the glass laminate comprises more than one layer of a coating comprising the composition of the present invention. In other embodiments, the glass laminate comprises a plurality of glass substrates and more than one coating comprising the composition of the present invention. Exemplary glass laminates include windows (eg, high-rise buildings, windows of building entrances); safety glass for transportation applications (eg, cars, buses, jets, armored vehicles), windshields; bulletproof glass, safety glass (eg for Bank); anti-hurricane glass; aircraft cockpit cover, mirror, solar glass panel, flat panel display and explosion-proof windows. The glass laminate is transparent and can be matte, engraved or patterned. In one embodiment, the glass laminate can withstand temperatures in the range of -1 to 12 Torr. In another embodiment, as disclosed herein, it can be made by adding, for example, at least one UV additive. The glass laminate has UV resistance. The method of laminating the film and/or sheet of the present invention to glass is well known to those skilled in the art and can be laminated by vacuum lamination without the need for 122661.doc-117 - 200819496 The use of an adhesive layer. In order to obtain an effective bond between the glass layer and the laminate, in one embodiment, the glass has a low surface roughness. Alternatively, a double-sided tape, an adhesive layer or a gelatin layer can be used (by coating For example, a hot melt, a pressure sensitive adhesive or a heat sensitive adhesive or a UV or electron beam curable adhesive is used to bond the laminate of the present invention to glass. The adhesive layer can be applied to glass sheets, laminates or Both, and may be protected by a release layer, which may be removed prior to lamination. In one embodiment, the glass laminate has at least one selected from the group consisting of toughness, clarity, chemical resistance, hydrolytic stability, and Tg2 characteristics. this For the purposes of this specification, the term "wt" means, by weight. The following examples further illustrate how to prepare and evaluate the polyester of the present invention, and are intended to be merely illustrative of the invention and are not intended to limit the scope thereof unless otherwise stated. 'Other parts are parts by weight, temperature is in degrees Celsius or room temperature, and the pressure is at or near atmospheric. Examples The following examples generally illustrate how to prepare the copolymers of the present invention and based on 2, 2, 4, 4 - 2,2,4,4-tetramethyl-1,3-cyclobutanediol, 1,4-cyclohexane compared to other copolyesters of tetramethyl-1,3-cyclobutanediol The effect of dimethanol and ethylene glycol on various copolyester properties such as glass transition temperature, Izod notched impact strength, and flexural modulus. Further, based on the following examples, those skilled in the art will understand how to use certain Catalyst system and heat stabilizer to prepare the polyester of the invention. Measurement method The inherent viscosity of the polyester is at 25 ° C, at a concentration of 0.5 g / l 122 丨 122 122661.doc -118- 200819496 60/ Measured in 40 (by weight) phenol/tetrachloroethane and reported in units of dL/g Unless otherwise stated, the glass transition temperature (Tg) is based on Thermal.

Analyst Instrument 之 ΤΑ DSC 2920儀器、以20°C/min 之掃描速率根據ASTMD3418來測定。二醇含量及組合物之順/反比率係藉由質子核磁共振 (NMR)光譜法來測定。對於聚合物而言，使用氣仿-三氟乙酸（70-30體積/體積），或對於寡聚物樣本而言使用添加有氘化氣仿以供固定之60/40(重量比）酚/四氯乙烷，將所有 NMR光譜記錄於JEOL Eclipse Plus 600MHz核磁共振光譜儀上。藉由比較2,2,4,4-四甲基-1，3-環丁二醇之典型單苯甲酸酯與二苯甲酸酯對2,2,4,4-四甲基-1，3-環丁二醇之共振峰進行分配。該等典型化合物與聚合物及寡聚物中所見之共振位置非常接近。除非另有說明，否則將聚合物於80°C乾燥劑乾燥器中乾燥隔夜，之後於Boy 22S模製機中射出成形為1/8x1/2x5 4 之撓曲棒。將該等棒切割為2.5吋之長度且經10密耳之缺口開出％吋寬度之缺口。伊佐德氏衝擊強度係根據ASTM D256經測定為5個樣本之量測值的平均值。撓曲模數係根據ASTMD790之程序來測定。本文所報導之色值為遵照ASTM D 6290-98及ASTM E308-99，使用具有以下參數之Hunter Lab Ultrascan XE分光光度計（Hunter Associates Laboratory Inc·，Reston，VA) 之量測法所量測之CIELAB L*、a*及b*值：（1)D65光源； 122661.doc -119- 200819496 (2)10度觀測者；（3)包括有鏡面角之及身〈夂射杈式；（4)大面積視域；（5)1 ”孔徑。除非另有說明，否货則對經研磨可通過6 mm篩之聚合物顆粒進行量測。根據astm 〇_1〇〇3量測 4χ4χ1/8π之混濁度。以下實例中錫（Sn)及鈦（Ti)之量係以金屬之每百萬份之份數（PPm)來報導且藉由X射線螢光法，使用pANanaiyticai Axios Advanced波長色散X射線螢光分光計來量測。磷含量類似地以磷元素之ppm報導，且亦藉由xrf使用相同儀器 ί 來量測。以下實例中之"Ρ量測值"行中所報導之數值係如上文所述藉由量測磷而獲得。除非另有說明，否則以下實例中所用之丨，4-環己烷二甲醇之順/反比率約為30/70，且可在35/65至25/75之範圍内變化。除非另有說明，否則以下實例中所用之2,2,4,4-四甲基-1,3-環丁二醇之順/反比率約為50/50且可在45/55至 55/45之範圍内變化。以下縮略語適用於所有工作實例： CHDM Μ-環己烷二曱醇 DBTO 二丁基氧化錫 DMT 對苯二甲酸二甲酯 DEG 二乙二醇 DMTO 二曱基氧化錫 EG 乙二醇 IV 固有黏度 _ Tg 玻璃轉移溫度 122661.doc -120- 200819496 TIIP 異丙醇鈦 TMCD 2,2,4,4-四甲基·1，3-環丁二醇 TPA 對苯二甲酸 TPP 磷酸三苯酯實例1 此實例說明包含對苯二甲酸二甲酯（DMT)、1，4-環己烷二曱醇（CHDM)、2,2,4,4-四甲基-1，3-環丁二醇（TMCD)及乙二醇（EG)之聚酯之製備。 DMT 購自 Cape Industries，CHDM(最小 98 %)、EG 及 TMCD(最小 98 %)購自 Eastman Chemical Company 〇錫化合物為二丁基氧化錫（IV)(Fascat 4201 ;購自Aldrich)。鈦化合物為異丙醇鈦（IV)(Aldrich)。磷化合物為磷酸三苯酯 (TPP，購自 Aldrich(98 %)或 FERRO, Corp)。除非下文另有說明，否則首先添加磷源，剩餘為聚酯試劑。CHDM及 TMCD之順/反比率係如上所述。Analyst Instrument ΤΑ DSC 2920 instrument, measured at a scan rate of 20 ° C/min according to ASTM D3418. The diol content and the cis/inverse ratio of the composition are determined by proton nuclear magnetic resonance (NMR) spectroscopy. For the polymer, use gas-trifluoroacetic acid (70-30 vol/vol), or for the oligo sample, use hydrazine gas to add 60/40 (by weight) phenol/ Tetrachloroethane, all NMR spectra were recorded on a JEOL Eclipse Plus 600 MHz NMR spectrometer. By comparing typical monobenzoic acid esters of 2,2,4,4-tetramethyl-1,3-cyclobutanediol with dibenzoate to 2,2,4,4-tetramethyl-1 , the resonance peak of 3-cyclobutanediol was distributed. These typical compounds are very close to the resonance sites seen in polymers and oligomers. Unless otherwise stated, the polymer was dried overnight in a desiccant dryer at 80 ° C, after which a flex bar formed at 1/8 x 1/2 x 5 4 was shot out in a Boy 22S molding machine. The rods were cut to a length of 2.5 inches and a gap of % 吋 width was opened through a 10 mil gap. The Izod impact strength is an average of the measured values of 5 samples determined according to ASTM D256. The flexural modulus is determined according to the procedure of ASTM D790. The color values reported herein were measured according to ASTM D 6290-98 and ASTM E308-99 using a Hunter Lab Ultrascan XE spectrophotometer (Hunter Associates Laboratory Inc., Reston, VA) having the following parameters. CIELAB L*, a*, and b* values: (1) D65 light source; 122661.doc -119- 200819496 (2) 10 degree observer; (3) including mirrored angle and body 夂夂杈; (4 Large area of view; (5) 1" aperture. Unless otherwise stated, the product is measured by polymer particles that can be ground through a 6 mm sieve. Measured by astm 〇_1〇〇3 4χ4χ1/8π Turbidity. The amount of tin (Sn) and titanium (Ti) in the following examples is reported in parts per million (ppm) of metal and by X-ray fluorescence, using pANanaiyticai Axios Advanced wavelength dispersion X Measured by a ray fluorescence spectrometer. The phosphorus content is similarly reported in ppm of phosphorus and is also measured by xrf using the same instrument ί. The "Ρ measured value" The values are obtained by measuring phosphorus as described above. Unless otherwise stated, the following examples are used. The cis/trans ratio of 丨, 4-cyclohexanedimethanol is about 30/70, and can vary from 35/65 to 25/75. Unless otherwise stated, 2, 2 used in the following examples, The cis/trans ratio of 4,4-tetramethyl-1,3-cyclobutanediol is about 50/50 and can vary from 45/55 to 55/45. The following abbreviations apply to all working examples: CHDM Μ-cyclohexane didecyl alcohol DBTO dibutyl tin oxide DMT dimethyl terephthalate DEG diethylene glycol DMTO didecyl oxytin EG ethylene glycol IV intrinsic viscosity _ Tg glass transfer temperature 122661.doc - 120- 200819496 TIIP Titanium isopropoxide TMCD 2,2,4,4-Tetramethyl·1,3-cyclobutanediol TPA Terephthalic acid TPP Triphenyl phosphate Example 1 This example illustrates the inclusion of terephthalic acid Methyl ester (DMT), 1,4-cyclohexanedimethanol (CHDM), 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) and ethylene glycol (EG) Preparation of polyester. DMT was purchased from Cape Industries, CHDM (minimum 98%), EG and TMCD (minimum 98%) were purchased from Eastman Chemical Company. The antimony tin compound was dibutyltin oxide (IV) (Fascat 4201; purchased from Aldrich). The titanium compound was titanium (IV) isopropoxide (Aldrich). The phosphorus compound was triphenyl phosphate (TPP, available from Aldrich (98%) or FERRO, Corp). Unless otherwise stated below, a phosphorus source is first added, with the remainder being a polyester reagent. The cis/inverse ratios of CHDM and TMCD are as described above.

實例1A 此實例說明以如下目標組成製備共聚酯：100莫耳％之對苯二甲酸二曱酯殘基、30莫耳％之2,2,4,4-四甲基-1，3-環丁二醇殘基及30莫耳％之1，4_環己烷二曱醇殘基且剩餘為乙二醇殘基。將99.71 g對苯二甲酸二甲酯、21.63 g 1，4-環己烷二甲醇、37.86 g 2,2,4,4-四甲基-1，3-環丁二醇及 20.95 g乙二醇之混合物置於裝配有氮氣入口、金屬攪:拌器及短蒸餾管柱之500毫升燒瓶中。此外，將0.0077 g二丁基氧化錫（IV)、 122661.doc -121 · 200819496 0.0218 g異丙醇鈦（ιν)及0.50 g鱗酸三苯酯添加至500毫升燒瓶中。將燒舰置於已加熱至200°C之Wood金屬浴中。實驗開始時，將攪拌速度設定為200 RPM。將燒瓶内含物於 200°C下加熱60分鐘，且接著經5分鐘將溫度逐漸升至 210°C。使反應混合物於210°C下保持60分鐘，且接著於9〇分鐘内加熱至275°C。一旦達到275°C，即在接下來之10分鐘内以1 00 mm Hg之設定點逐漸施加真空，且亦將攪拌速度減低至100 RPM。在接下來之5分鐘内，將燒瓶内之壓力進一步減低至0·3 mm Hg之設定點，且將攪拌速度減低至50 RPM。將此壓力維持220分鐘之總時間以移除過量未反應之二元醇。此方法產生具有1〇7。(3之玻璃轉移溫度及〇·67 dl/g之固有黏度的高熔體黏度、透明可視及無色至極為微黃色之聚合物。NMR分析表明，共聚酯由3〇莫耳。/〇之 1，4_環己烷二甲醇殘基、30莫耳〇/〇之2,2,4,4_四甲基心义環丁二醇殘基及40莫耳％之乙二醇殘基組成。Example 1A This example illustrates the preparation of a copolyester with a target composition of 100 mol% of dinonyl terephthalate residue, 30 mol% of 2,2,4,4-tetramethyl-1,3- The cyclobutanediol residue and 30 mol% of the 1,4-cyclohexanedimethanol residue and the remainder are ethylene glycol residues. 99.71 g of dimethyl terephthalate, 21.63 g of 1,4-cyclohexanedimethanol, 37.86 g of 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 20.95 g of ethylene The mixture of alcohols was placed in a 500 ml flask equipped with a nitrogen inlet, a metal stirrer and a short distillation column. Further, 0.0077 g of dibutyltin oxide (IV), 122661.doc -121 · 200819496 0.0218 g of titanium isopropoxide (ιν), and 0.50 g of triphenyl phthalate were added to a 500 ml flask. The burning vessel was placed in a Wood metal bath that had been heated to 200 °C. At the beginning of the experiment, set the agitation speed to 200 RPM. The contents of the flask were heated at 200 ° C for 60 minutes, and then the temperature was gradually increased to 210 ° C over 5 minutes. The reaction mixture was maintained at 210 ° C for 60 minutes and then heated to 275 ° C over 9 minutes. Once 275 ° C is reached, the vacuum is gradually applied at a set point of 100 mm Hg for the next 10 minutes and the agitation speed is also reduced to 100 RPM. During the next 5 minutes, the pressure in the flask was further reduced to a set point of 0. 3 mm Hg and the agitation speed was reduced to 50 RPM. This pressure was maintained for a total time of 220 minutes to remove excess unreacted glycol. This method produces 1〇7. (3) Glass transition temperature and high melt viscosity of intrinsic viscosity of 67·67 dl/g, transparent visible and colorless to extremely yellowish polymer. NMR analysis showed that the copolyester consisted of 3 〇mol. 1,4_cyclohexane dimethanol residue, 30 moles/〇 2,2,4,4_tetramethylxincyclobutanediol residue and 40 mol% of ethylene glycol residue .

實例1B至實例1K 如上所述由100莫耳〇/〇之對苯二甲酸二甲酯製備多種聚酯。然而，如表1所示將不同量之磷酸三苯酯添加至初始反應混合物中。此實例之實驗中之TMCD及CHDM的莫耳 °/〇亦報導於表1中，剩餘物二醇為EG。二醇/酸比率為 1.5/1，二醇饋料具有2〇莫耳％之CHDM、35莫耳％2Tmcd 及45莫耳％之EG。藉由Camile方法控制系統便於設定點及數據之收集。一旦反應物熔融，即起始攪拌且緩慢增加攪拌速度。使用下 122661.doc •122- 200819496 文所示之Camile次序製備該等共聚酯。實例1B至實例1K之Camile次序階段… 時間(分鐘） &顧磁、> 攪拌(RPM) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 5 275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 在階段10中，若黏度過高，則將攪拌速率降至25 rpm且甚至降至10 rpm。實例G及Η之階段10中之保持時間為130 分鐘。 122661.doc -123 - 200819496 r\ 制？|杷111^染<03,噠瑞》餵鉍》1革駟 122661.doc — m rn r-H 00 a! vd 00 r-H ir! % cn r-H 1 卜 cn rji S r-H 1 P； 1 1 r-H 1 79.51 77.69 77.57 78.02 78.29 〇\ ημ〇〇 'S^ 106.5 117.7 118.2 117.2 115.3 109.9 112.6 112.4 P量測值 (ppm) 165.8 v〇〇 in 121.8 P理論值 (ppm) o T-H ON <N r-H VO (N CN 1—^ CN r—H Q： H w 0.500 0.024 0.075 0.125 0.150 0.303 0.200 0.200 5 ^ 6 ^ m m m (N cn m (N m Z B ^ §： H v〇 m Pi cn m S DEG1 mol% ^sO d 寸 ο ▼—H 寸 o (N d r- d m 〇寸 o CHDM mol% d m 卜 00 (Ν a； (N a cK (N o m vo 00 (N VO OO (N iT) cn TMCD mol% 00 cK (N cn 00 m m P： m r—1 in m o — (N m OO cn cn 0.670 0.953 0.792 0.774 0.751 0.691 0.647 0.688 C PQ 〇 Q W [Xi 〇 ffi -124- 200819496 實例2 八^實例使用錫催化劑與鈦催化劑之組合，說明熱穩定劑含量對於具有如下目標組成之共聚g|之聚合物色彩及固有黏度之影響·· 1GG莫耳％對苯二甲酸二甲S旨殘基、3〇莫耳％ 2,2,4,4四甲基_!，3_環丁二醇殘基、3〇莫耳。^，心環己烧二曱醇殘基及40莫耳％乙二醇殘基。除非另有說明，否則單體、催化劑及熱穩定劑之來源與實例丨相同。Examples 1B to 1K A variety of polyesters were prepared from 100 moles of dimethyl phthalate/terephthalate as described above. However, different amounts of triphenyl phosphate were added to the initial reaction mixture as shown in Table 1. The MOCD/〇 of TMCD and CHDM in the experiments of this example are also reported in Table 1, and the residual diol is EG. The diol/acid ratio was 1.5/1 and the diol feed had 2 〇 mol % CHDM, 35 mol % 2 Tmcd and 45 mol % EG. The Camile method controls the system for easy collection of points and data. Once the reactants melt, the agitation is initiated and the agitation speed is slowly increased. The copolyesters were prepared using the Camile sequence as shown in 122661.doc • 122-200819496. The Camile sequence phase of Example 1B to Example 1K... Time (minutes) & Magnetic, > Stirring (RPM) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 5 275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 In stage 10, if the viscosity is too high, the agitation rate is reduced to 25 rpm and even to 10 rpm. The hold time in stage 10 of Example G and Η is 130 minutes. 122661.doc -123 - 200819496 r\ System? |杷111^染<03,哒瑞》铋铋》1革驷122661.doc — m rn rH 00 a! vd 00 rH ir! % cn rH 1 卜 rji S rH 1 P; 1 1 rH 1 79.51 77.69 77.57 78.02 78.29 〇\ ημ〇〇'S^ 106.5 117.7 118.2 117.2 115.3 109.9 112.6 112.4 P measurement (ppm) 165.8 v〇〇in 121.8 P theoretical value (ppm) o TH ON <N rH VO (N CN 1 —^ CN r—HQ: H w 0.500 0.024 0.075 0.125 0.150 0.303 0.200 0.200 5 ^ 6 ^ mmm (N cn m (N m ZB ^ §: H v〇m Pi cn m S DEG1 mol% ^sO d inch ο ▼ —H 寸 o (N d r- dm 〇 o CHDM mol% dm 卜 (Ν a; (N a cK (N om vo 00 (N VO OO (N iT) cn TMCD mol% 00 cK (N cn 00 Mm P: mr—1 in mo — (N m OO cn cn 0.670 0.953 0.792 0.774 0.751 0.691 0.647 0.688 C PQ 〇QW [Xi 〇ffi -124- 200819496 Example 2 VIII Example using a combination of a tin catalyst and a titanium catalyst, Effect of heat stabilizer content on the color and intrinsic viscosity of the polymer of copolymerization g| with the following target composition······················ 2,2,4,4 tetramethyl _!, 3_cyclobutanediol residue, 3 〇mol. ^, heart-ring hexanol residue and 40 mol% ethylene glycol residue. Otherwise stated, otherwise the source of the monomer, catalyst and heat stabilizer is the same as the example.

實例2A 將99·71 g對苯二甲酸二甲酯、21.63 g 1，4-環己烷二甲醇 37.86 g 2,2,4,4-四甲基·ι，3-環丁二醇及 2〇·95 g 乙二醇之此a物置於裝配有氮氣入口、金屬攪拌器及短蒸餾管柱之500毫升燒瓶中。此外，將〇〇〇77 g二丁基氧化錫（ιν)及 0.0218 g異丙醇鈦（Iv)添加至5〇〇毫升燒瓶中。將燒瓶置於已加熱至200°C之Wood金屬浴中。實驗開始時，將攪拌速度設定為200 RPM。將燒瓶内含物於200°C下加熱60分鐘，且接著經5分鐘將溫度逐漸升至21(rc。使反應混合物於 210 C下保持60分鐘，且接著於9〇分鐘内加熱至275〇c。一旦達到275 C ’即在接下來之10分鐘内以1〇〇 mm Hg之設定點逐漸施加真空，且亦將擾拌速度減低至1〇〇 RPM。在接下來之5分鐘内將燒瓶内之壓力進一步減低至〇.3 mm Hg之设定點’且將攪拌速度減低至5〇 RPM。將此壓力維持22〇分鐘之總時間以移除過量未反應之二元醇。此方法產生具有117.7°C之玻璃轉移溫度及1〇u dL/g之固有黏度的聚合物。NMR分析表明，共聚酯由29莫耳％之匕肛環己烷二甲 122661.doc -125- 200819496 醇殘基、37莫耳％之2,2,4,4-四甲基〇環丁二醇殘基及34 莫耳。/〇之乙二醇殘基組成。儘管超出最初申請之申請專利 fe圍的範鹫，但本文仍包括此實例以表明熱穩定劑含量對色彩及固有黏度之影響。Example 2A 99.71 g of dimethyl terephthalate, 21.63 g of 1,4-cyclohexanedimethanol 37.86 g of 2,2,4,4-tetramethyl·ι,3-cyclobutanediol and 2 a·95 g of ethylene glycol was placed in a 500 ml flask equipped with a nitrogen inlet, a metal stirrer and a short distillation column. Further, g77 g of dibutyltin oxide (ιν) and 0.0218 g of titanium isopropoxide (Iv) were added to a 5 〇〇 ml flask. The flask was placed in a Wood metal bath that had been heated to 200 °C. At the beginning of the experiment, the agitation speed was set to 200 RPM. The contents of the flask were heated at 200 ° C for 60 minutes and then gradually increased to 21 (rc) over 5 minutes. The reaction mixture was held at 210 C for 60 minutes and then heated to 275 Torr in 9 minutes. c. Once 275 C ' is reached, the vacuum is gradually applied at the set point of 1 〇〇 mm Hg for the next 10 minutes, and the scavenging speed is also reduced to 1 〇〇 RPM. The flask is placed for the next 5 minutes. The pressure inside is further reduced to a set point of 〇.3 mm Hg' and the agitation speed is reduced to 5 〇 RPM. This pressure is maintained for a total time of 22 〇 minutes to remove excess unreacted glycol. A polymer having a glass transition temperature of 117.7 ° C and an intrinsic viscosity of 1 〇 u dL / g. NMR analysis showed that the copolyester consisted of 29 mol% of anal cyclohexane dimethyl 122661.doc -125- 200819496 alcohol Residue, 37 mole % of 2,2,4,4-tetramethylguanidinium diol residue and 34 moles of ethylene glycol residue. Although the patent application exceeds the original application Fan Wei, but this article still includes this example to show the effect of heat stabilizer content on color and intrinsic viscosity.

實例2B至實例2E 如上所述由100莫耳％之對苯二甲酸二甲酯製備多種聚酉曰。然而，如表2所示將不同量之磷酸三苯酯添加至初始反應混合物中。此實例之實驗之TMCD及CHDM的莫耳％〇亦報導於表2中，剩餘物二醇為EG。二醇/酸比率為K5/1，其中二醇饋料具有20莫耳％之CHDM、35莫耳％之TMCD及 45莫耳％iEG。藉由Camile方法控制系統便於設定點及數據之收集。一旦反應物熔融，即起始攪拌且緩慢增加攪拌速度。使用下文所示之Camile次序製備該等共聚酯。實例2B至實例2E之Camile次序 •階段厂 \ 1 0.5 200 730 ^ V v , 0 2 4.5 200 730 200 3 — 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 r 5 卜275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 在階段10中，若黏度過高，則將攪拌速率降至25 rpm且甚至降至10 rpm。 122661.doc -126- 200819496 麴礆w^杷tae染w is鉍咪葙¥^嘗 00 (N r-H <N (N v〇 — % r-H o H 1 f—H 1 1 (N (N ^H 1 70.76 76.18 73.43 77.73 78.51 HM〇〇 117.7 115.9 117.5 113.1 109.3 P量測值 (PPm) (N OO (N 卜 00 152.2 P理論值 (PPm) 〇 v〇 00 T-H o cn 0.000 0.052 0.100 0.205 0.396 Μ m m m cn cn 1ρ cn cn m m DEG1 mol% 寸 ο 〇 i—H d 00 O CHDM mol% (N α； (N (N CN cK (N m od (N (N <N TMCD mol% r-H P； in ΓΛ (N m in od cn (N m >? 3 1.011 0.913 0·777 0.744 0.722 < U Q -127- οωα W噠狯茫浞踩鹄^命齡· ϊ 122661.doc 200819496 實例3 此實例說明催化劑選擇及熱穩定劑之量對於具有如下目才示組成之共聚酯之最終色彩及固有黏度之影響·· 1 〇〇莫耳 %之對苯二曱酸二甲酯殘基、30莫耳％之2,2,4,肛四曱基_ 1，3-裱丁二醇殘基、3〇莫耳％之丨，4•環己烷二甲醇殘基及4〇莫耳％之乙二醇殘基。將99.71 g對苯二甲酸二甲酯、2163 g i，扣環己烷二甲醇、37.86 g 2,2,4,4-四甲基 _1，3_環丁二醇及20·95 g乙二醇之混合物置於裝配有氮氣入口、金屬攪拌器及短蒸餾管柱之500耄升燒瓶中。將各種量之二丁基氧化錫、異丙醇鈦（IV)及磷酸三苯酯添加至5〇〇毫升燒瓶中。將燒瓶置於已加熱至200°C之Wood金屬浴中。實驗開始時，將攪拌速度没疋為200 RPM。將燒瓶内含物於2〇〇°c下加熱60分鐘，且接著經5分鐘將溫度逐漸升至21(rc。使反應混合物於210°C下保持60分鐘，且接著於9〇分鐘内加熱至275〇c。旦達到275 C ’即在接下來之1〇分鐘内以1〇〇 mni Hg之設定點逐漸施加真空，且亦將攪拌速度減低至1〇〇 rPM。在接下來之5分鐘内將燒瓶内之壓力進一步減低至〇.3 mm Hg 之設定點，且將攪拌速度減低至5〇 RpM。將此壓力維持 220为鐘之總時間以移除過量未反應之二元醇。所有樣本均係藉由相同方法，使用表3中所報導之催化劑及磷酸三苯知含$而製備。該等共聚酯之最終TMCD& chdm莫耳 %亦報導於表3中，剩餘二元醇為EG。表3中展示催化劑系統及熱穩定劑對於2,2,4,4-四甲基-i，3_環丁二醇之併入、 122661.doc -128- 200819496 共聚酯色彩及固有黏度之影響。下表3中之實例G、η及I分別對應於實例2A、實例2D及實例1A且包括於表3中以便於使用不同催化劑系統及不同碟含量所製備之聚酯之間的比較0 表3 催化劑及磷酸三苯酯含量對TMCD併入、色彩及固有黏度之影響實例 THP(g)/ ppm Ti DBTO(g)/ ppm Sn TPP (g) 共聚酯中之 TMCD (莫耳％) 共聚酯中之 CHDM (莫耳％) b* IV (dL/g) A 0 0.0154/60 ppm 0.00 40.0 29.1 15.1 0.78 B 0 0.0154/ 60 ppm 0.20 28.5 31.2 2.6 0.18 C 0 0.0154/ 60 ppm 0.50 24.1 30.7 3.7 0.17 D 0.042/ 60 ppm 0 0.00 28.7 29.4 21.1 0.91 E 0.042/ 60 ppm 0 0.20 27.7 31.0 11.1 0.78 F 0.042/ 60 ppm 0 0.50 25.5 31.0 10.6 0.56 G 0.021/ 30 ppm 0.077/ 30 ppm 0.00 37.1 29.2 18.0 1.01 Η 0.021/ 30 ppm 0.077/ 30 ppm 0.21 38.5 28.3 6.2 0.74 I 0.021/ 30 ppm 0.077/ 30 ppm 0.50 29.8 30.1 4.9 0.67 儘管超出最初申請之申請專利範圍的範疇，但本文仍包括實例A、D及G以表明催化劑系統及熱穩定劑對TMCD併入、色彩及固有黏度之影響。實例4 此實例說明包含對苯二甲酸二曱酯（DMT)、2,2,4,4-四甲基-1，3·環丁二醇（TMCD)及乙二醇（EG)之聚酯之製備。除非另有說明，否則單體、催化劑及熱穩定劑之來源與實例1相同。各種聚酯係利用以下程序、由1〇〇莫耳％之對苯二甲酸二甲酯而製備。將99.71 g對苯二甲酸二甲酯、 34.07 g 2,2,4,4-四甲基-l，3-環丁二醇及31.89 g乙二醇之混 122661.doc -129- 200819496 合物置於裝配有氮氣入口、金屬攪拌器及短蒸餾管柱之 5⑽毫升燒瓶中。此外，將0·0069 g二丁基氧化錫（ιν)及 0·〇19 g異丙醇鈦（IV)添加至5〇〇毫升燒瓶中。將燒瓶置於已加熱至20(TC之Wood金屬浴中。實驗開始時，將攪拌速度設定為200 RPM。將燒瓶内含物於2〇(TC下加熱6〇分鐘，且接著經5分鐘將温度逐漸升至21(rc。使反應混合物於 21〇°C下保持60分鐘，且接著在9〇分鐘内加熱至275^。一旦達到275 C，即在接下來之1〇分鐘内以1〇〇 mm Hg之設定點逐漸施加真空，且亦將攪拌速度減低至1〇〇 RPM。在接下來之5分鐘内將燒瓶内之壓力進一步減低至〇·3 mm Hg之設定點，且將攪拌速度減低至50 RPM。將此壓力維持220 为鐘之總時間以移除過量未反應之二元醇。使用此方法，採用表4中所報導之磷酸三苯酯之量來製備共聚酯。將磷源添加至反應混合物中，同時添加催化劑。此實例之實驗中之TMCD的莫耳％亦報導於表4中，剩餘二醇為EG。二醇/酸比率為1.5/1，二醇饋料中32 mol% 為TMCD且剩餘為EG。藉由Camile方法控制系統便於設定點及數據之收集。一旦反應物熔融，即起始攪拌且緩慢增加攪拌速度。用於製備此實例之共聚酯之Camile次序 122661.doc -130- 200819496 .階段· 時間(分鐘）攪拌(RPM) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 5 275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 在階段10中，若黏度過高，則將攪拌速率降至25 rpm且甚至降至10 rpm。 122661.doc 131 - 200819496 制礤杷tue染w ,噠凜w餵龄》寸¥駟Examples 2B to 2E A variety of polyfluorenes were prepared from 100 mol% of dimethyl terephthalate as described above. However, different amounts of triphenyl phosphate were added to the initial reaction mixture as shown in Table 2. The TMCD of this example and the mole % of CHDM are also reported in Table 2, and the residual diol is EG. The diol/acid ratio was K5/1 with the diol feed having 20 mole % CHDM, 35 mole % TMCD and 45 mole % iEG. The Camile method controls the system for easy collection of points and data. Once the reactants melt, the agitation is initiated and the agitation speed is slowly increased. The copolyesters were prepared using the Camile sequence shown below. Camile sequence of Example 2B to Example 2E • Stage plant \ 1 0.5 200 730 ^ V v , 0 2 4.5 200 730 200 3 — 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 r 5 Bu 275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 In stage 10, if the viscosity is too high, the stirring rate is reduced to 25 rpm and even to 10 rpm. 122661.doc -126- 200819496 麴礆w^杷tae dye w is铋咪葙¥^try00 (N rH <N (N v〇- % rH o H 1 f-H 1 1 (N (N ^H 1 70.76 76.18 73.43 77.73 78.51 HM〇〇117.7 115.9 117.5 113.1 109.3 P measured value (PPm) (N OO (N 00 152.2 P theoretical value (PPm) 〇v〇00 TH o cn 0.000 0.052 0.100 0.205 0.396 Μ mmm cn Cn 1ρ cn cn mm DEG1 mol% 寸ο 〇i—H d 00 O CHDM mol% (N α; (N (N CN cK (N m od (N (N < N TM CD mol% rH P; in ΓΛ ( N m in od cn (N m >? 3 1.011 0.913 0·777 0.744 0.722 < UQ -127- οωα W哒狯茫浞His 鹄^命龄· ϊ 122661.doc 200819496 Example 3 This example illustrates the catalyst selection and The effect of the amount of heat stabilizer on the final color and intrinsic viscosity of the copolyester having the following composition: · 1% by mole of dimethyl terephthalate residue, 30% by mole , 2, 4, anal tetradecyl _ 1,3-butanediol residue, 3 〇 mol% 丨, 4 • cyclohexane dimethanol residue and 4 〇 mol% of ethylene glycol residues 99.71 g of dimethyl terephthalate, 2163 gi, a mixture of cyclohexanedimethanol, 37.86 g of 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 20.95 g of ethylene glycol was placed in a nitrogen inlet, a metal stirrer and Short distillation column in a 500 liter flask. Various amounts of dibutyltin oxide, titanium (IV) isopropoxide and triphenyl phosphate were added to a 5 cc flask. The flask was placed in a heated to 200 liters. In a Wood metal bath at °C. At the beginning of the experiment, the stirring speed was not changed to 200 RPM. The contents of the flask were heated at 2 ° C for 60 minutes, and then the temperature was gradually increased to 21 (rc) over 5 minutes. The reaction mixture was held at 210 ° C for 60 minutes and then heated to 275 ° C in 9 minutes. Once it reached 275 C ', it was gradually set at 1 〇〇mni Hg in the next 1 minute. A vacuum was applied and the agitation speed was also reduced to 1 〇〇 rPM. The pressure in the flask was further reduced to a set point of 〇.3 mm Hg over the next 5 minutes and the agitation speed was reduced to 5 〇 RpM. This pressure was maintained at 220 for the total time of the clock to remove excess unreacted glycol. All samples were prepared by the same method using the catalysts reported in Table 3 and triphenyl phosphate. The final TMCD & chdm mole % of these copolyesters is also reported in Table 3, with the remaining glycol being EG. Table 3 shows the incorporation of the catalyst system and heat stabilizer for 2,2,4,4-tetramethyl-i,3-cyclobutanediol, and the color and inherent viscosity of the co-ester of 122661.doc-128-200819496. influences. Examples G, η, and I in Table 3 below correspond to Example 2A, Example 2D, and Example 1A, respectively, and are included in Table 3 to facilitate comparison between polyesters prepared using different catalyst systems and different dish contents. Table 3 Effect of catalyst and triphenyl phosphate content on TMCD incorporation, color and intrinsic viscosity Example THP(g)/ppm Ti DBTO(g)/ppm Sn TPP (g) TMCD (mol%) copolymerization in copolyester CHDM in the ester (% by mole) b* IV (dL/g) A 0 0.0154/60 ppm 0.00 40.0 29.1 15.1 0.78 B 0 0.0154/ 60 ppm 0.20 28.5 31.2 2.6 0.18 C 0 0.0154/ 60 ppm 0.50 24.1 30.7 3.7 0.17 D 0.042/ 60 ppm 0 0.00 28.7 29.4 21.1 0.91 E 0.042/ 60 ppm 0 0.20 27.7 31.0 11.1 0.78 F 0.042/ 60 ppm 0 0.50 25.5 31.0 10.6 0.56 G 0.021/ 30 ppm 0.077/ 30 ppm 0.00 37.1 29.2 18.0 1.01 Η 0.021/ 30 ppm 0.077/ 30 ppm 0.21 38.5 28.3 6.2 0.74 I 0.021/ 30 ppm 0.077/ 30 ppm 0.50 29.8 30.1 4.9 0.67 Despite the scope of the original patent application, examples A, D and G are included to indicate the catalyst system. And heat stabilizer for TMCD incorporation, color and inherent viscosity ring. Example 4 This example illustrates a polyester comprising dinonyl terephthalate (DMT), 2,2,4,4-tetramethyl-1,3·cyclobutanediol (TMCD) and ethylene glycol (EG). Preparation. The source of the monomer, catalyst and heat stabilizer was the same as in Example 1 unless otherwise stated. Each of the polyesters was prepared by the following procedure using 1% by mole of dimethyl terephthalate. Mixing 99.71 g of dimethyl terephthalate, 34.07 g of 2,2,4,4-tetramethyl-l,3-cyclobutanediol and 31.89 g of ethylene glycol 122661.doc -129-200819496 It was placed in a 5 (10) ml flask equipped with a nitrogen inlet, a metal stirrer and a short distillation column. Further, 0·0069 g of dibutyltin oxide (ιν) and 0·〇19 g of titanium (IV) isopropoxide were added to a 5 ml flask. The flask was placed in a Wood metal bath heated to 20 (TC). At the beginning of the experiment, the stirring speed was set to 200 RPM. The contents of the flask were heated at 2 Torr for 6 minutes, and then for 5 minutes. The temperature gradually rose to 21 (rc. The reaction mixture was held at 21 ° C for 60 minutes and then heated to 275 ° in 9 minutes. Once it reached 275 C, it was 1 接下来 in the next 1 minute. The vacuum is gradually applied to the set point of 〇mm Hg, and the stirring speed is also reduced to 1〇〇RPM. The pressure in the flask is further reduced to the set point of 〇·3 mm Hg in the next 5 minutes, and the stirring speed is set. Reduce to 50 RPM. Maintain this pressure for a total time of 220 to remove excess unreacted glycol. Using this method, prepare the copolyester using the amount of triphenyl phosphate reported in Table 4. A phosphorus source was added to the reaction mixture while adding a catalyst. The mole % of TMCD in the experiment of this example is also reported in Table 4, the remaining diol is EG. The diol/acid ratio is 1.5/1, the diol feed 32 mol% is TMCD and the remainder is EG. It is easy to set up by Camile method control system. Collection of points and data. Once the reactants are melted, the agitation is initiated and the agitation speed is slowly increased. The Camile sequence used to prepare the copolyesters of this example 122661.doc -130 - 200819496 . Stage · Time (minutes) Stirring (RPM ) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 210 730 200 5 60 210 730 100 6 90 275 730 100 7 5 275 400 50 8 5 275 100 50 9 5 275 0.3 50 10 220 275 0.3 50 In stage 10, if the viscosity is too high, the stirring rate is reduced to 25 rpm and even to 10 rpm. 122661.doc 131 - 200819496 礤杷tue dyeing w, 哒凛w feeding age" inch ¥ 驷

4.28 00 cn 3.94 12.78 8.28 6.32 8.73 5.92 7.01 4.58 % -1.44 VO T—H r-H 1 r-H -1.22 -2.43 -2.02 -1.58 -2.23 r-H r-H 1 -1.86 -1.44 81.04 82.04 77.73 83.3 78.84 77.9 80.56 79.2 79.37 80.83 80.81 Η Ρ 104.3 102.1 101.3 95.0 107.6 103.8 103.8 107.1 105.8 104.9 103.4 P量測值 (PPm) (N (N 00 00 (N P： o P理論值 (PPm)^ r-H m T—( (N 262 430 00 〇 r-H r-H 00 T-H a 00 r-H TPP (Si 0.148 0.248 0.305 0.500 0.023 0.079 0.128 0.050 0.100 0.129 0.220 ppm Sn cn (N m m cn (N m <N m ppm Ti (N (N cn m (N cn m m m m (N m 芝 DEG1 mol% 卜〇卜 ο d 卜 d 寸 o 〇〇 v〇〇 vo 〇· v〇〇卜 ο 反 TMCD mol% 51.3 51.9 52.3 50.6 52.2 50.3 51.2 52.4 51.3 51.4 50.8 TMCD mol% 32.9 32.5 31.4 27.7 34.6 33.5 32.7 34.8 34.3 33.6 32.7 -i 0.622 0.567 0.590 0.438 0.907 0.704 0.701 0.756 0.733 0.631 0.620 < PO 〇 Q pq Ph ϋ ffi HH οωα W^^^SES^龄· i 122661.doc -132- 200819496 實例5 此實例使用锡催化劑與鈦催化劑之組合，說明熱穩定劑 • 、有如下目標組成之共聚S旨之聚合物色彩及固有黏度之影響：100莫耳％之對苯二甲酸二甲酯殘基、33莫耳％之2,2,4,4-四甲基-1，3-環丁二醇殘基及67莫耳〇/〇之乙二醇殘基。除非另有說明，否則單體、催化劑及熱穩定劑之來源與實例1相同。各種聚酯係利用以下程序、由1 〇〇莫耳❻之對苯二甲酸二甲酯而製備。將99.71 g對苯二甲酸二甲酯、 34.07 g 2,2,4,4·四甲基-ΐ，3·環丁二醇及31.89 g乙二醇之混合物置於裝配有氮氣入口、金屬攪拌器及短蒸餾管柱之 5〇〇毫升燒瓶中。此外，將0 0069 g二丁基氧化錫（IV)及 0.019 g異丙醇鈦（IV)添加至5〇〇毫升燒瓶中。將燒瓶置於已加熱至200°C之Wood金屬浴中。實驗開始時，將攪拌速度設定為200 RPM。將燒瓶内含物於200°C下加熱60分鐘，且接著經5分鐘將溫度逐漸升至21 〇°C。使反應混合物於 21〇°C下保持60分鐘，且接著在90分鐘内加熱至275°C。一旦達到275°C，即在接下來之10分鐘内以100 mm Hg之設定點逐漸施加真空，且亦將攪拌速度減低至100 RPM。在接下來之5分鐘内將燒瓶内之壓力進一步減低至0.3 mm Hg之設定點，且將攪拌速度減低至50 RPM。將此壓力維持220 分鐘之總時間以移除過量未反應之二元醇。使用此方法，採用表5中所報導之磷酸三苯酯之量來製備共聚酯。將磷源添加至反應混合物中，同時添加催化 122661.doc -133- 200819496 劑。此實例之實驗中之TMCD的莫耳％亦報導於表5中，剩餘二醇為EG。二醇/酸比率為1.5/1，二醇饋料中32 mol% 為TMCD且剩餘為EG。藉由Camile方法控制系統便於設定點及數據之收集。一旦反應物炼融，即起始攪拌且緩慢增加擾拌速度。用於製備此實例之共聚酯之Camile次序 mm&ms mwmm 真空ί托）攪拌(ϋΡΜ) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 Γ 210 730 200 5 60 210 「730 100 6 90 275 730 1 \J\J 100 7 〇 5 275 400 L \J\J 50 8 5 275 ΙΟΟ 50 9 1 r\ 5 275 0.3 w/ \J ΙΟ 220 275 0.3 *J\J 50 在階段10中，若黏度過高，則將攪拌速率降至25 rpm且甚至降至10 rpm。儘管超出最初申請之申請專利範圍的範命，但本文仍包括實例A以表明熱穩定劑含量對色彩及固有黏度之影響。4.28 00 cn 3.94 12.78 8.28 6.32 8.73 5.92 7.01 4.58 % -1.44 VO T-H rH 1 rH -1.22 -2.43 -2.02 -1.58 -2.23 rH rH 1 -1.86 -1.44 81.04 82.04 77.73 83.3 78.84 77.9 80.56 79.2 79.37 80.83 80.81 Η Ρ 104.3 102.1 101.3 95.0 107.6 103.8 103.8 107.1 105.8 104.9 103.4 P measured value (PPm) (N (N 00 00 (NP: o P theoretical value (PPm) ^ rH m T—( (N 262 430 00 〇rH rH 00 TH a 00 rH TPP (Si 0.148 0.248 0.305 0.500 0.023 0.079 0.128 0.050 0.100 0.129 0.220 ppm Sn cn (N mm cn (N m < N m ppm Ti (N (N cn m (N cn mmmm (N m DE DEG1 mol % 卜〇卜ο d 卜 d inch o 〇〇v〇〇vo 〇· v〇〇卜ο AntiTMCD mol% 51.3 51.9 52.3 50.6 52.2 50.3 51.2 52.4 51.3 51.4 50.8 TMCD mol% 32.9 32.5 31.4 27.7 34.6 33.5 32.7 34.8 34.3 33.6 32.7 -i 0.622 0.567 0.590 0.438 0.907 0.704 0.701 0.756 0.733 0.631 0.620 < PO 〇Q pq Ph ϋ ffi HH οωα W^^^SES^ Age · i 122661.doc -132- 200819496 Example 5 This example uses a tin catalyst and Combination of titanium catalysts, illustrating heat stabilizers • The effect of the color and intrinsic viscosity of the copolymer consisting of the following target composition: 100 mol% of dimethyl terephthalate residue, 33 mol% of 2,2,4,4-tetra The base-1,3-cyclobutanediol residue and the 67 molar/glycol ethylene glycol residue. The monomers, catalysts and heat stabilizers were of the same source as in Example 1 unless otherwise stated. Various polyesters were prepared by the following procedure using dimethyl terephthalate. A mixture of 99.71 g of dimethyl terephthalate, 34.07 g of 2,2,4,4·tetramethyl-indole, 3·cyclobutanediol and 31.89 g of ethylene glycol was placed in a nitrogen inlet and stirred with metal. And a short distillation column in a 5 ml flask. Further, 0 0069 g of dibutyltin oxide (IV) and 0.019 g of titanium (IV) isopropoxide were added to a 5 ml flask. The flask was placed in a Wood metal bath that had been heated to 200 °C. At the beginning of the experiment, the agitation speed was set to 200 RPM. The contents of the flask were heated at 200 ° C for 60 minutes, and then the temperature was gradually increased to 21 ° C over 5 minutes. The reaction mixture was maintained at 21 ° C for 60 minutes and then heated to 275 ° C over 90 minutes. Once 275 ° C is reached, the vacuum is gradually applied at a set point of 100 mm Hg over the next 10 minutes and the agitation speed is also reduced to 100 RPM. The pressure in the flask was further reduced to a set point of 0.3 mm Hg within 5 minutes of the next pass, and the agitation speed was reduced to 50 RPM. This pressure was maintained for a total time of 220 minutes to remove excess unreacted glycol. Using this method, the amount of triphenyl phosphate reported in Table 5 was used to prepare a copolyester. A phosphorus source was added to the reaction mixture while adding the catalyst 122661.doc-133-200819496. The mole % of TMCD in the experiments of this example is also reported in Table 5, with the residual diol being EG. The diol/acid ratio was 1.5/1, and 32 mol% of the diol feed was TMCD with the remainder being EG. The Camile method controls the system for easy collection of points and data. Once the reactants are smelted, the agitation is initiated and the scavenging rate is slowly increased. Camile order mm&ms mwmm vacuum for the preparation of the copolyester of this example) Stirring (ϋΡΜ) 1 0.5 200 730 0 2 4.5 200 730 200 3 60 200 730 200 4 5 Γ 210 730 200 5 60 210 730 100 6 90 275 730 1 \J\J 100 7 〇5 275 400 L \J\J 50 8 5 275 ΙΟΟ 50 9 1 r\ 5 275 0.3 w/ \J ΙΟ 220 275 0.3 *J\J 50 In stage 10 If the viscosity is too high, the stirring rate is reduced to 25 rpm and even to 10 rpm. Although beyond the scope of the original patent application scope, this article still includes Example A to show the heat stabilizer content to color and inherent The effect of viscosity.

C 122661.doc 134- 200819496C 122661.doc 134- 200819496

麴磙w^?t杷画女染w is齡咪叙¥ ♦黎 122661.doc 20.28 (N CO Os ON <N vd r—H 〇\ cn % t—H 1 cn <N t> T-H 1 r—H 1 -1.16 75.61 79.45 80.38 81.65 82.68 Η 'w/ 108.6 107.1 104.2 104.1 100.9 P量測值 (ppm) o (N T-H 00 00 00 VO P理論值 (ppm) o (N r—i. 0.000 0.048 0.107 0.203 0.405 cn cn m in cn m m S 一 §：H cn m (N m m m (N cn DEG1 mol% 寸 o o v〇 o 卜〇卜 d 反 TMCD mol% cn ci m m (N (N (N ^T) ON 窆寸 o in TMCD mol% r-H cn 卜 m ON H 寸· cn IV (dL/g) 0.868 0.777 0.698 0.613 0.588 < o Q -135- ϋ3α w^^tSE琛^^如龄· i 200819496 本發明已參考本文所揭示之實施例加以詳述，但應瞭解可在本發明之精神及範疇内實施各種變化及修改。 122661.doc 136-麴磙w^?t杷画画染 dye is age 咪叙¥ ♦黎122661.doc 20.28 (N CO Os ON <N vd r-H 〇\ cn % t-H 1 cn <N t> TH 1 r—H 1 -1.16 75.61 79.45 80.38 81.65 82.68 Η 'w/ 108.6 107.1 104.2 104.1 100.9 P measured value (ppm) o (N TH 00 00 00 VO P theoretical value (ppm) o (N r — i. 0.000 0.048 0.107 0.203 0.405 cn cn m in cn mm S §: H cn m (N mmm (N cn DEG1 mol% inch oov〇o 卜〇d d antiTMCD mol% cn ci mm (N (N ^T) ON窆 inch in in TMCD mol% rH cn 卜 m ON H inch · cn IV (dL/g) 0.868 0.777 0.698 0.613 0.588 < o Q -135- ϋ3α w^^tSE琛^^如龄· i 200819496 The present invention has been The embodiments disclosed herein are described in detail, but it should be understood that various changes and modifications may be made within the spirit and scope of the invention. 122661.doc 136-

Claims

200819496 十、申請專利範圍：種包含至少一種聚醋之聚g旨組合物，該聚醋包含： (a) 二羧酸組份，其包含： (I) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (II) 約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含·· ⑴約1至小於90莫耳％之2,2,4,4-四甲基_1，3_環丁 ( 二醇殘基；及 (11)約0至約89莫耳％之環己烷二甲醇殘基； (v)大於1〇莫耳％之乙二醇殘基，及 (Vi)小於約2莫耳％之具有3至16個碳原子之改質性二醇； (C)鈦原子及鱗原子；其中該二羧酸組份之總莫耳％為1〇〇莫耳％，且其中該二醇組份之總莫耳％為1〇〇莫耳％ ;且 ( 其中如於2rc下，在濃度為0.25 g/5〇 ml^_(重量比）酚/四氯乙燒中所測定，該聚醋之固有黏度為〇 5〇至12 dL/g。 2 ·如睛求項1之聚酯組合物，其中乙莫耳％之量存在。 3 ·如睛求項1之聚酯組合物，其中乙莫耳％之量存在。 4·如請求項1之聚酯组合物，其中乙醇係以約30至約60 醇係以約3 0至約5 0 係以約35至約45 122661.doc 200819496 莫耳％之量存在。如明求項1之聚酯組合物，其包含1至75 I 3：。/ ·> π 一，、匕3丄主75莫耳％之環己烷一甲醇。 6·如請求項丄之聚酯組合物，i 一八巴a別至50莫耳％之環己烷如明求項1之聚酯組合物，其包含2〇至4〇莫耳％之環己二甲醇义200819496 X. Patent Application Range: A composition comprising at least one polyacetate comprising: (a) a dicarboxylic acid component comprising: (I) from about 90 to about 1 mole % a terephthalic acid residue; (II) from about 0 to about 1 mole % of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and (b) a diol component , which comprises (1) from about 1 to less than 90 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutane (diol residue; and (11) from about 0 to about 89 moles % cyclohexane dimethanol residue; (v) greater than 1 mole % of ethylene glycol residue, and (Vi) less than about 2 mole % of modified diol having 3 to 16 carbon atoms (C) a titanium atom and a squamous atom; wherein the total molar % of the dicarboxylic acid component is 1 〇〇 mol %, and wherein the total molar % of the diol component is 1 〇〇 mol %; And (in the case of 2rc, the intrinsic viscosity of the vinegar is 〇5〇 to 12 dL/g as measured in a concentration of 0.25 g/5 〇ml^_(weight ratio) phenol/tetrachloroethane. 2 · The polyester composition of claim 1, wherein the amount of Emolar is present. A polyester composition, wherein the amount of acetam is present in an amount of 4. The polyester composition of claim 1 wherein the ethanol is from about 30 to about 60 alcohols from about 30 to about 50 to about 35 to Approx. 45 122661.doc 200819496 The amount of mol% is present. The polyester composition of claim 1, which comprises 1 to 75 I 3: . / · > π I, 匕 3 丄 main 75 mol% Cyclohexane-methanol. 6. The polyester composition of claim ,, i 八巴 a to 50 mol% of cyclohexane, such as the polyester composition of claim 1, which comprises from 2 to 4 〇莫耳% of cyclohexanediethanol

如巧求項1之聚I組合物’ #包含25至35莫耳％之環己烧 ^一"甲醇。 9.如明求項丨之聚酯組合物，其包含丨至”莫耳％之量之環己烷二甲醇及約30至約60莫耳％之量之乙二醇。 1〇·如請求項丨之聚醋組合物，其中該聚醋之固有黏度為〇·5 至 1 dL/g 〇 11 ·如請求項1之聚酯組合物至〇·75 dL/g。 12.如請求項1之聚酯組合物至〇·75 dL/g。 13·如請求項1之聚酯組合物之Tg。 14·如請求項1之聚酯組合物之Tg 〇其中該聚酯之固有黏度為0.5 其中該聚酯之固有黏度為0.60 其中該聚酯具有l〇〇°C至120°C 其中該聚酯具有100°C至110°C -2 - 1 5 ·如請求項1之聚酯組合物，其包含至少一種選自以下各物中至少一者之磷化合物：烷基磷酸酯、芳基磷酸酯、混合型烷基芳基磷酸酯。 122661.doc 200819496 1 6 ·如請求項1之聚酯組合物，其包含至少一種選自以下各物中至少一者之磷化合物：三烷基磷酸酯、三芳基磷酸酯、烷基二芳基磷酸酯及混合型烷基芳基磷酸_ ° 1 7·如請求項1之聚酯組合物，其包含至少一種選自以下各物中至少一者之磷化合物··三芳基磷酸酯、烷基二芳基填酸酯及混合型炫基芳基磷酸酯。 1 8.如請求項1之聚酯組合物，其包含至少一種選自以下各物中至少一者之磷化合物：磷酸二丁基苯酯、磷酸三苯酯、磷酸三甲苯酯、鱗酸三丁酯、填酸三-2·乙基己酯、磷酸三辛酯、攝酸異十六烷基二苯酯及磷酸2-乙基己基 —本酉旨0 19 ·如請求項1之聚酯組合物，其包含至少一種選自以下各物之磷化合物：磷酸二丁基苯酯、磷酸三苯酯、磷酸異十六烷基二苯酯及磷酸2-乙基己基二苯酯。 20.如請求項1之聚酯組合物，其包含至少一種選自以下各物之碟化合物：磷酸三苯g旨、M erpol A及填酸2 -乙基己基二苯酿。 21_如請求項1之聚酯組合物，其包含以該聚酯之總重量計以約1 ppm至約500 ppm之量存在於該最終聚酯中之鱗化合物。 22·如請求項1之聚酯組合物，其包含以該聚酯之總重量計以約1 ppm至約300 ppm之量存在於該最終聚酯中之磷化合物。 23·如請求項1之聚酯組合物，其包含以該聚酯之總重量計 122661.doc 200819496 以約1 ppm至約100 ppm之量存在於該最終聚酯中之磷化合物。 24.如請求項1之聚酯組合物，其中該最終聚酯中全部磷原子與全部鈦原子之重量比為〇-1〇: ：1。 25·如請求項1之聚酯組合物，其中該最終聚酯中全部磷原子與全部鈦原子之重量比為1_10:1。 26_如請求項【之聚酯組合物，其中該最終聚酯中全部磷原子與全部鈦原子之重量比為0_5:;1。 27·如請求項i之聚酯組合物，其中該最終聚酯中全部磷原子與全部鈦原子之重量比為1·5:1。 28. 如請求項i之聚酯組合物，其中該聚酯包含至少一種選自以下各物之改質性二醇：二乙二醇、1，2-丙二醇、新戍一醇、聚丁二醇、1，5-戊二醇、16·己二醇、對二甲苯一酵、1，3-丙二醇及丨，4_ 丁二醇或其混合物。 29. 如叫求項1之聚酯組合物，其中該聚酯包含二乙二醇。 3 0.如明求項1之聚酯組合物，其中該2,2,4,4_四甲基_ι，3-環丁一醇殘基為包含4〇至6〇莫耳％之順2,2,4,4·四甲基-1，3-% 丁一醇殘基與4〇至6〇莫耳％之反2,2,4,4_四甲基-丨，3_環丁二醇殘基之混合物。 31· 一種包含如請求項1之聚酯組合物之摻合物，其包含至夕種以下聚合物：聚（醚醯亞胺）、聚苯醚、聚（苯醚）/ 聚苯？烯摻合物、聚苯乙烯樹脂、聚苯硫醚、聚苯硫醚/ 颯聚（酯-碳酸酯）、聚碳酸酯、聚砜、聚砜醚、聚（醚_ 酮）不同於如請求項1之彼等聚酯之聚酯及其混合物。 122661.doc 200819496 •—種包含如請求項1之聚酯組合物之聚合物摻合物，其包含至少一種聚碳酸酯。 33·如睛求項1之聚酯組合物，其中該聚酯組合物包含用於該聚酯之分枝劑。 34·如請求項1之聚酯組合物，其中該聚酯之撓曲模數係等於或大於290,〇〇〇 psi。 35·如請求項1之聚酯組合物，其中該聚酯為非晶形的。 36·如請求項1之聚酯組合物，其中該聚酯於170°C下具有大於5分鐘之半結晶期。 37·如請求項1之聚酯組合物，其中該聚酯於23°C下具有大於 g/ml之密度。 38·如請求項1之聚酯組合物，其中該聚酯組合物包含至少一種以下添加劑··著色劑、脫模劑、不同於如請求項1 所述之磷化合物之熱穩定劑、增塑劑、成核劑、uv穩定劑、玻璃纖維、碳纖維、填充劑、抗衝擊改質劑或其混合物。 39. 如凊求項1之聚酯組合物，其中該聚酯於23。〇下根據 ASTM D256以使用1/8吋厚棒之1〇密耳（mil)缺口具有至 3 ft lb/in之伊佐德氏缺口衝擊強度 impact strength)。 40. 如請求項丄之聚醋組合物，其中該聚醋於23。〇下根據 ASTM D256以使们/8时厚棒之1〇密耳缺口具有至少 ft-lWin之伊佐德氏缺口衝擊強度。 41. 如請求項1之聚醋組合物，其中該聚醋具有兩種或兩種 122661.doc 200819496 以上之以下特性，該等特性係選自：如藉由ΤΑ 2100 Thermal Analyst Instrument以 20。(：/min之掃描速率所量測之約100°C至約11〇。〇之Tg;如ASTM D790所定義之於 23C下等於或大於290,000 pSi之撓曲模數；及於23°C下根據AS TM D256以使用1/8忖厚棒之1〇密耳缺口之大於1〇 ft-lb/in之伊佐德氏缺口衝擊強度。 42·如請求項1之聚酯組合物，其中如藉由L*a*b*色彩系統所測疋’適用於本發明之該等聚酯在調色劑不存在下之 b*色值為-12至小於12。 43· —種包含如請求項1之聚酯組合物之製品，其包含一薄膜或薄片。 44· 一種包含如請求項1之聚酯組合物之製品，其包含一熱成型薄膜或薄片。 45_如清求項1之聚酯組合物，其中以該聚酯之總重量計，該聚醋包含〇·〇1至5重量。/()之量之分枝劑。 46·如請求項1之聚酯組合物，其中以該聚酯之總重量計，該聚醋包含〇.〇1至1重量％之量之分枝劑。 47·如請求項1之聚酯組合物，以該聚酯之總重量計，其包含至少一種以約1 ppm至約500 ppm之量存在於最終聚酯中之磷化合物。 48. 如請求項1之聚酯組合物，以該聚酯之總重量計，其包含至少一種以約1 ppm至約100 ppm之量存在於該最終聚酯中之磷化合物。 49. 一種製備聚g旨之方法，其包含以下步驟： 122661.doc -6 - 200819496 (I)在至少一種選自150°C至250°C之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸組份，其包含： (i) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (ii) 約0至約10莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,扣四曱基」，3· 環丁二醇殘基；及 (ii) 約0至約89莫耳％之環己烷二甲醇殘基； (iii) 大於1〇莫耳％之乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中遠步驟（I)中所添加之二醇組份/二緩酸組份之莫耳比為1.01-3.0/1.0 ; 其中步驟（I)中之該混合物係於以下各物存在下加熱： (1)至少一種包含至少一種鈦化合物之催化劑，及視情況至少一種選自以下各物之催化劑：錫化合物、鎵化合物、鋅化合物、銻化合物、鈷化合物、錳化合物、鎂化合物、鍺化合物、鋰化合物、銘化合物及具有氳氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物、其反應產物及其 122661.doc 200819496 混合物； (Η)於23 0°C至320°C之溫度下，在至少一種選自該步驟⑴之最終壓力至0.02托（torr)絕對壓力範圍内之壓力下將步驟（I)之该產物加熱1至6小時以形成最終聚酯；其中該最終聚酯中之該二羧酸組份之總莫耳％為1〇〇莫耳 /〇 ’且其中該最終聚酯中之該二醇組份之總莫耳％為1 〇〇莫耳％; 其中如於25°c下，在濃度為0.25 g/50 ml之60/40(重量比）紛/四氯乙烧中所測定，該聚酯之固有黏度為〇 5〇至 dL/g。 50.如叫求項49之方法，其中該步驟⑴中所添加之二醇組份/ 二敌酸組份之莫耳比為1.01-2/1.0。 51·如4求項5〇之方法，其中該步驟⑴中所添加之二醇組份/ 二魏酸組份之莫耳比為1.01-1.5/1.0。 52·如清求項5〇之方法，其中該步驟（η)中之加熱時間為1至 4小時。 53·如明求項5〇之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為〇·2:1。 54·如請求項50之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為Μ〇:1。 55·如明求項5〇之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為0-5:1。 56.如明求項5〇之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為1_5:1。 122661.doc 200819496 5 7 ·如明求項5 〇之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為1 - 3 :1。 58.如請求項5〇之方法，其中以該最終聚酯之重量計，該最終聚㈣所存在之鈦原子之量可為1至100 ppm鈦原子。 59·如叫求項5〇之方法，其中該最終聚酯中存在約π莫耳％至約60莫耳％之乙二醇。 60·如叫求項5〇之方法，其中步驟⑴中所用之該（等）催化劑包含至少一種鈦化合物及至少一種錫化合物。 61·如請求項50之方法，其中步驟⑴中所用之該催化劑基本上係由至少一種鈦化合物組成。 62·如請求項5〇之聚酯組合物，其包含丨至乃莫耳％之環己烷二甲醇。兀 63·如明求項5〇之聚酯組合物，其包含⑼至％莫耳％之烷二甲醇。 64·如請求項50之聚醋組合物，其包含2〇至扣莫烷二甲醇。衣已 65·如請求項50之聚i组合物，其包含25至35莫、化一 m设 ^衣匕 66.如請求項50之聚醋組合物，#包含！至75莫耳％之己烧二甲醇及約30至約60莫耳0/〇之量之乙二醇。衣 ⑺.如請求項50之聚醋組合物，其中如藉由訂統戶:測定’適用於本發明之該等聚醋在調色劑不存：：之b色值為-10至小於1〇。 68. -種製備聚酯之方法，其包含以下步驟： 122661.doc 200819496 (i)在至少一種選自i5(rcs25(rc之溫度下，在至少一種選自0 psig至75 psig範圍内之壓力下加熱一混合物’其中該混合物包含： (a) 二羧酸組份，其包含： (i) 約90至約1〇〇莫耳％之對苯二甲酸殘基； (η)約0至約1〇莫耳％之具有至多2〇個碳原子之芳族及/或脂族二羧酸殘基；及 (b) 二醇組份，其包含： ⑴約1至小於90莫耳％之2,2,4,4-四甲基-1，3_ 環丁二醇殘基；及 (ii) 約0至約89莫耳％之環己烷二甲醇殘基； (iii) 大於10莫耳％之乙二醇殘基，及 (iv) 小於約2莫耳％之具有3至16個碳原子之改質性二醇；其中該步驛（I)中所添加之二醇組份/二致酸組份之莫耳比為1.01-3.0/1.0 ; 其中步驟（I)中之該混合物係於以下各物存在下加熱： (i)至少一種包含至少一種鈦化合物、至少一種錫化合物之催化劑，及視情況至少一種選自以下各物之催化劑：鎵化合物、鋅化合物、銻化合物、姑化合物、猛化合物、鐫化合物、鍺化合物、鋰化合物、銘化合物及具有氫氧化鋰或氫氧化鈉之鋁化合物；及（ii)至少一種磷化合物； 122661.doc -10- 200819496 (II)於23 0 °C至320 °C之溫度下，在至少一種選自該步驟（I)之最終壓力至〇·〇2托絕對壓力範圍内之壓力下將步驟（I)之該產物加熱1至6小時以形成最終聚醋；其中該最終聚酯中之該二羧酸組份之總莫耳％為1〇〇莫耳 % ;且其中該最終聚酯中之該二醇組份之總莫耳％為工莫耳％ ; 且其中如於25C下，在濃度為〇·25 g/50 ml之60/40(重量比）酚/四氣乙烷中所測定，該聚酯之固有黏度為〇 5〇至i 2 dL/g。 69·如請求項68之聚酯組合物，其包含1至乃莫耳％之環己烷二甲醇。 70·如請求項68之聚酯組合物，烷二甲醇。 71 ·如晴求項6 8之聚醋組合物，其包含20至50莫耳％之環己烷二甲醇。 72·如请求項68之聚醋組合物，其包含20至40莫耳％之環己烷二甲醇。 73.如請求項68之聚酯組合物，其包含25至35莫耳％之環己 ’其包含1至75莫耳％之量之環For example, the poly-I composition of the item 1 ' contains 25 to 35 mol% of cyclohexanthene " methanol. 9. A polyester composition according to the invention, which comprises cyclohexane dimethanol in an amount of from 丨% to mol% and ethylene glycol in an amount of from about 30 to about 60 mol%. The polyester vinegar composition of the formula, wherein the intrinsic viscosity of the polyester is 〇·5 to 1 dL/g 〇11 · The polyester composition of claim 1 to 〇·75 dL/g. The polyester composition to 〇·75 dL/g. 13· The Tg of the polyester composition of claim 1. 14. The Tg of the polyester composition of claim 1 wherein the polyester has an intrinsic viscosity of 0.5 Wherein the polyester has an intrinsic viscosity of 0.60, wherein the polyester has a temperature of from 10 ° C to 120 ° C, wherein the polyester has a temperature of from 100 ° C to 110 ° C - 2 - 15 · The polyester composition of claim 1 And comprising at least one phosphorus compound selected from the group consisting of alkyl phosphates, aryl phosphates, mixed alkyl aryl phosphates. 122661.doc 200819496 1 6 · As claimed in claim 1 An ester composition comprising at least one phosphorus compound selected from the group consisting of trialkyl phosphates, triaryl phosphates, alkyl diaryl phosphates A mixed alkyl aryl phosphoric acid _ 1.7 The polyester composition of claim 1, comprising at least one phosphorus compound selected from at least one of the following: a triaryl phosphate, an alkyl diaryl group And a mixed type of aryl aryl phosphate. The polyester composition according to claim 1, which comprises at least one phosphorus compound selected from at least one of the following: dibutyl phenyl phosphate, Triphenyl phosphate, tricresyl phosphate, tributyl squarate, tris-ethylhexyl acrylate, trioctyl phosphate, isohexyl diphenyl phthalate and 2-ethylhexyl phosphate - The polyester composition of claim 1, comprising at least one phosphorus compound selected from the group consisting of dibutyl phenyl phosphate, triphenyl phosphate, and isohexadecyl diphenyl phosphate And 2-ethylhexyldiphenyl phosphate. The polyester composition according to claim 1, which comprises at least one dish compound selected from the group consisting of triphenyl phosphite, M erpol A and acid 2 - Ethylhexyldiphenyl styrene. The polyester composition of claim 1 comprising from about 1 ppm to the total weight of the polyester A scaly compound present in the final polyester in an amount of from 500 ppm, wherein the polyester composition of claim 1 is present in an amount of from about 1 ppm to about 300 ppm based on the total weight of the polyester. A phosphorus compound in the final polyester. 23. The polyester composition of claim 1 comprising 122661.doc 200819496 in an amount of from about 1 ppm to about 100 ppm based on the total weight of the polyester. A phosphorus composition according to claim 1, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 〇-1〇: :1. The polyester composition of claim 1, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is from 1 to 10:1. 26_ The polyester composition of claim 2, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 0_5:; The polyester composition of claim i, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 1.5:1. 28. The polyester composition of claim i, wherein the polyester comprises at least one modified diol selected from the group consisting of diethylene glycol, 1,2-propanediol, neodecyl alcohol, polybutane Alcohol, 1,5-pentanediol, 16·hexanediol, p-xylene monopropanol, 1,3-propanediol and hydrazine, 4-butanediol or a mixture thereof. 29. The polyester composition of claim 1 wherein the polyester comprises diethylene glycol. The polyester composition according to claim 1, wherein the 2,2,4,4-tetramethyl-, 3-cyclobutanol residue is a sulfonate containing 4 to 6 moles per mole. 2,2,4,4·tetramethyl-1,3-% butyl alcohol residue and 4〇 to 6〇mol% of 2,2,4,4_tetramethyl-hydrazine, 3_ ring A mixture of butanediol residues. 31. A blend comprising the polyester composition of claim 1 comprising at least the following polymers: poly(ether quinone imine), polyphenylene ether, poly(phenylene ether) / polyphenylene? Ane blend, polystyrene resin, polyphenylene sulfide, polyphenylene sulfide / decyl (ester-carbonate), polycarbonate, polysulfone, polysulfone ether, poly(ether ketone) are different from request The polyesters of the polyesters of item 1 and mixtures thereof. 122661.doc 200819496 - A polymer blend comprising the polyester composition of claim 1 comprising at least one polycarbonate. 33. The polyester composition of claim 1, wherein the polyester composition comprises a branching agent for the polyester. 34. The polyester composition of claim 1 wherein the polyester has a flexural modulus equal to or greater than 290, 〇〇〇 psi. 35. The polyester composition of claim 1 wherein the polyester is amorphous. 36. The polyester composition of claim 1 wherein the polyester has a half crystallization period of greater than 5 minutes at 170 °C. 37. The polyester composition of claim 1 wherein the polyester has a density greater than g/ml at 23 °C. 38. The polyester composition of claim 1, wherein the polyester composition comprises at least one of the following additives: a colorant, a release agent, a heat stabilizer different from the phosphorus compound as claimed in claim 1, plasticizing Agent, nucleating agent, uv stabilizer, glass fiber, carbon fiber, filler, impact modifier or a mixture thereof. 39. The polyester composition of claim 1, wherein the polyester is at 23. Under the ASTM D256, a 1 mil mil notch with a 1/8 吋 thick bar has an Izod notched impact strength of 3 ft lb/in. 40. A poly- vinegar composition as claimed in claim 1, wherein the polyacetate is at 23. The underarms have an Izod notched impact strength of at least ft-lWin according to ASTM D256. 41. The polyacetate composition of claim 1, wherein the polyester has two or more of the following characteristics of 122661.doc 200819496 or more selected from: 20 by a 100 2100 Thermal Analyst Instrument. (: / min scan rate measured from about 100 ° C to about 11 〇. Tg of T; as defined by ASTM D790 at 23 C equal to or greater than 290,000 pSi flexural modulus; and at 23 ° C Izod's notched impact strength of more than 1 ft-lb/in using a 1 mil mil notch according to ASTM D256. 42. The polyester composition of claim 1 wherein Measured by the L*a*b* color system, the polyesters suitable for use in the present invention have a b* color value of -12 to less than 12 in the absence of toner. 43. An article of a polyester composition comprising a film or sheet. 44. An article comprising the polyester composition of claim 1 comprising a thermoformed film or sheet. 45_Polyester according to claim 1 a composition, wherein the polyester comprises a branching agent in an amount of from 1 to 5 by weight based on the total weight of the polyester. 46. The polyester composition of claim 1, wherein The polyester comprises a branching agent in an amount of from 1 to 1% by weight based on the total weight of the polyester. 47. The polyester composition of claim 1, which comprises, based on the total weight of the polyester, At least one phosphorus compound present in the final polyester in an amount of from about 1 ppm to about 500 ppm. 48. The polyester composition of claim 1 comprising at least one of about 1 based on the total weight of the polyester A phosphorus compound present in the final polyester in an amount of from ppm to about 100 ppm. 49. A method of preparing a polyg, comprising the steps of: 122661.doc -6 - 200819496 (I) at least one selected from the group consisting of 150° Heating a mixture at a temperature of from C to 250 ° C in at least one pressure selected from the range of from 0 psig to 75 psig, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: (i) about 90 Up to about 1% by mole of terephthalic acid residues; (ii) from about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 2 carbon atoms; (b) a diol component comprising: (1) from about 1 to less than 90 mol% of 2,2,4, decanthenyl, 3·cyclobutanediol residues; and (ii) from about 0 to about 89 mole % cyclohexane dimethanol residue; (iii) greater than 1 mole % of ethylene glycol residue, and (iv) less than about 2 mole % of modification with 3 to 16 carbon atoms Sex The alcohol; wherein the molar ratio of the diol component/di-acidifying component added in the step (I) is from 1.01 to 3.0/1.0; wherein the mixture in the step (I) is heated in the presence of the following (1) at least one catalyst comprising at least one titanium compound, and optionally at least one catalyst selected from the group consisting of tin compounds, gallium compounds, zinc compounds, antimony compounds, cobalt compounds, manganese compounds, magnesium compounds, antimony compounds , a lithium compound, an indole compound and an aluminum compound having lithium niobate or sodium hydroxide; and (ii) at least one phosphorus compound, a reaction product thereof and a mixture thereof 122661.doc 200819496; (Η) at 23 0 ° C to 320 ° The product of step (I) is heated at a temperature of C at a pressure selected from the group consisting of the final pressure of step (1) to a pressure of 0.02 torr absolute for 1 to 6 hours to form a final polyester; The total mole % of the dicarboxylic acid component in the final polyester is 1 Torr/〇' and wherein the total mole % of the diol component in the final polyester is 1 〇〇 mol % ; as in 25 °c Measured at a concentration of 0.25 g / 50 ml of 60/40 (weight ratio) Fun / tetrachloro acetate burning, the inherent viscosity of the polyester is square to 5〇 dL / g. 50. The method of claim 49, wherein the molar ratio of the diol component/dithio acid component added in the step (1) is 1.01-2/1.0. 51. The method of claim 5, wherein the molar ratio of the diol component/diweilic acid component added in the step (1) is 1.01 to 1.5/1.0. 52. The method of claim 5, wherein the heating time in the step (n) is from 1 to 4 hours. 53. The method of claim 5, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is 〇·2:1. 54. The method of claim 50, wherein the weight ratio of all of the phosphorus atoms to the total of the titanium atoms in the final polyester is Μ〇:1. 55. The method of claim 5, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is from 0 to 5:1. 56. The method of claim 5, wherein the weight ratio of all of the phosphorus atoms to the total of the titanium atoms in the final polyester is from 1 to 5:1. The method of claim 5, wherein the weight ratio of all phosphorus atoms to all titanium atoms in the final polyester is from 1 to 3:1. 58. The method of claim 5, wherein the amount of titanium atoms present in the final poly(tetra) is from 1 to 100 ppm titanium atoms based on the weight of the final polyester. 59. The method of claim 5, wherein from about π mol% to about 60 mol% of ethylene glycol is present in the final polyester. 60. The method of claim 5, wherein the (etc.) catalyst used in the step (1) comprises at least one titanium compound and at least one tin compound. 61. The method of claim 50, wherein the catalyst used in step (1) consists essentially of at least one titanium compound. 62. The polyester composition of claim 5, which comprises hydrazine to mol% of cyclohexanedimethanol.兀 63. A polyester composition according to the item 5, which comprises (9) to % mol% of alkane dimethanol. 64. The polyacetic composition of claim 50 which comprises 2 Torr to deoxymethylene dimethanol. The composition of the poly-i composition of claim 50, which comprises 25 to 35 moles, and the composition of the composition is 66. The polyacetal composition of claim 50, #include! Up to 75 mole % of di-methanol and about 30 to about 60 moles of ethylene glycol. (7) The polyacetal composition of claim 50, wherein, by the ordering unit: determining that the polyesters suitable for use in the present invention are not present in the toner: the b color value is -10 to less than 1 Hey. 68. A method of preparing a polyester comprising the steps of: 122661.doc 200819496 (i) at least one pressure selected from the group consisting of i5 (rcs25 (rc, at least one selected from the range of 0 psig to 75 psig) Lower heating a mixture wherein the mixture comprises: (a) a dicarboxylic acid component comprising: (i) from about 90 to about 1 mole percent terephthalic acid residue; (η) from about 0 to about 1 〇% by mole of an aromatic and/or aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and (b) a diol component comprising: (1) from about 1 to less than 90 mol% , 2,4,4-tetramethyl-1,3_cyclobutanediol residue; and (ii) from about 0 to about 89 mole % of cyclohexanedimethanol residue; (iii) greater than 10 mole % a glycol residue, and (iv) less than about 2 mole % of a modified diol having 3 to 16 carbon atoms; wherein the diol component/secondary added in the step (I) The molar ratio of the acid component is from 1.01 to 3.0/1.0; wherein the mixture in the step (I) is heated in the presence of: (i) at least one catalyst comprising at least one titanium compound, at least one tin compound, And At least one catalyst selected from the group consisting of a gallium compound, a zinc compound, a cerium compound, a urinary compound, a stimulating compound, a cerium compound, a cerium compound, a lithium compound, an indole compound, and an aluminum compound having lithium hydroxide or sodium hydroxide; And (ii) at least one phosphorus compound; 122661.doc -10- 200819496 (II) at a temperature of from 23 ° C to 320 ° C, at least one final pressure selected from the step (I) to 〇·〇2 The product of step (I) is heated for 1 to 6 hours under pressure within the absolute pressure range to form the final polyester; wherein the total mole % of the dicarboxylic acid component in the final polyester is 1 〇〇 Ear % ; and wherein the total molar % of the diol component in the final polyester is % Mog; and wherein, at 25 C, at a concentration of 〇 25 g / 50 ml of 60/40 (weight The polyester has an inherent viscosity of from 〇5〇 to i 2 dL/g as determined in phenol/tetra-ethane. 69. The polyester composition of claim 68, which comprises from 1 to a mole of Cyclohexanedimethanol 70. The polyester composition of claim 68, alkane dimethanol. 71 · A polylactic acid composition comprising 8 to 50 mol% of cyclohexanedimethanol. 72. The polyacetic acid composition of claim 68, which comprises 20 to 40 mol% of cyclohexanedimethanol. The polyester composition of claim 68, which comprises from 25 to 35 mol% of cyclohexene, which comprises a ring in an amount of from 1 to 75 mol%

羧酸組份之莫耳比為1.01-2/1.0。之二醇組份/The molar ratio of the carboxylic acid component was 1.01-2/1.0. Glycol component /

122661.doc 200819496 76·如明求項68之方法，其中該步驟（η)中之加熱時間為i至 4個小時。 77·如明求項68之方法，其中該最終聚酯中之全部磷原子與王°卩鈦原子與全部錫原子之重量比為0-10:0-10:1。 78·如明求項68之方法，其中該最終聚酯中之全部磷原子與王°卩鈦原子與全部錫原子之重量比為1 -5:1。 79.如请求項68之方法，其中該最終聚酯中之全部錫原子與全部鈦原子之重量比為。 80·如明求項68之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為1-1〇:1。 81·如明求項68之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為〇_5:1。 82·如咕求項68之方法，其中該最終聚酯中之全部磷原子與全部鈦原子之重量比為1-5:1。 83·如叫求項68之方法，其中以該最終聚酯之重量計，該最終聚知中所存在之鈦原子之量可為1至丨〇〇卯m鈦原子。 84·如印求項68之方法，其中以該最終聚酯之重量計，該最終聚酯中所存在之錫原子之量可為1至400 ppm錫原子。 85·如请求項68之方法，其中以該最終聚酯之重量計，該最終聚酯中所存在之磷原子之量可為丨至纟⑼卯㈤磷原子。 86·如凊求項68之方法，其中以該最終聚酯之重量計，該最終聚酯中所存在之鈦原子之量可為丨至丨⑽ppm鈦原子；以该最終聚酯之重量計，該最終聚酯中所存在之錫原子之里可為1至4〇〇 ppm錫原子，·且以該最終聚酯之重量 122661.doc •12- 200819496 計’該最終聚酯中所存在之磁眉1 a田 PPm T丨廿牡原子之量可為1至5〇〇磷原子。 8 7.如請求項68之方法，其中嗜畏玖取…丄丄 /、甲Θ被終聚酯中存在約3〇莫耳0/〇至約60莫耳％之乙二醇。 88.如請求項68之方法，其中步驟⑴中所用之該（等）催化劑基本上係由至少一種鈦化合物及至少-種錫化合物组成。、 89·如請求項68之聚酯組合物，苴肀如错由該L*a*b*色彩系統所測定，適詩本發明之該等聚自旨在調色劑不存在; 之b*色值為-ίο至小於1〇。 9〇· 一種包含至少一種聚_之聚醋組合物，該聚醋包含： (&)-竣酸組份，其包含： ⑴約9〇至約100莫耳％之對苯二甲酸殘基； (Π)約〇至約1〇莫耳％之具有至多20個碳原子之芳族及/或脂族二羧酸殘基；及 (b)二醇組份，其包含： ⑴、、、勺1至小於9〇莫耳％之2,2,4,4_四甲基衷丁二醇殘基；及 3 (11)約0至約89莫耳〇/〇之環己烷二甲醇殘基； (iii)大於10莫耳％之乙二醇殘基，及㈣小於約2莫耳％之具有3至16個碳原子之改質性二醇； (C)鈦原子及磷原子，其中該二㈣組份之總莫耳⑼莫耳％，且其中該二 122661.doc -13 - 200819496 醇組份之總莫耳％為100莫耳且其中如於25°C下，在濃度為〇·25 g/50 ml之60/40(重量比）酚/四氯乙烷中所測定，戎聚酯之固有黏度為0·5〇至1 2 dL/g ;且其中該聚酯包含至少一種分枝劑。 υ -14- 122661.doc 200819496 七、指定代表囷： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明：八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無） 122661.docThe method of claim 68, wherein the heating time in the step (n) is from i to 4 hours. 77. The method of claim 68, wherein the weight ratio of all of the phosphorus atoms in the final polyester to the titanium atoms and all of the tin atoms is from 0 to 10:0 to 10:1. 78. The method of claim 68, wherein the weight ratio of all of the phosphorus atoms to the total of the tin atoms in the final polyester is from 1 to 5:1. 79. The method of claim 68, wherein the weight ratio of all tin atoms to total titanium atoms in the final polyester is. 80. The method of claim 68, wherein the weight ratio of all of the phosphorus atoms to the total of the titanium atoms in the final polyester is 1-1 〇:1. The method of claim 68, wherein the weight ratio of all of the phosphorus atoms to the total of the titanium atoms in the final polyester is 〇_5:1. 82. The method of claim 68, wherein the weight ratio of all of the phosphorus atoms to the total of the titanium atoms in the final polyester is from 1 to 5:1. 83. The method of claim 68, wherein the amount of titanium atoms present in the final collection is from 1 to 丨〇〇卯m titanium atoms based on the weight of the final polyester. 84. The method of claim 68, wherein the amount of tin atoms present in the final polyester is from 1 to 400 ppm tin atoms based on the weight of the final polyester. 85. The method of claim 68, wherein the amount of phosphorus atoms present in the final polyester, based on the weight of the final polyester, is from 丨 to 纟(9)卯(五)phosphorus. 86. The method of claim 68, wherein the amount of titanium atoms present in the final polyester is from 丨 to 丨 (10) ppm titanium atom based on the weight of the final polyester; The tin atoms present in the final polyester may be from 1 to 4 〇〇ppm tin atoms, and the magnetic content of the final polyester is 122661.doc •12-200819496 The amount of the eyebrow 1 a field PPm T 丨廿原子 atom can be 1 to 5 〇〇 phosphorus atom. 8. The method of claim 68, wherein the phobia is extracted from the final polyester in an amount of from about 3 moles per mole to about 60 mole percent of ethylene glycol. 88. The method of claim 68, wherein the (etc.) catalyst used in step (1) consists essentially of at least one titanium compound and at least one tin compound. 89. The polyester composition of claim 68, as determined by the L*a*b* color system, is suitable for the absence of the toner of the present invention; b* The color value is -ίο to less than 1〇. 9A. A polyacetic acid composition comprising at least one poly- acetal comprising: (&)-decanoic acid component comprising: (1) from about 9 〇 to about 100 mol% of terephthalic acid residues (Π) about 〇% to about 1% by mole of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (1), Scoop 1 to less than 9 〇 mol% of 2,2,4,4-tetramethyl-butanediol residues; and 3 (11) from about 0 to about 89 moles/〇 of cyclohexanedimethanol residue (iii) greater than 10 mol% of ethylene glycol residues, and (d) less than about 2 mol% of a modified diol having 3 to 16 carbon atoms; (C) a titanium atom and a phosphorus atom, The total mole (9) mole % of the two (four) components, and wherein the total molar percentage of the alcohol component of the two 122661.doc -13 - 200819496 is 100 moles and wherein, at 25 ° C, the concentration is 〇 25 g/50 ml of 60/40 (by weight) as determined in phenol/tetrachloroethane, the intrinsic viscosity of the ruthenium polyester is from 0.5 to 12 dL/g; and wherein the polyester contains at least one Branching agent. υ -14- 122661.doc 200819496 VII. Designated representative 囷: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please reveal the best Chemical formula showing the characteristics of the invention: (none) 122661.doc