MX2009003369A - Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor. - Google Patents
Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor.Info
- Publication number
- MX2009003369A MX2009003369A MX2009003369A MX2009003369A MX2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A
- Authority
- MX
- Mexico
- Prior art keywords
- mole
- titanium
- phosphorus
- ethylene glycol
- residues
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
Abstract
Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 90 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a glycol component comprising: (i) about 1 to less than 90 mole % 2,2,4,4-tetramethyl-1,3- cyclobutanediol residues; and (ii) about 0 to about 89 mole % cyclohexanedimethanol residues; (iii) greater than 10 mole % ethylene glycol residues, and (iv) less than about 2 mole % of a modifying glycol having from 3 to 16 carbon atoms; (c) titanium atoms and phosphorus atoms, wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C. The polyesters may be manufactured into articles.
Applications Claiming Priority (24)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/588,554 US20070100125A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
| PCT/US2006/042293 WO2007053550A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having high glass transition temperature and articles made therefrom |
| US11/588,524 US20100096589A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom |
| US11/588,527 US20100087574A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US11/588,907 US20070106054A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom |
| US11/588,883 US20070105993A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| US11/588,906 US8193302B2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| PCT/US2006/041917 WO2007053434A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| PCT/US2006/042291 WO2007053548A2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
| PCT/US2006/042069 WO2007053460A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| US11/588,458 US20070100122A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol and articles made therefrom |
| PCT/US2006/042292 WO2007053549A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US11/635,434 US7737246B2 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US11/635,433 US20070142511A1 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
| US11/706,791 US20070232779A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid |
| US11/706,476 US20070232778A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
| PCT/US2007/007632 WO2007126855A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| PCT/US2007/007532 WO2007123631A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| PCT/US2007/010590 WO2007139655A1 (en) | 2006-05-23 | 2007-05-02 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| PCT/US2007/010551 WO2007139653A1 (en) | 2006-05-23 | 2007-05-02 | Lcd films or sheets comprising films comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| PCT/US2007/011150 WO2007139663A1 (en) | 2006-05-23 | 2007-05-09 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| US91731607P | 2007-05-10 | 2007-05-10 | |
| US11/773,275 US8586701B2 (en) | 2005-10-28 | 2007-07-03 | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| PCT/US2007/015704 WO2008051321A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009003369A true MX2009003369A (en) | 2009-04-14 |
Family
ID=47831243
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009003375A MX2009003375A (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor. |
| MX2009003369A MX2009003369A (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009003375A MX2009003375A (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor. |
Country Status (8)
| Country | Link |
|---|---|
| EP (2) | EP2074174A1 (en) |
| JP (2) | JP2010507716A (en) |
| KR (2) | KR20090079212A (en) |
| BR (2) | BRPI0717761A2 (en) |
| CA (2) | CA2666571A1 (en) |
| MX (2) | MX2009003375A (en) |
| TW (2) | TW200819497A (en) |
| WO (4) | WO2008051320A1 (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8168721B2 (en) * | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
| US9029460B2 (en) * | 2009-02-06 | 2015-05-12 | Stacey James Marsh | Coating compositions containing acrylic and aliphatic polyester blends |
| US8163850B2 (en) * | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
| US7915374B2 (en) * | 2009-04-27 | 2011-03-29 | Eastman Chemical Company | Copolyesters having improved thermal stability and methods for making them |
| US9156941B2 (en) * | 2010-12-20 | 2015-10-13 | Eastman Chemical Company | Color in titanium catalyzed polyesters |
| US8309624B2 (en) * | 2011-01-17 | 2012-11-13 | Eastman Chemical Company | Haze reduction for blends of aromatic-aliphatic polyesters and antimicrobial additives |
| US8580872B2 (en) * | 2011-07-21 | 2013-11-12 | Eastman Chemical Company | Sulfopolyester polymer compositions with improved water dispersibility |
| US10093796B2 (en) | 2011-11-01 | 2018-10-09 | Midori Anzen Co., Ltd. | Resin composition and molded body |
| US8623483B1 (en) * | 2012-10-23 | 2014-01-07 | Eastman Chemical Company | Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl 1,3-cyclobutanediol |
| JP6489012B2 (en) * | 2014-02-24 | 2019-03-27 | 東レ株式会社 | Polyester film |
| JPWO2015129500A1 (en) * | 2014-02-27 | 2017-03-30 | 東レ株式会社 | Laminated film |
| JP6323872B2 (en) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | Toner for electrophotography |
| JP6323871B2 (en) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | Toner for electrophotography |
| JP2015028177A (en) * | 2014-09-22 | 2015-02-12 | イーストマン ケミカル カンパニー | Improved method for producing polyester |
| WO2018035345A1 (en) * | 2016-08-18 | 2018-02-22 | Eastman Chemical Company | Oriented films and shrink films comprising polyesters which comprise tetramethyl cyclobutanediol and ethylene glycol |
| JP7130621B2 (en) * | 2016-08-18 | 2022-09-05 | イーストマン ケミカル カンパニー | Polyester composition containing tetramethylcyclobutanediol and ethylene glycol with improved catalyst system |
| WO2018035337A1 (en) * | 2016-08-18 | 2018-02-22 | Eastman Chemical Company | Polyester compositions which comprise tetramethylcyclobutandiol and ethylene glycol, with improved catalyst system |
| KR102589382B1 (en) * | 2018-08-08 | 2023-10-12 | 에스케이케미칼 주식회사 | Polyester resin and preparation method of the same |
| WO2021025967A1 (en) * | 2019-08-02 | 2021-02-11 | Eastman Chemical Company | Multilayer sheet |
| KR20220079915A (en) * | 2019-10-08 | 2022-06-14 | 이스트만 케미칼 컴파니 | Catalyst System for Crystallizable Reactor Grade Resins |
| US11788317B2 (en) * | 2020-09-28 | 2023-10-17 | Kathryn Corcoran | Cell phone canopy |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4525504A (en) * | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
| US6495656B1 (en) * | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
| US5498668A (en) * | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
| US6037424A (en) * | 1996-12-28 | 2000-03-14 | Eastman Chemical Company | Clear blends of polycarbonates and polyesters |
| US6043322A (en) * | 1996-12-28 | 2000-03-28 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
| US5989663A (en) * | 1996-12-30 | 1999-11-23 | Eastman Chemical Company | Blow-molding polyesters from terephthalic acid, 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol, and ethylene glycol |
| US6120889A (en) * | 1999-06-03 | 2000-09-19 | Eastman Chemical Company | Low melt viscosity amorphous copolyesters with enhanced glass transition temperatures |
| US20050010017A1 (en) * | 2003-07-11 | 2005-01-13 | Blakely Dale Milton | Addition of UV inhibitors to pet process for maximum yield |
| EP1644436A2 (en) * | 2003-07-11 | 2006-04-12 | Eastman Chemical Company | Addition of uv absorbers to pet process for maximum yield |
| US20060094858A1 (en) * | 2004-10-28 | 2006-05-04 | Turner Sam R | Novel copolyester compositions with improved impact strength at low temperatures |
| WO2007053549A1 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| EP1940908B1 (en) * | 2005-10-28 | 2010-11-03 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
-
2007
- 2007-07-10 BR BRPI0717761-5A patent/BRPI0717761A2/en not_active Application Discontinuation
- 2007-07-10 CA CA002666571A patent/CA2666571A1/en not_active Abandoned
- 2007-07-10 WO PCT/US2007/015701 patent/WO2008051320A1/en active Application Filing
- 2007-07-10 JP JP2009534565A patent/JP2010507716A/en not_active Withdrawn
- 2007-07-10 EP EP07836026A patent/EP2074174A1/en not_active Withdrawn
- 2007-07-10 KR KR1020097008484A patent/KR20090079212A/en not_active Application Discontinuation
- 2007-07-10 MX MX2009003375A patent/MX2009003375A/en unknown
- 2007-07-10 TW TW096125125A patent/TW200819497A/en unknown
- 2007-07-10 BR BRPI0717755-0A patent/BRPI0717755A2/en not_active Application Discontinuation
- 2007-07-10 MX MX2009003369A patent/MX2009003369A/en unknown
- 2007-07-10 JP JP2009534566A patent/JP2010507717A/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015713 patent/WO2008054560A2/en active Application Filing
- 2007-07-10 EP EP07836029A patent/EP2074158A1/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015704 patent/WO2008051321A1/en active Application Filing
- 2007-07-10 KR KR1020097008483A patent/KR20090079211A/en not_active Application Discontinuation
- 2007-07-10 CA CA002666585A patent/CA2666585A1/en not_active Abandoned
- 2007-07-10 WO PCT/US2007/015702 patent/WO2008054559A1/en active Application Filing
- 2007-07-10 TW TW096125089A patent/TW200819496A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008051320A1 (en) | 2008-05-02 |
| WO2008051321A1 (en) | 2008-05-02 |
| WO2008054560A2 (en) | 2008-05-08 |
| CA2666571A1 (en) | 2008-05-02 |
| BRPI0717761A2 (en) | 2013-03-12 |
| CA2666585A1 (en) | 2008-05-02 |
| WO2008054559A1 (en) | 2008-05-08 |
| KR20090079211A (en) | 2009-07-21 |
| BRPI0717755A2 (en) | 2013-03-12 |
| WO2008051321A8 (en) | 2008-07-10 |
| JP2010507716A (en) | 2010-03-11 |
| WO2008054560A3 (en) | 2008-07-24 |
| KR20090079212A (en) | 2009-07-21 |
| TW200819496A (en) | 2008-05-01 |
| TW200819497A (en) | 2008-05-01 |
| MX2009003375A (en) | 2009-04-14 |
| EP2074158A1 (en) | 2009-07-01 |
| JP2010507717A (en) | 2010-03-11 |
| EP2074174A1 (en) | 2009-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX2009003369A (en) | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor. | |
| TW200700494A (en) | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom | |
| HK1120531A1 (en) | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom | |
| WO2009072462A1 (en) | Polyester with improved heat resistance produced from biomass ethylene glycol | |
| DE60317238D1 (en) | MIXTURES OF POLYESTER AND POLYCARBONATE FOR EXTRUSION BLOWING PROCESSES | |
| MX2013003502A (en) | High functionality aromatic polyesters, polyol blends comprising the same and resultant products therefrom. | |
| WO2009044283A3 (en) | Polyester compositions having improved heat resistance | |
| PL2137230T3 (en) | Branched polyester for powder coatings | |
| CA2366515A1 (en) | Process for esterifying 1,3-propanediol | |
| HK1115405A1 (en) | Transparent oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom | |
| WO2007127117A3 (en) | Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol | |
| MX2007007437A (en) | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom. | |
| WO2010001252A3 (en) | Copolyester for shrink film applications | |
| DE502008003169D1 (en) | POLYESTER BLEND CONTAINING BIODIESEL | |
| MXPA04005370A (en) | Multi-layer product. | |
| DE602004010887D1 (en) | Process for the preparation of copolyesters of polyethylene terephthalate | |
| WO2011106760A3 (en) | High melt viscosity polyester or co-polyester compositions | |
| EP2354174A4 (en) | Copolymer polyester resin and molded product using same | |
| TH83904B (en) | Polyester mixtures contain small amounts of cyclobutane diol. | |
| TH83904A (en) | Polyester mixtures contain a small amount of cyclobutane diol. |