TW200624376A - Reactor and process for steam reforming - Google Patents
Reactor and process for steam reformingInfo
- Publication number
- TW200624376A TW200624376A TW094132239A TW94132239A TW200624376A TW 200624376 A TW200624376 A TW 200624376A TW 094132239 A TW094132239 A TW 094132239A TW 94132239 A TW94132239 A TW 94132239A TW 200624376 A TW200624376 A TW 200624376A
- Authority
- TW
- Taiwan
- Prior art keywords
- hydrogen
- intermediate layer
- reactor
- disclosed
- reaction products
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/108—Inorganic support material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02232—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
- C01B3/505—Membranes containing palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/86—Carbon dioxide sequestration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
Abstract
A hydrogen producing reactor is disclosed. The hydrogen producing reactor has a reaction chamber containing a catalyst bed adapted to produce reaction products containing hydrogen from a hydrogen-producing feedstock. The reaction chamber also includes a hydrogen-selective, hydrogen-permeable gas separation module adapted to receive the reaction products from the catalyst bed and to separate a product stream containing hydrogen from the reaction products. The gas separation module comprises a porous substrate, an intermediate layer located at the porous substrate, and a hydrogen-selective membrane overlying the intermediate layer. The intermediate layer comprises particles and a binder metal, where the binder metal is distributed through out the intermediate layer. A steam reforming process is also disclosed using the disclosed reactor.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61168204P | 2004-09-21 | 2004-09-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW200624376A true TW200624376A (en) | 2006-07-16 |
Family
ID=35677491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW094132239A TW200624376A (en) | 2004-09-21 | 2005-09-19 | Reactor and process for steam reforming |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1791631A1 (en) |
JP (1) | JP2008513339A (en) |
AU (1) | AU2005286955B2 (en) |
CA (1) | CA2580279A1 (en) |
NO (1) | NO20071531L (en) |
TW (1) | TW200624376A (en) |
WO (1) | WO2006034103A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITPG20060028A1 (en) * | 2006-04-18 | 2006-07-18 | Leonardo Valentini | EQUIPMENT FOR THE THERMO-PHYSICAL CATALYTIC DETACHMENT OF THE LIQUID AMMONIA IN THE NITROGEN AND HYDROGEN CONSTITUENTS IN THE GASEOUS STATE |
JP4805736B2 (en) * | 2006-06-29 | 2011-11-02 | Jx日鉱日石エネルギー株式会社 | Indirect internal reforming type solid oxide fuel cell |
JP4805735B2 (en) * | 2006-06-29 | 2011-11-02 | Jx日鉱日石エネルギー株式会社 | Indirect internal reforming type solid oxide fuel cell |
US8048199B2 (en) * | 2007-02-20 | 2011-11-01 | Shell Oil Company | Method of making a leak stable gas separation membrane system |
CN101631605B (en) * | 2007-02-20 | 2012-10-03 | 国际壳牌研究有限公司 | A gas separation membrane system and a method of preparing or reconditioning and the use thereof |
FR2914395B1 (en) * | 2007-03-30 | 2009-11-20 | Inst Francais Du Petrole | NEW COMPACT EXCHANGER REACTOR USING A POROUS BURNER |
CA2684771A1 (en) | 2007-04-05 | 2008-10-16 | Worcester Polytechnic Institute | Composite structures with porous anodic oxide layers and methods of fabrication |
EP2103586A1 (en) | 2008-03-20 | 2009-09-23 | Bp Oil International Limited | Process for converting methane into ethane in a membrane reactor |
CA2785351A1 (en) * | 2009-12-22 | 2011-06-30 | Airscience Technologies | System and process for the production of hydrogen from raw gas using a nanoparticle ceria based catalyst |
WO2011119800A1 (en) | 2010-03-26 | 2011-09-29 | Shell Oil Company | Method and device for forming a supported gas separation membrane |
US8652239B2 (en) | 2010-05-03 | 2014-02-18 | Worcester Polytechnic Institute | High permeance sulfur tolerant Pd/Cu alloy membranes |
CN102782189A (en) * | 2010-12-01 | 2012-11-14 | 吉坤日矿日石金属株式会社 | Surface treatment agent for pd or alloy mainly composed of pd, and surface coating layer structure of copper surface |
JP5672548B2 (en) * | 2011-04-07 | 2015-02-18 | 有限会社アイエンジ | Hydrogen recovery device |
JP5850329B2 (en) * | 2012-02-28 | 2016-02-03 | 株式会社リコー | Fluid purification device |
DE102012016561B4 (en) * | 2012-08-22 | 2019-05-16 | Airbus Defence and Space GmbH | Aircraft fuel cell system and use thereof |
WO2017146589A1 (en) * | 2016-02-25 | 2017-08-31 | Hydrogen Mem-Tech As | Hydrogen production from natural gas in combination with injection of co2 for enhanced oil recovery |
JP7261235B2 (en) * | 2017-12-08 | 2023-04-19 | トプソー・アクチエゼルスカベット | System and method for synthesis gas production |
US11492255B2 (en) | 2020-04-03 | 2022-11-08 | Saudi Arabian Oil Company | Steam methane reforming with steam regeneration |
US11322766B2 (en) | 2020-05-28 | 2022-05-03 | Saudi Arabian Oil Company | Direct hydrocarbon metal supported solid oxide fuel cell |
US11639290B2 (en) | 2020-06-04 | 2023-05-02 | Saudi Arabian Oil Company | Dry reforming of methane with carbon dioxide at elevated pressure |
US20210395085A1 (en) * | 2020-06-18 | 2021-12-23 | Saudi Arabian Oil Company | Hydrogen Production with Membrane Reactor |
US11492254B2 (en) | 2020-06-18 | 2022-11-08 | Saudi Arabian Oil Company | Hydrogen production with membrane reformer |
US11583824B2 (en) | 2020-06-18 | 2023-02-21 | Saudi Arabian Oil Company | Hydrogen production with membrane reformer |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
WO2023162352A1 (en) * | 2022-02-28 | 2023-08-31 | 日本碍子株式会社 | Reactor module and separation membrane module |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5498278A (en) * | 1990-08-10 | 1996-03-12 | Bend Research, Inc. | Composite hydrogen separation element and module |
US5139541A (en) * | 1990-08-10 | 1992-08-18 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane |
US5393325A (en) * | 1990-08-10 | 1995-02-28 | Bend Research, Inc. | Composite hydrogen separation metal membrane |
US5217506A (en) * | 1990-08-10 | 1993-06-08 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane and uses thereof |
JPH04346824A (en) * | 1991-05-21 | 1992-12-02 | Mitsubishi Heavy Ind Ltd | Hydrogen separating membrane |
JPH0585702A (en) * | 1991-09-30 | 1993-04-06 | Mitsubishi Heavy Ind Ltd | Production of hydrogen separation membrane |
JP3117276B2 (en) * | 1992-04-09 | 2000-12-11 | 三菱重工業株式会社 | Hydrogen separation membrane |
JP3621785B2 (en) * | 1996-07-12 | 2005-02-16 | トヨタ自動車株式会社 | Hydrogen separation structure |
US6152987A (en) * | 1997-12-15 | 2000-11-28 | Worcester Polytechnic Institute | Hydrogen gas-extraction module and method of fabrication |
JP2001286742A (en) * | 2000-04-10 | 2001-10-16 | Mitsubishi Heavy Ind Ltd | Hydrogen separation membrane |
JP2002219341A (en) * | 2001-01-30 | 2002-08-06 | Kobe Steel Ltd | Supporting base for hydrogen-permselective membrane and hydrogen-permselective member |
FR2820988B1 (en) * | 2001-02-19 | 2003-04-25 | Cie D Etudes Des Technologies | COMPOSITE STRUCTURES OF SELECTIVELY HYDROGEN PERMEABLE MEMBRANES AND COMBUSTIBLE GAS PROCESSORS USING THE SAME |
DE10135390A1 (en) * | 2001-07-25 | 2003-02-20 | Fraunhofer Ges Forschung | Metallic solution-diffusion membrane, used for separating and purifying hydrogen for use in the electronics, metals and chemical industry, consists of a macroporous base body with a thin metallic membrane layer |
JP4782423B2 (en) * | 2002-09-05 | 2011-09-28 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | High purity hydrogen production apparatus and method |
JP2006520686A (en) * | 2003-03-21 | 2006-09-14 | ウスター ポリテクニック インスティチュート | Composite gas separation module with intermediate metal layer |
EP1622698B1 (en) * | 2003-05-02 | 2010-01-06 | Worcester Polytechnic Institute | Composite gas separation modules having high tamman temperature intermediate layers |
-
2005
- 2005-09-19 EP EP05798472A patent/EP1791631A1/en not_active Withdrawn
- 2005-09-19 TW TW094132239A patent/TW200624376A/en unknown
- 2005-09-19 WO PCT/US2005/033295 patent/WO2006034103A1/en active Application Filing
- 2005-09-19 JP JP2007532541A patent/JP2008513339A/en active Pending
- 2005-09-19 AU AU2005286955A patent/AU2005286955B2/en not_active Ceased
- 2005-09-19 CA CA002580279A patent/CA2580279A1/en not_active Abandoned
-
2007
- 2007-03-23 NO NO20071531A patent/NO20071531L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU2005286955B2 (en) | 2009-06-11 |
AU2005286955A1 (en) | 2006-03-30 |
WO2006034103A1 (en) | 2006-03-30 |
CA2580279A1 (en) | 2006-03-30 |
JP2008513339A (en) | 2008-05-01 |
NO20071531L (en) | 2007-06-20 |
EP1791631A1 (en) | 2007-06-06 |
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