TW200540309A - Filler-fixed fiber, fiber structure, molded fiber, and processes for producing these - Google Patents

Abstract

A filler-fixed fiber which comprises a fiber (2), a binder resin (1) disposed on the surface thereof, and a filler (3) fixed to the binder resin (1), wherein the binder resin (1) is a moisture/heat-gelling resin which gels upon heating in the presence of water and the filler (3) has been fixed to the gel obtained by causing the moisture/heat-gelling resin to gel. Due to this, the fiber (2) retains its fiber form and the gel formed by the gelation of the moisture/heat-gelling resin functions as a binder for fixing the filler (3).

Description

-200540309 九、發明說明： 【發明所屬之技術領域】 本i明係、關於-種將添加物（filler)附著於纖維表面之 加物附著纖維、纖維構造物、纖維成形體、以及其等之 製造方法。 【先前技術】 以往，於纖維表面附著添加物之方法，係提出於不織 布之表面以乾式法來載持粒子之後，加熱到纖維之軟化溫 度以^之溫度使得粒子附著之方法（下述專利文獻丨）。再 者，、提出了於含有粒子之水分散溶液中使得片狀或塊狀纖 維成型物含次、壓榨後，加熱至纖維之熔點乃至不超過纖 維熔點6(TC之溫度使得粒子附著之方法（下述專利文獻 2) 〇 ^再者，以往以來於纖維表面附著有添加物之纖維製品， 係使用於各種用途。例如，基於研磨與潔淨化目的之纖維 或布，在潔淨化目的之纖維方面一般已眾所皆知者為用以 研磨牙齒之長絲纖維（DENT.e_fl()ss)。纟工業用途上，研磨 布或研磨紙等係使用於透鏡、半導體、金屬、塑膠、陶瓷、 破璃等各種領域。再者於家庭用或業務用廚房等也使用著 研磨布。 ^ 又，由於吸入揮發性有機化合物（以下簡稱為V〇C)而 k成致病屋（sick house)症候群發生之增加，是以需要可將 〇c氣體等之有害氣體加以吸附之氣體吸附材。做為前述 氣體吸附材，例如於專利文獻3中係提出了對於v〇c氣 5 -200540309 體整體具有吸附效果之氣體吸附片。於專利文獻3所提出 之氣體吸附片’係於2片之片材間挾持活性碳粒子固定化、 並於前述片材當中至少一者之片材使得吸附劑粒子固定 化。在吸附劑粒子之固定化方法方面，可舉出例如⑴於黏 結劑樹脂溶液中混合吸附劑粒子然後塗佈於—者之片材 上’於其上重疊另一片材之方法；⑺事先於一者之片材塗 佈熱熔劑等，於其上散佈吸附劑粒子，進而於其上重疊另 一片材之方法。 再者，做為工廠廢水等淨化用水質淨化材，已提出使 用纖維狀活性碳、亦即使用活性碳纖維之錢水質淨化材 (例如專利文獻4等）。但是，使用活性碳纖維之水質淨化 材，會有構成活性碳纖維之活性碳在使用中脫落，造成淨 化性能惡化之虞。#者，尚有脫落之活性石炭混入淨化後之 液體中之虞°另—方面’於專利文獻5當中係提出了使得 活性碳粒+等之有機吸附性粒子透過不溶性減劑來附著 於片狀構件之水質淨化過濾器。 又附著物附著於纖維表面之纖維製品有纖維成形體 之形態。例如，已提出一種纖維成形體之製造方法，係將 粒子與黏結劑樹脂混合於纖維材料形成纖維鋼（fieece广並 =黏結劑樹脂做熔固來製造高體積墊之後，加壓成形為既 疋形狀者（下述專利文獻6)。再者，已提出一種立體成形 體，係將植物纖維、熱熔固性纖維、以及粉體狀或纖維狀 之機能性材料所構成之機能性纖維片以熱成形所成形者 述專利文獻7)。 6 •200540309 [專利文獻1]特開平7-268767號公報 [專利文獻2]特公昭51-22557號公報 [專利文獻3]特開2〇〇〇_246827號公報 [專利文獻4]特開9_234365號公報 [專利文獻5]特開平9_2〇1583號公報 [專利文獻6]特開平9_254264號公報 [專利文獻7]特開2〇〇4_52116號公報 但是若如前述專利文獻丨〜2般將纖維加熱至軟化溫度 或熔點以上之溫度，則纖維會收縮變硬，且在軟化溫度程 度粒子無法有效固定於纖維上，有時必須調整至溶點以 上之溫度，如此一來有無法保持纖維形態之問題。再者， 纖維會收縮變硬，甚至是做成不織布時有伴隨收縮而無法 保持不織布形態之問題。-200540309 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a kind of additive-attached fibers, fiber structures, fiber formed bodies, and the like that attach fillers to the surface of fibers Production method. [Prior art] In the past, a method of attaching an additive to a fiber surface was proposed to dry particles on a surface of a non-woven fabric, and then heat the fiber to a softening temperature of the fiber to attach the particles at a temperature of ^ (the following patent documents).丨). Furthermore, a method is proposed to make the sheet-like or block-shaped fiber molding in the water-dispersed solution containing particles sub-thin, and then press it to heat the fiber to a melting point of not more than 6 (the temperature of TC to make the particles adhere ( The following patent document 2) 〇 ^ Furthermore, conventionally, fiber products with additives attached to the fiber surface have been used for various purposes. For example, fibers or cloths for polishing and cleaning purposes, and fibers for cleaning purposes Generally known as filament fibers (DENT.e_fl () ss) for grinding teeth. 牙齿 In industrial applications, abrasive cloths or abrasive papers are used in lenses, semiconductors, metals, plastics, ceramics, Various fields such as glass. Abrasive cloths are also used in homes and business kitchens. ^ In addition, a sick house syndrome occurs due to inhalation of volatile organic compounds (hereinafter referred to as VOC). The increase is based on the need for a gas adsorbent that can adsorb harmful gases such as 0c gas. As the aforementioned gas adsorbent, for example, in Patent Document 3, 5-20 for voc gas is proposed. 0540309 A gas adsorbing sheet having an adsorption effect on the entire body. The gas adsorbing sheet proposed in Patent Document 3 is an activated carbon particle immobilized between two sheets, and at least one of the foregoing sheets makes Immobilization of adsorbent particles. For the method of immobilizing the adsorbent particles, for example, mixing the adsorbent particles in a binder resin solution and then coating the adsorbent particles on one of the sheets, superimpose another sheet thereon. (1) a method of coating hot melt agent on one sheet in advance, spreading adsorbent particles thereon, and then superimposing another sheet thereon. Furthermore, as a water purification material for purification of factory wastewater and the like It has been proposed to use fibrous activated carbon, that is, water purification materials using activated carbon fibers (for example, Patent Document 4). However, water purification materials using activated carbon fibers may cause the activated carbon constituting activated carbon fibers to fall off during use. It may cause deterioration of purification performance. In the case of #, there is a possibility that the fallen active charcoal may be mixed into the purified liquid. In addition, in Patent Document 5, it is proposed that Organic adsorbent particles such as carbon particles + are attached to the water purification filter of the sheet-like member through the insoluble reducing agent. The fibrous products that adhere to the surface of the fiber are in the form of fiber shaped bodies. For example, a fiber forming has been proposed The manufacturing method of the body is to mix the particles and the binder resin into the fiber material to form a fiber steel (fieece == binder resin is used to fuse to make a high-volume pad, and then press-molded into the existing shape (the following patent documents) 6). Furthermore, a three-dimensional shaped body has been proposed, which is formed by thermoforming a functional fiber sheet composed of plant fibers, thermosetting fibers, and powdery or fibrous functional materials. Document 7). 6 • 200540309 [Patent Document 1] JP 7-268767 [Patent Document 2] JP 51-22557 [Patent Document 3] JP 2000-246827 [Patent Document 4] ] Japanese Unexamined Patent Publication No. 9_234365 [Patent Document 5] Japanese Unexamined Patent Publication No. 9_2〇1583 [Patent Document 6] Japanese Unexamined Patent Publication No. 9_254264 [Patent Document 7] Japanese Unexamined Patent Publication No. 2004_52116 Generally, if the fiber is heated to a temperature above the softening temperature or melting point, the fiber will shrink and harden, and the particles cannot be effectively fixed to the fiber at the softening temperature. Sometimes it must be adjusted to a temperature above the melting point. Problems in maintaining fiber morphology. Furthermore, the fibers shrink and harden, and even when they are made into a non-woven fabric, there is a problem that the shape of the non-woven fabric cannot be maintained due to the shrinkage.

又，别述專利文獻3所提出之氣體吸附片中之前述（〇 之固疋化方法’會有吸附劑粒子埋沒於黏結劑樹脂溶液 中’無法得到充分氣體吸附效果之虞。又，前述⑺之固定 化方法，由於熱熔劑與吸附劑粒子之接觸面積少，乃有吸 附劑粒子脫落之虞。再者，於專利歧4所提出之氣體吸 附片’為了提高通氣性，於前述2片片材當中之至少一片 係使用多孔質片材，但是於 一疋於β亥2片片材之間挾持活性碳粒 * ’為了防止活性碳粒子脫落’必 粒徑調整為大於多孔皙κ妊夕具^_丨" 反祖十之 子㈣田最大孔#。是以，活性碳粒 ’、 。。卩01〜1 〇〇〇Μΐη之粒徑者，由於、圣吣山上1 # ^ ^ 田於活性碳粒子之比 積小，乃有無法得到充分氣體吸附效果之虞。 7 * 200540309 於别述專利文獻5所提出之水質淨化過濾器，會有 機吸附性粒子埋沒於黏結劑中，有機吸附性粒子之比表面 積減少，無法得到充分淨化性能之虞。 前述專利文獻6所提出之成形體，由於將粒子盘黏处 劑樹脂事先混合來將粒子固定於纖維表面，所以粒子會= :交於黏結劑樹脂中，無法充分發揮粒子所具功能，此：問 題所在。再者，於前述專利文獻7中，雖嘗試將熱炫固性 纖維加以炫㉞來使得粒子狀機能性材料固$，但以該方 法丄若未將熱炫固性纖維以相當高溫來溶融，則粒子無法 固定，若以高溫溶融又恐有收縮之虞，是以有時難以得到 均勻之成形體。又有時難以製作深抽成形體。 【發明内容】 本發明係用以解決上述習知問題，其目的在於提供一 種添加物附著纖維’可在保持原有纖維之性質的前提下有 效地附著於纖維表面；並提供一種纖維構造物可防止於 =表面所附著之添加物之脫落，可抑制添加物之比表面 卞咸少，適用於研磨材、氣體吸附材、水質淨化材等； 、、提ί、#纖維成形體，可將添加物有效地附著於纖維表 成形均勻、深抽之形狀，即使於一般之用途亦 i 成本本發明並提供前述添加物附著纖維、纖 維構‘物、纖維成形體之製造方法。 2明之添加物附著纖維’含有纖維、於該纖維表面 劑樹脂、以及於該黏結劑樹脂所附著之添加物；其 '於·该黏結劑樹脂為在水分存在下經加熱會凝膠化 8 •200540309 之濕熱凝膠化樹脂，該添加物係藉由該濕熱凝膠化樹脂經 凝膠化之凝膠化物來附著。 本發明之纖維構造物係含有添加物附著纖維，該添加 物附著纖維含有纖維、於該纖維表面之黏結劑樹脂、以及 於該黏結劑樹脂所附著之添加物；其特徵在於··該黏結劑 樹脂為在水分存在下經加熱會凝膠化之濕熱凝膠化樹脂， δ亥添加物係藉由該濕熱凝膠化樹脂經凝膠化之凝膠化物來 附著。 鲁 本發明之纖維成形體係纖維構造物所成形而得者，該 纖維構造物係含有纖維、於該纖維表面之黏結劑樹脂、以 及於该黏結劑樹脂所附著之添加物附著纖維；其特徵在 於：該黏結劑樹脂含有在水分存在下經加熱會凝膠化之濕 熱凝膠化樹脂，該纖維構造物中，該纖維係藉由該濕熱凝 膠化樹脂經凝膠化之凝膠化物來固定並成形為既定之形 狀。 本發明之添加物附著纖維之製造方法，係用以製造含 有纖維、於該纖維表面之黏結劑樹脂、於該黏結劑樹脂所 附著之添加物的添加物附著纖維；其特徵在於：該纖維以 及該黏結劑樹脂係在水分存在下經加熱而凝膠化之濕熱凝 膠化纖維，將溶液中分散有該添加物之添加物分散溶液賦 予於忒濕熱凝膠化纖維，其次，在濕熱環境氣氛下對該濕 熱减膠化纖維進行濕熱處理，使得該濕熱凝膠化纖維凝膠 化’以凝膠化物將該添加物附著於纖維表面。 本發明之添加物附著纖維之其他製造方法，係用以製 9 • 200540309 ^ έ有纖維、於該纖維表面之黏結劑樹脂、於該黏結劑樹 脂所附著之添加物的添加物附著纖維；其特徵在於：該纖 維與該黏結劑樹脂係其他纖維與濕熱凝膠化樹脂，對該其 他纖維賦予該濕熱凝膠化樹脂之後再賦予添加物，或是將 溶液中分散有該添加物以及該濕熱凝膠化樹脂之添加物分 散溶液賦予於該其他纖維，其次，在濕熱環境氣氛下進行 濕熱處理將該濕熱凝膠化樹脂凝膠化，以凝膠化物將該添 加物附著於其他纖維表面。 本發明之纖維構造物之製造方法，係用以製造含有添 加物附著纖維之纖維構造物，該添加物附著纖維含有纖 維、於該纖維表面之黏結劑樹脂、以及於該黏結劑樹脂所 附著之添加物；其特徵在於：該黏結劑樹脂為在水分存在 下‘加熱會凝膠化之濕熱凝膠化樹脂，該纖維以及該黏結 劑樹脂係擇自 (I )含有濕熱凝膠化樹脂纖維成分與其他熱塑性合成 纖維成分之複合纖維； (Π )該複合纖維與其他纖維所混合而成者； (ΠΙ)該複合纖維與濕熱凝膠化樹脂所混合而成者； (IV)濕熱凝膠化樹脂與其他纖維所混合而成者，· 中至J 一種的組合，以該纖維以及該黏結劑樹脂來製 作纖維構造物，將溶液中分散有該添加物之添加物分散溶 液賦予於該纖維構造物，其次，在濕熱環境氣氛下對該濕 熱凝膠化樹脂進行濕熱處理，使得該濕熱凝膠化樹脂凝膠 化，以凝膠化物將該添加物附著於纖維表面來形成添加物 .200540309 附著纖維。 ▲本發明之纖維成形體之製造方法，係用以製造由纖維 構造物所成形而得之纖維成形體，該纖維構造物含有纖 維、於該纖維表面之黏結劑樹脂、於該黏結劑樹脂所附著 之’』、、加物附著纖維，其特徵在於，該黏結劑樹脂係含有藉 在欠刀存在下加熱而凝膠化之濕熱凝膠化樹脂，形成含 有該纖維與黏結劑樹脂之纖維構造物，使得該纖維構造物 在金屬模具内、濕熱環境氣氛下將該濕熱凝膠化樹脂濕熱 减膠化做濕熱成形加工。 【實施方式】 於本發明中’做為在水分存在下加熱可凝膠化之黏結 劑樹脂，係使用濕熱凝膠化樹脂。濕熱凝膠化樹脂之形態 可舉出粉末狀、尖突（tip)狀、纖維狀等。特別是，濕熱凝 膠化樹脂以纖維狀為佳。做為纖維狀之濕熱凝膠化樹脂（以 下稱為「濕熱凝膠化纖維」）可使用濕熱凝膠化樹脂單獨之 纖維、或是含有濕熱凝膠化樹脂纖維成分與其他熱塑性合 成纖維成分之複合纖維（以下稱為「濕熱凝膠化複合纖 維」）。藉此，其他纖維或是至少其他熱塑性合成纖維成分 可保持纖維形態，且濕熱凝膠化樹脂可被凝膠化而發揮可 將添加物加以附著之黏結劑的作用功能。再者，添加物可 藉由濕熱凝膠化樹脂纖維成分或是於纖維表面所附著之濕 熱凝膠化樹脂經濕熱凝膠化之凝膠化物來被附著。較佳為 添加物係外露而附著。又，濕熱凝膠化樹脂彼此以及/或是 其他纖維可藉由濕熱凝膠化樹脂纖維成分或是於纖維表面 11 ^ 200540309 所附著之濕熱凝膠化樹脂經濕熱凝膠化所得之凝膠化物來 固定。 又，本發明之纖維成形體可藉由在金屬模具内使得纖 維構造物凝膠化之狀態下進行濕熱成形，來成形為既定形 狀之成形體。濕熱凝膠化樹脂之形態可舉出粉末狀、尖突 狀、纖維狀等。特別是，若考慮成形加工性，以纖維狀、 亦即濕熱凝膠化纖維為佳。In addition, in the gas adsorption sheet proposed in Patent Document 3, the above-mentioned (the solidification method of 0) may cause the adsorbent particles to be buried in the binder resin solution, and may not obtain a sufficient gas adsorption effect. In the immobilization method, because the contact area between the hot melt agent and the adsorbent particles is small, the adsorbent particles may fall off. In addition, the gas adsorption sheet proposed in Patent No. 4 is used to improve the air permeability. At least one of the materials is a porous sheet, but the activated carbon particles are held between the two sheets of βH2 sheet * 'In order to prevent the activated carbon particles from falling off', the particle size must be adjusted to be larger than porous _ 丨 " The son of anti-ancestor ten ㈣ 田 最 孔 #. It is the activated carbon particles', 卩 01 ~ 1 〇〇〇〇〇〇Ｍ〇η particle size, because, Shengtuoshan 1 # ^ ^ Tian Yu activated carbon The specific volume of the particles is small, so there is a risk that a sufficient gas adsorption effect cannot be obtained. 7 * 200540309 In the water purification filter proposed in Patent Document 5 mentioned above, the organic adsorbent particles are buried in the binder, and the organic adsorbent particles The surface area is reduced, and sufficient purification performance may not be obtained. In the molded body proposed in the aforementioned Patent Document 6, the particle disk adhesive resin is mixed in advance to fix the particles on the fiber surface, so the particles are =: Intersect in the binder resin The function of particles cannot be brought into full play, this is the problem. Furthermore, in the aforementioned Patent Document 7, although an attempt was made to dazzle the thermosetting fiber to make the particulate functional material solid, but in this way, If the heat-resistant solid fiber is not melted at a relatively high temperature, the particles cannot be fixed. If it is melted at a high temperature, there is a fear of shrinkage, so it is sometimes difficult to obtain a uniform shaped body. Sometimes it is difficult to produce a deep-drawn shaped body. [Summary of the Invention] The present invention is to solve the above-mentioned conventional problems, and the purpose thereof is to provide an additive-attached fiber 'which can effectively adhere to the fiber surface while maintaining the properties of the original fiber; and to provide a fiber structure It can prevent the additives attached on the surface from falling off, can suppress the additives from being less salty than the surface, and is suitable for abrasive materials, gas adsorption materials, water Quality purification materials, etc., ， 提 ί ， # Fiber forming body, can effectively add additives to the fiber surface to form a uniform, deep-drawing shape, even for general use. The present invention also provides the aforementioned additive-attached fibers 2. A method for manufacturing a fibrous structure and a fibrous formed body. 2 Additives attached to the fiber include fibers, an additive to the fiber surface resin, and an additive to the adhesive resin; and the adhesive resin In order to moisturize and gel the resin 8 • 200540309 in the presence of moisture, the additive is adhered by the gelled gel of the moist and gelled resin. The fiber structure of the present invention It contains additive-attached fibers containing fibers, a binder resin on the surface of the fibers, and additives attached to the binder resin; characterized in that the binder resin is in the presence of moisture The moist heat gelled resin that gels when heated, and the δH additive is adhered by the gelled gel of the moist heat gelled resin. The fiber structure of the fiber forming system of the present invention is obtained by forming a fiber structure. The fiber structure contains fibers, a binder resin on the surface of the fibers, and an additive-attached fiber attached to the binder resin. : The binder resin contains a moist heat gelling resin that will gel when heated in the presence of moisture. In the fiber structure, the fibers are fixed by the gelled gel of the moist heat gelling resin. And formed into a predetermined shape. The manufacturing method of the additive-attached fiber of the present invention is used for manufacturing an additive-attached fiber containing the fiber, a binder resin on the surface of the fiber, and an additive attached to the binder resin; The binder resin is a moist heat-gelated fiber that is gelled by heating in the presence of moisture, and the additive dispersion solution in which the additive is dispersed in the solution is imparted to the moist heat-gelated fiber. Secondly, in a moist heat environment atmosphere Next, the moist heat degelatinized fiber is subjected to a wet heat treatment, so that the moist heat gelled fiber is gelled, and the additive is attached to the surface of the fiber as a gel. The other manufacturing method of the additive-adhered fiber of the present invention is used to prepare the additive-adhered fiber having a fiber, a binder resin on the surface of the fiber, and an additive attached to the binder resin; It is characterized in that the fiber and the binder resin are other fibers and the moist heat-gelation resin, and the moist heat-gelation resin is added to the other fibers and then additives are added, or the additive and the moist heat are dispersed in the solution. The additive dispersion solution of the gelled resin is imparted to the other fibers. Next, a wet heat treatment is performed in a humid hot ambient atmosphere to gel the moist heat gelled resin, and the additive is adhered to the surface of the other fibers as a gel. The method for manufacturing a fibrous structure of the present invention is used for manufacturing a fibrous structure containing an additive-attached fiber containing fibers, a binder resin on a surface of the fiber, and a resin to which the binder resin is attached. The additive is characterized in that the binder resin is a moist heat gelling resin that will gel when heated in the presence of moisture, and the fiber and the binder resin are selected from (I) containing a moist gelling resin fiber component Composite fibers with other thermoplastic synthetic fiber components; (Π) The composite fiber is mixed with other fibers; (ΠΙ) The composite fiber is mixed with a moist gelling resin; (IV) Moist gelling Resin and other fibers are mixed, · A medium to J combination, the fiber and the binder resin are used to make a fiber structure, and an additive dispersion solution in which the additive is dispersed in the solution is given to the fiber structure Secondly, the wet heat gelled resin is subjected to a wet heat treatment in a humid hot ambient atmosphere, so that the wet heat gelled resin is gelled, and Additive adhered to the fiber surface to form the additive .200540309 adhered fibers. ▲ The manufacturing method of the fiber shaped body of the present invention is used for manufacturing a fiber shaped body formed from a fiber structure. The fiber structure contains fibers, a binder resin on the surface of the fibers, and a binder resin. Attachment '", and additive-attached fibers, characterized in that the binder resin contains a moist heat gelling resin that gels by heating in the presence of an underknife to form a fibrous structure containing the fiber and the binder resin Material, so that the fibrous structure is wet-moisturized and de-gelatinized in a metal mold under a moist-heat environment to perform moist-heat forming processing. [Embodiment] In the present invention, as the binder resin which can be gelled by heating in the presence of moisture, a moist gelling resin is used. Examples of the form of the moist gelled resin include powder, tip, and fiber. In particular, it is preferable that the wet heat gelled resin is fibrous. As the fibrous moist gelling resin (hereinafter referred to as "moist gelling fiber"), the fiber of the moist gelling resin alone, or the fiber containing the moist gelling resin fiber component and other thermoplastic synthetic fiber components may be used. Composite fiber (hereinafter referred to as "hygrothermal gelled composite fiber"). Thereby, other fibers or at least other thermoplastic synthetic fiber components can maintain the fiber morphology, and the moist heat gelled resin can be gelled to function as a binder capable of adhering additives. Furthermore, the additive may be adhered by the moist heat-gelatinized resin fiber component or the moist heat-gelated gelation product of the moist heat-gelated resin adhered to the fiber surface. It is preferable that the additive is exposed and adhered. In addition, the moist heat gelled resins and / or other fibers can be obtained by moist heat gelled resin fiber components or gelled products obtained by moist heat gelation of moist heat gelled resin attached to the fiber surface 11 ^ 200540309. To fix. In addition, the fibrous formed body of the present invention can be formed into a shaped body having a predetermined shape by subjecting the fibrous structure to gelation in a metal mold to wet-moulding. Examples of the form of the moist gelled resin include a powdery shape, a spike shape, and a fibrous shape. In particular, in consideration of the formability, it is preferable to use fibrous fibers, that is, moist gelled fibers.

前述濕熱凝膠化樹脂之較佳凝膠化溫度為50〇c以上。 更佳之凝膠化溫度為80°C以上。若使用能在未滿50°c凝 膠化之樹脂，有時於凝膠加工之際會嚴重黏附於輥子或金 屬模具等造成纖維構造物與纖維成形體之生產變得困難， 或是在盛夏或高溫環境無法使用。又，所謂的「凝膠加工_ 係使得濕熱凝膠化樹脂凝膠化之加工。 月’J述濕熱凝膠化樹脂以乙烯一乙烯醇共聚樹脂為佳。 其理由在於，可藉由濕熱而凝膠化，避免其他纖維以及/或 是其他熱塑性合成纖維成分變質之故。所說的乙烯一乙烯 醇八聚树月曰’係使得乙烯—乙酸乙烯酯鹼化所得之樹脂， 其鹼化度以95%以上兔4 ^ 為佳。更佳之鹼化度為98%以上。又， 較佳之乙稀含有率為# π 莫爾/〇以上。較佳之乙浠含有率為 5 〇莫爾％以下。更佳之7" 之乙烯含有率為25莫爾％以上。更伟 之乙烯含有率為45莫爾％以τ # 、 乂下。若驗化度未滿95%有時於 凝膠加工之際會黏附於 、 ,、 於親子或金屬模具等造成纖維構造物 〃纖維成形體之生產變得 装爾又，乙烯含有率為未滿20 莫爾/〇的情況也同樣，有 另呀於凝膠加工之際會黏附於觀子 12 ^ 200540309 或金屬模具等造成纖維構造物盥_ ，、纖維成形體之生產變得困 難。另一方面，若乙烯含有量超過 ^川莫爾/〇，則濕熱凝膠 化溫度會變高，不得不將加工溫产 /皿度上升至熔點附近，其社 果，有時會對於纖維構造物與纖維 ° 私唯成形體之尺寸安定性造 成不良影響。 前述纖維與前述黏結劑樹脂之較佳組合可舉出 ⑴含有濕熱凝膠化樹脂纖維成分與其他熱塑性 纖維成分之複合纖維； (π)該複合纖維與其他纖維所混合而成者； (瓜）該複合纖維與濕熱凝膠化樹脂所混合而成者； (iv)濕熱凝膠化樹脂與其他纖維所混合而成者； …t中至少一種（以下稱為「形態（1)〜形態（IV)」）。前述 形憑⑴係以「黏結劑樹脂」做為濕熱凝膠化樹脂，以「纖 維」做為其他熱塑性合成纖維成分之濕熱凝膠化複合纖 、隹别述形態（π )係以「黏結劑樹脂」做為濕熱凝膠化複 口纖維，以「纖維」做為其他纖維所混合而成者。前述形 。（ΠΙ)係以纖維」做為濕熱凝膠化複合纖維，並以「黏 結劑樹脂」做為濕熱凝膠化樹脂所混合而成者。前述形態（IV) 系乂黏結劑樹脂」做為採取前述濕熱凝膠化複合纖維以 外之形悲的濕熱凝膠化樹脂（例如濕熱凝膠化樹脂單獨之纖 、准）以「纖維」做為其他纖維所混合而成者。 於别述形態（I )〜（UJ)所使用之濕熱凝膠化複合纖維， 以濕熱凝膠化樹脂纖維成分露出或是部份區分之複合纖維 為佳。其複合形狀係指同心圓型、偏心芯套型、並列型、 13 -200540309 分割型、海島型等。特別是同心圓型以添加物容易附著於 纖維表面為佳。又，其截面形狀可為圓形、中空、異型、 擴圓形、星形、扁平形等任一，從纖維製造之難易程度來 考量以圓形為佳。分割形複合纖維以事先噴射高壓水流等 做部分性分割為佳。藉此，經分割之濕熱凝膠化樹脂纖維 成分可藉由濕熱處理來凝膠化，形成凝膠化物來附著於其 他纖維表面，將添加物附著。亦即，發揮黏結劑之功能。 於該濕熱凝膠化複合纖維所佔濕熱凝膠化樹脂纖維成 分之比例以10質量％〜90質量％之範圍内為佳。更佳之濕 熱凝膠化樹脂纖維成分的含有量為3〇質量％〜7〇質量％。 若濕熱凝膠化樹脂纖維成分之含有量未滿1〇質量％，添加 物有難以附著之傾向。若濕熱凝膠化樹脂纖維成分之含有 量超過90質量％，則複合纖維之纖維成形性有降低之傾 向。 前述濕熱凝膠化複合纖維中之其他熱塑性合成纖維成 分，可為聚烯烴、聚酯、聚醯胺等，較佳為聚稀烴。使用 乙烯一乙烯醇系共聚樹脂當作濕熱凝膠化樹脂纖維成分的 清況谷易形成以熔融紡絲所構成之複合纖維（組合纖維）。 又’做為其他熱塑性合成纖維成分，以使用具有炼點 高於用以將濕熱凝膠化樹脂纖維成分凝膠化之溫度的熱塑 性合成纖維成分為佳。若其他熱塑性合成纖維成分為具有 炫點低於用以形成凝膠化物之溫度之熱塑性合成纖維成 分，則其他熱塑性合成纖維成分本身有熔融變硬之傾向， 例如做成纖維成形體時有時會伴隨收縮而成為不均勻。 •200540309 前述濕熱凝膠化複合纖維在纖維構造物中所佔之比例 只要是可將添加物附著之量即可並無特別限定，藉由凝膠 化物將纖維固定以及/或是將添加物有效固定所需之複合纖 維的比例以H)質量％以上為佳。更佳之複合纖維之比例為 30質量％以上。特佳之複合纖維之比例為5〇質量％以上。 例如，當纖維構造物係含有複合纖維之纖維網存在於兩表 面’内部存在其他纖維的情況’係指含有複合纖維之纖維 網的含有量。A preferable gelatinization temperature of the aforementioned moist gelling resin is 50 ° C or higher. A more preferred gelation temperature is above 80 ° C. If a resin that can be gelled at less than 50 ° C is used, it may be severely adhered to rollers or metal molds during gel processing, which may make the production of fiber structures and fiber formed bodies difficult, or in midsummer or Unusable in high temperature environments. In addition, the so-called "gel processing_" refers to a process for gelling a moist heat-gelation resin. The month's moist heat-gelation resin is preferably an ethylene-vinyl alcohol copolymer resin. The reason for this is that moist heat can be used to Gelation, to avoid the deterioration of other fibers and / or other thermoplastic synthetic fiber components. The ethylene-vinyl alcohol octamer is the resin obtained by alkalizing ethylene-vinyl acetate, and its alkalinity It is preferably 95% or more rabbits. The more preferable degree of alkalinity is 98% or more. Also, the preferred ethylenic content is # πmol / 0 or more. The preferred ethylpyridine content is 50mol% or less. . Better 7 " The ethylene content is more than 25 mol%. The more powerful ethylene content is 45 mol% with τ #, 乂. If the test degree is less than 95%, it may occur during gel processing. The production of fibrous structures and fiber moldings due to adhesion to parents, children, or metal molds becomes more complicated, and the same applies to the case where the ethylene content is less than 20 Moore / 〇, and there is another problem in gel processing. At the time, it will stick to Guanzi 12 ^ 200540309 or metal molds. It is difficult to produce fibrous structures and fiber molded products. On the other hand, if the ethylene content exceeds ^ Chuan Moore / 〇, the moist heat gelation temperature will increase, and the processing temperature will have to be increased. When the temperature rises to the vicinity of the melting point, the social effects may adversely affect the dimensional stability of the fiber structure and the fiber °. The preferred combination of the fiber and the binder resin includes moist heat. Composite fibers of gelled resin fiber components and other thermoplastic fiber components; (π) The composite fibers are mixed with other fibers; (Melon) The composite fibers are mixed with moist gelled resin; (iv) ) A mixture of moist heat gelled resin and other fibers; at least one of t (hereinafter referred to as "form (1) to form (IV)"). The aforementioned shape is based on the "hygrothermal gelled resin" with "binder resin" as the moist heat gelled resin, and "fiber" as other thermoplastic synthetic fiber components, and the other form (π) is based on the "bond agent" "Resin" is a moist-heat gelled composite fiber, and "fiber" is a mixture of other fibers. The aforementioned shape. (II) is made by mixing fibers as moist heat-gelated composite fibers and "binder resin" as moist heat-gelated resin. The above-mentioned form (IV) series of “bond resin” is used as the moist heat gelled resin other than the aforementioned moist heat gelled composite fiber (for example, the fiber of the moist heat gelled resin alone, and the standard) is “fiber”. Blended with other fibers. For the wet-heat-gelated composite fibers used in the other forms (I) to (UJ), the composite fibers in which the moisture-heat-gelated resin fiber components are exposed or partially distinguished are preferred. Its composite shape refers to concentric circle type, eccentric core sleeve type, side-by-side type, 13-200540309 split type, sea-island type, etc. In particular, it is preferable that the concentric circle type has an additive that easily adheres to the fiber surface. The cross-sectional shape may be any of circular, hollow, irregular, rounded, star-shaped, and flat shapes. A circular shape is preferred in terms of the ease of fiber manufacturing. The split composite fiber is preferably partially split by spraying high-pressure water in advance. Thereby, the divided moist heat-gelatinized resin fiber component can be gelled by wet heat treatment to form a gelatinous substance to adhere to the surface of other fibers, and to attach the additive. That is, it functions as an adhesive. The proportion of the moist gelled resin fiber component in the moist gelled composite fiber is preferably within a range from 10% by mass to 90% by mass. A more preferable content of the moisture-thermogelable resin fiber component is 30% to 70% by mass. If the content of the moist heat gelled resin fiber component is less than 10% by mass, the additive tends to be difficult to adhere. If the content of the moist heat gelled resin fiber component exceeds 90% by mass, the fiber formability of the composite fiber tends to decrease. The other thermoplastic synthetic fiber components in the aforementioned moist-heat-gelled composite fiber may be polyolefins, polyesters, polyamides, etc., and are preferably polyolein. Qingxinggu, which uses an ethylene-vinyl alcohol copolymer resin as the fiber component of the moist gelled resin, easily forms a composite fiber (combined fiber) composed of melt spinning. As another thermoplastic synthetic fiber component, it is preferable to use a thermoplastic synthetic fiber component having a melting point higher than a temperature for gelling the moist heat gelled resin fiber component. If the other thermoplastic synthetic fiber component is a thermoplastic synthetic fiber component having a dazzling point lower than the temperature for forming a gel, the other thermoplastic synthetic fiber component itself tends to melt and harden, for example, it may sometimes be formed into a fiber formed body. It becomes uneven with shrinkage. • 200540309 The proportion of the above-mentioned moist gelled composite fiber in the fiber structure is not particularly limited as long as it can attach the additive. The fiber is fixed by the gel and / or the additive is effective. The proportion of the composite fibers required for the fixation is preferably H)% by mass or more. A more preferable ratio of the composite fiber is 30% by mass or more. The proportion of particularly good composite fibers is 50% by mass or more. For example, when a fibrous structure containing a fiber web containing composite fibers is present on both surfaces, 'where other fibers are present' means the content of the fiber web containing composite fibers.

在前述形態（瓜）中m濕熱凝膠化複合纖維進— :含有濕熱凝膠化樹脂而於複合纖維表面形成凝膠化物。 藉此，可進一步提升添加物之附著效果。 於前述形態（Π)或是形態（IV)所使用之其他纖維，可選 擇使用人造絲等之化學纖維、棉、麻、羊毛等之天然纖維 等、聚烯烴樹脂、聚酯樹月旨、聚酿胺樹脂、丙烯酸樹脂、 聚胺基甲酸S旨樹脂等合成樹脂之單獨或複數成 > 之合成纖 維專任意之物。 於前述形態（IV)中，濕熱凝膠化樹脂相對於纖維構造 物以含有1質量％〜90質量％之範圍内為佳。更佳之含有量 為3質量％〜70質量％。若濕熱凝膠化樹脂之含有量未滿！ 質量％，要藉由凝膠化物來固定其他纖維會有困難，或是 有添加物變得難以附著之傾向。若濕熱凝膠化樹脂之含有 里超過90貝里％，有時纖維形狀會消失而成為薄膜狀、或 是添加物埋沒於凝膠化物中。 前述添加物只要是粒子即可能使用任意物質。例如， 15 ^ 200540309 添加物以無機粒子為佳。尸 栋m ^ h主、 、為“、、機粒子，則做為研磨劑 使用的t月況，研磨作用顯著。 一新#坊_ , 引砍無機粒子可舉出氧化鋁、 、二聚鱗酸釣（trip〇〗y)、鑽$ 、p y)鑽石、剛玉、剛砂、石 =:1石、合成鑽石、氣化，、碳切、碳化硼、氧 … 氧化鐵、石夕酸膠體'碳、石墨、沸石、二 乳化鈦、兩嶺土、黏土等。該等粒子可適宜混合使用。 :添加物為氣體吸附性粒子的情況，氣體吸附性粒子In the aforementioned form (melon), the m-thermogelatinized composite fiber contains a moist-gelatinized resin and forms a gel on the surface of the composite fiber. This can further improve the adhesion effect of the additives. For the other fibers used in the aforementioned form (Π) or form (IV), chemical fibers such as rayon, natural fibers such as cotton, linen, and wool, polyolefin resins, polyester trees, and polyester Synthetic resins such as amine resins, acrylic resins, and polyurethane S resins can be used alone or in combination as synthetic fibers. In the aforementioned aspect (IV), the moist gelled resin is preferably contained in a range of 1 to 90% by mass based on the fiber structure. A more preferable content is 3 to 70% by mass. If the content of the moist gelling resin is not full! Mass%, it may be difficult to fix other fibers with a gel, or the additive tends to be difficult to adhere. If the content of the moist gelling resin exceeds 90 bery, the fiber shape may disappear and become a thin film, or the additive may be buried in the gel. As long as the said additive is a particle, arbitrary substances can be used. For example, 15 ^ 200540309 additives are preferably inorganic particles. The corpse m ^ h is composed of main particles, and particles, and is used as an abrasive. The grinding effect is significant. Yixin # 坊 _, Aluminium oxide, dimeric scales can be cited as the inorganic particles. Acid fishing (trip〇〗 y), diamond $, py) diamond, corundum, corundum, stone =: 1 stone, synthetic diamond, gasification, carbon cutting, boron carbide, oxygen ... iron oxide, stone acid colloid ' Carbon, graphite, zeolite, di-emulsified titanium, amphibious clay, clay, etc. These particles can be mixed and used appropriately.: When the additive is a gas-adsorbing particle, the gas-adsorbing particle

㈣μ中之氣體物質加以吸附之功能者即可並 …、特別限I又以活性碳粒子、沸石、石夕膠、活性白土、 層狀鱗酸鹽等之多孔質粒子、於該等多孔質粒子擔載化學 吸附劑之多孔質粒子等為佳。於多孔質粒子當中又以活性 碳粒子為特佳、 ▲前述添加物為有機物吸附性粒子的情況，有機物吸 附性粒子只要是具有可將液體中之有機物予以吸附之功能 者即可並無特別限定，以活性碳粒子、沸石、矽膠、活性 白土、層狀磷酸鹽等之多孔質粒子、於該等多孔質粒子擔 載化學吸附劑之多孔質粒子等為佳。力多孔質粒子當中又 以活性碳粒子為特佳。 再者除了前述研磨劑、氣體吸附性粒子以及有機物吸 附性粒子以外，亦可使用做為乾燥劑之矽膠、做為光觸媒 之一氧化鈦、病毒吸附/分解劑、抗菌劑、除臭劑、導電劑、 抗電劑、調濕劑、防蟲劑、防黴劑、難燃劑等之功能性添 加物之1種或2種以上。 前述添加物之平均粒徑以〇·〇1〜1〇0μπι之範圍為佳。 16 200540309 更仏之平均粒梭為〇瓜以上、 上。# 4 ^ 符佳之千均粒徑為Ιμπί以 更佳之平均粒徑為8〇陣以下。若 〇·〇1_，則有時添加物會埋沒於凝膠。另：：未滿 若平均粒徑超過-^ = = 果。 传到充分之添加物之功能、例如氣體吸附效 :述纖維構造物係含有纖維以及黏結 ,Γ:::構造物係指由纖維束、纖維塊、不織布、編織 ”網專之纖維所形成者。特別是由於不織 二二有：各種用途。例如，做為本發明之纖維構 有液體之研磨不織布來使用的情況， 著纖維於兩表面以纖唯, 添加物附 為佳… 維網狀存在，内部存在著親水性纖維 為佳。則述親水性纖維以擇自 漿中至少-種““擇自人m维、棉纖維以及紙 劑、、先㈣^ 其理由在於，賦予水、界面活性 μ 4之液體進行研磨之際，水分保持性高之故。 ，附性粒實施形態，例如在添加物方面使用氣體吸 ,,/ 附材’不限定於不織布，亦能為以該添 =附著纖維所形成之複數束纖維束做為氣氣 :吸附模組。另外，亦可將該添加物附著纖維…物； %成圓筒狀者、成形為打擅 八 用。又，使用有機物附著性二吸附過_使 並不限定於不織布，亦了/ 物之水質淨化材 成之#uMh 該添加物附著纖維複數束形 L纖維束做為有機物吸附部之水質淨化模組。又，亦可 、4添加物附著纖維之集合物捲繞成圓筒狀者、成形為打 17 •200540309 指狀者當做水質淨化過遽器來使用。 構造物以金屬模具做成形加工之際，纖維 ‘、、、右為不織布，則製造成本便宜，加 也谷易’ μ加工成艰主 全屬描且… 容易適度伸長而順沿 眉U形狀，容易得到深抽成形體。 纖維構造物之較佳的單位面 20g/m2〜600g/m2。纖维 里里馮 纖維構每物之較佳厚度（2.94cN/cm2負荷） 為0.1mm〜3mm之範圍。The function of adsorbing gaseous substances in ㈣μ can be combined with ..., especially limited I, and porous carbon particles such as activated carbon particles, zeolite, stone gum, activated clay, layered phosphonate, etc. Porous particles and the like supporting a chemical adsorbent are preferred. Among the porous particles, activated carbon particles are particularly preferred. ▲ In the case where the aforementioned additive is an organic substance adsorbing particle, the organic substance adsorbing particle is not particularly limited as long as it has a function of adsorbing organic substances in a liquid. Preferably, porous carbon particles such as activated carbon particles, zeolite, silica gel, activated clay, layered phosphate, etc., and porous particles on which the chemical adsorbent is supported on the porous particles are preferred. Among the porous particles, activated carbon particles are particularly preferred. In addition to the aforementioned abrasives, gas-adsorbing particles, and organic-adsorbing particles, it is also possible to use silica gel as a desiccant, titanium oxide as a photocatalyst, virus adsorption / decomposition agent, antibacterial agent, deodorant, and conductive agent. One or two or more functional additives such as agents, anti-electric agents, humidity regulators, insect repellents, mold inhibitors, and flame retardants. The average particle diameter of the additive is preferably in the range of 0.001 to 100 μm. 16 200540309 The average grain shuttle is more than 0%. # 4 ^ Fu Jiazhi has a thousand-average particle size of Ιμπί and a better average particle size is less than 80 arrays. If 〇 · 〇1_, the additive may be buried in the gel. In addition :: not full If the average particle size exceeds-^ = = fruit. The function of sufficient additives, such as gas adsorption effect: the fiber structure contains fibers and bonds, Γ ::: structure refers to the fiber formed by fiber bundles, fiber blocks, non-woven fabrics, and woven fabrics .Especially because of the non-woven two kinds: various uses. For example, as the fibrous structure of the present invention is used in the case of liquid abrasive non-woven fabrics, the fibers are fibrous on both surfaces, and the additives are better ... It is better to have hydrophilic fibers in the interior. The hydrophilic fibers are selected from at least one kind of "" selected from human m-dimensional, cotton fibers and paper agents, and firstly selected from the pulp. The reason is that it provides water and an interface. When the liquid with the activity of μ 4 is ground, the moisture retention is high. The embodiment of the additive granules, such as the use of gas absorption in the additive aspect, / The appendix 'is not limited to non-woven fabrics, but can also be used to add this = The multiple fiber bundles formed by the attached fibers are used as a gas-air: adsorption module. In addition, the additives can also be attached to the fibers ... Sex two adsorbed_ It is not limited to non-woven fabrics, but also the water purification material of the material #uMh This additive-attached fiber plurality of bundled L fiber bundles are used as the water purification module of the organic substance adsorption section. Also, 4 additives can be attached to the fiber The aggregate is wound into a cylindrical shape and shaped into a shape. • 200540309 The finger is used as a water purification purifier. When the structure is formed by a metal mold, the fibers',, and right are non-woven fabrics. The manufacturing cost is cheap, and Kayagu's μ is processed into all the main parts and ... It is easy to moderately stretch and follow the U shape of the eyebrow, and it is easy to obtain a deep-drawn shaped body. The preferred unit surface of the fiber structure is 20g / m2 ~ 600g / m2. The preferred thickness (2.94cN / cm2 load) of each fiber in the fiber is in the range of 0.1mm ~ 3mm.

前述纖維構造物為了使得添加物之功能性有效發揮， 前述添加物之附著量對於纖維構造物每im2w 2 佳，以10g以上為更佳，％以上為特佳。 其-人針對本發明之添加物附著纖維以及纖維構造物 之製造方法做說明。本發明Φ夕、爲為老 +赞月中之濕熱處理係以濕熱環境氣 氛來施行。此處所說的「濕熱環境氣氛」，意指包含水分 而被加熱之環境氣氛。所謂的濕熱處理，係對於職予了黏 結劑樹脂之纖維、含有濕熱凝膠化纖維成分之纖維、或是 含有該等纖維之纖維構造物賦予例如含有、添加物之添加物 分散溶液之後進行加熱之處理、或是一邊賦予前述添加物 分散溶液-邊加熱之處理。加熱方法可舉出暴露於加熱環 境氣氛中之方法、使貫通加熱空氣中之方法、以及使其與 加熱體接觸之方法等。 賦予前述添加物分散溶液後進行加熱的情況，對於濕 熱處理中之纖維或是纖維構造物所賦予之水分的此例（以; 稱為「水分率」）以20質量％〜800質量。/。為佳。更佳之水 18 •200540309 分率為30質量％〜700質量％。再更佳之水 %〜600質量％。水分率若未滿2〇 旦 ’、、、 質置 無法充分產生。另一方面，若水分率：膠化 濕熱處理在纖維構造物表面與内部 '里/。，則 熱凝膠化之程度有不均勻之傾向。又，水分之賦丁去： 以喷霧、浸潰於水槽中等眾知方法來進行。特別日方法月匕 添加物分散溶液含浸於纖維構造物之方法，：得：： 添加物進入纖維構造物内部，故為所喜好者。:大1 分之纖維或纖維構造物可利用擠㈣ 2水 整為既定之水分率。 作寺方法來調 膠丄，凝 調整添加物分 之溫度來調整添加物之附著量即可。刀放冷液 維或纖維構造物含浸於含有添力““：體而§，藉由將纖 可將添加物附著於纖:二一 -==::=Γ行親水處理。若施 對織維構造物大致=::::疎:::維=況，可 在親水處理方而 匆附者，故為所吾好者。 光放電法、電^可舉出界面活性劑處理、弧光放電或輝 子法、火水处理法、電子束照射法、7線照射法、光 等。a法、氣處理法、接枝處理法、以及續化處理法 200540309 前述濕熱處理中之濕熱處理溫度以濕熱凝膠化樹脂或 是濕熱凝膠化樹脂纖維成分（以下有時也將兩者統稱為「黏 結劑樹脂」）之凝膠化溫度以上、熔點_2〇它以下為佳。更 佳之濕熱處理溫度為5(rc以上。特佳之濕熱處理溫度為8〇 °c以上。另一方面，更佳之濕熱處理溫度為黏結劑樹脂之 熔點-30°C以下。特佳之濕熱處理溫度為黏結劑樹脂之熔點 40 C以下。若濕熱處理溫度未滿黏結劑樹脂之凝膠化溫 度，有時無法有效地附著添加物。若濕熱處理溫度超過黏 結劑樹脂之炫點-201，由於接近黏結劑樹脂之溶點，所以 做成纖維構造物時有時會引起收縮。 於前述濕熱處理中，與加熱體接觸的情況，面壓以 0·01〜〇·2ΜΡα為佳。更佳之面壓下限為G•隨Pa。更佳之 面壓上限A G.G8MPa。又，當加熱體為熱輥來進行壓縮成 形處理的情況，熱輥之線壓以1〇〜4〇〇N/cm為佳。更佳之 熱親線麼為50N/cm。更佳之熱輥線壓的上限為2_/cm。 依據此方法由於可瞬間將濕熱凝膠化樹脂纖維成分濕熱 凝膠化並同時壓展凝膠化物，所以可廣範圍地使得添加物 附者。又，依據此方法，當濕熱凝膠化時，添加物可壓入 綾膠化物當中，可將添加物更強固地附著於纖維表面。 對纖維構造物賦予體積膨脹性以及/或是柔軟性的情 况對於&有則述纖維與前述濕熱凝膠化樹脂之纖維網進 行1、氣處理可形成濕熱凝膠化樹脂經凝勝化所得之凝膠 化物來使得添加物附著。做為蒸氣處理方法，可舉出例如 從纖維網等之上方以及/或是下方吹送蒸氣之方法、以熱壓 20 200540309 鋼等曝露於蒸氣中之方法等。依據前述方★ 維構造物施加凝膠加工時所需壓力 ‘、、、：對於纖 纖維構造物可—邊維持纖維形 力：其結果， 維表面而在此狀態下附著。 路ία y纖In order for the fiber structure to effectively exhibit the functionality of the additive, the adhesion amount of the additive is preferably per im2w 2 of the fiber structure, more preferably 10 g or more, and particularly preferably% or more. The following explains the manufacturing method of the additive-adhered fiber and the fiber structure of the present invention. In the present invention, the wet heat treatment in the middle of the year + the moon is performed in a moist and hot environment. The "humid hot ambient atmosphere" referred to here means an ambient atmosphere that is heated by containing moisture. The so-called wet heat treatment is performed after applying a binder resin to a fiber, a fiber containing a moist gelling fiber component, or a fiber structure containing such a fiber to a dispersion solution containing, for example, an additive. Treatment, or heating while imparting the aforementioned additive dispersion solution. Examples of the heating method include a method of exposing to a heating ambient atmosphere, a method of passing through heated air, and a method of contacting the heating body. In the case where the additive dispersion solution is applied and then heated, the moisture (fibrous structure) in this example (referred to as "moisture ratio") for the fiber or fiber structure during the wet heat treatment is from 20% by mass to 800% by mass. /. Better. Better water 18 • 200540309 The score is 30% to 700% by mass. Even better water% ~ 600% by mass. If the water content is less than 20 deniers, the quality cannot be sufficiently generated. On the other hand, if the moisture content is: gelatinization, the heat treatment is performed on the surface and inside of the fiber structure. , The degree of thermal gelation tends to be uneven. In addition, the water supply is performed by a known method such as spraying or dipping in a water tank. Special Japanese method The method of impregnating the fiber structure with the additive dispersion solution is: get: The additive enters the inside of the fiber structure, so it is a favorite. : Larger fibers or fiber structures can be squeezed to a predetermined moisture content using squeezed 2 water. Use the temple method to adjust the gelatin, and adjust the temperature of the additives to adjust the amount of additives. The knife puts cold liquid or fiber structure impregnated with the fiber "": body and §. By adding fibers, the additives can be attached to the fiber: two one-== :: = Γ hydrophilic treatment. If Shi Zhiwei structure is roughly = :::: 疎 :::: dimensional = condition, it can be attached to the hydrophilic treatment side, so it is the one who likes it. Examples of the photodischarge method and the electrolysis method include a surfactant treatment, an arc discharge or a glow method, a fire water treatment method, an electron beam irradiation method, a 7-ray irradiation method, and light. a method, gas treatment method, graft treatment method, and continuation treatment method 200540309 The wet heat treatment temperature in the aforementioned wet heat treatment is based on the moist heat-gelation resin or the moist heat-gelation resin fiber component (hereinafter sometimes referred to as the two together) "Binder resin") is preferably above the gelation temperature and below the melting point -20. A more preferable wet heat treatment temperature is 5 (rc or more. A particularly good wet heat treatment temperature is 80 ° c or more. On the other hand, a more preferable wet heat treatment temperature is the melting point of the binder resin below -30 ° C. A particularly good wet heat treatment temperature is The melting point of the binder resin is below 40 C. If the wet heat treatment temperature is lower than the gelation temperature of the binder resin, the additives may not be effectively attached. If the wet heat treatment temperature exceeds the dazzling point of the binder resin -201, it is close to the adhesion. Because of the melting point of the resin, it may cause shrinkage when it is made into a fibrous structure. In the aforementioned wet heat treatment, the contact pressure with the heating body is preferably from 0. 01 to 0.2 MPα. The lower limit of the more preferable surface pressure It is G • With Pa. A better upper pressure limit A G.G8MPa. When the heating body is a hot roll for compression molding, the linear pressure of the hot roll is preferably 10 ~ 400N / cm. The better thermophilic line is 50N / cm. The upper limit of the better hot roller line pressure is 2_ / cm. According to this method, the moist heat gelled resin fiber component can be instantaneously moisturized and gelled at the same time. So it can be added in a wide range In addition, according to this method, when the gel is moist-heated, the additive can be pressed into the gelatin compound, and the additive can be more firmly attached to the surface of the fiber. The fiber structure is given volume expansion and / or It is a case of softness. For & there are the above-mentioned fibers and the fiber web of the above-mentioned moist heat gelled resin. 1. The air treatment can form a gelation product obtained by coagulation of the moist heat gelled resin to make the additive adhere. The steam treatment method includes, for example, a method of blowing steam from above and / or below a fiber web, a method of exposing the steel to steam by hot pressing 20 200540309, and the like. Applying a gel according to the foregoing method The pressure required during processing ',,, and: For fiber-fibrous structures, it is possible to maintain the fiber shape force: as a result, the surface is adhered in this state.

本於=針對本發明之纖維成形體之製造方法做說明。於 、、“:物八：：的濕熱成形加工，係表示對纖維構造物賦予 =;二:液後進行加熱之處理、或是-邊賦予添加物 、域、成形為既定形狀。加熱方法可舉出曝 路於加熱％境氣氛中之方法、與加熱體接觸之方法等。對 ㈣+添加物分散溶液之際之水分率係與上述水 为率相同，在此省略其說明。 於刖述濕熱成形加工中，將含有添加物分散溶液之纖 隹構、物***一對之金屬模具内進行加熱加壓處理乃為較 佳做法。若在不含水分之狀態下加熱，不織布本身會適度 =長而今易順沿金屬模具之形狀，容易得到；果抽成形體。 田邊賦予添加物分散溶液一邊加熱的情況，可藉由例如 將纖維構造物插人—對之金屬模具内並含浸於熱水中（9(rc 以上）來得到成形體。 濕熱成形加工係在濕熱環境氣氛下施行。濕熱成形加 工溫度以凝膠化樹脂之凝膠化溫度以上〜熔點_2〇 t為佳。 更佳之濕熱成形加工溫度為5(rc以上。特佳之濕熱成形加 工溫度為80°C以上。另一方面，更佳之濕熱成形加工溫度 為濕熱凝膠化樹脂之熔點-3(rc以下。特佳之濕熱成形加工 /里度為濕熱凝膠化樹脂之熔點_4〇〇c以下。若濕熱成形加工 21 •200540309 /m度未滿濕熱凝膠化樹脂之凝膠化溫度，則難以形成凝膠 化物。若濕熱成形加工溫度超過濕熱凝膠化樹脂之熔點 °C，由於接近濕熱凝膠化樹脂之熔點，有時成形體會變得 不均勻。 於本發明中，以濕熱環境氣氛來使得該濕熱凝膠化樹 脂濕熱凝膠化之際，較佳為在金屬模具内進行接觸壓成形 加工來製造纖維成形體。此處所說的接觸壓成形加工，係 施加纖維構造物與金屬模具可接觸之程度的壓力之加工。 所明的接觸壓，係纖維構造物與金屬模具密合時施加金屬 模具本身重量，為包含到此程度之壓力的減。該濕熱凝 膠化樹脂由於在濕熱環境氣氛凝膠化即會變得柔軟，所以 僅僅是成形的情況，成形壓力即使未變得相當高亦可。依 據接觸壓成形加工，由於纖維成形體係一邊維持纖維之狀 態一邊以凝膠化物來固定纖維，所以可得到蓬鬆、柔軟之 成形體。前述金屬模具只要係例如不鏽鋼板般之輕薄的金 屬模具即足夠，亦可為緻密的網眼狀金屬模具。 於本發明中，當纖維成形體需要硬度、或是需將濕熱 凝膠化樹脂壓展成為膜狀之凝膠化物的情況，&以通常之 製造纖維成形體的壓力來進行加熱加壓加工。 其次，針對本發明參照圖式做說明。圖1A〜c係本發 明之一實施形態之添加物附著纖維之截面圖。圖1a係以 聚丙稀做為怒成分2、以乙稀—乙稀醇共聚樹脂做為勒成 分1之複合纖維5，勒成分1係具有黏結劑樹脂之功能， 鞘成分1中係附著有添加物3。圖1B係以聚丙烯做為芯成 22 200540309 分2、以乙稀—乙稀醇共聚樹脂做為稍成分i之複合纖維 6,於鞘成分i之外側係附著有乙稀—乙稀醇共聚樹脂做 為黏結劑4’於此黏結劑4中混合著添加物3。圖⑴係聚 丙稀8與乙烯—乙稀醇共聚樹脂7以多分割配置之複合纖 維9’乙稀-乙烯醇共聚樹脂7係具有黏結劑樹脂之功能， 其週邊部附著有添加物3。 圖2係本發明之一實施形態之3 圖，外側配置著添加物附著纖維層 人造絲纖維層12之例。 層構造的不織布截面 11，11，於内側配置著 圖3係本發明之製造方法之一例的製程圖。將纖維或 ”布31纟浸於;^ 32 0之含有添加物之添加物分散溶液 或是含有添加物與乙烯一乙烯醇共聚樹脂之添加物分散溶 液33中，以擠壓輥34做擠壓，於蒸氣機35與吸氣機％ 之間進仃濕熱處理，然後在該狀態下加以捲繞，或是若是 不、、哉布的情況係以附設有一對加熱親3 7，3 7之圖案化用 _帆布輸送帶輥（canvas r〇ller)38,38來壓縮成形，對不織布 表面職予既定圖案模樣後，以捲繞機39做捲繞。亦可取 、二、氧機3 5與吸氣機3 ό，改用上下熱板以例如溫度1 5 〇 C進行5分鐘之加壓處理。在其他實施形態方面尚有不設 置蒸氣機35而僅以一對之加熱輥做壓縮成形之方法、不 °又置4氣機35而僅以附設有一對加熱輥37,37之圖案化用 帆布輪送帶輥38,38做壓縮成形之方法。 圖4 Α〜F係顯示以本發明之一實施例所得之不織布及 八構成纖維附著有添加物之狀態，A係顯示不織布之掃描 23 ^ 200540309 電子顯微鏡平面照片（倍率100)、B為同截面照片（倍率 100)、C為同不織布表面之纖維表面放大照片（倍率、 D為同其他部分不織布的掃描電子顯微鏡平面照片（倍率 100)、E係同截面照片（倍率100)、F為同不織布表面之纖 維表面放大照片（倍率1000)。 圖5A〜C係顯示以本發明之其他實施例所得之不織布 及其構成纖維附著有添加物之狀態，A係顯示不織布之掃 •描電子顯微鏡平面照片（倍率1〇〇)、B為同截面照片（倍率 1〇〇)、C為同不織布表面之纖維表面放大照片（倍率丨〇〇〇)。 圖7係本發明之纖維成形體之一實施形態之含有水分 與添加物之不織布之製造方法之一例製程圖。將不織布原 板3 1含浸於槽32内之含有添加物之添加物分散溶液或是 含有添加物與乙烯一乙烯醇共聚樹脂之添加物分散溶液33 中，以擠壓輥34做擠壓。藉此，對於不織布賦予水分以 及添加物約5〇〇質量％。其次，密合於厚度〇.3mm之不鏽 φ鋼板製金屬模具呈為接處壓狀態，放入加工溫度1c之 熱風乾燥機進行1〇分鐘熱處理來做接觸壓加工。成形體 係製作成為圖8所示之用以覆蓋人的口鼻之罩體40、以及 圖9所不之空氣清靜機過濾器之打摺加工品50。 係本發明之其他實施形態之添加物附著纖維或不 、、我布之製造方法之一例製程圖。將纖維或不織布原板3 1 含浸於摊 1 0 a 9 内之含有添加物（例如氣體吸附性粒子）之水系 液或疋含有添加物（例如氣體吸附性粒子）與乙烯一乙烯醇 聚知f月曰之添加物分散溶液33中，以擠壓輥34做擠壓， 24 •200540309 以從下方吹出蒸氣之蒸氣機35做蒸氣處理，以乾燥機41 做乾燥並以捲繞機3 9做捲繞。圖π a、B所示係本發明之 一實施例所得之不織布及其構成纖維附著有添加物之狀 悲，A係顯示不織布之掃描電子顯微鏡平面照片（倍率 2〇0)、B為同不織布表面之纖維表面放大照片（倍率2〇〇〇)。 實施例 以下依據實施例做更具體的說明。 [實施例1 ] 做為研磨不織布係準備以下之物。 (不織布） 形成下述三層構成之水流交絡不織布。 第1層與弟3層係做為鞘成分之乙烯一乙烯醇共聚樹 脂（EVOH，乙烯38莫爾％，熔點176。〇與做為芯成分之聚 丙烯呈50 : 50之比例的芯鞘型複合纖維（纖度：2.8dtex， 纖維長度：5 1 mm)所構成之梳棉纖維網，單位面積重量各 層皆為30g/m2。 第2層係人造絲纖維（纖度：i 7dtex，纖維長度：4〇mm) 所構成之梳棉纖維網，單位面積重量為3 〇g/m2。 月’J述二層構成之水流交絡不織布之單位面積重量為 9〇g/m2。此不織布係以第1層/第2層/第3層之順序疊合， 進行6MPa之高壓水流處理，使得厚度方向之纖維交絡。 (添加物分散溶液） 使付做為添加物之日本輕金屬公司製造，，氧化紹，，（平均 粒徑〇.7μιη)以3質量％的比例在水中懸浮成為添加物分散 25 • 200540309 溶液（研磨劑溶液）。 (研磨劑之賦予與凝膠加工） 將該不織布浸潰於該研磨劑溶 -細。挟帶…)率係調整為5。。=^ 之添加物量成為表丨所示數值的方式進行調整。又，:: =係：！量與添加物量之和相對於不織布質量乘:; ^ 、:人於加熱至㈣的上下熱板張設帆布輸送 ^網一vas net)，於其間夾入不織布，以〇偏咖的壓 進订2秒鐘的凝膠加工。其次以1〇代之熱風來乾燥。 (研磨特性評價試驗） 將下述之墨水塗覆於不鏽鋼板與陶器皿上， 用各研磨材來去除油污。油污之去除係以人的手對各樣本 施加相同的力量進行摩擦。墨水與評價物體以及評分如下 所示。 (1) 墨水The present invention will be described with reference to a method for producing the fiber formed article of the present invention. Yu ,, ": thing eight :: wet-moulding processing means that the fiber structure is given =; two: heat treatment after the liquid, or-side to add additives, domains, forming into a predetermined shape. The heating method can be The method of exposure to a heating atmosphere, the method of contact with a heating body, etc. are given. The moisture content of the thallium + additive dispersion solution is the same as that of the above water, and the description is omitted here. In the wet thermoforming process, it is a good practice to insert the fibrous structure and material containing the additive dispersion solution into a pair of metal molds for heating and pressure treatment. If it is heated without moisture, the nonwoven fabric itself will be moderate = In the long run, it is easy to follow the shape of the metal mold, which is easy to obtain; the fruit is drawn into a shaped body. In the case where Tanabe gives the additive a dispersion solution while heating, the fiber structure can be inserted into the metal mold and immersed in hot water. Medium (9 (rc or more)) to obtain a molded body. The wet-hot forming process is performed in a hot-humid environment. The temperature of the wet-hot forming process is from the gelation temperature of the gelled resin to the melting point of -20 ° t. . A better wet thermoforming processing temperature is 5 (rc or more. A particularly good wet thermoforming processing temperature is 80 ° C or more. On the other hand, a more preferable wet thermoforming processing temperature is the melting point of the hydrothermal gelling resin -3 (rc or less. Special). The good moisture-moulding processing / degree is the melting point of the moisture-heating gelling resin _400 ° C. If the moisture-thermoforming processing 21 • 200540309 / m degree is less than the gelling temperature of the moisture-heating gelling resin, it is difficult to form a gel If the temperature of the wet-heat forming process exceeds the melting point of the wet-heat gelled resin ° C, the molded body may become non-uniform because the melting point of the wet-heat gelled resin is approached. In the present invention, the wet-heat environment atmosphere is used to make the wet heat When the gelled resin is hydrothermally gelled, it is preferable to perform contact compression molding in a metal mold to produce a fiber molded body. Here, the contact compression molding is performed so that the fiber structure can be brought into contact with the mold. The processing of the pressure. The known contact pressure is the weight of the metal mold applied when the fiber structure is in close contact with the metal mold, which is the reduction of the pressure to this extent. The moist gelled resin will soften when gelled in a moist and hot atmosphere, so it is only for molding, and the molding pressure may not be too high. According to the contact compression molding process, the fiber molding system maintains the fibers In this state, the fiber is fixed by gelation, so a fluffy and soft shaped body can be obtained. The aforementioned metal mold is sufficient as long as it is a thin metal mold such as a stainless steel plate, and it can also be a dense mesh metal mold. In the present invention, when the fibrous formed body requires hardness, or when a moist heat gelled resin is rolled into a film-like gel, & the heating and pressurizing process is carried out under the pressure at which a fibrous formed body is usually produced. Next, the present invention will be described with reference to the drawings. Figs. 1A to c are cross-sectional views of the additive-attached fiber according to an embodiment of the present invention. Fig. 1a is made of polypropylene as the anger component 2, and ethylene-vinyl alcohol. The copolymer resin is used as the composite fiber 5 of the Le component 1. The Le component 1 has the function of a binder resin, and the sheath component 1 has an additive 3 attached thereto. Figure 1B is a composite fiber 6 with polypropylene as the core 22 200540309 points 2. Ethylene-vinyl alcohol copolymer resin is used as the component i with a slight component i. Ethylene-vinyl alcohol copolymer is attached to the side of the sheath component i. A resin is used as a binder 4 ′, and an additive 3 is mixed in the binder 4. Figure VII is a composite fiber 9 ' ethylene-vinyl alcohol copolymer resin 7 in a multi-part arrangement of polypropylene 8 and ethylene-vinyl alcohol copolymer resin 7, which has the function of a binder resin, and additives 3 are attached to its periphery. Fig. 2 is a third view of an embodiment of the present invention, and an example of an rayon fiber layer 12 with an additive-attached fiber layer arranged on the outside. The non-woven fabric cross-sections 11, 11 of the layer structure are arranged on the inside. Fig. 3 is a process drawing showing an example of the manufacturing method of the present invention. The fiber or cloth 31 was immersed in the additive dispersion solution 33 containing additives or the additive dispersion solution 33 containing additives and ethylene-vinyl alcohol copolymer resin, and squeezed with a squeeze roller 34 , Wet heat treatment is performed between the steam engine 35 and the getter%, and then wound in this state, or if it is not, the cloth is attached with a pair of heating patterns 3 7, 3 7 Use _ canvas roller rolls (canvas rolls) 38, 38 to compress and form, and apply a predetermined pattern to the surface of the non-woven fabric, and then wind it with a winder 39. It can also be used. For the gas engine 3, the upper and lower hot plates are used to perform the pressure treatment for 5 minutes at a temperature of, for example, 150 ° C. In other embodiments, there is a method in which a pair of heating rollers are used instead of the steam engine 35 to perform compression molding. No air compressor 35 is installed, and only the patterned canvas roller belt rolls 38 and 38 with a pair of heating rollers 37 and 37 are used for compression molding. Figure 4 A ~ F show one of the inventions. The non-woven fabric and the eight constituent fibers obtained in the examples are in a state where additives are attached, and A is a non-woven fabric. Scanning 23 ^ 200540309 Plane photograph of electron microscope (magnification 100), B is a photograph of the same cross section (magnification 100), C is a magnified photograph of the surface of the fiber with the same non-woven surface (magnification, D is a scanning electron microscope plane of the same non-woven fabric ( Magnification 100), E is a photograph of the same cross section (magnification 100), F is an enlarged photo of the surface of the same fiber (1000 magnification). Figures 5A to C show the adhesion of the nonwoven fabric and its constituent fibers obtained in other embodiments of the present invention. In the state with additives, A shows the scanning and scanning electron microscope plane picture (magnification 100) of the non-woven fabric, B is a photograph of the same cross-section (magnification 100), and C is an enlarged photo of the fiber surface of the same nonwoven surface (magnification 丨〇〇〇). FIG. 7 is an example of a method for manufacturing a non-woven fabric containing moisture and additives according to an embodiment of the fiber formed product of the present invention. The non-woven fabric original plate 31 is impregnated in the groove 32 with the additive-containing additive. The polymer dispersion solution or the additive dispersion solution 33 containing an additive and an ethylene-vinyl alcohol copolymer resin is extruded by a squeeze roller 34. Thus, for the The woven fabric imparts moisture and additives of about 500% by mass. Next, a metal mold made of stainless φ steel sheet with a thickness of 0.3mm is brought into contact with the press and placed in a hot-air dryer at a processing temperature of 1c for 1 °. Minute heat treatment is used for contact pressure processing. The molding system is made into a cover 40 for covering the mouth and nose of a person shown in FIG. 8 and a discounted processed product 50 of an air cleaner filter shown in FIG. 9. The present invention In another embodiment, the additive is attached to the fiber or non-woven fabric, and an example of a manufacturing method of the cloth. The fiber or non-woven fabric original plate 3 1 is impregnated with the additive (such as gas-adsorbing particles) in the booth 10 a 9 Aqueous liquids or mashes contain additives (such as gas-adsorbing particles) and ethylene-vinyl alcohol polymer additive dispersion solution 33, and are squeezed by squeeze roller 34, 24 • 200540309 to blow out steam from below Steam machine 35 is used for steam treatment, dryer 41 is used for drying and winder 39 is used for winding. Figures π a and B show the appearance of the nonwoven fabric and its constituent fibers attached with additives in one embodiment of the present invention. A is a scanning electron microscope plan photograph (magnification 2000) showing the nonwoven fabric, and B is the same as the nonwoven fabric. A magnified photo of the surface of the fiber surface (magnification 2000). Examples Hereinafter, a more specific description will be made based on examples. [Example 1] The following were prepared as abrasive nonwovens. (Non-woven fabric) A three-layered water-flow interwoven non-woven fabric is formed. The first layer and the third layer are ethylene-vinyl alcohol copolymer resins (EVOH, 38 mole% ethylene, melting point 176. 0) as the sheath component. The core-sheath type has a 50:50 ratio with polypropylene as the core component. The carded fiber web composed of composite fibers (fineness: 2.8dtex, fiber length: 51 mm), the unit weight of each layer is 30g / m2. The second layer is rayon fiber (fineness: i 7dtex, fiber length: 4 〇mm) The carded cotton fiber web has a unit area weight of 30 g / m2. The unit area weight of the water flow interwoven non-woven fabric composed of two layers described above is 90 g / m2. This non-woven fabric is based on the first layer / 2nd layer / 3rd layer are superimposed in order, and high pressure water flow treatment of 6MPa is performed to make the fibers in the thickness direction entangled. (Additive dispersion solution) Made by Nippon Light Metal Co., Ltd. as an additive. (Average particle size: 0.7 μιη) Suspended in water at a ratio of 3% by mass to form an additive dispersion 25 • 200540309 solution (abrasive solution). (Grinding of the abrasive and gel processing) The nonwoven fabric was impregnated with the abrasive Dissolve-fine. Banding ...) The ratio is adjusted to 5. . The amount of additive added to = ^ is adjusted in such a way that the value shown in Table 丨. Also :: = 系:! The sum of the amount and the amount of the additive is relative to the mass of the non-woven fabric: ^,: The person sets up the canvas conveyer on the upper and lower hot plates heated to ㈣ (a net vas net), sandwiches the non-woven fabric in between, and orders with the bias of 0 2 seconds of gel processing. Next, it was dried with hot air of 10 generations. (Grinding characteristic evaluation test) The following inks were applied to stainless steel plates and ceramic dishes, and each grind material was used to remove oil stains. The oil stain is removed by rubbing the same force on each sample with human hands. The inks and evaluation objects and scores are shown below. (1) Ink

寺西化學工業製油性墨水（No.500) 夏基海特公司製造油性墨水（artline) 謝普拉公司製造油性墨水（海瑪奇） 三菱錯筆公司製造油性墨水（三菱馬卡匹絲） E :櫻花克雷帕斯公司製造油性墨水（麥尼姆） (2) 评價物體與研磨材之狀態 a :不鏽鋼板 b :陶器皿 dry :在乾燥狀態使用 26 .200540309 备 wet •沾水後甩脫水之狀態下使用 (3)評分 6分：摩擦次數5次可使得油污完全消失 5刀·摩擦次數1 〇次可使得油污完全消失 4分：摩擦次數20次可使得油污完全消失 3分：摩擦次數30次可使得油污完全消失 2分·摩擦次數30次仍部分有些許的油污殘留 1分··摩擦次數3〇次仍殘留一半程度之油污 修 〇刀·摩擦次數3 0次油污仍幾乎不會掉落 又，評價樣本係各試驗5個。研磨性試驗之結果係總 結於表1。 又，所得不織布及其構成纖維附著有添加物之狀態係 表示於圖4A〜F。 [比較例1 ] 形成下述三層構成之水流交絡不織布。 φ 第1層與第3層係乙烯—乙酸乙烯酯共聚樹脂（EVA， 熔點1〇1 C)與聚兩稀呈50:50之比例的芯勒型複合纖維（纖 度· 2’2dteX，纖維長度：51mm)所構成之梳棉纖維網，單 位面積重量各層皆為30g/m2。 第2層係人造絲纖維（纖度·· 1.7dtex，纖維長度·· 40mm) 所構成之梳棉纖維網，單位面積重量為3〇g/m2。 前述三層構成之水流交絡不織布之單位面積重量為 9〇g/m2。此不織布係以第1層/第2層/第3層之順序疊合， 進仃6MPa之高壓水流處理，使得厚度方向之纖維交絡。 27 200540309 研磨劑之賦予等其他的條株 们悚件係與實施例1相同。研磨 性试驗之結果係總結於表1。 [比較例2] 形成下述二層構成之水流交絡不織布。 —第。|與第3層係乙烯—丙烯酸甲酯共聚樹脂(ema， 气86 C )與聚丙婦呈5〇 ·· 5〇之比例的芯勒型複合纖維（纖 度：2.2dtex ’纖維長度：45_)所構成之梳棉纖維網，單 位面積重量各層皆為3〇g/m2。 第2層係人造絲纖維（纖度·· 17(^χ，纖維長度· 4〇mm) 所構成之梳棉纖維網，單位面積重量為3〇g/m2。 刖述一層構成之水流交絡不織布之單位面積重量為 9〇g/m2。此不織布係以第i層/第2層/第3層之順序疊合， 進仃6MPa之高壓水流處理，使得厚度方向之纖維交絡。 研磨劑之賦予等其他的條件係與實施例1相同。研磨 性试驗之結果係總結於表1。 [習知品1 ] 使用附有市售研磨粒子之不織布刷（3M公司製造）來進 订與實施例1相同之研磨性試驗。結果係總結於表1。 [習知品2] 使用附有市售研磨粒子之海綿刷（愛司提公司製造）來 進行與實施例1相同之研磨性試驗。結果係總結於表1。 28 200540309Terase Chemical Industrial Oily Ink (No. 500) Oily Ink (Artline) manufactured by Sharkey Hite Company Oily Ink (Haimaqi) made by Shepra Company Mitsubishi Wrong Pen Company Oily Ink (Mitsubishi Macapas) E: Oil-based ink (manim) manufactured by Sakura Krepps Company (2) Evaluation of the state of objects and abrasive materials a: Stainless steel plate b: Pottery ware dry: Use in a dry state 26.200540309 Prepare wet • Shake after dewatering Use (3) under the state to score 6 points: 5 times of rubbing can make the oil completely disappear 5 knives · friction times 10 times can make the oil completely disappear 4 points: 20 times of rubbing can make the oil completely disappear 3 points: friction 30 times can make the oil completely disappear for 2 minutes. 30 times of rubbing with a little oil residue remaining for 1 minute. 30 times of rubbing with 30 times of oil stain repair. Knife. 30 rubbing times with oil. Falling again, the evaluation samples were 5 in each test. The results of the abrasiveness test are summarized in Table 1. In addition, the obtained nonwoven fabric and its constituent fibers are shown in Figs. 4A to 4F with additives attached thereto. [Comparative Example 1] A water-entangled nonwoven fabric having the following three-layer structure was formed. φ The first layer and the third layer are ethylene-vinyl acetate copolymer resins (EVA, melting point: 101 ° C) and polycondensation at a ratio of 50:50 core-shaped composite fibers (fineness · 2'2dteX, fiber length : 51mm), each layer of carded fiber web is 30g / m2. The second layer is a carded fiber web composed of rayon fibers (fineness: 1.7 dtex, fiber length: 40 mm). The basis weight is 30 g / m2. The weight per unit area of the three-layer water-flow-entangled non-woven fabric was 90 g / m2. The non-woven fabric is laminated in the order of the first layer, the second layer, and the third layer, and is subjected to a high pressure water flow treatment of 6 MPa, so that the fibers in the thickness direction are entangled. 27 200540309 Other materials such as the application of abrasives are the same as in Example 1. The results of the abrasiveness test are summarized in Table 1. [Comparative Example 2] The following two-layered water-flow-entangled nonwoven fabric was formed. — Cap. | Corele-type composite fibers (fineness: 2.2dtex 'fiber length: 45_) with a third layer of ethylene-methyl acrylate copolymer resin (ema, gas 86 C) and polypropylene at a ratio of 50 ·· 50. The carded fiber web is composed of 30 g / m2 of each layer per unit weight. The second layer is a carded fiber web composed of rayon fibers (fineness ·· 17 (^ χ, fiber length · 40mm). The unit area weight is 30g / m2. The weight per unit area is 90 g / m2. The non-woven fabric is laminated in the order of the i-th layer, the second layer, and the third layer, and is subjected to a high-pressure water flow treatment of 6 MPa, so that the fibers in the thickness direction are entangled. Other conditions are the same as those in Example 1. The results of the abrasiveness test are summarized in Table 1. [Knowledge 1] A non-woven brush (manufactured by 3M Co., Ltd.) with commercially available abrasive particles was used to order the same as in Example 1. Abrasiveness test. The results are summarized in Table 1. [Conventional article 2] The same abrasiveness test as in Example 1 was performed using a sponge brush (manufactured by Estee Corporation) with commercially available abrasive particles. The results are summarized in Table 1. 28 200540309

總平均分數 <N •ri ro <N uS 寸 w PQ wet 1 1 Ό Ό VO Ό Ό VO vo cd wet Ό v〇 1 VO Os rn m rn 卜 r〇 ΓΟ 寸· 寸· 卜 Ό cd 寸 d d 00 d 1 VO d O O ο ο ο m rn 卜 (N Q wet 1 VO 1 Ό •ri Ό oo uS ό ν〇 Ό 卜 cd wet v〇 VO VO 1 OO (N m On (N ro 寸· rn 寸· VO 卜 Λ VO fO (N ro 寸 rn 1 寸 rn O O 〇 ο ο 卜 rn 〇 x> wet 1 VO 1 Ό v〇 卜 ro / a wet — 寸· ίΠ 1 00 寸· o 寸 r〇 m r〇 m 寸· IT) cd (N cn m 00 (N 1 o O o ο ο 寸 ro PQ wet 1 v〇 1 v〇 00 uS 寸 uS Γ〇 Ur； ΓΟ 卜 »r! v〇 c3 wet Ό V〇 vo 1 VO ro 00 rn 寸 rn 卜 寸· ι> — VO a Ό vo vo 1 VO 〇 寸 rn (N CN ro 寸· VO C Xi wet 1 v〇 1 V〇 in 00 iT) 00 寸· O) — 卜 — ι> — Ό v〇 a wet v〇 VO 1 VO m oo (N 〇\ cs ^Τ) VO VO I' v〇 v〇 VO 1 v〇 ΓΠ m m ΓΟ rn 寸· m Ό 氧化鋁附著率 (質量％) 寸 CO oo 平均分數 (NI 卜 平均分數 CO 平均分數 平均分數 平均分數 實施例 比較例 實施例1 比較例1 比較例2 習知品1 習知品2 200540309 如表1所示般，本實施例之含有添加物附著纖維之不 織布展現與市售研磨材大致相同等級之研磨性。再者，本 實施例之含有添加物附著纖維之不織布，添加物不會脫 落，耐久性可得到良好的結果。添加物不脫落對於透鏡與 半導體之研磨等特別有用。 ” [實施例2] (不織布） 使用由實施例1之芯鞘型複合纖維所構成之單位面積 重ϊ 100g/m2之水流交絡不織布（水壓6MPa之高壓水流處 理）〇 (加工順序與條件） 將該不織布含浸於含有界面活性劑（烷基之碳數為9之 聚氧化乙烯烧基苯酚醚）〇1質量％之水溶液中、擠壓來做 則處理。其次，浸潰於乙稀一乙烯醇共聚樹脂（EVOH)粉末 (曰本合成化學公司製造，商品名「索阿諾魯」，粉末類型 B-7 ’乙烯29莫爾％，熔點188。〇與活性碳（庫拉雷化學公 司製造，商品名「庫拉雷可魯」PL_D)之水分散溶液中， 以軋輥機做擠壓。之後，使用熱板油壓加壓機（將上下熱板 力口熱）’於帆布輸送帶網之間夾入不織布施行凝膠加工。加 熱溫度為12(TC、加壓壓力為〇.〇32MPa，加熱時間為2分 姜里。之後洗掉殘餘量之添加物，以1 〇〇°C之熱風做乾燥。 前述活性碳係強固且均勻地附著著。所得之含有添加 物附著纖維之不織布的結果係總結於表2。 30 200540309 [實施例3] 除了使用人造絲纖維1.7dtex、5 1mm所構成之60g/m2 之水流交絡不織布（水壓6MPa之高壓水流處理）以外，其 餘與實施例2同樣來進行處理。 則述活性碳係強固且均勻地附著著。所得之添加物附 著不織布的結果係總結於表2。 [實施例4] 除了使用聚酯纖維l.7dtex、51mm所構成之50g/m2之 水流父絡不織布（水壓6MPa之高壓水流處理）以外，其餘 與實施例2同樣來進行處理。 ^前述活性碳係強固且均勻地附著著。所得之添加物附 著不織布的結果係總結於表2。 [實施例5] 除了使用聚丙烯纖維17dtex、51mm所構成之6〇g/m2 之水流乂絡不織布（水壓6MPa之高壓水流處理）以外，其 餘與實施例2同樣來進行處理。 ^前述活性碳係強固且均勻地附著著。所得之添加物附 著不織布的結果係總結於表2。 31 200540309 表2 實施例 編號 EV0H粉末+活性碳之分散溶液 挾帶率 (11¾) 全附著率 (質量〇/〇) EV0H附著率 (質量》 活性碳附著率 (質量％) EV0H粉末量 (質量» 活性碳量 (質量》 實施例2 1 5 425 63 11 52 3 5 500 77 29 48 3 10 498 85 20 65 實施例3 1 5 452 52 9 43 3 5 565 94 35 59 3 10 550 96 22 74 實施例4 1 5 556 67 11 56 3 5 820 165 62 103 3 10 575 105 24 81 實施例5 1 5 582 67 11 56 3 5 688 106 40 66 3 10 622 117 27 90 [實施例6] 第1層與第3層係實施例1之乙烯一乙烯醇共聚樹脂 # (EV0H)與實施例1之聚丙烯呈50 : 50之比例的分割型複 合纖維（纖度：3.3dtex，纖維長度：51nlm)所構成之梳棉纖 維網’單位面積重量各層為3〇g/m2。第1層與第3層之間 的第2層係實施例丨之人造絲纖維與聚酯纖維（纖度： 1.7dtex ’纖維長度：51mm)以1 :丨混合之梳棉纖維網，單 位面積重量為3〇g/m2。以下，以與實施例i相同之方法做 成水流父絡不織布，進行凝膠加工。與實施例1同樣，添 加物係強固且均勻地附著著。所得之不織布及其構成纖維 附者有添加物之狀態係示於圖5 A〜C。 32 200540309 [實施例7] (不織布原板之製作） 準備鞘成分為乙烯一乙烯醇共聚樹脂（EVOH，乙稀含 有里3 8莫爾％ ’溶點176C)、芯成分為聚丙焊（PP，溶點 161°C)之EVOH : PP為50 : 50之比例（體積比）之芯鞘型複 合纖維（纖度·· 3_3dtex，纖維長度：51mm)。再者，準備勒 成分為聚乙烯（PE，熔點132°C )、芯成分為聚丙烯（PP，炼 點161C)之纖度：2.2dtex，纖維長度：51mm之乾熱接著 _ 性複合纖維（大和紡織製造，NBF(H))。 將前述芯鞘型複合纖維75質量％與前述乾熱接著性纖 維25質量％混合，以半隨機梳棉機進行開纖，製作單位面 積重量45g/m2之梳棉網（card web)。其次，將該梳棉網載 放於90網眼之平織支持體上，自在該梳棉網之寬方向配 置一列孔口（直徑：0.12mm，間距：〇.6mm)之噴嘴朝向該 梳棉網以水壓3MPa進行喷射之後，進一步以水壓4Mpa 進行喷射。接著，將該梳棉網反過來，自該喷嘴以水壓4MPa 噴射水流，製作水流交絡不織布原板。 (添加物之準備） 在添加物方面係使用活性碳粒子：「太閣SA1〇〇〇」（二 村化學製造，平均粒徑1〇μηι)。 (含有添加物附著纖維之不織布的製作） 將前述不織布原板浸潰於由水中分散有8質量％之活 性碳粒子所構成之添加物分散溶液（2(rc )中，使用軋輥機 以線壓約60N/cm之擠壓壓力來調整挾帶率。其次，使用 33 .200540309 可從不織布原板下部吹出蒸氣之蒸氣機，對於含浸有添加 物分散溶液之該不織布原板以槽内溫度1 〇2 〇c、加工時間 15秒施以蒸氣處理，以熱風乾燥器（1〇(rc )乾燥，得到本 發明之不織布。所得之不織布的單位面積重量為68g/m2, 約23 g/m2之添加物呈現附著狀態。所得之不織布及其構 成纖維附著有添加物之狀態係示於圖丨丨A_B。所得之不織 布維持著纖維狀態，添加物係以露出於纖維表面之狀態附著。 [實施例8〜11 ] 做為氣體吸附材係準備以下之物。 (不織布原板之製作） 準備勒成分為乙烯一乙烯醇共聚樹脂（ev〇h，乙烯含 有量38莫爾％，熔點176。〇)、芯成分為聚丙烯（pp，熔點 161°C)之EVOH : PP為5〇 : 5〇之比例（體積比）之芯鞘型複 合纖維（纖度：2.8dtex，纖維長度：51mm)。 將前述芯鞘型複合纖維以半隨機梳棉機進行開纖，製 作具有表3所示單位面積重量之梳棉網。其次，將該梳棉 網載放於90網眼之平織支持體上，自在該梳棉網之寬方 向配置一列孔口（直徑：0.12mm，間距·· 0.6mm)之喷嘴朝 向該梳棉網以水壓3MPa來喷射水流之後，進一步以水壓 4MPa進行喷射。接著，將該梳棉網反過來，自該喷嘴以 水壓4MPa喷射水流，製作實施例8〜11所使用之水流交絡 不織布原板。 (添加物之準備） 在添加物方面係準備氣體吸附性粒子。做為氣體吸附 34 200540309 性2子係使用活性碳粒子：「庫拉雷可魯PL_D」（庫拉雷 化子A司製造，椰子殼碳，平均粒徑40〜50μηι)。 (含有添加物附著纖維之不織布的製作） 將前述不織布原板浸潰於由水中分散有1〇質量％之前 述活性碳粒子所構成之添加物分散溶液（20。〇中，以軋輥 桟之擠壓壓力來調整挾帶率，將活性碳粒子之附著量調整 為表3所示之數值。又，所謂的挾帶率係水分量與活性碳 I之和相對於不織布原板質量乘以1〇〇之值。其次，將含 浸有添加物分散溶液之該不織布原板以線徑：〇.3mm、網 艮數·縱30條/lnchx橫25條/inch之2片平織塑膠網（縱 40cmx検40cm)做挾持，載放於加熱到"(^之熱板上，進 而將上側之該塑膠網以鋁片（lg/cm2)被覆做15分鐘之濕熱 處理。將所得之不織布水洗，以熱風乾燥器（100°c )乾燥， 得到本發明之不織布。 [實施例12] 將與實施例8所使用之水流交絡不織布原板相同之不 織布原板浸潰於由水中分散有5質量％之前述活性碳粒子 所構成之添加物分散溶液（95它）中3〇秒之後上拉。接著， 將該不織布原板勾掛支撐直到該不織布原板之溫度成為50 c。之後’將該不織布水洗，以熱風乾燥器（1〇(rc)乾燥， 得到本發明之不織布（氣體吸附材）。 表3針對實施例8〜12之不織布（氣體吸附材）顯示了不 織布原板之單位面積重量、活性碳粒子之附著量、活性碳 粒子之附著率以及不織布（氣體吸附材）之單位面積重量。 35 .200540309 表3 實施例 編號 不織布原板之單位 面積重量（g/m2) 活性碳粒子之附 著量(g/m2) 活性碳粒子之附著 率(質量°/〇) 不織布（氣體吸附材）之單 位面積重量(g/m2) 8 113 159 141 272 9 114 98 86 212 10 110 114 104 224 11 41 43 105 84 12 113 27 24 140 [比較例3] 準備含有自交聯型丙烯酸酯乳膠（日本碳化物工業製 造，商品名「尼卡索魯FX-555A」）15質量％與前述活性碳 粒子10質量％之添加物分散溶液。其次，將與前述實施例 8所使用之水流交絡不織布原板相同之不織布原板浸潰於 該溶液中，以軋輥機做擠壓，使用熱風乾燥機在溫度14〇 C、處理時間15分鐘進行乾燥、硬化，得到活性碳粒子 之附著量為38g/m2之化學黏附（chemicalbond)不織布。 [比較例4] 比較例4係準備VOC氣體吸附片（旭成化纖維製造， 商品名「謝米阿V」，單位面積重量134g/m2，活性碳粒 子之附著量為約40g/m2)，此V0C氣體吸附片係於表面固 疋了除臭劑之2片的紡黏（spunb〇nd)不織布間使得活性碳 粒子以熱炼劑做固定所得者。 [voc氣體吸附試驗方法] 將實施例8〜12以及比較例3,4之片材分別切斷為縱 36 200540309 lOcmx橫10cm之大小，放入容量5公升之公害分析用袋（商 品名「提德拉袋」），以成為表4〜6所示初期濃度的方式注 入空氣與調合之各VOC氣體。然後，以注入時刻為開始 時間，每隔一段時間以氣體檢測管來測定袋内之各VOC 氣體濃度。結果係示於表4〜6。又，於表4〜6中所謂的「ND」 係各VOC氣體濃度未滿所使用之氣體檢測管之測定濃度 (2ppm)的情況。 表4 初期濃度 30分鐘後 卜J、時後 3小時後 6小時後 甲醛殘存濃 度(ppm) 實施例8 100 4 3 2 2 實施例12 100 9 8 __ — 20 3 3 一 — 比較例3 100 10 8 7 7Total average score < N • ri ro < N uS inch w PQ wet 1 1 Ό Ό VO Ό Ό VO vo cd wet Ό v〇1 VO Os rn m rn r〇Γ〇 inch · inch · inch cd inch dd 00 d 1 VO d OO ο ο ο m rn Bu (NQ wet 1 VO 1 Ό • ri Ό oo uS ό ν〇Ό cd wet v〇VO VO 1 OO (N m On (N ro inch Λ VO fO (N ro inch rn 1 inch rn OO ο ο bu rn 〇x > wet 1 VO 1 Ό v〇 卜 ro / a wet — inch · ίΠ 100 inch · o inch r〇mr〇m inch · IT) cd (N cn m 00 (N 1 o O o ο ο Inch ro PQ wet 1 v〇1 v〇00 uS Inch uS Γ〇Ur; ΓΟ Bu »r! V〇c3 wet Ό V〇vo 1 VO ro 00 rn inch rn Bu inch · ι > — VO a Ό vo vo 1 VO 〇 inch rn (N CN ro inch · VO C Xi wet 1 v〇1 V〇in 00 iT) 00 inch · O) — Bu — ι > — Ό v〇a wet v〇VO 1 VO m oo (N 〇 \ cs ^ Τ) VO VO I 'v〇v〇VO 1 v〇ΓΠ mm ΓΟ rn inch · m Ό Alumina adhesion rate (% by mass) inch CO oo average score (NI BU average score CO average score average score average score EXAMPLES Comparative Examples Example 1 Comparative Example 1 Comparative Example 2 Known Product 1 Known Product 2 200540309 As shown in Table 1, the non-woven fabric containing the additive-adhering fibers of this example exhibited the same level of abrasiveness as a commercially available abrasive. That is, the non-woven fabric containing the additive-attached fibers in this embodiment does not fall off the additives, and good results are obtained in terms of durability. The non-detachment of the additives is particularly useful for lens and semiconductor polishing, etc. "[Example 2] (Non-woven fabric ) Using a core-sheath composite fiber of Example 1 with a unit area weight of 100 g / m2, a water flow interwoven nonwoven fabric (high-pressure water flow treatment with a water pressure of 6 MPa) 〇 (Processing sequence and conditions) The nonwoven fabric was impregnated with interface activity Agent (polyoxyethylene alkylene phenol ether having 9 carbon atoms in the alkyl group) in a 1% by mass aqueous solution, and processed by extrusion. Next, it was impregnated with ethylene-vinyl alcohol copolymer resin (EVOH) powder (manufactured by Japan Synthetic Chemical Co., Ltd. under the trade name "Soanolu"), powder type B-7 'ethylene 29 mole%, melting point 188. Activated carbon (Kuraray Chemical Co., Ltd., trade name "Kuraray Keru" PL_D) in a water-dispersed solution was extruded with a roll mill. Then, a hot plate hydraulic press (pressing the upper and lower heat plates) was used. Mouth heat) 'sandwiched between the canvas conveyor belt mesh to perform gel processing. The heating temperature is 12 (TC, pressurization pressure is 0.032MPa, the heating time is 2 minutes ginger. After that, the remaining amount is added by washing The material was dried with hot air at 100 ° C. The aforementioned activated carbon was strongly and uniformly adhered. The results of the obtained non-woven fabric containing additive-attached fibers are summarized in Table 2. 30 200540309 [Example 3] Except for use Except for 60g / m2 water flow non-woven fabric (water pressure 6MPa high pressure water flow treatment) composed of 1.7dtex and 5 1mm rayon fibers, the rest were treated in the same manner as in Example 2. The activated carbon is strongly and uniformly adhered. 。The obtained additives are attached The results of the non-woven fabric are summarized in Table 2. [Example 4] Except for using a 50 g / m2 water flow non-woven fabric made of polyester fiber 1. 7 dtex and 51 mm (high-pressure water flow treatment with a water pressure of 6 MPa), the rest are the same as in the example. 2 Treated in the same way. ^ The activated carbon is strongly and uniformly adhered. The results of the obtained additive-attached nonwoven fabric are summarized in Table 2. [Example 5] Except the polypropylene fiber 17dtex and 51mm, which is 60%. Except for g / m2 water flow non-woven fabric (high pressure water flow treatment with a water pressure of 6 MPa), the rest were treated in the same manner as in Example 2. ^ The aforementioned activated carbon was strongly and uniformly adhered. The result of the addition of the adhered nonwoven fabric was It is summarized in Table 2. 31 200540309 Table 2 Example No. EV0H powder + activated carbon dispersion solution (11¾) Total adhesion rate (mass 0 / 〇) EV0H adhesion rate (mass) Activated carbon adhesion rate (mass%) EV0H Powder amount (mass »activated carbon amount (mass)) Example 2 1 5 425 63 11 52 3 5 500 77 29 48 3 10 498 85 20 65 Example 3 1 5 452 52 9 43 3 5 565 94 35 59 3 10 550 96 22 74 real Example 4 1 5 556 67 11 56 3 5 820 165 62 103 3 10 575 105 24 81 Example 5 1 5 582 67 11 56 3 5 688 106 40 66 3 10 622 117 27 90 [Example 6] The first layer and The third layer is a split composite fiber (denier: 3.3 dtex, fiber length: 51 nlm) composed of the ethylene-vinyl alcohol copolymer resin # (EV0H) of Example 1 and the polypropylene of Example 1 in a ratio of 50:50. Each layer of carded fiber web 'has a basis weight of 30 g / m2. The second layer between the first layer and the third layer is an embodiment of the rayon fiber and polyester fiber (fineness: 1.7dtex 'fiber length: 51mm) in a card fiber web of 1: 丨 mixed, unit area weight It was 30 g / m2. In the following, a water flow non-woven fabric was prepared in the same manner as in Example i, and gel processing was performed. As in Example 1, the additive system was strongly and uniformly adhered. The state of the obtained nonwoven fabric and its constituent fibers with additives is shown in Figs. 5A to 5C. 32 200540309 [Example 7] (Manufacture of non-woven original plate) Preparation of sheath component is ethylene-vinyl alcohol copolymer resin (EVOH, ethylene contains 38 Moore% 'melting point 176C), core component is polypropylene welding (PP, solvent Point 161 ° C) core-sheath composite fiber (fineness ·· 3_3dtex, fiber length: 51mm) with a ratio of EVOH: PP of 50: 50 (volume ratio). Furthermore, a dry heat-bonded composite fiber (Yamato) with a fineness of 2.2 dtex and a fiber length of 51 mm was prepared with polyethylene (PE, melting point 132 ° C) and polypropylene (PP, 161C) as the core component. Textile manufacturing, NBF (H)). 75 mass% of the core-sheath composite fiber was mixed with 25 mass% of the dry heat-adhesive fiber, and the fiber was opened by a semi-random carding machine to produce a card web having a unit area weight of 45 g / m2. Next, the card is placed on a 90-mesh plain-woven support, and a row of orifices (diameter: 0.12 mm, pitch: 0.6 mm) is arranged in the width direction of the card toward the card. After spraying at a water pressure of 3 MPa, the spray was further performed at a water pressure of 4 MPa. Next, the card was turned upside down, and a water flow was sprayed from the nozzle at a water pressure of 4 MPa to produce a water flow non-woven original sheet. (Preparation of Additives) For the additives, activated carbon particles were used: "Taige SA1000" (manufactured by Nimura Chemical Co., Ltd., average particle size: 10 μm). (Production of Non-woven Fabric Containing Additive Adhesive Fibers) The original non-woven fabric sheet was immersed in an additive dispersion solution (2 (rc)) composed of 8% by mass of activated carbon particles dispersed in water, and pressed by a roller using a roller 60N / cm extrusion pressure is used to adjust the taping rate. Secondly, a steam machine that can blow steam from the lower part of the original non-woven fabric sheet using 33.200540309 is used. For the original non-woven fabric sheet impregnated with the additive dispersion solution, the temperature in the tank is 1 〇2 〇c. The processing time is 15 seconds, steam treatment is applied, and the non-woven fabric of the present invention is obtained by drying with a hot air dryer (10 (rc)). The basis weight of the obtained non-woven fabric is 68 g / m2, and the additive of about 23 g / m2 exhibits adhesion. State. The obtained nonwoven fabric and its constituent fibers are attached with additives as shown in Figure 丨 A_B. The obtained nonwoven fabric maintains the fiber state, and the additives are attached in a state exposed on the fiber surface. [Examples 8 to 11] The following materials were prepared as the gas adsorbent system. (Production of the original non-woven fabric sheet) Preparation of ethylene-vinyl alcohol copolymer resin (ev0h, ethylene content 38 mol%, melting point) 176.〇) Core-sheath composite fibers (fineness: 2.8 dtex, fiber length: 51 mm) with a core component of polypropylene (pp, melting point 161 ° C) and an EVOH: PP ratio of 50:50 (volume ratio) ). The core-sheath composite fiber was opened with a semi-random carding machine to produce a card web having a unit area weight shown in Table 3. Next, the card web was placed on a 90-mesh plain-woven support. In the above, since a row of nozzles (diameter: 0.12mm, pitch · 0.6mm) is arranged in the width direction of the card, the card is sprayed with water at a pressure of 3 MPa toward the card, and then sprayed at a pressure of 4 MPa. Next, the card was turned upside down, and a water flow was sprayed from the nozzle at a water pressure of 4 MPa to produce a water-flow-entangled nonwoven fabric original plate used in Examples 8 to 11. (Preparation of Additives) In terms of additives, gas-absorbing particles were prepared. . As a gas adsorption 34 200540309 sex 2 sub-system using activated carbon particles: "Kurarecolu PL_D" (manufactured by Courareco A, Coconut Shell Carbon, average particle size 40 ~ 50μηι). (Contains additives Fabrication of non-woven fabric with attached fibers) The original non-woven fabric sheet is immersed in an additive dispersion solution (20. 0%) of the above-mentioned activated carbon particles dispersed in water (in 20.0, the banding rate is adjusted by the pressing pressure of the rollers, and the activated carbon particles are attached. The amount was adjusted to the value shown in Table 3. In addition, the so-called banding rate is a value obtained by multiplying the sum of the water content and the activated carbon I with respect to the mass of the original nonwoven fabric by 100. Next, the amount impregnated with the additive dispersion solution The original non-woven fabric is held by 2 flat woven plastic nets (40cmx 検 40cm in length) with a wire diameter of 0.3mm, the number of nets, 30 pieces / lnchx, 25 pieces / inch, and placed in the heat of " (^ 之 热On the board, the plastic mesh on the upper side was covered with aluminum sheet (lg / cm2) for 15 minutes of wet heat treatment. The obtained non-woven fabric was washed with water and dried with a hot air dryer (100 ° C) to obtain the non-woven fabric of the present invention. [Example 12] The same original nonwoven fabric sheet as the water-flow-entangled nonwoven fabric original sheet used in Example 8 was immersed in an additive dispersion solution (95%) composed of the aforementioned activated carbon particles dispersed in water by 5% by mass. Pull up after seconds. Next, the non-woven raw plate was hung and supported until the temperature of the non-woven raw plate became 50 c. After that, the non-woven fabric was washed with water and dried with a hot air dryer (10 (rc) to obtain the non-woven fabric (gas adsorbent) of the present invention. Table 3 shows the non-woven fabric (gas adsorbent) of Examples 8 to 12). Weight per unit area, the amount of activated carbon particles attached, the rate of attachment of activated carbon particles, and the weight per unit area of non-woven fabrics (gas-adsorbing materials). 35.200540309 Table 3 Example No. Unit Weight of Non-woven Raw Plate (g / m2) Activated Carbon Adhesion of particles (g / m2) Adhesion of activated carbon particles (mass ° / 〇) Weight per unit area (g / m2) of non-woven fabric (gas adsorbent) 8 113 159 141 272 9 114 98 86 212 10 110 114 104 224 11 41 43 105 84 12 113 27 24 140 [Comparative Example 3] A self-crosslinking acrylic latex (manufactured by Japan Carbide Industries, trade name "Nicassour FX-555A") was prepared with 15 mass% and the aforementioned activity. An additive dispersion solution of 10% by mass of carbon particles. Next, the same original non-woven fabric sheet as the water-flow-entangled non-woven original sheet used in Example 8 was immersed in the solution, and extruded by a roll mill. It was pressed and dried using a hot-air drier at a temperature of 14 ° C and a treatment time of 15 minutes to obtain a chemically bonded non-woven fabric with an activated carbon particle adhesion amount of 38 g / m2. [Comparative Example 4] Comparative Example 4 was prepared VOC gas adsorption sheet (manufactured by Asahi Kasei Chemicals Co., Ltd. under the trade name "Shemia V", the unit weight is 134g / m2, and the amount of activated carbon particles attached is about 40g / m2). This V0C gas adsorption sheet is fixed on the surface. The two obtained deodorant spunbond non-woven fabrics were obtained by fixing activated carbon particles with a hot refining agent. [Voc gas adsorption test method] Examples 8 to 12 and Comparative Examples 3 and 4 were used. The sheets were cut to a length of 36 200540309 lcm × 10cm in width, and they were placed in a pollution analysis bag with a capacity of 5 liters (trade name “Tidra bag”), and air was injected so as to have initial concentrations shown in Tables 4 to 6. And each of the VOC gases prepared. Then, the injection time is used as the starting time, and the concentration of each VOC gas in the bag is measured with a gas detection tube at regular intervals. The results are shown in Tables 4-6. The so-called "ND" is the concentration of each VOC gas The measured concentration (2ppm) of the gas detection tube used is not full. Table 4 Initial concentration 30 minutes later, 3 hours later 6 hours later 6 hours later Formaldehyde residual concentration (ppm) Example 8 100 4 3 2 2 Implementation Example 12 100 9 8 __ — 20 3 3 One — Comparative Example 3 100 10 8 7 7

表5table 5

初期濃度 5分鐘後 30分鐘後 1小時後 曱苯殘存濃度 (ppm) 實施例9 20 10 2 ND 實施例12 23 4 ND ND 比較例4 20 11 4 ND 二曱苯殘存濃 度(ppm) 實施例9 24 11 ND ND 實施例12 24 5 ND ND 比較例4 24 15 5 ND 對二氣苯殘存 濃度(ppm) 實施例9 28 6 ND ND 實施例12 20 5 ND ND 比較例4 28 18 ND ND 37 200540309 表6 初期濃度 5分鐘後 30分鐘後 1小時後 乙基苯殘存濃 度(ppm) 實施例10 20 6 1 ND 實施例11 20 6 1 ND 實施例12 20 3 ND ND 比較例4 20 8 1.5 ND 苯乙烯殘存濃 度(ppm) 實施例10 22 4 2 2 實施例11 22 6 3 2 實施例12 24 4 2 2 比較例4 22 10 3 3Initial concentration 5 minutes, 30 minutes, and 1 hour later, residual toluene concentration (ppm) Example 9 20 10 2 ND Example 12 23 4 ND ND Comparative Example 4 20 11 4 ND Dibenzobenzene residual concentration (ppm) Example 9 24 11 ND ND Example 12 24 5 ND ND Comparative Example 4 24 15 5 ND Residual Concentration of Diphenylbenzene (ppm) Example 9 28 6 ND ND Example 12 20 5 ND ND Comparative Example 4 28 18 ND ND 37 200540309 Table 6 Initial concentration of residual ethylbenzene (ppm) after initial concentration of 5 minutes and 30 minutes after 1 minute Example 10 20 6 1 ND Example 11 20 6 1 ND Example 12 20 3 ND ND Comparative Example 4 20 8 1.5 ND Benzene Residual ethylene concentration (ppm) Example 10 22 4 2 2 Example 11 22 6 3 2 Example 12 24 4 2 2 Comparative Example 4 22 10 3 3

[結果] 如表4〜6所示般，使用實施例8〜1 1之不織布的情況， 相較於比較例3,4 ’各VOC氣體之濃度減少速度快，氣體 之吸附性能獲得提升。又，如表4所示般，實施例12相 較於比較例3雖活性碳粒子之附著量少，但展現與比較例 3同等之甲醛吸附性能。再者，如表5,6所示般，實施例a 相較於比較例4雖活性碳粒子之附著晉少， 但氧體吸附性 能獲得提升。此被認為係實施例8〜12之士 个螂布中之活性 奴粒子（氣體吸附性粒子）由纖維表面 < /”、、熱凝膠化之凝膠 化物來附著，所以氣體吸附性粒子係在露 乂 4 α、表面之壯能 下被附著，故相較於比較例3,4，氧 心 虱體吸附性粒 面積的減少受到抑制。又，實施例8〜12 丁〈比表 纖維形狀，於凝膠加工時並無不織之不織布保持著 广砜命收縮之情事 施例8〜12之不織布並無氣體吸附性 。又，實 孤于脫落之情事。 38 200540309 [實施例13] 做為水質淨化材係準備以下之物。 (不織布原板之製作） 準備顆成分為乙稀一乙烯醇共聚樹脂（EVOH，乙稀含 有量38莫爾％，熔點176。〇、芯成分為聚丙烯（Pp，炫點 161 C )之EVOH : PP為50 : 50之比例（體積比）之芯鞘型複 合纖維（纖度：2.8dtex，纖維長度：51mm)。[Results] As shown in Tables 4 to 6, when the nonwoven fabrics of Examples 8 to 11 were used, the concentration of each VOC gas decreased faster than that of Comparative Examples 3 and 4 ', and the gas adsorption performance was improved. In addition, as shown in Table 4, Example 12 exhibited a smaller amount of activated carbon particles than Comparative Example 3, but exhibited the same formaldehyde adsorption performance as Comparative Example 3. In addition, as shown in Tables 5 and 6, in Example a, compared with Comparative Example 4, although the adhesion of activated carbon particles was reduced, the oxygen gas adsorption performance was improved. This is considered to be that the active slave particles (gas-adsorbing particles) in the mantle cloth of Examples 8 to 12 are adhered by the surface of the fiber < / " Because it is attached under the condition of dew 4 α and the surface energy, compared with Comparative Examples 3 and 4, the reduction of the area of the adsorbable particles of oxygen heart louse is suppressed. Moreover, Examples 8 to 12 Shape, there is no non-woven non-woven fabric that keeps the shrinkage of polysulfone during gel processing. The non-woven fabrics of Examples 8 to 12 have no gas adsorption. Also, it is lonely to fall off. 38 200540309 [Example 13] Prepare the following as the water purification material. (Production of the original non-woven fabric sheet) Prepare the particles as ethylene-vinyl alcohol copolymer resin (EVOH, ethylene content 38 mol%, melting point 176.0), and the core component is polypropylene. The core-sheath composite fiber (fineness: 2.8 dtex, fiber length: 51 mm) with an EVOH: PP ratio of 50:50 (volume ratio) (Pp, dazzle point 161 C).

將前述芯鞘型複合纖維以半隨機梳棉機進行開纖，製 作單位面積重量1 〇 1 g/m2之梳棉網。其次，將該梳棉網載 放於90網眼之平織支持體上，自在該梳棉網之寬方向配 置 列孔口（直控：0· 12mm，間距·· 0·6mm)之噴嘴朝向兮 梳棉網以水壓3MPa來喷射水流之後，進一步以水壓 進行噴射。接著，將該梳棉網反過來，自該噴嘴以水壓4MPa 喷射水流，製作實施例丨所使用之水流交絡不織布原板。 (添加物之準備） 在添加物方面係準備有機物吸附性粒子。做為有機物 吸附性粒子係使用活性碳粒子：「庫拉雷可魯PL_D」（庫 拉雷化學公司製造，椰子殼碳，平均粒徑4〇〜陣）。 (含有添加物附著纖維之不織布的製作） 、十、本以 只印个Τ刀政有W質量％之前 述活***粒子所構成之添加物分散溶液（2〇。^中，以 ::擠歸力來調整挾帶率，將活性碳粒子之附著量調整 不η布？：'數值。其次，將含浸有添加物分散溶液之該 、哉布原板以線徑：〇.3mm、網眼數：縱3〇條/_橫υ 39 200540309 ' 之2片平織塑膠網（縱40cmx橫4〇cm)做挾持，栽 放於加熱$ 15(rc之熱板上，進而將上側之該塑膠網以銘 片（Ig/cm2)被覆⑼15分鐘之濕熱處理。將所得之不織布水 洗’以熱風乾燥器（1G(rc)乾燥，得到本發明之不織布（水 [實施例1 4 ] 除了使用單位面積重量4〇g/m2之梳棉 =…際之水分散液中之活性碳粒子之濃度調= 貝里/〇,以軋輥機來調整挾帶率使得活性碳粒子之附著量 成為表1户斤示之數值以外，其餘與實施你J U才目同之方^ 來得到本發明之不織布（水質淨化材）。 表7中針對實施例13以及實施例14之不織布（水質淨 化材），顯示了不織布原板之單位面積重量、活性碳粒子之 附者里、活性碳粒子之附著率以及不織布(水質淨化材)之 早位面積重量。實施例13〜不織布係保持著纖維形 狀，於凝膠加工時並無不織布之收縮。 表7 實施例 編號 不織布原板之單位 面積重量（g/m2) 13 101 |l4 40 活性碳粒子之附 著量(g/m2) 90 [比較例5] 比較例5係準備活性碳 A纖維不織布（庫拉雷化學製造 200540309 商品名「庫拉庫提布」，單位面積重量約180g/m2)。 [水質淨化性能試驗方法]The core-sheath type composite fiber was opened with a semi-random carding machine to prepare a carded web having a basis weight of 101 g / m2. Next, the card is placed on a 90-mesh plain woven support, and the nozzles of the row orifices (direct control: 0 · 12mm, pitch ···· 0.6mm) are arranged in the wide direction of the card. The card was sprayed with water at a water pressure of 3 MPa, and then sprayed with water pressure. Then, the card is turned upside down, and a water flow is sprayed from the nozzle at a water pressure of 4 MPa to produce a water flow non-woven original plate used in Example 丨. (Preparation of Additives) Organic additives are prepared for the additives. As an organic substance, activated carbon particles are used: "Kurarecolu PL_D" (manufactured by Kurare Chemical Co., Ltd., coconut shell carbon, average particle size: 40 ~ array). (Production of non-woven fabrics containing additive-attached fibers) 10. The additive dispersion solution (20. ^, in the form of :: squeeze) Force to adjust the banding rate, adjust the amount of activated carbon particles attached to the cloth ?: 'value. Second, the original cloth cloth impregnated with the additive dispersion solution with a wire diameter: 0.3mm, mesh number: Longitudinal 30 pieces / _cross υ 39 200540309 '2 pieces of flat woven plastic net (40cm in length x 40cm in width) for holding, placed on a heating plate of $ 15 (rc hot plate, and then the plastic net on the upper side with the inscription The sheet (Ig / cm2) was coated with a wet heat treatment for 15 minutes. The obtained non-woven fabric was washed with water and dried with a hot air dryer (1G (rc) to obtain the non-woven fabric of the present invention (water [Example 1 4].) g / m2 carded cotton = ... the concentration of activated carbon particles in the aqueous dispersion = Berry / 〇, the rolling rate is adjusted by a roller machine so that the amount of activated carbon particles attached is the value shown in Table 1 Except the rest, it is the same as implementing your JU ^ to obtain the non-woven fabric (water purification material of the present invention) Table 7 shows the nonwoven fabrics (water purification materials) of Examples 13 and 14 in Table 7. The weight per unit area of the original board of the nonwoven fabric, the attachment of activated carbon particles, the adhesion rate of activated carbon particles, and the nonwoven fabric (water purification material) are shown in Table 7. Area weight in the early position. Example 13 ~ The non-woven fabric maintains the fiber shape, and there is no shrinkage of the non-woven fabric during gel processing. Table 7 Example unit weight of the original non-woven fabric sheet (g / m2) 13 101 | l40 40 Adhesive amount of activated carbon particles (g / m2) 90 [Comparative Example 5] Comparative Example 5 prepared an activated carbon A fiber nonwoven fabric (manufactured by Curaray Chemicals 200540309 under the trade name "Curacutib"), with a unit weight of about 180g / m2). [Test method for water purification performance]

針對實施例13,14以及比較例3,5，以圖6所示之水循 環式簡易試驗機來進行水質淨化性能試驗。如圖6所示般， 水循環式簡易試驗機20係由台座2 1、於台座21所安裝之 固定夾具22a，22b、藉由固定夾具22a來固定於台座21之 有底圓筒狀容器23、以及使得容器23内之水循環之泵24。 泵24係具備於容器23之底部開口 23a所安裝之管24a、 以及藉由固定夾具22b固定於台座21之管24b，從容器23 之開口 23a將容器23内之水加以吸引，所吸引之水藉由管 24b朝容器23之上部排出。又，於本試驗中，針對實施例 13以及比較例5係對於容器23内注入化學需氧量（c〇D)為 40ppm之工廠廢水，針對實施例14以及比較例3係注入c〇D 為20ppm之工廠廢水。又，藉由在泵24所連接之電力調 整裝置（未圖示）將水的循環流量控制在6升/分鐘，於試I 中將谷器23内之工廠廢水的液量維持在丨升。 [試驗用樣本之製作方法] 將實施例U，14以及比較例3,…織布分別 3CmX3Cm之小片25(參照圖6)。其次，分別針對實施例13 ^ 以及比較例3’5’以活性碳量成為IGg的方式秤取小片25’ 4 將所秤取之小片25裝入市售之茶包％(參照圖6)二 驗用樣本27(參照® 6)°又，於水質淨化性能試驗之^ 如圖6所不般，將試驗用樣本27浸潰於容器23内之:’ 工廠廢水中，以金屬線28固定於固定夾具2几。則逆 200540309 [COD濃度測定方法] COD濃度係每到測定時間將容器23内之工廠廢水以 滴官採集至燒瓶中，利用共理化學研究所製造之簡易水質 分析製品「包裝試驗機」（WAK-COD，測定範圍〇〜ioomg/ 升）來與標準色做比色進行測定。結果顯示於表8。 表8 C0D 濃度(ppm ) _ --- 初期濃度 10分鐘後 15分鐘後 30分鐘後 60分鐘後 120分鐘後 實施例13 40 30 30 28 Τό 實施例14 20 — 20 13 η 10 比較例3 20 一 20 20 20 20 比較例5 40 35 30 30 Is — [結果] 如表8所示，使用實施例13，14之不織布的情況，相 較於比較例3，5，COD濃度之減少速度快，展現良好之水 質淨化性能。特別是，於測定開始12〇分鐘後，實施例14 # 之COD濃度會成為比較例3之c〇D濃度的一半，水質淨 化性能獲得提升。此被認為乃由於實施例14之不織布中 之活性碳粒子（有機物吸附性粒子）藉由纖維表面所固定之 濕熱凝膠化凝膠化物來附著，於是有機物吸附性粒子係在 路出表面的狀態下附著，相較於比較例，有機物吸附性粒 子之比表面積的減少受到抑制之故。 [活性碳脫落率] 將實施例14以及比較例5之不織布以活性碳量成為 1 · 2 1 g的方式做裁切。所裁切之樣本的尺寸，實施例1 *為 42 200540309 30cmx2〇cm，比較例5為66cmxl〇cm。其次，於3升之燒 瓶中加入2升的水’將實施例丨3以及比較例$之前述樣 本分別放入燒瓶内之水中，以磁攪拌子攪拌4小時。之後， 取出樣本’將燒瓶内之殘存液以質量事先測定過之玻璃濾 紙（東洋濾紙公司製造，商品名「阿德幫提克」，型錄「glass fiber GS25」，直徑47mm)來抽氣過濾，將過濾後之玻璃 濾紙加以乾燥，然後測定乾燥後之玻璃濾紙之質量。然後， 攸所彳于之玻璃遽紙之質量來算出活性碳之脫落量以及脫落 率。又，活性碳之脫落量係乾燥後之玻璃濾紙之質量減掉 過濾前之玻璃濾紙之質量所得之值。又，活性碳之脫落率， 係活性碳之脫落量除以試驗前之活性碳量（121g)再乘以 100之值。結果顯示於表9。 表9 活性碳量(g) 脫落量(g) 脫落率(g) 實施例14 1.21 0.0016 0.13 比較例5 1.21 0.0201 1.66 [結果] 如表9所顯示般’實施例14之不織布相較於比較例5 之不織布在活性碳之脫落量以及脫落率獲得抑制。此被認 為是由於實施例丨4之不織布中之活性碳（活性碳粒子）被在 纖維表面所固定之濕熱凝膠化之凝膠化物所附著，所以相 較於比較例5，活性碳能更強固地保持之故。 43 .200540309 [實施例15] (不織布原板之製作） 準備鞘成分為乙烯一乙烯醇共聚樹脂⑺v〇H，乙烯含 有量38莫爾％，熔點176°c)、芯成分為聚丙烯（pp，熔點 161 C )之EVOH · PP為50 : 50之比例（體積比）之芯鞘型複 合纖維（纖度：2.8dtex，纖維長度：51mm)。 將前述芯鞘型複合纖維以半隨機梳棉機進行開纖，製 作單位面積重篁40g/m2之梳棉網。其次，將該梳棉網載放 於90網眼之平織支持體上，自在該梳棉網之寬方向配置 列孔口（直徑· 0.12mm，間距：0·6ππη)之噴嘴朝向該梳 棉網以水Μ廳來喷射水流之後，進一步以水Μ缝 進行噴射。接著，將該梳棉網反過來，自該噴嘴以水壓4Mpa 噴射水流，製作水流交絡不織布原板。 (添加物之準備） 在添加物方面係使用活性碳粒子：「庫拉雷可魯pl-D」（庫拉雷化學公司製造，椰子殼碳平均粒徑糾〜。 (添加物附著濕熱成形加工） 將前述不織布原板浸潰於由水中分散有1〇質量％之前 述活性碳粒子所構成之添加物分散溶液（2〇。〇中，以軋輥 機之擠壓壓力來調整挾帶率。 > 〇-3mm之不鏽 工溫度140°C 理。成形體係 以覆蓋人的口 將含有水分與添加物之不織布失在厚度 鋼板製之1對金屬模具之間做密合，放入加 之熱風乾燥機，以1 0分鐘之接觸壓做熱處 使用碗型之金屬模具來製作成圖8所示之用 44 ,200540309 來製作成圖9所示 叶算所得之罩體以 結果均為100質量 鼻之罩體40 ’另使用打摺型之金屬模具 之空氣清靜機用過濾器之打摺加工品。 及打摺加工品之活性碳粒子之附著率， %。 能，1龜 之罩體’具有適度的柔軟性，保持著纖維形The water purification performance test was performed on Examples 13, 14 and Comparative Examples 3 and 5 using a simple water cycle tester as shown in FIG. 6. As shown in FIG. 6, the water circulation type simple testing machine 20 is composed of a base 21, fixed fixtures 22 a and 22 b installed on the base 21, and a bottomed cylindrical container 23 fixed to the base 21 by the fixed fixture 22 a. And a pump 24 for circulating water in the container 23. The pump 24 is provided with a tube 24a installed at the bottom opening 23a of the container 23, and a tube 24b fixed to the pedestal 21 by a fixing jig 22b. The water in the container 23 is attracted from the opening 23a of the container 23, and the attracted water It is discharged toward the upper part of the container 23 through the tube 24b. In this test, for Example 13 and Comparative Example 5, the plant waste water with a chemical oxygen demand (cod) of 40 ppm was injected into the container 23, and for the examples 14 and Comparative Example 3, the cod was injected as follows: 20ppm of factory wastewater. In addition, the power circulating device (not shown) connected to the pump 24 was used to control the circulating flow rate of water at 6 liters / minute, and the amount of the factory wastewater in the valley device 23 was maintained at liters in Trial I. [Production method of test sample] Examples U, 14 and Comparative Example 3, ... were woven pieces of 3Cm × 3Cm (refer to FIG. 6). Next, according to Example 13 ^ and Comparative Example 3'5 ', the small pieces 25' were weighed so that the amount of activated carbon became IGg. 4 The small pieces 25 weighed were put into a commercially available tea bag% (see FIG. 6). Test sample 27 (refer to ® 6) ° In the water purification performance test ^ As shown in Figure 6, the test sample 27 was immersed in the container 23: 'In factory wastewater, fixed with metal wire 28 2 fixtures. Then reverse 200540309 [Method for measuring COD concentration] COD concentration is the collection of factory wastewater in container 23 into the flask every time the measurement time is reached, and a simple water quality analysis product "Packaging Tester" (WAK -COD, measuring range 0 ~ ioomg / liter) to compare with standard color and measure. The results are shown in Table 8. Table 8 COD concentration (ppm) _ --- Initial concentration 10 minutes 15 minutes after 30 minutes 60 minutes after 120 minutes Example 13 40 30 30 28 Τ Example 14 20 — 20 13 η 10 Comparative Example 3 20 1 20 20 20 20 Comparative Example 5 40 35 30 30 Is — [Result] As shown in Table 8, when the nonwoven fabrics of Examples 13 and 14 were used, compared with Comparative Examples 3 and 5, the COD concentration decreased faster and showed Good water purification performance. In particular, after 12 minutes from the start of measurement, the COD concentration of Example 14 # will be half of the concentration of COD of Comparative Example 3, and the water purification performance will be improved. This is considered to be because the activated carbon particles (organic substance adsorbing particles) in the nonwoven fabric of Example 14 were adhered by the moist heat gelled gelation substance fixed on the fiber surface, so that the state of the organic substance adsorbing particles was on the exit surface. Compared with the comparative example, the reduction in the specific surface area of the organic-adsorbing particles was suppressed. [Activated carbon shedding rate] The nonwoven fabrics of Example 14 and Comparative Example 5 were cut so that the amount of activated carbon became 1.21 g. The size of the cut sample is 42 200540309 30 cm x 20 cm in Example 1 and 66 cm x 10 cm in Comparative Example 5. Next, 2 liters of water was added to a 3 liter flask, and the aforementioned samples of Examples 3 and Comparative Example $ were placed in the water in the flask and stirred with a magnetic stirrer for 4 hours. After that, take out the sample 'glass filter paper (manufactured by Toyo Filter Co., Ltd. under the trade name "Adebon Tik", catalog "glass fiber GS25", diameter 47mm) of the remaining liquid in the flask to filter by suction. , Dry the filtered glass filter paper, and then measure the quality of the dried glass filter paper. Then, calculate the amount of active carbon shedding and the shedding rate based on the mass of glass paper. The amount of active carbon shedding is a value obtained by subtracting the mass of the glass filter paper after drying from the mass of the glass filter paper before filtering. The shedding rate of activated carbon is a value obtained by dividing the shedding amount of activated carbon by the amount of activated carbon (121 g) before the test and multiplying by 100. The results are shown in Table 9. Table 9 Activated carbon amount (g) Shedding amount (g) Shedding rate (g) Example 14 1.21 0.0016 0.13 Comparative example 5 1.21 0.0201 1.66 [Result] As shown in Table 9, the nonwoven fabric of Example 14 was compared with the comparative example The amount of non-woven fabrics to be detached from activated carbon and the detachment rate were suppressed. This is considered to be because the activated carbon (activated carbon particles) in the non-woven fabric of Example 丨 4 was adhered by the moist heat gelled gelation substance fixed on the fiber surface, so compared with Comparative Example 5, the activated carbon can be more Keep it strong. 43.200540309 [Example 15] (Production of a non-woven original plate) The sheath component was ethylene-vinyl alcohol copolymer resin vOH, the ethylene content was 38 mol%, and the melting point was 176 ° C. The core component was polypropylene (pp, Core-sheath composite fiber (fineness: 2.8 dtex, fiber length: 51 mm) with an EVOH · PP of 50:50 (volume ratio) with a melting point of 161 C). The core-sheath type composite fiber was opened with a semi-random carding machine, and a card web having a weight per unit area of 40 g / m2 was produced. Next, the card is placed on a 90-mesh plain-woven support, and the nozzles of the row orifices (diameter · 0.12mm, pitch: 0 · 6ππη) are arranged in the width direction of the card toward the card. After the water stream was sprayed in the water M hall, the water m slit was further used for spraying. Next, the card was turned upside down, and a water flow was sprayed from the nozzle at a water pressure of 4 Mpa to produce a water-flow-entangled nonwoven fabric original sheet. (Preparation of Additives) For the additives, activated carbon particles are used: "Kuraray Colu pl-D" (manufactured by Kuraray Chemical Co., Ltd., the average diameter of coconut shell carbon is corrected.) ) The original non-woven fabric sheet was immersed in an additive dispersion solution (in 20.0) composed of 10% by mass of the aforementioned activated carbon particles dispersed in water, and the stripping rate was adjusted by the pressing pressure of a roll mill. ≫ 〇-3mm stainless working temperature 140 ° C. The forming system covers the mouth of the person, and the non-woven fabric containing moisture and additives is lost between a pair of metal molds made of a thick steel plate and put into a hot air dryer. With a contact pressure of 10 minutes as the heating place, a bowl-shaped metal mold was used to make the shape shown in Figure 8, and 200540309 was used to make the cover calculated from the leaves shown in Figure 9. The results were all 100 mass nose. Cover 40 'A discounted processed product using a filter for an air quieter using a discounted metal mold. The percentage of activated carbon particles attached to the discounted processed product,%. Yes, 1 turtle's cover' has a moderate Soft and maintains a fibrous shape

二維均勻分散之深抽的碗型成形體。藉由凝膠化物 4疋之活性碳粒子，並不會從成形體脫^。又，即使戴 上罩體’也不會有呼吸困難的感覺。目9之打摺加工品， 保持著纖維狀態’纖維呈均勻分散，為打摺之山谷（折曲面） 明顯之深抽的成形體。藉由凝膠化物所固定之活性碳粒 子’並不會從成形體脫落。冑9之打摺加工品，由於確實 地摺疊者，所以對於打摺型卡匣式過濾器之加工性也良 好0 本發明能提供一種可保持原本纖維之性質、且能有效 毛揮H、、加物所具有之功能的添加物附著纖維、纖維構造物 以及纖維成形體、以及其等之製造方法。 本發明中，由於添加物在纖維表面係以凝膠化物來附 著，所以添加物不易脫落，可於露出在纖維表面之狀態下 附著。例如’將本發明之纖維構造物使用於氣體吸附材的 情況，氣體吸附性粒子利用纖維表面之凝膠化物來附著， 所以氣體吸附性粒子可在露出於表面之狀態下附著。藉 此’可防止於纖維表面所附著之氣體吸附性粒子之脫落， 且可抑制氣體吸附性粒子之比表面積的減少，故相較於以 往之氣體吸附材，可提升氣體吸附性能。又，將本發明之 45 200540309 纖維構造物使用於水質淨化材的情況，由於有機物吸附性 粒子以纖維表面之凝膠化物來附著，所以有機物吸附性粒 子可在露出於表面之狀態下附著。藉此，彳防止於纖維表 面所附著之有機物吸附性粒子之脫^，且可抑制有機物吸 附性粒子之比表面積的減少，故相較於以往之水質淨化 材’可提升淨化性能。 本發明之纖維成形體’黏結劑樹脂係含有濕熱凝勝化 樹脂，纖維構造物之纖維係以濕熱凝膠化樹脂經濕孰凝膠 化之凝膠化物所固定，成形為既定之形狀，藉此，於衣料 用途的情$兄，喊直接《間接接觸至,】人的a膚也呈現柔軟 之感覺。又’成形均勻’可得到深抽之形&。再者，添加 物可有效地附著於纖維表面。 又，本發明之纖維成形體之製造方 維與濕熱凝膠化樹脂之纖維集合體，進行濕熱成形加工， 藉此，可均勾地成形，即使是深抽之形狀也容易成形。於 一般用途可降低成形成本。 產業上可刺用料 本發明之添加物附著纖維以及纖維構造物可適用於用 以研磨牙齒之長絲纖維（DENT.e彻s)、做為工業用研磨 之於透鏡、半導體、金屬、塑膠、陶竟、玻璃等各種領域 的研磨材、於家庭用或業務用厨房等所使用之研磨材 以吸附有害氣體等之氣體吸附材、抗菌材、除臭材、離子 交換材、污水處理用材、吸油材、金屬吸附材、電池分隔 物用不織材、導電性材、制電性（抗靜電）材、調濕、除濕（防 46 200540309 止結露）材、吸音一隔音材、防蟲—防黴材、抗病毒材等。 例如’氣體吸附材、抗病毒材可使用於建材之養生片、壁 紙、罩體、空調用等之過濾器。 本發明之纖維成形體於衣料用途的情況，可用於例如 肩塾、***墊、外套之衣領襯布、袖襯布、口袋襯布、前 身大片、後身大片、鑲邊、褲子的腰襯布等。又非衣料用 途的情況，可成形為：罩體、空氣清靜機或真空室所使用 之過濾器濾材的打摺加工品、空調用空氣導管之隔熱材、 配官、管子、平板、經壓延機加工之表面具有凹凸花紋之 片材等。 【圖式簡單說明】 圖1A〜1C係本發明之一實施形態之添加物附著纖維之 截面圖。 圖2係本發明之一實施形態之3層構造之不織布截面A bowl-shaped formed body that is two-dimensionally and evenly drawn. The activated carbon particles of the gel 4 疋 are not removed from the formed body. In addition, even when the cover is worn, there is no feeling of breathing difficulty. The discounted processed product of No. 9 maintains the fiber state, and the fibers are uniformly dispersed and formed into a deep-drawn deep-drawn valley (folded curved surface). The activated carbon particles' fixed by the gelation material do not fall off from the formed body. The discounted processed product of 胄 9 has good processability for discounted cassette filters because it is surely folded. The present invention can provide a fiber that can maintain the properties of the original fiber and can effectively fluff H ,, Additives having the functions of the additive adhere to fibers, fiber structures, and fiber formed bodies, and methods for manufacturing the same. In the present invention, since the additive is adhered as a gel on the surface of the fiber, the additive is not easily detached and can be adhered while being exposed on the surface of the fiber. For example, when the fibrous structure of the present invention is used for a gas adsorbent, the gas adsorbent particles are adhered by the gelation on the fiber surface, so the gas adsorbent particles can be adhered while exposed on the surface. This can prevent the gas-adsorbing particles attached to the fiber surface from falling off, and can suppress the decrease in the specific surface area of the gas-adsorbing particles. Therefore, compared with the conventional gas-adsorbing materials, the gas-adsorbing performance can be improved. In addition, when the fiber structure of the present invention 45 200540309 is used in a water purification material, since the organic-adsorbing particles are adhered as a gel on the surface of the fiber, the organic-adsorbing particles can be attached while exposed on the surface. Thereby, 彳 prevents the desorption of organic-adsorbing particles attached to the surface of the fiber, and can suppress the reduction of the specific surface area of the organic-adsorbing particles, so that the purification performance can be improved compared to the conventional water purification materials. The fibrous formed body 'binder resin of the present invention contains a moist thermosetting resin, and the fibers of the fibrous structure are fixed with a moist gelled resin by a wet gelled gel, and formed into a predetermined shape. Therefore, in the clothing use of love brother, shouted directly "indirect contact to," human a skin also appears soft. Also, "formed uniformly" can obtain the shape of deep drawing &. Furthermore, the additives can effectively adhere to the fiber surface. In addition, the manufacturing method of the fiber shaped body of the present invention and the fiber assembly of the moist heat gelled resin are subjected to moist heat forming processing, so that it can be uniformly shaped, and it is easy to form even a deep drawn shape. Reduces molding costs for general use. Industrially stabile materials The additive-attached fibers and fiber structures of the present invention can be applied to filament fibers (DENT.e.s.) used to grind teeth, and used in lenses, semiconductors, metals, and plastics for industrial grinding Abrasive materials in various fields such as ceramics, ceramics, glass, etc., abrasive materials used in household or business kitchens to absorb harmful gases, antibacterial materials, deodorant materials, ion exchange materials, sewage treatment materials, Oil absorbing materials, metal absorbing materials, non-woven materials for battery separators, conductive materials, electrical (antistatic) materials, humidity control, dehumidification (anti-46 200540309 anti-condensation) materials, sound-absorbing sound insulation materials, insect-proof Mold material, antiviral material, etc. For example, the 'gas adsorbent material and antiviral material can be used as filters for building materials, wall paper, covers, air conditioners, and the like. When the fiber formed product of the present invention is used for clothing, it can be used in, for example, shoulder pads, breast pads, collar interlinings of sleeves, sleeve interlinings, pocket interlinings, front body large pieces, rear body large pieces, trimmings, waist interlinings of pants, and the like. In the case of non-clothing applications, it can be formed into a discounted product of a filter body used in a cover body, an air purifier or a vacuum chamber, an insulation material for an air duct for an air conditioner, a distribution official, a pipe, a flat plate, and a calendar Sheets and the like with a textured pattern on the machined surface. [Brief description of the drawings] Figs. 1A to 1C are cross-sectional views of an additive-adhering fiber according to an embodiment of the present invention. Fig. 2 is a cross section of a non-woven fabric with a three-layer structure according to an embodiment of the present invention

圖3係本發明之製造方法之一例製程圖。FIG. 3 is a process diagram of an example of a manufacturing method of the present invention.

子^圖4A係以本發日月之實施例1所得之不織布的掃描 "’貝祕鏡平面照片（倍率100)。 圖4B係同截面照片（倍率1〇〇)。 1〇〇〇) 圖4C係、同不織布表面之纖維表面放大照片(倍率 圖 片（倍率 奶係同其他部分不織布的掃#電子顯微鏡平 100) 〇 面照 圖4E係同截面照片（倍率100)。 47 200540309 圖4F係同不織布表面之纖維表面放大照片（倍率 1000) 〇 圖5 A係以本發明之實施例6所得之不織布的掃描電 子顯微鏡平面照片（倍率1〇〇)。 圖5B係同戴面照片（倍率100)。 圖5C係同不織布表面之纖維表面放大照片（倍率 !〇0〇) 〇 • 圖6係水循環式簡易試驗機之示意立體圖。 圖7係本發明之一實施形態之對於不織布賦予水分之 一例製程圖。 圖8係本發明之一實施形態之纖維成形體（罩體）之立 體圖。 圖9係本發明之一實施形態之纖維成形體（空氣清靜機 過據器之打損加工品）之立體圖。 圖10係本發明之製造方法其他實施例之製程圖。 % 圖11A係以本發明之實施例7所得之不織布的掃描電 子顯微鏡平面照片（倍率200)。 圖11B係同不織布表面之纖維表面放大照片（倍率 2〇〇0) 〇 【主要元件符號說明】 1 勒成分（黏結劑樹脂） 2 芯成分 0 、 添加物 4 黏結劑樹脂 48 200540309 5,6,9 複合纖維 7 乙烯一乙烯醇共聚樹脂 8 聚丙烯 11 添加物附著纖維層 12 人造絲纖維層 20 水循環式簡易試驗機 21 台座 22a，22b 固定夾具 23 容器 23a 開口 24 泵 24a，24b 管 25 小片 26 茶包 27 試驗用樣本 28 金屬線 31 纖維或不織布 32 槽 33 添加物分散溶液 34 擠壓輥 35 蒸氣機 36 吸氣機 37 加熱輥 38 圖案化用帆布輸送帶幸昆 49 200540309Fig. 4A is a scanning " 'bemy mirror plane photograph (magnification 100) obtained from Example 1 of the present sun and moon. FIG. 4B is a photograph of the same cross section (magnification 100). 100) Figure 4C is an enlarged photograph of the fiber surface of the same non-woven fabric surface (magnification picture (magnification milk system is the same as the other parts of the non-woven scan #electron microscope flat 100). Figure 4E is the same cross-section photograph (magnification 100). 47 200540309 Figure 4F is an enlarged photo of the fiber surface of the same nonwoven surface (magnification 1000). Figure 5 A is a scanning electron microscope plan photograph of the non-woven fabric obtained in Example 6 of the present invention (magnification 100). Figure 5B is worn together. Photo (magnification 100). Figure 5C is an enlarged photo of the fiber surface of the same non-woven fabric surface (magnification! 〇〇〇) 〇 • Figure 6 is a schematic perspective view of a simple water cycle test machine. Figure 7 is an embodiment of the present invention. An example of a process for imparting moisture to a non-woven fabric. Fig. 8 is a perspective view of a fiber formed body (cover) according to an embodiment of the present invention. Fig. 9 is a fiber formed body (air-static machine passing device) according to an embodiment of the present invention. (Defective processed product). Figure 10 is a process drawing of another embodiment of the manufacturing method of the present invention.% Figure 11A is a scanning electron display of a non-woven fabric obtained in Example 7 of the present invention. Mirror plane photo (magnification 200). Figure 11B is an enlarged photo of the fiber surface on the same surface of the non-woven fabric (magnification 2000). [Description of main component symbols] 1 Le component (binder resin) 2 Core component 0, additive 4 Bonding Agent resin 48 200540309 5,6,9 Composite fiber 7 Ethylene-vinyl alcohol copolymer resin 8 Polypropylene 11 Additive attached fiber layer 12 Rayon fiber layer 20 Water cycle simple test machine 21 Stand 22a, 22b Fixing fixture 23 Container 23a Opening 24 Pump 24a, 24b, tube 25, small piece 26, tea bag 27, test sample 28, metal wire 31, fiber or non-woven cloth 32, slot 33, additive dispersion solution 34, squeeze roller 35, steam machine 36, aspirator 37, heating roller 38, patterned canvas conveyor belt. Kun 49 200540309

39 捲繞機 40 罩體 41 乾燥機 50 空氣清靜機過濾器之打摺加工品 5039 Winder 40 Hood 41 Dryer 50 Discounted air filter 50

Claims (1)

200540309 十、申請專利範圍： 1 · 一種添加物附著纖維，含有纖維、 "、邊纖維表面之 黏結劑樹脂、以及於該黏結劑樹脂所 娜夫机· 考之添加物；其特 之濕熱 該黏結劑樹脂為在水分存在下經加熱會凝膠化 凝膠化樹脂， > 該添加物係藉由該濕熱凝膠化樹脂 物來附著。 1是膠化之凝膠化 2·如申明專利範圍帛丨χ員之添加物附著纖維，其中， 该濕熱凝膠化樹脂係乙烯一乙烯醇共聚樹脂。 3.如申凊專利範圍帛J項之添加物附著纖維，其中， 該添加物之平均粒徑為〇 〇1〜1〇〇μηι之範圍。 4·-種纖維構造物，係含有添加物附著纖維，該添加 物附著纖維含有纖維、於該纖維表面之黏結劑樹脂、以及 於該黏結劑樹脂所附著之添加物；其特徵在於·· 該黏結劑樹脂為在水分存在下經加熱會凝膠化之渴執 凝膠化樹脂， 該添加物係藉由該濕熱凝膠化樹脂經凝膠化之凝膠化 物來附著。 / 5·如申請專利範圍帛4項之纖維構造物，其中，該渴 熱凝膠化樹脂係乙稀—乙#_㈣^ 6.如申晴專利範圍帛4項之纖維構造物，其中，該纖 維以及該黏結劑樹脂係擇自 / ⑴含有濕熱凝膠化樹脂成分與其他熱塑性合成纖維 51 200540309 成分之複合纖維； (π)該複合纖維與其他纖維所混合而成者； (瓜）該複合纖維與濕熱凝膠化樹脂所混合而成者；以 及 (IV)濕熱凝膠化樹脂與其他纖維所混合而成者； 中至少一種的組合。 7 ·如申請專利範圍第4項之纖維構造物，其中，該添 加物之平均粒徑為〇〇1〜1〇〇|1111之範圍。 8·如申請專利範圍第4項之纖維構造物，其中，該添 加物為無機粒子。 9·如申請專利範圍第8項之纖維構造物，其中，該無 機粒子係擇自氧化鋁、二氧化矽、三聚磷酸鈉(tripoly)、 鑽石、剛玉、剛砂、石榴石、打火石、合成鑽石、氮化硼、 山夕厌化硼、氧化鉻、氧化鈽、氧化鐵、矽酸膠體、 土沸石、二氧化鈦、高嶺土、黏土以及矽膠中至200540309 X. Scope of patent application: 1. An additive-attached fiber containing fibers, ", a binder resin on the surface of the fiber, and additives to the binder resin test; its special hot and humid The binder resin is a gelled resin that gels upon heating in the presence of moisture, and the additive is adhered by the moist heat gelled resin. 1 is the gelation of gelatinization. 2 · As stated in the patent, the additive-attached fibers of the members, wherein the moist heat gelation resin is an ethylene-vinyl alcohol copolymer resin. 3. The additive-attached fiber as described in the patent scope of item 帛 J, wherein the average particle diameter of the additive is in the range of 0.001 to 100 μm. 4 · -a fiber structure containing additive-attached fibers containing fibers, a binder resin on the surface of the fibers, and an additive attached to the binder resin; characterized in that ... The binder resin is a thirsty gelling resin that will gel when heated in the presence of moisture. The additive is adhered by the gelled gel of the moist heat gelling resin. / 5 · If the fiber structure of item 4 of the patent scope is applied for, the thirsty thermal gelation resin is ethylene—B # _㈣ ^ 6. If the fiber structure of item 4 of the Shenqing patent scope, where the The fiber and the binder resin are selected from / 纤维 composite fibers containing a moist gelling resin component and other thermoplastic synthetic fibers 51 200540309 component; (π) the composite fiber is mixed with other fibers; (melon) the composite A combination of fibers and moist heat gelled resin; and (IV) a combination of moist heat gelled resin and other fibers; a combination of at least one of them. 7. The fibrous structure according to item 4 of the patent application range, wherein the average particle size of the additive is in the range of 0.001 to 1100 | 1111. 8. The fibrous structure according to item 4 of the application, wherein the additive is inorganic particles. 9. The fibrous structure according to item 8 of the application, wherein the inorganic particles are selected from alumina, silica, tripoly, diamond, corundum, corundum, garnet, flint, Synthetic diamond, boron nitride, anaerobic boron oxide, chromium oxide, hafnium oxide, iron oxide, silicic acid colloid, clay zeolite, titanium dioxide, kaolin, clay, and silica gel. 少一種之粒子。 其中，該添 10·如申請專利範圍第9項之纖維構造物 °物係研磨劑，該纖維構造物係研磨不織布。 其中，該添 11·如申請專利範圍第4項之纖維構造物 ϋ物含有多孔質粒子。 多孔1 質2:子申物刪11項之纖維構造物，其中，該 匕質粒子係活性碳粒子。 / U·如申請專利範圍第12 纖維構造物係氣體吸附材。、義維構造物，其中，該 52 200540309 4.如申凊專利範圍第 纖維構造物係水質淨化材 12項之纖維構造物，其中，7 I5.如申請專利範 加物附著纖維係存在 維0 圍第4項之纖維構造物，其巾 於兩表面，内部係存在著親 ’該添 水性纖 Μ辱利範圍第15項之纖維構造物，复 親水性纖維孫姓1 Α ^ 、糸擇自人造絲纖維、棉纖維以及紙漿中、 種之纖維。 νOne less particle. Among them, the tenth, such as the fibrous structure of item 9 of the scope of the patent application ° material-based abrasive, the fiber structure is a non-woven fabric. Among them, the fibrous structure according to item 4 of the patent application scope contains porous particles. Porous 1 substance 2: Sub-item delete the fibrous structure of item 11, wherein the dagger particles are activated carbon particles. / U · As the 12th in the scope of patent application, the fiber structure is a gas adsorbent. Yiwei structure, of which 52 200540309 4. The fibrous structure of the fibrous structure of the water purifying material of the 12th category of the patent scope of the application, wherein 7 I5. If the patent application for the addition of the fibrous system, there is dimension 0. The fibrous structure surrounding item 4 has towels on both surfaces, and there is a fibrous structure within the range 15 of the humiliating fiber, and the complex hydrophilic fiber is surnamed 1 Α ^ Rayon fiber, cotton fiber, and pulp, the kind of fiber. ν 1 7·如申請專利範圍第4項之纖維構造物，其中， 維構造物係在厚度方向被壓縮成形而附著著。 ^ 種、截維成形體，係纖維構造物所成形而得者，該 纖維構造物係含有纖維、於該纖維表面之黏結劑樹脂、以 及於该黏結劑樹脂所附著之添加物附著纖維；其特徵在 於： 、1 〆黏、、° Θ丨树脂含有在水分存在下經加熱會凝膠化之濕 熱凝膠化樹脂， 該纖維構造物中，該纖維係藉由該濕熱凝膠化樹脂經 凝膠化之凝膠化物來固定並成形為既定之形狀。 19.如申請專利範圍第18項之纖維成形體，其中，該 纖維成形體係以接觸壓成形加工所成形者。 2〇·—種添加物附著纖維之製造方法，係用以製造含有 纖維、於該纖維表面之黏結劑樹脂、以及於該黏結劑樹脂 所附著之添加物的添加物附著纖維；其特徵在於： 該纖維以及該黏結劑樹脂係在水分存在下經加熱而凝 53 200540309 膠化之濕熱凝膠化纖維， 將溶液中分散有該添加物之添加物分散溶液賦予於該 濕熱凝膠化纖維， 其次，在濕熱環境氣氛下對該濕熱凝膠化纖維進行滿 熱處理，使得該濕熱凝膠化纖維凝膠化，以凝膠化物將該 添加物附著於纖維表面。 、儿如申請專利範圍第20項之添加物附著纖維之製造 方法’其中，該濕熱凝膠化纖維係濕熱凝膠化樹脂單獨或 是含有濕熱凝膠化樹脂成分與其他熱塑性合成纖維成分之 複合纖維。 士申明專利範圍第20項之添加物附著纖維之製造 方法中，忒濕熱環境氣氛係該濕熱凝膠化樹脂之凝膠 化溫度〜熔點_2(TC之溫度範圍。 ’ 23.—種添加物附著纖維之製造方法，係用以製造含有 纖維H纖維表面之黏結劑樹脂、於該黏結劑樹脂所附 著之添加物的添加物附著纖維；其特徵在於： I纖維與該黏結劑樹脂係其他纖維與濕熱凝膠化樹 脂， 對T其他纖維賦予該濕熱凝膠化樹脂之後再賦予添加 物，或是將溶液中分散有該添加物以及該濕熱凝膠化樹脂 之添加物分散溶液賦予於該其他纖維， 士 =次，在濕熱環境氣氛下進行濕熱處理將該濕熱凝膠 化樹脂凝膠化，以凝膠化物將該添加物附著於其他纖維表 面。 54 200540309 24. —種纖維構造物之製造方法，係用以製造含有添加 物附著纖維之纖維構造物，該添加物附著纖維含有纖維、 於該纖維表面之黏結劑樹脂、以及於該黏結劑樹脂所附著 之添加物；其特徵在於： 該黏結劑樹脂為在水分存在下經加熱會凝膠化之濕熱 凝膠化樹脂， A… 該纖維以及該黏結劑樹脂係擇自 (I )含有濕熱凝膠化樹脂纖維成分與其他熱塑性合成 纖維成分之複合纖維； (Π )該複合纖維與其他纖維所混合而成者； (Π)該複合纖維與濕熱凝膠化樹脂所混合而成者； (IV)濕熱凝膠化樹脂與其他纖維所混合而成者； 中至少一種的組合， 以該纖維以及該黏結劑樹脂來製作纖維構造物， 將溶液中分散有該添加物之添加物分散溶液賦予於該 纖維構造物， 其次，在濕熱環境氣氛下對該濕熱凝膠化樹脂進行濕 熱處理，使得该濕熱凝膠化樹脂凝膠化，以凝膠化物將該 添加物附著於纖維表面來形成添加物附著纖維。 25·如申請專利範圍第24項之纖維構造物之製造方 法’其中’該濕熱環境氣氛係該濕熱凝膠化樹脂之凝膠化 溫度〜熔點-20°C之溫度範圍。 26.如申請專利範圍第24項之纖維構造物之製造方 法，其中，該濕熱處理係在厚度方向壓縮成形之處理。 55 200540309 27·如申請專利範圍第24項之 、哉維構造物之製造方 法，其中，該濕熱處理係以蒸氣所進行之處理。 28·如申請專利範圍第24項之總祕扭 貝之纖維構造物之製造方 法，其中，該添加物分散溶液係水 丁八心/夜或是含有濕熱凝膠 化樹脂之水溶液。 29_—種纖維成形體之製造方法 1恭用以製造由纖維構 造物所成形而得之纖維成形體，該纖維構造物含有纖維、 於該纖維表面之黏結劑樹脂、於該黏結劑樹脂所附著之添 加物附著纖維；其特徵在於， 该黏結劑樹脂係含有藉由在水分存在下加熱而凝膠化 之濕熱凝膠化樹脂， 形成含有該纖維與黏結劑樹脂之纖維構造物， 使得該纖維構造物在金屬模具内、濕熱環境氣氛下將 〇亥濕熱凝膠化樹脂濕熱凝膠化做濕熱成形加工。 30.如申請專利範圍第29項之纖維成形體之製造方 法’其中’該濕熱成形加工係將含有水分與添加物之纖維 構造物***一對之金屬模具内，進行加熱加壓處理之加 工 〇 31·如申請專利範圍第29項之纖維成形體之製造方 法’其中’該濕熱成形加工係以纖維構造物與金屬模具之 接觸壓力來進行加工之接觸壓成形加工。 十一、囷式： 如次頁。 5617. The fiber structure according to item 4 of the scope of patent application, wherein the dimension structure is compressed and formed in the thickness direction and adheres. ^ Species, cut-shaped shaped bodies, obtained by forming a fiber structure, the fiber structure containing fibers, a binder resin on the surface of the fibers, and an additive-attached fiber attached to the binder resin; It is characterized by:, 1 〆 sticky, ° Θ 丨 The resin contains a moist heat-gelation resin that will gel when heated in the presence of moisture. In the fiber structure, the fibers are coagulated by the moist heat-gelation resin. The gelled gel is fixed and shaped into a predetermined shape. 19. The fibrous formed body according to claim 18, wherein the fibrous formed system is formed by contact pressing. 2 ·· A manufacturing method of an additive-attached fiber is used for manufacturing an additive-attached fiber containing the fiber, a binder resin on the surface of the fiber, and an additive attached to the binder resin; The fiber and the binder resin are coagulated by heating in the presence of moisture. 53 200540309 Gelatinized moist heat gelled fiber. An additive dispersion solution in which the additive is dispersed in a solution is given to the moist gelled fiber. Next, , Performing a full heat treatment on the moist gelled fiber in a moist and hot environment atmosphere, so that the moist gelled fiber is gelled, and the additive is attached to the surface of the fiber as a gel. 2. The manufacturing method of the additive-attached fiber according to item 20 of the patent application, wherein the moist gelling fiber is a moist gelling resin alone or a compound containing a moist gelling resin component and other thermoplastic synthetic fiber components. fiber. In the manufacturing method of the additive-attached fiber according to the patent claim No. 20, the moist heat environment atmosphere is the gelation temperature of the moist-heat gelled resin to the melting point of _2 (TC temperature range. '23.—Additives The manufacturing method of the attached fiber is used to produce a binder resin containing the surface of the fiber H fiber and an additive attached fiber to the additive to which the binder resin is attached; characterized in that: the I fiber and the binder resin are other fibers With the moist gelling resin, add the moist gelling resin to other fibers, and then add the additive, or disperse the additive and the moist gelling resin dispersion solution in the solution to the other fibers. Fiber, ± = times, wet heat treatment in a hot and humid environment atmosphere to gel the moist heat gelled resin, and the additive is attached to the surface of other fibers with a gel. 54 200540309 24. — Fabrication of a kind of fiber structure The method is used for manufacturing a fibrous structure containing fibers attached to the additive, the fibers containing the additive attached to the fiber, Binder resin, and additives attached to the binder resin; characterized in that: the binder resin is a moist heat gelling resin that will gel when heated in the presence of moisture, A ... the fiber and the binder resin It is selected from (I) a composite fiber containing a moist gelling resin fiber component and other thermoplastic synthetic fiber components; (Π) the composite fiber and other fibers are mixed; (Π) the composite fiber and moist gelation (IV) a mixture of resin and resin; (IV) a mixture of at least one of wet-moist gelled resin and other fibers; a combination of at least one of the following: the fiber and the binder resin are used to make a fiber structure, and the solution is dispersed in the solution; An additive dispersion solution of the additive is provided to the fiber structure. Next, the wet-heat gelled resin is subjected to a wet heat treatment in a humid and hot environment atmosphere, so that the wet-heat gelled resin is gelled, and the added The fiber adheres to the surface of the fiber to form an additive-attached fiber. 25. The manufacturing method of the fiber structure according to item 24 of the patent application 'wherein' the moist heat ring The atmosphere is a temperature range from the gelation temperature of the moist gelled resin to the melting point of -20 ° C. 26. The method for manufacturing a fiber structure according to item 24 of the application for a patent, wherein the wet heat treatment is compressed in the thickness direction Forming treatment. 55 200540309 27. For example, the manufacturing method of the three-dimensional structure according to item 24 of the patent application, wherein the heat treatment is performed by steam. 28. The general secret of item 24 of the patent application A method for producing a twisted fibrous structure, wherein the additive dispersion solution is hydration, or an aqueous solution containing a moist gelling resin. 29_—A method for manufacturing a fiber formed article A fibrous formed body formed from a fibrous structure, the fibrous structure comprising fibers, a binder resin on the surface of the fibers, and an additive-attached fiber attached to the binder resin; characterized in that the binder resin is Containing a moist gelling resin gelled by heating in the presence of moisture to form a fibrous structure containing the fiber and a binder resin such that The fibrous structure was hydrothermally gelled in a metal mold under a humid and hot ambient atmosphere to perform a hydrothermal forming process. 30. The method for manufacturing a fibrous formed article according to item 29 of the scope of the patent application, wherein the wet thermoforming process is a process in which a fibrous structure containing moisture and additives is inserted into a pair of metal molds and subjected to heat and pressure treatment. 31. The method for manufacturing a fibrous formed article according to item 29 of the patent application, wherein the wet thermoforming process is a contact pressure forming process in which the contact pressure between the fiber structure and the metal mold is used for processing. Eleven, style: as the next page. 56