TW200529916A - Germicidal solution generation device and a compact and easy-to-use water purifier having germicidal solution generation device - Google Patents

Abstract

This invention provides a germicidal solution generation device capable of effectively generating germicidal solution and a compact and easy-to-use water purifier having germicidal solution generation device, without the need of electrical current and having a simple and safe structure. The germicidal solution generation device includes: a tubular cathode that is open at opposite ends formed by base metal upon contact erosion of different metals; and an anode that is configured as an open compartment within the cathode in a non-contact manner, and formed by noble metal upon contact erosion of different metals. An electromotive force greater than 0.7 volts is generated by placing the liquid between the anode and cathode. The germicidal solution generation device can be installed in a liquid circulation device. The liquid circulation device can serve as a compact and easy-to-use water purifier having the germicidal solution generation device.

Description

200529916 玖、發明說明： 【發明所屬之技術領域】 發明領域 本發明係有關於一種可使用於各種液體，特別是可適 5用於飲料用之殺菌液產生裝置及附設有殺菌液產生裝置之 小型簡易淨水器。 C先前3 發明背景 迄今，在食品用等液體中之殺菌技術一直擔任重要任 10 務’且目前已有各種殺菌方法。 代表者有使用化學藥品之方法、加熱方法、加壓方法、 及利用紫外線·輻射線·超音波照射等方法，但上述使用 化學藥品之方法中，會有添加藥劑的殘留的問題，又，加 熱、加壓方法雖然乾淨，但會有限定適用對象物且必須有 15 較大設備，故有消耗能源高之缺點。 又’習知也有使用活性碳及中空系過濾器吸附異種菌 之過濾式淨水器，雖然具有構造簡單之優點，但本身並無 殺菌作用，也會產生吸附於過濾材之活性碳及中空系過濾 器等表面的菌體繁殖而容易引起堵塞等缺點。 20 另一方面，因近年來的研究而開發出一種利用細胞-電 極間的電子移動反應之電化學殺菌方法，且使用當中的低 電壓殺菌法之習知淨水器。即，如第8圖所示，在淨水器51 下方設置陽極體52(活性碳纖維）及陰電極53,並浸潰於所注 入之未處理水（自來水）内，利用乾電池施加15伏特之電 200529916 位，則存在於自來水中之菌體會死亡，再使水流過活性碳 纖維以產生乾淨的水。藉由此方法，可以安全且較簡單的 構造殺菌抑制菌體繁殖，但，仍希望有構造更簡單之殺菌 裝置。 5 又，也有在貯液容器内浸潰過濾材之各種小型簡易淨 水器，該等淨水器保留對過濾材之異種菌吸附作用，對於 使用者而言更有助於水質提升。 再者，飲料用液體的殺菌設備，亦希望開發可以手動 方式將注入杯内的飲料用液體輕易地殺菌之殺菌裝置。 10 此外，近年來發現鎂離子與鈣離子對皮膚表面之抗衡 可促進回復皮膚阻抗機能的事實，因而開發摻合具有此作 用之鎂鹽的化妝品。但是，由於在化妝品中包含多種鎂鹽 以外的化妝品成分，因而，因應需要將鎂離子供給至皮膚 表面是有限制的。 15 【發明内容】 發明概要 有鑒於上述情形，本發明之第1目的係提供一種以可實 現具有簡單構造、安全且有效之液體殺菌之殺菌產生裝置 及附設有殺菌液產生裝置之小型簡易淨水器。 20 本發明之第2目的，係提供一種可以手動將注入杯内之 飲料用液體進行簡易地殺菌之攪拌器、附帶攪拌器的杯子 及杯子。 本發明之第3目的，係提供一種藉由因應所需將鎂離子 簡易地供給至皮膚表面，可有效地促進回復皮膚阻隔機能 200529916 之皮膚滚輪。 為了解決上述問題，發明人銳意檢討的結果發現，在 本發明中，若殺菌液產生裝置包含：筒狀陰電極，係開放由 在異種金屬接觸腐蝕時之賤金屬所形成之兩端者；及陽電極， 5 具有於前述陰電極内側以非接觸狀態配置之開放室構造且係 由在異種金屬接觸腐蝕時之責金屬所形成者，又，可藉由將液 體置於前述陰電極與陽電極之間而產生0.7伏特以上之電動 勢，則可令置於兩極間之液體中的多數菌體以大面積接觸 在開放室構造之陽電極而死亡，故適用於殺菌。 10 在該情形下，陰電極以鎭為佳。 又，由於陽電極為銅或銅合金時，難溶出至液體中且 由於為泛用材料、價格低，故較理想。 又，由於在陰電極下方設置過濾裝置可吸附液體中的 異物，故較理想。 15 此外，由於本殺菌裝置可小型地形成，故可安裝成可 使液體流過各種液體循環裝置内之型態。 因此，也可在貯液容器内裝載於收容有過濾部之液體 強制循環流路，並可達成提昇水質之小型簡易淨水器。 如申請專利範圍第7項之攪拌器，係由絕緣性細長棒狀 20 所形成者，又，在前述棒體分別設有間隔地安裝有由賤金 屬所形成之陰電極構件與由貴金屬所形成之陽電極構件所 形成者。利用該攪拌器，可將注入杯内之飲料用液體並僅 以手攪拌簡易地殺菌。 如申請專利範圍第8項之攪拌器，係在申請專利範圍第 200529916 7項中，於該棒體表面„方向設置複數具有間隔且沿著該 棒體長手方向之凹溝，並於前述凹溝分別安裳有由賤金屬 所形成之陰電極構件與由貴金屬卿紅陽電極構件所形 成者。利用該攪拌器’由於可均一地進行全部業已注入杯 内之飲料歸體之㈣，並可使前述㈣器型態更為緊 緻，故在設計上也是優異的。 ' 如申請專利範圍第9項之授拌器，係由絕緣體所形成之 細長棒體與由形成於該棒體-端之平板狀㈣部所形成 者，又，在前述_部設置複數間隔之凹溝，並於前述凹 1〇溝分別安裝由賤金屬所形成之陰電極構件與由責金屬所形 成之陽電極構件所形成者。利用該_器由於具有平板 狀之授拌:而增加搜拌作用，因而可在短時間進行飲料用 液體之杈囷，亚且在添加砂糖等粉末時，也可在短時間内 15 如申清專利範圍第10項之附設有授拌器之杯子，係具 有=自於由賤金屬所形成陰電極構件或由貴金屬所形成 構件之其中—電極構件所構成之杯子，及將與前 二，電極構件成對之另-電極構件安裝於絕緣性細長 j -所开/成之攪拌器。利用該附設有攪拌器之杯子，由於 杯子内圓周面之電極表面積，故可提升飲料用液 體的殺_效率。 =料利範圍第丨丨項之杯子，係㈣金屬所形成之 電極構件與由責金屬所形成之板狀陽電極構件以分 別隔開的狀態，設料在由合成翻旨卿成之杯子本體 20 200529916 内周面所形成者。利用該杯子，可藉由使用-般撥拌器來 擾拌飲料用液體，可輕易地進行收容於杯子的飲料用液體 之殺菌，並降低前述杯子的製造成本。 如申巧專利範圍第12項之皮膚滚輪，包含：握柄，係 5由絕緣體所形成；圓筒狀滾輪，係在該握柄前端可維持自 由旋轉且由鎂所形成；板狀金屬片，係安裝於前述握柄且 由鎂之貴金屬所形成；水分供給構件，係安裝於該金屬片 一端且配置為在旋轉前述滾輪時，可與該滾輪摩擦接觸； 及金屬細線，一端連接前述板狀金屬片並且另一端安裝於 10 前述握柄。 該皮膚滚輪，藉由在水分供給部材保持含浸水溶液， JL以手握住的握柄，在皮膚上以前後方向旋轉圓筒狀滾輪 之簡易操作，可從上述滾輪有效率地提供鎮離子至皮膚表 面，故可有效地促進回復皮膚阻抗機能。 又 15 【實施方式】 發明之實施型態 L不又围 液產生裝置與附設有該裝置之小型簡易淨水器] 在本發明中產生殺菌作用之原理是依據如上述之電化 學殺困方法所示，由於存在於液體巾㈣料貞電㈠，且 在可=的狀態下靠近陽電極，並在該狀態施加q 7伏特以 上之Μ，則生菌率會急劇地減少_死亡)之理論， 该叙囷法中之施加電壓的產生方法，係藉由相對配 腐料之賤金屬卿叙陰電極與由在異種全 屬接蜀雜金屬卿紅陽私，並使其浸漬於前 20 200529916 述液體中而形成電流電池，並且利用在其間自然地產生之 電動勢，以取代使用乾電池等電源者。 ，又，鎂顯示一1.6 一 1 ·0伏特左右之電 賤金屬可為鎂、辞、鈹、鋁合金等 伏特左右之電位，鋅、鈹、鋁金等顯示 位。 阶 测3、貧(J、鈦· 鎳·鉻·銅·矽合金B、鎳·鎩.狄 鐵鉻合金825、合金2〇、不 銹鋼、銅、銀等。其中，石墨 土及鉑係顯示+ 0·2伏特左右 電位，其他金屬係顯示0伏特左右之電位 10 15 本發明中之兩電極材料，可在該等貴金屬及賤 適當地選擇可產生〇.7伏特以上電動勢之組合來使用。 又，本發明所使用之陽電極係採用開放室構造。 藉由如此之構造，由於液體易流動並且相較於僅為平 面者可特別擴大陽電極表面積，因而接觸使液體中之多數 細菌，且可提升殺菌效率。 又’陽電極可油油合㈣⑽㈣，並以鎖作為 丢電極之組合，且這組合係可得到高且安定之電動勢。 以下，以貫施例為基礎加以說明具體之構造。 第1圖及第2圖顯示本發明之第丨實施例。 、^第1圖所示，本發賴使用之殺g液產生裝置i包含 :成筒狀之兩側端面3、娜放之陰電極2，及具有在該陰電 玉2内部以非接觸狀態配置之開放室構造的陽電極5。 y *電極2係鎮所製，且，如第2圖的照片所示，陽電極5 係由開放室構造形成，並_或含有5〜遍銀之銅合金所 200529916 形成者。 又，陽電極5的製作方法，可使用標準材料的成型品， 或者亦可於芯材上將胺基甲酸乙醋海綿或金屬纖維等作成 刷子狀，且形成規定形狀後藉由各種電鑛來塗佈銅或 5 5〜30%銀之銅合金。 〆 又，為了使陰電極2與陽電極5為非接觸狀態，則可如 在第3圖中顯示之A-A擴大截面圖所示，使用適當樹脂製等 之隔板6來設置間隙部7’但亦可如第*圖所示，在前述兩極 間夾置樹脂製等的網狀絕緣薄板8，而該情形是適合於殺菌 10液產生裝置1的外直徑尺寸不是很大時使用。 第5圖係表不第2實施例，在該實施例中的殺菌液產生 裝置11，與第1實施例不同者係可利用螺絲構造等將具有形 成網目狀等複數通液口 17之覆蓋構件19可自由装卸地安裝 在陰電極12兩側的開口部13、14。利用該構造可防止陽電 15 極15移動。 第6圖係顯示第3實施例，在該實施例中的殺菌液產生 裝置21係將第2實施例所示之其中一覆蓋構件作為過滤構 造。即，在陰電極22之其中一開口部24端部，以螺絲構造 等可自由裝卸地安裝收納有過濾構件26之可過渡覆蓋構件 20 29，而成為可吸附液體中不純物之裝置。 又，過濾構件可使用中空系構造及活性碳等適當構件。 到此所說明的第1〜第3實施例，係浸潰於各種貯液槽及 貯液用容器内使用，或配置於使液體從陰電極其中—端部 朝另一端部流動之流路中來使用。 200529916 在該使用狀態下，在陰電極2乃睡+L 电不上2及％電極5兩極間隔200529916 (1) Description of the invention: [Technical field to which the invention belongs] Field of the invention The present invention relates to a germicidal liquid generating device that can be used for various liquids, especially 5 beverages, and a small-sized germicidal liquid generating device Simple water purifier. C Previous 3 Background of the Invention So far, sterilization technology in liquids such as food has been an important task 'and various sterilization methods have been developed. Representatives include methods using chemicals, heating methods, pressurization methods, and methods using ultraviolet rays, radiation, and ultrasonic irradiation. However, in the above-mentioned methods using chemicals, there is a problem of residues of added chemicals, and heating Although the pressurization method is clean, it has limited applicable objects and must have 15 large equipment, so it has the disadvantage of high energy consumption. It is also known that there are filter-type water purifiers that use activated carbon and hollow filters to adsorb heterogeneous bacteria. Although they have the advantage of simple structure, they do not have bactericidal effects themselves, and they also produce activated carbon and hollow systems that are adsorbed on the filter material. Filters and other bacteria on the surface multiply and easily cause blockages. 20 On the other hand, as a result of recent research, an electrochemical sterilization method using a cell-electrode electron transfer reaction has been developed, and a conventional water purifier using a low-voltage sterilization method among them has been developed. That is, as shown in FIG. 8, an anode body 52 (activated carbon fiber) and a cathode electrode 53 are provided below the water purifier 51, and are immersed in the injected untreated water (tap water). A dry battery is used to apply 15 volts of electricity. At 200529916, the bacteria in the tap water will die, and then the water will flow through the activated carbon fiber to produce clean water. By this method, a safe and simple structure can be used for sterilization to suppress the proliferation of bacteria, but a sterilization device with a simpler structure is still desired. 5 In addition, there are various small and simple water purifiers that impregnate the filter material in the liquid storage container. These water purifiers retain the heterogeneous bacteria adsorption effect on the filter material, which is more conducive to the improvement of water quality for users. Furthermore, it is also desirable to develop a sterilization device for liquids for beverages that can be used to manually sterilize the liquids for beverages poured into the cups. 10 In addition, in recent years, it has been discovered that the counterbalance of magnesium ions and calcium ions on the skin surface can promote the restoration of the skin's impedance function. Therefore, cosmetics containing magnesium salts having this effect have been developed. However, since cosmetics contain a variety of cosmetic ingredients other than magnesium salts, there is a limitation in supplying magnesium ions to the skin surface if necessary. 15 [Summary of the Invention] In view of the above circumstances, a first object of the present invention is to provide a sterilization generating device capable of realizing liquid sterilization with a simple structure, safe and effective, and a small and simple water purification device with a sterilizing liquid generating device. Device. 20 A second object of the present invention is to provide a stirrer, a cup and a cup with a stirrer, which can easily sterilize the beverage liquid poured into the cup manually. A third object of the present invention is to provide a skin roller which can effectively promote the restoration of skin barrier function by simply supplying magnesium ions to the skin surface in response to needs. In order to solve the above problems, the inventor's earnest review revealed that, in the present invention, if the sterilizing liquid generating device includes: a cylindrical negative electrode, both ends of which are formed by a base metal when the dissimilar metal contacts and corrodes; and The anode electrode, 5 has an open chamber structure arranged in a non-contact state on the inside of the foregoing cathode electrode and is formed of a metal responsible for dissimilar metal contact corrosion, and the liquid can be placed on the foregoing cathode electrode and anode electrode. When an electromotive force of 0.7 volts or more is generated between them, most of the bacteria in the liquid between the electrodes can die in a large area by contacting the positive electrode in the open chamber structure, so it is suitable for sterilization. 10 In this case, the cathode is preferably 鎭. In addition, when the anode electrode is copper or a copper alloy, it is difficult to elute into the liquid, and it is preferable because it is a general-purpose material and has a low price. Also, it is preferable to provide a filtering device under the cathode to adsorb foreign substances in the liquid. 15 In addition, since the sterilization device can be formed in a small size, it can be installed so that liquid can flow through various liquid circulation devices. Therefore, it is also possible to load a liquid forced circulation flow path containing a filtering part in a liquid storage container, and to achieve a small and simple water purifier for improving water quality. For example, the agitator in the seventh scope of the patent application is formed by an insulating slender rod-shaped 20, and the rod body is provided with a negative electrode member made of a base metal and a noble metal, which are separately installed. Formed by the positive electrode member. With this blender, the beverage liquid poured into the cup can be easily sterilized by just stirring by hand. For example, the agitator with the scope of patent application No. 8 is in the scope of the scope of patent application No. 200529916 7 with a plurality of grooves on the surface of the rod with a space along the long hand direction of the rod, and in the aforementioned groove. Ansang has a cathode electrode member made of base metal and a precious metal member made of red sun electrode. Using this blender, since all the drinks that have been poured into the cup can be uniformly integrated, and can make The shape of the aforementioned utensil is more compact, so it is also excellent in design. 'For example, the stirrer in the scope of patent application No. 9 is an elongated rod body formed of an insulator and a rod body formed at the end of the rod body. For the flat plate-shaped crotch, a plurality of grooves are provided in the _ section, and a female electrode member made of a base metal and a positive electrode member made of a metal are installed in the groove 10 respectively. Formed by the use of this device because of the flat-shaped mixing: to increase the search and mixing effect, so you can carry out a short time for the liquid liquid for beverages, and when adding powder such as sugar, can also be within a short time 15 Rushen The cup with a stirrer in item 10 of the Qing patent scope is a cup composed of an electrode member formed of a cathode electrode member formed of a base metal or a member formed of a precious metal, and will be the same as the first two, The electrode members are paired-the electrode members are mounted on an insulating slender j-blender. With this cup equipped with a stirrer, the surface area of the electrode on the inner circumferential surface of the cup can enhance the killing of beverage liquids. _Efficiency. = The cup of item 丨 丨 in the range of materials and materials, the electrode member formed of metal and the plate-shaped anode electrode member formed of metal are separated from each other. The cup body 20 200529916 is formed by the inner peripheral surface of the cup. By using the cup, it is possible to stir the beverage liquid by using a general stirrer, and the sterilization of the beverage liquid contained in the cup can be easily performed, and the aforementioned cup can be lowered. For example, the skin roller of item 12 of Shenqiao's patent scope includes: a grip, which is formed by an insulator 5; a cylindrical roller, which is maintained at the front end of the grip and can rotate freely and is made of magnesium Formed; a plate-shaped metal sheet mounted on the aforementioned handle and formed of a noble metal of magnesium; a moisture supply member mounted on one end of the metal sheet and configured to be in frictional contact with the roller when the aforementioned roller is rotated; and metal A thin wire with one end connected to the aforementioned plate-shaped metal sheet and the other end attached to the aforementioned handle 10. The skin roller maintains the impregnated aqueous solution in the moisture supply part, and the grip held by the hand is rotated round and round on the skin. The simple operation of the cylindrical roller can efficiently provide ballast ions to the skin surface from the above roller, so it can effectively promote the restoration of skin impedance function. Another embodiment [Embodiment] The embodiment L of the invention does not have a surrounding fluid generating device and The small and simple water purifier equipped with the device] The principle of generating bactericidal effect in the present invention is based on the electrochemical trapping method as described above. Close to the positive electrode, and apply M above q 7 volts in this state, the bacterial growth rate will decrease sharply _ death) theory, the application in this method The method of generating the pressure is to form a current battery by comparing the base metal electrode with a rot material to the negative electrode and the red metal material connected to the heterogeneous metal and immersing it in the liquid described in the first 20 200529916. And use the electromotive force naturally generated in the meantime to replace the use of power sources such as dry batteries. In addition, magnesium shows a voltage of about 1.6 to 1.0 volts. The base metal can be a potential of about volts such as magnesium, rhenium, beryllium, and aluminum alloys, and zinc, beryllium, aluminum, and gold. Level 3, Lean (J, Titanium, Nickel, Chromium, Copper, Silicon Alloy B, Nickel, 铩. DiFeCr alloy 825, Alloy 20, Stainless steel, Copper, Silver, etc. Among them, graphite and platinum show + A potential of about 0.2 volts, and other metals show a potential of about 0 volts 10 15 The two electrode materials in the present invention can be appropriately selected and used in combination with such precious metals and bases that can generate an electromotive force of 0.7 volts or more. The anode electrode used in the present invention adopts an open chamber structure. With such a structure, since the liquid is easy to flow and the surface area of the anode electrode can be particularly enlarged compared to a person who is only a flat surface, the contact can cause most bacteria in the liquid, and can Improve sterilization efficiency. The combination of the positive electrode can be combined with oil and oil, and the lock is used as a lost electrode combination, and this combination can obtain a high and stable electromotive force. The specific structure will be described below based on the examples. Fig. 1 and Fig. 2 show the first embodiment of the present invention. As shown in Fig. 1, the g-killing liquid generating device i used by the present invention includes: a cylindrical end surface 3 on both sides; 2, and having in the cathode electricity 2 The positive electrode 5 of the open-cell structure arranged inside in a non-contact state. Y * The electrode 2 is made by the town, and, as shown in the photo in FIG. 2, the positive electrode 5 is formed by the open-cell structure and contains or contains Founder of 5 ~ 5 times silver copper alloy institute 200529916. For the method of making the anode electrode 5, a molded product of a standard material can be used, or a urethane sponge or metal fiber can be made into a brush shape on the core material. After forming a predetermined shape, copper or a copper alloy of 5 5 to 30% silver is coated by various electric ore. 〆 In order to make the negative electrode 2 and the positive electrode 5 in a non-contact state, it can be as shown in FIG. 3 As shown in the enlarged AA sectional view shown in the figure, a spacer 6 'is provided using a spacer 6 made of an appropriate resin or the like. However, as shown in FIG. However, this case is suitable for use when the outer diameter size of the sterilizing 10-liquid generating device 1 is not very large. Fig. 5 shows the second embodiment, and the sterilizing liquid generating device 11 in this embodiment is the same as the first embodiment. The difference is that the mesh structure can be formed by using a screw structure, etc. The cover member 19 of the liquid port 17 is detachably mounted on the openings 13 and 14 on both sides of the cathode electrode 12. With this structure, the anode 15 pole 15 can be prevented from moving. FIG. 6 shows a third embodiment, in which The germicidal liquid generating device 21 in the example uses one of the covering members shown in the second embodiment as a filtering structure. That is, the end of one of the openings 24 of the cathode electrode 22 is detachably mounted with a screw structure or the like. The filter member 26 has a transitionally covering member 20 to 29, and becomes a device capable of adsorbing impurities in a liquid. In addition, the filter member can be a suitable member such as a hollow structure and activated carbon. The first to third embodiments described so far It is used by being immersed in various liquid storage tanks and containers for liquid storage, or placed in a flow path where liquid flows from one end of the cathode to the other. 200529916 In this use state, the cathode electrode 2 is sleeping + L is not electrically connected 2 and the electrode 5 is separated by two poles

具有使用於本實施例之循環流路之器體，係以日本公 開公報9-108658號所表示之小型簡易淨水器，本實施例中 之附設有殺菌液產生裝置之小型簡易淨水器3〇係，如第7圖 所不大致上亦由容量為1·5公升左右的容器部31及蓋部Μ =構成’亚在蓋部32上設置注人口 35、封蓋36、獅驅動 衣置37 拌翼％。㈣有礦物質含有材*峨過渡材“ 體形成電流電池，而產生1.5伏特左右之電動勢。 圓筒體39可自由裝卸地安裝於蓋部32，以遮蔽攪摔翼^ 又在圓茼體39下方安裝具有吸水口 43且為可撓性 才料之吸水官42。又，44係吸水口的吐出口，且形成為面 搜掉翼38之圓筒體39。另外，在容器部31與蓋部32間， 設置蓋鎖裝置33並可利用封環34成為密封狀態。 4 13 q 士么 土土 31内 "在由上述構造所形成之小型簡易淨水器3〇中，利用攪 # 動U37 ’使在容||部31内的液體巾為浸潰狀態的授The device having a circulation flow path used in this embodiment is a small simple water purifier shown in Japanese Laid-Open Publication No. 9-108658, and a small simple water purifier with a sterilizing liquid generating device in this embodiment 3 〇 Series, as shown in Figure 7, it is also roughly composed of a container portion 31 and a lid portion with a capacity of about 1.5 liters. M = constitutes a sub-population 35, a lid 36, and a lion-driven garment set on the lid 32 37% mixing wings. There is a mineral-containing material, such as a transition material, which forms a current battery and generates an electromotive force of about 1.5 volts. The cylindrical body 39 is detachably mounted on the cover portion 32 to cover the churning wings. A flexible water absorber 42 having a water inlet 43 is installed below. The 44 is a spout of the water inlet and is formed as a cylindrical body 39 for searching the wings 38. The container 31 and the lid A cover lock device 33 is installed between the sections 32 and can be sealed by the sealing ring 34. 4 13 q Shimatu soil 31 "In the small and simple water purifier 30 formed by the above structure, it is moved by stirring U37 'Giving the liquid towel in the capacity ||

42的吸水口 43，读 7 口 43，透過過濾材41及礦物質含有材40,使容器 P 1内的液體流入到攪拌翼38附近，藉此使容器内的液體 ^ ^于具'有過濾作用的掂if，而玎媒&丨純磨客之純淨 用的循環，而可得到純度高之純淨 12 200529916 水，更可利用礦物質含有材，得到相當於天然水及自然水 之礦泉水。 在此，在收容於圓筒體39之礦物質含有材40上方，依 據上已述及之本發明第1實施例及第2實施例來配置殺菌液 5產生裝置45，即可成為殺菌效果也很優異之殺菌液產生裝 置。又，本實施例係基於第1實施例而配置之殺菌液產生裝 置。 接著，對於有關第4實施例中之殺菌效果的實驗例加以 說明。 10 (實施例） 試驗水，係使用在蒸餾水5公升中，添加每1公升約 10,000個之預先以營養培養基培養而進入活潑繁殖期的大 腸桿菌（E.ColiK_12)。接著，將1，350公升之該試驗水加入小 型簡易淨水為30，並安裝由下述構造所形成之一殺菌液產 15生裝置45，進行3次每次為8分鐘的操作。 接著，在每次操作結束後，取出〇·1公升在小型簡易淨 水器30内的試驗水，並將該試驗水稀釋成1/1〇及1/1〇〇倍 後’將前述1公升稀釋水撒於生菌數確認用培養基，以37它 經2天培養後，計算所繁殖之菌落數，並除以稀釋率以求得 2〇在每1公升試驗水中所生存的菌數(cells/ml)。又，另外在實 驗丽及實驗後從試驗水採集水樣，並以與上述相同方法求 出生囷數（以下’以對照表示）。所得結果顯示於第1表。 (殺菌液產生裝置） 在由鎭製的言狀體（長度50mm、直徑18mm、厚度imm) 13 200529916 所形成之陰電極内部，嵌人單獨—合金卿成之陽 極用構成材料之陽極體，或者，在由胺基甲酸乙醋海綿所 形叙騎表面，安裝以電缝佈有前述構成材料之陽極 體，並藉此作成4種殺菌液產生裝置45以供實驗使用。 【第1表】 各試驗區中之生菌數測定結果 试驗區 1 冓造 " 1次操作後的 菌數（相對於 對照之％) 菌數（相對於 對照之❶/〇)、 乍後的 菌數（相對於 對照之°/〇) 1 甲酸乙酯〆 0(0) 〇(〇) 2 ^物） 400(8) 18ΓΟ) 3 Cu/Ag合金 (胺基甲酸乙酯） 〇(〇) 〇(〇) 0(0) 4 Cu/Ag合金（編物） 500(9) 430(8) 40(1) *數字單位係cells/ml(每lml之生存菌數） 由第1表結果可確说，不論使用任一種殺菌液產生裝置 10 45(試驗區1〜4)，都可在第1次的操作時殺死9〇%以上的菌， 且在3次操作結束後，殺死99%以上的菌。因此，以上述試 驗所使用之殺菌液產生裝置45，皆可具有優異之殺菌力。 如上述，依本發明之殺菌液產生裝置具有高殺菌力， 且，可使用於自來水、牛乳、果汁等各種飲料用液體。 15 又，本發明不限於上述之飲料用液體，亦可應用於被 污染或易污染之裝置及容器或循環液體流路中，例如，可 適用於包含24小時用之浴池、觀賞用·養殖用的水槽、游 泳池、其他各種貯液槽，並且，該型態及構造也不限於上 述實施例，可配合用途改變來實施。 2〇 [飲料用液體的殺菌用具] 14 200529916 第9圖係顯示有關於本發明攪拌器之第丨實施例。攪拌 器101係由絕緣性(例如，合成樹脂製）的細長棒體102形成， 並在棒體102表面圓周方向，從棒體1〇2一端設置沿著長手 方向之2個凹溝103、104到接近另1。接著，分別在凹溝 5 1〇3上安裝由賤金屬所形成之陰電極構件105，並在另一凹 溝上安裝由貴金屬所形成之陽電極ι〇6，使前述構件不 致於從凹溝103、104露出。 陰電極構件105的構成材料，可舉例如：鎮、辞、鈹、 銘合金等，又，賴示_L6伏特左右之電位，鋅、鍵、銘 10金等顯示一 1.0伏特左右之電位。 15 20 陽電極構件106的構成材料，可舉例如：石墨、鉑、鎳. (鉬合金C、鈦.錄·鉻.銅石夕合金B、錄鐵.絡合 金奶:合金20、不銹鋼、銅、銀等。其中，石墨及銘顯: + 0.2伏特左右之電位，其他金屬顯示^伏特左右之電位。 *本發明中兩電極材料，可在該等貴金屬及賤金屬中適 當地選擇，若採用在形成電流電池時可產生Q7伏特以上電 ▲:之'.且口 ’則並热特別限定兩電極的組合’但從為得到 車又问且安 < 之電動勢的觀點來看，以賤金屬為鎂、貴金屬 為銅或銅合金之組合為佳。在此點上對於後述附設 拌器之杯子及杯子亦相同。 又’陰電極構件1〇5與陽電極構件1〇6的型態，除了在 形成電流電池時可產彻伏特以上電動勢之外，並無特別 限！L但k使存在於飲料用液體中m量地靠近而提 升救囷效率的觀點來看，陽電極構件1⑽的型態，係以採用 15 200529916 ===::積之型態為佳，保如此大的表 形成之棒狀體表極構件106的構成材料所 • 進仃精袷加工而形成多數精密凹凸狀 5 10 將具有胺基甲酸乙自旨等連續氣泡之多孔構造體作 I彻電鍍等方法將陽電極構件106塗佈於其表面 之型態等。在此點卜^ 衣面 < ，對於使用於後述附設有攪拌器之杯 子及杯子之陽f極構件亦相同。 口、制該_器1〇1，並以手搜拌注入杯中的水、茶、咖 ^紅♦、果汁等，則存在於飲料中之㈣會靠並近接觸 陽電極顯件106，接著，因接觸〇·7伏特以上的電壓而死 :二此，可利用以攪拌器1〇1攪拌之簡易方法，均一地進 仃全部業已注入杯内之飲料用液體之殺菌。又，由於陰電 極構件1G5與陽電極構件1()6係分別安裝成不致於從凹溝 103 ι〇4路出，因而攪拌器i〇i本體也成為緊緻的型態，故 在5又计上也是優異的。 第！〇圖係顯示有關本發明之第2實施型態。攪拌器1〇1 之特徵在於：在棒體102之一端形成平板狀攪拌部1〇7，並 在該攪拌部107表裡兩面，分別設置有間隔地安裝由賤金屬 所形成之陰電極構件1 〇5與由貴金屬所形成之陽電極構件 106之凹溝 103、1〇4。 若使用由上述構造所形成之攪拌器101，由於可有效地 進行如上述包含於飲料用液體菌體之殺菌，並藉由面積大 於其他部分之攪拌部7而增加攪拌作用，因而可在短時間進 行飲料用液體之殺菌，並具有在添加有砂糖等粉末時，亦 20 200529916 可以短時間溶解之優點。 攪拌拌為101可在達成上述效果的範圍内，適當地改變 攪拌部及凹溝形狀，以及陰電極構件與陽電極構件的安裝 位置等，例如，如第11圖所示，亦可在形成於棒體102前端 5之平板狀攪拌部107上安裝有前述電極構件的情況下，在其 中一面上安裝前述電極構件，並在另一面上安裝與安裝於 前述面的電極構件成對之電極構件。此外，為了在攪拌時 可以手緊緊地拿著擾拌器，亦可在前述棒體另一端設置把 手部。 10 (實驗例） 添加在1ml蒸餾水中約含有1〇 〇〇〇個之預先以營養培 養基培養而進入活潑繁殖期的大腸桿菌（EC〇liK_i2)，並調 製容量3〇〇ml作為試驗水。接著，將前述試驗水舰注入容 量5_之離心機用管本體中，並放入艰下述祕器後以 15 蓋子關閉前述管本體的開口部。 接著’將收容有前述攪拌器的管子之振盈培養基固定 至水平，以1分鐘80次的速度開始來回振盡，且在卜3、5、 15、60及180分鐘後，採集規定量之試驗水。 湘蒸财’將前述所採集之試驗水_成1/10倍及 倍，再將該hn·於已進入寒冷5 亚以撒佈機擴大倾後’以37t培養以。培養結束後，計 算所繁殖之g落數並除以稀釋率，財得在每㈤試驗水。中 所生存的菌數(CeUs/ml)，又，另外以不裝入授掉器且鱼 上述相同條件振動僅收容水之離心機用管，作為對照。所 17 200529916 得結果顯示於第2表。 (攪拌器） 分別使用以鎂為陰電極構件、銅為陽電極構件來製作 第10圖所示之《崎拌^，並分職用簡為陰電極構 件、銅和銀的合金為陽電極構件來製作第1〇圖所示之型離 的攪拌器，以供試驗。 & 【第2表】 各試驗區中生菌數經時間的變化 試驗區 1 攪拌器構造 銅 + 鎂 ϊίϊι銀的合金 + 鎂 採樣時間（分、 1 ~ 3 5 15 60 180 1---— 3 5 15 60 180 菌數(％)(相的 600(22) ~ 373(14) 220(6) 62(2) 0(0) 祖—__ 2480(91) - 2480(89) 2890(87) 656(24) 0(0) 〇(〇) 對照 無攪拌器 0 2730(100) " - 60 2190(80) 80 2200(80) 10 *數字單位為cells/ml(每lml的生存菌數） 由第2表結果可確認，不論使用任一攪拌器（試驗區1、 2) ’菌數都會因時間的經過而減少，且經過6〇分鐘後殺死 全部細菌。因此，上述試驗所使用的攪拌器，皆具有優異 之殺菌力。 15 接著’參照圖示，對本發明附設搜拌器之杯子加以說 明。第12圖係本發明附設攪拌器之杯子的說明圖，且該附 S又搜拌器之杯子11丨包含··杯子丨丨2，係以由貴金屬（第丨2圖 18 200529916 ，中^鋼)所形成之陽電極構件構成全體；及攪拌器113，係 沿著性細長棒體102的長手方向安裝由賤金屬（第圖中的 鎂）所形成之陰電極構件1〇5。 山 <杯千111，符田μ亍捱任攪拌器ii3上 10 15 20 而來授拌業已倒人杯子112之飲料用液體，即可使存在於飲 料用液體中之細菌大量地靠近作為陽電極之杯子112的内 ^面Ϊ體’並可在該狀態下，因接觸G.7伏特以上之電壓而 提升殺菌效率。即’由於可確保在杯子112的内周面具有廣 大之電極表面積，故可提高飲料用液體的殺菌效率。 此外，本發明附設搜拌器之杯子111中，包含以陽電極 構:構成杯子112及以陰電極構件構成㈣器113，但也可 將月J述兩電極構件構造反過來，構成附設授摔器之杯子。 接著，對本發明之杯子加以說明。第13圖係本發明杯 子的說明圖，該杯子114係將由賤金屬所形成之板狀陰電極 構件1〇5(第13财使⑽)與由貴金屬所形成之板狀陽電極 構件1〇6(第13财使用銅），以分龍開的狀態，架設安裝 在由合成樹脂所形成之杯子本體115的側壁㈣面所形成 者。利用該杯子114,可藉由使用—般祕器來授拌飲料用Suction port 43 at 42 and 7 port 43 are read through filter material 41 and mineral-containing material 40 to allow the liquid in the container P 1 to flow into the vicinity of the stirring blade 38, thereby making the liquid in the container ^ ^ The effect of ， if, and the circulation of pure media & 丨 pure miller can be used to obtain high purity and pure water 12 200529916 Water can also use mineral materials to obtain mineral water equivalent to natural water and natural water . Here, the sterilizing liquid 5 generating device 45 is arranged above the mineral-containing material 40 stored in the cylindrical body 39 according to the first and second embodiments of the present invention described above. Very good sterilizing liquid generating device. In addition, this embodiment is a sterilizing liquid generating device arranged based on the first embodiment. Next, an experimental example of the sterilizing effect in the fourth embodiment will be described. 10 (Example) The test water was used in 5 liters of distilled water, and about 10,000 per liter of E. coli (E. ColiK_12), which had been cultured in a nutrient medium in advance and entered a lively breeding period, was added. Next, 1,350 liters of this test water was added to a small simple purified water to 30, and a sterilizing liquid producing device 45 formed by the following structure was installed, and the operation was performed 3 times for 8 minutes each time. Next, at the end of each operation, take out 0.1 litre of test water in the small simple water purifier 30, and dilute the test water to 1/1/10 and 1/100 times. Diluted water was sprinkled on the medium for confirming the number of bacteria. After 37 days of cultivation, the number of colonies that were propagated was calculated and divided by the dilution rate to obtain 20 cells per 1 liter of test water / ml). In addition, a water sample was collected from the test water after the experiment and after the experiment, and the number of births was calculated in the same manner as described above (hereinafter, '' is shown as a comparison). The results obtained are shown in Table 1. (Bactericidal fluid generating device) The anode electrode formed by the fabricated word body (length 50mm, diameter 18mm, thickness imm) 13 200529916 is embedded alone—the anode body made of alloy anode material, or, On the riding surface shaped by ethyl urethane sponge, an anode body with electric stitching cloth and the aforementioned constituent materials was installed, and four kinds of sterilizing liquid generating devices 45 were made for experimental use. [Table 1] Results of the measurement of the number of germs in each test area Test area 1 & & The number of bacteria after one operation (% relative to the control) The number of bacteria (relative to the control ❶ / 〇), After the number of bacteria (° / 〇 relative to the control) 1 ethyl formate 〆0 (0) 〇 (〇) 2 ^) 400 (8) 18Γ〇) 3 Cu / Ag alloy (urethane) 〇 ( 〇) 〇 (〇) 0 (0) 4 Cu / Ag alloy (edition) 500 (9) 430 (8) 40 (1) * The unit of number is cells / ml (the number of living bacteria per 1 ml). It can be said that no matter what kind of germicidal liquid generating device 10 45 (test areas 1 to 4) is used, more than 90% of bacteria can be killed in the first operation, and after 3 operations, the kill More than 99% of bacteria. Therefore, the sterilizing liquid generating device 45 used in the above test can have excellent sterilizing power. As described above, the sterilizing liquid generating device according to the present invention has high sterilizing power, and can be used for various beverage liquids such as tap water, milk, and fruit juice. 15 Furthermore, the present invention is not limited to the above-mentioned beverage liquids, but can also be applied to contaminated or easily contaminated devices and containers or circulating liquid flow paths. For example, the present invention can be applied to baths for 24 hours, for viewing and breeding Water tanks, swimming pools, and other various liquid storage tanks, and the type and structure are not limited to the above-mentioned embodiments, and can be implemented in accordance with changes in use. 20 [Bactericidal Apparatus for Beverage Liquid] 14 200529916 Fig. 9 shows a first embodiment of the blender of the present invention. The stirrer 101 is formed by an insulating (e.g., synthetic resin) elongated rod body 102, and two grooves 103, 104 along the long-hand direction are provided from one end of the rod body 102 in the circumferential direction of the surface of the rod body 102. To approach another 1. Next, a female electrode member 105 formed of a base metal is installed on the groove 5 103, and a positive electrode ι〇6 formed of a precious metal is installed on the other groove, so that the aforementioned members are not prevented from the groove 103 , 104 is exposed. The material of the cathode electrode member 105 may be, for example, a town, a word, a beryllium, an alloy, or the like, and a potential of about 6 volts is indicated, and a potential of about 1.0 volts is shown for zinc, a bond, or 10 gold. 15 20 The material of the anode electrode member 106 may be, for example, graphite, platinum, or nickel. (Molybdenum Alloy C, Titanium, Chromium, Chromium, Cerberite B, Iron, and Alloy Milk: Alloy 20, Stainless Steel, Copper , Silver, etc. Among them, graphite and inscription show: + 0.2 volt potential, other metals show ^ volt potential. * The two electrode materials in the present invention can be appropriately selected among these precious metals and base metals, if used In the formation of a current battery, Q7 volts or more can be generated ▲: of the '. And the mouth' is a combination of two electrodes is particularly limited ', but from the viewpoint of getting the car's electromotive force, from the perspective of base metals It is preferably a combination of magnesium and a noble metal of copper or a copper alloy. At this point, the same applies to a cup and a cup with a stirrer described later. The shape of the cathode electrode member 105 and the anode electrode member 106 is the same as There is no particular limitation on the generation of electromotive voltages above volts when forming a current battery! L but k brings the amount of m present in the liquid for beverages closer to each other to improve the rescue efficiency. The shape of the positive electrode member 1⑽ Based on the use of 15 200529916 === ::: product type It is better to keep the material of the rod-shaped body pole member 106 formed by such a large table. • It will be processed to form most precise irregularities. 5 10 A porous structure with continuous bubbles such as ethyl urethane. The method of coating the positive electrode member 106 on the surface by a method such as electroplating. At this point, the surface of the coat is the same as the positive electrode member used in a cup and a cup with a stirrer described later. Mouth, make the device 101, and manually search and pour water, tea, coffee, red juice, juice, etc. into the cup, and the pimple existing in the beverage will come in close contact with the positive electrode display 106, Then, he died because of contact with a voltage of more than 0.7 volts. Second, the simple method of stirring with a stirrer 101 can be used to uniformly sterilize all the beverage liquids that have been poured into the cup. The electrode member 1G5 and the anode electrode member 1 () 6 are installed so that they do not exit from the groove 103 ι04. Therefore, the body of the stirrer i〇i also becomes compact, so it is also excellent in 5 counts. No.! The figure shows the second embodiment of the present invention. Stirring The device 101 is characterized in that a flat plate-shaped agitating portion 107 is formed at one end of the rod body 102, and the cathode electrode member 1 made of a base metal is provided on both surfaces of the agitating portion 107 on the front and back surfaces at intervals. 5 and the grooves 103 and 104 of the anode electrode member 106 formed of the precious metal. If the agitator 101 formed by the above structure is used, the sterilization of the liquid bacteria contained in the beverage as described above can be effectively performed, and With the stirring part 7 larger in area than the other parts, the stirring effect is increased, so that the beverage liquid can be sterilized in a short time, and when powder such as sugar is added, it has the advantage of being dissolvable in a short time. 20 200529916 101 can appropriately change the shape of the stirring portion and the groove, and the positions of the cathode electrode member and the anode electrode member within the range that achieves the above effects. For example, as shown in FIG. 11, it can also be formed on the rod body 102. When the aforementioned electrode member is mounted on the flat plate-shaped stirring portion 107 of the front end 5, the aforementioned electrode member is mounted on one surface, and the electric device mounted on the other surface is mounted on the other surface. Member of the pair of electrode members. In addition, in order to hold the stirrer tightly while mixing, a handle can also be provided at the other end of the rod. 10 (Experimental example) E. coli (ECOliK_i2) containing about 10,000 preliminarily cultured with nutrient medium in 1 ml of distilled water was added, and a capacity of 300 ml was adjusted as test water. Next, the test water vessel was poured into a tube body for a centrifuge with a capacity of 5 mm, and the device was placed in a trap container, and the opening of the tube body was closed with a 15 cap. Then 'fix the vibration medium of the tube containing the aforementioned stirrer to a level, start to vibrate back and forth at a rate of 80 times per minute, and collect the specified amount of test after 3, 5, 15, 60 and 180 minutes water. "Xiang Zhengcai" made the collected test water into 1/10 times and 1 times, and then cultured the hn · in the cold 5 sub-Israel spreader and extended it to 37t. After the end of the cultivation, calculate the number of g drops that were propagated and divide by the dilution rate. The number of bacteria (CeUs / ml) surviving in the experiment was controlled by using a centrifuge tube containing only water without shaking the fish in the same condition as described above. The results of 17 200529916 are shown in Table 2. (Stirrer) Using "magnesium as the cathode electrode member and copper as the anode electrode member" to make the "Sakizaki ^" shown in Figure 10, and separate the anode electrode member and copper and silver alloys as anode electrode members Let's make a stirrer of the type shown in Figure 10 for testing. & [Table 2] Change of bacterial counts in each test area over time Test area 1 Stirrer structure Copper + Magnesium ϊ Silver alloy + Magnesium sampling time (minutes, 1 ~ 3 5 15 60 180 1 ---- 3 5 15 60 180 Number of bacteria (%) (phase of 600 (22) ~ 373 (14) 220 (6) 62 (2) 0 (0) Ancestor — __ 2480 (91)-2480 (89) 2890 (87) 656 (24) 0 (0) 〇 (〇) Control without agitator 0 2730 (100) "-60 2190 (80) 80 2200 (80) 10 * The unit of number is cells / ml (the number of living bacteria per lml) From the results in Table 2, it can be confirmed that the number of bacteria will decrease with the passage of time regardless of the use of any of the agitators (test zones 1, 2), and all bacteria will be killed after 60 minutes. Therefore, the test used in the above test The blender has excellent sterilizing power. 15 Next, the cup with a blender according to the present invention will be described with reference to the drawings. FIG. 12 is an explanatory diagram of the cup with the blender according to the present invention, and the attached S is searched and mixed. The cup 11 丨 contains ·· the cup 丨 丨 2, which is composed of a positive electrode member formed of a precious metal (No. 18, 200529916, and ^ steel); and the agitator 113, which is along the A female electrode member 105 made of a base metal (magnesium in the figure) is mounted in the long-hand direction of the slender rod body 102. Mountain < Cup Qian 111, Fu Tian μ 亍 were placed on the stirrer ii3 10 15 20 Mixing the beverage liquid that has been poured into the cup 112 can make a large number of bacteria present in the beverage liquid close to the inner surface of the cup 112 as a positive electrode ', and in this state, due to contact with G. The sterilization efficiency is improved by a voltage of 7 volts or more. That is, because a large electrode surface area can be ensured on the inner peripheral surface of the cup 112, the sterilization efficiency of the beverage liquid can be improved. In addition, in the cup 111 with a searcher of the present invention, It includes a positive electrode structure: a cup 112 and a negative electrode component to constitute the urn 113. However, the structure of the two electrode components described above can also be reversed to form a cup with a drop device. Next, the cup of the present invention will be described. Fig. 13 is an explanatory view of the cup of the present invention. The cup 114 is a plate-shaped negative electrode member 105 (thirteenth treasurer) formed of a base metal and a plate-shaped positive electrode member 1 formed of a precious metal. 6 (Thirteenth asset uses copper) Long points to the ON state, the erection and installation (iv) formed in the sidewall surface of the cup body 115 formed of a synthetic resin by the use of the cup 114, may be used by - as secret device to grant a beverage mix

液體’可輕易地進行倒入杯子114的飲料用液體之殺菌，並 降低杯子114的製造成本。 WLiquid 'can easily sterilize the beverage liquid poured into the cup 114, and reduce the manufacturing cost of the cup 114. W

[皮膚滾輪] 接著，參照圖示，對本發明之皮膚滾輪加以說明。第 14圖係顯林發明之第丨實施型態，該皮歧輪121大致上 包含·握柄122 ’係由絕緣體所形成；圓筒狀滾輪⑵，係 19 200529916 固持在該握柄前端且可自由旋轉並且由鎮所形成；板狀金 屬片124，係安裝於前述握柄122且由鎂之貴金屬所形成； 水刀供給構件125 ’係安裝於該金屬片124_端且配置成在 紅轉别述滚輪Π3時，可與該滾輪123摩擦接觸；及金屬細 5線126 ’係一端連接前述板狀金屬片124並且另一端大約安 衣於錢握柄122的中央部，且由與前述板狀金屬片124相 同材料所形成者。 10 15 20 握柄122係可以手握住皮膚滾輪121的構件，且由電氣 巴彖(1间的σ成；^脂(例如，丙烯酸樹脂)形成，因而當將滾 輪幸二幸二地推至身體的皮膚表面時，可輕易地以前後方向 疋轉/袞輪X 上方（第14⑷圖）來看，其構造為從基端 部逐漸地射央部變細，並狀正面（第14_)來看，其 構匕為k基端補中央部呈向上彎曲。另外，在握柄⑵其 中一基端部上’形成有切_基端部所形成之滾輪保持部 ma ’亚在構成料輪料部m之周壁面上，面對面地 -svu δ又置[Skin Roller] Next, the skin roller of the present invention will be described with reference to the drawings. Fig. 14 is the first embodiment of Xianlin's invention. The leather manifold 121 generally includes a grip 122 'formed by an insulator; a cylindrical roller ⑵, 19 200529916 is fixed at the front end of the handle and can be Freely rotating and formed by the town; a plate-shaped metal sheet 124, which is mounted on the aforementioned handle 122 and is formed of a precious metal of magnesium; a water jet supply member 125 'is mounted on the metal sheet 124_ end and is configured to rotate in red When the roller Π3 is mentioned, it can be in frictional contact with the roller 123; and a thin metal wire 126 'is connected at one end to the aforementioned plate-shaped metal sheet 124 and the other end is mounted on the central portion of the money grip 122, and is connected with the aforementioned plate The metal sheet 124 is formed of the same material. 10 15 20 The grip 122 is a component that can hold the skin roller 121 by hand, and is formed by an electric bar (σ composition of 1; grease (for example, acrylic resin), so when the roller is fortunately pushed to the body ’s When looking at the surface of the skin, you can easily turn forward / backward / above the wheel X (Figure 14), and its structure is gradually tapered from the base end to the central part, and shaped like a front view (14_). Its structure is that the central part of the base end of k is bent upward. In addition, one of the base end parts of the grip 'is formed with a roller holding part ma formed by a cut_base end part in the material part m of the material wheel. Perimeter wall, face to face -svu δ again

謂興_122的長手方向垂直之承轴凸部 122b。 滚輪I23係作為陰電極構件，以將鎂離子供給至皮 冓牛且由鎂製成’並構成由本體部稍微向外膨 之周側面與左右_狀之端面所形成的圓筒狀，而在該 面中心分卿成未®^之凹部。又，滾輪部123係收容於 述握柄I22的雜料部咖，並且形成於錢滾輪⑵ 右端面之凹部丧人面向前述滾輪心所設置之承軸凸 122b，以保持自由旋轉的狀態。 板Γ金屬>| 124係與作為前述陰電極構件的滾輪⑵ 20 200529916 對之陽電極構件，且在前述握柄122中靠近滾輪 置，以螺絲固定。板狀金屬片124的構成材料，若在/的位 流電池時可產生0.7伏特以上電動勢，則無特別限定形^ 例如：；5墨、#、鎳.鉻.銦合金c、敘 可舉 邱絡·鋼·石夕 5合金B、錦.鐵.鉻合金825、合金2〇、不鱗鋼、銅、銀等， 其中，從可獲得較高且安定之電動勢的_來看最好曰 使用石墨、銅或銅合金。 疋 水分供給射MM，料了分職給水分至前述滾輪 123與板狀金屬片124的構件，且係以例如，可保持吸收海 10綿及毛觀等的水分之材質製成略呈板狀之矩形。此外，水 分供給構件125，係-端安裝於前述板金屬片124，並且配 置為當前述滾輪123旋轉時’可與該滚輪123的周側面摩捧 接觸。 不 金屬細線126，係為了在以手握住前述握柄122時，確 15定板狀金屬片124與身體（即，皮膚）具有電氣連接而設置之 構件，又，係由與前述板狀金屬片124大致相同之材料形 成，並且一端連接於前述金屬片，而另一端安裝於前述握 柄122中以手所握住之中央部。 在使用由上述構造所形成之皮膚滾輪121時，使水分供 20給構件125中保持吸收有數滴水或水溶液後 ，再以手握住金 屬細線126的一端與握柄122的中央部，將滾輪123輕輕地推 至身體的皮膚表面，並朝前後方向轉動多次。如此一來， 水分供給構件125會與滾輪123周側面摩擦接觸，含有於水 分供給構件125中的水分會轉移至滾輪123，接著，將業已 21 200529916 移至該滾輪123水分會會供給至皮膚表面，並在皮膚滾輪 121形成電流電池，再將產生於滾輪123之鎂離子供給至皮 膚表面。因此，利用皮膚滾輪121，藉由以手握住握柄122 並在皮膚上轉滾輪123之簡易操作，可有效率地供給鎂離子 5至皮膚表面，故可有效地促進回復皮膚阻抗機能。又，本 發明之皮膚滾輪121所適用部位，並無特別限定，例如可 舉：額頭、臉頰、耳後、鼻側、腋下等。 本發明之皮膚滾輪121在可發揮上述作用效果的範圍 内，可適當地改變滾輪123的數量、安裳部位及滾輪123的 10 旋轉方向等，亦可例如，在握柄122兩端安裝滾輪123，或 者’亦可在以握柄122的長手方向作為基準線時，使滾輪123 的旋轉方向面向前述基準線，且以握柄122為中心，左右對 稱地女12個比弟14圖所不之滾輪123运小的滚輪123(灸戶夸 第15圖）。若如此構成之皮膚滾輪123，則可藉由適當地分 15開使用前述2個滾輪123之其中一個滾輪123，可不損及相對 於凹凸起伏大的皮膚表面之滾輪丨23的密接性，且有效率地 供給鎂離子至皮膚表面。 又，第14圖及第15圖所示之皮膚滾輪121中，當滾輪123 難以圓滑地旋轉時，亦可將滾輪123(參照第16圖）安裝成旋 20 轉方向與握柄122的長手方向垂直。 又，在上述滾輪121中，若相互地替換滾輪123與片狀 金屬片所使用之構成材料，則由於以陽電極構件構成滾輪 123，因而可成為對存在於皮膚表面之菌體（例如，含於汗 中的細菌等）具有優異殺菌力之皮膚滾輪。 22 200529916 發明效果 本發明係藉由相對配置在異種金屬接觸腐蝕時之賤金 屬所形成之陰電極與由在異種金屬接觸腐蝕時之貴金屬所 形成之陽電極，並使其浸潰於前述液體中而形成電流電 5 池，並且利用在其間自然地產生之電動勢，因而成為不需 特別的電源且簡單之構造，並且因陽電極為開放室構造， 故具有可得到高殺菌效率之優點。 I：圖式簡單說明3The long shaft direction of Xing_122 is perpendicular to the bearing shaft convex portion 122b. The roller I23 is used as a negative electrode member to supply magnesium ions to the skin yak and is made of magnesium, and formed into a cylindrical shape formed by a peripheral side surface that is slightly bulged outward and a left-right end surface. The center of the face is divided into a recessed part. In addition, the roller portion 123 is a miscellaneous portion coffee housed in the handle I22, and a concave portion formed on the right end face of the money roller 面向 faces a bearing boss 122b provided in the roller core to maintain a freely rotating state. The plate Γmetal > | 124 is a roller electrode 前述 20 200529916 which is the aforementioned negative electrode member, and is opposite to the positive electrode member, and is located close to the roller in the aforementioned handle 122 and fixed with screws. The constituent material of the plate-shaped metal sheet 124 is not particularly limited if it can generate an electromotive force of 0.7 volts or higher in a bit-flow battery. For example: 5 ink, #, nickel, chromium, indium alloy, c, Xu Keju Steel · Shi · Shixi 5 Alloy B, Jin. Iron. Chromium Alloy 825, Alloy 20, non-scale steel, copper, silver, etc. Among them, it is best to use it from the viewpoint of obtaining a high and stable electromotive force. Graphite, copper or copper alloy.疋 Moisture supply shot MM, it is expected to separate the components to feed the water to the aforementioned roller 123 and plate-shaped metal sheet 124, and it is made of a material that is slightly plate-shaped, for example, that can maintain the absorption of moisture such as sea water and wool. Of the rectangle. In addition, the moisture supply member 125 is attached to the aforementioned sheet metal sheet 124 at the system end, and is configured to be in contact with the peripheral surface of the roller 123 when the roller 123 rotates. The non-metal thin wire 126 is a member provided to ensure that the plate-shaped metal sheet 124 has an electrical connection with the body (ie, the skin) when the handle 122 is held by a hand, and is connected with the plate-shaped metal. The sheet 124 is formed of substantially the same material, and one end is connected to the aforementioned metal sheet, and the other end is mounted in the central portion of the aforementioned handle 122 to be held by a hand. When using the skin roller 121 formed by the above structure, a few drops of water or an aqueous solution are absorbed in the water supply member 125, and then one end of the thin metal wire 126 and the center of the grip 122 are held by the hand, and the roller 123 Gently push to the skin surface of the body and turn it back and forth multiple times. In this way, the moisture supply member 125 will come into frictional contact with the side surface of the roller 123, and the moisture contained in the moisture supply member 125 will be transferred to the roller 123. Then, the 2005 21916 will be moved to the roller 123. The moisture will be supplied to the skin surface A current battery is formed on the skin roller 121, and magnesium ions generated from the roller 123 are supplied to the skin surface. Therefore, with the skin roller 121, the simple operation of holding the handle 122 with the hand and turning the roller 123 on the skin can efficiently supply magnesium ions 5 to the skin surface, and thus can effectively promote the restoration of the skin impedance function. The area to which the skin roller 121 of the present invention is applied is not particularly limited, and examples thereof include the forehead, the cheek, the back of the ear, the side of the nose, and the underarm. The skin roller 121 of the present invention can appropriately change the number of the rollers 123, the position of the anchor, and the direction of rotation of the roller 123 within the range where the above-mentioned effects can be exerted. For example, the rollers 123 may be installed at both ends of the grip 122, Or 'When using the long hand direction of the grip 122 as the reference line, make the rotation direction of the roller 123 face the aforementioned reference line, and use the grip 122 as the center to symmetrically roll the female 12 rollers that are not shown in the figure 14 123 transport small roller 123 (moxibustion households boast Figure 15). If the skin roller 123 is configured in this way, one of the two rollers 123 can be used appropriately at 15 minutes, so as not to impair the adhesion of the roller to the skin surface with large unevenness. 23 Efficiently supply magnesium ions to the skin surface. In the skin roller 121 shown in FIGS. 14 and 15, when the roller 123 is difficult to rotate smoothly, the roller 123 (refer to FIG. 16) may be installed in a direction of 20 rotations and a long hand direction of the grip 122. vertical. In addition, in the above-mentioned roller 121, if the constituent materials used by the roller 123 and the sheet metal sheet are replaced with each other, the roller 123 is constituted by a positive electrode member, so that it can be used for bacteria (for example, Bacteria in sweat, etc.) skin roller with excellent bactericidal power. 22 200529916 Effect of the invention The present invention is to immerse a cathode electrode formed from a base metal that is placed in contact with dissimilar metals in contact corrosion and an anode electrode formed of a precious metal that is in contact to dissimilar metals to corrosion and immersed in the aforementioned liquid. The formation of a current cell and the use of the electromotive force naturally generated therebetween makes it a simple structure that does not require a special power source, and because the anode electrode has an open-cell structure, it has the advantage of high sterilization efficiency. I: Schematic description 3

第1圖係顯示本發明第1實施例之立體圖。 10 第2圖係顯示本發明在第1實施例中之陽電極的照片。 第3圖係顯示本發明在第1實施例中之A-A擴大截面 圖。 第4圖係顯示本發明為了將在第1實施例中之陰電極與 陽電極作為非接觸狀態的變化例。 15 第5圖係顯示本發明第2實施例之截面圖。Fig. 1 is a perspective view showing a first embodiment of the present invention. 10 FIG. 2 is a photograph showing the anode electrode of the first embodiment of the present invention. Fig. 3 is an enlarged A-A sectional view of the first embodiment of the present invention. Fig. 4 is a diagram showing a modification of the present invention in which the negative electrode and the positive electrode in the first embodiment are set in a non-contact state. 15 FIG. 5 is a sectional view showing a second embodiment of the present invention.

第6圖係顯示本發明第3實施例之截面圖。 第7圖係顯示本發明第4實施例之截面圖。 第8圖係顯示使用習知低電壓殺菌法之淨水器的截面 圖。 20 第9圖係顯示本發明攪拌器的第1實施型態之說明圖， 其中，（a)為俯視說明圖，（b)為正視說明圖，（c)為B-B截面 說明圖。 第10圖係顯示本發明攪拌器的第2實施型態之說明 圖，其中，（a)為俯視說明圖，（b)為正視說明圖。 23 200529916 第11圖係顯示本發明攪拌器的第3實施型態之說明 圖，其中，（a)為俯視說明圖，（b)為正視說明圖。 第12圖係顯示本發明附設有攪拌器之杯子的實施型態 之正視說明圖。 5 第13圖係顯示本發明杯子的實施型態之正視說明圖。Fig. 6 is a sectional view showing a third embodiment of the present invention. Fig. 7 is a sectional view showing a fourth embodiment of the present invention. Fig. 8 is a sectional view showing a water purifier using a conventional low-voltage sterilization method. 20 FIG. 9 is an explanatory diagram showing a first embodiment of the agitator according to the present invention, in which (a) is a plan explanatory diagram, (b) is a front explanatory diagram, and (c) is a B-B sectional explanatory diagram. Fig. 10 is an explanatory diagram showing a second embodiment of the agitator according to the present invention, in which (a) is a plan explanatory diagram and (b) is a front explanatory diagram. 23 200529916 Fig. 11 is an explanatory diagram showing a third embodiment of the agitator according to the present invention, in which (a) is a plan explanatory diagram and (b) is a front explanatory diagram. Fig. 12 is an explanatory front view showing an embodiment of a cup with a stirrer according to the present invention. 5 FIG. 13 is an explanatory front view showing an embodiment of a cup according to the present invention.

第14圖係顯示本發明皮膚滾輪的第1實施型態之說明 圖，其中，（a)為俯視說明圖，（b)為正視說明圖，（c)為仰視 說明圖。 第15圖係顯示本發明皮膚滾輪的第3實施型態之說明 10 圖，其中，（a)為俯視說明圖，（b)為正視說明圖，（c)仰視說 明圖。Fig. 14 is an explanatory view showing a first embodiment of the skin roller of the present invention, in which (a) is a plan explanatory diagram, (b) is a front explanatory diagram, and (c) is a bottom explanatory diagram. Fig. 15 is an explanatory view 10 showing a third embodiment of the skin roller of the present invention, in which (a) is an explanatory plan view, (b) is an explanatory view of a front view, and (c) is an explanatory view of a bottom view.

【圖式之主要元件代表符號表】 卜11、2卜45…殺菌液產生裝置 31...容器部 2、12、22...陰電極 32···蓋部 3、4、13、14、24··.開口部 33…蓋鎖裝置 5、15...陽電極 34...封環 6...隔板 35···注入口 7...間隙部 36...封蓋 8...網狀絕緣薄板 37…攪拌驅動裝置 19".覆蓋構件 38.··攪拌翼 26…過濾構件 39...圓筒體 29…附設過濾之覆蓋構件 40...礦物質含有材 30...附設有殺菌液產生裝置之小 41···過濾材 型簡易淨水器 42···吸水管 24 200529916[Representative symbols for the main elements of the figure] [11, 2] [45] ... sterilizing liquid generating device 31 ... container part 2, 12, 22 ... female electrode 32 ... lid part 3, 4, 13, 14 24 ... Opening 33 ... Cover lock device 5, 15 ... Positive electrode 34 ... Sealing ring 6 ... Separator 35 ... Injection port 7 ... Gap 36 ... Cover 8 ... Mesh insulation sheet 37 ... Stirring drive 19 " Covering member 38 ... Stirring wing 26 ... Filtering member 39 ... Cylinder 29 ... Covering member with filter 40 ... Mineral-containing material 30 ... Small 41 with bactericidal fluid generating device ... Filter type simple water purifier 42 ... Suction pipe 24 200529916

43.·.吸水口 115...杯子本體 44...吐出口 121...皮膚滾輪 KH、113.··攪拌器 122. · ·握柄 102…棒體 H2a...滾輪保持部 103、104···凹溝 122b...承軸凸部 105...陰電極構件 122c...螺絲 17...通液口 123 ·. ·滾 106...陽電極構件 124…板狀金屬片 107···攪拌部 125...水分供給構件 111...附設攪拌器之杯子 126.. •金J%細線 112、114…杯子43 .. Water inlet 115 ... Cup body 44 ... Ejection port 121 ... Skin rollers KH, 113 ... Blender 122. Grip 102 ... H2a ... Roller holding section 103 , 104 ··· recess 122b ... bearing convex portion 105 ... female electrode member 122c ... screw 17 ... liquid opening 123 ... roller 106 ... positive electrode member 124 ... plate shape Metal piece 107 ... Stirring section 125 ... Moisture supply member 111 ... Cup 126 with stirrer .. • Gold J% thin line 112, 114 ... Cup

2525

Claims (1)

200529916 拾、申請專利範圍： 1. 一種殺菌液產生裝置，包含：筒狀陰電極，係開放由在 異種金屬接觸腐蝕時之賤金屬所形成之兩端者；及陽電 極，具有於前述陰電極内側以非接觸狀態配置之開放室 5 構造且係由在異種金屬接觸腐蝕時之貴金屬所形成 者，又，可藉由將液體置於前述陰電極與陽電極之間而 產生0.7伏特以上之電動勢。 2. 如申請專利範圍第1項之殺菌液產生裝置，其中前述陰 電極為鎮。 10 3.如申請專利範圍第2項之殺菌液產生裝置，其中前述陽 電極為銅或酮合金。 4. 如申請專利範圍第3項之殺菌液產生裝置，係於前述陰 極部下方設置過濾設備。 5. 如申請專利範圍第4項之殺菌液產生裝置，係安裝成可 15 使液體流通於液體循環裝置者。 6. —種附設有殺菌液產生裝置之小型簡易淨水器，係具有 在貯液容器内收容有過濾部之液體強制循環管路，且申 請專利範圍第5項之殺菌液產生裝置收容於該液體強 制循環管路内者。 20 7. —種攪拌器，係由絕緣性細長棒體所形成者，又，於前 述棒體分別設有間隔地安裝有由賤金屬所形成之陰電 極構件與由貴金屬所形成之陽電極構件。 8. —種攪拌器係在申請專利範圍第7項中，於棒體表面圓 周方向設置複數具有間隔且沿著該棒體長手方向之凹 26 200529916 溝，並於前述凹溝分別安裝有由賤金屬所形成之陰電極 構件與由貴金屬所形成之陽電極構件。 9. 一種攪拌器，係由絕緣體所形成之細長棒體與由形成於 該棒體一端之平板狀攪拌部所形成者，又，在前述攪拌 5 部設置複數間隔之凹溝，並於前述凹溝分別安裝由賤金 屬所形成之陰電極構件與由貴金屬所形成之陽電極構 件。 10. —種附設有攪拌器之杯子，係具有以選自於由賤金屬所 形成陰電極構件或由貴金屬所形成之陽電極構件之其 10 中一電極構件所構成之杯子，及將與前述其中一電極構 件成對之另一電極構件安裝於絕緣性細長棒體所形成 之攪拌器。 11. 一種杯子，係由賤金屬所形成之板狀陰電極構件與由貴 金屬所形成之板狀陽極構件以分別隔開的狀態，架設安 15 裝在由合成樹脂所形成之杯子本體内周面所形成者。 12. —種皮膚滾輪，包含：握柄，係由絕緣體所形成；圓筒 狀滾輪，係在該握柄前端可維持自由旋轉且由鎂所形 成；板狀金屬片，係安裝於前述握柄且由鎂之貴金屬所 形成；水分供給構件，係安裝於該金屬片一端且配置為 20 在旋轉前述滾輪時，可與該滚輪摩擦接觸；及金屬細 線，一端連接前述板狀金屬片並且另一端安裝於前述握 柄0 27200529916 Patent application scope: 1. A sterilizing liquid generating device, including: a cylindrical negative electrode, which is open at both ends formed by a base metal when a dissimilar metal is in contact with corrosion; and an anode electrode having the aforementioned negative electrode The open chamber 5 is arranged in a non-contact state on the inside and is formed of a noble metal when a dissimilar metal is in contact with corrosion, and an electromotive force of 0.7 volts or more can be generated by placing a liquid between the foregoing cathode and anode electrodes . 2. The sterilizing liquid generating device according to item 1 of the patent application scope, wherein the foregoing negative electrode is a town. 10 3. The germicidal liquid generating device according to item 2 of the application, wherein the anode electrode is copper or a ketone alloy. 4. If the germicidal liquid generating device of item 3 of the patent application is applied, a filtering device is provided below the aforementioned cathode. 5. If the germicidal liquid generating device of item 4 of the patent application is installed, it is installed so that the liquid can circulate in the liquid circulation device. 6. —A small and simple water purifier with a germicidal liquid generating device, which has a liquid forced circulation pipeline containing a filtering part in a liquid storage container, and the sterilizing liquid generating device of the scope of application for patent No. 5 is housed in the Liquid forced circulation inside the pipeline. 20 7. —A stirrer formed of an insulating slender rod body, and a cathode electrode member made of a base metal and a positive electrode member made of a noble metal are respectively provided on the rod body at intervals. . 8. A kind of agitator is in the seventh item of the scope of the patent application. A plurality of recesses are provided in the circumferential direction of the surface of the rod body along the long hand direction of the rod body. 26 200529916 grooves are installed in the grooves respectively. A cathode electrode member formed of a metal and a anode electrode member formed of a noble metal. 9. A stirrer, which is formed by an elongated rod body formed of an insulator and a flat plate-shaped stirring portion formed at one end of the rod body, and a plurality of grooves with a plurality of intervals are provided in the foregoing stirring portion, and The trench is respectively installed with a cathode electrode member formed of a base metal and a anode electrode member formed of a noble metal. 10. — A cup with a stirrer is a cup having an electrode member selected from 10 of a negative electrode member formed of a base metal or a positive electrode member formed of a noble metal, and will be the same as the foregoing One electrode member is paired and the other electrode member is mounted on a stirrer formed of an insulating elongated rod. 11. A cup comprising a plate-shaped negative electrode member formed of a base metal and a plate-shaped anode member formed of a noble metal in a state of being separated from each other. The cup is mounted on a peripheral surface of a cup body made of synthetic resin. Formed by. 12. A skin roller, comprising: a grip formed by an insulator; a cylindrical roller that is maintained at the front end of the handle and can be rotated freely and is formed of magnesium; a plate-shaped metal sheet attached to the aforementioned handle And is formed of a noble metal of magnesium; a moisture supply member is installed at one end of the metal sheet and is arranged at 20 when the aforementioned roller is rotated, and can be in frictional contact with the roller; and a thin metal wire, one end is connected to the aforementioned plate-shaped metal sheet and the other end Attached to the aforementioned grip 0 27