JP2003010865A - Apparatus for producing acidic and reduced water - Google Patents
Apparatus for producing acidic and reduced waterInfo
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- JP2003010865A JP2003010865A JP2001237107A JP2001237107A JP2003010865A JP 2003010865 A JP2003010865 A JP 2003010865A JP 2001237107 A JP2001237107 A JP 2001237107A JP 2001237107 A JP2001237107 A JP 2001237107A JP 2003010865 A JP2003010865 A JP 2003010865A
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- water
- amount
- magnesium
- acid
- acidic
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】 本発明は飲料用や美容入浴
用に供され、主として水道水の塩素除去や、人体の活性
酸素除去に効果的とされる酸化還元電位の低い水を製造
する方法と装置にかんする。TECHNICAL FIELD The present invention relates to a method for producing water having a low oxidation-reduction potential, which is used for drinking or beauty bathing, and is mainly effective for removing chlorine from tap water and removing active oxygen of the human body. Take care of the equipment.
【０００２】[0002]
【従来の技術】 水の電気分解によって生じる電解水に
は酸性水、アルカリ性水の２種があり、前者は酸化還元
電位の高い酸性水であり、後者は酸化還元電位の低いア
ルカリ性水である。アルカリ性水の中で特に酸化還元電
位の低い水は人体の活性酸素を除去する効果が大きいこ
とから体内の免疫機能を高めるので、健康の維持と多く
の慢性病予防のための飲用に適するとされ、一般に還元
水ないし電解還元水と称してその製造装置が商品として
市販され、近年の河川水、地下水の汚染問題の深刻化と
健康意識の向上に伴い、広く普及するところとなってい
る。2. Description of the Related Art There are two types of electrolyzed water produced by electrolysis of water: acidic water and alkaline water. The former is acidic water having a high redox potential, and the latter is alkaline water having a low redox potential. Among alkaline water, water with a particularly low redox potential enhances the immune function in the body because it has a large effect of removing active oxygen in the human body, so it is said to be suitable for drinking to maintain health and prevent many chronic diseases. Generally, a manufacturing apparatus for reducing water or electrolytically reducing water is marketed as a commercial product, and it is becoming widespread with the serious pollution problem of river water and groundwater and improvement of health consciousness in recent years.
【０００３】 従来の還元水製造装置は、水に若干の電
解物質を投入し、直流または直流を含んだ交流電流を水
に流すことによって、水を直接に電気分解し、マイナス
極に発生する水素分子の働きによって溶融水の酸化還元
電位をマイナス２００ミリボルト以下に下げている。
また、マグネシウム等の金属をプラス極とする通電によ
って、プラス極に水素分子を発生させて酸化還元電位の
低い還元水を得る方法がある。何れの方法も水に水素ガ
スを溶解することを基本としており、外部からの直流成
分を含んだ電気エネルギー供給を必要とする。In a conventional reduced water producing apparatus, a slight amount of an electrolytic substance is added to water, and a direct current or an alternating current containing a direct current is passed through the water to directly electrolyze the water and generate hydrogen at a negative electrode. Due to the action of molecules, the redox potential of the molten water is reduced to less than −200 millivolts.
In addition, there is a method of generating hydrogen molecules in the positive electrode by applying electricity with a metal such as magnesium as the positive electrode to obtain reduced water having a low redox potential. Both methods are based on dissolving hydrogen gas in water, and require an electric energy supply containing a DC component from the outside.
【０００４】 一方、古くからの公知技術として、ナト
リウム等のアルカリ金属や、マグネシウムを含むアルカ
リ土類金属に希酸を接触させて水素ガスを発生させる方
法がある。この技術は専ら少量の水素気体を得るための
実験室的方法であり、同じく酢酸、クエン酸等の食用酸
や、弱酸の希釈液にマグネシウムを投入することによっ
て、水素ガスを得る方法があるが、その装置の目的とす
るところはあくまで実験室段階の気相水素ガスを得るこ
とであって、水素溶存水を得ることにはなく、従って一
般にこの方法で得られる酸化還元電位の低い還元水とし
ての位置付けは不明確であり、まして飲料用その他、日
常に還元水を供給できる装置としては実施例は無かっ
た。On the other hand, as a known technique from old times, there is a method in which an alkali metal such as sodium or an alkaline earth metal containing magnesium is brought into contact with a dilute acid to generate hydrogen gas. This technique is a laboratory method exclusively for obtaining a small amount of hydrogen gas, and there is also a method for obtaining hydrogen gas by adding magnesium to a dilute solution of an edible acid such as acetic acid and citric acid or a weak acid. However, the purpose of the device is to obtain gas phase hydrogen gas at the laboratory stage, not to obtain hydrogen-dissolved water. Therefore, as a reduced water with a low redox potential, which is generally obtained by this method, The position of No. was unclear, and there was no example as a device for drinking water or any other device that can supply reduced water on a daily basis.
【０００５】 現在市販されている還元水製造装置の殆
どはアルカリ性であり、一部に飲料としての嗜好性を高
めるために酸性液を添加して、中性ないし微弱酸性の還
元水を得ている。電気分解法によって直接に酸性還元水
を生成することが原理的に難しいことによって、酸性の
還元水製造装置は実現していない。Most of the reducing water production apparatuses currently on the market are alkaline, and an acidic liquid is added to a part thereof to enhance the palatability as a beverage to obtain neutral or weakly acidic reducing water. . Since it is theoretically difficult to directly generate acidic reduced water by the electrolysis method, an acidic reduced water producing apparatus has not been realized.
【０００６】[0006]
【発明が解決しようとする課題】 近年水溶液の水素イ
オン濃度で規定される酸性、アルカリ性の指標は本来食
品や飲料水の良否判定にとって何ら意味のあるものでは
ないことが理解されるようになった。例えば、健康に良
いとされるアルカリ性食品は、食前における生の性質は
概ね酸性であって、アルカリ性を示さない。この事実は
本発明に係わる酸性還元水と人体の健康との係わりに関
して重要な要件となるので、以下にやや詳述すると、ア
ルカリ性水のアルカリ度だけに注目するならば、アルカ
リ性水は人体にとって特別に有用なものではなく、却っ
て有害な場合が多いことが多くの文献で指摘されてい
る。例えばこれを常飲もしくは一時に多量に飲用すれば
胃酸を薄め、外部の有害な細菌の侵入を阻む力が低下す
ることや、胃液の消化酵素の働きを弱めることが示され
ている。また常態では弱酸性の腸内がアルカリ性化する
ことによって、弱酸性下で最も活発化する腸内有用細菌
の増殖は抑えられ、逆に腐敗菌の増殖が助けられるの
で、腸活動の低下による諸々の病気を誘発する原因とも
なる。しかるに一般にアルカリ性水が健康に良いとさ
れ、さらには特定の疾患とはいえ、一部のアルカリ水製
水器がわが国において医療用具として認可されているの
は、主としてアルカリ性水の多くが有する低い酸化還元
電位の性質によってもたらされるものである。低い酸化
還元電位の属性は必ずしもアルカリ性水固有のものでは
なく、一般のアルカリ性水が水の電気分解によって作ら
れるので、マイナス極に副次的に発生する水素ガス成分
の還元効果によるものである。従って、このようにして
作られたアルカリ性水は、時間の経過と共にアルカリ性
は保たれるものの、水素の大気中への拡散によって還元
電位は上昇する。即ちアルカリ性水は時間の経過と共に
有効性は薄れてるばかりではなく、アルカリ性に起因す
る有害性は持続するので、かえって飲用として適さない
水になる危険性が大きい。[Problems to be Solved by the Invention] In recent years, it has come to be understood that the index of acidity and alkalinity defined by the hydrogen ion concentration of an aqueous solution does not originally have any meaning in determining the quality of food or drinking water. . For example, alkaline foods that are considered to be healthy are generally acidic before eating, and do not exhibit alkalinity. This fact is an important requirement for the relationship between the acidic reduced water according to the present invention and the health of the human body. Therefore, a little detailed description will be made below. It is pointed out in many literatures that it is not useful for humans and is often harmful. For example, it has been shown that if it is drunk or consumed in large quantities at a time, the gastric acid is diluted, the ability to prevent the invasion of harmful bacteria from the outside is reduced, and the action of digestive enzymes in gastric juice is weakened. In addition, since the intestine, which is normally weakly acidic, becomes alkaline, the growth of useful intestinal bacteria, which is most active under weak acidity, is suppressed, and on the contrary, the growth of putrefactive bacteria is assisted. It also causes the disease. Alkaline water is generally considered to be good for health, and even though it is a specific disease, it is mainly the low oxidation of most alkaline water that is approved as a medical device in Japan. It is brought about by the nature of the reduction potential. The attribute of the low redox potential is not necessarily unique to alkaline water, and is because the general alkaline water is produced by the electrolysis of water, and is due to the reducing effect of the hydrogen gas component secondarily generated at the negative electrode. Therefore, the alkaline water thus produced maintains its alkalinity over time, but its reduction potential rises due to the diffusion of hydrogen into the atmosphere. That is, the effectiveness of alkaline water not only diminishes with the passage of time, but also the harmfulness due to alkalinity persists, so that there is a great risk of becoming water that is not suitable for drinking.
【０００７】一方身体とって良いとされる自然から採取
される飲物の多くはｐＨで示される酸度が６以下の弱酸
性であり、レモン汁や、梅エキス等は２ないし３の強い
酸性を示す。一般の酸性飲料はミネラルを多く含み栄養
学的に非常に活性の高いものであるが、胃腸内のｐＨ値
は酸性から弱酸性でバランスを保っているので、酸性飲
料は本来アルカリ性飲料に比べて整腸作用があり、身体
に適していると言える。この結果酸性、アルカリ性と酸
化性、還元性の２つの尺度から勘案して、酸性にして還
元性の水が最も身体に良いことが分かる。On the other hand, most drinks taken from nature, which are considered to be good for the body, have a weak acidity of pH 6 or less, and lemon juice, plum extract, etc. show a strong acidity of 2 to 3. . Generally acidic drinks contain a large amount of minerals and are highly active nutritionally, but since the pH value in the gastrointestinal tract is balanced from acidic to weakly acidic, acidic drinks are inherently better than alkaline drinks. It has an intestinal regulating effect and can be said to be suitable for the body. As a result, it can be seen that the acidified and reducible water is the best for the body in consideration of the two scales of acidity, alkalinity, oxidizability and reducibility.
【０００８】酸性にして酸化還元電位の低いいわゆる酸
性還元水が最も身体に良いことが明らかであるにもかか
わらず、飲料水としての普及の遅れている原因は一つに
は酸性還元水の飲料水としての定量的置づけが不明であ
ることの他に、通常の電気分解法では、酸性還元水の生
成が不可能な事による。すなわち、水の電気分解法で
は、プラス極には酸性にして酸化還元電位がプラス７０
０ミリボルト以上を示す、いわゆる酸性酸化水を生成す
る一方、マイナス極にはアルカリ性にして酸化還元電位
がマイナス２００ミリボルト以下を示す、いわゆるアル
カリ性還元水が生成し、最も求められる酸性還元水は、
原理的に二律相反となって生成されないことが確かめら
れるであろう。[0008] Despite the fact that so-called acid-reduced water, which is acidic and has a low redox potential, is the best for the body, one reason behind its delay in its use as drinking water is the drink of acid-reduced water. In addition to the fact that the quantitative placement as water is unknown, it is impossible to generate acidic reduced water by the usual electrolysis method. That is, in the electrolysis method of water, the positive electrode is made acidic and the redox potential is positive 70%.
The so-called acidic reduced water that produces 0 millivolt or more, that is, so-called acidic reduced water is produced, while the so-called alkaline reduced water that is made alkaline at the negative electrode and has an oxidation-reduction potential of −200 millivolt or less is produced.
It will be confirmed in principle that they are not generated as a reciprocal conflict.
【０００９】一方、先に述べた如く、酢酸、クエン酸等
の食用酸や、弱酸の希釈液にマグネシウムを投入するこ
とによって、酸の水素イオンを還元し、水素ガスを得る
方法がある。しかしこの方法の目的とするところはあく
まで実験室段階での気相の水素ガスを得ることであっ
て、水素溶存水を得ることではなく、従って一般にこの
方法で得られる酸化還元電位の低くするたの還元水とし
ての位置付けは不明確であり、また飲料用その他に日常
に少量から多量の範囲に供給できる還元水装置としての
実施例は無かった。On the other hand, as described above, there is a method of reducing hydrogen ions of an acid by adding magnesium to a dilute solution of an edible acid such as acetic acid or citric acid or a weak acid to obtain hydrogen gas. However, the purpose of this method is to obtain hydrogen gas in the gas phase at the laboratory stage, not to obtain hydrogen-dissolved water. Therefore, the redox potential generally obtained by this method is lowered. The position of the reducing water as a reducing water is unclear, and there is no example as a reducing water device that can be supplied to a range from a small amount to a large amount on a daily basis for beverages and the like.
【００１０】[0010]
【問題を解決するための手段】 上記目的を達成するた
めに請求項１の発明にあっては、図によって本発明の基
本構成を示すと、図１の１は真水を所定量蓄える容器で
あり、２は板状の金属マグネシウムであり、板状の金属
マグネシウムは取り付け部材３によって容器１の蓋３−
２の中央部に固定されている。これに真水４とともに、
酢酸、クエン酸等の食用酸５を所定量適宜投入すること
によって金属マグネシウムと酸性水化した水を反応させ
て水素ガスを所定量発生させる。ここで酸性水は発生し
た水素を取り込んで水素溶存水となって水素電極の電極
電位に相当する零ミリボルト以下の低い酸化還元電位を
示し、酸性度は使用する酸の酸性度を維持することが期
待される。かくして、水素の水中溶解によって生成した
酸化還元電位の低い酸性水を飲料用、入浴用として供給
するための酸性還元水製造装置が構成される。使用する
マグネシウム金属材は純度の高いものが望ましく、形状
として反応性に優れた粉末状やリボン状は選択されず、
耐久性と安全性に優れた厚い板状が選ばれる。厚い板状
が選ばれる理由としては、マグネシウム金属材が飲料用
水生成装置の一部を構成する素材として在る程度の強度
を必要とすることと、マグネシウム金属がマグネシウム
イオン化して還元水に溶け込み、消耗される量を抑制し
つつ、反応速度に直接関係のある、マグネシウム金属材
の表面積の大きさを管理し反応速度を制御し易くするた
めである。粉末状やリボン状が選ばれない他の理由は、
粉末状やリボン状は水素飽和水を得るにはあまりにも反
応性が高く、水素溶存水としての寿命が短いことによ
る。[Means for Solving the Problems] In order to achieve the above-mentioned object, in the invention of claim 1, the basic configuration of the present invention is shown in the figure. 1 in FIG. 1 is a container for storing a predetermined amount of fresh water. 2 is a plate-shaped metal magnesium, and the plate-shaped metal magnesium is attached to the lid 3 of the container 1 by the attachment member 3.
It is fixed to the center of 2. With fresh water 4
By appropriately adding a predetermined amount of edible acid 5 such as acetic acid or citric acid, metallic magnesium reacts with acidified water to generate a predetermined amount of hydrogen gas. Here, the acidic water takes in the generated hydrogen to become hydrogen-dissolved water and exhibits a low redox potential of 0 millivolt or less corresponding to the electrode potential of the hydrogen electrode, and the acidity can maintain the acidity of the acid used. Be expected. Thus, an acidic reduced water producing apparatus for supplying acidic water having a low redox potential generated by dissolution of hydrogen in water for drinking and bathing is constituted. It is desirable that the magnesium metal material to be used has a high degree of purity, and a powdery or ribbon-like shape having excellent reactivity is not selected as a shape,
A thick plate with excellent durability and safety is selected. The reason why the thick plate shape is selected is that the magnesium metal material needs to have such strength that it exists as a material forming a part of the drinking water generator, and the magnesium metal dissolves into the reduced water by magnesium ionization, This is because it is possible to control the reaction rate by controlling the size of the surface area of the magnesium metal material, which is directly related to the reaction rate while suppressing the amount consumed. Other reasons why powder and ribbon are not selected are
This is because the powder or ribbon is too reactive to obtain hydrogen saturated water and has a short life as hydrogen-dissolved water.
【００１１】 請求項２の発明にあっては、酸化還元電
位の低い酸性水を飲料用として効率的かつ実用的に供給
するための酸性還元水製造装置において使用される金属
マグネシウムの形状を、板状とし、この金属マグネシウ
ムの単位使用水量当たりの表面積をＳ（Ｃｍ２／リット
ル）とすると、
２０＜Ｓ＜２００ … 式（１）
の範囲とする。 本条件は食用酸とマグネシウムとの反
応で生じる水素の発生速度の時定数が投入酸の濃度によ
らず、マグネシウム材の表面積によってのみ規定される
ことから定められた。この設定条件は食用酸の１回の投
与で、水素飽和が左辺においては１０時間以上右辺にお
いては１時間以下に保たれる条件である。すなわち水素
溶存水を１容器当たり一回の食事時間に合わせて飲用を
終了すると考えた場合、水素飽和状態が飲用として適し
た状態が最低１時間継続することが必要であり、一方１
０時間以上水素飽和状態以上保つことは、水中から気中
への水素放散分を考えると、かえって過分の水素供給を
意味し、生成された水素が無駄になることによる。According to the second aspect of the present invention, the shape of metallic magnesium used in the acidic reduced water production apparatus for efficiently and practically supplying acidic water having a low redox potential for beverages And the surface area of this metallic magnesium per unit amount of water used is S (Cm 2 / liter), the range is 20 <S <200 (Equation (1)). This condition was determined because the time constant of the rate of hydrogen evolution generated by the reaction between edible acid and magnesium is defined only by the surface area of the magnesium material, not by the concentration of the input acid. This setting condition is a condition in which the edible acid is administered once and hydrogen saturation is maintained for 10 hours or more on the left side and 1 hour or less on the right side. That is, when it is considered that drinking of hydrogen-dissolved water will be completed in accordance with one meal time per container, it is necessary that the hydrogen-saturated state is suitable for drinking for at least 1 hour.
Keeping the hydrogen saturated state for 0 hours or more means excessive hydrogen supply, considering the amount of hydrogen released from water to the air, and the generated hydrogen is wasted.
【００１２】 さらに式（１）と同時に食用酸の投入初
期の所定モル濃度をＭ（モル／リットル）とすると、
０．５＜Ｓ・Ｍ ＜５ … 式（２）
の範囲にあることを条件とする。本発明の発明者等は金
属マグネシウムと食用酸との反応系において、反応によ
る水素ガスの時間当たりの発生量が金属マグネシウムの
表面積Ｓ（Ｃｍ２／リットル）と、食用酸の投入モル濃
度をＭ（モル／リットル）との積に比例し、その比例常
数は水素ガスの発生量をＶ（ＣＣ／分・リットル）とす
ると、約２になることを実験的に見いだした。すなわち
Ｖ＝２Ｍ・Ｓ （ＣＣ／分・リットル） … 式（３）
である。従って水に対する水素ガスの最大溶解量を常温
常圧下で約２０ＣＣ／リットルとした場合、式（２）左
辺は水素ガスの発生量が数分にして最大溶解量の１０分
の１に達する条件であり、右辺は数分後には最大溶解量
となる条件である。すなわち左辺最小値は金属マグネシ
ウムの表面積と、投入される食用酸のモル濃度との必要
最低限を示すものであるが、最大溶解量の１０分の１の
意味するところは、このとき得られる還元電位が食用酸
のｐＨを３近辺として水素基準電極で観測される電位で
理論上マイナス１５０ミリボルトが得られ、還元水とし
ての必要条件を充分満たすと考える。一方右辺最大値は
食用酸の投入後３分にして最大溶解量に達して、それ以
降の水素発生は過剰と考えられることによる。Further, at the same time as the formula (1), assuming that the predetermined molar concentration at the initial stage of the addition of the edible acid is M (mol / liter), the condition is 0.5 <S · M <5 (2) And In the reaction system of metallic magnesium and edible acid, the inventors of the present invention have determined that the amount of hydrogen gas generated per hour by the reaction is the surface area S (Cm 2 / liter) of metallic magnesium and the molar concentration of edible acid added is M. It has been experimentally found that the proportional constant is approximately 2 when the amount of hydrogen gas generated is V (CC / min.liter), which is proportional to the product of (mol / liter). That is, V = 2M · S (CC / min · liter) (3) Therefore, when the maximum amount of hydrogen gas dissolved in water is about 20 CC / liter at room temperature and normal pressure, the left side of equation (2) is a condition that the amount of hydrogen gas generated reaches a tenth of the maximum dissolved amount in a few minutes. Yes, the right side is the condition where the maximum amount of dissolution occurs after a few minutes. That is, the minimum value on the left side indicates the minimum required surface area of metallic magnesium and the molar concentration of the edible acid to be added, but one tenth of the maximum dissolution amount means that the reduction obtained at this time is It is considered that theoretically minus 150 millivolts is obtained at the potential observed at the hydrogen reference electrode when the pH of the edible acid is around 3, and the necessary condition as the reduced water is sufficiently satisfied. On the other hand, the maximum value on the right side is because the maximum amount of dissolution is reached 3 minutes after the addition of the edible acid, and it is considered that the hydrogen generation thereafter is excessive.
【００１３】 図２は前記式（１）、式（２）の条件を
図示したものである。これらの条件は水素ガスの水に対
する最大溶解度と水からの放散速度に関して、先に述べ
た如く本発明の発明者等の実験の結果得られた幾つかの
反応常数を元にして、還元水を提供するための装置を設
計するに当たって、水素の熔解効率を高め、投入する食
用酸の適量を定め、さらに常時飲用に適した構成となる
設置マグネシウム表面積Ｓと投入する食用酸のモル数Ｍ
の設定範囲を示すものであるが、飲用以外の例えば美容
水や、入浴水であれば、時間的、量的にも効率的に酸性
還元水を得るという本発明の基本条件に従って式
（１）、式（２）の要件は若干の変更は許容されるもの
である。FIG. 2 illustrates the conditions of the expressions (1) and (2). With respect to the maximum solubility of hydrogen gas in water and the rate of release from water, these conditions are based on several reaction constants obtained as a result of the experiments of the inventors of the present invention as described above. In designing the device for providing, the hydrogen melting efficiency is increased, an appropriate amount of edible acid to be charged is determined, and further, the installed magnesium surface area S and the number of moles M of edible acid to be configured to be suitable for constant drinking
The formula (1) according to the basic condition of the present invention is to obtain acidic reduced water efficiently in terms of time and quantity in the case of beauty water or bathing water other than drinking As for the requirement of the equation (2), some changes are allowed.
【００１４】 請求項３においては、図３に示したよう
に、複数枚の板状金属マグネシウム２を移動自由な棒状
ないしパイプ状のプラスチック材３とビス状の止め部材
３−２で固定することによってマグネシウム材の容器か
らの出し入れを自由にし、さらに酸性水溶液が請求項２
に示された式（１）、式（２）の条件を満たすために板
状金属マグネシウム２を必要枚数に応じて着脱し、さら
に投入する食用酸５を紙カプセル６ないし定量スプーン
７によって所要量、適宜投入することを得るものとす
る。According to the third aspect of the present invention, as shown in FIG. 3, a plurality of plate-shaped metal magnesiums 2 are fixed by a freely movable rod-shaped or pipe-shaped plastic material 3 and a screw-shaped stop member 3-2. The magnesium material can be freely put in and taken out of the container, and the acidic aqueous solution is used.
In order to satisfy the conditions of the formulas (1) and (2) shown in Fig. 2, the plate-shaped metallic magnesium 2 is attached and detached according to the required number, and the edible acid 5 to be charged is further supplied by the paper capsule 6 or the measuring spoon 7 in a required amount. , Shall be obtained appropriately.
【００１５】[0015]
【発明の効果】 請求項１に記載された発明にあっては
従来電気分解形による還元水製造装置で不可能とされ
た、酸化還元電位が低く酸性度の高い、いわゆる酸性還
元水を生成する装置を提供する。従来のアルカリ性還元
水が有する多量飲用時の有害性を解消し、、抗酸化作用
に優れ、かつ整腸作用のある飲料用に適した水を多量で
安定に効率的に得ることができる。また本発明になる酸
性還元水は人体にとって不足しがちなマグネシウムをイ
オンの形で取り込んでいるため、人体のミネラルバラン
スを良くする効果がある。また本発明は外部電源を一切
必要とせず、小形携帯用の安価な還元水製造装置とな
る。According to the invention described in claim 1, so-called acidic reduced water having a low redox potential and a high acidity, which has been impossible in the conventional electrolyzed reduced water producing apparatus, is generated. Provide a device. It is possible to eliminate the harmfulness of conventional alkaline reduced water when drinking in large amounts, obtain a large amount of water suitable for beverages having an excellent antioxidant action and having an intestinal regulating action, stably and efficiently. Further, the acidic reduced water according to the present invention incorporates magnesium, which tends to be insufficient for the human body, in the form of ions, and therefore has the effect of improving the mineral balance of the human body. Further, the present invention does not require any external power source, and is a small, portable, inexpensive reduced water producing apparatus.
【００１６】 請求項２に記載された発明にあっては飲
料用として充分な水量を供給し、長期間に亘って酸性還
元水製造装置として利用できるる。また耐久性、持続性
を備えた金属マグネシウムの形状と量を定め、随時、少
量の食用酸を使うだけの消耗材としての材料効率の良い
酸性還元水製造装置を提供し、飲料用に適した、効率的
な設計条件を与える。According to the second aspect of the present invention, a sufficient amount of water can be supplied for beverages, and it can be used as an acidic reduced water producing apparatus for a long period of time. In addition, by determining the shape and amount of durable and durable metallic magnesium, we provide an acidic reduced water production device with good material efficiency as a consumable material that uses only a small amount of edible acid at any time, and is suitable for beverages. Give efficient design conditions.
【００１７】 請求項３に記載された発明にあっては酸
性還元水の生成効率を損なうことなく酸性還元水の製造
装置を簡易に構成することが出来る。また装置全体の組
立、分解が容易なことから、短時間に保守や洗浄ができ
る。また板状マグネシウム材と板状マグネシウム材を取
り付ける棒状ないしパイプ状のプラスチック材を一体化
小型化することによってコップやポット等の一般の水容
器を本装置の容器部として代用することが出来る。According to the third aspect of the invention, it is possible to easily configure the acidic reduced water production apparatus without impairing the production efficiency of the acidic reduced water. Further, since the whole device is easily assembled and disassembled, maintenance and cleaning can be performed in a short time. Further, by integrally miniaturizing the plate-shaped magnesium material and the rod-shaped or pipe-shaped plastic material to which the plate-shaped magnesium material is attached, a general water container such as a cup or a pot can be used as the container portion of this device.
【００１８】[0018]
【発明の実施の形態】 以下、本発明の実施構造につい
て図面に基づいて説明する。図４は、図１で示された基
本構造に係わる一つの実施例で、理解を容易にするため
に内部構造を一部分解し、組み立構造として示した。図
４に於いて１はガラスで出来た容器である。約１５セン
チメートルの直径と約２０センチメートルの深さの大き
さで、約２リットルの酸性還元水を生成するための容量
を持っている。１−２は容器全体の取っ手である。１−
３は生成水の注ぎ口である。２は角板状のマグネシウム
金属である。一枚の大きさは約１インチ角で、同心状に
８枚取り付けられる。３はマグネシウム板を支持するた
めの軸芯である。３−２は容器の蓋であるが、３の軸芯
を中心軸としてスライド結合している。３−３は複数の
マグネシウム板２を軸芯に対して放射状に保持するため
の円筒状支持板である。３−４はマグネシウム板収納筐
体で、内部に十字構造のアームを介して３の軸芯と一体
構造を為し、アーム部が３−３の円筒状支持板と２の８
枚からなるマグネシウム板と勘合する。３−５は軸芯３
に繋がるノブである。軸芯は蓋に対してスライド構造
で、３−６の回転ナットによって軸芯を上下の自由な箇
所にかしめて固定する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, an embodiment structure of the present invention will be described with reference to the drawings. FIG. 4 shows an embodiment related to the basic structure shown in FIG. 1, in which the internal structure is partially disassembled for easy understanding and shown as an assembled structure. In FIG. 4, 1 is a container made of glass. It has a diameter of about 15 cm and a depth of about 20 cm, and has a capacity for producing about 2 liters of acid-reduced water. 1-2 is a handle of the entire container. 1-
3 is a spout of generated water. 2 is a rectangular plate-shaped magnesium metal. The size of one piece is about 1 inch square, and eight pieces are concentrically attached. Reference numeral 3 is a shaft core for supporting the magnesium plate. Reference numeral 3-2 denotes a lid of the container, which is slidably connected with the axis of 3 as a central axis. Reference numeral 3-3 is a cylindrical support plate for radially holding the plurality of magnesium plates 2 with respect to the shaft center. 3-4 is a magnesium plate housing, which is integrally formed with a shaft core of 3 through a cross-shaped arm inside, and an arm portion is a cylindrical support plate of 3-3 and 8 of 2.
Mates with a single magnesium plate. 3-5 is the shaft core 3
It is a knob connected to. The shaft core has a sliding structure with respect to the lid, and the shaft core is caulked and fixed to the upper and lower free portions by a rotating nut 3-6.
【００１９】本実施構造は、一回当たり２リットルの酸
性還元水を製造する装置である。酸性還元水製造の順序
として、まず角板状のマグネシウム金属２を、容器の蓋
を兼ねたマグネシウム金属支持構造部品群３、３−２、
３−３、３−４、３−５，３−６によって固定する。固
定した状態で、これら支持構造の最下部が容器底部のか
ら０．５ないし１センチメートルの間隙を保っている。
酸性還元水を生成するため、この他に必要とされる材料
は水及び食用酸である。水は水道水、井戸水等の真水で
ある。食用酸としては酢酸、クエン酸、ほか殆どの有機
酸が有効である。The structure of this embodiment is an apparatus for producing 2 liters of acid-reduced water each time. As the order of the production of acidic reduced water, first, the magnesium metal 2 in the shape of a rectangular plate is first added to the magnesium metal supporting structure parts group 3 and 3-2 which also serve as the lid of the container.
Fix by 3-3, 3-4, 3-5, 3-6. When fixed, the bottom of these support structures maintains a gap of 0.5 to 1 centimeter from the bottom of the container.
The other materials needed to produce acidic reduced water are water and edible acid. Water is fresh water such as tap water and well water. Acetic acid, citric acid, and most organic acids are effective as edible acids.
【００２０】 実施例として、水道水２リットルと、粉
末状クエン酸４グラムとを投入する。投入方法はマグネ
シウム板収納筐体設置前後の何れでも良い。本実施例で
は容器の注ぎ口を直径３センチメートルと大きめにして
あるので、マグネシウム板収納筐体を容器から離すこと
なく、水道水、クエン酸両者を注ぎ口から投入すること
が出来る。水道水２リットルに対してクエン酸４グラム
の投入量はクエン酸のモル濃度約０．０１規定に相当す
る。また、１インチ角のマグネシウム板８枚の表面積は
１００平方センチメートル／リットルである。投入初期
における酸性水のｐＨ値は２．７であり、ＯＲＰ値はプ
ラス６２０ミリボルトであった。この条件下での酸性還
元水の生成時間は、約５分となる。なを、ここでの還元
水の定義は容器中の全ての領域での酸化還元電位が、水
素基準電位で０ミリボルト以下。塩化銀／塩化カリウム
基準電位でマイナス２００ミリボルト以下を示す状態を
指す。反応が安定状態となる１０分後のｐＨ値及びＯＲ
Ｐ値はそれぞれ３．１、マイナス３６０ミリボルトであ
った。As an example, 2 liters of tap water and 4 grams of powdered citric acid are added. The charging method may be before or after installation of the magnesium plate housing. In the present embodiment, since the diameter of the spout of the container is as large as 3 cm, both tap water and citric acid can be poured from the spout without separating the magnesium plate housing from the container. An amount of 4 g of citric acid added to 2 liters of tap water corresponds to a molar concentration of citric acid of about 0.01 N. The surface area of eight 1-inch square magnesium plates is 100 square centimeters / liter. The pH value of the acidic water at the initial stage of charging was 2.7 and the ORP value was plus 620 millivolts. The production time of acidic reduced water under this condition is about 5 minutes. However, the definition of reduced water here is that the oxidation-reduction potential in all regions in the container is 0 millivolt or less at the hydrogen reference potential. Refers to the state where the silver chloride / potassium chloride reference potential is −200 millivolts or less. PH value and OR after 10 minutes when the reaction becomes stable
The P value was 3.1 and minus 360 millivolts, respectively.
【図１】 本発明の請求項１に係わる酸性還元水製造装
置の基本構成を示す図。FIG. 1 is a diagram showing a basic configuration of an acidic reduced water producing apparatus according to claim 1 of the present invention.
【図２】 本発明の請求項２に係わる酸性還元水製造装
置の構成要素を定量的に設定する条件を表すグラフ図。FIG. 2 is a graph showing conditions for quantitatively setting the constituent elements of the acidic reduced water production apparatus according to claim 2 of the present invention.
【図３】 本発明の請求項３に係わる酸性還元水製造装
置の部品構成図。FIG. 3 is a component configuration diagram of an acidic reduced water production apparatus according to claim 3 of the present invention.
【図４】 本発明の実施構造を示す組立図。FIG. 4 is an assembly view showing an embodiment structure of the present invention.
１ 水容器 １−２ 容器の取っ手 １−３ 注ぎ口 ２ 板状金属マグネシウム ３ 取り付け棒 ３−２ 蓋 ３−３ 円筒状支持板 ３−４ マグネシウム収納筐体 ３−５ ノブ ３−６ 固定用ナット ４ 真水 ５ 食用酸 ６ 紙カプセル ７ 計量スプーン 1 water container 1-2 Handle of container 1-3 spout 2 Plate metal magnesium 3 mounting rod 3-2 Lid 3-3 Cylindrical support plate 3-4 Magnesium storage case 3-5 knob 3-6 Fixing nut 4 fresh water 5 Edible acid 6 paper capsules 7 measuring spoon
Claims (3)
けられた板状の金属マグネシウムがあり、これに真水と
ともに、酢酸、クエン酸等の食用酸を所定量投入するこ
とで発生する水素ガス量を水に対する最大溶解量近辺と
し、水素の溶解によって生成する酸化還元電位の低い酸
性水において、酸化還元電位が零ミリボルト以下に設定
して、これを飲料用、美容、入浴用として供給すること
を特徴とする酸性還元水製造装置。1. A container for storing a predetermined amount of fresh water and a plate-shaped metal magnesium attached to the container. Hydrogen gas generated by charging a predetermined amount of edible acid such as acetic acid and citric acid together with fresh water into the container. Set the amount near the maximum amount of dissolution in water, and set the oxidation-reduction potential to 0 millivolts or less in acidic water with a low oxidation-reduction potential generated by the dissolution of hydrogen, and supply this for beverages, beauty, and bathing. A device for producing acidic reduced water, which is characterized by:
けられた板状の金属マグネシウムの単位水量当たりの表
面積をＳ（Ｃｍ２／リットル）とすると、 ２０＜Ｓ＜２００ … 式（１） をその範囲とし、食用酸の投入初期の所定モル濃度をＭ
（モル／リットル）とすると、 ０．５＜Ｓ・Ｍ ＜５ … 式（２） の範囲にあることを特徴とする飲料用の酸性還元水製造
方法及び装置。2. When the surface area per unit amount of water of the plate-shaped metallic magnesium attached to a part of the container is S (Cm 2 / liter) in claim 1, 20 <S <200 Formula (1) Is the range, and the prescribed molar concentration at the beginning of the addition of edible acid is M
(Mol / liter): 0.5 <S · M <5 (2) The method and apparatus for producing acidic reduced water for beverages, characterized in that
ムを複数枚、移動自由な棒状ないしパイプ状のプラスチ
ック材に着脱することによってマグネシウム材の容器か
らの出し入れを自由とし、酸性水溶液が請求項２に示さ
れた、式（１）、式（２）の条件を満たされる板状金属
マグネシウムの必要枚数を上限、下限の範囲内で増減
し、さらに投入する食用酸を定量カップないし紙カプセ
ルによって所要量、適宜投入することを得る飲料用、美
容、入浴用酸性還元水製造方法。3. The acidic aqueous solution according to claim 1, wherein a plurality of plate-shaped metallic magnesium is attached to and detached from a freely movable rod-shaped or pipe-shaped plastic material so that the magnesium material can be freely taken in and out of the container. The required number of tabular metallic magnesium satisfying the conditions of the formulas (1) and (2) shown in Fig. 3 is increased or decreased within the range of the upper limit and the lower limit, and the edible acid to be added is required by a fixed amount cup or a paper capsule. A method for producing acid-reduced water for beverages, beauty products, and baths, which can be added in an appropriate amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001237107A JP2003010865A (en) | 2001-07-02 | 2001-07-02 | Apparatus for producing acidic and reduced water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001237107A JP2003010865A (en) | 2001-07-02 | 2001-07-02 | Apparatus for producing acidic and reduced water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003010865A true JP2003010865A (en) | 2003-01-14 |
Family
ID=19068246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001237107A Pending JP2003010865A (en) | 2001-07-02 | 2001-07-02 | Apparatus for producing acidic and reduced water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003010865A (en) |
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| JP2015531363A (en) * | 2012-09-26 | 2015-11-02 | マックス−プランク−ゲゼルシャフト・ツア・フェルデルング・デア・ヴィッセンシャフテン・エー・ファオＭａｘ−Ｐｌａｎｃｋ−Ｇｅｓｅｌｌｓｃｈａｆｔ ｚｕｒ Ｆｏｅｒｄｅｒｕｎｇ ｄｅｒ Ｗｉｓｓｅｎｓｃｈａｆｔｅｎ ｅ．Ｖ． | Therapeutic use of hydrogen molecules |
| WO2015019984A1 (en) | 2013-08-05 | 2015-02-12 | ナチュラン・インターナショナル有限会社 | Beverage-containing pouch container and exterior sheet material therefor |
| KR20160039658A (en) | 2013-08-05 | 2016-04-11 | 나츄란 인타나쇼날 유겐가이샤 | Beverage-containing pouch container and exterior sheet material therefor |
| US11459167B2 (en) | 2013-08-05 | 2022-10-04 | Naturan International Co., Ltd. | Pouch container containing a beverage and exterior sheet material therefor |
| KR20160004000U (en) | 2014-03-11 | 2016-11-22 | 나츄란 인타나쇼날 유겐가이샤 | Hygiene product |
| KR20160133398A (en) | 2014-03-13 | 2016-11-22 | 나츄란 인타나쇼날 유겐가이샤 | Medical container |
| US10765603B2 (en) | 2014-03-13 | 2020-09-08 | Naturan International Co., Ltd. | Medical container |
| JP2018030743A (en) * | 2016-08-23 | 2018-03-01 | 株式会社アンノオフィス | Reaction vessel for hydrogen generator |
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