TW200400B - - Google Patents

Description

Λ () Π 6200400 五、發明説明（，） 本發明乃有關角蛋白纗雒（如頭髮）用之染料組成物 經濟部屮央標準局工消费合作社印製 料染 料操水的 之 /缺用 周g 值是 染t物 染本 ^ 0 Φ 0 劑，12之塗xsiHPH於 性Η成 性以 性染，頭 進7346物故 Mi?在， 酸ίΜ sgs化在斑及 促1912成， ㈣關只效 含 之有 氧，紅皮 透1/昭組劑 W 陽物無 包U言 果亦 有 W 生頭 0^000 H4,成 Η 物 U 據 效明 含化産對 用23特.染促 組範 成U。 理發 上氣，除 配昭利型透 髮性 組Ρ質 調本 質過膚消 物公專此滲 染酸 之g解 之。*用皮來 成特本。為 H/1此在。表"II 久者 c料配激用 組利日85做 3 性而而險發 Μ 機 持維法染下刺議 髮專及19劑98化然，危88?5g無 之纖方髮件接建 染本 ，3/溶^0/1氣。用之191^或 佳白之頭條直被 之日8691機M13用劑使虜4/_劑 極蛋維性性會料 料閲1928有㈣77配性能皮51⑽性 ，角繼化鹼，染 染參1/及的BW15含活才榭35U 活 好染白氣在髮性 性如2177量 Μ 昭包面画刺昭1.面 良於蛋的其頭酸 酸例5319大 Μ 開，界範或開2-界 性用角用因傷， 用，，8/用 U 待法子性髮特0.子 -fe·適染常。損此 採出8002使f 利方離_頭利比離 ___ Q-J 「一 会曰 固，物數劑會因 多提 19 為—專之陰之害專電性 指物成多化 ，c 。許被 7 ，因si本果及 8 損本荷兩 尤成組大氣中等害有術4087是,1日效物於有日及之 ，組料 及作泡危 技1219點後 理合大會 料劑 (請先閲讀背.ΙΓΠ之注意事項#塡寫本頁) 本紙ft尺度遑用中«家«準(CNS) T4規格(210x297公*) 81. 2. 20,000 200400 A 6 Ιϊ 6 經濟部中央檁準局貝工消费合作社印製Λ () Π 6200400 V. Description of the invention (,) The present invention is related to the dye composition for keratin keratin (such as hair). The value of g is the dyeing agent of dyeing ^ 0 Φ 0 agent, the coating of 12 is xsiHPH, and the dyeing is sexual, and the first is 7346. So Mi? is present, the acid is in the spot and promotes 1912, and the effect is only effective. Containing aerobic, red skin translucent 1 / zhao group agent W yangwuwu package U Yanguo also has raw head 0 ^ 000 H4, into Η 物 U According to the effect of containing chemical products to use 23 special. Into U. Haircuts are invigorating, except for the combination of the Zhaoli type translucent group P-quality skin-modifying skin cosmetics. * Use leather to make special edition. Done for H / 1. Table " II Jiujie c material is matched with the use of group profit day 85 to do 3 sexes and it ’s dangerous. The machine holds the dimensional method and dyes the stab and hair treatment and 19 doses of 98. It turns out that it ’s 88 ~ 5g. Then build the dye book, 3 / dissolve ^ 0/1 gas. Use 191 ^ or Jiabai's headlines until the day of the 8691 machine M13 agent to use 4 / _ agent extremely egg dimensional property materials 1928 with (77) matching performance skin 51 ⑽, keratinized alkali, dyed dye 1 / BW15 contains live Caixie 35U, it is good for dyeing white gas in hair, such as the amount of 2177 Μ Zhao Baomian painting thorn shows 1. The face is better than the egg acid of the egg example 5319 open, open or open 2-Boundary angles are used for injury, use, 8 / U to be used to treat hair type 0. 子 -fe · suitable dyeing. Losing this, 8002 was mined to make f lifangli _ head libili _ _ QJ "In a while, the number of agents will be increased due to more than 19 for-the specific power of the special Yin, the specific electric fingers will become more, c. Xu was 7, due to the si effect and 8 loss of the two groups of the two groups, the atmospheric damage is 4087, the effect of the day is in the day, the ingredients and the foaming technique will be adjusted after 1219 (please read first Back. ΙΓΠ 的 Notice # 塡 To write this page) This paper is used in the ft standard (CNS) T4 specification (210x297 g *) 81. 2. 20,000 200400 A 6 Ιϊ 6 Central Purlin Bureau of the Ministry of Economic Affairs Printed by consumer cooperatives

五、發明説明（> ) 具有強力染色能力。但是採用酸性染料及所磬稱的荷電 比之陽離子聚合物會形成油性錯合物，施塗於頭髮時， 會覆蓋頭髮的表面，使得染料無法滲入頭髮的内部。經 摩擦或洗髮後，此組成物所染之顔色會容易地去除。 因此，目前消費者急需一種採用感覺良好之酸性染料 ，經洗髮或摩擦不會脱色之角蛋白纖雒用之染色組成物 Ο 有鑑於此，本案發明者經廣泛的探討，發現配用酸性 染料，氮含量0.5至3.0¾之陽離子聚合物，及特殊的界 面活性劑，可抑制酸性染料和陽離子聚合.物形成錯合物 於低量之程度，亦保持良好的固色性及持久的調理效果 。於是導致本發明之完成。 本發明乃提供角蛋白绁維用染料組成物PH 2-4,包含 (a)有機溶劑，（b)酸性染料，（c)酸，（d)氮含量為 0.5至3.0%之陽離子聚合物及（e) —種或多種界面活性 劑，選自甜菜絵衍生物及醯化谷胺酸衍生物。 由下面的說明，可容易地明瞭本發明的特色及優點。 醑於本發明角蛋白繼雒用染料组成物中之有機溶劑（a) 並無限制，只要能均勻地溶解酸性染料（b),並促進染 料滲入角蛋白纖維即可。 此種有機溶劑例如是化合物（1)或（2)。 R 1 -(〇CH a CH 2 K -(0CH 2 CH) q -Z (1) I (CH 2 ) r -Y (請先閲讀背而之注意事項再填寫本頁) 裝· 訂- 線. 本紙張尺度遑用中B S家榣毕(CNS) 1M規格(210X297公*) 81. 2. 20,000 200400 五、發明説明（多） 式 中 R 1 、氣 原 子 f 直 鍵或 分枝 C i - 4 院 基， R 2 _ C 6 ；Η 4 - R Ξ 或 R 2 -c e 1 Η 5 其 中 R、 ?傜 氫原子，甲 基 或 甲 氣 基； R 3 傜 -C Η 2 - ,"C (CH 3 ) 2 _ » C Η 2 - C Η 2 - -C Η 2 C Η (C Η 3 )- t -C Η 2 ~ C H 2 -CH 2 -或- CH = C Η - C Η 2 -; P , q 及r 各 為 整 數 0 - 5 ; Υ 及Z 各 為 氮 原 子或羥基，但 不 包 含 式 中R 1 及 Z 係 氫， 所有 P , q 及 r偽0 之化合物。 Q^0 (2) (請先閲讀背而之注意事項再填寫本頁) 經濟部屮央標準局员工消费合作社印製 式中R ‘ 尤佳 正丁醇 ，甲異 氧乙醇 卡必醇 吡咯烷 欲加 (a)較 尤指為 的效果 例效大 50，端 常用 係直鐽或分枝Ci - 18烷基。 的化合物（1)或（2)有乙醇，異丙醇，正丙醇， ,異丁醇，乙二醇，丙二醇，1,3 -丁二醇，苄醇 丙苯醇，乙氧苯醇，對-苯胺醇，對-甲苄醇，苯 ,2 -苄氣乙醇，甲基卡必醇，丙基卡必醇，丁基 ,三甘醇單丁醇，甘油，N -甲基吡咯烷_，N -辛 酮，N -月桂吡咯烷麵等。 入本發明角蛋白缫維用染料組成物用之有機溶劑 佳之用量為G . 5 - 5 0 X重量（"X重量”以下略為"SS"), 2-305!。若用量低於Q.5S：,則無法獲致令人滿意 ,而大於5 (U ,則所得的效果無法按照過量之比 。較佳之有機溶劑（a)對水之比例為20:80至50: 賴於水在溶劑中之溶解度而定。 於染髮之任何酸性染料均可做為成分（b),而不 紙張尺度逍用中«家«毕0^)肀4規格（210x297公;»：) 81. 2. 20,000 經濟部中央標準局貝工消费合作社印製 200400_ 116_ 吞、發明説明（4) 受限制；例如CI (染料索引）酸性紅27 , 51， 18，92 , 94 ，52; CI酸性黃23，3; CI食物綠3;CI食物藍1 ; CI顔 料红5 7 - 1 ; C I酸性藍7 4 ; C I酸性紅3 3 , 8 7 , 9 5 ; C I酸性 橙7 ; C I酸性黃7 3，3 ; C I酸性緣2 5 ; C I溶劑緣7 ; C I酸 性綠5; CI酸性橙24; CI酸性紫9; CI酸性藍5, 9; CI酸 性红2 6 ; C Ϊ食物红1 , 6 ; C I酸性红8 8 ; C I酸性橙2 0 ; C I 酸性黃40, 1，36， 11; CI酸性緣1, 3; CI酸性紫43; CI酸性黑1等。 酸性染料（b)之較佳用量是佔本發明角蛋白缋維用染 料組成物重的0 . 1 - 5 % ,尤指為1 5 - 3 U用量低於0 . 1 X則 染色效果差；大於5 S；，則效果不按過量的比例放大。 有許多種常用的有機或無機酸可做為成分（c)。例如 包含：檸檬酸，乙醇酸，琥珀酸，酒石酸，乳酸，反丁 烯二酸，蘋果酸，乙醯丙酸，丁酸，戊酸，草酸，順丁 烯二酸，牖桃酸等；及無機酸，如磷酸，氫氛酸，硫酸 ，硝酸等。除用酸（c)外，尚可加入其鹽，如納鹽，鉀 鹽，銨鹽，以增加組成物之緩衝能力。 酸（c)之較佳用量佔本發明角蛋白纖雒用染料組成物 重量的0 . 1 - 1 5 3：,尤指為1 - 1 0 3；。 做為本發明組成物成分（d )之具氮含量0 . 5 - 3 . 0 3：之陽 離子聚合物可由不含氮之聚合物，如纖維素，羥乙基繼 維素，瓜耳樹膠（guar-gum)等經陽離子化而得。陽離子 化乃結合不含氪之聚合物和季銨基，如四烷銨基，羥 (請先閲讀背而之注意事項孙填寫本頁) 本紙張尺度逍用中困《家«準(CHS) 規格(210X297公釐) 8】.2. 20,000 200400 五、發明説明（r) 烷三甲銨基及二烷二丙烯銨基等。陽離子化纖維素衍生 化乙 子羥 翔 0 陽 } d , /V 物物 聚合 共聚 氯化 化子 銨離 烯陽 丙為 基做 甲可 二均 素等 維物 纖生 基衍 乙膠 羥樹 ，耳 物瓜 聯 ),為 105 鹽 ο 季40 聚R-L A,物 TF合 (C聚 氯及 化00 銨-4 甲JR 三物 基合 丙聚 羥 ， 素25 11 維 I K R 嫌 J 基物 合 聚 及 丙 名羥 標素 商維 之纖 物基 産乙 司羥 公在 物 C 化例 碩型 合典 之 物 生 II 素 維 敛 子 離 陽 為 量 含 氮 之 中 氯 化 銨 基 甲 三 基 第 法5. Description of the invention (>) It has strong dyeing ability. However, acidic dyes and cationic polymers with a so-called charge ratio will form oily complexes, which when applied to the hair, will cover the surface of the hair, preventing the dye from penetrating into the hair. After rubbing or shampooing, the color of this composition will be easily removed. Therefore, at present, consumers urgently need a dyeing composition for keratin fiber moisturizers that use good-feeling acid dyes and do not decolorize after shampooing or rubbing. In view of this, the inventors of the present invention have found after extensive discussion that acid dyes are used. , Cationic polymers with a nitrogen content of 0.5 to 3.0¾, and special surfactants, which can inhibit acid dyes and cationic polymers from forming complexes at a low level, and also maintain good color fixation and long-lasting conditioning effect . This led to the completion of the present invention. The present invention provides a dye composition PH 2-4 for keratin keratin, comprising (a) an organic solvent, (b) an acid dye, (c) an acid, (d) a cationic polymer with a nitrogen content of 0.5 to 3.0% and (E) One or more surfactants, selected from beetroot derivatives and glutamate derivatives. The features and advantages of the present invention can be easily understood from the following description. The organic solvent (a) in the dye composition for keratin succession of the present invention is not limited, as long as it can dissolve the acid dye (b) uniformly and promote dye penetration into keratin fibers. Such an organic solvent is, for example, compound (1) or (2). R 1-(〇CH a CH 2 K-(0CH 2 CH) q -Z (1) I (CH 2) r -Y (Please read the precautions before filling in this page) Binding · Binding- Line. The size of this paper is based on the BS home screen (CNS) 1M specification (210X297 g *) 81. 2. 20,000 200400 5. Description of the invention (multiple) where R 1, gas atom f direct bond or branch C i-4 Yuanji, R 2 _ C 6; Η 4-R Ξ or R 2 -ce 1 Η 5 where R,? Hydrogen atom, methyl or methyl group; R 3 傜 -C Η 2-, " C ( CH 3) 2 _ »C Η 2-C Η 2--C Η 2 C Η (C Η 3)-t -C Η 2 ~ CH 2 -CH 2 -or- CH = C Η-C Η 2-; P, q, and r are integers 0-5; Υ and Z are nitrogen atoms or hydroxyl groups, respectively, but do not include R 1 and Z hydrogens in the formula, and all P, q, and r pseudo-zero compounds. Q ^ 0 (2 ) (Please read the precautions before filling in this page) R 'Youjia n-butanol, methylisooxyethanol carbitol pyrrolidine to be added in the printed form of the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (a) More particularly, the effect is larger than 50, and the end is usually a straight or branched Ci-18 alkyl compound. 1) or (2) There are ethanol, isopropanol, n-propanol,, isobutanol, ethylene glycol, propylene glycol, 1,3-butanediol, benzyl alcohol propanol, ethoxybenzyl alcohol, p-aniline Alcohol, p-methylbenzyl alcohol, benzene, 2-benzyl alcohol, methyl carbitol, propyl carbitol, butyl, triethylene glycol monobutanol, glycerin, N-methylpyrrolidine_, N- Octanone, N-lauryl pyrrolidine, etc. The organic solvent used in the dye composition for keratin reeling of the present invention is preferably used in an amount of G. 5-5 0 X weight (" X weight " is abbreviated as " SS " below) , 2-305 !. If the amount is lower than Q.5S :, it will not be satisfactory, and if it is more than 5 (U, the effect cannot be obtained according to the excess ratio. The preferred ratio of organic solvent (a) to water is 20:80 to 50: Depends on the solubility of water in the solvent. Any acid dye used for dyeing hair can be used as the component (b), not in the paper size «Home« Bi 0 ^) Yu 4 specifications ( 210x297 ;;: :) 81. 2. 20,000 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, 200400_116_, description of invention (4) Restricted; for example, CI (Dye Index) Acid Red 27, 51, 18, 92, 94, 52; CI Acid Yellow 23, 3; CI Food Green 3; CI Food Blue 1; CI Pigment Red 5 7-1; CI Acid Blue 7 4; CI Acid Red 3 3, 8 7, 9 5; CI Acid Orange 7; CI Acid Yellow 7 3,3; CI Acid Edge 2 5; CI Solvent Edge 7; CI Acid Green 5; CI Acid Orange 24; CI Acid Violet 9; CI Acid Blue 5, 9; CI Acid Red 2 6; C Ϊ Food Red 1 , 6; CI Acid Red 8 8; CI Acid Orange 20; CI Acid Yellow 40, 1, 36, 11; CI Acid Edge 1, 3; CI Acid Violet 43; CI Acid Black 1 etc. The preferred amount of acid dye (b) is 0.1-5% of the weight of the dye composition of the keratin protein of the present invention, especially if the amount of 15-3 U is less than 0.1 X, the dyeing effect is poor; If it is greater than 5 S, the effect will not be amplified in excess proportion. There are many common organic or inorganic acids that can be used as component (c). Examples include: citric acid, glycolic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid, acetylpropionic acid, butyric acid, valeric acid, oxalic acid, maleic acid, pectic acid, etc .; and Inorganic acids, such as phosphoric acid, hydrogen acid, sulfuric acid, nitric acid, etc. In addition to the acid (c), its salts such as sodium salt, potassium salt, and ammonium salt can be added to increase the buffering capacity of the composition. The preferred amount of acid (c) accounts for 0.1 to 153: by weight of the dye composition for keratin fibrosis of the present invention, especially 1 to 103; As a component (d) of the composition of the present invention, the nitrogen content is 0.5-3.03: The cationic polymer can be a polymer that does not contain nitrogen, such as cellulose, hydroxyethyl ketone, guar gum ( guar-gum) is obtained by cationization. Cationization is a combination of Krypton-free polymers and quaternary ammonium groups, such as tetraalkylammonium groups, and hydroxyl groups (please read the precautions to be filled out by Sun to fill out this page). (210X297mm) 8] .2. 20,000 200400 V. Description of the invention (r) Alkyl trimethylammonium group and dioxane dipropenyl ammonium group, etc. Cationized cellulose derivatized ethionyl hydroxyxiang 0 yang} d, / V compound polymerization copolymerization of ammonium chloride ion ene yang propionyl as the basis of the two-dimensional homogenous fibrous cellulose derivative hydroxy tree ， Ears and melons), for 105 salts ο Season 40 Poly RL A, TF compound (C polychloride and chlorinated ammonium-4 A JR three compound compound propylene hydroxy, element 25 11-dimensional IKR suspected J base compound Poly- and C-hydroxyl hydroxy-labeled Shangwei's fibrous base-based production of hydroxybutyrate-based substance C. Chemical examples of the master-type code II. Suwei-convergent son-yangyang is in the amount of nitrogen. Ammonium chloride-based trimethyl-based law

Ft ! _ .物 L ::聚t® ο 氮 C 為化11 wisce 丨烯的 丙品 二出 基司 法甲公 氮二粉 測素澱 之維家 述纖國 所基有 中乙 4 解 -註 料 原 品 粧市 化 Ο 之 羥鹽 季 聚 售 ， (請先閲讀背而之注意事項#塡寫本頁) 及 素 雒 纖 基 乙 烴 知 法 氮 測 述 前 依 至 化 U銨 2 . 甲 三 基 1.丙 為羥 量素 含維 氮纖 之基 物乙 聚羥 共是型 氣如此 化例之 銨膠售 烯樹市 丙耳 。 二瓜脂 基化樹 甲子耳 二離瓜 陽 氛 有 膠 樹 耳 瓜 X 6 之 司 公 ⑧ 及 測 述 前 依 為 { 量量 含含 氮氮 之低 膠具 樹物 耳合 瓜聚 氯化 化子 銨離 甲陽 三型 基此 丙為 羥因 等 〇 此 ％ ο 得 · _ 3J 測 法 氮 至 度子 程離 量陽 低等 於此 制 〇 抑性 可色 物固 合進 錯促 成可 形物 料合 染聚 性化 酸子 和離 其陽 故等 ，此 %)加 ο添 經濟部中央標準局β工消t合作杜印製 ο 於 1-少 ο置 為用 佳之 較物 量合 用聚 之化 物子 合離 聚陽 化若 至 分 成 和 分 ο成 為此 fct Mu 佳 Μ 尤， 及無 齡果 菜效 甜理 自調 選好 劑良 性之 活物 面成 種之 多成 或形 一 所 二 述生 群衍 捋 以胺 α谷 }化 8 {醯 本紙張尺度逍用中困家樣毕(CNS) T4規格（210X297公:《：) 81. 2. 20,000 200400 Λ β Β 6 經濟部中央標準局貝工消费合作社印製 五、發明説明（b ) 法持久。若大於0.5¾，刖此成分和酸性染料所形成之錯 合物比例增大，導致固色性變差。 做為界面活性劑（e )之甜菜鹸衍生物例如化合物（3 ) 或（4 ) 0 C Η 3 ) R5 -N+ -CH2 COO- (3) I CH a 式中R5偽直鏈或分枝C10 _ 24烷基，R6 -C〇-NH-(CH2 )m - ，其中Re俗直鐽或分枝C9 -za烷基，m傜整數1-5 。 CH a I R T - N + - C H 2 -C H-C H 2 -S 0 3 - (4) I I CH 3 X 式中R7傺直鏈或分枝c10 - M烷基，R8-C〇-NH-(CH2 )n -，其中R8傷直_或分枝C9 -23烷基，n僳整數1-5; X像氫原子或羥基。 甜菜鹺衍生物例如是椰子醯胺丙基甜菜鹼，油醯胺丙 基甜菜驗，月桂醯胺丙基甜菜鹼，椰子甜菜油醯甜 菜齡，月桂醯甜菜_，鯨蠘甜菜鹼，椰子醯胺丙基羥沙 丁，月桂醛沙丁等；持佳為椰子醯胺丙基甜菜鹼及月桂 醛丙基甜菜鹼〇在此”椰子”指衍生自椰子油之C 12脂 肪酸混合物。 醯化谷胺酸衍生物如化合物（5)所示。 -8 - 本紙张尺度遑用中國國家«準(CNS) T4規格(210X297公《) 81. 2. 20,000 (請先閲讀背而之注意事項孙填窍木頁) 經濟部屮央標準局β工消费合作社印製 200400_Lli_五、發明説明（7) 0 II R 9 -C-NH-CHCH 2 CH 2 COOX ' (5) I COOX ' 式中R9傜直鋪或分枝C9 — 23烷基，X’偽氫，鉀，納， N Η 4或烷醇胺。 明確的例子包含椰子醯谷胺酸，月桂醯谷胺酸，油醯 谷胺酸，及其鉀鹽，納鹽，烷酵胺鹽及銨鹽。 前述之甜菜鹼衍生物及醯化谷胺酸衍生物可單獨使用 ,或配合兩或多種混合使用。 成分（e)之用量較佳為佔本發明組成物重量的〇. ίο . 5 % , 尤指為 Q . 2 - Q · 4 3! 。 若用 量少於 0 . 1 % ， 則組 成物之 良好調理效果不能持久。另方面，用量大於0.5%時，則 無法得按比例地放大。 本發明角蛋白纖維用染料組成物之水溶液之pH必須為2-4 。本組成物之pH可用成分（b)， （c), (d)及（e)之量調 整。但若添用納鹽，鉀鹽或銨鹽，使本組成物具有缓衝 能力更佳。 在本發明組成物中可任意添加常用於化粧品組成物之 其他成分，只要不妨害本發明之效果即可《此種任意之 成分有增稠劑，如羥乙基纖維素；矽_，香水，防腐劑 ,紫外線吸收商I,殺菌劑，水等。 利用本發明角蛋白繼維用染料組成物染角蛋白纖維如 頭髮時，將該組成物施用於角蛋白纖雒後，在20-50 °C, (請先閲讀背而之注意事項再蜞寫本頁) 本紙》尺度边用中因《家標毕(CNS)甲4規格（210X297公*) 81. 2. 20,000 200400 Λ (ί Η 6 五、發明説明（它） 較佳為30-45 °C加熱5-30分鐘，較佳為10-20分鐘。其後 經濟部中央標準局貝工消费合作社印製 物 量 成發 本 重 色，3^ ，工 組本 而 在 5 比及 Ρ 髮完 的瞭 ， 塗卻以 a),黑估 餘明 度 別冷。，1^0之評 殘能 0 分，燥人级 除更 效 C 物鐘乾以本等 洗， 有估 成分，須差㊆ 日列 精明 指評 組15洗Ξ色1 之下 。 髮説 乃法 照鬈清 Μ 之 W 克依 覺 洗例 度下 0 0 > ^ S ^10家 〇 觸 用施 濃依 及熱洗1¾頭& Μ約專 好。的。 利實 之則 物溫精)ί?之 1 量審 良好糙糙 如之 分物S)成°c髮製色E1S-重評 滑良粗粗 例圍 成成 組45洗司染 ί 於位 光滑有當色 ，範 諸組 e 明在以公未的 Μ 施 5 極光略相顔 維明 ，照 發 C,達及大 α 物由 ，，，來之 纖發 中對？ 本髮洗樂髮較覺成。 理理滑起後 链 白本。 例及{之白水美頭。烕組Μ梳梳光擦髮 蛋制色 施物力克Μ來本過力的髮髮 指指不摩洗 角限特 實成能 5 一自日染能後染理。手手髮髮次 洗非他 一列組色 ο 之以)0(量色髮克處覺以以頭頭 4 法以其 I下之染各克 ，20計染染5法威16:0:0:經 常玆之 1 在明}將1鐘CR，估}取前的AABBCCDD} 依明W發(1約分儀值評(2依後(3 (請先閲請背而之注意事項再堝窍木頁) 本紙張尺度遑用中明國家«準(CNS) f 4規格(210X297公《) 81. 2. 20,000 200400 Λ 6η 6 經濟部中央標準局貝工消#合作社印製 五、發明説明（今） 以市售的洗髮精重覆地洗經前面（1)染過之頭髮及乾 燥，共四次^測定染過頭髮及未染的頭髮之色差（<je2) ,以評估染色效果。3E2較大，表示染色能力較佳； e 2較小，表示經洗髮後，有褪色現象。 (Ο經4次洗髮後之觸凳 依前面（3)之方法處理日本人的黑髮，由5位評審專 家評估觸覺。 AAA:幾乎完全保持極優異的光滑性及手梳性。 BBB:保持良好的光滑性及手梳性。 CCC:頭髮之觸覺略顯粗糙。 DDD:頭髮變成相當粗糙。 例1 - 4及對照例1 - 2 依表1之配方製備組成物。在例1中，角蛋白纖維用 之膠狀染髮組成物（本發明之産物No. 1)之製法乃使CI酸 性红18，乳酸納及乳酸溶於水中，在所得溶液中分散著 聚合物JR400(聯合碳化物公司産品），又加入羥乙基纖 維素/少量水分散液，加熱混合物至約6 (TC ,以增加粘 度，冷卻混合物至室溫，加入乙醇，苄醇，Softazoline® LPBUawaken精密化學品公司出品），並均化混合物得之 0 同法可製得例2-4之角蛋白繼維用染料組成物（本發 明産物No.2-4),及對照例卜2組成物（對照例産物No. 1-2 ) 0 -11- 本紙Λ尺度遑用中β B家楳毕(CNS)f 4規格(210><297公龙） 81. 2. 20,000 (請先間讀背而之注意事項#蜞寫木頁) 200400 A6 B6 五、發明説明（10) m xfoos.s xoocsl Tosc »« »«*«>«»« UJK CO CSJ O CSJ «〇 嫌 〇 r~< to O r-«Ft! _. 物 L :: polyt® ο Nitrogen C is a compound of 11 wisce, a propylene product, a dimethod of justice, a male nitrogen, two powders, a monastery, a monastery, a monastery, a family of four, and a solution based on China. It is expected that the original cosmetics will be sold in seasons of hydroxy salt, (please read the back-end notes # 塡 write this page) and the basic method of nitrocellulose based hydrocarbons before the measurement of nitrogen. Three bases 1. Propylene is a hydroxydextrin-containing nitrocellulose-containing ethoxylate copolymer type gas. The ammonium gum sold in this example is propylene. Digut lipidated tree chrysanthemum, two cucurbita citrus atmosphere, gum tree ear melon X 6 ⑧ and before the measurement is based on {the amount of low-gel containing nitrogen containing nitrogen and tree melon polychlorination The sub-ammonium is a trivalent base of methionine. The propylene is hydroxyin and so on. This is the percentage of _ 3J measured from nitrogen to the degree of ionization. The amount of yang is equal to this system. Inhibition of the chromatographic solidification into the wrong contributes to the formation of dyeable materials. Acidification and Liyangyang, etc., this%) plus the cooperation of the Central Standards Bureau of the Ministry of Economic Affairs, β Gongxiaot, and the cooperation of du printing. In the case of 1-Shao, it is better to use a more suitable amount of the chemical compound. If it is divided into and divided into the fct Mu, it becomes the best, and the ageless fruit and vegetable sweetness self-adjusting chooses the good agent. The benign living surface is multiplying or forming. } Hua 8 {Standard paper standard for home use (CNS) T4 specification (210X297): ":) 81. 2. 20,000 200400 Λ β Β 6 Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs Description of invention (b) The method is durable. If it is greater than 0.5¾, the proportion of the complex formed by this component and the acid dye increases, resulting in poor fixability. Beetroot derivatives as surfactant (e) such as compound (3) or (4) 0 C Η 3) R5 -N + -CH2 COO- (3) I CH a where R5 is pseudo-straight or branched C10 _24 alkyl, R6-C〇-NH- (CH2) m-, where Re is straight or branched C9-za alkyl, m integer 1-5. CH a IRT-N +-CH 2 -C HC H 2 -S 0 3-(4) II CH 3 X where R7 is straight or branched C10 -M alkyl, R8-C〇-NH- (CH2 ) n-, where R8 is straight or branched C9 -23 alkyl, n is an integer 1-5; X is like a hydrogen atom or a hydroxyl group. Beetroot derivatives are, for example, coconut amidopropyl betaine, oleamidopropyl betaine, laurylaminopropyl betaine, coconut beet oil, betaine age, lauryl betaine, cetyl betaine, coconut amide Propyl hydroxysardine, lauraldehyde sardine, etc .; Chijia is coconut propylamine betaine and lauraldehyde propyl betaine. "Coconut" refers to a mixture of C 12 fatty acids derived from coconut oil. The glutamate derivatives are shown in compound (5). -8-This paper uses the Chinese National Standard (CNS) T4 (210X297). 81. 2. 20,000 (Please read the notes on the back of the page to fill in the Sun page). Printed by the consumer cooperative 200400_Lli_ V. Description of invention (7) 0 II R 9 -C-NH-CHCH 2 CH 2 COOX '(5) I COOX' Where R9 is directly paved or branched C9-23 alkyl, X 'Pseudo-hydrogen, potassium, sodium, N H 4 or alkanolamine. Specific examples include coconut glutamic acid, lauryl glutamic acid, oleoglutamic acid, and its potassium, sodium, alkanoyl and ammonium salts. The aforementioned betaine derivatives and glutamate derivatives can be used alone or in combination of two or more. The amount of component (e) is preferably 0.5% of the weight of the composition of the present invention, especially Q. 2-Q. 4 3 !. If the amount is less than 0.1%, the good conditioning effect of the composition cannot last. On the other hand, when the amount is greater than 0.5%, it cannot be scaled up proportionally. The pH of the aqueous solution of the dye composition for keratin fibers of the present invention must be 2-4. The pH of this composition can be adjusted by the amounts of components (b), (c), (d) and (e). However, if sodium salt, potassium salt or ammonium salt is added, the composition has better buffering capacity. In the composition of the present invention, other ingredients commonly used in cosmetic compositions can be arbitrarily added, as long as the effect of the present invention is not hindered. Such arbitrary ingredients have thickeners, such as hydroxyethyl cellulose; silicon, perfume, Preservative, UV absorber I, fungicide, water, etc. When using the keratin of the present invention to dye keratin fibers, such as hair, with a dye composition, after applying the composition to keratin fibers, at 20-50 ° C, (please read the precautions before writing. This page) This paper is used in the scale of the "Home Standard Bi (CNS) A 4 specifications (210X297 g *) 81. 2. 20,000 200400 Λ (ί Η 6 V. Description of the invention (it) is preferably 30-45 ° C is heated for 5-30 minutes, preferably 10-20 minutes. Afterwards, the volume of printed materials in the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs will be printed with a heavy color, 3 ^, and the work group will be 5 in comparison with Ρ By the way, Tu did not use a), so I would n’t be cold. , 1 ^ 0 reviews, residual energy, 0 points, dryness level, in addition to more effective, C, Zhong, dry, washed, etc., with estimated ingredients, must be poor ㊆ daily schedule, savvy Refer to the assessment group 15 under Ξ1. It is said that the method is based on the clearing of the W Ke Yijue washing example of Μ. 0 0 > ^ S ^ 10 home 〇 Use Shi Nuoyi and hot wash 1¾ head & Μ about good. of. The truth is that the material is warm and fine) ί? 1 The quantity is good and the rough is divided into the material S) into ° c hair coloring E1S- re-evaluation of the smooth and thick example rounded into a group of 45 washes dyed in place smooth In the right way, the Fan Zhu group e Ming is slightly different from the Wei M aurora with Yan Weiming, according to C, reaching C, and reaching the large alpha origin, and, is it right? This hair shampoo is more successful. After the rationale slides, the chain is white. Examples and {Baishui Meitou.烕 组 M comb combing and wiping hair egg coloring Shi Wu Like M original strength hair refers to no friction wash angle limit special can be achieved 5 one day after dyeing after dyeing. Hand-made hair and secondary hair washing are not a set of other colors ο 0) (measure the hair color by using the head and head 4 method to dye each gram under the I, 20 dyeing and dyeing 5 law 16: 0: 0: Frequently, the first one will be 1 CR in the Ming Dynasty, the AABBCCDD before the estimation} Yiming W will send (1 about the score evaluation (2 according to the later (3 (please read the precautions before reading again. This paper uses the Zhongming National Standards (CNS) f 4 specifications (210X297). 81. 2. 20,000 200400 Λ 6η 6 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Bei Gongxiao #Cooperative V. Description of the invention (present ) Repeatedly wash the hair dyed with the previous (1) and dry it with a commercially available shampoo, and measure the color difference between the dyed and undyed hair (< je2) to evaluate the dyeing effect. 3E2 is larger, indicating better dyeing ability; e 2 is smaller, indicating faded after shampooing. (Ο After 4 times of shampooing, touch the stool to treat Japanese black hair according to the method of front (3), The tactile sensation was evaluated by 5 reviewing experts. AAA: Almost completely maintain excellent smoothness and hand combability. BBB: maintain good smoothness and hand combability. CCC: hair feels slightly rough. DDD: hair becomes quite coarse Rough. Examples 1-4 and Comparative Examples 1-2. The composition was prepared according to the formula in Table 1. In Example 1, the preparation method of the gelatinous hair dye composition for keratin fibers (product No. 1 of the present invention) was made using CI Acid Red 18, sodium lactate and lactic acid are dissolved in water, polymer JR400 (product of Union Carbide) is dispersed in the resulting solution, and hydroxyethyl cellulose / a small amount of water dispersion is added, and the mixture is heated to about 6 (TC, To increase the viscosity, cool the mixture to room temperature, add ethanol, benzyl alcohol, Softazoline® LPBUawaken Precision Chemicals Co., Ltd.), and homogenize the mixture to obtain 0. The same method can be used to produce the keratin of Example 2-4. (Product No. 2-4 of the present invention), and Composition 2 of Comparative Example 2 (Product No. 1-2 of Comparative Example) 0 -11- This paper is used in Λ-scale test medium β B Jiashubi (CNS) f 4 specifications (210 > < 297 male dragon) 81. 2. 20,000 (please read back and forth precautions # 蜞 写 木 页) 200400 A6 B6 V. 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爷与揉(ευ _镅鼸_2躲UU 001 运鏟 ijuc S籯鈮(e 9 *17S1<® 之 os-v (~ radnu二s£os u) 寸 *003—_J<3>-+->salIa3 (9) Co*ΟΟΞΊιρ<π26 (e ζ·002Γίίφ<Εί& (对) ΓΟΟΙ <8>1ο1-<σΗ (ε) 勳栌(ζ) ®2 (U 表紙張尺度適用中國困家標準(CNS)甲4規格(210x297公釐） 〇o esi oo eg Ηα < < < 6 6 An 五、發明説明（11) {«)1 懈 'OSEgi 3·οη li zi I.OH 蓉蝴i ^000 經濟部屮央標準局β工消合作社印製 vvv vvv vvv vvv 000 i 攀馅 s斑》坭杯 _软班》0 C\JS ^ 5osM来ΙΛΤ ( ~ 3«0}槲啪£傘»坭杯寸酞 vvv vvv vvv vvv i ΰο(撕坭杯丨魄}v馅e傘》踩 S«5寸Lnln寸ΙΛ二oo畤 (一 3ec)觖卸？：班卸保 uutej 癱眯葙«IK挺魁世ΙΠ:·Ν«蕻陌名QS畊 钿«119>|?二 »€0·οα:_ 郝胺 a; 6 .?.#舶胺 U二由也胺 XS .6i40K*'3:o寸 ί B)蓉齡ir« q> 坻我1£n «蕻酝说职li (請先閱讀背而之注意事項#堝寫本頁) Γ 狴劝魁世tnrelsjsliffsy/^-N^iec 裝· 線· -13- 本紙張尺度逍用中Β β家«準（CNS)TM規格（2]0X297公址） 81. 2 . 20,000 200400 Λ (; Η (； 經濟部中央標準局员工消#合作杜印製 五、發明説明（/>)fiLJ5_ 依本發明産ttiio.l之製法製備角S白纖雄用之染料组 成· 成 分 X (1 )乙酵 1 5 . β (2 > Ν -甲基吡咯烷Η 10.0 (3 )聚合物 Ji4 0 0 e 1 0.4 (4) S〇ftaζο 1 ine® LPB* 2 0.3 (M乳酸納 1.2 (6)乳酸 β.Ο » <7>CI 酸性橙 7 0.18 (8)羥乙基纖雄素 1.6 (9>水 餘額 pH 2 . 8 κ 1職合磺化公司出品之Μ離子化織雄橐，含氰量 1 . 7Χ. * 2 IU wake η精密化學品公司製造之Ν-月桂齷胺丙基 甜菜齡.act 31Χβ 取5克前述组成ft染約10克洗遍的白色變束•在45*C 滬熱覇髮15分鏞，冷卻5分鐘，以水洗，遽以洗髮精洗 •於白髮染成深橙色•頭髮光»,用手指很容易械理· 經4次洗髮後，仍保持良好的效果β 仿本發明産物Νο·1之製法，可得角蛋白繼譫用之染料姐 14- 本紙张尺度逍用中國困家標毕(rJS)T4規格（210X297公;ft) 8]. 2. 20,000 (^先閲^背而之./|&庐項办艰'7.?本0) 裝- Γ 、v*t ,Master and knead (ευ _ 镅 鼸 _2 hide UU 001 shovel ijuc S niobium (e 9 * 17S1 < ® os-v (~ radnu two s £ os u) inch * 003—_J < 3 >-+- > salIa3 (9) Co * ΟΟΞΊιρ < π26 (e ζ · 002Γίίφ < Εί & (pair) ΓΟΟΙ < 8 > 1ο1- < σΗ (ε) Xunzhi (ζ) ®2 (U sheet size applies to China Home Standards (CNS) A 4 specifications (210x297 mm) 〇o esi oo eg Ηα < < < 6 6 An V. Description of the invention (11) {«) 1 無 'OSEgi 3 · οη li zi I.OH Ronghui ^ 000 Printed by the Industry and Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs vvv vvv vvv vvv 000 i Pan stuffing》 "Cup _ soft class" 0 C \ JS ^ 5osM 来 ΙΛΤ (~ 3 «0} Querpy £ Umbrella »vvv vvv vvv vvv i ΰο (tearing cup 丨 porch) v stuffing umbrella” stepping on S «5 inch Lnln inch ΙΛ two oo 畤 (one 3ec) to unload ?: class unloading uutej paralyzed葙 «IK Ting Kui Shi ΠΠ: · Ν« 註 Moming QS Gengdian «119 > |? 二» € 0 · οα: _ Hao amine a; 6.?. # Shipping amine U diyouye amine XS .6i40K * '3: o inchί B) Rongling ir «q > 坻 我 1 £ n« 蕻 華 計 講 li (please read the back-to-be note first #pot to write this page) Γ 狴 Advise Quiz tnrelsjsliffsy / ^-N ^ iec outfit · Line · -13- The standard for this paper is to be used in Beta Beta (CNS) TM specifications (2) 0X297 public address) 81. 2. 20,000 200400 Λ (; Η (; Ministry of Economic Affairs Central Bureau of Standards Employee Elimination # Cooperation Du Printed 5. Description of the invention (/ >) fiLJ5_ Dye composition for the preparation of horn S white fiber male according to the production method of ttiio.l produced by the present invention. Ingredient X (1) Ethanol 1 5. Β (2 > Ν-甲Pyrrolidine Η 10.0 (3) polymer Ji4 0 0 e 1 0.4 (4) S〇ftaζο 1 ine® LPB * 2 0.3 (M sodium lactate 1.2 (6) lactic acid β. Ο »< 7 > CI acid orange 7 0.18 (8) Hydroxyethylcellulose 1.6 (9> water balance pH 2. 8 κ 1 M ionized woven male prong produced by Zhehe Sulfonation Company, cyanide content 1. 7 Χ. * 2 IU wake η precision chemistry N-lauryl ammonium propyl beet age made by the product company. Act 31Χβ Take 5 grams of the aforementioned composition ft and dye it with about 10 grams of washed white variable beams. • At 45 * C, Hureba sends 15 minutes of Yung, cool for 5 minutes to Washed with water, washed with shampoo and fine wash • dyed dark orange on white hair • glowed on the head », easy to handle with fingers • After 4 times of shampooing, it still maintains good results β Imitate the production method of the product Νο · 1 of the invention , Available dyes for keratin succession Sister 14- This paper scale uses the Chinese trapped home standard (rJS) T4 specification (210X297 g; ft) 8]. 2. 20,000 (^ first reading ^ behind it./|&Lu Xiang difficult to do '7. ? This 0) loaded-Γ, v * t,

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Λ Η C 五、發明説明（6 ) 成物。 成 分 X (1) 異内醇 25.0 (2) 苄醇 5.0 (3 )聚合物 J R 4 0 0 1 0.4 (4) Softazoline®LPB" 2 0.3 (5 )乳酸鈉 1.2 (6 )乳酸 6.0 (7) CI酸性藍9 0.2 (8) 羥乙基纖維素 1.6 (9) 水 餘額 PH2.8 * 1及* 2同例5。 在約10克洗過的白色髮束施塗5克前述組成物。在45 °C溫熱15分鐘，冷卻5分鐘，以水清洗，以洗髮精洗。 於是白髮染成暗藍色。染過之頭髮光滑，可用手指容易 地梳髮。經4次洗髮後，仍保持良好的效果。 例7 仿本發明産物No. 1之製法，可得下列角蛋白纖雒用染 料組成物。 (請先閲讀背而之注意事項#填寫本頁) 經濟部屮央櫺準局KX工消"合作社印製 -15 本紙張尺度逍用中國國家楳準(CNS) T4規格(210X297公釐) 81. 2. 20,000 經濟部屮央標準局貝工消费合作杜印製 onOdOO_ 丨“ 五、發明説明（β) 成 分 (1 )乙醇 (2) 2-苄氣乙醇 (3 )聚合物 J R 4 0 G * 1 (4) Softazoline®1 LPB* 2 (5 )乳酸鈉 (6 )乳酸 (7 ) C I酸性紫4 3 (8 )羥乙基纖維素 (9)水 * 1及* 2同例5。 在約10克的洗過的白髮束上施塗5克前逑組成物。在 45 °C溫熱頭髮15分鐘，冷卻至5分鐘，以水洗，以洗髮 精洗。於是白髮染成暗紫色。染過之頭髮光滑，用手指 可容易地梳理。經4次洗髮後，仍保持良好的效果。 例8 仿本發明産物No. 1之製法，可得角蛋白纖維用染料組 成物。 本紙Λ尺度遑用中《«家楳毕(CNS)甲4規格(210X297公*) X 25 . 0 . 2 1 . β餘額pH 2.8 (請先間讀背而之注意事項洱填寫本頁) 8】.2. 20,000 200400 Λ 6 Π 6 五、發明説明（ι Ο 成 分 % (1 ) 乙 醇 25 . 0 (2 ) 苄 醇 5 . 0 (3 ) 聚 合 物 JR 4 0 0 * 1 0 . 4 (4 ) Amis 〇 f t® S L - 1 1 * 2 0 . 3 (5 ) 檸 m 酸 鈉 0 . 1 (6 ) 檸 樣 酸 0 . 5 (7 ) 乳 酸 5 . 0 (8 ) C I 食 物 綠 3 0 . 16 (9 ) 羥 乙 基 m 維 素 1 . 6 (1 〇 ) 水 餘額 PH 2 .7 餐 1 固例5之 餐 1. * 2 味 之 素 公 司 製造 之 谷 胺 酸 月 桂 m 酯 〇 取 約 10 克 洗 過 之 白髮 束 9 施 塗 以 5 克 刖 述 組 成 物 〇 在 4 5 °C 溫 熱 1 5分 鐘 9 冷卻 至 室 溫 9 以 水 洗 * 以 洗 髮 精 洗 〇 於 是 白 髮 染 成 暗 m 色。 染 過 之 頭 髮 光 滑 > 可 容 易 地 以 手 指 梳' 理 0 經 4 次 洗 髮後 » 仍 保 護 良 好 的 效 果 〇 例 9 仿 本 發 明 産 物 N 〇 • 1之 製 法 9 製 造 角 蛋 白 m 雒 用 染 料 組 成物。 (請先間讀背而之注意事項洱塡寫本頁) 裝· 訂_ 線· 經濟部中央標準局员工消费合作社印製 本紙張尺度遑用中《«家«準(CNS) Τ4規格（210X297公釐） 81. 2. 20,000 20040野 u 年月日 五、發明説明（) 成 (1) 乙醇 (2) 2-午氣乙醇 (3) Jaguarh® C- 15-S* 1 (4) Softazol in e® L P B * 2 (5 )乳酸納 (6 )乳酸 (7) C I酸性紫43 (8) C I酸性黑1 (9) C I酸性橙7 (10) 羥乙基纖雒素 (1 1 )水 分 25.0 10.0 0.3 0.3 1.2 6.0 0.09 0.08 0.17 1.6 餘額pH2 . 8 (請先閲讀背面之注意事項再蜞窩木页) 經濟部中央標準局貝工消费合作杜印製 ••Π Jaguarh公司製造的羥丙基三甲銨化氱瓜耳樹P, 含氣量〗.5 X。 *2同例5之*2。 取約10克洗過之白髮束，施塗以5克前述組成物。在 451溫熱頭髮15分鐘，冷卻5分鐘，以水洗，以洗髮精 洗。於是白髮染成暗褐色。染過之頭髮光滑，可用手指 容易地梳理。經4次洗髮後，仍可保持良好的效果。 例]0 - 1 7 仿本發明産品1之方法，製備角蛋白繼維用染料組成 物（本發明産物 .5-12) 18 本紙張尺度逍用中國國家標準(CNS>T4規格(210x297公；it) 2_n' 1;歧 Λ 6 η 6 明説 明發 Λ五 彩雕琛蚪渖撇(ΔΕΙ)(璇 t^« 寐)彩*笨3缀»(璇漭«聚)镟私分臶®艱蚪渖撇(ΔΕ:2) 羝玴笨W錤摊 (联4好漭雕蘇)Λ Η C 5. Description of the invention (6) Product. Ingredient X (1) Isolactone 25.0 (2) Benzyl alcohol 5.0 (3) Polymer JR 4 0 0 1 0.4 (4) Softazoline® LPB " 2 0.3 (5) Sodium lactate 1.2 (6) Lactic acid 6.0 (7) CI acidity Blue 9 0.2 (8) Hydroxyethyl cellulose 1.6 (9) Water balance PH2.8 * 1 and * 2 Same as Example 5. 5 grams of the aforementioned composition was applied to about 10 grams of washed white hair tresses. Warm for 15 minutes at 45 ° C, cool for 5 minutes, rinse with water, and shampoo. So the white hair was dyed dark blue. The dyed hair is smooth and can be easily combed with fingers. After 4 shampoos, it still maintains good results. Example 7 Following the production method of the product No. 1 of the present invention, the following dye composition for keratin fiber lobe can be obtained. (Please read the back and the precautions # fill out this page) Printed by KX Gongxiao & Cooperative Co., Ltd. of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs -15 Copies of this paper are used in China National Standard (CNS) T4 (210X297mm) 81. 2. 20,000 The Ministry of Economic Affairs, Bureau of Standards, Beigong Consumer Cooperation Co., Ltd. printed onOdOO_ 丨 "V. Description of the invention (β) Composition (1) Ethanol (2) 2-Benzyl alcohol (3) Polymer JR 4 0 G * 1 (4) Softazoline® 1 LPB * 2 (5) Sodium lactate (6) Lactic acid (7) CI acid violet 4 3 (8) Hydroxyethyl cellulose (9) Water * 1 and * 2 Same as Example 5. Apply 10 grams of pre-composition composition to 10 grams of washed white hair bundles. Warm the hair at 45 ° C for 15 minutes, cool to 5 minutes, wash with water, and wash with shampoo. Then the white hair is dyed dark purple. The dyed hair is smooth and can be easily combed with fingers. After 4 times of shampooing, it still maintains good results. Example 8 The dye composition for keratin fibers can be obtained by imitating the production method of the product No. 1 of the present invention. The paper Λ The standard is used in "《楊 楳 戳 (CNS) A 4 specifications (210X297 public *) X 25. 0 2 1. Beta balance pH 2.8 (please read the notes beforehand and fill in this page) 8】. 2. 20,000 2004 00 Λ 6 Π 6 V. Description of the invention (ι Ο Composition% (1) Ethanol 25.0 (2) Benzyl alcohol 5.0 (3) Polymer JR 4 0 0 * 1 0.4 (4) Amis 〇ft® SL-1 1 * 2 0. 3 (5) sodium citrate 0.1 (6) citric acid 0.5 (7) lactic acid 5.0 (8) CI food green 3 0. 16 (9) hydroxyethyl Base m Vitamin 1.6 (1 〇) Water balance PH 2.7 Meal 1 Solid Example 5 Meal 1. * 2 Lauryl glutamate produced by Ajinomoto Co. Take about 10 grams of washed white hair Bunch 9 was applied with 5 grams of the composition described above. Warm at 45 ° C for 15 minutes 9 Cool to room temperature 9 Wash with water * Wash with shampoo. Then the white hair was dyed dark m. The dyed hair is smooth > can be easily combed with fingers 0 after 4 shampoos »still good protection effect 〇 Example 9 imitating the product of the present invention N 〇 • 1 of the manufacturing method 9 manufacturing keratin m Luo composition with dye Thing. (Please read the back-to-back precautions in Eryuan first to write this page) Binding · Order _ Line · Printed on paper standard printed by the Staff Consumption Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The "« Home «Standard (CNS) Τ4 specification (210X297 Mm) 81. 2. 20,000 20040 wild year, month, day, five, description of invention () into (1) ethanol (2) 2-noon ethanol (3) Jaguarh® C- 15-S * 1 (4) Softazol in e® LPB * 2 (5) Sodium lactate (6) Lactic acid (7) CI Acid Violet 43 (8) CI Acid Black 1 (9) CI Acid Orange 7 (10) Hydroxyethyl Cellulose (1 1) Moisture 25.0 10.0 0.3 0.3 1.2 6.0 0.09 0.08 0.17 1.6 Balance pH2. 8 (Please read the precautions on the back and then slash the wooden page) DuPont Printing Co., Ltd. of the Ministry of Economic Affairs, Central Bureau of Standardization and Consumer Goods • Hydroxypropyl trimethacrylate manufactured by Π Jaguarh Ammonium guar tree P, gas content〗. 5 X. * 2 Same as in Example 5 * 2. Take about 10 grams of washed white hair tress and apply 5 grams of the aforementioned composition. Warm hair at 451 for 15 minutes, cool for 5 minutes, wash with water, and shampoo. So the white hair was dyed dark brown. The dyed hair is smooth and can be easily combed with fingers. After 4 shampoos, it still maintains good results. Example] 0-1 7 Imitate the method of product 1 of the present invention to prepare a keratin secondary dimensional dye composition (product of the present invention. 5-12) 18 The paper standard is used in China National Standard (CNS> T4 specification (210x297; it) 2_n '1; Qi Λ 6 η 6 It is clearly stated that Λ multicolored carvings are made (ΔΕΙ) (uan t ^ «sleep) color * stupid 3 embellishment» (璇 漭 «poly) 镟 privately divided ® hard worm渖 橫 (ΔΕ: 2) 玝 玴 笨 W 錤 湯 (連 4 好 漭 雕 苏)

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•2 Γ6 ΡΗ2* S 25*η 2·η 25·η 25·η 2-η 25.S ^ * S 25·η ζ0 · 5 Mo · 6 rio· 7 ^0- ζ0· 9 ζ0· 1 0ζ0 · 1 1ζ0· 1 2 (請先閲讀背面之注意事項再填寫本ίί) 裝· -5 _ 钭顆S海芽 線* 本紙張尺:度边用中Β Η家標準（CNS)肀4規格（210x297公;¢) - 19 禮0V， Λ 6 Β6 五、發明説明（) 由此可知本發明之角朊纖雒用染料組成物具有優越的 染色能力，重覆洗髮後仍可保持良好的固色性，並提供 持久的極佳的調理效果c 顳然地，根據前述的精義，可做各種修改及變化，均 羼本發明申請專利範圍内，亦即依本發明報導，可按說 明書中所述體条以外的方式施行。 (請先閲讀背面之注意事項再塡寫木頁) 裝· 訂_ 經濟部中央標準局员工消费合作社印褽 20 本紙張尺度边用中Η Η家標準（CNS)甲4規格（210x297公釐）• 2 Γ6 PH2 * S 25 * η 2 · η 25 · η 25 · η 2-η 25.S ^ * S 25 · η ζ0 · 5 Mo · 6 rio · 7 ^ 0- ζ0 · 9 ζ0 · 1 0ζ0 · 1 1ζ0 · 1 2 (please read the precautions on the back before filling in this) 装 装--5 _ 钭 粒 S 海 芽 线 * This paper ruler: for the edge of the Β Η family standard (CNS) 4 specifications (210x297 Public; ¢)-19 rituals 0V, Λ 6 Β6 V. Description of the invention () From this we can see that the dye composition for prion fiber lozenges of the present invention has excellent dyeing ability, and can maintain good fixation after repeated shampooing And provide a long-lasting and excellent conditioning effect. C Temporarily, according to the aforementioned precise meaning, various modifications and changes can be made, all within the scope of the patent application of the present invention, that is, according to the report of the present invention, as described in the specification Implemented in ways other than body strips. (Please read the precautions on the back before writing a wooden page) Binding · Order _ Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 20 The size of the paper is used in the middle Η Η family standard (CNS) A 4 specifications (210x297 mm)

Claims (1)

200400 A7 B7 C7 D7 六、申請專利範園 第8110163 3號「角蛋白纖雒用染料組成物」專利案 (81年1 1月修正） 一種角蛋白纖雒用染料組成物，包含（a)0·5-50重置 %下列式（1)或（2)所示之有機溶劑， R1 -(0CH2 CH2 )p-(0CH2 CH)q-Z ⑴ (C Η 2 ) r - Y 式中R1偽氫原子，直鐽或分枝Ci - *烷基， R2 -C6 H+ -R3 -或 R2 -Ce H5 其中 R2 傜氫原子， 甲基或甲氧基；R3 ^-ch2-,-c(ch3 )2-，-ch2-CH2 -，-ch2 -CH(CH3 )-，ch2 -ch2 -ch2 -或 -CH = CH-CH2 -, p, q及r各為整數0 —5; Y及2各為 氫原子或羥基，但不包含式中R1及z偽氫，所有p， q及r傺0之化合物；或 (2) (請先閲讀背晶之注意事項再填寫本百 -" '訂· Μ濟部中央樣準局負工消费合作社印奴 式中R4傜直鐽或分枝Ct - *烷基， (b)0.1-5重置％酸性染料，（0 0.1-15重量％酸， (d )0.1-0.5重置％氡含量為0.5至3.0%之陽離子聚合 物，偽不含氡，但被季銨基所陽離子化之聚合物，該 聚合物選自纖維素，羥乙基纖維素及瓜耳樹謬，及 (e) —種或多種界面活性劑，選自甜菜齡衍生物及醯 化谷胺酸衍生物，且該染料組成物之pH為2-4 。 -1 - 本纸張尺度適用中國S家標準（CNS)甲4規格（210x297公釐） 200400 A7 B7 C7 D7 六'申請專利範圍· 2 —種角蛋白纖維之染色法，包含： 在該角蛋白纖維上施塗下列PH2-4之染料組成物‘· (a)0.5-50重量％下列式（1)或（2)所示之有機溶劑， R1 - (OCH2 CH2 )p - (OCH2 CH)q -Z (1) I (CH2 )r -v 式中R1偽氳原子，直鐽或分枝Ci - 4烷基. R2 -Ce H* -R3 -或 R2 -C6 H5 其中 R2 傜氫原子， 甲基或甲氣基；R3 偽 _CH2 - , -C (CH3 )2 - , -CH2 -CH2 - , -ch2 -CH(CH3 )-，CH2 -CH2 -ch2 -或 -CH = CH-CH2 -，P, q 8：r 各為整數 0-5; Y 及 Z 各為 氫原子或羥基，但不包含式中R1及Z俗氫，所有P， <3及r^0之化合物；或200400 A7 B7 C7 D7 VI. Patent Application No. 8110163 No. 3 "Dye Composition for Keratin Fibrosis" (amended on January 1, 1981) A dye composition for keratin fibrosis, including (a) 0 · 5-50 reset% of the organic solvent shown in the following formula (1) or (2), R1-(0CH2 CH2) p- (0CH2 CH) qZ ⑴ (C Η 2) r-Y where R1 pseudo hydrogen atom , Straight-chain or branched Ci-* alkyl, R2-C6 H +-R3-or R2-Ce H5 where R2 is a hydrogen atom, methyl or methoxy; R3 ^ -ch2-,-c (ch3) 2- , -Ch2-CH2-, -ch2 -CH (CH3)-, ch2 -ch2 -ch2 -or -CH = CH-CH2-, p, q and r are each integer 0-5; Y and 2 are each hydrogen atom Or hydroxyl, but does not include R1 and z pseudohydrogens in the formula, all the compounds of p, q and r Ye0; or (2) (please read the precautions of the back crystal first and then fill in this booklet-" '定 · Ｍ 济Ministry of Central Bureau of Standards and Practitioners Consumer Labor Cooperatives Inno-style R4 邜 鐽 or branched Ct- * alkyl, (b) 0.1-5 reset% acid dye, (0 0.1-15 wt% acid, (d) 0.1-0.5 reset cationic polymer with radon content of 0.5 to 3.0%, pseudo-free of radon, but cationized by quaternary ammonium polymerization , The polymer is selected from cellulose, hydroxyethylcellulose and guar gum, and (e) one or more surfactants, selected from sugar beet age derivatives and glutamate derivatives, and the dye The pH of the composition is 2-4. -1-This paper scale is applicable to the Chinese S family standard (CNS) A 4 specifications (210x297 mm) 200400 A7 B7 C7 D7 Six 'patent application scope 2-keratin fibers Dyeing method, comprising: applying the following PH2-4 dye composition on the keratin fibers' (a) 0.5-50% by weight of an organic solvent represented by the following formula (1) or (2), R1-(OCH2 CH2) p-(OCH2 CH) q -Z (1) I (CH2) r -v where R1 is a pseudo-atom, straight or branched Ci-4 alkyl. R2 -Ce H * -R3 -or R2- C6 H5 where R2 is a hydrogen atom, methyl or methyl; R3 pseudo_CH2-, -C (CH3) 2-, -CH2 -CH2-, -ch2 -CH (CH3)-, CH2 -CH2 -ch2- Or -CH = CH-CH2-, P, q 8: r is an integer 0-5; Y and Z are each a hydrogen atom or a hydroxyl group, but does not include R1 and Z in the formula, all P, < 3 and r ^ 0 compound; or (請先閲讀背面之注意事項再填寫本頁) 經濟部屮央標準局员工消贽合作社印製 式中R4偽直鐽或分枝Ct - *烷基， (/)0.1-5重量％酸性染料.（c)0. 1-15重量％酸， (d) 0. 1-0.5重量％氡含置為0.5至3.0¾之陽離子聚合 物，偽不含氡.但被季銨基所陽離子化之聚合物，該 聚合物選自繼維素.羥乙基纖雒素及瓜耳樹_ ’及 (e) —或多種界面活性劑，選自甜菜齡衍生物，醯化 谷胺酸衍生物；在20-50 f,溫熱該角蛋白纖雒5-30分 鐘。 -2 ~ 本纸張尺度適用中國國家標準（CNS)甲4規格（210x297公#)(Please read the precautions on the back before filling in this page) R4 pseudo-straight or branched Ct- * alkyl, (/)0.1-5wt% acid dye in the printed form of the Employee Cooperative of the Bureau of Standards, Ministry of Economic Affairs . (C) 0. 1-15% by weight acid, (d) 0. 1-0.5% by weight radon containing cationic polymer 0.5 to 3.0¾, pseudo-free of radon. But cationized by quaternary ammonium polymer , The polymer is selected from following vitamins. Hydroxyethylcellulose and guar-and (e)-or a variety of surfactants, selected from beet age derivatives, glutamic acid derivatives; in 20 -50 f, warm the keratin fiber lobe for 5-30 minutes. -2 ~ This paper scale is applicable to China National Standard (CNS) A4 specifications (210x297 公 #)