SG11201811677QA - Procatalyst compositions useful for low comonomer incorporation and process for preparing the same - Google Patents

Procatalyst compositions useful for low comonomer incorporation and process for preparing the same

Info

Publication number
SG11201811677QA
SG11201811677QA SG11201811677QA SG11201811677QA SG11201811677QA SG 11201811677Q A SG11201811677Q A SG 11201811677QA SG 11201811677Q A SG11201811677Q A SG 11201811677QA SG 11201811677Q A SG11201811677Q A SG 11201811677QA SG 11201811677Q A SG11201811677Q A SG 11201811677QA
Authority
SG
Singapore
Prior art keywords
international
freeport
procatalyst compositions
pcat
preparing
Prior art date
Application number
SG11201811677QA
Inventor
Linfeng Chen
Teresa P Karjala
Mehmet Demirors
Douglas S Ginger
Marc A Springs
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11201811677QA publication Critical patent/SG11201811677QA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 111111101111 0 1110101011111 011101 0 011111111111111H1111111110111111111110111111 Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\" WO 2018/005789 Al 04 January 2018 (04.01.2018) W I PO I PCT (51) International Patent Classification: C08F 210/16 (2006.01) C08F C08F 4/651 (2006.01) CO8F (21) International Application Number: (22) International Filing Date: 29 June 2017 (29.06.2017) (25) Filing Language: (26) Publication Language: (30) Priority Data: 62/356,866 30 June 2016 (30.06.2016) (71) Applicant: DOW GLOBAL TECHNOLOGIES [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: CHEN, Linfeng; 2301 Freeport, TX 77541 (US). KARJALA, Brazosport Blvd., Freeport, TX 77541 — Mehmet; 2301 N. Brazosport Blvd., Freeport, TX 77541 (US). SPRINGS, Marc A.; 2301 N. 4/654 (2006.01) Brazosport Blvd., Freeport, TX 77541 (US). 4/655 (2006.01) (74) Agent: HUANG, Cheney; The The Dow Chemical Compa- ny, Intellectual Property, P. 0. Box 1967, Midland, Michi- PCT/US2017/039986 gan 48641-1967 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, English CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, English DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, US KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, LLC OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. N. Brazosport Blvd., Teresa P.; 2301 N. (84) Designated States (unless otherwise indicated, for every (US). DEMIRORS, kind of regional protection available): ARIPO (BW, GH, Freeport, TX 77541 GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, N. Brazosport Blvd., UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, (US). GINGER, Douglas S.; 2301 = = USEFUL FOR LOW COMONOMER INCORPORATION FIG. lA AND PROCESS FOR moiety, a magnesium halide modifier having the formula as well as use of the polymerizable monomer (54) Title: PROCATALYST COMPOSITIONS PREPARING THE SAME = = = = _ 0.9600 = * PCAT-1 I • PCAT-1-A A PCAT-1-B • PCAT-1-C • 0 . M I A t m U m m A • • A A 0 0 0.9500 = = 0.9400 = _ = 0.9300 , = = _ (71 0.9200 = = 0.9100 _ 0.9000 1-1 0.8900 01 GC IN ir) 0 0 ---- (57) : The present disclosure GC support, a hydrocarbon solution in which 1-1 © (I). The present disclosure further relates to a one-pot process for preparing the novel procatalyst compositions, el novel procatalyst compositions in solution processes for polymerization of ethylene and at least one additional C to form a polymer composition. 0 100 200 300 400 500 600 700 800 1-Octene (g) relates to novel procatalyst compositions including a titanium the magnesium halide support is formed, and an electron donor [Continued on next page] WO 2018/005789 Al MIDEDIMOMOIDEIREEMOOVIDEMEHOMEHOIMIE TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, SK, SM, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))
SG11201811677QA 2016-06-30 2017-06-29 Procatalyst compositions useful for low comonomer incorporation and process for preparing the same SG11201811677QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662356866P 2016-06-30 2016-06-30
PCT/US2017/039986 WO2018005789A1 (en) 2016-06-30 2017-06-29 Procatalyst compositions useful for low comonomer incorporation and process for preparing the same

Publications (1)

Publication Number Publication Date
SG11201811677QA true SG11201811677QA (en) 2019-01-30

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Family Applications (2)

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SG11201811677QA SG11201811677QA (en) 2016-06-30 2017-06-29 Procatalyst compositions useful for low comonomer incorporation and process for preparing the same
SG10202013131WA SG10202013131WA (en) 2016-06-30 2017-06-29 Procatalyst compositions useful for low comonomer incorporation and process for preparing the same

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Country Status (9)

Country Link
US (1) US20190322774A1 (en)
EP (2) EP3805277A1 (en)
JP (1) JP2019524922A (en)
KR (1) KR20190025648A (en)
CN (1) CN109563203A (en)
BR (1) BR112018077415B1 (en)
ES (1) ES2866924T3 (en)
SG (2) SG11201811677QA (en)
WO (1) WO2018005789A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019125989A1 (en) * 2017-12-20 2019-06-27 Dow Global Technologies Llc Multilayer cast films and methods of making thereof
SG11202011398SA (en) 2018-06-01 2020-12-30 Dow Global Technologies Llc Ziegler-natta catalyst with an electron donor compound for increasing polymer molecular weight
WO2021022011A1 (en) * 2019-07-31 2021-02-04 Dow Global Technologies Llc Polymerization catalysts for production of polyethylene with high molecular weight

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US4612300A (en) * 1985-06-06 1986-09-16 The Dow Chemical Company Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
IT1227258B (en) * 1988-09-30 1991-03-28 Himont Inc COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE
JP3279675B2 (en) * 1992-10-12 2002-04-30 三菱化学株式会社 Method for producing α-olefin polymer
IT1264679B1 (en) * 1993-07-07 1996-10-04 Spherilene Srl CATALYSTS FOR THE (CO) POLYMERIZATION OF ETHYLENE
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Also Published As

Publication number Publication date
EP3478730B1 (en) 2021-03-10
BR112018077415B1 (en) 2023-03-14
JP2019524922A (en) 2019-09-05
EP3478730A1 (en) 2019-05-08
BR112018077415A2 (en) 2019-07-16
ES2866924T3 (en) 2021-10-20
KR20190025648A (en) 2019-03-11
CN109563203A (en) 2019-04-02
SG10202013131WA (en) 2021-02-25
WO2018005789A1 (en) 2018-01-04
US20190322774A1 (en) 2019-10-24
EP3805277A1 (en) 2021-04-14

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