SG11201807488YA - Highly selective polynorbornene homopolymer membranes for natural gas upgrading - Google Patents

Highly selective polynorbornene homopolymer membranes for natural gas upgrading

Info

Publication number
SG11201807488YA
SG11201807488YA SG11201807488YA SG11201807488YA SG11201807488YA SG 11201807488Y A SG11201807488Y A SG 11201807488YA SG 11201807488Y A SG11201807488Y A SG 11201807488YA SG 11201807488Y A SG11201807488Y A SG 11201807488YA SG 11201807488Y A SG11201807488Y A SG 11201807488YA
Authority
SG
Singapore
Prior art keywords
polynorbornene
international
applicant
alkoxysilyl
dhahran
Prior art date
Application number
SG11201807488YA
Inventor
Benjamin J Sundell
John A Lawrence Iii
Original Assignee
Saudi Arabian Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Co filed Critical Saudi Arabian Oil Co
Publication of SG11201807488YA publication Critical patent/SG11201807488YA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F132/00—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F132/08—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/00091—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching by evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/44—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of groups B01D71/26-B01D71/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/70—Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D2053/221—Devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/11—Homopolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/135—Cross-linked structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/144—Side-chains containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/37—Metal complexes
    • C08G2261/374—Metal complexes of Os, Ir, Pt, Ru, Rh, Pd
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/76—Post-treatment crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/80—Functional group cleavage, e.g. removal of side-chains or protective groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Silicon Polymers (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

W O 20 17 / 15 135 0 Al i ci- l Ag opp s 'H o / 8 H o 0 .1 Pure Gas 50 psi 10 rc 1000 C 3 H 8 Permeability (Barrier) FIG. 1 • S • • RO -S ilvie 3 n ROMP-SiMe,OEr • ROMP-SiMe(OE t) : • RO; P-S i(OEt), (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2017/151350 Al 8 September 2017 (08.09.2017) WIPO I PCT 111111111111110111011111111111010111110111011111111111110111111111111111111111110111111 (51) International Patent Classification: BOlD 53/22 (2006.01) C08J 5/22 (2006.01) BOlD 71/26 (2006.01) C08L 45/00 (2006.01) BOlD 71/70 (2006.01) C08L 65/00 (2006.01) CO8G 61/08 (2006.01) C08F 132/08 (2006.01) CO8G 77/06 (2006.01) (21) International Application Number: PCT/US2017/018695 (22) International Filing Date: 21 February 2017 (21.02.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 15/057,894 1 March 2016 (01.03.2016) US (71) Applicant: SAUDI ARABIAN OIL COMPANY [SA/SA]; Post Office Box 500, Dhahran, 31311 (SA). (71) Applicant AG only): ARAMCO SERVICES COM- PANY [US/US]; 9009 West Loop South, Houston, Texas 77096 (US). (72) Inventors: SUNDELL, Benjamin J.; c/o Saudi Arabian Oil Company, Post Office Box 5000, Dhahran, 31311 (SA). LAWRENCE, John A. III; c/o Saudi Arabian Oil Company, Post Office Box 5000, Dhahran, 31311 (SA). (74) Agents: MOLLOY, Matthew A. et al.; Dinsmore & Shohl LLP, One South Main Street, Fifth Third Center - Suite 1300, Dayton, Ohio 45402 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, [Continued on next page] (54) Title: HIGHLY SELECTIVE POLYNORBORNENE HOMOPOLYMER MEMBRANES FOR NATURAL GAS UPGRAD- ING (57) : Embodiments for a cross- linked alkoxysilyl polynorbornene homo- polymer and methods of making cross- linked alkoxysilyl polynorbornene homo- polymer are provided, where the method comprises polymerizing through addition polymerization or ring opening metathesis polymerization a norbornene monomer comprising an alkoxysilyl moiety in the presence of a catalyst to produce an al- koxysilyl modified polynorbornene homo- polymer, and producing a crosslinked al- koxysilyl polynorbornene homopolymer through sol-gel initiated crosslinking of the alkoxysilyl modified polynorbornene ho- mopolymer at ambient conditions, or acid- catalyzed conditions. WO 2017/151350 Al MIDEDIMOMOIDEIR01013110MOMINIMEHOIS SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(0 as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) Published: — with international search report (Art. 21(3))
SG11201807488YA 2016-03-01 2017-02-21 Highly selective polynorbornene homopolymer membranes for natural gas upgrading SG11201807488YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/057,894 US9896527B2 (en) 2016-03-01 2016-03-01 Highly selective polynorbornene homopolymer membranes for natural gas upgrading
PCT/US2017/018695 WO2017151350A1 (en) 2016-03-01 2017-02-21 Highly selective polynorbornene homopolymer membranes for natural gas upgrading

Publications (1)

Publication Number Publication Date
SG11201807488YA true SG11201807488YA (en) 2018-09-27

Family

ID=58314501

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201807488YA SG11201807488YA (en) 2016-03-01 2017-02-21 Highly selective polynorbornene homopolymer membranes for natural gas upgrading

Country Status (8)

Country Link
US (1) US9896527B2 (en)
EP (1) EP3423172A1 (en)
JP (1) JP7029402B2 (en)
KR (1) KR20180117682A (en)
CN (1) CN108883359B (en)
SA (1) SA518392297B1 (en)
SG (1) SG11201807488YA (en)
WO (1) WO2017151350A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2685429C1 (en) * 2018-10-24 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Additive poly(3-tri(n-alkoxy)silyltricyclo[4.2.1.02.5]non-7-ene), synthesis method thereof and method for separation of gaseous hydrocarbons using membrane based thereof
US11597784B2 (en) * 2020-03-30 2023-03-07 Saudi Arabian Oil Company Enhanced yield, structural control, and transport properties of polynorbornenes for natural gas upgrading through Mizoroki-Heck cross-couplings
CN114307693B (en) * 2022-01-04 2022-11-11 大连理工大学 Preparation method of MOFs and polymer bicontinuous mixed matrix membrane

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4341796A (en) 1994-12-21 1996-07-10 Ciba Specialty Chemicals Holding Inc. Polymerisable acetylene composition and acetylene photopolymerisation process
US5912313A (en) 1995-11-22 1999-06-15 The B. F. Goodrich Company Addition polymers of polycycloolefins containing silyl functional groups
WO1998020394A1 (en) 1996-11-04 1998-05-14 The B.F. Goodrich Company Photodefinable dielectric compositions
ATE255769T1 (en) 1997-01-21 2003-12-15 Georgia Tech Res Inst METHOD FOR MAKING AN AIR GAP SEMICONDUCTOR DEVICE FOR ULTRA-LOW CAPACITY INTERCONNECTIONS
AU6291999A (en) 1998-10-05 2000-04-26 B.F. Goodrich Company, The Catalyst and methods for polymerizing cycloolefins
US20050208286A1 (en) 2000-09-21 2005-09-22 Hartmann Mark H Polymeric composites having enhanced reversible thermal properties and methods of forming thereof
JP4821943B2 (en) 2001-05-30 2011-11-24 Ｊｓｒ株式会社 Crosslinked product of cyclic olefin addition type copolymer, composition for crosslinking, and method for producing crosslinked product
KR100816931B1 (en) * 2000-10-04 2008-03-25 제이에스알 가부시끼가이샤 Composition of Cyclic Olefin Addition Copolymer and Cross-Linked Material
KR100526402B1 (en) 2002-11-22 2005-11-08 주식회사 엘지화학 Negative c-plate type optical anisotropic film comprising poly cycloolefin and method for preparing the same
JP2005105143A (en) 2003-09-30 2005-04-21 Jsr Corp Sealing material for optical element and surface mounting type led element
US7669719B2 (en) 2006-07-05 2010-03-02 General Electric Company Membrane structure and method of making
US8043418B2 (en) 2006-12-08 2011-10-25 General Electric Company Gas separator apparatus
US8215496B2 (en) 2008-01-28 2012-07-10 Promerus Llc Polynorbornene pervaporation membrane films, preparation and use thereof
JP2010174099A (en) 2009-01-28 2010-08-12 Shin-Etsu Chemical Co Ltd Cycloolefin addition polymer and method for producing the same
WO2015134095A1 (en) 2014-03-05 2015-09-11 Materia, Inc. Thermal insulation
US10029207B2 (en) 2013-11-14 2018-07-24 The University Of Melbourne Composite gas separation membrane

Also Published As

Publication number Publication date
EP3423172A1 (en) 2019-01-09
WO2017151350A1 (en) 2017-09-08
US20170253679A1 (en) 2017-09-07
US9896527B2 (en) 2018-02-20
JP7029402B2 (en) 2022-03-03
KR20180117682A (en) 2018-10-29
JP2019512565A (en) 2019-05-16
CN108883359A (en) 2018-11-23
CN108883359B (en) 2019-12-31
SA518392297B1 (en) 2021-09-14

Similar Documents

Publication Publication Date Title
SG11201900201YA (en) Methods for quantitating individual antibodies from a mixture
SG11201903857UA (en) Antibodies to pd-1 and uses thereof
SG11201804735RA (en) Supercritical reactor systems and processes for petroleum upgrading
SG11201804190YA (en) Method and system for blockchain variant using digital signatures
SG11201909724RA (en) Systems and processes for conversion of crude oil
SG11201900746RA (en) Engineered antibodies and other fc-domain containing molecules with enhanced agonism and effector functions
SG11201907671XA (en) Systems and methods for cracking hydrocarbon streams such as crude oils utilizing catalysts which include zeolite mixtures
SG11201806798XA (en) Systems and methods for allowing a user to access blocked media
SG11201804549SA (en) Supercritical water upgrading process to produce paraffinic stream from heavy oil
SG11201809284UA (en) Mobile device connection apparatus
SG11201809916SA (en) High temperature viscoelastic surfactant (ves) fluids comprising nanoparticle viscosity modifiers
SG11201807817SA (en) High aspect ratio layered double hydroxide materials and methods for preparation thereof
SG11201804383WA (en) Supercritical water processes for upgrading a petroleum-based composition while decreasing plugging
SG11201810542VA (en) Systems and methods for upgrading heavy oils
SG11201804764QA (en) Supercritical water upgrading process to produce high grade coke
SG11201809915XA (en) Heat generating catalyst for hydrocarbons cracking
SG11201803998PA (en) Systems and methods for updating sequence of services
SG11201809212RA (en) Integrated multi-stage solvent deasphalting and delayed coking process to produce high quality coke
SG11201910144RA (en) Methods of producing hierarchical beta zeolites with tunable mesoporosity through pore directing agent assisted base leaching
SG11201906565TA (en) Dual catalyst processes and systems for propylene production
SG11201805269QA (en) Process for preparation of polyethylene nanocomposite
SG11201900655UA (en) Mixed catalyst systems for producing multimodal elastomers
SG11201902792WA (en) Fiber reinforced polymer manufacturing
SG11201807488YA (en) Highly selective polynorbornene homopolymer membranes for natural gas upgrading
SG11201809793UA (en) Tl1a antibodies and uses thereof