SG11201806870WA - Process for preparing high-reactivity isobutene homo- or copolymers - Google Patents

Process for preparing high-reactivity isobutene homo- or copolymers

Info

Publication number
SG11201806870WA
SG11201806870WA SG11201806870WA SG11201806870WA SG11201806870WA SG 11201806870W A SG11201806870W A SG 11201806870WA SG 11201806870W A SG11201806870W A SG 11201806870WA SG 11201806870W A SG11201806870W A SG 11201806870WA SG 11201806870W A SG11201806870W A SG 11201806870WA
Authority
SG
Singapore
Prior art keywords
international
copolymers
appt
minsk
basf
Prior art date
Application number
SG11201806870WA
Inventor
Roc Rosa Corberan
Klaus Muehlbach
Thomas Wettling
Sergei V Kostjuk
Irina Vasilenko
Dmitryi Shiman
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of SG11201806870WA publication Critical patent/SG11201806870WA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2017/140603 Al 24 August 2017 (24.08.2017) WIPO I PCT 1111111111111101110101011111010111110 01011111110110011111011111111111110111111 (51) International Patent Classification: C08F 10/10 (2006.01) C08F 110/10 (2006.01) C08F 4/52 (2006.01) C08F 4/54 (2006.01) CO8F 4/14 (2006.01) (21) International Application Number: PCT/EP2017/053098 (22) International Filing Date: 13 February 2017 (13.02.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 16155930.7 16 February 2016 (16.02.2016) EP (71) Applicant: BASF SE [DE/DE]; Carl-Bosch-Str. 38, 67056 Ludwigshafen am Rhein (DE). (72) Inventors: CORBERAN ROC, Rosa; Richard-Wagn- er-Str. 33, 68165 Mannheim (DE). MUEHLBACH, Klaus; Im Zaunruecken 20, 67269 Gruenstadt (DE). WETTLING, Thomas; Trifelsring 11, 67117 Limburger- hof (DE). KOSTJUK, Sergei V.; 44, Zheleznodorozhnaya street, appt., Minsk, 220014 (BY). VASILENKO, Irina; 44, Zheleznodorozhnaya street, appt., Minsk, 220014 (BY). SHIMAN, Dmitryi; 51 Krapotkina st, appt 1105, Minsk, 220002 (BY). (74) Agent: BASF IP ASSOCIATION; BASF SE, ZRX - C6, 67056 Ludwigshafen (DE). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: with international search report (Art. 21(3)) before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) W O 20 17 / 140603 Al (54) Title: PROCESS FOR PREPARING HIGH-REACTIVITY ISOBUTENE HOMO- OR COPOLYMERS (57) : The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a con - tent of terminal vinylidene double bonds per homo- or copolymer chain end of at least 70 mol% which comprises polymerizing isob - utene or an isobutene- comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymer- ization catalyst or of an alkylaluminum halide-donor complex, said complex comprising, as the donor, a mixture of at least two or - ganic compounds with at least one ether function each.
SG11201806870WA 2016-02-16 2017-02-13 Process for preparing high-reactivity isobutene homo- or copolymers SG11201806870WA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16155930 2016-02-16
PCT/EP2017/053098 WO2017140603A1 (en) 2016-02-16 2017-02-13 Process for preparing high-reactivity isobutene homo- or copolymers

Publications (1)

Publication Number Publication Date
SG11201806870WA true SG11201806870WA (en) 2018-09-27

Family

ID=55398212

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201806870WA SG11201806870WA (en) 2016-02-16 2017-02-13 Process for preparing high-reactivity isobutene homo- or copolymers

Country Status (10)

Country Link
US (2) US10968294B2 (en)
EP (1) EP3416992B1 (en)
JP (1) JP6903069B2 (en)
KR (1) KR20180109939A (en)
CN (2) CN113698514B (en)
BR (1) BR112018016567B1 (en)
CA (1) CA3014685A1 (en)
MY (1) MY189238A (en)
SG (1) SG11201806870WA (en)
WO (1) WO2017140603A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113698514B (en) * 2016-02-16 2023-11-10 巴斯夫欧洲公司 Process for preparing highly reactive isobutylene homo-or copolymers
EP3444283B1 (en) 2017-08-17 2020-02-26 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
KR102469493B1 (en) 2019-08-19 2022-11-23 주식회사 엘지화학 Organic borate-based catalyst, method for producing isobutene oligomer using same, and isobutene oligomer prepared therefrom
EP3943518A1 (en) * 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene
EP4352159A1 (en) 2021-06-07 2024-04-17 Basf Se Polyisobutene with high content of certain double bond isomers
WO2023152033A1 (en) 2022-02-11 2023-08-17 Basf Se Medium molecular polyisobutene with a certain distribution of double bond isomers
WO2023152258A1 (en) 2022-02-11 2023-08-17 Basf Se Medium molecular polyisobutene with a high content of certain double bond isomers
WO2023198589A1 (en) 2022-04-14 2023-10-19 Basf Se Process for manufacturing of polyisobutene succinic anhydrides
WO2023198616A1 (en) 2022-04-14 2023-10-19 Basf Se Process for manufacturing of polyisobutene succinic anhydrides

Family Cites Families (15)

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Publication number Priority date Publication date Assignee Title
DE2702604C2 (en) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutenes
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
BE1006694A5 (en) 1991-06-22 1994-11-22 Basf Ag PREPARATION PROCESS EXTREMELY REACTIVE polyisobutenes.
US5340881A (en) 1992-11-16 1994-08-23 The University Of Akron Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform
DE19825334A1 (en) 1998-06-05 1999-12-09 Basf Ag Process for the production of highly reactive polyisobutenes
MY127714A (en) * 1999-07-16 2006-12-29 Basf Ag Method for producing highly reactive polyisobutenes
US7893176B2 (en) * 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
US8349977B2 (en) * 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN102762610A (en) * 2010-02-17 2012-10-31 巴斯夫欧洲公司 Method for producing highly reactive isobutene homo or copolymers
RU2608510C2 (en) * 2011-08-11 2017-01-18 Басф Се Process for preparing high-reactivity isobutylene homo- or copolymers
US8697820B2 (en) * 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US8816028B2 (en) * 2012-05-22 2014-08-26 Petrochemical Supply, Inc. Polyisobutylene composition having internal vinylidene and process for preparing the polyisobutylene polymer composition
US9631038B2 (en) * 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
CN113698514B (en) * 2016-02-16 2023-11-10 巴斯夫欧洲公司 Process for preparing highly reactive isobutylene homo-or copolymers
SG11201806357PA (en) 2016-02-16 2018-08-30 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers

Also Published As

Publication number Publication date
US20190062472A1 (en) 2019-02-28
CN113698514A (en) 2021-11-26
KR20180109939A (en) 2018-10-08
CA3014685A1 (en) 2017-08-24
BR112018016567A2 (en) 2019-01-02
US20210253752A1 (en) 2021-08-19
JP6903069B2 (en) 2021-07-14
BR112018016567B1 (en) 2022-07-05
CN108602914B (en) 2021-09-24
CN108602914A (en) 2018-09-28
CN113698514B (en) 2023-11-10
EP3416992B1 (en) 2020-04-15
EP3416992A1 (en) 2018-12-26
JP2019505643A (en) 2019-02-28
MY189238A (en) 2022-01-31
US11629206B2 (en) 2023-04-18
WO2017140603A1 (en) 2017-08-24
US10968294B2 (en) 2021-04-06

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