RU99127286A - CATALYTIC COMPOSITION FOR TREATING HYDROCARBONS WITH BOILING TEMPERATURES WITHIN THE LIGROIN FACTION - Google Patents
CATALYTIC COMPOSITION FOR TREATING HYDROCARBONS WITH BOILING TEMPERATURES WITHIN THE LIGROIN FACTIONInfo
- Publication number
- RU99127286A RU99127286A RU99127286/04A RU99127286A RU99127286A RU 99127286 A RU99127286 A RU 99127286A RU 99127286/04 A RU99127286/04 A RU 99127286/04A RU 99127286 A RU99127286 A RU 99127286A RU 99127286 A RU99127286 A RU 99127286A
- Authority
- RU
- Russia
- Prior art keywords
- metal
- group
- zeolite
- ers
- catalytic composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 43
- 230000003197 catalytic Effects 0.000 title claims 34
- 150000002430 hydrocarbons Chemical class 0.000 title claims 6
- 238000009835 boiling Methods 0.000 title claims 3
- 229910052751 metal Inorganic materials 0.000 claims 77
- 239000002184 metal Substances 0.000 claims 77
- 239000010457 zeolite Substances 0.000 claims 31
- 150000003839 salts Chemical class 0.000 claims 22
- 239000011780 sodium chloride Substances 0.000 claims 22
- 239000000969 carrier Substances 0.000 claims 17
- 239000006185 dispersion Substances 0.000 claims 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 10
- 230000000875 corresponding Effects 0.000 claims 9
- 239000000243 solution Substances 0.000 claims 8
- 238000001354 calcination Methods 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 7
- 238000001035 drying Methods 0.000 claims 7
- 150000002894 organic compounds Chemical class 0.000 claims 6
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims 6
- 239000007864 aqueous solution Substances 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 238000005470 impregnation Methods 0.000 claims 4
- 238000002156 mixing Methods 0.000 claims 4
- 150000004703 alkoxides Chemical class 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 3
- 238000006477 desulfuration reaction Methods 0.000 claims 3
- 230000003009 desulfurizing Effects 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 229910052710 silicon Inorganic materials 0.000 claims 3
- 239000010703 silicon Substances 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000004432 carbon atoms Chemical group C* 0.000 claims 2
- 125000002091 cationic group Chemical group 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052803 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- 238000005516 engineering process Methods 0.000 claims 2
- -1 hydrogen ions Chemical class 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 230000032683 aging Effects 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000006317 isomerization reaction Methods 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Claims (51)
а) готовят спиртовую дисперсию, содержащую растворимую соль металла VIII группы, цеолит ERS-10 и одно или более органическое соединение, способное образовать оксид или оксиды-носители;
б) готовят водный раствор, содержащий растворимую соль металла VI группы и, возможно, гидроксид тетраалкиламмония, соответствующий формуле R4NOH;
в) спиртовую дисперсию и водную дисперсию смешивают с получением геля;
г) гель подвергают старению при температуре от 10 до 40oC;
д) гель сушат;
е) гель прокаливают.26. The method of preparing the catalytic compositions according to claim 1, containing zeolite ERS-10, a metal of group VI, a metal of group VIII and one or more oxides as a carrier, according to the following sol-gel technology:
a) an alcohol dispersion is prepared containing a soluble salt of a Group VIII metal, ERS-10 zeolite and one or more organic compounds capable of forming oxide or carrier oxides;
b) prepare an aqueous solution containing a soluble salt of a metal of group VI and, possibly, tetraalkylammonium hydroxide corresponding to the formula R 4 NOH;
c) the alcohol dispersion and the aqueous dispersion are mixed to form a gel;
g) the gel is aged at a temperature of from 10 to 40 o C;
d) the gel is dried;
e) the gel is calcined.
а) готовят спиртовую дисперсию, содержащую цеолит ERS-10 и одно или более органическое соединение, способное образовать оксид или оксиды-носители;
б) готовят водный раствор, содержащий гидроксид тетраалкиламмония, соответствующий формуле R4NOH;
в) спиртовую дисперсию и водную дисперсию смешивают с получением геля;
г) гель подвергают старению при температуре от 10 до 40oC;
д) гель сушат;
е) гель прокаливают;
ж) прокаленный продукт пропитывают раствором, содержащим соль металла VI группы, сушат, прокаливают, пропитывают раствором, содержащим соль металла VIII группы, сушат и прокаливают.27. The method of preparing the catalytic compositions according to claim 1, containing zeolite ERS-10, a metal of group VI, a metal of group VIII and one or more oxides as a carrier, as follows:
a) an alcohol dispersion is prepared containing ERS-10 zeolite and one or more organic compounds capable of forming oxide or carrier oxides;
b) preparing an aqueous solution containing tetraalkylammonium hydroxide corresponding to the formula R 4 NOH;
c) the alcohol dispersion and the aqueous dispersion are mixed to form a gel;
g) the gel is aged at a temperature of from 10 to 40 o C;
d) the gel is dried;
e) the gel is calcined;
g) the calcined product is impregnated with a solution containing a Group VI metal salt, dried, calcined, impregnated with a solution containing a Group VIII metal salt, dried and calcined.
а) готовят спиртовую дисперсию, содержащую растворимую соль металла VIII группы и одно или более органическое соединение, способное образовать оксид или оксиды-носители;
б) готовят водный раствор, содержащий растворимую соль металла VI группы и, возможно, гидроксид тетраалкиламмония, соответствующий формуле R4NOH;
в) спиртовую дисперсию и водную дисперсию смешивают с получением геля;
г) гель подвергают старению при температуре от 10 до 40oC;
д) гель сушат;
е) высушенный продукт механически смешивают с цеолитом ERS-10;
ж) полученный продукт прокаливают.28. The method of preparing the catalytic compositions according to claim 1, containing zeolite ERS-10, a metal of group VI, a metal of group VIII and one or more oxides as a carrier, as follows:
a) an alcohol dispersion is prepared containing a soluble salt of a Group VIII metal and one or more organic compounds capable of forming oxide or carrier oxides;
b) prepare an aqueous solution containing a soluble salt of a metal of group VI and, possibly, tetraalkylammonium hydroxide corresponding to the formula R 4 NOH;
c) the alcohol dispersion and the aqueous dispersion are mixed to form a gel;
g) the gel is aged at a temperature of from 10 to 40 o C;
d) the gel is dried;
e) the dried product is mechanically mixed with zeolite ERS-10;
g) the resulting product is calcined.
а) приготовление спиртовой дисперсии, содержащей растворимую соль металла VIII группы и одно или более органическое соединение, способное образовать оксид или оксиды-носители;
б) приготовление водного раствора, содержащего растворимую соль металла VI группы и, возможно, гидроксид тетраалкиламмония, соответствующий формуле R4NOH;
в) смешение спиртовой дисперсии и водной дисперсии с получением геля;
г) старение геля при температуре от 10 до 40oC;
д) сушку геля;
е) механическое смешивание высушенного продукта с цеолитом ERS-10, на поверхность которого путем пропитки нанесен металл IIB и/или IIIA группы;
ж) прокаливание.37. A method of preparing a catalyst composition according to claim 3, including:
a) the preparation of an alcohol dispersion containing a soluble salt of a Group VIII metal and one or more organic compounds capable of forming oxide or carrier oxides;
b) the preparation of an aqueous solution containing a soluble salt of a metal of group VI and, possibly, tetraalkylammonium hydroxide corresponding to the formula R 4 NOH;
c) mixing the alcohol dispersion and the aqueous dispersion to obtain a gel;
g) aging of the gel at a temperature of from 10 to 40 o C;
d) drying the gel;
f) mechanical mixing of the dried product with zeolite ERS-10, on the surface of which a metal of group IIB and / or group IIIA is applied by impregnation;
g) calcination.
а) пропитку оксидного носителя солью металла VI группы и солью металла VIII группы;
б) сушку и прокаливание продукта, полученного на стадии а);
в) смешивание пропитанного оксида, полученного на стадии б), с цеолитом ERS-10.38. The method of preparing the catalytic compositions according to claim 1, containing zeolite ERS-10, a metal of group VI, a metal of group VIII and one or more oxides as a carrier, including:
a) impregnation of the oxide carrier with a salt of a metal of group VI and a salt of a metal of group VIII;
b) drying and calcining the product obtained in stage a);
c) mixing the impregnated oxide obtained in stage b) with zeolite ERS-10.
а) готовят спиртовую дисперсию, содержащую растворимую соль металла VIII группы, соль металла IIB и/или IIIA группы, цеолит ERS-10 и одно или более органическое соединение, способное образовать оксид или оксиды-носители;
б) готовят водный раствор, содержащий растворимую соль металла VI группы и, возможно, гидроксид тетраалкиламмония, соответствующий формуле R4NOH;
в) спиртовую дисперсию и водную дисперсию смешивают с получением геля;
г) гель подвергают старению при температуре от 10 до 40oC;
д) гель сушат;
е) гель прокаливают.40. The method of preparing the catalytic compositions according to claim 2, containing zeolite ERS-10, a metal of group VI, a metal of group VIII, one or more oxides as a carrier and a metal of group IIB and / or IIIA, according to the following sol-gel technology:
a) an alcohol dispersion is prepared containing a soluble salt of a Group VIII metal, a salt of a Group IIB and / or Group IIIA metal, an ERS-10 zeolite, and one or more organic compounds capable of forming oxide or carrier oxides;
b) prepare an aqueous solution containing a soluble salt of a metal of group VI and, possibly, tetraalkylammonium hydroxide corresponding to the formula R 4 NOH;
c) the alcohol dispersion and the aqueous dispersion are mixed to form a gel;
g) the gel is aged at a temperature of from 10 to 40 o C;
d) the gel is dried;
e) the gel is calcined.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI98A002773 | 1998-12-22 | ||
IT1998MI002773A IT1304792B1 (en) | 1998-12-22 | 1998-12-22 | CATALYTIC COMPOSITION FOR THE UPGRADING OF HYDROCARBONS WITH POINT BOILING IN THE NAFTA INTERVAL. |
Publications (2)
Publication Number | Publication Date |
---|---|
RU99127286A true RU99127286A (en) | 2001-09-10 |
RU2227066C2 RU2227066C2 (en) | 2004-04-20 |
Family
ID=11381304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU99127286/04A RU2227066C2 (en) | 1998-12-22 | 1999-12-20 | Catalytic composition for enrichment of hydrocarbons with boiling temperatures, that are in the range of naphtha fraction boiling temperatures |
Country Status (16)
Country | Link |
---|---|
US (2) | US6416660B1 (en) |
EP (1) | EP1013339A3 (en) |
JP (1) | JP2000288398A (en) |
CN (1) | CN1260375A (en) |
AR (1) | AR022003A1 (en) |
AU (1) | AU767598B2 (en) |
BR (1) | BR9905940A (en) |
CA (1) | CA2292950A1 (en) |
HR (1) | HRP990392A2 (en) |
HU (1) | HUP9904691A3 (en) |
IT (1) | IT1304792B1 (en) |
NO (1) | NO996371L (en) |
NZ (1) | NZ501970A (en) |
PL (1) | PL337358A1 (en) |
RU (1) | RU2227066C2 (en) |
SK (1) | SK183399A3 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0980908A1 (en) * | 1998-08-15 | 2000-02-23 | ENITECNOLOGIE S.p.a. | Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range |
IT1304792B1 (en) * | 1998-12-22 | 2001-03-29 | Agip Petroli | CATALYTIC COMPOSITION FOR THE UPGRADING OF HYDROCARBONS WITH POINT BOILING IN THE NAFTA INTERVAL. |
US6790803B2 (en) | 2001-08-17 | 2004-09-14 | Intevep, S.A. | Catalytic system for hydroconversion of naphtha |
US6867341B1 (en) * | 2002-09-17 | 2005-03-15 | Uop Llc | Catalytic naphtha cracking catalyst and process |
EP1403358A1 (en) * | 2002-09-27 | 2004-03-31 | ENI S.p.A. | Process and catalysts for deep desulphurization of fuels |
US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
IT1392806B1 (en) * | 2009-02-02 | 2012-03-23 | Eni Spa | FLUID BED INTEGRATED CATALYTIC CRACKING PROCESS TO OBTAIN HYDROCARBURIC MIXTURES WITH HIGH QUALITY AS FUEL |
FI128142B (en) * | 2010-02-02 | 2019-10-31 | Upm Kymmene Corp | Process and apparatus for producing hydrocarbons |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5620087A (en) * | 1979-07-30 | 1981-02-25 | Mitsubishi Chem Ind Ltd | Conversion of hydrocarbon |
JPS614786A (en) * | 1984-06-19 | 1986-01-10 | Fuji Sekiyu Kk | Method for reforming hydrocarbon fraction |
US5013423A (en) | 1987-11-17 | 1991-05-07 | Mobil Oil Corporation | Reforming and dehydrocyclization |
TW230217B (en) * | 1990-03-23 | 1994-09-11 | Cosmo Oil Co Ltd | |
US5326463A (en) * | 1991-08-15 | 1994-07-05 | Mobil Oil Corporation | Gasoline upgrading process |
AU658937B2 (en) * | 1991-11-19 | 1995-05-04 | Mobil Oil Corporation | Hydrocarbon upgrading process |
US5397455A (en) * | 1993-08-11 | 1995-03-14 | Mobil Oil Corporation | Gasoline upgrading process |
US5770047A (en) * | 1994-05-23 | 1998-06-23 | Intevep, S.A. | Process for producing reformulated gasoline by reducing sulfur, nitrogen and olefin |
US5576256A (en) | 1994-05-23 | 1996-11-19 | Intevep, S.A. | Hydroprocessing scheme for production of premium isomerized light gasoline |
TW470915B (en) * | 1996-03-12 | 2002-01-01 | Matsushita Electric Ind Co Ltd | Optimization apparatus which removes transfer instructions by a global analysis of equivalence relations |
IT1283284B1 (en) * | 1996-03-21 | 1998-04-16 | Eniricerche Spa | ZEOLITE ERS-10 AND PROCEDURE FOR ITS PREPARATION |
IT1299035B1 (en) * | 1998-04-07 | 2000-02-07 | Enichem Spa | PROCESS FOR THE PREPARATION OF MONOALKYLATED AROMATIC COMPOUNDS |
IT1304792B1 (en) * | 1998-12-22 | 2001-03-29 | Agip Petroli | CATALYTIC COMPOSITION FOR THE UPGRADING OF HYDROCARBONS WITH POINT BOILING IN THE NAFTA INTERVAL. |
-
1998
- 1998-12-22 IT IT1998MI002773A patent/IT1304792B1/en active
-
1999
- 1999-12-17 CA CA002292950A patent/CA2292950A1/en not_active Abandoned
- 1999-12-17 HR HR990392A patent/HRP990392A2/en not_active Application Discontinuation
- 1999-12-20 EP EP99204430A patent/EP1013339A3/en not_active Withdrawn
- 1999-12-20 US US09/466,791 patent/US6416660B1/en not_active Expired - Fee Related
- 1999-12-20 AU AU65323/99A patent/AU767598B2/en not_active Ceased
- 1999-12-20 RU RU99127286/04A patent/RU2227066C2/en not_active IP Right Cessation
- 1999-12-21 HU HU9904691A patent/HUP9904691A3/en unknown
- 1999-12-21 PL PL99337358A patent/PL337358A1/en unknown
- 1999-12-21 NZ NZ501970A patent/NZ501970A/en unknown
- 1999-12-21 SK SK1833-99A patent/SK183399A3/en unknown
- 1999-12-21 NO NO996371A patent/NO996371L/en not_active Application Discontinuation
- 1999-12-22 BR BR9905940-1A patent/BR9905940A/en not_active Application Discontinuation
- 1999-12-22 JP JP11365532A patent/JP2000288398A/en active Pending
- 1999-12-22 CN CN99127777A patent/CN1260375A/en active Pending
- 1999-12-22 AR ARP990106706A patent/AR022003A1/en active IP Right Grant
-
2002
- 2002-02-14 US US10/073,977 patent/US6660676B2/en not_active Expired - Fee Related
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