RU94044433A - Mixture of optically active cyclohexene oxime ethers, method of their production and intermediate products for their production and usage thereof as herbicides - Google Patents

Mixture of optically active cyclohexene oxime ethers, method of their production and intermediate products for their production and usage thereof as herbicides

Info

Publication number
RU94044433A
RU94044433A RU94044433/04A RU94044433A RU94044433A RU 94044433 A RU94044433 A RU 94044433A RU 94044433/04 A RU94044433/04 A RU 94044433/04A RU 94044433 A RU94044433 A RU 94044433A RU 94044433 A RU94044433 A RU 94044433A
Authority
RU
Russia
Prior art keywords
alkyl
halide
definite conditions
mixture
production
Prior art date
Application number
RU94044433/04A
Other languages
Russian (ru)
Inventor
Мисслитц Ульф
De]
Мейер Норберт
Каст Юрген
Ранг Харальд
Зигель Хардо
Вальтер Хельмут
Вестфален Карл-Отто
Гербер Маттиас
Кардорфф Уве
Original Assignee
БАСФ Акциенгезельшафт (DE)
Басф Акциенгезельшафт
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by БАСФ Акциенгезельшафт (DE), Басф Акциенгезельшафт filed Critical БАСФ Акциенгезельшафт (DE)
Publication of RU94044433A publication Critical patent/RU94044433A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
    • C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/54—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/46—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms
    • C07C323/47—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms to oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Abstract

FIELD: agriculture. SUBSTANCE: oxime ether fragment of desired mixture has formula Iwhere Ris C-C-alkyl; X is NO, CN, halide, C-C-alkyl, C-C-alkyl halide; n=0-3 or 1-5 if all substituents X represent halide; Ris C-C-alkoxy-C-C-alkyl, C-C-alkylthio-C-C-alkyl, at definite conditions substituted C-C-cycloalkyl, at definite conditions substituted C-C-cycloalkenyl, at definite conditions substituted 5-membered saturated heterocycle which contains 1 or 2 atoms of oxygen and/or sulfur, at definite conditions substituted 6- or 7-membered heterocycle having 1 or 2 adjacent atoms of oxygen and/or sulfur which may be saturated or single- or double unsaturated, at definite conditions substituted 5-membered heteroaromatic hydrocarbon containing 1-2 atoms of nitrogen and one atom of oxygen or of sulfur, phenyl or pyridyl, both of which may have additionally 1-3 substituents, namely: halide, NO,, CN, alkyl, alkoxy, alkylthio, alkyl halide, alkenyloxy, alkynyloxy and/or -NRRwhere Rrepresents H, alkyl, alkenyl or alkynyl and Rrepresents H, alkyl, alkenyl, alkynyl, acyl or at definite conditions substituted benzoyl. Mixture of optically active cyclohexene oxime ethers having R- and S-configuration together with acceptable in agriculture salts and esters of C-C-carboxylic acids and inorganic acids of compound having formula I is proposed as herbicide composition. Said mixture contains at least 75 mol % of isomers having R-configuration. EFFECT: improves quality of desired product, improves efficiency of method.

Claims (1)

Смеси из оптически активных простых циклогексеноноксимовых эфиров с R- и S-конфигурацией в оксимоэфирном фрагменте формулы I, а также применимые в сельском хозяйстве соли и сложные эфиры С1 -С10-карбоновых кислот и неорганических кислот соединений I при условии, что смеси содержат по крайней мере 75 мол.% изомеров с R-конфигурацией в оксимоэфирном фрагменте.Mixtures of optically active cyclohexenone oxime ethers with the R and S configuration in the oxime ester moiety of the formula I, as well as salts and esters of C 1 -C 10 carboxylic acids and inorganic acids of compounds I applicable in agriculture, provided that the mixtures contain at least 75 mol% of R-isomers in the oxime ester moiety.
RU94044433/04A 1992-02-13 1993-01-30 Mixture of optically active cyclohexene oxime ethers, method of their production and intermediate products for their production and usage thereof as herbicides RU94044433A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4204206A DE4204206A1 (en) 1992-02-13 1992-02-13 MIXTURES OF OPTICALLY ACTIVE CYCLOHEXENONE OXIMETHERS, PROCESSES AND INTERMEDIATE PRODUCTS FOR THEIR PREPARATION AND THEIR USE AS HERBICIDES
DEP4204206.2 1992-02-13

Publications (1)

Publication Number Publication Date
RU94044433A true RU94044433A (en) 1996-06-20

Family

ID=6451568

Family Applications (1)

Application Number Title Priority Date Filing Date
RU94044433/04A RU94044433A (en) 1992-02-13 1993-01-30 Mixture of optically active cyclohexene oxime ethers, method of their production and intermediate products for their production and usage thereof as herbicides

Country Status (11)

Country Link
EP (1) EP0625974A1 (en)
JP (1) JPH07505866A (en)
KR (1) KR950700271A (en)
BR (1) BR9305882A (en)
CA (1) CA2129121A1 (en)
DE (1) DE4204206A1 (en)
HU (1) HU216276B (en)
RU (1) RU94044433A (en)
TW (1) TW232646B (en)
WO (1) WO1993016062A1 (en)
ZA (1) ZA93970B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4244390A1 (en) * 1992-12-29 1994-06-30 Basf Ag Process for the preparation of oximino derivatives and new oximino derivatives
DE4403670A1 (en) * 1994-02-07 1995-09-07 Basf Ag 2-Aroylcyclohexanediones, process for their preparation and their use as herbicides or plant growth regulators
DE19510183A1 (en) * 1994-03-31 1995-10-05 Basf Ag New imino:alkyl-aminomethyl-cyclohexenone derivs.
DE4415887A1 (en) * 1994-05-05 1995-06-01 Basf Ag Prepn. of O-Phenoxy-oximes and hydroxyl-ammonium salts
HUP9900404A3 (en) * 1995-09-20 2000-01-28 Basf Ag Synergistic herbicidal mixtures containing cyclohexenone oxime ether
US6300281B1 (en) * 2000-07-03 2001-10-09 Valent U.S.A. Corporation Optically pure(−) clethodim, compositions and methods for controlling plant growth comprising the same
CN110483439B (en) * 2019-08-28 2022-12-30 郑州手性药物研究院有限公司 Method for synthesizing 6-aminomethyl-1, 1-dioxo-1, 2-benzothiazole-3-one
CN110483497B (en) * 2019-08-28 2022-12-30 郑州手性药物研究院有限公司 6-aminomethyl-1, 1-dioxo-1, 2-benzothiazol-3-one intermediate and synthetic method thereof
CN114105842A (en) * 2020-08-28 2022-03-01 郑州手性药物研究院有限公司 Cyclohexadiene oxime ether compound and application thereof
CN111205208B (en) * 2020-01-16 2021-12-17 郑州恒诚仪器耗材有限公司 Cyclohexane-1, 3-diketone compound and synthetic method and application thereof
WO2021143617A1 (en) * 2020-01-16 2021-07-22 郑州手性药物研究院有限公司 Cyclohexadiene oxime ether compound, synthesis method therefor and application thereof
CN116806829A (en) * 2020-04-10 2023-09-29 辽宁先达农业科学有限公司 Pesticide composition and application thereof and herbicide
CN112544621B (en) * 2020-04-13 2021-10-15 辽宁先达农业科学有限公司 Method for preparing 2- (4-chlorophenoxy) -propoxyamine
CN114591230A (en) * 2022-03-07 2022-06-07 沈阳万菱生物技术有限公司 Cyclohexenone compound, application thereof and pesticide herbicide
CN115417791B (en) * 2022-09-23 2023-10-27 郑州手性药物研究院有限公司 Oxime ether 1, 3-cyclohexanedione compound and synthetic method and application thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3036281A1 (en) * 1980-09-26 1982-05-13 Boehringer Mannheim Gmbh, 6800 Mannheim 0-SUBSTITUTED PETROLEUM ACID OXIMES, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AND MEDICINAL PRODUCTS CONTAINING THESE COMPOUNDS
US4647698A (en) * 1984-09-13 1987-03-03 Sandoz Ltd. Novel compositions
DE59102689D1 (en) * 1990-05-09 1994-10-06 Basf Ag Cyclohexenone oxime ether, process for their preparation and their use as herbicides.

Also Published As

Publication number Publication date
HU9402353D0 (en) 1994-11-28
JPH07505866A (en) 1995-06-29
BR9305882A (en) 1997-08-19
CA2129121A1 (en) 1993-08-19
DE4204206A1 (en) 1993-08-19
HU216276B (en) 1999-05-28
ZA93970B (en) 1994-08-12
HUT68901A (en) 1995-08-28
EP0625974A1 (en) 1994-11-30
WO1993016062A1 (en) 1993-08-19
TW232646B (en) 1994-10-21
KR950700271A (en) 1995-01-16

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