RU94006278A - METHOD OF HYDROXYCARBONYLATION OF LACTONES - Google Patents

METHOD OF HYDROXYCARBONYLATION OF LACTONES

Info

Publication number
RU94006278A
RU94006278A RU94006278/04A RU94006278A RU94006278A RU 94006278 A RU94006278 A RU 94006278A RU 94006278/04 A RU94006278/04 A RU 94006278/04A RU 94006278 A RU94006278 A RU 94006278A RU 94006278 A RU94006278 A RU 94006278A
Authority
RU
Russia
Prior art keywords
hydroxycarbonylation
lactones
carbon monoxide
water
promoter
Prior art date
Application number
RU94006278/04A
Other languages
Russian (ru)
Other versions
RU2117656C1 (en
Inventor
Дени Филипп
Патуа Карл
Перрон Робер
Original Assignee
Рон-Пуленк Шими
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9302483A external-priority patent/FR2701944B1/en
Application filed by Рон-Пуленк Шими filed Critical Рон-Пуленк Шими
Publication of RU94006278A publication Critical patent/RU94006278A/en
Application granted granted Critical
Publication of RU2117656C1 publication Critical patent/RU2117656C1/en

Links

Claims (1)

Настоящее изобретение относится к способу гидроксикарбонилирования лактонов, более конкретно - различных валеролактонов и их изомеров, путем введения во взаимодействие с монооксидом углерода и водой с целью получения соответствующей дикислоты. Способ состоит во введении во взаимодействие монооксида углерода и воды по крайней мере с одним лактоном с 5 С-атомами в присутствии эффективного количества иридиевого катализатора и иод- или бромсодержащего промотора, причем молярное соотношение промотор : иридий составляет 0,1 oC 20 : 1. Этот способ позволяет в особенности утилизовать при получении адипиновой кислоты гамма-валеролактон.The present invention relates to a method for hydroxycarbonylation of lactones, more specifically, various valerolactones and their isomers, by reacting with carbon monoxide and water to form the corresponding diacid. The method consists in introducing into the interaction of carbon monoxide and water with at least one lactone with 5 C-atoms in the presence of an effective amount of an iridium catalyst and an iodine or bromine-containing promoter, the promoter: iridium molar ratio being 0.1 o C 20: 1. This method makes it possible in particular to utilize gamma-valerolactone upon receipt of adipic acid.
RU94006278/04A 1993-02-26 1994-02-25 Hydroxycarbonylation of lactones RU2117656C1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9302483 1993-02-26
FR9302483A FR2701944B1 (en) 1993-02-26 1993-02-26 Process for the hydroxycarbonylation of lactones into aliphatic dicarboxylic acids.

Publications (2)

Publication Number Publication Date
RU94006278A true RU94006278A (en) 1995-09-27
RU2117656C1 RU2117656C1 (en) 1998-08-20

Family

ID=9444632

Family Applications (1)

Application Number Title Priority Date Filing Date
RU94006278/04A RU2117656C1 (en) 1993-02-26 1994-02-25 Hydroxycarbonylation of lactones

Country Status (18)

Country Link
EP (1) EP0612711B1 (en)
JP (1) JP2512386B2 (en)
KR (1) KR0133557B1 (en)
CN (1) CN1049648C (en)
BR (1) BR9400670A (en)
CA (1) CA2116502C (en)
CZ (1) CZ289016B6 (en)
DE (1) DE69400716T2 (en)
ES (1) ES2093501T3 (en)
FR (1) FR2701944B1 (en)
GR (1) GR3022119T3 (en)
MX (1) MX9401359A (en)
PL (1) PL174036B1 (en)
RU (1) RU2117656C1 (en)
SG (1) SG45344A1 (en)
SK (1) SK281749B6 (en)
TW (1) TW264468B (en)
UA (1) UA41274C2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5292944A (en) * 1993-06-29 1994-03-08 E. I. Du Pont De Nemours And Company Process for the preparation of adipic acid or pentenoic acid
US5710325A (en) * 1996-11-01 1998-01-20 E. I. Du Pont De Nemours And Company Manufacture of adipic acid
CN115445662B (en) * 2022-08-31 2023-08-15 迈奇化学股份有限公司 Catalyst for gamma-butyrolactone carbonylation and method for synthesizing glutaric acid from gamma-butyrolactone

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1941448A1 (en) * 1968-08-15 1970-04-23 Monsanto Co Process for the production of dicarboxylic acids
US5359137A (en) * 1989-04-26 1994-10-25 E. I. Du Pont De Nemours And Company Preparation of adipic acid from lactones

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