RU2768931C2 - Композиция гетерофазного полиолефина с улучшенными оптическими свойствами - Google Patents

Композиция гетерофазного полиолефина с улучшенными оптическими свойствами Download PDF

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RU2768931C2
RU2768931C2 RU2019125455A RU2019125455A RU2768931C2 RU 2768931 C2 RU2768931 C2 RU 2768931C2 RU 2019125455 A RU2019125455 A RU 2019125455A RU 2019125455 A RU2019125455 A RU 2019125455A RU 2768931 C2 RU2768931 C2 RU 2768931C2
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ethylene
heco
propylene copolymer
xcs
fraction
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RU2019125455A
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RU2019125455A (ru
RU2019125455A3 (es
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Джингбо Ванг
Маркус Гахлеитнер
Фридрих Бергер
Йоахим ФИЕБИГ
Маркку Вахтери
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Бореалис Аг
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05—Bimodal or multimodal molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/20—Activation energy or enthalpy
    • C—CHEMISTRY; METALLURGY
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    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26—Use as polymer for film forming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/24—Crystallisation aids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2314/00—Polymer mixtures characterised by way of preparation
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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
RU2019125455A 2017-01-30 2018-01-26 Композиция гетерофазного полиолефина с улучшенными оптическими свойствами RU2768931C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17153720.2 2017-01-30
EP17153720 2017-01-30
PCT/EP2018/051905 WO2018138235A1 (en) 2017-01-30 2018-01-26 Heterophasic polyolefin composition having improved optical properties

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Publication Number Publication Date
RU2019125455A RU2019125455A (ru) 2021-03-03
RU2019125455A3 RU2019125455A3 (es) 2021-03-03
RU2768931C2 true RU2768931C2 (ru) 2022-03-25

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US (1) US10752763B2 (es)
EP (1) EP3574025B1 (es)
KR (1) KR20190086577A (es)
CN (1) CN110177815B (es)
ES (1) ES2942332T3 (es)
RU (1) RU2768931C2 (es)
WO (1) WO2018138235A1 (es)

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Publication number Priority date Publication date Assignee Title
EP3722363A1 (en) * 2019-04-12 2020-10-14 Thai Polyethylene Co., Ltd. Impact copolymer polypropylene for thin-wall injection packaging
CN110438814A (zh) * 2019-07-26 2019-11-12 温多利遮阳材料（德州）股份有限公司 一种用于改善耐候性的特斯林纺织品涂层
US20230001674A1 (en) 2019-12-05 2023-01-05 Borealis Ag Multilayer film with improved properties
EP3650495A3 (en) 2020-02-14 2020-05-27 SABIC Global Technologies B.V. Film comprising heterophasic propylene copolymer composition
US20230071198A1 (en) 2020-02-14 2023-03-09 Sabic Global Technologies B.V. Film comprising heterophasic propylene copolymer composition
CN117597389A (zh) * 2021-06-14 2024-02-23 北欧化工公司 具有优异的光学性能和密封性能的多相丙烯乙烯共聚物组合物
CN116789884B (zh) * 2023-08-28 2024-01-09 万华化学集团股份有限公司 高透光率的乙烯/α-烯烃共聚物

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EP0887379B1 (en) * 1997-06-24 2004-12-22 Borealis Technology Oy Process and apparatus for preparing propylene homopolymers and copolymers
EP2145923A1 (en) * 2008-07-16 2010-01-20 Borealis AG Heterophasic polymer composition of high stiffness
RU2443729C2 (ru) * 2007-08-08 2012-02-27 Бореалис Текнолоджи Ой Стерилизуемая и ударопрочная полипропиленовая композиция
RU2478668C2 (ru) * 2008-08-06 2013-04-10 Бореалис Аг Состав на основе полипропилена с эластомерами на основе стирола
WO2016131907A1 (en) * 2015-02-20 2016-08-25 Borealis Ag Process for producing heterophasic copolymers of propylene

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US5204037A (en) 1991-01-25 1993-04-20 Idemitsu Petrochemical Co., Ltd. Process for production of polypropylene sheets or films
FI111845B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin homopolymeerien ja iskulujuudeltaan modifioitujen polymeerien valmistamiseksi
FI111846B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi
FI111847B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
FI974175A (fi) 1997-11-07 1999-05-08 Borealis As Menetelmä polypropeenin valmistamiseksi
FI980342A0 (fi) 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
IT1302123B1 (it) 1998-07-31 2000-07-31 Ennio Truono Dispositivo di pulizia automatica per catarifrangenti disposti lungostrade e autostrade
FI991057A0 (fi) 1999-05-07 1999-05-07 Borealis As Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
EP1236769A1 (en) * 2001-02-21 2002-09-04 Borealis Technology Oy Heterophasic propylene polymer
AU2002323878A1 (en) 2002-06-25 2004-01-06 Borealis Technology Oy Polyolefin with improved scratch resistance and process for producing the same
EP1484343A1 (en) 2003-06-06 2004-12-08 Universiteit Twente Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
EP2055739B1 (en) * 2007-11-02 2010-01-13 Borealis Technology Oy ß-nucleated Propylene Copolymer
EP2368938A1 (en) 2010-03-22 2011-09-28 Borealis AG Heterophasic polypropylene with excellent mechanical properties
ES2398654T3 (es) 2010-09-16 2013-03-20 Borealis Ag Material polímero rígido y de alto flujo con buenas propiedades de transparencia e impacto
WO2013079457A1 (en) 2011-11-29 2013-06-06 Borealis Ag Blow molding material
WO2013092620A1 (en) * 2011-12-23 2013-06-27 Borealis Ag Propylene copolymer for injection molded articles or films
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EP0887379B1 (en) * 1997-06-24 2004-12-22 Borealis Technology Oy Process and apparatus for preparing propylene homopolymers and copolymers
RU2443729C2 (ru) * 2007-08-08 2012-02-27 Бореалис Текнолоджи Ой Стерилизуемая и ударопрочная полипропиленовая композиция
EP2145923A1 (en) * 2008-07-16 2010-01-20 Borealis AG Heterophasic polymer composition of high stiffness
RU2478668C2 (ru) * 2008-08-06 2013-04-10 Бореалис Аг Состав на основе полипропилена с эластомерами на основе стирола
WO2016131907A1 (en) * 2015-02-20 2016-08-25 Borealis Ag Process for producing heterophasic copolymers of propylene

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ES2942332T3 (es) 2023-05-31
EP3574025A1 (en) 2019-12-04
US20190367715A1 (en) 2019-12-05
RU2019125455A (ru) 2021-03-03
US10752763B2 (en) 2020-08-25
CN110177815A (zh) 2019-08-27
BR112019010710A2 (pt) 2019-10-01
CN110177815B (zh) 2022-06-07
WO2018138235A1 (en) 2018-08-02
RU2019125455A3 (es) 2021-03-03
KR20190086577A (ko) 2019-07-22
EP3574025B1 (en) 2023-03-15

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