RU2018136229A - Гербициды - Google Patents
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- RU2018136229A RU2018136229A RU2018136229A RU2018136229A RU2018136229A RU 2018136229 A RU2018136229 A RU 2018136229A RU 2018136229 A RU2018136229 A RU 2018136229A RU 2018136229 A RU2018136229 A RU 2018136229A RU 2018136229 A RU2018136229 A RU 2018136229A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
- C07D213/85—Nitriles in position 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyridine Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Claims (41)
1. Соединение формулы (I)
или его соль или N-оксид, где
X1 представляет собой N или CR1;
R1 выбран из группы, состоящей из водорода, галогена, циано, С1-С6алкила, С3-С6циклоалкила, С2-С6алкенила, С2-С6алкинила, C1-С6алкокси, -С(О)ОС1-С6алкила, -S(O)pC1-С6алкила, NR6R7, C1-С6галогеналкокси и С1-С6галогеналкила;
R2 выбран из группы, состоящей из галогена, циано, нитро, C1-С6алкила, С1-С6галогеналкила, С2-С6алкенила, С2-С6алкинила, С3-С6циклоалкила, -С(O)ОС1-С6алкила, -S(O)р(С1-С6алкил), C1-С6алкокси и C1-С6галогеналкокси;
R3 представляет собой -C(O)R9;
R4 выбран из группы, состоящей из водорода, C1-С6алкила, С1-С6галогеналкила, С3-С6алкенила, С3-С6алкинила, СrалкоксиCsалкила, -СrалкоксиСsгалогеналкила, СrалкоксиСsтиоалкила, -C(O)R9 и -(CRaRb)qR5;
каждый Ra независимо представляет собой водород или C1-С2алкил;
каждый Rb независимо представляет собой водород или C1-С2алкил;
Rc представляет собой водород или С1-С4алкил;
R5 представляет собой -С(O)ОС1-С6алкил, -С3-С6циклоалкил, циано, -NR6R7, -C(O)NRaRb, -S(O)p(R11)n, -арил или -гетероарил, при этом указанные арил и гетероарил необязательно замещены 1-3 независимыми R8;
R6 и R7 независимо выбраны из группы, состоящей из водорода и С1-С6алкила;
каждый R8 независимо выбран из группы, состоящей из галогена, С1-С6алкила и С1-С6алкокси-, C1-С6галогеналкила, C1-С6галогеналкокси-, циано и S(O)Р(С1-C6алкил);
каждый R9 независимо выбран из группы, состоящей из водорода, C1-С6алкила, СrалкоксиCsалкила, C1-С6галогеналкила,
СrалкоксиCsгалогеналкила, С2-С6алкенила, С2-С6алкинила и -(CRaRb)qR10;
или R4 и R9 вместе с атомами, к которым они присоединены, образуют 5-7-членную кольцевую систему, содержащую 1-3 гетероатома, при этом по меньшей мере один гетероатом представляет собой N, и любой дополнительный гетероатом независимо выбран из S, О и N;
R10 представляет собой -C(O)ORc, -OC(O)Rc, -С3-С6циклоалкил или -арильное, -арилокси-, -гетероарильное, -гетероарилокси- или -гетероциклильное кольцо, при этом указанное кольцо необязательно замещено 1-3 независимыми R8;
каждый n независимо равняется 0 или 1;
p равняется 0, 1 или 2;
каждый q независимо равняется 0, 1, 2, 3, 4, 5 или 6;
r равняется 1, 2, 3, 4 или 5;
s равняется 1, 2, 3, 4 или 5, и сумма r+s равна 6 или меньше; и
R11 представляет собой C1-С6алкил.
2. Соединение формулы (I) по п. 1, где X1 представляет собой N.
3. Соединение формулы (I) по п. 1, где X1 представляет собой CR1, и R1 представляет собой галоген или циано.
4. Соединение формулы (I) по любому из предыдущих пунктов, где R2 представляет собой галоген, циано, C1-С6алкил или C1-С6галогеналкил.
5. Соединение формулы (I) по любому из предыдущих пунктов, где в R3 R9 представляет собой C1-С6алкил, C1-С3галогеналкил, C1-С3алкоксиС1-С3алкил или -(CRaRb)qR10.
6. Соединение формулы (I) по п. 5, где R10 представляет собой -C(O)ORc, -OC(O)Rc, циклопропил, циклобутил, циклопентил, циклогексил или кольцевую систему, выбранную из фенила, фенокси, пиридинила, пиримидинила, тиазолила и тиофенила, при этом указанная кольцевая система необязательно замещена 1-3 независимыми R8.
7. Соединение формулы (I) по любому из предыдущих пунктов, где R4 выбран из группы, состоящей из водорода, С1-С4алкила, С3-С6алкенила, СrалкоксиCsалкила, СrалкилтиоCsалкила, С3-С6алкинила, С1-С3галогеналкила, СrалкоксиCsгалогеналкила, -C(O)R9 и -(CRaRb)qR5.
8. Соединение формулы (I) по п. 7, где R4 представляет собой -C(O)R9, и указанный R9 представляет собой C1-С3алкил, С2-С4алкенил или -(CRaRb)qR10.
9. Соединение формулы (I) по п. 7, где R4 представляет собой -(CRaRb)qR5, и при этом в R4
q равняется 1, 2 или 3;
Ra и Rb независимо представляют собой водород, метил или этил; и
R5 представляет собой -C(O)NRaRb, -NR6R7, циано, -С3-С6циклоалкил, -арил или -гетероарил, при этом указанные арил и гетероарил необязательно замещены 1-3 независимыми R8.
10. Соединение формулы (I) по любому из пп. 1-4, где R4 и R9 вместе с атомами, к которым они присоединены, образуют 5-7-членную кольцевую систему, содержащую 1-3 гетероатома, при этом по меньшей мере один гетероатом представляет собой N, и любой дополнительный гетероатом независимо выбран из S, О и N.
11. Гербицидная композиция, содержащая гербицидно эффективное количество соединения формулы (I) по любому из предыдущих пунктов и приемлемое с точки зрения сельского хозяйства вспомогательное средство для составления.
12. Гербицидная композиция по п. 11, дополнительно содержащая по меньшей мере один дополнительный пестицид.
13. Гербицидная композиция по п. 12, где дополнительный пестицид представляет собой гербицид или антидот гербицида.
14. Способ контроля сорняков в месте произрастания, предусматривающий применение к месту произрастания достаточного для контроля сорняков количества соединения по любому из пп. 1-10 или достаточного для контроля сорняков количества композиции по любому из пп. 11-14.
15. Применение соединения формулы (I) по любому из пп. 1-10 в качестве гербицида.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1604970.2A GB201604970D0 (en) | 2016-03-23 | 2016-03-23 | Improvements in or relating to organic compounds |
GB1604970.2 | 2016-03-23 | ||
PCT/EP2017/056291 WO2017162524A1 (en) | 2016-03-23 | 2017-03-16 | Herbicides |
Publications (3)
Publication Number | Publication Date |
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RU2018136229A true RU2018136229A (ru) | 2020-04-23 |
RU2018136229A3 RU2018136229A3 (ru) | 2020-04-30 |
RU2762575C2 RU2762575C2 (ru) | 2021-12-21 |
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RU2018136229A RU2762575C2 (ru) | 2016-03-23 | 2017-03-16 | Гербициды |
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US (2) | US11230538B2 (ru) |
EP (2) | EP3433245B1 (ru) |
JP (1) | JP7171437B2 (ru) |
KR (1) | KR102423205B1 (ru) |
CN (1) | CN108884069B (ru) |
AR (1) | AR107953A1 (ru) |
AU (1) | AU2017239002B2 (ru) |
BR (2) | BR112018069394B1 (ru) |
CA (1) | CA3016207A1 (ru) |
DK (1) | DK3433245T3 (ru) |
ES (1) | ES2921649T3 (ru) |
GB (1) | GB201604970D0 (ru) |
HU (1) | HUE059462T2 (ru) |
MY (1) | MY197968A (ru) |
PL (1) | PL3433245T3 (ru) |
RS (1) | RS63363B1 (ru) |
RU (1) | RU2762575C2 (ru) |
UA (1) | UA124061C2 (ru) |
UY (1) | UY37162A (ru) |
WO (1) | WO2017162524A1 (ru) |
ZA (1) | ZA201805795B (ru) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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GB201604970D0 (en) * | 2016-03-23 | 2016-05-04 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
US20190327969A1 (en) * | 2016-03-23 | 2019-10-31 | Syngenta Participations Ag | Herbicides |
JP7240319B2 (ja) | 2017-01-23 | 2023-03-15 | レヴォリューション・メディスンズ,インコーポレイテッド | アロステリックshp2阻害剤としての二環式化合物 |
GB201715413D0 (en) | 2017-09-22 | 2017-11-08 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
GB201715323D0 (en) * | 2017-09-22 | 2017-11-08 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
TW201930292A (zh) * | 2017-10-12 | 2019-08-01 | 美商銳新醫藥公司 | 作為變構shp2抑制劑的吡啶、吡嗪和三嗪化合物 |
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ES2054088T3 (es) | 1988-10-20 | 1994-08-01 | Ciba Geigy Ag | Sulfamoilfenilureas. |
EP0374753A3 (de) | 1988-12-19 | 1991-05-29 | American Cyanamid Company | Insektizide Toxine, Gene, die diese Toxine kodieren, Antikörper, die sie binden, sowie transgene Pflanzenzellen und transgene Pflanzen, die diese Toxine exprimieren |
EP0427529B1 (en) | 1989-11-07 | 1995-04-19 | Pioneer Hi-Bred International, Inc. | Larvicidal lectins and plant insect resistance based thereon |
US5201938A (en) * | 1991-07-19 | 1993-04-13 | Dowelanco | N-pyrazolyl-1,2,4-triazolo[1,5-c]pyrimidine-2-sulfonamide herbicides |
UA48104C2 (ru) | 1991-10-04 | 2002-08-15 | Новартіс Аг | Фрагмент днк, содержащий последовательность, которая кодирует инсектицидный протеин, оптимизированную для кукурузы, фрагмент днк, обеспечивающий направленную желательную для сердцевины стебля экспрессию связанного с ней структурного гена в растении, фрагмент днк, обеспечивающий специфическую для пыльцы экспрессию связанного с ней структурного гена в растении, рекомбинантная молекула днк, способ получения оптимизированной для кукурузы кодирующей последовательности инсектицидного протеина, способ защиты растений кукурузы по меньшей мере от одного насекомого-вредителя |
US5530195A (en) | 1994-06-10 | 1996-06-25 | Ciba-Geigy Corporation | Bacillus thuringiensis gene encoding a toxin active against insects |
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2016
- 2016-03-23 GB GBGB1604970.2A patent/GB201604970D0/en not_active Ceased
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2017
- 2017-03-16 PL PL17710964.2T patent/PL3433245T3/pl unknown
- 2017-03-16 KR KR1020187029394A patent/KR102423205B1/ko active IP Right Grant
- 2017-03-16 RS RS20220643A patent/RS63363B1/sr unknown
- 2017-03-16 BR BR112018069394-4A patent/BR112018069394B1/pt active IP Right Grant
- 2017-03-16 EP EP17710964.2A patent/EP3433245B1/en active Active
- 2017-03-16 WO PCT/EP2017/056291 patent/WO2017162524A1/en active Application Filing
- 2017-03-16 MY MYPI2018001511A patent/MY197968A/en unknown
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- 2017-03-16 CA CA3016207A patent/CA3016207A1/en active Pending
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- 2017-03-16 RU RU2018136229A patent/RU2762575C2/ru active
- 2017-03-16 UA UAA201810138A patent/UA124061C2/uk unknown
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- 2017-03-16 HU HUE17710964A patent/HUE059462T2/hu unknown
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2018
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PL3433245T3 (pl) | 2022-08-01 |
RU2762575C2 (ru) | 2021-12-21 |
US20190330179A1 (en) | 2019-10-31 |
ZA201805795B (en) | 2019-06-26 |
AU2017239002A1 (en) | 2018-09-13 |
RU2018136229A3 (ru) | 2020-04-30 |
GB201604970D0 (en) | 2016-05-04 |
US20210130319A1 (en) | 2021-05-06 |
JP2019514848A (ja) | 2019-06-06 |
CN108884069B (zh) | 2021-04-27 |
ES2921649T3 (es) | 2022-08-30 |
BR112018069394A2 (pt) | 2019-01-22 |
RS63363B1 (sr) | 2022-07-29 |
MY197968A (en) | 2023-07-25 |
AR107953A1 (es) | 2018-07-04 |
EP3433245B1 (en) | 2022-04-27 |
AU2017239002B2 (en) | 2021-07-29 |
BR122022000691B1 (pt) | 2023-02-23 |
WO2017162524A1 (en) | 2017-09-28 |
CN108884069A (zh) | 2018-11-23 |
KR102423205B1 (ko) | 2022-07-19 |
US11230538B2 (en) | 2022-01-25 |
CA3016207A1 (en) | 2017-09-28 |
BR112018069394B1 (pt) | 2022-08-02 |
UY37162A (es) | 2017-10-31 |
JP7171437B2 (ja) | 2022-11-15 |
KR20180128004A (ko) | 2018-11-30 |
DK3433245T3 (da) | 2022-07-11 |
EP3868749A1 (en) | 2021-08-25 |
UA124061C2 (uk) | 2021-07-14 |
EP3433245A1 (en) | 2019-01-30 |
HUE059462T2 (hu) | 2022-11-28 |
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