RU2016106574A - Изоцианатно-эпоксидная вспениваемая система - Google Patents
Изоцианатно-эпоксидная вспениваемая система Download PDFInfo
- Publication number
- RU2016106574A RU2016106574A RU2016106574A RU2016106574A RU2016106574A RU 2016106574 A RU2016106574 A RU 2016106574A RU 2016106574 A RU2016106574 A RU 2016106574A RU 2016106574 A RU2016106574 A RU 2016106574A RU 2016106574 A RU2016106574 A RU 2016106574A
- Authority
- RU
- Russia
- Prior art keywords
- paragraphs
- polyepoxide
- group
- hydrogen atoms
- polyisocyanate
- Prior art date
Links
- 239000004593 Epoxy Substances 0.000 title 1
- 238000005187 foaming Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 13
- 229920000647 polyepoxide Polymers 0.000 claims 10
- 229920001228 polyisocyanate Polymers 0.000 claims 9
- 239000005056 polyisocyanate Substances 0.000 claims 9
- 230000002378 acidificating effect Effects 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 8
- 239000006260 foam Substances 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 7
- 125000001931 aliphatic group Chemical group 0.000 claims 4
- -1 bisphenol-A epoxides Chemical class 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- 230000003993 interaction Effects 0.000 claims 3
- 229920005862 polyol Polymers 0.000 claims 3
- 150000003077 polyols Chemical class 0.000 claims 3
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N Bisphenol F Natural products C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims 2
- 239000002879 Lewis base Substances 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229940106691 bisphenol a Drugs 0.000 claims 2
- 150000007527 lewis bases Chemical class 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 2
- 229920000768 polyamine Polymers 0.000 claims 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 claims 1
- 239000011810 insulating material Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims 1
- KMJFBHAJTOLWGZ-UHFFFAOYSA-N n,n-dimethyl-1-(4-methylpiperazin-1-yl)methanamine Chemical compound CN(C)CN1CCN(C)CC1 KMJFBHAJTOLWGZ-UHFFFAOYSA-N 0.000 claims 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920005906 polyester polyol Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 238000005057 refrigeration Methods 0.000 claims 1
- 150000003512 tertiary amines Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/003—Polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
- C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
- C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/58—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Claims (17)
1. Способ получения жесткого пеноматериала, включающий в себя взаимодействие по меньшей мере одного полиизоцианата со смесью, содержащей по меньшей мере один полиэпоксид, воду и по меньшей мере одно дополнительное соединение с кислотными атомами водорода, причем это взаимодействие осуществляется в присутствии не содержащего металлов основания Льюиса, имеющего по меньшей мере один атом азота,
причем катализатор выбирают из группы, состоящей из 1,8-диазабицикло-5,4,0-ундецен-7-ена, N-метил-N’-(диметиламино-метил)пиперазина, пентаметилдиэтилентриамина, метилимидазола и их смесей и их производных.
2. Способ по п. 1, причем причем по меньшей мере одно дополнительное соединение с кислотными атомами водорода выбирают из группы, состоящей из полиолов и полиаминов.
3. Способ по одному из пп. 1 или 2, причем полиэпоксид используют в количестве в диапазоне от 5 до 70% масс., в пересчете на сумму из использованного полиэпоксида и по меньшей мере одного дополнительного соединения с кислотными атомами водорода.
4. Способ по одному из пп. 1 или 2, причем катализатор представляет собой третичный амин.
5. Способ по одному из пп. 1 или 2, причем катализатор выбирают из группы, состоящей из 1,8-диазабицикло-5,4,0-ундецен-7-ена и его производных.
6. Способ по одному из пп. 1 или 2, причем катализатор используют в количестве от 0,01 до 2% масс., в пересчете на сумму использованного полиизоцианата и смеси, содержащей по меньшей мере один полиэпоксид, воду и по меньшей мере одно дополнительное соединение с кислотными атомами водорода.
7. Способ по одному из пп. 1 или 2, причем реакция по меньшей мере одного полиизоцианата со смесью, содержащей по меньшей мере один полиэпоксид, воду и по меньшей мере одно дополнительное соединение с кислотными атомами водорода, начинается при температуре <100°C.
8. Способ по одному из пп. 1 или 2, причем по меньшей мере одно дополнительное соединение с кислотными атомами водорода выбирают из группы, состоящей из простых полиэфирполиолов, сложных полиэфирполиолов, поликарбонатполиолов или полиаминов.
9. Способ по одному из пп. 1 или 2, причем по меньшей мере один полиэпоксид выбирают из группы, состоящей из эпоксидов бисфенола-А, эпоксидов бисфенола-F, их производных, алифатических ди- или триэпоксидов и смесей из двух или более из них.
10. Способ по одному из пп. 1 или 2, причем по меньшей мере один полиизоцианат выбирают из группы, состоящей из ароматических, арилалифатических и алифатических полиизоцианатов.
11. Способ по одному из пп. 1 или 2, причем по меньшей мере один полиизоцианат представляет собой форполимер с содержанием NCO-групп от 6 до 30%.
12. Жесткий пеноматериал, который может получаться или полученный при помощи способа, включающего в себя взаимодействие по меньшей мере одного полиизоцианата со смесью, содержащей по меньшей мере один полиэпоксид, воду и по меньшей мере одно дополнительное соединение с кислотными атомами водорода, причем взаимодействие происходит в присутствии не содержащего металлов основания Льюиса, имеющего по меньшей мере один атом азота.
13. Жесткий пеноматериал по п. 12, причем полиэпоксид используют в количестве в диапазоне от 5 до 70% масс., в пересчете на сумму из использованного полиэпоксида и по меньшей мере одного дополнительного соединения с кислотными атомами водорода.
14. Жесткий пеноматериал по п. 12 или 13, причем по меньшей мере один полиэпоксид выбирают из группы, состоящей из эпоксидов бисфенола-А, эпоксидов бисфенола-F, их производных, алифатических ди- или триэпоксидов и смесей из двух или более из них.
15. Жесткий пеноматериал по п. 12 или 13, причем по меньшей мере один полиизоцианат выбирают из группы, состоящей из ароматических, арилалифатических и алифатических полиизоцианатов.
16. Применение жесткого пеноматериала, который может получаться или получен по способу согласно по одному из пп. 1-11, или жесткого пеноматериала по одному из пп. 12-15, для изготовления изолирующих материалов, вакуумных изоляционных панелей, холодильных аппаратов, строительных элементов, лопастей винтов ветроэнергетических установок или элементов для строительства лодок и автомобилей.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13178203 | 2013-07-26 | ||
| EP13178203.9 | 2013-07-26 | ||
| PCT/EP2014/066044 WO2015011269A1 (de) | 2013-07-26 | 2014-07-25 | Isocyanat-epoxy-schaumsystem |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2016106574A true RU2016106574A (ru) | 2017-08-31 |
| RU2667523C2 RU2667523C2 (ru) | 2018-09-21 |
Family
ID=48874900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2016106574A RU2667523C2 (ru) | 2013-07-26 | 2014-07-25 | Изоцианатно-эпоксидная вспениваемая система |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10907021B2 (ru) |
| EP (1) | EP3024861B1 (ru) |
| JP (1) | JP6639387B2 (ru) |
| KR (1) | KR102228967B1 (ru) |
| CN (1) | CN105579483B (ru) |
| CA (1) | CA2919162C (ru) |
| DK (1) | DK3024861T3 (ru) |
| RU (1) | RU2667523C2 (ru) |
| WO (1) | WO2015011269A1 (ru) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2803684A1 (de) * | 2013-05-13 | 2014-11-19 | Basf Se | Isocyanat-Epoxid-Hybridharze |
| BR112016024976B1 (pt) | 2014-04-30 | 2022-02-01 | Basf Se | Artigo moldado revestido contendo grânulos espumados de poliuretano com revestimento de poliuretano, processo para produzir dito artigo moldado revestido e método de uso do dito artigo moldado revestido |
| MX2017011683A (es) | 2015-03-11 | 2018-04-11 | Basf Se | Metodo para producir poliuretanos compactos con mayor estabilidad hidrolitica. |
| WO2019218372A1 (en) | 2018-05-18 | 2019-11-21 | Dow Global Technologies Llc | A polyisocyanate component, a polyurethane foaming system and an article made therefrom |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1104394A (en) * | 1964-04-08 | 1968-02-28 | Gen Tire & Rubber Co | The preparation of polyisocyanurates |
| FR1441565A (fr) * | 1964-04-08 | 1966-06-10 | Gen Tire & Rubber Co | Polymères d'isocyanurates et leur préparation |
| US3313747A (en) * | 1964-10-29 | 1967-04-11 | Baker Chem Co J T | Polymers prepared from isocyanateoxazolidinones |
| JPS5183697A (ru) * | 1975-01-20 | 1976-07-22 | Hitachi Ltd | |
| JPS5723620A (en) * | 1980-07-18 | 1982-02-06 | Hitachi Ltd | Thermosetting resin composition |
| JPS5998120A (ja) * | 1982-11-29 | 1984-06-06 | Nippon Polyurethan Kogyo Kk | ポリイソシアネ−ト化合物からの発泡体の製造法 |
| DE3323122A1 (de) | 1983-06-27 | 1985-05-23 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur herstellung von reaktionsharzformstoffen |
| DE3600764A1 (de) | 1986-01-14 | 1987-07-16 | Bayer Ag | Waermehaertbare reaktionsharzgemische und ein verfahren zur herstellung von formkoerpern unter verwendung dieser gemische |
| US4699931A (en) | 1986-04-25 | 1987-10-13 | Olin Corporation | Oxazolidone-modified isocyanurate foams and a composition and method for their production |
| DE3938062A1 (de) * | 1989-11-16 | 1991-05-23 | Bayer Ag | Hochtemperaturbestaendige schaumstoffe |
| DE3942890A1 (de) * | 1989-12-23 | 1991-06-27 | Bayer Ag | Verfahren zur herstellung von kunststoff-formteilen |
| DE4104199A1 (de) * | 1991-02-12 | 1992-08-13 | Basf Ag | Verfahren zur herstellung von polyurethan-elastomeren und hierfuer geeignete mischungen aus polyoxybutylen-polyoxyalkylen-glykolen und glycidylverbindungen |
| US5530035A (en) * | 1994-06-15 | 1996-06-25 | General Electric Company | Method of preparing polyurethane foam of low thermal conductivity |
| CN1134474C (zh) * | 1996-11-04 | 2004-01-14 | 亨茨曼Ici化学品有限公司 | 硬质聚氨基甲酸酯发泡体 |
| DE602004009618T2 (de) * | 2004-05-28 | 2008-07-24 | Albemarle Corp. | Flammwidrige polyurethane und additive dafür |
| JP2006153951A (ja) | 2004-11-25 | 2006-06-15 | Canon Chemicals Inc | 画像形成装置用部材 |
| JP5129430B2 (ja) * | 2004-12-17 | 2013-01-30 | 住化バイエルウレタン株式会社 | ポリウレタンフォーム成形品の製造方法 |
| JP5240600B2 (ja) * | 2007-09-27 | 2013-07-17 | アキレス株式会社 | 発泡合成樹脂の製造装置およびその製造方法 |
| CA2698796A1 (en) * | 2007-10-05 | 2009-04-09 | Dow Global Technologies Inc. | Isocyanate modified epoxy resin and epoxy powder coating composition thereof |
| JP2009237465A (ja) | 2008-03-28 | 2009-10-15 | Canon Chemicals Inc | トナー供給ローラ |
| JP5407544B2 (ja) * | 2008-05-20 | 2014-02-05 | 旭硝子株式会社 | ポリマー分散ポリオールの製造方法 |
| JP5478877B2 (ja) * | 2008-12-26 | 2014-04-23 | ニッタ・ハース株式会社 | 研磨パッド |
| JP5270520B2 (ja) | 2009-11-25 | 2013-08-21 | 旭有機材工業株式会社 | ポリウレタンフォーム用発泡性組成物及びポリウレタンフォーム |
| KR20130041182A (ko) * | 2010-07-08 | 2013-04-24 | 바스프 에스이 | 경질 폴리우레탄 발포체 |
| KR20120128662A (ko) * | 2010-10-22 | 2012-11-27 | 남경 버신 폴리우레탄 컴퍼니 리미티드 | 일종의 저밀도 경질 폴리우레탄 폼을 제조하기 위한 빠른 반응 조합물 |
| RU2560552C2 (ru) * | 2011-06-21 | 2015-08-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Пенополимер на основе изоцианата с улучшенными термоизоляционными свойствами |
| CN103059242B (zh) * | 2013-01-09 | 2015-02-11 | 江苏科泰绝热新材料有限公司 | 一种环氧树脂改性的聚异氰脲酸酯耐高温硬质泡沫塑料及其制备方法 |
-
2014
- 2014-07-25 CA CA2919162A patent/CA2919162C/en active Active
- 2014-07-25 CN CN201480053244.4A patent/CN105579483B/zh active Active
- 2014-07-25 KR KR1020167005260A patent/KR102228967B1/ko active IP Right Grant
- 2014-07-25 US US14/908,079 patent/US10907021B2/en active Active
- 2014-07-25 EP EP14744095.2A patent/EP3024861B1/de active Active
- 2014-07-25 RU RU2016106574A patent/RU2667523C2/ru active
- 2014-07-25 WO PCT/EP2014/066044 patent/WO2015011269A1/de active Application Filing
- 2014-07-25 DK DK14744095.2T patent/DK3024861T3/da active
- 2014-07-25 JP JP2016528547A patent/JP6639387B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160038016A (ko) | 2016-04-06 |
| CA2919162C (en) | 2021-08-10 |
| WO2015011269A1 (de) | 2015-01-29 |
| KR102228967B1 (ko) | 2021-03-17 |
| JP2016525605A (ja) | 2016-08-25 |
| CN105579483A (zh) | 2016-05-11 |
| EP3024861A1 (de) | 2016-06-01 |
| DK3024861T3 (da) | 2021-05-03 |
| US20160159999A1 (en) | 2016-06-09 |
| US10907021B2 (en) | 2021-02-02 |
| JP6639387B2 (ja) | 2020-02-05 |
| CN105579483B (zh) | 2021-02-05 |
| EP3024861B1 (de) | 2021-02-10 |
| CA2919162A1 (en) | 2015-01-29 |
| RU2667523C2 (ru) | 2018-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Blattmann et al. | Isocyanate‐and phosgene‐free routes to polyfunctional cyclic carbonates and green polyurethanes by fixation of carbon dioxide | |
| RU2016106574A (ru) | Изоцианатно-эпоксидная вспениваемая система | |
| TWI579329B (zh) | 用於複合材料之掺合物 | |
| RU2011147117A (ru) | Полиизоцианатная композиция | |
| PT87200B (pt) | Processo para a preparacao de componentes endurecedores para resinas sinteticas | |
| CN103013322B (zh) | 一种环氧非异氰酸酯聚氨酯重防腐涂料制备方法 | |
| CN105683316A (zh) | 用于溢流涂布电子电路组件的配制的树脂组合物 | |
| BR112012015178B1 (pt) | "mistura de eteramina, processos para a preparação de uma mistura de eteramina, e para a produção de um sistema de resina epóxi e de uma poliuréia,e,poliuréia" | |
| MY163276A (en) | Adhesive agent composition and laminated body | |
| US20180258215A1 (en) | Organic aerogels based on isocyanate and cyclic ether polymer networks | |
| EP3199569A1 (en) | Non isocyanate polyurethane foams | |
| CN108659689A (zh) | 一种山梨醇基非异氰酸酯聚氨酯涂料及其制备方法 | |
| CN108675970A (zh) | 一种环氧树脂发泡剂，环氧树脂组合物及其制备和用途 | |
| CN102898611B (zh) | 一种有机硅聚氨酯胶粘剂的制备方法 | |
| US10513578B2 (en) | Etheramines and their use as curatives or intermediates for polymer synthesis | |
| RU2015136364A (ru) | 2,2',6,6'-тетраметил-4,4'-метиленбис(циклогексиламин) в качестве отвердителя для эпоксидных смол | |
| US10822519B2 (en) | Method for producing compact polyurethanes with improved hydrolytic stability | |
| EP2542610B1 (en) | Novel curing agents | |
| BR112012014496B1 (pt) | processos para preparar uma mistura de eteramina, e para produzir um sistema de resina epóxi curado | |
| EP3058007B1 (en) | Etheramines with enhanced thermal stability and their use as curatives or intermediates for polymer synthesis | |
| CN109749045A (zh) | 一种三(2-羟乙基)异氰尿酸酯改性的桐油基多元醇及其制备方法和应用 | |
| JP5279036B2 (ja) | 新規エポキシ樹脂、その製造方法、エポキシ樹脂組成物及び硬化物 | |
| US11718725B2 (en) | Method of forming foam material | |
| Stroganov | Epoxy-foam adhesives | |
| RU2003127012A (ru) | Композиция на основе модифицированной эпоксидной смолы |