RU2013114186A - Способ производства углеродсодержащего композита - Google Patents
Способ производства углеродсодержащего композита Download PDFInfo
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- RU2013114186A RU2013114186A RU2013114186/04A RU2013114186A RU2013114186A RU 2013114186 A RU2013114186 A RU 2013114186A RU 2013114186/04 A RU2013114186/04 A RU 2013114186/04A RU 2013114186 A RU2013114186 A RU 2013114186A RU 2013114186 A RU2013114186 A RU 2013114186A
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- Prior art keywords
- composite
- sulfur
- organic compound
- carried out
- nitrogen
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- 239000002131 composite material Substances 0.000 title claims abstract 9
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 claims abstract 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910052751 metal Inorganic materials 0.000 claims abstract 6
- 239000002184 metal Substances 0.000 claims abstract 6
- 150000002894 organic compounds Chemical class 0.000 claims abstract 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 6
- 239000011593 sulfur Substances 0.000 claims abstract 6
- 239000007789 gas Substances 0.000 claims abstract 4
- 229910021645 metal ion Inorganic materials 0.000 claims abstract 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 4
- 230000001681 protective effect Effects 0.000 claims abstract 4
- 238000000197 pyrolysis Methods 0.000 claims abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000002378 acidificating effect Effects 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims abstract 2
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- 238000005470 impregnation Methods 0.000 claims abstract 2
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims abstract 2
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract 2
- 150000004706 metal oxides Chemical class 0.000 claims abstract 2
- 150000002739 metals Chemical class 0.000 claims abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 2
- 125000002524 organometallic group Chemical group 0.000 claims abstract 2
- 239000007787 solid Substances 0.000 claims abstract 2
- 150000000000 tetracarboxylic acids Chemical class 0.000 claims abstract 2
- 229910052719 titanium Inorganic materials 0.000 claims abstract 2
- 150000003628 tricarboxylic acids Chemical class 0.000 claims abstract 2
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 claims abstract 2
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims 2
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000013270 controlled release Methods 0.000 claims 1
- 238000003860 storage Methods 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00853—Uses not provided for elsewhere in C04B2111/00 in electrochemical cells or batteries, e.g. fuel cells
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
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- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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- Carbon And Carbon Compounds (AREA)
Abstract
1. Способ производства углеродсодержащего композита, который включает стадию(а) пиролиза пористой металлоорганической каркасной структуры, содержащей по меньшей мере одно по меньшей мере бидентатное органическое соединение, координированное с по меньшей мере одним ионом металла, в защитной газовой атмосфере, где по меньшей мере одно по меньшей мере бидентатное органическое соединение является свободным от азота.2. Способ по п.1, в котором пиролиз проводят при, по меньшей мере, 500°C.3. Способ по п.1 или 2, в котором защитная газовая атмосфера содержит азот.4. Способ по п.1 или 2, в котором по меньшей мере один ион металла представляет собой ион, выбранный из группы металлов, состоящей из Mg, Al, Zr, Ti, V, Cr, Mo, Fe, Co, Cu, Mi и Zn.5. Способ по п.1 или 2, в котором свободное от азота по меньшей мере одно по меньшей мере бидентатное органическое соединение является производным дикарбоновой, трикарбоновой или тетракарбоновой кислоты.6. Способ по п.1, который включает дальнейшую стадию(б) по меньшей мере частичного удаления одного или более металлических компонентов из композита, полученного на стадии (а).7. Способ по п.6, в котором один или более металлических компонентов содержит по меньшей мере один оксид металла.8. Способ по п.6 или 7, в котором по меньшей мере частичное удаление проводят промыванием посредством щелочной или кислотной жидкости.9. Способ по п.1 или 6, который включает дальнейшую стадию(в) импрегнирования композита, полученного на стадии (а) или (б), серой.10. Способ по п.9, в котором импрегнирование проводят смешиванием и последующим нагреванием.11. Способ по п.9 или 10, в котором серу используют в виде твердого вещества или в растворе.12. Пр
Claims (14)
1. Способ производства углеродсодержащего композита, который включает стадию
(а) пиролиза пористой металлоорганической каркасной структуры, содержащей по меньшей мере одно по меньшей мере бидентатное органическое соединение, координированное с по меньшей мере одним ионом металла, в защитной газовой атмосфере, где по меньшей мере одно по меньшей мере бидентатное органическое соединение является свободным от азота.
2. Способ по п.1, в котором пиролиз проводят при, по меньшей мере, 500°C.
3. Способ по п.1 или 2, в котором защитная газовая атмосфера содержит азот.
4. Способ по п.1 или 2, в котором по меньшей мере один ион металла представляет собой ион, выбранный из группы металлов, состоящей из Mg, Al, Zr, Ti, V, Cr, Mo, Fe, Co, Cu, Mi и Zn.
5. Способ по п.1 или 2, в котором свободное от азота по меньшей мере одно по меньшей мере бидентатное органическое соединение является производным дикарбоновой, трикарбоновой или тетракарбоновой кислоты.
6. Способ по п.1, который включает дальнейшую стадию
(б) по меньшей мере частичного удаления одного или более металлических компонентов из композита, полученного на стадии (а).
7. Способ по п.6, в котором один или более металлических компонентов содержит по меньшей мере один оксид металла.
8. Способ по п.6 или 7, в котором по меньшей мере частичное удаление проводят промыванием посредством щелочной или кислотной жидкости.
9. Способ по п.1 или 6, который включает дальнейшую стадию
(в) импрегнирования композита, полученного на стадии (а) или (б), серой.
10. Способ по п.9, в котором импрегнирование проводят смешиванием и последующим нагреванием.
11. Способ по п.9 или 10, в котором серу используют в виде твердого вещества или в растворе.
12. Применение композита, который может быть получен способом по любому из п.п.1, 6 или 9, для абсорбции по меньшей мере одного материала с целью хранения, удаления, контролируемого выделения, химической реакции по меньшей мере одного материала, или в качестве носителя.
13. Серный электрод, содержащий композит, который может быть получен способом по любому из пп.9-11.
14. Применение серного электрода по п.13 в литий-серном аккумуляторе.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP10174939 | 2010-09-01 | ||
EP10174939.8 | 2010-09-01 | ||
PCT/IB2011/053646 WO2012028989A1 (en) | 2010-09-01 | 2011-08-18 | Process for producing carbon-comprising composite |
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Publication Number | Publication Date |
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RU2013114186A true RU2013114186A (ru) | 2014-10-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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RU2013114186/04A RU2013114186A (ru) | 2010-09-01 | 2011-08-18 | Способ производства углеродсодержащего композита |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2611766A4 (ru) |
JP (1) | JP2013537877A (ru) |
KR (1) | KR20130101038A (ru) |
CN (1) | CN103180282A (ru) |
AU (1) | AU2011298030A1 (ru) |
BR (1) | BR112013004984A2 (ru) |
CA (1) | CA2809928A1 (ru) |
MX (1) | MX2013002219A (ru) |
RU (1) | RU2013114186A (ru) |
TW (1) | TW201223962A (ru) |
WO (1) | WO2012028989A1 (ru) |
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US9099744B2 (en) | 2011-03-31 | 2015-08-04 | Basf Se | Particulate porous carbon material and use thereof in lithium cells |
US9527751B2 (en) | 2011-11-11 | 2016-12-27 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure |
CN103456929B (zh) * | 2013-09-04 | 2015-08-12 | 中南大学 | 一种锂硫电池正极材料及其制备方法 |
CN103500819B (zh) * | 2013-09-18 | 2015-11-18 | 中南大学 | 一种表面修饰多孔状碳结构的碳纤维/硫复合正极材料及其制备方法 |
WO2015040593A1 (en) * | 2013-09-23 | 2015-03-26 | Basf Se | Process for the recovery of components forming a metal-organic framework material |
JPWO2015137272A1 (ja) * | 2014-03-11 | 2017-04-06 | 国立大学法人京都大学 | 多孔性構造体およびその製造方法並びに複合金属ナノ粒子の製造方法 |
WO2015171613A1 (en) * | 2014-05-05 | 2015-11-12 | Nivo Systems, Inc. | Carbon-enriched open framework composites, methods for producing and using such composites |
DE102015215088A1 (de) | 2015-08-07 | 2017-02-09 | Robert Bosch Gmbh | MOF-Silicium-Kohlenstoff-Komposit-Anodenmaterial |
EP3429963B1 (en) * | 2016-03-17 | 2023-09-20 | Saudi Arabian Oil Company | Synthesis of transition-metal adamantane carboxylic salts and oxide nanocomposites |
US10138199B2 (en) | 2016-03-17 | 2018-11-27 | Saudi Arabian Oil Company | High aspect ratio layered double hydroxide materials and methods for preparation thereof |
CN105932230B (zh) * | 2016-04-27 | 2018-10-26 | 长沙矿冶研究院有限责任公司 | 一种纳米棒多孔碳-硫复合正极材料及其制备方法、锂硫电池 |
CN108336308A (zh) * | 2017-01-20 | 2018-07-27 | 华为技术有限公司 | 一种锂硫电池正极保护材料及其应用 |
KR101969410B1 (ko) * | 2017-02-28 | 2019-08-13 | 가천대학교 산학협력단 | 다공성 탄소 복합 구조체 및 그 제조 방법 |
US10875092B2 (en) | 2017-05-19 | 2020-12-29 | Saudi Arabian Oil Company | Methods for preparing mixed-metal oxide diamondoid nanocomposites and catalytic systems including the nanocomposites |
CN110678419B (zh) | 2017-05-19 | 2022-03-29 | 沙特***石油公司 | 过渡金属金刚烷盐和氧化物纳米复合材料的合成 |
CN107768652A (zh) * | 2017-10-25 | 2018-03-06 | 北京理工大学 | 一种基于中微双孔金属氧化物或尖晶石的锂硫电池正极材料及其制备方法 |
CN109888236B (zh) * | 2019-03-07 | 2021-09-28 | 南京邮电大学 | 一种锂硫电池正极材料的制备方法 |
CN111302476B (zh) * | 2020-02-27 | 2021-12-17 | 南京大学 | 一种可活化过硫酸盐的mof原位生长cnt的磁性材料的制备与应用 |
CN113488654B (zh) * | 2021-07-27 | 2022-04-19 | 深圳齐锂纳米科技有限公司 | 一种碳纳米管支撑的石墨烯复合层状导电剂 |
CN113725434B (zh) * | 2021-08-06 | 2023-05-16 | 九江学院 | 一种镍基金属有机框架衍生的复合电极及其制备方法 |
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AU2009223442B2 (en) * | 2008-03-12 | 2014-01-30 | Toyota Jidosha Kabushiki Kaisha | Sulfur-carbon material |
CN101587951A (zh) * | 2008-05-23 | 2009-11-25 | 中国人民解放军63971部队 | 一种用于锂-硫电池的新型碳硫复合物 |
CN101604580B (zh) * | 2009-04-03 | 2011-10-05 | 中国科学院上海硅酸盐研究所 | 单源化合物一步分解法制备多孔碳电极材料的方法 |
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2011
- 2011-08-18 BR BR112013004984A patent/BR112013004984A2/pt not_active IP Right Cessation
- 2011-08-18 MX MX2013002219A patent/MX2013002219A/es not_active Application Discontinuation
- 2011-08-18 CA CA2809928A patent/CA2809928A1/en not_active Abandoned
- 2011-08-18 KR KR1020137007878A patent/KR20130101038A/ko not_active Application Discontinuation
- 2011-08-18 AU AU2011298030A patent/AU2011298030A1/en not_active Abandoned
- 2011-08-18 EP EP11821197.8A patent/EP2611766A4/en not_active Withdrawn
- 2011-08-18 WO PCT/IB2011/053646 patent/WO2012028989A1/en active Application Filing
- 2011-08-18 CN CN2011800514847A patent/CN103180282A/zh active Pending
- 2011-08-18 RU RU2013114186/04A patent/RU2013114186A/ru not_active Application Discontinuation
- 2011-08-18 JP JP2013526572A patent/JP2013537877A/ja not_active Withdrawn
- 2011-09-01 TW TW100131559A patent/TW201223962A/zh unknown
Also Published As
Publication number | Publication date |
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WO2012028989A1 (en) | 2012-03-08 |
CA2809928A1 (en) | 2012-03-08 |
AU2011298030A1 (en) | 2013-03-21 |
TW201223962A (en) | 2012-06-16 |
MX2013002219A (es) | 2013-06-03 |
BR112013004984A2 (pt) | 2016-05-31 |
CN103180282A (zh) | 2013-06-26 |
KR20130101038A (ko) | 2013-09-12 |
JP2013537877A (ja) | 2013-10-07 |
EP2611766A1 (en) | 2013-07-10 |
EP2611766A4 (en) | 2014-04-30 |
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