RU2011137188A - Фотополимерные композиции в качестве пригодных для печатания композиций - Google Patents
Фотополимерные композиции в качестве пригодных для печатания композиций Download PDFInfo
- Publication number
- RU2011137188A RU2011137188A RU2011137188/04A RU2011137188A RU2011137188A RU 2011137188 A RU2011137188 A RU 2011137188A RU 2011137188/04 A RU2011137188/04 A RU 2011137188/04A RU 2011137188 A RU2011137188 A RU 2011137188A RU 2011137188 A RU2011137188 A RU 2011137188A
- Authority
- RU
- Russia
- Prior art keywords
- polyurethane composition
- composition according
- isocyanate
- component
- printing
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract 14
- 229920002635 polyurethane Polymers 0.000 claims abstract 11
- 239000004814 polyurethane Substances 0.000 claims abstract 11
- 239000012948 isocyanate Substances 0.000 claims abstract 5
- 150000002513 isocyanates Chemical class 0.000 claims abstract 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920000570 polyether Polymers 0.000 claims abstract 4
- 239000000654 additive Substances 0.000 claims abstract 3
- 125000003118 aryl group Chemical group 0.000 claims abstract 3
- 239000003054 catalyst Substances 0.000 claims abstract 3
- 239000000975 dye Substances 0.000 claims abstract 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 3
- 229920005862 polyol Polymers 0.000 claims abstract 3
- 150000003077 polyols Chemical class 0.000 claims abstract 3
- 239000003381 stabilizer Substances 0.000 claims abstract 3
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000010521 absorption reaction Methods 0.000 claims abstract 2
- 150000007824 aliphatic compounds Chemical class 0.000 claims abstract 2
- 230000001588 bifunctional effect Effects 0.000 claims abstract 2
- 150000001638 boron Chemical class 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical class CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 229920001228 polyisocyanate Polymers 0.000 claims abstract 2
- 239000005056 polyisocyanate Substances 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims abstract 2
- 230000003595 spectral effect Effects 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims abstract 2
- 150000003673 urethanes Chemical class 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 8
- 239000010410 layer Substances 0.000 claims 5
- -1 polyethylene terephthalate Polymers 0.000 claims 4
- 229920002301 cellulose acetate Polymers 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 2
- 239000011241 protective layer Substances 0.000 claims 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims 1
- 229920002284 Cellulose triacetate Polymers 0.000 claims 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
- 239000000020 Nitrocellulose Substances 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 229920001153 Polydicyclopentadiene Polymers 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 claims 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims 1
- 238000000862 absorption spectrum Methods 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229920001220 nitrocellulos Polymers 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 239000000546 pharmaceutical excipient Substances 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920001707 polybutylene terephthalate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000013638 trimer Substances 0.000 claims 1
- 230000000007 visual effect Effects 0.000 claims 1
- 229920005871 reactive polyether polyol Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/67—Unsaturated compounds having active hydrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/67—Unsaturated compounds having active hydrogen
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- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/72—Polyisocyanates or polyisothiocyanates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/72—Polyisocyanates or polyisothiocyanates
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- C08G18/776—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur phosphorus
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/78—Nitrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
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- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
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- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
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- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
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- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H1/024—Hologram nature or properties
- G03H1/0244—Surface relief holograms
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- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
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- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Polyurethanes Or Polyureas (AREA)
- Holo Graphy (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Laminated Bodies (AREA)
- Polymerisation Methods In General (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
1. Пригодная для печатания полиуретановая композиция, включающая:A) полиизоцианатный компонент, по меньшей мере содержащий полиуретановый форполимер с первично алифатически присоединенными концевыми изоцианатными группами, который основан на гидроксифункциональных соединениях с ОН-функциональностью в интервале от 1,6 до 2,05,B) реакционноспособные по отношению к изоцианатам простые полиэфирполиолы,C) уретанакрилаты и/или уретанметакрилаты по меньшей мере с одной ароматической структурной единицей и показателем преломления при 405 нм более 1,50, которые свободны от изоцианатных и гидроксильных групп,D) стабилизаторы радикалов,Е) фотоинициаторы на основе комбинаций из солей бора и одного или нескольких красителей, полосы поглощения которых по меньшей мере частично перекрывают спектральный диапазон от 400 до 800 нм,F) при необходимости катализаторы,G) вспомогательные вещества и добавки.2. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров используют уретаны или аллофанаты на основе алифатических соединений с изоцианатными функциональными группами и реакционноспособных по отношению к изоцианатам олигомерных или полимерных соединений, причем указанные форполимеры обладают среднечисловой молекулярной массой от 200 до 10000 г/моль и NCO-функциональностью от 1,9 до 5,0.3. Полиуретановая композиция по п.1, отличающаяся тем, что в В) используют бифункциональные простые полиэфирполиолы на основе пропиленоксида и этиленоксида с содержанием этиленоксидных структурных единиц в пересчете на общую массу исходного простого полиэфира, составляющим менее 10 мас.%, и среднечисловой молекулярной массой
Claims (13)
1. Пригодная для печатания полиуретановая композиция, включающая:
A) полиизоцианатный компонент, по меньшей мере содержащий полиуретановый форполимер с первично алифатически присоединенными концевыми изоцианатными группами, который основан на гидроксифункциональных соединениях с ОН-функциональностью в интервале от 1,6 до 2,05,
B) реакционноспособные по отношению к изоцианатам простые полиэфирполиолы,
C) уретанакрилаты и/или уретанметакрилаты по меньшей мере с одной ароматической структурной единицей и показателем преломления при 405 нм более 1,50, которые свободны от изоцианатных и гидроксильных групп,
D) стабилизаторы радикалов,
Е) фотоинициаторы на основе комбинаций из солей бора и одного или нескольких красителей, полосы поглощения которых по меньшей мере частично перекрывают спектральный диапазон от 400 до 800 нм,
F) при необходимости катализаторы,
G) вспомогательные вещества и добавки.
2. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров используют уретаны или аллофанаты на основе алифатических соединений с изоцианатными функциональными группами и реакционноспособных по отношению к изоцианатам олигомерных или полимерных соединений, причем указанные форполимеры обладают среднечисловой молекулярной массой от 200 до 10000 г/моль и NCO-функциональностью от 1,9 до 5,0.
3. Полиуретановая композиция по п.1, отличающаяся тем, что в В) используют бифункциональные простые полиэфирполиолы на основе пропиленоксида и этиленоксида с содержанием этиленоксидных структурных единиц в пересчете на общую массу исходного простого полиэфира, составляющим менее 10 мас.%, и среднечисловой молекулярной массой от 2000 до 4200 г/моль.
4. Полиуретановая композиция по п.1, отличающаяся тем, что в С) в качестве уретанакрилатов используют продукты присоединения ароматических триизоцианатов или тримеров ароматических диизоцианатов с гидроксиэтилакрилатом, гидроксипропилакриалатом, 4-гидроксибутилакрилатом.
5. Полиуретановая композиция по одному из пп.1-3, отличающаяся тем, что она содержит:
от 15 до 30 мас.% компонента А),
от 30 до 56,96 мас.% компонента В),
от 20 до 35 мас.% компонента С),
от 0,01 до 0,5 мас.% стабилизаторов радикалов D),
от 1 до 3 мас.% фотоинициаторов Е1),
соответственно от 0,01 до 0,2 мас.% каждого из трех красителей Е2), спектр поглощения которых соответствует длинам волн красного, зеленого и синего лазерного излучения,
от 0 до 1 мас.% катализатора F) и
от 7 до 20 мас.% вспомогательных веществ и добавок G).
6. Способ нанесения печатного рисунка или текста на основу, в соответствии с которым полиуретановую композицию по одному из пп.1-5 в качестве компонента печатной краски наносят на несущий изображение слой (I).
7. Способ по п.6, отличающийся тем, что несущий изображение слой (I) основан на поликарбонате (PC), полиэтилентерефталате (PET), полибутилентерефталате, полиэтилене, полипропилене, ацетате целлюлозы (СТА), гидрате целлюлозы, нитрате целлюлозы, полимерах циклоолефинов, полистироле, полиэпоксидах, полисульфоне, триацетате целлюлозы, полиамиде, полиметилметакрилате, поливинилхлориде, поливинилбутирале, полидициклопентадиене или их 1 смесях при необходимости также в виде многослойных пленок или соэкструдатов.
8. Способ по п.6, отличающийся тем, что общая толщина наносимого путем печати фотополимерного слоя (II) составляет от 3 до 100 мкм.
9. Способ по п.6, отличающийся тем, что по завершении процесса печати на фотополимерный слой (II) наносят защитный слой (III).
10. Способ по одному из пп.6-9, отличающийся тем, что материал защитного слоя (III) аналогичен материалу несущего изображение слоя (I).
11. Применение изделия, на которое нанесен рисунок или текст способом по одному из пп.6-10, для записи визуальных голограмм и для изготовления оптических элементов, изображений и данных.
12. Способ записи голограмм, отличающийся тем, что используют полиуретановую композицию по одному из пп.1-5.
13. Среда или голографическая пленка, содержащая полиуретановую композицию по одному из пп.1-5.
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EP09001949A EP2218742A1 (de) | 2009-02-12 | 2009-02-12 | Photopolymerzusammensetzungen als verdruckbare Formulierungen |
PCT/EP2010/000618 WO2010091807A1 (de) | 2009-02-12 | 2010-02-02 | Photopolymerzusammensetzungen als verdruckbare formulierungen |
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TW201035146A (en) | 2010-10-01 |
KR20110123242A (ko) | 2011-11-14 |
US8715889B2 (en) | 2014-05-06 |
CN102317336A (zh) | 2012-01-11 |
EP2396359A1 (de) | 2011-12-21 |
SG173436A1 (en) | 2011-09-29 |
CA2751911A1 (en) | 2010-08-19 |
JP2012517514A (ja) | 2012-08-02 |
EP2396359B1 (de) | 2017-09-27 |
WO2010091807A1 (de) | 2010-08-19 |
JP5684733B2 (ja) | 2015-03-18 |
EP2218742A1 (de) | 2010-08-18 |
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