RU2010126213A - COMPOSITE MATERIALS INCLUDING INTERNAL CONDUCTING POLYMER AND METHOD AND DEVICES - Google Patents

COMPOSITE MATERIALS INCLUDING INTERNAL CONDUCTING POLYMER AND METHOD AND DEVICES Download PDF

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RU2010126213A
RU2010126213A RU2010126213/07A RU2010126213A RU2010126213A RU 2010126213 A RU2010126213 A RU 2010126213A RU 2010126213/07 A RU2010126213/07 A RU 2010126213/07A RU 2010126213 A RU2010126213 A RU 2010126213A RU 2010126213 A RU2010126213 A RU 2010126213A
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composite material
material according
cellulose
substrate
runway
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RU2010126213/07A
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RU2490738C2 (en
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Мария СТРЕММЕ (SE)
Мария СТРЕММЕ
Лейф НЮХОЛЬМ (SE)
Лейф НЮХОЛЬМ
Альберт МИГРАНЯН (SE)
Альберт МИГРАНЯН
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Мария СТРЕММЕ (SE)
Мария СТРЕММЕ
Лейф НЮХОЛЬМ (SE)
Лейф НЮХОЛЬМ
Альберт МИГРАНЯН (SE)
Альберт МИГРАНЯН
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    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00—Stock material or miscellaneous articles
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    • Y10T428/1331—Single layer [continuous layer]

Abstract

1. Композитный материал в форме непрерывной структуры, также включающий слой внутренне проводящего полимера (ВПП), нанесенный на подложку, причем композитный материал имеет площадь поверхности, равную, по крайней мере, 0,1 м2/г, по крайней мере, 1 м2/г или, по крайней мере, 5 м2/г. ! 2. Композитный материал по п.1, где композитный материал имеет площадь поверхности, равную, по крайней мере, 10 м2/г, по крайней мере, 15 м2/г или, по крайней мере, 20 м2/г. ! 3. Композитный материал по п.1, где ВПП слой, нанесенный на подложку, имеет толщину менее 5 мкм, менее 500 нм, менее 250 нм или менее 100 нм. ! 4. Композитный материал по п.1, где подложка имеет площадь поверхности, равную, по крайней мере, 1 м2/г, по крайней мере, 5 м2/г, по крайней мере, 10 м2/г, по крайней мере, 20 м2/г или, по крайней мере, 40 м2/г. ! 5. Композитный материал по п.4, где подложка включает полимер или геополимер в качестве основного компонента. !6. Композитный материал по п.5, где полимер или геополимер подложки выбирается из группы, состоящей из декстрана, целлюлозы, микроволокнистой целлюлозы, агарозы, полимеров и сополимеров стирола, полимеров и сополимеров акриловой кислоты, полимеров и сополимеров акриламида, полимеров и сополимеров пропилена, полимеров и сополимеров дивинилбензола, геополимера нитрата калия, геополимера галлуазита и других алюмосиликатных геополимеров. ! 7. Композитный материал по п.6, где подложка включает микроволокнистую целлюлозу в качестве основного компонента. ! 8. Композитный материал по п.6, где подложка включает целлюлозу в качестве основного компонента, и целлюлоза выбирается из целлюлозы из морских водорослей и бактериальной целлюлозы. ! 9. Композитный материал  1. A composite material in the form of a continuous structure, also comprising a layer of internally conductive polymer (WFP), deposited on a substrate, and the composite material has a surface area equal to at least 0.1 m2 / g, at least 1 m2 / g or at least 5 m2 / g. ! 2. The composite material according to claim 1, where the composite material has a surface area equal to at least 10 m2 / g, at least 15 m2 / g, or at least 20 m2 / g ! 3. The composite material according to claim 1, where the runway layer deposited on the substrate has a thickness of less than 5 microns, less than 500 nm, less than 250 nm or less than 100 nm. ! 4. The composite material according to claim 1, where the substrate has a surface area equal to at least 1 m2 / g, at least 5 m2 / g, at least 10 m2 / g, at least 20 m2 / g or at least 40 m2 / g. ! 5. The composite material according to claim 4, where the substrate includes a polymer or geopolymer as the main component. ! 6. The composite material according to claim 5, where the polymer or geopolymer of the substrate is selected from the group consisting of dextran, cellulose, microfibrous cellulose, agarose, polymers and copolymers of styrene, polymers and copolymers of acrylic acid, polymers and copolymers of acrylamide, polymers and copolymers of propylene, polymers and copolymers of divinylbenzene, potassium nitrate geopolymer, halloysite geopolymer and other aluminosilicate geopolymers. ! 7. The composite material according to claim 6, where the substrate includes microfiber cellulose as the main component. ! 8. The composite material according to claim 6, where the substrate includes cellulose as the main component, and the cellulose is selected from cellulose from algae and bacterial cellulose. ! 9. Composite material

Claims (34)

1. Композитный материал в форме непрерывной структуры, также включающий слой внутренне проводящего полимера (ВПП), нанесенный на подложку, причем композитный материал имеет площадь поверхности, равную, по крайней мере, 0,1 м2/г, по крайней мере, 1 м2/г или, по крайней мере, 5 м2/г.1. A composite material in the form of a continuous structure, also comprising a layer of internally conductive polymer (WFP), deposited on a substrate, the composite material having a surface area equal to at least 0.1 m 2 / g, at least 1 m 2 / g or at least 5 m 2 / g. 2. Композитный материал по п.1, где композитный материал имеет площадь поверхности, равную, по крайней мере, 10 м2/г, по крайней мере, 15 м2/г или, по крайней мере, 20 м2/г.2. The composite material according to claim 1, where the composite material has a surface area equal to at least 10 m 2 / g, at least 15 m 2 / g, or at least 20 m 2 / g 3. Композитный материал по п.1, где ВПП слой, нанесенный на подложку, имеет толщину менее 5 мкм, менее 500 нм, менее 250 нм или менее 100 нм.3. The composite material according to claim 1, where the runway layer deposited on a substrate has a thickness of less than 5 μm, less than 500 nm, less than 250 nm or less than 100 nm. 4. Композитный материал по п.1, где подложка имеет площадь поверхности, равную, по крайней мере, 1 м2/г, по крайней мере, 5 м2/г, по крайней мере, 10 м2/г, по крайней мере, 20 м2/г или, по крайней мере, 40 м2/г.4. The composite material according to claim 1, where the substrate has a surface area equal to at least 1 m 2 / g, at least 5 m 2 / g, at least 10 m 2 / g, at least , 20 m 2 / g or at least 40 m 2 / g. 5. Композитный материал по п.4, где подложка включает полимер или геополимер в качестве основного компонента.5. The composite material according to claim 4, where the substrate includes a polymer or geopolymer as the main component. 6. Композитный материал по п.5, где полимер или геополимер подложки выбирается из группы, состоящей из декстрана, целлюлозы, микроволокнистой целлюлозы, агарозы, полимеров и сополимеров стирола, полимеров и сополимеров акриловой кислоты, полимеров и сополимеров акриламида, полимеров и сополимеров пропилена, полимеров и сополимеров дивинилбензола, геополимера нитрата калия, геополимера галлуазита и других алюмосиликатных геополимеров.6. The composite material according to claim 5, where the polymer or geopolymer of the substrate is selected from the group consisting of dextran, cellulose, microfiber cellulose, agarose, polymers and copolymers of styrene, polymers and copolymers of acrylic acid, polymers and copolymers of acrylamide, polymers and copolymers of propylene, polymers and copolymers of divinylbenzene, geopolymer of potassium nitrate, geopolymer of halloysite and other aluminosilicate geopolymers. 7. Композитный материал по п.6, где подложка включает микроволокнистую целлюлозу в качестве основного компонента.7. The composite material according to claim 6, where the substrate includes microfiber cellulose as the main component. 8. Композитный материал по п.6, где подложка включает целлюлозу в качестве основного компонента, и целлюлоза выбирается из целлюлозы из морских водорослей и бактериальной целлюлозы.8. The composite material according to claim 6, where the substrate includes cellulose as the main component, and the cellulose is selected from cellulose from seaweed and bacterial cellulose. 9. Композитный материал по п.8, где целлюлоза из морских водорослей получается из нитевидных морских водорослей и/или шарообразных морских водорослей.9. The composite material of claim 8, where the cellulose from algae is obtained from filamentous algae and / or spherical seaweed. 10. Композитный материал по п.9, где целлюлоза из морских водорослей получается из водорослей отряда Кладофоровых или отряда Сифонокладовых.10. The composite material according to claim 9, where the cellulose from seaweed is obtained from the algae of the Kladoforov detachment or the Siphon and treasure detachment. 11. Композитный материал по п.10, где целлюлоза из морских водорослей получается из таких морских водорослей, как Кладофора, Хетоморфа, Ризоклониум, Микродиктиум, Валония, Диктиосферия, Сифонокладус или Бергесения.11. The composite material of claim 10, where the cellulose from seaweed is obtained from such seaweeds as Kladofora, Khetomorfa, Rizoklonium, Microdictium, Valonia, Diktiosferiya, Sifonokladus or Bergeseniya. 12. Композитный материал по п.8, где бактериальная целлюлоза получается из Acetobacter xylinum.12. The composite material of claim 8, where the bacterial cellulose is obtained from Acetobacter xylinum. 13. Композитный материал по п.8, где целлюлоза получается из вида зеленых морских водорослей Кладофоры.13. The composite material of claim 8, where the cellulose is obtained from the species of green algae Kladofora. 14. Композитный материал по п.7, где композит был сформирован в виде похожего на бумагу листа.14. The composite material according to claim 7, where the composite was formed into a paper-like sheet. 15. Композитный материал по любому из пп.1-14, в котором подложка была сделана проводящей путем функционализации углеродными наноматериалами или путем нанесения тонкого проводящего слоя на подложку.15. The composite material according to any one of claims 1 to 14, in which the substrate was made conductive by functionalization with carbon nanomaterials or by applying a thin conductive layer to the substrate. 16. Композитный материал по любому из пп.1-14, где ВПП получается из ацетилена.16. The composite material according to any one of claims 1 to 14, where the runway is obtained from acetylene. 17. Композитный материал по пп.1-14, где ВПП выбирается из группы, состоящей из полифенилена (ПФ), полифениленсульфида (ПФС), полифениленвинилена (ПФВ), полипиррола (ППи), политиофена и полианилина (ПАн).17. The composite material according to claims 1-14, wherein the runway is selected from the group consisting of polyphenylene (PF), polyphenylene sulfide (PPS), polyphenylenevinylene (PFV), polypyrrole (PPi), polythiophene and polyaniline (PAn). 18. Композитный материал по любому из пп.1-14, где подложка включает целлюлозу, полученную из вида зеленых морских водорослей Кладофоры в качестве основного компонента, а ВПП включает полипиррол.18. The composite material according to any one of claims 1 to 14, where the substrate includes cellulose obtained from the species of green algae Kladofora as the main component, and the runway includes polypyrrole. 19. Композитный материал по любому из пп.1-14, где подложка включает микроволокнистую целлюлозу в качестве основного компонента, а ВПП включает полипиррол.19. The composite material according to any one of claims 1 to 14, where the substrate includes microfiber cellulose as the main component, and the runway includes polypyrrole. 20. Композитный материал по любому из пп.1-14, где композитный материал сохраняет свою механическую целостность в интервале рН от 2 до 11.20. The composite material according to any one of claims 1 to 14, where the composite material retains its mechanical integrity in the pH range from 2 to 11. 21. Композитный материал по любому из пп.1-14, где подложка имеет степень кристаллизации, равную, по крайней мере, 50%, по крайней мере, 60%, по крайней мере, 70%, по крайней мере, 75%, по крайней мере, 80%, по крайней мере, 85% или, по крайней мере, 90%.21. The composite material according to any one of claims 1 to 14, where the substrate has a crystallization degree equal to at least 50%, at least 60%, at least 70%, at least 75%, at least 80%, at least 85%, or at least 90%. 22. Электрохимическое или электрическое устройство, включающее, по крайней мере, один компонент, сформированный из композитного материала по любому из пп.1-14.22. An electrochemical or electrical device comprising at least one component formed from a composite material according to any one of claims 1 to 14. 23. Электрохимическая цепь, включающая электрохимически управляемый слой, сформированный из композитного материала по любому из пп.1-14.23. An electrochemical circuit comprising an electrochemically controlled layer formed from a composite material according to any one of claims 1-14. 24. Устройство аккумуляции энергии, включающее батарею или конденсатор большой мощности, сформированные из композитного материала по любому из пп.1-14.24. An energy storage device comprising a high power battery or capacitor formed from a composite material according to any one of claims 1-14. 25. Электромеханический соленоид, включающий электрохимически управляемый слой, сформированный из композитного материала по любому из пп.1-14.25. An electromechanical solenoid comprising an electrochemically controlled layer formed of a composite material according to any one of claims 1-14. 26. Способ производства композитного материала в соответствии с любым из пп.1-14, причем способ включает покрытие подложки слоем внутренне проводящего полимера (ВПП).26. A method of manufacturing a composite material in accordance with any one of claims 1 to 14, the method comprising coating the substrate with a layer of internally conductive polymer (WFP). 27. Способ по п.26, где этап нанесения включает полимеризацию формирующего ВПП мономера в растворе, содержащем окисляющий агент.27. The method according to p, where the step of applying includes the polymerization of the forming runway monomer in a solution containing an oxidizing agent. 28. Способ по п.27, где окисляющий агент выбирается из группы, состоящей из S2O8 2-, H2O2, фосфорномолибдата и солей ионов переходных металлов, выбранных из группы, состоящей из Fe3+, Cu2+, Cr6+, Mo6+, Се4+, Ru3+ и Mn7+.28. The method according to item 27, where the oxidizing agent is selected from the group consisting of S 2 O 8 2- , H 2 O 2 , phosphor molybdate and salts of transition metal ions selected from the group consisting of Fe 3+ , Cu 2+ , Cr 6+ , Mo 6+ , Ce 4+ , Ru 3+ and Mn 7+ . 29. Способ по п.27, где окисляющий агент включает хлорид, бромид, сульфат, фосфат, формиат, карбонат, ацетат, перхлорат, п-толуолсульфонат и/или фосфорномолибдат анион.29. The method of claim 27, wherein the oxidizing agent comprises chloride, bromide, sulfate, phosphate, formate, carbonate, acetate, perchlorate, p-toluenesulfonate and / or phosphoromolybdate anion. 30. Способ по п.27, также включающий электрополимеризацию управляемым потенциалом или током, чтобы увеличить толщину ВПП слоя.30. The method according to item 27, also comprising electropolymerization controlled potential or current, to increase the thickness of the runway layer. 31. Способ по п.26, где этап нанесения включает электрополимеризацию управляемым потенциалом или током формирующего ВПП мономера, проведенную непосредственно на электронно-проводящей подложке.31. The method according to p. 26, where the deposition step involves the electropolymerization of a controlled potential or current of the forming runway monomer, carried out directly on an electronically conductive substrate. 32. Способ по п.31, также включающий полимеризацию формирующего ВПП мономера в растворе, включающем окисляющий агент, после этапа электрополимеризации.32. The method according to p, also including the polymerization of the runway-forming runway monomer in a solution comprising an oxidizing agent, after the step of electropolymerization. 33. Способ по п.26, где проводимость слоя ВПП увеличивается путем полимеризации формирующего ВПП мономера в присутствии поверхностно-активного вещества.33. The method according to p, where the conductivity of the runway layer is increased by polymerization of the runway-forming monomer in the presence of a surfactant. 34. Способ по п.26, где композитный материал выполняется в форме листа бумаги, который может быть фольгирован, сложен, согнут или скручен, при этом сохраняя свою механическую целостность. 34. The method according to p, where the composite material is in the form of a sheet of paper that can be folded, folded, bent or twisted, while maintaining its mechanical integrity.
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