RU2009120403A - Нафталиндикарбоксилат алюминия в качестве пористого металлорганического материала со скелетной структурой - Google Patents

Нафталиндикарбоксилат алюминия в качестве пористого металлорганического материала со скелетной структурой Download PDF

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RU2009120403A
RU2009120403A RU2009120403/05A RU2009120403A RU2009120403A RU 2009120403 A RU2009120403 A RU 2009120403A RU 2009120403/05 A RU2009120403/05 A RU 2009120403/05A RU 2009120403 A RU2009120403 A RU 2009120403A RU 2009120403 A RU2009120403 A RU 2009120403A
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Маркус ШУБЕРТ (DE)
Маркус Шуберт
Ульрих МЮЛЛЕР (DE)
Ульрих Мюллер
Штефан МАРКС (CH)
Штефан МАРКС
Кристоф КИНЕР (DE)
Кристоф Кинер
Джеймс Рубен БРАУН (DE)
Джеймс Рубен БРАУН
Герхард КРЕННРИХ (DE)
Герхард КРЕННРИХ
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Басф Се (De)
Басф Се
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Abstract

1. Пористый металлорганический материал со скелетной структурой, содержащий координационно связанное с ионом металла двузубчато-образное органическое соединение, причем ионом металла является AlIII, а двузубчатообразным органическим соединением является 2,6-нафталиндикарбоксилат, отличающийся тем, что рентгеновская дифрактограмма (XRD) материала со скелетной структурой имеет первый рефлекс в области 6,5°<2Θ<7,5°, а второй рефлекс - в области 13,8°<2Θ<15,0°, причем по отношению к площади всех рефлексов в области 2°<2Θ<70° площадь первого рефлекса является наибольшей, а площадь второго рефлекса является вдвое большей и при этом сумма площадей первого и второго рефлексов по отношению к общей площади всех рефлексов в области 2°<2Θ<70° составляет, по меньшей мере, 50%. ! 2. Материал со скелетной структурой по п.1, отличающийся тем, что первый рефлекс находится в области 6,7°<2Θ<7,3°, а второй рефлекс находится в области 13,9°<2Θ<14,8°. ! 3. Пористый металлорганический материал со скелетной структурой по п.1 или 2, отличающийся тем, что в виде порошка он имеет удельную поверхность согласно Langmuir по адсорбции азота N2 при 77 K, по меньшей мере, 1000 м2/г. ! 4. Формованное изделие, содержащее пористый металлорганический материал со скелетной структурой по одному из пп.1-3. ! 5. Формованное изделие по п.4, отличающееся тем, что оно имеет удельную поверхность, определенную согласно Langmuir по адсорбции азота N2 при 77 K, по меньшей мере, 500 м2/г. ! 6. Способ получения пористого металлорганического материала со скелетной структурой, содержащий стадию взаимодействия реакционной смеси, содержащей соединение алюминия, 2,6-нафталиндикарбоновую кислоту или ее соль и органическ

Claims (10)

1. Пористый металлорганический материал со скелетной структурой, содержащий координационно связанное с ионом металла двузубчато-образное органическое соединение, причем ионом металла является AlIII, а двузубчатообразным органическим соединением является 2,6-нафталиндикарбоксилат, отличающийся тем, что рентгеновская дифрактограмма (XRD) материала со скелетной структурой имеет первый рефлекс в области 6,5°<2Θ<7,5°, а второй рефлекс - в области 13,8°<2Θ<15,0°, причем по отношению к площади всех рефлексов в области 2°<2Θ<70° площадь первого рефлекса является наибольшей, а площадь второго рефлекса является вдвое большей и при этом сумма площадей первого и второго рефлексов по отношению к общей площади всех рефлексов в области 2°<2Θ<70° составляет, по меньшей мере, 50%.
2. Материал со скелетной структурой по п.1, отличающийся тем, что первый рефлекс находится в области 6,7°<2Θ<7,3°, а второй рефлекс находится в области 13,9°<2Θ<14,8°.
3. Пористый металлорганический материал со скелетной структурой по п.1 или 2, отличающийся тем, что в виде порошка он имеет удельную поверхность согласно Langmuir по адсорбции азота N2 при 77 K, по меньшей мере, 1000 м2/г.
4. Формованное изделие, содержащее пористый металлорганический материал со скелетной структурой по одному из пп.1-3.
5. Формованное изделие по п.4, отличающееся тем, что оно имеет удельную поверхность, определенную согласно Langmuir по адсорбции азота N2 при 77 K, по меньшей мере, 500 м2/г.
6. Способ получения пористого металлорганического материала со скелетной структурой, содержащий стадию взаимодействия реакционной смеси, содержащей соединение алюминия, 2,6-нафталиндикарбоновую кислоту или ее соль и органический растворитель, при температуре в области от 100°C до 200°C при перемешивании, причем суммарное содержание соединения алюминия и 2,6-нафталиндикарбоновой кислоты или ее соли составляет менее 20 мас.% от общей массы реакционной смеси.
7. Способ по п.6, отличающийся тем, что молярное отношение соединения алюминия к 2,6-нафталиндикарбоновой кислоте или ее соли находится в области от 0,3 до 1,5.
8. Применение металлорганического материала со скелетной структурой по одному из пп.1-3 или формованного изделия по п.4 или 5 для поглощения, по меньшей мере, одного вещества для его хранения, отделения, контролируемого выделения, химического взаимодействия или в качестве носителя.
9. Применение по п.8, отличающееся тем, что, по меньшей мере, одним веществом является диоксид углерода для отделения его из содержащей диоксид углерода газовой смеси.
10. Применение по п.8, отличающееся тем, что, по меньшей мере, одним веществом является газ для хранения его при минимальном давлении 100 бар (абсолютное давление).
RU2009120403/05A 2006-10-30 2007-10-24 Нафталиндикарбоксилат алюминия в качестве пористого металлорганического материала со скелетной структурой RU2009120403A (ru)

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