RU2007121687A - Способ риформинга с использованием катализатора высокой плотности - Google Patents
Способ риформинга с использованием катализатора высокой плотности Download PDFInfo
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- RU2007121687A RU2007121687A RU2007121687/04A RU2007121687A RU2007121687A RU 2007121687 A RU2007121687 A RU 2007121687A RU 2007121687/04 A RU2007121687/04 A RU 2007121687/04A RU 2007121687 A RU2007121687 A RU 2007121687A RU 2007121687 A RU2007121687 A RU 2007121687A
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- oxide
- tin
- catalyst
- metal
- platinum group
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- 239000003054 catalyst Substances 0.000 title claims abstract 18
- 238000000034 method Methods 0.000 title claims 7
- 238000002407 reforming Methods 0.000 title 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 17
- 229910052751 metal Inorganic materials 0.000 claims abstract 15
- 239000002184 metal Substances 0.000 claims abstract 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract 13
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 7
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000011230 binding agent Substances 0.000 claims abstract 4
- 238000006243 chemical reaction Methods 0.000 claims abstract 4
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims abstract 4
- 229910052697 platinum Inorganic materials 0.000 claims abstract 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052684 Cerium Inorganic materials 0.000 claims abstract 2
- 229910052693 Europium Inorganic materials 0.000 claims abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000004813 Moessbauer spectroscopy Methods 0.000 claims abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract 2
- 229910052793 cadmium Inorganic materials 0.000 claims abstract 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052733 gallium Inorganic materials 0.000 claims abstract 2
- 229910052732 germanium Inorganic materials 0.000 claims abstract 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052738 indium Inorganic materials 0.000 claims abstract 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000395 magnesium oxide Substances 0.000 claims abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 2
- 239000011733 molybdenum Substances 0.000 claims abstract 2
- 229910052759 nickel Inorganic materials 0.000 claims abstract 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 2
- 239000010452 phosphate Substances 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 239000011574 phosphorus Substances 0.000 claims abstract 2
- -1 platinum group metals Chemical class 0.000 claims abstract 2
- 229910052702 rhenium Inorganic materials 0.000 claims abstract 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract 2
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910003452 thorium oxide Inorganic materials 0.000 claims abstract 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052721 tungsten Inorganic materials 0.000 claims abstract 2
- 239000010937 tungsten Substances 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- 239000011701 zinc Substances 0.000 claims abstract 2
- 239000011787 zinc oxide Substances 0.000 claims abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 4
- 239000000758 substrate Substances 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 238000004458 analytical method Methods 0.000 claims 1
- 238000001833 catalytic reforming Methods 0.000 claims 1
- 238000006356 dehydrogenation reaction Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/31—Density
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/24—Chlorinating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
1. Катализатор конверсии углеводородов, включающий металл платиновой группы, олово и подложку, имеющий среднюю объемную плотность больше 0,6 г/см и предпочтительно больше 0,65 г/см, в которой объемно-массовое отношение металла платиновой группы к олову менее 0,9 и предпочтительно менее 0,85, где металлом платиновой группы является платина в количестве от 0,01 до 2,0 мас.% в расчете на элемент и где вышеупомянутый катализатор содержит ассоциированное олово в специфических кластерах из олова и металлов платиновой группы в количестве, по меньшей мере, 33 мас.% и эффективное молярное отношение ассоциированного олова к платине в вышеупомянутых кластерах составляет, по меньшей мере, 0,65 по анализу мессбауэровской спектроскопией.2. Катализатор по п.1, где компонентом подложки является связующее, представляющее собой неорганический оксид, выбранный из группы, состоящей из оксида алюминия, оксида магния, диоксида циркония, оксида хрома, оксида титана, оксида бора, оксида тория, фосфата, оксида цинка, оксида кремния и их смеси, предпочтительно оксид алюминия.3. Катализатор по п.2, где связующим неорганическим оксидом является оксид алюминия, имеющий на рентгенограмме отношение интенсивностей пиков при значениях два-тета брэгговского угла 34,0:32,5, по меньшей мере, 1,2 и отношение интенсивностей пиков при значениях два-тета брэгговского угла 46,0:45,5, не больше 1,1.4. Катализатор по любому из пп.1-3, дополнительно включающий металлический промотор, выбранный из группы, состоящей из германия, рения, галлия, церия, лантана, европия, индия, фосфора, никеля, железа, вольфрама, молибдена, цинка, кадмия и их смесей, где металлический промотор составляет о
Claims (10)
1. Катализатор конверсии углеводородов, включающий металл платиновой группы, олово и подложку, имеющий среднюю объемную плотность больше 0,6 г/см и предпочтительно больше 0,65 г/см, в которой объемно-массовое отношение металла платиновой группы к олову менее 0,9 и предпочтительно менее 0,85, где металлом платиновой группы является платина в количестве от 0,01 до 2,0 мас.% в расчете на элемент и где вышеупомянутый катализатор содержит ассоциированное олово в специфических кластерах из олова и металлов платиновой группы в количестве, по меньшей мере, 33 мас.% и эффективное молярное отношение ассоциированного олова к платине в вышеупомянутых кластерах составляет, по меньшей мере, 0,65 по анализу мессбауэровской спектроскопией.
2. Катализатор по п.1, где компонентом подложки является связующее, представляющее собой неорганический оксид, выбранный из группы, состоящей из оксида алюминия, оксида магния, диоксида циркония, оксида хрома, оксида титана, оксида бора, оксида тория, фосфата, оксида цинка, оксида кремния и их смеси, предпочтительно оксид алюминия.
3. Катализатор по п.2, где связующим неорганическим оксидом является оксид алюминия, имеющий на рентгенограмме отношение интенсивностей пиков при значениях два-тета брэгговского угла 34,0:32,5, по меньшей мере, 1,2 и отношение интенсивностей пиков при значениях два-тета брэгговского угла 46,0:45,5, не больше 1,1.
4. Катализатор по любому из пп.1-3, дополнительно включающий металлический промотор, выбранный из группы, состоящей из германия, рения, галлия, церия, лантана, европия, индия, фосфора, никеля, железа, вольфрама, молибдена, цинка, кадмия и их смесей, где металлический промотор составляет от 0,01 до 5,0 мас.% в расчете на элемент.
5. Катализатор по любому из пп.1-3, дополнительно включающий галоген в количестве от 0,1 до 10 мас.%.
6. Катализатор по любому из пп.1-3, где оксид алюминия имеет площадь поверхности от 140 до 210 м2/г, предпочтительно от 150 до 180 м2/г.
7. Катализатор по любому из пп.1-3, где объемно массовое отношение металла платиновой группы к олову менее 0,85.
8. Способ конверсии углеводородов, включающий контактирование углеводородного сырья с катализатором по любому из пп.1-7 при условиях конверсии углеводородов, конвертированного углеводорода, где катализатор включает металл платиновой группы, олово и подложку, имеющий среднюю объемную плотность больше 0,6 г/см3, где объемно-массовое отношение металла платиновой группы к олову менее 0,9.
9. Способ по п.8, где углеводородным сырьем является сырье ряда лигроина и способом является процесс каталитического риформинга.
10. Способ по п.8, где способом является дегидрирование и катализатор дополнительно включает щелочной или щелочноземельный металл, диспергированный в имеющем определенную форму катализаторе в количестве от 0,01 до 5,0 мас.% в расчете на элемент.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/986?585 | 2004-11-12 | ||
| US10/986,585 | 2004-11-12 | ||
| US10/986,585 US20060102520A1 (en) | 2004-11-12 | 2004-11-12 | Reforming process using high density catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2007121687A true RU2007121687A (ru) | 2008-12-20 |
| RU2388534C2 RU2388534C2 (ru) | 2010-05-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2007121687/04A RU2388534C2 (ru) | 2004-11-12 | 2005-10-31 | Способ реформинга с использованием катализатора высокой плотности |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20060102520A1 (ru) |
| EP (1) | EP1656991B1 (ru) |
| JP (1) | JP4979586B2 (ru) |
| KR (1) | KR101233017B1 (ru) |
| CN (1) | CN101056704B (ru) |
| AT (1) | ATE427158T1 (ru) |
| AU (1) | AU2005306957B2 (ru) |
| CA (1) | CA2586727C (ru) |
| DE (1) | DE602005013629D1 (ru) |
| MY (1) | MY142468A (ru) |
| NZ (1) | NZ554911A (ru) |
| RU (1) | RU2388534C2 (ru) |
| TW (1) | TWI356732B (ru) |
| WO (1) | WO2006055229A1 (ru) |
| ZA (1) | ZA200703790B (ru) |
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| US20100197486A1 (en) * | 2008-07-31 | 2010-08-05 | Celanese International Corporation | Catalysts for making ethyl acetate from acetic acid |
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| KR101218453B1 (ko) * | 2008-12-30 | 2013-01-04 | 주식회사 효성 | 탈수소화 촉매 |
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| FR2947464B1 (fr) | 2009-07-01 | 2011-07-22 | Inst Francais Du Petrole | Catalyseur multi-metallique presentant une forte interaction metallique |
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| US8541633B2 (en) * | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
| US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
| TW201136660A (en) | 2010-02-02 | 2011-11-01 | Celanese Int Corp | Catalyst supports having crystalline support modifiers |
| US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
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| US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
| US8858659B2 (en) * | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8460405B2 (en) * | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
| US8551328B2 (en) * | 2011-01-20 | 2013-10-08 | Basf Corporation | Organic chloride adsorbent |
| US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
| US8758599B2 (en) * | 2011-07-15 | 2014-06-24 | Uop Llc | Reforming catalyst and process |
| US8658843B2 (en) | 2011-10-06 | 2014-02-25 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation |
| US8536382B2 (en) | 2011-10-06 | 2013-09-17 | Celanese International Corporation | Processes for hydrogenating alkanoic acids using catalyst comprising tungsten |
| US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
| US9024099B2 (en) * | 2011-12-15 | 2015-05-05 | Uop Llc | Co-current catalyst flow with feed for fractionated feed recombined and sent to high temperature reforming reactors |
| US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
| US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
| CN104039446B (zh) | 2012-01-06 | 2016-12-28 | 国际人造丝公司 | 加氢催化剂 |
| US9024086B2 (en) | 2012-01-06 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts with acidic sites |
| US8981164B2 (en) | 2012-01-06 | 2015-03-17 | Celanese International Corporation | Cobalt and tin hydrogenation catalysts |
| US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
| US8912110B2 (en) | 2012-03-29 | 2014-12-16 | Uop Llc | Catalyst for conversion of hydrocarbons |
| US9266091B2 (en) | 2012-03-29 | 2016-02-23 | Uop Llc | Reforming catalysts with tuned acidity for maximum aromatics yield |
| US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
| CN102925206B (zh) * | 2012-10-31 | 2015-06-10 | 成都易态科技有限公司 | 用于催化重整的膜过滤元件及其制备方法 |
| CN104275198B (zh) * | 2013-07-01 | 2016-04-27 | 中国石油化工股份有限公司 | 一种多金属重整催化剂的制备方法 |
| FR3039082B1 (fr) * | 2015-07-24 | 2017-07-21 | Ifp Energies Now | Catalyseur multi-metallique dope par du phosphore et un lanthanide |
| US10646855B2 (en) * | 2017-11-02 | 2020-05-12 | Uop Llc | Catalyst and process for the selective conversion of hydrocarbons |
| FR3074063B1 (fr) * | 2017-11-30 | 2019-11-01 | IFP Energies Nouvelles | Catalyseur multi-metallique dope par du phosphore et de l'ytterbium |
| FR3074062B1 (fr) | 2017-11-30 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur multi-metallique dope par du phosphore et de l'yttrium |
| US10981149B2 (en) * | 2019-03-18 | 2021-04-20 | Uop Llc | Dehydrogenation catalyst with optimum modifier profile index |
| CN111905776B (zh) * | 2019-05-09 | 2023-07-11 | 中国石油化工股份有限公司 | 一种连续重整催化剂及其制备与应用 |
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| US3852190A (en) * | 1972-10-27 | 1974-12-03 | Chevron Res | Reforming with platinum on alumina derived from a byproduct of a ziegler process |
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| US4865719A (en) * | 1986-09-22 | 1989-09-12 | Uop | Trimetallic reforming catalyst |
| US4677094A (en) * | 1986-09-22 | 1987-06-30 | Uop Inc. | Trimetallic reforming catalyst |
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| CN1032678C (zh) * | 1992-12-21 | 1996-09-04 | 中国石油化工总公司 | 饱和烃类脱氢用催化剂 |
| ES2151015T3 (es) * | 1994-11-29 | 2000-12-16 | Degussa | Catalizador para la deshidrogenacion de parafinas c6 a c15. |
| US6514904B1 (en) * | 2000-06-05 | 2003-02-04 | Uop Llc | Hydrocarbon conversion catalyst and process of using thereof |
| US6503866B1 (en) * | 2000-06-05 | 2003-01-07 | Uop Llc | Attrition resistant catalyst with reduced surface area |
| FR2813304B1 (fr) * | 2000-08-23 | 2002-11-29 | Inst Francais Du Petrole | Procede de deshydrogenation de composes organiques en presence d'un catalyseur bimetallique supporte comportant une forte interaction entre un metal du groupe viii et de l'etain |
| FR2813209B1 (fr) * | 2000-08-23 | 2002-11-29 | Inst Francais Du Petrole | Catalyseur bimetallique supporte comportant une forte interaction entre un metal du groupe viii et de l'etain et son utilisation dans un procede de reformage catalytique |
| CN1384175A (zh) * | 2001-04-28 | 2002-12-11 | 中国石油化工股份有限公司 | 含铂、锡的多金属重整催化剂及其制备与应用 |
| US6756340B2 (en) * | 2002-04-08 | 2004-06-29 | Uop Llc | Dehydrogenation catalyst composition |
-
2004
- 2004-11-12 US US10/986,585 patent/US20060102520A1/en not_active Abandoned
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2005
- 2005-10-31 JP JP2007541225A patent/JP4979586B2/ja active Active
- 2005-10-31 AU AU2005306957A patent/AU2005306957B2/en active Active
- 2005-10-31 CA CA2586727A patent/CA2586727C/en active Active
- 2005-10-31 CN CN2005800388425A patent/CN101056704B/zh active Active
- 2005-10-31 NZ NZ554911A patent/NZ554911A/en unknown
- 2005-10-31 ZA ZA200703790A patent/ZA200703790B/xx unknown
- 2005-10-31 RU RU2007121687/04A patent/RU2388534C2/ru active
- 2005-10-31 WO PCT/US2005/039357 patent/WO2006055229A1/en active Application Filing
- 2005-10-31 KR KR1020077012951A patent/KR101233017B1/ko active IP Right Grant
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- 2005-11-07 AT AT05256891T patent/ATE427158T1/de active
- 2005-11-07 DE DE602005013629T patent/DE602005013629D1/de active Active
- 2005-11-10 MY MYPI20055276A patent/MY142468A/en unknown
- 2005-11-11 TW TW094139677A patent/TWI356732B/zh active
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| AU2005306957A1 (en) | 2006-05-26 |
| ATE427158T1 (de) | 2009-04-15 |
| WO2006055229A1 (en) | 2006-05-26 |
| TWI356732B (en) | 2012-01-21 |
| TW200640571A (en) | 2006-12-01 |
| ZA200703790B (en) | 2008-08-27 |
| NZ554911A (en) | 2010-12-24 |
| EP1656991A1 (en) | 2006-05-17 |
| AU2005306957B2 (en) | 2010-11-18 |
| US20060102520A1 (en) | 2006-05-18 |
| CA2586727C (en) | 2013-01-22 |
| CN101056704A (zh) | 2007-10-17 |
| JP2008519685A (ja) | 2008-06-12 |
| MY142468A (en) | 2010-11-30 |
| RU2388534C2 (ru) | 2010-05-10 |
| KR101233017B1 (ko) | 2013-02-13 |
| KR20070074662A (ko) | 2007-07-12 |
| CN101056704B (zh) | 2011-08-31 |
| EP1656991B1 (en) | 2009-04-01 |
| CA2586727A1 (en) | 2006-05-26 |
| DE602005013629D1 (de) | 2009-05-14 |
| JP4979586B2 (ja) | 2012-07-18 |
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