RU2003128601A - Способ получения синтез-газа - Google Patents
Способ получения синтез-газа Download PDFInfo
- Publication number
- RU2003128601A RU2003128601A RU2003128601/15A RU2003128601A RU2003128601A RU 2003128601 A RU2003128601 A RU 2003128601A RU 2003128601/15 A RU2003128601/15 A RU 2003128601/15A RU 2003128601 A RU2003128601 A RU 2003128601A RU 2003128601 A RU2003128601 A RU 2003128601A
- Authority
- RU
- Russia
- Prior art keywords
- reforming
- steam
- adiabatic
- endothermic
- gas
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
Claims (10)
1. Способ получения синтез-газа из углеводородного сырья, включающий стадии эндотермического и/или адиабатического каталитического реформинга с водяным паром и автотермического реформинга с водяным паром последовательно, где реформинг с водяным паром проводят в одну или более эндотермических стадий последовательно и/или в одну или более адиабатических стадий реформинга с водяным паром последовательно с промежуточным нагреванием газообразного сырья, отводимого со стадий адиабатического реформинга, и где содержащий моноксид углерода газ, характеризующийся тем, что имеет мольное соотношение водорода к углероду менее 4,5, добавляют перед, по меньшей мере, одной из эндотермических или адиабатических стадий реформинга с водяным паром и/или перед стадией автотермического реформинга с водяным паром.
2. Способ по п.1, включающий дополнительно стадию адиабатического предварительного реформинга сырья перед эндотермическим или адиабатическим реформингом с водяным паром.
3. Способ по п.1, где эндотермический или адиабатический реформинг с водяным паром проводят в присутствии каталитического средства.
4. Способ по п.3, где каталитическое средство находится в форме керамического монолита или складчатой керамической структуры.
5. Способ по п.1, где эндотермическую стадию реформинга с водяным паром проводят в теплопроводящей связи с горячим перерабатываемым газом.
6. Способ по п.5, где горячий перерабатываемый газ представляет собой поток, отходящий из автотермической реформинг- установки.
7. Способ по п.1, где промежуточное нагревание реагирующего сырья проводят в теплопроводящей связи с горячим перерабатываемым газом.
8. Способ по п.7, где горячий перерабатываемый газ представляет собой поток, отходящий из автотермической реформинг - установки.
9. Способ по любому из предшествующих пунктов, где содержащий моноксид углерода газ представляет собой остаточный газ из процесса Фишера-Тропша.
10. Система реформинга с водяным паром для использования в способе производства синтез-газа из углеводородного сырья, включающая: необязательно, установку предварительного реформинга для адиабатического предварительного реформинга сырья; установку эндотермического каталитического реформинга с водяным паром и/или, по меньшей мере, первую и последнюю адиабатические установки каталитического реформинга с водяным паром, соединенные последовательно; средства для промежуточного нагревания сырья между, по меньшей мере, первой и последней адиабатическими реформинг-установками с водяным паром; автотермическую реформинг-установку с водяным паром с нисходящим потоком, соединенную последовательно с установкой для эндотермического реформинга с водяным паром или с последней адиабатической реформинг-установкой с водяным паром; и средства для добавления содержащего монооксид углерода газа, расположенные выше по потоку эндотермической реформинг-установки с водяным паром или выше по потоку, по меньшей мере, первой и/или последней адиабатических реформинг-установок и/или выше по потоку автотермической реформинг-установки.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA200201435 | 2002-09-26 | ||
DKPA200201435 | 2003-09-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2003128601A true RU2003128601A (ru) | 2005-03-27 |
RU2342318C2 RU2342318C2 (ru) | 2008-12-27 |
Family
ID=29414640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2003128601/04A RU2342318C2 (ru) | 2002-09-26 | 2003-09-25 | Способ получения синтез-газа |
Country Status (10)
Country | Link |
---|---|
US (2) | US7241401B2 (ru) |
EP (1) | EP1413547A1 (ru) |
JP (1) | JP4807929B2 (ru) |
KR (1) | KR101003727B1 (ru) |
CN (1) | CN1310828C (ru) |
AU (1) | AU2003248389B2 (ru) |
CA (1) | CA2442491C (ru) |
NO (1) | NO20034285L (ru) |
RU (1) | RU2342318C2 (ru) |
ZA (1) | ZA200307450B (ru) |
Cited By (1)
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---|---|---|---|---|
RU2503613C2 (ru) * | 2008-12-03 | 2014-01-10 | КЕЛЛОГГ БРАУН ЭНД РУТ ЭлЭлСи | Способ производства синтез-газа |
Families Citing this family (42)
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-
2003
- 2003-09-11 EP EP03020673A patent/EP1413547A1/en not_active Withdrawn
- 2003-09-23 US US10/667,389 patent/US7241401B2/en active Active
- 2003-09-24 JP JP2003331066A patent/JP4807929B2/ja not_active Expired - Fee Related
- 2003-09-25 AU AU2003248389A patent/AU2003248389B2/en not_active Ceased
- 2003-09-25 ZA ZA200307450A patent/ZA200307450B/xx unknown
- 2003-09-25 NO NO20034285A patent/NO20034285L/no not_active Application Discontinuation
- 2003-09-25 RU RU2003128601/04A patent/RU2342318C2/ru active
- 2003-09-25 CA CA2442491A patent/CA2442491C/en not_active Expired - Lifetime
- 2003-09-26 KR KR1020030066831A patent/KR101003727B1/ko not_active IP Right Cessation
- 2003-09-26 CN CNB031648800A patent/CN1310828C/zh not_active Expired - Lifetime
-
2007
- 2007-06-06 US US11/759,096 patent/US7717971B2/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2503613C2 (ru) * | 2008-12-03 | 2014-01-10 | КЕЛЛОГГ БРАУН ЭНД РУТ ЭлЭлСи | Способ производства синтез-газа |
Also Published As
Publication number | Publication date |
---|---|
KR20040027440A (ko) | 2004-04-01 |
NO20034285D0 (no) | 2003-09-25 |
CN1498850A (zh) | 2004-05-26 |
NO20034285L (no) | 2004-03-29 |
AU2003248389B2 (en) | 2010-03-18 |
RU2342318C2 (ru) | 2008-12-27 |
US20040063797A1 (en) | 2004-04-01 |
ZA200307450B (en) | 2004-07-06 |
CA2442491C (en) | 2011-07-05 |
CA2442491A1 (en) | 2004-03-26 |
US7241401B2 (en) | 2007-07-10 |
EP1413547A1 (en) | 2004-04-28 |
JP4807929B2 (ja) | 2011-11-02 |
CN1310828C (zh) | 2007-04-18 |
KR101003727B1 (ko) | 2010-12-23 |
AU2003248389A1 (en) | 2004-04-22 |
US20070231221A1 (en) | 2007-10-04 |
JP2004149406A (ja) | 2004-05-27 |
US7717971B2 (en) | 2010-05-18 |
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