RU1830060C - Способ разложени гидроперекиси циклогексила - Google Patents

Способ разложени гидроперекиси циклогексила

Info

Publication number
RU1830060C
RU1830060C SU894742257A SU4742257A RU1830060C RU 1830060 C RU1830060 C RU 1830060C SU 894742257 A SU894742257 A SU 894742257A SU 4742257 A SU4742257 A SU 4742257A RU 1830060 C RU1830060 C RU 1830060C
Authority
RU
Russia
Prior art keywords
cyclohexyl hydroperoxide
hydroperoxide
carried out
decomposing
complex
Prior art date
Application number
SU894742257A
Other languages
English (en)
Inventor
Анна Христиан Баур Хенрикус
Францискус Крагтен Убальдус
Original Assignee
Стамикарбон Б.В. (Лайсенсинг Сабсидиари Ов Дсм)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Стамикарбон Б.В. (Лайсенсинг Сабсидиари Ов Дсм) filed Critical Стамикарбон Б.В. (Лайсенсинг Сабсидиари Ов Дсм)
Application granted granted Critical
Publication of RU1830060C publication Critical patent/RU1830060C/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Использование: получение циклогекса- нола и/или циклогексанона, комплексы переходных металлов. Сущность изобретени : при разложении гидроперекиси циклогек- сила в качестве катализатора используют порфириновый или фталоцианиновый комплекс металла, выбранного из группы: хром, кобальт, марганец, железо, ванадий, медь, ковалентно св занный с носителем - двуокисью кремни  или полистиролом. Процесс провод т при концентрации катализатора в расчете на металл в составе комплекса 10-150 м,д. от смеси, содержащей гидроперекись. Предпочтительно разложение гидроперекиси циклогексила провод т в присутствии кислорода. 1 з.п. ф-лы.
SU894742257A 1988-10-21 1989-10-20 Способ разложени гидроперекиси циклогексила RU1830060C (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8802592A NL8802592A (nl) 1988-10-21 1988-10-21 Werkwijze voor de bereiding van een k/a-mengsel.

Publications (1)

Publication Number Publication Date
RU1830060C true RU1830060C (ru) 1993-07-23

Family

ID=19853094

Family Applications (1)

Application Number Title Priority Date Filing Date
SU894742257A RU1830060C (ru) 1988-10-21 1989-10-20 Способ разложени гидроперекиси циклогексила

Country Status (19)

Country Link
US (1) US5004837A (ru)
EP (1) EP0367326B1 (ru)
JP (1) JPH02164836A (ru)
KR (1) KR920000904B1 (ru)
CN (1) CN1025025C (ru)
AR (1) AR245436A1 (ru)
AT (1) ATE99278T1 (ru)
AU (1) AU616315B2 (ru)
BR (1) BR8905349A (ru)
CA (1) CA2001000C (ru)
DE (1) DE68911859T2 (ru)
ES (1) ES2061948T3 (ru)
GE (1) GEP19960458B (ru)
HU (1) HU204754B (ru)
MX (1) MX172660B (ru)
NL (1) NL8802592A (ru)
PT (1) PT92027B (ru)
RU (1) RU1830060C (ru)
SK (1) SK596289A3 (ru)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9000893A (nl) * 1990-04-14 1991-11-01 Stamicarbon Werkwijze voor de bereiding van een cycloalkanon en/of cycloalkanol.
NL9100521A (nl) * 1991-03-25 1992-10-16 Stamicarbon Werkwijze voor de bereiding van een alkanon en/of alkanol.
US5120886A (en) * 1991-07-09 1992-06-09 Sun Refining And Marketing Company Decomposition of organic hydroperoxides
US5345008A (en) * 1993-06-09 1994-09-06 Sun Company, Inc. (R&M) Decomposition of organic hydroperoxides with nitrated porphyrin complexes
US5395988A (en) * 1994-04-04 1995-03-07 Sun Company, Inc. (R&M) Metal-ligand catalyzed decomposition of organic hydroperoxides
US5550301A (en) * 1994-04-04 1996-08-27 Sun Company, Inc. (R&M) Dried catalytic systems for decomposition of organic hydroperoxides
CN1063419C (zh) * 1994-04-22 2001-03-21 肖藻生 从环己烷制备环己醇、环己酮的工艺
IN192732B (ru) * 1995-09-29 2004-05-15 Council Scient Ind Res
EP1012130B9 (en) 1997-02-11 2003-05-02 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition process
US6160183A (en) * 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes
FR2802526B1 (fr) * 1999-12-17 2003-04-18 Rhodia Polyamide Intermediates Procede de preparation de melanges alcools/cetones
EP1309534B1 (en) * 2000-08-18 2005-10-19 INVISTA Technologies S.à.r.l. Improved hydroperoxide decomposition catalyst
TW200604151A (en) * 2004-04-30 2006-02-01 Sumitomo Chemical Co Process for producing cycloalkanol and/or cycloalkanone
JP4736368B2 (ja) * 2004-07-22 2011-07-27 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
JP2006069977A (ja) * 2004-09-03 2006-03-16 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
US7442841B2 (en) * 2006-08-18 2008-10-28 Invista North America S.A R.L. Extraction process
CN102671708A (zh) * 2012-03-06 2012-09-19 广西大学 用两性勃姆石离子键接枝固载四(4-羧基苯基)金属卟啉的方法
CN105237355B (zh) * 2015-10-28 2018-03-27 江西科苑生物药业有限公司 一种环戊烷氧化制备环戊醇和环戊酮的方法
CN113231105B (zh) * 2021-05-31 2022-03-29 华中科技大学 二氧化锰负载金属酞菁复合材料及制备与降解抗生素应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1530986A (fr) * 1966-07-11 1968-06-28 Ici Ltd Procédé d'oxydation d'hydrocarbures
US3816548A (en) * 1971-04-27 1974-06-11 Mobil Oil Corp Catalytic oxidation process for isoparaffin hydrocarbons
US3816348A (en) * 1972-04-24 1974-06-11 Du Pont Compositions for stable low resistivity resistors
US4326084A (en) * 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
US4459427A (en) * 1981-10-31 1984-07-10 The British Petroleum Company P.L.C. Process for the conversion of an alkane to a mixture of an alcohol and a ketone
DE3222143A1 (de) * 1982-06-11 1983-12-15 Basf Ag, 6700 Ludwigshafen Kobalt enthaltende traegerkatalysatoren, deren herstellung und verwendung
US4482746A (en) * 1983-04-11 1984-11-13 E. I. Du Pont De Nemours & Company Staged catalyst process for cyclohexyl hydroperoxide decomposition
US4499305A (en) * 1983-04-11 1985-02-12 E. I. Du Pont De Nemours And Company Process for preparation of cyclohexyl hydroperoxide decomposition catalysts
JPS60126237A (ja) * 1983-12-14 1985-07-05 Sumitomo Chem Co Ltd シクロアルカンの酸化によるケトンおよびアルコ−ルの製造法
EP0157657B1 (fr) * 1984-01-31 1988-09-14 Institut Français du Pétrole Complexes peroxydiques de métaux, leur préparation et leur utilisation dans les réactions d'oxydations d'hydrocarbures en alcools et/ou cetone
FR2607805B1 (fr) * 1986-12-05 1989-03-24 Rhone Poulenc Chimie Procede de preparation d'un melange renfermant du cyclohexanol et de la cyclohexanone a partir du cyclohexane

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Патент JP А-60-126237, кл. С 07 С 27/12, опублик. 1985. *

Also Published As

Publication number Publication date
HU895393D0 (en) 1990-01-28
EP0367326B1 (en) 1993-12-29
JPH02164836A (ja) 1990-06-25
GEP19960458B (en) 1996-05-13
DE68911859T2 (de) 1994-07-14
CN1025025C (zh) 1994-06-15
HU204754B (en) 1992-02-28
AU4355089A (en) 1990-04-26
MX172660B (es) 1994-01-06
US5004837A (en) 1991-04-02
CA2001000C (en) 1999-12-14
ES2061948T3 (es) 1994-12-16
EP0367326A1 (en) 1990-05-09
PT92027B (pt) 1995-08-09
PT92027A (pt) 1990-04-30
AU616315B2 (en) 1991-10-24
KR900006268A (ko) 1990-05-07
HUT52747A (en) 1990-08-28
AR245436A1 (es) 1994-01-31
NL8802592A (nl) 1990-05-16
KR920000904B1 (ko) 1992-01-31
SK280850B6 (sk) 2000-08-14
ATE99278T1 (de) 1994-01-15
SK596289A3 (en) 2000-08-14
BR8905349A (pt) 1990-05-22
CN1041937A (zh) 1990-05-09
CA2001000A1 (en) 1990-04-21
DE68911859D1 (de) 1994-02-10

Similar Documents

Publication Publication Date Title
RU1830060C (ru) Способ разложени гидроперекиси циклогексила
Ohtake et al. Highly efficient oxidation of alkanes and alkyl alcohols with heteroaromatic N-oxides catalyzed by ruthenium porphyrins
TW240176B (ru)
ATE74333T1 (de) Katalytisches verfahren zur herstellung von wasserstoffperoxyd aus wasserstoff und sauerstoff mittels eines bromidpromotor.
Battioni et al. Reactivity of polyhalogenated and zeolite-encapsulated metalloporphyrins in oxidation with dioxygen
RU94044355A (ru) Способ получения алканона и/или алканола
DE69122402D1 (de) Verfahren zur Herstellung von Sauerstoffsäuren aus Kohlenhydraten
GB1442965A (en) Process for the manufacture of ketoisophorone
ATE10485T1 (de) Verfahren zur oxidation von reaktiven aromaten.
AU4781990A (en) Recovery of hydrogen peroxide
De Poorter et al. Metalloporphyrin-catalysed epoxidation of terminal aliphatic olefins with hypochlorite salts or potassium hydrogen persulphate
Larsson et al. A catalytic system for allylic acetoxylation consisting of palladium (II) and nitrate and using oxygen as final oxidant
FR2654364B1 (fr) Catalyseur pour realiser l'oxydation ou la decomposition d'un gaz contenant des constituants odoriferants, procede et applications utilisant un tel catalyseur.
ES8201520A1 (es) Procedimiento para la preparacion de un acido bencenocarbo- xilico
RU94003019A (ru) Способ получения никотиновой кислоты
ATE126199T1 (de) Verfahren zur herstellung von trimellithsäure.
ATE63471T1 (de) Verfahren zur katalytischen reduktion von no.
DE69228114D1 (de) Verfahren zur Herstellung von Gamma-Butyrolacton
KR860003196A (ko) 신나메이트 에스테르의 제조방법
Momenteau Models of hemoprotein active sites
KR880011107A (ko) 7-클로로퀴놀린-8-카르복실산의 제조방법
JPS55102528A (en) Preparation of carbonyl compound
WANG et al. Oxidation of aromatic aldehydes in the presence of metallotetraphenylporphyrins
Iwanejko et al. Metalloporphyrin-catalyzed oxidation of cyclohexane with dioxygen
TH10975EX (th) กระบวนการสำหรับการเตรียมไซโคลอัลคาโนนและ/หรือไซโคลอัลคานอล