PL428878A1 - Method for producing powder kesterite of Cu₂SnZnS₄ type - Google Patents

Method for producing powder kesterite of Cu₂SnZnS₄ type

Info

Publication number
PL428878A1
PL428878A1 PL428878A PL42887819A PL428878A1 PL 428878 A1 PL428878 A1 PL 428878A1 PL 428878 A PL428878 A PL 428878A PL 42887819 A PL42887819 A PL 42887819A PL 428878 A1 PL428878 A1 PL 428878A1
Authority
PL
Poland
Prior art keywords
kesterite
cu2snzns4
type
hours
powder
Prior art date
Application number
PL428878A
Other languages
Polish (pl)
Other versions
PL241410B1 (en
Inventor
Jerzy Franciszek Janik
Mariusz Drygaś
Katarzyna Kapusta
Original Assignee
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie filed Critical Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Priority to PL428878A priority Critical patent/PL241410B1/en
Publication of PL428878A1 publication Critical patent/PL428878A1/en
Publication of PL241410B1 publication Critical patent/PL241410B1/en

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/541—CuInSe2 material PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Luminescent Compositions (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób wytwarzania proszkowego kesterytu typu Cu2SnZnS4, który polega na tym, że odważa się proszki metali Cu, Sn i Zn w proporcji molowej Cu:Sn:Zn = 2:1:1 i miesza w wysokoenergetycznym młynie kulowym z dodatkiem cieczy dyspergującej w postaci wysokowrzących ciekłych węglowodorów alifatycznych lub aromatycznych wybranych z grupy obejmującej heksan, toluen i ksylen przez okres od 30 minut do 100 godzin, przy prędkości obrotowej młyna od 200 do 1100 obr/min, po czym do mieszaniny dodaje się siarkę elementarną w ilości od stechiometrycznej do 100% nadmiaru w stosunku do ilości teoretycznej siarki występującej w kesterycie typu Cu2SnZnS4 i dalej mieli przez okres od 30 minut do 100 godzin przy prędkości obrotowej młyna kulowego od 200 do 1100 obr/min, następnie odparowuje się ciecz dyspergującą, a uzyskaną mieszaninę ogrzewa się w atmosferze gazu obojętnego w temperaturze od 400 do 700°C przez okres od 0,5 do 36 godzin, uzyskując proszkowy czysty kesteryt o średniej wielkości krystalitów w zakresie od 10 do 200 nm.The subject of the application is a method for the production of Cu2SnZnS4 type kesterite powder, which consists in weighing the powders of metals Cu, Sn and Zn in the molar ratio of Cu: Sn: Zn = 2: 1: 1 and mixed in a high-energy ball mill with the addition of a dispersing liquid in forms of high-boiling liquid aliphatic or aromatic hydrocarbons selected from the group consisting of hexane, toluene and xylene for a period of 30 minutes to 100 hours, at the rotational speed of the mill from 200 to 1100 rpm, then elemental sulfur in an amount ranging from stoichiometric to 100% excess in relation to the theoretical amount of sulfur present in the Cu2SnZnS4 type kesterite and further ground for a period from 30 minutes to 100 hours at the rotational speed of the ball mill from 200 to 1100 rpm, then the dispersing liquid is evaporated and the resulting mixture is heated in atmosphere of inert gas at a temperature of 400 to 700 ° C for 0.5 to 36 hours, obtaining pure kesterite powder with a mean lower crystallite sizes ranging from 10 to 200 nm.

PL428878A 2019-02-11 2019-02-11 Method for producing powder kesterite of Cu₂SnZnS₄ type PL241410B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL428878A PL241410B1 (en) 2019-02-11 2019-02-11 Method for producing powder kesterite of Cu₂SnZnS₄ type

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL428878A PL241410B1 (en) 2019-02-11 2019-02-11 Method for producing powder kesterite of Cu₂SnZnS₄ type

Publications (2)

Publication Number Publication Date
PL428878A1 true PL428878A1 (en) 2019-10-21
PL241410B1 PL241410B1 (en) 2022-09-26

Family

ID=68238701

Family Applications (1)

Application Number Title Priority Date Filing Date
PL428878A PL241410B1 (en) 2019-02-11 2019-02-11 Method for producing powder kesterite of Cu₂SnZnS₄ type

Country Status (1)

Country Link
PL (1) PL241410B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL441793A1 (en) * 2022-07-20 2023-07-03 Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie Method of producing sinters from nanopowders of the kesterite Cu2ZnSnS4 type semiconductor

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010135622A1 (en) * 2009-05-21 2010-11-25 E. I. Du Pont De Nemours And Company Copper zinc tin chalcogenide nanoparticles
US20120055554A1 (en) * 2009-05-21 2012-03-08 E.I. Du Pont De Nemours And Company Copper zinc tin chalcogenide nanoparticles
US20120100664A1 (en) * 2010-10-26 2012-04-26 International Business Machines Corporation Fabricating kesterite solar cells and parts thereof
US8366975B2 (en) * 2010-05-21 2013-02-05 E I Du Pont De Nemours And Company Atypical kesterite compositions
US20130037111A1 (en) * 2011-08-10 2013-02-14 International Business Machines Corporation Process for Preparation of Elemental Chalcogen Solutions and Method of Employing Said Solutions in Preparation of Kesterite Films
PL406175A1 (en) * 2013-11-21 2015-05-25 Stanley Aleksander Rokicki Carrying composite of photovoltaic cells
US20180069146A1 (en) * 2016-09-02 2018-03-08 International Business Machines Corporation Minimizing Tin Loss During Thermal Processing of Kesterite Films
WO2018065156A1 (en) * 2016-10-07 2018-04-12 Haldor Topsøe A/S KESTERITE MATERIAL OF CZTS, CZTSe OR CZTSSe TYPE
PL229752B1 (en) * 2014-10-27 2018-08-31 Politechnika Slaska Photovoltaic dye cell and method for producing it

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010135622A1 (en) * 2009-05-21 2010-11-25 E. I. Du Pont De Nemours And Company Copper zinc tin chalcogenide nanoparticles
US20120055554A1 (en) * 2009-05-21 2012-03-08 E.I. Du Pont De Nemours And Company Copper zinc tin chalcogenide nanoparticles
US8366975B2 (en) * 2010-05-21 2013-02-05 E I Du Pont De Nemours And Company Atypical kesterite compositions
US20120100664A1 (en) * 2010-10-26 2012-04-26 International Business Machines Corporation Fabricating kesterite solar cells and parts thereof
US20130037111A1 (en) * 2011-08-10 2013-02-14 International Business Machines Corporation Process for Preparation of Elemental Chalcogen Solutions and Method of Employing Said Solutions in Preparation of Kesterite Films
PL406175A1 (en) * 2013-11-21 2015-05-25 Stanley Aleksander Rokicki Carrying composite of photovoltaic cells
PL229752B1 (en) * 2014-10-27 2018-08-31 Politechnika Slaska Photovoltaic dye cell and method for producing it
US20180069146A1 (en) * 2016-09-02 2018-03-08 International Business Machines Corporation Minimizing Tin Loss During Thermal Processing of Kesterite Films
WO2018065156A1 (en) * 2016-10-07 2018-04-12 Haldor Topsøe A/S KESTERITE MATERIAL OF CZTS, CZTSe OR CZTSSe TYPE

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WOJSKOWA AKADEMIA TECHNICZNA IM. A ZASTRZEŻENIE JAROSŁAWA DĄBROWSKIEGO, ADVANCES IN CZTS THIN FILMS AND NANOSTRUCTURED, 201S *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL441793A1 (en) * 2022-07-20 2023-07-03 Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie Method of producing sinters from nanopowders of the kesterite Cu2ZnSnS4 type semiconductor

Also Published As

Publication number Publication date
PL241410B1 (en) 2022-09-26

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