PL3110868T3 - Utwardzalne wodne dyspersje poliuretanowe wykonane z zasobów odnawialnych - Google Patents

Utwardzalne wodne dyspersje poliuretanowe wykonane z zasobów odnawialnych

Info

Publication number
PL3110868T3
PL3110868T3 PL15706041T PL15706041T PL3110868T3 PL 3110868 T3 PL3110868 T3 PL 3110868T3 PL 15706041 T PL15706041 T PL 15706041T PL 15706041 T PL15706041 T PL 15706041T PL 3110868 T3 PL3110868 T3 PL 3110868T3
Authority
PL
Poland
Prior art keywords
aqueous polyurethane
renewable resources
polyurethane dispersions
curable aqueous
dispersions made
Prior art date
Application number
PL15706041T
Other languages
English (en)
Inventor
Jeffrey Klang
Jin Lu
Indu VAPPALA
Yuhong He
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of PL3110868T3 publication Critical patent/PL3110868T3/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/428—Lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
PL15706041T 2014-02-28 2015-02-25 Utwardzalne wodne dyspersje poliuretanowe wykonane z zasobów odnawialnych PL3110868T3 (pl)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201461946016P 2014-02-28 2014-02-28
US201461986170P 2014-04-30 2014-04-30
PCT/EP2015/053924 WO2015128373A1 (en) 2014-02-28 2015-02-25 Curable aqueous polyurethane dispersions made from renewable resources
EP15706041.9A EP3110868B1 (en) 2014-02-28 2015-02-25 Curable aqueous polyurethane dispersions made from renewable resources

Publications (1)

Publication Number Publication Date
PL3110868T3 true PL3110868T3 (pl) 2020-05-18

Family

ID=52574172

Family Applications (1)

Application Number Title Priority Date Filing Date
PL15706041T PL3110868T3 (pl) 2014-02-28 2015-02-25 Utwardzalne wodne dyspersje poliuretanowe wykonane z zasobów odnawialnych

Country Status (7)

Country Link
US (1) US20160362515A1 (pl)
EP (1) EP3110868B1 (pl)
CN (1) CN106068293B (pl)
ES (1) ES2773655T3 (pl)
PL (1) PL3110868T3 (pl)
TW (1) TWI565730B (pl)
WO (1) WO2015128373A1 (pl)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3137530T3 (pl) * 2014-04-30 2020-09-07 Arkema France Utwardzalne wodne dyspersje poliuretanowe wytwarzane z surowców odnawialnych
CN105885004A (zh) * 2016-06-22 2016-08-24 江南大学 一种生物基光固化聚氨酯及其制备的光刻胶
WO2018058016A1 (en) * 2016-09-25 2018-03-29 Myriant Corporation Biorenewable high performance polyester polyols
US10573772B2 (en) * 2017-05-22 2020-02-25 Swift Engineering, Inc. Composite vehicle skin co-cured with solar-cell array
WO2019084243A1 (en) 2017-10-25 2019-05-02 Sun Chemical Corporation ACTINICALLY CURABLE ADHESIVE COMPOSITION HAVING IMPROVED PROPERTIES
CN107857869B (zh) * 2017-11-27 2018-08-28 上海金狮化工有限公司 水性聚氨酯及其制备方法和应用
EP3636321A1 (en) * 2018-10-10 2020-04-15 Covestro Deutschland AG Polyurethane urea dispersions at least partially originated from renewable sources and their production and uses
WO2020122954A1 (en) * 2018-12-14 2020-06-18 Hewlett-Packard Development Company, L.P. Textile printing
EP3986948A1 (en) * 2019-06-18 2022-04-27 Allnex Belgium, S.A. Biobased urethane (meth)acrylate for use in cladding
JP7459626B2 (ja) 2020-04-02 2024-04-02 ａｒｔｉｅｎｃｅ株式会社 水性グラビアまたはフレキソインキ、およびその利用
TW202200655A (zh) * 2020-06-23 2022-01-01 日商Ｄｉｃ股份有限公司 胺基甲酸酯樹脂組成物、皮膜、及合成皮革
CN112480350B (zh) * 2020-11-06 2022-04-05 中国科学院化学研究所 亲水性聚氨酯及其制备方法、生物打印复合材料和应用
KR102442189B1 (ko) * 2021-02-17 2022-09-13 주식회사 삼양사 내유성 및 접착성이 향상된 금속용 코팅 조성물 및 그 제조 방법, 및 이 조성물로 코팅된 금속 물품
CN114517035B (zh) * 2021-12-29 2023-04-14 广东大自然家居科技研究有限公司 水性植物基清面漆及其制备方法、木器
US11530332B1 (en) * 2022-07-12 2022-12-20 Evoco Limited Biobased aqueous polyurethane dispersions

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19722862C1 (de) * 1997-05-31 1999-01-14 Basf Coatings Ag Wäßriger Lack und dessen Verwendung zur Herstellung einer zweischichtigen Lackierung
US6140422A (en) * 1998-04-23 2000-10-31 E.I. Dupont De Nemours And Company Polyesters including isosorbide as a comonomer blended with other thermoplastic polymers
GB0207345D0 (en) * 2002-03-28 2002-05-08 Unichema Chemie Bv Polyurethane
JP5025483B2 (ja) * 2004-10-26 2012-09-12 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド オイル変性ウレタン重合体の水媒介分散体
US20070149704A1 (en) * 2005-06-17 2007-06-28 Reichhold, Inc. Radiation curable polyurethane dispersions
EP1845143A1 (en) * 2006-04-14 2007-10-17 Cytec Surface Specialties, S.A. Aqueous radiation curable polyurethane compositions
DE102010009896A1 (de) * 2010-03-02 2011-09-08 Bayer Materialscience Ag Wässrige Polyurethandispersionen
EP2644634A1 (en) * 2012-03-30 2013-10-02 Cytec Surface Specialties, S.A. Radiation curable (meth)acrylated compounds

Also Published As

Publication number Publication date
US20160362515A1 (en) 2016-12-15
TWI565730B (zh) 2017-01-11
WO2015128373A1 (en) 2015-09-03
EP3110868B1 (en) 2019-11-13
ES2773655T3 (es) 2020-07-14
EP3110868A1 (en) 2017-01-04
CN106068293B (zh) 2021-08-10
TW201546117A (zh) 2015-12-16
CN106068293A (zh) 2016-11-02

Similar Documents

Publication Publication Date Title
PL3110868T3 (pl) Utwardzalne wodne dyspersje poliuretanowe wykonane z zasobów odnawialnych
PL3137530T3 (pl) Utwardzalne wodne dyspersje poliuretanowe wytwarzane z surowców odnawialnych
PL3127187T3 (pl) Zespół antenowy
GB2524056B (en) Connection assembly
GB2525662B (en) Free-flex harness
GB201413163D0 (en) Energy resource system
PT3002841T (pt) Conjunto de remoção de cabo
PL3253812T3 (pl) Wodne dyspersje poliuretanowe
PL3207273T3 (pl) Zespół amortyzatora
GB2521836B (en) Hydrokinetic system
GB2544021B (en) Well assembly
HK1225829A1 (zh) 程序
GB201410264D0 (en) An assembly
GB201402585D0 (en) Polyurethane dispersions
GB2547859B (en) Membrane-seal assembly
GB201412295D0 (en) Generator assembly
GB2554706B (en) Membrane-seal assembly
PL3009460T3 (pl) Wodne dyspersje poliuretanowe stabilizowane peptydem
GB201405378D0 (en) An assembly
GB201515139D0 (en) Step assembly
SG11201704507YA (en) Rivet
TWM490525U (en) Fixed buckling member
GB201412813D0 (en) An assembly
EP3222767A4 (en) Laundry method
GB201409897D0 (en) Beam assembly