PE20130759A1 - Deshidratacion e isomerizacion esqueletica simultaneas de isobutanol en catalizadores acidos - Google Patents
Deshidratacion e isomerizacion esqueletica simultaneas de isobutanol en catalizadores acidosInfo
- Publication number
- PE20130759A1 PE20130759A1 PE2012001548A PE2012001548A PE20130759A1 PE 20130759 A1 PE20130759 A1 PE 20130759A1 PE 2012001548 A PE2012001548 A PE 2012001548A PE 2012001548 A PE2012001548 A PE 2012001548A PE 20130759 A1 PE20130759 A1 PE 20130759A1
- Authority
- PE
- Peru
- Prior art keywords
- isobutanol
- group
- euo
- mww
- mfs
- Prior art date
Links
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 title abstract 8
- 230000018044 dehydration Effects 0.000 title abstract 2
- 238000006297 dehydration reaction Methods 0.000 title abstract 2
- 238000006317 isomerization reaction Methods 0.000 title abstract 2
- 239000003377 acid catalyst Substances 0.000 title 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001282 iso-butane Substances 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
- C07C11/09—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2518—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
QUE COMPRENDE: a) INTRODUCIR EN UN REACTOR UNA CORRIENTE (A) QUE COMPRENDE ISOBUTANOL, OPCIONALMENTE AGUA Y OPCIONALMENTE UN COMPONENTE INERTE; b) PONER EN CONTACTO DICHA CORRIENTE CON UN CATALIZADOR EN DICHO REACTOR EN CONDICIONES EFICACES PARA DESHIDRATAR E ISOMERIZAR EL ESQUELETO DE AL MENOS UNA PORCION DEL ISOBUTANOL, DANDO UNA MEZCLA DE n-BUTENOS E ISOBUTENO; c) RECUPERAR DE DICHO REACTOR UNA CORRIENTE (B), RETIRAR EL AGUA, EL COMPONENTE INERTE SI LO HUBIERA Y EL ISOBUTANOL NO CONVERTIDO SI LO HUBIERA PARA CONSEGUIR UNA MEZCLA DE n-BUTENOS E ISOBUTENO, EN EL QUE LA WHSV DEL ISOBUTANOL ES DE AL MENOS 1 h-1 Y EL CATALIZADOR ES CAPAZ DE REALIZAR SIMULTANEAMENTE LA DESHIDRATACION E ISOMERIZACION ESQUELETICA DEL BUTENO Y ES UN SILICATO CRISTALINO DEL GRUPO DE FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL O TON QUE TIENE UNA Si/Al SUPERIOR A 10, O UN SILICATO CRSITALINO DESALUMINADO DEL GRUPO DE FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL O TON QUE TIENE UNA Si/Al SUPERIOR A 10, O UN SILICATO CRISTALINO MODIFICADO CON FOSFORO DEL GRUPO FER, MWW, EUO, MFS, ZSM-48, MTT, MEL O TON QUE TIENE UNA Si/Al SUPERIOR A 10, O UN TAMIZ MOLECULAR DE SILICOALUMINAFOSFATO DEL GRUPO AEL, O UNA ALUMINA SILICIADA, CIRCONIADA O TITANIADA O FLUORADA
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10156537A EP2366682A1 (en) | 2010-03-15 | 2010-03-15 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
| EP10159463A EP2374781A1 (en) | 2010-04-09 | 2010-04-09 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
| EP10161125 | 2010-04-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20130759A1 true PE20130759A1 (es) | 2013-06-21 |
Family
ID=44242479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2012001548A PE20130759A1 (es) | 2010-03-15 | 2011-03-15 | Deshidratacion e isomerizacion esqueletica simultaneas de isobutanol en catalizadores acidos |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US9233886B2 (es) |
| EP (1) | EP2547638B1 (es) |
| JP (1) | JP5784646B2 (es) |
| KR (1) | KR101544257B1 (es) |
| CN (1) | CN102892729B (es) |
| AR (1) | AR080756A1 (es) |
| BR (1) | BR112012023262B1 (es) |
| CA (1) | CA2791218C (es) |
| CO (1) | CO6602154A2 (es) |
| DK (1) | DK2547638T3 (es) |
| EA (1) | EA025806B1 (es) |
| ES (1) | ES2603029T3 (es) |
| MY (1) | MY158968A (es) |
| PE (1) | PE20130759A1 (es) |
| PL (1) | PL2547638T3 (es) |
| WO (1) | WO2011113834A1 (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2583957A1 (de) * | 2011-10-18 | 2013-04-24 | LANXESS Deutschland GmbH | Lineare Butene aus Isobutanol |
| JP5797545B2 (ja) * | 2011-12-26 | 2015-10-21 | 旭化成ケミカルズ株式会社 | 触媒前駆体の熱処理方法、触媒の製造方法、並びにプロピレンの製造方法 |
| FR2988718B1 (fr) | 2012-03-29 | 2014-04-11 | Ifp Energies Now | Procede de deshydratation et d'isomerisation d'alcools utilisant un solide de type aluminosilicate non zeolithique |
| WO2015170686A1 (ja) * | 2014-05-07 | 2015-11-12 | 三菱レイヨン株式会社 | イソブタノールからイソブチレンを製造する方法 |
| EP2949635A1 (de) * | 2014-05-28 | 2015-12-02 | Linde Aktiengesellschaft | Verfahren zur Herstellung von Produktolefinen durch katalytische Dehydratisierung geeigneter Reaktanden |
| BR112017006109A2 (pt) | 2014-09-26 | 2017-12-19 | Ifp Energies Now | aluminosilicato cristalino modificado para desidratação de álcoois |
| FR3026406B1 (fr) * | 2014-09-26 | 2016-12-09 | Ifp Energies Now | Procede de deshydratation isomerisante d'une charge alcool primaire substitue en position 2 par un groupement alkyl sur un catalyseur comprenant une zeolithe de type fer |
| CN105585396B (zh) | 2014-10-20 | 2018-03-20 | 中国石油化工股份有限公司 | 一种由含氧化合物制取低碳烯烃的方法 |
| KR101871641B1 (ko) | 2015-04-22 | 2018-06-26 | 미쯔비시 케미컬 주식회사 | 이소부틸렌 제조용 촉매 및 이소부틸렌의 제조 방법 |
| KR101966773B1 (ko) | 2015-05-13 | 2019-04-08 | 주식회사 엘지화학 | 이성질화 반응을 이용한 노말부텐의 분리방법 및 노말부텐을 분리하기 위한 공정시스템 |
| WO2017005719A1 (en) | 2015-07-09 | 2017-01-12 | Total Research & Technology Feluy | Modified crystalline aluminosilicate for dehydration of alcohols |
| EP3162763A1 (en) | 2015-10-30 | 2017-05-03 | Total Research & Technology Feluy SA | Simultaneous dehydration and skeletal isomerisation of isobutanol on ti-containing zeolite catalysts |
| SG11201901292YA (en) | 2016-09-06 | 2019-03-28 | Mitsubishi Chem Corp | Method for separating and purifying isobutylene and method for producing isobutylene |
| DK3509745T3 (da) | 2016-09-09 | 2020-08-10 | Total Res & Technology Feluy | Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer |
| FR3056982A1 (fr) * | 2016-09-30 | 2018-04-06 | IFP Energies Nouvelles | Procede de production d'isoprene biosource mettant en œuvre une etape de deshydratation de butanols, une etape de metathese et une etape de deshydrogenation |
| PL3523269T3 (pl) | 2016-10-06 | 2021-10-25 | Shell Internationale Research Maatschappij B.V. | Katalizator do konwersji związków alkiloaromatycznych |
| FR3058414B1 (fr) | 2016-11-08 | 2019-08-16 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'un alcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un liant aluminique |
| FR3058415B1 (fr) | 2016-11-08 | 2018-12-07 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge alcool primaire non lineaire en presence d'injection d'eau et d' un catalyseur comprenant une zeolithe de type fer ou mfs |
| FR3058413A1 (fr) | 2016-11-08 | 2018-05-11 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin |
| CA2965062A1 (en) * | 2017-04-25 | 2018-10-25 | Nova Chemicals Corporation | Complex comprising odh unit with integrated oxygen separation module |
| CN107118069A (zh) * | 2017-06-17 | 2017-09-01 | 安徽海德石油化工有限公司 | 一种利用异丁醇脱水制备异丁烯的方法 |
| FR3068692B1 (fr) | 2017-07-10 | 2019-08-16 | IFP Energies Nouvelles | Procede de deshydratation des alcools en olefines comprenant une etape de selectivation du catalyseur |
| EP3678774A4 (en) * | 2017-09-07 | 2021-05-05 | BASF Corporation | ZEOLITE WITH REDUCED EXTRA-STRUCTURE ALUMINUM |
| FR3074803B1 (fr) | 2017-12-13 | 2019-11-29 | IFP Energies Nouvelles | Procede d’elimination simultanee d’isobutanal et d’ethanol de charges olefiniques par adsorption sur un materiau a base d’oxyde refractaire poreux |
| FR3077818B1 (fr) | 2018-02-09 | 2020-02-28 | IFP Energies Nouvelles | Procede de separation d'olefines non lineaires d'une charge olefinique par distillation reactive |
| CN108218654A (zh) * | 2018-02-12 | 2018-06-29 | 安徽海德化工科技有限公司 | 一种利用异丁醇制备异辛烷的方法 |
| FR3080546B1 (fr) | 2018-04-25 | 2022-12-16 | Ifp Energies Now | Procede de deshydratation isomerisante de monoalcool primaire non lineaire sur un catalyseur zeolithique quadrilobe de type fer |
| CN113877624B (zh) * | 2020-07-03 | 2024-01-26 | 中国石油化工股份有限公司 | 一种碳四烯烃骨架正构化方法及其应用 |
| AU2022262789A1 (en) * | 2021-04-23 | 2023-10-26 | Gevo, Inc. | Systems and processes for catalytic conversion of c1-c5 alcohols to c2-c5 olefin mixtures |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE890953C (de) | 1938-08-21 | 1953-10-29 | Basf Ag | Verfahren zur Herstellung von Butylen-Isobutylen-Gemischen |
| ZA966107B (en) * | 1995-07-21 | 1997-02-03 | Shell Int Research | Dehydration of primary alcohols. |
| US6768035B2 (en) * | 2002-01-31 | 2004-07-27 | Chevron U.S.A. Inc. | Manufacture of high octane alkylate |
| JP4431408B2 (ja) * | 2004-01-16 | 2010-03-17 | 新日本石油株式会社 | イソブテンの異性化によるｎ−ブテン類の製造方法 |
| US6977318B2 (en) | 2004-05-04 | 2005-12-20 | Equistar Chemicals, Lp | Propylene production |
| DE102005062700A1 (de) * | 2005-12-28 | 2007-07-05 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen |
| US20080132741A1 (en) | 2006-06-16 | 2008-06-05 | D Amore Michael B | Process for making butenes from dry isobutanol |
| MX2009011192A (es) | 2007-04-18 | 2009-10-30 | Du Pont | Produccion fermentativa de isobutanol con el uso de enzimas reductoisomerasas con alta actividad acida y cetolica. |
| EP2108634A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| CN104761427A (zh) * | 2008-02-07 | 2015-07-08 | 道达尔研究技术弗吕公司 | 醇在结晶硅酸盐上的脱水 |
| EP2090561A1 (en) | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| JP2011511037A (ja) * | 2008-02-07 | 2011-04-07 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | 不活性成分の存在下でのアルコールの脱水 |
| US7982086B2 (en) * | 2009-02-03 | 2011-07-19 | Catalytic Distillation Technologies | Deisobutenizer |
-
2011
- 2011-03-15 EP EP11708283.4A patent/EP2547638B1/en active Active
- 2011-03-15 PE PE2012001548A patent/PE20130759A1/es not_active Application Discontinuation
- 2011-03-15 CN CN201180024174.6A patent/CN102892729B/zh not_active Expired - Fee Related
- 2011-03-15 AR ARP110100834A patent/AR080756A1/es not_active Application Discontinuation
- 2011-03-15 EA EA201270737A patent/EA025806B1/ru not_active IP Right Cessation
- 2011-03-15 DK DK11708283.4T patent/DK2547638T3/en active
- 2011-03-15 US US13/582,759 patent/US9233886B2/en not_active Expired - Fee Related
- 2011-03-15 JP JP2012557529A patent/JP5784646B2/ja not_active Expired - Fee Related
- 2011-03-15 WO PCT/EP2011/053902 patent/WO2011113834A1/en active Application Filing
- 2011-03-15 ES ES11708283.4T patent/ES2603029T3/es active Active
- 2011-03-15 CA CA2791218A patent/CA2791218C/en not_active Expired - Fee Related
- 2011-03-15 KR KR1020127024104A patent/KR101544257B1/ko active IP Right Grant
- 2011-03-15 MY MYPI2012003837A patent/MY158968A/en unknown
- 2011-03-15 BR BR112012023262-2A patent/BR112012023262B1/pt not_active IP Right Cessation
- 2011-03-15 PL PL11708283T patent/PL2547638T3/pl unknown
-
2012
- 2012-09-14 CO CO12158684A patent/CO6602154A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| DK2547638T3 (en) | 2016-12-12 |
| JP5784646B2 (ja) | 2015-09-24 |
| WO2011113834A1 (en) | 2011-09-22 |
| KR101544257B1 (ko) | 2015-08-12 |
| CO6602154A2 (es) | 2013-01-18 |
| EP2547638B1 (en) | 2016-08-17 |
| US9233886B2 (en) | 2016-01-12 |
| ES2603029T3 (es) | 2017-02-23 |
| CA2791218A1 (en) | 2011-09-22 |
| BR112012023262B1 (pt) | 2018-06-19 |
| CA2791218C (en) | 2014-11-25 |
| AR080756A1 (es) | 2012-05-09 |
| JP2013522270A (ja) | 2013-06-13 |
| MY158968A (en) | 2016-11-30 |
| PL2547638T3 (pl) | 2017-02-28 |
| EP2547638A1 (en) | 2013-01-23 |
| CN102892729A (zh) | 2013-01-23 |
| KR20120128685A (ko) | 2012-11-27 |
| US20130204057A1 (en) | 2013-08-08 |
| EA201270737A1 (ru) | 2013-02-28 |
| CN102892729B (zh) | 2015-08-05 |
| EA025806B1 (ru) | 2017-01-30 |
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