NO996282L - Homogeneous oxidation catalysis using metal complexes - Google Patents
Homogeneous oxidation catalysis using metal complexesInfo
- Publication number
- NO996282L NO996282L NO996282A NO996282A NO996282L NO 996282 L NO996282 L NO 996282L NO 996282 A NO996282 A NO 996282A NO 996282 A NO996282 A NO 996282A NO 996282 L NO996282 L NO 996282L
- Authority
- NO
- Norway
- Prior art keywords
- point
- target compound
- lewis acid
- catalyst
- metal complexes
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/39—Actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Foreliggende oppfinnelse tilveiebringer en fremgangsmåte for å overføre oksygen til minst ett oksiderbart punkt på en målforbindelse. Fremgangsmåten inkluderer trinnene å selektivt oksidere et oksiderbart punkt på en målfor- bindelse ved reaksjon i løsning: målforbindelsen, en Kilde av oksygenatomer, en kilde av Lewis-syre, så som proton, alkali-, jordalkali-, sjeldne jordalkali-, overgangsmetall, eller hovedgruppemetallioner, og en katalysator. Kataly- satoren har den generelle strukturen (I) hvor Z fortrinns- vis er N, men kan inkludere O, og MO er en metall-okso type. Lewis-syren binder seg til et totakket punkt på Chj- substituenten for å gi et Lewis-syre katalysatorkompleks.The present invention provides a method for transferring oxygen to at least one oxidizable point on a target compound. The process includes the steps of selectively oxidizing an oxidizable point of a target compound by reaction in solution: the target compound, a source of oxygen atoms, a source of Lewis acid, such as proton, alkali, alkaline earth, rare earth alkaline, transition metal, or main group metal ions, and a catalyst. The catalyst has the general structure (I) where Z is preferably N but may include O and MO is a metal oxo type. The Lewis acid binds to a two-point point on the Chj substituent to give a Lewis acid catalyst complex.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87975297A | 1997-06-20 | 1997-06-20 | |
PCT/US1998/012749 WO1998058735A1 (en) | 1997-06-20 | 1998-06-18 | Homogeneous oxidation catalysis using metal complexes |
Publications (2)
Publication Number | Publication Date |
---|---|
NO996282D0 NO996282D0 (en) | 1999-12-17 |
NO996282L true NO996282L (en) | 2000-02-21 |
Family
ID=25374825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO996282A NO996282L (en) | 1997-06-20 | 1999-12-17 | Homogeneous oxidation catalysis using metal complexes |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP0991468A1 (en) |
JP (1) | JP2002505688A (en) |
KR (1) | KR20010013986A (en) |
CN (1) | CN1267238A (en) |
AP (1) | AP9901723A0 (en) |
AU (1) | AU8152998A (en) |
BR (1) | BR9810754A (en) |
CA (1) | CA2295006A1 (en) |
IL (1) | IL133484A0 (en) |
NO (1) | NO996282L (en) |
OA (1) | OA11237A (en) |
PL (1) | PL337523A1 (en) |
WO (1) | WO1998058735A1 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6797196B2 (en) | 2001-01-10 | 2004-09-28 | Kao Corporation | Bleaching formulation |
JP4104966B2 (en) * | 2002-03-06 | 2008-06-18 | 花王株式会社 | Bleaching catalyst |
KR100561058B1 (en) * | 2004-09-23 | 2006-03-17 | 삼성토탈 주식회사 | Catalyst for olefin polymerization including phenoxy ligand and method of (co)polymerization of olefin using the same |
JP5002761B2 (en) * | 2007-03-09 | 2012-08-15 | 国立大学法人大阪大学 | Oxoporphyrin-based electrode catalyst material |
CN104785296B (en) * | 2015-04-17 | 2017-03-08 | 中国石油大学(华东) | A kind of liquid cobalt sulfonated phthalocyanine catalyst for petroleum gas sweetening |
CN106082419B (en) * | 2016-05-10 | 2019-05-31 | 北京服装学院 | Method and application of the degradation of macrocyclic amide metal complex containing organic pollutant wastewater |
CN106111199B (en) * | 2016-06-21 | 2018-10-12 | 中南民族大学 | The nanocrystalline preparation and application of more sulfur-bearing aza porphyrin arrays |
CN112675908A (en) * | 2020-12-23 | 2021-04-20 | 清华大学 | Aerobic oxidation method of alcohols |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4758682A (en) * | 1983-03-17 | 1988-07-19 | California Institute Of Technology | Homogeneous coordination compounds as oxidation catalysts |
US5665890A (en) * | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
US5847120A (en) * | 1996-07-22 | 1998-12-08 | Carnegie Mellon University | Long-lived homogenous oxidation catalysts |
-
1998
- 1998-06-18 AU AU81529/98A patent/AU8152998A/en not_active Abandoned
- 1998-06-18 EP EP98931384A patent/EP0991468A1/en not_active Withdrawn
- 1998-06-18 IL IL13348498A patent/IL133484A0/en unknown
- 1998-06-18 AP APAP/P/1999/001723A patent/AP9901723A0/en unknown
- 1998-06-18 PL PL98337523A patent/PL337523A1/en unknown
- 1998-06-18 CN CN98808220A patent/CN1267238A/en active Pending
- 1998-06-18 JP JP50482899A patent/JP2002505688A/en active Pending
- 1998-06-18 KR KR19997012013A patent/KR20010013986A/en not_active Application Discontinuation
- 1998-06-18 BR BR9810754-2A patent/BR9810754A/en not_active Application Discontinuation
- 1998-06-18 CA CA002295006A patent/CA2295006A1/en not_active Abandoned
- 1998-06-18 WO PCT/US1998/012749 patent/WO1998058735A1/en not_active Application Discontinuation
-
1999
- 1999-12-15 OA OA9900283A patent/OA11237A/en unknown
- 1999-12-17 NO NO996282A patent/NO996282L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
IL133484A0 (en) | 2001-04-30 |
BR9810754A (en) | 2000-08-15 |
NO996282D0 (en) | 1999-12-17 |
CA2295006A1 (en) | 1998-12-30 |
EP0991468A1 (en) | 2000-04-12 |
KR20010013986A (en) | 2001-02-26 |
OA11237A (en) | 2003-05-27 |
AU8152998A (en) | 1999-01-04 |
CN1267238A (en) | 2000-09-20 |
JP2002505688A (en) | 2002-02-19 |
AP9901723A0 (en) | 1999-12-31 |
PL337523A1 (en) | 2000-08-28 |
WO1998058735A1 (en) | 1998-12-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Khan et al. | Kinetics of metal ion and metal chelate catalyzed oxidation of ascorbic acid. III. Vanadyl ion catalyzed oxidation | |
Creutz et al. | Electron-transfer reactions of excited states. Reductive quenching of the tris (2, 2'-bipyridine) ruthenium (II) luminescence | |
Siegbahn | Theoretical models for the oxygen radical mechanism of water oxidation and of the water oxidizing complex of photosystem II | |
Mitchell et al. | Proton uptake by cytochrome c oxidase on reduction and on ligand binding | |
Hamilton et al. | The hydroxylation of anisole by hydrogen peroxide in the presence of catalytic amounts of ferric ion and catechol. scope, requirements, and kinetic studies1, 2 | |
Hamilton et al. | The valence of copper and the role of superoxide in the D-galactose oxidase catalyzed reaction | |
Ehrenfeld et al. | Activation of oxygen and mediation of DNA degradation by manganese-bleomycin | |
NO996282L (en) | Homogeneous oxidation catalysis using metal complexes | |
Bortolini et al. | Metal catalysis in oxidation by peroxides. 28. Kinetics and mechanism of the molybdenum-catalyzed oxidation of sulfoxides to sulfones with hydrogen peroxide | |
Baciocchi et al. | 1, 2-and 1, 4-addition in the reactions of carbonyl compounds with 1, 3-butadiene induced by cerium (IV) ammonium nitrate | |
Wang et al. | 1, 5, 7‐Triazabicyclo [4.4. 0] dec‐5‐ene Enhances Activity of Peroxide Intermediates in Phosphine‐Free α‐Hydroxylation of Ketones | |
Samsel et al. | Radical chain mechanisms for alkyl rearrangement in organocobalt complexes | |
Sellmann et al. | The nitrogenase catalyzed N2 dependent HD formation: a model reaction and its significance for the FeMoco function | |
Hoganson et al. | From water to oxygen and back again: Mechanistic similarities in the enzymatic redox conversion between water and dioxygen | |
Brackman et al. | The oxidation of phenols with copper‐amine catalysts and its relation to the mode of action of tyrosinase V. Reaction mechanisms | |
NO20032335D0 (en) | Process for Preparation of Alkoxylated Carbonyl Compounds by Enanionic Oxidation Method Using Cathodic Coupler Reaction for Organic Synthesis | |
Santa et al. | Oxidation of tertiary amines and sulfides by an iron (III) porphyrin-O2-Na2S2O4 system as a model of cytochrome P-450 | |
Chum et al. | Photochemistry of iron (II) diimine complexes in a room temperature molten salt | |
Balakumar et al. | Application of the Marcus theory to the electron transfer reaction between benzylthioacetic acid and tris (1, 10-phenanthroline) iron (III) perchlorate | |
De Ley et al. | Intramolecular electron transport in human ferroxidase (caeruloplasmin). | |
Zhou et al. | Room Temperature Lewis Base‐Catalyzed Alumination of Terminal Alkynes | |
Dubey et al. | Kinetics and mechanism of oxidation of hypophosphorous acid by peroxomonosulphate in acid aqueous medium | |
Hatano et al. | Redox reaction of the central metal ions coordinated to tetra-(p-sulfophenyl) porphine (TPPS). I. Photoreduction of Co (III) TPPS by methanol and 2-propanol. | |
MX173297B (en) | PROCEDURE FOR PREPARING 3-AMINOPROPIL-2-SULFATE ETILSULFONE | |
O'Brien et al. | A study of the kinetics of the reduction of chromate by ascorbate under aerobic and anaerobic conditions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Withdrawal, rejection or dismissal of laid open patent application |