NO885649L - Fremgangsmaate for emulsjonspolymerisering av vinyl-alkanoat. - Google Patents

Fremgangsmaate for emulsjonspolymerisering av vinyl-alkanoat.

Info

Publication number: NO885649L
Authority: NO; Norway
Prior art keywords: approx; chain transfer; emulsion; transfer agent; vinyl
Prior art date: 1987-12-21

Application number

NO88885649A

Other languages

English (en)

Norwegian (no)

Other versions

NO885649D0 (no

Inventor

David Bretland Farmer

Bashir Hassan Qadri

Original Assignee

Unilever Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-12-21

Filing date

1988-12-20

Publication date

1989-06-22

1988-12-20 Application filed by Unilever Nv filed Critical Unilever Nv

1988-12-20 Publication of NO885649D0 publication Critical patent/NO885649D0/no

1989-06-22 Publication of NO885649L publication Critical patent/NO885649L/no

Links

238000000034 method Methods 0.000 title claims description 11
238000007720 emulsion polymerization reaction Methods 0.000 title claims description 4
229920002554 vinyl polymer Polymers 0.000 title description 5
ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 title 1
239000000839 emulsion Substances 0.000 claims description 18
NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 14
230000001070 adhesive effect Effects 0.000 claims description 12
239000000853 adhesive Substances 0.000 claims description 11
239000000178 monomer Substances 0.000 claims description 11
239000012986 chain transfer agent Substances 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 10
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 9
239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 claims description 5
150000001299 aldehydes Chemical class 0.000 claims description 5
150000001298 alcohols Chemical class 0.000 claims description 4
239000001191 butyl (2R)-2-hydroxypropanoate Substances 0.000 claims description 4
238000006116 polymerization reaction Methods 0.000 claims description 4
DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 4
230000015572 biosynthetic process Effects 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
239000001913 cellulose Substances 0.000 claims description 3
229920002678 cellulose Polymers 0.000 claims description 3
239000000203 mixture Substances 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical group [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 description 8
239000000123 paper Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
229920000642 polymer Polymers 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
238000012546 transfer Methods 0.000 description 6
230000008901 benefit Effects 0.000 description 5
239000000835 fiber Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
239000000654 additive Substances 0.000 description 2
-1 aliphatic aldehydes Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000000084 colloidal system Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
239000005022 packaging material Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
238000010008 shearing Methods 0.000 description 2
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
ISWCYPUKRLCRSG-KTKRTIGZSA-N (3z)-1,6-dioxacyclohexadec-3-ene-2,5-dione Chemical compound O=C\1OCCCCCCCCCCOC(=O)\C=C/1 ISWCYPUKRLCRSG-KTKRTIGZSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
241001315609 Pittosporum crassifolium Species 0.000 description 1
229920004482 WACKER® Polymers 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000000872 buffer Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
125000004494 ethyl ester group Chemical group 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000003999 initiator Substances 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Adhesives Or Adhesive Processes (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

NO88885649A 1987-12-21 1988-12-20 Fremgangsmaate for emulsjonspolymerisering av vinyl-alkanoat. NO885649L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB878729702A GB8729702D0 (en)	1987-12-21	1987-12-21	Emulsion polymerisation

Publications (2)

Publication Number	Publication Date
NO885649D0 NO885649D0 (no)	1988-12-20
NO885649L true NO885649L (no)	1989-06-22

Family

ID=10628794

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO88885649A NO885649L (no)	1987-12-21	1988-12-20	Fremgangsmaate for emulsjonspolymerisering av vinyl-alkanoat.

Country Status (8)

Country	Link
EP (1)	EP0322175A3 (fi)
JP (1)	JPH02138305A (fi)
AU (1)	AU2701588A (fi)
FI (1)	FI885866A (fi)
GB (1)	GB8729702D0 (fi)
NO (1)	NO885649L (fi)
PT (1)	PT89298A (fi)
ZA (1)	ZA889487B (fi)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6794466B2 (en) †	2001-10-19	2004-09-21	Air Products Polymers, L.P.	Shear thinning vinyl acetate based polymer latex composition, especially for adhesives
DE10233934A1 (de)	2002-07-25	2004-02-12	Wacker Polymer Systems Gmbh & Co. Kg	Silan-haltige Polyvinylalkohole und Polyvinylacetale
DE102006037317A1 (de)	2006-08-08	2008-02-14	Celanese Emulsions Gmbh	Vinylestercopolymer-Dispersionen, Verfahren zu deren Herstellung und Verwendung
DE102006037318A1 (de) *	2006-08-08	2008-02-14	Celanese Emulsions Gmbh	Verfahren zur Applikation eines Dispersionsklebstoffes mittels Düsenauftrag und Verwendung von Dispersionsklebstoffen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1060142B (de) *	1956-12-28	1959-06-25	Ministerul Ind Petrolului	Verfahren zur Herstellung von Polyvinylacetatperlpolymeren mit niedrigem Molekulargewicht
IT1039354B (it) *	1975-06-24	1979-12-10	Anic Spa	Procedimento per la produzione di dispersioni poliacetoviniliche e dispersioni cosi ottenute

1987
- 1987-12-21 GB GB878729702A patent/GB8729702D0/en active Pending
1988
- 1988-12-16 AU AU27015/88A patent/AU2701588A/en not_active Abandoned
- 1988-12-19 EP EP88312017A patent/EP0322175A3/en not_active Withdrawn
- 1988-12-19 FI FI885866A patent/FI885866A/fi not_active Application Discontinuation
- 1988-12-20 ZA ZA889487A patent/ZA889487B/xx unknown
- 1988-12-20 NO NO88885649A patent/NO885649L/no unknown
- 1988-12-21 JP JP63320749A patent/JPH02138305A/ja active Pending
- 1988-12-21 PT PT89298A patent/PT89298A/pt not_active Application Discontinuation

Also Published As

Publication number	Publication date
EP0322175A2 (en)	1989-06-28
JPH02138305A (ja)	1990-05-28
GB8729702D0 (en)	1988-02-03
ZA889487B (en)	1990-08-29
AU2701588A (en)	1989-06-22
FI885866A (fi)	1989-06-22
PT89298A (pt)	1989-12-29
NO885649D0 (no)	1988-12-20
FI885866A0 (fi)	1988-12-19
EP0322175A3 (en)	1989-08-02

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