NO790263L - PROCEDURE FOR CLEANING THE WASHING AND WASTE THAT APPEARS IN PREPARATION OF OLD PAPER - Google Patents

PROCEDURE FOR CLEANING THE WASHING AND WASTE THAT APPEARS IN PREPARATION OF OLD PAPER

Info

Publication number
NO790263L
NO790263L NO790263A NO790263A NO790263L NO 790263 L NO790263 L NO 790263L NO 790263 A NO790263 A NO 790263A NO 790263 A NO790263 A NO 790263A NO 790263 L NO790263 L NO 790263L
Authority
NO
Norway
Prior art keywords
washing
water
calcium
substances
soap
Prior art date
Application number
NO790263A
Other languages
Norwegian (no)
Inventor
Lothar Pfalzer
Siegbert Fischer
Original Assignee
Voith Gmbh J M
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voith Gmbh J M filed Critical Voith Gmbh J M
Publication of NO790263L publication Critical patent/NO790263L/en

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02Working-up waste paper
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/26Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
    • C02F2103/28Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Detergent Compositions (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Physical Water Treatments (AREA)
  • Water Treatment By Sorption (AREA)

Description

Oppfinnelsen vedrører en fremgangsmåte til rensing The invention relates to a method for cleaning

ved vaske- eller avvann som fremkommer ved oppberedning av gammelt papir for fremmedstoffer, spesielt for stoffer som forholder seg hydrofobt. by washing or waste water arising from the preparation of old paper for foreign substances, especially for substances that are hydrophobic.

På grunn av økologiske betingelser og vannknapphet Due to ecological conditions and water scarcity

er det nødvendig ved oppberedning av gammelt papir å kjøre mest mulig i kretsløp med det vann som anvendes. Oppberedningen av vaske- eller avvann byr imidlertid på vanskeligheter. For det meste etterrenses vaske- eller avvann i omstendelig flota-sjons- eller sedimentasjonsanlegg og innføres deretter igjen i oppberedningsprosessen. Uheldig er derved imidlertid at disse metoder er relativt omstendelig eller avvannet bare renses util-strekkelig. Foregår gammelt papir oppberedning ved en vaskefremgangsmåte, består vanskeligheter i å utskille de trykkfarvepartikler som er tilstede :i vaskevannet.1 Da vaskevannet vanlig-vis igjen tilbakeføres i prosessen, fører dette til at ved en stadig sterkere blivende anrikning med trykkfarvepartikler blir produktet alltid mørkere. when processing old paper, it is necessary to cycle as much as possible with the water used. However, the preparation of washing or waste water presents difficulties. For the most part, washing or waste water is purified in an elaborate flotation or sedimentation plant and then reintroduced into the preparation process. Unfortunately, however, these methods are relatively cumbersome or the dewatered water is only insufficiently purified. If old paper is prepared by a washing process, there are difficulties in separating the printing ink particles that are present: in the washing water.1 As the washing water is usually returned to the process, this leads to an increasingly stronger enrichment with printing ink particles, the product always becomes darker.

Til grunn for oppfinnelsen ligger følgelig den oppgave å tilveiebringe en fremgangsmåte til rensing av vaske- The invention is therefore based on the task of providing a method for cleaning laundry

eller avvannet som fremkommer ved oppberedning av gammelt papir, og hvorved det oppnås en bedre rensing av avvannet. or the waste water that arises from the preparation of old paper, and by which a better purification of the waste water is achieved.

Ifølge oppfinnelsen løses denne oppgave ved at According to the invention, this task is solved by

vannet som skal '. renses blandes med kalsiumsåper og kalsiumsåpene som virker som samlere for de hydrofobt reagerende stoffer utskilles ved sedimentasjon, flotasjon, sentrifugering eller ut-siling sammen med de hydrofobe stoffer og det rensede vann til-bakeføres igjen i oppberedningsprosessen. the water that should '. cleaned is mixed with calcium soaps and the calcium soaps, which act as collectors for the hydrophobically reacting substances, are separated by sedimentation, flotation, centrifugation or screening together with the hydrophobic substances and the purified water is fed back into the preparation process.

Det har nemlig vist seg at kalsiumsåper sammen med hydrofobt reagerende, dvs. vannavstøtende stoffer utfnokker meget godt og således kan utskilles på grunn av deres størrelse ved sedimentasjon, enkel flotasjon, siling eller sentrifugering fra vannet som skal renses. Spesielt ved rensing av vaskevann har det vist seg at trykkfarvepartiklene kan utskilles iløpet av kort tid. It has been shown that calcium soaps together with hydrophobically reacting, i.e. water-repellent, substances degrade very well and can thus be separated due to their size by sedimentation, simple flotation, screening or centrifugation from the water to be purified. Especially when cleaning washing water, it has been shown that the printing ink particles can be separated within a short time.

En fordelaktig videreutforming av oppfinnelsen består i at kalsiumsåpene behandles med terpeniske hydrokarboner eller deres alkoholer, alifatiske eller aromatiske hydrokarboner eller deres alkoholer resp. deres blandinger. Disse tilsetnings-stoffer som tilblandes til kalsiumsåpen tjener i det vesentlige som klebe- resp. bindemiddel. An advantageous further development of the invention consists in the calcium soaps being treated with terpenic hydrocarbons or their alcohols, aliphatic or aromatic hydrocarbons or their alcohols or their mixtures. These additives which are mixed into the calcium soap essentially serve as adhesives or binder.

For kjemikaliebesparelse er det derved fordelaktig når det som bærestoff for kalsiumsåpekulene anvendes stoffer med spesifikt stor overflate,på deres overflater påføres en såpe som deretter omdannes i en kalsiumsåpe. In order to save chemicals, it is therefore advantageous when substances with a specifically large surface are used as a carrier for the calcium soap balls, and a soap is applied to their surfaces which is then converted into a calcium soap.

En fordelaktig fremgangsmåte til rensing av vaskevann ved vaske-"deinken" består i at vaskevannet blandes i en blandebeholder med kalsiumsåper og i et etterfølgende skilletrinn fore-tas adskillelse av vaskevannet fra de til kalsiumsåpen hengende forurensninger. An advantageous method for purifying washing water at the washing "deinken" consists in the washing water being mixed in a mixing container with calcium soaps and in a subsequent separation step the washing water is separated from the contaminants attached to the calcium soap.

En fordelaktig utførelse av oppfinnelsen består i at skilletrinnet har en eller flere hydrocykloner. An advantageous embodiment of the invention consists in the separation step having one or more hydrocyclones.

I det følgende omtales eksempel på oppfinnelsen for en vaskefremgangsmåte. In the following, an example of the invention is described for a washing method.

Det ved vaskefremgangsmåten dannede vaskevann ifylles i en blandebeholder og blandes der intenst sammen med natriumsåpe impregnert trestoff. Når det er tilstede en tilstrekkelig høy vannhårdhet på mer enn 6° dH og en pH-verdi på ca. 10, omdannes natriumsåpen til kalsiumsåpe. Alt etter trykkfarvenes sammen-setning kan det dessuten tilsettes terpeniske hydrokarboner eller deres alkoholer, alifatiske eller aromatiske hydrokarboner eller deres alkoholer resp. deres blanding. Disse kjemikalier blandes derved best på forhånd allerede med kalsiumsåpen. The washing water produced by the washing process is filled into a mixing container and mixed intensively with sodium soap impregnated wood. When there is a sufficiently high water hardness of more than 6° dH and a pH value of approx. 10, the sodium soap is converted into calcium soap. Depending on the composition of the printing inks, terpene hydrocarbons or their alcohols, aliphatic or aromatic hydrocarbons or their alcohols or their alcohols can also be added. their mixture. These chemicals are therefore best mixed in advance already with the calcium soap.

For kjemikaliebesparelse er det også mulig å fukte opphakket kutt eller andre stoffer med spesifikk stor overflate med oljesyre som deretter forsåpes. I:'tilsvarende hårdt vann danner det seg da på hakkekuttets overflate kalsiumsåper, hvorpå da trykkfarvepartiklene og andre hydrofobt reagerende stoffer legger seg. To save chemicals, it is also possible to moisten chopped cuts or other substances with a specific large surface area with oleic acid which is then saponified. In correspondingly hard water, calcium soaps form on the surface of the chop, on which the printing ink particles and other hydrophobically reacting substances settle.

Kalsiumsåpene, hvorpå trykkfarvepartiklene legger seg, The calcium soaps, on which the ink particles settle,

faller ut under blandeprosessen i beholderen i. størrelse på falls out during the mixing process in the container i. size of

ca. 1 til 5 mm. Ved sedimentasjon, fIotasjon eller ved skilling i en hydrocyklon, kan disse fremmedstoffer deretter avsiles. about. 1 to 5 mm. By sedimentation, flotation or by separation in a hydrocyclone, these foreign substances can then be filtered out.

På grunn av deres størrelse er det også mulig med en sortering over en sikt. Due to their size, it is also possible to sort over a sieve.

Claims (5)

1. Fremgangsmåte til rensing av det vaske- eller avvann som fremkommer ved opparbeidelse av gammelt papir for fremmedstoffer spesielt for stoffer som forholder seg hydrofobt,karakterisert vedat vannet som skal renses blandes med kalsiumsåpe og de som samler for de hydrofobt reagerende stoffer virkende kalsiumsåper utskilles ved sedimentasjon, flotasjon, sentrifugering eller utsikting, sammen med de hydrofobt reagerende stoffer og det rensede vann tilbakeføres igjen i oppberedningsprosessen.1. Procedure for purifying the washing or waste water that arises from the processing of old paper for foreign substances, especially for substances that are hydrophobic, characterized by the fact that the water to be cleaned is mixed with calcium soap and those that collect for the hydrophobically reacting substances acting calcium soaps are separated by sedimentation, flotation, centrifugation or screening, together with the hydrophobically reacting substances and the purified water are returned to the preparation process. 2. Fremgangsmåte ifølge krav 1,karakterisert vedat kalsiumsåpene behandles med terpeniske hydrokarboner eller deres alkoholer, alifatiske eller aromatiske hydrokarboner eller deres alkoholer, resp. deres blanding. 2. Method according to claim 1, characterized in that the calcium soaps are treated with terpenic hydrocarbons or their alcohols, aliphatic or aromatic hydrocarbons or their alcohols, resp. their mixture. 3. Fremgangsmåte ifølge krav 1 eller 2,karakterisert vedat det som bærestoff for kalsiumsåpen anvendes stoffer med spesifikk stor overflate, på hvis overflate påføres en såpe som deretter omdannes i en kalsiumsåpe. 3. Method according to claim 1 or 2, characterized in that substances with a specific large surface are used as a carrier for the calcium soap, on the surface of which a soap is applied which is then converted into a calcium soap. 4. Fremgangsmåte ifølge krav 1 eller 2 til rensing av vaskevann ved vaske-"deinken",karakterisert vedat vaskevannet blandes i en blandebeholder med kalsiumsåpe og i et etterfølgende skilletrinn foregår adskillelsen av vannet fra de til kalsiumsåpen vedhengende forurensning. 4. Method according to claim 1 or 2 for purifying washing water at the washing "deinken", characterized in that the washing water is mixed in a mixing container with calcium soap and in a subsequent separation step the water is separated from the contamination attached to the calcium soap. 5. Fremgangsmåte ifølge krav 4,karakterisertved at det som skilletrinn anvendes en eller flere hydrocykloner.5. Method according to claim 4, characterized in that one or more hydrocyclones are used as the separating step.
NO790263A 1978-01-28 1979-01-26 PROCEDURE FOR CLEANING THE WASHING AND WASTE THAT APPEARS IN PREPARATION OF OLD PAPER NO790263L (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19782803700 DE2803700A1 (en) 1978-01-28 1978-01-28 METHOD OF CLEANING WASHER OR WASTE WATER FROM RECEIVING PAPER

Publications (1)

Publication Number Publication Date
NO790263L true NO790263L (en) 1979-07-31

Family

ID=6030596

Family Applications (1)

Application Number Title Priority Date Filing Date
NO790263A NO790263L (en) 1978-01-28 1979-01-26 PROCEDURE FOR CLEANING THE WASHING AND WASTE THAT APPEARS IN PREPARATION OF OLD PAPER

Country Status (10)

Country Link
JP (1) JPS54110652A (en)
AT (1) AT362321B (en)
DE (1) DE2803700A1 (en)
ES (1) ES477150A1 (en)
FI (1) FI790245A (en)
FR (1) FR2415606A1 (en)
GB (1) GB2013169A (en)
IT (1) IT1110985B (en)
NO (1) NO790263L (en)
SE (1) SE7900652L (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3914146A1 (en) * 1989-04-28 1990-10-31 Baehre & Greten Disposal of flushing water produced in mfr. of composite wood prods. - by absorbing waste water into wood particles forming raw material for mfg. process
DE69333941T2 (en) * 1992-12-23 2006-06-14 Imerys Minerals Ltd Process for the treatment of waste suspensions
DE69408807T2 (en) * 1993-12-14 1998-06-18 Ecc Int Ltd Water and solids recovery in a paper mill
JP5252485B2 (en) * 2008-05-12 2013-07-31 中越パルプ工業株式会社 Method for producing deinked pulp and deinking aid used therefor
JP5215799B2 (en) * 2008-09-30 2013-06-19 東邦化学工業株式会社 Pitch remover

Also Published As

Publication number Publication date
JPS54110652A (en) 1979-08-30
IT7919243A0 (en) 1979-01-12
DE2803700A1 (en) 1979-08-02
FI790245A (en) 1979-07-29
SE7900652L (en) 1979-07-29
FR2415606A1 (en) 1979-08-24
ES477150A1 (en) 1979-07-01
AT362321B (en) 1981-04-27
GB2013169A (en) 1979-08-08
ATA812678A (en) 1980-09-15
IT1110985B (en) 1986-01-13

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