NO782258L - Fremgangsmaate for fremstilling av en ticl3-katalysator for polymerisering - Google Patents

Fremgangsmaate for fremstilling av en ticl3-katalysator for polymerisering

Info

Publication number: NO782258L
Authority: NO; Norway
Prior art keywords: iodine; titanium trichloride; formula; stated; compound
Prior art date: 1977-06-30

Application number

NO782258A

Other languages

English (en)

Norwegian (no)

Inventor

Akinobu Shiga

Yoshiharu Fukui

Kazuhiro Matsumura

Toshio Sasaki

Masahisa Okawa

Original Assignee

Sumitomo Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-06-30

Filing date

1978-06-29

Publication date

1979-01-03

1978-06-29 Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co

1979-01-03 Publication of NO782258L publication Critical patent/NO782258L/no

Links

238000000034 method Methods 0.000 title claims description 39
239000002685 polymerization catalyst Substances 0.000 title 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 85
239000003054 catalyst Substances 0.000 claims description 74
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 67
239000011630 iodine Substances 0.000 claims description 64
229910052740 iodine Inorganic materials 0.000 claims description 64
239000007787 solid Substances 0.000 claims description 61
-1 ether compound Chemical class 0.000 claims description 51
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 48
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 46
150000001875 compounds Chemical class 0.000 claims description 36
230000009467 reduction Effects 0.000 claims description 33
239000000203 mixture Substances 0.000 claims description 19
230000008569 process Effects 0.000 claims description 19
239000007788 liquid Substances 0.000 claims description 18
229920000098 polyolefin Polymers 0.000 claims description 14
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 13
125000004432 carbon atom Chemical group C* 0.000 claims description 13
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 12
229910052782 aluminium Inorganic materials 0.000 claims description 11
150000001336 alkenes Chemical class 0.000 claims description 10
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 7
125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 7
125000005843 halogen group Chemical group 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
125000001931 aliphatic group Chemical group 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 5
125000003342 alkenyl group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
125000004122 cyclic group Chemical group 0.000 claims description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
230000003213 activating effect Effects 0.000 claims 3
150000004820 halides Chemical class 0.000 claims 1
150000004678 hydrides Chemical class 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
238000006116 polymerization reaction Methods 0.000 description 23
238000006243 chemical reaction Methods 0.000 description 21
229920000642 polymer Polymers 0.000 description 21
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 18
239000000243 solution Substances 0.000 description 17
239000002904 solvent Substances 0.000 description 15
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 13
230000003197 catalytic effect Effects 0.000 description 13
229930195733 hydrocarbon Natural products 0.000 description 12
150000002430 hydrocarbons Chemical class 0.000 description 11
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical group [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
239000004215 Carbon black (E152) Substances 0.000 description 10
239000000047 product Substances 0.000 description 10
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
238000003756 stirring Methods 0.000 description 10
239000011259 mixed solution Substances 0.000 description 9
230000000694 effects Effects 0.000 description 8
239000010936 titanium Substances 0.000 description 8
230000001976 improved effect Effects 0.000 description 7
150000002497 iodine compounds Chemical class 0.000 description 7
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 6
238000005406 washing Methods 0.000 description 6
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
229920006125 amorphous polymer Polymers 0.000 description 5
229910052786 argon Inorganic materials 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 4
239000012298 atmosphere Substances 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
230000006872 improvement Effects 0.000 description 4
238000000926 separation method Methods 0.000 description 4
239000011949 solid catalyst Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
238000009835 boiling Methods 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
230000004913 activation Effects 0.000 description 2
239000012190 activator Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000008139 complexing agent Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
150000002899 organoaluminium compounds Chemical class 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
NMLLTHLOSVNFMY-UHFFFAOYSA-N 1-butoxy-3-methylbutane Chemical compound CCCCOCCC(C)C NMLLTHLOSVNFMY-UHFFFAOYSA-N 0.000 description 1
PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
YGZQJYIITOMTMD-UHFFFAOYSA-N 1-propoxybutane Chemical compound CCCCOCCC YGZQJYIITOMTMD-UHFFFAOYSA-N 0.000 description 1
LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ITTNLYCDPKZOOU-UHFFFAOYSA-N CC[Al](C1CCCCC1)C1CCCCC1 Chemical compound CC[Al](C1CCCCC1)C1CCCCC1 ITTNLYCDPKZOOU-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
239000013078 crystal Substances 0.000 description 1
JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
238000012674 dispersion polymerization Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
238000011835 investigation Methods 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
229940006461 iodide ion Drugs 0.000 description 1
SZNYYWIUQFZLLT-UHFFFAOYSA-N isopropylmethyl ether Natural products CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
FVUDRZSBJPQJBX-UHFFFAOYSA-N n-Butyl-n-pentyl-aether Natural products CCCCCOCCCC FVUDRZSBJPQJBX-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
125000002734 organomagnesium group Chemical group 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
230000005070 ripening Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO782258A 1977-06-30 1978-06-29 Fremgangsmaate for fremstilling av en ticl3-katalysator for polymerisering NO782258L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7865577A JPS5411985A (en)	1977-06-30	1977-06-30	Preparation of olefin polymer

Publications (1)

Publication Number	Publication Date
NO782258L true NO782258L (no)	1979-01-03

Family

ID=13667864

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO782258A NO782258L (no)	1977-06-30	1978-06-29	Fremgangsmaate for fremstilling av en ticl3-katalysator for polymerisering

Country Status (16)

Country	Link
US (2)	US4246135A (fr)
JP (1)	JPS5411985A (fr)
AR (1)	AR221486A1 (fr)
BE (1)	BE868565A (fr)
BR (1)	BR7804066A (fr)
CA (1)	CA1120022A (fr)
DE (1)	DE2827999A1 (fr)
ES (1)	ES472025A1 (fr)
FR (1)	FR2395778A1 (fr)
GB (1)	GB2000513A (fr)
GR (1)	GR64977B (fr)
IT (1)	IT1105048B (fr)
NL (1)	NL7807022A (fr)
NO (1)	NO782258L (fr)
PT (1)	PT68242A (fr)
YU (1)	YU154878A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1162495B (it) *	1978-12-28	1987-04-01	Sumitomo Chemical Co	Prodimenzo per produrre copolimeri di propilene
US4382018A (en) *	1979-06-27	1983-05-03	Dart Industries, Inc.	Method for making titanium trichloride catalysts
JPS5922913A (ja) *	1982-07-15	1984-02-06	Chisso Corp	高剛性成形品用ポリプロピレン樹脂
JPS59122506A (ja) *	1982-12-28	1984-07-16	Sumitomo Chem Co Ltd	軟質プロピレン重合体
EP0121011A1 (fr) *	1983-03-30	1984-10-10	Sumitomo Chemical Company, Limited	Procédé de préparation d'un catalyseur solide à base de trichlorure de titane
EP0324835B1 (fr) *	1987-07-10	1992-12-02	Quantum Chemical Corporation	Procede et catalyseur de polymerisation du propylene
AU6147398A (en) *	1997-02-05	1998-08-25	Penn State Research Foundation, The	Metal catalyzed synthesis of hyperbranched ethylene and/or alpha-olefin polymers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3129256A (en) *	1959-12-01	1964-04-14	Gulf Research Development Co	Alkylation of benzene with propylene in the presence of a catalyst containing titanium tetrachloride, alkyl aluminum sesquichloride, and oxygen
US3409681A (en) *	1964-06-25	1968-11-05	Exxon Research Engineering Co	Method of making novel bimetallic heterogeneous catalysts and their use in hydrocarbon conversions
US3414554A (en) *	1965-07-06	1968-12-03	Phillips Petroleum Co	Polymerization process and catalyst
US3558271A (en) *	1969-06-25	1971-01-26	Benedetto Calcagno	Method of preparing catalytically active ticl3
US3865749A (en) *	1973-08-30	1975-02-11	Exxon Research Engineering Co	Butadiene polymerization catalyst
US4060593A (en) *	1974-07-31	1977-11-29	Mitsubishi Chemical Industries	Preparation of titanium trichloride

1977
- 1977-06-30 JP JP7865577A patent/JPS5411985A/ja active Pending
1978
- 1978-06-26 DE DE19782827999 patent/DE2827999A1/de not_active Withdrawn
- 1978-06-26 BR BR787804066A patent/BR7804066A/pt unknown
- 1978-06-27 CA CA000306335A patent/CA1120022A/fr not_active Expired
- 1978-06-27 GB GB7828064A patent/GB2000513A/en not_active Withdrawn
- 1978-06-28 IT IT50068/78A patent/IT1105048B/it active
- 1978-06-28 GR GR56620A patent/GR64977B/el unknown
- 1978-06-29 NL NL7807022A patent/NL7807022A/xx not_active Application Discontinuation
- 1978-06-29 PT PT68242A patent/PT68242A/pt unknown
- 1978-06-29 YU YU01548/78A patent/YU154878A/xx unknown
- 1978-06-29 BE BE188925A patent/BE868565A/fr not_active IP Right Cessation
- 1978-06-29 NO NO782258A patent/NO782258L/no unknown
- 1978-06-29 AR AR272756A patent/AR221486A1/es active
- 1978-06-30 ES ES472025A patent/ES472025A1/es not_active Expired
- 1978-06-30 FR FR7819721A patent/FR2395778A1/fr active Granted
1979
- 1979-05-23 US US06/041,972 patent/US4246135A/en not_active Expired - Lifetime
1980
- 1980-07-08 US US06/166,873 patent/US4304892A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
AR221486A1 (es)	1981-02-13
PT68242A (en)	1978-07-01
US4246135A (en)	1981-01-20
JPS5411985A (en)	1979-01-29
IT1105048B (it)	1985-10-28
US4304892A (en)	1981-12-08
IT7850068A0 (it)	1978-06-28
ES472025A1 (es)	1980-01-01
NL7807022A (nl)	1979-01-03
DE2827999A1 (de)	1979-01-18
BE868565A (fr)	1978-10-16
CA1120022A (fr)	1982-03-16
GB2000513A (en)	1979-01-10
FR2395778A1 (fr)	1979-01-26
GR64977B (en)	1980-06-11
BR7804066A (pt)	1979-05-22
FR2395778B1 (fr)	1982-01-22
YU154878A (en)	1982-06-30

Publication	Publication Date	Title
EP0136163B1 (fr)	1988-09-14	Procédé pour la polymérisation des oléfines
CA1162526A (fr)	1984-02-21	Matiere composite et sa preparation, catalyseur, methode de production du catalyseur, et procede de polymerisation a l'aide dudit catalyseur
CA1102048A (fr)	1981-05-26	Traduction non-disponible
US4235984A (en)	1980-11-25	Process for producing highly stereoregular α-olefin polymers
US4175171A (en)	1979-11-20	Catalyst for polymerizing α-olefins
EP0778291B1 (fr)	2001-03-28	Catalyseur et procédé pour préparer des polymères de diènes conjugués
CA1140913A (fr)	1983-02-08	METHODE D'OBTENTION DE POLYMERES .alpha.-OLEFINIQUES A DISPOSITION STERIQUE TRES REGULIERE
EP0115833B1 (fr)	1991-08-07	Procédé de préparation de polyoléfines par polymérisation et catalyseurs utilisés
NO160786B (no)	1989-02-20	Katalysator til polymerisering av alkener og anvendelse av katalysatoren til polymerisering av propen.
US4123387A (en)	1978-10-31	Catalysts for polymerization of olefins
NO782258L (no)	1979-01-03	Fremgangsmaate for fremstilling av en ticl3-katalysator for polymerisering
US4533706A (en)	1985-08-06	Catalyst and process using same for producing olefin polymer
EP0139969A2 (fr)	1985-05-08	Procédé pour la polymérisation d'oléfines et catalyseur
CA1079485A (fr)	1980-06-17	Composant de catalyseur au trichlorure de titane
NO171317B (no)	1992-11-16	Katalysatorsystem for fremstilling av en alfa-olefinpolyme
EP0493070A2 (fr)	1992-07-01	Composition à base d'un copolymère éthylène-propylène
US4217432A (en)	1980-08-12	Process for the polymerization of olefins
US4563511A (en)	1986-01-07	Polyolefin polymerization process and catalyst
US3494910A (en)	1970-02-10	Process for polymerizing alpha-olefins utilizing a novel ternary catalyst
JP3248385B2 (ja)	2002-01-21	オレフィン（共）重合用触媒及びオレフィン（共）重合体の製造方法
JPS591285B2 (ja)	1984-01-11	アルフア − オレフインノジユウゴウホウホウ
NO842961L (no)	1985-01-22	Katalysator for polymerisering av alfa-olefiner, samt anvendelse av en slik katalysator
CA1118147A (fr)	1982-02-09	Methode de preparation de l'element catalyseur pour la polymerisation des olefines
Galimberti et al.	1993	Transition-metal organometallic compounds as cocatalysts in olefin polymerization with magnesium chloride-supported catalysts
JPH0689071B2 (ja)	1994-11-09	非晶質プロピレン−エチレン共重合体